removal assessment report - appendix g -lab data sheets

Data Fila: /chem/5972hp60*i/DF020314B60*b/QE1877-3RBb0.d

Date : 14-MAR-2G02 22:59

Client ID: MU-8ARE

Sample Info:

Volume Injected <uL>: 1*0

Column phase: J&W DE-5*625

Instrument: 5972hp60*i

Operator: 2319

Column diameter: 0*32

CD■^T

30225964

Data Fi let /chem/5972hp60. i/DF02Ci3i4B60*b/QEl877-3RB&0*d

Date t 14-MAR-2002 22:59

Client ID: MW-8ARE

Sample Info:

Volume Injected CuL): 1*0

Column phase: J&W DB-5.625

Instrument: 5972hp60.i

Operator: 2319

Column diameter: 0.32

o

18 21 22

Data File: /chem/5972hp60.i/DF020314B60.b/QE1877-3RB60.dReport Date: 15-Mar-2030 12:14

CompuChem

Data file Lab Smp Id Inj Date'Operator Smp Info Misc Info Comment .Method Meth Date Cal Date Als bottle Dil Factor Integrator Target Version: 3.50

Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020314B60.b/QE1877-3RB60.d QE1877-3 Client Smp ID: MW-8ARE14-MAR- 2 0 0 2 22:592319 Inst ID: 5972hp60.i

/chem/5 9 72hp6 0.i/DF02 0314B6 0,b/82 70Cv6.m 15-Mar-2030 10:11 byrd Quant Type: ISTD0 3-MAR- 2 0 0 2 17:20 Cal File: HL020303A60.d51.00000HP RTE Compound Sublist: OLM03 sub

Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable

Name Value Description

DFVtVoVi

1.00000 500.00000500.000001.00000

Dilution Factor Volume of final extract (uL) Volume of sample extracted (mL) Volume injected (uL)

Cpnd Variable Local Compound Variable

CONCENTRATIONS

OUANT SIG ON-COLUMN FINAL

Compounds MASS RT EX 7 RT REL RT RESPONSE ( NG) ( ug/L) SIMILARITY

* 1 1 , 4 - D i cdc: c/cer. crc.e - d4 152 8.13 9 -j o o o 90055 40.0000

: ■ .ir 13 6 10 2 8 8 1 0 . 235 ( 1 . 000 251806 40.0000

: -a:.: 164 13 . 3 3 7 : . 364 ::.0 0 0• 209733 40.0000

■i :i1 ‘ 1 5 5 c n 7 -.5 . 3 8“ t1.000 = 418204 40.0000

:6-'7 2 i: •:. o o: 437640 4 0 . 0000

: 1 . : 7 ■; : 1 7 v , ; dn • 336171 40.0000

: " 1 . - •: . 7, ' 742. 534190 186 405 1 c 5 4iAMJ ^

r Pr-.r.c' ■ c. 7 5 d 4 377 .1:5, i 33930 41.4158 41.42

: :■ • .i; 32 7.-7 7 = = 0; 97921 27 . 197 8 27.20 ■;r )

V :: l-Elucrodicdecv: 1 ~>Z 12 .: e i 229315 28 . i838 2 8.18 i R :

: 1 1 2 .4 ■. :■ :-:rop^nc; 3 3 0 14 .7^4 : 4. 7-1-9 -. 1.104 179627 9 1 . 0287 91.03 (Mi ’

244 13.78'.: 1 3 . 7 7 3 1 C . 9111 479876 39 . 5056 39.51 (R )

-94 Ccmpc ur.d Not. Detected

Els : u - cr.::r.y i 'Adde:' 3 3 Cohdcu r.c Noe Detected

'•-Chiorop.-icr.c.: 128 C Off; pc ur.a Not Detected

40a


Compounds

19 1,3-Dichlorobenzene

2C 1,4-Dichlorobenzene

22 1.2-Dichlorobenzene

2 3 2 - Met hy lphe.no 1

24 2,2'-cxyb:s(1 -Chloropropane)

2~> 4 -MethylphencI

26 N-Nitroso-di-N-propylamine

29 Hexachloroethane

30 Nitrobenzene

31 Isophorone

32 2-Nitrophenol

33 2,4-Dimethylphenol

34 Eis (2-chloroethoxy)methane

35 2,4-Dichlorophenol

36 1,2,4-Trichlorobenzene

37 Naphthalene

38 4-Chloroani1ine

35 Hexachiorobutadiene

414-Chioro-3-methylphenol

4 2 2-Methy Inaphtha 1ene

44 Hexacnlorocyclopentadiene

4 5 2.4,6 -Trich1oropheno1

46 2,4,5-Trichioropheno1

5 1 2 , 6 - D i n 1 r o : o. u e:e

5 2 Ac e n a pr. t ny lent

5 3 3 - N: c roan i; r.e

54 Acenaphtheue

5 5 2 . 4 - Dm: : rop.oenc i

5 5 4 - N’: t ropner.o 1

5.7 2 , 4 • D: r.; t r o t c 1 u e n e

58 Pibenzofurar.

5 5 C'lethy 1 pht ha la t e

60 4 • Ch 1 oropheny 1 - pher.y i et.ner

51 ~luorene

6 2 4 • N11roan: 1 ::".e6 3 4 , 6 - D: r.: : ro - 2 - me t hy: pheno 1

6 4 N - N •. t msec •„oheny lamine

65 4 - Bromopher/.h - pher.y 1 et her

?7 Hexach:orober.zene

6? Pencach1oropheno1

7 C P h e n ant r. r e r, e

QUANT SIG

MASS RT EXP RT REL RT

146 Compound Not Detected











122 9.729 9.727 (0 . 946)








14 2 Compound Not Detected






1 6 3 Compound Not Detected








CTi

Compound Not Detected







24 S Compound No: Detected


2 6 6 Compound Detected

17 a Compound Not Detected

-.73 Compound N't t Detected


149 Comccuud Not Detected

RESPONSE

35268

CONCENTRATIONS

ON-COLUMN FINAL

{ NG) ( ug/L)

18.8473 18.85

SIMILARITY

8188

40o


Compounds

74 Fluoranthene

76 Pyrene

77 Butylbenzylphthalate

78 3,3'-Dichlorobenzidine

7 9 bis (2-ethylhexyl)Phthalate

8C Eenzoia)anthracene

SI Chrysene

3 2 C:-n-cct y1pnt ha late

63 Eenzo{b)f1uorant bene

34 Eenzo:k' fluoranthene

85 Eenzo (a •• pyrene

3 6 Indenc;1,2,3 -cd!pyrene

87 Dibenzcla , h)anthracene

38 Eenzo >g , h , : ) pery lene

QUANT SIG

MASS RT EXP RT 1REL RT





149 20.574 20.588 (0.998)










RESPONSE

15356

CONCENTRATIONS

ON-COLUMN FINAL

( NG) ( ug/L) SIMILARITY

9304 (

QC Flag Legend

a

A

#

Target compound detected but, quantitated amount Below Limit Of Quantitation(BLOQ).Target compound detected but, quantitated amount exceeded maximum amount.Spike/Surrogate failed recovery limits.Compound response manually integrated.

404

Data File: /chem/5972hp60.1/DF020314B60.b/QE1877-3RB60.d Injection Date: 14-MAR-2002 22:59 Instrument: 5972hpb0.i Client Sample ID: MLI-8ARE

ouna: 2 Number:

-F luorophenol 367-12-4

Ion 112.00: Area: 534190 Height: 301504

1.8-m 1.6-

~ 1.4-

1.2 1.0

j 0.8 | 0.6 : 0.4-

0.2' 0.0-

5.55 5.60 5.65 5.70 5.75 5.80 5.85 5.90 5.95 6.00 6.05 6.10' 6.15 6.20 6.25 6.30 6.35 6.40 6.45 6.50Min

Ion 64.00: Area: Height: 0

5.55 5.60 5.65 5.75 5.80 5.85 5.90 5.95 6.00 6.05 6.10 6.15 6.20 6.25 6.30 6.35 6.40 6.45 6.50

MinIon 92.00: Area: Height: 0

1

5.55 5.60 5.05 5.70 5.75 5.80

i£b6.05 6.10 6.15 6.20 6.2 6.30 6.35 6.40 6.45 6.50

Data file: /chem/5972hp60.i/DF0203l4B60.b/QE1877-3RB60.dInjection Date: 14-MAR-2002 22:59Instrument: 5972hp60.iClient Sample ID: MU-8ARE

ound: 2.4.6-T nbromophenoiMumper: 116-79-6

T-

Ion 329.60; Area: 179627 Height: 116767

0.0-

1.1-

1 . o-

14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.BO 14.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20 15.25 iMin I

Ion 332.00: Area: 0 Height: 0

14.55 14.60 14.65 14.70 14.M l n

14.80 14.85 14.90 14.95 15.00 15.05 15.1':' 15.15 15.20 1e:

Height:

4

: 4.30 : 4 . ;.3 1 4.4H 14.45 14.50 14.55 14.60 14.65 14.70 1

40 0

’5 14.80 1-1.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20 15.25

Data Filar /ehem/5972hpb0*i/DF020314B60*b/QE1377-3RB60*d

Date : 14-MAR-2002 22:59

C1 i ant- ID MW-8ARE

■Sample InferVo 1 ume I n j acted <. uL): 1 * 0

Column phaser J&W DB-5*625


Operator: 2319


33 2,4-Dimethylphenol Concentration: 18*85 ug/L

Data File; /chem/5972hp60*i/DF020314B60*b/QE1877-3RB60*d

Date : 14-MAR-2002 22:59

Client ID: MW-8ARE

Sample Info:

Volume Injected <u!_>: 1*0

Column phase: J&U DEs-5*625

Instrument: 5972tip60* i

Operator: 2319


79 bis(2-et-hy lhexy 1 )Phthalate Concentration: 1*36 ug/L

CompuChema Division of Liberty Analytical Corp.

GC/MS SEM1-VOA WORKSHEET

LAB INSTRUCTIONS: PPS 985**'VOC 8260B TCL3CT.SUB**SVOC 8270C TCL3**D1SS. METALS-RPT. As,Cr,Cu & Pb~

FILTER & PRESERVE IN-HOUSE

RECEIPT DATE: 3/6/02 0:00 SAMPLE DATE: 3/5/02 14:30 DUE DATE: 3/18/02 0:00

CASES: Q1877 SDG: QE1877 COMPUCHEM#: QE1877-3 ,

CLIENT ID: MW-8A

ANALYSIS DESCRIPTION: SVOA-8270C

Injection Volume :IpL Dilution Prep (if needed)

Extraction Date___3______ 14____ /___02

DFTPP Filename_____ DF020314B60

Sample File Name_____ QEI877-3^B60______________ ____________

ANALYST (S): Injection2319 Work-up

GC/MS DATE REVIEW

CONDITION CODE ■

■ScfS

Extraneous Peak Search Results:

Number of peaks found: _____

Number of Hits found:________

Number of Surrogate Outliers:

(jualitv Assurance Notice (s)

Number of Nonces Required__

%.

i

Comments:

Disposition: [

[ ] Reinjection Required

ivf Re-extraction Required

[ ] Reinject Neat

[ ] Dilute! X).

=GC. MS Rc\ lew

Final Reportable Packaueis):

Date Z'1 Auditor Date

6) fcr / i'}

40 O'

SV1 -6/27/01: PTF

fyi * M

ASSIGNED TO:

KM I* II) NUMBER:

CompuChem

EXTRACTION WORKSHEET

SEMI-VOI.ATH.E WATER, Method 3510C for 8270C

3 ■ ITDATE F.XTRAL 'TED/POSTEl):

-079

J-' •/ 3::A.-Vy. v.,V;-:”7

SAMPLE FINAL Adjusted pHSAMPLE ‘.

-NUMBER//

ktiC SAMPLE:,

-•:; TYPE 3. VOLUME !■' 3.' (ml)

VOLUME____ 0"Q-

A/N BASE 7:7. COMMENTS ' T)

V

1^/r77-5'K\ hpQ_____ Of ly

'2.jr■^r '

«■* /

■»

1

\ 1 LI f)/0o.f \‘(c 12-5" /

3<6-0J -0-Z,

-X—[Z s / *,<*&} U'^ml kb< S\ f,T

41 /r <!

.£>ol_____OS yv

S/ lb‘ dl M..... IZf

0-----------------JTl 3'0d

OS yy iz- 5

1

1TTT 50^ 03 \.y ll-f

S

Spa 05 \ s V [2.5

9- ¥,

0 o0U 12. 5

73/" <7 V K 7^0 5 ”7 7*,- £ y-7'

0

/^£?22W f 1 ~5dD Of) /z-5 7 ._S7*yY 5-"" /<&

11'/OF K-77--?" <5oo Of Jo— \2-0

■ ................. / /

12-*dT^P*1 ^oc Os ..ia,o

13--------------

14l ft? _

IS \±_1

1(>k \

17

IH

l‘>

:oS'

21

--------------------- ,

23 !//0'1Q^ /y Ri.k^0 J \.y \z.g

24 LCS ~$Ud yoy

*Add 1.0 ml. validation spike to I.( S and SSs unless otherwise noted

S-VOL / Add B/N 8270

FINAL VOLUME VERIFIED:NO. 393 4 317 /,/ .SURROGATE AMT. 1.0 ml (17 7/7'^7

/ fLOT 5? 737- vY — SUPERVISOR REVIEWED: 7;'. ■ K/lU-^X

NO. 3012^ 2021 VALID.

SPIKE AMI l^JHnl 1.0ml 1.0 mlLOT

.jsSSi SURROGATE & SPIKE AUDI 1) lt\ : 7\)v / , 3 ) H ( l/U

Analyst initials Extracted

HtK^

Initials I )ale

Ma ,urer and lot number of reagents/solvcnts used

c £\y<b-

Bottle up Witncs*Initials Date

./Sk_Qti_

QUALITY ASSURANCE NOTICE

CompuChem ID# QE1877-3

Client ID# MW-8A

SDG # QE1877

Surrogate recoveries in the semivolatile fraction fell outside the established Quality Control limits in the analyses of both the original and repeated preparations of this sample. Results were comparable between the two analyses. Since all other QC criteria associated with these analyses were met, we have attributed the out-of - control surrogate recoveries to the particular sample matrix, rather than to deficiencies in the laboratory's analytical system.

Under some circumstances, depending on the client's requirements, both sets of data will be reported. When only one report is required, the analyst considers whether or not the repreparation was completed within holding time specifications in deciding which set of data to report. If holding times were met for both preparations, the analysis that appears to be the least affected by the sample matrix will be reported.

Reviewer's initials/ID /6 24

date 3-15-2002

QAN-VSV-4 S 0 10 0 1

411

FORM 1SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

CLIENT SAMPLE NO.

Lab Name: COMPUCHEM

Lab Code: LIBRTY

Matrix: (soil/water)

Sample wt/vol:

Level: (low/med)

% Moisture: _______

Concentrated Extract

Injection Volume:

Contract:

Case No.: SAS No.:

WATER

1000 (g/mL) ML

LOW

decanted: (Y/N)

Volume: 1000(uL)

1.0(uL)

8270CMW - 9 A

SDG No.: QE1877

Lab Sample ID: QE1877-4

Lab File ID: QE1877-4A64

Date Received: 03/06/02

Date Extracted:03/08/02

Date Analyzed: 03/13/02

Dilution Factor: 1.0

GPC Cleanup: (Y/N) N pH:

CAS NO. COMPOUNDCONCENTRATION UNITS: (ug/L or ug/Kg) UG/L Q

108 -95-2-------- Phenol 10 u111-44-4-------- Bis (2 -chloroethyl) ether 10 u95-57-8----------2 - Chlorophenol 10 u541-73-1---------1,3 - Di chlorobenzene 10 u106-46-7---------1,4 - Dichlorobenzene 10 u95-50-1----------1,2 - Di chlorobenzene 10 u95-48-7----.----- 2 -Methyl phenol 10 u108-60-1---------2,2' -oxybis (1 -Chloropropane) 10 u106-44-5---------4 -Methyl phenol 10 u621-64-7-------- N-Ni t roso - di - N-propy 1 amine 10 u67-72-1----------Hexachloroethane 10 u98- 95-3 ----------Nitrobenzene 10 u78-59-1----------I sophorone -10 u88-75-5----------2 -Ni trophenol 10 u105-67-9-------- 2,4 -Dimethylphenol 10 u111-91-1-------- Bis(2 - chloroethoxy) methane 10 u120-83-2-------- 2,4 - Di chlorophenol 10 u120-82-1---------1,2,4 -Tri chlorobenzene 10 u91-20-3----------Naphthalene 10 u106-47- 8 -------- 4 - Chloroanil me 10 u87-63 - 3 ----------Hexachlorobutadiene 10 u59-5 0- 7----------4-Ch lor o-3 -methyl phenol 10 u91-57-6----------2-Methvlnaphthalene 10 u77-47-4----------Hexachlorocyclopentadiene 10 u88-06-2----------2,4,6 -Tnchlorophenol 10 u9 5- 95-4----------2,4,5 - Tri chlorophenol 10 u91-58-7----------2-Chloronaphthalene 10 u88-74-4----------2 - Ni t roanil ine 20 u131 -11 - 3---------Dimethylphthalate 10 u6 06-20-2-------- 2, 6-Dinitrotoluene 10 u2 0 8 - 9 6 - 8---------Acenaphthylene 10 u9 9 - 09 -2 ---------- 3 - Ni t roam 1 ine 20 u33-42-9----------Acenaphthene 10 u

FORM I SV 8270C

412


CLIENT SAMPLE NO.

Lab Name: COMPUCHEM

Lab Code: LIBRTY


Sample wt/vol:

Level: (low/med)I

% Moisture: _______


Injection Volume:

GPC Cleanup: (Y/N)

Contract:

Case No.: SAS No.:

WATER

1000 (g/mL) ML

LOW

decanted: (Y/N)

Volume: 1000 (uL)

1.0(uL)

N pH: ___

8270CMW - 9 A

SDG No.: QE1877

Lab Sample ID: QE1877-4

Lab File ID: QE1877-4A64




Dilution Factor: 1.0 '

CAS NO.CONCENTRATION UNITS:

COMPOUND (ug/L or ug/Kg) UG/L Q

51-28-5----------2,4 -Dinitrophenol 50 u100-02-7---------4 -Nitrophenol 20 u121-14-2-------- 2,4 - Dinitrotoluene 10 u132-64 -9-------- Dibenzofuran 10 u84-66-2----------Diet hylpht ha late 10 u7005-72-3------- 4 -Chlorophenyl-phenylether 10 u86-73-7----------Fluorene 10 u100-01-6---------4 -Nitroaniline 20 u534-52-1-------- 4,6-Dinit ro-2 -methylphenol 20 u86-30-6'--------- N - Nitro sod iphenyl amine (1) 10 u101-55-3-------- 4 -Bromophenyl - phenyl etHer 10 u118-74-1-------- Hexachlorobenzene 10 u87-86-5----------Pentachlorophenol 20 u85-01-8----------Phenanthrene 10 u120-12-7-------- Anthracene 10 u86-74-8----------Carbazole 10 u84-74-2----------Di-n - buty lpht ha late 10 u206-44-0---------Fluoranthene 10 u129-00-0-------- Pyrene 10 u85-68-7----------Butyl be nzylpht ha late 10 u91-94-1----------3,3' -Dichiorobenzidine 20 u117-81-7-------- bis (2-ethyl hexyl) Phthalate 10 u56-55-3----------Benzo (a) anthracene 10 u218-01-9-------- Chrysene 10 u117-S4-0-------- Di-n-octylphthalate 10 u205 - 9 9- 2-------- Benzo (b) tiuoranthene 10 u207-0 8- 9---------Benzo (k) tiuoranthene 10 u50-32- 8 ----------Benzo (a ) pvrene 10 u193- 3 9- 5-------- Indeno (1,2,3- cd) pyrene ■ 10 u53 - 70-3----------Dibenzo (a, h) anthracene 10 u191-24-2-------- Benzo (g , h , i ) perylene 10 u

(ll 1 Cannot be separated trom Diphenylamine

FORM I SV

4 'i V J_vJ

8270C

Sample Info:

Volume Injected CuL>: 1,0 Operator; 917

Column phase: RTX-5 Column diameter: 0.32

Data Fi le: /chem/5972hpt.4. i.-yDF020313Ht>4.b/uE1877-4A64,i'J

Date : 13-MAR-2002 15:34

Client ID; MW-9A Instrument: 5972hpti4.i '"•J" \—I

Sample Info:

Volume Injected <”uL>: 1*0 Operator: 917


Data Fi la: /chem/5972hp64. i/DF020313A64.b/QE1877-4A64.d

Date : 13-MAR-2002 15:34

Client ID: MU-9A Instrument: 5972hp64.i

41b

Data File: /chem/5972hp64.i/DF020313A64.b/QE1877-4A64.dReport Date: 14-Mar-2030 11:42

CompuChem

Data file Lab Smp Id Inj Date Operator Smp Infer Misc Info Comment ■ Method Meth Date Cal Date'

Semivolatile Report SW-846 Method 8270C /chem/5972hp64.i/DF020313A64.b/QE1877-4A64.d QE1877-4 Client Smp ID: MW-9A13-MAR- 2 0 0 2 15:34917 Inst ID: 5972hp64.i

/chem/5 9 72hp6 4.i/DF020313A64.b/82 70Cv6.m14-Mar-2030 11:17 byrd Quant Type: ISTD10-MAR- 2 0 0 2 17:23 Cal File: HLO20310A64.d

Als bottle :' Dil Factor: Integrator: Target Vers

101.00000 HP RTE ion: 3.50

Compound Sublist: OLM03.sub



DFVtVoVi

1.00000 1000.00000 1000.00000 1.00000



:ONCENTRATIONS

-vu’-iT o!G ON - COLUMN FINAL

. ^ MAS i R7 X : : RESPONSE { NG) i ug/Li SIMILARITY

: . .9 r. -J 5 2 r .24 6 6.24. 2 U 0 n 4 7 4 0.000 0

: 1- ■ \ 2 - 2 21 2 : . 22 i 2 j : ' : 1 j -59027 4 0.000 0

: Ac-carci ^1” 2 64 : 3. : u :: : 3 :• ■: . 710723 4 0.0 0 0 0

■, ' IBr ;; n o o • 1266904 4 0.0 0 0 0

-I ' ' •- 2 4 0 : 3 5-V : .• non) 1004780 40.0000

2 z> 4 . :: .v:; :: : = •:.:'. j ■ 638843 o o

112 •, 4 2- o 4 22 '■ 7 3 ?; 709688 72.7224 73 . ~2

- ; 5 9 7 74-: 7 ~s: • g j g c, i 636345 50 . 0936 5 0 . 10

’■ 6“ ■■■.' : 9 : e 1 - 3 g u 518337 4 3.57 9 2 4 3.58

, r • • - . - ; .. .. 7 2 • - _ •• - i ■> t g -j 4 7 . 8 S 7 9

121 641

4 7.86.

12 1 6: 1 : . ; . ■■ ■ 7:'-,:rr.v::c : '.4 .442 : 4 4 2 ~ : :> - ? i 870418 •• i

U' ' : 7-.y. : - 24 4 : 7 2 4; ;" - 7 2 '..595, 2297665 9 6 . 3 1 6 3 6.35

:■■■= • ' • =

■ " I'etecied

Selected IS

41b


Compounds

QUANT SIC

MASS EXP RT REL RT RESPONSE

CONCENTRATIONS

ON-COLUMN FINAL

{ NG) ( ug/L)

9 1,3-Dichlorobenzene 146 Compound Not Detected



3 2-Methylphenol 108 Compound Not Detected

4 2,2'-oxybis(1 - Chioropropane) 45 Compound Not Detected


.3 N-Niiroso-di-N-propylamine 70 Compound Not Detected

9 Hexacnloroethane 117 Compound Not Detected

G N i t robenzer.e 77 Compound Not Detected

I sophorone 82 Compound Not Detected

- 2 - Nitropnenci 139 Compound Not Detected

3 2.4-Dimethyl phenol 122 Compound Not Detected

4 Bisi2-chioroethoxy)methane 93 Compound Not Detected

5 2,4 -Dichlorophenoi 162 Compound Not Detected

, 2,4- Trichlorobenzene 180 Compound Not Detected

7 Naphtha ier.e 126 Compound Not Detected

4 -Ch1 Groani:ine 127 Compound Not Detected

9 Hexach1orobotadiene 225 Compound Not Detected

4 - Ch 1 ore - :• - me t hy 1 pheno : 107 Compound Not Detected

2 2 - Me thy • nap.ot ha 1 er.e 142 Compound Not Detected

Hexach•orocyciopen:adiene ~> 7 7 Compound Not Detected

3 2 . 4.5-7r. rr. 1 or ophenci 196 Compound Not Detected

6 2.4.5 -Tr:chioropnenol 1 96 Compound Not Detected

2 ■ Chioronaphtha lene 152 Compound Not Detected

9 2 - Nit rc an : 1 ir.e 6 5 Compound Not Detected

0 Dimethy:pheha 1 ate i 6 2 Compound Not Detected

2 . 6 -D: r.i t rotcluene 16 5 Compound Not Detected

2 Acenaphc hy; er.e 152 Compound Net Detected

; - N:: roar.: : :r.e 1 3 S Compound Not Detected

■; 1 54 Compound Not Detected

5 2.4-2". n: t r •: o h end 1 b4 Compound Not Detected

3 109 Compound Not Dec ected

7 2 . ; -11: n :: : *::■ uene 165 Compound Not Detected

1 6 S Compound Not Detected

: •' •'*•*•* • i v : >••••• i-iS' Compound Not Detected

o 4 -Chic reph-rry : ■ pr.eny 1 ether 204 Compound Not Detected

F ; uc: 156 Compound Not Detect ed

2 - : • ' ■ ■■:■■■■■ 13? Compound No: Detected

4 . : r.:' r- - - - m-t ry j pheno i - 9 z Co-pou.-.c No: Detected

■’ • • • • • • ..... - 1 - • ■ - - - :> ...... Detected

. :: r.'.-:'.y : •‘•I : 24 - Cc-vpo.;:- -N..V. D=:ec^ci

2 T V V, rr. v N;.t Detected

: 7 r Tcrcturz Nt \ 2>e: ect ed

-r :or?:-jr.r. Detected

Icmpvur : No: De t ected

: 4 9 Compound No: Detected

SIMILARITY


QUANT SIG

Compounds MASS

74 Fluoranthene 202

74 Pyrene 202

7 7 ButylbenzyIphtha late 14 9

7 3 2 . 3 ' - D: ch i.orobenzidine 2 52

79 bis:0-echyihexyi;Phtha late 149

30 Benzo >'a ; ant hracene 226

51 Chrysene 226

32 D:-n-ocr yiphtha late 14 5

33 Benzo(b)f1uoranthene 252

34 Benzoik’:luoranthene 252

85 Benzo1 a 1 pyrene 252

56 Indeno(1,2,3-cd)pyrene 276

57 D:benzo(a,h)anthracene 278

88 Benzo(g,n,i)perylene 276

CONCENTRATIONS

ON-COLUMN FINAL

RT EXP RT REL RT RESPONSE ( NG) ( ug/L)















SIMILARITY

QC Flag Legend

M - Compound response manually integrated.

418

Data File: /chem/5972hpb4.i/DF020313A64.b/QE1877-4A64.dInjection Date: 13-MAR-2002 15:34Instnument: 5972hp64.1Client Sample ID: MU-9A

#ouno: 2.4.6-TribromophenolMumper-: 118-79-b

Ion 329.60: Area: 670418 Height: 5747o5

14.00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.05 14.90 14.9;Min ■


1

0

rvinT

1 4 . 00 1 4.05 14.10 14. 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.85 14.90 14.9 _____ _______ M l n

Ion 141.00: Area: Heignt:

4 19l-.OO 14.05 1 -. i 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.30 14.75 14.80 14.S5 14.90 14.9

_____ ________ _ _ Min


GC/MS SEMI-VOA WORKSHEET

LAB INSTRUCTIONS: PPS 985**VOC 8260B TCL3CT.SUB**SVOC 8270C TCL3**DISS. METALS-RPT. As,Cr,Cu & Pb»

FILTER & PRESERVE IN-HOUSE

RECEIPT DATE: 3/6/02 0:00 SAMPLE DATE: 3/5/02 13:50 DUE DATE: 3/18/02 0:00

CASE#: Q1877 SDG: QE1877 COMPUCHEM#: QE1877-4

CLIENT ID: MW-9A


Injection Volume :1pL Dilution Prep (if needed)

Extraction Date___3___/___8/____ 02____

DFTPP Filename_____ DF0203 /■> A ________________

Sample File Name_____ QE1877-4 A i'<A-

ANALYST (S): InjectionQ( 1 Work-up4 / 7

GC/MS DATE REVIEW

CONDITION CODE


Number of peaks found: _

Number of Hits found: <P


Quality Assurance Notice (s)

Number of Notices Required____

Comments:

-GC/MS ReviewP61

Final Reportable Package! s):

Disposition: \/\ Complete


[ ] Re-extraction Required

[ ] Reinject Neat

[ ] Dilute ( X)

Date__Q / /4^.' Z- Auditor_

At y

Date / /

42 GSVI - 6/27/01: PTF

Analyst initials lxttactcTlKD i#* *,*($?

Mannjjirtiircr and lot nnmbrr or rmgrnls/solvf nts used libxb,.

D

(HIMw U" lS-u^

^\0^

VI-Initials <>?'«' | . \\LWhitt-

O-'i

\\ ilnr'A

• 3. Standards Data

a. Initial Calibration Data (Form VI SV)

b. Continuing Calibration Data (Form VII SV)

42

a. Initial Calibration Data

(Form VI SV)

If more than one instrument is used, forms shall be arranged in order by instrument. Multiple initial calibrations from the same instrument shall be in chronological order. Within each initial calibration, the standards are in order by level, from lowest to highest.

(1) Reconstructed Ion Chromatograms and quantitationreports for the initial (five-point) calibration;Spectra not required

(2) EICPs displaying each manual integration

FORM 6SEMIVOLATILE INITIAL CALIBRATION DATA

Lab Name: COMPUCHEM

Lab Code: LIBRTY Case No.:

Instrument ID: 5972HP60

Column: J&W DB-5.625 ID: 0.32

Contract: 8270C

SAS No.: SDG No.: QE1877

Calibration Date(s): 03/03/02 03/03/02

(mm) Calibration Time(s): 1401 1720

LAB FILE ID: RF10: HI020303A60 RF20: HK020303A60 RF50: HL020303A60RF80: HG020303A60 RF120: HJ020303A60RF160: HH020303A60

I COMPOUND

jPhenol

j Bis(2-chloroethyl)ether

|2 -Chlorophenol

|1,3-Dichlorobenzene

I 1,4 -Dichlorobenzene

| 1,2-Dichlorobenzene

|2-Methvlphenol

| 2,2'-oxybis(1-Chloropropane)

j 4-Methylphenol

|N-Nitroso-di-N-propylamine__

[Hexachloroethane

I Nitrobenzene

jIsophorone

| 2-Nitrophenol

^2 , 4-DimethylphenolBis(2-chloroethoxy)methane__

^,4 -Dichlorophenol

j1, 2 , 4-Trichlorobenzene

) Naphthalene

| 4 - Chloroanil me

j Hexachlorobutadiene

j 4 - Chloro-3-methylphenol

! 2 -Methylnaphthalene

i Hexachlorocyclopentadiene___

2,4,6-Trichlorophenol

; 2 , 4,5-Trichlorophenol

; 2 -Chloronaphthalene

2 -Ni t roan 11 me

. Dunethylphthalate

’2, 6- Dime rotoluene

Acenaphthylene

3 - Nit roam 1 me

Acenaphthene

2,4-Dinit rophenol

■ 4 -Nit rophenol

2 , 4 -Dmicrotoluene

Dibenzofuran

D i e t hylpnt ha 1ace

4 - Ch. 1 o r op he n v 1 - oheny1e t he r

FIuorene

4 - Mi t roanil me

4 , 6 - Dim t ro - 2 - me thy 1 phenol__

Ll-Nicrosodiphenylamine

Bromonher.v I - Dhenvlet her

RF10 | RF2 0 | RF5 0

1.279| 1.253 | 1.2600.916 | 0.869 j 0.8951.024 1.050 j 1.0401 . 380| 1.409| 1.3731.386 | 1.406| 1.4331.348 1.344 j 1.3340.862 0.794 0.7781.266 | 1.279| 1.2151.009 0.990| 0 . 9710.700 0.692 0.7200.617) 0.616 0.6170.468 | 0.470 0.4680.729 0.749 0.7320.222 | 0.235 0.2390.281 0.275| 0.2890.443 | 0.449 j 0.4700.405 0.412| 0.4150.484 0.486 | 0.4911.082 1 . 0 8 3 [ 1.1090.488 0 . 502 0.4950.384 0.392 0.4020.352 0.351 0.3600.826 0.842| 0.8470.277) 0.3 91 | 0.4750.410 0.421) 0.4270.450) 0.478 0.4761 . 167 j 1 . 174 j

1.1400.478) 0.469) 0.4601.632 1.606) 1.5970.340 0.3481 0.3451.9241 1.916) 1.8750.362) o. 3 t i; 0.3491.136 1.138) 1.0910.108) 0.170) 0.2100.260) 0.272) 0.2930.487) 0 . 5 0 5 j 0.5042.060) 2.060) 2.0901 . 8021 i . 778 i 1.7250 . 827: 0.322) 0.8561.543! 1 . 504 J 1.5590.365' 0.372 0.355C . 113 ! 0.137) 0 . 1660.532' 0.501) 0.5270.233: 0.234)

i0.296

FORM VI SV

RF8 0 RF120 RF160|

1.522| 1.408 1.5731.044| 0.967 1.0181.221j

1.084 1.1061.668| 1.521| 1.5971.650 j

1.489 1 . 552

1.567 1.463 1 . 528

1.008 0.916 | 0.939

1.522[ 1.389| 1.478

1.233 1.209 1.3190.913| 0.880| 0.9800.687| 0.627 j

0.6400.536 | 0.499| 0.535

0.868 0.795| 0.815

0.268 0.250 0.2560.339| 0.297 0.302

0.501| 0.468 0.4900.481j

0.448 0.4650.577 j

0.529 0.5511.285| 1.236 1.3380.519 j 0.492| 0.5100.436| 0.410| 0.4140.391j 0.368) 0.360

0 . 956| 0.899) 0.946

0.537) 0 . 522| 0.5570.480) 0.453 0.4510.544 | 0.450| 0.4761.331) 1.278) 1.3530.540 j 0.465 j

0.4871.684 | 1 . 589| 1.667

0 . 362 0.343 0.3462.122) 2 . 007 j

2.1270.396 j 0.355| 0.380

1.2321.216 j

1.2270.260| 0.274 0.2810.336) 0.305) 0.3120.5-44) 0 . 522 0.525

2.340) 2.237 2.298

1.792 1.695 1.7681.046)

1.082 j1.12 9

1.872 1 . 904 2.067

0.402 0.359 0.3760.192) 0.180 0.201

0.577 | 0.521) 0.540

0.320 0.300 0.314


Lab Name: COMPUCHEM Contract: 8270C^ Lab Code: LIBRTY Case No.: SAS No.: SDG No.: QE1877

Instrument ID: 5972HP60 Calibration Date(s): 03/03/02 03/03/02

Column: J&W DB-5.625 ID: 0.32 (mm) Calibration Time(s): 1401 1720

LAB FILE ID: RF10: HI020303A60 RF20: HK020303A60 RF50: HL020303A60

RF80: HG020303A60 RF120: HJ020303A60RF160: HH020303A60

COMPOUND

1 !

j RFl0 |1

RF2 0 |

|

1

RF5 0 ]

1

RF8 0 |

1

RF120 |

1 .

RF160 j

Hexachlorobenzene- 1----------- 1 -

1 0.339|----------1 -

0.314|---------- 1 -

0.340|----------[

0.367|---------- 1

0.341| 0.345

Pentachlorophenol 1 1 0.060| 0.082 j0.124 0.108| 0.125

Phenanthrene | 1.244 | 1.191 | 1.226 | 1.297| 1.265| 1.303 j

Anthracene | 1.226 1.214 j 1.1801.345 j 1.300| 1.312 j

Carbazole 1.001| 0.982 j 0.988 | 0 . 977 j0.953

0.976 j

Di-n-butvlphthalate | 1.687| 1.6761 1.645 | 1.646 j 1.618| 1.558 |

Fluoranthene 1 1.452| 1.3981 1.416 1.498| 1.454| 1.478 j

Pyrene 1 1 - 539| 1 . 495 j1.407

1.410 j 1.364 j 1.395|

Butylbenzylphthalate | 0.813| 0.804 0.766 | 0.719 j 0.678| 0.665 j

3,3'-Dichlorobenzidine I 0.5881 0 . 578 I 0.556 j 0.601j 0.528 j 0.543 j

bis(2 -ethylhexyl)Phthalate

Benzo(a)anthracene

1.014 |

! 1.413|0 . 966

1.370

0.957 |

1.413

1.087 j

1.492

1.068

1.405

1.118 |

1.496 |

Chrysene | 1.246| 1.206 j 1.206) 1.390 1.295| 1.399 j

Di-n-octylphthalate ! 1.9081 1 . 961| 1.926 | 2.076 | 2.024 j 2.191|

fienjo(b)fluoranthene 1.670 1.735 1.780 1.614 1.778 1.772Benzo(k)fluoranthene 1.493 1.434 | 1.426 1.787| 1.565| 1.653|^enzo(a)pyrene 1 1.311J 1.309 1.360| 1.468 1.394 1.440|

Indeno{1,2,3 -cd)pyrene | 1.400| 1.409 1.455 1 . 585| 1.482 1.507Dibenzo(a,h)anthracene 1.204 1 . 223 | 1.246 | 1.386 j 1.307] 1.327|

Benzo (g,h,i)Dervlene 1.210 1.192] 1.237| 1.3291.232 j 1.248 j

2 -Fluoroonenol 1 1.168] 1.185]1.175 j

1.472| 1.285) 1 . 353|

Phenol -d5 1 1-3411 1.313 1 . 326| 1.6261.481j

1.530!-i i t robenzene - d 5 j 0.533| 0.5551 0 . 544 j

0.6300.566 j

0.6032 -Fluorobiphenvl | 1.487 | 1 . 452 | 1.509 j

1.690 1.552 1.6412,4,6-Tribromophenol 1 0.359] 0 . 356 | 0.369 |' 0.408| 0.385| 0.380|

Terphenvl - dl 4 ! 1.153| 1.152 1 . 104 | 1.112 | 1.065 1 . 074

1 I 1 1 L 1

FORM VI SV

42b

Data File: /chem/5972hp60.i/DF020303A60.b/H1020303A60.d

Date J 03-MAR-2002 15:21

ooC\J

Client ID: SSTD010 Instrument: 5972hp60.i

Sample Info: SSTD010:2319

Volume Injected (uL>: 1,0 Operator: 2319

Column phase; J8.W DB-5.625 Column diameter: 0*32

/chom/5,372hpfcO, i 7DF020303A60.b/H1020303A60.d (Part 1 of 2)

7.0-i

6.8-:6.676.4- :6.2-;

6.0:5.8:

5.6- +

5.4- 7

Data File: /chem/5972hp60. i 7DF020303AC0, h/H 1020303A60. d

Date : 03-MAR-2002 15:21

Client ID: SSTD010

Sample Info: S3TD010:2319

Volume Injected (uL>: 1.0

Column phase: J8.W DB-5.625

Instrument; 5972hp60.i nC\J

Operator; 2319

Column diameter; 0*32

Data File: /chem/5972hp60.i/DF020303A60.b/HI020303A60.dReport Date: 04-Mar-2030 08:37

CompuChem

Data file : Lab Smp Id: Ini Date : Operator : Smp Info : Misc Info : Comment : Method Meth Date : Cal Date : Als bottle: Dil Factor: Integrator: Target Vers Processing

Semivolatile Report /chem/5972hp60.i/DF020303A60 SSTD0100 3-MAR- 2 0 0 2 15:21 2319SSTD010:2319

/chem/5972hp60.i/DF020303A60 04-Mar-2030 08:37 mikhael 0 3-MAR- 2 0 0 2 15:21 41.00000 HP RTE ion: 3.50Host: einstein

SW-846 Method 8270C .b/HI0203 03A6 0.d Client Smp ID: SSTD010

Inst ID: 5972np60.i

.b/8270Cv6.m Quant Type: ISTD Cal File: HI0203 03A60.d Calibration Sample, Level

Compound Sublist: all.sub

1

Concentration Formula: Amt DF * Vt/(Vo * Vi) * CpndVariable


DF 1.00000 Dilution FactorVt 1000.00000 Volume of final extract (uL)Vo 1000.00000 Volume of sample extracted (mLVi 1.00000 Volume injected (uL)

:pnd Variable Local Compound Variable

AMOUNTS

1:-;AN. X; c CAL-AMT ON-COL

;-C. ■■-"■a ^ F.T =T r.EI . -:-:s?onse l NG ] ( NG) ST MI LAP. I TV

.. • - . .

5 2 7 4 2 4 0 . 0 0 0 0

.: .. 1 ' j : • : 4 0 . Of DO

i ; : ■ t ■; ; •- . ;;; - ; ' ' \ i; c i_ 40. or:.o

■■ h.TL';:.:- 22504 1 4 0 , •. I ) 0

. . . . ...... . : • • - nice :

• • 2 5 5 0 n 2 ■; 'j o o

117 ■ ■ ■ - '■ 2X15 \ 1 7 • 0 C 0 ? e- ■a:

277X5 17 .ooc o . 01 (a;

V T-X 2 04 C 2 : o. o o o o '= 0- is i

i t;. :. $ j 1 10.0000 2.26 (a.M)

:: : . 1 • • . : : e 15 15 C 1C . oooc 5 2 5 UM)

:: - 5 2 0 54 : o .ooo o 1 C1 . 2 -

■a ::b- •;i :• • : • •••-'?. :• •; x:: • 2 5 22 5 10 . 0000 0 5 0 9020 <a)

■ 4 4 7 1 ? i o .oo t 7 •' 5587 (a;

c■J

' - ^ - v C

Data File: /chem/5972hp60.i/DF020303A60.b/HI020303A60.dReport Date: 04-Mar-2030 08:37

QUANT SIG CAL-AMT ON-COL

■r-po^s MAS S RT EXP RT REL RT RESF3NSE ( NG) ( NG) SIMILARITY

1 5 Ben za Idehyde 77 7.472 7.472 :0.911) 16545 10 . 0000 12.64 83 J2

16 Phenol 94 7.641 7.541 : 0. 9 3 2; 26459 10.0000 8.77 (a)

1 n B is .2 - chloroer.hvl > ether 93 7.760 7 . 76C ;0 946) 18945 10.0000 9.23 (a)

l1: 2 - Ch ioropher.ol 123 7 . 844 7.344 (0.9571 21131 10.0000 9.17 8616(a)

14 6 8.098 9 . C 9 9 ■: 0.9 8 8 ) 28556 10.0000 3 . 9 1 (a)

2 '' 1 , t - D: :.t 1 zrzbenzene 14 5 3.216 5.21$ 1 002; 23663 10.0000 ; ^ 1

1Ber.zy - 3 : c :r.-: ; 1 08 3 .436 3.436 ■ 1 . 029) 13470 10.0000 6.93 ia)

:: 14 6 3.470 3.470 ;; . 033) 27877 . 10.0000 9.10 ( a )

I _• ; -Memvlpher.:: : os 3.639 3 . 639 :1. 054 ) 17828 10.0000 9.29 (a;

IS I . j ■ - oxyr.: a • 1 Ch .oropropar.e ' 46 3 . 666 ■9.556 ■ 1.056) 26199 10.0000 8 . 90 8239 (a)

106 3.676 8 376 ,1.9931 29875 10.0000 8.59 7535 (a.-

-Met ivy :pne:-o; 1 08' 3 .993' S . 393 : 1 . 3 5 I 20867 10.0000 8.50 (a)

2i 4-Metnyipheno; 109* $.893' 3 . S 9 3 (1.035) 20867 10.0000 8.50 (a)

13 - Nj c rose - d; - N - z ropy lam me 70 3 .876 3.376 (1.033) 14476 10.0000 8.09 7125 (a)

II Hexachlcroerhar.e 117 9.045 9.045 (1.103) 12766 10.0000 9.52 9204 (a)

H) Nitrobenzene 77 9.147 9.147 (0.832) 26677 10.0000 9.12 9091 (a)

Q O 9 . 570' 9 . 570 (0.923) 41553 10.0000 9.07 9597 (a)

•••••:•. . 1 3 9 9 . 705 9 . 70S (0.936) 12626 10.0000 8 .91 8857 (a!

2..; -i-^hvPPi-oi 12 2 9 . 7 9 C 9.790 (0.944) 16007 10.0000 9 . 13 3304 (a)

: 4 e.: s - - ■ c.n . ■: : t- mo■ net nane 93 9.942 9.942 (0.959) 25259 10.0000 9.27 8617 (al

162 10 i n c -. n i 2 ? ■ 0.977) 23106 10.0000 9.00 (a)

180 10.263 1C . 2 6 3 ! 0 . 9 9 0 ) 27574 10.0000 9.01 (a)

N'apn: 12 8 10 399 10.39 9 (1.003' 616 64 10.0000 8 . 76 9144 (a)P'

127 10.500 10 500 . 1 . 0 3 i 27809 10.0000 9 . 65 3784(ai

226 10.519 10.619 : 1.624 ) 21835 10.0000 9.33 9380 (a)

Papiolazrao 1 ‘ 11 .042 11 .04 2 (1.065) 4772 10.0000 9.59 8 6 8 3 ia)

~ ' '-'h b. : j ■■ "bylpt/n. : 107 11.36? 11 ■ 6 3 , 1.295; 20087 10.0000 9 . 57 9535 (a)

. I r..n! yr'.-r 142 11.600 ::. 600 (1.119) 47072 10.0000 9.08 (a)

' 4 "1 11.76? 11.759 : 1.: 3 5) 40190 1C.0000 9.60 (a)

2?7 11.867 11 5$7 (0. s a 5) 11S 70 10.0000 6.06 9457(a)

2 - •• • • : 12.:: : 2 . : 7 ! '■. -? 0 2 ' 17594 10.0000 9.16 (a)

■■■: 2 . . r -T:-: : ^ •; 2 , 1 7 5 12. -.7$ (C- . ■■07:- 19 310 10.0000 9.18 (a)

;: : . : ■ -i izn^.y. 12 .-12? :: . 2251 53773 10.0000 9.2: 3023 (a)

■; - :.t l-.r- ■: 2 :: .9$: 1:. 4 5 . 92 8) 5004 1 10.0000 9.05 (a;

:J . 9 33 -. 1 -1 : . 9 4 1; 4 1-001 20.0000 19.07 9160 (a;

. :: ■ ■■■■■■-.■■■..■ ■ 1 2 :• 5 . •..• 6 5 . 6 9935 10.0000 9.53 9503 la)

; . ■ : •; $ 1 ; : - 2 .7 ■-7 - 4: 14 5 0 4 1 0.0000 6 7?: 9610 (a)

; . A • c ■> 13.: O'" ■ ■ ' " ■ : . 6 2 : 3 2 4 9 ’ 10.0000 9 . : 5 953 0 ia)

■ ■ :■■■■■■■■; ■•>■■■■ ■ ■■■■■■ 1 3 6 6 • ■ ; $ :■ .:.$$$> 310 2 5 20.0000 10.09 3 7 5 5 »a )

■- : :. 4 ;• o r. *• 5; 4 3 6 9 10.0000 0 . -1 8 3 6 34 ■ -n)

: L. i ' ' ' • . : 3., ■ . $51 .. ■, 1 n , 2 310 3 50.0000 2 4 . 9 1 .a )

■ ■ : ■. . :rr . :: .1.019) 22255 20.0000 17.16 84 55 ; b)

■ . 5 1 ; • 7 -;; : :•. v 'I 926 i 20394 10.0000 3.39 3 5 7 1 ■ a)

: 3.3 : : . 7■■ ■ 1 . 029 :■ 9 3 3 1 5 10.0000 9.22 9 5 2 •. a )

1 4 9 1 4 . 2 0 b . _ . 0 5 3 1 77251 :o.nooo 1 0.0 ? 965 V

- - 4 . 4 1 ! ::.: 7 3: 35469 :0.0000 3 27 7 7 2 0 (a ;

1 ; 6615 9 10.000c S . 4 4 7752 (a)

43 i

Data File: /chem/5972hp60.i/DF020303A60.b/HI020303A60.dRetort Date: 04-Mar-2030 08:37

O’JANT SIG CAL-AMT ON-COL

CcTpour.ds MAS S FT EXP FT REL F.T RESPONSE i NG) ( NG) SIMILARITY

62 13 = * 4 425 11 07 4: 31319

19741

20.00C0 IS . IS 8439 (a)

8487 (a)62 6 . 6 - D: r. 17 ro - 2 - Techy 1 phenol 199 14.493 14.493 (C.902) 20.0000 13 . 95

N-Ni i roscdip'reny Lamir.e 16 9 - -j . 6 j. * 14 611 1C. 90?) 44603 10.0000 9 . SB &3Hla)

6 5 1,2- Dcpher.yl hydra z me 77 76740 1C.0000 10.24 9073

6 o 4 -Bromopheny 1 -pn.enylecher 243 15 2 71 15.271 : C . 9 5 0 ) 24103 10 . 0 0 0 0 9 . 36 9057 (a)

6 1 Hexachl or obenze.ne 264 15.372 15 .373 !C.957; 2 6 3 7 9 10.0000 9 . 67 9294(a)

6 6 Ac razine 2CG 15.542 15 . 542 '.0.967) 17522 10.0000 29.28 8 3 91

6 9 ? e r. c a c r. 1 c r o p h e i o • 253 15.728 IE.726 •■0.979) 673 1 20.0000 8 . 33 9197 (a)

~ z Phenan:. h.rer.e 179 16.100 16.100 ■ 1.002' 10423? 10.0000 9.71 (a)

7: Ancr.racene 176 16 . 1S 5 16.185 : 1 . 0 C 7 -i 102716 10.0000 9.47 a)

O Sarbazoie 167 16.472 16.472 : 1 . 025; S 3 8 32 10.0000 10.16 8799

7 1 Di- n •cutyipnthaiac e 14 9 17 064 17.064 . 052) 141315 10.0000 10.35 9' 7 9

7-1 Fluoranthene 202 13.198 13.199 11.133) 121651 10.0000 9.84 (a)

75 Benz idine 134 13 4 35 16.435 •' 0.3 9 1) 30206 20.0000 35.69 3605

7 6 Pvrer.e 2 02 1 3 6 04 18.604 (0.399) 124236 10 . 0000 10.6 3

77 Butyi benzylph.tha lace 14 Q 19 703 19.703 :0.953) 65605 10.0000 11 . 10 94 C 3

7 6 3,3' -DiC^Io:-orii:i:^i;^ 252 20.617 20.617 (0.997) 47517 10.0000 10.19 7 15 9 (a!

76 bis : 2 - ethyl he >:y ! 1 Phcr.j late 14 9 2 C 6 5 1 2 0.5 5 1 (0.998} 81841 10.0000 9.45 9 76 7 \a I

? ' Benzo ■ ar.chrncme 2 2 z u 0 6 6 3 20.666 {r- .999) 114093 10.0000 S 63 (a)

e. :3h: ys^ne 223 2 0 7 1 cj 2C . 719 1:.G02j 100603 10.0000 9.26 ; U ;

to - n - o"C y : pot t ■< .ate 14 9 11 . 14 9 21 .649 '0.929i 136015 10.0000 5 2? : 11

___Berizo ■ :.o f 1 tor a of r.ene 252 22 .4 76 22.415 t 0 . 9 5 4 ' 119026 10 . 0000 5 91 (a;

m Benco -. ' .■ : l oOFDor .-—ne 252 2 2 6 7 c 2 2 5 2 9 ; 0.95 7) 106362 10.0000 9 08 1 a)Wr Ber.z-c -a pyre:-.-:- 252 2 ? . 1 71 23.172 (0.994) 93455 10.0000 9.32 ia;

Inoeno ■ 1 . 2 . 1 - :d r-y: one 2 7 6 26-. 26 9 25 . 25 5 ■■ 1 . 127' 99794 10.0000 9.35 0 (aM)

f. 7 2 ; h-!'.: a , r. -.l:/. a "T-nO 2 7 3 2 4 ,31c. 2 •: 2 1 f ■ 1 . 129, 3 5 8 3 0 10.0000 9.22 8975 !a)

3- ^ n ■ * P- :V - -r.e 276 2 7. • Ai 2 " . 1 6 1 '1.166) 86228 10.0000 9.59 7750 1 a)

QC Flag Legend

a - Target compound detected but, quantitated amount Below Limit Of Quantitation(BLOQ).


Data File: /chem/5972hp60 . 1 •,'DF020303m6i

Injection Date: 03-MhR-2002 15:21Instrument: 5972hp60.iClient Sample ID: S5TD010

ound:Mumper

Fluorcblphemy1 321 -ni.'- c:

P/H 1020303H6C . d

Ion 172.00: Hrea: 63770 Height: j6272

3.6- rrit7 4- oi

3.0-

2.8-

2.6-

2.4 -

4-

'J . P •

I

11 .80 11.65 1 1.90 11.95 12.00 12.05 12.10 12.15 12.20 12.25 12.30 12.35 12.40 12.45 12.50 12.55 12.60 12.65 12.70 12.7jM i n________________________________________________ _______ __________i

Ion 171.00: Hrea: 0 Height:

I

I

!

12.45 12.50 12.55 12.60 12.bp 12.70 12

ion i.-.

433

:i. :5 12.20 12.25 12.70 12.35 12.40 12.45 12.50 12.55 12.60 12.65 12.70 12.7■

Data Fiie: .•cnem/5?^2ho60.1/DF020' Injection Date: 03-MAR-2002 15:21

mst rument: 5972ho60.1

nt Sample ID: SSTDulu

Ouno: 2.4.6-Trloromopnenol

Number:

*60. b/H1020303A60.a

'?. 0-

3.5-

d.;.'- 7 . 5-

?. 0-

6.5-

6.0-

~ 5.5-;^ 5.0-

329.60: Area 5390 Heigrr 9915

o. o- 5.0-

I

1.5-

1. 0-

1 J - 35 M . 40 14.45 U.50 14.55 14.60 14.65 1*4! 70 14.75 14.30 14.85 14:90 14^95 15!oO 15^05 151 10 15.15 15.20 15.25 15.30 j_____ Min_________________________________________________________!

Ion 332.00: Area: 0 Heignt: 0 j

l i

7.5-

i

ii

'XI

14.95 15.00 15.05 15.10 15.15 15.20 15.25 1 5.;4.5'*: 14.55 1-1.50 14.65 14.'

43

/5 14.3'Ml

14 5 14.90 14.35 15.00 15.05 15.10 15.15 15.20 15.25 15.30

Data File: /chem/5972hp60.1 /DF020 Injection Date: 03-MAR-2002 15:21 Instrument: 5972hp6u.1

ent Samole ID: 55TD010

■uuno: Indenoi 1,2.3-ca .‘pyrene :■ r-hjmper; 193-39-5

703A60.b/HI020303A60.d

1 .6- I .5-

1. J-

. . J •

1.2-

1.1-

1.0-

0.9-

0.8-.

1 j .4 ■

0. 1 ••

25.50 25.53 '5.95 25 .

2.8-

Ion 276.00: Area: 99794 Height; 19584 <z-

•SJ

>0 26.05 26 ! 10 26.15 26.20 26.25 26.30 26.35 26! 40 26^45 26^50 26.55 26.60 26.65 26.70 26^75

___________________________ run_________________________________________________________________Ion 139.00: Area: 0 Height: 0

I

[Ii

i

0.4

'i.1 _’b . u5 Jo . 1 0 Jo . 15 26.20 jo . jo Jo . 30 jo . 75 26.4u 26.45 26.50 26.55 26.60 26.65 26.70 26.75 i-1 i r,

I-:n 2?7_iVi; Ar-?=i: <: nei-gnt: 0

435

i 11 n

26.40 26.45 26.50 26.55 26.60 26.65 2b. 70 26.75 |

(:<10~5>

Data File: 2chem/5972hp60, i2BF020303A60.b/HK020303060.d

Date : 03-MAR-2002 16:41

Client ID: SSTD020Instrument: 5972hp60*i ■L.O

Sample Info: SSTD020;23lS OOVolume Injected <uL>: 1.0

Operator; 2319Column phase: J&W DB-5,625


8.28.07.8

7.6

7.4

7.2

7.0

6.86.66.4

6.26.05.8

5.6

5.4

5.2

5.0

4.8

4.6

4.4

4.2

4.0

3.8

3.6

3.4

3.2

3.0

2.8 2.6*

2.4-

2.0-

1.8

1.61.4

1.2- 1.0-

0.8- o.6-

0.4

7chsrn/5972hp60. i 2DF020303A60 .b7HK020303fl60. d (Part 1 of

•C4-

II J ■j M / __ jj1,

1.1'

L__J A},.14

Data File; /chem/S^hpSO. i/DF020303A60.b/HK020303A60.d

Date ; 03-MAR-2002 16;41

Client ID: SSTD020

Sample Info: SSTD02OJ231'?

Volume Injected <uL>: 1.0



Operator: 2319


CO

.2-

.0-

.8-i

.6-

.4-i

.2-:

.0-

.8-:

.6-i,4-i

,0-

.8-

.6-

.4

.2

. 0-

,8

.6

.4

.2

.0

.8

.6

.4

.2 ,0

.8

.6

.4

.2

.0

.8

.6

.4

*0

*8 .6

* 4

/ch®m/5972hpio0 * i /DF020303A60 ♦ b/HK020303A60 ♦ d• +

CPirt 2 of 2)

7)ca>X

..__I1:3

I i_ _| .

19

Ul. I l

2117

Data File: /chem/5972hp60.1/DF020303A60.b/HK020303A60.dReport Date: 04-Mar-2030 08:38

CompuChem

Data file Lab Smp Id Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date Als bottle Dil Factor Integrator Target Ve

Semivolatile Report /chem/5 972hp6 0.i/DF02 03 0 3A6 0 SSTD0200 3-MAR- 2 0 0 2 16:41 2319SSTD020:2319

/chem/5 9 72hp6 0 04-Mar-2030 08 03-MAR-2002 16 61 . 00000 HP RTE

sion: 3.50

i/DF020303A60 38 mikhael 41

Processing Host: einstein

SW-846 Method 8270C .b/HK02 03 03A6 0.d Client Smp ID: SSTD020

Inst ID: 5972hp60.i

,b/8270Cv6.m Quant Type: ISTD Cal File*': HK020303A60 . d

Calibration Sample, Level:


2

Concentration Formula Amt * DF * Vt/(Vo * Vi) * CpndVariable


DF ■ 1 . 00000 Dilution FactorVt 1000.00000 Volume of final extract (uL)Vo ' 1000.00000 Volume of sample extracted (mLVi 1.00000 Volume injected (uL)

Variable Local Compound Variable

AMOUNTS

C'J.a:.-; s:g CAL-AMT ON-COL

po—.cs :-'A£3 RT rX? RT F:r:. RT RESPONSE MG' ( MG) SIMILARITY

1 : , •; - 2 ■. cb.; r. •• :>• - 18 2 • ■. 31232 40.000

: ::ophic,i : e:-.- :r ; J 1 4 : 1 1 . E 4 E- - . j 0 0 i 2 -1 3 2 & 6 4 0 0 0 0 -j

: /• -. .: •..... 16 4 : E ■ 4 7 : e m.7-; 133404 4 0. c c 3

■: :- = : -j : ■ ■ : . •; ■;7 : . :» 372421 40 . 0002

■■■ - ■: t-- iSii-li 4 0.0 c

. CP : ■: 4 IE E ' - :c. 303687 4. 0 0 j 0

” c - F:-.; : 1:: ■■ ' -c 7 4 1 5 4 C 6 ? 20 . 0:.,jO 16.34

- nit-,,.-.;: ■■ . viOi 5 9 3 5 3 2 0 . on0-0 ; 8 . 01

E2 ' :■ 674 83 C'G 10.22

u : ~ 2 : (:. 344 • " ~~ q • g • 2 0 ; 00 0 18.56 (M)

: : 1: . 4 . - 7 c E '• .4 ee 2 . -32 . iobj 1 0 /, c- F; 20.0 000 10 Q Q 'M)

: : 7-^: V 18 i 5 ; :1 650 ,c . 01::■ 203794 20.0000 20 . 74

: • :. y.1 E . •• 4 " E..:.:- ' . 4 2 0 ■ 8 5 3 4 9 2. 0000 10.96 V 4 0

j; no 7• : 5 /■: :iqt. 64147 20.0000 17 47 0735

43LL * 0- L

Data File: /chem/5972hp60.i/DF020303A60.b/HK020303A60.dReport Date: 04-Mar-2030 08:38

AMOUNTS


1 v Z-Me: nylrnenol24 Z,2' -oxyois ! . - Zh _o: opi'opar

25 Acetophenone26 3-Methyiphenoi

2 7 4 - Me:hy1 phenol

2 5 N • N: t no so - di - N - prccy iarir.e

MASS RT EX? RT REL RT RESPONSE ( NG) ( NG) SIMILARITY

? 7 7 473 7 473 : 0 . 9 11} 33619 20.0000 23.12 9147

94 7.642 7.642 (G.932! 57164 20.0000 17.81

93 7.761 7.761 IC.946 > 3S65e 20.0000 IS . 06

12 5 7.345 7.845 \ 0.9 SV 4 790S 20.000C 19.15 904 5

14 6 . 099 8 . 059 (0.988) 64261 20.oooe 13 .60

14 5 5.217 .5.217 (1.002) 54 163 20.0000 IS . 79

ice 43^ 3 . 4 37 (1 . 029! 28989 20.0000 17.93

14 6 £ 4^1 5.471 f1 . 033; 51297 20.0000 18.54

10b 8.640 8.440 f 1.054/ 36207 20.0000 17.57

4 5 £ . 5 5 7 - . 6 5 7 (1.056) 58326 20.0000 18 .44 8277

105 3.360 6 . £40 (1.080) 63079 20.0000 17.10 8101

ICS ' 8.894- S . S 5 4 (1.085) 45167 20.0000 17 . 19

103' 3 . 894 3 . 854 (1.085) 45167 20.0000 17.19

70 S . 877 8 . 877. (1.083) 31569 ■ 20.0000 16.61 7313

1 17 9 . 03 0 9.030 [1.101) 28082 20.0000 19.31 3 5 81

7 7 9 . 14 £ 9.148 (0.834) 57184 20.0000 18.74 c, 2 4 9

3 Z 9 . 554 ■' 9.554 i C . 923) 91094 20.0000 18 . 93 9135

: ? !■ c. 7 £ - 5.70 6 10.933 28631 20.0000 19.12 9 C 0 7

12 2 9.721 '1 751 '0.546) 334 99 20.0000 16.42 c 4 9 6

93 9 . 94 3 - J T V 0 . 9 6 1 J 5466? 20.0000 15.10 87 81

162 10.12? -..0,113 (0 . 979) 50059 20.0000 18.61

’ o f, '•0 2 64 10.264 (0.992) 55156 20.0000 18 . 51

123 10.400 10.400 (1.005) 131778 20.0000 17.98 937 3

127 10.484 1 0 . 4 2 4 ( 1 . 01 3 i 61137 20.0000 20.01 6 5 3 0

225 i;.-o; 1 -I . o 3 ; 1 . 025) 47740 20.0000 19.27 •b 7 9 3

1 12 1 1 . 06 2 1 1 . j 4 0 (1.069) 10087 20.0000 19.06 5 Oil

1C7 11 34 7 11 34 7 (1.056) 42712 20.0000 19.25

14 2 :: id ,1.121) 102471 20.0000 18 . 85

14 7 LI 7 7 2 ii 7-: '1.127) 84515 20.0000 19.23

i: t : 1 1 : " 2 :c 35J1 35875 2C . 0000 17.13 3 3 7 3

i:- 2 . 1 0 2 12.1 • 5 3 3 616 20.0000 19.01

1 9 -j 12.174 12 1 ' . . 17 ) 4 3358 20.0000 19.93

154 12 ; _• . J . *7 . 1 • 5 2 4 . 1 2 6 : 0 20.0000 18 .73 82 34

:5: 12.44" • •' • *7 ■3.527 107645 20.00CC 13.63

"3 3 . : i 3 6 0 4 5 40.0C00 3 8 4 8 9155

12 9 54 !- 5 54 .i.5-11 : 147244 20.0000 19.63 9 6 6 6

16 ■ : 0 7 1 • . 4 7 4 • 31 ->65 20.0000 20.05 96 6 C

1 4 . 1 . 5 £ 1 ■ 1 7 5 5 7 1 20.0000 13.98 8776

• ‘ . 5 V = 67988 40.0000 3 5.30 92 8 9

1 7. 4 4 •• : 335, 104 386 20 . G0C0 19.13 8 64 2

1 34 ■:.235^ 77532 10 0 0 C 0 77 . ?0

1 .I 9 1 • - 1 1.21 5; 4 9 5 6 £ 40.0000 3 6.65 £274

1 ■’ - 1 ): 2 r. ■ 4 4 3 0 0 2 0.000 0 19.55 3 7 7 9

: i -' . 1.22 • 183863 20.0000 * Q IT 54 92

; . : - . ; ‘ •: 1 . .5 5, 163037 20.0000 n : pi 964 1

7:4 : •;. :: 14. j :• 2 . : .'.'72; 7540G 20.0000 1 6 . 7 6 74 31

; ? 137881 20.0000 16 .91 7-42

43o

Data File: /'chem/5972hp6 0 . i/DF02 03 03A6 0 . b/HK0203 03A6 0 . dReport Date: 04-Mar-2030 08:38

6 2 4 - Uiz roan: 1 me

6 3 4.6- Cir.it: ro - 2 - mecnyiphenol

6 4 N’ - N i c rcsod: phe.ny lam: re

6 5 1.2- Cipheny 1 hydrazine

66 4 - Ercmcpner.yi -pnenylezhe:'

5 7 Hexazhicrcbenzene

69 Penzachiorophenoi

70 Phenant: hrene

7: Anthracene

72 Carbazole

7 3 Z i - n - cu t y i r: r. z ha 1 a z e

74 Flucrar.zhene

75 Benzidine

~7 Buzy 1 benzy 1 pr.zhaia z e

AMOUNTS

;ant sig cal-amt on-col

MASS F.T zXP RT REL RT RESPONSE { NG) f NG) SIMILARITY

138 14.426 14 .426 [1 . 074 ' 68288 40.0000 39.74 8431

198 14.494 14.494 (0.902) 51067 40 . 0000 33 . 14 8514

2 6 9 14.612 14 612 iG.909) 93305 2 C.0000 IS . 76 Q652

77 • 14 . 680 14.63e i 1.093) 167008 20.0000 20.71 944 1

243 15.272 15.272 t 0.9 = 0 ) 52913 20.9000 16.87 3754

294 15.374 15 374 (0.957 : 58578 2 0.0 0 0 0 18.43 9390

200 “ 15.543 15.54 5 (0.95'; 23259 20.0000 36.55 8577

2 66 1 5 729 15 729 ( 0 . 5 7 91 22176 4 0.0 0 0 C 2 6.03 66 32

I7E 16.101 16.101 fl.002, 221352 20.0000 16 . 91

173 1 6 . 1 o 6 1 6 . 18 6 ;i.007) 226073 20.00C0 16.98

167 16 .473 16.473 !1.025) 182857 20.0000 20 . 08 8901

149 l7.059 17.065 11.062) 312093 20.0000 20.48 9073

2 02 ie.:m 13.199 (1.133)■ 260326 20.0000 19.20

184 15.435 18.436 (0.991) 124999 40.0000 52 .65 S 516

2 02 i 8 6 0 5 16.505 1 0 . 899) 264401 20 . 0000 20.76

249 19 705 19.705 ;o.953; 142273 20.0000 21.86 9538

252 20.613 20.618 (0.997} 102181 20.0000 20.35 7153

149 20 652 20.652 (0.998) 170867 20.0000 18.40 9502

? O D 2 0.66 9 2 0 . 6 6 9 (0.999) 242315 20.0000 19 . 09

2 2 Q 2 C 7 2 0 20.7 2 C (1.C 02) 213297 20.0000 16.45

14 9 21 6 50 1: .650 (0.929) 297829 20.0000 19.31

252 22 4 79 22.473 (0.964 ) 263488 - 20.0000 ■ 20.25

252 22.530 2:.520 (0.967) 217746 20.0000 18.08

OC*l 23.173 23.173 '0.994) 198825 20.0000 13.91

2m; 26.252 26.252 11.126) 213949 20.0000 19.08 0 i’

2 7 8 2i. 3i-; 2 u . 3 1 5 ’1.129) 185740 20.0000 18 . 97 9006

276 2 7 15 2 2 7 ; 0 2 ' 1. 166) 181081 20.0000 19.20 7782

QC Flag Legend


44 G

U - - L

Data "lie: cner.i /5972np50 .In.;,ec t ion Date : 03-MhF:-200! IP5trument: 5g72no60.i

?nr 5ampl

pound: 2- Number:

a ID: 3STD020

F laorompnenyl 321-60-3

DF020 jOGhdu . o''HK020303^60 . a

10:41

Ion 172.00: Ores: i_*oll6 heignt: 89762

3.0-

2.5-

I 1.30 11.35 11.90 11.95 12.00 12.05 12.10 12.15 12.20 12.25 12.30 12.35 12.40 12.45 12.50 12.55 12.60 12.65 12.70 12,

M l n ____________________Ion 171.00: Area : Height: 0

2.3-

I

I

15 12.30 12.35 12.40 12.45 12.50 12.55 12.60 12.65 12.70 12.1

jji;

441

II.I? 11.30 11.33 12.40 12.45 12.50 12.55 12.60 12^65 12.70 12i L 7 !

o£'st sc'st cc’si srsi or si scsi oo'si sen ocn ss'n om s,

Vt7

uZ*SI SZ'ST U3*ST ST 'SI uI*ST SO'SI 00* S:. Sc ' r

r

I

n :il<oTc3|-| q :i?0jh *uiVc££ uoj——

OE * S1 S3*ST 03 * ST ST'ST OT'ST SO'ST OO'QT S6*M 06'bT S8*t-T OS'bT S3>I 03>T S9‘fl 09 1 f! SS’rl OS'fT St-'rl Or>f M--O’ 0

-O' I

-t* l

CD

&03S03 •1u3t£<h 8693E :e3-<1^ :09‘63£ u0I

-9' I

-S' T

-0*3

C * mCihC

\ OU0uQDuiU-.j Q T J _[ — * (7jcqwrifj :

:puno'

nu/o * 091I t’ : I Z

osoja/f

:»3uai9'T ' I'l

juClu7£>

: a I 51 awe-:''^IcoS : iuauj £0 uOT.C.'.'JHUJ' :*TT

iri/i = o;

4 ?1Ef

b/HK020b03A60.dData File: .'chi Inject ion Date instrument: 59'

?mo i e

em/5'?72hG6l : 03-MhF:-2’ 72np60.i ID: 35TD021

DF020303A60.

16:^1

^HfiOurHumpi

Ina*r.oi 1.2 : l?3-39-5

dipyi-cne

'• Q.

Ion 276.00: Area: 213?4? Height: *40056

cmin ', cm •

>£>(M

I

1.2-

. 90 25 . ':'5 26 . oo 26.05 26.10 26.15 26.20 26.25 26.30 26.35 26. *40 26.45 26.50 26.55 26.60 26.65 26.70 26.75

___________ M in_________ __________________________________________________________________Ion 133.00: Area Height: 0

55 26.40 26.4D 26.50 26.55 26.60 26.65 26.70 26.75

nt ;

44 •0 I J .

Id . 26.40 26.45 26.50 26.55 26.60 26.65 26 . ■ 0 26.7f,

<:<10~&>

Data File: 7chem/5972hp60. i/DF020303A60.b/HL0203C7AC.O.d

Date : 03-MAR-2002 17:20



Volume Injected CuLi; 1.0 Operator: 2319

Column phase: J&U DB-5.625 Column diameter: 0.32

/chem/5972hp60.i/DF020303A60.b/HL020303A60,d <Part 1 of O

1.5-

1.4-

1.3-

1.2-

1.1-

1.0-

^r

>T1

c>1>

0-I

Data File: 2chem/5572hp60. ir'BF020303ACO.b/HL020303A60.d

Date : 03-MAR-2002 17:20

Client ID; SSTD0G0


Volume Injected <uL>: 1,0

Column phase; J8.W DB-5.625

/Chem/5972hp60.i/DF020303AC0.

_oInstrument: 5972hp60.i*=3"

Operator: 2319

Column diameter': 0,32

b/HL020303A60.d (Part 2 of 2)

1.5-

1.4-

1.3-

1.2-

1.1-

1.0-

0.9-

\s 0.8- orH

0.7-

0 . -

0.5-

0.4 -

m-P

i3?c<!■■C

+CMH75

I0/CHiIfl7)

18 1* 20

_JL^.j

0JH75

I<li

'll

<1*LL

17

Data File: /chem/5972hp60.i/DF020303A60.b/HL020303A60.dReport Date: 04-Mar-2030 08:38

Data file Lab Smp Id Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date Ais bottle Dil Factor Integrator

CompuChem

Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020303A60.b/HL020303A60.d SSTD050 Client Smp ID: SSTD0500 3-MAR- 2 0 0 2 17:202319 Inst ID: 5972hp60.i

SSTD050:2319

/chem/5972hp60.i/DF020303A60.b/8270Cv6.m 04-Mar-2030 08:38 mikhael Quant Type: ISTD0 3-MAR- 2 0 0 2 17:20 Cal File: HL020303A60.d7 Calibration Sample, Level:1 . 00000

HP RTE Compound Sublist: all.subTarget Version.- 3.50 Processing Host: einstein



DFVt

VoVi

1.00000'

1000.00000

1000 .00000

I . 00000



AMOUNTS

CAL-AMT ON-COL

NO,' NG,' S IMI 1AJ\ I > Y

■j :: :o 4C . 3 0 G 0

■; j . o o o

4- 0000

^ .0000

4 . .0000

; ■■. oooo

uG.0000

00.0000

s . 0 o o

5 0 . 0 0 C 0

00.0000

5 0 .of) 0 o

44b

Data File: iprt Date

/chem/5972hp60 . i./DF020303A60 . b/HL020303A60 .d: 04-Mar-2030 08:38

AMOUNTS

•jUANT S l o CAL-AMT ON-COL

^pounds MASS RT rv: :t Rc.L RT RESPONSe. 1 NG) ( NG) SIMILARITY

IE B'rr.zaloer.yde ii 7.460 7.460 '.0.911; 70853 50.0000 50.35 5 7 7 2

Phe-cl 54 7 . 646 7.546 ;0. 934 ■ 138897 50.0000 45.58

93 7.764 7 764 :0.94 8 : 98658 50.0000 47.05

2-Cr.:z,rc?r*".c: 12S 7.945 7.349 (C.959) 114660 50.0000 4 7.83 916

1 '■ 1.5 -Bichi: 14 5 8 . 103 8.103 .'0.9 9 Ci) 151325 50 . 0000 46 . 03

2‘ 1 , 4 - j Lchl : .-Db-.tzer.e 14 t 3.222 3.221 '1.004) 157907 50.0000 48.21

2: B^r.zy: aL"or,D'. 10? 6.441 3.441 11.051) 71419 50.0000 46.38

. I : . 2-2:-:-:o:-ors- = ?r;e 145 S . 475 a .'475 ; 1.035.) 147025 50.0000 4 6.63

2 3 2 - ‘\?zr.y : pr.e ad ' 1 0 9 S 627 8 . 627 '1.054' 85756 50.0000 44 . U8

24 2,2'-oxyci- 1•Ch1Dropropanei 45 & 6 6 1 3.661 : 1 .053' 133943 50.0000 44 . 74 8285

2: Aoecoonencne 1 0 5 c . 3 54 6.664 (1.093; 156762 50.0000 44 . 89 6141

2 5 ; - Me: ny:c:'.er,o : 10? ' D c- q q » . 3 9 9 11.087) 107022 50.0000 43.28

27 4 -Mecir/lphenoJ ICS' 8.653 3.898 (1.037) 107022 50.0000 43.28

2 : N- N: z roso - d: - X -orDp/: an: p.e 70 3.381 8.331 (1.035) 79303 50.0000 44 . 19 7343

1 1 7 5.733 5.03 3 :i. 10 3 ) 67965 50.0000 48.64 8877

: X:: 77 9 . 152 9 . 152 (0.884) 132650 50.0000 47.17 9268

: : :v:pAf: o::- 52 9.555, 5.553 (0 . 923) 207385 50.0000 46.82 9154

y : .• 5.692 (0.93 6) 57780 50.0000 48 .31 8564

12 2 9.795 5.795 :0.946? 31855 50.9000 48.58 8639

a 2a : • ••••.--. •• 9.947 9 . 94 7 (0.961) 133196 50.0000 49.96 9912

^ • :a.a : . : r 2 10 115 1 j . 11 6 ;0.977; 117516 50 . 0000 47.36

1 7 10.251 10.251 (0.930) 139256 50.0000 47.27

• t a 10.337 • x a 7 11.003) 314335 5 0 . 0 0 0 0 46.65 8742

1 2 7 10.433 10.438 (1.013) 140280 50.0000 49.39 8947

: ■ r. A >: n ~ A. : ■' ^ ■;r,.rj 2JL 1 'J 6 0 7 1 . 5 0 7 ; 1. 024 :■ 113878 50.0000 49.43 9159

a ::: D J -i ' 1 A 4 Q 24 022 5 C.0000 48.92 8736

a ' aa . 1 11.35: a . :• r.: ■ 1 . 0S6) 10190? 5 C . 0 0 0 0 4 9.40 8950

2 -X-: :v.';a:,ad r : 4 2 i 1 . 6 01 a:s ;:. 12 i: 240085 50.0000 47 . 80

■W ■ r.i:: .=!■ ■. ••: 1 : .774 77.. :; . 12 7 ■■ 192978 50.000C 47.83

P.-v.-, ■, - 7 • - '47 c 1: .575 ■2.584) 100430 50.0000 51.68 9364

2 •; . • -7r : ::••••:•. . 12 . 0 9 12 . 15 5 ■; . 10 0 1 9024 6 50.0000 48 .48

; i • 2': a-.-a' 12.1.6 ; 12. 182 ::.907; 100708 5 3.00C0 49.70

■ 1 . 1 ■ 12 417 12 4 17 ■ a-; 264 133 5 0.0000 4 6.47 9185

- - 2;. : DA-:; 12.; 51 12.421 ■- ■■ 241031 50.0000 45 . 97

4 •• : : . •••• 12.627 ■ a a aasa 100.000 95 27 906 ’.

1 2 : 2 . • •• 337590 50 . 0000 4 9.02 9 82 1

•: 1 :;. .-a.: 2 • 7 2 9 0 6 50.0000 49 . 66 9 0 ; 0

: 1 . 1 396345 50 . 0000 4 7 . 0 0 9 ? 9!

V.: . ■ 13 3 0 4 ; ? 2 5 4 : 775 : 147395 100 coc 94 . 62 9-79

■- AD;...A 5 4 15 4 f \ a . r . 1 '.24; 2 3. 0 5 ? 2 5 C . 0 0 0 0 9a .49 a-23

:-■ ; 1 3 . 5 3 " . : . 2 1 . 7 0 7 ; 22215? 250 000 2 .0

-., ■ - ? -■ 1 :■; 12 2 9-) 1 100 000 7 8.93 ;-717

■- ■■■■ s ; . 7 7 . .._ . J 5 106450 50.9000 4 8.96 •(916

- : • » : . • ' •; 1 0 2 8 ; 441621 50 . 0GCC 4 7 . C- i 7 3 4 9

1 4 .21' 1 . 0 = ? 314 6 14 50.0000 4 9.01 9645

;.: v: •• 1.072. 150877 50.0000 4 4 . D 6 7354

.4/ 1 ^ 2 , 3 2 9 5 5 e 5 3.000 0 4 4 . 7 7 1 9 6

44 i

Data File: /chem/5972hp60.i/DF020303A60.b/HL020303A60.dReport Date: 04-Mar-2030 08:38

Compounds

62 4 - N i troam i ins

63 4 , 6-Di.nit.ro-2 - methyl phenol

64 N-Nitrosodiphenylamine

55 1.2-Diphenylhydrasine

66 4 - BrcT.opr.eny 1 - phenylether

6" Hexacr.lo;'wbenzene

6 S At ra z me

65 Pentacn1drophenol

7 0 Phenar.t hrene

7 1 Anthracene

22 Carbazole

2 3 Di - .n - buty 1 pht ha I at e

n4 Fluoranthene

25 Benzldine

26 Pyrene

22 Buty1 benzylphtha late

2£ 3,3' -Dichiorobenzidine

2 5 b i s »’ 2 - e t h y 1 h r y i i F h t ha 1 a t e

QC Flag Legend

M - Compound response

amounts

u<-u-.T Sic CAL-AMT ON-COL

MASS RT EX? RT REL RT RESPONSE ( NG) ( NG) SIMILARITY

1 3 S 14 .447 14 .447 (1.076) 150242 100.000 95 . 66 . 8759

1?8 14.498 14.498 (0.903) 134057 100.000 100.0 9663

16? 14.616 14.616 (C.910) 213376 50.0000 49.43 7982

77 14-684 14.684 H.093 ) 365818 50.0000 49.35 9357

248 15.255 15.259 (0.950) 119926 50.0000 49 . 30 94 32

2 84 15 . 372 15.327 -'0 . 958 J 137774 50.0000 49.86 9617

20C 15.547 15.547 t'C.568) 16882 50.0000 32.62 9096

266 15.733 15.733 (0.980) 56378 100.000 91 . 15 8422

173 16 . 105 16 . 105 (1.0C3! 496674 50.GC00 48 . 83

179 16.189 16.199 (1.008) 477906 50.0CC0 46.72

167 16.477 16 .427 (1.026! 400210 50.0000 SO .44 9093

14 5 12.069 12.069 (1.063) 666310 50.0000 50.21 93 03

202 15.203 16.203 (1.134) 573470 50.0000 48.85

184 15 . 423 18.423 (0.890) 193938 100.000 89.28 3945

202 18.609 18.609 (0.899) 580941 50.0000 49.02

14? 19 . 208 19.208 (0.953) 316447 50.0000 51.71 9562

2 52 20.622 20.622 (0.997) 229753 50.0000 49.16 6 913

:■;? 20.656 2 0.6 5 6 (0.993) 395276 50.0000 46.25 504 3

225 20.673 20.673 ( 0 . 599) 593605 50.0000 49.36

223 20.723 20.723 (1.002) 497786 50.0000 46.71

14 5 21.654 21.554 (0.930) 679141 50.0000 47.80

T C *1 22.463 23.333 (0.565) 627S96 50.0000 51.61

2 52 22 . 5 34 22.534 '.C . 967) 502900 50.0000 45.72

252 23.127 2 3. 177 (0.995) 479685 50.0000 49.26

2 76 25.272 26 .272 il.123) 513015 50.0000 4 9.37 C iM) \

2 7 5 ~i s i 2 ' nr ' o ■j (1.130) 439434 50.0000 48 . 59 393 1

276 27.186 2 7 136 (1.167) 436122 50.0000 49.61 7709

manually integrated.

> - p - u L

Data ^lie: • chern/5'?72hp60. i/DFO: Infection Date*: 6;.-MhR-2002 i"7:! Instrumenr ; 5972hp60.i Client Sample ID: 3STD050

■ouncJ: 1 na~

Mumoei': 1:':<■ 1.2. 3-cd : pqr~ -3?-5

ipr 0 . p/h! 3h60.a

Ion 276.00: wrea: 51301

Oj r 4c-i

Height: 93704

6

i

2.5-

I .5-

1 .0-

26.1 26.2 26.3 26.4 26.5 26.6 26.7

__________________M m___________________________________________________ _Ion 139.00: Prea: 0 height: 0

Cy

i n

26.4 26.6 26.7

n r : 0

44o

26.5

Data File: /chem/5972: ;p60. i/DF020303A60.ti/HG020303A60.d

Date : 03-MAR-2002 14:01

Client ID: SSTD080


Volume Injected CuD: 1.0

Column phase: J&W DE-5,625

/'chcm/'5972hpfe0. i 7DF020303AC.0.b/HG020303Af.0.d (Part 1 of 2)

2.3-;

2.2:

2.1:

2.0-

1.9:

1.8-

1.7-

1.6-

Inst rument: 5972hp60.i

Operator: 2319


'...3

LO

Data File: 7chem/5972hp60. i/TiF020303A60.b/'HGC120303A6u.d

Date : 03'HAR-2002 14; 01

Client ID: SSTD080


Volume Injected (uL): 1.0



Operator: 2319


7chem/5972hp60.i7DF020303A60.b/HC020303A60.d (Part 2 of 2>

ejtHTJI4*c

18 18

; ft. ,,i L. i i

1'4

451

Data File: /chem/5972hp60.i/DF020303A60.b/HGO20303A60.dReport Dace: 04-Mar-2030 08:37

CompuChem

Data file : Lab Smp Id: Inj Date : Operator : Smp Info : Misc Info : Comment : Method : Meth Date : Cal Date : Als bottle: Dil Factor: Integrator: Target Vers Processing

Semivolatile Report /chem/5972hp60.i/DF020303A60 SSTD08003-MAR- 2 0 0 2 14:01 2319SSTD080:2319

/chem/5 972hp6 0.i/DF020303A60 04-Mar-2030 OSM"7 mikhael 0 3 -MAR-2002 14:01OZ,

1.00000 HP RTE ion: 3.50Host: einstein

SW-846 Method 8270C .b/HG020303A60.d Client Smp ID: SSTD080

Inst ID: 5 9 72hp6 0.i

b/8 2 7 0 Cv 6.m Quant Type: ISTD Cal File: HG020303A60.d Calibration Sample, Level:


4



^ DF 1.00000 Dilution Factorw 1000.00000 Volume of final extract (uL)^ Vo 1000.00000 Volume of sample extracted (mL)

Vi 1 . 00000 Volume injected (uL)


AMOUNTS

0JAN7 Si 3 CAL-AMT ON-COL

' yrv.-r-nds MASS R: ' XK‘ -- RESPONSE ! NG) ' NG}

5697 3

224311

167^69

2: a: ? 9

359192

252595

56 7 E18

- ~ n ■ fi r,

759056

25408':.

