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Insights into karst groundwater- stream interactions using dissolved natural radon concentrations, Central Texas Stephanie S. Wong and Joe C. Yelderman Jr. Department of Geology | Baylor University | One Bear Place #97354 | Waco TX 76798 [email protected] Presented at the NGWA Groundwater Summit 2015 Monday, 16 March, 2015 || San Antonio, Texas

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Page 1: Insights into karst groundwater- stream interactions using ...staging.cuwcd.org/pdf/Aquifer-Science/CUWCD... · Below dam: 80 194. Salado Creek Big Boiling Springs Spring, 2014 160

Insights into karst groundwater-stream interactions using dissolved

natural radon concentrations, Central Texas

Stephanie S. Wong and Joe C. Yelderman Jr.Department of Geology | Baylor University | One Bear Place #97354 | Waco TX 76798

[email protected]

Presented at the NGWA Groundwater Summit 2015Monday, 16 March, 2015 || San Antonio, Texas

Page 2: Insights into karst groundwater- stream interactions using ...staging.cuwcd.org/pdf/Aquifer-Science/CUWCD... · Below dam: 80 194. Salado Creek Big Boiling Springs Spring, 2014 160

Outline

• Background – Groundwater/Surface water interactions in karst– Setting– Natural radon (Rn-222)– Research question

• Methods• Results• Conclusions• Acknowledgements

2

Page 3: Insights into karst groundwater- stream interactions using ...staging.cuwcd.org/pdf/Aquifer-Science/CUWCD... · Below dam: 80 194. Salado Creek Big Boiling Springs Spring, 2014 160

Groundwater / Surface Water Interactions in Karst Systems

streamflowwatercress

3

Page 4: Insights into karst groundwater- stream interactions using ...staging.cuwcd.org/pdf/Aquifer-Science/CUWCD... · Below dam: 80 194. Salado Creek Big Boiling Springs Spring, 2014 160

Northern Segment

Barton Springs Segment

San Antonio Segment

Setting: The Edwards BFZ Aquifer

SALADO

SAN ANTONIO

AUSTIN

4(I-35 CAC, 2011)

Page 5: Insights into karst groundwater- stream interactions using ...staging.cuwcd.org/pdf/Aquifer-Science/CUWCD... · Below dam: 80 194. Salado Creek Big Boiling Springs Spring, 2014 160

Setting: The Edwards BFZ Aquifer

5

0

50,000

100,000

150,000

200,000

250,000

300,000

350,000

201320101990198019701960

Popu

latio

n

(United States Census Bureau, 2015)

2013: 326,843

Bell County Population

What are the impacts of construction and

increasing resource demands on the aquifer?

(I-35 CAC, 2011)

Page 6: Insights into karst groundwater- stream interactions using ...staging.cuwcd.org/pdf/Aquifer-Science/CUWCD... · Below dam: 80 194. Salado Creek Big Boiling Springs Spring, 2014 160

Setting: The Northern Segment, Edwards BFZ Aquifer

A A’

SALADO

AUSTIN

AUSTIN CHALK

EAGLE FORD GROUP

BUDA LIMESTONESDEL RIO CLAY

EDWARDS LIMESTONES

WALNUT FORMATION

Outcrop portion

Down-dip portion

Bell

Milam

Williamson

Bastrop

Travis

Burnet

Hays

6

Page 7: Insights into karst groundwater- stream interactions using ...staging.cuwcd.org/pdf/Aquifer-Science/CUWCD... · Below dam: 80 194. Salado Creek Big Boiling Springs Spring, 2014 160

Study area: Salado Springs complex

Big BoilingSpring

Anderson Spring

Critchfield Spring

Doc Benedict Spring

Little Bubbly Spring

• Historical – stage stop• Present – local landmark

(tourism)• Habitat for Salado

salamander, E. chisolmensis• Local groundwater

management measure USGS stream gage

7

Big Boilingsprings

Salado salamander

Page 8: Insights into karst groundwater- stream interactions using ...staging.cuwcd.org/pdf/Aquifer-Science/CUWCD... · Below dam: 80 194. Salado Creek Big Boiling Springs Spring, 2014 160

Big BoilingSpring

Anderson Spring

Critchfield Spring

Doc Benedict Spring

Little Bubbly Spring

USGS stream gage

8

Study area: Salado Springs complex• Historical – stage stop• Present – local landmark