•I 3 . :,ono

•; o . o c o o

•; n .0000

; o . o o u:

40.0000

4 0 . C 0 0 0

SO . 0000

9 0 . 0 0 0 0

6 0 . 0 0 0 0

9 0.00 0 0

50.0000

9 o .noo r.i

5:. ooco

60 0000

r. 7.00

) . 00

50 . 00

5 0.00

3 0.00

3 C . 0 0

SIMILAR I"":'

• . V,.- • .. i

Daca File: /chem/5972hp60.i/DF020303A60.b/HG020303A60.dReoorc Dace: 04-Mar-2030 08:37

"pc ar.ds

Ou.ANT BIB

MASS 3*T K>:r ?.T PEL ST RESPONSE

CAL- AMT

: no

ON-COL

( NG) SIMILARITY

5 Beroza iaer.yd* 77 7.477 7.477 C . 9 11: 109279 80.0000 90.00 9172P::erci'

94 7.542 n 6 4 6 10.9321 264357 80.0000 SO . 00

:7 Bis .2 - chizreezhyl - ezner 0 7 7 . 764 7 ">64 '0.946'. 181559 80.0000 6 3'. CO

:? 2 - 2h 1 orepner.c : 2 ? 7.842 7 54 ? ■'0.957! 212381 80.0000 8 C 0; 9038

-- i. 3 J l'i ch 1 c robbnCcna 145 8 . 103 a .101 ( 0 . 9 S 5 ;■ 290202 SO.0000 so. 00

1,4•Di chlorobenzene a 2 * r .221 i ’ rl u 2 ' 286972 30 . 0000 s 0.: 0

- - Benzy 1 a loc-noi i ■: s 8 . *i i. 5.441 '1 02 9.' 139546 80.0000 80.0:

^2 3,2- :■ i c h I o r c b e n z e r. €• 14 o 5.475 3.475 ;: . 0 3 3 i 272537 90.0000 so. oc

2 - m s c h v 2 d h e r. o I 109 3.644 0 c.p ■: 1 . 054 } 175420 SO.0000 80.00

24 I 2' • oxyc: s . 1 - Ch: oropropane '• 45 8.661 r> . 0 0 1 : 1 .0561 264702 80.0000 60.00 8334

~i ^ Acetophenone 1 0 5 8.361 5 . 0 S 1 ■: 1 . 082 ; 313697 SO 0000 80.00 7901

-■j 3 -Mezhylpnenol 108 • 8.393 ' S . 3 ? 5 1. s 51 214569 80.0000 80.00

7) -< 4 -Met ny:phenei 10 8- 6 i 9 S 3 3 0 S >' : .035) 214565 80.0000 SO . 00

--- N - N: t rose - d i - N - propyl amine 7 C ■ 8.331 5 . A 8 l i 1 . : 3 2 ) 158995 so.0000 80.00 704 5

H-e:-:a zh ■ ernetnare 9.033 9.233 '1 101) 119546 50.0000 80.00 8512

;• e Nitroner.zer.e 77 9 168 9.155 (0.356) 240569 80.0000 30.00 94 52

isochcror.e 5 2 ? . 5 7 > 9 .575 (0.925) 389565 80 . 0000 80.00 9440

12 ? 9 . 7 ; ^ 1 :3 .0.933) 120423 30.0000 30.00 9000

2.4-L:m~::.y.ph-:.:.; 12 2 9 . 7 94 5 .754 ■ 0.945) 152170 30.0000 eo. 00 8373

bis': - ::. i o c. : i o y ’ .7. e : h a- r' 3 9.-47 5 4 4 7 : 0 . 9 6 1 ) 224808 80.0000 so. 00 8 6 6 6

■- 2 4- Diceic roehene 2 ■ 'i 7 12 13 3 1 0 1 3 ' ;0.979) 215902 80.0000 80.00

170 10.258 10 . 266 :C.952!. 258805 80.0000 80.00

12 5 10.403 1 O' .403 11 . 0 0 5 i 576418 80.0C00 90 . 00 9411

4-Dhlorcan i 1 i:v- 12 7 12. 4 3 3 10.455 (1.013) 232715 80.0000 80.00 3932

;v Hfxacn 1 or :• r •: t -.v i 2ir 10.505 10 -yis (1.024) 19584? 30.0000 80.00 9766

-' _rtl‘r 1 . FI B'". 11 .757 — . 1 .072' 41473 8 0 . 0 0 0 0 80.00 8SP0 !M) 1

- : ? ■ "-.ioio- ; i ?■? 11.368 1:. IPS (1 . c 9 8 '< 175523 30.0000 80.00 9353

O-M^.hyinaphnhal-r.e 142 .00; 11 .505 (1.121! 428754 SO.0000 80.00

: - Mvi--1 14 2 : • .77-; : 1.774 (1.157) 339356 50.0000 h C . 00

: ' :yv: : •:. . 2 2 7 1. 4 ” 5 • ’ : 7 t l 2 . 6 4 1 1 a Q c 0 0 53.0000 80. 00 0 818

■; I.-;.- - T : : 2: r; :'r.-r.o 2 12.112 : .1:2 :c.902) 161030 ■SO . 0000 90 . 00

: . . b -T: :"::2c:-op:--;:-,2 1 2 . : 5 0 12 12 0 (•:. 50 7! 182767 3 0.0000 80.00

" ■■;.• *y* 1: ; 12.434 ‘.2.434 : : . 5 2 6 • 51 374 0 60.0000 30 . 00 8414

1 - Dh 2 :: 2 • :>.• 2 5 2 12.45 7 '.2.4-7 446753 30.0000 80.00

c " :: 654 ; . 54 2, -> ~4 i 7 160.000 16 0.0 9185

: i r.y 2 r." ' « 2 c ■ - - ; • • 2 2 2 4 " r .05-. 5 6 54 0 0 SC . OCCO ao. 00 9136

: ■■ 1. ■ . : -ip.:? 30.CC00 3 c. 0 c 93 5 5

:".: '.2.2 ■- ■ : :■? 30 0000 3 0 . 0 3 9 4 01

..2.05. • 265590 1 6 0.000 ::o.: 04 04

■-00 1 2 . ; 4 -■ 413711 = 0 -0000 5 0.3'".' r, ~i i ^

■ .-.v : ; '. 0 - _ . 0 2 4 J r ? 4 5 400.005 4 3’C . '■

, : p :■ i 2 " .2 1 2 1 • 2 2 5 1 z/j iSl.DOO 1 3 0 94 34

' • .• - ; ;• c 2 - 1 . 026■ n2-.11 6 0.000 Ci 0 *‘j Q "j 8774

:■■■■ •; 1 : : 7=5720 5 0.0 0 0 0 5 0 . 0 0 a z. c ’

•• * ~ -••••• r...................... • ■’ • . -r - . " ■ = • • ••■ k-‘ • • " - ■ u ■j 3 ^ c

2 - :-o I--::-.-::-..-'. c vr.y 2 -12ie : 2 2 •; 1 j • • 1 1.: ? :• > 1-.--2H 5 0 0 0 :.'M)\

F 1:: ; 4 -i : : ■■ 1 . 17 5' ^ 54 ' ^ 3 0 00'’° 50.00 ' 717 ‘

45o

Data File: ./chem/5 372hp6 0 . i/DF0203 03A6 0 . b/HG02 03 03A6 0 . d Report Date: 04-Mar-2030 08:37

5 2 4 . 4 - Dir.: z ro - 2 - nenhylphenoi

64 N -Nicrosodip.oer.yi amine

:: 1, 2-D:pher.yihynrazme

5 4 4 -5:G.mopr.eny: • yhenylecher

r e n t a c r. i o i' c- c n e n c .

I’d Pher.ar.chrer.e

7 I Anthracene

72 ■Taroazoic'

7 3 r: - r. - bucy; phc ha late

74 Fluoranthene

- Compound response

O'JANT SIC-

mass RT EX? RT EEL RT

13 S 14 .4 64 * 4 . 4 d -t

193 14.514 14 . 514 i 0 . 5 0 3 )

169 14.616 14 .616 (0 .905■

77 14.634 14.634 il.033»

2-i 3 15.276 15.276 ;C.951

2 9 4 15.177 :=.i77 : •: 9 5 7.'

2C0 15 . 'j 4 -j 15.54 o .' C . 36 7}

2 6 6 15 . " 3 15.. 73 3 : C . 5 7 9 )

17S 16.1.5 1 6 . 1C 5 I 1 . 002)

173 1 6 . 2 0 6 16.206 (1.008)

167 16.47_' 16.477 ' 1 . 02 5)

14 9 17 . 06 5 17.065 : 1 . J 6 2 )

202 16.215 18.219 (1.134)

184 13.439 IS 4 3 9 >' 0 . e 9 1)

2 0 2 18.603 18.605 ( 0 . S 9 9 )

i 4 y 19 . 708 15.70S (.0.95 3)

TCI 2 c 4 2 2 22 . 522 i 0 . 5971

1 4 9 2 l . 654 20.455 ■'0. 9 3 s ;

2 2°. 20.673 2 4 673 (0.999:

223 20 74 0 2 ■. 7-r 3 (1.002)

14 9 21 . 654 21.654 (0.529;

252 2 2.50 0 22.503

'•'CO 22.550 21.553 : D . 94 7 ;•

2 52 2 3 . 1 9 3 2 * . 1 5 3 < 0.5 9 5)

2 7 4 26.255 ~ -) ^ r. ; 1 . 113 i

779 2 5.55 o c . j i 0

274 27 ")";•) OU . 2 2 0 •. 1 . 1 A B '

manually intearaned.

AMOUNTS

CAL-AMT CN-COL

RESPONSE ( NG) ( NG) SIMILAR .’’TY

269615 160.000 : 4 . o c • 1 ?

251793 160.000 1 o. 0 8 r 1 :*

379012

ooooo

3 c. o 8 502.

599307 30.0000 8 0 0J 8716

209916 SO . 0000 80 . Or 8705

241003 30.0000 80 . GO 9295

2935 80.0000 30.00 S622

163090 160.000 160.0 9196

351323 80.0000 80.00

882630 SO . 0000 80.00

64 1447 30.0000 30.00 8673

1080618 80.0000 80.00 3915

983385 80 . 0000 80.00

281890 160.000 160.0 84 36

1013043 80.0000 80 . 00

516569 30.0000 30.00 9196

4 3 1S17 30.0000 30.00 7529

■30785 3 0 . 0 C 0 0 80.00 9574

1071777 SO.0000 3 0.00

993339 ' 80.00C0 80.00

1262937 30.0C00 eo. oo

932062 80.0000 8 0.00108 714 2' 90.0000 3 0.00

393373 SO.oooo 80.00

964633 30.0000 80.00 893 0

843146 80.0000 80.00 8902

608731 SC . OOOO 8 0.00 766 3

45 A

:=. rL If: .•Vnfm/nl^ZhjjGO. 1/DF020:

.]fct ign Data: OZ-h^F.-ZOOI 1*4:01=.r-• Ijfr^nr : 59~ ZhoOO . 1:enr '5amole ID: 53T0030

h£iU . ij/HGOZO JiU-jHf.O . d

"□ouna: 2.4. 6-Tr ibromoDnenoi

Nijmcier: 1 13-39-3

Ion 329.60: Area: 137100 Height: 6Jj51

1 .5

1.0

14.7 14.3Mm

14.9 15.0 15.1 15.2 15.3

Ion 332.00: Or Height:

15.1 15. 15.:

15.0 15.1 15.:

45

is.:

0

jjit =, v i ip: •• cnem-' 5'?72hp60 . Df 020303HbO. o •HG020393HbO . oInfection Date: 03-MhF-2002 14:01I r\~ t runenr : SO^lhoGO. iClient Sample ID: zbTDOOO

Ion 113.00: 'Area: JlJ7b Height: 145i

. 6'.

b-

10.9 11.0 11.1 11.2Min______________________

Ion 55.00: Hrea: 3095 Height: 3095

11.3 11.4 11.5

1

i cn

11 .3 11.4 11.5

■■ t: 244;

45b

11.2 11.3 11.511.4

J=i"3 'ii?: .• i:he<Ti./5972hp60. i- DrijZCGOZ-^bO. d/HGOIO^OjhoO . a Injection Date-: 03-HmF-2002 lJ:ui I n = t rument; 5972hp50.i

•=nr Samole [[i; 55TD080

ouno: *i-Ch loroonenu i -ijnenu 1 ether' lumper; ^0'J5-72-7

1 .9-

i. 6-

Ion 204.00; Hrea: 351265 Height: 19S273

rri

1 j . 0 14.1 14.2 14.3 14.4 m.5_____________________________________________M 1 n

14.b 14.7 14.8 14.?!

Ion 206.00: Hrea: 0 Heieht: 0

14.5 14.6 14.7 14.8

4 5 7

14.6 14.9i1 14 14.8

l-t.884

k- I

14.884

Data File: /chem75972hp60.i/'DF020303A60.b/HJ020303A60,d

Date : 03-MAR-2002 16:01

Client ID; SSTD120


Volume Injected CuD: 1.0



Operator: 2319


:o

LD

Data File; roher',/5072hp60. i/DF020303A60.b/H;i020303H60.d

Date : 03-MAR-2002 16;01

Client ID; SSTD120 Instrument: 5072hp60.i


Volume Injected <uL); 1.0 Operator: 2310

Column phase: J&W DB-5.G25 Column diameter: 0.32

0~)

LO

'vd'

/chem/'5072hpfc0. i/DF020303Afc0.b/HJ020303A60,d (Part 2 of 2>

LJ L

IS 10

1 I

Data File: /chem/5 9 72hp6 0 . i/DF020303A60 . b/'HJ02 03 03A60 . dReport Date: 04-Mar-2030 08:38

CompuChem

Data file : Lab Smp Id: Inj Date : Operator : Smp Info ■ : Misc Info : Comment : Method : Meth Date : Cal Date : Als bottle: Dll Factor: Integrator: Target Vers Processing

Semivolatile Report /chem/5972hp60.i/DF020303A60 SSTD12003-MAR- 2 0 0 2 16:01 2319SSTD120:2319

/chem/5972hp60.i/DF020303A60 04-Mar-2030 08:37 mikhael 0 3-MAR- 2 0 0 2 16:01 51.00000 HP RTE ion: 3.50Host: einstein

SW-846 Method 8270C .b/HJ02 03 03A6 0.d Client Smp ID: SSTD120

Inst ID: 5972hp60.i

b./8270Cv6 .m Quant Type: ISTD Cal File: HJ020303A60.d Calibration Sample, Level:




DF 1.00000 Dilution Factor

vt. 1000.00000 Volume of final extract (uL)

P 1000 . 00000 Volume of sample extracted (mL)

\J r 1.00000 Volume injected (uL)


1AMOUNTS

. LAN!' : G CAL-AMT ON-COL

is 1 v ,7 - ,7 RESPONSE : FJG) ( NG)

-.: ■ ■ - . i . 0 0 00

: :■ . ;;v

■ A.:-::.-,;:.:;::--..- - ■- ;' : 1 n i 0 3 9 4 d . 0 0 0 0

i.: , ■ ?. -< ■:-*:: . c . o o o o

2 : - • 377QP4 4 d . nnoo

- ' - um-ir :7c..-:; -C -

- ; . -!: • ■ • ■

::. - : : I2C.000 lib. 9

: .: :. 4 cio.coo ::0 7

. : 7- tc.-.r • i : . - - "• . .•: i I j 9 31r ? . 12 0. 00 C lib . 1

. ;■ ; .: 4:2. ■: b i 120.0 00 117.:

. •> " 1 3 '} 34 12 1 . '■ 0 '3 '14.;

5

oIMILAP.IT

46U

Data File: /chem/5972hp60 . i/DF020303A60 . b./HJ020303A60 . dReport Date: 04-Mar-2030 08:38

k'uA2'« : itij CAL-AMT ON-COL

^pounds MAS S ?.7 pv? RT REL RT RESPONSE 1 NG) ( NG) SIMILAR:TV

15 Ee-zal uehyie 77 7.475 7.473 . . 9:1, 137022 120.000 10 3.1 913 ■;

Phene: . 94 7.55 :■ 7.659 ' 0.934) 349394 120.000 115.9

• “ Bis 2 - cr. 1 or?-e:.:v/2 1 echer ? 2 7.77? 7 7 7 C ;c. 243: 239995 120.000 117.7

1? 2 - Ph ; :noche:n-n 12c 7.545 1 345 < n . .= 5 7 > 269075 120 00C ii7.:- 8937

Id 1 . 3 - 2:c;;io:-:oe:;:ete 1 -i 6 i.05R 5.000 .3.95=: 377599 1 2 0 0 C 0 119.4

2 3 1 , 4 - d: chic vicer.^ne 14 6 2' 7 3.217 *'1.0 1 2 3 0 9616 120.000 117.5

21 benzy: elcenol 10 2 = .457 3.437 (1 . 02 5■ 179201 120.000 119 . 1

2 2 1. 2 - D i chicrobenzene 14*5 5.471 9.471 ■'i 7 - 7 - 363165 120.000 119 . 9

2> 2-Mechylpeencl 10? 5 . 44 0 3 . 4 4 C '1.054: 227264 120.000 11 e. c

24 2,2' -oxybi 3 ' 1 - Cn 1 c-ropropane : 45 5 .'5 = 7 9.657 >1.054 344834 120.000 117.9 3 3 0 3

2; Acer opr.en cn- ICS 5 -7C 5 . 67"> 1.08 3 ; 426126 120.000 123.0 8 126

? ->:e:hy: phen.: 103 5. 8 55 3.994 (1.085- 300041 120.000 121.6

2 *■ 4 - Mec hv lpheno : 108 3 =74 p C Q ^ (1.085) 300041 120.000 121.6

2 9 N * N: c rose -hi- N - prepyiazn ne 7 0 5 .7 -7 6 .377 !1.033; 218470 120.000 121.6 0(m: \

23 Hexachloroe:bane 1 1 3.04 3.045 ( 1 i r> i 1 155699 120.000 117.1 9168

3 0 N ic robehzene 11 9 . 15 3 3.165 { G . 3 S 5 J 326256 120.000 117.5 94 2 9

33 sophoror.e 32 9,571. 3 . 5 ' 1 ( 0 . 525) 519393 120.000 119.0 9 3 57

12 • ' 139 3.704. 9.705 • r Q 1 ; 1 163244 120.000 120.4 2 Q 5

1? 2 . -1 - 2 : n-r, l hy 1 nneno 1 ' ? 7> 9.791 9 .791 (0.946) 193934 120.000 115.8 S 3 58

b:e :■-■■:n:.-,; :-rne-v ne:h.-,n.e 3 9.34 3 0. 00 5 (0.361.1 306241 120.000 118 .2 864 9

ll 2 . -xl v: re-: 162 12.123 . 125 ( f . y 7 5 ) 293058 120.000 119.6

122 1 C . J 6 4 10.264 (0.992:- 345713 120.000 118.6| --'I:-

122 10 -4 0 0 10 4 00 '.1.0 0 5 ■ 307511 120.000 120.0 9 3 6 3-

• i 7 10.001 :o.501 ■: 1. oi5) 321823 120.000 117.6 3917

12 He:-:enh:e:rr n i.nee 22 5 10.-2:;: ::. 4 2 c ' 1.026' 263238 120.000 119.3 922?

- - i 11.7 2 :• o > "> C. 1 [\ 072: 59011 120.000 123 . 1 88 95 (M! \

; 1 ry.::he:-.A i 11.=44 (1.093' 240720 120.000 120 . 1 9131

il 2 _ i. 5 :: 1.121: 587510 120.000 119.0

.n-. hn.m 142 • * 777 1 13 7! 468741 120.000 13 n . 8

lexnnh in ..■ y:. np , e ::: env 2 o 11-972 0.552, 252G74 120.000 13 2.3 866 3

; 2 2 , 4 . 6 - 7ri -h . ;: :pheec: : vh :: i - 12.1 24 ■O.OOl: 2 | r. 1 2 £ 120 000 121.3

2 •; . 5 7 I j: *. : o ; 2. : 12 17-3 (0.906) 217709 120.000 112.5

154 -2.43'; : 2 ■ 4 ■ ' '0 •} 7 4 ) 7 2 2-12 1 120.000 120.4 8195

•. - . y •••■•.•• v 2 :o o-: ; . 2 7 ' 517602 12L 000 119.5

"2 : 1 •' 11 " . V 4 1 •14 5 12 7 2 4 .:. 0 0 0 2 2*= .6 ?! ?7

I.--' . , “ ■ ■ : 1 ■" 1 - 7 -, 7 9 7 7 i 2 -. .000 . 115.1 555R

• 15555P :i . o o o 116.3 9 14 =

■ - : 5 2 555=55 .000 1 i 7 . = 54 7 7-

342850 h. 00 a 7 ? 9 57 = 7

: 4 A- ::. : 5 4 1 .004. 55755: : 20.ooo " 2 1 :-4 0 7

- - • ~........ -4 : - . 0 : 0 6 5 2 2 7 3 ■■■ 00.000 7 1 2

-■ A - .' r *> <, c, 7 £ r. 24 0. n:;o 24 1 7 -.b

- •; ;• , ;■ ; - . . -51. 2 :• 1 j -1 •'.) 12 0.?0 0 12.. 7 5 7

- :■ ■■ : : •: - 3 4 5 ' : 5. - v. 1.02 5 - 1:612 2 5 120.000 : 2 ' 2 3555

: ■; v :4 2 '■ 11 . i ■ 1. :■ = = . 3:9327 120.000 115. 3 9 14:

• ■; . p-nyhy n 7:4 • 7i 4: ■ .5 10 1 . O' 7 2 : 322516 12 0.00 0 12 7 2 M, \

:-6 * 1 . ~ 2 . 120 00? '23.7 7 0 7"

',-461

t ->. <-

Data File: /chem/5972hp60.i/DF020303A60.b/HJ020303A60.dReoort Date: 04-Mar-2030 08:38

AMOUNTS

quant s:g CAL - AMT ON-COL

L-~pounds MASS RT EXF RT REL RT RESPONSE [ NG) ( NG) SIMILARITY

52 4 -Nicroanilme 138 14 .477 14.477 11 . 0771 346S25 240.000 226 5 8 5 57

5 3 4,6-Dinicrc-2 -methy Ipnenol ■95 14.511 14 .511 (0.903 = 34 086 6 240.000 2 5 C . .: 7?7r

•5 4 N - N i c rosod l oh^nv: ar.i ne 16a 14 . 6 2 z 14.612 ■G.505) 492579 120 000 115.2 3682

3 5 1,2-liphenyl hydraoine 77 14.530 14 580 (1.052: 334159 120 000 11Q 8742

6 4 - Sromcpheny: - oner.y lecher t 4 0 15.272 15 2 72 T .550! 283947 12. J . 000 117.8 9291

'T Hexa c h. I o r obe;: - er.e 264 15 3=0 15.390 . 9 5 9' 322523 : 2 0 . 0 0 0 117.5 9 04 0

)9 At ratine 200 15 . 542 15.543 ' G . 16 7' 2356 120.000 5 . 51 8119 (a

•: 9 Pencachloropher.c: 266 15 . 720 15.729 : C . 7 5 205416 24 C. 000 261.7 8821

’’■? Fhenancr.renm 17$ 16.116 16 . 11 S : 1. eoi 1197263 120.COO 1 18 . S

2; Anthracene 1 7 S 16.2C3 1 6 . 2 C 3 (1.023■ 1230579 12C.000 120.4

22 CarbazcOe 16" 2 t 4 5 : ■ 16.450 :i. Q'Jr - 902314 120.000 117.1 q22 5

"•'3 D: - n - duty 1 phtna i at e 14 9 17.052 :7.032 •1.062: 1531388 120.000 119.3 9626

24 E1 u 0 r a n c h e n e 202 18.215 19 .215 '1.1341 1376284 120.000 118.6

?5 3enzid:ne 154 18.436 1 0 . 4 3 5 ( 0 . S 9 Cm 318184 240.000 149.6 8548

2-; Pvr^n- 2 C 2 ' 3 5 2 2 18.622 1 0 . 3 5 e ; 1406929 120.000 114 . 7

14 0 19 704 12.704 (0.952) 699859 120.000 113.2 9121

i.l-lcni::;-::::--. ? g '> 2 0 .618 2 C 1 4 ’ 0 . ? 9 6 1 545300 12 0.0 00 112.2 7961

O c-sll-hyl-v; Ph: r.a laz~ 14 0 ' 20.652 20.652 10.998) 1101654 120.0C0 119.6 9742

“••• Benzc :a ■ an.: hr icene 2 2 3 20.636 20.6S6 i 0 . 9 2 9 ) 1449464 120.000 116 . 1

:1 Chrysene •11: 20.726 20.736 i 1 . 0021 1336201 12 0.0C 0 116.6

c2 2: - n - c-c y ion:: n , lace 14 0 21 550 21.550 (0 . 929) 1682062 120.000 118 . 5

Benzo'b. : icon —nere 252 22 .4 55 n -1 .- c. g (0.965) 1477875 120.000 124 . 9m —

-> g g 22.547 22 54'' (0 967) 1301121 120.000 115.6

2 5 2 23.1=0 33.150 ( G . 5 9 5 1 1158573 120.00G 119.2

he Indenc ' I , nynene 2 7 6 26 302 2 6 . 3 02 (1.128) 1231963 120.000 119.1 8 7 04

^ 2 i ben.no : a . h ' anthracene 276 2 ^ 5 • 2p.’53 : 1 . 131 * 1065275 120 . GOO 110 . I 9 ?2o

Hence n.h. . . yler.e 224 2 7 2 3 : 2" 23.;. '1.1-8' 1 G 2 4 3 8 4 1 2 0 .0:0 117 . 9 7 6 52

QC Flag Legend



Daio file: ' c hen•• 5972hc"-0.: ••'DF020503^60 . b/H JO. injection Dei : OD-^dF.'-DOOD i 8: 0 ii n = t nijmenr ; 5972n;jo0. *^l~nt Oamijle ID: 35TD1I'0

Mina : H-M i z rC'jo-oi -N-oroou 1 smi ne lumot* 1'' : 621

jwb0.d

Ion 70.00: Area: 218^70 Height: 110300

fv

N.cd

OD

3.70 8.-5 8.80 3.88 3.90 8.95 9.00 9.05 9.10 9,15 9.20 9.25 9.30 9.35 I______________________ M 1 n_______________________________________________________________________ |

Ion 130.00: Ores: 0 Height: 0 j

l

I

9.05 9.1 Jj 9.15 9.20 3.25 9.30 9.35

46 J

71. =' : . _-0 C.. :-5 9.99 9.05 9.10 9.15 9.20 9.25 9.30 9.35

Data File: 'charr,/5972hp60Inj^ction Date: 03-MhR-20' I ns t'' urgent : 5972np60.i

le^t Bampie' ID: S5TD120m'Ouna : 6 apro 1 ac t .an-i Hamper : L05-60-2

DF02016:01

■hdO.b/HJ020303060.d

Ion 113.00: Orea: 59011 Heignt: 151*48

m.j. .

1 .2

1 . 1

l

/

. 60 10.65 10.70 10.75 10.80 10.65 10.90 10.95 11.00 11.05 11.10 11.15 11.20 11.25 11.30 11.35 11.40 11.45 11.50 11.55

__________________ _ _______ Min ____________ .___________Ion 55.00: Orea Height: 4039

1.6

: : . i 5 11.20 11.25 11.30 11.35 1 1.40 11.45 11.50 1 1.55

46:;. 05 :;. :i.>* i:. 20 11.25 11.30 11.35 11. jo 11.45 11.50 11.55

J n t ■Si Inj* I ns*

i Tilt: cnem/5':'r2np>50•ct ion Date: 03~MhF.-20' rument: 5972fip60.i.'nt SamDle ID: S3TD120

1/DF02- 2 16: 0

ti/HJ' “O' 1h60 . a

Pfccuna: -:• NijUfOer :

.l’ilC'«"Oon*r.u 1 -ohenu let her '005-~2-7

Ion 204.00: wrea: 522916 Height: 365656

$

•7

TT ]

^ . o-

2.6-

2.4-

1.4-

1.0-

0.3-

0.6-

n. 4-

15.95 14.00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14^65 14^70 1^.75 14.80 14.85

__________________run_________________________________________________________________Ion 206.00: erea; 0 heignt.; 0

i or.

14.50 14.55 14.60 14.65 14.70 14.To 14.80 14.S5

46 0 !

0 ;j. 1J.50 14.55 14.60 14.65 14.70 14 '5 14.60 14.85; J “ ■=. i j

Data File: /chem/5972r,l-.C,0. i/DF020303A60,b/HH020303Af.0,d

Date J 03-MAR-2002 14:41

Client ID: SSTD160

Sample Info: SSTDlfcO^SlS1

Volume Injected <uL): 1,0


Instrument; 5972hp60*1 •_DCD

Operator: 2319


Data File: /chem/5972hp60. i/DF020303A60.b/HH020303A60.d

Date : 03-MAR-2002 14:41

Client ID: SSTD160 Instrument: G972hp60. i

Sample Info: S3TD160:2319

Volume Injected <uL): 1.0 Operator: 2319

Column phase: J&W DB-5.625 Column diameter: 0*32

CD

7chem/5972hp60.i7DF020303A60.b/HH020303A60.d (Part 2 of 2>

5.2

5.0-

4.8-

4.6

4.4

4.2-

4.0

3.8

3.6-

3.4

3.0-

2.8-

2.6

2.4-

2.2-

2.0

1.8

1.6

1.4

1.2

1.0

0.8

0.6

0.4

0.2

LJ

IS

l—i’r>

..__ J l_J LJ

Data File: /chem/5972hp60.i/DF020303A60.b/HH020303A60.dReoort Date: 04-Mar-2030 08:37

"ompuChem

Data file :Lab Smp Id:Inj Date : Operator Smp Info :Misc Info : Comment : Method :Meth Date :Cal Date :Als bottle:Dil Factor: Integrator: Target Version: Processing Host:

Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020303A60.b/HH020303A60.d SSTD160 Client Smp ID: SSTD1600 3-MAR- 2 0 0 2 14:412319 Inst ID:SSTD160:2319

5972hp60.i

/chem/5972hp60.1/DF020303A60.b/8270Cv6.m 04-Mar-2030 08:37 mikhael Quant Type: ISTD0 3-MAR- 2 0 0 2 14:41 Cal File: HH020303A60.d.3 Calibration Sample, Level1.00000

HP RTE Compound Sublist: all.sub3 . 50einstein

Concentrat ion Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable



A 1000.00000 Volume of final extract (uL)w 1000 . 00000 Volume of sample extracted (mL)

Vi 1.00000 Volume injected (uL)


AMOUNTS

s;g CAL-AMT ON-COL

iCTpour.ds MASS ?T ^ ?T REL RT RESPONSE ‘ NG) ( NG)

. 1 .: cr.: l: • :4 E.I -.l- 7 - 3 2 0 40.0000

■- •' ""C" " : : u . o:o: 1 v ■> 1 5 -3 40.0000

: ••• • ••: ' • ••••" • : u ; ■■■:■: 0.7 '2 : .000: I 4 4 5 5 4 40.0000

? 7 - ■■ i. lo: : 2 B G 2 2 C 40.0C0C

* ?'y v v s -■ • :I ' : :.vo: 40.0000

* •' - i 3.. 2 64 /•: .'/ r: ■ i. ?• o i ■ 2 2 7 1 C 0 40 . 0000

“ ...- • • • ** - • -» - " =■ - ioO.OOO i7i . J

". 4; • ■ ': :• -. :• ?.: • 4624-f^ 1-30.0 0 0 155.3

• N : : • . : • ..-Hr 473S47 16C . 0 0 0 15 6.6

: or:-;-::.: 1 ~2 7 .. : n:: ■•.’4 306c 160.000 157.6

: :: • . ;. • ; •j ; • : ; -.••'• . •;. -5 :■ ■ . i 4 2 1 3 7 7 160 000 154.2

; ::: Teicr.-^r.v: : - - £ ■ . ;* 12 ■ 1 z' 5 g "> c 160.000 157.2

; ;• ■ 4 u - 1 . 4 £ c ' C . 4 2 3 ; 451572 160.000 146.£

•. 4 Yyr id:::-; : £ ; J f ;i ■:.427. /. L 0/22 160.CC0 145.4

SIMILARITY

468

Data File: /chem/5972hp60.i/DF020303A60.b/HH020303A60.dReport Date: 04-Mar-2030 08:37

.'CANT o _G CAL-AMT or;-col

-•impounds MASS R 4 EXP 2:7 REL ST RESPONSE 1 NG) ( ng: SIMILARITY

15 Eenzaldenvde ~7 7 . 4 7 n 7477 - ^ 1 ' ’ 148507 160.000 137 1 917?

54 7 . 663 7.663 to. 534J 49S843 150.000 162.6 ;r.

Bis:2-chioroe zh y 1) e ther 5 3 7 . 782 7 , 7 6 2 ;c. 44 8 ■ 320891 162.000 158 . :•

Is 2- Chic ropheno 1 128 7.64 9 7.349 , 0 . 9 5 7 ' 348818 16 0 0 00 152 . 1 8998

:v 1 . j - ■? u r. 1 c r' o be :l z e: i e 14 6 3 . 1C j 3.103 '0.535' 503465 16 C.000 15 6.=

IT :.<-::c,-.::.roh5n:w? i4G i.221 = ->2' ■:.00: 489474 160.200 155.1

i: Bezzyi alcohol 106 £ 4 4 1 S . 44 1 <1.0291 231243 150.000 152 . e

22 1 . 2 - Di cr. 1 orooer.zene 14 5 3.4'-' = 6 .475 ■1.033: 481611 160.000 1 5 S . 0

21 2 - Xethy • phenol 1 08 3 544 5.644 i 1.054: 296003 160.000 154.3

24 2,2'-oxyb:s<1 - Coloropropane) 4 5 3.641 3.661 (1.056) 466066 160.000 157.7 84 39

2 5 Acetophenone 10E 3.831 3.881 i 1.032) 547908 160.000 157.0 8318

2S :-Merhyipheno: 106 8 . 3 IE 3.915 '■l . 0671 415847 160.000 165.4 IA)

2 7 4 -Methy i'phencl 1 0 8 ' 3.915' 3.915. (1.OS 7) 415847 160.000 165.4 (A)

2 : N- N : z rose- d : -N - prepy Ian: ne 7 0 6.693 3.898 (2 .035) 309069 160.000 165.7 7697(A)

2 r Hrxacnioroezhar.e 117 5 . 050 5.050 11.103) 201941 150.000 154 .4 9174

K Nitrobenzene 77 9.16 9 5.169 (0.884 ) 419930 160.000 159 . S 9420

3; sophoror.e , 9 . 575 9.575 {c Q23) 639303 160.00C 154.9 9311

32 . 13 ;• 9.710 ,.viu ' 0 . 5 6 ) 200599 160 . 00G 156 . 1 8815

‘2 j. . 4 - 2: :".ez n.y . or.tz.o - i 7 -> 5.795 '■ . '>9 5 i 0 . 94 5, 237383 16 0.000 150.9 8 24 6

5. 54 7 ..- . 54 7 ,0.959) 334475 160.000 158 . 2 8703

25 :.-4-;':c:-;-:opi'-r’o; 15 2 1C . i 3- 3 " ' ■ 3 ? < 0 . 9 7 7 ) 364897 160.000 157 . 3

ISO 10.265 1 . 2 6 ■: ; 0 . 9 9 0 ) 4 32092 160.000 155 . 3

12 = 10.4:4 • .404 ( I .003) 1050011 160 . 000 16 3.3 9423{A}

; 2 7 1 C . 5 0 5 .505 : 1 . 013 ) 400235 160.00C 15 3.7 3 866

:= Hv:<ach:crob'.;ia-:: jne ") Z. 10.424 1 - :. 4 2 4 '1.0241 324514 150.000 155.7 9057

•;1 C 3 p i.1 a •: z a :c i : 2 11.114 : 1.114 :2.772) 67205 150.000 153.9 8745(M)

: 7 7 1 1 . 3 5 3 11.35- Oib! 2 2 2 Q 4 3 160.000 153 . 5 9038

5-:-:r^y2::i.p-: 142 11 . 4 0 5 1 1 .605 (1.119) 742760 160.000 159.2

■i. ; -.-■Jeznyln-.,I-:-::-. :42 1 1 . 7 74 11.774 .1.235; 55 16'74 150.C0C 153.3

4 4 hi ::r:y :1 rp-.-::: a : en- 2 37 07.: ::.272 '■1.664; 322032 160.000 162 . 9 8774(A)

18 2 . 4 . ■; - 1: i ;n 1 : . :2 . :: 7 ' ■! . 6 02 : 260699 160.000 15 5.0

2.4.1 -T: : ml : I-;.::-.---:-. : ! ; 1 2 .'I - 12.12:: 275594 160 . 900 149.4

: : ■ ••..•• . 15-; 12.437 1 2 . 4 3 4 0 . --2 5 905355 150.002 151.8 8C36(A)

■ir 2-2'. r;:-::-,:::-::::, 1-32 12.4 4 : :::. 4 - 7 72 - 752419 i sn n;yi 161.3 (A)

; •::.: no..:-.. : •: 12.'' 12 4 'I 'll 562270 320.230 3 0 3.5 5099

- - 12.271 964305 160.0-:)■ 0 15 9.2 5675

; ■ -7 ■ . *. r. 0 c 1 ") 150.100 156.3 5 14 3

. .2 - : 3 r. . .'-2 : 1- :■ c- 7 3 v 160 . .. 00 1 0 0.2 54 37 {A

: 7-3 ' 7 . : ■ 7 4 394 65 3 2 f.000 3::.; 5 3 4 0

'•••••••• '• * * 6 4 ■: . ■7 E 1 709733 I'D). 0 00 15 9.7 9612

h ■; -2 : nil vn.ph:::-. ■ . 1 1. 2 4 513925 0 0.000 832.2 (A

- - 1 ;■ - ■ : ■ ~ . 1 . ■ 2 0 . 0 1 r» c 3 2 0 . 0 00 1 n M. = 54 0t

h-i-hCL: -. ■ : . 7 -■ ■: '1 . 12 5 '• ; 0 37 6 6 1 6 C 0 0 2 15 7.2 3657

- ' : : •: :R = : J r . ■; : 0^5. 1 3 2 ° 2 S 3 160.000 i5B. 864 7

•• 2 : -rzh.y : :• - a ! i' •• 4 :■ 14 :: 11 ; 4 21: ■7.-27 - 7 2 "> 4 "• 7 16 0.000 15 8. 9 511 6

4 - 2 14 -. 14 4: ■ : .772 160.000 16 6 .:. 0 </■_

; r _ - . ... I i - ■; 1 ■ 7 : 1 1 2 5 5 54 1 r n . f: n c i7 . 9 7 3 2’ /•

^ 463T. - L/ - OL

O f ) III

Data File: ,/chem/5972hp60 . i/DFQ20303A60 . b/HH020303A60 . dReport Date: 04-Mar-2030 08:37

•yJAi. l SIC- CAL-AMT ON-COL

MASS RT EX? RT REX RT RESPONSE i NG) ( NG) SIMILARITY

•S2 4 - N i c r c a r.: I cr.e 13 8 r 4 .-id. . 1 . L' 7 0 . 434638 320.000 305.4 8655

h : 4 - -1 tr.: : rr. • 1 • T.-2Thypr.er.c 1 ns 14 532 14 5 32 ( :• . 9 04 ' 450216 320.000 327.4 8857 iA)

64 N •N: 7 rosea ipher.y-an ir.e 159 14 .633 1 4 c 3 3 • C . 9 11 604842 150.000 154.6 7663

7 7 14 . 584 14.534 • 1 .093.' 966239 160.000 154 . 7 3 724

6 4 4 -B:onopneoyi-phenylecher 245 15 . 276 15.276 U.SrUi 352443 160.000 153 . 6 9051

u" Hexac.-.ldrober.aer.e 234 15.395 15.395 : 0 . ;■ 5 0; 357119 160 . 000 155.1 9S36

Arrarme 2 00 15.547 15.547 'C.n-- 735 1 6 C.000 4 0.93 603 1 fH)

6 5 Peneacr. I orcpher.c 1 2 6 6 15.733 15.733 !C. s-u- 230411 320.000 321.1 9047(A!

7:- ?he:ianchrene 178 16 . 122 16.122 il.00 3 ■ 1460976 160.000 160.4 (A)

"■ A 178 16.207 15.207 a . 0 0 5 • 1470826 160.000 156.0

7 2 CarbazoLe 1 6 1 16.494 16.494 ■i 1 . 026 1094038 160.000 159.9 9258

7 3 Dbe: yir hzha lace X *1 it 1 7 035 17.086 (1.06 3'- 1746563 160.007 155.6 96 62

76 rlocrar.cnene ng-) 1 3 220 1 3 .220 (1.134) 1655770 160.000 159.9

n ns 13.4 r, C 1 8 . 4 4 C : C . 3 91) 343125 320.000 268 . 9 3 4 6 9

2 22 1 6 6 2 6 16.626 (0. 500 .1709263 160.00C 159 . 1

14 5 19.700 15.70? <0.953' 615064 160.000 153 . S 9121

2 5" 20.622 2 C . 6 2 2 1 0 . 9 9 7 i 664946 L60 . 000 151.3 7955

■■■■ 4 5 20.656 2 0 . 6 5 6 '0.?08i 1 3 6 9 6 0 6 160 . 000 16 2.3 9704(A)

r '. b--: a a:-.-, r.rae 22 c 2 0 6 5 7 20.690 : 1 . 0 0 0.1 1933405 160.000 160.2 (A’’

-■ 'Ihryeere 225 2 C . ^ 4 1 37.7q; t r g 1714299 1 60 . 000 160.5 (A)

S :• 2^.554 21.654 (9 . 92 0 2077607 160.000 164 . 3 (A)

-> 5 2 22.5CC 2:. sec (0.965) 1560505 160.000 167 . 6 (A)) — —

252 22.563 22 . 56b' ( C . 5 6 S ) 1557646 160.000 153.6

252 23.211 23.211 (10.9 9 6 } I 3 6 56 92 160.000 158 .4

■ vh: yyr-rr- 26.307 2S i 1 128; 1429387 160 . 000 155.9 6 956

• ' . - - 275 2 6 . 3 5 7 2 -j . 2 5 7 (1.131) 1 2 5 8 6 3 S 160.000 15 6.5 3 912

b-rrt u r.. ;::ry ,e:> 2 v •; 27.354 2 • . 2 t>4 '.1.165; 1133203 1 6 0.0 D 0 154.9 754 3

~}C Flag Legend

\ - Target compound detected xceeded maximum amount. ompound response manually integrated, aerator selected

but, quantitated amount

hit .an alternate compound

6 W

Dar.a "lie: .•'rntm.''5972ho60 . 1 '07020303^60 . t-,-HH020303H60 . d In iect ion l;=it.9: 03-HhF.'-200I 14:41 in=Tir'ijfnanr : 5'?72no60. i C^ent Barnol a . ID : 55TD160

Ound: Nijmo*

ipro 105

tarn

Ion 113.00: wrea: 67203 Height: 20272

ii

i1.4

1 'I'. 9 11.0 11.1 M l ri

ii.: 11.3 11.4 11.5

Ion 55.00: Mrea: O250O Haight: 32509

11.2 11.3 11.4 11.5

1 11.4

• n ;t r->jfn?nt : 5972ho60.i Ent Sample ID: S'STDlbd

Data F i let chern/j 972no6 0 . i / Dr" 02030 3*460 . b/HH020303Ob0 . dIniection Date: OD-H-'F.-2002 14;4l

:uncJ; nt razing* lumber; 1912-24-?

Ion 200.00: Hrea: 7*35 Height: -J45

u. o •

4 •

15.2 15.: 15.4 15.5

M i n15.C 15. 15.8 15.9 16.0

Ion 173.00: drea: Heignt: 0

15.8 15.9

47Z

15.7 15.8 15.9 16.0

Data File: ,/chem/B972hp6 0 . i/DF02 03 03 A60 . b/HM02 03 03A6 0 . dReport Date: 04-Mar-2030 12:46

Client Name:Sample Matrix: LIQUIDLab Smp Id: SSTDO8OVALLevel: LOWData Type: MS DATASpikeList File: 2ndSourcev2.spkSublist File: 2ndSourcev2.subMethod File: /chem/5972hp60 . i/D:Misc Info: 2ND SOURCE STANDARD

CompuChem

RECOVERY REPORT

Client SDG: DF020303A60 Fraction: SVClient Smp ID: SSTDO8OVAL Operator: 2319 SampleType: LCS Quant Type: ISTD

20303A60.b/827 0Cv6.m

SPIKE COMPOUNDAMOUNTADDEDNG

AMOUNTRECOVERED

NG

O,oRECOVERED LIMITS

13 N-Nitrosodimethyla 80.00 81.20 101.50 70-130; 14 Pyridine 80.00 77.15 96.44 70-130

15 Benzaldehyde 50.00 28.28 56.55* 70-13016 Phenol 80.00 83 . 85 104.81 70-13017 Bis(2-chloroethyl) 80.00 74.43 93.03 70-13018 2 -Chlorophenol 80.00 74.99 93.74 70-13019 1,3 - Diehlorobenzen 80.00 81.43 101.79 70-130

^ 20 1,4-Dichlorobenzen 80.00 80 . 85 101.06 70-130B 21 Benzyl alcohol 80.00 67.10 83.88 70-130^ 22 1,2-Dichlorobenzen 80 . 00 78.31 97.89 70-130

23 2-Methylphenol 80.00 79.25 99.06 70-13024 2,2' -oxybis(1- Ohio 8 0.00 77.98 97.47 70-13025 Acetoohenone 160.0 165.8 103.63 70-13027 4-Methvlphenol 80.00 78.86 98.57 70-1302 8 N-Nit ro s o-dl-N-p ro 8 0.00 81.38 101.72 70-13029 Hexachloroethane 80.00 82.64 103.30 70-1303 0 Nit rcbenzene 8 0.00 77.96 97.45 70-13031 isoDhcrone 8 0.00 84 . 10 105.13 70-1303 2 2 -Nitropnenol 8 0.00 78.17 97.71 70-1303 3 2 , 4 -Dimet hvlD’nenol 8 0.00 79.23 99.04 70-1303 4 B i s 2 - c h 1 oroe t hoxv 3 0.00 74.36 92.95 70-13035 2,4-Dichlorophenol 8 0.00 77.03 96.28 70-1303 6 1,2,4 -Trichloroben 8 C . 0 0 82 . 87 103.59 70-13037 Nachthalene 8 0.00 70.09 87.62 70-1303 6 4 -Chloroani!ine 3 0.0 0 76.03 ■ 95.10 70-1303 9 H e x a c h 1 c r c b u t a d i e n 8 0.00 8 5.53 106.92 70-1304 0 Caorolacta m 9 0.00 79.20 99.00 70-13041 4 - Chioro- 3-methvlp 3 0.00 74.58 93.22 70-1304 2 2 - Me t hv■naoht ha1 3 0.00 6 9.30 8 6.63 70-1304 3 1 -Methylnaphthalen 8 0.00 75.91 94.89 70-1304 4 Hexachlorocvclopen 80.00 70.14 87.67 70-1304 5 2,4,6 -Trichicrophe 8 0.00 78.99 98.74 70-1304 ■- 2,4,5 -Trichlordphe 8 0.00 74 . 04 92.55 7 0 - 13 0

Data File: /chem/5972hp60:1/DF020303A50.b/HM020303A60.dReport Dare: 04-Mar-2030 12:46

¥----------------- ----------

SPIKE COMPOUNDAMOUNTADDEDNG

AMOUNTRECOVERED

NG

o,0RECOVERED LIMITS

47 1,1'-Biphenyl 80.00 80.19 100.23 70-13048 2-Chloronaphthalen 80.00 95.81 119.76 70-13049 2-Nitroaniline 80.00 63 . 13 78.91 70 -1_> 050 Dimethylphthalate 801 00 73.14 91.43 70-13051 2,6-Dinitrotoluene 80.00 82.28 102.85 70-13052 Acenaphthylene 80.00 68.60 55.75 70-13053 3-Nitroaniline 80.00 66.74 83 .^3 70-13054 Acenaphthene 80.00 71.32 89.15 70-13055 2,4 -Dinit.rophenol 80.00 62.83 78.54 70-13056 4 -Nitrophenol 80.00 79.40 99.25 70-13057 2,4-Dinicrotoluene 80.00 78.78 98.47 70-13058 Dibenzofuran 80.00 69.55 86.93 70-13059 Diethylphthalate 80.00 73.05 91.31 70-13060 4 -Chloropheny1-phe 80.00 65.67 82.08 70-13061 Fluorene 80.00 67.32 84.15 70-13062 4-Nitroaniline 80.00 64.91 81.14 70-13063 4,6-Dinitro-2-meth 80.00 69.69 87.11 70-13064 N-Nitrosodiphenyla 200.0 165.5 82.76 70-13065 1,2-Diphenylhydraz 80.00 76.15 95.18 70-13066 4-Bromophenyl-phen 80.00 61.74 77.17 70-13067 Hexachlorobenzene 80.00 75.38 94.23 70-13068 Atrazine 80.00 166.9 208.67* 70-13069 Pentachlorophenol 80.00 66 . 91 83.64 70-130

™ 70 Phenanthrene 80.00 65.20 81.50 70-13071 Anthracene 80.00 68.40 85.50 70-13072 Carbazole 80.00 76.06 95 . 08 70-13073 Di-n-butylphthalat 80.00 71.62 89.52 70-13074 Fluoranthene 80.00 67.06 83 . 82 70-13075 Benzidine 160.0 112.4 70.25 70-13076 Pyrene 80.00 71.40 89.24 70-1307 7 Buty1benzv1phtha1a 80.00 79.27 99.08 70-13078 3,3'-Dichlorobenzi 80.00 68.65 85.81 70-13079 bis(2-ethvlhexyl)P 80.00 75.57 94.46 70-13080 Benzo(a)anthracene 80 . 00 71.68 89.60 70-13081 Chrvsene 3 0.00 73 . 16 91.45 70-130 |82 Di-n-octvlphthalat 8 0.00 73.88 92.35 70-13083 Benzo(b;fluoranthe 8 0.00 68.67 85.84 70-13084 Benzo(k)£lucranthe 30.00 80.67 100.84 70-1303 5 Benzo (a ) pvrer.e 30.00 71.57 8 9.46 70-1306 6 I n.deno (1,2,3- cd) dv 3 0.00 76.51 95.64 70-13087 Dibenzo(a,h)anthra 8 0 . 0 C 72.00 90.00 70-13038 Benzo!g,h,i;peryle 8 0.0 0 71.73 8 9.66 70-130

47-

<:tlO‘sb)

Data File: /chen/5972hp60. i/DF020303A60.b/HH020303H60.d

Date : 03-M8R-2002 18:01

Client ID: SSTD080VAL

Sample Info: SSTD080VAL:2319

Volume Injected (uL); 1.0


I ns tr-ument; 5972hpb0* i■-O

Is-

Operator: 2319

Column diameter: 0,32

Data Fi le; 7chem/5972hp60. i/DF020303660.b.'HM020.7n7A60,rj

Date : 03-MAR-2002 18:01

Client ID: SSTD080VAL

Sample Info: SSTD030VAL;2319




Operator; 2319


2.0-

1.9-

1.8-

1.7-

1.6-' 1.6- 1.4-

1.3-

1.2- - 1.1-

1.0-

7chem/5972hp60.i/DF0203C3A60.b/HM020303A60.d (Part 2 of 21

+<MtH■O

I•i5i/lT)

LJ

I

47b

Data File: /chem / 5 9 7 2hp6 0 . i /DFO 2 0 3 G 3 A6 G . b/'HMO 20303 AGO .d Report Date: 04-Mar-2030 12:46

CompuChem

Data file Lab Smp Id:Inj Date : Operator Smp Info :Misc Info : Comment : Method :Meth Date :Cal Date :Als bottle:Dil Factor: Integrator: Target Version: Processing Host

Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020303A60.b/HM0 2 03 03A6 0.d SSTD08OVAL Client Smp ID: SSTD080VAI03-MAR- 2 0 0 2 18:012319 Inst ID: 5972hp60.iSSTD0 8 OVAL:2319 2ND SOURCE STANDARD

,/chem/5 972hp6 0 . i/DFO2 03 0 3A6 0 .b/82 70Cv6 .m 04-Mar-2030 08:41 mikhael Quant Type: 0 3-MAR- 2 0 0 2 17:20 8

1.00000 HP RTE

3 . 50einstein

I STDCal File: HL020303A60.d QC Sample: LCS

Compound Sublist: 2ndSourcev2.sub



^ DF 1.00000 Dilution FactorA1000.00000 Volume of final extract (uL)

Vo' 1000.00000 Volume of sample extracted (mL)Vi 1.00000 Volume injected (uL)


CONCENTRATIONS

-•jiv- 0N-COLUMN FINAL

iitpc;::'..:;' AT £yp RT RESPONSE J NO) ( ug/L) SIMILARITY

e: : 7 8 2 04

~ C i ^ 1

40.0400

: -‘.4 : • . •;i 1 5 j 0 4 4 4 0 . 0 2 0 0

r--....... . • J .

• 1’ ", : ■/. 7 = - ■ ■ D /i: 301900 40 . oono

- :: . -■e 2- ■: il :: a ■ : . 255315 40.0000

: ? N • A : i r ...ir. .. .* : c 1 22: 235703 21.2012 '4 1 .20 02 3 5

7 • 7 312555 77 . 14P-4 77.1 5 0 5 12

■- ' - :--L 7 35293 24.2753 23.23 8585(Hi

1 V . ..a:. 2 2 : J O 4 7 55.S551 53.83

" •: •••5-: 1 5 9 4 0 7 7 4 9 3 9 4 7i c. 0 4 5 8

- : :■ ■ 227442 51 .429 '3 51.43

- : ■ - . d: ; ; . ■ 2:4; 5 5 ' . 3 4 p ^ 8 C . 3 j

47/

Data File: /chem/5 972hp6 0 . i/DF02 03 03A60 . b,/HM02 03 03 A60 . dReport Date: 04-Mar-2030 12:46

..cnoo'jr.as

21 Benzyl alcohol

24 2.2'-"xynis:1-Chlcropropane)

2 H-xacn . z-tcez l-.cc.e

• ? N'.z I'oc-enzenr

lb 2 , 4 - Z: : h. o: z p h •= n o 1

1 “ Naphtha : ene

2UANT SI

MASS

10S

14 6

108 '

45

105

108/

*70,

139

CONCENTRATIONS

ON-COLUMN FINAL

107

:42

142

62.3313

79.4315

7 5 . 7 7 o j

5 3.545 C

72.0457

4 5 b — ;•

/1

o ; i1.? '

: 4 6 2 5 a

222311

75 1454

61 . 7350

75 . 331 7

166.935

7 9.40

7 5.73

69.55

. . 91

75 . 15

61 .74

E i EX? F.T RE L RT RESPONSE ( NG) ; ug/Li SIMILARITY

3 .439 3 .441 : 1 . 029 1 91670 67.1030 67 . 10

S .473 3.475 ! 2 t > 219032 73 .3150 78 . 31

5 . 559 3.627 ■. 1 056 ;■ 136784 79.2517 79.25

3.659- 3 .661 ; 1 0561 207069 77.9769 77 . 98 775C

8.679 3 8 c 4 11 03 3 ' 513702 165 . 913 16 5.3 8 7 6 2 (A}

- 3.696 3.393 ! 1 06 5'. 172963 78.856“ 78 . 86

/ 6 . 895 3.831 1 085) 129545 31 . 3762 81.38 0 (M)

9 . 04 b ? . 0 3 3 : 1 103 i 102461 62.64 28 92 . 64 32 32

3.167 d ' z. 2 : 0 884 : 198353 77.9580 77 . 96 53 58

9 . 573 c z j (0 923.1 336961 34.103C 94 . 10 3 .1 7

9 . 708 v .69? (0 936 ) 9321 1 73 . 1705 78.17 3293

9.793 ; . 795 ( 0 94 5) 1 20778 79.2290 79.23 8 1 9 6

9 . 962 3 . 94 7 (0 961) 179367 74 . 3582 74 . 36 8 7 a 9

10.121 A 116 . 0 577) 1'72S03 77.0278 77.03

1 0 . 2 6 4 10.251 990) 220863 S2.8744 82.87

10.402 : 0.357 ,1 0 0 3 1 427348 70.0949 70.09 9 14 0

20.503 i 0 . ~t 8 3 013) 195524 76.0821 76.08 8 I 3

10.621 1 0 . 607 ( 024 ) 173294 35.5323 85.53 916 3

ii . 112 1 1 . 063 1 0 7 2 ) 35157 79 . 1997 79.20 8 6 6 3

11.366 ::. 2 51 1 096 ) 139169 74 . 5772 74 . 58 84 56

11.602 11 . 5 0 c- • 11 9 • 314929 59 . 3022 69.30

11.775 11.7-4 . 125 : 278964 75.9148 75 . 91

11.3 :■ o 11.575. : r iss: 123895 70:1352 70.14 8 94 0

-.2.11 0 1 2 . . 3 5 (0 902 ; 133103 73 . 9886 78 . 99

12. 173 12.150 :o 0 27 • 1 358 2 5 74 . 0372 74 . 04

12.432 12.417 ; ■326 443999 80. 1864 30.19 y 07

12.466 47; : r, 52 8 ) 454303 95.3117 95.31

12.635 :-37 1 0 94 1: 116695 6 3 . 1289 63 . 13 39 9 2

12.973 ->55 56-5 > 456007 73 . 14 11 73 . 14 7-h?

1 3 . O'1 5 : ■ ■ 0 574 : 1 9 2 56 32.2811 92 .28 “y.-i12.15 3 '■ 0 552; 52.3 74 5 63.6016 6S . 50 :< 4 ■? 113.34 2 1 -• 3 4 4 ■ c 555 ■ ‘■■4 132 56.7437 6 6.74 - 2 9 9

0 (M'

-"56

\

:? 1 ■) t

jn:

5 3 06

5 1 9 :• < AF.'

LT/

t-

47o

j L

Data File: /chem/5972hp60.1/DF020303A60.b/HM020303A60.dReport Date: 04-Mar-2030 12:46

CONCENTRATIONS

:uant sig ON-COLUMN FINAL

-Ttpour.os MASS RT CA? .-\T RSL RT RESPONSE ( NG) ( ug/L) SIMILARITY

2 o r 1 6 . 7 ? 1 15.733 ,0.579. 52702 66.9126 66 . 91 0 fM) \

X ,v - 17 8 15.103 lo 105 (1.002) 645141. 65.1990 65.20

7 1 Ar. d h racer.3 176 16.204 16 189 ■1.008; 681281 68.3982 6 8.40

’’I Zazzazz ie 15 7 15.475 15 .477 :i.025: 5576SS 76.0649 76 . 06 0 7 02

7 I 0: - r. - r-u 2 y p.-;2 na lace 14 6 i7.06 n 17.06? .1.062! 925454 71. 6150 ■7 r q g Q P - 3

74 c iccrar.2her.re 202 1S . 2 01 15 2 0 ~ (1 . 13 3 ) 756615 67.0598 6 7.06

” Berziaine 164 16 .437 10.423 ■0.891) 223014 112.396 112.4 853 1

X Pyr-r.-X 2 02 18 . 6 C 7 1 6 . 6 C r 7 . 999) 773252 71.3956 71.40

Brry Icerzy'.zh: ha ; are 14 6 19.706 15 . 708 ? . 953) 443338 79.2673 .21 9191

1 8 2 , 2 ' •L,:cr.:orcben::dir.e 252 20.620 20.622 i 0.997) 293202 68.6520 6 8.65 7455

n'? ois 2 - ec hyihexy 1 > Fhz’r.a laze 14 S 20.654 20.656 ■ t .998) 590309 75.5704 75.57 9633

i'j Benzclaiamihracene 2 2 6 20.671 2 C.673 ■ 0. 999) 774575 71.6823 71.68

1 Chrysene 226 20.738 20.723 (1.002) 712495 73 . 1617 73 16

-■2 Di - n - C'C 2 y i p)'i2 ha 1 a c e 14 9 21.652 21.654 (0.929) 549890 73.8796 73.88

= i 2enzo:b; : 1 zozar.z here 252 22.498 22.483 (0.965) 756094 6 8 . 6 6 96 60 67

252 22.546 22 . 534 1 0.9 0 7 J 603084 80.6696 80.67

-5 Bcrze a zyrer- "| c o 23.191 2 ^ n 7 ■0.995; 630629 71.5657 71 5^

"■■■■ 1.2.1 pyrer- 2 7 5 26.237 26 .272 ; 1.12 e) 719409 76.5085 76.51 om; j

Ciherrc. a . z a r: h : acer-u 2 7 5 26 . 3 3S 26 323 (1.130) 599259 71.9967 7 2.00 9907

- - 5 --rz r -i. h. . r-rr-.-lmro 2 7 4 27.201 27.156 ; 1.16 7) 568354 71 . 7271 71.79 7678

lag Legend

A - Target compound detected but, quantitated amount exceeded maximum amount..

R - Spike/Surrogate failed recovery limits.M - Compound response manually integrated.

C a .<-V

1 ■ U V. (_

47c

j ate -lie: ■ * injection Date: 0! Instrument: 5972n: Client Sample ID:

1‘71'nrcCO. :/D^020: -MHF.-2002 18:01 60 . iS'STDOSO'vhL

i/Hm02Ci203*60 . a

jocund: H-Nitrg*o-di-N-propu1 am:ne Mumnen; 521-54-7

lor. 70.00: Hrea: 129p*45 Heignt: /c58*4

Tu<00

co

4.4-

4 . 0

1 .2-

8-

4-

.45 8.50 8.55 6.50 8.55 8. 6.75 8.80 8.05 8.90 8.95 9.00 9.05 9.10 9.15 9.20 9.25 9.30. 9.35

___ _______ Min ________ ________________________________________I on 130.00: nrea: Height: 0

9 . 'jO 9.05 9.10 9.15 9.20 9.25 9. jO 9.35

48Gr. 00 9.05 9.10 9.15 9.20 9.25 9.30 9.35

Iniectior: Date: OD-MwP-T'uuT 15; instrument: :59"'Dnp60.i I-ient Sample ID: SSTDOSOVAl

loounc: Pent sen loropnenol P Number-: 67-36-5

2.0-

1.3-

1 .6-

1 4-

0 . p H M020 30 3A 6 0. a

Ion 266.00: Area: 52/02 Height: 21533

mrv

IP

0.4-

15.35 II: i5.35 ’5.40 15.45 15.50 15.55 15.60 15.65 15.70 15.75 15.60 15.85 15.90 15.95 16.00 16.05 16.10 16.15 16.20 |

____________________ Min jIon 263.00: Area: 0 Height: 0

I

15.90 IS 16.00 16.05 16.10 16.15 16.20

481

15.6-j li'.'O !5.75 ! 5.60 15.85 15.90 15.95 16.00 16.05 16.10 16.15 16.20■; n

J-=ir.ri Fill?: jn;:>60 . : .'DF* 1in.lecticr. Dst-r; 03-MhF'-2002 18 In* fument: 5972no60 . 1

nr •Sample ID: 55tD080'./hl

10 unci : 4-n 11 rcipn*?r,cMump*1': iOO-92-7

HMOI'OjOj^qU . d

3.4-

lon 109.00: 90060 Height: ji*4787

1 . c-

1 .4 •

1 n !

0.3- ;

0.6- !

0.0 1 ;5 13.40 i 3.45 13.50 13.55 13.60 13.65 13.70 13.75 13.30 13.35 13.90 13.95 14.00 14.05 14.10 14.15

_______________________________ Min___________________________________________Ion 65.00: 0 Haight: 0

■D

l

55

Ion 13

35 13.9' 95 14.U0 14.05 14 14 . 15

4847. J = ; 3.75 13. £0 13.63 13.70 13.75 13.801 13.85 13.90 13.95 15.00 14.05 14.10 14.15

"..iect:on Dare: .;:7-mwF-2’002 Ic r.-= r rijrrienr : 5977'hp60 . : lient Semole ID: 557D0S0,,"'hL

O'jno: : ndeno c 1, 2. 3-c a ) pij rene nwr: 193-39-5

■•HMm1,03036>10.cI

Ion 276.00: Area: 719409 Height: 13*4901

03

Tr-j

I

. 30 29.89 29.9" 29.99 2b. 00 2b .05 26.10 26.15 26.20 26.25 26.30 26.35 26.40 26.45 26.50 26.55 26.60 26.65 26.70 26.75______ ___________ H i n ________________________________________

Ion loS.OO: Height: 0

l

'5 26.30 2>i . :3 . 40 26.45 26.50 26.55 26.60 26.65 26.70 26.75

48

_0 . '1*5 !•: . 10 2. 15 ii . 20 26.2o _'6 . j,0 26.33 26.40 26.45 26.50 26.55 26.60 26.65 26.70 26.75

COMPUCHEM ;t division ofLibcity Analytical Corp DATE ^ /

<;C7MS SEMIVOLATILE RUN LOG[UjC. INITIAL TIME Of TUNE___ /

TIME TUNE EXPIRES____.. / 3 A__

SIIII'T/S(A) .........(C).

LINKER /MIN HOP V £ ;'u

—

uEiE

X

iroPREVEN TIVE MAINTENANCE

C

T1DFILE NAME tE DATE TIME CLIENT ID# CASE/S DG# AMOUNT

INJECTEDCHEMIST COMMHNTS(E rc )/DlSI’OSn iunzcc )

oo^ -1 "Drs n Sc !■> A/cj z 5 O 'a / 7 AZ hPrf/'

.0 E • li 1 ‘l-- / ______________ _

\ 1 IL- l- ('. \> if tj / / / / C- y / *5 SfT)(, r\ t, ■ ■r s’7 0 5 /1 i'llh.v'c '5o s /Cn / / / /Hf \ 5 fb /A, t- s‘> e 2 j .

1 j-iL. n. Wi> .Vo z / / / S 7 / UVt’/o-p K ) u f\ ...

|~/jo <i 2 A Cu z / / l b u 1V ,> u . - ;_______________

hKKo l 0- Sc'1, Aoz / / ! l U i Zf fbc/r.

v 5 y c' 1 ‘/ -....... ..............

/ 'll. ti i C K S A6 L’ z / / i 7 Zo~ Zv 7

— s' 7 s <: c-

s /"/ A/o Z 1, Zv 5 /Vc / G________ 1 5 v l s sTf-.rA. . \/7 l\/ \ /

C- S~ / -■ ' A'_______________________

«) / /

10 / / H P <?az...........

11 / /

12 / /

13 / /

M / /

/15 /

10 / /

17 / / a/ ;

18 / / CT1 r

—

i

—10 / /

20 / /

21

■>2 / /

23 / /

/ /

Std. ID ft

I ,Ol it

Tune

a ‘j s

Analytical int. Std.

dJL&_

Column Type

[ ’■ f K

l

X1 s

SUPERVISOR APPROVAI

DATE o\‘6?1.0L'

. V'fepczz

~k C 'j L M/ ■ •*. V.) lie presence oj (lie Chemist's employee II) number. »>i signal me. on 1 his run |o^» attests that sii i*.I compliance \Mth die incdmd *■ M d’ ha-

occurred. Any SOP deviations require documentation hy the responsible chemist together with the chemist's initials and the initials o| du

lab supervisor and a OA department representative, si^ni tyiny approval ofthe deviation I-’’I l/,(l


Lab Name: COMPUCHEM Contract: 8270C

k Lab Code: LIBRTY Case No. SAS No.: SDG No.: QE1877

Instrument ID: 5972HP64 Calibration Date (s) : 03/10/02 03/10/02

Column: RTX-5 ID: 0.32 (mm) Calibration Time(s): 1416 1723

LAB FILE ID: RF10 :

RF80 : HG020310A64 RF120

HI020310A64 RF20:

: HJ02 0310A6 4RF16 0

HK020310A64 RF50

: HH02 0310A64

: HL020310A64

1

COMPOUND

1

RF10 |

I .

1

RF2 0 |

1

1

RF5 0 |

I

1

RF8 0 |

|

1

RF120 |

|RF160

Phenol [ 1 . 579| 1.514 | 1.434 | 1.441| 1.413| 1 . 339|

Bis ( 2-chloroethyl)ether | 1.055 1.007 0.950 1 0.975 0 . 9631 0.974

2-Chlorophenol 1 1.396 1.360 1.341 1.335 1.327| 1.305

1,3-Dichlorobenzene | 1.658| 1.569| 1.529| 1.536| 1.506 | 1.467|

1, 4-Dichlorobenzene | 1.6511.616 j 1.549| 1.572| 1.492 j

1.469

1, 2-Dichlorobenzene [ 1.631 1.5691.520 j 1.509 j

1.490 1.483|

2-Methylphenol | 1.242 1.189| 1.170 1.116 1.156| 1.1582,2'-oxybis(l-Chloropropane)| 1.919|

1.861j 1.803] 1.783 | 1.776| 1.797|

4-Methylphenol | 1.361 1.3171.245 j 1.258 j

1.247 1.215|

N-Nitroso-di-N-propvlamine | 0.884 | 0.818| 0.777 ■0.767 0.787 | 0.784Hexachloroethane I 0.874 | 0.820 0.802 0.804 | 0.782 0.757|

Nitrobenzene | 0.370 j 0.340 j 0.338] 0.342 | 0.320 j 0.329]

Isophorone I 0.741 0.680 0.669| 0.665| 0.637 0.6462-Nitrophenol | 0.239 0.216 0.214 0.212 0.206 0.2022,4 -Dimethvlphenol | 0.355| 0.326 ] 0.319 0.312 0.304 0.302kis ( 2-chloroethoxv)methane ] 0.451| 0.413 | 0.399 j 0.399| 0.379| 0.370|

W, 4-Dichlorophenol | 0.3540.331j 0.331| 0.334 0.320| 0.317]

1, 2 , 4-Trichlorobenzene | 0.429 0.3960.393 j 0.380| 0.366 | 0.354

Naphthalene | 1.637 | 1.491 1.454] 1.423 1.337] 1.332

4 - Chioroari11ine 0.513] 0.461| 0.460 0.463| 0.440] 0.436Hexachlorobutadiene | 0.291 0.274 0.266

0.264 j0.253 0.247|

4-Chloro-3-methylphenol | 0.413 0 . 371 | 0.357] 0.368 0.350| 0.3492-Methylnaphthalene ] 0.814 0 . 722| 0.729 j 0.713 | 0.686 0.682Hexacnlorocyclopentadiene ] 0.408] 0.377] 0.394 | 0.410| 0.394| 0.395|

2 , 4,6-Trichlorophenol | 0.430 0.414 0.4040.415 j

0.384 0.3942 , 4,5 -Trichlorophenol | 0.470 0.424 0.434 0.437| 0.413 0.4122-Chloronaphthalene | 1.123| 1.100 1 . 027 | 1.Oil| 0.945 0 . 9512-Nitroanilme | 0.397 | 0 . 372 j

0.364 | 0.3651 0.356 | 0.350 |

Dimethylphthalate | 1.415 1.320] 1.254 1.221 1.167| 1.1452,6-Dinitrotoluene | 0.372] 0.348| 0.339 0.343 0.338 0.330Acenaphthvlene j 2.727] 2 . 588 j

2.429 2.373] 2.208] 2 . 127|

3-Nitroanilme 0.403] 0 . 3 6 6 | 0.356] 0.359| 0 . 358 | 0.350 |

Acenaphthene j 1.803; 1.659] 1 . 584 1.548 1.441] 1 . 319|

2 , 4 - Dmitrophenoi | 0.054 0.048 0.060 0.066 | 0.068 0.0694-Nit ropnenol | 0.231] 0.204 j 0.212 j 0.225] 0.221| 0.2101

2,4-Dinitrotoluene ] 0 . 552 i 0 . 501 | 0.493 | 0.478] 0.488 0.488]Dibenzofuran j 1.845] 1.699 1.608 1.560] 1 . 502 1.471Diethy1phtha la c e ! 1.706; 1.563 1.480 1.417| 1.394] 1.3434 -Ch1oropheny1-phenylecher 1 0 . 7S2 ] 0.723 j

0.699] 0.686 | 0.648| 0.622 |

Fluorene i 2.175] 2.032] 1.883]1.782 j

1.639 1.6024 - r.:i t roam 1 ine ] 0.408] 0 . 3 6 1 j 0.384] 0.373 0.375 0.3794 , 6 - Dim t ro - 2 - methylphenol 0 . 1 b | ■ 0.145 0.164 0 . 168 0.167 0.160]:: - Nit rosodipheny 1 amine 1 .0.513] 0 . 448 | 0.434] 0.420] 0.408] 0 . 391|

Bromophenyl-phenylether j 0.247]

|0.220

!

0.218]

10.203

10.193

1

0.192 |

W5FORM VI SV



Lab Code: LIBRTY Case No.: SAS No.: SDG No.: QE1877

Instrument ID: 5972HP64 Calibration Date (s) :: 03/10/02 03/10/02

Column: RTX-5 ID: 0.32 (mm) Calibration Time(s) : 1416 1723

LAB FILE ID: RF10 :

RF80: HG020 310A64 RF120

HI 02 0310A6 4 RF20:

HJ02 0 310A6 4RF16 0

HK020310A64

HH020310A64

RF5 O': HL020310A64

!

I COMPOUND

1

1

1

1

RF10 !

1

1 I

RF2 0 | RF5 0 1

1 . !

1

RF8 0 )

|

1

RF120 |

|

RF160 j

j-------------------- =------ :|Hexachlorobenzene

11----------- |

0.311|-------- I-----0.282|

10.268 |

----------- |0.247|

--------- | _0.233 | 0.224

|Pentachlorophenol 1 0.192 | 0.1660.173 j 0.176 j 0.169 j

0.166IPhenanthrene 1 1.845 j 1.623 j 1.507 j 1.396 j 1.299| 1.260|

|Anthracene 1 1.889[ 1.663 j1.565 1.431| 1.296 j 1.232 |

|Carbazole 1 1.171 1.044 | 1.018| 0.972| 0.9040.865 j

|Di-n-butvlphthalate 1 1.802| 1.598 j1.523 1.434 1.312] 1.263

I Fluoranthene 1 2.061j 1.816 j 1 . 769| 1.626) 1.535) 1.488)

j Pyrene 1 2 . 264 2 . 164 1.994 |1.818 j

1.679 1.590

I Butvlbenzvlphthalate 1 0.878| 0.819| 0.782 0.757| 0.694 | 0.689|

!3 , 3' -Dichiorobenzidine ... 1 0.629 0.575 0.554 | 0.524 j0.495

0.475 j

Ibis(2-ethylhexyliPhthalate I

1Benzo(a)anthracene !

1.337[

2.085 |

1.225)

1.872 |

1.19 3 |

1.798

1.114 |

1.716

1.038|

1.569

0 . 980|

1.513iChrysene 1 1 . 958 1.817| 1.717| 1.618| 1.451| 1.389iDi-n-octvlphthalate 1 2.469) 2.330| 2.364 | 2.286 j 2.131] 2.004j^enzo(b)fluoranthene 1 2.548) 2.359) 2.033 j 1.867 j 2.156| 1.909|Benzo(k)fluoranthene 1 2.014 1.939 2.156 2.160 1.642| 1.720^en:o (a) pyrene 1 1.897 1.745 1.736 1.683| 1.602 j

1.535|Indeno(1,2,3 -cd)pyrene 1 1.379) 1.302 1.264 1.178 1.155 1.090|

!Dibenzo(a,h)anthracene 11

1.675) 1.568 1.541 1.438 1.405 1.314)

j Benzo(q,h,i)pervlene 1 1.710 1 . 653| 1 . 618| 1 . 504 | 1.465 1.421]

1 2 -Fluorophenol 1 1.361 1.316

=====1

1.263 | 1.286 1.287 1.2771 Phenol-dS t 1.339) 1 . 758| 1.661| 1.665] 1.618) 1.607 )

! Nitrobenzene-d5 1 0.458) 0.436 0.442 0.429 0.419| 0.413 |

!2 -Fluorobiphen\T 11 1.520 1.422 | 1.334 1.312 | 1 . 210| 1.198]

: 2,4,6 -Tribromophenol 1 0.452 0.415] 0.412 0.402 0.375) 0.360Terphenyl-d!4 1

11.272) 1.158) 1.097) 1.010| 0.923] 0.893]

1 ) 1 1 1 1 1

FORM VI SV




Instrument ID: 5972HP64 Calibration Date(s) : 03/10/02 03/10/02

Column: RTX-5 ID: 0.32 (mm) Calibration Time(s): 1416 1723

1 |COEFFICENT| %RSD MAX %RSD ]

COMPOUND |CURVE

1

1 A1 |

| |

OR R~21

OR R~2 j

Phenol|------| AVRG | 1.45344780|

----------- |5.734 | 30.000 j

Bis(2 -chloroethvl)etherj AVRG 1 0.98746534 | 3 . 861j 50.000 j

2-Chlorophenol [ AVRG 1 . 344051842.321j

50.000

1, 3-Dichlorobenzene AVRG | 1.54422209 4.234 50.000|

1 , 4-Dichiorobenzene AVRG 1.55817949| 4 . 497| 30.000 j

1,2-Dichiorobenzene | AVRG | 1.53368056| 3.687 j 50.000 j

2-Methylphenol AVRG | 1.17202670 3.584 | 50.000

2,2'-oxybis(1-Chloropropane) AVRG 1.82351039| 3.052 j 50.000|

4-Methylphenol | AVRG |1.27392635 j 4.258 j 50.000 j

N-Nitroso-di-N-propylamine | AVRG jo.80287373 ! 5.402 j 50.000 j

Hexachioroethane AVRG 0.80639443 | 4.884 | 50.000 |

Nitrobenzene | AVRG 0.339861264.958 j 50.000 j

Isophoronej AVRG |0.67295879 5.485 j 50.000 j

2 -Nitrophenol AVRG 0.21456245 6.129 30.000

2,4-DimethvTphenol | AVRG |0.31978990| 6.156 | 50.000

£is (2 -chloroethoxy)methane AVRG [0.40165650 7.124 | 50.000k, 4-Dichlorophenol AVRG 0.33121894

3.934 j30.000

^,2,4- Tn chlorobenzene 1 AVRG 0.386223186.812 j

50.000

Naphthalene | AVRG j1.44 570691j 7.832 j 50.000 j

4 -Chloroanilme AVRG |0.46229995 | 5.921 50.000

Hexachiorobutadiene AVRGjo.26598517J

5.821 30.000

4 - Chioro-3 - methvlphenol AVRG [0.36798386 6 . 505 30.000|

2-Methvlnaphthalene | AVRG 0.72460592 6 . 616 | 50.000 j

Hexachiorocyclopentadiene AVRG 0.396223183 . 024 j 50.000 j

2,4,6-Trichlorophenol AVRG 0.40708278 [ 4 . 043 | 30.0002,4,5-Trichlorophenol | AVRG |0.43186681 4 . 979 j

50.0002 -Chloronaphtha 1ene

j AVRG1 1.02624724 [ 7 . 187 j 50.000 j

2 - Hitroam 1 ine ! AVRG 10.36736680 4.463 50.000Dimethvlphtha laze | AVRG 1 1.25397872 1 8.035 50.0002 , 6 - Dimtrotoluene | AVRG [0.34504949| 4 . 154 | 50.000Acenaphthylene | AVRG i2.40886410 1 9.377 j

50.000|

3 - Hi t roam line | AVRG 1 0 . 36 5264 00; 5.215 50.000 |

A.cenaphther.e | AVRG [ 1 . 55908773 10.804 30.000|

2,4-Dinitrophenol | AVRG |0.06102654j 13.919) 50.000 j

4-Nitrophenol 1 AVRG jo.21725178)4.688 50.000

2 , 4 - Dimtrotoluene | AVRG j 0. 50009479! 5 . 323 j 50.000 |

Dibenzofuran i AVRG i 1 . 61418043 [ 8.619[ 50.000Dle t hy1ph t ha 1a t e | AVRG j 1 . 48402924 [ 8.933 50.0004 -Ch1orophenyl-phenylether | AVRG |0.6933645S! 8.184 50.000|

riuorene i AVRG :i.35220534] 12.078 j 50.000 j

4 - Hi t roam 1 me 1 AVRG 0.38018555) 4.098 50.0004 , 5 -Dmitro- 2 - me t hvlphenol : v R G !0.16193990 | 5 . 334 | 50.000N-IJit rosod ip he nvl amine ; AVRG

i 0.43553311 j 9.834 j30.000

a - 3romopheny1 -pheny1ether i ’ T, V r.1 j ! 0.212194951

i

9 . 839 j

1

5 0.0 0 0 j

.1

48/FORM VI SV

FORM 6

SEMIVOLATILE INITIAL CALIBRATION DATA



Instrument ID: 5972HP64 Calibration Date (s) :: 03/10/02 03/10/02

Column: RTX-5 ID: 0.32 (mm) Calibration Time(s) : 1416 1723

1 |COEFFICENT| %RSD | MAX %RSD |

COMPOUND |CURVE

1

A1 | OR R~2 OR R"2 |

Hexachlorobenzene1------| AVRG

1------------ 1 -| 0.26088302|

----------- 112.450| 50.000

Pentachlorophenol AVRG |0.17365523] 5.747 30.000

Phenanthrene | AVRG j1.48848182 | 14.776 | 50.000 j

Anthracene AVRG 1.5127839116.183 j 50.000 j

Carbazole | AVRG 0.9956973210.968 j 50.000 j

Di - n-butylphthalate AVRG |1.48863045| 13.305 50.000

Fluoranthene | AVRG j1.71594315| 12.345 j 30.000 j

Pvrene | AVRG 1.91825998 13.990| 50.000|

Butylbenzylphthalate AVRG |0.76979770| 9.502 j 50.000 j

3,3'-Dichlorobenzidine AVRG 0.54217088 10.400 50.000

bis(2-ethylhexvl)Phthalate | AVRGj 1.14804654 j 11.372 j 50.000 j

Benzo (a)ianthracene AVRGj1.75898011 |

11.907 50.000|

Chrvsene AVRG 1.65827586 13.08450.000 j

Di -n-octvlphthalate AVRG 2.26401888 7.452| 30.000

Benzo(b)fluoranthenej AVRG

2.14529204 | 12 . 400| 50.000 |

£en:o(k)fluoranthene | AVRG1.93865787 j 11.259 j

50.000Benzo(a)pyrene AVRG |1.69970922 7.409 30.000|^ndeno(1,2,3-cd)pvrene [ AVRG j1.22817824 | 8 . 660| 50.000|

Dibenzo(a,h)anthracene AVRG 1.49016952 | 8.687 j50.000

Benzo(q,h,l)pervlene AVRG|1.56267939 j 7.400 j

50.000

2 -Fluoroohenol

!=====

| AVRG

l==========l=

|1.29838103 j

=========1

2.723 | 50.000|

Phenol -d5 J AVRG 1.69126416 5.31650.000 j

Nit roben z ene-d5 AVRG 0.43289678 3.813 50.000

2 - rluorofcipnenvi AVRG 1.33263082 9.277| 50.0002,4,6 -Tribromophenol ] AVRG |0.40272334] 8.039| 50.000|

Terphenvl-dl4 AVRG 11.05889874 13.697 j50.000

I ! 1 ]

Average %RSD test result.

Calculate Average %RSD: 7.923093319

Maximum 1 Average %RSD: 15.00000000

Mote : Passes Average %P.SD Test.

48 c

FORM VI SV

CxlO^'t

Dfl'-a PiJ^i .•’chem/5972h|o64. j25F020310A64.b/H1020310A64 .d

Date : 10-MAR-2002 15:32

Client ID: SSTD010 Instrument; 5972hpb4* i '.OSample Info: COVolume Injected <uL): 1.0 Operator: 2319Column phase: RTX-5 Column diameter: 0*32

PI-j?nanthrene-dlO+

Data File: /chem/5972hp64. i/'DF020310A64.t./HI020310Afc4.d

Date : 10-MfiR“2002 15*32

Client ID: SSTD010

Sample Info:

Volume Injected <uL>: 140

Column phase: RTX-5

Instrument: 5972hp644i

Operator: 2319

Column diameter: 0432

■:.d

CD

Data File: /chem/5972hp64.i/DF020310A64.b/HI020310A64.dReport Date: ll-Mar-2030 14:32

CompuChem

Data file Lab Smp Id Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date Als bottle Dil Factor Integrator Target Version: Processing Host

Semivolatile Report SW-846 Method 8270C /chem/5972hp64.i/DF020310A64.b/HI020310A64.d

Client Smp ID: SSTD01015:32

Inst ID: 5 972hp64.i

SSTD010 10 -MAR-2 0 0 2 2319

/chem/5972hp64.i/DF020310A64.b/8270Cv6.mll-Mar-2030 14:32 frankson Quant Type: ISTD

15:32 Cal File: HI020310A64.dCalibration Sample, Level:

MAR-200210 41.00000 HP RTE

3 . 50einstein


Concentration Formula: Amt * DF * Vt./ (Vo * Vi) * CpndVariable


DF 1 . 00000 Dilution FactorVt 1000.00000 Volume of final extract (uL)Vo 1000.00000 Volume of sample extracted (mL)• 1.00000 Volume injected (uL)


AMOUNTS

CAL-AMT ON

P7 exp e7 L RESPONSE ( NG) (

• 1 . . ^ P:-:-z: o:-.-::::-- i . 2 *1 % - 2 4 r . ICC' 224256 40.0000

* 0 Napb.t r.a • -tr.-j • c •• ' "5 ;; . 14 .• i v. i : -’■VC' 875539 40.0000

: AT*::*:::-!: n-r-v t : 4 4 e.v ••PC . 4179S0 4 C . 0000

4 r : : : c .4-o : iri 0C 0 i 1246632 40.0000

• -:y. ••••■ 24.' v •••. ') 0 0 i 1174122 40.0000

■■ :. . •;2: . ■ 0 r. 1 4 2 4 14 9 4 0.0 0 0 0

I • f-". • ■ 1.4 74 ■ ..793, 75212 10.0000

: ■■■ ~ "'cl "749 ’ 1 . 4 3 P ' 102100 10.0000

■■ r--r.l ,.4551 .00203 1 C . 0 0 0 0

1 / 3 • ; tcbcy '. 1 7 2 135; 1:564: j 902' 224782 10.0000

: 1: :V- V. :• 1 • 4.4V. 14 4 ' 1 ■ . . 0 9 9 : 49579 in QCOO

: . r Ti:-pr.c--y: 344 . = 5=: 372394 .10 . 0000

SI MI LAP I TV

i:: o o or

:0.3000

• 'J . 41

j C . 7 9

10.56

11.31

11.17

10 48

1 Ci . - 1

«\

f.v

49:

■0'7N-

_L

Data File: /'chem/'5972hp64 . i/'DF0203 10A64 . b/HI0203 10A64 . aReport Date: ll-Mar-2030 14:32

AMOUNTS

Compounds

QUANT SIG

MASS PT EXP RT REL RT RESPONSE

CAL-AMT

( NG)

ON-COL

( NG) SIMILARITY

15 Benzaldehyde 77 7 . 657 7.657 (0.926) 52799 10.0000 10 94 9431

16 Phenol 94 7.776 7 776 (0.941) 88548 10.0000 10.87

17 Bis (2 - chioroechy1)ether 93 7.911 7.911 (0.957) 59151 10.0000 10.53

10 2-Chlorophenol 12 S 8 . C12 3.012 (0.969) 78286 10 . 0000 10.35 8821

19 1,3-DichloroDenzene ■a 6 6.215 8.215 (0.994) 92975 10.0000 10.67

20 1,4 - Dicr. 1 crcoenzene 146 6.263 5.283 ■■ 1.002.' 92 5 S 1 10.0000 1C . 56

21 Benzyl alcohol ICS 3.469 3.469 (1.0251 47235 10.0000 10 . 52

22 1,2 - Dicn lorober.zene 14 6 8.570 8 . 570 (1.037) 91437 10.0000 1C . 58

23 2-Mechylphenoi 103 8.621 8.621 (1.043) 6 9 644 10 . 0000 10.60

24 2,2 ' -oxybis 1 - Chi ore-propane! 0.672 8.672 (1.049) 107604 10.0000 10.47 0 (M'

25 Acetophenone 105 9 075 6.37^ 11 - 074 ) 102237 10.0000 10.76 7924

26 3-Methylphenol 103 6.824 5 . 324 11 . 067' 7 6 3 14 10 . 0000 10.65

2 7 4 - Methy1phenoi 108 3 824 8 .324 (1 . 067) 76314 10 . 0000 10.65

2 6 N-Ni t roso-d: - N- propy 1 amine 70 8.875 8 . 375 (1 .074) 49581 10.0000 10.89 7583

2 9 Hexacnloroet nane ll7 9.010 9.010 (1 0^0) 48973 10.0000 10.76 9515

3C Nicrooenzene 77 9.126 9.120 (0.900) 81015 10.0000 10.66 9654

31 Isopnorone 32 9 . 45C 9.450 iO.932) 162211 10.0000 10.84 9333

3 2 2 -Nitrophencl 139 9 602 9 . 602 (0.947) 52359 10.0000 11.00 9300

3 3 2 . 4 - 2> l me t h y 1 p h e n z 1 • n 9 . 6 C 2 9.602 -0.947' 77790 10.0000 11 . 00 7878

34 3is » 2 -cr. 1 orcet hoxy ; methane 9 3 9.754 9 754 ;C . 962) 98711 10.0000 11.10 9458

35 2 . 4 - 211cr. 1 omphenc 1 -.62 5 q; n 9.940 (0 980' 77517 10.0000 10.57

3 6 1 . 2 . -4 - T r l o n.r o oe n z e r. e 1 s 0 1 0 . 0 7 6 1C. ; 7 5 '0.993; 93856 10 . 0000 11.07

? 7 Napnt na 1 er.e 1 2 3 10. 17 7 10 . 17*7 1 1 . 003) 358401 10.0000 11 . 18 9710

^36 4-Chioroar.;'. me 1 2 7 10.261 10.261 :i.012) 112295 10 . 0000 10.90 8198B: 6 Hexam i oroz-cz ad i er.e

225 10.413 10 4 13 »1.027) 6 3 5 62 10.0000 10.87 9279

•i C ._apro; acc am ■ i 3 10 701 10.701 (1 055; 25809 10.0000 10.13 9685

41 4-Ctioro-3-methyipnenc1 1 n 7 1 0 . 5 5 7 1 0 9 3 7 <1 . 078) 90477 10.0000 10.97 9531

4 2 2 - Met hynapnt na : er.e _ -1 w 11.225 :: .225 (1.107) 178261 10.0000 11.06

4 3 : -Metnvmacntna lene 14 2 11.41: 163442 10.0000 10.75

44 Hexa m 1 cI'ocyctpent ad :er.e 2.- 11.597 • • ;:i-j ; 0 . s a:: 63111 10.0000 10. 10 9064

45 2.4 v -Tr: rrmrocr-mn. 11 7 4 5 ■74 '< '0.692' 6 6 518 10.0000 10.42

:: ?:s 1 0 5 5 7 j 72661 10.0000 10.69

4- ! 1 S:-Sr.~:-.y ; r-; 12 ’ 7 • 1 2 . 0 7 0 ■ :■. : ■’' 204955 10.0000 11.00 7527

•«- 2- mmrmatmm:-:- : i .5 :: 12 12: -0?' I 7 3 4 6 9 10.0000 10.52

12 . : 41 12. .= 4 1 :0. 2i2; 6 13 3 5 10.0 >10 0 10 7Q 6605(a)

= : : :■ : - : 12 '■ 7 : 2 • V 14 3 • :: -.665 0 1C.oncc 11 23 5 15 £

z'. m r : : '.2 - '■ -*''4. 5 7 4 : 0.0000 1 0 . 4 7 s, 2 i F

• •" ■:• ■■■ ■ . r •i 2 1 3 3 7 I 0 . J 0 0 c 11.32 9215

5 } : ■ N* t : cor.: 1 : ■- ■= • ■"■■■ 1 : 1. 4 ■: 2 6 22 31 10.000 0 15.32 3253 (a)

i-—-: : 3 . 2 2 :■ -1 . : 14 ■ 2 7 8 5 3-0 10 . 0 0 o; 11.58 9 4 6 d

' ; • ' :: : : • ' • :; 23 - 1 ■ 2 5 4 r) 0 5 '■ 4.150? so.0000 42 50 (a )

-- .. . i: :■ : 3 ■ - :• ■ 1. 0 01 35677 10-000:: 10.40 7966 (a)

' •' • 2 3 1 . 5 0 7 - l 85324 10.00']0 10.91 3 6 3 S

;; —cr^ar. 1 5 . - 7 5 11 4 7 3 ■■1 22 2) 2.3 5 11 5 10.0000 11.35 94 99

53 C:etnvmh:h3 .'i--' :• ■■ - : I . 9 5 3: 263579 1 0.000 0 11.46 9759

; : ■ a: v: - no:' : 1 . 14 022 - 9 - a q -> 1 0 . 0 0 0 0 11.23 0 l M)

T. 1 Plur re:>_- : 14 ' 4 . •; • 1 5 7 • 336038 10.0000 11.74 77 22

\

\

49l

Data File: /chem/5972hp64.i/DF020310A64.b/HI020310A64.dReport Date: ll-Mar-2030 14:32

AMOUNTS

QC

MH

Flag Legend

■ Target compound detected but, quantitated amount Below Limit Of Quantitation(BLOQ).Compound response manually integrated.

■ Operator selected an alternate compound hit.


Compounds MASS RT EXP RT REL RT RESPONSE ( NG) ( NG) SIMILARITY

62 4 - Ni . roar.: line 138 14.116 14.116 (1.072) 63001 10.0000 10.54 921-1 (a)

63 4,6-Dinitro-2-methylphenol 198 14.166 14.166 (0.915) 52604 10.0000 10.10 5C11 (a)

6*4 N-Nitrosodiphenylamine 169 14 200 14.200 (0.917) 162531 10.0000 11.63 9145

65 1,2 -Diphenylhydrazine 77 14 .251 14 .251 (1.082) 265073 10.0000 ■1.37 9357

6 6 4 -Bromopheny1-phenyl ether 24S 14.775 14 . 775 (0.954) 78176 10.0000 11 . 55 84 7 B

67 HexachIorobenzene 284 15.029 15.029 (0 . 971) 98392 10.0000 11 . 92 9323

6 5 Acrazme 200 15.012 15.012 (D.969) 76049 10.0000 12.04 8600

59 Pentachlorophenol 2 6 5 15.282 15.282 (0.987) 6 0 96 6 10.0000 10.30 9489(a)

7 0 Phenanthrene 170 15.519 15.519 (1.002) 584255 10.0000 12.30

71 Anthracene 178 15 . 567 15.587 ■Cl . 007) 598331 10.0000 12 .45

72 Carbazole 167 15.790 15.79C (1.0201 370848 10.0000 11 .68 9385

73 Di-n-butvlphthalate 149 16 .229 16.229 (1.048) 570484 10.0000 12 . 01 9489

74 F1 uorantnene 202 17.277 17.277 (1.116) 652591 10.0000 11 . 95

75 5enz id l r.e 184 17.429 17 429 (0 873) 373491 20.0000 22.75 0528

7c Pyrene 202 17.533 17.583 i C 5 6 6; 6 644 54 1 0.0 0 0 0 11.97

77 Bury 1 ben.zy i pnt ha la c e 149 18.816 19.815 C . 94 2; 257690 10.0000 11 . 33 9644

70 3,3' •Dichlorobenzidine 252 19 . 847 19.847 (0.994 ) 184736 10.0000 11.60 754 1 (a)

bis ; 2 - e: r.y 1 nexy 1 Phr ha ir.e 14 9 1 5 7 96 19.796 ' C . ? 9 2 : 392596 10.0000 11 .69 9120

i *> Benzc .a ^rtr.tae-r.~ 22 t 19.932 1 a ; n (0.998! 612116 10.0000 11.77

Chrysen- 2 2° 1 9 9 9 5 -.9 999 ; 1 . 002) 574669 10.0000 11.83

j - '• • • C: :v 14 9 20.760 2C . 750 (0. 92 5) 386510 10.0000 1C . 96

9 3 Benzoin: iuorantnene 252 21 . 707 21 .707 (C.967) 398987 10.0000 12.09 (HI

e 4 = enzo ■ x . 252 21.741 21.741 >0.969) 315305 10.0000 10.25

iss Benzo ■ a < py: er.~ 252 22 . 332 22.332 (C.995: 296915 10.0000 11. 13

•ndeno•) .2. } - :d■pyrene 278 25.020 25.020 (1.114) 215885 10.0000 11 . 34 0 (M)

07 31 nenzc r>, n '• ant n:*acene 2 5.02 0 25.020 ! 1 . 1.14 J 262141 10.0000 11.35 8080

5 r Benzo q.r.. t.o-ryler.e 27- 25 . 832 *> c j 3 2 {1.151) 267641 10.0000 11.07 94 30

v

49

Data r-is; 'cm Injection Date I nst rument: 59

i lent Sample

ound: 2.4. Numoer': 11

em/59 72hp64 . : /' DF 020 : 10-Mm R-2002 15:3“72hp64 . 1

ID: 55TD010

6-Tr1bromopneno1^ _ 7* o _ tf,

0h64 . b-,-h I 1 Oh34 . c

Ion 329.60: Hrc^; 69579 Height: 43509

xt

■a4.2 ^

4.3-

4.

1.6-

1.5-

0.9-

0.6

1 4 . On 1 4.05 1 14.15 14.20 14 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.85 14^90 14.95 j

_________________ h i r. ______________________________________________________________1Ion 332.00: Hrea: 0 Height: 0

cp

:4 . ; t ;4 .60 14.65 14.70 14.75 14.80 14.85 14.90 14.95

Hei?nt: 0

494

Data F l le : /chem/5972ho64. 1 /DF020310A64 . b.'HI020310A64 . dInjection Date: 10-MAR-2002 15:32Instrument: 5972hpb4.1

Client Sample ID; 35TD010

oound : 2.2 ' -o>.uo 1 s i l-Chlor-npropane) Number: 108-60-1

Ion 45 .00: Area: 107604 Heignt: 55992

5.4-

5 1 •

4.8-

cvrv43CD

4.5-

4.2- ;

3.9-;

3.6-

3.3-ii

T ^ . U- i

;2.4-

1 .5 i i

1.5- i i

1.2- ji ii j

0.9- ; i

0.6 1

0.3-

0.0- -S.20 6.25 3.30 5.35 6. JO 3.-45 8.50 8.55 8.60 8.65 6

M i n

20 6.25 6.80 8.85 8.90 8.95 9.00 9.05 9.10 9.151

I on 1 21.00: Area: 0 Height: 0 1

9 . Ci

H _ 5

I !

! i ;II 1

»

5.5

| \

; 1

’ l :

i i i

1 i '

i 1i i| j

i i !

CO

1 1

l :

■5 :o 8.35 •• ' "• •: 5.-45 5.50 8 55 5.60 6.65 5."

M : r.

8.75 8.90 8.85 8.90 8.95 9.00 9.05 9.10 9.15

i nn --.00: Jro=,; Height: 0

49 j

’5 d.60 8.55 8.90 8.95 9.00 9.05 9.10 9.15

Data 71 ie : /chem/5972hp64. 1 /DF0203 10A64 . £>, H102031 0h64 . dInjection Date: 10-MAR-2002 15:32Instrument: 5972hp6J.lClient Sample tD: SSTDuiu

impound: *5 Numbe

4-ChiorophenuI-pheny1 ether r: 7005-72-3

o. ti-b. 4

6.0-

5.6-

5.2-

4 . o

4.4-

Ion 204.00: Area: 120382 Height: 72056

T ]

2.3

2.4

0.3- I

0.4-

13.55 1 3.00 13.65 13.70 13.75 13.'-30 13.35 13.90 13.95 14.00 14.05 14.IQ 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50

____ M;p______________________________________________________________________________________________________ •Ion 206.00: Area: C Heignt: 0 I

14.: 14.3 14.4 14.?

14.:

49 C

14.514.4

dData rile: •'i;nem/5972riC'6>4 • i ■' DF0203 10»-Injection Date: i0-MdR-2002 15:32Instrument: 5972np64.1Client Sample ID: SSTDOlO

Impound: Benzo* t>f1uon anthe fS thumper: 205-99-2

Ion 252.00: Mrea: 393887 Height: 135163

1 • D-

1.5-

1.4-

1 . 3-"

1.2- 1.1-

1.0-

0.2

0.1

?1.25 21 . 30 21.35 21 .40 21.45 21 .50 21.55 21.60 21.65 21 . 70' 21.75 21.80 21.65 21.90 21.95 22.00 22.05 22.10 22.15____________________________________________________ M l n_____________________________________________________________ _

ion 253 . ■ j> j: wrea: 35956 height: 28920

21 . 75 21.60 21.35 21 .90 21.95 22.00 22.05 22.10 22.15

-eight: 13445

4 9 74- Cl . c-' 2 i . c-5 21.60 2 1 . do 21. 75 21.60 21.85 21.90 21.95 22.00 22.05 22.10 22. 15

0h64.dData File: .-'chem/5972hp64. 1 ••'DF020310A64 . b.'Hin;Injection Date: 10-HAR-2002 15:32Instrument: 5972hp64.iClient Sample ID: 55TD010

*pound: Number

Indenoi1 : 193-39- 5

cd)pu rene

Ion 276.00

5.7-

5.4-

5.1-

4.d-

4.5

4.2-

3.9-

3.6-

3.3-

Area 15905 Height: 57896

inr-j

2.4-

1 .3-

1 .5

1.2-

0.9-

0.6-

24.55 24.60 24.65 24. "D 24.75 ?J. 80 24.85 24.90 24.95 25.00 25.05 25.10 25.15 25.20 25.25 25.30 25.35 25.40 25.45 25.50_____________________________________________________________________________________________________________________ M 1 n

‘ Inn 139.00: Area: 0 Height: 0

25.2 25.3 25.5

1 4r'

_________ 49b25.3 25.4 25.5

<:<10

Data File: /chem/5972hp64. i/DF020310A64 . 1:./HK020310A64. d

Date : 10-MAR-2002 1F,;46

Client ID: SSTD02v

Sample Info:

Volume Injected (ul_>: 1*0

Column phase: RTX-5

Instrument: 5972hp644i

CD

Operator: 2319

Column diameter: 0432

1.2-

/chem/5972hp64 *i/DF020310A64,b/HK0203l0A64 * d <Part 1 o*

_ UI .J L__■ J _ , J J-

Pk«s,nanthrene-dlO+

(.<10*6)

Data File: /chem/5972hr- :4. i/DF020310A64.b/HK02031C'H64.d

Date : 10-MAR-2002 16:46

Client ID: SSTD020 Instrument: 5'?72hp64.i

Sample Info:

Volume Injected (uL>: 1.0 Operator: 2319

Column phase; RTX-5 Column diameter: 0.32

1.2-

1.1-

1.0-

2chem/'5972hp64. i2DF020310A64,b/HK020310A64*d (Part 2 of 2)

+<MrH73

I

£

i..co

: ?) o i_o

Data File: /chem/5972hp64.i/DF020310A64.b/HK020310A64.dReport Date: ll-Mar-2030 14:32

CompuChem

Data file :

Lab Smp ' Id:

Inj Date :

Operator :

Smp Info :

Semivolatile Report /chem/5972hp64.i/DF020310A64 SSTD02010-MAR- 2 0 0 2 16:46 2319

Misc Info : Comment : Method : Meth Date : Cal Date : Als bottle: Dil Factor: Integrator: Target Vers Processing

/'chem/5 9 72hp6 4ll-Mar-2030 1410-MAR- 2 0 0 2 16 6

1.00000 HP RTE ion: 3.50Host: einstein

i/DF020310A64 32 frankson 46

SW-846 Method 8270C .b/HK02 0310A64.d Client Smp ID: SSTD020

Inst ID: 5972hp64.i

b/8270Cv6.m Quant Type: ISTD Cal File: HK020310A64.d Calibration Sample, Level:


2



DF;VtVo

1.00000

1000.00000

1000.00000

1.00000



;«:t s:c-

amounts

CAL-AMT ON-COL

p p7 RSL FT RESPONSE i NGJ NG)

p t 6 4 : 1 ?00) 112: 40.0000

:: : 4 i 3 Z'-~ \ 4 51 b 9 2 40.0000

■ \ 0 ’• 211330 40.0000

: =. 4 r. < • 1 N 0 1 6 4 4 5 3 5 4 0.0 00 0

v ■ : L ■ 592360 40.0000

22.445 3 0 0 1 303690 4 0.0 0 0 0

1 7 3996 20 . 0000 20.16

* ~ 3 7 ; 3 ■ 5 3 7 02 2 0 . 0 0 0 0 2 0.71

:■ '0.3933 9 S 4 B 2 20.0000 20.24

. -; ■ :. 302 ■ 22I7Q0 20.0000 21 . 34

• g :> c >, 6 4 6 3 0 20.0000 2 0.63

17 -.6 7 1 0.6951 343060 20.0000 2 2 0 3

6.342 ■. ■:. 5 2 5 ■ 2 6 713 20 . 0000 19.55

4 ' 4 ■0.525) 4 5326 2 0 . 0 0 0 0 19.49

SIMILARITY

iM)\

56 13

34 *4 9

501

Dana File: /'chem/5 9 72hp64 . i/DF02 0310A64 . b/HK02 03 10A64 . dReport Date: ll-Mar-2030 14:32

AMOUNTS

v’JANT 513 CAL - AMT ON-COL

Compounds MASS RT EXP RT REL RT RESPONSE ( NG) 1 NG) SIMILARITY

15 Bengaldehyde 77 7 ..555 7 655 1' 0 . 52 6) 53499 20.0000 21.37 9423

16 Phenol . 94 7 . 774 7 . 774 (0.941) 84993 20.0000 20.77

17 Bisi2 -chlore-thy1)ether 93 7.529 7 . 909 [0.957) 5654 1 20.0000 20.24

19 2 - Ch loropner.c 1 125 3.011 8.311 (0.969) 76351 20.0000 20.22 3 9 3 1

1 5 1 . 3 - C i ch lor coenzer.e 14 c 3.213 e . 213 ,’0.994) 88086 20.0000 2 0.28

2>“ 1 , 4 • C i ch lorobenzene 14 6 9 . 2 e 1 e . 231 :. 002) 50729 20.000C 20 . 72

21 Benzyl aizcnzl 1 0 6 6.467 3.467 : 1 .025) 45119 20.0000 2 0 . .1 3

22 l . 2 • 2’:ch 1 crocenzene 14 4 7 . 3 55 6 ( 1 . -’37) 86109 20 . 0000 2C . 43

2 ? 2-Met pyIpheno 1 ■.0 5 5 .636 5 6 2 r> 1 . )45 ’■ 6 6 7 9 7 70 . 0000 20.29

2 4 2 . 2 1 -oxyms . 1 - Ch 1 oroprcpar.e) 95 8 6 7 C 6.67 0 ' 1.04 9 ) 104494 20.0000 20.37 • \

25 Acetophenone 125 3.873 5.373 ! 1 . '274 ) 99231 20.0000 20.79 8 12 0

26 3 -Methyl phenol 108 S . 822 9 . 222 (1.067) 73945 20.0000 20.53

27 4 - Me t hy Ipher.o 1 IDS 5 . 322 3 . 322 { 1 . 067 ) 73945 20.0000 20.55

26 N-Nitroso-d:-N-propylamine 7 0 3.873 5 . 373 (1.074 ; 45909 20.0000 20.24 7302

z? Hexarni oroet.nane : 7 9 . ooe 3.003 (1.090! 46058 20.0000 20.32 94 7 5

32 Si t rooer.zene 7 9 . 126 9 126 i0.900' 76734 20.0000 19.97 9663

i 1 1 sepr.crcne J 3 4 4 8 9.445 ,0.932-' 153599 20 0000 20.19 94 2 7

11 2 - STi t ropnenol 9.60 0 9.600 ,'C . 94 7 , 43698 20.0000 20.08 8235

1 4 Oimetnyiphenz; 122 2 6 00 9-iOC .0.947' 7 3 65 4 20.0000 20.39 7714

:6 5 is ■ 2 ■ znlcroe: n-r.xy - me: nan.e 3 757 9 . "’52 :0.=-.2 93202 20.0000 20.52 94 85

11 1 . 4 • 1 ; rr. 1 : o::ne:tc . 1 4 2 5. = :■. i 3; r, 0 ,i 1 7 4/46 20.000C 19.98

;• •; : 2,.; • T: i tone:', zer.e :: •: 7 2 It .273 -.0.39 3/ 89356 20.0000 20.57

121 10.173 .1.003' 336690 20.0000 20.65 9817| -----

'.2 7 1 ■: .259 11- . 2 5 9 1 . 012 1 104218 20.0000 19 94 3 33 3

2 2 6 10.42t 1 -: .: 2 3, 61905 20 . 0000 2 0 o 1 8 8 5 9

: - - 1 . 0 5 5 ■ 24563 20 . r’000 19 . 17 9 7 0 0

■> - ^tnyl pner.-t 1 1-• - - --- : -- • 2 5 : V*. 7 0 •• S 3 6 9 9 20.0000 20.02 9 616

:■ •••••• ..------ 11.2-3 :: ::: :: .107' 1 6 3 1 9 6 20 . 0000 19.97

,- 1 ■-■.-r;:-.-. .=:.=• : :: . c -1 - : 2;, 161741 20.0000 20 74

” -----r.^ :-j- 2 1 7 : : . ;=■=. : 1 5 5 5 :o.SS : : 5 8 768 20.0000 19.00 874 5

: ■; - - 7 r : ::-.l-:nFth-nol : :■; 1 1 77 11 747 ■ 0 . 5 9 2 '■ S 4 S 7 0 20.0000 20 . 32

: : 7- 11.514 66183 29.0000 19.68

-- ----- - 12 :41 1 2 . •; - ; : . ; 7 15:3-5: 20.0000 2 0.76 7 5 0c

4- 2 ■ 7 n 1 “ : f : ’dtp nt n t .-ne : 4 _ 12 :9 -c 171454 20.0000 21.44

-.V . 3 i: . 0 5 3 01 0 20.0000 20 22 96 3 :

‘ ■’ i “...... *. 2 6 7 ~ 205837 2 0.0000 2 1 .06 r, 1 ;

• - • : - r 1 2 . 2 - ■ - --'4 54 34 6 2 0.000 G 2 0. : .3 9 _•■;

-1 -.i-n-:n-:-.:nv. : 2 7 ■ 403563 ::o. 0000 2 1 5.3 9 7 r ■ j

1 - - : : : - 1 ■ - 5 7 0 0 3 :;o. 0000 24.17 3 4 9 5

-1.j. : - 256744 2 0 . 0 0 0 C 21. } 5 --- --•

: ■ - - ;;" ■ - ■. ■ ■ . :. 1 : ; - 22;: -.. 3 7 4 7 6 100.coo 7<; ;• 7

317 6] 2 0. coon 15.65 8 0 i 4 : a

....... f ' ■ - • 1 12 4' 7 8 1 0 3 20.0000 19.99

. ■ -- : ■ -: : 12: 264921 2 0.0 c 0 0 : 1.0 3 39 n

' : hy . y: ; n 11 ? ‘ • : : - ' .: '32 24 J 7 G 5- 2 C .0000 ::. 05

- ■; 7:.. -: j':-r.y --- v . ■; . - ; .; •, t .: '- - 4 ■ 112730 20 . 0000 2 0.89 0 IN!) \

-:i - . 4 ■ ; . 1 •' 7 114 5 F1‘ 2 0.0000 2 2 01 7 4 5:

50^

Data File: /chem/5972hp64.i/DF020310A64.b/HK020310A64.dReport Date: ll-Mar-2030 14:32

AMOUNTS

J OL’ANT SIC CAL-AMT ON-COL

ToT.poup.ds MASS RT EXP RT EEL RT RESPONSE ! NG) ( NG) SIMILARITY

!1 3 S 14.114 14.114 (1.072) 56308 20.0000 19.04 9208 (a)

6 3 , 0 - D:r. i ; ro • 2 - met hylphenol 193 14 . 164 14.164 (0.915) 48291 20.0000 16.01 8811 (a)

6*i N - N: t rbsod: phenyl am ne 169 14.196 14.199 (0.917) 148922 20.0000 20.56 9082

6 5 1,2- C ipher.y 1 hydrazine 77 14 . 249 14 249 (1.082) 248371 20.0000 21.26 9320

66 •; -Brcr.opheny 1 -phenyiezher 249 14.773 14 773 (0.954 ) 73156 20.0000 20.88 8855

17 H5>:a;n!u:-oUn:ene 2 5 4 15.044 15.044 (0.972) 93579 20.0000 21.72 8543

■3f\t ra z: ne 200 15.010 15.010 (0.959) 70399 20.0000 21.45 8324

5 ? P -r r. t a c n 1 o r c p h e n o: 2 6 6 15.23C IS .290 (0.937) 55185 20.0000 19.11 3625 (a)

70 Phenanz-hren-r 1 7 5 IS . 517 15 517 il.002 ) 539141 20.0000 21.36

' - /■viiti'.i'a ren.e 1-; IS.56S 15 . 5 6 5 a.007) 552453 20.0000 22 . 14

73 Carbazoie 15' IS.304 15.804 a. 021) 346871 20.0000 21.06 0 .< 2 2

7 3 u:-n- butv1chzha 2 a:e 24 9 16 227 Id . 227 (1.04 S ) 530934 20.0000 21.57 9616

2 02 17.275 17.275 (1.116) 6 •} 4 0 8 20.0000 21.30

7r ner.ziciV.-- 9 4 17 4 27 17.427 ■■ 0.5 " 3 : 389739 40.0000 46 . 02 3565

O Pv:-:,r i 2‘.’2.

11.661 .0.886; ■ 5 4 0 S 9 8 20.0000 22.74

14 6 16.614 15.514 (0.942) 242516 20.0000 21.34 96 3 2

252 19.845 19 84 5 (0.994) 17 C 324 20.0000 21 31 7620

h: = -e'rr.y'.i-.TXv: 1 Phzha ia:e '-4 5 19.794 19.7?4 '0.992) 362306 20.0000 21.51 9 2 1

- • Eer.zn anr. n rac^ne 2 2 5 15.930 19.930 ■0.3981 5544 07 20.0000 21 .33

O ::n:-y?e;T 2 2 a 1 3 oc: 19.997 : 1.002: 538192 20.0000 22 07

C 1: r: = 20.75c 2 0 7 5 9 •:o. 925 ■■ 353732 20.0000 20 76

:s: 21.705 21 7 0S iC . 967 ; 358176 20.0000 21.76 i H)_ . - . . I ... ....

251 21.739 21.73*. i 0 . 9 6 5 ; 294443 20.0000 20.46^ Be:'.::- ~>z 22.330 21 .: 5 C ' 0 . 9 9 5; 265C30 20.0000 20.63

2 5 0 1 5 25.019 (1.114' 197790 20.0000 21.34 'MM) \

--.I-.-.-.:" ■ - ■' : ' • J 7 3 :s.::s '1.114; 239:39 20.0000 21.19 S 0 s r

: c r . v-rv . 'mi 2 r 3 3 ‘ 23 . 6 ! ' 1 15 1' 251722 20.0000 21.37 94 -.-.9

i ac

I;Leaend

Target compound detected but, quantitated amount Below limit Of Quantitation(BLOQ).Compound response manually integrated.Operator selected an alternate compound hit.

501

I

I

Data' F i i•=>: /cnem.'‘59~,2hij64 . l /DF02031 Injection Date: i9-mhF-1'mm2 16:46Instrument: 5972hp64.i Client Samcle 'ID: S5TD020

bound: . rNunfrer

4 .

1 i

r i bromooheno1

o •'HK02031 '.'064 . d

4.5

4.2

Ion 329.60: ^rea: 6*46b6 Heignt: 4736b

iT

tr

3.6

3.3-

2.4-

2.1-

1.6-

i <=, - 1 .2

0.9-

1 4 . 'i 1 14 14.3 14.4 14.5 14.6 14.7 14.8 14.9

Mir.Ion 332.00: -"'ea: 0 Heignt: 0

1

a?

14.8 14.9

50414.5 14.6 14.7 14.3 14.9

i

Data file: •/chem/5?72np64. i.'D7020310h64Injection Date: 10-MhR-2002 16:46Instrument: 5972np64.:Client Sample ID: SSTD020

pound: : Number

2 ’ -o • ub i s1 1 -Ch loropropane J 106-50-1

5.1-

4.6-'

4.5-

4.2-

3.9-

3.6-

3.3-

3. 0-

b-,-Hr.'02031 O^d-4 . a

Ic-n 45.00: P.-'ea: 104494 Height: 51064

rCiT

ill

2.4-

2.1-

1 _ Q_

1.5-

1.2-

0.9-

3.2

I

i . 5

II

3.4 6.5 8!,6 317 8^8 8^9 9.0 9ll

___________________________________________________M in_____________________________________________________________________________________i_____________

Ion 121.00: Hr-ea: 0 Height: 0

"I '■6 ■

■x> •

i\

8. "5 3.30 8.Q5 5.90 6.95 9.00 9.05 9.10 9.15

I

2 ____ 50o•5. •;5 5. 70 8.75 6.80 6.85 8.90 8.95 9.00 9.05 9.10 9.15

m i r.

Client Sample'ID: 35TD020

Data File: /chem.'5972hp64.1 /DF0203 10064 . b/hh0203 10064 . dinjection Dat*: 10-MwR-2002 16:4*5Instrument; 5972hpb4.1

ound : 4-i_h ioropnem.) 1 - pheni.i 1 ether founder: "’005-72-3

Ion 204.00: Hrea: 112730 Height: 76232

*

5.2-.

4.0-

4.4-

4.0-

13.9 14.1Min

14.1 14.; 14.3 14.4 14.5

ion i’jo.Ut1: nrea Height: 0

Cc

1 4 . oo 14.10 14.15 14.20 14.25 14.70 14.35 14.40 14.45 14.50

I ht

- _;50b

: : . ' " 1 - . O'. : 4 . 05 14.;-;, l 4 . l 5 14.20 14.25 14.30 14.35 14.40 14.45 14.50

l

I

I

Dats File: .''ch~rri/5972r.p34 . 1 .<Injection Date: 1u-MmR-2002I ns t rument: 5972hp64.1

Client Sample ID: SSTD020

DF.

ound: Bemo < b > f luoranthene Mumper: 205-99-2

14 . p/Hr'.i.'i031 09»54 . d

1.5-.

1 .J-

1 . V

1.2-

Ion 252.00: area ;58176 Height: 134272

in , crv

OJ

0.9-

0.3-

0. b-

0

0.3- •

I

on 253.00:

21.7 21.8 21.9 22.0 22.1iM: r;____________________________________________________________________________________________

7rr35 Heignc: 23492

U*i

•Al

2 1.8 1

ion ii n 521

TSI

He:gr t: 1 'u

I

t

5021.9 22.0 22.1 !

Date* F 1 1 <=■: .''r hpm.''. 1 .•' DF 0203 iOHqU.p Hk 020310964.cInjection Date: 10-M9R-2002 16:46Instrument: 5972hp64.lClient Sample ID: S5TD020

pound : Inaeno( 1. 2, j--cd J py rene Number: 193-39-5

5.1-

•4.8-

4.5-

3.6-

2.4-

2.1-

1.3-

J . 5

1.2-

'3.9

Ion 276.00: Ores: 197790 Height: 52520

24.3 24.9 25. CMir

25.1 25. 25.3 25.4 25.5

Ion 133.00:

''5 25 . 10 25.1 5 25.20 25.25 25.30 25.35 25.40 25.45 25.50

50:3 o: J4 . r- 2 j . ,2 :u . r.r : 5. ;=. :D. ; -5 _ :5 25.20 25.25 25.30 25.35 25.40 25.45 25.50

Data File: /chem7597;hpf.4. i/DF021310A64 .b/HL020310A64 ,d

Date : 10-MAR-2002 17:23

Cl ient ID: SSTD050 Instrument; 5972hp64.i :.nSample Info: CD

Volume Injected (uL>: 1.0 Operator; 2319 LSD

Co1umn phase: RTX-5 Column diameter; 0*32

2chem/5?72hp64.i/DF020310A64.b/HL020310A64.d (Part 1 of 2>

2.0-1.9-

1.8-

1.7-

1.6-

1.5-

+CO

F'hj?nanthrene-diO+

C:<10

Data Pile: /chern/5'572hpe.4.i/IiF020310A64.b/HL020310lHb4.d

Date : 10-MAR-2002 17;23

Client ID: SSTD050

Sample Info;

Volume Injected (uL); 1*0

Column phase; RTX-5

/chem/’5972hp64.i/DF020310A64.b/HL020310A64.d (Part 2 of 2>

+OJ

Instrument; 5972hp64*1

Operator; 2319


LO

i

Data File: /chem/5972hp64.i/DF020310A64.b/HL020310A64.dReport Date: ll-Mar-2030 14:32

CompuChem

Data file Lab Smp , Id Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date Als bottle Dil Factor Integrator Target Veit Processing

Semivolatile Report SW-846 Method 8270C /chem/5972hp64.i/DF020310A64.b/HL020310A64.d SSTDO50 Client Smp ID: SSTD05010-MAR-2 0 02 17:232319 Inst ID: 5972hp64.i

/chem/5972hp64.i/DF020310A64,b/8270Cvb.mll-Mar-2030 14:32 frankson Quant Type: ISTD10-MAR- 2 0 0 2 17:23 Cal File: HL020310A64.d7 Calibration Sample, Level:1.00000

HP RTE Compound Sublist: all.sub'ion: 3.50Host: einstein

3


NanVe Value Description

DF:VCVo'Vi,

1.00000

1000.00000

1000.00000

I . 0 0 0 0 0


Cpnc Variab Local Compound Variable

AMOUNTS

CAL-AMT ON-COL

K 7 'r\ v Q t ~ RESPONSE t NG) ( NG)

11 ? 5 = o 40 .0C00

: :-wu. 4 4 2 3 7 rj 4 0.0000

u i U . 0 0 0 0

■:1: ■ 74 7772 40.0000

■3 3 3 1 3 7 40.0000

■■■■■■- 307230 4 0.0000

; •; 1 - 50.0000 46 . 6 4

50.0000

: -t 244^45 50.0000 51.12

5 2 0 12 I 50 . 0000 50.04

: 6 i 5 1 3 5 C . 0 0 0 C 51.10

•5269*55 50.0000 51.79

■ 6 *j..- 96 5 0 . C 0 C 0 49.42

' 4 . - 2 = • 1 1 6 - 2 2 5 0.000 C 4 5.75

511

I

/Data File: , Report Date :

hem/5972hp64.i/DF020310A64.b/HL020310A64.d11-Mar-203 0 14:32

Ezmpc zr.ds

51G

R . - X ? E - REL RT RESPONSE

AMOUNTS

CAL - AMT

i NG)

ON-COL

( NG) SIMILARITY

1 r1

Ser.za Ideh.yde 77 7.655 7.455 (0.925) 127916 50.0000 51.42 94 r

15 Phenol . 54 7.773 7 7 7 3 :C.941! 203581 50.0000 4 9 . j

17 3 is 12 - cr.lcrzet'r.yl: echer 53 7 90S 7 . SOS i0. 957) 134861 SO.0000 4 3 . 1■

15 2-Chioropheno1 1 2 S 8.010 6 .CIO (0.969) 190352 50.0000 4 9.9 = 9 919

- c, 1. 3 -Dich 1 orober.zene 14 5 8.212 8.212 (0.9941 217072 50.0000 4 9.51

2 0 I , 4 -Dicr.iorcoenzene 145 8 2 S 0 3.290 ,1.002) 219903 50.0000 4 9.70

-> i Benzyl alcohol 10 3 5.466 3.466 (1.025) 103013 50 . GJ00 48.02

2 2 : . 2 -D: or. 1 orobenzene 14 5 8.558 3.565 (1.037) 215798 50.0C. 00 49.55

2 1 2-Methviphenol 105 8 . 635 -.635 (1.045) 166121 50.0000 4 9.92 \2-; 2.2' - oxyb '.s'.'. - Ch 1 oropropane) 45 3.669 ° . 6 6 9 (1.C49) 256048 50.0000 49.45 0 (M ) \

2 5 Azet r-pr.er.one ICS 3 8 72 . 3 7 2 (1 . 0 7 4 ) 236090 50.0000 49.09 8494

2c 3 -Me: hy lpnenc ; 1 OP 3.838 - 9 3 8 (1.070) 176775 50.0000 48.87

2 7 4 -Mezhy 1 p.neno. 1 0 5 5.338 5.339 11.070) . 176775 50.0000 48.87 \25 N • N 11. rose - q: •N-propy1 an:ne 7 0 9 . S 7 2 8 . 972 i 1 . 074) 110300 50.0000 48.38 0 (M) V

2 0 He:<a-:r.: or-: n^ne 1 17 9.007 4 : 0 7 ( 1 . 090i 113815 50.0000 49.71 94 34

i .• 9.125 -. ::s ■'0 . 6 58 : 136678 5 0.0 0 0 C 49.72 95 92

i Isopnorzr.e 4 2 2.447 5.447 i C 9 3 0; 37QQ06 50 . 0000 49.71 94 5 0

i 2 2 - N i - : tcr-’i.;. 1 3 C, 5 55 5 9 5 r '••• 0 94 5> 118107 50.0000 4 9.77 326 1

5 ;■ 2.4-: : c,e: :\v 1 r;r.-.tc: 12 2 - V-> 0 . 94 5. 1 7 c 5 6 0 50.0000 49. 92 754^

3 4 h: ^ ; 2 -' net na ? 1 =- : ; 7?: 0 . 36 0'- 2 2 0 4 2 ^ 50.0000 49.62 9525

;5 2 . - 2; .t . -• :l •,! 142 ' . 9 -• 4 4 0 . ? 13 ; 163158 50.0000 5 0.0 C

992 : 217541 50.0000 50.88

1 002 . 804036 50.0000 50.29 9794

.01 o ■ 25-i 134 50.0000 49.71 3309

-2’’ ■ 14 1 R 8 50.000C 50.04 3 8 59

: . 055) V 0 3 0 0 50.0000 4 9.71 9553

277; 157374 50 . 0000 43.50 9732

■ 105) 4C3254 50.0000 50 . 32

■; ; • 12 3) j 3 4 6 5 6 50.0000 50 . 30

. 5 54 i C . 331; 153557 50.0000 49.69 8963

74 6 ■0 5 92 i 157780 50.0000 49.69

r: . c. 899; 169239 50.0000 50.24

7 9 1 7 . 47Q704 50 . 0000 50.37 7 5 7 4

:: r ■ 'j 9 2 0 i 400643 50.00GC 5 0.05

.3 5 ■■ 14 IS65 50.0000 4 9.51 52 7 0

•. 7-' c 4 • 489241 5 o . o c o o 50.02 9 3 9 7

. -• 1 .= 9 7 4 , 132126 50 . 0 00 0 4 5.09 9 3 34

7 W 3 547450 50.0v00 50.43 9673

9 94 : 129354 50 . C200 57,17 9 2 06

: 3 4 ■■ o 1 7 7 6 c 5 c . r, 200 5 0.30

' 1 7 ‘A 4 2 5 C . 0 0 C 247.6

'■12' = 266 3 5 0 1 0 0 0 4 6.9 0 7 24 4

■' 1 2 2 4 : :■ = i :■ e 51 0 0 0 0 4 9.2 7 -> - '<

' 1 024 ' c 2 S ri t '■ 5".0 0 0 2 4 5.5 9 0 9 r-

5 5 .■ 5 7 7 5 1 50.0090 4 5 . c - •j 7 54

: D ' 2 6 4 ci 50.0090 50.4.

■y , 1 4 7 , 7 3 4 3z 50.0000 5 0 =4 7 0 5'

51 c.

Data File: /chem/5972hp64.i/DF020310A64.b/HL020310A64.dReport Date: ll-Mar-2030 14:32

AMOUNTS

’ Q’JAi-i 31G CAL-AMT ON-GOL

Compounds MASS RT EX? RT REL RT RESPONSE ( NG) ( NG) SIMILARITY

6 2 4-Nitrear.lime 138 14.113 14.113 11.072: 149845 50.0000 50.53 9214

6 3 6 , 6 - Di ni t ro- 2 -methylphenol q - 14.130 14 180 * C.916 > 133572 50.0000 50.78 6717

64 N - N i t ros ed i pher.y lami ne 165 14.197 14 197 : 0 . 9171 352250 50.0000 49.77 6 8 3 0

65 1,2-Dipheny1hydrazine 11 14 . 24S 14 .248 (1.092) 585881 50.0000 50.11 9 515

6 6 4 - Brc-mopheny 1 • phenyl ether 24 6 14 . 772 14 . 772 (0.954) 177456 50.0000 51.46 8 922.

67 Hexach orober.zer.e 2 84 15.04 5 15.C43 (0.972) 218116 50.0000 51.47 9 6 C 9

6 S At razine 2 C 0 : 5 . 0 0 9 15.009 t0.969) 167227 50 . 0000 5 1.74 3 0 0 7

65 Per.tachiorotherc 1 264 15.279 15.279 iC.987) 140243 50 . 0000 •19 . 7 2 8 777

70 Phenanc h.rer.r :7S 15.514 15.516 (1.002; 1224268 50.0000 50. 63

71 Anthracene : 73 15 . 584 15 . 5S4 (1.007) 1271482 50.0000 51 . / 4

72 Carbazoie 167 15.803 15.503 (1.0211 826857 50.0000 51.12 9498

73 Di-n- butviphtna1 ate 145 16 226 16 . 226 (1.0481 1237206 50.0000 51.16 9 6 6 5

74 Fluoranthene 2 02 17.274 17.274 (1.116) 1436834 50.0000 51 . 55

75 5enz;cnre 1 84 it 427 1 7 . 427 (0.873) 556332 100.000 103 . 3 8649

76 Pyrene 202 17 6 8 C 1 7 . 6 8 C ; 0 . 8 8 6 ■■ 1503681 50.0000 51.93

Suty 1 be,r.iy > pr.i na ! a:e 14 5 18.313 18 .313 ;0.942; 589864 50.0000 50.82 9683

7 w 3 /■ - 7: c r. i c r 0 b e n z id i r e 252 19.844 19.344 iC. 994) 418034 50.0000 51 . 13 7836

79 o 1 s : 2 -et ny 1 n.-xy 1 ; Pnt ha la t e 149 19.793 19.793 ( 0.992) 899506 50.0000 51 . 96 929530 Ber.zo 'a!- an: rracene 223 19.529 ’9.929 (0.999) 1355883 50.0000 51.12

61 Cn ryse.ne 2 2 6 2 0 0 1 5 20.013 : 1 . 0 C 3 i 1294305 50.0000 51.76

92 Z: n ••ut v . t-.n: r.a . a t ~ '-4 6 20.774 :r. . '74 iC 925: 307967 50 . 0000 52.21

2 5 2 2 1 .704 2 1 7 04 ■ 0 9 6 7.. 780631 50.0000 4 7.38

2 52 21.7?- :i 7>; •. 0 . 5 6 5 •• 828139 50.0000 55.62 (

2 -1 2 22 3 2 5 2 2 3 2 9 .0 3 55': 6 66 8 09 SC .0000 51.03

2 7 5 25.0:4 25.034 ;1.115 ) 485486 50.0000 51.46 0 (

"i" C 1 oer.zr- r art hrar-rr-v 27 4 2 5.0 3 t 2 5 0 34 ■ 1. ; 15 ; . 591905 50.0000 51.71 8065

36 Renzo ■ 7 . n . ■_ :".n yr.e 2 7 4 25.646 25.646 (1.151) 521583 50.0000 51.79 94 17

(M)D \

QC flag,Legend


bio

II

Data F 11 e: /chem/5972ho64 . 1 /DF020310964 . b-' HL.0203 10H64 . clInjection Date: i0-MhP-2002 17:23Instrument: 5?72no64 .Oiient Sample ID: 5STD050

? pound:

Mumper

2 ' - o ■ y b i 106-60-1

1 -Chloropropane '•

1.1-

1.0-

0.9-

0.9-

0.6 •

n.5-

,j 4.

on 45.00: 4rea: 256046 Height: 120376

(?•«r»'OZ

0.2-

0.1-

6.7' 3.3 3.4 6.5 o.c 3.7 S.8 8.9 9.0 9.1

______________________________________________________________________________ ________M 1 nIon 121.00: n^ea: 0 Heignt: 0

1

3.40 .5. 5.55 3.3 0 3.3 5 5.70 5.7-; 5. SO 6.85 8.90 3.95 9.00 9.05 9.10 9.15

5145.65 5.50 5.-5 S.80 6.85 6.90 3.95 9.00 9.05 9.10 9.15

M 1 n

Data F i 1 a : /chem/5972ho64 . 1 .'DF02031096*4. b/HL.1Injection Date: 10-MAR-2002 17:23Instrument: '5972ho64.iClient Sample ID: 55TD050

mpound: 5 Numoe

N-li 11 roei: '321-64

N-prnpu 1 am i ne

6.4-

4.9-

4.4-

4.0 -

3. b-

1 . b-

1.2.

0.8-

0310A64 . d

'0.00: Area: 110300 Height: 65240

airvCD

03

I

•5.4 c. 5 3.6 8.7 6.0 8.9 9.0 * I

____________________________________________________________________________ Min___________________________, Ion 130.00: Area: 0 Height: 0

I

I

I!I

' I

!

/

9.1 9.3

' • f 9.1

T'rv•r-

13

lgn:: u

c,

M i n

51 o

9.0 Q.i Q.2 9.3 ;

!

8.9

pound: 4-Chlo-opneny 1 -pheny letter Number: ?005-72-3

Ion 204.00: nrea: 272646 Height: 189974i . 9-

1.8-.

1 . ~

1.6

l .S';

1 .4-

1.3-;

1

1.1;

f 1 ■2 0.9-:

Data File: .• chem/5972'np&4 . 1 / DF02031 0964. b/HLOI‘0310964.0Injection Date: 10-MwR-2002 17:23Instrument: 5972hp64.iClient Sample ID: SSTD050

l

R-

0 . o

0.5-

0 . 4

13.7 13.9 13.9 M.O 14.1 14.2 14.3 14.4 14.5 I

________________________________________________ M i n____________________________________________________________________________ _____________Ion 206.00: 0 Height: 0

i

I

- I2.4 |

I

• 5 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50

neignr: 0

'5 14

o

:5 , 40 14.45 14.50

Data F: 1 a: .'cnem/5972hD64. 1. DFInjection Data: 1Q-MftR-2002 17Instrunent: 5?72hp64 . lClient Sample ID: 35TD050

029310964. b/H!_0203l0964 .d

pound: Benzo(k > Fluor anrnene r5 Mumper; 207-08-9

Ion 252.00: wrea: 828138 Height: 359300

2.0-

1.0-

1.6-

1 . 4-"

1 . 2

1.0-'

0.8-

0.6-

21.6 21.8 HI .9 22.0 22.1

Ion 253.00: 9rea: 16830' Heignt: 74332

>;•. _ 4

0. 0

J16‘

f

bl/1 1

Data File: cnem • = ?_,2hp64 . : •Injection Date: 10-l":2-

I nst rjnen r : ,5 ? “’I hp64 . 1 Client Sample ID: S5TD050

mpound: I ndeno . l.J.D-cd,1 pyrene :. Number; l?3-7?-5

1.2-

1.1-

1.0

0. ?••

o.a-

'64 . b- nL:

Ion 276.00: Area: 4b54S6 Height: 125664

*T

ui'.co

25.1 25.2 25.3 25.4

35 25.40 25.45 2';i. 50

'5lo

"<= i'i“ ?n 1"ic, 1 c, -c,25.20 25.25 25.30 25.35 25.40 25.45 25.:

Data File: /chem/5972hp64. i/DF020310fi64.tj/HG020310A£4.i-J

Date : 10-MAR-2002 14;16

Client ID: SSTD080 I nstrument: 597£hp6*4. i o~>

Sample Info: t—i

Volume Injected <uL>: 1.0 Operator: 2319 LO


Pbenanthrene-dlO+

Data File: 7chem/5972hp64. i7DF020310A64.b/HG020310A64.d

Date : 10-MAR-2002 14:16


Sample Info;

Volume Injected <uL>: 1.0 Operator: 2319


C\J1-0

2chem/5972hp64.i7DF020310A64.b/HG020310A64.d (Part 2 of 2t

Data File: /chem/5972hp64.i/DF020310A64.b/HG02031CA64.dReport Date: ll-Mar-2030 14:32

CompuChem

SSTD080 10 -MAR- 2 0 0 2 2319

Data file Lab Smp ; Id Inj Date Operator Smp Info Misc Info Comment ■Method Meth Date Cal Date Als bottle Dil Factpr: 1.00000 Integrator: HP RTE Target Version: 3.50Processing Host: einstein

Semivolatile Report SW-846 Method 8270C /chem/5 972hp64.i/DF020310A64.b/HG02 0310A64.d

Client Smp ID: SSTD08014 : 16

Inst ID: 5972hp64.i

/chem/5 9 72hp64.i/DF02 0310A64,b/8 2 7 0Cv6.m ll-Mar-2030 14:32 frankson Quant Type: ISTD10-MAR-2002 14:16 Cal File: HG020310A64.d2 Calibration Sample, Level:




uir

Vt

VcVi'

1.00000

1000.00000

1000 .00000

1.00000



AMOUNTS

•I CAN. ?i j cal-amt ON-COL

•• •• •• jZ X X- REL XT RESPONSE ; NG) i NG) SIMILARITY

r. i;.:- - 106:5 9 40.0000

2 N,v.y.: . i- 4 .■ :4 ■ 4 1 ? 2 1 C 40.0000

• Ac':;;.: : . : - / :■.> ■■ 2:-: j4 40.0000

4 3: : ' •- 4-:- .: . O . O C 4 4 0.0000

: :: : c 2 g 4 0.000 02::. •; : 4T. !; 4 0.0000 IHJ

1 - / . . :.2 - ;■ ■. 7 - 271242 5 o . o: c 0 a o . c c

- . - . 35362: ao. cooe 80.00

•- ■ : _ . c :■ r isss::- a o . c o o o 50.00

• •; 7 z n p c c C . 0 0 0 0 9 0.00

: : : •' *. • 4: 239975 9 0 . 0000 ao. oo

-■ ■ 1 2 G 5 0 2 5 80 0000 ao. oo

: 2 -- : 1 2 7 X 80 0000 a o.oo a 71 -j

.4 7 . : . : ; 4 b 9 8 0 . 0000 a o.oo 9 56 S

521

!I

Data File: /chem/5972hp64.i/DF020310A64.b/HG020310A64.dReport Date: ll-Mar-2030 14:32

Compounds

CUANT SIG

MASS

15 Eenzaidehytie

16 Phenol ,

17 Bis(2 -ch1o roe t hyi) e zher

IB 2-Ch1orophenoJ

15 1 , 2 - D: chlorobenzene

2-.' I , 4 -D: :hlororenrene

Benzyl alcc-nol

2 2 1.2 -Dichlorobenzene

21 2 - Met hy 1 phen.o 1

IN 2,2'-oxybis'1 - Chicropropane)

25 Acetophenone

26 3 -Methylpher.ol

27 4 -Methylpher.ol

2 8 N - N : t rose- - d ] - N - prop-y lam me

2 9 Hexachicroet har.e

'• 0 N: t rocer.zene

: 1 Isopncione

: 1 2 - N: z ropnenc :

77

?4

28

1 0 8

14 6

100

4 5

1 05

108

103

TQ

1 1 7

Nap.n: r.a

r. e x a c r.:

Capro:£

: rottr. ;«o : - r.-e

127

r'c

RT

7 . 776

7 .694

7.996

6.216

6.263

8 .469

3.571

5 . 638

9.672

?. . 37S

6 . 824

3 . 924

8 . 3^5

9.010

o • n g

3.602

5 . 7 04

AMOUNTS

CAL-AMT ON-COL

? RT RE L RT RESPONSE ( NG) NG) SIMILARITY

7 . 641 (n . 524 j 183909 90 . 0000 30 . 00 95 16

7 . 776 10 . 941) 306128 so . 0000 8 0 . 00

7 . 394 I 0 . 955) 207109 30 . 0000 00

7 . 996 (0 . 967) 233461 3 0 . 0000 a:- . 0 0 9 6 66

6 . 2 i ’3 . 994 ) 326246 5 0 0000 6'1 00

3 .25? ' 1 0 02 ' 333767 3 0 0000 8 5 0 0

3 4 o 5 1: 02 5) 1 6 9 6 6 1 0 0 0000 80 2 0

o 571 (i 0 3’’) 320414 6 0 0000 30 OO

0 6 3 3 (1 04 5' 237000 80 0000 80 00

8 672 :i 049' 378746 80 0000 80 00 9164

8 875 (i 074 ) 347948 80 0000 80 OC 8240

S 324 (1 067) 267213 80 0000 80 00

6 824 11 067) 267213 80 0000 80 00

•3 875 11 074) 162945 80 0000 80 00 7171

Q 010 11 0901 170719 80 0000 80 00 9517

G 22 9 ' 0 9 0 C 1 285815 80 . 0000 90 . 00 9672

•7 4 50 ■ c 932: 556109 80 . 0000 80 . 00 94 07

602 10 94 7 t 177032 80 . 0000 80 . 00 94 16

9 . 6 02 ;o 947 ; 260625 30 . 0000 80 . 00 7744

r 754 c 9 6 2.' 333480 80 . 0000 80 . 00 94 97

3 94 <' } 4 n •• 279037 80 . 0000 80 . 00

:. 075 . 0 593 ) 317936 30 . ocoo 80 . 00

: c. L7-7 ■ i. 003? 219022S 90. 0000 80 . 00 9689

1 o. :s: -:. 012 1 387424 80 . 0000 80 . 00 8203

4 1 3 'i. 027) 221086 80 . 0000 80 . 00 9393

10 7 16 V . 057) 9B014 30 . 0000 80 . 00 9722

K ■ 9 3 5 ■ 0 7 ? i 3 C 7 6 7 2 80 . 000c 80 . 00 97 32

•; - L < . 1 0 7 ) 596306 60 . 0 2 0 0 80 . 00

4 1 125 : 5 B 116 3 30 . 0 0 0 0 80 . 00

5 9 7 1; 243425 80 . 00 00 3 0 . 00 9 06 5

7 4 9 852 • 246461 80 . 0000 80 . 00

5 54 l-j a 5: 259845 30 . 0000 ec. 00

• r. ' 7; :• 17 '• 7C8392 80 . 0000 30 00 7 54 6

2 1 2 5 2 0 1 600948 30 0000 eo OC

: 2 : ; 1 ■ 5 ? 7 217120 SO 0000 8 0 00 96 34

12 ' -7 r. 36? ■ 725308 80 0 0 c 0 30 00 9365

2 -74 ■ 203S45 50 0 000 80 00 94 14

3 n •. v ; 1 1410309 a C 0000 80 OC 927 9

•a? 213346 b<:/. 000 8 9/. 5 5354

2 2 :-04. 5 2 015 3 = "■ 000 0 3 C 00 0 n 1 6

: " = : 15 7 5 5 O' 4 0C .000 4 0

1 2 ■ : :■ 5 7 :■ 0000 9 0 72:;

r. : ■ ■::a 2 a1;: c 0 0 0 a 5 -j 9 9 9 5

4 7.: 2 • 5 2 7 03 6 80 0 0 00 3 0 9552

- j 2 5 5. 542152 a; 0 0 0 0 as 9 0 9 7 5 5

'.4 ■ 4 0 7 4 12 a '1 C 0 0 0 b: DC

T ' 1 0 3 1 7 1 - ‘j 0 <j 0 0 OO 112':

sT

52


Compounds

QUANT s:g

MASS RT EXP RT REL RT RESPONSE

AMOUNTS

CAL-AMT

{ NG)

CN- COL

[ NG) SIMILARITY

6 2 4 - Nit roan: : ir-.e 133 14.116 14.116 f1.072 > 22 1 7 8 S SO.0000 80 00 9220

63 4 , 3 - Dm 11 ro - 2 - mo thy 1 phenol 19 8 14.164 14.184 (0.916) 212659 80.0000 90.00 3844

6 ‘l N-Nit rosoaipnen/iamine 16 9 14.201 14.201 ' C . 917) 530029 80.0000 80 00 3976

6 5 1,2-Dipnenv:hydra zine 77 14 . 251 14 251 (1 . 082 i 363349 30.0000 30.00 9422

6 6 4 -Bromophenyl-cheny1 ether 243 14.775 14.775 : 0.9 54) 256313 80.0000 90.00 3572

•3 7 H e :< a c h ir o r o benzene 23 4 15 . 02 9 15.029 (0.971) 3116 5 6’ 80.0000 60.00 916 7

3 9 At ra z i r.e :ac i; 16.012 (0.969■ 244606 30.0000 3 0.00 9 14 3

5 9 Pent ach ' c : jpr:-1 266 15.233 15.263 \ C.997) 221370 9 C . 0 0 0 0 30 . 00 3 6 3 0

7 0 Phenant’hrer.e m? 15.515 15.519 (1.002) 1763994 80 . 0000 80 . 00

71 An t h r a c e n e 1 7 S 15.537 15.597 11.007) 1807941 80.0000 80.00

7 ^ C3ixazoie 16 7 15 . 307 15.807 (1.021) 1227719 80.000C 80.00 9457

73 D i - n - bu t i pht ha late 14 9 16.229 16 . 229 (1.048) 1811649 80.0000 80.00 9543

74 Fluoranthene 2C2 17.278 17.278 (1.115) 2054576 80.0000 80.00

It Benzidine 184 17.430 17.430 (0.973) 1273220 160.000 160.0 3647

•X Pyrene 2 02 17.693 17.683 ( C . 5 8 6 ) 2167993 80.0000 80.00

77 Buty ibenzy 1 phtna ;ate 14 9 19.916 1 S . S 1 6 (0.942) 502911 80.0000 80.00 9673

7 6 3.3' -Dicn1crooen zidine 252 19.847 1 9 847 < 0.994 i 624855 80.0000 80.00 7917

1 c bis i 2 • ethv lhe>:v: . Phtna late 14 9 19.797 1 9 79 7 ■0.952: 1326967 80 . 0000 80.00 913 3

3 Benzo . a . an: racen.e 2 o - 1 9 9 3 2 19 -32 ■ C 9 9 S ; 2046890 30.0000 80.00

n Thr/anne 2 2 8 2 0 216 2 0 1 5 ;:. 003) 1929267 SO.0000 80.00

n —•i • n • y :iA.AT-r : ■; ■? :: 7-:o 2 0 .760 ■0.923; 1413191 80.0000 80.00

r :■ Benzc . .?■ : „ t:: rant n.ene 252 2 : 7 0 7 2 : ' 0 7 '0.965' 1154198 80.0000 80.00 : W

Benzc ■ x .- : .uz>r ant nmr.e 2 5 2. 21.74: 21 "41 ' 0.9 6 6 i 1335389 80 . 0000 80.00| Be.nzo a t y'. rr.-. 2 3 2 22.543 22.543 . C . 5 9 3 i 1040333 80.0000 80.00 • (HI

r ^ Inoeno • 1 . 2 . - : j . ovrere * 7 r "> C. ATS nr n : a ; 1 . 115 : 729107 80.0000 80.00 0 iM'

3-, Dibenzo a . r. ■ =mr nrazene 17- 25.036 25.038 '1.115) 830952 80.0000 80.00 82 81

*' 3 Benzc 3,:..: nervlene 2 ~ ~ 2 5 . 5 6 6 ' - A - •: 1 . 15 0 : 929697 80.0000 80.00 9 37 7I

QC Flag ^LegendI

A - Target compound detected but, quantitated amount exceeded maximum amount.

M - Compound response manually integrated.H - Operator selected an alternate compound hit.

523

D3ta File: ''chem/5972hp6 4 . i / DF 02031 0h64 . P/HG020310064 . dInjection Date: 10-MOR-2002 1*4:16Instrument: 5972hp64. iClient Samole' ID: 55TD080

ipound:I Number

Perglene-dl2 : 1520-96-3

' Ion 264.00: Prea: 309056 Height: 137792

ihi. j- 1

i* *j1 2- c'*

1.1.

IT’ . _U f

0.6-

> 0.5-

0.4

!j

1

21.95 22.00 22.05 22. 10 22.15 22.20 22.25 22.30 22,35 22.40 22.45 22.50 22.55 22.60 22.65 22.70 22.75 22.80 22.85 22.90

■_______ M i r.Ion 260.00: wrea: 6“596 heignt: 30464

• J i?n

3-

1 . o

i

;5 2? . •• j 22.45 22.50 22.55 22.60 22.65 22.70 22.75 22.80 22.85 22.90

o 22.60

— 522.70 22.75 22.80 22.85 22.90

i

!Data File: /dnem/5972hp64 . i /DFO Injection Date; l0-Mwp.-2002 14: Instrument: 5972hp64.i Client Sample ID: 3STD030

pouna: Number

4-'thlaropheny1-pheng17005-72-2

20310.lb

ether

Hb HG020310P64.a

Ion 204.00: nrea: 407612 Height: 259066

S

o

1.6-'

1.6-

ir', 1.4-

7 1.2-

1.0-

0.3-

0. o-

.55 13.60 13.65 13.70 13.75 13.80 13.85 13.90 13.95 14.00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50Min ___ ________ ___________ ___________ ______ ____________________________________

Ion 206.00: Hrea: 0 Height: 0

cd

14.2 *. 4

f

l

52 o

1 4 .14.3 14.4

I

Data File: /chem/5972hp64.1 /DF020310h64 . b/HG0203l0A64. dInjection Date: IO-MhR-2002 1*4:16Instrument: 5972np64.iClient Sample ID: S5TD080

pound: Benzo<b■fluoranthene Mumper: 205-99-2

Ion 252.00: 115*4198 neignt: 5076*40

4.8-

4.5-

4.2-

3.9-

2.4-

2.1-

2 . 9-

; .5-

1 .2-

0.9-

0.6-

0.0-------21.20 21. 30 21.35 21.40 21.45 21.50 21.55 21.60 21.65 21.70 21.75 21.80 21 .£5 21.90 21.95 22.00 22.05 22.10 22.15

____________________________________________________________ Min _______________________________________________________________________________

Ion 253.00: Area: 252200 Height: 111202

f«j

55 21 .90 21.95

i4

5.0

I

I

1.90 21.85 21 .90 21.95 22.00 22.05 22.10 22.15

I

Data F : i ? : . rhem-'S:i7 2'noh4 . i /DF020310064 . p.-'hi Injection Date: 1 0-M-F.-2002 14; 16 Instrument: 5?72hp6J.i Client Sample ID: 5STD090

Impound : Benzo < 5 ' py ne^

FS NurnDf': 50-32-6

10064 . d

Ion 2o2.00: Area: 1040333 Height: 399805

1 .2-

0 4 •

Ion 253.00: wrea: 224399 Height: 85064

3.5-

5 . >j

.60 ' .80

I

:5 22.40 22.45 22.50 22.55 22.60 22.65 22.7

527

i

usta File: ''chem/5972hp64 . 1 .'DF020310064 . b/HG0203 10h64 . dInjection Date: i0-MwF>2002 14:16Instrument: 597-2hpb4 . iClient Sample ID: S3TD080

impound WS Numb'

Indeno : 193-

a)pu rene

1 .;

Ion 236.00: Area: 328107 Height: 173577

cn >

1 .4-

1 . 3

1. U-

55 24.60 24.65 24 . “V. 24.75 24.00 24.85 24.90 24.95 25'.00 25.05 25.10 25.15 25.20 25.25 25.30 25.35 25.40 25.45 25.50;____ ______ _____ __________ ____ ___ M 1 r.__________ __________________________ _____________ ______


!

•n

'5.5

\

52o

25.4 25.5

Data File: /chem/5972hp64.i/DF020310A64 .b/HJ020310AC4 . d

Date : 10-MAR-2002 let*'/?

Cl ient ID: SSTDlcO Instrument: 5972hp64* i :.nSample Info: C\JVolume Injected <uL>: lt0 Operator: 2319 ldColumn phase: RTX-5 Column diameter: 0.32

(xlO-

Data File: /chem75372hp64.i/DF020310A€.4,b/HJ020310AC4.d

Date : 10-MAR-2002 1C; 03

Client ID: SSTD120

Sample Info:


Column phase; RTX-5

Instrument: 5972hpC4.i

Operator: 2313


4.1-

4.0- ;

3.9-:

3.8- i3.7- 1

3.6- i3.5- i

3.4- :3.3- j

3.2- :

3*1-1

3.OH2.9- 1

2.8- i

2.7- ;

2.6- i2.5- j

2.4- i

2.3- ; 2.2-!

■f 2.1-

2.OH

1.9- :

^ 1.8-;

1.7-1.6- i

1.5-1.4- 1

1.3- :

1.2-;

1.1- j

1.0-j

0.9H

0.8H

0.7-:

o.6::o.c-i6.4- ;

0.3-i

0.2-

/chem/5972hp64.i/DF020310A64.b/HJ020310A64.d (Part 2 of 2>

17 18 19

b3U

Data File: /chem/5972hpb4 . i/DF0203 10A64 . b/'H J02 0 3 10A64 . dReport D|ate : ll-Mar-2030 14:32

CompuChem

Data file Lab Smp Id Inj Datei Operator Smp Info Misc Info

Semivolatile Report /chem/5972hp64.i/DF020310A64 SSTD12010 -MAR-2002 16:09 2319

CommentMethod /chem/5972Meth Date Cal Date' Als bottle Dil Factor Integrator Target Vers

11-Mar- 2 03 1C-MAR-200 51 . 00000 HP RTE on: 3.50

hp6 4 0 14 2 16

Processing Host : emstein

i/DF020310A64 32 frankson 09

SW-846 Method 8270C .b/HJ020310A64.d Client Smp ID: SSTD120

Inst ID: 5972hp64.i

,b/8270Cv6.m Quant Type: ISTDCal File: HJ020310A64.d Calibration Sample, Level


5

Concentration

Name

Formula: Amt

Value

* DF * Vt/(Vo * Vi)

Description

* CpndVariable

DF 1.00000 Dilution FactorVt, 1000.00000 Volume of final extract (uL)

4b Vo’ 1000.00000 Volume of sample extracted (mL)w Vi | 1 . 00000 Volume injected (uL)


: 93557

■',292 4 5

■ 25 32 l

235222

-14S44

CAL-AMT

{ NG«

ON-COI,

( NG)

4 0.000G

4 0 . COCO

40.00‘-

4 0 . CO"; .'

. oc

40 . 0000

12 0 . 0 00 113.5

120 . 000 115.4

120.0C0 117.1

120 000 11 G . 3

i o c .ooo 115.2

12 J . 00 0 108.1

1 2 C . 0 0 C 11 9 . G

t J o o 115 . 5

■:A

I

531

$

Data File: /chem/5972hp64.i/DF020310A64.b/HJ020310A64.dReport Eiate : ll-Mar-2030 14:32

Compounds MASS

15 Benzaidenyde 77

16 Phenol 94

17 Bis:2-chloroethyl)ether S3

18 2-Chlorophenol 128

19 1.3 - Dichlorobenzene 146

20 1.4-Dichlorobenzene 146

21 Benzyl alcohol 10S

22 1.2-D:chiorobenzene 146

23 2-Methyipnenol 108

2 4 2,2' -oxycis ; 1 -Chloropropsne) 45

25 Acetophenone 105

26 3-Methylphenoi 10S

27 4-Metnylphencl 108

28 N - N11roso-dN-propylamine io

25 Hexachioroetbane 117

3G Nitrobenzene

3 1 Iscpnoror.e =2

AMOUNTS

CAL-AMT ON-COL

RT EXP RT REL RT RESPONSE ( NG) ( NG) SIMILARITY

7.642 7.642 : C.924 } 266817 120.000 115.8 9794

7 . 777 7.777 '0.54 1) 459392 120.000 1.1 7.5

7 . 912 7 912 (0.957) 313182 120.000 115.5

7.957 7 997 (0.967) 431539 120 000 11 r . 8 56 8 6

8 .217 8.217 (0.954) 499684 120.000 117 . 2

8 . 284 3.284 (1.002; 455146

oooo113 . 9

8.470 8.470 (1.025) 255545 120.000 110.3

8.572 6 . 572 (1.037; 484421 120.000 117.0

■'.539 9 .539 :i.045) 375924 120.000 118 .8

.■3.673 S . 6 7 3 (1.049) 577559 120.000 117 . 2 9110

8.876 8.876 (1.074) 536248 12 C.000 117.6 8803

0 . 642 8.842 (1.070) 405298 120.000 117.8

8.842 8 . 842 (1.070) 405298 120.000 117.8

8 . t 9 ' 8 . 893 (1.076) 255772 120.000 117.2 9171

a 3 -i 9.011 ■; 1 . 0 9 0 ) 254226 120.000 116.7 9522

9 1 3 C 9.130 10.900) 412249 120.000 112.9 9696

9.451 9.451 (0.532) 520376 120.000 113.7 94 36

9 6 03 r . s 0 3 iO.547} 264 942 120.000 115.1 8 4 6 6

5 5 0 3 9 . 603 ■0.947: 391585 120.000 114.6 7536 [

9.706 5.755 ■0 962' 438405 120.0C0 113 . 9 9509

-. 54: 5 . 34 : : o. 98 0■ 412119 12C.C0C 115.9

0 . '70 i . ; n 6 ■■0.993) 471217 120.000 114.9

■; 17 10.175 ■' 1 . 0 0 3 ■ 1722036 120.000 112.0 9714

0.262 10.262 . 012) 567085 120.000 114 . 1 S255

0 . A l i 10.415 .1.027: 325758 120 . OOC 115.0 9365

0 7 10.736 .1.358) 140902 120.000 114.6 9716

0.93 5 1 0 9 3 5 ;i.Q73) ■ 451013 120.000 113.6 9806

2 2- 11.226 !1.107) 383265 120.000 113 . 7

1 . 4 1: 11.412 (i.125; 341198 120.000 114.6

1 5 5- 11.5 9 3 ! 0 . 881 ) 360792 120.000 117.7 9162

1 .751 11 .750 10 .692) 351806 120.CC0 113.5

i . 5 : l 11.635 ■0.595; 378722 120.000 114 . 5

2 . 0 1 : 12 071 ip yj; 1027207 120.000 113.6 7575

:.:: i 12 12 2 ‘0.320) 865773 120.000 112.6

2 J 7 1 Z. ■■:. :• 3 ■-:.- 325632 120 . 000 116.2 9 3 2 -■■

2 . ■ - 12.6s.' 3. 1069125 120.000 113.2 9506

-. r-« 11.647 i i* a"; 2 CBS 11 :2C.000 117.3 84 7 V

i. - -• 1 2 . :i -7 r. \ 2J22751 125.000 112.3 9557

3. •27905 120.000 14 9.0 be?-:

::i 1 '• 2 2 l ' 1 . ■ 7.4 ' 1319556 i:■■■■. .ooc !l!.i

: 1 : . 7 7 3 ;l too. : 1 C 3 1 6 6 0 :J . 0 U 0 6 3 1 . ’•)

2 202770 1 7: ■ j . OOC 119.7 Sir 3

-• 7 -. 3 1.72". 4 4 5 3 1 0 15.0 . 000 116." 3 1 5 1

:. 4: : ■ . 4r-1 -;.: 1375412 12 0.000 112. j i ■ jn

:■ .T ' 77.- • ■' c 4 1 2 7 c 2 1 4 120 . 000 114.2 2 0 1

I . .1 4 ■. 1 . :) 6 4 ; 59-739 120.000 119. 6 0

•; ' • C r 1 -J 12 0 . OOC If: . 3 v 5 6 4

Data File: /chem/5972hp64.i/DF020310A64.b/HJ020310A64.dReport Date: ll-Mar-2030 14:32

AMOUNTS

1 s:g 'vAl - AM 1 ON-COL

Compounds ; MASS P.T ryp py PEL PT .RESPONSE : ng) { NG) SIMILARITY

o «: l.} B 14 117 14 . 117 :1.372- 343642 120.000 117. 3 29

c 3 6 . 6 - 2it.: t ro- 2 -T.er. hy 1 phene’ 1 ? 6 14 .18 5 14 1 S E • 0 . 9 16 • 315645 1 2 0 C 0 C 120.9 0

5-i N-Ninrosedlpheny1 amine 14 .215 14.215 (C.915 ) 762705 120.000 113.1 •; ■„ • 2

65 1,2-DiphenyIhydrazine 77 14 2 6 5 14.26? (1.083) 1255476 120.000 111 . 5 S 9 9 9

o 6 6 -Bromcpnenyl-pnenylecher 26 3 14 . 777 14 777 (0.954) 3 7IQS 120 000 .111.1 c s; 3

6 7 Hexachlorobenzene 286 15.047 15.047 (0.972) 447461 120.000 110.4 8 5 90

6 5 Atrazir.e 2 C 0 15.03 r 15.030 ! 0 . 5 7 1) 34 C 6?9 120.000 1 ■9 . 9 94 0 9

6 9 ? e r. c a c h. 1 o r c p h e r. o 1 ■HS 15.284 15.284 (0.987) 323286 120.000 115.1 8 8':..

7'} Phenar.ihrer.e 1 7 £ 15 . 520 15.520 (1.002) 24 911 “4 120.000 107 . 5

7; Ancnracene i 78 15 . 588 15.589 i 1 . 0 0 7 ) 2483918 120.000 106.3

7 2 Ca rba zo 2 e 16 7 15.908 15.80S (1.021) 1733802 120.000 111.0 9542

“U Di * n - bdeyIpht ha laze ■ 4 9 16.230 ■ 15.23 0 (1.043) 2514493 120.000 10 8. 1 9 6 6 6

P1 j o r 3 n c h e r. e 17.279 17.279 ! 1 . 116) 2942800 120.000 109.8

't Sens: z:r.e : 4 17.431 17.431 1 C . 8 7 3 '■ 1930020 240.000 228.2 8725

76 Pyrene , 2C2 1 7 701 17.701 :0.887) 3096955 120.000 109.6

11 Bu z y 1 be r zy: p.nz ha laze 14 9 15.917 16.917 ( 0.9421 1279313 120.000 110 . 3 9664

’t 1 J 2 5 2 19.643 s : 0.994. 913695 120.000 112.0 7906

ois -2 • e-.nyir.exy: J Pnzha laze 19.795 1 9 79? • 0.992! 1914934 120.000 111.5 9151

B e r. z ?. a a r. z m a c e n e 226 19.935 15.983 ■0.993: 2894006 120.000 109 .4

:'••• • 2 2r. 2 0 01 £ 21 Olr. (1.003) 2676624 120.000 108 6

14 9 2 0 . "• 7 8 2 0 77 l ; 0 . 9 2 5 ) 2051396 120.000 115 . 1

: Benzc c ■ : in: rant ner.e 2^-7 21.705 31. 7:: 5 [0.967; 2075039 120.000 122 . G (

-> 4 3tr.:;,k';:.»rjr,:h{w 25 2 21.755 21.739 •0.969) 1580562 120.000 104.6

Btnzz a py : £ 12 . 5 5 : ■ 0.9 95' 154 133 5 120.000 114.5Inder.o} : . 2 . ' r..i. pyrene

7 •. 5 ■: 2 5. ?5 6 ••1.116) 1112109 120 000 115.5 0 :

- ,, .. . > •; : “) c i C. P 1C •- ^; ■ • - i ; 1 1352076 120 000 8 367

9 315- - o : p-rv. -r::-.- j ~! :■ 2 t . r r. 4 2 4 ... : 4 j 1410258 120 . 000 115.3

QC FlaaiLegend i

M - Compound response manually integrated.H - Operator selected an alternate compound hit

i

i

53 J

Data Tila: .•'•ihem/5972hp64. 1 /DF020310A6- . p/H J0203 10964 . d I r,j ec 11 on [lata: iO-MhR-20C'2 16:09 Instrument: 5972hp64. 1

21ient Sample jp: 55^2120

Impound: 2.4,Is Number: 11

TriprnmophercI

I On '9.60 area 343433

a1

T

Height '44320

1.6-

1 . -J-lPo 1.2-

1.0-'

0.3-

0. a-

14.00 id.Of. id.:0 Id.15 1d.20 Id.25 14.30 14.35 14.40 id.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.85 14.90 14.95 ■

___________________________________________________________Min____________________________________________________Ion 332.00: area: 0 height: 0

' I

CD

14.45 Id.50 14.55 14.60 14.65 14.70 14.75 14.80 14.05 14.90 14.53

5^:a. JO ;d.~6 1 a . Jp I a. 50 14.55 14.60 1*4.65 14.70 14.75 14.30 14.65 14.90 14.95

:031C'w64.nData- File: .'cnerr- 59^21'o64 . 1 ■'

Injection Oat e: 1 0-M4R-2002Instrument; 5972hpo4.iClient Sample ID: 58TD120

mpound:5 Number

4-Dimethuionenol105-67-9'

nli

2.0

1.8-

1 . 6

1 .4-

.b-i.o--H.-02

Ion 122.00: ^rea: 391585 Height: 200158

okD

■T>

1.0

0.4-

9.35 9.-10 9.45 9.50 9.55 9.60 9.65 9.70 9.75 9.80 9.85 9.90 9.95 10.00 10.05

______________________________________ Min______________________________________________________________________ _______________Ion 107.00: Hrea: 229419 Heignt: 229419

rciO

O’-

1 .8

I|

I

9.0 3 9.70 9.75 9 . SO 9.85 9.90 9.95 1 0.00 10.05

Ion IC'I.I'O: wea: I '-66: 9 Mei*nt: 106819

b3b

9.90 9.9c. 1 0.00 10.0580 9.95

Data Fjie: ,'cHem/5972hp64. l ••'DF020310h64 . b/H J' Injection Date: iO-mhR-2002 16:0?Instrument: 5972np6J. :Client Sample ID: SSTD120

pound: 4-rnloropher>ul-phpnyleth~'rS Number: 7005-72-3

'0310*64. d

3.9-

3.6-

3.3-

3.0-

Ion 204.00: Area: 593738 Height: 412495

O

2.1-

1.8

1 .5

1.2

i*i a..’

0 n'

U. :■

.'i n... ____

.65 13. .'0 13.35 13.80 13.85 13.90 13.95 1- .00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50i

M i r ____________________________________________

Ion 206.00: nrea: Height: 0

I! 4 1 4 . n

53b

1 J.1 14.2 14.3 14.4 14.5

I

Lat 5 riie: 'cner, 5'r’. i -'■ 731Injection Date: i0-MwF:-2002 lb:0911*,« t rument : 5?72hp64. :Client Sample ID: 55TD120

. c-mCOI'OCIO^SJ.c

pound : - . 6-Din i r no-2-methy lpheno 1 S Number: 534-52-1

Ion 198.00: Orea: 319645 Height: 230920

$

1.9-

1 . 4

Ii

i

1 . 2-

1.0-

i j . 4 -

n. : •

l j 13.85 90 95 1 00 14.Q5 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65

_______________________M i n______________ _____________________________________1 an 51.00: Hrea: 0 Haight: 0

l

14.35 14.40 14.45 14.50 14.55 14.60 14.6-5

I

l

i

l14.25 14 :5 14.40 14.45 14.50 14.55 14.60 14.6514

Data File: /cnem/5972hp64.i/DFiInjection Date: IO-MhP-2002 16Instrument: 5972hp64.1Client Sample ID: S5T0120

pound:Mumper

Benzo '• b ) F luoranthene: 205-99-2

'031iQ

iJ . b/HJ020310m64 . d

| Ion 252.00: drea: ^0750j>9 Height: 629376

i6.0J

o?7 5- o

• T 1."•J

6.5-

6.0

5.5- ( ' ■■

5.0: . ■

in 4.5-

' 4.0 - ;

~ 3.5-: !

i7 |‘|.

2 5- i2.0- ! 1

1.5- ‘

0.5

21.25 2: . 30 2i .35 21.40 21.45 21.50 21.55 21.60 21.65 21.70 21.75 21 .SO 21.05 21.90 21^95 22.00 22.05 221 10 221 15

_____________________ M i n_________________________________________________________________Ion 253.00: jr-ea: 454365 Heignt: 138250

ip

1 . d

1 . 6

: 1

S5 21 . "0 21 . 75 2! . ?0 21 .85 21.90 21.95 22.00 22.05 22.10 22.15

>1; r_______________________________________________________________________________________________

II 1:01 ^ H r l fcn t; 56489

■X:

53 o

15 21.90 21.35 2;. 00 22.05 22.10 22.15

pound: Indeno<1.2.3-cd)pyrene Mumper: 193-39-5

Data File: /chem/5972hp64 . i .'BF02031 0h64 . b/H J020310064 . dInjection Date: 10-M£R“2002 16:09Instrument: 5972ho64.1Client Sample ID: S5TD120

! Ion 276.00: Area: 1112109 Height: 240268

<o2 4-' ID

o

' LP- . - - t • f.J

1.0-

1 . 4-ll"O 1.2 ■

1.0-

0.8-'

0.6-

i J . 4 •

0.0------24.55 24.60 24.65 24 . tyj 24.75 24.80 24.85 24.90 24.95 25.00 25.05 25.10 25 ! 15 25 ! 20 25.25 25.30 25.35 25.40 25.45 25.50

Min ___________________________lor. 138.00: 4rea: Helcht:

'5.2 25 4 2b.5

o4l>

560-

520

400

280

5325.4 25.5

LG

Data File: ^chem/5972hr ' 4 . i/DF020310A64 .b/HH0203K'A£.4 .d

Date : iO-HAR-200.2 1-1; 55

Client ID: SSTD160 Instrument: 5972hpb4.i

Sample Info:

Volume Injected (uL>: 1.0 Operator: 2319


/chem/5972hpb4.iXDF020310A64.b/HH020310Ab4*d (Part 1 of 2)

4.6-

4.4-

1-0

4.2-

4.0-

3.8-

3.6-

Pk^nar.thr^rie-dlO

Data File: r'chem/5972hp64, i /DF020310A64 ,b/HH020310A64 .d

Date : 10-MAR-2002 14:55

Client ID: SSTD160

Sample Info:

Volume Injected CuLl: 1.0

Column phase: RTX-5


Operator: 2319


4.7-

4.6 4.5

4.4

4.3-:4.2- |

4.1

4.0 3.9

3.3- |

3.7

3.6-

3.5

3.4

■? ~2

3.2

3,1-i

2* to2.5

2.4

0 ~2

2.1

2. 0 1.‘?

1.3

1,71 .to

1.5

1.4

1.3

1.2

1.1

1.0

0.9

0.4

to. £ -0. l

/chett/5972hp£4. i/BF020310A64.b/HH<>20310A64.d (Part 2 of 2)

U tAj -I

l 16 17

■ 'J

18

aj -J L-----

'vf

1-0

)i

19

Data File: /chem/5972hp64.i/DF020310A64.b/HH020310A64.dReport Date: ll-Mar-2030 14:32

CompuChem

Data file Lab Smp Id Inj Date Operator Smp Info Misc Info Comment 'Method Meth Date Cal Date Als bottle Dil Factor Integrator Target Version: Processing Host:

Semivolatile Report SW-846 Method 8270C /chem/5972hp64.i/DF020310A64.b/HH020310A64.d SSTD160 Client Smp ID: SSTD16010-MAR- 2 0 0 2 14:552319 Inst ID: 5972hp64.i

/chem/5972hp64.i/DF020310A64.b/8270Cv6.m

ll-Mar-2030 14:32 frankson Quant Type: ISTD10-MAR- 2 0 0 2 14:55 Cal File: HH020310AS4.d3 Calibration Sample, Level:1.00000

HP RTE Compound Sublist: all.sub3 . 50einstem



DFVt

Vc

Vi

1.00000

1000.000001000.000001.00000



AMOUNTS

7 DAM 7 7 i _• CAL - AMT ON-COL

MASS Z-r ~ A ? 5 Z L .-. T RESPONSE : ( NG) SIMILARITY

- 2 ■■ " - .oo,a 109005 4 0.0 C 0 0

11.: •. : • • • u'.' ‘ 426344 j. o ocoo

• ; - j - : : . r.:; . 3 0 3 5 9 6 40 . C 000

=■ ■ 4 - ■ - 1 -.4 1 . . . C, . 632194 40.C 000

r : y -• :;' i.;:; 90706 5 40.1 0 0 0

22 . . • 220574 4 0.2 000

. . 251590 16.' . 000 159 . 4

.. 994203 15 . 000 157 . 2

. ■ : ■ ■ V ■■ - 702774 ic. 0 0 0 16 7. 0

■-■I.:-.:!- . : .. -- . . - 7 • 1455342 0 0 0 152 .7

-.4 ; ■ - 437753 .60. 000 151.3

. _ ... -■■■ . ■ ,05. 2 1 6 o 0 6 7 15 0 ooc 150 . 1

.; ;• 4 ; 4 - ■; =i 5, . 1 5 9 6 6 7 ] 6 C coo 15 7.-' 3 920

- ;■ •• <4 92 35 160 0 0 161. 0 94 95

Data File: /’chem/5972hp64.1/DF020310A64.b/HH020310A64.dReport Date: ll-Mar-2030 14:32

AMOUNTS

QUANT STG CAL-AMT ON-COL

Compounds MASS RT EM? RT Rs.L RT RESPONSE ( NG) ( NG) SIMILARITY

- ~ i r. 2 ci * 'i -f r. v " £• 7 7 7.656 7.353 (0.926' 334400 160.000 151 . 0 9390

>: Pher.ol 54 7.777 7.777 (0.941! 579549 160 000 154 . 1

5 1 7.512 7 . 512 0 . 957! 420937 160 000 159.9

16 2 - Cr.1 Drr.-pher.D ! 126 S . 0 1 3 3.012 ; r, 9 o o ;■ 563929 160 000 15 5.2 8 9 C 7

15 1, 3 - Ci rhlo-cb-nzer.e 14 5 3.216 5.216 (0.994) 6337Q5 160.000 156 . 3

2 0 1.4-Dicr.:orobenzene i 4 n 8.234 5 .234 (1 .002) 634701 160.000 154 . 6

2 1 Her. zyl alcohol 1 0 5 3.470 3 . 4 7 C (1.025) 326967 160.000 156 . 2

14 5 3.571 5.571 (1.037) 640709 16C.000 158 . 6

23 2-yetbylph-Dc; 10S 8.635 9.63? ; 1 . 04 5) 5 C 034 9 160.C00 163.0 (A)

24 2,2'- : s • 1 - Zr. :c repropane) 4 3 8.673 ?. . r 7 3 (1.04?) 77651C 160.0C0 160.6 9096(A)

-i ? Act; Dphe.po.pf 2 Q c 3 976 9.576 (1.074: 699933 160.000 155.1 9101

26 2 -MecnyIchenc 1 106 3 542 3 . 342 (1.0701 525099 160.000 157.2

2 ■■ -t ~ >‘er. ny . pher.o; 103 6.342 0.342 ( 1 . 070: 525099 1 6 0.0 C 0 157.2

a = N -.. ‘ 1 r. 5 r ■ d . - ,'py - a ("■ i 7 Z -07 4.992 '1.076; 338968 16C . 000 161.6 9 9 2 7 (A:

2 t HcXjT. '/ ;■ I — t to*.-- 1 1 n r 3 11 1.1:. 1 090 1 327077 160.000 15 5.2 94 92

: ::.-vcr-E.-..'e:-.- -.144 c. :• o o ■ 5 £ 1S 5 ~ 1 6 C . 0 0 C 15 7.1 9:; 3

- Isz-pr. r2 1 4 5 9 46" C . 9 3 0 . 1100836 160.000 157.6 94 9 9

1-1 2 -.‘.'iii'Dor'.er.t 3. ; :y 9 . 5 j 3 il . ? 4 5 ; 343734 160.000 156 . 1 8 5 1 4

2 4 - Di---:-:. r.y . pp--:- l 12 2 4.615 :. 94 7 ■ 514972 160.000 157.4 6 6 2 6

i4 Els 2-id . - i-'.-er.n-xy- ?.75 = 7 7 = = '0.960' 630469 160.000 154 . G 9 54 2

ir. ■: 161 2 ■ '34 : 5.-41 0.973- 541196 160.000 156 . 0

:• is: 10.074 : ; 7 4 (0.992: 603114 160.000 154 . 2

: ■ Na pr.: r.a .. -.-r.-z 126 . 177 12 177 . 1 . 002, 227HS7 160.000 154 . 7 974 3

| = 12*7 :o.23: 1 ‘ . 262 1.010) 743327 160.000 155.2 826”

r a:'-.. 2 2 5 10.414 1 0 4:4 11 025' 422026 160.000 154 . V 936?

i.j 10.752 10.7 5 2 ( 1 .056) 194337 160.000 157.8 95 95

- ■■■■■=•■• ■ . : r. 7 10.555 11 . 155 (1 0 7 p} 595061 160.000 155.9 897''.