(tourism)• Habitat for Salado

salamander, E. chisolmensis• Local groundwater

management measure

Page 9: Insights into karst groundwater- stream interactions using ...staging.cuwcd.org/pdf/Aquifer-Science/CUWCD... · Below dam: 80 194. Salado Creek Big Boiling Springs Spring, 2014 160

Radon‐222

• Naturally-occurring; trace amounts in soils and geology

• Radioactive alpha decay product of radium-226 (uranium-238 series)

• Rapid dispersal from groundwater to atmosphere

• Applications (over short time scales): apparent age estimation, infiltration rates, discharge location and magnitude, fracture aperture estimation, contamination studies

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222Rn Half-life = 3.8 days

Page 10: Insights into karst groundwater- stream interactions using ...staging.cuwcd.org/pdf/Aquifer-Science/CUWCD... · Below dam: 80 194. Salado Creek Big Boiling Springs Spring, 2014 160

No Rn-222

Increasing Rn-222Decreasing Rn-222

Radon‐222 conceptual model

(Ref.: Stellato et al., 2012; Neupane et al., 2014; Hoehn and Von Gunten, 1989) 10

Is this true at Salado Creek?

Equilibrium

Distance or time since infiltration

Rn-

222

Distance or time since discharge

Rn-

222

Page 11: Insights into karst groundwater- stream interactions using ...staging.cuwcd.org/pdf/Aquifer-Science/CUWCD... · Below dam: 80 194. Salado Creek Big Boiling Springs Spring, 2014 160

Methods: field sampling

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• Sampling:– Zero headspace– Sampling depth (~6 in)

• Focused sampling:– Salado Creek – Salado Springs complex

• Monitoring samples:– Big Boiling springs/Salado

Creek

Page 12: Insights into karst groundwater- stream interactions using ...staging.cuwcd.org/pdf/Aquifer-Science/CUWCD... · Below dam: 80 194. Salado Creek Big Boiling Springs Spring, 2014 160

Methods: analysis

RAD7 with the RAD H2O accessory

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• Analysis within 24 hours• Instrument: RAD7• Solid state alpha detector

– Conversion of alpha radiation to an electrical signal

Page 13: Insights into karst groundwater- stream interactions using ...staging.cuwcd.org/pdf/Aquifer-Science/CUWCD... · Below dam: 80 194. Salado Creek Big Boiling Springs Spring, 2014 160

Radon concentration: Salado Creek basin(May‐June 2014)

127

3

8529

5

35 5 39 2

60113

80

LK STILLHOUSEHOLLOW

I‐35

I‐195

13* Radon concentrations are in pCi/L

222 R

n (p

Ci/L

)

5

125

127

3

85

295

35

5 3 9 2

60

113

80

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Big BoilingSpring

Anderson Spring

Critchfield Spring

Doc Benedict SpringLittle Bubbly

Spring

238 228

15893

179

180

MEAN RADON CONCENTRATION:

Groundwater = 190 pCi/LSurface water = 84 pCi/L

Radon concentration: Salado Springs(March 2014)

14

* Radon concentrations are in pCi/L

58

USGS Stream Gage

Above dam: 104

Below dam: 80

194

Page 15: Insights into karst groundwater- stream interactions using ...staging.cuwcd.org/pdf/Aquifer-Science/CUWCD... · Below dam: 80 194. Salado Creek Big Boiling Springs Spring, 2014 160

Salado Creek

Big Boiling Springs

Spring, 2014

160

62

113

Autumn, 2014

164

44

102

Radon concentration: seasonal patterns

15

* Radon concentrations are in pCi/L

050

100150200

1 2 3

Rn-

222

050

100150200

1 2 3

Rn-

222

Page 16: Insights into karst groundwater- stream interactions using ...staging.cuwcd.org/pdf/Aquifer-Science/CUWCD... · Below dam: 80 194. Salado Creek Big Boiling Springs Spring, 2014 160

Salado Creek

Big Boiling Springs

Radon concentration: seasonal patterns

Season Modeled GW flow (cfs)

Observed GW flow (cfs)

Spring 2014 3.23 1.64

Autumn 2014 1.79 1.1

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(Lee and Hollyday, 1991)

Page 17: Insights into karst groundwater- stream interactions using ...staging.cuwcd.org/pdf/Aquifer-Science/CUWCD... · Below dam: 80 194. Salado Creek Big Boiling Springs Spring, 2014 160