■■I 2 142 11 2 2 6 11 2 2-. 1 . 10 5) 1164006 150 . 000 156.5

: ■ : - . - 11 4 12 :1 ■ 4 1 2 •. i - 1 C 9 502 0 1 6 0 . 0 0 0 15 3.7

11 30r ii • - • l q i. ; 475256 160 . 000 157 .0 9 G 0 i

;; -7V : y . : *. • 7 ~ 1 11 ’3 :: 3 921 470974 160.000 156.0

3-. . 1-3 * * 7 J 4 . . " .’ -1 : 399. 499943 160 . 00G 155.2

■■ ■■ ■ -S:- . 3 4 1 2 . :• 7 i i" 71 •: .• i_ 1334420 1 6 0 . 0 G C 15 3.8. •; r. -j q

■ - :: : nap . .a-: . 21 •2.122 i;. ::i •: • '? 2 •’ • 1154344 160.000 15 5.1

- '••• 33 i:. 2 = - 1 2 :: 5 •. 0 . ? 2 ■ ' 425580 250.00? 156 . 7 94 5 5

6 : y •••--■•; b.v ! -i: • - ^ c 13 -30 •: ? 41 ■■ 13 9 0 9 1 2 150 . 000 154 . ? 3 5 57

: - - O' . o 4 '711 32 1 6 G . G 0 C 15 7.0 7053

.y:- 12. :• i • 12 .••:; •; 2 160.09? 151.2 -723

-.3- :• ■■ . -79.' 4 z j 2 0 4 1 0 0 . 0 0 2 9 0.2 7-1 = 3 ' A ■

• 2. . ■■■■4 150153] 150 900 147.2 >4 7 :

i : :. ~ i a ■ •1 2 5 7 7 300 . O00 5:7. ;• (A)

1i •.::» 1 2 25556: i 6 0 . 0 C C 154 7 7 51 7

. .027. - “ 1 ^ 'j ■> 1 6 0 . 0 0 C :Si 0 2 0 7 ?■Ai

: t 1 ::■■■■■■:■ ; : 333 1 ■ 4 ■ 1 1756591 150.000 155.3 0 015

■ -- 1 ■■ 5 4 , 15 3 0 9: 16 0.0 c 155.7 9 3 8 9

■■ - 2 •; : 4 : i' ' : ■' 4 4 '■ 754740 1 6 0 . 9 C C 152 . 1 0 '.Ml

1 ■ 1 4 14 6 1 4 • 1 . 06 5■ 1945435 16 0 0 C 0 15) .5 7 355

\$0

54 j

t

Data File: /chem/5972hp64.i/DF020310A64.b/HH020310A64.dReport Date: ll-Mar-2030 14:32

TUAN. 5IG CAL-AMT ON-COL

Compounds mass RT EXP RT REL RT RESPONSE ( NGi t NG) SIMILARITY

62 4-N i zrcar. i 1 me 13 8 14.133 14.133 (1.073! 460576 160.000 161.3 9 2 51

6 3 4 , 6 - Ji n: z ro - 2 - mer r.y 1 phene ] 15? 14.154 14 .134 : 0 . 916) 4 0 4 6 0 3 160.000 155 . 9 0

54 N-Nitrpsodiphenylamine 16 5 14.215 14 .218 (0.918) 988884 160.000 154.4 8009

65 1,2 -Oipher.yih.ydrazine 77 14 .269 14.269 (1.083) 1651424 160.000 1:34 . 7 9175

5 6 4 -3romophen>': -pheny 1 ether 24 c 14.775 14 . 776 (C.954 ) 484539 160 0C0 IBS 4 8963

6 7 Hexach:crober.zene 284 15.045 15.C46 (0.972) 566716 160.000 15Z . 3 3 S 14

6 i Atrazme 200 15.030 15.030 *0.971) 415397 160.000 14 7.0 9384

6 5 Pencach I oropher.c i 266 15.2S3 15.283 (0.937) 420499 160.000 155 . 6 9010

7 c ? h e n a r. t h v e n e 176 15.520 15 . 520 !1.0C2} 3186075 16C.000 151.8

71 Ant h facer.e 173 15 . 587 IS.587 ! 1.007) 3115701 160.000 14 8.0

72 Carcazcle 167 15.807 15 . 3 0 7 i:.C2i) ■2186711 160.000 150. “ 9576

7 3 2 i - n - bury 1 phz La 1 at e 14 9 16.230 16.230 (1.043) 3194338 160.000 149.9 9 6 9 8

74 FI uoranmenc 2 02 17.27? 17.273 (1.116) 3763182 160.000 152 . 5

■b Benz:::- 1 34 17 .447 : 7 . 4 4 7 '0.374: 2467765 320.000 312.1 6234

u:ir 2 U 2 • i i r - 17.701 . 0 . 6 8 7 :■ 3362210 160.000 149 . 3

7" 3u t v 1 r?e n z y m m. n a : a z e 14 r 15.834 16.334 (0.543) 1672953 160.000 152.4 9098

m : . : cr. I orezenz : a ■ ne 25 2 19.348 ;5.348 (0.994) 1152883 160.000 152 . 1 8036

7[- ms 2-ezn.-m.-rxy. Pr.r.n;.. a - 14 9 19.797 15.797 0 . 992 ) 2379996 160.000 149.7 9261

4.: Benz: a. an: nr men.- ?■:. 1 3 v j 2 ' I; . 9 9 6 : 3673446 160.000 149.9

m Z:-mys-jnv _2c Z Z i 1 7- 21.01“ .1 0 C 3 ' 3372976 16 0. 300 14 7.9

n - ccm mm :.a . m t 2 i - 7 .; Z V 7 7 4 . 0 92 5: 2571762 160 . 000 14 5. 5.

- i nenzo :L mm: mzmm-r 1 5 Z 21 725 Z 1 ’mb •0.968i 2450242 160 . 000 16 1 . S

~4 5-mm: f mm ■ m.Z r.m- 252 1 7 c. j 21.753 • 0.9-59) 2207306 160.000 141.8 i

fc —n. ■) c. 2 7 7 e, p ::.?5= C . 9 9 5 : 1969998 160.000 152.6

f — ^ 2"-' 25.072 25 m2 -’ll 1398885 160.000 153.8 0 (

Cmenzr m n : amm.;-d ;-:m 2 7 6 25.072 2 5.;; 7 ? t:. i) 7) 1686525 160.COO 152.8 5 3 2 3

v. bm.z: u . . ; m-mm e:m 2 7 5 -> c q 11 f. 2 5 . 9 C C -.1.154: 182364 3 160.000 155.4 9213

«>\

QC

M

H

.aq jeaend

Target compound detected but, quantitated amount exceeded maximum amiount .Compound response manually integrated.Operator selected an alternate compound hit.

r

544

[ists File-: / :r.er>'i.,,5':|74.,r,p64 . 1 .'DF 02031 0h6j . t./HH0203l 0A64.0 Ii'i.J'&ct1 O'*' Date: lO-^R-r'X^ 1-5:53 instrument : 5972np64. :Client Sample ID: 53TD160

#pound: 2.4.6-Tr ipromopheno iNumber: 1i8-39-6

?.8-

Ion 329.60: Area: 437753 Height: 298709

ft

1.-5-

1 . 2-

m . q.

0 . 6

0.4-

14.00 14.05 14.;n ;4. ] 0 14.25 14.30 14.35 14.4m 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.05 14.90 14.95 j

Mir, __ ________lor 332.00: Area: -<ei fc'nt : 0

14.55 14.60 1 4.65 14.ro 14.75 14.80 14.83 14.90 14.95

54b4.75 14‘.SO 14.85 1 4 '. 9 ri 14'. 95

1

Data File: .• chem/59''2hp6j . i /DF020310064. b.'HH020310064. dInjection Date: 10-MOR-2002 14:55I nstrument: 5972hp64.iClient Sample ID: SSTD160

Impound : 4-Chloropheny l-pheny 1 ether S Number: 7005-72-3

5.4-

5.1:'

4.8-'

a 5-

Ion 204.00: Prea: 754740 height: 544170

£O

60 13.65 13.70 13.75 l3.SO 13.85 13.90 13.95 14.00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50'____________________________________________ M i n_______________________________________________________ __________ '

Ion 206.00: Onea: 0 Heignt: 0

14.5

11 h=irn' ;

54b14.3 14.4 14.5

261116

Data F 11 * ; /•: hem/59r2hp6- Injection Dale: 10-mwF:-2' Instrument: $972hpn4. 1

Client Sample ID: 5STD161

pouna : 4 . b-D in 11 r-p-2- Numper-: 534-52-1

i /DF 02031On 64. b''HH020310964. d '2 14: So

thylonenol

Ion 198.00: brea: 40*460t*

jheight:

v

1.8-

1 . 6-

ir. 1.4-

1 ■0_.

0.3-

0.6-

0.4-

0.2

13.70 13."8 13.80 13.SS 13.90 13.98 14.00 1-4.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 1

|Mmi'Ion 51.00: Or^a: 0 Height: 0

j . c 3. J- T

1 . O

> 4

I

I

■1-. 6

a

’5 14.00 14.05 14.10 : a.15 14.20 ia.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.05

in’*' 105.00: ---ea. 0 rteipr.t: 0

•j 8'

a

54 1

1-4. 3'5 14.30 14.35 14.40 14.45 14.5'.') 14.55 14.60 14.65

b-'HH02Q31 0h54 . djEtlS Fli~; 'crieF'.-'n'Pri'npn^ . 1 .• DF C!2'j3 1 C'Hn4 . injection Q*te: i0-mhR-2002 14:55InstI'umenr ; 5972hpb4.i Client Sample ID: SSTD160

kmpouna: 13 Humber*

Benro '■ k ) f 1 uoranthene : 207-08-9

9.8

Ion 282.00: Area: 2207506 Heignt: 958219

in

6.5-

6.0-

5.5-

1 4.5-

2 j.ij.

■“ 3.5-

2.5-

1. 0-

■; . ?■

21.28 21 . 30 21.75 21.40 2 1 . 45 21.50 21.55 21.60 21.65 21.70 21 . ?5 21.80 21.85 21.90 21.95 22.00 22.05 22.10 22.15 22.20

Min________________________________________________________________________________________________________________________ __________ __I on 253.00: brea: 478079 heignt: 208519

; ct. . ! m

. 48 .80 21 .55 21 .60 2: . 55 2 • . 21.75 21 .80 21 .85 21.90 21.95 22.00 22.05 22.10 22.15

•xS'

II

54822.10 22.15

t

Data File: .•'cnam/59':'2hp64 Injection Date; lO-MOR-20' Instrument: 5972hp64.l Client Sample ID: SSTDlbO

pound: Mumper

Indenof1 : 195-39

cd

i /OF020 '2 1J:55

pu nene

1 O^i

2 . d-

2.6

2.4-

,4 . b/Hu020310Pb4 .d

Ion 226.00: Hrea: 1496880 Height: 294306

CMr.

in: CM

1 . b-

LTi 1 • 6

S 1.4-'

1.2-

1.0-

0. 6

0.6

4

24.55 24.60 24.65 24 . ~0 24. ?5 24.80 24.85 24.90 24.95 25.00 25.05 25.10 25.15 25.20 25.25 25.30 25.35 25.40 25.45 25.50

H i n________________________________________________________________________________________________ _______ _________________________Ion 138.00: H^ea: 0 Heignt: 0

0 . ?

:5.4 25.3

460

54025.4 ■' 6 5

b. Continuing Calibration Data

(Form VII SV)

If more than one instrument is used, forms shall be arranged in order by instrument. If multiple continuing calibrations from the same instrument are used, they shall be in chronological order.

ti

i

(1) Reconstructed Ion Chromatograms and quantitationreports for all continuing (12-hour) calibrations; Spectra not required

(2) EICPs displaying each manual integration i

i

551

FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY



Instrument ID: 5972HP60 Calibration Date: 03/12/02 Time: 1017

'Lab File ID: HG020312A60 Init. Calib. Date(s): 03/03/02 03/03/02

Init. Calib. Times: 1401 1720

GC Column: J&W DB-5.625 ID: 0.32 (mm)

COMPOU ID

|___ |RRF8 0.0 00|

RRF OR ORJ AMOUNT |AMOUNT

1 - 1

1

MIN |

RRF1

1

%D OR I

%DRIFT1

MAX %D OR

%DRIFT

CURV

TYPE

Phenol 1 1 . 3820000|1.2008222| 0.01 | -13.11| 20.00j AVRG

Bis ( 2 -chiloroethyl) ether | 0.9520000 0 . 9599782 0.01 I 0.84 50.00j AVRG

2-Chlorophenol 1 . 0880000 1.1040369 0.01 1.47 | 50.00 AVRG

1,3-Dichlorobenzene 1.4910000 1 . 5304621| 0.01 2.65 50.00 | AVRG

1,4 -Dichlorobenzene | 1.4860000 1.6051513 0.01 8.02 20.00 AVRG

1,2-Dichlorobenzene | 1.4310000|1.4978057| 0.01 j4.67 | 50.00

j AVRG

2-Methylphenol 0.8830000 0.8964040| 0.01 j1.52 50.00

j AVRG

2,2'-oxybis(1 -Chloropropane)

4-Methylphenol

j1.3580000|1.3558819 j

1 . 1220000|1.05980480.010.01 1

-0.16 -5.54 |

50.00

50.00

AVRG

AVRG

N-Nitroso-di- W- propylamine

Hexachioroethane

0.8140000 0.7984051 | 0.6340000 j0.7273466

0.050.01 j

-1.92 14.72 j

50.00

50.00

| AVRG j AVRG

Hit roben :ene 0.49600000.4643285 0.01 -6.38 50.00 AVRG

Jsophorone | 0 . 7810000 | 0.7513808 0.01 -3.79 50.00 AVRGB-Nitrophenol jo . 2450000 | 0.2498400

0.01 ■ 1.98 | 20.00 AVRGW, 4 - Dimethylphenol 0.2970000 0.2919625 j 0.01 j

-1.70] 50.00j AVRG

Eis ( 2 -chloroethoxy1 methane

2 , 4 - Dichiorophenol

[ 0.4700000| 0 . 4839004

0.4380000 0.4323532

0.01 j

0.01

2.96

-1.29

50.00

20.00

I AVRG

| AVRG

1,2,4-Trichlorobenzene | 0 . 5200000 0.5161232 0.01 -0.74 50.00j AVRG

Naphthalene i 1 . 1890000 1.2196058 0.01 2.57 50.00 AVRG4 - Chloroaniline 0 . 5010000 | 0.4843112 0.01 -3.33 50.00 AVRGHexachiorobutadiene

! 0.4060000 j 0.4212530 j0.01 3.76 20.00 AVRG

4 -Chloro ■ 3-methvlphenoij 0 . 3640000 jo.3220704

0.01 -11.52 20.00 AVRG2 -Methvlijiaphthalene 0.8860000 0 . 9245955 j 0.01 4.36 50.00 AVRGHexachiorocyclopentadiene

2,4,6-Trichlorophencl

0.4600000 0.4811605

[0.440000010.4038658[

0.05 1

0.01 j4.60

-8.21

50.00

20.00

AVRG j AVRG

2 , 4 , 5 - Tn chlorophenol 0.4790000 0.460644 3 0.01 — 3 .83 f 50.00 AVRG2 - Chi oroijiaoh t ha 1 ene 1 . 2400000 | 1 .2204 970 [ 0.01 -1.57 50.00 AVRG2 -Nitroaml me j 0 . 4S30000 j 0 . 4824943 | 0.01 -0.10 50 . 00 AVRGDimethy1phthalate i 1 . 62900 0 Oil. 518 317 4 i 0 . 01 1

-6 . 79 j50.00 AVRG

2 , 6 - D i n l .rotoluene | 0 . 347000010.3333067| 0 . 01 1 -3.95 50 . 00 | AVRG

Acenaphtlv/1 ene i 1 . 9950000 | 1 .8703 961 0.01 -6.24 50 . 00 AVRG3 - Hi t roan 11 me ; 0 . 3 6 9 0 0 0 0 [ 0 . 3 3 7 5 7 0 3 0.01 1 -6.52 50.00 AVRGAcenaphthene j 1 . 1730000 | 1 . 0784801 0.01 -8.06 20.00 | AVRG

2 , 4 - Dm 11 rop henol 0.2170000 | 0 . 1883675 0.05 j- 13 . 19 | 50.00 j AVRG

4-Nitrophenol 0.2960000 | 0.2992935 0.05 1 . 11 j 50.00 | AVRG

2,4- Dim u rotol nene [0. 514000 0(0. 5124825 0.01 -0.30 50 . 00 AVRGDibenzofuran. j2.1S10000l2.1805926| 0.01 -0.02 . 50.00 AVRGDiet hy1pH t ha1 at e ; 1 . 7 6 0 0 0 0 0 1 1 . 6 8 0 0 3 5 7 0.01) -4.54 50.00 AVRG4 -Chlorophenyl- phenyl etherFluorene |

iO. 96000OOjO. 9286261]

1 . 7420000! 1 . 7378112 |

0.01 1

0.01

-3.27 -0.24 |

50.00

50 . 00

| AVRG

j AVRG

J - N i t roan lime i U . d 7 j 0 ij (j L' 0 . 3 6 0 5 9 4 5 j 0.01 -3.06 5 0.00 AVRG^6 - Dim d ro - 2 - methylphenol ‘0.16 6 0 00 0'0.1500552! o. o i!

i

- 9.60 j

i5 0.00 | AVRG

a q e 1 o 'I J

FORM VII sv

b53





Lab File ID: HG020312A60 Init. Calib. Date(s): 03/03/02 03/03/02



RRF80.000

| COMPOUND1

|RRF OR | OR [|AMOUNT j AMOUNT j

1 1 1

MIN |

RRF |

1

%D OR

%DRIFT1

MAX %D OR

%DRIFT

|CURV|

TYPE |

1 ||N-Nitrosodiphenylamine

1 110.5330000 0.4895377|

10.01 I

i-8.15| 20.00

|AVRGj

|4-Bromophenyl-phenylether

IHexachlorobenzene

| 0.300000010.2626789|| 0.3410000 j 0.3108058

0.01 I0.01 j

-12.44|

-8.85|50.00

50.00

|AVRG|

|AVRG|

IPentachlorophenol 0.1000000 0.1101310| 0.0510.13 j

20.00j AVRG|

1Phenanthrene |1.2540000|1.2258290| 0.01 | -2 . 25| 50.00|AVRG j

|Anthracene |1.2630000|1.2439978 | 0.01 | -1.50| 50.00 |AVRG|

| Carbazole 0.9800000|0.9122507 | 0.01-6 . 91j

50.00j AVRG j

iDi-n-butvlphthalate|1.6380000 j1.5921469 j 0.01 1 -2.80| 50.00

j AVRG

|Fluoranthene 1.4490000 1.4257731| 0.01 j -1.60 j20.00 AVRG |

|Pyrene | |1.4350000|1.3502826 | 0.01 j -5.90 j50.00 |AVRG|

|Butylbenzylphthalate |0.7410000 0.6995314 0.01-5.60 j

50.00 |AVRG|

!3,3'-Dichlorobenzidine |0 . 5660000 j 0.5708737 j 0.01 1 0.86 50.00j AVRG j

Lois(2 -ethylhexyl)Phthalate

Knzo (a) anthracene

1 . 0350000|1.1977421|

| 1.4320000 | 1.6669665|

0.01 j

0.01 1

15.72|

16.41[50.00

50.00

j AVRG|

|AVRG j

"hrysene | 1.2900000 1.2586506| 0.01 1 -2.43 50.00 AVRG|Di-n-octvlphthalate | 2.0140000|2.3464786 0.01 I 16.51| 20.00 |AVRG|

I Benzo(b)fluoranthene 1 . 7250000 | 1.7012509| 0.01 1 -1.38| 50.00j AVRG j

! Benzo(k) fluoranthene 1 . 5600000 2 . 0517998 0.01 1 31.52 50.00 AVRG| Benzo(a)pvrene i 1 . 3800000 | 1.5755806 0.01 14.17| 20.00 ] AVRG|Indeno(1J 2,3 -cd)pyrene 1 1 . 4730000 1.7135069| 0.01 1 16 . 33 j

50.00jAVRG|

IDibenzo(a,h)anthracene j1 . 2820000|1.5240366| 0.01 j 18.88 | 50.00jAVRG j

i Benzo(q,A,i)pervlene j1.2410000 j1.4501195|0.01 1 16 . 85 | 50.00 |AVRG|

1

i2 -Fluorophenol j 1 . 2730000 j1.06988950.01 -15.96 50.00

AVRG j

iPhenol - d5 i 1 . 4360000 | 1.3412205| 0 . 01 i -6 . 60 j50.00

|AVRG j

!Nitrobenzene-d5 0 . 5720000 0 . 5583855 0.01 -2.38 50 . 00AVRG j

1 2 - Fluoro&iphenvl | 1 . 5550000 1 . 4480327| 0.01 1 -6.88 50.00 AVRG| 2,4,6 -Tribromophenol | 0 . 3760000|0.3336466 0.01 -11.26 | 50 . 00 | AVRG

! Terphenyl- dll ! 1 . 1100000 | 1 . 0273398| 0 . 01 1 -7.45 50 . 00 AVRG |

page 2 ofFORM VII SV

b5o

CxlO-'fe)

Data File} /chem/5972hp60. i/DF020312A60.b.'HG020312A«>.d

Date } 12-MAR-2002 10:17

Client ID} SSTD080

Sample Info: SSTD080}917



Instrument: 5972hp60. i

Operator: 917

Column, diameter: 0.32

■ J

LOLO

-Phmnanthrmnc-d1

Data File: /chem/5972hp60,i/DF020312A60,b/HG0203i2A60*d

Date : 12-MAR-2002 i0;17

Client ID: SSTD080 Instrument: 5972hp60.i _nSample Info: SSTD080:917 LOVolume Injected <uL): 1*0 Operator; 917 LOColumn phase: J&W DB-5*625 Column diameter: 0.32

Data File: /chem/5972hp60.i/DF020312A60.b/HG020312A60.dReport Date: 12-Mar-2030 10:50

Data file Lab Smp| Id Inj Date Operator Smp Info Misc Info Comment MethodMeth Date Cal Date Als bottle Dil Factor Integrator

CompuChem

Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020312A60.b/HG020312A60.d SSTD080 Client Smp ID: SSTD08012-MAR-2002 10:17917 Inst ID: 5972hp60.iSSTD080:917

/chem/5972hp60.i/DF020312A60.b/8270Cv6.m12-Mar-2030 10:50 mikhael Quant Type: ISTD 03-MAR-2002 17:20 Cal File: HL020303A60.d2 Continuing Calibration Sample1.00000

HP RTE Compound Sublist: all.subTarget Version: 3.50Processing Host: einstein


Description


Cpnd

Name1

Value

iDF 1.00000VtL 1000.00000Vo 1000.00000Vi 1.00000


AMOUNTS

CUANT SIG CAL-AMT ON-COL


' 1 1 , 4 - Dich io t ober.zene - d4 152 9.123 S . 123 (1 . 000) 100945 40.0000

* 2 Naohtha iene*d5 13 6 10.286 10.288 (1 . 000) 295932 40.0000

' 3 Acenapn z her.e • d I C 1 6 4 13.351 13 351 (1.000) 244221 40.0000

* 4 Phenan: 1 18 S 15.973 15.973 (1.000) 476283 40.0000

• 5 Chrvse:: e-d:- 240 20.608 20.408 <1.000) 517505 40.0000

.• n 'ervien - d i 2 264 23.163 23 163 (1 . 000) 375407 40.0000

opheno: 12 6 . 003 4.008 (0.740) 216000 80.0000 67.24

~ 6 Phenoi - dF 9 9 7 . 565 7.565 (0.931) 270779 80.0000 74 . 70

3 9 N11 robe n z e n e - d F 92 9.053^ 9 353

| 0 . 8 8 0 ) 331611 80.0000 78 . 11

cn:phenyl 172 12 156 12.166 (0.911) 7C7280 80.0000 74.49

3 30 14.756 14 755 (1.105) 162967 80.0000 70.92

" : 2 :erpher. 1 - d; 4 244 19.781 19.781 (0.911) 1063307 80.0000 74 . 03

so.: :~.eiby- aiine 42 3.369 3 369 (0.415) 346238 80.0000 91 . 99 8710

:4 ?yi-id:n 7 3 3.403 3.402 (0.4191 ■ 691561 80.0000 132.3 9175

Data Fi|le : /chem/5972hp60 . i/DF020212A60 . b/HG020312A60 . dReport Date: 12-Mar-2030 10:50

Compounds

IB Benzaldenyde

16 Phenol

17 Bis(2-chloroethyl'ether

16 2-Chlorophenol19 1, 3-DJchlorobenzene

20 1, 4-DJchlorobenzene

21 BenzyJ alcohol

I22 1,2-Drchlorobenzene

2 3 2 - Methylphenol

24 2 oxybis(1 -Chloropropane)

25 Acetophenone

26 3-Methylpnenoi

27 4-Methylphenol


29 Hexachloroethane

30 Nitrobenzene

31 Isophorone

32 2-Nitrcpheno1

33 2,4-Dimethylpnenol

34 Bis(2-ch1oroethoxy)methane

35 2,4-DichlorzohenolI

36 1,2,4-Trichlorobenzene

i37 Naphthalene

35 4-Chloroani 1 me 39 HexachJorobutadiene

4u Caprolactam|

41 4 - Ch iorjo - -metny iphenoi

42 2 - Met h\j 1 naphtha 1 ene

4 3 1 - Met hyjlnapht ha 1 ene

4 4 Hexachlorocvc 1 ocer.t ad i eneJ

4 5 2 , 4 , n - .rich 11ropnencl

4 6

48

4 9

52

53

54

65

2,4 , 5 - T-r 1 ch i orophenoi

1,1'-Bipneny1

2 -Chlorcnaphtha 1ene

2 • N i t roar,: 1 : r.eI

0imet hvipntna ; at e

„ -

Acenaoht nyiene

2 -Nit roan:1ine

Acenaphthenei

2,4 -Pin:t roohenc1, ,,■ i.4 -Nit roonenoi, ,_„.j.............. _

Plben:::uran

Diet hvlohtha 1 a t e. i .t - ..or tor.envi • oneny : -

r ' 'r .uorene

ne r

AMOUNTS

QUANT SIG

MASS RT EX? RT REL RT RESPONSE

CAL-AMT

( NG)

ON-COL

( NG)

— —

77 7 . 396 7 396 (0.910) 115126 80.0000 ■ 71.45

94 7 . 599 7 599 (0.935) 242434 80.0000 69.48

93 7.700 7 700 (0.948) 1938 1C 80.0000 80.71

128 7.785 7 785 (0.958) 222894 80.0000 81.20

146 8.021 8 021 (0.988) 308985 80.0000 82.09

146 8 . 157 8 157 (1.004) 324064 80.0000 86.41

108 8 . 377 8 377 (1.031) 131809 80.0000 74.75

146 8.411 8 .411 (1.035) 302392 80.0000 83.76

108 8 . 580 8 580 (1.056) 180975 80.0000 81.23

45 8.597 8.597 (1.058) 273739 80.0000 79.86

105 8.800 8 800 (1.083) 321662 80.0000 80.44

108 ^8 . 834 ' 8 .834 (1.007) 213964 80.0000 . 75.57

1087 8 . 834x 8.834 (1.087) 213964 80.0000 75.57

70 8.817 8.817 (1.085) 161190 80.0000 78.44

117 8 . 969 8.969 (1.104) 146844 80.0000 91.76

77 9.087 9.087 (0.883) 275748 80.0000 74.87

82 9.493-/ 9.493 (0.923) 446218 80.0000 76.94

139 9 . 629 9 . 629 (0.936) 148371 80.0000 81.59

122 9.730 9.730 (0.946) 173306 80.0000 78.58

93 9 .882 9.882 (0.961) 287371 80.0000 82.30

162 10.069 10.069 (0.979) 256759 80.0000 79.02

130 10 187 10.187 (0.990) 306507 80.0000 79.45

128 10.322 10.322 (1 . 003) 724280 80.0000 82.07

127 1 0.424 10.424 (1.013) 287615 80.0000 77.32

225 10 542 10.542 (1.025) 250167 80.0000 82.91113 11 016

11 . 016 (1.071) 56348 SO . 0000 87.62107 11.237 11.287 11 . 097) 191266 80.0000 70.81

142 11.523 11.523 (1.120) 549084 80.0000 83.47

142 11.693 11.693 (1.136) 449345 8 C.0000 84 . 51

237 11.794 11.794 (0.883) 235019 80.0000 83.72

196 12.031 12.031 (0.901) 197265 80.0000 73.37• 196 • 12.116 12.116 ( 0 . 907) 224998 80.0000 76.87154 12.352 12 3 c ? ( 0. 9251 687495 80.0000 77.64162 12.386 12.33': (0.928) 596142 80.0000 78.71

6 5 12.572 12 . 5 f n 94 2 i 471341 160.000 159.8

163 1 J. . 6 i 4 12.594 ! 0 . 9 6 6 1 741610 80.0000 74 . 5516 6 ' ") 3 Q C 1 2 . - ? 5 iC.9T3; 162801 80.0000 76 . 77152 1 ? 114 1 ; ■ 1 4 • :'i o 3 2 913580 80.0000 75 . 0013 6 1 ? . 3 (J •: ■- :• . J 0 . 0 9 6 ) 329767 160.000 146.5

154 13.41b 1 J .415 ' 1 . 3 o 5 ' 525775 80.0000 73.53

194 13.486 : • ■: •' • 1 .010, 460033 400.000 346.915 1 j . 6 z 1 ‘ . T 2 ■ ■ 1 . 0 2 0 ) ■ 292375 160.000 161.6

- ^ c : 3. .'0- : 3 . F 2 6 1 .027; 250318 80.0000 79.70168 13.723 1 3 7 2 3 1.028i 1065093 80.0000 79.99

14? 14 12 ? 14.12? 1.058' 820600 80.0000 76.36204 ^ . t - S’ 14.315 1.072) 453580 80.0000 77.35

16 6 ✓ 14.315' 14 3 15 1 0 7 2' 348820 80.0000 7?.83

SIMILARITY

8667

8893

7957

8233

7256

8949

9080

9068

8615

8607

8686

8940

8894

9286

8717(M)

8726

8605

8524

9183

9285

9474

9589

5427

9178

82 00

8497

9514

9462

726 1

7739

i55/


Compounds

AMOUNTS


MASS RT EXP RT REL RT RESPONSE ( NG) i NG) SIMILARITY

62 4 -Nicroan j. i meI

63 4 , 6 - Dmic.ro • 2 -methyl phenoi

64 N- Nit: rosed i phenyl amine

65 1,2-Diphenyi'nydrazine

66 4-Bromophenyl-phenylether

6 7 Hexachlorobenzene

66 Acrazine I

69 Pentachlorophenol

70 Phenanthrene

71 Anthracene

72 Carbazole

73 Di - r. - butylpheha late

74 Fluoranthene

75 Benzidine76 Pyrene |

77 But ylbenzylphthalate

73 3,3'-Dichlorobenzidine7 9 bis(2 -eJhyIhexy1)Phtha 1 ace

60 Benzo(aJantoracene

91 Chrysene|

92 Di-n-octylphthaiate

P485

Benzo(b) f 1 uo: ar.c her.;

Benzo (k) f luor ar.c hene

Benzo(a:pyrene

Inaeno (!.2, } -~d)pyrene

O', benzo (*a . h : ancnracene Benzo ;a Jr.. : ; cc-rv 1 ere

138 14 . 383 14.383 (1.077) 352259 160.000 155.3

190 14 .433 14 .433 (0.904) 285875 160.000 145.0

16 9 14.535 14.535 (0.910) 466317 SO.0000 73 .47

77 14 .602 14.602 (1.094) 893482 80.0000 83.43

248 15.178 15.178 (0.950) 250219 80.0000 69.96

284 15.296 15.296 (0.958) 296063 00.0000 72.88

200 .15.465 15.465 (0.968) 17940 80.0000 19.68

266 15.651 15.651 (0.900) 209ei4 160.000 176.5

178 16.024 16.024 (1.003) 1167683 80.0000 78.17

178 16.108 16.108 (1.008) 1184990 80.0000 78.80

167 16.396 16.396 (1.026) 868979 80.0000 74 . 50

149 16.988 16.988 (1.064) 1516625 80.0000 77.74

202 18 . 121 18.121 (1.135) 1358143 80.0000 78.69

184 18.341 18 . 341 (0.890) 208629 160.000 61.34

202 18 . 510 18.510 (0.898) 1397556 80.0000 75.28

149 19.610 19.610 (0.952) 724022 80.0000 75.52

252 20.541 20.541 (0.997) 590860 80.0000 80.71

14 9 20.574 20.574 (0.998) 1239675 80.0000 92.58

228 20.593 20.591 (0.999) 1725327 80.0000 93 . 15

228 20.642 20.642 (1.002) 1302716 80.0000 78.04

149 21.556 ' 21 . 556 (0.931) 1761769 80.0000 93 . 19

252 22 . 368 22.368 (0.966) 1277323 80.0000 78.90

252 22.418 22.418 (0.968) 1540520 80.0000 105.2

252 23.044 23.044 (0.995} 1182968 80.0000 91 . 30

276 26.056 26.056 (1.125) 1286525 80.0000 93.05

270 26.107 26.107 (1.127) 1144268 60.0000 95.09

276 25 . 952 26 . 952 (1.164) 1088770 80.0000 93.45

8150

9064

8S77

9460

9312

9343

8571

8887

9047

9229

8561

9116

7095

9546

8729

8845

8014

QC Flag Legend


55S

m

Data File: /chem/5972hp60. i/'DF0203l2A60.b/HG020312A60.d Injection Date: 12-MAR-2002 10:17 Instrument: 5972hp60 . i

lent Sample ID: S5TD0Q0

ipound: 2.4,6-Tribromophenoi Number: il0-79-0

1.0-

0.9-

o. s-;

0.7-

0.6-

0.

0.4-

0.3

0.2

0.1-

0.0-

Ion 329.60: Area: 162967 Height: 100792

IS

14.3 14.4 14.5 14.6 14.? 14.e 14.9 15.0 15.1 15.2

9.5

9.0

8.5

6.0-

7.5-7.0-

6.5

6.0-

5.5-

■ 5.0-

4.5-

4.0-

3.5- .

7.0- '

2.5-

2.0-

1 .5-

1 .0-

0.5-.

0.0 - -

14 .


:5 14 130 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20 I M i n

1 . 4-

1 .3-

1 .2-

1.1-

1.0-

. 9-

. 8-

. 6-

. 5-

. 4-

. 3-

. 1 -

14.25 1-


■J

14.35 14.40 i4 . -?5 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20

: /[Chem/597I!hp60.1/DF02Q31 2A60. b/HG020312h60 .d

Date: 12-MAR-2002 10:17Data file Inject LonInstrument: |5972hp60.i

lent Sampl'e ID: 5STD08

i■mpound : Capro 1 actam "AS Number: 105-60-2

j. u-

2.0-

2.6-

2. 4-

2.0-

1.3-

1.6-

1 . 4-

1.2-

1.0-

0.8-

Ion 55.00: Area: 28807 Height: 28807

if

s

10.8 10.9 11.0

M i n

11.1 11.2

/\! \

11.3 11.4 11.5

2.6-

: .8"

1 . b~

1 . 4-

1 . 0

i 0 ■ 3 ■

Ion 56.00: Area: 26546 Height: 26546

• 56 L

10.9 11.0Min

11.1 11.2 11.3 11.4 11.5

COMPUCHEM a division of Liberty Analytical Corp DATE 3 / / 2-/ ol INITIAL TIME OF TUNE S~Jv-i tm m omm/ni A Til I? DT TM 1 nr ___________ “------- —----

GC/MS SEMIVOLATILE RUN LOG TIME TUNE EXPIRES ? g S' /SHIFT/S(A)_k/_(B) (C)LINKER/METHOD g'JJj,.’

■Eit

tit :0PREVENTIVE MAINTENANCE /v^ p ...H

T

tD■; ■ FILE NAME; , LT--I

~ D''DATE TIME •.I cygNTiD# ;

-1 .......^ ' •CASE/SDG# AMOUNT

INJECTEDCHEMIST

---------------------------------------------U-J-, 'COMMHNTS(ETC.)/DISPOSlT[g^ P—

1 l)rv 'd a 3 h A Aq / -5 1 (L1 01 r/ AryV°> 4 m

______________________________ SJ"— /r?)

2 A/%0 lo3 HAdo / l / to n —^ -f rA q Kp J.- ^-LS- 1 y---- i-L/-'________________

3 S'C. H U-Q Ah 4 t i II os -I/1- 7 5r 2 / //------ V--------

1 ,04 U)fs)(/il3o-3Ah z / / II os f M c

5 UJA Uzlo-* ACv / / / |U?

6 Sc it6C-(oA(>v / / /

7 Sr ? 6bdo / / / nw —Tr~8 idfa/AziS ■ LAfjL / / / mS

- AT \/ AA i u u c—J—X------------------------------------------

9 /A 11^-2 A Aq_. / / / (<roz1

10 aaim L / / AW s?>p acttii11 / / / — t-wj--------------

-PTFlohiT {IftlDZH12 J- or

_/ / /7o7 '

13 GfltlO-*1/900 / /----- :----

/ ///?

14 /IPMOI-tO/jU, 4 / / Wiv-IZR15 a?iWhli?iuo L / / /fak P\U)~i3Q16

1 7

/ 'v

--- >

l"

__*___

/9/A> r<ioo-/3&____ Vt / V ^___ V

y

db\ - 4 ~ ’j'Ofi,18 / / k ----------19 / /

—20 / /

______21 / /___ __ ______ '

=----- ----------------—

22 /

23

24•

/ /

—---- /----/— -r y"

Std. ID tr

Lot #

Analytical

5" -3 ? (f-L/L

lnt. Std. Column Type

-x If-Cy r

SUPERVISOR APPROVAL3ilsto-7r

DATEO 5 X 'A"''

e presence of the Chemist s employee 11) number, or signature, on this run log attests that stiici compliance with the method's Sr

occurred. Any St^dcviations require documentation by the responsible chemist together with the chemist's initials and the initial

lab supervisor department representative, signifying approval of the deviation 12/1 1/til dc







GC Column: J&W DB-5-.625 ID: 0.32 (mm)

COMPOUND

Phenol_J____________________

Bis (2 - ch'loroethyl) ether

2 -Chlorophenol____________

1.3 -Dichlorobenzene_____

1.4 - Dich'lorobenzene_____1,2 -Dichjlorobenzene

. I2-Methylphenol2,2'-oxybis(1 -Chloropropane)

4-Methylphenol

[M-Nitroso-di-N-propylamine_

| Hexachloroethane______________

I Nitrobenzene

isophorone_________________ .

■-Nitrophenol

2 , 4 - Dimejthylphenol___________

Bis ( 2 - chjloroethoxy) rnethane_

2 , 4 - Dichlorophenol___________1,2,4 -Tr|ichlorobenzene

Naphthalene________________

4 - Chioroaniline___________

iHexachlorobutaaiene_____4 - Chloroj- 3 - methylphenol

2-Methylnaphthalene_____

Hexachlorocyclopentadiene 2 , 4 , 6 -Tr'ichlorophenol_____

4,5-Trdcnlorophenol

2 -Chloronaphthalene_

2 - Hi t roam 1 me______

Dimethy1phtha1 ate___

2,6- Dini|trotolnene_AcenaDhthvlene

i ' . --------:oar. 11 me

RRF OR

AMOUNT

■Nit:

Xcer.aphthenei

2 , 4 - D i n 11

4 - Hi t r ooh'' i

rophenolmol

: - Dim protolueneDibenzofuran

I ---Diethylphthalat

4 -Chlorophenyl- Fluorenel

onenvl ether

-Hit roan i 1 me

6-Dinitro-2-me thvlohenoi

1 . 0 .

1 . 1 . 1. 1 , 0 .

1 . 1 , 0 .

0 .

0 .

0 .

0 .

0 ,

0 , 0 .

0 .

1.

0 .

0 .

0 .

0 . 0 ,

0 .

0 . 1,

0 .

1. '! C.

.11.

I 0 .■ i 1.

i 0 .

>■

! o ,'h-

.11.

; o. 'll

.1°

! 0 .

3820000

9520000

0880000

4910000

4860000

4310000

8830000

3580000 1220000

8140000

6340000

4960000

7810000

2450000

2970000

4700000

4380000

5200000

1890000

5010000

4060000

3640000

8860000

4600000

4400000

4790000

2400000

4830000

6290000 3470000

9950000

3690000

1730000

2170000

2960000

5140000

1810000

7600000

9 6 0 0 0 0 0

7420000 3720000!

i 6 6 0 0 0 0

Daqe 1 of

RRF80.000

OR

AMOUNT

. 2278442

.8673226

. 1312333

.5968505

. 5874369

.4962370

.9473773

.2232542

. 0802883

. 7091428

. 7233980

. 4463165

.6969587

. 2454144

.2887574

.4251300

.4618499

. 5742556

.1563816

.4521012

.4734603

. 3475495

.9501716

. 5344338

. 4514415

. 5203548

.1843315

.4375715

. 5470646

.3388357

. 9069708

.3533331

.1826551

. 1967293

.3196374

.5228070

.2300703

.5732787

.9905059

.7087524

.3615634

.1478998

MIN

RRF

0.01 0.01 0.01

0.01 0.01

0.01 0.01

0.01 0.01

0.05

0.01 0.01

0.01

0.01

0.01 0.01 0.01 0.01 0.01 0.01 0.01

0.01 0.01

0.05

0.01

0.01 0.01

0.01

0.01

0.01

0.01

0.01

0.01 0.05

0.05

0.01 0.01

0.01

0.01

0.01

0.01

0.01

irD OR

kDRIFT

-11.15

-8.89

3 . 97

7.10

6 . 83

4 . 56

7.29

-9.92

-3.72

-12.88 14.10

-10.02 -10.76

0.17

-2.78

-9.55

5.44

10.43

-2.74

-9.76

16 . 62

-4.52

7.24

16.18

2.60

8.63

-4.49

- 9

- 5

_ 2 -4

. 40

. 03

. 41

-2.89

0.82

-9.34

7 . 98

1.71

2.25

, 931 R

-4

3

-1.91

-2.80

-10.90

MAX %D OR

%DRIFT

20.00

50.00

50.00

50 . 00

20.00

50.00

50.00

50.00

50.00

50.00

50.00

50.00

50.00

20.00

50.00

50.00

20.00

50.00

50.00

50.00

20.00

20.00

50.00

50.00

20.00

50 . 00

50.00

50.00

50.00

50.00

50.00

50.00

20.00

50.00

50 . 00

50.00

50 . 00

50.00

50.00

50.00

50.00

50 . 00

CURV

TYPE

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVP.G

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

FORM VII SV56l








| | RRF80.000 j i 1 1

l COMPOUND | P.RF OR | OR MIN | %D OR 1 MAX %D OR|CURV

J AMOUNT AMOUNT | RRF1%DRIFT

1%DRIFT TYPE

1i ----------

j N - N i t r o s odiphenylaminej -------- ------------- || 0.5330000 0.4765422 j

------10.01 [

-------- 1-10.591 2 0.0 0|AVRG

|4 -Bromophenyl-phenylether Jo.30000000.2703204[ 0.01 -9.89 50.00 AVRG

Hexachlorobenzene 0.3410000|0.3195736 0.01 1 -6.28| 50.00|AVRG

| Pentachl'orophenol 0.1000000|0.1148339| 0.05 I 14.83 | 2 0.0 0|AVRG

|Phenanthrene 1 . 2540000|1.1483615 0.01 | -8.42 50.00 AVRG

!Anthracene | 1.2630000 1.1493896 0.01 j -9.00| 50.00|AVRG

|Carbazole |0.98000000.8954495| 0.01 j -8.63 | 5 0.0 0|AVRG

|Di-n-but ylphthalate | 1.6380000 1.4562558| 0.01 j -11.10 | 5 0.0 0|AVRG

:Fluoranthene | 1.44 90000|1.4178103 | 0.01 -2.15| 20.00 jAVRG

|Pvrene | 1.4350000| 1 . 3974664 0.01 1 -2.62 50.00 AVRG

jButyl benzylphthalate | 0 . 7410000|0.6656803| 0.01 I -10.1650.00 j AVRG

i 3 , 3 ' -Dichlorobenzidine 0 . 5660000 0. 5777214 0.01 2.07 50.00 AVRGrtjis(2 - ethylhexyl)Phthalate 1 . 0350000 0 . 9965946 0.01 -3.71 5 0.0 0|AVRG

Benzo(a)anthracene | 1.4320000 1.6085199 0.01 12.335 0.0 0 jAVRG

iChrysene| 1 . 2900000 j1.2647011j 0.01 J -1.961 5 0.0 0|AVRG

Di-n-octvlphthalate 2 . 0140000 J 1.9020777[ 0.01 -5.56 | 20.00 AVRGBenzo(b)fluoranthene 1.7250000 1.6598364 | 0.01 -3.781 50.00|AVRG

Benzo(k)fluoranthene 1 . 5600000 1.7624998| 0.01 12.985 0.0 0 j AVRG

|Benzo(a)pyrene | 1.3800000|1.4738244 0.01 6.80 20.00 AVRGIndeno(1 2,3 -cd)pyrene 1.4730000 1 . 6969110 0.01 15.20| 50.00|AVRG

Dibenzo(a,h)anthracene 1 .2820000 1 .4997111 0.01 16.98 50.00|AVRG

Benzo(q,h,i)perylene 1 1 . 24100001 1 . 4097750| 0.01 1

113 .60 |

15 0.0 0|AVRG

i2-Fluorophenol 1 . 2730000 1.2161236J 0.01 -4.47 50.00 AVRGPhenol - dS 1.43600001.38361521 0.01 -3.65 50.00 AVRGUitroben zene-d5 j 0.572000010.5194193 | 0.01 i -9.191 5 0.0 0|AVRG

2 - Fluorobiphenyl ] 1 . 5550000|1.5298129j 0.01 -1.62 50.00 AVRG2,4,6-Tribromophenol | 0. 37 6 0000 J 0.4450193 ! 0.01 18.36 | 50.00|AVRG

Terpheny 1 - d 14 1 . 1 100000! 1. 1057504 1

i : :

0 . 01 1 -0.38

150.00 AVRG

1

iao!

FORM VII SV

b6 o

Data File: /chem/5972hp60.i/DF020313A60.b/HG020313A60.d

Date : 13-MAR-2002 13:12


564

Sample Info: SSTD080;917

Volume Injected <uL)t 1*0 Operator: 917

Column phase: J&W DB-5*625 Column diameter: 0.32

Data File: /chem/5972hp60.i7DF020313A60.b/HG020313A60.d

Date : 13-MAR-2002 13;12

Client ID: SSTD080




Instrument: 5972hp60,i

Operator: 817


■_o

CDLO


Data file Lab Smp Id Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date|Als bottle Dil Factor Integrator Target Version: Processing Host:

CompuChem

Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020313A60.b/HG020313A60.d SSTD080 Client Smp ID: SSTD08013-MAR-2002 13:12917 Inst ID: 5972hp60.iSSTD080:917

/chem/5972hp60.i/DF020313A60,b/8270Cv6.m13-Mar-2030 13:44 mikhael Quant Type: ISTD0 3-MAR- 2 0 0 2 17:20 Cal File: HL020303A60.d2 Continuing Calibration Sample1.00000

HP RTE Compound Sublist: all.sub3.50einstein


Name Value DescriptionI ____ ________________ _ ^

DFVtVoVi

1.00000

1000.00000

1000.00000

1.00000



AMOUNTS

QUANT SIG C.AL-AMT ON-COL

Compounds MASS RT EXP RT REL RT RESPONSE ( NG) ( NG)

• 1.4 -Lien ) orohenzene -d-i 162 8 . 163 8 . 153 (1.000) 8344 3 40.0000

• -> Nacr.L hd i 136 10.301 1 0 . 301 (1.000) 243315 40.0000

Acenacr. c •

16-i 13 . 380 "3 380 (1.000) 208182 40.0000

1 88 16.003 1 6 . 0 0 3 (1.000) 463513 40.0000

Chrysene • d2 2 24 0 20.638 -> p 6 3 8 (1.000) 498466 40.0000

:•••:.. • • -• -h'.: 264 23.209 2 8 . 206 a . o o o i 415406 40.0000

7 7 3-Flucro 112 6 . 038 =■. 03 = •, 0.7 4 1 i 202954 30.0000 76.43

:■ ; ?h-=.nc: -c 99 7 . 594 7 6 9 4 iO 932' 230906 80.0000 77.06

: = 82 9.06JK 08 3 10.802 j 252765 80.0000 72.66

•; :: 2 - F1 v c *■ c biphenyl 172 12.196 ■2 . 196 (0.911i 636959 80.0000 78.70

; :: 2 T r j r,romopnenol 330 14'. 734 734 (1.105) 185290 80.0000 94 . 60

3 .3 Terpr.-r.', -r-, 244 18.611 16 6 1 iO.911; 1102358 80.0000 79.68

s Gdirr.eir.y 4 2 )QC l a c (0.417; 307934 80.0000 98.98

1 y: :air; 79 3 .433 3 . ^ i (0.421) 309499 80.0000 71.61

SIMILARITY

(M) ^

9668

9339

56b


Zompounds

15 Benzaldehyde

16 Phenol

17

16

i ?

20

Bis(2-chloroethyl)ether

2-Chlorophenol

1.3-Dichlorobenzene

i i c h 1 ;,r ooenzer.e

21

22

23

24

25

Benzyl -alconolI

1.2-Dichlorobenzene

2 - Methy|lphenol

2,2' -oxybis : 1 -Chloropropane)

Acetophenone

2 6 3 - Me thyjl phenol

27 4-Methy-lpnenol

2 8 N-Nitroso-di-N- propyl amine

29 Hexachioroethane

30 Nitrobenzene

31 Isophorone

32 2-Nitrophenol

33 2,4 - Dimethy1pheno1I

3 4 Bis v 2 -chloroet noxy(methane

35 2,4 - Diehl oropnenoI

36 1,2.4 -Tr:chJ.orobenzene

40

4 3

Naphthalene

4 -Chioroam i '.ne

u .Hexach:orooutaaiene

Caprolact am

4 -ChI ore - 3 - met hy1pnenol2 - Met hvllnatnt na 1 ene

‘ I ']- Met hvl nachtna1ene

. :i ■ .

nexacr.. orocyc .opent a a lene

2,4,6-Trichiorophenol

46 2,4,5-:richlcrophenoi

4 1 1 , 1 ' - 3 i p h e n y 1

4 8 2 -Chioronaoht haiene2.Ni;roinihr.e

r ' Dine:r.v) r::: pa 1 a: a

.. . . _ T: - .. . - a : n : : rot: o i uene

a. Ac-j::apr.:

5? 4-N:troche.. _ „i

-- 1^.1" "l

55 Diethviiht

' i- .*1 - tr.ioro p n

u ene

- on-e ether

AMOUNTS


MASS RT EXP RT REL RT RESPONSE ( NG) ( NG) SIMILARITY

77 7.425 7.425 (0 . 911) 100794 80.0000 75.67 8700

94 7.611 7.611 (0.934) 204910 80.0000 71.04

93 7 730 7.730 (0.948) 144744 80.0000 72.92

128 7.814 7 . 814 (0.958) 188787 80.0000 83.20 8973

146 0 051 8 . 051 (0.988) 266492 80.0000 85.65

14 6 B 1B7 B . 1B7 (1.004 ) 264921 B0.0000 85.45

108 8 .390 8 . 390 (1.029) 105101 80.0000 72.10

146 6 .423 8.423 11.033) 249701 80.0000 83.68

108 / 8 6ioy 8.610 (1.056) 158104 80.0000 85.85

4 5' 8 610/ 3 . 610 (1.056) 204144 80.0000 72.05 7097

- 105 8 829 8 . 829 (1.083) 263285 80.0000 79.65 7865

108 ■' "Q 863 8.863 (1.087) 180285 80.0000 77.03

1 08/ - 8 863 8 . 863 (1.087) 180285 80.0000 77.03

70 8 829 " 8 . 829 (1.083) 118346 80.0000 69.67 0 (M) |

117 8 999 8 . 999 (1.104) 120725 80.0000 91.26 8972

77 9 117 9.117 (0.885) 217191 80.0000 71.97 8953

82 9 523 , 9.523 (0.924 ) 339161 80.0000 71.37 8815

139 9 658 9.658 (0.938) 119426 80.0000 80.14 8783

122 9 760 9.760 (0.947) 140518 80.0000 77.71 8647

93 9.895 9 . 895 (0.961) 206881 80.0000 72.31 7742

162 10.081 10.081 (0.979) 224750 80.0000 84.41

ISO 10.217 10.217 (0.992) 279450 80.0000 88.40

128 10.352 10.352 (1.005) 562730 80.0000 77.82 8979

127 10.454 10.454 (1.015) 220006 80.0000 72.17 8792

225 10.572 10.572 (1.026) 230400 80.0000 93 . 19 9122

113 11.046 11.046 (1.072) 45814 80.0000 86.94 8555(M)^

107 11.316 11.316 (1 . 099) 169128 80.0000 76.41 8707

142 11 553 11.553 (I.122) 462382 80.0000 85.78

142 11 722 11.722 (1.138) 371059 80.0000 85.16

237 11 824 11.824 (0.884) 222519 80.0000 92.99 9085

196 12.061 12.061 (0.901) 187964 80.0000 82.01

196 12 145 12.145 (0.908) 216657 80.0000 86.83

154 12 365 12.365 (0.924) 572659 80.0000 76.06 8290

162 12 399 12.399 (0.927) 493113 80.0000 76.38

65 12.602 12.602 (0.942) 364378 160 000 144 . 9 8852

163 12 907 12.907 (0.965) 644142 80.0000 75.96 9491

16 5 13.025 13.025 (G.973) 141079 80.0000 78.05 9566

152 13.127 25.12" iC.581; 793994 80.0000 76.46 9875

1 3 S 1 3 3 3 0 1 5 .530 ! 0.996) 298394 160.000 155 6 9191

15-5 13.446 13.446 (1.005) 492415 80.0000 80.63 8743

164 13.516 . 51£ a . 0 1 0 ) 409555 400 000 362.3

109 13.651 1 3 651 (1 .020) 266171 160.000 172.5 7983

16 5 13 736 i 3 . 7 3 6 ; 1 .027 J 217678 80.0000 81.30 8400

16 8 13 752 15.752 I 1.028) 928521 80.0000 81.81 94 39

149 14.155 14.155 : i. o 5 8 :■ 696693 80.0000 76 . 06 9374

204 ' 14.345/ 14.345 (1 . 072) 412411 80.0000 82.51 714 9

16b ' 14.345 , 711463 80.0000 78 . 50 7612

Data File: /chem/5972hp60 . i'/DF020313A60 .b/HG020313A60 .dReport Date: 13-Mar-2030 13:44

1

Compounds

QUANT SIG


AMOUNTS

CAL-AMT

( NG)

ON-COL

( NG) SIMILARITY

62 4-Nitro aniline 138 14.412 14 .412 (1.077) 301084 160.000 155.7 7970

63 4,6-Dinitro-2-methylphenol 198 14 .463 14 .463 (0.904) 274214 160.000 143.0 8803

64 N-Nitrosodiphenylamine 169 14.565 14.565 (0.910) 441767 80.0000 71 52 8816

6£ 1,2-Diphenylhydrazine 77 14 .632 14 .632 (1.0941 725417 80.0000 ' "79.47 9238

6 6 4-Bromophenyl-phenylether 248 15.207 15.207 (0.950) 250594 80.0000 72 00 94 01

67 Hexachlorobenzene 284 15.326 15 . 326 lO.958 ) 296253 80.0000 74 94 9514

6£ At razine 200 15.495 15.495 (0.968) 15622 80.0000 17 61 8993

65 Pent achjlorophenol 266 15.681 15.681 (0.980) 212908 160.000 184 . 0 8900

70 Phenanthrene 178 16.053 16.053 (1.003) 1064561 80.0000 73.23

71 Anthracene 178 16.138 16.138 (1.008) 1065514 80.0000 72 81

72 Carbazole 167 16.425 16.425 (1 . 026) 830105 80.0000 73 13 8918

73 Di-n-butylphthalate 149 17.018 17.018 (1.063) 1349987 80.0000 71.10 9112

74 Fluoran :hene 202 18.151 18.151 (1.134) 1314347 80.0000 78.25

75 Benzidine 184 18.371 18.371 (0.890) 253628 160.000 77.42 8620

76 Pyrene 202 18.557 18.557 (0.899) 1393179 80.0000 77.91

Bu t y 1 be n z y 1 p h t ha 1 a t e 149 19.657 19.657 (0 "952) 663638 80.0000 71 87 9446

16 3,3'■Diehlorobenzldine 252 20.570 20.570 (0.997) 575949 80.0000 81 68 6930

79 bis(2-ethvlhexyl)Phthalate 149 20.604 20.604 (0.998) 993537 80.0000 77 03 9107

80 Benzo(a)anthracene 228 20.621 20.621 (0.999 > 1603585 80.0000 89.88

81 Chrysene 228 20.672 20.672 (1.002) 1260821 80.0000 78.41

82 Di-n-octylphthalate 14 9 21.585 21.585 (0.930) 1580269 80.0000 75 54

9 3 Benzo >b fluoranthene 252 22.414 22.414 (0.966) 1379012 ' 80.0000 76 98

Benzoik fluoranthene 252 22.465 22.465 (0.968) 1464306 80.0000 90.40

W Benzo(a)pyrene 252 23.091 23.091 (0.995) 1224471 80.0000 85.41

86 Indeno (1,2,3 -cdipyrene 276 26.136 ■ 26.136 (1.126) 1409814 80.0000 92 15 8540

87 Dibenzo < a . h)anthracene 278 26 . 187 26 . 187 (1.128) 1245978 80.0000 93.57 8610

86 Benzo(g h.i:pe ry1ene 276 27.033 27.033 (1.165) 1171258 80.0000 90.85 7460

QC Flag Legend


Data File: /chem/5972hp60.i/DF020313A60.b/HG0203l3A60.d Injection Date: 13-MAR-2002 13:12 Instrument: 5972hp60.iClient Sample ID: SSTD080

pound: 2.4.6-Tribromophenol Number: 118-79-6

1.1-

1.0-

0.9-

>0.8-"

0.7-

u. d-

0.1-

0. u- -


14.4 14.5 1 *4.6 1*4.7 14.0Min

14.9 15.0 15.1 15.2

1 .4-

1 . 3-

1

1

1

0.9-

8-


14.3 4.4

56 514.5 14.6 14.7 14.8 14.9 15.0 15.1 1!

Min

Data File: /chem/5972hp60.i/DF020313A60.b/HG0203l3A60.d Injection Date: 13-MAR-2002 13:12 Instrument: 5972hp60.1 Client Sample ID: SSTD060

>ound: N-Nitroso-di-N-propylamine

Number: 621-64-7

5.1-

4.B-

4.5- .

4.2-

3.9-

3.6-

3.3-

3.0-

2.7-

2.4-

2.1-

1 .3-

1.5-

1.2-

0.9-;

0.6-

0.3-

0 0-'

Ion 70.00: Area: 118346 Height: 53832

l\

/ ,i

6.5 8.6 8.7 8.8Min

8.9 9.0 9.1 9.2 9.3

1.2-

1.1-


1.0-

fi

o. 5-;

0.4-

0.3-

0.2-

0.1-

0.0-8.5 B.6 8.7 8.8

Min8.9 9.0 9.1 9.2 9.3

8.5

5-


9.0 9.1

57G9.3

Data File: /chem/5972hp60.i/DF020313A60.b/HG0203l3A60.d Injection Date: 13-MAR-2002 13:12

COMPUCHEM a division of Liberty Analytical Corp DATE 3_/ii_/P^lNITIAL TIME OF TUNE__X2^l£___ SHIFT/S(A)_^__ (B)(C)

GC/MS SEMIVOLATILE RUN LOG TIME TUNE EXPIRES_ LINKER/METHOD Ally;

COMPUCHEM .LOGBOOK 4 V(4) 4 (5972hp60)nr\ r*n ddcv/cxitiv/c maimtfkiavirr o / —ftet

KEr

PREVENTIVE MAINTENANCE xi/^r-/ -------------------------------------------------------------------------- LU_iUr

cTl

FILE NAME rTeD

DATE TIME CLIENT ID# CASE/SDG# AMOUNTINJECTED

CHEMIST COMMENTStETC )/DISI’OSlT[Qti p--..

1 ? o ^ (3 A £ u / 3 ;/J ; oi lid dfrAt_____ i ya9 ___ ^ZJ_____ ro) /c7

2 flh/o / iv / / i A/fj / V / 1J i A ?S77l^c-____*-----

______ 1______

3 \>)h,)h i / f-1 .A/o / / / / .3 53. ev/U/~ ZZ.ZT r^F ___ \ (a4

4 (nJAv/rG L 5T- / / / 3 ________| M jb __ ___'■‘■In 1 / V r < _5 / / / / S'/5 MUj -?v A hi

6 Ae ivm- teftbo / / / 15b* Kvo-tec

7 Cos fail-1 w A(/o / / / lbV3> Mw-hA

8 he isn- iSAU / / / Hi* S

9 be i<6T)- It? AGo 7 / / ns* Mt/o - K A

10 be fa'll -\1 Abo7 ■ / / iSSM iv\w- ng

11 file i *11-1ft f\Uo / / / 131H Moj -/b>*

12 befall- Ki Abo / / / hSS tovJ.- i^ife N / \13 i/\3t7i\(>3£i 1-1 AG° 7 / / Sgcici \> VA^XvisaS 7*\\

14 V06tl(>3‘»I^A^ / / PUS b'53bLy<> 1/

15 / / / 315* CaapIuj E,±2>}?

16 GFl&Tl-WCAfo 7 // / (Mud - JeA Qf fall

17 6)Fm>2/NAb° 7 / 7 ;>sn MvaJ - ?o £> s7___ s a

18 / /___ —-

19 / /

20 / / ^ , 7 ||^ 3 ^

21 / /P7O

22 / /

23 ■------ - /

24 / /•

Tune

Std-ID-#----------- C S' 0 •

Lot U s' L {s

STANDARDS Analytical Ini. Std.

V? 7 r_____

Column Type SUPERVISOR APPROVAL

-J7-u—7m~—ua:i:e__ ____

The presence ol the Chemist's employee II) ninnher, or signature. on I his run lop altcsts that si riel conipluiucc with i ho method . S' > I ‘ lu

occurred. Any SOI’ deviations require documentation by the responsible ehenusl logclhci with ihe eheinisl's iin 1 ials. ami ihe iniii ii■, >.| il

lab supervisor and a OA department represemalive. signifying approval of ihe deviation I .VI I ml dee



lLab Code: LIBRTY Case No.: . SAS No.: SDG No.-. QE1877


Lab File ID: HG020314B60 Init. Calib. Date(s): 03/03/02 03/03/02



COMPOUND |RRF OR

I AMOUNT

I|Phenol 1___________________

I Bis(2 -chloroethyl)ether_

1

-Chlorophenol_3-Dichlloroben:

j,, j-un.ni'uiuui;ii^ene1 , 4 - Di chllorobenzene

1 , 2 - Di chllorobenzene

2-Methylphenol

1.3820000

0.9520000

1.0880000

1.4910000

1.4860000

1.4310000

-oxybis(1-Chloropropane)

|4-MethylphenolI N-NitrosoJ-di - N - propylamine__

|Hexachloroethane

!Nitrobenzene

0.8830000

ophorone__________^Hi trophenol______

4 -Dimethylphenol|Bis(2-chlbroethoxy)methane__

,4-Dichlorophenol_

,4-Trichlorobenzenei 1 : ____!Naphthalene___________________

i 4 - Chi oroam 1 me_____________

.Hexachlorobutadiene________

I 4 -Chloro- 3 -methvlDhenol, | ---2-Methylnaphthalene________

He.xa chi orocycl open tadiene

■ 2 , 4 ,■ 6 - Tr i chi orophenol_____

;2 , 4, 5 -Trichiorophenol_____

2 -Chloronaphthalene________

' 2-Nitroanil me__________

■Dimethylphthalate

2,6- Dmi trot clue ne_________■ Acenaphtrvj-lene_______________

3 - Hit roan illne

.-.cenaphthen-

- Dmitrophr i - N11ropheno1

,4 - Din: loluen-Dibenzofuran

methylphthalat

4 - Chiorophen Flucrene I

- phenvlether

.H11 roan 111 n-

b - uin. 11 ro - 2 - me t hvl phenol

raqe 1 c:

1.3580000 1.1220000

0.8140000

0.6340000

0.4960000

0.7810000

0.2450000

0.2970000

0.4700000

0.4380000

0.5200000

1.1890000

0.5010000

0.4060000

0.3640000

0.8S60000

0.4600000

0.4400000

0.4790000

1.2400000

0.4830000

1.6290000

0.3470000

9950000

3690000

1 3 0 0 0 0

217 0 0 0 0

2 9 6 0 0 0 0

5140000

2 . 1 8 1 0 0 0 0

i . / 6 0 0 0 0 0

0.96 0 000 0

1 . 7420000

0. 3 "" 2 0 0 0 0

0 . 1 6 o 0 0 0 0

|RRF80.000[ 1 ] 1 1

1 OR 1 MIN | %D OR 1 MAX %D OR|CURV|

AMOUNT1 j

RRF %DRIFT 1

I

%DRIFT |TYPE j

1 |

| 1.2750753 |------ 10.01 I

-------- 1-7.74

----------- |----- |20.00|AVRG|

|0.8755671| 0.01 1 -8.031 50.00|AVRG|

1.11011500.01 j 2.03 j 5 0.0 0|AVRG|

j1.6373799 j 0.01 j 9.82 j 50.00|AVRG|

1 . 5998988 0.017.66 j

20.00 AVRG

|1.5359906| 0.01 1 7.34 j 5 0.0 0|AVRG|

|0.9068195| 0.01 1 2.70 j 5 0.0 0|AVRG|

1.1937974 | 0.01 -12.0950.00 j AVRG|

1,1.0953021| 0.01 i-2.38|

50.00|AVRGj

|0.7133376 0.05 -12.37 50.00 AVRGjo.7421203 j

0.01 17.05 50.00|AVRG|

i 0 . 4382909| 0.01 1 -11.63 j 50.00jAVRG)

0.6846384) 0.01 -12.34| 50.00 AVRG

0.2407559 0.01 -1.73 2 0.0 0|AVRG|0.2769714 j 0.01 1 -6.74 j 50.00|AVRG|

0.4023271 0.01 - 14.40| 50.00 AVRG|

0.4600051j 0.01 [ 5.02 20.00 AVRG

0 . 5643432 0.01 8.53 50.00 AVRGj1.1397945 0.01 -4.14) 50.00 AVRG0.4297048 j 0 . 01 j -14.23 5 0.0 0|AVRG]0.4613911j 0 . 01 j 13 . 64 j 2 0.0 0 j AVRG j|0.3461601 1 0.01 -4.90 20.00 AVRG0.9192144 | 0.01 3.75 50.00 AVRG0.4473442 | 0.05 -2.75) 5 0.0 0|AVRG|

j 0.4297655 0 . 01 1 -2.33 20.00 AVRG

0.4557583 0.01 1-4 . 85 j 5 0.00 AVRG j

1.1247789| 0 . 01 1 -9.29| 5 0.0 0 .j AVRG |

|0.4269821 0.01 1 - 11.60 | 50.00 AVRG|

|1.4134 548 | o. oi j -13.23) 5 0.0 0|AVRGI

I0.3222148 ! 0 . 01 1 -7 . 14 | 50.00 AVRG|) 1.81 3 784 2 i 0 . 01 1 -9.08 50.00|AVRG

)0.3262621) 0 . 01 j-11.58)

5 0.0 0 j AVRG j

1 1 . 11^4 3 669 | 0.01 -5.00 20.00 AVRGlo.1856698) 0.05 -14.44 50.00)AVRG

i 0.3208015| 0.05) 3.38) 5 0.00)AVRG j

j 0.4 8 2 6 1 3 0 0.01 -6.11) 50.00 AVRG

2 . 137821-7 0.01 1 -1.98 50.00 AVRG[

I 1 . 6 1 3 5 0 3 0 |0 . 01 j

-8.32) 50.00)AVRG|

0 .9886520 0 . 01 [ 2 . 98 | 50.00 AVRGjl.7789175 0 . 01 j 2.12 50.00 AVRG| 0. 3076896 | 0 . 01 1 -17.29) 50.00|AVRG|

j0.1538125]

j 10.01)

[-7.34

150.00 AVRG

1 1

FORM VII SV 57c








i j |RRF8 0.0 0 0| 1 1 1 1

J COMPOUIID | P.RF OR OR MIN | %D OR 1 MAX %D OR j CURV|

i |AMOUNT AMOUNT |

1 i

RRF j

|

%DRIFT 1

1

%DRIFT jTYPE|

1 i1 ||N-Ni trosodiphenylamine

1 1 | 0.5330000 0.4876334 |

------ 10.01 I

-------- j-8.511

----------- |----- |20.00|AVRG|

I 4-Bromophenyl-phenylether | 0.3000000 j0.2951585| 0.01 | -1.611 50.00 jAVRG|

|Hexachlorobenzene | 0.3410000|0.3303247 j 0.01 1 -3.13 1 50.00 j AVRG|

|Pentachlorophenol 0 . 1000000 0.1177405 0.0517.74 j 20.00 AVRG|

|Phenanthrene | 1.2540000 1.1727415| 0.01 | -6.4850.00|AVRG j

Anthracene | 1.2630000|1.2627789| 0.01 I -0.02| 5 0.0 0 j AVRG|

! Carbazole 0 . 9800000 0.9256850 0.01 -5.54 50.00 AVRG|

!Di-n-but;Tphthalate j1.6380000 1 . 5508453| 0.01 -5.32 50.00|AVRG

! Fluoranthene | 1.4490000I1.5026635| 0.01 1 3 . 70 | 2 0.0 0 jAVRG|

| Pyrene 1.4350000 1.3087822 0.01 -8.80 50.00 AVRG|

]Butylben::\Tphthalate 0.7410000 0.6061015| 0.01 1 -18.20| 50.00|AVRG|

1 3,3' -Dichlorobenzidine 0 . 5660000|0.5614097 0.01 1 - 0.81 j 5 0.0 0|AVRG j

Hfiis ( 2 - etfivlnexvl) Pnthalate j1.0350000|1.0530921| 0.01 1 1.75 | 50.00|AVRGj

Bfenzo(a)anthracene | 1 .4320000 1.6387461| 0.01 1 14.44| 50.00 AVRG“hrysene 1.2900000 1.3561748 j 0.01 1 5 . 13 j 50.00|AVRG|

|Di-n-oct;Tphthalate 2 . 0140000 J 2.1167437 0.01 5.102 0.0 0 j AVRG j

; Benzo(b)fluoranthene [1.7250000 1 . 9346295 0.01 12.15 50.00 AVRG

Benzo(k)fluoranthene j 1 . 5600000 1.7494808 0.01 12.15 50.00|AVRG

i Benzo(a)pyrene 1 . 3800000 1.5472874 0.01 1 12.12 | 20.00|AVRG|

; Indeno i 1 2,3 - cd)pyrene i 1.4730000|1.7093933 j 0 . 01 1 16.05| 5 0.0 0|AVRG|

1Dibenzo(a,h)anthracene |1.2820000 1.5231834 0.01 18 . 81| 50.00 AVRG1 Benzo(a,

,

:, i)pervlene j 1 . 2410000 | 1 . 4 311206 | 0.01 1 15.32] 50.00 AVRG

j 2 - Fluorophenol t 1 . 2730000 j1.2073047 j 0.01 1 -5.16 50.00 AVRG;Phenol-d5

j 1 . 4360000 j 1 . 3727927 10.01 - 4 . 4 0 | 50.00 AVRG

! Hicroben: ene-d5 i 0 . 5720000|0.5252068 0.01 -8.18] 50.00 AVRG’ 2 - Fluorobipher.yl i 1 . 5550000|1.5076698 j 0 . 01 i -3.04 j

5 0.0 0 j AVRG|

2 . 4 , 6 - T r bromophenol 0.3 7 6 0000 0.4124754| o. oi! 9.70 5 0.0 0 j AVRG

Terphenyl -di A | 1 . 1100000 j 1 . 0347666

! ! I0.01

1-6.78

150.00 AVRG

I |

FORM VII SV

574

Data File: 7chem/5972hp60. i7DF020314B60.b/HC020314E60.d

Date : 14-MAR-2002 20;54

Client ID: SSTD080

Sample Info: SST0980:2319


Column phase: J8.W BB-5.625

Instrument: 5972hpb0.i

Operator: 2319

Column diameter: 0.--2

4.3- ;4.2- i

4.1-:

4.0; 3.9-i

3.8-1

3.7-; 3.6-i

3.5-i

3.4- ;3.3- 1

2,s;O J j

2.6-:

2.1-i

2.0-i

> 1.9-

l.s-:1.7-i

1.6-

1.5;

1.4-i

1.3-:

1.2; 1.1; i .0-;

0.,4_-.

0.3-

0.1-

0.0 -

7ch*m/5972hp60.i/BF020314B60*b/HC020314B60.d (Part 1 of 2)

VjC

oa>

o

o

u.'■‘J

liJ■75

Ir,

•1>Cl

VJ

b 7

Q

ntH

.1L , \j ij . Uj . .ill19 10

oLO

II

14

'..O

r—

LO

ij

i1

,<J

15 ih

Data File: 7chem/5972hp60. i/DF020314B60.b/HG020314B60.d

Date : 14-MAR-2002 20:54

Client ID: SSTD030


Volume Injected (uL); 2.0

Column phase: JiU DB-5.625


Operator: 2319


LO

r^-

LO

4.3- i

4.2- i4.1- 1

4.O'

3.9-:

3.8- 1 3.7-j

3.6

3.5

3.4- ;3.3- 1

3.2- i3.1

3.0

2.9

2.8

2.7

2.6

2.5-

2.42.3- i

2.2

2.1- j

2.0

1.9- i

1.8

1.7

1.6

1.5- j

1.4 1.31.2- 1

1.1

1.0

0.9

0.8

0.7

0.6-

0.4

0

20

0.1

16

7chem25972hp60.i/DF020314B60.b/HC020314E60.d (Part 2 of 2>

17 18 19 20 21

Data Fi Report

le: /chem/5972hp60.i/DF020314B60.b/HG020314B60.d Date: 14-Mar-2030 21:31

CompuChem

Data fi Lab SmpInj Date Operator Smp Info Misc Info Comment Method Meth Da Cal Da Als bot Dil Fac Integra Target Process

Semivolatile Report SW-846 Method 8270C le : /chem/5 9 72hp6 0.i/DF020 314B60.b/HG02 0 314B6 0.d Id: SSTD080 Client Smp ID: SSTD080

14-MAR-2002 20:542319 Inst ID: 5972hp60.iSSTD080:2319

/chem/5972hp60.i/DF020314B60.b/8270Cv6.m14-Mar-2030 21:31 naegler Quant Type: ISTD0 3-MAR-2002 17:20 Cal File: HL020303A60.d2 Continuing Calibration Sample1.00000

HP RTE Compound Sublist: all.subVersion: 3.50ing Host: einstein

te : e : tie : tor : tor:

Concent rat ion Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable


D'F 1.00000 Dilution Factorv|t

1000.00000 Volume of final extract (uL)

A o 1000.00000 Volume of sample extracted (mL)

w i 1.00000 Volume injected (uL)

Cpnd Va riable Local Compound Variable

AMOUNTS

Ggan-; s:g CAL-AMT ON - COL

Compounds :v.ss 9T rvp py F.EL RT RESPONSE [ NG) ( NG)

ch 1 Dtcb-.-n - d-i 15: ‘1 . j 0 0 i 91913 40.0000

; 3-7 : i - 5 i ■ :4 5 '1.0 f j 7. 272010 40.0000

1 n 4 . /y .:. :• il- o! 242509 40.0000

. -y-n ' 1 . C•■0 i 495405 40.0000

r --.rvs- 7 .• :-y ■::: i 7 o: 579436 40.0000

:■■■ ■ ;. :■ ■; :: ; - v • ; - - 45P410 4 0 . Ohft

7 7.it;.,- i:i . -22 . 7 4 0- 221934 8 0.000 0 7 5 9 -.

•: ■il.. - z-,z ( 0 92-1 : 252355 90 . Oi.iOO 7 n 4 h

tr.z-j-.w-Si 4 7 -'0.832) 295723 6 0.0 0 C 0 73.47

:h:;v::v::yl 7 o ^ G: . ? 11 -■ 7 312J 7 30.0000 77 . 56

: 3 2- 14 . ::.: c 5.- 20005S 3 0.0 0 C 0 97 . 63: ::: T-i-p-jyl - : : 144 > 77- 14.775 1159162 30.0000 74 . 56

osodir-d-.by : :■ ’.9.416) 353083 eo. oooo 10 4.5

14 Pyrid: Cd 7v j ; 7 -.4 20: 353333 90.0000 76.43

SIMILARITY

b

964 3

9395

577

fa

Data File: /'chem/5 972hp6 0 . i/DF02 0314B6 0 . b/'HG02 03 14B6 0 . d Report Date: 14-Mar-2030 21:31

AMOUNTS

CUANT SIG CAL-AMT o o o tn

ompounds MASS RT EXF RT RE' RT RESPONSE ( NG) ( NG) SIMILARITY

15 Benzaldehvde 77 7.409 7.409 (0.911) 127371 60 . 0000 66 . 31 8580

16 Phenol 9-1 7 . 556 7.596 (0.933; 234392 SO.0000 73.75

17 Bis 12 -chloroethyl)ether 93 7.714 7 . 714 (0.948; 160952 80.0000 73 . 62

18 2 -Chroropheno1 123 7.799 7,799 (0.958: 204068 90 . C000 81 . 65 8965

*9 1,3-Dichicrober.zene 146 8 . 035 3 . 0 3 5 ■'0 9 8 9! 300993 30.0000 97.33

i.ehloroter.zene 1 4 c 3 . 1 54 8 . 154 (1.002: 294103 8 0 . 0 0 0 0 S 6 . 12

2: Benzy ) alcohol 104 8.374 6 . 374 '.1.029 123291 8 0 . 0 0 0 0 76.79

2 2 1 2 -D :en1c rooenzere 14 6 8.409 8 . 408 a . 033i 282355 80.0000 85.90

22 2 - Met nv 1 oheno 1 109 / 8 .544^ 8.594 (1.056) 166697 80.0000 82 . 18

2* 2.2 - oxyDis ■ 1 - ;_r.ioropropane ‘ •is' 8 5 2- 4 / 8.594 11 . C 5 6 .' 219451 60.0000 70.31 7 J 5 6

25 Acetophenone ✓ 105 3.914 ^ S.814 (1 . 083) 294264 80.0000 80.82 7756

2 6 3 -Methylphenol 105 - ✓ 8 . 647 8 . 647 (1.087) 201345 80.0000 78.10

27 4-Methylphenol 108 * ' 8.847 8.847 (1.087) 201345 80.0000 78.10

2 8 N-Nit rose-di-N-propylamine , 70 8.814' 8.814 (1.083) 131130 80.0000 70.09 0 (M)

29 Hexachlorosthane 117 8 . 966 3 . 966 (1.102) 136421 80.0000 93 .62 8046)it N ’ * mn~ ^ r- 77 9 . 101 9 . 101 (0.8 e 5 J 238439 80.0000 70.67 3895

31 Isoohcrone £ 2 9 . 507 ✓ 9.507 (0.924) 372457 80.0000 70.11 8762

3 2 2 -N l zrooheno1 13 9 5.543 3.543 (0.937) 130976 80.000C 76.62 8809

3} 2 . A ■ LuzetnyIphenoi 122 9.727 7.727 (0.945) 150678 80.0000 74 . 54 7970

3:s :2 ch 1 crce: r.cxy; rezhane 9 9.87? 9. S?9 (0.961) 21SS74 90.000C 69.43 7698

3 $ 2 . A - D ch 1 c ropner.o 1 ' 4 7 10 06 6 10.056 (0.979) 250252 80.0000 84 . 07

M i 7 .i • . --- 7:ich1crooenzene 180 10.201 10.201 (0.992) 307014 80.0000 66.88

37 Naph:.ya 1 ene 12S 10.336 ■10.336 (1.005) 620071 80.0000 76 . 70 8986

3!? 4 - Cl"! 1 croa: 1; re 127 1C.438 1 0 .438 11.015) 233768 80.0000 68 .60 3559

39 Hexach 1 orer-ueazi er.e |

225 10.539 1C . 539 11 . 025) 251006 80.0000 90.81 84 16

•1C Caprolactamr i 113 11.030 11 . 030 11.072) 31907 80.0000 54 . 16 8314

ro-j--n-jthylphenj' 1 0 7 11.30 0 11.300 ;i.059; 188318 80.0000 76.10 3775

2•Me f y iraphtha ler-- 14 2 11.537 11.537 i 1 .122) 500071 80.0000 82 . 99

i - y : rapntr.a 1 ene 142 11.707 11 .707 (1.138) 411619 80.0000 84 .50

i -i H s x a c . 2 3 7 11 . 3 0 S 11 . 303 (0.884) 216970 80.0000 77.84 9284

4T. 3 <■ ■ ■

I":' ^ ch 1 ere phene 1 i 9 6 12.04S 12.045 '0.9 01, 208444 80.0000 78.07

4 -j " 4 5 Czioricrcpren.t; 15? 12.113 : 2 . 1 1 ? i 0.9 0 6 < 221051 80.0000 76.05

: pr.or.y : ■:54 12 . 543 1 2 2 4 5 •.0.924) 632222 80.0000 72.08 e382

fc _ . 142 '•2 4 - '• 1 2 . 6 3 :. 5 2 7; 545538 80.0000 72.54

4 5 2 - N : t r oar.: ! : r.c 61 12.556 '.0.94 2) 414198 160 000 141.4 6995

y Ip:-.Is-.- 12.551 2 . 2 5 : 10.5 5 5i 685551 80.C000 69.40 9481

’ 2 . 0 0 5 ' 5 0 n 9 ' C c 7 2 ; 156280 80 . 0000 74 . 22 9533

... i. I'.thy i *) ii- : ? . 11 ■ • '1 u 3 1 ] 979718 80.0000 72.73 8 8 7 6

can : 1 ; r.e 125 12.214 15.314 • C . v o i 316486 160.000 141 .6 9243

t-i Arena-. ::v:-. = nv 12 4 15 *..•.4:5 -.004. 540483 8C . 0000 75 . 98 9364 ■

n:t roe non-! 144 :: : : '; . r. i o 450266 4 L 0.0 0 0 341.5

3 ti 4 -..; r. ; : 3 . •: 5 i 1 5.25: : 1 . 12:. 3 1118 9 1 f 0.0 0 0 ; 73 . 2 7 5 9 9

;. i rcr.v .2.7:.' : 1:1 1 ".■227: 234076 3 3.0000 75.05 7853

•.5.7 7 1 i . 7 i 7 ; 1 . 0 2 3 • 10 3 68 8 2 p. n . o o o n 78.42 9 3 7 6

-■= 19 " 14 142 (1.058. 732578 80.0000 73.34 9 3 90

, ,r..l - _• / ' ' 14.52' 1.072; 479514 80.0000 8 2. 25 7113

: • 14 3 2 3 ' ’4 2 - : 1 . 072: 862307 30.0000 81 . 72 7339

Data File: /chem/5972hp60.1/DF020314B60.b/HG020314860.d Report Date: 14-Mar-2030 21:31

AMOUNTS

QC Flag Legend


y'UANT S2o CAL-AMT ON-COL

Compounds MASS RT IX? RT REL RT RESPONSE i NG) ( NG) SIMILARITY

12 4-NilroaniIine13 8 14.396 14 396 a.077i 298470 160.000 132.5 3219

6 3 4 . 6 - 0 i r. 11 ro - 2 - mechv In-heno I 198 14.447 14 447 i 0 . 504 .) 304798 160.000 148.7 8779

6A N-Nitrosediohenviamine 169 14.549 14.549 (0.910: 483152 80.0000 73.18 8322

6 5 1.2 -OiohenvIdvdrazine 77 14.616 14 .616 : 1 . 0 94 ) 796739 80.0000 74.93 ■ 9124

ii 4 - Brcmpoher.v 1 - Dnenvlecher 243 15.192 15.192 ! 0.9501 292446 80.0000 78 . 61 9673

67 Hexachlorobenzene 294 15.310 15.3 1 0 (0.958; 327289 00.0000 77.46 9185

63 Atra: i ne 200 15.479 15.479 (C.568) 10502 80.0000 11.16 8997

69 Pen.tachiorophenol 2 6 6 15 . 665 15 . 6 d 5 ( 0.9 h 0 233317 16C, . 000 188 . 6 8503(M)

7Q Phenanchrene 178 16 . 037 16.037 (1.003: 1161964 80.0000 74 . 73

Ar.chraesne 178 16.122 16.122 (1 . 003- 1251174 80.0000 79.99

~>2 Carba zole 167 16.410 16.410 (1.0261 917178 80.0000 75.60 9187

7 i n 2 -- buc’/iphcha late 14 9 17.002 17.002 (1.053: 1536593 SO.OOCO 75.72 928 3

74 Fluoranthene 202 13.110 10.113 (1.133! 1488854 80.0000 32.94

75 Benzidine 134 18 .355 18 . 355 (0.890) 277868 160.0C0 72.96 8103. _ 1

7-3 pyrene 202 1 8 524 18.524 (0 . 898 } 1516711 80.0000 72 . 96

11 B’-cyi jenzvl one ha lace 14 9 1 9 624 19 . 624 (0.952) 702394 8 C.0000 6 5.43 504 1

73 2,3'- 2 i cn1orobenzidine 252 20 555 20.555 (0.987) 650602 80.0000 79.37 6 613

7 9 b1s ' 2 -echy1nexy1:?hc ha lace 149 20.588 20.588 (0.998) 1220399 80.0000 81.40 S 9 6 4

= S-r;c ! a ) a n r. n r a c e r: e 22 8 20 605 20.605 10.599) 1899097 80.0000 91 . 57

6I Chrvs ere 2 2 S 20.655 20.65o (1.002' 1571633 80.0000 84 . 08

= : : 0,__ • , 145 2 ■ 570 21 . 570 (0.931) 1940673 80.0000 84 . 07

6 2 Pen z o : : ur.'rantnene 252 22 332 22.382 (0.966) 1773707 80.0000 89.72

i '< ) f 1 uoranchene 252 22.432 22.432 (0.969) 1603959 80.0000 89.74

i „ ( a 5 r.y ren~ 2 52 23 058 23 . 05S (0.955) 1418584 80.0000 8 9.66

56 Inden o • 1 . 2 , j —I'd ) pyrene 276 26 007 26.087 (1 . 126) 1567206 80.0000 92.83 8760

-7 .0: be:'. 17 3 26 137 26.127 (1.128) 1396485 80.0000 95.03 8745

j; 9 o n z 276 27.000 2 7 . n 0 0 ( 1 . 165) 1312080 30.0000 *2 .23 7388

>

ol3 y

57S

Data File: /chem/597.40060. 1 / DF02031-IB60. b/ HG020314B60 . dInjection Date: 14-MAR-2002 20:5*3Instrument: 5972hp60.lClient Sample ID: 5STD030

i

ompouna: 2.4,6-Trlbramophenol 9S Number: 118-79-6

1 . 1-

1.0*

0.?:

0.8:

0.7-'

u. 6 -

0.5-

0.4*

o.3-;

0.2-

0.1-

0.0—H.:

Ion 329.60: Area: 200058 Height: 109896

kn

14.4 14.5 14.6 14.7 14.8 14.9 15.0 15.1 15.4

1.0-

0.9-

0.6-

0.7’

0.6-

Ion 4.32.00: Area: 0 Height: 0

14.4 14.7 14.8M i n

14.9 15.0 15.1 15.2

1 .5-

1.3-

1 . 1

ion 141.00: Area: Height:

! 1

14.9 15.0 15.1y"

Data File: .•'chem./5972np60.1 .'DF020314B60. o.'HG0203 14E6Q. oInjection Date: 14-MAR-2002 20:54Instrument:|5972hp60.1

Client 5amole ID: SSTD030

ompouna: N pS Number:

Nitroso-dl-N-propy 1 amine 521-64-7

6.0-

5.6-

5.2-

4.0-

4.4-

4.0-

3.6-

3.2- '

2.8-

2.4-

n.O-

1.6-

1.2-

0.8-

0.4-

0.0--

Ion 70.00: Area: 131130 Height: 61720

TCD

0D-

/ l

8.5 8.3Min

8.9 9.0 9.1 9.2 9.3

1.2-

1 • It

1.0

0.9-.