Decreasing Rn-222

Distance or time since discharge

Rn-

222

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1. Clear difference between groundwater and surface water Rn‐222 concentrations at downtown Salado

Increasing Rn-222

Distance or time since infiltration

Rn-

222

Equilibrium

0 pCi/L

84 pCi/L190 pCi/L

• Complimented by other field measurements, Rn-222 concentration allow identification, confirmation, and monitoring of groundwater discharge sites

Cascade

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2. Rn‐222 concentrations at Salado Springs support stream gauge site

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Big BoilingSpring

Anderson Spring

Critchfield Spring

Doc Benedict SpringLittle Bubbly

Spring

USGS stream gage

• No major groundwater addition after Salado Springs

• Additional geochemical and dye trace data indicate spring connectivity

• Stream gauge location is suitable for aquifer monitoring

Page 19: Insights into karst groundwater- stream interactions using ...staging.cuwcd.org/pdf/Aquifer-Science/CUWCD... · Below dam: 80 194. Salado Creek Big Boiling Springs Spring, 2014 160

3. The use of Rn‐222 as a natural tracer is relevant in a critical habitat setting

Big BoilingSpring

Anderson Spring

Critchfield Spring

Doc Benedict Spring

Little Bubbly Spring

• Short half-life – useful in karst system

• Relatively quick analysis turn-around time

• Natural tracers are useful in critical habitat settings

USGS stream gage

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Salado salamander

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Page 21: Insights into karst groundwater- stream interactions using ...staging.cuwcd.org/pdf/Aquifer-Science/CUWCD... · Below dam: 80 194. Salado Creek Big Boiling Springs Spring, 2014 160

Sources• Cecil, L.D. and J.R. Green, 2000, Radon-222. In Environmental Tracers in Subsurface Hydrology. P. Cook, and

A.L. Herczeg (eds.), pp. 175-194.• Cothern, C.R. and J.E. Smith, Jr., 1987, Environmental Radon, Environmental Science Research Volume 35.

Plenum Press, New York. 363 p.• Durrance, E.M., 1986, Radioactivity in Geology. Ellis Horwood Limited, Chichester, 441 p.• Durridge Company, 2014, RAD7 Radon Detector User Manual. Durridge Company Inc., Billerica, Massachusetts.• Ellins, K.K., A. Roman-Mas, and R. Lee, 1990, Using 222Rn to examine groundwater/surface discharge interaction

in the Rio Grande de Manati, Puerto Rico. Journal of Hydrology, 114(1-4):319-341.• Hoehn E. and H.R. Von Gunten, 1989, Radon in groundwater: a tool to assess infiltration from surface waters into

aquifers. Water Resources Research, 25(8):1795-1803.• Interstate 35 Corridor Advisory Committee (I-35 CAC), 2011, I-35 Corridor Advisory Committee Plan.

<http://ftp.dot.state.tx.us/pub/txdot-info/my35/advisory_plan.pdf> Last accessed 11 March, 2015.• Lee, R.W. and E.F. Hollyday, 1991, Use of radon measurements in Carters Creek, Maury County, Tennessee, to

determine location and magnitude of groundwater seepage. In Field Studies of Radon in Rocks, Soils, and Water. L.C.S. Gundersen and R.B. Wanty (eds.), pp.237-242. C.K. Smoley, Boca Raton, Florida.

• Neupane, R.P., J.D. White, P.M. Allen, and S.I. Dworkin, 2014, A snapshot comparison of environmental tracers for estimating groundwater contribution to recession flow in a mountain stream. Hydrological Processes, in press.

• Stellato, L., F. Terrasi, F. Marzaioli, M. Belli, U. Sansone, and F. Celico, 2013, Is 222Rn a suitable tracer of stream-groundwater interactions? A case study in central Italy. Applied Geochemistry, 32:108-117.

• Torgersen, T., J. Benoit, and D. Mackie, 1992, Lithological control of groundwater 222Rn concentrations in gractured rock media. In Isotopes of Nobel Gases as Tracers in Environmental Studies, pp.263-287.IAEA, Vienna.

• United States Census Bureau, 2015, State and County QuickFacts. <http://quickfacts.census.gov/qfd/states/48/48027.html> Last accessed 10 March, 2015.

• Photo credits: P. Diaz, S. Wong, J.C. Yelderman Jr.

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