0.8-

0.5 '

0.4

0.1-

0.0 -

Ion 130.00: Area: Helght: 0

9.0 9.1

0.8-

6.9 9.1 9.3

10 •'

Lompound: Pentachlorophenol kCAS Number: 87-66-5

Data File: .'chem/59?2hp60 . l / DF 02031 4 360 . b/HG020314B60 . dInjection Date: 14-MAR-2002 20:54Instrument^: 5972hp60. lClient Sample ID: SSTD080

i

1.2-.

1.1-

1.0-'

0. 9-

0.8-

0.7-

0.6-

0.5:

0.4-'

0.3-

0.2-

0.1-

n n~—15.2

Ion 266.00: Area: 233317 Height: 124965

$

15. 15.4 15.5 15.6 15.7 15.8 15.9 16.0 16.1Min

3.0-

7.5-

6.5-

b. 0-

5.5-

5.0-

w~ 4.5-

4.U

3.5'

I .5-

1.0-

0.5-

0.0 -

Ion 268.00: Area: 80179 Heignt: 80179

i£sO

15. j 15.! 15.6 15.9 16.0

I Of. 26-4.00: A ro 5: 7S067 Heiznt: 7B067

15 15.6 15.7

M i nlb.1!

COMPUCHEM a i. vision of Liberty Analytical Corp DATE

GC/MS SEMIVOI ATILI: RUN LOG

COMPUCHEM .LOGBOOK 4 V(4) 4 (5972hp60)

/ )M/0^ INITIAL TIME OF TUNE__2<Vbi

TIME TUNE EXPIRES 03 S

SHIFT/S(A)(B) .(C)

LINKER /METHOD__ C

PREVENTIVE MAINTENANCE (Oon-c

C ' T l0: FILENAME; • k ■'T

> D •■ DATE TIME Z* , :GLlENtID# CASE/SDG# AMOUNT

INJECTEDCHEMIST COMMENTS(ETC.)/DISPOSITION^^~-

1 / y 1 IH7 o; Soil TFTfP _ c?5I5 Li )ScD-LcDy

2 |46iO)H ELo / / / SST^oftsC 4/3 y/06i|L£oM-l£U / / / X 0 S?>Ll^36s utL4 U6) z / / S3 6 LcS 4/5 / Q&ivn-sfc&fro / Mw-%A Ifc'n Hf^se/.Vr rf l ^Z5/-

6 Qe nm-s< g(/o2

' / MiaI-uS 4/7 / b /lb/o> CXVfr Mvu-ZiB apnon

8 « ;&)yw»mo / / <00 5^ Alto - i9 / / otF2 F733Z

10 / SL / / 6^/7 owFV f?3 221 1 / / CZ-5? ) AK12 L&ltrWJ'-H&Jb z / / 04l? 1

13 P?3?z-/sm> z / / OTP 3/ -

14 4 lumj> / / oHOs*

15 nv?- /mo fk / / 0433 CftfF?16 / mvi-nfibLo SL / / (%/7 WF3t,Pt)L

____ \17 / Tl /^1/

N \?Ol^

18 ----- 7“ /------ flbl - » To^e ____ —19 / /20 / /21 / / ———-— 5 /

22 / /23

---- —~ ----L‘---- 7 /

----aA24 ----- A--/------

Std. ID tt

TuneSTANDARDS

Analytical

Hbll

Int. Std. Column Type

yh

Lot tt 3l2lS -g-ysb'H-

3*-^ DATE

SUPERVISOR APPROVAL

The presence of the Chemist's employee II) number, or signature, on this run log attests that strict compliance with the method's Si >1' ha-,

occurred Any SOP deviations require documentation by the responsible chemist together with the chemist's initials and the umiak oi i1,.

lab supervisor and a QA department representative, signifying approval of the deviation , ?:■ i/n; a,.


Lab Name: COMPUCHEM



Lab File ID: HG020311A64

Contract: 8270C


Calibration Date: 03/11/02 Time: 0855

Init. Calib. Date(s): 03/10/02 03/10/02

Init. Calib. Times : 1416 1723

•—1

0uuo

,umn: RTX-5 ID: 0.32 (mm)

1

1 COMPOU

1

1

MD

|___ |RRF80.000|

RRF OR | OR

|AMOUNT |AMOUNT |

1 i |

1 1

MIN |%D OR |MAX %D ORRRF |%DRIFT j %DRIFT

l i

1 1

|CURV| j TYPE j

1 l1----------1 Phenol

__ |----------- |------------ | .j 1.4530000|1.3750083 j

----- 1 __0.01 |

------1------5.371 20.00 |AVRG|

1 Bis (2 - ch'loroethvl) ether | 0.9870000 I 0.9678347| 0.01 1 -1.94 | 50.00 |AVRG|

| 2 -Chlorophenol| 1.3440000 j1.3378068 j 0.01 j -0.46 j

50.00j AVRG j

| 1,3 -Dichlorobenzene I 1.5440000|1.5053199 0.01 -2.50 50.00|AVRG j

| 1,4-Dichlorobenzene |1.5580000 j1.5087010| 0.01 1 -3.16 20.00 |AVRG|

| 1,2-Dichlorobenzene|1.5340000 j1.4831560| 0.01 I -3.31| 50.00

|AVRG j

! 2-Methylphenolj1.1720000 1.1752022 j 0.01 1 0.27 | 50.00

j AVRG

| 2 , 2' -oxybis(1 -Chloropropan

|4-Methvlphenol

e) 1.8230000|1.7884050|]1.2740000 j1.2270109|

0.010 . 01 1

-1.90 -3 . 69|

50.00

50.00

|AVRG|

|AVRG|

|N-Nitroso-di-N-propylamine

|Hexachloroethane

__ 0.80300000.78429090.8060000|0.7866033

0.05

0.01

-2 . 33 j

-2.41j50.00

50.00

|AVRG|

| AVRG

!Nitrobenzene |0.3400000 0.3524220| 0.01 3.65 50.00jAVRG '

Jjlsophorone |0.6730000|0.6543315 | 0.01 1 -2.77 50.00 |AVRG|

B-Nitrophenol 0.2150000 0.2096179 0: 011 -2.50 20.00 AVRGW, 4 - Dimethylphenol |0.3200000|0.3189410 0.01 1 -0.33| 50.00 |AVRG|

)Bis(2 - chloroethoxy)methane

2,4 -Dichlorophenol

__ 0.40200000.3752985

| 0.3310000 0.3137093|0.01

0.01

-6.64 |

-5.22

50.00

20.00

j AVRG j

AVRG1 1, 2 , 4 - Trichlorobenzene 0.3860000 | 0.3640747 0.01 1 -5.68 50 . 00 AVRG |

1 Naphthalene 1.4460000 1 .43295490 . 01 j -0 . 90| 50.00 |AVRG|

|4 -Chloroaniline| 0.4620000|0 .4635959 j 0.01 1 0.34) 50.00 )AVRG|

1 Hexachlorobutadiene | 0.2660000|0.2515176| 0.01 1 -5.44| 20.00j AVRG|

! 4-Chloro 13 -methvlphenol 0 . 3680000|0 . 3701861j0.01 0.59) 20.00 AVRG |

j2-Methvlnaphthalene ] 0 . 7240000 0.6882150 0.01 1 -4.94 50.00AVRG j

|Hexachlorocyclopentadiene

! 2,4,6 -Trichlorophenol

S 0.3960000|0.4023036j

0.4070000 0.4109771

0.05)0.01 j

1.72 |

0.98

50.00

20.00

|AVRG| AVRG j

; 2,4,5-Tr ichlorophenol | 0.4320000|0.4324343 0 . 01 I 0.10 50.00 AVRG2-Chloronaphthalene 1 . 0260000 1.0233779[ 0.01 -0.26| 50.00 | AVRG

2 - Mitroaniline j0.3670000|0.3652370| 0 . 01 1-0.48 j

50.00 |AVRG|

1 Dimethylphthalate j1 . 2540000 1 . 2669037 0.01 1 . 03 | 50.00 |AVRG|

2,g-Diniurotoluene| 0 . 3450000| 0. 3444937 j

0.01 -0.15 50.00 | AVRG

:Acenaphthylene 1 2 . 4090000 12.3553686 0 . 01 1 -2.18 50.00 AVRG. 3 - Mi t roam 1 me i 0.3650000|0.3£18 763} 0 . 01 1 - 0.86| 50.00 [AVRG|

■Acenaphthene 1.5590000|1.4453141 0.01 -7.23 20.00 | AVRG

2 , 4 -Dmitrophenol 0.0610000j0.0678740 0.05 11.27 50.00 |AVRG|4-Mitrophenol i 0 . 2170000 i 0 . 2 154058 1 0.05 j

-0.73| 50.00 |AVRG1

2,4-Dinitrotoluene |0.5000000i 0.5007911! 0.01 1 0 . 16 | 50 . 00 AVRG |

Dibenzofuran | 1 . 6140000 j1 . 5663238 0 . 01 j -2.95 50.00AVRG j

D i e t hy 1 p!i t ha 1 a t e 1 1 . 4340000 1 1 . 4 539740 j0 . 01 1 -2.021 50.00 | AVRG

4 - Chlorophenyl-phenylether Fluorene |

(0.693000010.6747008)! 1 . 8 5 2 0 0 0 0 j1.8500119|

0.01 |

o. oi |

-2.64 |

-0.11

50.00

50.00

j AVRG|

AVRG |

_4 - N11 roan 111ne 1 0 . 3800000 ! 0.3839842j 0.01 1 1 . 05 | 50 . 00|AVRG j

^ 6 - D i n i Jro - 2 - me t hvl oheno 11

; 0. 1620000 i 0.1713274 j

i _ ! 10.01

15.76

i50.00 AVRG |

1 1

orFORM VII SV 584

<:<10~6)

Data File: /chem/5972hP64.i/DF020311A64.b/HG020311A64.d

Date : ll-MAR-2002 08:55

Client ID: SSTD080 Instrument: 5972hp64. i LOSample Info: SSTD080;2070 OOVolume Injected <uL): 1.0 Operator: 2070 LO

Column phase; RTX-5 Column diameter: 0.32

Data File: /chem/5972hp64.i/DF020311A64.b/HG0203ilA64.d

Date : ll-MAR-2002 08:55

Client ID: SSTD080



Column phase: RTX-5


Operator: 2070


ooLO

* *ISTD DIFFERENCE REPORT**

Inj ection

Inj ection

Date

Date

of Current CCAL:

of Previous CCAL:

ll-MAR-2002 08:55

10-MAR-2002 14:16

Maximum %Difference of ISTD: + 100 Minimum %Difference of ISTD:

ISTD Name Current CCAL Previous CCAL % DiffArea Area

1,4-Dichlorobenzene-d4 105735 106189 -0.4Naphthalene-d8 414967 418210 -0.8

Acenaphthene-dlO 285056 297124 V4.1Phenanthrene-dlO 592430 631561 -6.2

Chrysene-dl2 562509 596220 -5.7

¥Perylene-dl2 300075 309056 -2.9

Retention time must fall within +/- 30 seconds (0.5)

ISTD Name Current CCAL Previous CCAL AbsoluteRT RT Difference

1,4-Dichlorobenzene-d4 8.249 8.266 0.017Naphthalene-d8 10.143 10.143 0.000

Acenaphthene-dlO 13.152 13.169 0.017Phenanthrene-dlO 15.485 15.485 0.000

Chrysene-dl2 19.949 19.966 0.017Perylene-dl2 22.434 22.451 0.017

-50

PASSESPASSESPASSESPASSESPASSESPASSES


588


Data file Lab Smp Id Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date|

Als bottle Dil Factor Integrator Target Version: Processing Host:

CompuChem

Semivolatile Report SW-846 Method 8270C /chem/5972hp64.i/DF020311A64.b/HG020311A64.d SSTD080 Client Smp ID: SSTD080ll-MAR-2002 08:552070 Inst ID: 5 972hp64.iSSTDO 80:2 0 7 0

/chem/5972hp64.i/DF020311A64,b/8270Cv6.mll-Mar-2030 09:26 mikhael Quant Type: ISTD10-MAR-20 02 17:23 Cal File: HL020310A64.d2 Continuing Calibration Sample1.00000





_ Vt 1000.00000 Volume of final extract (uL)Vo 1000.00000 Volume of sample extracted (mL)Vi 1.00000 Volume inj ected (uL)

Cpnd Var iable Local Compound Variable

AMOUNTSQUANT SIG CAL-AMT ON -COL

Compounds MASS RT EXP RT REL RT RESPONSE ( NG)' ( NG)

- 1 1,4 - Dietilorobenz ene-d4 152 0.249 8.249 (1.000) 105735 40.0000* - Naphtha 1ene-dS 136 10.143 10.143 (1.000) 414967 40.0000

3 Acenapht he ne-d10 164 13.152 13.152 (1.000) 285056 40.0000• 4 Fhenant nrene-d10 188 15.485 15.485 (1.000) 592430 40.0000

s Chryserv > - d:: 2 4 0 19 . 94 9 19.94 9 (1.000) 562509 40.0000Perviene-dlI 264 22.434 2 2.4 34 (1.000) 300075 40.0000

: 7 2 - Fluor. >ohenoi 112 6 . 4 5 7 6.457 (0.783) 269927 80.0000 78 658 Pheno1 - d5 9 9 7 . 7 4 2 7.742 (0.939) 342935 80.0000 76.71

5 9 Nit robentene- dr 8 2 9 095 3 . 095 (0 . 897] 346462 80.0000 77 . 15S 10 2-Fluorobi phenyli r 1 172 11 . 8e4 11 . 804 (0.904) 771345 80.0000 81.223 :: 14.454 14.454 (1.099) 226159 80.0000 78.80- : ~i Terphen1 • 1 - d 11 244 17.652 17.852 (0.895) 1136294 80.0000 76 . 31

1 1 N -Nit rosedimethr 1 amine 4 2 4 . 327 4.327 ( 0.525) 100269 80.0000 79.4511 Pyndin- 7* - ■327 4.327 (0 . 525) 175431 80.0000 80.18

SIMILARITY

8 84 0

9411


AMOUNTS



15 Benzaldehyde 77 7.641 7.641 (0.926) 182826 80.0000 78.95 9710

16 Phenol 94 7.776 7.776 (0.943) 290773 80.0000 75.68

17 Bis(2-chloroethyl)ether 93 7.894 7.894 (0.957) 204668 80.0000 78.41

182-Chlorophenol 128 7 . 996 7.996 (0.969) 282906 80.0000 79.63 9323

19 1,3-Dichlorobenzene 146 8.199 8.199 (0.994) 318330 80.0000 77.98


21 Benzyl alcohol 100 8.452 8.452 (1.025) 162485 80.0000 77.59


23 2-Methylphenol 108 8.621 8.621 (1.045) 248520 80.0000 80.22

2 4 2,2'-oxybis (1 - Chioropropane) 45 8 . 672 8.672 (1 ..051) 378194 80.0000 78.46 9006

25 Acetophenone 105 8.858 8.858 (1.074) 344398 80.0000 f!6.93 9239

26 3 -Methylphenol 108 8.824 8.824 (1.070) 259476 80.0000 77.05

27 4-Methylphenol 108 8.824 8.824 (1.070) 259476 80.0000 77.05

28 N-Nitrose-di-N-propylamine 70 8 . 875 8.875 (1.076) 165854 80.0000 78 . 15 8492

29 Hexachloroethane 117 9.010 9.010 (1.092) 166343 80.0000 78.04 9379

30 Nitrobenzene 77 9.129 9.129 (0.900) 292487 80.0000 82.96 9283

31 Isophorone 82 9.450 9.450 (0.932) 543052 80.0000 77.79 9178

32 2-Nitrophenol 139 9.602 9.602 (0.947) 173969 80.0000 78.16 8442

33 2,4-Dim -1 hylpheno1 122 ■ 9.602 9.602 (0.947) 264700 80.0000 79.79 8456

34 Bis[2 -chloroethoxy]methane 93 9.737 9.737 (0.960} 311473 80.0000 74.75 9462

25 2,4•DichloroDhenol 162 9 . 923 9 . 923 (0.978) 260358 80.0000 75.77

36 1,2,4-Trichlorobenzene 180 10.075 10.075 (0.993) 302158 80.0000 75.41

■^3 7 Naphthalene 128 10.177 10.177 (1.003) 1189258 80.0000 79.29 9319^H3 6 4 - Chloroani 1 me 127 10.261 10.261 (1.012) 384754 80.0000 80.22 7545

3? Hexachlorobucadiene |

225 10.413 10.413 (1.027) 208743 80.0000 75.65 9362

40 CaDrolactam |

113 10.718 10.718 (1.057) 93949 80.0000 79.92 9664

4 1 4 -Chlore - 3 -methylphenol 107 10.938 10.93S 11.078) 307230 80.0000 80.48 9218

42 2 -Methyjlnaphtha 1 ene 142 11.208 11.208 (1.105) 571173 80.0000 75.98

4 3 1-Met hyl napht halene 142 11.394 11 . 394 (1.123) 534977 80.0000 74.58

44 Hexach1orocyclopentadiene 237 11.597 11 . 597 (0.882) 229646 80.0000 81.33 9604

45 2,4,6-Trichlorophenol 196 11.749 11.749 (0.893) 234303 80.0000 80.77

46 2,4,5-Ti ichlorophenol 196 11 . 817 11 .817 (0 . 898) 246536 80.0000 80.11

47 l.i'-Eipheny1 154 12.053 12 053 (0.916) 672680 80.0000 78.78 7597

4 8 2 - Ch 1 o ror;at-hr na me1 h 162 12.104 12.104 (0.920) 583440 80.0000 79.78

4 9 2 -Nltro ini; me 65 12 . 34 1 12.341 ! 0.938) 208226 160.000 159.1 9503

50 D:methy1 -pht ha late 163 12.679 12 679 (0.964) 722277 80.0000 80.82 0804

r. • -> r. . o ^ -- roio1jene 165 12.831 12.831 (0.976) 196400 80.0000 79.87 9274

5 2 Acer..ich•

- hylone 152 12.399 12.8 9'? (0.981 ) 1343394 80.0000 78.26 8903

6 3 3 - N i 11 t”::;ne 138 13.095 1 3 03 5 (0.9951 206310 160.000 158 . 5 9159

54 Arenaph -hen e 154 13.220 12.220 (1.005) 824561 80.0000 74 .21 8962

5 5 2,4 -Dlr -1 rophene: 184 13 .254 13.254 (1 .008! 193479 400.000 444 . 9

5 6 4 - Ni tropher:o i 109 13.304 1 3 304 [ 1.012) 122806 160.000 158 . 6 7625

6 7 2 , 4 - 2-1 r. ~ r:h oh.ene 165 13.507 I 3 507 (1.027) 235507 80.0000 80 . 11 8725

58 Dibenzo "ut an 165 13.474 1 3 4 74 (1.024) 892980 80.0000 77.63 9193

5 t u: e tn y 1 p h r n a 1 a c e 149 13.862 13 B 6 2 (1.054) 828928 80.0000 78.38 9551

6. 4 - Ch 1 orc-phery i - phenyl ether 2 C4 i 3 . 9 5 9 1 3 998 (1.064) 384655 80 . 0000 77.85 7476

•r : riot v v r. 16 6 14.043 1 4 04 3 (1.063) 1054714 80 . 0000 T9 . 91 7525

5 9 G


i

Compounds

QUANT SIG


AMOUNTS

CAL-AMT ON-COL

( NG) ( NG) SIMILARITY

62 4-Nitroani1ine 138 14.116 14.116 (1.073) 218914 160.000 161.6 8758

63 4,6-Dinitro-2-methylphenol 198 14 .167 14.167 (0.915} 202999 160.000 169.3 9422

64 N-Nitrosodiphenylamine 169 14.201 14.201 (0.917) 505817 80.0000 78.39 8113

65 1,2-Diphenylhydrazine 77 14 . 251 14.251 (1.084) 846132 80.0000 79.20 9353

66 4-Bromophenyl-phenylether 248 14.758 14.758 (0.953) 246209 80.0000 78.34 .9666

67 Hexachlorobenzene 284 15.029 15.029 (0.971) 304808 80.0000 78.89 9456

6 31

Atrazine 200 15.012 15.012 (0.969) 234997 80.0000 79.75 9163

69 Pentachlorophenol 266 15.283 15.283 (0.987) 206161 160.000 160.3 7691

70 Phenanthrene 178 15.519 15.519 (1.002) 1712112 80.0000 77.66

71 Anthracene 178 15.570 15.570 (1.005) 1721445 80.0000 76.83

72 Carbazole 167 15.790 15.790 (1.020) 1144864 80.0000 77.63 9621


74 Fluoranthene 202 17.261 17.261 (1.115) 2000353 80.0000 78.71

7 S_ . .. 1Benzidine 184 17.413 17.413 (0.873} 1203807 160.0.00 148 7 8821

76 Pyrene 202 17.683 17.683 (0.886) 2109351 80.0000 78.19

77 ButyIbenzylphthalate 149 18.816 18.816 (0.943) 837050 80.0000 77.32 9192

78 3,3'-Dichlorobenzidine 252 19.830 19.830 (0.994) 571523 80.0000 74.96 8084

79 bis (2-ethylhexyl)Phthalate 149 19.780 19.780 (0.992) 1257689 80.0000 77.90 9433

80 Benzo (a)janthracene 228 19.915 19.915 (0.998) 1955302 80.0000 79.05

31 Chrysen* 228 19.999 19.999 (1.003) 1797549 80.0000 77.08

82 Di •n -oct y lphchalate 149 20.760 20.760 (0.925) 1305562 80.0000 76.87

93 Benzo{b) fluorant hene 252 21.690 21.690 (0.967) 1385076 80.0000 86.06

ft4 Benzo (k) f 1 uoranthene 252 21.741 21.741 (0.969) 1049072 80.0000 72.13P

Benzo(a) pyrene 252 22.333 22.333 (0.995) 997775 80.0000 78.25

3 6 1 ndeno(1 ,2.3-cdipyrene 276 25.021 25.021 (1.115) 718869 80.0000 78.02 0 (M)

87 Dibenzo a,hiant hracene 278 25.021 25.021 (1.115) 866844 80.0000 77.54 8247

8 8 Benzo(a, h,l)perylene 276 25.849 25.849 (1.152) 915216 80.0000 78.07 9281

QC Flag -.egend

M - Comp Dund response manually integrated.

3- //- „ l

Data File: /chem/5972hp64.i/DF020311A64.b/HG020311A64.d Injection Date: ll-MAR-2002 08:55 Instrument: 5972hp64 . i

Data File: /chem/5972hp64.i/DF0203llA64.b/HG020311A64.d Injection Date: ll-MAR-2002 08:55

COMPUCHEM a division of Liberty Analytical Corp DATE 3 / // Id INITIAL TIME OF TUNE off b 2. SH1FT/S(A) (B)(C)

GC/MS SEMIVOLATILE RUN LOG TIME TUNE EXPIRES 2 51 LINKER/METHOD___* y 'COMPUCHEM .LOGBOOK 4 YYY 4 (5972hp64)

T1 fTl PREVENTIVE MAINTENANCE/VrY\ t,

(CT(

FILENAMEo*TED


CHEMIST COMMENTSIPTC VlMpU^lTft tNLO 'cj-

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STANDARDS / * ^ /Tune Analytical hit. Std. Column Type SUPERVISOR APPROVAL ZZ-./j'AZ

StdrlD#---Z-SA ------ k > -•---- _______________________ DATE'ZjjJ.io > _____________________ __________

Lot #-— ^ C 3 /3 2 '6 /_____ __S i S \ V( I he presence of the Chemist's employee II) numhci. or srgnrmne. on this rim log attests that strict compliance with the method's St H

occurred Any SOP deviations require documentation by the responsible chemist together with the chemist s initial-, and the initials -

Idh supervisor aru^if,)A department represeritatue siuriil) ine approval ol the deviation __ I I .'o.;(i|


Lab Name: COMPUCHEM

Lab Code: LIBRTY Case Instrument ID: 5972HP64

Lab File ID: HG020311B64

Contract: 8270C

No.: SAS NO.: SDG No.: QE1877


Init. Calib. Date(s): 03/10/02 03/10/02


GC Column: RTX-5 ID: 0.32 (mm)

COMPOUND

Phenol_J____________________Bis (2 - chjloroethyl) ether

Chlorophenol_

1, 3-Dichlorobenzene_ 1,4 -DiclJlorobenzene_

1,2- Dich'lorobenzene_

2-Methvlphenol_______

2,2' -oxybis(1 -Chloropropane) 4 - Methyllphenol

N-Ni trosjo-di - N - propylamine__

Hexachioroethane

Nitrobenzene

Isophorone

Nitrop'henoi

thylphenol_4 -Dime

|Bis(2 -ch j2,4-Dich

|1,2,4-Tr j Naphthal

! 4 - Chi oro'ani line

loroethoxy)methane_

lorophenol___________

ichlorobenzene_

ene

| Hexachlorobutadiene_____

| 4-Chloro-3-methylphenol_

| 2-MethyLnaphthalene_____

Hexachiorocyclopentadiene

i 6 - Tr

5 - Tr

ichlorophenol_

ichlorophenol

j 2 -Chloronaphthalene_

! 2-Nitroani1ine

;Dimethylphthalate_2,6 -Dinijtrotoluene

'■ Acenaphthylene______! 3-Nitroajnil me_

1 A.cenaphthene___

2,4 -Dinijtropnenol

4 -Nitrop'henoi_____

! 2 , 4 -Dmi|trotoluene

; Dibenzofuran

! Diethylp'hthalate_____________

| 4 -Chloropheny1 - phenylether i Fluorenel

i 4 - Nit roam line. i

6-Dinitro-2-methvlohenol

page 1 of 2

|RRF80.000| 1 1 1 1

RRF OR | OR | MIN %D OR 1 MAX %D OR|CURV|

AMOUNT |AMOUNT |

1 |RRF

j%DRIFT

1

%DRIFT jTYPE

1 I

1.4530000|1.4288473|----- i0.01 I

-------- 1-1.66 1 2 0.0 0|AVRG|

0.9870000 I 0.9319326 j0.01 -5.58 50.00 AVRG]

1.3440000|1.2835053| 0.01 1 -4 . 50| 5 0.0 0|AVRG j

1.5440000|1.4632976 | 0.01 j -5.23 j 50.00|AVRG|

1.5580000|1.4927116| 0.01 -4.192 0.00 AVRG j

1.5340000 1.4513183 j 0.01 1 -5.39| 50.00|AVRG|

1.1720000|1.1246352 | 0.01 j -4.04 j 5 0.0 0 jAVRG|

1.8230000|1.7604245| 0.01 -3.435 0.00 AVRG j

1.2740000 1.2347748 j 0 . 01 1 -3.08 | 5 0.0 0|AVRG

0.8030000|0.7450387 0.05 1 -7.22 j 50.00 j AVRG

0.8060000|0.7630464 | 0.01 1 -5.33 | 5 0.0 0|AVRG|

0.3400000 0.3503588 | 0.01 3.05 | 5 0.0 0 j AVRG

0.6730000|0.6693175 0.01 1 -0.55 j 50.00]AVRG|0.2150000|0.2121352 j 0.01 1 -1.33

2 0.0 0|AVRG j

0.3200000 0.3120055| 0.01 1

1 to o 50.00 AVRG

0.4020000|0.4105081 0.01 j 2 . 12 1 50.00|AVRG|

0.3310000 0.3376091 0.01 2.00 20.00 AVRG0.3860000 0.3810025 | 0.01 1 -1.29 50.00 AVRG|

1.4460000|1.4735112 0.01 1 1.90 | 50.00|AVRG|

0.4620000|0.4780432 I 0.01 1 3 . 47 j 5 0.0 0|AVRG j

0.2660000|0.2634745 | 0.01 1 -0 . 95 | 2 0.0 0|AVRG|0.3680000 0.3647257 j

0.01 -0.89| 20.00 AVRG0.7240000|0.7112745 0.01 -1 . 76 | 50.00 AVRG0.3960000|0.3675725 | 0.05 1 -7 . 18| 50.00|AVRG|

0.4070000 0.4156495 | 0.01 2.12 | 20.00|AVRG|

0.4320000 | 0.4243734 | 0.01 ■ -1.76 50.00)AVRG]

1.0260000 j1.0308065 j 0 . 01 1 0.47 | 50.00|AVRG|

0.3670000 0 . 3725542 0.01 1 1 . 51 | 50.00 AVRG1.2540000 1.2582962 1 0.01 0.34 50.00 AVRG0.345000010.3419095| 0 . 01 1 - 0.90| 5 0.0 0|AVRG)

2.4090000 2.3558S10 0.01 1 -2.20 50.00 AVRG0.3650000|0.3619142 0.01 -0.84 50.00 AVRG1.5590000|1.5356203 | 0 . 01 1 -1 . 50| 2 0.0 0|AVRG|

0.061000010.0600705 0.05 -1.525 0.0 0 jAVRG

0.2170000|0.2001577 0.05 -7.76 50.00 AVRG0.5000000|0.5006206 | 0.01 1

0.12 j50.00|AVRG|

1.6140000|1.5783827 j 0 . 01 1 -2 . 21 | 50.00|AVRG

1.4840000|1.4485386 | 0.01 -2.39 50.00)AVRG

0.6930000|0.6786956 J 0.01 j -2.06 50.00 AVRG[

1.8520000|1.8147222 | 0 . 01 1 -2.01 5 0.0 0|AVRG|

0.33000000.3698028 0.01 to CTi

CO 50.00 AVRG|

0. 16 20000i0.1618847 j

i 1

0 . 01 11

-0.07|

1

50.00 AVRG|1 1

FORM VII SV



I Lab Code: LIBRTY Case No.: SAS No.: SDG No.: QE1877

Instrument ID: 5972HP64 Calibration Date: 03/11/02 Time: 2253I




1 | |RRF8 0.0 0 0| 1 1 1 1

| COMPOUND |RRF OR OR MIN | %D OR MAX %D OR|CURV|

1

|AMOUNT AMOUNT

1 1 1

RRF |

1%DRIFT

1

%DRIFT |TYPE|

| i

|N-Nitrosodiphenylamine | 0.4360000 I 0.4252453 |----- 10.01 I

-------- 1-2.471

----------- 1 — i2 0.0 0|AVRG|

1 4 -Bromophenyl-phenylether ] 0.2120000|0.2045793] 0.01 j -3.50] 50.00|AVRG|

|Hexachlorobenzene | 0.2610000 0.2538997| 0.01 -2.72[ 50.00 AVRGiPentachlorophenol 0.1740000|0.1662047 0.05 -4.48 | 20.00|AVRG

I Phenanthrene 1.4880000 1.4072421| 0.01 I -5.43 50.00|AVRG|

iAnthracene | 1 . 5130000|1.4303164| 0.01 j -5.46 | 50.00|AVRG j

Carbazol 0 I 0 . 9960000|1.0017379| 0.01 0.58 5 0.0 0|AVRG

I Di - n - butivlphthalate 1.4890000 1.4193083 0.01 1 -4.68| 5 0.0 0 j AVRG

!Fluoranthene 1 . 7160000 1.6799277| 0.01 1 -2.10| 20.00 j AVRG|

i Pyrene j 1 . 9180000|1.8215947 j 0.01 1 -5.03] 50.00]AVRG]

!Butvlben zvlphthalate jO.7700000 0.7258042 0.01-5.74 j 50.00|AVRG

!3,3'-Dichlorobenzidine 0 . 5420000 | 0.5545583| 0.012.32 j 50.00|AVRG

1 bis(2-ethvlhexvl)Phthalate | 1 . 1480000 j 1 . 1003856 j0.01 -4.15 50.00|AVRG|

hpnzo(a)Anthracene j 1 . 7590000 1.6720496 0.01 -4.945 0.00 AVRG j

PFhrysene j 1 . 6580000 | 1 . 5703507 0.01 1 -5.29 5 0.0 0|AVRG|

1Di-n-octylphthalate 2 . 2640000|2.1379883 | 0.01 j -5.56| 2 0.0 0|AVRG j

Benzo(b) fluoranthene2 . 1450000|1.7689854 j

0.01 -17.53| 50.00 AVRG|

!Benzo(k) fluoranthenej1 . 9380000|2.3180102| 0.01 1 19.61j 50.00|AVRG|

! Benzo (a) pvrene j1.7000000 1.6622862 0.01 -2.22 | 20.00|AVRG|

!Indeno(1 , 2,3 -cd)pyrene | 1 . 2280000|1.1811904| 0.01-3 . 81j 50.00|AVRG j

!Dibenzo( a,h)anthracene | 1 . 4900000 1.4441409| 0.01 -3.08 | 5 0.00 AVRG j

| Benzo i g, h, l)perylene | 1 . 5630000 j 1.5193161 0.01 -2 . 79| 50.00|AVRG|

i 2 - Fluorophenol 1 . 2980000 1 . 2760461 0.01 -1 . 69| 5 0.0 0 j AVRG

: Phenol -d 5 1 . 6910000 1.6267774 0 . 01 1 -3 . 80| 5 0.0 0|AVRG

Nitroben zene-d5 0.43300000.44585451 0.01 2.97 | 50.00 jAVRG

[•J

I—*

c 0 d biphenvl j1 . 3330000 1 . 3289473 | 0 . 01 1 - 0.3 0 j 5 0.0 0 j AVRG|

:2,4,6-Tr ibromophenol 0.4030000(0.3861743 0.01 j -4.18 50.00 AVRG|

1Terpheny 1 -dll 1 . 0590000|0.99011981 1 1

0.011

-6.501

50.00 AVRG

1 1

a o erORM VII SV

59b

Data Files /chemr,5972hp64. i /BF020311B64. b/HG020311B64. d

Date S ll-MAR-2002 22:53

Client IDS SSTD080 Instrument: 5972hp64.i >-

Sample Info: SSTD080S2319 CJ^

Volume Injected <uL>: 1.0 Operator; 2319 LO


Phenanthrene-dlO-

Data File: /chem/5972hp64.i/DF020311B64.b/HG0203UB64.d

Date t ll-MAR-2002 22:53

Client ID: SSTD080



Column phase: RTX-5

Instrument; 5972hp64.i lO

cnOperator: 2319 LO


Data File: /chem/5972hp64.i/DF020311B64.b/HG020311B64.dReport Date: ll-Mar-2030 23:20

Data file Lab Snip Id Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal DateAls bottle Dil Factor Integrator

CompuChem

Semivolatile Report SW-846 Method 8270C /chem/5972hp64.i/DF020311B64.b/HG020311B64.d SSTD080 Client Smp ID: SSTD080ll-MAR-2002 22:53 2319SSTD080:2319

Inst ID: 5972hp64.i

/chem/5972hp64 ll-Mar-2030 23 10-MAR-2 0 02 17 2

1.00000

HP RTE Target Version: 3.50Processing Host: einstein

i/DF020311B64 20 naegler 23

. b/8270Cv6.m Quant Type: ISTD Cal File: HL020310A64.d Continuing Calibration Sample





Vt 1000.00000 Volume of final extract (uL)p

Vo 1000.00000 Volume of sample extracted (mL)

Vi 1.00000 Volume injected (uL)

Cpnd Var iable Local Compound Variable

AMOUNTS

QUANT SIG CAL-AMT Oh -COL

Compounds MASS RT EXP RT REL RT RESPONSE ( NG) ( NG)

{1,4-DicHlorcbenzene -d4 152 S . 264 8.264 (1.000) 123003 40.0000

-Naphtha l'er.e - cl S 136 10.158 10.158 (1.000) 450795 40.0000

• T Acenaphi her.e-dlC' 164 13 167 13.167 (1.000) 321474 40.0000

*T Phenanzhrene -d 1 0 188 15.483 15 ‘1 3 3 (1 .000) 666326 40.0000

Chrvser.e -d)2 240 19.963 : 9 . 56 3 !I .000) 642652 40.0000

* 6 Perviene'

- d 1 2 264 22.445 2 2.44 9 i1 .0 0 0) 350874 40.0000

7 2 ■ r \uorocrteno1 j-

112 6.456 6.455 (0.781) 313915 80 - 0000 78 62

C - Pheno!•d5 99 7.757 7.757 (0.939) 400197 80.0000 76 95

N:2 rober z e r. o - a 5 82 5.105 6 . 10 9 (0.697) 401978 80.0000 82.39

. 0 2 -F1uorofc•ohenv1i

17 2 11 . 8 S 2 1!.582 (0.902) 854444 80.0000 79.78

: : i lbr omophenc 3 30 14 .466 1 4 .4 69 i 1 .099) 248290 80.0000 76.71

c ; 2 : erpher.\ 2 - d: 4 244 1 7 . S 6 7 17.567 (0.695) 1272605 80.0000 74 . 00

'■ : N - N11 rosco i met nv larrl

ine 42 4.542 4.342 (0.525) 116554 80.0000 79 . 39

‘.4 ?yv \ d : r.f 7 c. 4 2 2 F 4.325 : C.5 2 3) 203742 80.0000 80.05

SIMILARITY

(M) |

8711

9454

frO

59 S Mo>-


Compounds

15

16

17

10

19

20

21

22

2 3

24

25

26

27

26

29

30

3 1

7

33

34

39

4 0

43

44

45

4 6

4 7

4 5

49

Benzaldehyde

Phenol |

Bis (2-ch'loroet hyl)ether

2-ChlorophenolI

1, 3 -Dich'lorobenzeneI

1,4 -Dich'lorobenzeneI

Benzyl alcoholI

1,2 -Dichlorobenzene

2- Methylphenoli

2,2'-oxybis{1-Chloropropane)

Acetophenone

3- Methylphenol

4- Methylphenol

N-Nitroso-di-N-propylamine

Hexachioroethane

Nitrobenzene

1 sophorone

2-Nitrophenol

2.4- Dimethylphenol

Bis (2 -chloroethoxv)methaneI

2.4- Dichlorophenol

1.2.4- Trichlorobenzene

Naphthalene

4 -Chloroaniline

HexachlorobutadieneI

Caprolactam

4 - Ch 1 c ro J- 3 - met hy 1 pheno 1

2-Methyl naphthalene

1-Methvinaphthaiene‘ I

Hexachlorocyclopentad:ene

2.4.5- Tnchlo rooheno 1

2,4,5-TrichloroohenolI

- , 1 ' - B i pher.y 1

2 -Ch1oronaphtha 1ene

2 - N i t roar, i 1 i nei

D i me t h y 1 p n t ha 1 a t et

2,6 - D i n : t r c t o 1 u e n e!

Acenaphthylene

3 - Ni t ro-'.n L1 : r.cI

Acenauhthene■ i

2 . 4 - P j n 11 rophe r.o 1

4 -Nitropheno1

2 . 4 - Dm: tret o in ene Dibenzoilran

Diethyip h t na i at -

4 - Ch I oropher.y 1 - phenyl ether

Fluorene

AMOUNTS



77 7.639 7 .639 (0.924) 206263 80.0000 76.57 9764

94 7.774 7.774 (0.941) 351505 80.0000 78.65

93 7.909 7.909 (0.957) 229261 80.0000 75.50

128 8.010 8.010 (0.969) 315750 80.0000 76.40 8907

146 8.213 8.213 (0.994) 359980 80.0000 75.81

146 8 .281 8.281 (1.002) 367216 80.0000 76.64

108 8.467 8.467 (1.025) 185510 80.0000 76.15

146 8.568 8.568 (1.037) 357033 80.0000 75.70

108 8.636 8 . 636 (1.045) 276667 80.0000 76.77

45 8.670 8.670 (1.049) 433075 80.0000 77.23 9063

105 8 . 873 8 . 873 (1.074} 403904 80.0000 77.55 8639

108 8 . 839 8.839 (1.070) 303762 80.0000 77.54

108 8.839 8.839 (1.070) 303762 80.0000 77.54

70 8 . 873 8.873 (1.074 ) 183284 80.0000 74.24 0 (M)

117 9.008 9.008 (1.090) 187714 80.0000 75.70 9488

77 9.126 9.126 (0.898) 315880 80.0000 82.47 9707

82 9.448 9.448 (0.930) 603450 80.0000 79.57 9454

139 9.600 9.600 (0.945) 191259 80.0000 79.10 8394

122 9.600 9.600 (0.945) 281301 80.0000 70.05 7495

93 9.752 9.752 (0.960) 370110 80.0000 81.76 9538

162 9 . 938 9 . 938 (0.978) 304385 80.0000 81.54

180 10.073 10.073 (0.992) 343508 80.0000 78.92

128 10.175 10.175 (1.002) 1328503 80.0000 81.54 9764

127 10.259 10.259 (1.010) 430999 80.0000 82.72 8206

225 10.428 10.428 (1.027) 237546 80.0000 79.24 8793

113 10.732 10 . 732 (1.057) 107053 80.0000 83.83 9501

107 10.935 10.935 (1.077) 328833 80.0000 79.29 9776

142 11 .223 11.223 (1.105) 641270 80.0000 78.53

142 11.409 11.409 (1.123) 617137 80.0000 79.20

237 11 . 595 11.595 (0.881) 236330 80.0000 74.22 8926

196 11 . 747 11 . 747 (0.892) 267241 80.0000 81.68

196 11 . 831 11.831 (0.899) 272850 80.0000 78.61

154 12.066 12.068 (0.917} 768624 80.0000 79.82 7592

162 12.119 12.115 (0.920) 662755 80.0000 80.36

65 12.355 12.355 (0.938) 239533 80.0000 31.13 9292

163 12.677 12.677 (0.963) 809019 80.0000 80.28 9463

165 12.346 12.346 (0.976) 219830 80.0000 79.27 8272

152 12.396 ' o q £ (0 . 979) 1514709 80.0000 78 . 24 9610

133 1 3 . 0 8 2 13 . 082 \0 . 994) 232692 800.000 92.97 9421

154 15.213 13.218 (1 .004) 987324 80.0000 70.80 9654

184 13.268 13 .268 f'l. 008 )193111 400.000 393.7

109 13.319 13.319 (1.012) 128691 00.0000 73.71 8006

165 13.522 1 3 5 2 2 (1.027) 321873 80.0000 80.08 8199

163 13.43? 13.458 (1.024 ) 1014818 80.0000 78 .23 9023

14 5 13.860 1 3 . 650 (1.053) 931335 80.0000 78.09 9710

2 04 1 4 . C 1 2 14.?12 (1.064) 436366 30.0000 78.31 0 (M)

18 6 14.045 14.046 (1.067) 1166772 00.0000 78.38 7662

ft)

60U

b. Continuing Calibration Data (Form VII SV)

If more than one instrument is used, forms shall be arranged in order by instrument. If multiple continuing calibrations from the same instrument are used, they shall be in chronological order.

(1) Reconstructed Ion Chromatograms and quantitationreports for all continuing (12-hour) calibrations; Spectra not required

(2) EICPs displaying each manual integration

551


Lab Name: COMPUCHEM Contract: 8270CLab CcJde : LIBRTY Case No.: SAS No.: SDG No.: QE1877


Init. Calib. Date(s): 03/03/02 03/03/02



Lab Fi le ID: HG020312A60

I

COMPOUND

Phenol |

I Eis(2 -chloroethvl)ether

| 2 -Chlorophenol_______| 1, 3 -Dichl!orobenzene_

j1,4-Dichiorobenzene_

j 1,2-Dichiorobenzene_

|2-Methvlphenol_______

12,2'-oxybis(1 -Chloropropane)

; 4-Methvlphenol________________

j U-Nitroso-di-N-propylamine_

jHexachlonoethane

Nitrobenzen

sophorone____

Mitrophenol_

, _ , 4-Dimethylphenol___________! B i s ( 2 - chlloroe t hoxy} me t hane

i 2 , 4 -Dichilorophenol___________

; 1 , 2 . 4 -Trilchlorobenzene

| Naphthalene

: -Chloroanilme I

l Hexachloi'obutadiene_____

i 4 -Chloro-j3 -methvlphenol


Hexachlorocyclopentadiene 2 , 4 , 6 - Tr ilchlorophenol

5-TrJchioroDhenoi

2 - Chloronaphchalent

2 - N11 roa ni1ine_____

Dimethylphthalate_

2,2'Dmitrotoluene

Acenaphthylene_____

2 - Nit roan i 1 me

Acenaphthene_______2 , 4 -Dmidrophenol

4 -Nit rophenoI_____

: - umi drotol uene I

Dibenzofuran

D i e c h yl p h t h a 1 a t e_____________

4 -Chiorophenyl -phenyiet’ner Fluorenej

. - Ni t roan 11 me; -Dinidro- 2 - me thvlphenol

I _ _ ;iage 1 o

1 |RRF80.000| 1 1

|RRF OR 1 OR | MIN | %D OR 1 MAX %D OR

AMOUNT AMOUNT | RRF %DRIFT | %DRIFT|

| 1 . 3820000 | 1 . 20082220.01 j -13.11j

20.00

0 . 9520000jo. 9599782

0.01 0.84 50.00|1.0880000 1.1040369| 0.01 1.47 50.00| 1.4910000 j1.5304621j 0.01 j 2.65 j

50.00

1.4860000j 1.6051513| 0.01 j

8.02 20.00

1.4310000 1.4978057| 0.01 4.67 50.00i 0.8830000 | 0.8964040 j 0.01 1 1.52 | 50.00| 1.3580000 j1.3558819 j 0.01 j -0.16 j

50.00

1.1220000| 1.0598048 j 0.01 1 -5 . 54 | 50.00

| 0.8140000 | 0 . 7984051 0.05 1 -1.92 | 50.00| 0.6340000 j 0.7273466 0.01 j

14.72 50.00

0.4960000 0.4643285) 0.01 -6.38 50.00j0.7810000 j 0.7513808| 0.01 j -3 . 79 j

50.00|0.24 50000 0.2498400 j

0.01 1.98 20.00

0.29700000.2919625 j

0.01 -1.70] 50.00

0.4700000 0.4839004 0.01 2.96 50.00

0.4380000 | 0.4323532 0.01 1 -1 . 29| 20.00

0.5200000 0.51612320.01 j -0.74 | 50.00

] 1 . 1890000j 1 . 2196058 j

0.01 2.57 50.00jO.5010000 0.4843112 0.01 -3.33 50.00j 0.4060000 | 0.4212530 j 0.01 j 3 . 76 j

20.00|0.3640000 j 0 . 3220704 j 0.01 1 -11 . 52 | 20.00

0.8860000 0.9245955j 0.01 4.36 50.00|0.4600000 0.4811605 0.05 1 4.60 50.00

0.4400000 0.40386580.01 j -8 . 21| 20.00

0.47900000.4606443j 0.01 j

-3.83 50.00|1.2400000 |1.2204970) 0.01 -1 . 57 j 50.00

0.4830000| 0.4824943 j 0 . 01 1 -0.10 50.00

1.6290000 ! 1. 518 3 174 ) 0.01 j-6.79 50.00

|0.3470000 10.3333067) 0.01 j -3.95) 50.00j1.9950000 | 1 . 8703951 o. oi j -6.24 50.00j0 . 3690000 10.3375703 0.01 -8.52 50.00

1.1730000 1.0784801 ] 0.01 -8.06 20.00

0.2170000 jO.1883675 0 . 05 j- 13 . 19| 50.00

| 0 . 2960000 |0.2992935 | 0 . 05 1 1 . 11 | 50 . 00jo.5140000

0.5124825 0.01 -0.30 50.00

2.1810000 12.1805926 0.01 - 0.02 j . 50.00j1.7600000 j1 . 6800357 j

0.01 -4.54 50.0010.9600000 | 0 . 3236261|

0 . 01 j -3 . 27 j50 . 00

j 1 . 7420000| 1 .7378112 i

0.01 1 -0.24 50.00! 0.3720000 j 0.360 594 5 j 0.01 -3 . 06| 50.00

10.1660000 )0.1500552 j 0.01) - 9.6 0 j50.00

CURV

TYPE

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVRG

AVP.G

AVRG

55,FORM VII SV


Lab Nabe: COMPUCHEM Contract: 8270CLab Cojde : LIBRTY Case No.: SAS No.: SDG No.: QE1877





I COMPOUND

N-Nitrosodiphenylamine____

4-Bromophenyl-phenylether_

Hexachlorobenzene

Pentachlgrophenol

Phenanthrene______

Anthracene_________

Carbazole

Di-n-butvlphthalateFluorantLene__________Pvrene I

Butylbenzylphthalate___

3,3'-Dichlorobenzidine

is (2 - ethylhexyl)Phthalate

enzo (a)anthracene___________

hrvsene

|Di-n-octylphthalate____

| Benzo(b)fluoranthene___

! Benzo(k)fluoranthene___

| Benzo(a)pyrene___________; Indeno(1J2,3 -cd)pyrene

1Dibenzo(a,h!anthracene_

i Benzo(g,h,l)perylene___

2 -Fluorophenol_

Phenol - d5

|Nitrobenzene-d5_______

I 2 -Fluorobiphenyl

| 2,4,6 -Tribromophenol

: Terohenvl-dl4

|RRF80.000| 1 1 !

RRF OR | OR | MIN | %D OR 1 MAX %D OR|CURV

AMOUNT AMOUNT |

| iRRF %DRIFT

1%DRIFT TYPE

1 10.5330000|0.4895377|

------10.01 I

-------- 1-8.151

----------- 1 —20.00|AVRG

0.3000000 I 0.2626789| 0.01 1 - 12.441 50.00|AVRG

0.3410000 0.3108058| 0.01 1 -8.855 0.0 0 j AVRG

0.1000000|0.1101310 0.05 j 10.13 | 2 0.0 0|AVRG

1.2540000 1.2258290] 0.01 -2.255 0.0 0 j AVRG

1.2630000|1.2439978 | 0.01 1 -1.50| 50.00|AVRG

0.9800000 0.9122507 0.01 1 -6 . 91| 5 0.0 0|AVRG

1.6380000|1.5921469| 0.01- 2.8 0 j 50.00|AVRG

1.4490000|1.4257731 | 0.01 1 -1.60| 2 0.0 0 j AVRG

1.4350000|1.3502826 | 0.01 1 -5.90 | 50.00|AVRG

0.7410000|0.6995314 | 0.01 1 -5.60| 50.00|AVRG0.5660000 j 0.5708737 0.01 1 0.86 j 5 0.0 0 j AVRG

1.0350000 1.1977421 | 0.01 15.72 50.00|AVRG

1.4320000|1.6669665 | 0.01 1 16.41| 50.00 jAVRG

1.2900000|1.2586506 0.01 -2 . 43 | 5 0.0 0 j AVRG

2.0140000 2.3464786 | 0.01 1 16.51j 2 0.0 0 jAVRG

1.7250000 1.7012509| 0.01 j-1.38 50.00 AVRG

1.5600000 2.0517998 0.01 31.52| 50.00|AVRG

1.3800000|1.5755806 | 0.01 1 14.172 0.0 0 jAVRG

1.4730000 1.7135069 j 0.01 j16.33 50.00 AVRG

1.2820000 | 1. 5240366 j 0.01 j18.88 | 50.00 jAVRG

1.2410000] 1 . 4501195| 0.01 1 16 . 85 j 50.00 jAVRG

1 . 2730000 1.0698895j0.01 1

-15.96 j 50.00 jAVRG

1.4360000|l.34122051 0.01 i-6.60 | 5 0.0 0 j AVRG

0 . 5720000 | 0.5583955i 0.01 j -2.38 | 50.00|AVRG1.5550000|1.44 80327 j 0.01 1 - 6 . 8 8 j 5 0.0 0|AVRG

0.3760000 0.3336466 0.01 -11.26 50.00 AVRG1.110 0 0 0 0 | 1 .0273398! 0.01 1 -7.45! 50.00 IAVRG

page 2 o f 2FORM VII SV

b5 j

Data Filet /chem/5972hp60.i,'DF020312A60.b,'HG020312A60.d

Date t 12-MAR-2002 10:17

Client ID: SSTD080 Instrument: 5972hp60.i ‘ J"

Sample Info: SSTD080J917 LO

Volume Injected <uL); 1.0 Operator: 917 LO

Column phase: J&W DE-5.825 Column diameter: 0,32

-Ph.sn.ar> fchr • ■=■ r. a

j

Sample Info: SSTD0801917


Column phase: J8.W DB-5.625 Column diameter: 0.32


Date : 12-MAR-2002 10;17


.5

5b


CompuChem

Data fi Lab Smp jId Inj Date Operator Smp Info Misc Info Comment{ MethodMeth DateCalAls

Date bottlle

Dil Facdor Integrator

Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020312A60.b/HG020312A60.d SSTD080 Client Smp ID: SSTD08012-MAR-2 002 10:17917 Inst ID: 5972hp60.iSSTD080:917

/chem/5 9 72hp6 0.i/DF020312A60.b/8270Cv6.m12-Mar-2030 10:50 mikhael Quant Type: ISTD03-MAR-2002 17:20 Cal File: HL020303A60.d2 Continuing Calibration Sample1.00000

HP RTE Compound Sublist: all.subTarget Version: 3.50Processing Host: einstein



DFVtVoVi

1.00000

1000.00000

1000.00000

1.00000



AMOUNTS

CUANT SIG CAL-AMT ON-COL

Conpcur.ds MASS RT EXP RT REL RT RESPONSE ! NG) ( NG) SIMILARITY

* 1 1 , 4 - D i c r lot ober.zene • d4 152 6 . 123 9.123 (j.000) 100945 40.0000

• 7 Naohc ha! e n e - d 6 13 5 10.238 10.288 (1.000) 296932 40.0000

3 Acenaphcr

her.o • d 1 C 164 13.351 13.351 (1.000) 244221 40.0000

4 P h <° p. a n z r r e n e - d 1 C 18 8 15.973 15.973 (1.000) 476283 40.0000

• Chrysene - a; 24 G 20.608 20 60S (1.000) 517505 40.0000

• 'Je rv i ene -dll 2 64 23.163 23.163 (1.000) 375407 40.0000

: 7 - . 112 6 . 003 6 008 (0.740) 216000 80.0000 67.24

r 3 Phene 1 - d'5 59 7 . 565 7.565 (0.931; 270779 80.0000 74 . 70

3 9 Nilroben z e n »"■ • b 62 5 . 0 5 3 ? . 353 '0.880' 331611 80.0000 78.11

1C e.pner.y. 172 12.166 12. 146 (0.911) 707280 80.0000 74 .49

; ; ; - -“ ■ ‘ 1 r 3 3 G 14.755 14 . 755 (1.105) 162967 80.0000 70.92 (M)

: -.2 Terpheny . .. .--a-- 244 i 3 . 7 S 1 13.751 (0.911) 1063307 80.0000 74 . 03

^ 7 u... _ 42 3.365 3 . 3 6 9 (0.415) 346238 80.0000 91 . 99 8710

14 Pyridine 7 :■ 3.403 i' .403 (0.419) 691561 80.0000 132.3 9175

Data Fi e:

Report Date

/chem/5 972hp6 0.i/DF02 0312A60.b/HG02 0 312A6 0 . d : 12-Mar-2030 10:50

Compounds

15

16

17

18

19

20

21

2 2

23

24

25

26

2128

29

30

31

32

33

34

35

3 6

39

4 u

4 1

42

4 3

4 4

9enzaldehyde Phenol|

Bis (2-chloroethyl)ether

2-Chlorophenol

1.3- Dichlorobenzene

1.4- Dichlorobenzene Benzyl|alcohol

1,2-Dichlorobenzene

2-Methylphenol

2,2'-oxybis (1-Chloropropane)

Acetophenone

3 -Meth^lpneno 1

4 - Met h\jlphenol

N-Nit roso-di-N-propylamine Hexachlbroethane

Nitrobenzene

Isophor.one

2-Nitrophenol

2.4- Dimethylphenol

Bis(2-chloroethoxy)methane

2.4- Dichlorophenol

1.2.4- TrichlorobenzeneI

Naphtha 1ene

4 -Chloroani i me

Hexachlorobutadiene

Caprolactam

4 -Chloro - 3-methylphenol

2-Methylnaphthalene

1 -Methyinaphtha 1ene

Hexachlorccyc 1 oper.t arii ene

2,4,5 -Trichicroohenol

46 2,4,S-Trichiorophenol

47 1.1'-B:pheny1

48 2 -Chloronaphtha 1ene

4 9 2 - Ni t roar, .line

r-C Dimethv l'ont r.a late

52 Acenapht-ny1ene

53 3 - Nit roar.: : : ne

54 Acer.apht her.e

55 .4 - Din: t ropheno1

5 6 4 -Nitrophenoi

5 5 Dibenzcr’jran

59 Dietr.y Lpht ha 1 at e

6 0 4 -Ch1oropheny1 -pheny1et he r

6 1 F *. u o r e n e

AMOUNTS

QUANT SIG


CAL-AMT

t NG)

ON-COL

( NG)

77 7 .396 7 . 396 (0.910) 115126 80.0000 71 .45

94 7.599 7.599 (0.935) 242434 80.0000 69.48

93 7.700 7.700 (0.948) 19381G 80.0000 00.71

128 7 . 785 7.785 (0.958) 222894 80.0000 81.20

146 6.021 8 . 021 (0.988) 308985 80.0000 82.09

146 8.157 B . 157 (1.004) 324064 80.0000 86.41

108 8.377 8 . 377 (1.031) 131809 80.0000 74 . 75

146 8.411 8.411 (1.035) 302392 80.0000 83.76

108 8.580 8 . 530 (1.056) 180975 80.0000 81.23

45 8 . 597 8.597 (1.058) 273739 80.0000 79.86

105 8 . 800 8 . 800 (1.083) 321662 80.0000 80.44

108 S 8.834 -" 8 . 834 (1.087) 213964 80.0000 . 75.57

108/ 8 . 834x 8.834 (1.087) 213964 80.0000 75.57

70 8 . 817 8.817 (1.085) 161190 80.0000 78.44

117 8 . 969 8 . 969 (1.104) 146844 80.0000 91.76

77 9 087 9.087 (0.883) 275748 80.0000 74.87

82 9.493 ✓ 9.493 (0.923) 446218 80.0000 76.94

139 9.629 9.629 (0.936) 148371 80.0000 81.59

122 9 730 9.730 (0.946) 173386 80.0000 78.58

93 9 882 9 . 392 (0.951) 287371 80.0000 82.30

162 10.069 10.069 (0.979) 256759 80.0000 79.02

130 10.187 10.187 (0.990) 306507 80.0000 79.45

128 10 . 322 10.322 (1.003) 724280 80.0000 82.07

127 1C.424 10.424 (1.013) 287615 80.0000 77.32

225 10.542 10.542 (1.025) 250167 80.0000 82.91

113 11.016 11.016 (1.071) 56348 80.0000 87.62

107 11 . 287 11.287 (1 . 097) 191266 80.0000 70.81

142' 11.523 11.523 (1.120) 549084 80.0000 83.47

14 2 11 . 693 11.593 (1.136) 449345 8 C.0000 84 . 51

237 11.794 11.794 (0.883) 235019 80.0000 83.72

195 12.031 12.031 (C.901) 197265 80.0000 73.37

196 12.116 12.116 (0.907) 224998 80.0000 76.87

1 54 12 . 352 12 3 c. 7 (0.925! 687495 80.0000 77.64

162 12 . 386 12.3-0 10.928) 596142 80.0000 78 .71

65 12.5^2 .2 5 n f 0 94 2' 471341 160.000 159.8

16 3 12.694 .2.694 i G . 9 6 6 1 741610 80.0000 74 . 55

16 5 12 9 ° 5 . 2 . v ? 5 ,2.973; 162801 80.0000 76 . 77

152 13.114 ■’ :: -i '0 ‘iiZ) 913580 80.0000 75 . 00

13 8 : 3.3 o ■: : 0.c 96) 329767 160 . 000 14 6.5

154 1 -i 4 • - 5 ^ -. C 1.005) 526775 90.0000 73.53

1 84 13 .486 ? . 4 36 i. o i o; 460033 400.000 346 . 9

109 u . o z , 292375 160.000 161.6

165 :: 3 . 7 06 1 .027) 250318 80.0000 79.70

168 13.723 -.723 1 .028i 1065093 80.0000 79.99

14? 14.12'.- 4.129 1.058' 820600 80.0000 76.36

204 ^ 4 . 3 1 6 1 .072: 453580 80.0000 77 . 35

1 6 6 ✓ ^.315/ 4.315 1.072) 848820 80.0000 79.83

SIMILARITY

8667

8893

7957

8233

7256

8949

9080

9068

8615

8607

8686

8940

8894

9286

8717 <M)

8726

8605

8524

9183

9285

9474

9589

9427

9173

8200

8497

9514

9462

726 1

7739

• 55 /'

Data FiLe: /chem/5972hp60.i/DF020312AGO.b/HG020312A60.d

Report Date: 12-Mar-2030 10:50

AMOUNTS


Compounds j MASS RT EXP RT REL RT RESPONSE ( NG) ( NG)

6 2 4-Nitroaniline 138 14.383 14 .333 (1.077) 352259 160.000 155.3

63 4 , 6 - Dir.it ro- 2 -me thy 1 phenol 198 14 .433 14.433 (0.904) 285875 160 000 145.0

64 N-Nitresodiphenylamine 16 9 14 . S35 14 535 (0.910) 466317 60.0000' 73.47

65 1,2 - Diphenylhydrazine 77 14.602 14 .602 (1.094) 893482 80.0000 83.43

6 6 4 -Bromophenyl•phenylether 248 15.178 15.178 (0.950) 250219 80.0000 69.96

67 Hexach1orobenzene 284 15.296 15.296 (0.958) 296063 80.0000 72.88

68 Atrazine 200 . 15.465 15.465 (0.968 ) 17940 80.0000 19.68

69 Pentachlorophenol 266 15.651 15 651 (0.980) 209814 160.000 176.5

7 0 Phenanthrene 178 16.024 16.024 (1.003) 1167683 80.0000 78.17

71 Anthracene 178 16.108 16.108 (1.008) 1184990 80.0000 78.80

72 Carbazoie 167 16.396 16.396 (.1.026) 868979 80.0000 74 . 50

7 3 Di-n-butylphthalate 149 16.988 16.988 (1.064 ) 1516625 80.0000 77.74

74 Fluoranthene 202 18.121 18.121 (1.135) 1358143 80.0000 78.69

75_ . 1Benziame 184 13 . 341 18.341 (0.890) 208629 160.000 61.34

76Pyrene J

202 18.510 18 . 510 (0.898) 1397556 80.0000 75.28

77 Buty1 benzylphtha late 14 9 19.610 19.610 (0.952) 724022 80.0000 75.52

73 3, 3' - Dichlorobenzidine 252 20.541 20.541 (0.997) 590860 80.0000 80.71

7 9 bis (2 - ethylhexyl ) Phthalate 149 20.574 20.574 (0.998) 1239675 80.0000 92.58

? 0Ber.zo la Jar.thracer.e

■ 223 20.591 20.591 (0.999) 1725327 80.0000 93 . 15

8 1 Chrysenej 228 20.642 20.642 (1.002) 1302716 80.0000 78.04

82 Di-n-octylphthaiate 149 21 . 556 ' 21.556 (0.931) 1761769 80.0000 93 . 19

Benzo I b; v luorant her.a 252 22.368 22 .368 (0.966) 1277323 80.0000 78.90

W' Benzo (k) 51 uorar.t her.e 252 22 .413 22.418 (0.968) 1540520 80.0000 105.2

85 Benzo ia:pyrene 2 52 23.044 23.044 (0.995) 1182968 80.0000 91.30

36I ndeno (l|, 2 , 3 - cd) py rene

276 26.056 26.056 (1.125) 1286525 80.0000 93.05

7 D: benzo (a , h ; ant nr acer.e 278 26.107 26.107 (1.127) 1144268 80.0000 95.09

6? Benzo (a , r. : oc-rv 1 er.e 27 6 26.952 26.952 (1.164 ) 1088770 80.0000 93.45

QC Flag begend


SIMILARITY

8150

9064

8577

9460

9312

9343

8571

8887

9047

9229

8561

9116

7095

9546

8729

8845

8014

55b

m

^^iS

Data File: /chem.'5972hp60.:/DF020312860.P/HG020312660.d Injection Dajte: 12-M8R-2Q02 10:1?

Instrument: 59?2hp60.i

lent Sample ID: S5TD080

pound: 2-,9 . b-Tr ibromophenoi ftS Mumper: 118-79-6

1.0-

0.9-

0.0-

0.7-

0 . b-

0.5-

Ion 329.60: Area: 162967 Height: 100792

is

0.4-;

ii

. 0.3-1 i

I

• 0.2- 1i1

1l

0.1-J I

\

14.3

)

14.4 19.5 14.6 14.7

Min

14.0 14.9 15.0 15.1 15.2


9.5- ;

9.0 •'

8.5-

8.0-

^ 7.5-

!

i\i i

il

6.5

6.0-

5.5

5.0- '

4 .5-

4.0- :

3.5-

2.0-

1.5-

1 .0-

0.5-:

r, m n-_14 .

I i

:5 14.'30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.05 14.90 14.95 15.00 15.05 15.10 15.15 15.20________ 1_____________________________________________________________________________Min_____________________________________________________________________

I Ion 141.00: ffrea: 0 Height: 0

1 . 4-

1 . 3-

1 .2-

1.1-

1.0-

j. 9-

). 8-

. b-

s-

/■ 5\5S

14.30 14.55 14.4-1 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.00 14.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20

i Min

Data File: /chem/5972hp60.1. Infection Date: 12-MAR-2002Instrument: 5972hp6u.i Client Sample ID: SSTD080

mpound: Caprolactam AS Number: 105-60-2

''DF020312h60 . b/HG020312A60. d

10:17


Lab Nalme :

Lab Code:

Instrument

COMPUCHEM

LIBRTY Case

ID: 5972HP60

Contract: 8270C

No.: SAS No.:

Calibration Date: 03/13/02

SDG No.: QE1877

Time: 1312

Lab File ID: HG020313A60 Init . Calib. Date (s) 03/03/02 03/03/02

l Init . Calib. Times: 1401 1720GC ColLmn: J&W DB-5.625 ID:

0.32 (mm)

COMPOUND

|Phenol 1_________

Bis (2 -chloroeth',I

| 2-Chlorophenol_

1)ether

3 - Dichlorobenzene_

4 -Dichlorobenzene_

,2 - Dichlorobenzene

-MethylphenolJ 2 , 2 ' -oxybis!1-Chloropropane)

I 4-Methvlphenol

|N'Nitroso-di-N-propylamine

! Hexachloroethane_____________

I Nitrobenzenel l----------------------Ksophororie______________________.

^■-Nitrophenol

I 2,4-Dimethylphenol___________| Bis ( 2 - chlloroethoxy) methane

| 2 , 4 - Di chllorophenol___________

I 1, 2 , 4 -Tri! chlorobenzene

|Naphthalene________________

! 4 - Ohio roam 1 me___________

i Hexachlorobutadiene_____j 4 - Chloro-j3 -methvlphenol

| 2-Methvlnaphthalene_____

! Hexachlci]ocyclopentadiene_ 1 2 , 4 , 6 - Tr ijchlorophenol _

2,4 5 - Tr iichlorophenol_

-Chloronaphthalene___

■ 2 - Ni t roani 1 me_____

' Dimethylphthalate_; 2 , 6 - Dim drotoluene_

i Acenaphthylene_____

: 3 -Hitroan.il me_____

: Acenaphtnene________! 2 , 4 - Dim tlrophenol_

■ i -Mitroph^enol

2,4-Dmic rotoiuene_

1 Dibenzofuran

Diethylph ! 4 - Chloropjh

;Fluorene

tnalate

;nvl-ohenvlether

-Hit roan1

6 - Dim t

Ll me

>-2 -methvlohenol

oaqe of 2

| |RRF80.000| I 1 1 1

RRF OR OR MIN | %D OR 1 MAX %D OR|CURV|AMOUNT jAMOUNT |

1 1 1

RRF |

|

%DRIFT 1

1

%DRIFT |TYPE|

1 |1 1 1 | 1.3820000 | 1.2278442 |

----- |0.01 |

-------- 1-11.151

----------- |----- j20.00|AVRG|

j 0 . 952000010.8673226| 0 . 01 I -8.89] 50.00|AVRG|j1.0880000 j1.1312333| 0.01 1 3 . 97 | 50.00|AVRG j

1.4910000 j1.5968505 0.01 1 7.10 j 5 0.0 0 jAVRG|

1 . 4860000 1 . 5874369 0.01 1 6.832 0.00 AVRG j

| 1.4310000|1.4962370| 0.01 1 4.56] 50.00]AVRG|

0.8830000| 0.9473773 [ 0.01 1 7.29 | 50.00|AVRG|

1.35800001.2232542 0.01 1 -9.92| 50.00 AVRGj1.1220000|1.0802883 | 0.01 1 - 3.72| 50.00jAVRG|

0.8140000 0.7091428 j 0.05 j -12 . 88| 50.00jAVRG|

| 0.6340000|0.7233980 0.01 14.10| 5 0.0 0 j AVRG

j0.4960000 j0.4463165 | 0.01 1 -10.02 | 5 0.0 0 j AVRG

|0.7810000|0.6969587| 0.01 1 -10.76 | 5 0.0 0 j AVRG j

|0.2450000 0.2454144 0.01 j 0.17 | 2 0.00 AVRG j

| 0.2970000|0.2887574 0.01 -2.7850.00|AVRGj

0.4700000 j0.4251300 |0.01 -9.55

5 0.0 0 j AVRG|

0.4380000 0.4618499 0.01 5.44 20.00|AVRG

0 . 5200000 0 . 5742556 0.01 10.43 50.00 AVRG1.1890000 j1.1563816 0.01 j -2.74 | 50.00 AVRG

i 0.5010000 j 0.4521012| 0.01] -9.76] 50.00]AVRG|

| 0.4060000 0.4734603| 0.0116.62 j 20.00 AVRG|

0.3640000|0.3475495 0.01 -4.52| 2 0.00 AVRG j

| 0.8860000|0.9501716| 0.01 1 7.24] 5 0.0 0 jAVRG]

[0.4600000 0.5344338 0.05 1 16.18 j 50.00 AVRG j

0 . 4400000 0.4514415 0.012 . 60 j 20.00|AVRG|

j 0.4790000 0.5203548 0.01 8.63] 50.00 AVRG1 . 2400000|1.1843315 j

0 . 01 I -4.49| 5 0.0 0|AVRG j

1 0 . 4830000 0.4375715 0.01) -9.40] 50.00]AVRG

i 1 . 6290000 j 1. 5470646 j 0.01 -5.03 50.00]AVRG

|0.3470000|0.3388357| 0.01] -2.35] 5 0.0 0 jAVRG|

| 1 . 9950000|1.9069708 j 0.01 1 -4 . 41 | 5 0.0 0|AVRG

! 0 . 3690000 0 . 3533331 0.01 -2.89 50.00 AVRGj 1 . 1730000 1 . 1826551

0.01 0.82 20.00 AVRGj0 . 2170000|0.1967293| 0.05] -9.34 j 5 0.0 0|AVRG|

| 0.2960000 | 0.3 196374| 0.05 7 . 98 | 5 0.0 0 AVRG! 0 . 5140000|0.5228070 0.01 1.71 50.00 AVRG1 2 . 1810000|2.2300703] 0.01] 2.25]

50.00 jAVRG|

1 . 7600000 jl.6732787 0.01 -4.93 50.00 AVRG0 . 9 50000010.9905059 j 0.01 3.18 5 0.0 0|AVRG

j 1 . 7420000 | 1 . 7087524 0.01 -1.91 50.00 AVRG|jo. 372000010.36156341

0 . 01 1 -2 . 80| 50.00|AVRG]

] 0. 1660000|0.1478998 j 0.01 1

1

-10.90]

1

5 0.00 AVRG j

1 !

FORM VII SV56.0


Lab Name: COMPUCHEM




Contract: 8270C



Init. Calib. Date(s): 03/03/02 03/03/02



COMPOUND

| N-Nitrosodiphenylamine____

|4-Bromophenyl-phenylether

IHexachlorobenzene

Pentachlorophenol_

Phenanthrene

j Anthracene_

ICarbazole] Di-n-but’j’lphthal

Fluoranthene_____Pvrene I

ate

|Butylbenzylphthalate

j 3 , 3 ' -Dicnlorobenzidine

is(2-etnvlhexvl)PhthalateI'nzo(a)anthracene_

bhrysenej_____________

!Di-n-octvlphthalate____

|Benzo(b)fluoranthene___

!Benzo(k)fluoranthene___

Benzo(a)pyrene___________j Indeno {1 ,j2 , 3 - cd) pyrene^

|Dibenzo(a,h)anthracene

;Benzo(g,h,llperylene _

1 2 - FI uoropjhenol

Phenol -d5'

Nitrobenzene-d5_______

2 -Fluorobiphenyl

2 , 4,6 -Tribromopheno1

Terohen'.’l - dl 4

|RRF8 0.000 | 1 1 1 1

RRF OR OR . J MIN | %D OR 1 MAX %D OR|CURV

AMOUNT J AMOUNT |

| |

RRF j

1

% DR. I FT I

1

%DRIFT |TYPE|

0.5330000|0.4765422j------10.01 1

-------- 1-10.591

----------- 1 — |2 0.0 0|AVRG|

0.3000000 0.2703204 0.01 1 -9.89| 5 0.0 0 j AVRG

0.3410000|0.3195736 | 0.01 1 -6.28| 5 0.0 0|AVRG j

0.1000000 0 .'1148339 0.05 i 14.83| 20.00|AVRG|

1 . 2540000 1 . 1483615| 0.01 -8.42 5 0.0 0|AVRG

1.2630000|1.1493896 0.01 1 -9.00 50.00|AVRG|

0.9800000|0.8954495| 0.01 1 -8.63| 5 0.0 0|AVRG|

1.6380000|1.4562558 0.01 1 -11.10 j50.00 AVRG

1 . 4490000 1.41781030.01 j -2.15| 20.00 j AVRG|

1.4350000|1.3974664 j 0.01 1 - 2.62 j 50.00|AVRG|

0.7410000 0.6656803 0.01 1 -10.16 50.00 AVRG0 . 5660000 j 0.5777214 j

0.01 2.07| 50.00 AVRG1.0350000 j 0.9965946 0.01 -3.71 50.00|AVRG|

1 . 4 320000|1.6085199| 0 . 01 1 12 . 33| 50.00 jAVRG|

1.2900000 1.2647011 0.01 -1.96 50.00 AVRG2 . 0140000 | 1 . 9020777 0.01 1 -5.56 20.00 AVRG1.7250000 | 1.6598364. 0.01 -3.78| 50.00|AVRG|

1.5600000 1.7624998 j 0.0112.98 j 5 0.0 0 j AVRG j

1 . 3800000 | 1 . 4738244 0.01 6.802 0.0 0 jAVRG

1.4730000 1.6969110 0.01 1 15.20| 50.00|AVRG|1.2820000 j1.4997111j

0.01 1 16.98| 50.00|AVRG|

1.2410000 | 1.4097750 0.01 13.6050.00 jAVRG

1.2730000|1.2161236 | 0.01 1 -4.475 0.0 0|AVRG j

1. 436 0 0 0 0 | 1 .3836152| 0.01 1 -3.65 | 50.00 AVRG|

0. 5720000 j 0. 5194193 0.01 -9.19 50.00 AVRG1 .5550000|1.5298129 j 0.01 -1.62| 50.00 AVRG0.3760000|0.44 50193 ! o. oi! 18.36 | 50.00|AVRG j

1 . 1100000i 1. 1057504 |

' i

0 . 01 1

11

-0.38

150.00 AVRG

1 1

of 2FORM VII SV

Data File: /chem/5972hp60.i/DF020313A60.b/'HG020313A60.d

Date : 13-MAR-2002 13:12

Client ID: SSTD080



Column phase: J&U DB-5.625

Instrument: 5972hp60, iCD

Operator: 917LO



Date : 13-MAR-2002 13:12

Client ID; SSTD080 Instrument; 5972hp60.i


Volume Injected <uL); 1.0 Operator: 917

Column phase; J4.W DB-5,625 Column diameter: 0.32

-O

CD

LO


CompuChem

Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020313A60.b/HG020313A60.d SSTD080 Client Smp ID: SSTD08013-MAR-2 0 02 13:12917 Inst ID: 5972hp60.iSSTD080:917

Data file Lab Smp Id Inj Date |

Operator Smp Info Misc Info Comment !Method I

Meth Date Cal Date J

Als bottle Dil Factor Integrator Target Version: 3.50Processing Host: einstein

/chem/5972hp60.i/DF020313A60.b/8270Cv6.m13-Mar-2030 13:44 mikhael Quant Type: ISTD0 3-MAR-2002 17:20 Cal File: HL020303A60.d2 Continuing Calibration Sample1.00000

HP RTE Compound Sublist: all.sub



DFVtVoVi

1.00000

1000.00000

1000.00000

1.00000



AMOUNTS


ompounas MASS RT EXP RT REL RT RESPONSE ( NG) ( NG) SIMILARITY

1 1. 4 - 0 i c h crooenzer'.e - d4 152 8 153 0.153 (1.000) 83443 40.0000

2 NachLhrt i cP.-r - d i 136 10.301 10.301 (1.0C0) 243315 40.0000

164 13 . 360 13.380 (1.000) 208182 40.0000

1 59 16 00 3 16 00 7 467617

- 24 0 20.636 2 0.6 38 (1.000) 498466 40.0000

- • - 264 23.205 23.206 (1.000) 415406 40.0000

7 2 -cc roc he PC': 112 6.03- ■,0.741; 202954 80.0000 76.43

-■ Pher.cl-dB 9 9 ■7 594 " 5 94 i0.932 1 230906 80.0000 77.06

82 9.0 8 3-'' 5 . 0 b 3 (0.882) 252765 80.0000 72.66

2 - Fluorcb: oceny I 172 12.196 12. 156 (0.911) 636959 80.0000 78.70

brOTopneno1 330 1 4 764 14 .704 (1.105) 185290 80.0000 94.60 (M)

- d - 4 244 1 6 S i : iO.911; 1102358 80.0000 79.68

’2 1 'CiC, ; i 3 c. (0.417; 307934 80.0000 98 . 98 9668

- PvriQi-e 79 *> 4 3’ 3 4 73 (0.421) 309499 80.0000 71.61 9339


Compounds

15

16

17

1 o

1 i

2 0

21

23

24

25

2 6

27

26

2 9

3 0

31

32

•j i

34

35

36

2 9

40

4 3

4 5

4 1

4 fc

Benzaldehyde

Phenol jBis i 2 -chloroethy1)ether

2-Chlorophenol

1.3- DichlorobenzeneI


Benzyl alcoholI

1'. 2-DichlorobenzeneI

2- Methylphenol

2,2'-oxybis11 -Chloropropane)

Acet oohenone‘ I

3- Metnyipneno-

4- Methylphenol


Hexachloroethane

Nitrobenzene

1sophorone

2-Nitrophenol

2.4- Dimethylphenol

Bis v2-cnloroethoxv)methanei

2.4- Diehl oropnenol

1.2.4 -Tr:chlorcbenzenei

Naphtha ler.e

4•Ch1oroani1ineu h,i .

HexachloroDutaaiene

Caprolactam

4 • Ch loro- ; • mecnv ; oh endI

2 -Methyin.apntnalene

1 - Methy1 naphtha!ene

Hexach. 1 orocyc open tad lene

2 , 4 , 6 - Tr ich 1 ot'ophenoi

2.4.5 -Trich1orophenoi

1.1'-Biphenvl1 ‘

2 - Cnioronaoh.tha 1 ene

D:met r. y 1 p n t n a 1 a t e

2,6 -u:nit roto1uene

■t-ir.io rocner. v i - one n: e t ne rr

AMOUNTS



77 7.425 7.425 (0.911) 100794 80.0000 75.67 8700

94 7.611 7.611 (0.934) 204910 80.0000 71.04

93 7 730 7.730 (0 . 948) 144744 80.0000 72.92

128 7.814 7.814 (0.958) 188787 80.0000 83.20 8973

146 8 051 8 . 051 (0.988) 266492 80.0000 85.65

146 8 187 8.187 (1.004 .' 264921 80.0000 85.45

108 8 390 8 . 39C (1 . 029) 105101 80.0000 72.10

146 8 .423 6.423 11.033) 249701 80.0000 83.68

108 / 8.610/ 8.610 (1.056) 158104 80.0000 85.85

4 5' 8.610/ 8 . 610 (1.056) 204144 80.0000 72.05 7097

105 6 829 8 . 829 (1.083) 263285 80.0000 79.65 7865

108 ■ '8 863 8 . 863 (1.087) 180285 80.0000 77.03

108' - 8.863 8 .863 (1.087) 180285 80.0000 77.03

7 0 8 829 - 8 . 829 (1.083) 118346 80.0000 69.67 0 (M)|

117 8 999 8.999 (1 . 104) 120725 80.0000 91.26 8972

77 9 117 9 . 117 (0.885) 217191 80.0000 71.97 8953

82 9 52 3, 9.523 (0.924) 339161 80.0000 71.37 8815

139 9 658 9.658 (0.938) 119426 80.0000 80.14 8783

122 9 760 9.760 (0.947) 140518 80.0000 77.71 8647

93 9.895 9.895 (0.961) 206881 80.0000 72.31 7742

162 10.081 10.081 (0.979) 224750 80.0000 84.41

180 10.217 10.217 (0.992) 279450 80.0000 88.40

128 10 352 10.352 (1.005) 562730 80.0000 77.82 8979

127 10.454 10.454 (1.015) 220006 80.0000 72.17 8792

226 10.572 10.572 (1.026) 230400 80.0000 93.19 9122

113 11.046 11.046 (1.072) 45814 80.0000 86.94 8555(M)^

107 11.316 11 . 316 (1 . 099) 169128 80.0000 76.41 8707

142 11 553 11.553 (1.122) 462382 80.0000 85.78

142 11 722 11.722 (1.138) 371059 80.0000 85.16

237 11 S24 11.824 (0.884) 222519 80.0000 92.99 9085

196 12.061 12.061 (0.901) 187964 80.0000 82.01

196 12.145 12.145 (0.908) 216657 80.0000 86.83

154 12 365 12 . 365 (0.924) 572659 80.0000 76.06 8290

162 12 399 12.399 (0.927) 493113 80.0000 76 . 38

6 5 12 .602 12.602 (0.942) 364378 160 000 144 . 9 8852

16 3 12 907 12.907 !0.965) 644142 80.0000 75.96 9481

16 5 13 025 18.025 (0 . 973) 141079 80.0000 78.05 9566

152 13 127 13.127 it.981j 793994 80.0000 7 6.46 9975

138 1 3 3 3 0 1 • • "J 0 (0 996) 2 9e 3 94 160.000 155.6 9191

- 54 . 3 . -ii 8 (1 .005i 492415 80.0000 80.63 8743

184 13.516 (1.010) 409555 400 000 362.3

109 1 3 65 1 12.651 (1.020) 266171 160 000 172.5 7983

165 13.73b 1 3 7 3 6 i 1 . 027; 217678 80.0000 81.30 8400

168 13 752 1 3 . 752 ( 1.028) 928521 80.0000 81.81 94 39

149 14.15? 14 . 159 (1 .053) 696693 30.0000 76.06 3374

204 ' 14.345/ 14.345 (1 .072) 412411 80.0000 82.51 7149

166 ' 14.34 5 , 14.345 :: .C 72) 711463 80.0000 • 78.50 7612

Data File:

Report Date

/chem/5972hp6 0 . i'/DF020313A60 . b/HG020313A60 . d: 13-Mar-2030 13:44

Compounds

62

63

64

65

6 6

& /

6 &

65

70

72

73

74

75

76

~>l

7 6

79

80

31

82

93

rfss86

87

I4 -Ni troar.i line

4.6-Dinitro-2-methylphenol

N-Nitrosodiphenylamine

1,2-Diphenylhydrazine

4 -Bromophenyl- phenylecherHexachlbrobenzene

Atr3Zirie

Pentachloropnenoi Phenantlhrene

Anthracene

Carbazoie

Di-n-butylphthalate

Fluoranthene

Benzidine Pyrene j

Butylbenzylphthalat e

3,3'-Dichiorobenzidinej

bis(2 - ethyl hexyl)phthalat eI

Benzo(aianthracene

Chrysene

Di-n-octylphtnalate

Benzo(b)iiucranthene

Benzoik)f1uorantheneI

Benzo(a)pyrene

Indeno(1,2,3-cd)pyrene

Dibenzo(a,h)anthracene

8 8 Benzo(gJ h, :;perylene

QC Flag Legend

QUANT SIG

MASS

138

198

169

77

248

284

200

266

178

178

167

149

202

184

202

149

252

14 9

228

22S

149

252

252

252

276

273

276

RT EXP RT REL RT

14.412 14

14.463 14

14.565 14

14.632 14

15.207 15

15.326 15

15.495 15

15.681 15

16.053 16

16.138 16

16.425 16

17.018 17

18.151 18

18.371 18

18.557 18

19.657 19

20.570 20

20.604 20

20.621 20

20.672 20

21.585 21

22.414 22

22.465 22

23.091 23

26.136 ■ 26

26.187 26

27.033 27

.412 (1.077)

.463 (0.904)

565 (0.910)

.632 (1.094)

207 (0.950)

.326 (0.958)

.495 (0.968)

.681 (0.980)

.053 (1.003)

.138 (1.008)

.425 (1.026)

.018 (1.063)

151 (1.134)

371 (0.890)

.557 (0.899)

.657 (0.952)

.570 10.997)

.604 (0.998)

.621 (0.999)

672 (1.002)

585 (0.930)

.414 (0.966)

.465 (0.968)

091 (0.995)

136 (1.126)

187 (1.128)

.033 (1.165)


RESPONSE

301084

274214

441767

725417

250594

296253

15622

212908

1064561

1065514

830105

1349987

1314347

253628

1393179

663638

575949

993537

1603585

1260821

1580269

1379012

1464306

1224471

1409814

1245978

1171258

AMOUNTS

CAL-AMT ON-COL

( NG) ( NG)

160.000

160.000

80.0000

80.0000

80.0000

80.0000

80.0000

160.000

80.0000

80.0000

80.0000

80.0000

80.0000

160.000

80.0000

80.0000

80.0000

80.0000

80.0000

80.0000

80.0000

80.0000

80.0000

80.0000

80.0000

80.0000

80.0000

155.7

143.0

71.52

79.47

72.00

74 . 94

17.61

184.0

73.23

72.81

73.13

71.10

78.25

77.42

77.91

71.87

01.68

77.03

89.88

78.41

75.54

76.98

90.40

85.41

92.15

93.57

90.85

SIMILARITY

7970

8803

8816

9238

9401

9514

8993

8900

8918

9112

8620

9446

6930

9107

8540

8610

7460

56 y

pounp: 2.4.b-Trlpromophenol Numper : ljlS— 7*9—6

Data File: /chem/5972hp60.i/DF0203l3A60.b/HG020313A60.dInjection Date: 13-MAR-2002 13:12Instrument: 5972hp60.1Client Sample ID: S5TD080

Ion 141, no: *^rea :

1 . 4-

1 .

1

1

1

Cl

Height: 0

0.1-

14. 14.4 14.5 14.b 14.; 14.6 14.9 15.0 15.1

/ \

5SS

Data File: /che‘m/5972hp60. i/DF020313A60.b/HG020313A60.dInjection Date:| 13-MAR-2002 13:12

Instrument: 59712hp60.iClient Sample I'D: SSTD080

lound: N-Nitroso-di-N-propy 1 amine jNumber: 621'-64-7

5.1-

4.B-

4.5-

4.2-

3.9-;

3.6-

3.3-

3.0-

2.4-

2.1-

1.8-

1 ■

1.2-

0.9-

0.6-

0.3-

0.0-

Ion 70.00: Area: 110346 Height: 53832

! I

8.4 8.5 6.6 8.7 8.0Min

8.9 9.0 9.1 9.2 9.3 j

1.2- 1 - 1-

1.0- 0. o-'

.8-

0.7-

0.6-

0.5;

0.4-

0.3-

•0.2-

0.1-

0.0-


8.5 8.6 8.7 8.8Min

8.9 9.0 9.1 9.2 9.3


/ \

d. 8 Min

3.9 9.0 9.1 9.2

57 G9.3

Data File: /chem/5972hp60.i/DF020313A60.d/HG0203l3A60.dInjection Date: 13-MAR-2002 13:12Instrument: 5972hp60.iClient Sample ID: SSTD080

ouna: Caprolactam Number: ll05-b0-2

1.3-

1.2

1 . r

1.0'

0.9-

0.8

0.7

0.6

0.5-

0 . 4-

0.3-

0.2-

0.1-

0.0-

Ion 113.00: Area: 45814 Height: 13537

/f

:/Ii I

L

10.6 10. 10.8 10.9 11.0Min

11.1 11.2

2.0-

1 .0-

1 . b-

4-

1.2-

: Tio 1.0

! x

r o.8-

0,6-

0.4-

0.2-

0.0-

Ion 55.00: Area: 15298 Height: 15298

\ in\^r o

L-,

'\

10 . 10.8 10.9 11.0

M i n11.1 LI.2 11.3 11.4 11.5

1 . b-

1.5-.

1 .4-:1.3-

1 .1-

1.0-'.

0 . ?-■ . 8-

. 6-

. 5-

0.0--

Ion 56.00: Area: 13300 Height: 13300

' UT'

;o !b

i10.6 10.9 11.0

Min11.1 11.2

57j±

11.3 11.4 11.5

COMPUCH EM a division of Liberty Analytical Corp DATE 3 //J/el INITIAL TIME OF TUNE / In $ SHIFT/SIA)^ (D)(C)

GC/MS SEMIVOLATILE RUN LOG TIME TUNE EXPIRES0 c, 0 h LINKER /METHOD a 7 7y

COMPUCHEM .LOGBOOK 4 V(4) 4 (5972hp60)m m DDC\/CK!TI\/C N/( AIKITPKIAWPF*i

ikEP

PREVENTIVE MAINTE:nance... _________________________; v1

cT FILENAME ItT DATE TIME CLIENT ID# CASE/SDG# AMOUNTTxirerTcn

CHEMIST COMMENTS(ETC )/DISPOSIT(QfcL pv-..t ------------------------------------------ LC5—

1 ? o ^ (3 A 7 c / 3 7 7 Ho9 ypnAA uJP ___ <ln SV' A! : /C3

2 H fiio > i -! \ An,-) / / / (3ii S f f/3 o ? c^------

______ i______

3 U (it Hj v / f- ~*> A Ac/ / / 1 353 1 F77 I

4 (aJ/’7 // '( L ^ AA\; / / / 7] 3 ________ jiM sj)- ________ l_________---d-w, , t l Sr '■ r . .■'■ _

5 7 1 -XA A Ao / / / isrii ajlv-.’v

6 AtS IMY-)- / / / 1SSS KaMSC

7 A(jo / / / loss Mv-o -im A

8 £)£ OT- Pika / / / nii S

9 lHm- lfe/%07 / / nss Mm-KA___

10 71 / / iSSH iv\w- ns

1 1 &£l<lTn-lk f\Uo / / / l‘>H MuO -/S 3*

12 ^ AOo / / / hbs MvJ- IAS 7_________ N13 \- \(\b° 7 / / Poss S&LIC3 v> VA^XovaS

14 / PUS bTOLcS

15 / / / Pl^S cmPluj

16 fiFl«n-W(/\6a 7 / . / IMl/d - ?cA Qf ^11

17 Q Fm>2flA</o 7 / P$lS N\uJ - ?o & 4/___ d, ^______

18 ____ z___Z_____'—

19 / /

20 / /21 / /22 / /23 —7 7

/ /

Std. ID H

Lot U

Tune

(C- s

STANDARDS Analytical Inrjstd.

------- ■----

7 'I S'Sc.

Column Type SUPERVISOR APPROVAL

J r H-. :L• ! ;i A- V - i>-vu: . . _ j*//s/> .

The presence ol the Chemist's employee II) number, or signature. on III is run log nrtesis thru slnel compliance with ilie method ■. S' 'I' li:>

occurred Any SOI’ deviations require doaimentalion hy (he responsible chemist together with the chemist's initials and the initial'. ni ill

lab supervisor and a QA department representative, sigmlying approval of the deviation | .VI | /ti! dee


Lab Name:

'Lab Code :

COMPUCHEM

LIBRTY Case



GC Column: J&W DB-5.625

Contract: 8270C



Init . Calib. Date (s) :: 03/03/02 03/03/02

Init . Calib. Times: 1401 1720

0 . 32 (mm)

i

COMPOUND

___________ L_________ '______________

|___ |RRF80.000|

\RRF OR | OR |

AMOUNT |AMOUNT |

1 I 1

1

MIN |

RRF |

1

1

%D OR 1

%DRIFT |

1

MAX %D OR

%DRIFT

j CURV

| TYPE

Phenol | | 1.3820000|1.2750753|------|0.01 |

-------- |-7.74| 20.00 | AVRG

Bis(2 -chlbroethyl)ether 0.9520000|0.8755671 0.01 j -8.03 j50.00 | AVRG

2 -Chlorophenol |1.0880000|1.1101150| 0.01 [ 2.03 | 50.00 | AVRG

1,3LDichlorobenzene |1.4910000|1.6373799| 0.01 1 9.82 [ 50.00 | AVRG

1,4-Dichlorobenzene |1.4860000|1.5998988 | 0.01 1 7.66 20.00 | AVRG

1,2-Dichlorobenzene |1.4310000|1 . 5359906 | 0.01 I 7.34 | 50.00 | AVRG

2-Methvlphenol |0.8830000|0.9068195 | 0.01 1 2.70 | 50.00 | AVRG

2,2'-oxybjis(1-Chloropropane)

4-Methvlphenol

1 . 3580000 1.1937974 |1.1220000|1.0953021 |

0.01 j

0.01 1

-12.09|

-2 . 38 |50.00

50.00

| AVRG

| AVRGN-Ni t roso j- di - N- propylamine

Hexachloroethane

|0.8140000 0.7133376 j

j0.6340000]0 . 7421203 |0.05 10 . 01 j

-12.37|

17.05 |50.00

50.00

| AVRG

| AVRG

Nitrobenzene |0.4960000 0.4382909| 0.01 1 -11.63 50.00 | AVRG

fcophorone 0.7810000|0.6846384 0.01 j -12.34| 50.00j AVRG

^pNitrophenol | 0.2450000|0.2407559 j 0.01 I -1.73| 20.00 | AVRG

4 -Dimethylphenol 0.2970000|0.2769714 j 0.01 1 -6.74 50.00 | AVRGBis(2 - chibroethoxv)methane

2,4-Dichlorophenol

|0.4700000|0.4023271

0.4380000 0.4600051 |0.010.01 1

-14.40

5.02 |

50.00

20.00

| AVRG

AVRG1,2,4-Trichlorobenzene

0.5200000 0.5643432 j0.01 I 8.53 50.00 AVRG

Naphthalene i1 .1890000 i 1.1397945 j 0.01 1 -4.14] 50.00j AVRG

4 -Chloroaniline | 0. 5010000 0.4297048 | 0.01 1 - 14 .23 | 50.00j AVRG

Hexachlorobutadlene |0.4060000 0.4613911 0.01 13.64 20.00 AVRG4-Chloro-3-methvlphenol 10.3640000 j 0.3461601 I 0.01 1 -4.90 | 20.00 | AVRG

2-Methylnaphthalene i0.8860000 0.91921441 0.01 3 . 75 | 50 . 00 AVRGHexachlorocycloper.cadiene

2,4,6-Trichlorophenol

|0.460000C|0.4473442|

j 0.4400000 0.4297655

0 ] C 5 1

0.01]

-2.75] - 2 . 3 3 j

50.00

20.00

| AVRG

AVRG2,4,5-Trichlorophenol 0.4790000 0.4557583 | 0.01 1 -4.85 50.00 | AVRG

2 -Chloronaphthalene |1.2400000 J 1.1247789| 0.01 1 -9.29| 50.00 | AVRG

2 -Nitroaniline |0.4830000 0.4269821 | 0.01 -11.60 50.00 | AVRG

Dimethylphthalate |l.6290000|l.4134548] 0.01] -13.23] 50 . 00 | AVRG

2 , 6 -Dmitrotoluene 10.347000010.3222148! 0.01 1 - 7.14| 50.00 | AVRG

Acenaphthylene |1.9950000|1.813 784 2 j 0.01 I -9.08j 50.00 AVRG1 * Hit roani 1 me |0.3690000|0.3262521] 0.01 1 -11.58] 50.00 | AVRG

Acenaphthene ] 1 . 1730000 ! 1. 114 3569 ] 0.01 1 -5.00 20.00 | AVRG

2 , 4 - Dinitrophenol !0.2170000!0.1355693 0.05] -14.44 50 . 00 | AVRG

- H11 rophenol ;0.2960000 j 0.3208015 0.05 8 . 38 | 50.00 AVRG2 , 4 - Dim trotoluene 0. 5140000 j 0.4826130 0.01 1 -6.11 50.00 AVRGEiibenzof uran ]2.1810 0 0 0|2.1378217j 0.01 1 -1.98] 50 . 00 ] AVRGDiethylphthalate ! 1. 7600000]!.613503 0| 0.01 1 -8.32 50.00 AVRG4 -Cnlorophenyl-phenylether Fluorene |

|0.9600000!0.9886 520 j

| 1. 7420000| 1. 7789175 j0.010.01 i

2.98]

2 . 12 |50.00

50.00

| AVRG

| AVRGi t roani 1 i ne !0.3720000|0.3076896 0.01 -17.29 50 . 00 | AVRG- Dim tro - 2 - methvlphenol 0.1560000|0.1538125]

!. i 1

0 . 01 1

1

-7.34]

150.00 | AVRG

raae i oi> 2 573FORM VII SV







GC CoIumn : JScW DB-5.625 ID: 0 . 31 (mm)

1| COMPOU

iND RRF OR

AMOUNT

jRRF80.000|

1 0R

AMOUNT | (

1

MIN |

RRF1

1

%D OR 1

%DRIFT1

MAX %D OR

%DRIFT

j CURV

TYPE

' ||N-Nitrosodiphenylamine

|-----------| 0.5330000 1 0.4876334 |

------10.01 |

-------- 1-8.51| 20.00

jAVRG|

| 4 -Bromophenyl-phenvlether

| Hexachlorobenzene

|0.3000000

0.3410000

0.2951585 I

| 0.3303247

0.01 I

0.01

-1.61 -3.13|

50.00

50.00

|AVRG|

AVRG |

i Pentachlorophenol | 0.1000000 | 0.1177405| 0.05 1 17.74| 20.00 |AVRG|

| Phenanthrene j1.2540000 1.1727415| 0.01 | -6.48 | 50.00 | AVRG

!Anthracene 1 . 2630000 | 1.2627789 0.01 j-0.02 50.00 |AVRG|

iCarbazolej 0.9800000 | 0 . 9256850| 0.01 1 -5.54| 50.00

|AVRG j

i Di-n-butylphthalate |1.6380000 | 1 . 5508453| 0.01 1 -5 . 32 | 50.00 AVRG |

i Fluoranthene |1.4490000 1 . 5026635 0.01 3.70 20.00|AVRG j

|Pyrene | j1.4350000 |1 . 3087822 | 0.01 1 -8.80] 50.00j AVRG|

J Butylben z vlphthalate 0.7410000 |0.6061015 0.01 -18.20 50.00 AVRG13,3'-Diclilorobenzidine 0.5660000 |0.5614097 0.01 -0.81 50.00 AVRGgeis ( 2 - etlWl hexyl) Phthalate

Mbnzo(a)anthracene|1.0350000

|1.4320000

|1.0530921 j1.6387461|

0.01 1 0.01 j

1.75

14.44

50 . 00

50.00

| AVRG jAVRG|

^hrysene | 1.2900000 |1.3561748 0.01 5.13 50.00 |AVRG|

I Di-n-octvlphthalate |2.0140000 2.1167437 0.01 1 5.10 20.00 AVRG |

jBenzo(b)fluoranthene 1 . 7250000 1.9346295| 0.01 1 12.15| 50.00 |AVRG|

1Benzo(k) fluoranthenej1 . 5600000 (1.7494808 | 0.01

12.15 j50.00

|AVRG j

iBenzo (a)pvrene 1.3800000 |1.5472874 0.01 12.12 20.00 AVRG1Indeno(1 ,j 2,3 -ca)pvrene j1.4730000

j1.7093933 |0.01 1 16.05| 50.00 |AVRG j

!Dibenzo( a ,h)anthracene 1 . 2820000 1.5231834 0 . 01 1 18.81 50.00jAVRG j

]Benzo iq,H, 1)pervlene | 1 . 24 10000 j 1.4311206 j 0.01 15.32 50.00 AVRG

j 2 -rluorc

i

phenol 1 . 2730000 1.2073047 0.01 -5.16 50.00 |AVRG|

jPhenol -d5 1.4360000 1.3727927 0.01 -4.40 50.00 1 AVRG

] Hitroben z ene-d5 10.5720000 (0.52520681 0.01 j -8 . 18 j50.001AVRG

: 2 - Fluorobyphenol j1.5550000 |1.5076698 0.01 -3.04) 50 . 00 |AVRG|

2 , -J , 6 - Tr i brorr.ophenol 10.3760000 |0.4124754 | o. oi! 9.70 50.00 | AVRG

1 7e rphenv 1 - d I 4 j1.1100000 [ 1 . 0347666 | 0.01 -6.78 50.00 AVRG| I 1 1 1

!nacre 2 of 2

FORM VII SV

Data File: /'chem/5g72hp60.1/DF020314B60.1VHG02031-4E60 d

Date : 14-MAR-2002 20:54

Client ID: SSTD080

Sample Info: SSTD080;2319

Volume Injected <uL): 2.0



Operator: 2310


'-O

r"-

LO

<:<10~6>

Data File: /chem75972hp60.i/DF020314B60.b/HG020314B60.d

Date : 14-MAR-2002 20:54

Client ID: SSTD080


Volume Injected (uLl: 2.0

Column phase: JS.W DB-5.625

Instrument; 5972hp60,i

Operator; 231?

Cc» 1 urnn d i amet er : 0 ♦ 32

;_0

r-LD

4.34.2

4.1

4.0- i 3.93.8

3.7-i

3.6- i

3.5-:

3.4

3.3- 1

3.2- ;3.1 J

3.0

2.9

2.82.7

2.62.5

2.4- j

2.3

2.22.12.0- i

1.9-j

1.81.7-

1.61.5- ;1.41.3-

1.21.1-

1.0 0,9-

0.8 0.7

0.6-

0.5-

0.4- 0.3

~0T2'

0.1 UL

7chem/5972hp60, i/DF020314E60,b/HG020314B60.d (Part 2 of 21

Lj J

16 17 18 19 20 21

Data File: /chem/5972hp60.i/DF020314B60.b/HG020314B60.dReport Date: 14-Mar-2030 21:31

CompuChem

| Semivolatile Report SW-846 Method 8270CData file : /chem/5972hp60.i/DF020314B60.b/HG020314B60.d Lab Smp|Id: SSTD080 Client Smp ID: SSTD080

Inj Date : 14-MAR-2002 20:54Operator : 2319 Inst ID: 5972hp60.iSmp Info : SSTD08 0:2319 Misc Info :Comment I :Method j : /chem/5972hp60.i/DF020314B60.b/8270Cv6.m

Meth Date : 14-Mar-2030 21:31 naegler Quant Type: ISTDCal Date : 03-MAR-2002 17:20 Cal File: HL020303A60.dAls bottle: 2 Continuing Calibration SampleDil Factor: 1.00000Integrator: HP RTE Compound Sublist: all.subTarget Version: 3.50Processing Host: einstein

Concent ration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable

Name1

Value Description

iDF 1.00000 Dilution Factorvi 1000.00000 Volume of final extract (uL)vo 1000.00.000 Volume of sample extracted (mL)

W 1.00000 Volume injected (uL)

Cpnd Va riable Local Compound Variable

AMOUNTSC'UANT s:g CAL-AMT ON-COL

Compounds MASS K. £:■:? ET F.EL FT RESPONSE ( MG) ( NO

* 1 1 , 4 - D :h 1 or r.hen zi 151 0 1 3 7 5 . 1 J ~ 1 . 0 0 0 . 91913 40.0000- Nnpr.ih : 3-i : <: . .1 .f; 5 i. .15 5 DDL. 272010 40.0000

- 6 4 12.254 1 2 . 3 v 4 .1 300; 242509 40.0000:r = . •= ' 1 •' 0 01 495405 40.0000

cv ill. 24... V. : 1 •?0 ; 579435 40.000'

■> J-?.:-.:: 11 5 •' "22 ' 2Z 221534 8 0 . 0 0 2 0 7 5 . y 8i ■ 1 J - 7 i ; 252355 80 . (-00 0 78.48

:b C z 3 2 ) 235723 S0.00CO 73.47*: • ' - . v . , . ,. . . ........... . • : • j

* ‘ “ 1 ^ 1 : | ;• •. c i'—. ct: ;r: 14." •• : 1 4 . 7 •: 5 ,; . 15 ; 200055 30.0000 37.69- 4 1 - 7 7- -.775 "' 1 ■ 1199152 30.0000 74.56

N-.l: i - = --.i — r.y 1 2 :.ir: ‘ '■ .415' 358085 80.0000 104 . 514 1 4 1 7 j.417 ■ 0 . 4 I L : 353833 90.0 0 C 0 7 6.4 2

SIMILARITY

2643

5 3 8 5

fa

577

Data Fijle : /chem/5972hp60.i/DF020314B60.b/HG020314B60.dReport 'Date: 14-Mar-2030 21:31

Compounds

==a,a“=““r===”““===a15 Benzaldenyde

16 Phenol17 B i s 12 -jch ioroethyl) ether

13 2-Chlorophenol19 1 . j -Dilchiorobenzene

. “*■''"r—iOIOCen“er*<r2: BenzvJ alcohol

2 3 2 - Methv i ohenoi

2« 1.2 -oxyo 1 s : 1 ->_nloropropane)

25 Acetophenone

26 ?-Methylphenol

27 4-Methylphenol

2 8 N-Nitroso-di-N-prcpy1 amine2 9 HexachJloroethane

3C Nitrobenzene

3i IsoDhcrcn?

I .3 2 2 - N 11 ropnenoi

3, - - J•4 e: s : 2 -pr.: orc-et hoxy 1 xetnane

3 7 t.'aph: na lene

3 9 A - 2!: 1 o roa r. 1 . in —

39 Hexach 1 ore rntzaz 1 er.e

4 C i. 3 d rc i c t (i ~j..o_

•t ^ N ; t roa.n 1 . : z-

AMOUNTS

UANT SIG CAL-AMT ON-COL

MASS RT EX F R: REL RT RESPONSE ( NG) ( NG) SIMILARITY

R7 7.409 7.409 (0.911) 127371 80.0000 86 . 31 8580

94 7 . 59c 7 59b (0.933) 234392 30.0000 73 . 78

93 7 714 7.714 i0 943) 160952 90.0000 73 . 62

128 7 7 9 9 7 7 9 9 (0.958) 204053 50.C000 81.65 3965

146 9 . 035 8.035 ■0 988) 300993 30.0000 3 7.8:-

14 5 9.154 8.154 r1.002' 294103 SO.000c 36.12

10S 9 . 3 7 4 9 . 374 '.1.029' 123291 80 - 0000 76.79

'.4 6 S 4 09 8.408 ! 1 . C 3 3 ) 232355 80.0000 85.90

103 /0 '.')i 8 . 594 (1.056) 166697 80.0000 82.18

as' - - / 8.594 (1.056) 219451 80.0000 70.31 "7056

:os 8.814 ^ 3.914 (1.083) 294264 80.0000 80.82 7756

105 ' '8.847 8 . 847 (1.087) 201345 80.0000 78 .10

109 ' 8 847 8 . 847 (1.037) 201345 80.0000 78.10

, 70 8.814' 8.814 {1.ce 3) 131130 80.0000 70.09 0 (M)

117 8 . 966 3 . 966 (1.102) 136421 80.0000 93 .62 8046

77 3 . 101 9 . 101 (0.885) 238439 80.0000 70 . 67 8895

5 2 9 . 507 ✓ 9.507 (0.924) 372457 80.0000 70. 11 3762

13 9 9.643 9 . 64 3 (0.937; 130976 so.000c 78.62 8809

:cc q 72 7 2.727 1 r . 94 6 ) I 50678 so.oooc 74 . 54 7970

9 3 5 .879 9.379 (0.961) 218S74 80.OOOC 6S .43 7688

16 2 10 Goo 10.066 (0.979) 250252 80.0000 84 . 07

180 10.201 1 0.2 0 J (0.992) 307014 80.0000 86.88

128 10.336 10.336 (1.005) 520071 80.0000 76 . 70 8986

12 7 10.438 1 0 . 4 3 3 : 1.nisi 233768 30.0000 68.60 8559

225 10.539 1 C . 5 3 9 (1.025) 251006 80.0000 90.81 8416

113 11 .030 11.030 (1.072) 31907 80.0000 54 . 16 8314

107 11 . 300 1I.300 (1.099) 188318 80.0000 76 . 10 8775

142 11 .537 11.537 {1 . 122) 500071 80.0000 82 . 99

142 11 .707 11.707 (1.138) 411619 80.0000 84 . 50

237 1 1 .BOB 11.303 (0.384) 216970 80.0000 77.84 9284

1 96 :2.04 5 1 2 04 E '0 9 011 203444 80.0000 78 . 07

: = - 12 11 12.113 ( n 5 0b '< 221051 80.0000 76.05

: 5 4 :: .M-- 12.2 4 9 (0 924) 632222 80.OOCO 72 . 08 3382

-.4: 1 2 . 3 1' 1 2 . 5 2 :;. .527; 545538 30.0000 72.54

Z - 1 2 . 5 r c ’0 c 4 ^) 414158 16 0 . C 0 0 14 1.4 8895

:ii 12.531 1 2 . : T-1 ', • 9 6 5 . 585551 80.0000 69.40 9481

: ' 5 1 : . 0 0 5 1 :■. 009 ('1.973; 156280 80.0000 74 . 22 9533

1 D 2’ 13.111 *.".11: ■' 0 . 5 £ 1 i 379718 80.0000 72.73 8376

13 3 :: r.4 --.Jit 1 -j . : v 6 i 316486 160.000 141.6 9243

154 12 415 .4 1 j ' 1 • 0 04) 540488 8 C.0000 75.96 9 3 64 '

- ^ 4 1 • 5 ■; ;:-v 450266 4 C 0.0 0 0 3 41.9

1 :• 435 = : 1. : 2: ’ 311189 160 . 000 173 . 2 7989

19 5 12 .":' : ?. 7 2: 1 . .'<27; 234076 5 D . 0 0 0 0 75 . 05 7853

: 4 1 3 7 7 7 1 : . V 7 523; 1036882 30.0000 7 8.42 9376

'• 4 4 . : 4 ■ • • • • ; 1. 0 5 6: 782578 80.0000 73.34 9 3 90

X 14.12^ • i . 0 7 2) 479514 80.0000 32 25 7113

: 5 6 • • ^ 1 '1 / , 17- .'1 .072 : 862807 30 . OOCO 81 .72 7339

57b\

fiJ

Data File: /chem/5972hp60.1/DF020314B60.b/HGO20314B60.dReport Date: 14-Mar-2030 21:31

COfTDCUDdS

64

6 5

4-Nitroan:1ineI

4 , 6 - 31 r. i t r

N-Nizrosodiphe

necnyIpneno:

mine

1.2•Dipheny1hydra 21ne

4 -Eromophenvl-onenviezher|

Hexachlorobenzene

45 Per.zachioropneno 1

70 Phenanzhrene

71 Ar.zhr.acene72 CarbJzole

Di -n-bnzyiphthalat-f

F1 uorancheneQ !..

Benziame

IUANi 5IG

MASS

13 5

158

169

77

243

294

200 266

1 7S

178

167

14 9

202

134

AMOUNTS

CAL-AMT ON-COL

EX? RT REL NG) NG) SIMILARITY

14 .396

14 .447

14 .549

14.616

15.192

15.310

15.475

15.665

16 . 037

16.122

16.410

17.002

19.119

16 . 355

14 . 396

14 .447

14.54 9

14 .616

15.192

15.310

15.479

15.665

16 . 037

16 . 122

16.410

17.002

18.118

18 . 355

;l.077i

(0. 904.1

(0.910':

(1 . 094)

( 0.9 5 0 i

(0. 953 :

(0.968)

(0.980)

(1.003'(1.009

(1.0261

(1 . 0 6 3 ’•

(1 . 133)

(0.890)

298470

304798

483152

796739

292446

327289

10582

233317

1161964

1251174

917178

1536593

1488854

277868

160.000

160.000

80.0000

30.0000

80.0000

80.0000

80.0000

16 C.000

80.CG00

80.0000

80.00C0

80.OOCO

80.0000

160.0C0

132.5

148 . 7

73.18

74.93

78 . 61

77 .46

11.16

18 8.6

74 . 78

79.99

75.60

75.12

82.94

72 . 96

QC Flag Legend

M - Compound, response manually integrated.

8219

8779

8322

9124

9673

9185

8997

8508(M) >

9107

9293

7 6 202 1 . 5 2 4 10.524 (0.998) 1516711 80.0000 72.96

77 Buzyibenz y1pnz ha laze 149 19.624 19.624 (0.952) 702394 8 C.0000 6 5.43 9 04 1

7 9 3,3'- r,;.- v- 252 20.555 20.555 (0.997) 650602 90.0000 79.37 6 u 13

7 5 b: s 1 2 -et:- / i ne:*:y i ' Pnz ha laze 14 y 20.586 20.568 (0.996) 1220399 80.0000 81 .40 8 964

•3 G 1 a ) a n z h i' a c e n e 22S 20.605 20.605 (0.999) 1899097 80.0000 91.57

Chrvs 228 20.656 20.656 (1.002) 1571533 30.0000 34 . 08

14 9 2 ■ 5 7 n 2' 570 (0 0 71) '•94 06 7 3 80 0000 84 07

5 ez 0 ■r,-: ( noranzhene 252 22.332 "'2 3 82 (0.966) 1773707 80.0000 89 . 72

? 4 3jr o'"' 1 ! f luoranzhene 252 22.432 2 2 4 3 2 (0.968) 1603959 80.0000 89.74

3; E^nzc "'f- • 252 23.056 23 . 058 (0.995) 1418534 80.0000 8 9.66

1j naeno• .. 3 . 3 - c d 1 pyrene 276 26.037 26.087 (1.126) 1567206 80.0000 92 . 63 -9 76 0

bet. .h 2 7? 26.137 26.137 (1.128: 1396485 80.0000 95.03 8745

Z'.‘- , . . ' ue : y 276 27.00-' 27.000 (1.165) 1312080 SO . 0000 y2.23 7 3 8 P

571

ompound: z[4,6-Tribromophenol

A5 Mumper: 110-?9-6

Data File: .•'chem./597iripri0.1 /DF020314B60 . t?/ HG020314860. dInjection Date: 14-MAR-2002 20:54Instrument: | 59?2hp60. lClient Samole ID: 537D030

1.1-

1.0-

0.9-

0.0- 0.7-

0.6 -

0.5-'

0.4-

0.3-

0.2~

0.1-

0.0—

Ion 329.60: Area: 200056 Height: 109896

14.4 14.5 14.6 14.7 14.8 14.9Min______________________

15.0 15.1 15.

1.0-

0.9-

0.8-

0.7-

0.6-

0.5-

n 4.

Ion j>32.00: Area: 0 Height: 0

14.7 14.8M l n

14.9 15.0 15.1 15.2

Ion 141.00: Area: Height: o

,§84ZT

in. a 15. o 15.1

Data File: [••'cnem/5972hp60.1 /DF02031*4660. P/HG02031*4660. aInjection Date: 14-mhR-2002 20:5*4Instrument;1 5972hp60.iClient Sample ID: SSTDuQO

ompound: r4—r4it roso-dl-N-propg1 am in* k'S Number;! 621-64-7

I

6.0-

5.6-

5.2-

4.0-

4.4- '

4.0-

3.6-

3.2-

2.8-.

2.4-

2.0- .

1.6-

1.2-

0.8-

0.4*

0.0--

Ion 70.00: nrea: 131130 Height: 61720

©<D'

8.5 3.6 8.0Min

8.9 9.0 9.1 9.2 9.3

1.2-

1 . 1-

1 - 0-.

0.9-.

0.8-

0.6-

0.5-.

0.4-

0.1-

0 i'i -

Ion 130.00: Hrea: Height: 0

= . 3M .

9.0 9.1

j.8

j.5

I

0.0- -6.5 . Ci 8.9 9.1 9.3

Data File: /chem/5972hp60 . i .'DF020314 660 . b/ HG02031 *4560 . dInjection Date: 14-MAR-2002 20:54Instrument: 5972hp60.iClient Sample ID: S5TD080

Compound: kCAS Number

Rentachlorophenol : 87-66-5

1.2-

1.1'

1.0-

0.9-

0.3-

0.7-

0.6-

0.5-;

0.4-

0.3-

0.2-

0.1-

0.0—

Ion 266.00: Area: 23^317 Height: 1249b5

!£

15.4 15.5 15.6 15.'

Mm15.8 15.9 16.0 16.1

\5-

6.5-'

5.5-

5.0-

1.0

0.5-;

0.0

O . b 6.4-

Ion 268.00: Area: 30179 Height: 30179

15.4 15.6 15.7 15.9 16.0 16.1

I or-. Heignt: 78067

15.9 16.0 165Sr

COMPUCHEM a uiv ision of Liberty Analytical Corp DATE

GC/MS SEMI VOLATILE RIJN LOG

/ 14/0*4 INITIAL TIME OF TUNE

TIME TUNE EXPIRES S 1

SHIFT/S(A)CC)

LINKER /METHOD__ L-...................

at

• a a PREVENTIVE MAINTENANCE tOon*_/ O

i 0 ------------------------------------------------- -

aD

V FILE NAME; . J '%>.1 d-

DATE Z TIME 7- LTGLjJENTlD# CASE/SDG# AMOUNT - INJECTED

CHEMIST COMMENTS(ETC.)/DlSPOSITION_r^- •

1 / ^ 7 IM7 4; »>oSI ’DFt/’P •?5>I5u)

:2 H-61O)M gt.o / / / — i

3 / / / S?>LU:36s VlAAxosZ> )m L

4 Vo 6n IU5oH O &(/° z / / S756 L<-S vl/

5 / / |V\uj-%A cZVr.h-ir-l

6 qb i%n- sc 2 7 /7 4/

7/ b 7ib7o> AuJ - c^/rS aFiinn

8 < l&M'n-W&o / / 00 5^

9 1 / / CfiffFZ R32?

10 / si / / 62/7 09/9 FY FP32Z

1 1 / / 625?t At?

12 k'&lUW ~H&jb z / /! A5&

13 Fz3n-ism> z / / cm avr-3114 / ?tb n-iumj> / /

15 nizi- niti&o £ / / man

16 / FWl-lWbLO ?L / / PUS C,qFF3/.DdP_______ X

17 / F?s?7-msnui /(N47 C/MFfN V

18 --------f—-7---------- r>bl - < • TrDne ___ _______

19 / / u

20 / /77<T^

21 / / __----------------------------

22 / /

23 ----- "’f/

■■ ------zsT24 --------A--7---------

Std. ID ft

Tune Analytical

Hbil

Int. Std.

S'yo

Column Type

Lot ft

date

_______O -

SUPERVISOR APPROVAL_,3Zs/o2-

The presence of the Chemist s employee ID number, or signature, on this run log attests that stne'l compliance with the niciliod s St il1 li occurred Any SOP deviations require documentation by the responsible chemist together with the chemist s initials and the initials m i lab supervisor and a QA department representative, signify ing approval of the deviation . ;,-j i m; ,i. L





Lab File ID: HG020311A64 Init. Calib. Date(s): 03/10/02 03/10/02| Init. Calib. Times: 1416 1723


COMPOtND |RRF OR

|AMOUNT

|

|RRF80.000|1 OR j

AMOUNT |

| |

1

MIN |

RRF |

1

1

%D OR 1

%DRIFT |

1

MAX %D OR

%DRIFT

CURV j

|TYPE|

Phenol | 1.4530000 |1.3750083| 0.01 | -5.37| 20.00|AVRG j

Eis (2 - chlloroethyl) ether | 0.9870000 0.9678347 0.01 -1.94 50.00j AVRG j

2 -Chlorophenol | 1.3440000 | 1.3378068 j 0.01 1 -0.46| 50.00 |AVRG|

1, 3 -Dichlorobenzene 1.5440000j1.5053199 j 0.01 j -2.50| 50.00

j AVRG j

1 , 4 -Dichlorobenzene [1.5580000 1 . 5087010 0.01 -3.16 20.00j AVRG j

1, 2 - Dichlorobenzene 1.5340000 | 1.4831560| 0.01 1 -3 . 31| 50.00 AVRG |

2-Methylphenol [1.1720000 | 1.1752022 j 0.01 I 0.27 j50.00

jAVRG|

2,2' -oxybis(1 -Chloropropane)

4-Methvlphenol

|1.8230000

1.2740000

1.7884050 [1.2270109|

0.010.01 1

-1.90

-3.69

50.00

50.00

AVRG | AVRG j

N-Nitroso-di-N-propylamine__

Hexachioroethane

|0.8030000

|0.8060000

0.7842909 j

[0.7866033|

0.05 1

0.01 1-2.33 -2.41|

50.00

50.00

AVRG j

j AVRG|

Nitrobenzene |0.3400000 | 0.3524220 0.01 ■ 3 . 65| 50.00jAVRG j

Jsophorone |0.6730000 0.6543315 0.01 -2.77 50.00j AVRG j

fc-Nitrophenol |0.2150000 | 0.2096179| 0 . 01 1 -2.50| 20.00|AVRG j

W, 4-Dimethvlphenol 0 . 3200000 0.3189410 0.01 1 -0.33 50.00 AVRG

Bis (2-chloroethoxy)methane

2,4-Dichlorophenol

| 0.4020000

0.3310000

| 0.3752985

| 0.3137093

0.01 j

0.01

-6.64 |-5.22 j

50.00

20.00

|AVRG| j AVRG j

1,2,4-Trichlorobenzene 0.3860000 0 . 3640747 0.01-5.68 j

50.00j AVRG j

Naphthalene j 1 . 4460000 1 .4329549 0.01 -0.90 50.00 AVRG4 - Chloroanil me 0.4620000 | 0.4635959 0.01 1 0.34 | 50.00 | AVRG

Hexachlorobutadiene | 0.2660000 | 0 . 2515176 | 0.01 1 -5.44| 20.00|AVRG j

4 -Chloro 3-methylphenol [0.3680000 | 0 . 3701861 | 0.01 j 0.59 j20.00 [AVRG|

2-Methvlnaphthalene | 0 . 7240000 0.6882150[ 0.01 -4.94 | 50.00 ]AVRG|

Hexachlorocyclopentadiene

2,4,6 -Trichlorophenol

0.3960000I 0.4070000

| 0 . 4028086 j 0 . 4109771j

0.050.01 I

1.720.98 |

50.00

20.00

AVRG j

|AVRG|

2 , 4 , 5 - T r ichlorophenol [0.4320000 0 . 4324343 0.01 0.10 50.00|AVRG j

2 -Chlororiaphthalene j 1 . 0260000 1.0233779[ 0 . 01 [ -0.26 50.00 AVRG2 - 111 t roani 1 me 0 . 3670000 [0.3652370| 0.01 -0.48| 50.00 |AVRG|

Dimethyl bhthalate | 1 . 2540000 | 1 .26 6 9037[ 0.01 1 1 . 03 | 50 . 00 |AVRG|

2 , 6 - D i n i rotoluene 0.3450000 [0.3444937 0.01] -0.15| 50.00 |AVRG|

Acenaphth y lene [ 2 . 4090000 [2 . 3563686 J 0.01 -2.18 50.00j AVRG

3 - Mitroan 11 me | 0 . 3650000 | 0 . 3 £ 1 8 7 6 3 | 0.01 1 -0.86| 50.00 |AVRG|

Acenaphthene 1.5590000 1 . 446314 1 0.01 1 - 7.23| 20.00 AVRG |

2 , 4 -Dini prophenol 0 . 0610000 |0.06’78’740| 0 . 05 1 11.27| 50.00 AVRG4 -NitrophJenol [0.2170000 I 0.2154068 0.05 -0.73 50.00 AVRG2,4-Dinit rotoluene 10 . 5000000 10.5007911] 0 . 01 1 0 . 16 | 50.00

jAVRG|

Dibenzofuran |1.6140000 ■ 1 . 5663238 1 o. oi [ -2.95 50.00 |AVRG|

Diethylpntha late 11.4840000 ! 1 . 4 539740 j0.01 -2.02 50 . 00 AVRG [

4 -Chloropheny1 -phenylether Fluorene 1

i 0 . 6930000

[1.8520000

; 0 . 5 14 7 0 0 8 j

[ 1 . 8500119 [

0 . 0 1 1 0 . 01 j

-2.64 - 0.11J

50.00

50.00

j AVRG j

AVRG |

4-Nitroan lime 10.3300000 •0.3339842j 0.01 1.05 50.00 AVRG |^ 6 - D i n i ro- 2 -methylphenol : 0.1620000

1

i 0 . 1713274 [

! !0.01

1

5.76 [

150.00 [ AVRG

FORM VII SV 584



|Lab Code: LIBRTY Case No.: SAS No.: SDG No.: QE1877





1 1

COMPOUND1 1

| 1

RRF OR |AMOUNT

1

|RRF80.000| OR j

AMOUNTi |

1

MIN |

RRFI

1

%D OR 1

%DRIFT1

MAX %D OR

%DRIFT

CURV

TYPE

' ||N-Nitrosodiphenvlamine

-- 1-----------| 0.4360000

|------------ || 0.4269002|

------ 10.01 |

-- =---- 1-2.09| 20.00 | AVRG

j 4 -Bromophenyl-phenylether

I Hexachlorobenzene__ 0.2120000

| 0.26100000.2077959

| 0.2572523|0.010.01 1

-1.98]

-1.44

50 . 00

50.00

AVRG | AVRG

!Pentachlorophenol 0.1740000 0.1739961| 0.05 -0.00 20.00j AVRG

! Phenanthrene 1.4880000 1.4449910| 0.01 -2.89 50.00 [ AVRG

I Anthracene | 1.5130000 | 1.4528678 0.01 | -3.97 | 50.00 | AVRG

i Carbazole I 0 . 9960000 | 0 . 9662441j0.01 I -2.99| 50.00 | AVRG

! Di-n-but’ilphthalate 1.4890000 1.4738923| 0.01 -1.01| 50.00j AVRG

! Fluoranthene 1.7160000 1.6882611 0.01-1.62 j

20.00 AVRG:Pvrene I | 1 . 9180000 | 1.8749487 0.01 -2.24 50.00 AVRG

!Butvlbenz ylphthalate 0.7700000 0.7440325| 0.01 1 -3.37 50.00 | AVRG|3,3'-Dichlorobenzidine 0.5420000

0.5080123 j 0.01 j-6.27 50.00

j AVRG

ysis (2 - etliylhexyl) Phthalate Anzc (a) anthracene

| 1 . 1480000

i 1 . 7590000

| 1.1179279|

| 1 . 7380184

0.01 1

0.01

-2 . 62 |

-1.19150.00

50.00

| AVRG

AVRGRirvsene | 1 . 6580000 1.5977958 0.01

- 3 . 63 j50.00 AVRG

[ Di - n - oct\- lphthalate 2.2640000 2.1753928 0.01 - 3.91| 20.00 AVRGBenzo(b) £ 1uoranthene 2 . 1450000 2.3078830 0.01 1 7.59 50.00 | AVRG

!Benzo(h)£ luoranthene 1.9380000j1.7480163 |

0.01 1 -9.80 50.00 | AVRG

:Benzo ! a!p vrenej1.7000000 1.6625427 j

0.01) -2.20 20.00 | AVRG

|Indeno(1 : 2,3 -cdipyrene j1.2280000 j1.1978155 0.01 -2.46 50.00 AVRG:Dibenzo(a ,h)anthracene 1.4900000 1.4443789 0.01 -3.06 50.00

j AVRG

Benzo (g,h ,i)pervlene 1 . 5630000 1.5249788 0.01 -2.43 50.00 | AVRG1

2 -Fluorophenol !1.2980000 | 1.2764316 | 0.01 1 -1.66| 50.00 | AVRG

Phenol -d5 |1.6910000 1.6216721 0.01 -4.10 50.00j AVRG

Nitrobenz e n e - d 5 0.4330000 ! 0.4 174 573 0.01 -3.59 50.00 [ AVRG

2 -Fluorob iphenvl | 1.3330000 1.3529710 0.01 1.50 50.00 j AVRG

2 , 4 , o - T r i oromooiienol 0.4030000 ! 0 . 3956922 j 0 . 01 j - 1.56 | 50.00 AVRGTerphenyI -dl4 | 1 . 0590000 i 1 . 01002 30 j 0.01 -4.62 50.00 AVRG

1 i i i I 1

FORM VII SV

58b

y c:<i<y6>

Data File; 2chem/5972hp64.i/DF020311A64.b^HG020311A64.dDate : ll-MAR-2002 08:55Client ID: SSTD080Sample Info: SSTD080:2070Volume Injected <uL): 1.0Column phase: RTX-5


Operator: 2070 Column diameter: 0.32

LO

ooLO

Sample Info: SSTD080:2070Volume Injected <uL>: 1.0 Operator: 2070



Date : ll-MAR-2002 08}55


587

* * ISTD DIFFERENCE REPORT**

Injection Date of Current CCAL: ll-MAR-2002 08:55

Injection Date of Previous CCAL: 10-MAR-2002 14:16

Maximum %Difference of ISTD: + 100 Minimum %Difference of ISTD:

ISTD Name Current CCAL Previous CCAL % DiffArea Area

1,4-Dichlorobenzene-d4 105735 106189 -0.4Naphthalene-d8 414967 418210 -0.8

Acenaphthene-dlO 285056 297124 + 4.1Phenanthrene-dlO 592430 631561 -6.2

Chrysene-dl2 562509 596220 -5.7

¥Perylene-d!2 300075 309056 -2.9

within +/- 30 seconds (0.5)

Current CCAL Previous CCAL AbsoluteRT RT Difference

1,4-Dichlorobenzene-d4 Naphthalene-d8

Acenaphthene-dlO Phenanthrene-dlO

Chrysene-dl2 Perylene-dl2

8 249 8 266 0 01710 143 10 143 0 00013 152 13 169 0 01715 485 15 485 0 00019 949 19 966 0 01722 434 22 451 0 017

Retention time must fall

ISTD Name

i

-50



588


Data file Lab Smp id Inj Datej

Operator Smp Info]

Misc Info Comment j

Method | Meth DateCal DateAls bottle Dil Factor Integrator

CompuChem

Semivolatile Report SW-846 Method 8270C /chem/5972hp64.i/DF020311A64.b/HG020311A64.d

SSTD080ll-MAR-2002 08:55 2070SSTD080:2070

Client Smp ID: SSTD080

Inst ID: 5972hp64.i

/chem/5 972hp64 ll-Mar-2030 09 10-MAR-20 02 17 2

1.00000 HP RTE

Target Version: Processing Host:

3.50einstein

i/DF020311A64.b/8270Cv6 .m26 mikhael Quant Type: ISTD23 Cal File: HL020310A64.d

Continuing Calibration Sample




DF 1.00000 Dilution Factor^ vt 1000.00000 Volume of final extract (uL)■ Vo 1000.00000 Volume of sample extracted (mL)W vi 1.00000 Volume injected (uL)


Compounds

QUANT SIG


AMOUNTS

CAL-AMT

( NG)

ON-COL

( NG) SIMILARITY

• 1 1,4-Dichlorober:zene-d4 152 0.249 8.249 (1.000) 105735 40.0000

• 2 Naphthalene-d6 136 10.143 10.143 (1.000) 414967 40.0000

. •> Acenaph’ h n e - a 10 164 13.152 13.152 (1.000) 285056 40.0000

• 1 Phenanthrene-dlC 188 15.485 15.485 (1.000) 592430 40.0000

• E> Chrysene - d ■ 2 24 0 19.949 1 9 94 9 (1.000) 562509 40.0000

' Pervleru - d ; 2 264 22.434 22.434 (1 . 000) 300075 40.0000

2 7 2 -Fluorochenci 112 6.457 6.457 (0 . 783) 269927 80.0000 -j

CD (J\i_n

6 Phenol-dS 95 7.742 7 74 2 (0.939) 342935 80 . 0000 76.71

5 9 Nitrobenzene-dB 8 2 9.065 9.095 (0.897) 346462 80.0000 77.15

S 10 2 -Fluoroblpheny1 172 11.884 11 . e84 (0.904) 771345 80.0000 81.22

? 11 2 , 4 , 6 - Tr ibroitoohenol 330 14 . 454 14.454 (1.099) 226159 80.0000 78.80

;• 12 Terphenyl-d!4 24 4 17.852 17.852 (0.855) 1136294 80 . 0000' 76 31

I 1 N - N11 rosed imet hy laini ne 4 2 4 . 327 4.327 ( 0.525) 100269 80 . 0000 79.45 8840

M Py r id l n« 7 5 4.327 4 . 327 (0.525) 175431 80.0000 8 0.18 9411


Compounds

15 Benzaldehyde

16 Phenol j

17 Bis(2-chloroethyl)ether

18 2-Chlorophenol

19 1,3 - DichlorobenzeneI

20 1,4-Dichlorobenzene21 Benzyl Llcohol

22 1,2-Dichlorobenzene23 2-Methyjlphenol

24 2,2' -oxybis(1 -Chloropropane)

25 Acetophenone26 3 - Met hyjlphenol

27 4-Methylphenol


2 9 Hexachl'o roe thane

30 Nitrobenzene

31 Isophorone32 2-NitrJphenol

33 2,4-Dimethylphenol

34 Bis(2-chloroethoxy)methane

35 2,4 -Dichloroohenoli

36 1,2,4-Ijr ic h loro benzene

.37 Naphthalene|3 S 4 • Chlorjoani 1 me

3 9 He >: a c h ll o r o b u t a diene

40 Caprolactam

41 4-Chioro-3-methylphenoll|

42 2 - Methy 1 naphtha 1ene

43 1-Methy1 naphthalene4 4 Hexachllorocyclopentadiene

45 2,4,6-Trichlorophenol

46 2,4,5-Trichlorophenol ■17 1.1' -Eijphenyl

4 8 2 - Ch 1 o ronaphc n.a 1 ene|

4 9 2 • N: t roar.: 1 i ne

5 0 Dimethy1pht ha late

: 1 j e n e

rer.ann5 : 3 - N l t r 'ian.: 1: ne

J .Acen.apht ne ne

5 5 2.4 - D i :• • t rooheno:

.1

56 4 -N11rophenoi

• o toluene

5 8 Dibenzofurar.

na la: e

.er.y 1 - phenyl ethe

AMOUNTS

QUANT SIG


CAL-AMT

( NG)

ON-COL

( NG) SIMILARITY

77 7.641 7.641 (0.926) 182826 80.0000 78.95 9710

94 7.776 7.776 (0.943) 290773 80.0000 75.68

93 7.894 7.894 (0.957) 204668 80.0000 78.41

128 7.996 7.996 (0.969) 282906 80.0000 79.63 9323

146 8.199 8 . 199 (0.994) 318330 80.0000 77.98

146 8.283 8.283 (1.004) 319045 80.0000 77.46

108 8.452 8.452 (1.025) 162485 80.0000 77.59

146 8.554 8.554 (1.037) 313643 80.0000 77.36

108 8 . 621 8.621 (1.045) 248520 80.0000 80.22

45 8.672 8 . 672 (1.051) 378194 80.0000 78.46 9006

105 8.858 8.858 (1.074) 344398 80.0000 hs . 93 9239

108 8 . 824 8.824 (1.070) 259476 80.0000 77.05

108 8 . 824 8 . 824 (1.070) 259476 80.0000 77.05

70 8.875 8.875 (1.076) 165854 80.0000 78.15 8492

117 9 . 010 9.010 (1.092) 166343 80.0000 78.04 9379

77 9.129 9.129 (0.900) 292487 80.0000 82.96 9283

82 9.450 9.450 (0.932) 543052 80.0000 77.79 9178

139 9.602 9.602 (0.947) 173969 80.0000 78.16 8442

122 9.602 9.602 (0.947) 264700 80.0000 79.79 8456

93 9.737 9.737 (0.960) 311473 80.0000 74 . 75 9462

162 9.923 9.923 (0.978) 260358 80.0000 75.77

180 10.075 10.075 (0.993) 302158 80.0000 75.41

128 10.177 10.177 (1.003) 1189258 80.0000 79.29 9319

127 10.261 10.261 (1.012) 384754 80.0000 80.22 7545

225 10.413 10.413 (1.027) 208743 80.0000 75.65 9362

113 10.718 10.718 (1.057) 93949 80.0000 79.92 9664

107 10.938 10.938 (1.078) 307230 80.0000 80.48 9218

142 11.208 11.208 (1.105} 571173 80.0000 75.98

142 11.394 11.394 (1.123) 534977 80.0000 74 . 58

237 11.597 11 . 597 (0 . 882) 229646 80.0000 81.33 9604

19b 11.749 11 .749 (0.893) 234303 80.0000 80.77

196 11.817 11 .817 (0.898) 246536 80.0000 80.11

154 12.053 12.053 (0.916) 672680 80.0000 78.78 7597

162 12.104 12.104 (0.920) 583440 80.0000 79.78

65 12.341 12.341 (0.938) 208226 160.000 159.1 9503

16 3 12.67? 12.679 (0.964 ) 722277 80.0000 80.82 8804

165 12.831 12.831 (0.976 ) 196400 80.0000 79.87 9274

152 12.899 12 8 0 9 n . 9 9 1 ) 1343394 80.0000 78.26 8903

138 13.085 13.085 (0 . 995 1 206310 160.000 158 . 5 9159'

154 13.220 1 3 . 220 (1 . 005) 824561 80.0000 74 .21 8962

184 13.254 13.254 (1.008! 193479 400.000 444 . 9

109 13.304 13.304 (1.012) 122806 160.000 158.6 7625

165 13.507 13.507 11.02 7 J 285507 80.0000 80. 11 8725

168 13.474 13.4 74 (1 . 024) 892980 80.0000 77.63 9193

149 13 . 962 1 3 562 (1.054) 028928 ' 80.0000 78.38 9551

204 13.996 I 3 . 9 9 S (1.064) 384655 80 . 0000 77.85 7476

164 14 .048 14.048 (1.066) 1054714 80 . 0000 7 9 . 91 7 525

59


»

Compounds

QUANT SIG


AMOUNTS

CAL-AMT

( NG)

ON-COL

( NG) SIMILARITY

62 4-Nitroaniline 138 14.116 14.116 (1.073) 213914 160.000 161.6 8758

6 3 4 , 6-Dinitro-2-methylphenol 198 14 . 167 14 . 167 (0.915) 202999 160.000 169.3 9422

64 N-Nitrosodipheny1amine 169 14.201 14.201 (0.917) 505817 80.0000 78.39 8113

65 1,2-Diphenylhydrazine 77 14.251 14.251 (1.084) 846132 80.0000 79.20 9353

6 6 4-Bromophenyl-phenylether 248 14.758 14.758 (0.953) 246209 80.0000 78 34 9666


69 Atrazine 200 15.012 15.012 (0.969) 234997 80.0000 79.75 9163

. 69 Peneachlorophenol 266 15.283 15.283 (0.987) 206161 160.000 160.3 7691

70 Phenanthrene 178 15.519 15.519 (1.002) 1712112 80.0000 77.66

71 Anthracene 178 15.570 15.570 (1.005) 1721445 80.0000 76.83

72 Carbazole 167 15.790 15.790 (1.020) 1144864 80.0000 77.63 9621


74 Fluoranthene 202 17.261 17.261 (1.115) 2000353 80.0000 78.71

75 Benzidine 184 17.413 17.413 (0.873) 1203807 160.000 148.7 8821

76

77

Pyrene |

Butylbenzylphthalate

202

149

17 . 683

18 . 816

17.683

10.816

(0.886)

(0.943)

2109351

837050

80.0000

00.0000

78.19

77.32 9192

78 3,3'-Dichlorobenzidine 252 19.830 19.830 (0.994) 571523 80.0000 74.96 8084

79 bis (2-ethylhexyl)Phthalate 149 19.780 19.780 (0.992) 1257689 80.0000 77.90 9433

80 Benzo(a! ant nracene 228 19.915 19.915 (0.998) 1955302 80.0000 79.05

81 Chrysene 228 19.999 19.999 (1.003) 1797549 80.0000 77.08

82 Di -n-oct •/lphtha late 14 9 20.760 20.760 (0.925) 1305562 80.0000 76.87

83 Benzo(b) f luoranthene 252 21.690 21.690 (0.967) 1385076 00.0000 86.06

■^4 B e n z o i k ) fluoranthene 252 21.741 21.741 (0.969} 1049072 80.0000 72.13

P Benzo la) pyrene 252 22.333 22.333 (0.995) 997775 80.0000 78.25

86 I ndeno(1 , 2,3■cdipyrene 276 25.021 25.021 (1.115} 718869 80.0000 78.02 0 (M)

37 Dibenzo a,n)anthracene 273 25.021 25.021 (1.115) 866844 80.0000 77.54 8247

98 Benzo !a, h,i)peiy1ene 276 25.849 25.349 (1.152) 915216 80.0000 78.07 9281

QC

M -

Flag

Comp

Liegend

3und response manually integrated.

3- //- „ l

Data File: /chem/5972hp64.i/DF020311A64.b/HG020311A64.dInjection Date: ll-MAR-2002 08:55Instrument: 5972hp64.iClient Samplej ID: S5TD0B0

lound: 2,4'.6-Tribromophenol Number: ljl0-79-6

Data File: /chem/5972hp64.1/DF020311A64.b/HG020311A64.d Injection Date: ll-MAR-2002 08:55 Instrument: 5972hp64.i

COMPUCHEM a division of Liberty Analytical Corp DATE 3 / // Wl INITIAL TIME OF TUNE O# y ? SH1FT/S(A) (B)(C)

GC/MS SEMIVOLATILE RUN LOG TIME TUNE EXPIRES 2 o > LINKER /METHOD St ^COMPUCHEM .LOGBOOK 4 YYY 4 (5972hp64)

Tl [T1 PREVENTIVE MAINTENANCE/Vw f_______________________________________________________________

£CTE

FILE NAMEotTED


CHEMIST COMMENTS! PTC j/lM'blfiTibNLO

1 l)ro l c l l( A Zu / .5 >H >61 T) Att/1 i_i4L ________Z7 -rzv- - /.-A

2 —* If A/<7 / / / oS st ^sr7>,û___

3 JA/lAlU-IrUu / / / 0C(?l rfd/cjA______ (/A/1 V /V.- t 1

4 / (7h 0-7 7- 1ta/c S| / / IV i i û//C OCC 2 0-__ £? 24 7 ?____ _____ f~ - n. x r______________________

5 7 fD ? U-7 r. ? h l\A(i f|- / / ‘*<4% ^r/Z^q pc' s ____ z_z___________t o____________

6 / r?) 70.1 j- ihAfa Kf / / i/3'7 A 1-J.Uouv ! 6 /____Z-i-

7 ZTZcTUcYi AC// /7/ / / ?/V ZcifC Gt.c- l ^ z K

8 / TH / / 12 ‘TO __________ ^ /i j_ ___Z-X______

9 (a)Ailld Zv-PAZv / / / / 3 7 5 ___________ 1 H<>p ^______________________

10 rr)7 0.n-ib?A& / / / / If 0 s' fidfCnuu ifr'hL___i-Z.A-

1 1 fTnoos .sT) Mv in / / '44-2 vv-Pf'Go c?p 2 S'

12 (Z? U 73 / / / /r /A________ _______:

13 (a)Z> /0/U- TiVM, / / / s'vr '5nt 4a cit’2. ~) /~1 t L

14 lAWSa-'VSAun 4 / / lu>^ D>»CSiAO

15 IA3MS2 -H3 A(*HZ

■/ no 02 ouûo'-f

16 / lms2 -S/UW JU/ / HMfe Ojo L 3ct oj>

17 / m/ / 0 ia o l

18 / / / 02oL>MUO^

19 UuMO-fcAld z / / IW 02OGHU03

20 IA240 -AH / / /

________

V l» 0 2o6>H Wo3D

21 / I/I 2 Aid mor

/ <!' 0 >û^| WoM 4\J

s/

22 ---------L_

/

_J----------

/-------------------------------------------- ------------------

24 t___2=_i______ —

STANDARDS -4 yTune Analytical lilt. Std. Column Type SUPERVISOR APPROVAL ZZvZZ ^

StdHD-ft-------- -------------------------------------------------------------------------------- --ZZ^sV-A--------------- DA-FE/l(o >_________________________

Lot # llAiS. ■— C 3 /> Z * a I_______ ___S 1 \ f, \^. The presence of the Cheinisi's employee II) number. or signntuic. on this run log attests iliat .and compliance vnih ilie method •. M »l'

occurred Any SOI’ deviations require documentation by the responsible chemist tngethei with the chemist's initials ami ihc initials «

lab supervisor aijî (,)A department representative, signifying nppiovnl of the deviation I I Oo/nl


Lab

Lab

Name :

Code :

COMPUCHEM

LIBRTY Case



Contract: 8270C



Init. Calib. Date(s): 03/10/02 03/10/02


GC Col umn : RTX - 5 ID: 0.32 (mm)

iI COMPOUND

|Phenol |

|Bis(2 -chioroethyl)ether

J 2 -Chlorophenol I 1, 3-Dichiorobenzenei 1 --------------|1,4-Dichiorobenzene

I 1,2-DichiorobenzeneI | -----------j2'Methylphenol |2,2 ' -oxyEis(1 -Chloropropane)

[4-Methylphenol

|N-Nitroso-di-N-propylamine__

IHexachloroethane

[Nitrobenzene

Isophorone___-Nitrophenol

, 4-Dimethylphenol___________

Bis(2 -chloroethoxy)methane_

2 , 4-Dichlorophenol

1,2,4-Trichlorobenzene

|Naphthalene

I 4 - Chioroaniline___________

IHexachlorobutadiene1 I -----i 4-Chloroi3-methvlohenol

| 2-Methylnaphthalene_________

| Hexachlorocyclopentadiene_j 2,4,6 -Trichlorophenol______

'2,4,5-Trichlorophenol______

2-Chloronaphthalene_________

j2 - Nit roani1ine________________

|Dimethvlphthalate____________

;2 , 6-Dinitrotoluene__________

iAcenaphthylene

- 3-Nitroani 1 me________________

!Acenaphthene__________________

;2,4 - DiniDrophenol____________

I 4-Nitrophenol_________________

! 2,4-Dinitrotoluene__________

! Dibenzofuran___________________

iDiethylphthalate_____________

4 -Chlorophenyl-phenylether ] FluoreneJ

i 4 -Nitroariil me

6-Dinibro-2-methvlohenol

page 1 oE 2

(RRF8 0.000 | 1 1 1 1

RRF OR 1 OR | MIN | %D OR 1 MAX %D OR|CURV|j AMOUNT |AMOUNT |

1 I

RRF j

1

%DRIFT 1

1

%DRIFT |TYPE|

1.4530000

1----------- 1| 1.4288473|

------10.01 1

-------- 1-1.661

----------- 1 — |2 0.0 0|AVRG|

| 0.9870000 0 . 9319326 0.01 -5.58 50.00 AVRG| 1.3440000 j1.2835053 | 0.01 1 -4.50 | 50.00 AVRG|

| 1 . 5440000 1.4632976 j 0.01 1 -5.23| 50.00|AVRG j

j1.5580000 |1.4927116 0.01 1 -4.19 j 20.00 jAVRG|

|1.5340000 j1.4513183 j 0.01 1 -5.39| 50.00|AVRGj

|1.1720000 1.1246352 | 0.01 1 -4.04| 5 0.0 0|AVRG

1.8230000 1.7604245 0.01-3.43 j 50.00 AVRG|

1.2740000 1.2347748| 0.01 -3.08 50.00 AVRG

|0.8030000 |0.7450387 | 0.05] -7.22| 50.00]AVRG|

|0.8060000 |0.7630464 0.01 j -5.33 j 50.00|AVRG

|0.3400000 0.3503588 | 0.01 3 . 05 | 5 0.0 0 j AVRG

(0.6730000 |0.6693175| 0.01 j -0.55| 5 0.0 0 jAVRG|

j 0.2150000 10.2121352 0.01 j -1.33 | 20.00|AVRG|

0.3200000 0.3120055| 0.01 -2.505 0.0 0 j AVRG j

0.4020000 0.4105081 0.01 1 2.12 5 0.0 0|AVRG|

| 0 . 3310000 |0.3376091 0.01 j 2.00 | 20.00|AVRG|

|0.3860000 j 0.3810025| 0.01 1 - 1.2 9 j 5 0.0 0 j AVRG j

1.4460000 1.4735112 0.01 1 1.. 90 | 50.00 AVRG|

(0.4620000 (0.4780432 | o . o i ( 3 . 4 7 j 50.00[AVRG(

|0.2660000 (0.2634745 0.01 -0.9520.00 jAVRG j

0.3680000 0.3647257 | 0.01 -0.89 20.00 AVRG|0.7240000 |0.7112745 | 0.01 1 -1.76 50.00 AVRG|0.3960000|0.3675725| 0.05 1 -7 . 18 | 5 0.0 0|AVRG j

|0.4070000 |0.41564 95 | 0.012.12 j

20.00 AVRG

0.4320000 0.4243734 0.01 -1.76] 50.00 AVRG|1.0260000 (1.0308065( 0 . 01 1 0.47 | 50.00|AVRG||0.3670000 |0.3725542 0.01 1.51 50.00|AVRG

|1.2540000 1.2582962 0.01 1 0 . 34 | 50.00 AVRG(0.3450000 j 0. 3419095 | 0.01 j -0 . 90 j

50.00]AVRG|

(2.4090000 |2.3558810 | 0.01 ( -2 . 20| 5 0.0 0|AVRG|

(0.3650000 0.3619142 0.01 -0.84 50.00 AVRG

1.5590000 (1.5356203 0.01 -1.50( 20.00]AVRG

(0.0610000 (0.0600705| 0 . 05 1 - 1.52| 50.00(AVRG|

0.2170000 (0.2001577 0.05 -7.76 5 0.0 0|AVRG(0.5000000 (0.5006206 0.01 1 0.12 50.00 AVRG|]1.6140000 1 . 5783827 j 0.01 -2.21 50.00 AVRG|1.4840000 | 1 . 4485386 | 0.01 1 -2 . 39| 5 0.0 0|AVRG|i0.6930000 0.57S6956| 0.01 - 2.06 | 50.00 j AVRG|

(1.8520000 1 . 8147222 | 0.01 1 -2.01 50.00 AVRG10.3800000 I 0.3698028 | 0.01 1 -2 . 68| 50.00(AVRG|!0.1620000i0.1618847 j

! i i

0.01 1

1

- 0.07 j

1

5 0.0 0 jAVRG|

1 1

FORM VII SV59 j


Lab Name: COMPUCHEM Lab cLde: LIBRTY Case No.



Contract: 8270C



Init. Calib. Date(s): 03/10/02 03/10/02


gc co: .umn: RTX-5 ID: 0.32 (mm)

1| COMPOL

i1

ND

1___

j RP.F OR

AMOUNT

| P.RF8 0.000 |

OR|AMOUNT I

1 |

1

MIN |

RRF |

I

%D OR %DRIFT |

1

MAX %D OR

%DRIFT

jCURvj

j TYPE

|N-Nitrosodiphenylamine““ 1-----------

[0.4360000|----------- || 0.4252453 |

------I0.01 |

-------- 1-2.47| 20.00 AVRG

| 4 - Bromophenyl -phenvlether

| Hexachlorobenzene

|0.2120000

0.2610000

| 0.20457930.2538997 j

0.010.01 1

-3 . 50|

-2.72]50.00

50.00

AVRG |AVRG j

I Pentachl'orophenol |0.1740000 | 0 . 1662047| 0.05 1 - 4.4 8 | 20.00|AVRG j

!Phenanthrene 1.4880000 1.4072421| 0.01 j -5.43 j50.00

jAVRG j

iAnthracene I 1.5130000 | 1.4303164 j0.01

-5.46 j50.00 | AVRG

|Carbazol e 0.9960000 1.0017379 0.01 I 0.58 | 50.00j AVRG|

|Di-n- but vlphthalate |1.4890000 1.4193083| 0.01 1 - 4 .68 j 50.00|AVRG j

;Fluoranthene |1.7160000 1 . 6799277 | 0.01 -2.10 | 20.00jAVRG j

| Pvrene 1.9180000 | 1 . 8215947 0.01 -5.03 50.00IAVRG j

! Butylben'zylphthalate 0.7700000 | 0.7258042 0.01 -5.74 50.00 AVRG |

! 3 , 3' -Dichlorobenzidine i0.5420000 | 0.5545583| 0.01] 2.32] 50.00 |AVRG]

!bis(2-ethvlhexyl)Phthalate ^enzo(a)anthracene

|1.1480000

1.7590000

| 1 . 1003856 j

| 1.6720496 j0.01 I

0.01

-4 . 15|

-4.94

50.00

50.00

|AVRG| jAVRG j

PPhrysene 1.6580000 1 . 5703507 0.01 -5.29| 50.00 | AVRG

]Di-n-octvlphthalate 2.2640000 2 . 1379883 0.01 -5.56] 20.00 ] AVRG

Benzo(b)fluoranthene 2.1450000 1 . 7689854 0.01 1 -17.53 50.00j AVRG|

!Benzo(k) fluoranthene I 1.9380000 | 2.3180102 | 0.01] 19.61 50.00jAVRG|

| Benzo(a)pvrene j1 . 7000000 | 1.6622862 j 0.01 j-2.22 20.00

AVRG j

! Indeno (1 l2 , 3 - cd)pvrene 1.22800001 . 1811904 j

0.01] -3.81 50 . 00 AVRG!Dibenzo(a,h)anthracene 1 .4900000 1.4441409

0.01 j-3.08 50.00 AVRG

i Benzo ig, n,i)pervlene 1 . 5630000 1.5193161 0.01 -2.79 50.00 AVRG1

i 2 -Fluorophenol ! 1 . 2980000 | 1 . 2760461 0.01 -1.69 50.00AVRG j

: Phenol - dS 1 . 5910000 1.6267774 0.01 -3.80 50.00 AVRG |1 Mitrobenzene-d5 | 0.4330000 j 0 . 4458545 0.01 2.97 50.00 AVRG■ 2 - r luorotpiphenyl j1 . 3330000 1.3289473| 0.01 -0.30 50.00 AVRG2 , 4,6 -Tribromophenol 0.4030000

|0 . 3861743 j0.01 -4 . 18 | 50.00 | AVRG

ierpher.v 1 - dl 4 | 1 . 0590000 ]0.9901198] 0.01 1 - 6.5 0 | 50.00j AVRG

1 [ 1

oaqe

FORM VII SV

59b

<:<10A6>

Data Filet /chem/5972hp64. iXDF020311B64. b/HG020311B64. d

Date : ll-MAR-2002 22:53

Client ID: SSTD080


Volume Injected (uL): 1+0

Column phase: RTX-5


Operator: 2319


cnLD

3.1- j

3.0- i

2.9-i

2.8- i

2.7- :

2.6-:

2.5- ;

2.4- ;

2.3-j

2.2- j

2.1- i

2.0- i

1.9- j

l.s-i

1.7- ;

1.6- ;

1.5- j

> 1.4-1

1*3-:

1.2- i

1.1- i i.o-i0.9-i

0.8-i

0.7-;

0.6-i

0.5-j

0.4-1

/chem/5972hp64,i/DF020311B64.b/HC020311B64,d (Part 1 of 21

Phenanthrene-dlO+

Data File: /chem/5972hp64. i/DF020311B64.b/HG020311B64.d

Date : ll-MAR-2002 22:53

Client ID: SSTD080



Column phase: RTX-5

Instrument: 5972hp64.i ;oCD

Operator: 2319 LO



CompuChem

Semivolatile Report SW-846 Method 8270C /chem/5972hp64.i/DF020311B64.b/HG020311B64.d SSTD080 Client Smp ID: SSTD08011-MAR-2 0 02 22:532319 Inst ID: 5972hp64.iSSTD080:2319

Data file Lab Smp id

Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date|

Als bottle Dil Factor Integrator Target Version: Processing Host:

/chem/5 972hp64.i/DF020311B64.b/8270Cv6.m ll-Mar-2030 23:20 naegler Quant Type: ISTD10-MAR-20 02 17:23 Cal File: HL020310A64.d2 Continuing Calibration Sample1.00000



Name I

Value Description

DF 1.00000 Dilution Factor^ vt 1000.00000 Volume of final extract (uL)■ Vo 1000.00000 Volume of sample extracted (mL)^ Vi 1.00000 Volume injected (uL)


AMOUNTS

Compounds

QUANT SIG


CAL-AMT

( NG)

ON-COL

{ NG)

* L 1,4-Dich lorebenzene-d-i 152 8 . 264 0 . 264 (1 .000) 123003 40.0000

. 2 Naoncha 1‘

ere-d3 13d 10 . 150 10 . 158 (1 . 000) 450795 40.0000

* 2 Acer.aphr 164 13 . 167 1 3 167 (1 . 000) 321474 40.0000

Phenanohrene-d 1 01

186 15.433 !5 . 4 8 3 .ooo) 666326 40.0000

Chryse,, . -i i 240 19.943 1'.' . 3 4 i 1 1 .0001 642652 40.0000

• Pervlene•

-di: 264 22.449 -> ■? 44 9 ( 1 .000) 350874 40.0000

f 7 1 - r iuoroohencd r

112 6.455 455 (0.781) 313915 80.0000 78.62

C C Pher.o 1 - d c. 9 9 7 . 757 7 . 757 (0.939) 400197 80.0000 76.95

Ns z rebar. car.o - d£ 82 9.109 : 0 9 (0.£97} 401978 80.0000 CDru

1 19 2 -Fiuoro b i pheny1 172 11.882 882 (0 . 902) 854444 80.0000 79.78

-■ ;; lbromopnenol 330 1 4 4 69 14 . 4 5 9 (1 .099) 248290 80.0000 76.71

5 : 2 1 - d : 4 244 1 7.547 : 7 . eo-; (0.395) 1272605 80.0000

oCD

N-N:crosodinethvlam:na1

4 1 4.342 4 . 34 2 (0.525) 116554 80.0000 79.39

P y r i c i r. a 7 9 4.224 4 . 3 2 5 (0.523) 203742 80.0000 80.05

SIMILARITY

8711

9454

(Mi j

flO

59 b) h\o/-

Data File: /chem/5972hp64.i/DF020311B64.b/HG020311B64.dReport Dalte: ll-Mar-2030 23:20

Compounds

15

16

17

18

13

20

21

23

2425

26

27

2 B

29

30

34

4 0

4 2

4 3

44

4 1

4 8

4 9

50

Benzaldehyde Phenol J

Bis {2-chloroethy1)ether

2 -Chlorophenol



Benzyl alcohol I

1,2-Dichlorobenzene

2- Methylphenol

2,2'-oxybis(1-Chloropropane)

Acetophenone

3- Methylphenol

4- Methylphenol


Hexachloroethane

Nitrobenzene

1 sophorone

2 -Nit rophenol

2.4- DimethyIphenolBis (2-chlbroethoxy)methane

2.4- DichJorophenol

1.2.4 - Trilchlorobenzene

Naphthalene

4-Chloroanilme

Hexachlorobutadiene

Caprolactam4 - Chioro-jj ■ methylphenol

2-Methylnapht halene

1-Methy1 naphthalene

Hexachiorocyc1ooentadieneI

2,4,0- TriJch lorophenol2.4.5 -TrJchlorophenol1 . 1' - £ ipller.y 1

2 - Chi orenapht ha 1ene

2 - N i t roam 1 i ne

Dimethvipnthalate' \

2,6-Dimtrotoiuene

Acenaphthy1ene

3 - N j t ro-i n : 1 i ne

Acenapht’neneI

2,4 -D: :u drocheno1J '.4 -Nit rophenoi

Dibe;--zo: Jrar-

Diet hv ipht ha late‘ I

4 - Ch i oropher.y 1 - phenyl et iter

F1corone

AMOUNTS

QUANT SIG


CAL-AMT

( NG)

ON-COL

( NG) SIMILARITY

77 7.639 7.639 (0.924 ) 206263 80.0000 76.57 9764

94 7.774 7.774 (0.941) 351505 80.0000 78.65

93 7.909 7.909 (0.957) 229261 80.0000 75.50

128 8 . 010 8.010 (0.969) 315750 80.0000 76.40 8907

146 8.213 8.213 (0.994) 359980 80.0000 75.81

146 8.281 8.281 (1.002) 367216 00.0000 76.64

108 8.467 8.467 (1.025) 185510 80.0000 76.15

146 8 . 568 8.568 (1.037) 357033 80.0000 75.70

108 8 . 636 8.636 {1.045) 276667 80.0000 76.77

45 8.670 8.670 {1.049) 433075 80.0000 77.23 9063

105 8.873 8.873 (1.074) 403904 00.0000 77.55 8639

ioe 8 . e39 8.839 (1.070) 303762 80.0000 77.54

108 8.839 8 . B 3 9 (1.070) 303762 80.0000 77.54

70 8.873 8.873 (1.074) 183284 80.0000 74.24 0 (M)

117 9.008 9.008 (1.090) 187714 80.0000 75.70 9488

77 9 . 126 9 . 126 (0.898) 315880 80.0000 82.47 9707

82 9.448 9.448 (0.930) 603450 80.0000 79.57 9454

139 9.600 9.600 (0.945) 191259 80.0000 79.10 8394

122 9.600 9.600 (0.945) 281301 80.0000 78.05 7495

93 9.752 9.752 (0.960) 370110 80.0000 81.76 9538

162 9.938 9 . 938 (0.978) 304385 80.0000 81.54

180 10.073 10.073 (0.992) 343508 80.0000 78.92

128 10.175 10.175 (1.002) 1328503 80.0000 81.54 9764

127 10.259 10.259 (1.010) 430999 80.0000 82.72 8286

225 10.428 10.428 (1.027) 237546 80.0000 79.24 8793

113 10.732 10.732 (1.057) 107053 80.0000 83.83 9501

107 10.935 10 . 935 (1.077) 328833 80.0000 79.29 9776

142 11.223 11 . 223 (1.105) 641278 80.0000 78.53

142 11.409 11.409 (1.123) 617137 80.0000 79.20

237 11 .595 11.595 (0.881) 236330 80.0000 74.22 8926

196 11 . 747 11 . 747 (0.892} 26724 1 80.0000 81.68

196 11.831 11.831 (0.899) 272850 80.0000 78.61

154 12 . 068 12.068 (0.917) 768624 80.0000 79.82 7592

162 12.119 12.119 (0.920) 662755 80.0000 80.36

6 5 12.355 12.355 (0.938) 239533 80.0000 81.13 9292

163 12 . 677 12 . 677 (0.963) 809019 80.0000 80.28 9463

155 12.646 12.346 (0.976) 219830 80.0000 79.27 8272

152 12 . 996 12.996 (0.979) 1514709 80.0000 78 . 24 9610

1 35 13 .082 13.062 (0.994) 232692 800.000 92.97 9421

154 13.218 12 . 2 1 B (1 . 004) 987324 so. OOOC 78. eo 9654

184 1 3 . 2 6 S 13.268 (1.008) 193111 400.000 393 . 7

109 13 . 319 13.315 (1.012) ■ 128691 80.0000 73.71 8086

16 5 i 3 522 13.522 (1.027) 321873 80.0000 80.08 8199

163 13.499 13.496 (1.024) 1014818 80.0000 78.23 9023

14 9 1 3 . 8 6 0 13.350 (1.053) 931335 00 . 0000 78 . 09 9710

2 04 ■ c 14.012 (1.064) 436366 80.0000 78.31 0 (M)

16 6 14.04 6 14.046 (1.067) 1166772 80.0000 78 . 38 7662

fu

60:J 2>WW


Compounds

QUANT SIG


CAL-AMT

( NG)

ON-COL

( NG) SIMILARITY

62 4-Nitroaniline 138 14.114 14.114 (1.072) 237764 80.0000 77.82 9061

63 4,6-Dinitro-2-methylphenol 198 14.181 14.181 (0.916) 215736 80.0000 79.97 9208

64 N-Nitrosodiphenylamine 169 14.198 14.198 (0.917) 566704 80.0000 78.08 8785

65 1,2-Diphenylhydrazine 77 14.249 14.249 (1.082) 953497 80.0000 79.14 9523

6 6 4 -Bromophenyl-phenylether 248 14.773 14.773 (0.954) 272633 80.0000 77.13 8927


68x • 1Atrazine 200 15.027 15.027 (0.971) 260062 80.0000 78.47 9199

69 Pentachjlorophenol 266 15.280 15.280 (0.987) 221493 80.0000 76.57 8941

70 Phenanthrene 178 15.517 15.517 (1.002) 1875364 80.0000 75.63

71 Anthracene 178 15.585 15.585 (1.007) 1906114 80.0000 75.64

72 Carbazole 167 15.804 15.804 (1.021) 1334968 80.0000 80.49 9546


74 Fluoranthene 202 17.275 17.275 (1.116) 2238759 80.0000 78.32

75 Benzidine 184 17.427 17.427 (0.873) 1156391 160.000 125.0 0749

76 Pyrene 202 17.698 17.698 (0.887) 2341303 80.0000 75.97

77 Butylbenzylphthalate 149 18.814 18.814 (0.942) 932879 80.0000 75.43 9713

78 3,3' -Dichlorobenzidine 252 19.845 19.845 (0.994) 712776 80.0000 81.83 7889

79 bis (2-ethylhexyl}Phthalate 149 19.794 19.794 (0.992) 1414330 80.0000 76.68 9233

80 Benzo(a)anthracene 228 19.930 19.930 (0.998) 2149092 80.0000 76.05

81 Chrysene 228 20.014 20.014 (1.003) 2018378 80.0000 75.76

82 Di-n-octylphtha late 14 9 20.775 20.775 (0.925) 1500329 80.0000 75.55

83 Benzo(b}fluoranthene 252 21.705 21.705 (0.967) 1241382 80.0000 65.97

Benzo(k)fluoranthene 252 21 . 756 21.756 (0.969) 1626659 80.0000 95.65

Benzo(a ipyrene 252 22.347 22.347 (0.995) 1166506 80.0000 78.24^^86

Indeno (1,2,3-cd)pvrene1

276 25.052 25.052 (1.116) 828898 80.0000 76.94 0

87 Dibenzo(a,h)anthracene 278 25.035 25.035 (1.115) 1013423 80.0000 77.53 8370

88 Benzo(g i h,i}perylene 276 25.864 25.864 (1.152) 1066177 80.0000 77.78 9408

QC Flag Legend


f|0

601

Data File: /chem/5972hp64.1/DF020311B64 . b/HG020311B64 . d Injection Date: ll-MAR-2002 22:53

Data File: /cbem/5972hp64.i/DF020311B64.b/HG020311B64.d Injection Date: ll-MAR-2002 22:53

Data File: /chem/59?2hp64.1/DF020311B64.b/HG020311B64.d Injection Date: ll-MAR-2002 22:53

Data File: /chem/5972hp64.i/DF0203l1B64.b/HG020311B64.d Injection Date: ll-MAR-2002 22:53

COMPUCHEM a division of Liberty Analytical Corp DATE 3 / \ > / 0.3- INITIAL TIME OF TUNE___ SH1FT/S(A) (B) 7 (C)GC/MS SEMIVOLATILE RUN LOG TIME TUNE EXPIRES o c> LINKER /METHOD

ltlftlpo

PREVENTIVE MAINTENANCE j\)c>4(L

CTtFILENAME ftT

EO


CHEMISTCOMMLNTS(F.TC.)/DISPO^jp^

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s ✓ \ r18 '/f f,) 2lo c - irAOu / / / etc S" Hu. C->uT. Ehl /A C7 22 n u Q/ 2

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_________ _ --------------------

23 / /_

24_ . ~77./.

... .

Std. ID ft

Tuneloii

Analytical

-■. <7?S 7

Int. Std.

___y

Column Type

ftTx -b

SUPERVISOR APPROVAL .DATE___3A-^U

Lot ft5)1*5 5)^

I he presence ot the Chemist’s employee II) number, m signature. on this mn log attests that si net compliance with the me tin "l s )l li.ii

occurred Any SOP deviations require documentation by the responsible chemist together with the chemist s initials ;uui the initials o[ the

lab supervisor and a OA department representative, signilymg approval ot the deviation. (i l dee


Lab Name: COMPUCHEM




Contract: 8270C



Init. Calib. Date(s): 03/10/02 03/10/02


GC Column RTX-5 ID: 0.32 (mm)

I COMPOUND |RRF OR

I AMOUNT

| Phenol__I| 1.4530000| Bis { 2 -ch'loroe thyl) etherj 0.9870000 j 2 -Chiorophenolj 1 . 3440000

j 1, 3 -Dichllorobenzenej 1 . 5440000

1,4 -Dichllorobenzenej 1.5580000

1 1, 2 - Dichllorobenzene'| 1 . 5340000

j 2 -Methvljphenolj 1.1720000

j 2,2'-oxybis(1 -Chloropropane) j1.8230000

| 4 - Me thyl phenolj 1.2740000

|N-Nitroso-di-N-propylamine__|0.8030000

IHexachloroethane 1 )|Nitrobenzene_____

IIsophorone________

i-Nitrophenol_______

:, 4-Dimethylphenol

Bis(2 -chjloroethoxy)methane_

2,4 -Diehlorophenol___________

j1,2,4-Trichlorobenzene_

!Naphthalene

4-Chloroaniline___________

Hexachlorobutadiene_____4 -Chloroj- 3 -methylphenol


!Hexachlorocyclopentadiene_I 2 , 4 , 6-Trichlorophenol_____

: 2,4 ,5-Trichlorophenol_____

!2-Chloronaphtha1ene________

' 2 - Nit roan lime_______________

Dime t hy1ph t h a1a t e___________

2,6 - Dim trotoluene_________

■ Acenaphthylene_______________

3-Nitroaniline

Acenaphthene__

I 2,4-Dinitrophenol

| 4 -Nitrophenoi_______

!2 , 4-Dinitrotoluene 1 |1Dibenzofuran________

IDiethylphthalate___

: 4 -Chloropheny 'Fluorene |

- pherivle t he r

: -Nitroani1ine I- Dim t ro - 2 - met nvlohenol

page 1 o

| 0.8060000

| 0.3400000

|0.6730000

|0.2150000 j0.3200000

0.4020000 |0.3310000

| 0 . 3860000 j 1 . 4460000

|0.4620000j0.2660000

j 0.3680000

j0.7240000

| 0.3960000

| 0.4070000

| 0 . 4320000

! 1 . 0260000

0.3670000

; 1 . 2540000 j0.3450000

j 2 .4090000 j 0 . 3650000

j 1 . 5590000

| 0.0610000 jo.2170000

jo.5000000

|l.6140000

j 1 . 4840000

■0.6930000

j1.3520000

10.3300000

0.1620000

|RRF80.000 | 1 1 1 1

1 OR | MIN | %D OR 1 MAX %D OR|CURV|

|AMOUNT | RRFi%DRIFT

1

%DRIFT TYPEj

1.4397790|0.01 j

-0.9120.00|AVRGj

0 . 9141643 j 0.01 j-7.38

5 0.0 0|AVRG j

j1.2938858 0.01 1 -3.73 | 50.00 jAVRG

j1.4731548I 0.01 j -4.59 j 50.00 jAVRG j

1.5080776 0.01 -3.2020.00 j AVRG j

|1.4652527 0.01 -4 . 48| 50.00 AVRG|

1.0669099| o. oi | -8.97 j 5 0.00 AVRG j

1.6512777 j 0.01 j-9.42

50.00|AVRG j

|1.1709711| 0.01 1 -8.09| 50.00|AVRG|

|0.7155306 0.05 1 -10.89|50.00 j AVRG j

jo.7663317 0.01 j -4.92 | 50.00 j AVRG j

0.3568400| 0.01 j 4.95 j 50.00jAVRGj

jo.6538337j 0.01 j -2.10 j 50.00 j AVRG j

0.2255032 j0.01 4.88 20.00 AVRG

|0.3211349 0.01 0.35 50.00 AVRG|0.4 046702 0.01 0.66 50.00|AVRG|

0.3299363 0.01 -0.32 20.00 AVRG

0.3884482 0.01 1 0.63 | 50.00 j AVRG j

| 1 . 4601014 j0.01 0.98 50.00 AVRG

|0.4794892 0.01 3.78 | 50.00 AVRG

0.2717179 0.012 . 15 j 20.00|AVRG

j 0.3443585 j 0.01 j -6 . 42 | 2 0.0 0 j AVRG j

0.6950783 j 0.01 1 -3.99 j50.00 AVRG

|0.45563790.05 j 15.06 | 50.00 AVRG

0.42597170.01 j

4.66 20.00 AVRG|0.4416700| 0.01 1

2 . 24 j 50.00 j AVRG j

|1.06427940 . 01 j 3 . 73 j 5 0.0 0|AVRG|

i0. 3600090 1 0.01 -1.90 50.00 AVRG! 1 . 2426044 | 0.01 -0.91 50.00 AVRGj 0 . 3 3 1 3 5 5 7 0.01 1 -3.95 5 0.0 0|AVRG|

j2 . 3562358 j 0 . 01 1 -2 . 19 j 50.00|AVRG|

j 0 . 32 34 94 6 0.01 -11.37 50.00 AVRG: 1 . 3979094 0.01 -10.33 20.00 AVRG| 0.0614193 0.05 0.69 50.00 AVRGj0.214318lj 0.05 j

-1 . 24 | 5 0.0 0 j AVRG|

| 0.4 516069 0.01-9.68 j 5 0.00 AVRG j

j 1 . 5369302| 0.01-4.78 j 5 0.00 AVRG j

j 1 . 4003320 0.01-5.64 j 5 0.00 AVRG j

0 . 6 6 8 9 7 9 9 | 0.01 j -3 . 47 j 5 0.0 0 j AVP.G 1

jl.7331799! 0.01 -6.42 5 0.0 0 j AVRG j

i0.314 33 75 ! 0.01 - 1 7 . 2 8 | 50.00 AVRG

1 0. 1678505 I

! j

0.01 J

13.61

1

5 0.0 0|AVRG

1 !

FORM VII SV60/'


Lab Name: COMPUCHEM




GC Column: RTX-5 ID:

Contract: 8270C



Init. Calib. Date(s): 03/10/02 03/10/02


0.32 (mm)

] 1

j COMPOUND1 1

i 1 _

|___ |RRF80.000]|RRF OR | OR j

|AMOUNT jAMOUNT |

1 1 1

1

MIN |

RRF |

1

1

%D OR 1

%DRIFT I

|

1

MAX %D OR|CURV

%DRIFT |TYPE

|1 iIN-Nitrosodiphenylamine

I 11 0.4360000 0.4140995|

----------- |0.01 I

---------------- |-5.02|

--------------------- |----------20.00|AVRG

!4-Bromophenyl-phenylether

|Hexachlorobenzene

|0.212000010.2223332 |

0.2610000|0.2485915 |

0.01 1

0.01 1

4.87 j

-4.75

50.00|AVRG 5 0.0 0 j AVRG

| Pentachllorophenol |0.1740000|0.1716925[ 0.05 1 -1.33| 2 0.0 0|AVRG

iPhenanthrenej1.4880000|1.3325226 | 0.01 | -10.45| 50.00 jAVRG

|Anthracene |1.5130000|1.4127003 | 0.01 I -6.63 | 50.00|AVRG

1Carbazole 0.9960000 0.8634642 | 0.01 I -13.31j 5 0.0 0 j AVRG

|Di-n-butiylphchalate 1.4890000|1.3337870 | 0.01 1 -10.42| 5 0.0 0|AVRGI Fluorantlhene 1.7160000 1.5570159| 0.01 - 9.2 6 | 2 0.0 0 j AVRG

|Pyrene|1.9180000|1.9991696 j 0.01 1 4.23] 5 0.0 0 j AVRG

[Butylberizvlphthalate j 0.7700000 j 0.7563360 j0.01

-1 . 77 j 50.00 jAVRG

|3,3'-Dichlorobenzidine |0.5420000|0.5467303 | 0.010.87 j 50.00 jAVRG

Mpis (2 - et'hylhexyl) Phthalate kenzo (a ) ^anthracene

|1.1480000|1.0855520|

|1.7590000 1.7345633

0.01 j

0.01 j-5.44|

-1.39

50.00 jAVRG

5 0.0 0|AVRGChrysene 1.6580000 1.6363928 | 0.01 -1.301 5 0.0 0 j AVRG

j Di-n-oct /lphthalate 2.2640000|2.1436980 0.01 1 -5.31 20.00 AVRG|Benzo(b) fluoranchene 2.1450000 2.1523610 0.01 0.341 5 0.0 0|AVRG

!Benzo (k} fluoranthene |1.9380000|1.9126477 | o. oi! -1.31 | 5 0.0 0|AVRG

t Benzo(a) pvrene i1.7000000|1.7032079 | 0.01 1 0.19 j 2 0.0 0 j AVRG

!Indeno (1 ,2, 3 -cd)pyrene j 1.2280000 | 1 . 1778233 0 . 01 j-4.09 50.00 AVRG

!Dibenzo( a,h)anthracene |1.4900000|1.4512775| 0.01 1 -2.60 j 50.00 jAVRG

1Benzo(g, i,i)perylene |1.5630000 1 . 5155586 0.01 1 -3.04 | 50.00|AVRGj 1

i2 -Fluorophenol |1.2980000|1.3243293 | 0.01] 2.03 | 50.00|AVRG

!Phenol-d5 1.6910000 1.6025778 | 0.01 -5.23 5 0.0 0|AVRG

iMitrobenzene-d5 | 0.4330000|0.44 3 7773 1 0.01 1 2.49] 5 0.0 0 j AVRG

:2 -Fluorobiphenvl | 1 . 3330000 | 1.3594772 0.01 1 1.99] 50.00|AVRG

12,4,6-Tribromophenol j 0.4030000|0. 3871519 j 0.01 -3 . 93| 50.00 AVRGTerpheny 1 - d 14 i 1 . 0590 000|1. 1633097| 0.01 1 9.85 | 5 0.0 0|AVRG

! ! i 1 I

page 2 of 2FORM VII SV

C:<106)

Data Filet /chem/5972hp64.i/DF020313A64.b/HG020313Ai't.d

Date t 13-MAR-2002 09:56

Client ID: SSTD080


Volume Injected (uL>; 1.0

Column phase: RTX-5


Operator; 917


oCD

z'4:

5.2-

5.0- :

4.8-

4.6^

4.4^

4.2- j

4.0-

3.8-

3.6-

3.4- :

3.2-

3.0-

2.8- |

2.6-

^ 2.4-;

2.2- ;

2.0:

1.3:

1.6-

1.4-

1.2- ;

l.o:

0.8-

0.6-

---0T4~-

0.2-

/chem/5972hp64.iXDF020313A64,b/HG020313A64,d (Part 1 of 2)

+00*0

I4!

.-Jr 1 brorfopheno 1

Data File: /chem/5972hp64.i/DF020313A64.b/HG020313ft64.d

Date : 13-MAR-2002 09:56

Client ID: SSTD080



Column phase: RTX-5


Operator: 917


CO


CompuChem

Data file Lab Smp jId

Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date Als bottle Dil Factior Integrator

Target Version:

Semivolatile Report SW-846 Method 8270C /chem/5972hp64.i/DF020313A64.b/HG020313A64.d

SSTD08013-MAR-2002 09:56 917SSTD080:917

Client Smp ID: SSTD080

Inst ID: 5972hp64.i

/chem/5972hp64.i/DF020313A64 13-Mar-2030 10:27 mikhael 10-MAR-2002 17 2

1.00000 HP RTE

23

Processing Host:3.50einstein

, b/8270Cv6.m Quant Type: ISTD Cal File: HL020310A64.d Continuing Calibration Sample



Name Value Description,

DF 1.00000 Dilution Factorvt 1000.00000 Volume of final extract (uL)

W Vo 1000.00000 Volume of sample extracted (mL)Vi 1.00000 Volume injected (uL)

Cpnd Var Lable Local Compound Variable

AMOUNTS

QUANT SIG CAL-AMT ON -COL

Co:.'pounds MASS RT EXP RT REL RT RESPONSE ( NG) ( NG)

* 11.4-Dich lorober.ee ne-d4 1 52 3.240 9.240 ( 1 . 000 290555 40.0000

* 2 Naphthalene-d3 136 10.132 10.132 (1 . 000 1028482 40.0000

* 3 Acenaphchene-dl9 164 13.139 13.139 (1.000) 667461 40.0000

* 4 Phenar.ch rene-dlO 189 15.470 15.470 f 1 . C 0 C ) 1280056 40.0000

• 5 Chrysene 240 19.947 19.947 ( 1 . 000) 980906 40.0000

• • Pervlene -d ■ 2 [

264 22.4 1 3 2 2 .4 1 3 (1 . COO 1 547673 40.0000

t 7 2 -F1uorophenoi 112 6.450 6.450 (0.783) 769581 80.0000 81.60

$ 8 Phenol-d5 99 7.75C 7.750 (0.941) 931274 80.0000' 75 80

5 9 Nicroben zene dS 82 9 . 085 ' 5.035 (0 . 997) 912834 80.0000 82 01

2 10 2 - Fluorob; phenyl 172 11.856 11.355 (0.902) 1814796 80.0000 81 .61

1 : 2,4 . 6 - T rl .ibromooneno* 330 14.457 14.457 (1. 100) 516831 80.0000 76 91

? 12 Terpheny 1 - d 14 244 17.835 17.835 (0.894) 2282195 80.0000 87.89

' I 3 N - N i L r o s odimer.ny1 ami ne 42 4.355 4.355 (0.528) 280370 80.0000 80 . 85

14 Pyridine 7 5 4.335 4 .333 .(0 . 526) 508730 80.0000 84.61

SIMILARITY

i ’

86 90

9402

0 L


AMOUNTS


Compounds MASS RT EXP RT REL RT RESPONSE l NG) ( NG) SIMILARITY

115 Benzaldehyde 77 7.632 7.632 (0.926) 471878 80.0000 74.16 9667

16 Phenol 94 7.767 7.767 (0.943) 836670 80.0000 79.25

17 Bis(2-chloroethyl)ether 93 7.886 7 . 886 (0.957) 531230 80.0000 74.06

18 2-Chlorophenol 128 7 . 987 7.987 (0.969) 751890 80.0000 77.01 9296

19 1,3- Dichlorobenzene 146 8 .190 8.190 (0.994) 856065 80.0000 76 - 32

20 1,4-DIl hlorobenzene 146 8.274 8.274 (1.004) 876359 80.0000 77.43

21 Benzyl alcohol 108 8.460 8.460 (1.027) 444713 80.0000 77.28

22 1,2 -Dichlorobenzene 146 8.544 8.544 (1.037) 851473 80.0000 76.43

23 2-Meth> lphenol 108 8.612 8.612 (1.045) 619992 80.0000 72.82

24 2,2'-oxybis(1-Chloropropane) 45 8 . 663 8.663 (1.051) 959574 80.0000 72.44 8969

25 Acetophenone 105 8 . 848 8 848 (1.074) 883268 80.0000 71.80 9434

26 3-Methylphenol 108 - 8 . 815 ^ 8.815 (1.070) 680463 80.0000 73-53

27 4-Methylphenol 108 ' 8.815 / 8.815 (1.070) 680463 80.0000 73.53

28 N-Nitroso-di-N-propylamine 70 8 . 865 8 865 (1.076) 415802 80.0000 71.30 8009

29 Hexachloroethane 117 9.000 9 000 (1.092) 445323 80.0000 76.03 9256

30 Nitrobenzene 77 9 . 119 9.119 (0.900) 734007 80.0000 84.00 9419

31 Isophorone 82 9.440-/ 9.440 (0.932) 1355300 80.0000 78.33 9229

32 2-Nitrophenol 139 9.592 9.592 (0.947) 463852 80.0000 84.08 8460

33 2,4-Dimethylphenol 122 9 . 592 9.592 (0.947) 660563 80.0000 80.34 8463

34 Bis(2 -chloroethoxy)methane 93 9.744 9.744 (0.962) 832392 80.0000 80.60 9289

3 5 2,4 -Dichlorophenol 162 9 . 913 9 . 913 (0.978) 678667 80.0000 ‘ 79.69

3 6 1,2,4 -Tnchlorobenzene 180 10.065 10.065 (0.993) 799024 80.0000 80.4G

^^7 Naphthalene 128 10.166 10.166 (1.003) 3003376 80.0000 80.80 9299

8 <1 -Chloroani 1 me 127 10.250 10.250 (1.012) 986292 80.0000 82.97 7628|

39 Hexachlorobutadiene 225 10.402 10.402 (1.027) 558914 80.0000 81.72 9248

40 Caprolactam 113 10.723 10.723 (1.058) 210501 80.0000. 72.25 9645

41 4-Chloro-3-methylpheno1 107 10.926 10.926 (1.078) 708333 80.0000 74.86 949042 2-MethyJnaphthalene

142 li 196 11.196 (1.105) 1429751 80.0000 76.744 3 1-MethyJnaphthalene

142 11 382 11 . 382 (1.123) 1360957 80.0000 76.55

4 4 Hexach lorocvc loper.tadiene 237 11.585 11.585 (0.882' 608241 80.0000 92.00 9538

45 2,4,6-* "i: ch 1 cropheno 1 196 11.737 11 . 737 (0.893) 568639 80.0000 83.71

46 2,4 , 5 - 7r,i ch lorophenoi 196 11 805 11 . 805 (0.898) 589595 80.0000 81.82

4 7 1,1'- B lpheny1 154 12.041 12.041 (0.916) 1643165 80.0000 92.18 7549

4 8 2 -Chloronaphthalene 162 12.092 12.092 (0.920) 1420730 80.0000 82.96

4 9 2 - Nit roam line 65 12 328 12 . 328 (0.938) 480584 80.0000 78.40 9590

SC Dimethy1 phtha late 163 12 666 12 . 6 6 6 (0.964) 1658780 80.0000 79.27 8945

51 2 , 6 • Dmi t rotoluer.e 165 12.818 12.818 (0.976) 442334 80.0000 76.83 9409

52 Acenapht hylene 152 12 .885 12 . 886 (0.981) 3145391 80.0000 ■ 78.25 9930

5 5 3 - N : t roam 1 i ne 138 13.071 13.071 (0.995) 431840 600.000 83.10 9247

54 Acenapnt hene 164 13 207 13.207 (1.005) 1866100 80.0000 71.73 9079

55 2,4 -Dir.i tropheno1 134 13.240 13 .240 (1.008) 409950 400.000 402.6

5 6 4 -N11rophenol 109 1 3 308 1 3 3 08 (1.013) 286098 80 . 0000 78.92 0 (M) |

57 2,4 - Dinitrotoluene 165 13 .494 13 .4 94 (1.027) 602860 80.0000 72.24 8941

5S D:ber.zot 1u ran 168 13.460 13.460 (1.024) 2051682 80.0000 76.17 9239

59 Diethylphthaiace 14 9 13.343 13.843 (1.054) 1869334 80.0000 75.49 9737

60 4 • Chioropr.eny 1 -pher.yiether 204 1 3 934 13.984 (1.064 ) 093036 80.0000 77.19 7526

Fluor-- 16 6 14.034 14.034 (1.066) 2313660 80.0000 74 . 86 7689


Compounds

62 4-Nitroaniline63 4,6-Dinitro-2 -methylphenol64 N-Nitrosodiphenylamine 6 5 1,2-Diphenylhydrazine66 4-Bromophenyl-phenylether67 Hexachlorobenzene68 Atrazine69 Pentachlcrophenol70 Phenanthrene71 Anthracene72 Carbazole73 Di-n-butylphchalace74 Fluoranthene75 Benzidine76 Pyrene j77 Butylbenzylphthalate78 3,3'-Dichlorobenzidine79 bis(2-ethylhexyl)Phthalate\80 Benzo(a)anthracene81 ChryseneI82 Di-n-octylpnthalateI83 Benzo(b)fluoranthene

I84 Benzo(k)fluoranthene

:|5 Benzo(a)pyrene

86 Indeno(1,2,3-cd)pyreneI

87 Dibenzofa,h)anthracene

88 Benzo(g J h,i)perylene

QC Flag Legend

AMOUNTS



138 14.102 14.102 (1.0731 419616 80.0000 66.14 9496

198 14 . 169 14.169 (0.916) 429716 80.0000 82.92 8104

169 14.136 14.186 (0.917) 1060141 80.0000 76.04 9298

77 14 .237 14.237 (1.084) 1790238 80.0000 71.57 9429

249 14.761 14.761 (0.954) 569198 80.0000 93.82 7468(H)

284 15.014 15.014 (0.971) 636422 80.0000 76.23 9617

200 14.997 14.9? 7 (0.969) 472577 80.0000 74.23 8405

266 15.267 15.267 (0.987) 439552 80.0000 79.10 8305

178 15.504 15.504 (1.002) 3411407 80.0000 71.62

178 15.571 15.571 (1.007) 3616671 80.0000 74.71

167 15.774 15.774 (1.020) 2210565 80.0000 69.38 9341

149 16.213 ■ 16.213 (1.048) 3414644 80.0000 71.68 9498

202 17.261 17.261 (1.116) 3986135 80.0000 72.59

184 17.413 17.413 (0.873) 2006051 160.000 142.1 8436

202 17.666 17.666 (0.886) 3921995 80.0000 83.37

149 18.798 18.798 (0.942) 1483789 80.0000 78.60 9393

252 19 . 828 19.828 (0.994) 1072582 80.0000 80.67 7550

149 19.778 19.778 (0.992) 2129649 80.0000 75.65 9010

228 19 . 913 19.913 (0.998) 3402887 80.0000 78 .89

228 19.997 19.997 (1.003) 3210295 80.0000 78.94

149 20.741 20.741 (0.925) 2348091 80.0000 - 75.75

252 21.686 21.686 (0.968) 2357580 80.0000 80.26

2 52 21 . 720 21.720 (0.969} 2095011 80.0000 78.93 ■

252 22.311 22.311 (0.995) 1865602 80.0000 80.16

276 24.997 24.997 (1.115) 1290124 80.0000 76.72 0 (M) I

276 24.960 24.980 11.115) 1589651 80.0000. 77.91 6391

276 . 25.808 25.808 (1-151) 1660061 80.0000 77.59 9184

M - Compound response manually integrated.H - Operator selected an alternate compound hit

^•^6 1 J

? tl - oLj ^

Round: 2.4J6-Tribromophenol Number: 118-79-6

Data File: /chern/5972hp64. i /DF020313A64. b/HG020313A64. dInjection Date: 13-MAR-2002 09:56Instrument: 5972hpb4.i

^ent SamplejlD; 55TDOBO

13.95 14.00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.85 14.90

__ « _____ ____ _______ Min ______ ________________________ ________________________

JPfmpound: 4-Ni trophenol CPS Number: fl00-02-7

Data Fiio; /cherri/5972hpb4.1/DF020313A64. b/HG0203l 3P64 . dInjection Date: 13-MPR-2002 09:56Instrument: 5972hp64.1

Mkient Sample ID: SSTDOSO

Ion 109.00: Area: 286098 Height: 142857

12.9 13.0 13.1 13.2 13.3

Ion 65.00: Area:

13.4

Height: 0

13.5 13.6 13.7 13,8

3.0-

I i

! \

12.85 12.90 12.95 13.00 13.05 13.10 13.15 13.20 13.25 13.30 13.35 13.40 13.45 13.50 13.55 13,60 13.65 13.70 13.75M i n

5.1-

4.0-

3.9-

3.6-

3.3-'

3.0-

. . d '

1.5-

1 .2- 0.9-

0.6-

0.3-

0.0—-12.SO 12.35


61;j

12.90 .00 13.05 13.10 13.15 13.20 13.25 13.30 13.35 13.40 13.45 13.50 13.55 13.60 13.65 13.70 13.75

Data File: /chem/5972hp64. j. /DFG20313A64. b/HG0203l3A64. dInjection Date: 13-MAR-2002 09:56Instrument: 5972hp64.i

lent Sample ID: SSTD08U

pound: 4-Bromopheny1-phenylether "S Number: l;0l-55-3

2. u-

1.8-

1.6

1.0-

0.8-

Ion 141.00: Area: 117975 Height: 117975

• 61U

i j .= 1-4.0 i4.a 14.9 15.0 15.1 15.2Min

Data File: /cnem/5972hp64.1 /DF020313A64. b/HG020313A64. dInjection Date: 13-MAR-2002 09:5bInstrument: 5972hp64.i

lent Sample ID: SSTD080

pound: Indeno<1.2.3-cd)pyrene S Number: i93-39-5

if1;b

3. O'

2.0

2.6

2.4

c . e.

2.0

1.8

1.6

1.4

1.2

1.0-

0.8-

0.6-

0.4-

0.2-

0.0----24.5

Ion 276.00: Area: 1290124 Height: 310642.ft

2-4.6 2-4.; 24.8 24.9 25.0

_______ Min25.1 25.2 25.3 25.4 25.5

1.0-

0.9;

C;

0.6-

0.5-'

0.4-

0.3-

0.2-

0.1-'

0.0----24.5


co \ m/?/ i

/ I

24.7 24.8 24.9 25.0 25.1 25.2 25.3 25.4 25.5

950-

900-.

850-

800-

750-

700-

650-

600-

550-

500-

450-

4 00-

350- 300-'

50-

00-

150-

1 CO-

50-

n -•---24.5

Ion 227.00: Area: Heignt: 0

61774.6 24.: 74.6 24.9 25.0 25.1 25.2

_____________Min25.3 25.4 25.5

COMPUCHEM a division of Liberty Analytical Corp DATE 3 / (l / 0 ? INITIAL TIME OE TUNE___ (iRjj.____ SHIIT/S(A) ...(C)

SEMIVOLATILE RUN LOG TIME TIJNE EXPIRES___ ? j_J>'L LINKER /METI101) M n ^COMPUCHEM LOGBOOK 4 YVY 4 (5972hp64) "

rn m _______ ______________»>1

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PREVENTIVE MAINTENANCE ZVZv\f ;.0

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FILENAME T

10

date TIME CLIENT ID# CASE/SDG# AMOUNT

INJECTEDCHEMIST COMMHN TS(1:1C 1/i JISp^CPl’KlN

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13 Qe ifcT7- &AGM/ / / IbM*

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£T/ IW 8>Ui-K 0 00 35 'i/

16 (s>l - IA^ z/ /

I’bMo C.A - S - 01

17 / / / hn b A - S - 0 3

18 UGi / / / C iVt<i

19 Voa^ivma^

z/ / 3°l* J; MSD

20 / 7z_______£A-S- ) i vV

21 ------(____ /

22

23

/

/

/

/

//0 3liiCz---------

—

24 -------Z-------- " 1 -

STANDARDSTune

-std-i p-ff "7'p-3-b—

Lot It T 2 £ ^ S'

Analytical Int. Std.

-(rrM------licr

-iVZii!_____CzsZa

Column Type SUPERVISOR APPROVAL.

/ 7// ?7?:, date: i7/T/°z

4^7

c * >2. ^ w-1 he presence ol ihe Chemist’s employee 11) number, or signature, on this urn toy; attests that slnet compliance with the method\ S( )i

occurred. Any SOI1 deviations require documentation b\ the responsible chemist together with the chemi.-d'^mmtials ami the initials i lab supcrvisor^^^kOA department representative, siumlvmp appioval of the deviation I I/2MU .

4. Raw QC Data

a. DFTPP Data

b. Blank Data

c. Laboratory Control Sample Data

d. Matrix Spike Data

e. Matrix Spike Duplicate Data

619

a. DFTPP Data

For each 12-hour period, per instrument utilized, include:

- Bar Graph spectrum and Tabulated Relative Abundances

- Mass listing

- Reconstructed ion chromatogram

- Tailing Factors for Benzidine and Pentachlorophenol

- Determination of DDT Breakdown

62 G

Data F11*: /chem/5972hp60*i/DF020303A60 *b/BF020303A60*d

Date : 03rMAR-2002 13:38

[Client ID: DFTPP

Sample Info: DFTFF';231 T1


Column phase: JSJ-J DBS*625

Instrument: 5972hp60 *i

Operator: 2319


Data F1 le: /chem/5972hp6o. i/DF020303A60.b/DF026303A60*d

Date : 03-MAR-2002 13:33I

Client ID: DFTF'P

Sample Info: DFTPP:2319

Volume Injected CuL>: 2*0

Column pfjiase: J?.-W BB5.625


Operator: 2313


f

Data File: DF020303A60*d

Spectrum: Avg. Scans 122-124 < 7*11), Background Scan 113

Location of Maximum: 133*00

Humber of points: 100

m/2 Y m/z Y m/z Y

1

m/z Y

11 1

78. 00 403 1 105*00 304 181.00 274 1 255.00 17640 1

39*00 1834 107.00 5153 135.00 768 256.00 2522 1

4?. 00 287 103.00 754 186.00 4542 258.00 1376

50.00 7943 110*00 7746 137.00 1417 265.00 510

51.00 21313 111.00 1365 139.00 259 273.00 469

54.00 1107 117.00 9688 192.00 353 274.00 1565

53.00 452 113.00 358 193.00 236 275.00 7623 1

57*00 993 122.00 236 196.00 787 276.00 829 1

33.00 422 123.00 620 198.00 32408 277.00 771 1

39 * oo 18o53 127*00 11339 199.00 2222 1 296.00 3149 1

73.00 274 123.00 957 204.00 1296 1 297,00 332 1

74.00 2527 129.00 6634 205.00 2222 1 303.00 247 1

75.00 3120 130.00 537 206*00 3019 1 315.00 291 1

73.00 1132 135.00 294 207.00 1136 1 323.00 607 1

77 O'.' 17152 141.00 999 203.00 230 334.00 496 1

1

73. Ov 1139 147.00 533 217.00 2576 365.00 1214 1

79.00 1332 143.00 1924 221.00 934 1 372.00 352

30.00 1207 15A.00 700 223.00 393 423.00 1140 1

31*o.. 1402 131.00 263 224.00 4694 441.00 432

33.0- 333 165.00 236 225.00 1237 442.00 23912

91. ■11 ■ 304 167.00 2707 237.0o 2661 443.00 4397 1

-<2. 7945 163.00 1343 223.00 230 444.00 335 1

93."-' “o 175.00 742 229.00 ■ c:r, 1

99. 1073 177.00 244 1 244.00 3637 1 1

11 11.1 1' 040 179..-,0 1639 1 245.1"'' 367 1 I

1 '

v ■■4. 7,,. 180.00 879 1 246.00 9 1 1

Dat* F i 1 o; /■:tern•'0972hp60.1 ,-'DF020303A60.b/DF020303A60. d

Date : 03-NAR-2002 13:38

Client ID: DFTF’P Instrument: 5972hp'60.i


.Volume Injected CuL); 2.0 Operator: 2318

Column phase: J8.U DB5.625 Column diameter: 0.32

/chem/5972hp60.i/DF0203O3A60.b/DF020303A60.d

2.0-

1.9-

1.8-

1.7-

1.6-

1.5-

1.4-

1.3-

1.2-

1.1-

■r>

CvJ

CO

u.i 11 .-i L . 7 1 1 £.

TAILING FACTOR and DEGRADATION SUMMARY RESULTS

EjECAFLUOROTRIPHENYLPHOSPHINE Ion Abundance/Ratio Criteria Chart

Kon 1 Abundance Criteria | Base Peak Other | Test

n.98 Ba^se Peak, 100% relative abundance 100.00 PASSSI 3|o - 80% of mass 198 67.33 PASS68 Less than 2% of mass 69 0.00 ( 0.00) PASS69 Ma ss 69 relative abundance 57.56 PASS70 Le ss than 2% of mass 69 0.00 ( 0.00) PASS

127 2 5 - 75% of mass 198 36.68 PASS197 0 - 1% of mass 198 0.00 PASS199 5 - 9% of mass 198 6.86 PASS275 1 0 - 30% of mass 198 23.52 PASS365 Greater than 0.75% of mass 198 3.75 PASS441 Present, but less than mass 443 1.33 ( 9.82) PASS442 4p - 110 % of mass 198 73.78 PASS443 15 - 24% of mass 442

l13.57 ( 18.39) PASS

TAILING ANALYSIS SUMMARY

Compound1

Tail Factor Max Allowed Test |

Pentachlorophenol 1.8 5.0 PASSBenzidine 2.0 3.0 PASS

DDT DEGRADATION BREAKDOWN ANALYSIS SUMMARY

^ Compound Response %Breakdown Max Allowed Test |

4,4-DpT 527898 N/A4,4-DpE 0 0.0 20 . 0 PASS4,4 -DDD 17289 3 . 2 20.0 PASS

4,4-DDD - DDE 17289 3 . 2 20 . 0 PASS

Tuning Sample, /chem/5572hp60 . 1 ,/DFO 2 0 3 0 3 A6 Q . b/DF020303A60 . d/DFO 2 0 3 0 3 A6 0 .d

** + PASSED ***

62

TAILING FACTOR and DEGRADATION SAMPLE AND GRAPHIC REPORT

ort Date: 03/04/2030 12:51

Analyzed: /chem/5972hp60.i/DFO20303A60.b/DF020303A60.d/DF020303A60.dDatafileMethod Used: /chem/5972hp60.i/DFQ20303A60.b/dftpp8270C.m Inst: 5972hp60Injection Date: 03-MAR-2002 13:38 Sample Info: DFTPP DFTPP:2319 Misc Info:

Operator: 2319

1 . 1

HP MS DFOiOSOS^bO.d_

r- I

't.t

iC*D*V.'•jt.cy-

i !'

cr.t Z( .r.j-.jr.ro 'X> cerooro . -Irl

EooroCD O- c_ —Or- cto -r—C-J'.D COO c • _■

-L.'< DTT11 ;>.a ii. 11.6 12.?’ 12.4

Report Date: 03/04/2030 12:51

03/04/2030 12:51Report Date:

Datafilem

Sam

Analyzed: /'chem/5972hp60 . i/DF020303A60 .b/DF020303A60 .d/DF020303A60 .dthod Used: /chem/5972hp60.i/DF020303A60.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972haction Date: 03-MAR-2002 13:38 ODeratof:

ample Info: DFTPP DFTPP-.2319 Misc Info:

h'F Mj DF020o03h60 . a. Ion 266.00

Ion 266

Tailinq Factor =■ 1.83899

! j b ! 3.4

!1 2.8

I

i 2.4

'm onI <

•2 1.0 !- i-6-

!:- 1.4.

) 1.2-

i 1.0 j 0.0

j 0.6- j 0.4-

I _1_ 0.0

HP H5 DF020303A60._d. Ion 266.00

inkD

6.35 6J40 6.45 6.50 .55 6.60 6.65 6.70 6.75 6.t~ 1 mj (Min)_________

hF- m0 DFu2'j31.,3^6i

j 6.35 6.90 6.95*

____________________ i—. d, jean mq; h,. 65‘J min

6.40 6.50 6.60 6.70 6.60 6.90

Timp (Min)

r'entachlorccnenoi

Exp. R7 ’ound RT

iass

ailma

6.639

t a c t o r

Factor

Ratio

10 0. 0 0

?e n t a e h1o rophe no 1 OK

: M a x. i m u m A11 o w e d = ^

62

Reoort Date: 03/04/2030 12:51

Datafile] Analyzed: /chem/5972hp60.1/DF020303A60.b/DF020303A60.d/DF020303A60

^ifcthod Uised: /chem/5 972hp6 0 . i/DF0203 03A6 0 . b/df tpp8270C . m/BrkDwnTF . m Inst:(■jection Date: 03-MAR-2002 13:38 Operator:

sample I Misc Inf

nfo: DFTPP DFTPP:2 319O :

if MS DF020303Ht,u.a„ Ion 184.00 HP MS DF020303h60^ Ion 184.00

:on 184

Tailing Factor = 2.03209

i. i-

1 . o-'

o. 9-;

0.8-

0.7-

0.6-

0.5-

0.4-

•0.3

0.2-

0 1 -

0.08.30 8.35 8.40 8.45T i m*= i M i n )

8.50 8.55 3.60 3.65 !.]

8.10 8.20 6.30 8.40 8.50Tim*? (Min )

HP MS DF020.: 034P0. cl. Scan 197 8.b59 min.184-

160 190 200

.'UP1

_ea Ratio

:enziame OK

.d5 972h

. 60

628

Report: Dane: 03/04/2030 12:51

matafile Analyzed: /chem/5972hp6C.1/DFC20303A60.b/DF020303A60.d/DF020303A60.d

hod Used: /chem/5 972hp6 0 . i/'DF02 03 03A6 0 . b/df tpp8270C :m/BrkDwnTF . m Inst: r3"A2hection Date: 03-MAR-2002 13:38

Sample Info: DFTPP DFTPP:2319 Misc Info:

Operator:

HP M5 DF0-C'30i-fHDL-. C. Ion 235.00

Ion 235

IS o.2i

3 IS 354 tc:

Area Ratio

>7305 100.00

62

pore Date: 03/04/2030 12:51

Datafile Analyzed: /chem/5972hp60.1/DF020303A6C' .b/DF020303A60 . d/DF020303A60 ^k:hod Used: /chem/5 972hp6 0 . i/DF0203 03A6 0 . b/df tpp8270C . m/BrkDwnTF . m Inst: ^^iection Date: 03-MAR-2002 13:38 Operator:

DFTPP:2 319Sample Info: DFTPP Mi sc Info:

HP MS Dr,i- '.'yj JiHhl.l . Inn 235.0C

ion 1 ^ S

X'

0.5

i'1 _ 4

a.o2 0.35 D.tfo 3.Hi a.H4

_ __________ ______ T i mo ( M^_njHP MS 07020303960.d. Scan

H' 9.00 9.0j> 9.06 9.09 9.12 9.15

32: 3.951 mm.

9.16 9.21

263

Vi 231

317

1

630

.d5 9 7 2 h

>por: Jfi I 03/Q4/2C30 12:51

Uacaflie Analyzed: /chem/5972hp60.1/DF020303A60.b/DF020303A60.d/DF020303A60^^khod Used: /chem/5972hp60.i/DF02Q303A60.b/dftpp8270C.m/BrkDwnTF.m Inst: ^BFjection Date: 03-MAR-2002 13:38 Operator:


HP M5 DF020303H60.d. Ion 246.00

Ion 246

4-:- P.4 3 3.4b 3.49 3.52

' ' ' hp"mV d’fozo:

.58 6.61 S.b4 8.67 8.70 8.73 8.76 8.79 8.52 3.35•U n> ^rear. 210: 3.578 min.

■'"20?

r, q q n

Area Ratio

0 0.00

210

631

.d5972h

a.83 •

a Q D:

I or. 235.

5.0-

4-

6-

1.

? . 30 0 . J’j 9.50 9l m ■=■ -Mm'1

HP Mf. jF 0 :-h60,J, Ion 435.00

ccl

Compound: 4,4'-DDT

Quant Mass: 235

RT: 9.340

Area: 527898

Compound: 4,4'-DDD

Quant Mass: 235

RT: 8.951

Area: 17289

V . 1

I

90' M :

9 . i 0 9

JP

Compound: 4,4'-DDE

Quant Mass: 245

RT:. 0.000

Area: 0

.onoounc

T

riON BREAKDOWN ANALYSIS SUMMARY

Response %3reakdown Max Allowed Test |

R27398 N/A0 !

0 . 0 20.0 PASS17289! 3 . 2 20 . 0 PASS

; 17239 i ■Q n 20.0 PASS

PASSED *** DDT BREAKDOWN TEST 632:

Data Filet /chem/5972hp60.i/DF020312A60.b/DF020312A60,d

Date : 12-MAR-2002 08:51 l

Client i'd: DFTPP

Sample Info: DFTPP;917

Volume Injected <uL): 2*0I

Column phase: J&U DB5.625

1 Decaflucrotriphenylphosphine


Operator: 917


4*8

4*6

4.4

4.2

4.0

3.8

3.6

3.4

3.2

3.0

2.8-

2.6-

2.4-

2.2-

2.0

1.8

1.6

1.4 ! 1.2'

1.0-

0.8-

O.b-

0.4-

0.2-

o.oJ

Avg. Sc-ans 118-120 < 7.04), Background Scan 116. 198''"

,-51

77

,t l:

44N/255

A17

167\

I i II I I il, I ill I. .i ljl.il I , J.lli J ,i,l I

/275

224

il li.i , I II I....

X323

j, I,, I.

365^

40O^ .

60 80 100 120 140 160 180 200 220 240 260 280 300 320 340m/z

360 380 400 420 440

X RELATIVE

m/e ION ABUNDANCE CRITERIA ABUNDANCE

193 1 Base Peak, 100X relative abundance 1 100.00 1

1 51 1 30.00 - 30.00* of mass 198 1 63.46 1

6 8 1 Less than 2.00X of mass 69 1 0.00 < 0.00) 1

1 69 1 Mass 69 relative abundance 1 43.77 1

70 1 Less than 2.00X of mass 69 1 0.00 ( 0.00) 1

1 127 1 25.00 - 75.00* of mass 198 1 30.61 1

l 197 1 Less than 1.00X of mass 193 t 0,00 1

1 199 1 5.00 - 9.00* of mass 198 1 6.93 1

1 275 1 10.00 - 30.00X of mass 198 1 27.25 1

I 365 1 Greater than 0.75X of mass 193 1 4.72 1

l 441 I Present, but less than mass 443 1 10.63 i

1 442 1 40.00 - 110.00X of mass 193 1 66.87 !

1 443 1 15.00 - 24.00* of mass 442 1 12.61 ( 13.85) 1

633

Data Fi le: /chem25972hp60« i/DF020312A60.b/’DF020312A60.d

Date : 12-MAR-2002 08:51

Client ID: DFTPP Instrument: 5972hp60.i


Volume Injected CuL): 2.0 Operator: 917

Column phase: J8.W DB5.625 Column diameter: 0.32

Data File: DF020312A60.d

Spectrum: Avg. Scans 118-120 ( 7.04), Background Scan 116

Location of Maximum: 198.00

Number of points: 164

m/z Y m/z Y m/z

*

Y m/z Y

*

1 37.00 208 1 127.00 14914 1 191.00 217 1 259.00 376 1

1 38.00 855 1 128.00 1340 1 192.00 977 1 265.00 1054 1

1 39.00 2261 1 129.00 9323 1 193.00 894 1 273.00 967 1

1 49.00 307 1 130.00 814 1 196.00 1192 1 274.00 3022 1

1 50*00

1

12400 1 134.00

*

408 1 198.00 48720 1 275.00 13276 1

* * *

1 51.00 30920 1 135.00 727 1 199.00 3375 1 276.00 1582 1

1 52*00 1519 1 136.00 233 1 200.00 249 1 277.00 1780 1

1 5b.00 599 1 137.00 421 1 203.00 489 1 278.00 271 1

1 57*00 1104 1 141.00 1590 1 204.00 2355 1 285.00 225 1

1 61.00 200 1 142.00 330 1 205.00 3970 1 293.00 269 1

* *

1 62.00 438 1 143.00 197 1 206.00 13092 1 296.00 6199 1

1 63.00 793 1 146.00 244 1 207.00 1665 1 297.00 731 1

1 69.00 21320 1 147.00 289 1 208.00 533 1 303.00 486 1

1 73.00 516 1 148.00 3708 1 209.00 192 1 314.00 241 1

1 74.00 4338 1 149.00 351 1 210.00 259 1 315.00 563 1

1 1 *

1 75.00 4126 1 153.00 530 1 211.00 452 1 316.00 291 1

1 76.00 1927 1 154.00 196 1 215.00 178 1 323.00 1206 1

1 77.00 27712 1 155.00 816 1 217.00 4635 1 324.00 248 1

1 73.00 1901 1 156.00 1046 1 218.00 507 1 327.00 297 1

1 79.00 2376 1 158.00 179 1 221.00 1531 1 334.00 806 1

* 1 1

1 80.00 1430 159.00 175 222.00 560 1 335.00 228 1

1 81.00 1743 160.00 428 223.00 1012 1 346.00 338 1

1 32.00 373 161.00 726 224.00 3570 352.00 354 1

1 36.00 824 165.00 710 225.00 2054 353.00 266 1

1 91.00 472 167.00 6120 227.00 5066 354.00 325 1

*

1 92.00 576 168.00 2834 223.00 541 365.00 . 2301 1

1 93.00 5494 169.00 260 229.00 691 366.00 349 1

i 9e.oo 4498 172.00 208 231.00 217 372.00 594 1

99.00 2093 173.00 275 234.00 309 402.00 232 1

101.00 776 174.00 426 235.00 313 403.00 294 1

1044 00 646 175.00 1219 236.00 246 421.00 213 1

105.00 651 176.00 249 237.00 235 422.00 256 1

107.00 7039 177.00 510 241.00 223 423.00 1931 1

103.00 339 179.00 2702 242.00 429 424,00 299 1

no.oo 9055 130.00 1442 244.00 6480 441.00 5177 1

Data F11 a: /chem/5972hp60 . i /DF020312A60. b/DF020312A60. cl

Date : 12-MAR-2002 08:51



Volume Injected <uL): 2.0 Operator: 917I

Column phase: J8.U DB5.625 Column diameter: 0.32


Spectrum: Avg, Scans 118-120 < 7.04), Background Scan 116



m/z Y n/z Y n/z Y n/z

*

Y

+ * +

1 111.00 1517 1 181.00 514 1 245.00 791 1 442.00 32576 1

1 117.00 15728 1 184.00 205 1 246.00 1882 1 443.00 6143 1

1 118.00 997 1 185.00 1192 1 247.00 308 1 444.00 468 1

1 122.00 599 1 186.00 7293 1 255.00 30688 1 1

1 123.00 787 1 187.00 2290 1 256.00 4475 1

1

1

1+

1 124.00 242 1 188.00 212 1 257.00 359 1 1

1 125.00 201 1 189.00 468 1 258.00 2712 1 1

<xl

0~6)

Data File: /chem/5972hp60.i/DF020312A60.b/DF020312A60.d

Date : 12-MAR-2002 08:51

Client ID: DFTPP Instrument: 5972hp60,i



• 6

3b


DECAFLUOROTRIPHENYLPHOSPHINE Ion Abundance/Ratio Criteria Chart

(Ion | Abundance Criteria Base Peak Other Test

198 B'ase Peak, 100% relative abundance 100.00 PASS51 30 - 80% of mass 198 63.46 PASS68 Less than 2% of mass 69 0.00 ( 0.00) PASS69 Mass 69 relative abundance 43.77 PASS70 L'ess than 2% of mass 69 0.00 ( 0.00) PASS

127 25 - 75% of mass 198 30.61 PASS197 0 - 1% of mass 198 0.00 PASS199 5 - 9% of mass 198 6.93 PASS275 10 - 30% of mass 198 27.25 PASS365 Greater than 0.75% of mass 198 4.72 PASS441 Present, but less than mass 443 10.63 ( 84.27) PASS442 40 - 110 % of mass 198 66.87 PASS443 15 - 24% of mass 442 12.61 ( 18.85) PASS


Compound |Tail Factor Max Allowed | Test

Pentachlorophenol 2.2 5.0 PASSBenzidine

i0.0 3 . 0 PASS


^ Compound Response %Breakdown Max Allowed Test

4,4-DDT 901952 N/A4,4-DDE 0 0.0 20.0 PASS4,4 -DDD 0 0.0 20.0 PASS

4,4-DDD + DDE1

0 0.0 20.0 PASS

Tuning Sample, /chem/5972hpS0.i/DF020312A60.b/DF020312A60.d/DF020312A60.d

*** PASSED ***

■ 63/


port Date: 03/12/2030 10:53

Datafile Analyzed: /chem/5 9 72hp60.i/DF020312A60.b/DF02 0312A60.d/DF020312A60.d Method Used: /chem/5972hp60.i/DF020312A60.b/dftpp8270C.m Inst: 5972hp60 Injection Date: 12-MAR-2002 08:51 Operator: 917Sample Info: DFTPP DFTPP:917 Misc Info:

5.2-

5.0-

4.6-

4.6- '

4.4- ;

4.2-

4.0-

3.8-

3.6-

3.4-

3.0-

2.8-

2.6-

:.u-

1 .8-

1 -6-.

1 . 4-

1 .2-

1.0-

0.8-

0.6-'

0.4-in

0.2- 12

0.0- <-

HP MS DF020312A60 *-d

C' C'J|JD CD TV j |

garni ^ i tgicEtD) tnjrt/yj il brerfo

Eg* UJUJ1JOMT*03 IP

0)co•*->ai

"o **45 oirc\Dinn -< cmt Cftflj cnrvqvHatr co c CD U-CcrjO ^(\r7T^JP >£> Is*

<-• r<u c>jin <7> a\ co cn rccmo•-h m inn co o w-o\ro

uo CDJ

o or v un

ip CMiCW'JNk CN|CQ-4

b . 8 8.0 8.4 8.8

Time (Min)9.: 9.6 10.0 10.4 10.8 11.2 11.6 12.0 12.4

• 63o

Report Date: 03/12/2030 10:53

0atafile Analyzed: /chem/5972hp60.i/DF020312A60.b/DF020312A60.d/DF020312A60.d■fethod Used: /chem/5972hp60.i/DF020312A60.b/dftpp8270C.m Inst: 5972hp60

njection Date: 12-MAR-2002 08:51 Operator: 917Sample jlnfo: DFTPP DFTPP:917

Misc Info:

5.1-

4.8-

4.5-

4.2-

3.9-

3.6-

3.3-

3.0- '

£. . > ”2.4-

2.1-

1.8-

1.5-

1 ■

0.9-

0.6-

0.3-

n 0--

HP MS DF0203l2A60.d

6.8 6.9 7.0Time (Min)

7.1 \2 7.3 7.4 7.5

1.0-

0.9-

0.6-

0.7-

0.6-

0.5-.

0.4-

0.3-

0.2-

o. i

0.0-

HP MS DF020312A60.d. Scan 119: 7.043 min. ,"'"198

255

51 ! 275s

127

186 ,'296

, 323.•365

403

1 00 140 16C 180

:l.i. _ .

260 280 300 320 340 360 380 400 420

444

S.440


I on | Abundance Criteria Base Peak Other Test

198 Base Peak, 100% relative abundance 100.00 PASS51 30 - 80% of mass 198 63.46 PASS68 Less than 2% of mass 69 0.00 ( 0.00) PASS69 Mass 69 relative abundance 43.77 PASS70 Less than 2% of mass 69 0.00 ( 0.00) PASS

j 127 25 - 75% of mass 198 30.61 PASS197 0 - 1% of mass 198 0.00 PASS199 5 - 9% of mass 198 6 . 93 PASS

j 275 I 0 - ’30% of mass 198 27.25 PASSl65 eacer than 0.75% of mass 198 4 . 72 PASSr41 Pi esenc, but less than mass 443 10.63 ( 84.27) PASS1442 40 - 110% of mass 198 66 . 87 PASS443

----

1 5 - 24% of mass 442 12.61 ( 18.85) •TO7

Report Date: 03/12/2030 10:53

« Datafile Analyzed: /chem/5972hp60.i/DF020312A60.b/DF020312A60.d/DF020312A60.d Method Used: /chem/5972hp60.i/DF020312A60.b/dftpp8270C.m/BrkDwnTF.m Inst: 59

lniection Date: 12-MAR-2002 08:51 Operator:Inst: 5 9 7 2 h

.njection Date: 12-MAR-2002 08:51 Sample jlnfo: DFTPP DFTPP:917 Misc In'fo:

Operator:

Report

Datafil let hod "nj ecti

Sample Misc In

1.3-

1.2-

1 . It

1.0-

0.9-

0.6-

0.7-

0.6-

0.5-

0.4-

0.3-

0.2-

0.1 •.

e Analyzed: /chem/5972hp60.i/DF020312A60.b/DF020312A60.d/DF020312A60.dUsed: /chem/5 972hp6 0.i/DF02 0312A6 0.b/dftpp8 2 7 0C.m/BrkDwnTF.m Inst: 5972h

on Date: 12-MAR-2002 08:51 Operator:Info: DFTPP DFTPP:917 f o :

Date: 03/12/2030 10:53

HP MS DFC20312A60.d. Ion 184.00

Ion 184

Tailing Factor =j 0.00000

ij .

0.00 s.i:

i.i-

0.4-

8.10 8.15 S.20 8.25 0.30Time (Min)

1.3-

1.2g

1. It

1.0-j 0.9-_

0.8-

[n 0.7~

0.6-

0.5-i

0.4-f

0.3-1

0.2~

o. i-;

0.0--

HP MS DF020312Ab0^, Ion 184.00

8.35 8.40 8.45 0.50 8.55 8.00 8.10 8.20 8.30Time (Min)

8.40 8.50

HP MS DF020312Ab0.d. Scan 193: 8.295 min.184-",

158 .'25“

186 • 213239v

120 180 200 220 240 260 280

Senziaine i

Exp. RT Found RT

Mass

3.3978.295

Area Ratio

162361 100.00

tailing factor for Benzidine OK

Filing Factor = 0.0 Maximum Allowed 3 . 0641

If Tailing Factor < 1.0, then it is assumed that the peak is not ‘tailing and a Tailing Factor of zero is reported.

Report Date: 03/12/2030 10:53

tafile Analyzed: /chem/5972hp60.i/DF020312A60.b/DF020312A60.d/DF020312A60.dthod Used: /chem/5972hp60.i/DF020312A60.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h

njection Date: 12-MAR-2002 08:51 Operator:Sample Info: DFTPP DFTPP:917 Misc Into:

8.0-

7.5- :

7.0/

6.5-

6.0-:

5.5r

5.0-

•1.5-

4 .Or

3.5-

3. Or

2.5-

2.0-

i .5-;

1.0-

0.5-

n n-~

HP MS DF020312A60.d. Ion 235.00

Ion 235

0.94 8.97 9.03 9.06 9.09 9.12 9.15 9.10 9.21 9.24 9.27 9.30 9.33 9.36 9.39 9.42 9.45 9.40 9.51 9.54__________________ Time (Min)

6.4-

6.0-ke-

4.8-

4.4-

4.0-

— 2.6- u"l

7 2.8-

50

>.8-

4,4'-DDT

Exp. RT Found RT

Mass

235

HP MS DF020312A60.d. Scan 249: 9.243 min."-235

165

199

136

121.1 14m 160 10'J 20um .<■ z

212

282 ,284 •319 354.^50

260 200 300 320

9.3629.243

Area Ratio

•01952 100.00

Report Date: 03/12/2030 10:53

^atafile Analyzed: /chem/5972hp60.i/DF020312A60.b/DF020312A60.d/DF020312A60.dt hod Used: /chem/5972hp6 0 . i/DF02 03.12A60 . b/df tpp8270C . m/BrkDwnTF . m Inst: 5972h

rnjection Date: 12-MAR-2002 08:51 Operator:Sample Info: DFTPP DFTPP:917Misc Info: »

HP H5 DF020312H60. d. Ion 235.00

6.6-

6.4-

6.0-

5.6-

5.2-

4.8-

4.4-

4.0

3.6-

3.2/2.8- :

2.4- 2.0-'

1.6- "

1.2- ' 0.8-'

0.4-

Ion 235

. \

0.0- —--------s. ro 6.73 8.76 8.

73

•1 .0-

0.9-

u. 8 -

■ pr.

— 0.0-

“ 0.5-'

0.3

4,4'-DDD

-o e-

Fxo. RT = 8.989Found RT 0 .000

Mass Area

9 0 c; o

T l me (Min)HP MS DF020312060.a. Scan 234: 8.989 min.

207

281

160 220 260

Ratio

0 . 00

64 j

Report Date: 03/12/2030 10:53

+Analyzed: /chem/5972hp60.i/DF020312A60.b/DF020312A60.d/DF020312A60.d sed: /chem/5972hp60.i/DF020312A60.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h

tafile hod U

jection Date: 12-MAR-2002 08:51 Operator:Sample Info: DFTPP DFTPP:917 Misc Info:

1 . 4-

1 . 3-

1.1-

1.0'

0.9-

0.8

:S 0.7-

0.6-

0.5-

n, 4-'

0.3-

0.2-

0.1

0.0----3.28

950-

00-

300-

750

700

450- 4 00 •

350-300-'

250-

150-

HP MS DF0203l2A60.d. Ion 246.00

Ion 246

31 3.34 0.37 3.40 3.43 3.46 8.49 8.52 3.55 8.58 0.61 8.64 0.67 8.70 8.73 8.76 8.79 8.82 8.85 0.88______________ ___________ _________ Time (Min) __ ____________________ _____

HP MS DF020312h60.d. Scan 210: 8.583 min.207,

120 1 40 150 160 170 180 190 200

4' - DDE

Exp. R7 = 3.583Found RT = 0.000

Mass Area Ratio

0 0.00

• 644

HP M5 DF02Col2H60fd„ Ion 235.00

9.00 9.10 9.20 9.30| Time (Min)_____

9.40 9.50

HP MS DF020312A60.d, Ion 235.00

.5-.

.0-;

5-

0-

5-!

0-:

5-

0-

5-

.0-

. 5-

.0-

.5-

.0-

.5-

.0— 8.

L70 8.80 9.90 9.00 9-. 10 9

| T i me (Min'.20

HP MS DF020312H60.d. Ion 246.00

1.4-

1 .3-.

1.2-

1.1-

1.0-.0.9-:

0.8-

0.7-:

0.6-

0.5-

0.4-

0.3-.

0.2-

0.1-'

0.0-' - 8. 8.50 8.60

Time (Min)8.70 0.80

Compound: 4,4'-DDT

Quant Mass: 235

RT: 9.243

Area: 901952

Compound: 4,4'-DDD

Quant Mass: 235

RT: 0.000

Area: 0

Compound: 4,4'-DDE

Quant Mass: 246

RT: 0.000

Area: 0


Compound Response %Breakdown Max Allowed Test

4,4-DDT4,4 -DDE

9019520 0.0 20.0

N/APASS

4,4-DDD 0 0 . 0 20.0 PASS^,4 -DDD + DDE 0 0.0 20.0 PASS

TUNE SAMPLE

ir-k-k-k’k'k’k'kir'k-k-k'k'k

*** PASSED *** DDT BREAKDOWN TEST

Data File: 7chem/5972hp60.i/'DF020313A60.b/DF020313A60.d

Date : 13-MAR-2002 12:09

Client ID: DFTPP|




Operator: 917

Data File: 7chem/5972hp60.i/DF020313A60.b/DF020313A60.d

Date : 13-MAR-2002 12:09I

Client ID: DFTPP

iSample Info: DFTPP:917



Operator: 917

Column phase: J&W DB5.6251


#


Spectrum; Av/g* Scans 119-121 ( 7.06), Background Scan 117

Location of Maximum; 198*00

Number of points; 261

m/z Y m/z Y m/z Y m/z •<

**■

1 36 * 00 38 1 125.00 267 196.00 1282 1 275.00 11290 1

t 37.00 270 1 127.00 15296 198.00 48032 276.00 1450 1

1 38.00 671 1 128.00 1369 199.00 3453 277.00 1610 1

1 39.00 2013 1 129.00 9106 200.00 255 278.00 207 1

1 42*00 34 1 130.00 789 201.00 139 1 282.00 39 1

+ *

1 43*00 141 1 131.00 145 202.00 111 283.00 117 1

I 45*00 41 1 132.00 85 203.00 568 284.00 71 1

1 43*00 463 1 133.00 35 204.00 2213 1 285.00 196 1

1 50.00 10681 1 134.00 287 205.00 3699 1 286.00 37 1

1 SI. 00 27872 1 135.00 641 206.00 13336 289.00 62 1

+ +

1 52*00 1341 1 136.00 314 207.00 1569 1 290.00 40 1

1 53*00 37 1 137.00 448 208.00 617 293.00 202 1

i 55*00 238 1 138.00 65 209.00 159 294.00 119 1

[ 56.00 605 1 139.00 45 210.00 246 1 296.00 5506 1

t 57.00 942 1 140.00

1

158 211.00 563 297.00 683 1

*

1 53,00 36 1 141.00 1494 213.00 52 298.00 47 1

1 81.00 200 1 142.00 363 215.00 188 301.00 75 1

1 82.00 353 1 143.00 336 216.00 34 303.00 450 1

1 63.00 735 1 144,00 75 217.00 4578 304.00 113 1

l 64.00 99 t 146*00

*

332 218.00 514 1 308.00 81 1

*

1 65.00 216 1 147.00 171 219.00 58 309.00 48 1

1 67.00 44 f 148.00 3096 221.00 1378 310.00 65 1

1 63 00 19832 1 149.00 485 222.00 524 313.00 46 1

1 70.00 95 1 150.00 69 223.00 63 314.00 214 1

l 73.00 313 1 151.00 121 224.00 7985 315.00 534 1

1

l 74.00 4062 1 152.00 69 225.00 1899 316.00 292 1

i 75.00 3324 1 153.00 522 227.00 4925 321.00 96 1

1 76.00 1907 1 154,00 331 228.00 641 323.00 1217 1

I 77 00 26096 1 155.00 829 229.00 824 324.00 183 1

1 73*00 1740 1 156.00 1091 1 230.00 85 1 327.00 288 1

' 1 *

\ 73.00 2436 ! 157.00 159 1 231.00 217 1 328.00 127 1

l 30 00 1303 1 158.00 335 1 232.00 42 1 332.00 105 1

l 31 00 1621 1 159.00 218 1 233.00 63 1 333.00 33 1

i 32 * 'J'v1 383 1 160.00 5«6 1 234.00 240 1 334.00 779 1

1 244 1 161.00 631 1 235.00 268 1 335.00 166 164 i

Data File: /chem,'5972hp60.i/DF020313A60.b/DF020313A60.d

Date : l3pMAR-2002 12:09

Client ID: DFTPP

Sample Info: DFTPP:917Volume Injjected CuL): 2.0

Column phase: J8.W DB5.625


Operator: 917



Spectrum: Avg. Scans 119-121 ( 7.06), Background Scan 117



m/z V m/z Y m/z Y m/z Y

85.00 220 162.00 172 236.00 214 341.00 84

86.00 642 i 163.00 62 237.00 270 346.00 251

87.00 193 i 165.00 726 238.00 40 347.00 37

88.00 45 167.00 5396 239.00 202 1 352.00 392

89,00 35 168,00 2638 240.00 117 353.00 266

91.00 413 169.00 304 241.00 165 1 354.00 310

92.00 386 170.00 139 242.00 442 355.00 149

93.00 5199 171.00 145 244.00 5706 365.00 2344

94.00 308 i 172.00 312 245.00 676 1 366.00 299

95.00 119 173.00 363 246.00 1676 371.00 101

96.00 115 174.00 696 i 247.00 268 1 372.00 585

98.00 4574 175.00 1118 248.00 76 373.00 113

o o 2063 176.00 270 249.00 139 383.00 163

100.00 203 177.00 587 250.00 37 1 384.00 34

101.00 790 179.00 2533 251.00 40 390.00 55

103.00 312 180.00 1348 252.00 96 391.00 43

104.00 713 181.00 598 253.00 137 1 401.00 49

105.00 672 182.00 83 255.00 26896 402.00 202

107.00 6774 183.00 49 i 256.00 3816 403.00 304

108.00 863 184.00 243 257.00 34 404.00 104

110,00 9042 185.00 1183 258.00 2493 421.00 244

111.00 1562 186.00 6910 259.00 325 422.00 260

112.00 236 187.00 1970 260,00 55 423.00 1631

113.00 107 188.00 246 261.00 56 424.00 317

115.00 55 139.00 748 263.00 37 441.00 2106

117.00 16001 190,00 109 265.00 1103 442.00 31728

118.00 1020 191.00 246 266.00 38 443.00 6135

120.00 67 192.00 828 271.00 56 444.00 484

122.00 558 193.00 940 272.00 131

123.00 826 194.00 130 273.00 915

124.00 342 195.00 79 274.00 2608 1

(x!0A6)


Date : 13-MAR-2002 12:09

Client ID: DFTPP





Operator: 917


■:r>

'=3'

co


D:ECAFLUOROTRIPHENYLPHOSPHINE Ion Abundance/Ratio Criteria Chart

Son | Abundance Criteria Base Peak Other= = = = = + Test |

198 Base Peak, 100% relative abundance 100 .00 PASS51 3 0 - 80% of mass 198 58.04 PASS68 Le ss than 2% of mass 69 0.00 ( 0.00) PASS69 Mass 69 relative abundance 41.29 PASS70 Less than 2% of mass 69 0.20 ( 0.48) PASS

127 2 5 ' 75% of mass 198 31.84 PASS197 0 - 1% of mass 198 0.00 PASS199 5 ' 9% of mass 198 7.19 PASS275 1 0 - 30% of mass 198 23.50 PASS365 Greater than 0.75% of mass 198 4.88 PASS441 Present, but less than mass 443 4.38 ( 34.33) PASS442 4jo - 110 % of mass 198 66.06 PASS443 15 - 24% of mass 442 12.77 ( 19.33) PASS

TAILING ANALYSIS SUMMARYl

Compound1

Tail Factor Max Allowed Test

Pentachiorophenol 1.9 5.0 PASSBenzidine

i2.0 3.0 PASS


* Compound Response %Breakdown Max Allowed Test

W 4,4 -DDT . 762064 N/A4,4 - DDE 0 0.0 20.0 PASS4,4 -DDD 2380 0.3 20.0 PASS

4,4-DDD + DDE 2380 0.3 20.0 PASS

Tuning Sample, /chem/5972hp60.i/DF020313A60.b/DF020313A60.d/DF020313A60.d

PASSED

65:J


ort Date :i

03/13/2030 14:02

Datafile1 Analyzed: /chem/5972hp60.i/DF020313A60.b/DF020313A60.d/DF020313A60 . d Method Used: /chem/5972hp60.i/DF020313A60.b/dftpp8270C.m Inst: 5972hp60 Injection Date: 13-MAR-2002 12:09 Operator: 917Sample Info: DFTPP DFTPP:917 Misc Info:

651

Report Date: 03/13/2030 14:02

Datafile Analyzed: /chem/5972hp60.i/DF020313A60.b/DF020313A60.d/DF020313A60.d^tethod Used: /chem/5972hp60.i/DF020313A60.b/dftpp8270C.m Inst: 5972hp60^■jection Date: 13-MAR-2002 12:09 Operator: 917

Sample Info: DFTPP DFTPP-.917Misc Info:

HP MS DF0203l3A60.d

3.6-

3.3-

3.0-

2 7-

2.4-

2.1-

1.0-

1.5-

1.2-

0.9-

0.6-

0.3-'

0.0-

/ \CM

ro

b. b___I

6.8 6.9 7.0 7.1Time (Min)

7.2 7.3 7.4 7.5

1.1-

1.0-

i0.9-

0.8-

0.7-

0.6-

0.5-

0.4-

0.3-

0.2-

0.1-

HP MS DF020313A60.d. Scan 120: 7.058 min. >-198

255

442-,

275

18b ! - 1 .296. 148 i

. I'li , „,i ii ..

j . 323

.... 1.

60 100 120 140 160 180 200 220 2-40 260 280 300 320 340 360m/z

-365403.

380 400 420 440

DECAFLUOROTRI PHENYLPHOSPHINE Ion Abundance/Ratio Criteria Chart

Ion | Abundance Criteria Base Peak Other Test |


127 25 - 75% of mass 198 31.84 PASS197 0 - 1% of mass 198 0.00 PASS199 5 - 9% of mass 198 7.19 PASS275 10 - 30% of mass 198 23.50 PASS365 Greater than 0.75% of mass 198 4.88 PASSto1 Present, but less than mass 443 4.38 ( 34.33) PASSP12 4 o| - 110% of mass 198 66 . 06 PASS443 15 - 24% of mass 442 12.77 ( 19.33) PASS-

Report Date: 03/13/2030 14:02

Datafile Analyzed: /chem/5972hp60.i/DF020313A60.b/DF020313A60.d/DF020313A60.d

Report Date: 03/13/2030 14:02

Datafile Analyzed: /chem/5972hp60.i/DF020313A60.b/DF020313A60.d/DF020313A60.d^^:hod Used: /chem/5972hp60.i/DF020313A60.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h^^^jection Date: 13-MAR-2002 12:09 Operator:

Sample Info: DFTPP DFTPP-.917Misc Info:

HP MS DF0203l3A60.d, Ion 184.00

Ion 184

Tailing Factor =! 1.99576

1.3

1.2^

i. i-:

1.0-

0.9-

0.8-

<P 0.7-

0.6-i

V 0.5-

0.4

0.3-j

0.2^

o. 1-; o.o-

HP MS 07020313960^. Ion 1B4. 00

8.10 0.20 0.30 0.40Time (Min)

0.50 8.60

HP MS DF020313A60.d, Scan 194: 8.310 min.184""',

rf\. o-

0.9-

o.e-

0.7-

0.6

0.5-

(j,4-

0.5-

0.1

Benzidine

Exp. RT Found RT

Mass

184

ii/ 130156

100 160

8.3978.310

Area

196518

Ratio

100.00

Tailing factor for Benzidine OKm

ling Factor = 2.0

186

■! 01

180 200

.207 239.

220 240

.257281.

I

260 280

Maximum Allowed = 3.0

31313

300

65-

Report Date: 03/13/2030 14:02

m

Sarr

Datafile Analyzed: /chem/5972hp60.i/DF020313A60.b/DF020313A60.d/DF020313A60.d kthod Used: /chem/5 972Hp6 0 . i/DF02 0313A6 0 . b/df tpp82 70C . m/BrkDwnTF . m Inst: 5972h ectio'n Date: 13-MAR-2002 12:09 Operator:

ample Info: DFTPP DFTPP:917Misc Info:

HP MS DF020313860.Q. Ion 235.00

6.8-

6.4-

6.0-

5.6-

5.2

4.8-

4.4-

4.0-

3.6-

2. d\

2.4-

2.0-

1.6-

1.2-

0.8-

0.4-

0.0-

Ion 235

: \

1 /• /

/ l1

\ i

9.12 9.15 9.18 9.21 9.24Time

9.27(Min)

9.30 9.33 9,36 9.39 9.42 9.45 9.48 9.51 9.54 9.57

HP MS.DF0203l3Hb0.d. Scan 251: 9.274 mn."-235

m8-

2. 1

1.3-

1.5-

4,4'-DDT

Exp. RT Found RT

Mass

23 5

165

199

136

100 120 140 160 lbO 200

212

282. ,•286 -319 35-1 360 I

220 240 260 280 300 320 340 360 I

9.3629.274

Area

762064

Ratio

65::o

100.00

Report Date: 03/13/2030 14:02

«Datafile Analyzed: /chem/5972hp60.i/DF020313A60.b/DF020313A60.d/DF020313A60.d

.thod Used: /chem/5972hp60.i/DF020313A60.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h ection Date: 13-MAR-2002 12:09 Operator:

ample Info: DFTPP DFTPP:917Misc Info:

HP HS DF020313A60rd, Ion 235.00

600-

560

520

480-

4 4f>

400

360

320-

280-

240-

200-

160-

120-

80-

40-

Ion 235N'

I

iV-

8.26 3.29 8.82 8.85 8.88 8.91 8.94 8.97 9.00 9.03 9.06 9.09 9.12 9.15 9.18 9.21 9.24 9.27 9.30 9.33_________________________________ Time (Min)

HP MS DF020313A60.d. Scan 237: 9.037 min."‘"••207

✓281

176

147235

193

85

100

111

120 140 160

; I! Iin i

ii'i liill ;l.; ,!i;i

180 200 220

i |

240

•251

260

311

345

3.47

280 3001 I 1

340

I i

4,4'-DDD

Exp. RT Found RT

Mass

235

8.9899.037

Area Ratio

2380 100.00

65b

Report Date: 03/13/2030 14:02

Datafile Analyzed: /chem/5972hp60.i/DF020313A60.b/DF020313A60.d/DF020313A60.d^tethod Used: /chem/5972hp60.i/DF020313A60.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h^Bjjection Date: 13-MAR-2002 12:09 Operator:Sample Info: DFTPP DFTPP:917

Misc Info:

5.1-

4.8-

4.5-

4.2-

3.9-

3.6-

T T

3.0-

2.4-

2.1-

1.8-

1.5;

1.2;

0.9-

0.8;

0.3-

HP MS DF020313A60.CJ. Ion 246.00

Ion 246

8.28 el 31 8.34 8.37 8.40 8.43 8.46 8.49 8.52 8.55 0.58 8.61 8.64 8.67 8.70 8.73 8.76 8.79 8.82 8.85 8.08 I

I_________________ ________ _Time < Min) ____ _

A9'

950-

q 00- 50-

'80':'

750

700-

650-:

600-.

550-

500-

■_ 4 50-

400 :

350-

300-

250-

nn

HF MS DF0203l3A60.d. Scan 210: 8.580 min.207--5

28 K

,244

1B4

150;: :10 j 133

100-iij i;

50-/: ■'

0-','40 6'J 80 10' ' 120

4,4'-DDE

Exp. RT 8.583Found RT = 0.000

Mass Area Ratio

24 6 0 0.00

140 180 1Q0 200 220m/z

283

240 260 280 300 320

3.55

I !

340

65

6.0-

5.6-

5.2- 4.B-

i 4 . 4-I4.0-

3.6-

3.2- :

2. a-;2.4-:

2.0-

1.6-

1.2-

0.8-

Ci. 4-

0.0--

HP MS DF020313P60.^i. Ion 235.00

CM

CP

9.10 9.20 9.30______ T ime lMin >

9.40 9.50

HP MS DF020313060kJ. Ion 235.00

520-

480-

440-

400-

360-

320-

200-

240-

200-

160-.

120-

00

40-I

8.80 8.90 9.00 9.10 9.201Time (Min)

9.30

HP MS- DF02031 3060 . d. Ion 246.00

' o. ou i M l n j

8.80

Compound: 4,4'-DDT

Quant Mass: 235

RT: 9.274

Area: 762064

Compound: 4,4'-DDD

Quant Mass: 235

RT: 9.037

Area: 2380

Compound: 4,4'-DDE

Quant Mass: 246

RT: 0.000

Area: 0



4,4 - DDT 762064 N/A4, 4-DDE 0 0.0 20.0 PASS4,4-DDD 2380 0.3 20.0 PASS4,4-DDD + DDE 2380 0.3 20.0 PASSm

TUIUNE SAMPLE★ ★★★★★★★★★★★★★ *** PASSED ***'k'k'k'kir'k'k'k'k'k'kic'k'k

DDT BREAKDOWN TEST

658

V

Data f|i le: /chern/S'^ShpkO* i/DF020314E’b0*b/IiF02C,314B60,d

Date : 14-MhR-2002 2^:31

Delta F i

Date :

Client

Sample

le: /chem/5972hp60

'14-MAR-2002 20:31

ID: DFTPP

Info: DFTPP:231'?

Volume Injected (uL) 0

i/DF020314B60.b/DF020314B60.d


Data File: DF020314B60.d

Spectrum: Avg. Scans 118-120




Operator; 2319


7.04), Background Scan 116

\

1

m/z Y m/z Y m/z Y m/z Y

1

1 3b ♦ 00 41 119.09 87 190.00 132 1 273.00 931 1

1 77 no 404 120.00 75 191.00 336 l 274.00 2777 1

1 38*00 1090 122.00 79? 192,00 920 1 275.00 11835 1

I 39.00 3063 123.00 1026 153.00 in? 1 276.00 1703 1

1 40.00 143 124.00 446 1 134.00 182 1 277.00 1635 1

,1 1

1 41.00 97 125.00 316 1 136.00 1472 1 278.00 269 1

1 43.00 66 127.00 18488 1 193.00 53376 1 279.00 41 1

l 44.00 57 123.00 1508 1 199.00 3524 1 283.00 159 1

1 45.00 109 129.00 10838 1 200.00 296 1 284.00 108 1

1 48.00 35 130.00 1024 1 201.00 15? 1 285.00 265 1

*1 1 1 *

1 49,00 92 1 131.00 223 1 203.00 560 1 290.00 39 1

1 . 1614b 1 132.00 66 1 204.00 2461 1 292.00 44 1

1 51.00 40064 1 133.00 41 1 205.00 4172 1 293.00 287 1

1 52.0';' 2121 1 134.00 336 1 206.00 13963 1 294.00 38 1

1 57 - 1 • < 49 1 135.00 906 1 207.00 2078 I 296.00 5696 1

+ 1 1 1

1 55.0'..' 272 136.00 335 1 208.00 717 1 297.00 820 1

1 5»:. ■ 782 137.00 517 1 209.00 231 1 298.00 51 1

1 57.00 1315 138,00 111 1 210.00 265 1 301,00 45 1

1 58.00 32 139.00' 70 1 211.00 707 1 302.00 68 1

i 57 140.00' 134 212.00 93 l 303.0c 456 1

i 61.00 4 0 0 141.00- 213.00 51 1 304.00 134

1 0.1'. 00 0.09 142.00' 497 215.00 263 1 308.00 97

1 05.0' c,5b 143.00' 315 217.00 4674 | 313,00 36

1 0.4 . 124 144.00 103 218.00 605 1 314.00 ;ii

! 05 <Vi 204 146.00 383 219.00 43 1 315.00 593

; 8;•. i>-i 92 147.00 1107 1 221.00 150" l 316.00 235 1

j 69.00 20.0.88 143.00' 4273 1 222.00 61? 1 321.00 166 1

i 73, .ii, 5"?0> l 149.00 (i 44 1 224.On 9012 t 323.00 1302 1

1 74.0".' 5498 1 150.00 92 1 225. 2526 i 324.00 182 1

1 75. no 5304 1 151.00' 171 1 227.00 5409 1 326.00 45 1

273? 1 152.00 ?3 l 223.00 *2- 4 4> 1 327.00 341

77..;,,, 37253 l 153.0.0' 651 l 229 Oo 921 1 328 00 132

78.■ " ■ 2348 I 154.''O' 334 ; 23':*. 00 90 1 332 00 114

. 743^ 1 155.. .0 1162 1 231.-'0 704 1 333.00 99

IS 19 1 156.00 1239 1 233.00 77 1 334 00 CO 7

Data File-: /chem/5972hp60.1 /DF020314B60. b/BF0203l4B60.d

Date : 14-MhR-2002 2o:3l

Client ID: DFTPP

Cample Info: DFTPP:231?


Column phase J8.U DBS.625


Spectrum: Avg. Scans 118-120




Operator: 2319


7.04), Background Scan 116

m/z V m/z Y m/z Y m/z Y

1 1 *

31.00 2309 1 157.00 170 1 234.00 299 335.00 211

82 00 559 1 158.00 269 235.00 272 341.00 169

33.00 332 159.00 194 236.00 238 346.00 353

35.00 354 160.00 698 237.00 341 352.00 382

ob. 00 1115 161.00 716 239.00 219 353.00 261

37.00 272 162.00 142 24-). 00 151 354.00 343

38.00 121 163.00 92 241.00 212 355.00 50

91.00 613 165.00 832 242.00 509 365.00 2589

92.00 707 167.00 7014 244.00 6317 366.00 326

93.00 7355 168.00 3447 245.00 399 371.00 110

1

94.00 373 1 169.00 406 1 246.00 1803 I 372.00 671

87 1 170.00 137 247.00 358 373.00 171

96. 00 1*3 1 171.00 184 248.00 61 383.00 186

:'o. 6391 1 172.00 363 1 249.00 159 l 384.00 35

9?. Oo ii c- 3 1 173.00 399 251.00 65 390.00 54

1

100.00 213 1 174.0':- 790 252.00 47 392.00 33

101.00 981 1 175.00 1461 253.00 175 402.00 241

103.00 4 43 1 176.00 252 255.00 23792 403.00 356

104.00 941 177.00 745 256.00 4216 404.00 72

105,00 808 179.00 3176 257.00 93 421.00 299

106.00 35 180.00 1572 ! 253.00 2520 422.00 S3

107.00 8958 131.00 816 259.00 371 423.00 2022

103.00 1056 132.00 75 260'. 00 56 424.00 351

110.0>-> 12196 133.0':' 67 261.00 38 1 425.00 45

111.00 2117 184.00 265 1 264.00 31 i 441.00 6795

1

112.00 33u 135.00 1485 1 V.5 00> 1101 1 442.00 33944

113.00 114 1 136.'-:":' 3830 1 266.00 223 i 443.00 7680

114.00 5i i IS 7..JO 2621 1 27'). 00 46 1 444.00 581

117.00 22416 l 138.',":' 301 1 271.00 139 .

113.00 1423 1 139.00 301 [ to 6F- 1 I

<s xio-

Instrument; 5*'"172hp60. i

Operator; 231*3


,V:hem/59?2hpbO. i/BF020314B60,b/DF020314B60.d5.2-

5.0-

4.8-

4.6-

4.4-

4.2-

4.0- ;

3.8-

3.6-

3.4-

Data File: /’chem/5972hp60.i/DF020314B60.b/DF020314B60.d

Date : 14-HAR-2002 20:31

Client ID: DFTPP

Sample Info; IiFTPP;2319

Volume Injected <uL); 2*0

Column phase; J&W DB5.625

. v Jco

CjD

3.0-

2.0 -

l. y -

1.6-

1,4-

1.2-

0.4-

1' ■. 5 1«\8 11.1 11.4 11.7 12.0 1 2. »:•


DECAFLUOROTRIPHENYLPHOSPHINE Icn Abundance/Ratio Criteria Chart

^Ion Abundance Criteria Base Peak Other Test |

*198Base Peak, 100% relative abundance 100.00 PASS

51 30 - 80% of mass 198 75.06 PASS68 Less than 2% of mass 69 0.00 ( 0.00) PASS69 Mass 69 relative abundance 50.01 PASS70 L'ess than 2% of mass 6 9 0.00 ( 0.00) PASS

127 25 - 75% of mass 198 34.64 PASS197 0 - 1% of mass 198 0.00 PASS199 5 - 9% of mass 198 6.60 PASS275 10 - 30% of mass 198 22.27 PASS365 Greater than 0.75% of mass 198 4.85 PASS441 Present, but less than mass 443 12.73 ( 88.48) PASS442 <10 - 110 1 of mass 198 72.96 PASS443 15- 24% of mass 442 14.39 ( 19.72) PASS |

+ = = = =

TAILING ANALYSIS SUMMARYl

Compound Tail Factor Max Allowed Test

Pentachlorophenol 0.8 5.0 PASSBenzidine

i0.0 3.0 PASS

j

DDT DEGRADATION BREAKDOWN ANALYSIS SUMMARY1


4,4-DDT 962075 N/A4,4-DDE 867 0.1 20.0 PASS4,4 -DDD 61380 6 . 0 20.0 PASS

4,4-DDD + DDE 62247 6 . 1 20.0 PASS

Tuning Sample, /chem/5972hp60.i/DF020314B60.b/DF020314B60.d/DF020314B60.d

*** PASSED ***

66 j


Report Date: 03/14/2030 22:06

Datafile Analyzed: /chem/5972hp60.i/DF020314B60.b/DF020314B60.d/DF020314B60.dMethod Used: /chem/5972hp60.i/DF020314B60.b/dftpp8270C.m Injection Date: 14-MAR-2002 20 :31 Operator: 2319Sample!Info: DFTPP DFTPP:2319

Misc Info:

Inst: 5.972hp60

HP M5 DF020314B60 ,,d

•• i-no r n'c « d — lIC' •: .••'C- ODD • • D~TT• r

"D ;■£> iRFC-I' — i'< J iID irn'lDirUTN: lY1>

<yz' c-irv-r •£. g- TjD -k -Lr j rTTU“ O iDD -76 -^l

rj, km-, r. can

d . d (Mid)

9.6 10.0 10.4 10.8 LI.2 11.6 12.0 12.4

664

Report Date: 03/14/2030 22:06

Datafi le Analyzed: /chem/5 972hp6 0 . i/DF020314B60 . b/DF020314B60 . d/DF020314B60 . .1 Used: /'chem/5 9 72hp6 0 ,i/DF020314B60.b/dftpp8270C.m Inst: 5972hp60

ion Date: 14-MAR-2002 20:31 Operator: 2319Info: DFTPP DFTPP:2319

Misc Info:

5.1-

4.3-

4.5-

4.2- '

3.9-

3. b-

3.0-

2.1-

1 . 8-

1.5-

1 . 2-

HP M5 DF020314B60.d

6.9 7.0Tim^ < Min)

M ’.2 \5

HP MS DF020314B60.d. Scan 119: 7.041 min. 1 96'

148 .296

365

j o r ■■ r0 : 20 140 160 2 60 .".'00 220 240 260m.-' c

280 300 320 340 360 350 40

DEC LUOROTRIPHENYLPHOSPHINE ion Abundance/Ratio Criteria Chart

lor. Abundance Criteria Base Peak Other Test |

193 Base Peak, 100% relative abundance 100.00 PASSD 2 3 0 30% of mass 198 75.06 PASS6 3 L ,6SS than 2% of mass 69 0.00 { 0.00) PASS6 9 Mass 65 relative abundance 50.01 E^ASS7 0 Less than 2% of mass 65 0.00 ( 0.00) PASS

127 — 75% of mass 19B 34 . 64 PASS1 2 7 Q 1% of mass 198 0 . 00 PASS1 9 9 5 5% of mass 198 5 . 60 PASS2 75 1 0 30% of mass 19S 22.27 PASS3 6 5 Urea ter than 0.75% of mass 198 4.85 PASS441 ■'ves ere, but less than mass 443 12.73 8 3 .43) PASS

’ A *-i *1 -1 o' - 11C% of mass 198 72 . 96 PASS4 ~ 3 1 2 3 4? c I m ca. s s 'i-t 14.39 19.72) .PASS

----- +66b

Report Date: 03/14/2030 22:06

dDatafi'le Analyzed: /'chem/5 9 72hp6 0.1/DF020 314B60 . b/DF02 0314B6 0 . d/DF02 0314B60 . dMethod] Used: /chem/5972hp60.i/DF020314B60.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h

(Injection Date: 14-MAR-2002 20:31 Operator:Sample]Info: DFTPP DFTPP:2319

Misc Info:

4

3-.

3-

3.4

5.1-

4.6-

4.5-

riF ms DFij2u3l4560.d. Ion 266.00

Ion 266

Tailinq Factor .= 0.82149

6.0-

5.6-

5.2- '

4.8-

4.4-

4.0-

3.6

3.2-

2.8-

2.4- ;

2.0-

1.6:

1.2-

0.8-

0.4-

HP MS DF020314B60.jjJ, Ion 266.00

6.55 6.60T : me •: M 1 n )

6.65 6.70 6.75 6. SC' 6.35 6.90 10.0-i :--------- ——— ----

6.30 6.40 6.50 6.60Time (Min)

6.80 6.90;

HP MS DF020j14B60.d. Scan 93: 6.601 min.

Fentacn

,202230.

180 190 200 240 250

i;!

i iiil

II:Hi2

111!.

"i 2?n

Exp. RT = Found

jpneno ^

6.639

Mass Area

2 o o 110 2 0

Tail me rector f o

l1ing Factor =

12 Talia Tail ina Factor

Rat io

100.00

Pentachlorophencl OK

3 Maximum Allowed = 5.0

o T z p r oit is assumed that the peak is not tailing and ■sported. m-

bbo

Dace: 03/14/2030 22:06Report

Datafile Analyzed: /chem/5972hp60 . i/DF020314B60 . b/DF020314B60 . d/DF020314B60 . ,:i Method j Used: /chem/5972hp60.i/DF02 0314B6 0.b/dftpp8270C.m/BrkDwnTF.m Inst: b 9 ~'2h

njection Date: 14-MAR-2002 20:31 Operator:Sample{Info: DFTPP DFTPP:2319

Misc Info:

9.5-9.0- :

8.5- ;

3.0- ;

7.5- .

7.0-

6.5-

6.0-

5.5-

5.0- .

4.5- .

4. o-:3.5- .

3.0- '

2.5-

2.0-

1 .5-

1.0

0.5

0.0-------

HP MS DF020314B60.a. Ion 184.00

Ion 184

Tailing Factor ;= 0.00000

HP MS DF020314B60JJ. Ion 184.00Onco

8.10 3. n 3.25 S.30Tlme (Min >

3.35 8.40 8.45 8.50 3.55 e.60

5

5

4

4

3

3.0

2.5-

2.0-

1.5-

1.0-'

0.5-:

0. u-:

HP MS DF02C 314560.d. Scan 194: d.309 min. 104‘,

o.o- 6.4-

6.0-

5.6-

5 . eL-

4.8 4.4

-j 4 . •

2.3

cenziame l_ _i

Exp. Rj. = Found RT

Mass

184

8.357

3.305

"ai 1 ina

Area

164610

factor for 3

Factor = 0.0

Ratio

100.00

enzidine OK


8.10 8.20 8.30 8.-40 8.50 8.80;Time (Min) _______ _ :

239. 231 .

280 300

If Tailing Factor < 1.0, then it is assumed that the peak is not -t£ijCl£ng and a Tail ina Factor of zero is reDorted . UU ,

Report Date: 03/14/2030 22:06

Datafile Analyzed: /chem/5972hp60.i/DF020314B60.b/DF020314B60.d/DF020314B60 .Method Used: /chem/5972hp60.i/DF020314B60.b/dftpp8270C.ra/BrkDwnTF.m Inst: r_njection Date: 14-MAR-2002 20:31 Operator:Sample]Info: DFTPP DFTPP:2319

Misc Info:

5

5-

HF MS DF020314860.d. Ion 235.00

Ion 235

P.06 9.09 9.12 9.15 9.18 9.21 9.2-4 9.27 9.30 9.33 9.36 9.39 9.42 9.45 9.43 9.51 1______ Time (Min) ________________________ _________ __

HP MS DF020314860.d. Scan 250: 9.257 min.• • '235 ’’,

199

240 260 2d'

- DDT

219

ixr . a

Fount

Mass Area Ratio

; 2 0 75 10 0.00

666

.d5972h

.54

1 0 0.0 0

Report.

^^iyi

m

Method

Dace: 03/14/2030 22:06

Datafile Analyzed: /chem/5972hp60.i/DF020314B60.b/DF020314B60.d/DF020314B60.dUsed: /chem/5972hp60.i/DF020314B60.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h

r njection Date: 14-MAR-2002 20:31 Operator:Sample| Info: DFTPP DFTPP:2319

Misc Info:

5. J-

5.1-

4.8-

4 . 5-

4.2-3.9- '

3.6-

3.3-

3 n-

2.1-

1 *3-.

1.5-

1.2-

0.9 0. 6

HP M5 DF020314B60.d. Ion 235.00

Ion 235

a.5-

5-

5

•*T 4

5.61 8.64 8.62 8.30 8.33 8.76 S.7Q 8.82 3.85 8.88 8.91 8.94 8.97 9.00 9.03 9.06 9.09 9.12 9.15 9.18___________ T ime (Hin)________ ___ ______ ______ ________ ___ ________________

HP MS DF020314B60.d. Scan 228: 8.805 min.2b3""’

5-. !!

103 ,281

317345

240 260 280 300

380 384

I 380

4,4'-DDD =======L

Exp. RT Found RT

Mas;

235

.98 9 ! 8 5o .

Area Ratio

61380 100.00

66i

Reoort Date: 03/14/2030 22:06

Datafile Analyzed: /chem/5 972hp6 0.i/DF02 0314B60.b/DF02 0314B60.d/DF02 0314B60.dMethodJused: /chem/5972hp60.i/DF020314B60.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h ‘njection Date: 14-MAR-2002 20:31 Operator:ample|Info: DFTPP DFTPP:2319

Misc Info:

800-

750-

700-

650-'

600-

550-'

500-

450-

4Q0’

300-

250-

200-

I50r

100-

50-

hP mS 0F020314B6U. d. Ion 246.00

Ion 246

O'J'J-

560-

520-

401.'

J4ij

•400

360 ■

260

240

160

1 20

30 •

25 8.28 3.31 8.3*4 3.37 8.40 3.43 8.46 0.49 8.52 8.55 8.58 8.61 8.64 8.67 8.70 8.73 8.76 3.79__ Time (Min; _____________________

HP MS DF020314E60.d. Scan 205: 8.495 min.207-

•246

281- 316

12510"

I 328

j:j!|i'll!

240 260 280 220

4,4'-DD

txp . Found RT

Mass

246

8.583 8 .495

Area Ratio

3 6 7 10 0.00

67G

7.0-

5.0-

- . 0-

2.0-

2.0-

1 .0-'

4. 5-

4.2-

2 G-

9.00 9.10 9.20 9.30___ Time (Min)_____

HP m3 DFu20314Ef6u . Ion

i £CD

9.40 9.50

'35.00

Compound: 4,4'-DDT

Quant Mass: 235

RT: 9.257

Area: 962075

Compound: 4,4'-DDD

Quant Mass: 235

RT: 8.885

Area: 61380

0.9-

0.6

0.3-

650-

600-

550 ■

50 '0 -

4 50

400

350

l ft.= : M i n )

314660^*5. Ion 046

t

9.10

250

200

Compound: 4,4'-DDE

Quant Mass: 246

RT: 8.495

Area: 867

DDT D^GRADATiOl BREAKDOWN ANALYSIS SUMMARY-=========================================-=============+

Comocund | Resoonse I ^Breakdown I Max Allowed I Test I+

4,4 - DDT 962075 N/A4,4-DDE 867 0 . 1 20.0 PASS4,4-DDD 61330 6 . 0 20.0 PASS4,4-DDD - DDE 6 2 2 4 7 6 . 1 20.0 PASS

+

■k'k'k^-k-k-k'ir-k-k-k-k-k-k

RLE *** PASSED *** DDT BREAKDOWN TEST

67

Data F i 1 a; /char«-i/5?72hpl.:'4. i/DF020310A64 *b/DF0203'10ft64 .d I

Date : iojt1AR-2002 13:53

Client ID: DFTPPI

'sample Info: DFTPP:231?I

Volume In,iacted m.jLJ j j*•:>

Co I umn phii.e; J-'M'J DE5 * C25

1 Dae af 1 ucrotr i pheny 1 pho = f-4'i i na

Operator: 231?


I nstrument: 5?72hp64*i

Instrument: 5972*hp64. i

Dat b F11 ■=•: .•'•:.h*M/5972hp64. i,''E1Fv2,",31vh^4.6/1^020310864*<:Ji

Date : lOj-MAP.-zoo/ 13:53

Client ID1: DFTPP

ISample Info: DFTPP:231?

Volume IrJieoted ’.uL>: 2,0 Operator': 231?

Column phk=e: i;,W PBS.625 Column diameter: 0.32


Spectrum: Avg. Scans 185-187 ( 8*17), Background Scan 182

Loeaticn of Maximum: 193,00

Numk«?r of points: 274

>1/Z "■| m/z Y m/z Y m/z Y

1 *1 , 36.00 32 1 12?.00 35416 1 200.00 862 233.« 463 1

1 37*00 534 1 130,00 2?07 1 201,00 766 284,CO 166

1 38.00 1371 131.00 562 1 203,00 1087 235.CO 4S4 1

1 38.00 7424 132.00 276 1 204.00 5265 286.CO 70 1

1 45.00 104 133,00 82 1 205.00 8343 283. CO 32 1

1 + *

1 4?. 00 777 134.00 1013 1 206.00 36230 1 290.CO 74 1

1 50.00 24072 135.00 2530 1 207.00 4323 1 231. CO 70 1

1 51 * oo 35936 136.00 1131 1 203,00 1376 1 292,CO 117 1

I .... ', 4383 137.00 1235 1 203.00 437 1 293,CO 645 1

J 53 * 00 20 7 133.0.0 261 1 210.00 747 1 294.CO 13S 1

1 r.p, ,-Vi 1 138.00 195 1 211.00 1543 1 236.CO 3322 1

! ro i ii"i 2278 f 140.00 412 1 213.00 75 1 237. CO 1337 1

1 i r,7 5Si2S 1 141.00 4314 l 215.00 416 1 293,CO 71 11 l

61. Ou 105.5 1 142.00 1375 1 217.00 . 10601 1 301,CO 104 11

02.00 1247 143.00 961 1 218.00 113? 1 302,CO 165 t

1

1 63.00 31S1 144.00 253 1 219.00 10? 303,CO 1006 1

1 64.v11 483 145.00 271 l ..... . ?.,17 304,CO 221 1

1 05.00 ■15--.4 146.00 SO? 1 227.00 2344 303.CO 11? 1

1 67.01'1 11 147,0.':. 1894 1 224 00 ■ i-i^c; -- 309.CO 80 1

1 C?.o,'. 1''6582 143.00 5233 l 225.‘''0 5020 310.CO 115 1

1

t 7'.'.'.".' 2'23 148.'".' 1060 1 227.Ou 8941 313.CO 0 7

1 T7. O'"1 150.no 296 1 223. O'-1 120; 714. Cv 416

i 74 ■ ::3-‘'' 1 151. ■'.■ • 492 l 229. • * 1701 315.‘ 1076

i t r . •,, , 123C4. 152.00 138 1 23'.'. 255 316.00 530

i 4273 153.00 123- : 23l..,0 666 317.CO S3

1

i 77. v ’ "r476-'1 i 154.uO 876 1 232. ■ >0 ■86 721.CO 258 1

: 5.,-ic 155. OO- 2030 : 277.00 122 1 323.CO 3094 1

! 70 . , n • 6138 ! « rlk:, . 1, 1 28ii : 3 74 . 5 1 324.CO 536 1

1 s 4'>86 1 157.on 670 1 275.nn . -07 1 327.CO 645 1

1 31.0., 5721 1 153. 46" 1 2 3n. 4 27 1 328 CO 254 1

! i 1512 1 15?.'"-. 53’ 9 1 27-V.n 583 1 332. CO1 I'd 8 1

1 12vi: 1 160.0' ■ 1-27 1 27:'.”0 34 1 333 ~,/'1 260 1

1 24 . • . 15 1 161. ■ 17-41 ’ 279 ■ •v 747 1 334,CO 1353 1

i ,::rri . 1172 1 102..>, 4 72 1 24 0 00 237 1 !■ 1-Zj . 463

1 1737 1 1. 189 ! I-U . ■ " 4 5t 1 341.CO 462 1

Data F i 1 ■=•; /cher-i. '5972hp64* i/DFO20310H64 *1:i/DF020310h64 . d

Hat* : lo-jMftR-2002 13:53

IIlent ID: DFTFPI

Sample Inty;.; DFTPP;2319

"‘o 1 urn* I n j f *d (. uL): 2. u

Column ph-i-H; 3Ul DE5.625

Operator: 2319

Column diameter; 0.32

Instrument: 59721*ip64.i


Spectrum: Hvg. Scans 185-187 C 8.17), Background Scan 182

Locat of Maximum: 198.00

Humlrer of points: 274

*i/Z v m/z V m/z V

1

m/z Y

1+ +

1 87.00 594 1 164.00 213 1 242..00 1022 t 342.CO 36 1

i ss.oo 7*33 1 165.00 1736 ! 243. 00 1196 1 346.00 612 i

1 S'?, oo 192 1 166.00 1193 1 244. 00 16536 1 347.CO 94 1

1 91.00' 1447 1 167.00 3362 1 245. 00 2259 1 352,CO 933 i

1 1405 1 168.00 3774 1 246. 00 3039 1

*

353. CO 571 f

*

1 93.00 11.351 l 169,00 686 1 247. 00 565 1 354.CO 1024 1

[ 94.00 ^*-.7 1 170.00 316 1 248. 00 111 1 355.CO 199 1

1 95.00 146 1 171.00 301 1 249. 00 577 1 365.CO 4125 i

1 96.00 355 1 172.00 691 1 250. 00 97 1 366.CO 552 1

1 98. CO.- S513 1 173.00 858 1 251. 00 102 1

1

370.CO 94 1

*1 1

1 53*0 1 174.00 1607 1 00 130 1 371. CO 205 1

1-‘1.00 27->l 1 175.00 2792 1 “'57 00 264 1 372.CO 1733 t

i 102. .-o 198 1 176.00 830 1 •or.r, no 75736 l 373.CO 359 1

' 103.oo 1150 1 177.00 1622 1 256. 00 10989 f 333.CO 355 i

i iv4 .0"? 2153 1 178.00 195 1 257. 00 804 1 384*CO 99 1

1 1

1' ‘5 *1 2-’73 1 179.00 6273 1 258. •0 4506 1 390,CO 134 1

! l1 '7.1111 242O0- t 180.00 3904 1 “ P,v. 00 677 1 391.CO 146 1

1 1-S.oO 7789 1 181.00 1901 t 260. 00 109 1 392.CO 38 I

110.00 43520 1 132.00 32" 1 261. 00 97 1 401.CO 92 1

] 111.00' -13 l 187.00 203 1 264. 00 145 1 402.CO 646 1

1 112. ::81 1 184.00 230 1 “'i: 5 .00 1952 1 403.CO 1037 1

] 113."':' 71" 1 135.00 2706 i 266..'■'0 421 1 404.CO 260 1

■ 1 1 [T , ,, . 199 l 186.00 19934 267..00 36 1 421.CO 847 1

' 24712 1 137. O'". 567 4 1 270,. Ov 7o 1 422.CO 730 1

1 US."' 1"1" 1 1S-3.0, 1200 ■ 271. 137 1 423.CO 7135 1

1 119.00 144 1 1-;.o. 263 1 273 .V'J 2452 1 424.CO 1356 1

120.00 295 t 191.00 c-2" 1 274 .■•■0 ►2-678 1 425.CO 110 1

i 121.00- ?? 1 192.0- 2142 1 -.■TP, 36240 1 441.CO 19496 1

1 132.'V. 106.9 1 193.00 1980 ! 2"6 . 00 4790 1 442.CO 134843 1

1 123 tVi 25-4 5 1 194.no 42" 1 27" . oo 2957 1

1

443.CO 26104 l

1 124.0-'- 1270 1 195.00 224 1 273 . oo 473 1 444. CO- 2409 1

1 125. ■■■■ l.;r,:. 1 196.vv 4 f 55 1 279 . O'O 75 1 445.CO 121 1

i 127.'." ■ "3152 1 ■ 193.00 131952 1 231 .0'-' 73 1 1

12-:.'"' 0117 1 1 11951 ! l-"’4 1 1

674

Dat a Fi le: /chem/5972hp64.i/DF020310AC.4,b/DF020310fl64.d

Date : 10-HAR-2002 13:53

Client ID: DFTPP Instrument: 5972hp64.i COSample Info: DFTPP;2319 h-Volume Injected <uL)j 2.0 Operator: 2319 CDColumn phase: J&W DBS.625 Column diameter: 0.32

/chem/5972hp64*i/DF020310A64 * b/DF020310A64.d

5*b:

5.4-

5*2-

5,0-

4.8-

4,6-

4.4-

4,2-

ui

2.4 -

2. 0 -

i. s

1 , b ^

1.4-|

1.2-

1 * 0 -

b , ‘o b . 9 7 * S 8.1 8.4

i I j “ kJr'.

1 * 2 10. 5 l" 11.1 11.4 11.7 12.- L 2.7 12.0 li 13*84


DECAFLUOROTRIPHENYLPHOSPHINE Ion Abundance/Rati.o Criteria Chart

H--------^°n | Abundance Criteria Base Peak Other | Test

*98Base Peak, 100% relative abundance 100.00 PASS

51 3 0 - 80% of mass 198 47.23 PASS68 Le ss than 2% of mass 69 0.00 ( 0.00) PASS69 Ma ss 69 relative abundance 58.59 PASS70 Lejss than 2% of mass 69 0.12 ( 0.21) PASS

127 25 - 75% of mass 198 42.95 PASS197 0 - 1% of mass 198 0.00 PASS199 5 - 9% of mass 198 6.57 PASS275 1 0 - 30% of mass 198 19.92 PASS365 Greater than 0.75% of mass 198 2.27 PASS441 Present, but less than mass 443 10.72 ( 74.69) PASS442 40 - 110 % of mass 198 74.12 PASS443 15 - 24% of mass 442

i14.35 ( 19.36) PASS

TAILING ANALYSIS SUMMARYi

Compound

PentachiorophenolBenzidine

Tail Factor Max Allowed Test

0 . 0 5.0 PASS0.8 3 . 0 PASS

DDTiDEGRADATION BREAKDOWN ANALYSIS SUMMARY

| Compound Response %Breakdown Max Allowed Test

B 4,4-DDT

W 4,4-DDE2311475

1256 0.1 20.0N/APASS

| 4,4-DDD 19 8 4 4 0 . 9 20.0 PASSi 4,4-DDD * DDE

I21100 0 . 9 20.0 PASS

= = = = == H


*** PASSED ***

67b

TAILING FACTOR and DEGRADATION SAMPLE AND GRAPHIC■REPORT

ort Date: 03/11/2030 08:43

Datafile Analyzed: /chem/5972hp64.i/DF020310A64.b/DF0 20310A64.d/DF020310A64.d Method Used: /chem/5972hp64.i/DF020310A64.b/dftpp8270C.m Inst: 5972hp64Injection Date: 10-MAR-2002 13:53 Sample Info: DFTPP DFTPP:2319 M i s c Info:

Operator: 231.9

5.6-

5.4-.

HP MS DF020310P64.d

ii'-i 'Hi—m

•r COf-.-C-C' JJf-'IT J

oj rr*7-nnnF'-: t n .,?/

67

Report Da te: 03/11/2030 08:43

Qaraf ile Analyzed: /chem/5972hp64.1./DF020310A64 . b/DF020310A64 . d/DF020310A64 .d •hod Us|ed: /chem/5 972hp64 . i/DF02 0310A64 . b/df tpp82 70C . m Inst: 5972hp64 ^^ection; Date: 10-MAR-2002 13:53 Operator: 2319

Sample In'fo: DFTPP DFTPP:2319 Misc Info:

2.6-

HP M5 DF0203iG464.d

n.

1 . b

1.2-;

0.6

0. 4-

8.0 8.1 8.2 Tim-? 'Min.1

8.3 3.4 3.5 8.6

HP MS DF020310A64.d. bean 186: 8.170 min. 198

255

275

323

340 330 380 400

DECAFLuOROTRIPHENYLPHOSPHINE Ion Abundance/Ratio Criteria Chart

I on Abundance Criteria Base Peak Other Test |

1 9 S j S a s e Peak, 100% relative abundance 100.00 PASS51 3 0 80% of mass 198 47.23 PASS31 Les s than 2% of mass 69 0.00 ( 0.00) PASS

6 9 Mas s 69 relative abundance 58.59 PASS70 Less than .2% of mass 69 0.12 ( 0.21) PASS

127 25 75% of mass 19 8 42 . S5 PASS197 1 o 1% of mass 198 0.00 PASS1 ? 5 | 5 9% of mass 198 6.57 PASS

i n 30% of mass 198 19.92 PASSGre ater than 0.75% of mass 193 2.27 PASS

Rl! sent, but ^ =ss than mass 443 10.72 ( 74.69) PASSia? ! 40 - i :J O Cl- IT; cl S S J. 9 5 74.12 PASS44 3 | 15

ii q, _ .c _ __ _ « .1 ^jL ~t 'o C i. :. i ci br 4 % Z 14.35 ( 19.36)

= = = +

445

44m

.592

Report Date: 03/11/2030 0S:43

:afile Analyzed: /chem/5972hp64.1/DF020310A64.b/DF020310A64.d/DF020310A64.d Ipoa Used: /chem/5972hp64.1/DF020310A64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h rect ion! Date : 10-MAR-2002 13:53 Operator:

Sample Info: DFTP? DFTPP:2319 Mi sc Info!:

HP M'z DF020310H6*1 . d. Ion

Ion 266

Tailinq Factor* = 0.00000

i.

i.

0.3

Time- < Mi.00 3.05 8.10

HP M'S DF020 b 1 0h6-i . d. Scan 165: 7.615 min.

HP MS DF020310H6J Ion 266.00

.60 7.70 7.90 7.9STime (Min)

3.1'!

- :-:p .' c-cnd

7.830

7.31b

toe' i

Rat ic

100.00

;wea = n

Tailing Factor < 1.0, then it is assumed that the peak is not tailing and Tailmo Factor of zero is retorted.

^ Uh

03/11/2030 08:43report Date:

atafile Analyzed: /chem/'5972hp64 . i/DF020310A64 . b/DF020310A64 . d/DF020310A64 ,thod Used: /chem/5 972hp64 . i/DF020310A64 . b/df tpp82 70C . m/BrkDwnTF . m Inst:action Date: 10-MAR-2002 13:53 Operator:

ample Info: DFTPP DFTPP:2319 isc Info:

n? MS D F t'j'.'S 1 uhcM . d , Ion 18*4.0'. HP MS DF020310h6*4 r$. Ion 184.00CM

Ion 184

Tailing Factor = 0.79167

b. 6-

6. 4- 6. 0-'

5.6-

5.2z

4.8-

4.4- ; 4. o-:

3. b

3.2

2.8-

2.4-

2.0-

. 6-

.5'!' 9.55( h : n )

HP~S~

?. 60

DF020:

9.65 9. 9.80 9.30 9.40 9.50 9.60Time (Min)

1 0w64 ' 1S4

. d. Scan 266: 9.522 min.

; cr-7 ■yi 34 1 355

300 340 p60 ;>80

Rat: io

0 0

i :~.a e n zidine


Cl

1.0. then it is assumed that the peak is not zero is retorted.

.d5 9 7 2 h

680tailing and

XtiCGT b' J> 1/2030 08:43

Datafile Analyzed: /chem/5972hp64.1/DF020310A64.b/DF020310A64,d/DF020310A64.dod Usjed : /chem/5 972hp64 . i/DF020310A64 . b/'df tpp8270C . m/BrkDwnTF . m Inst: 5972h

ectionl Date: 10-MAR-2002 13:53 Operator:

fo: DFTPP DFTPP:2 319Sample In Mi sc Info

HP MS DP'j203l0H64.d. Ion Z'j5.00

Ion 235

.o.4j 10.65 10.66 10.71 10.74 10.: T i m.-r (Min)

10.bO 10.63 10.86 10.69 10.92 10.95 10. '48 11.01 11.04

HP Mb DP 020310wP,4 . a . Scsn 338: 10.74>j min.

105

r oun 4. U . / *4

Area Ka o

0 0

68

;DOr' ace

m

03,'ll/'2030 03:4:

Datafile thod U jection mple I sc Inf

Analyzed: /chem/5972hp64.1/DF020310A64.b/DF020310A64.d/DF020310A64

M:

;a : / chem/ 5 9 72hpS4 . i,/DF02 0 310A64 .b/'dftpp8270C. m/BrkDwnTF . m Date: 10-MAR-2002 13:53 Operator:

Inst :

nr o o :

DFTPP DFTPP:2 319

HP M5 DF02G3 1 0h64 . cJ. Ion 235.00

Ion 235

ii o. ■’ 3 10.11 10.14 10.17 10.70 10.23 10.26 10.29 10.32 10.35 10.38 10.41 10.44 10.47 10.50 1C

„ ,, - — T 1 me '• H 1 n ) _____._ _____ ________ __ _____________________HF m3 DF020310064 . d . 5c-an 309: 10.249 min.

318

34i; 36'.'

;• :-\;no3 0

a Ratio

100.00

681

i

i

.d5 9 7 2 h

.53

405

Dace: 03/11/2030 03:43Rerx

Datafile Analyzed: /chem/5972hp64.i/DF020310A64.b/DF020310A64.d/DF020310A64 thod Used: /chem/5972hp64.i/DF020310A64.b/dftpp8270C.m/BrkDwnTF.m Inst:mjection Date: 10-MAR-2002 13:53

Sample Info: DFTPP DFTPP:2319 Wise Inf'o:

Operator:

HP MS DF020310A64.a. Ion 246.00

Ion 246

l

10. o;

JoU: y./oy min,

281.

316 358

2d1.1 JdO

•-••ass

7 9 075 9

ea Ratio

D 6 10 0. 0 0

,d5 972h

10.05

4

400

68 j

— 0.5-

Compound: 4,4'-DDT

Quant Mass: 235

RT: 10.740

Area: 2311475

h F M 5

1 . 0-

10.30 10.70 10.

F \ m-? f, M i n '

DF020310OK4 4ji. Ion

10.00 ~*hF’"’Tb

F i mo •; M : f !>31 O^O- ,-c

iO.JO 10.50

Compound: 4,4'-DDD

Quant Mass: 235

RT: 10.249

Area: 19844

Compound: 4,4'-DDE

Quant Mass: 246

RT: 9.759

Area: 1256


TL

Compound j Response %Breakdown I Max Allowed!Test

,1*-£,4 - DDT j 2311475 i i N/A

4 ,4-DCjE i 12 5 6 | 0.1 | 20 . 0 PASS4 , 4-DD>D | 1 9 3 4 4 0.9 20 . 0 PASS4-DDD + DDE ; o r “i r. r | 0.9 20.0 PASS

. ZL CD CD■TIP + ★ * d ; .Qs"?: * * + DDT BREAKDOWN TEST 684

Data File: /chem/5972hp64. i/DF020311A64.b/DF020311A64.d Date : llj-MAR-2002 08:32

,Client ID: DFTPPI

Volume Injjected CuL>: 2,0


40 60 80 100 120 140 160 180 200 220 240 2m/z

60 280 300 320 340 360 380 400 420 440

X RELATIVE

m/e ION ABUNDANCE CRITERIA ABUNDANCE

I 198 Base Peak, 100# relative abundance 1 100*00 1

1 51 30*00 - 80*00# of mass 198 1 50.10 1

1 68 Less than 2*00# of mass 69 1 0.00 < 0.00) 1

1 6'? Hass 69 relative abundance 1 61.28 1

1 70 Less than 2*00# of mass 69 1 0.30 < 0.49) 1

1 127 25.00 - 75.00* of mass 198 1 43.64 1

1 l'?7 Less than 1*00# of mass 198 1 0,00 1

1 1?'? 5.00 - 9.00* of mass 193 1 6.75 !

1 10.00 - 30.00* of mass 193 1 20.20 1

1 Creater than 0.75# of mass 198 1 2.29 l

! 441 Present, but less than mass 443 1 10.15 i

1 442 40.00 - 110.00* of mass 193 1 69.71 1

9 1 447 15*00 - 24*00?* of mas ^ 442 1 13.23 < 18.97) 1

*

CD

CO

L.V


Date : llyMAR-2002 08:32

|Client ID: DFTPP



Volume Injected <uL); 2,0 Operator: 2070

Column phase J8.W DB5.625 Column diameter: 0,32

Data File; DF020311A64.d

Spectrum: Avg. Scans 184-186 < 8.16), Background Scan 181



I

i

m/z Y m/z Y m/z Y m/2 Y

11 1 1 1

1 36.00 19 116.00 339 1 180.00 1615 1 257.00 360 1

1 37.00 264 i 117.00 10172 1 181.00 817 1 258.00 1823 1

1 38.00 700 i 118.00 708 1 182.00 105 1 259.00 241 1

1 39*00 3419 119.00 256 1 184.00 2 1 265.00 911 1

1

1

41*00 . 111 120.00 96 1 185.00 1172 1 266.00 112 1

1 1

1 45.00 227 122.00 707 1 186.00 8443 1 271.00 68 1

1 49*00 273 i 123.00 1091 187.00 2392 273.00 959 1

1 50.00 10887 124.00 523 1 189.00 438 274.00 2771 1

1 51*00 39152 125.00 436 190.00 80 1 275.00 15786 1

I 52.00 2012 127.00 34104 191.00 309 276.00 2154

1 53.00 73 128.00 2683 192,00 832 277.00 1164 1

1 55.00 206 129.00 14904 193.00 860 278.00 174

1 56.00 1335 130.00 1282 1 194.00 201 1 281.00 174 1

1 57.00 2884 131.00 291 1 195.00 119 1 282.00 276 1

1 53.00 83 132.00 67 196.00 1931 283.00 300

.

1 61.00 497 133.00 48 1 198.00 78152 284.00 85 1

1 62*00 550 134.00 448 199.00 5273 285.00 181

1 63.00 1433 135.00 1050 200.00 363 1 293.00 258 1

1 64.00 207 136*00 450 1 201.00 325 296.00 4014 1

1 65 * 00 745 i 137.00 570 1 203.00 493 297.00 587 1

1

1 67.00 149 140.00 179 204.00 2182 303.00 468 1

1 69.00 4733S 141.00 1752 205.00 3813 1 304.00 126 1

I 70.00 233 1 142.00 600 1 206.00 15594 1 314.00 143 1

1 73.00 341 1 143.00 407 1 207.00 1982 315.00 393 1

1 74.00 3723 1 144.00 69 1 208,00 486 316.00 197 1

1

1 75.00 5943 1 145.00 75 1 209.00 183 321.00 105 1

l 76.00 1789 1 146.00 323 1 210.00 330 323.00 1294 1

1 77,00 34512 1 147.00 863 1 211.00 663 1 324.00 209 1

1 78.00 2134 1 148.00 2156 1 215.00 157 1 327.00 234 1

1 7':1.00 2631 1 149.00 453 1 216.00 337 1 328.00 103 1

1

1 SO. 00 1981 1 150.00 87 1 217.00 4447 l 332.00 81 1

1 31.00 271S 1 151.00 216 I 213.00 553 1 334.00 812 1

1 82.00 677 1 153.00 585 1 221.00 3835 1 335.00 185 1

1 33.00 593 1 154.0') 466 1 223.00 947 1 341.00 162 1

1 35.00 444 1 155.0') 872 1 224.00 8604 1 346.00 211 1

686


Date : ll-MAR-2002 08:32

Client ID: DFTPP



Column phase: J8.U DB5.625

Operator: 2070

Column diameter; 0.32



Spectrum; Avg. Scans 184-186 ( 8.16), Background Scan 181



m/z . Y m/z Y m/z Y m/z Y

11 1

1 86.00 888 156.00 1312 1 225.00 2157 1 352.00 331 1

l 87*00 394 157.00 286 227.00 3736 1 353.00 198 1

1 88.00 81 1 158.00 375 i 228.00 546 1 354.00 373 1

1 91.00 779 1 159,00 256 i 229.00 693 1 355,00 93 1

92.00 680 160.00 572 231.00 227 365.00 1790 1

93.00 4750 161.00 803 234.00 175 1 366.00 187 1

94.00 405 162.00 243 235.00 181 371.00 71 1

95*00 70 I- 163.00 71 236.00 135 372.00 663 1

96.00 263 165.00 761 237.00 218 373.00 153 1

98.00 3473 166.00 546 i 239.00 114 1 383.00 142 1

99.00 2503 167.00 3398 240.00 82 402.00 238

100*00 254 168.00 1764 i 241.00 165 403.00 431 1

101*00 1383 169.00 286 i 242.00 455 404.00 132 1

103.00 558 170.00 86 i 243.00 465 421.00 297 1

104.00 905 171.00 86 244.00 7050 1 422.00 263 1

1

105.00 882 172.00 295 245.00 913 423.00 2853 1

107.00 10174 1 173.00 350 246.00 1180 424.00 552 1

103.00 1584 174.00 675 247.00 186 1 441.00 7934 1

110.00 21536 175.00 1165 249.00 282 1 442.00 54480 1

111.00 3093 176.00 393 i 253.00 218 1 443.00 10337 1

1 1 1

112.00 372 177.00 786 1 255.00 32256 1 444.00 962 1

113.00 75 1 179.00 2708 ! 256.00 4692 1 1

68/'

(xlO)


Date : ll-MAR-2002 08:32

Client ID: DFTPP


Volume Injected (uL): 2*0

Column phase: J&W DB5.625----------------- " /chem/5972hp64. i /DF020311A64. b/DF020311A64. d

3.0-1

2,9-j

2.8-j

2.7-j

2.6-j


Operator: 2070


2.5- :2.4- j

2.3- j

2.2- j

2.1-:

2.0-; i.9-i

1.8-j

1.7-j

1.6- 11.5- j

1.4- ;

1.3- ;

s:a.

rtO.C

T) C <b

. .C C_

5 5*7 6.0 6*3 6*6 6.9 7.2 7.5 7*8 8.1 3*4 8.7 9.9 10.2 10*5 10.3 11.1 11.4 11.7 12.0 12.

:oooCO

5 1

I TAILING FACTOR and DEGRADATION SUMMARY RESULTS

>nm


| Base Peak Other |Test|Abundance Criteria


127 2 5 - 75% of mass 198 43.64 PASS197 0 - 1% of mass 198 0.00 PASS199 5 - 9% of mass 198 6.75 PASS275 1 0 - 30% of mass 198 20.20 PASS365 Greater than 0.75% of mass 198 2.29 PASS441 Present, but less than mass 443 10.15 ( 76.75) PASS442 4 0 - 110 % of mass 198 69.71 PASS443 1 5 - 24% of mass 442 13.23 ( 18.97) PASS



Pentachllorophenol 0.6 5.0 PASSBenzidine

i0.7 3.0 PASS

DDt| DEGRADATION BREAKDOWN ANALYSIS SUMMARY


4,4-DDT 1050204 N/A4,4-DDE 1721 0.2 20.0 PASS4,4 -DDD 9898 0.9 20.0 PASS

4,4-DDD + DDE1

11619 1.1 20.0 PASS

+


PASSED

68


ort Date : 03/11/2030 09:27

Datafile Analyzed: /chem/5 972hp64.i/DF02 0311A64.b/DF02 0311A64.d/DF020311A64.d Method Used: /chem/5972hp64.i/DF020311A64.b/dftpp8270C.m Inst: 5972hp64 Injection Date: ll-MAR-2002 08:32 Operator: 2070Sample Info: DFTPP DFTPP:2070 Misc Info:

690

Report Date: 03/11/2030 09:27

Datafile■Analyzed: /chem/5972hp64.i/DF020311A64.b/DF020311A64.d/DF020311A64.d^fcthod Used: /chem/5972hp64.i/DF020311A64.b/dftpp8270C.m Inst: 5972hp64^Jrjection Date: ll-MAR-2002 08:32 Operator: 2070

Sample Info: DFTPP DFTPP:2070Misc Info:

Report Date: 03/11/2030 09:27

Datafile

m

Analyzed: /chem/5972hp64.i/DF020311A64.b/DF020311A64.d/DF020311A64.d.thod Used: /chem/5972hp64.i/DF020311A64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972hection Date: ll-MAR-2002 08

DFTPP DFTPP:207032

Tample Info Misc Info:

Operator:

Exp. RT Found RT

Mass

266

7.8307.804

Area

42191

Ratio

100.00

Tailing factor for

filing Factor = 0

If Tailing Factor a Tailing Factor

Pentachlorophenol OK

.6 Maximum Allowed = 5.0

< 1.0, then it is assumed that the peak is not ta^^L'rig and of zero is reported.

Report Date: 03/11/2030 09:27

Exp. RT = 9.550Found RT = 9.512

Mass Area Ratio

184 454615 100.00

Tailing

i ling

factor

Factor

for Benzidine OK

= 0.7 Maximum Allowed 3.0

If Tailjing Factor < 1.0, then it is assumed that the peak is not t^Qlijng and

a Tailing Factor of zero is reported.

Report Date: 03/11/2030 09:27

Datafile Analyzed: /chem/5972hp64.i/DF020311A64.b/DF020311A64.d/DF020311A64.d

•thod Used: /chem/5972hp64 . i/DF020311A64 . b/df tpp8270C . m/BrkDwnTF . m Inst: 5972h jection Date: ll-MAR-2002 08:32 Operator:


Found RT

M ass

2 3 F

10.729

Area Ratio

1050204 100.00

694

Report Date: 03/11/2030 09:27

Datafile! Analyzed: /chem/5 972hp64.i/DF020311A64.b/DF02 0311A64.d/DF020311A64.dJfcthod Used: /chem/5972hp64.i/DF020311A64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972hWPjection Date: ll-MAR-2002 08:32 Operator:

Sample Info: DFTPP DFTPP:2070Misc Irif'o:

4,4'-DDDi

Exp. Rif Found RT

Mass

235

10.28010.239

Area Ratio.

9898 ' 100.00

6 9 b

«taf ile : Analyzed: /chem/5972hp64 .i/DF020311A64.b/DF020311A64.d/DF020311A64.dkhod Used: /chem/5972hp64.i/DF020311A64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h

section Date: ll-MAR-2002 08:32 Operator:Sample Info: DFTPP DFTPP:2070 Misc Info:

Report Date: 03/11/2030 09:27

Exp. RT, = 9.790Found RT| = 9.748

Mass

246

Area Ratio

1721 100.00

69b

9.50 9.80 9.70 9.80 9.90 10.00l| T i me- < M1 n )

Compound: 4,4'-DDT

Quant Mass: 235 RT: 10.729Area: 1050204

Compound: 4,4'-DDD


Compound: 4,4'-DDE

Quant Mass: 246

RT: 9.748Area: 1721



4.4- DDT4.4- DDE

10502041721 0.2 20.0

N/APASS

4,4-DDD 9898 0.9 20.0 PASS4,4-DDD + DDE 11619 1.1 20.0 PASS

TUNE SAMPLE *** PASSED *** DDT BREAKDOWN TEST 69 7

Data Filet .'chem/5972hp64.i/DF020311B64.b/DF020311B64.d Date : 1i|mAR-2002 22:30

.Client ID: DFTPP


Volume Injected CuL>: 2.0

Instrument; 5972hpfe4.i

Operator: 2319

Column phase: J&W DB5.625 Column diameter: 0.32

Data File: /chem/5972hp64.i/DF020311B64.b/DF020311B64.d

Date t lljMAR-2002 22:30



Volume Injected <uL)r 2.0 Operator: 2319

Column phase: J&U DB5.625 Column diameter: 0.32

]| Data File: DF020311B64.d

Spectrum: Aug, Scans 184-186 < 8.16), Background Scan 182

Location of Maximum; 198.00

I Number of points: 259


11 1 1

1 37.00 502 1 122.00 1510 i 189.00 1085 i 275.00 29688 1

1 38.00 1360 i 123.00 2234 i 190.00 224 i 276.00 4034 i

1 39.00 6449 1 124.00 1180 i 191.00 445 i 277.00 2518 i

1 45.00 96 i 125.00 795 i 192.00 1701 i 278.00 396 i

1 49*00 535 l 127.00 66784 i 193.00 1559 i 281.00 186 i

11 1 1 1

1 50.00 21216 1 128.00 5315 1 194.00 387 i 282.00 12 i

1 51*00 74752 1 129.00 29880 1 196.00 3725 283.00 491 1

1 52.00 3731 130.00 2593 198.00 147520 i 284.00 202 i

1 53 * 00 132 131.00 508 199.00 10148 285.00 436 1

1 56,00 2089 132.00 88 i 200.00 674 292.00 75 i

11

1 57.00 4961 133.00 140 201.00 622 i 293.00 381 i

1 60*00 72 134.00 877 203,00 977 i 294.00 223 i

1 61*00 1042 135.00 2023 i 204.00 4192 i 296.00 8180 i

1 62.00 1144 136.00 980 205,00 7521 297.00 1176 i

1

1

63,00 2923 137.00 1177 206.00 29680 i 301.00 67 i

1 64*00 425 138.00 273 207.00 4023 i 302.00 104

1 65.00 1253 139.00 182 208.00 1056 i 303.00 940 i

1 68.00 53 i 140.00 405 209.00 321 304.00 252 i

1 69.00 90392 141.00 3391 210.00 368 i 308.00 226 i

1

1

70,00 138 142.00 1238 211.00 1331 i 309.00 67 i

1 1

1 72,00 7 143.00 788 1 213.00 70 i 310.00 93 i

1 73.00 645 1 144.00 13? 1 215.00 355 1 314.00 385 i

1 --J o o 7096 1 145.00 228 l 217.00 8722 1 315.00 902 i

75.00 11014 i 146.00 800 i 218.00 1092 i 316.00 456 i

76.00 3295 1 147.00 1684 1 221.00 6651 t 321.00 283 i

1 1 1 1

1 77*00 65360 i 148.00 4408 1 223.00 1874 f 323.00 2608 i

1 78 * 00 4429 1 149.00 469 1 224.00 16324 i 324.00 450 i

1 79,00 5114 1 150.00 294 1 225.00 4236 1 327.00 554 1

80.00 3475 1 151.00 367 1 227.00 7460 i 328.00 295 i

81,00 4780 1 152.00 307 1 228.00 1020 1 332.00 160 !

1 1 1 1

32.00 1125 1 153.00 1099 1 229.00 1404 i 333.00 195 1

S3,00 90S l 154.00 875 1 230.00 216 1 334.00 1625 1

84.00 12 1 155.00 1814 1 231.00 578 1 335.00 424 1

85.00 477 1 156.00 . 2430 1 233.00 74 1 341.00 373 i

86,00 1430 1 157.00 537 1 234.00 444 1 342.00 83 1

Data File: /chem/5972hp64, i /DF020311B64. b/DF020311B64, d

Date : ll-MAR-2002 22:30

kClient ID: DFTPP

^Sample Info: DFTPP:2319




Operator: 2319



SpectrumJ Avg* Scans 184-186 < 8.16), Background Scan 182



m/z Y m/z Y m/z Y

1

m/z Y

1+ 1 1

1 87.00 888 1 158.00 573 1 235.00 469 1 346.00 599 1

1 88.00 302 1 159.00 506 1 236.00 354 1 347.00 82 1

1 89.00 190 1 160.00 1004 1 237.00 538 1 352.00 781 1

1 91.00 1062 1 161.00 1529 1 239.00 308 1 353.00 522 1

1 92*00 1174 1 162*00 415 1 240.00 212 1 354.00 817 1

*+ + 1 1

i 93.00 9544 1 163.00 197 1 241.00 390 1 355.00 136 1

1 94*00 438 1 164.00 212 1 242.00 887 1 365.00 3425 1

1 95.00 33 1 165.00 1214 243.00 978 1 366.00 500 1

1 96*00 238 1 166.00 1022 1 244.00 13619 1 371.00 162 1

1 98.00 7102 1 167.00 6946 245.00 1843 1 372.00 1437 1

** *

1 99*00 5037 1 168.00 3382 246.00 2541 373,00 403 1

1 100 * 00 491 1.169.00 561 247.00 533 383.00 371 1

l 101.00 2800 1 170.00 243 248.00 69 1 384.00 92 1

1 102.00 103 1 171.00 268 1 249.00 560 1 390.00 161 1

1

+

103.00 1040 1 172.00

1

625 251.00 150 1 391.00 105 1

*

I 104.00 1802 1 173.00 721 252.00 153 392.00 69 1

1 105.00 1718 1 174.00 1351 253.00 337 1 402.00 571 1

1 106.00 88 1 175.00 2370 255.00 62976 1 403.00 856 1

1 107.00 20528 1 176.00 894 1 256.00 9235 1 404.00 239 1

1 108.00 3282 1 177.00 1206 1 257.00 678 1 421.00 726 1

1

1 110.00 41904 1 178.00 326 253.00 3770 1 422.00 644 1

1 111.00 6063 1 179.00 5245 1 259.00 607 1 423.00 5603 1

1 112.00 573 1 180.00 3253 1 261.00 67 1 424.00 1075 1

l 113.00 310 1 181.00 1624 1 264.00 87 1 425.00 69 1

1 115.00 218 1 182.00 290 1 265,00 1669 1 441.00 15234 1

. .1

1 117.00 20568 1 183.00 189 1 266.00 279 1 442.00 104120 1

1 118,00 1520 1 184.00 298 1 271.00 151 1 443.00 20504 1

1 119.00 130 1 135.00 2263 1 272.00 96 1 444.00 1912 1

1 120.00 322 1 186.00 16220 1 273.00 2047 I 445.00 83 1

1 121.00 125 1 187.00 4608 I 274.00 5248 1

_____ znu____

<xi<r6>

Data File; /-chem/5972h|o64.i/DF020311B64.b/DF020311B64.d



tffen| j Abundance Criteria | Base Peak Other |Test|


127 25 - 75% of mass 198 45.26 PASS197 6 - 1% of mass 198 0.00 PASS199 5 - 9% of mass 198 6.88 PASS275 10 - 30% of mass 198 20.12 PASS365 Greater than 0.75% of mass 198 2.32 PASS441 Present, but less than mass 443 10.32 ( 74.28) PASS442 40 - 110 % of mass 198 70.57 PASS443 15 - 24% of mass 442

ii13.90 ( 19.70) PASS



Pentachlorophenol 2 . 1 5.0 PASSBenzidine

■i0 . 0 3.0 PASS



^ 4,4-DDT2067201 N/A

4,4 -DDE 3857 0.2 20.0 PASS4,4 -DDD 17219 0.8 20.0 PASS

4,4-DDD + DDE 21076 1.0 20.0 PASS

Tuning Sample, /chem/5972hp64.i/DF020311B64.b/DF020311B64.d/DF020311B64.d

*** PASSED ***

7 Oi


ort Date : 03/11/2030 23:29

Datafile.Analyzed: /chem/5972hp64.i/DF020311B64.b/DF020311B64.d/DF020311B64.d Method Used: /chem/5972hp64.i/DF020311B64.b/dftpp8270C.m Inst: 5972hp64 Injection Date: ll-MAR-2002 22:30 Operator: 2319Sample Info: DFTPP DFTPP:2319 Misc Info:

703

Report Date: 03/11/2030 23:29

Jection Date: ll-MAR-2002 22:30 Operator: 2319


Datafile 'Analyzed: /chem/5972hp64.i/DF020311B64.b/DF020311B64.d/DF020311B64.dkhod Used: /chem/5972hp64.i/DF020311B64.b/dftpp8270C.m Inst: 5972hp64


127 25 - 75% of mass 198 45.26 PASS197 0 - 1% of mass 198 0.00 PASS199 5- 9% of mass 198 6.88 PASS275 id - 30% of mass 198 20.12 PASS^6 5 Greater than 0.75% of mass 198 2.32 PASSm Present, but less than mass 443 10.32 ( 74.28) PASSW4 2 40 - 110% of mass 198 70.57 PASS44 3 15; - 24% of mass 442 13.90 ( 19.70)

Report Date: 03/11/2030 23:29

Datafile|Analyzed: /chem/5972hp64.i/DF020311B64.b/DF020311B64.d/DF020311B64.d J^ihod Used: /chem/5972hp64.i/DF020311B64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h ^Hjjection Date: ll-MAR-2002 22:30 Operator:


Pentachlorophenol

Exp. RT Found RTl

7.830 7.803

Mass Area Ratio

266 93234 100.00

Tailing

fil ing

factor

Factor

for Pentachlorophenol OK

= 2.1 Maximum Allowed 5.0

70 j

Report Date: 03/11/2030 23:29

Datafile;Analyzed: /chem/5972hp64.i/DF020311B64.b/DF020311B64.d/DF020311B64.d

• hod Used: /chem/5972hp64.i/DF020311B64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972hection Date: ll-MAR-2002 22:30 Operator:


Exp. RT i = 9.5 50Found RT 1 = 9.527

Mass Area Ratio

184 ( 924932 100.00

Tailing factor for Benzidine OK

ling Factor = 0.0 Maximum Allowed = 3.070ou

If Tailing Factor < 1.0, then it is assumed that the peak is not tailing and a Tailing Factor of zero is reported.

Report Date: 03/11/2030 23:29

^^jection Date: ll-MAR-2002 22:30 Operator:


Datafile|Analyzed: /chem/5972hp64.i/DF020311B64.b/DF020311B64.d/DF020311B64.dhod Used: /chem/5972hp64 . i/DF02 0311B64 . b/df tpp8270C . m/BrkDwnTF. m Inst: 5972h

Found RT = 10.744

Mass Area Ratio

235 1 2067201 100.00

Datafile[Analyzed: /chem/5972hp64.i/DF020311B64.b/DF020311B64.d/DF020311B64.d Jfcthod Used: /chem/5972hp64.i/DF020311B64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h ^Hectiori Date: ll-MAR-2002 22:30 Operator:


Report Date: 03/11/2030 23:29

i . l-

1.0-

0.9-

0.8-

0.7-

0.6- 0.5-

0.4-

0.3-

0.2-

0.1-

0.0-

HP MS DF020311B64.d. Ion 235.00

Ion 235

9.96 9.99 10.02 10.05 10.00 10.11 10.14 10.17 10.20 10.23 10.26 10.29 10.32 10.35 10.38 10.41 10.44 10.47 10.50 10.53____________________________________________ ___Time (Min)

1 • It

: .0-

ro.9-;

0.8-

0.7-

0.6-;

ly 0.5-

56"'HP MS DF020311B64.d. Scan 309: 10.254 min.

i i

il0.4-

0.3-' ii

l j0.2- I;

0.1- o.o- ■l!'1

40

■•129 207 205..

165

IliU.i! !

jil.. . I,

■105

I.

. 235

/297340,

-355 405\

60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400___________________m/z_____________________________________________________

4,4'-DDD

Exp. RT = 10.280Found RT = 10.254

Mass Area Ratio

235 17219 100.00

70S

Report Date: 03/11/2030 23:29

^Jgection Date: ll-MAR-2002 22:30 Operator:


Datafile 1 Analyzed: /chem/5972hp64.i/DF020311B64.b/DF020311B64.d/DF02 0311B64.d^jfchod Used: /chem/5972hp64.i/DF020311B64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h

Found RT

Mass

246

9.764

Area

3 8 57

Rat io

100.00

70

0.6-M , 4 -

9.50 9.00 9.^0 9. SO 9.90 10.00T ijn? ( M i n ) _____ __________

Compound: 4,4'-DDT

Quant Mass: 235

RT: 10.744Area: 2067201

Compound: 4,4'-DDD


Compound: 4,4'-DDE

Quant Mass: 246 RT: 9.764

Area: 3857

J

i

DDT!DEGRADATION BREAKDOWN ANALYSIS SUMMARY

Compoundi

Response %Breakdown Max Allowed|Test

4,4 - DDT 2067201 N/A4,4 - DDE 3857 0.2 20.0 PASS4,4 - DDD 17219 0.8 20.0 PASS4,4-DDD + DDE 21076 1.0 20.0 PASS

TUNE SAMPLE *** PASSED *** DDT BREAKDOWN TEST71G

Data File; /'chem/'5972hp64 +i/DF020313A64.b/DF020313A64.d

Date ; 13-MAR-2002 09:32

Client ID: DFTPP


i|Volume Injected (uL); 2.0

Column phase: J&l-I DB5.625

1 Decaflucrotriphenylphosphine


Operator: 917


1.5

1.4

' 1.3

1.2

1.1

1.0

0.9-

0.8-

0.7-

0.6-

0.5

|o.4

0.3

0.2

0.1

0.0-

Avg. Scans 184-186 < 8.15), Background Scan 181 19&^

■N

/77 127\

167\

<j.l . .11 IlLv.i JLni I.. i./i Li, I

44;N

■255

/224

I.. i.ll I .1. ..I!

29:N,323 365\

( | N |L ..k .. .,11 ,Lu ..I . I. II. Ii ..l .. .Ik iJl.

40 60 80 100 120 140 160 180 200 220 240 260m/z

280 300 320 340 360 380 400 420 440

1 RELATIVE

nr/t* ION ABUNDANCE CRITERIA ABUNDANCE

1 198 1 Base Peak, 100X relative abundance 1 100.00

1 51 1 30.00 - 80.001 of mass 198 1 49.46

CO 1 Less than 2.OCX of mass 69 1 0.00 < 0,00) 1

1 69 1 Hass 69 relative abundance 1 60.72 1

1 70 1 Less than 2.00X of mass 69 1 0.26 < 0.43) 1

1 127 1 25.00 - 75.001 of mass 198 1 42.36 1

1 197 1 Less than 1.00X of mass 198 1 0.00 1

1 199 1 5.00 - 9.00X of mass 198 6.94 1

1 275 1 10.00 - 30.00X of mass 198 1 22.78 1

1 365 1 Greater than 0.75X of mass 193 1 2.99 1

1 441 1 Present, but less than mass 443 ! 13.68 1

1 442 1 40.00 _ 110,OCX of mass 193 i 91.28 1

1 443

*

1 15.00 - 24.00X of mass 442

*

1 17.94 < 19.65)

* *

■ 711

Data File /chem/5972hp64 * i /DF020313A64 * b/DF0203l3A64.d

Date : ll3-MAR-2002 09:32

Client ID DFTPP Instrument: 5972hp64.i


Volume Injected CuL): 2*0 Operator: 917

Column phase: J&W DB5.625 Column diameter: 0.32


Spectrum: Avg. Scans 184-186 < 8.15), Background Scan 181



m/z Y n/z Y m/'z Y n/z Y

*

1 37*00 481 124.00 1112 1 188.00 10618 282.00 72

1 38*00 1478 125.00 858 1 200.00 744 283.00 483

1 38.00 7087 127.00 64784 1 201*00 611 284.00 224

1 40.00 273 128.00 5187 1 203.00 1057 285.00 536

1 41.00 173 128.00 30864 1 204.00 4868 1 288.00 105

+ + +

1 44.00 78 130.00 2604 1 205.00 8188 1 290.00 74

1 45.00 274 1 131.00 515 1 206.00 33136 1 282.00 88

1 48.00 762 1 132.00 268 1 207.00 4443 1 283.00 646

1 50.00 22048 1 133.00 81 1 208.00 1186 1 284.00 142

1 51.00 75640 1

*

134.00 881 1 209.00 371 1 286.00 10054

1 *

1 52.00 3832 1 135.00 2211 1 210.00 388 1 287.00 1386

53.00 222 1 136.00 818 1 211.00 1425 1 288.00 81

55.00 478 1 137.00 1055 1 212.00 115 1 301.00 87

56.00 2574 1 138.00 232 1 213.00 68 1 302.00 138

57.00 5321 i 138.00 170 1 215.00 384 1 303.00 1040

*

58.00 266 1 140.00 354 1 216.00 278 1 304.00 314

1 59.00 88 1 141,00 3722 1 217.00 8855 1 308.00 126

1 61.00 1033 1 142.00 1208 1 218.00 1180 1 308.00 81

1 62.00 1144 I 143.00 805 1 218.00 78 1 310.00 88

1 Uy w o o 2S23 1 144.00 256 ! 221.00 6853 1 313.00 88

1

1 64.00 401 1 145.00 217 223.00 2226 1 314.00 438

1 65.00 1239 1 146.00 689 224.00 18848 1 315.00 1138

1 66. C»o 178 1 147.00 2026 225.00 4716 1 316.00 572

1 67.00 111 1 148.00 5187 227.00 8778 1 317.00 88

1 69.00 92S72 1 149.00 886 228.00 1166 1 321.00 242

1 *

1 70.00 400 1 150.00 260 229.00 1732 1 323.00 3288

1 73.00 518 1 151.00 471 230.00 240 1 324.00 583

1 74.00 7478 1 152.00 254 231.00 601 1 325.00 78

1 75.00 11266 1 153.00 1187 232.00 85 1 327.00 686

1 76.00 3662 1 154.00 812 233.00 88 1 328.00 284

r„-i 63696 1 155.0>) 1828

78.00 4347 1 156.00 2734

79.00 5567 I 157.00 494

80.00 3717 ,1 158.00 711

31.00 5093 !1 159.0':* 482

234.00 548 1 328.00 71

235.00 563 1 332.00 275

236.00 388 1 333.00 214

237.00 583 t 334.00 2007

233.00 68 1 335.00 501

■ 71c

Data File: /chem/5972hpiS4.

Date : 13-MAR-2002 09:32

Client ID: DFTPP

i/DF020313A64.b/DF020313A64 *d



Volume Injected CuL): 2*0

Column phase: J&W DBS,625

Operator: 917


i

I

i

Data File: DF020313A64,d

Spectrum: Avg. Scans 184-186 < 8,15), Background Scan 181

Location of Maximum: 198,00



1 +

1 S2.00 1321 1 160.00 1201 1 239.00 323 1 341.00 383 1

1 83.00 1053 1 161.00 1664 1 240.00 244 1 342.00 104 1

1 84,00 153 1 162.00 512 1 241.00 453 1 346.00 698 1

1 85.00 925 1 163.00 214 1 242.00 999 1 347.00 103 1

1 86,00 1743 1 164,00 203 1 243.00 1066 1 352.00 928 1

1 87.00 657 1 165.00 1577 1 244.00 15672 1 353.00 611 1

1 88.00 307 1 166.00 1108 1 245.00 2006 1 354.00 986 1

1 89.00 170 1 167.00 7649 1 246.00 3019 1 355.00 265 l

1 91.00 1174 1 168.00 3682 1 247.00 598 1 365.00 4570 1

1 92.00 1375 1 169.00 669 1 248.00 95 1 366.00 543 1

*+ * * *

1 93.00 10780 1 170.00 240 1 249.00 556 1 370.00 72 1

1 94,00 495 1 171.00 297 1 250.00 103 1 371.00 223 1

1 95.00 254 I 172.00 638 1 251.00 117 1 372.00 1873 1

1 96.00 309 1 173.00 827 1 252.00 133 1 373.00 338 1

1 98.00 8168 t 174.00 1444 1 253.00

1

361 1 383.00 374 r

*1 *

1 99.00 5134 1 175.00 2544 1 255.00 72152 1 384.00 133 1

1 100.00 479 1 176.00 753 1 256.00 10740 1 390.00 213 i

1 101.00 2711 1 177.00 1471 1 257.00 840 1 391.00 155 1

1 102.00 219 1 178.00 253 1 258.00 4496 1 392.00 101 i

I 103.00 1029 1 179.00 5802 1 259.00 709 1 401.00 86 i

*+ * 1 *

1 104.00 1926 1 180.00 3425 1 260.00 88 1 402.00 676 1

i 105,00 1865 1 181.00 1728 1 261.00 111 1 403.00 1035 1

1 107.00 21712 ! 182.00 280 1 264.00 134 1 404.00 310 1

I 108.00 3143 1 183.00 158 1 265.00 2009 1 421.00 932 i

I 110.00 40S24 1

*

184.00 248 I 266.00 239 1 422.00 896 1

* 1 *

1 111.00 6164 1 185.00 2583 1 267.00 162 1 423.00 7515 1

! 112.00 835 1 186.00 18600 1 270.00 93 1 424.00 1416 1

I 113.00 271 1 137.00 5099 1 271.00 134 1 425.00 118 1

1 115.00 177. 1 189.00 1259 I 273.00 2198 1 441,00 20912 1

1 117.00 23984 1 190.00 228 1 274.00 6197 1 442.00 139584 1

1

1 118.00 1618 1 191.00 698 1 275.00 34840 1 443.00 27432 1

1 119.00 262 1 192.00 1819 1 276.00 4769 1 444.00 2567 1

1 120.00 250 1 193.00 1813 1 277.00 3196 1 445.00 115 1

' 121.00 83 1 194.00 410 1 273.00 571 1 I

; 122.00 1572 1 196.00 4025 1 279.00 86 1 i

i

■ 71 o

Data File: /chem/5972hp64.i/DF020313A64.b/DF020313At.4.d

Date : 13-MAR-2002 09:32

Client ID: DFTPPl|


Volume Injected iuLi: 2.0

Column phase: J8.U DB5.625


Operator: 917


o

Data File: DF020313A64*d

Spectrum: Avg* Scans 184-186 ( 8*15), Background Scan 181



m/z m/z m/z m/z

I 123*00 2372 I 198*00 152896 I 281*00 86 I

■ 714

(xlO)


Volume Injected <uL): 2.0 Operator: 917

Column phase: J8.W DB5.625 Column diameter: 0.32

Data File: /chem/5972hp64. i/'BF020313A64.b/,DF020313A64.d

Date : 13-MAR-2002 09:32

Client ID: DFTPP Instrument: 5972hp64.i -O —1 h~-

13.5 13.8



►"nAbundance Criteria Base Peak Other Test |

198 Base Peak, 100% relative abundance 100.00 PASS51 30 - 80% of mass 198 49.46 PASS68 Less than 2% of mass 69 0.00 ( 0.00) PASS69 Mass 69 relative abundance 60.72 PASS

70 Less than 2% of mass 69 0.26 ( 0.43) PASS

127 25 - 75% of mass 198 42.36 PASS197 1 0 - 1% of mass 198 0.00 PASS199 5 - 9% of mass 198 6.94 PASS275 10 - 30% of mass 198 22.78 PASS365 Greater than 0.75% of mass 198 2.99 PASS441 Present, but less than mass 443 13.68 ( 76.25) PASS442 40 - 110 % of mass 198 91.28 PASS443 15 - 24% of mass 442 17.94 ( 19.65) PASS


#:

Compound |Tail Factor | Max Allowed | Test

Pentachilorophenol 0.0 5.0 PASSBenzidine

,i0.5 3.0 PASS


^ CompoundResponse %Breakdown Max Allowed Test

4,4-DDT 2411404 N/A4,4-DDE 2329 0.1 ■20.0 PASS4,4- D.DD 21021 0.9 20.0 PASS

4,4-DDD + DDE 23350 1.0 20.0 PASS

Tuning S ample, /chem/5972hp64.i/DFO20313A64.b/DF020313A64.d/DF020313A64.d

PASSED

71b

I


port Date : 03/13/2030 10:34

Datafile Analyzed: /chem/5972hp64.i/DF020313A64.b/DF020313A64.d/DF020313A64.d Method Used: /chem/5972hp64.i/DF020313A64.b/dftpp8270C.m Inst: 5972hp64Injection Date: 13-MAR-2002 09:32 Operator: 917Sample Ijnfo: DFTPP DFTPP:917 Misc Info:

iI

• 711

iO

Report Date: 03/:.3/2030 10:34

atafile Analyzed: /chem/5972hp64.i/DF020313A64.b/DF020313A64.d/DF020313A64.d thod Used: /chem/5972hp64.i/DF020313A64.b/dftpp8270C.m Inst: 5972hp64

bisection Date: 13-MAR-2002 09:32 Operator: 917Sample Info: DFTPP DFTPP:917 Misc Info:

6. * *4-.

6.0' 5.b:

5.2-'

4.0-

4.4-

4.0- '

3.6-

HP MS DF0203i3Ab‘4.d

2.8-2.4-

2.0- 1.6-1.2-

0.8- 0.4-

/ \

_L2_CS 8.0 8.1 8.2

T imp (Min?_______8.3 8.4 8.5 8.6

HP MS DF020313A64.d. Scan 185: 8.151 nun.442-0

. 6-

il:::

9 9.

2.0- 1.8-

1 .6-

1 .4-

1-0.

0.6-0.6-0.4-

69

'51

136

; 148

40 60 SO 100 1J

• 198

255.

275.

,296■ 323 .365

403,

140 160 100 200 220 240 260 280 300 320 340 360 380 400 420

1440

I Ion

DECAFLUOROTRIPHENYLPHOSPHINE Ion Abundance/Ratio Criteria

| Abundance Criteria I Base Peak Other

198 51 686970

127 19 7199 275

.6 5 1

4 4 2 44 3

Base Peak, 100% relative abundance 30 - 80% of mass 198

Less than 2% of mass 69 Mass 69 relative abundanceLess than y '■ of mass 692505

id

75% of mass 1981% of mass 198 9% of mass 198

30% of mass 198 Greacer chan 0.75% of mass 198 Present, but less than mass 443 40 - 110% of mass 198 15 - 24% of mass 442

100.00 49.46 0.00

60.72 0.26

42.36 0.00 6.94

22.78 2 . 99

13 . 68 91.28 17.94

( 0.00)

( 0.43)

76.25)

19.65)

Report Date: 03/13/2030 10:34

atafile Analyzed: /chem/5972hp64.1/DF020313A64.b/DF020313A64.d/DF020313A64.d fethod Used: /chem/5972hp64.i/DF020313A64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h

rijection Date: 13-MAR-2002 09:32 Operator:Sample Info: DFTPP DFTPP:917 Misc Info:

5.4-

5.1:

4.6-

4.5- ;

•4.2-

3.9-

3.6-

3.3-

3.0-

2.4-

2.1- i .b-;

1.5T

1.2- 0.9-

0.6- 0.3-

0.0- -

HP M5 DF020313A64.d. Ion 266.00

Ion 266

Tailing Factor .'= jp . 00000

.50 .55 7.60 7.65 70 7.75 7.80 7.85Time (Min)

7.90 .95 8.00 3.05 8.10

4.8

4.5

4.23.9

3.6

3.3

3.0

2.7

2.4-

2.1-1.8

1.5-

1.2- 0.9-

0.6- 0.3-

0.0-7

HP MS DF0203l3A64x£jl, Ion 266.00

CD

.50 7.60 7.70 7.80Time (Min)

7.90 8.00 9.10

HP MS DF020313A64.d. Scan 164: 7.796 min.

4.5- '"•266

3.9-

3.6-

3.3-

3.0-

2.1- 1 .3-

1 .5-

1 .2 0.9-

9.6-

165

; i 202.95

130i ,

60

•

3’ 118 i. I

169

.... ii20?

111,!.'

90 100 120 140 160 180

________ ____________ ______ m/z______________ ___200

,-730

I. M. 11 I .

220 240

Pentachlorophenol

I!

260

281

280

Exp. RT| Found RT

Mass

7.8307.796

Area Ratio

266 , S8740 100.00

I^^iling factor for Pentachlorophenol OK

^R_ling Factor = 0.0 Maximum Allowed = 5.0

If Tailing Factor < 1.0, then it is assumed that the peak is not t'ail4iVg and a Tailing Factor of zero is reported.

Report Date: 03/13/2030 10:34

ga^aWn

ataf ile Analyzed: /chem/5 972hp64.i/DF02 0313A64.b/DF02 0313A64.d/DF020313A64.d thod Used: /chem/5972hp64.1/DF020313A64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h

njection Date: 13-MAR-2002 09:32 Operator:Sample Info: DFTPP DFTPP:917 Misc Info:

Benzidine

Exp. RT:| =

Found RT =9.550 9.502

Mass | Area Ratio

184 1026092 100.00

•iling 'factor for Benzidine OK

iling Factor = 0.5 Maximum Allowed = 3.0

If Tailing Factor < 1.0, then it is assumed that the peak is not ’tZi2.iLng and

a Tailing Factor of zero is reported.

Report Date: 03/13/2030 10:34

tafile1 Analyzed: /chem/5972hp64.i/DF020313A64.b/DF020313A64.d/DF020313A64.dthod Used: /chem/5972hp64.i/DF020313A64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h


HP MS DF020313A64.d. Ion 235.00

1.4-;i .3-:

i.i-

1.0- 0.9'

0.8- 0.7-

0.6- 0.5-

0 4-

0.3

Ion 235o

0.1-

0.0--

r-1.0-'

0.9-

0.8-

0.7-

0.6-

0.5-

0.4-

0.3-

10.4- 10.47 10.50 10.53 10.56 10.59 10.62 10.65 10.68 10.71 10.74 10.77 10.80 10.83 10.86 10.89 10.92 10.95 10.98 11.01 1 Time (Min)I HP MS DF020313A64.d. Scan 337: 10.710 min.

235-",

165

199

,50

4,4'-DDT

Exp. RT Found RT

248 319 354.

30 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380

.405)29

400 420

10.770 10.718

Mass

235

Area Ratio

2411404 100.00

Report Date: 03/13/2030 10:34

Datafil'e Analyzed: /chem/5972hp64 . i/DF020313A64 . b/DF02 0313A64 . d/DF02 0313A64 . d Method Used: /chem/5972hp64.i/DF020313A64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972b

Injection Dace: 13-MAR-2002 09:32 Operator:Sample :Info: DFTPP DFTPP:917 Misc Info:

i .4-

1.3-

1.2-

1.1-

1 - 0-

0.9-£ 0.8-' ;2 0.7-

■ ~ 0.6-

0.5-

0.4-

0.3-

0.2-

0.1 -

0.0 - —

Ion 235

HP MS DF020313A64.d. Ion 235.00

,/\

I \

1 \

9 . ?:• '9 9A 9.99 10.02 10.05 10.08 10.11 10.14 10.17 10.20 10.23 10.26 10.29 10.32 10.35 10.38 10.41 10.44 10.47 10.50 10.52 ________ Time (Min) ________________

HP MS DF020313H64.d. Scan 308: 10.228 min.

1.8-

1.6-

; . 4

1.0-

0.8-

0.6-

0.4-

4,4'-DDD

Exp. RT Found RT

,20?235

129

120 140 150

199

mmIi . ,i. t:

180 200

281.

I I 310...340.

. 355 405

In

240 260 280 300 320 340 360 380 400

10.280 in ioq

Mass

235

Area Ratio

21021 100.00

■722

Report Date: 03/13/2030 10:34

tafile Analyzed: /chem/5972hp64.i/DF020313A64.b/DF020313A64.d/DF020313A64.dthod Used: /chem/5972hp64.i/DF020313A64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h


HP MS DF020313A6<4 .d. Ion 2-46.00

1 . 7 1.61.5-

i . -*• 1 3-

ion 246

i . i- i. 0-.

0.9-

0.0- 0.7-

0.6-i0.5-

0.4-

0.3-

0.2-.

0. It 0.0-'

! \

9.45i

1.1-

1.0-

0.9-

0.8-

9.48 9.51 9.54 9.57 9.60 9.63 9.66 9.69 9.72 9.75 9.78 9.91 9.84 9.8? 9.90 9.93 9.96 9.99 10.02_______ ____ ________ Time (Min) ___

HF MS DF020313964.d. Scan ^79: 9.739 min.

*r 0.6-

7 0 5-

0.4- 73

0.3-

191 .jr- ' c' a j

n ?1 76

0.0An 120 140 160 160 200

4,4'-DDE

Exp. RTi = 9.790Found RT = 9.739.

Mass Area Ratio

246 2 3 2 9 100.00

253.

201-

310341 .355

405

ih i

•723

HP- MS DF02031 3964 Ion 235.00

1.5-

1 .2- 1.1- 1.0- 0.9-

0.0- 0.7-;

0.6- 0.5-.

0.4-

0.3-

0.2-

0.1- 0.0-

10.50 10.60 10.70 10.80 10.90 11.00r Time (Min) ___________________

1.2

1.1-

1.0-

0.9-;

0.8-

0.7-

0.6-

0.5-

0.4-

0.3-

0.2-

0.1-

0.0-4

1.5-

1 . 4-

1 . 3-

1 .2- 1.1-

1.0- 0.9 ' 0.8-' 0.7- 0.6- 0.5 (J. 40.3-

HP MS DF020313H64Ion 235.00

OT

I 1 !

10..00 10.10 10.20 10.30 10.40 10.50_____ ,_______ T i me (Min)________________________

HP MS 0^020313064^. Ion 246.00

? . 50 50 9.70 9.80 9.90 10.00T i ne (Mm)

Compound: 4,4'-DDT

Quant Mass: 235

RT: 10.718

Area: 2411404

Compound: 4,4'-DDD

Quant Mass: 235

RT: 10.228

Area: 21021

Compound: 4,4'-DDE

Quant Mass: 246

RT: 9.739

Area: 2329


Compound Response ^Breakdown |Max Allowed|Test|

4,4-DDT 2411404 N/A4,4-DDE 2329 0 . 1 20.0 PASS4,4-DDD 21021 0 . 9 20.0 PASS4,4-DDD + DDE

l. 23350 1.0 20.0 PASS

TUNE SAMPLE★ ★★★★★★★★★★★★★ *** PASSED *** DDT BREAKDOWN TEST•x-k-k-k'k'k-klric'k’k’k'kli: ■724

b. Blank Data

Arranged in chronological order, by extraction date.

- Tabulated Results (Form I SV)

- Tentatively Identified Compounds (Form I SV-TIC)

- Reconstructed Ion Chromatogram and quantitation report

- Target compound spectra with lab-generated standard

spectra

- Quantitation/Calculation of TIC concentrations

- GC/MS library search spectra for TICs

725

' FORM

SEMIVOLATILE ORGANICS1ANALYSIS DATA

CLIENT SAMPLE NO.SHEET

.

|Lab Name: COMPUCHEM

Lab Code: LIBRTY

Contract 8270CSBLKIB

Case No.: SAS No. SDG No.: QE1877

Matrix: (soil/water) WATER Lab Sample ID WG16194-1

Sample wt/vol: 1000 (g/mL) ML Lab File ID: WG16194-1JA6 4_S

Level : (low/med) LOW Date Received

% Moisture: decanted: (Y/N) Date Extracted:03/08/02

Concentrated Extract Volume: 1000(uL) Date Analyzed 03/11/02

Injection Volume: 1.0(uL) Dilution Factor: 1.0


CAS NO. COMPOUNDCONCENTRATION UNITS: (ug/L or ug/Kg) UG/L

i 10 8-9 5-2---- ----Phenol 10 Ui| 11 1-4 4-4---- ----Bis(2 -chloroethyl)ether 10 u95 -57 -8----- ----2 -Chlorophenol 10 u

!54 1-7 3-1---- ----1,3-Dichlorobenzene 10 uj 10 6-4 6 -7---- ----1,4 -Dichlorobenzene 10 uS 5 -50 - 1----- ----1,2-Dichlorobenzene 10 u95 -48 -7----- ----2-Methylphenol 10 u

| 10 8-6 0-1---- ----2,2'-oxvbis(1-Chloropropane) 10 u10 6-4 4-5---- ----4-Methylphenol 10 u,62 1-6 4-7---- ----N-Nitroso-di-N-propylamine 10 u1 67 -72 - 1----- ----Hexachioroethane 10 u98 -95 - 3 ----- ----Nitrobenzene 10 u7 8 -59 -1----- ----Isophorone 10 u

:i n n'| O o -75 -5----- ----2-Nitrophenol 10 u10 5 - 6 7-9---- ----2,4 - Dimethylphenol 10 u11 1 - 9 1-1---- ----Bis(2 -chloroethoxy)methane 10 u

! i 2 10 u12 0-3 2-1---- ----1,2,4-Trichlorobenzene 10 u91 -20 ----Naphthalene 10 u

:l 10 6 -4 7 _ p___ ----4 -Chloroani1ine 10 u■ 8 7 -68 _ d _ _ _ _ _ ----Hexachlorobutadiene 10 u

,i 5 9 - 5 0 _ 7 _ _ _ _ _ ----4 -Chloro- 3 - me t hy1phenol 10 u] j. - 2 - 6----- ----2-Methylnapnt ha1ene 10 u,77 -47 - 4----- ----Hexachlorocyclopentadiene 10 uSB - Q ^ ----2,4,6-Trichlorophenol 10 u

i 95 - 9 5 _4----- ----2,4,5 -Trichlorophenol ■ 10 u; q i -5 8 -7----- ----2-Chloronaphthalene 10 u:.B8 - 74 -4----- ----2 -Nitroanil me 20 u1 1 " _L 1_3---- ----Dimethylphthalate 10 u6 0 6 - 2 0-2---- ----2,6-Dinitrotoluene 10 u'2 0 S - 9 r<o - o _ _ - _ ----Acenaphthylene 10 u

I 8 2 - 0 5 - - “ “ - “ ----3 - Mi t roam line 20 u- 10 u

FORM I SV 8270C

72u


CLIENT SAMPLE NO.

Lab Name: COMPUCHEMil


Contract: 8270C

SAS No.:

SBLKIB

Matrix;

Sample!

Level:

Moisture:

(soil/water) WATER

wt/vol: 1000 (g/mL) ML

(low/med) LOW

decanted: (Y/N)

Concentrated Extract Volume:

Injection Volume: 1.0(uL)


1000(uL)

SDG No.: QE1877

Lab Sample ID: WG16194-1

Lab File ID: WG16194-1JA64_985

Date Received: _______ _

Date Extracted: 03/0.8/02



( 1

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

51-28-5----------2,4 -Dini trophenol 50 U100-02-7---------4 -Ni trophenol 20 u121-14-2-------- 2,4 - Dinit rot oluene 10 u132-64-9---------Dibenzofuran 10 u84-66-2----------Diethylphthalate 10 u70 0 5- 72-3------- 4-Chlorophenyl-phenylether 10 u86-73-7----------Fluorene 10 u100-01-6---------4 -Nitroanil ine 20 u534-52-1-------- 4,6-Dinit ro-2 - methylphenol 20 u86-30-6----------N-Nitrosodiphenyl amine (1) 10 u101-55-3---------4 -Bromophenyl - phenyl ether 10 u118-74-1-------- Hexa chlorobenzene 10 u87-8 6- 5----------Pentachlorophenol 20 u85-01-8----------Phenanthrene 10 u12 0-12-7-------- Anthracene 10 u86-74-8 ----------Carbazole 10 u8 4- 74-2----------Di-n-butylphthalate 10 u2 0 6- 44-0---------Fluoranthene 10 u129-00 - 0-------- Pyrene 10 u85-68-7----------Butylbenzylphthalate 10 u91-94-1----------3,3' -Dichlorobenzidine 20 u117-81-7---------bis ( 2 - et hvlhexvl ) Phthalate 0 . 9 J56 - 55 - 3 ----------Benzo (a) anthracene 10 ' u213-01-9---------Chrysene 10 u117-84-0---------Di-n-octylphtnalate 10 u205- 99-2---------Benzo (b) fluoranthene 10 u2 0 7 -08- 9---------Benzo ( k ) f iuoranthene 10 u50 - 32 -8 ----------Benzo (a; ovrene 10 u19 3 - 39-5-------- Indeno (1,2,3- cd ) pyrene . 10 u

15 3 - 70 - 3 ----------Dibenzo (a , h .■ anthracene 10 u191 - 24 - 2------- - Benzo (q , h , t ) oerviene 10 u

Cannot be separate : roffi L FORM I SV

72 i

8270C

Data File: /chem/5972hp64.i/DF020311A64.b/WG16194-lJA64_985.d

Date : ll-MAR-2002 09:32

Client ID: SBLKIB

Sample Info:

Volume Injected (uL>: 1*0

Column phase: RTX-5


Operator: 917


cvir--

(:<10~6>

Data File: /chem/5972hp64.i/DF020311A64.b7WG16194-lJA64_985.d

Date : ll-MAR-2002 09:32

Client ID; SBLKIB Instrument: 5972hp64.i O')Sample Info: CVJVolume Injected (uL): 1.0 Operator: 917


Data File: /chem/5972hp64.i/DF020311A64.b/WG16194-1JA64_985.dReport Date: 13-Mar-2030 09:51

Data file Lab Smp Id Inj Date Operator Smp Info Misc Info

CompuChem

Semivolatile Report SW-846 Method 8270C /chem/5 972hp64.i/DF020311A64.b/WG16194-1JA64_985.d WG16194-1 Client Smp ID: SBLKIB11-MAR-2 002 09:32917 Inst ID: 5972hp64.i

Comment ; Method \ Meth Date Cal Date1 Als bottjle

Dil Factor IntegratorTarget Version: 3.50

/chem/5972hp64 . i/DF020311A64 . b/82-70Cv6 . m 12-Mar-2030 12:00 respass Quant Type: ISTD 10-MAR-2002 17:23 Cal File: HL020310A64.d3 QC Sample: BLANK1.00000HP RTE Compound Sublist: OLM03 sub


Name ValueI

Description

D^jvtvo!

Vi

1.00000 1000.000001000.000001.00000



CoT.pGG

CONCENTRATIONS

nds

C’UANT SIG

MASS F.T e:-:f F.T REL RT RESPONSE

ON-COLUMN

l NG)

FINAL

( ug/L)

i .i , -i - Dico.oronenr.en~ - a4 52 5 . 2 n 1 S . 24 9 (1.000) 98611 4 0.0000

Naphtha e n e - d 8 125 10.128 10.142 ; i.000) 379742 40.0000

Acenaoh he-c-.n: 16 4 12 . 1A~> 12.152 (1.000' 272997 40.0000

Phenar.t hre:':rr - d 1 S 5 15.460 15 4 o 5 11.000) 554445 40.0000

Chrysene ■ h 1 24 0 19.944 ; 9 Q 4 9 ; i ,ooo) 450039 40.0000

2^-i 22 .4 29 22.434 1 1 .0001 242083 40 . 0000

j . r ; :jor ::: 5 4 5 2 - : 0 . 7 S 1) 245885 76 .8183 76.82

Ph^r.o: • i E 9 5 7 7 5 4 7 7 7 ; 0 . 5 3 9 ) 221615 53 . 1523 53.15

Nltrcr-c 52 ;. o 7 . 2 3 1 C . 897; 181134 4 4 .0745 44 . 07

: - r 1 '.it, I. l p ."i v: ■.. ; : v: 11 v' :: ■ ;s-; . 0 904' 421100 46 .2996 4 6.30

::. 4 -j - t 2 2 r; 1 4 4 5 4 ' 1 . 10 o ■■ 372293 135.450 135.5

v - i 1 4 :s4 1 7 . r 7 ■■■ iDi ■ 0.3951 1049356 88 . 0802 88 . 08

Pher.c ; *•; c u r. d Not Detected

3 : s : 2 - c 9 2 Compound Not Detected

Z -Ch.orophrr-c •. o - Cor.i: our.d Not Detected

SIMILARITY

\

&

73G


QUANT SIG

Compounds MASS RT EX? RT REL RT


20 1,4-Dichlorobenzene • 146 Compound Not Detected



24 2,2'-oxybis(1-Chloropropane) 45 Compound Not Detected


28 N-Nit rose-di-N-propylamine 70 Compound Not Detected

29 Hexachloroethane 117 Compound Not Detected

301

NitroDenzene 77 Compound Not Detected

31 Isophorone 82 Compound Not Detected

32 2-Nitrophenol 139 Compound Not Detected

33 2.4-Dimethyl phenol 122 Compound Not Detected

34 Bis(2-chloroethoxy)methane 93 Compound Not Detected

35 2,4-Dichioropheno1 162 Compound Not Detected

36 1,2,4- Tnchlorobenzene 180 Compound Not Detected

37 Naphthalene 128 Compound Not Detected

38 4-Chioroanil:ne 127 Compound Not Detected

35 Hexachlorooutadiene 225 Compound Not Detected

41 4 -Chloro - 3-methy 1phenol 107 Compound Not Detected

42 2-MethyInaphchalene 14 2 Compound Not Detected

4 4 Hexachlcrocyclopentadiene 2 3 7 Compound Not Detected

45 19c Compound Not Detected

4 6 2,4.5 -Tr:ch1oropheno 1 156 Compound Not Detected

__ 49 2-Chlornnaphthalene 162 Compound Not Detected

2 - N i t roa mime 65 Compound Not DetectedWiO

Dimet hyipnt ha 1 at e 1 6 3 Compound Not Detected

5 1 2,6 - Dm: t rotoluene 165 Compound Not Detected

52 AcenaDht hv 1 er.e 152 Compound Not Detected

53 5 -Nitroan:1:ne T_ 7 Q Compound Not Detected

54 Acenaphthene 154 Compound Not Detected

c c. 2 . 4 - Dim t rophenoi 184 Compound Not Detected

56 4 -Nin rophero1 109 Compound Not Detected

57 2.4-Dinitrotoluene 16b Compound Not Detected

56 Dibenzot u r an 1 6 8 Compound Not Detected

5 5 Dietnyipntha late 1 4 5 Compound Not Detected

60 4 -Chlcrobhenvi-phenviether 2 04 Compound Not Detected

6'; r 1 u o r e ri e ■■ir. Compound Not Detected

6 2 4-N:trcan:;:ne 1 36 Compound Not Detected

6 3 4 6 - D l r. it ro - 2 - met hy ’ phene 1 1 9 ? Compound Not. Detected

44 N-Nit re sod:pneny i ami re 16 5 Com,pound Not Detected

in 4 -Bromopheny: -phenyiether 2 4". Comnc unci Net Det ected

4 7 Hexachlorobenzene 264 Comooun-d Detected

6? Pentachicropheno: 2 6 r Comcourd N 71 Detected

7 0 Pnenar.: rrene : Cc-T.:;'-. Not Detected

7 Antnra :en- 7W \ : Detected

7 2 Carbazo j‘e : 6 7 Dcrpcur.i Det ected

7 3 Di - n - but y: pnt ha 1 ate : 4 5 i Detected

RESPONSE

CONCENTRATIONS

ON-COLUMN FINAL


731


ipounds

QUANT SIG

MASS RT EXP RT REL RT

74 Fluoranthene 202 Compound Not Detected

76 Pyrene 202 Compound Not Detected

77 Butylbenzylphthalate 149 Compound Not Detected

78 3,3'-Dichlorobenzidine 252 Compound Not Detected

79 bis (2-ethylhexyl)Phthalate 149 19.775 19.780 (0.992)

80 Benzo(a)anthracene 228 Compound Not Detected

61 Chrysene 228 Compound Not Detected

82 Di-n-octylphthalate 14 9 Compound Not Detected

9 3 Benzo (t>) fluoranthene 252 Compound Not Detected

84 Benzo lk 'fluoranthene 252 Compound Not Detected

85Benzo i a' i pyrene


86 1 ndeno f'l,2,3-cd'pyrene 276 Compound Not Detected

87Dibenzoji a , h i anthracene


33 Benzo igi, h, i) perylene 276 Compound ■Not Detected

RESPONSE

CONCENTRATIONS

ON-COLUMN FINAL


9136 (a)

QC Flag Legend



i

Data File: 7chem,'5972hp64. i/DF020311A64.b/UG16194-lJA64_985.d

Date : ll-MAR-2002 09:32

Client ID: SBLKIB I nstrument: 5972Vip64. i

Sample Info:


Column phase: RTX-5

Operator: 917


Data File: /chem/5972hp64.1/DF020311A64.b/UGl6l94-lJA64_985.dInjection Date: ll-MAR-2002 09:32Instrument: 5972hp64.1Client Sample ID: 5BLKIB

ipound: 2.4.6-TribromophenolHumber: l'lB-79-6

; 2.0i

i i.8i: 1.6i

1.4-

1.2-'iDio 1.0-

0.8-

i 0.6-

0.4-

! 0.2-

Ion 329.60: Area: 372293 Height: 204815

$

! i

14.00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14Min

50 14.5514^60 14!. 65 14^70 14^75 m'sO 14.85 14.90 14.95

2.0-

Ion 332.00: Area: 0

\

Height: 0

1.8-

1.6-

1.4-

1.2-

1.C-

0.8-

0.6-

0.4-

0.2-

0.0»14.00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.05 14.90 14.95

______ _____ M i n

6.0- " . 5

i.O6.5-

6. 0-5.5-

5.0-

4.5

4.0-

3.5

3.0-

2.5-

1 on i4i.00: 0 Height: 0

0.5-

n,0-----'--1 4 . u'o 1 - 5 14,10 14.15 14.20 ;4.; 14.40 14.45 14.50 14.55 14.60 14.65 14.20 14.75 14.80 14.85 14,90 14.95:

M i n

CompuChema Division of Libertv Analytical Corp.

i


\

LAB INSTRUCTIONS:

RECEIPT DATE: SAMPLE DATE: DUE DATE:

CASE#: i SDG: COMPUCHEM#: - I j

CLIENT ID: Sgif //J

ANALYSIS DESCRIPTION:

Injection Volume :[pL Dilution Prep (if needed)

Extraction Date J / S' / C ?

DFTPP Filename h f~7? I o 7 II A Jk

Sample File Name jj & !6 / f U - / JA /(/

ANALYST (S): Injection' I H__________________ Work-upw 7

GC/MS DATE REVIEW

iCONDITION CODE

3ft


Number o|f peaks found:

Number of Hits found: _ (£L


jOualin Assurance Notice (S)

Number of Notices Required _I

Comments:

m

Disposition: [ vf^omplete



[ ] Reinject Neat

f ] Dilute) X)

=GC MS Review

Final Reportable Package)s):

i

Auditor Date / /

\,\G\ fa ,

- 73

SVI -6/27/01: PTF


CLIENT SAMPLE NO.

Lab Name: COMPUCHEM Contract:

Lab Code: LIBRTY Case No.: SAS No.:

Matrix: (soil/water) WATER

Sample wt/vol: 1000 (g/mL) ML

Level: (low/med) LOW

% Moisture: _______ decanted: (Y/N)

Concentrated Extract Volume: 1000(uL)



8270C

SDG

Lab Sample ID:

Lab File ID:

SBLKII

No.: QE1877

WG16228-1

WG16228-1A60

Date Received:




CONCENTRATION UNITS:CAS NO. COMPOUND ■ (ug/L or ug/Kg). UG/L Q

108-95-2 - - 111-44-4--95 - 57- 8 ------541-73-1- - 106-46-7--95- 50 - 1 ------9 5-48-7------1 0 8 - 6 0 - 1 - - 106-44-5 - - 621-64-7--67-72 - 1------98 - 95 - 3 ------7 8-59-1------

i 8 8-75-5------105- 67-9 - -111-91-1-- 120-83-2-- 120-S2-1-- 91-20-3------106- 47-3 —

: 8 7 - 6 S - 3------59-50-7------

' 91-5 7-6------77 - 47 -4 ------

I 9 5- 95 -4 ------51-58-7------

i; 8 8 - 74 -4 --

; 606-20-2-- 2 0 8 - 9 6 - S - -

; 9 9 - 09-2 ------

- - Phenol ____________________- - Bis(2-chloroethyl)ether- - 2 -Chlorophenol --1,3 - Dichlorobenzene --1,4-Dichlorobenzene --1,2 -Dichlorobenzene- -2-Methylphenol ___________--2,2' -oxybis(1 -Chloropropane)- - 4 -Methylphenol______________--N-Nitroso-di-N-propylamine--Hexachloroethane --Nitrobenzene- -Isophorone --2 -Nitrophenol --2,4-Dimethylphenol- - Bis(2 -chloroethoxy)methane --2,4-Dichiorophenoi --1,2,4-Trichlorobenzene--Naphthalene- -4 -Chloroani1ine--Hexachlorobutadiene --l-Chloro-3-methylphenol- - 2-Methylnaphthalene ______- -Hexachlorocyc1opentadiene- - 2,4,6 -Trlchlorophenol --2,4,5-Trichlorophenol- - 2 -Chloronaphthalene- - 2 - N11 roan ill re_____--Dime t hy1pht haIa t e- - 2 , 6 - D i n i t ro t o 1 u e ne- - Acenaphthylene --3-Nitroaniiine --Acenaththere

10 u10 u10 u10 u10 u1.0 u10 u10 u10 u10 u

.10 u10 u10 ■ u10 u10 u10 u10 u10 u10 u10 u10 u10 u10 u10 u10 u10 u

■ 10 u20 u10 u10 u10 u20 u10 u

73b


Lab

Lab

Name :i|

Code :

COMPUCHEM

LIBRTY Case No.:

Contract: 8270C

SAS No.:

CLIENT SAMPLE NO.

SBLKII

SDG NO.: QE1877

Matrix: (soil/water) WATERi[


Level (low/med) LOW



[|Injection Volume: 1.0(uL)


Lab File ID: WG16228-1A60

Date Received:




GPC Cleanup: (Y/N)

j- CAS NO.

N pH :

COMPOUNDCONCENTRATION UNITS: (ug/L or ug/Kg) UG/L Q

I

/ 11T

51-28-5------100-02-7- - 121-14- 2- - 132-64-9--84 - 66 -2------7005-72-3-86 - 73 - 7------100-01 -6- -

534-52-1--3 6 - 30 -6 --1 0 1 - 5 5 - 3 - - 1.1 8 - 74 - 1 - - 37-86-5---85-G1-8------120 - 12 - 7 - -8 6- 74- 8 ------8 4 -74 - 2 ------206 -44 - 0 - - 129-00- 0- -3 5 -66 - 7 ------91-94-1------117-91-7--

205-99-2--207-08-9--5 0 - 32 - 8 ---1 93 - 3 9 - 5 - -

1 9 1 - 2 4 - 2 - -

- Can riot

.---2,4-Dinitrophenol___________-- 4-Nitrophenol_______________-- 2,4-Dinitrotoluene-- Dibenzofuran________________-- Diethylphthalate-- 4 -Chlorophenyl-phenylether-- Fluorene __________________-- 4-Nitroaniline ~-- 4,6-Dinitro-2-methylphenol-- N-Nitrosodiphenylamine (1)-- 4 -Bromopheny1 -phenyletEer_-- Hexachlorobenzene___________-- Pentachlorophenol___________-- Phenanthrene_________________-- Anthracene-- Carbazole ____________-- Di-n-butylphthalate-- Fluoranthene_________________-- Pyrene_______ ________________-- Butylbenzylphthalate-- 3,3'-Diehlorobenzidine-- bis(2 - ethyl hexyl)Phthalate-- Benzo(a)anthracene__________-- Chrysene __________________-- Di-n-octylphthalate-- Benzo(b)fluoranthene_______-- Benzo(k)fluoranthene_______-- Benzo(a)pyrene _____________-- Indeno(1,2,3-cd)pyrene-- Dibenzo(a,h)anthracene_____-- Benzofg,h,i)perylene_______

separated trom Diphenvlamine FORM I SV■'

50 U20 U10 U10 u10 u10 u10 u20 u20 u10 u10 u10 u20 u10 u10 u10 u10 u10 u10 u10 u20 u

7 J10 u10 u10 u10 u10 u10 u10 u10 u10 u

8270C

73/

Data File: /chem/5872hp60. i/DF020312A60 * b/WGl£>228-lA&0 . d

Date : 12-MAR-2002 14;28

Client ID: SBLKII

Sample Info:




Operator: 817


00

COr~-

Data File: /chem/5972hp60. i/DF020312A&0. h/NGlb228-lAbO*d

Date : 12-MAR-2002 14:28

Client ID: SBLKII

Sample Info:

Volume Injected <uL): 1*0

Column phase: J&W DB-5*625

I nstrument: 5972hp60 * 1

cr>Operator: 917


Data File: /chem/5972hp60.i/DF020312A60.b/WG16228-1A60.dReport Date: 13-Mar-2030 09:53

Data file Lab Smp Id Inj Date Operator Smp Info ■ Misc Info Comment Method Meth Date Cal Date | Als bottle Dil Factor Integrator

CompuChem

Semivolatile Report SW-846 Method 8270C /chem/59 72hp6 0.i/DF020312A60.b/WG16228 -1A60.d WG16228-1 Client Smp ID: SBLKII12-MAR- 2 0 0 2 14:28917 Inst ID: 5972hp60.i

/chem/5972hp60.i/DF020312A60.b/8270Cv6.m13-Mar-2030 09:03 byrd Quant Type: ISTD0 3-MAR- 2 0 0 2 17:20 Cal File: HL020303A60.d8 QC Sample: BLANK1.00000HP RTE Compound Sublist: OLM03.sub

Target Version: 3.50Processing Host: einstein

Concentration Formula: Amt * DF * Vt/(Vo * Vi) CpndVariable


DF 1 1.00000 Dilution Factorvt '! 1000 . 00000 Volume of final extract (uL)vo: 1000.00000 Volume of sample extracted (mL)

# Vi 1 . 00000 Volume injected (uL)


CONCENTRATIONSQUANT SIG ON-COLUMN FINAL

CLT.t'OUC.DS MASS : Zj \ p p7 EEL ?.T RESPONSE ( NG) ( ug/L)

'.r-d4 152 0 . ■ 4 1 r.: 2: {: .00.?} 9 7 0 3 S 40.0000• 1 6 : . 2 e :..2 = - • 1 . 0 0 C ; 2 3 9 5 2 3 4 C.0000

* ;■ .:-.c~GDpci:'e::-- d 1 ; :• j o • : '] o :'i : • c q i • c. 40 0000: E :• 2: ; E.. 7 : o: } ? 12 9 0 4 0.0000

IN '2 i ■ : . : ;• C:: 440199 40.00002o-; 2 ■ : ~: :: 4 1 4 2 8 n 4 C 0000

. r . t:: : 2 2 - . ■.: = 7 4 '.)' 2 7-5010 89.3364 89.34• V ~ ■ T ■ i ■0. ?311 208307 59.8929 5 9.89

:• ~ 2 ■ - ■ V . 8 -;. : 21116 2 61 .6570 6 1 . 6 6T ' r - .:c y .::v : 72 : 7 : :• = ■ :■■■; .'■.PH; 464030 599390 59 . 94

- \ ~ 1 4 7 i - T . " - V 1 . 104 , 319014 170.283 170.3: :: 7* 244 : f. 7 -. ' 0 . Oil. 3 92 515 73.0486 73.05

Cent c ; : Getect^d.v: N:

SIMILARITY

I AM) |

740


w

Compounds

QUANT SIG


CONCENTRATIONS

ON-COLUMN FINAL


18 2 ' Chloro'phenol 12S Compound Not Detected.

19 1 , 3-Dichloirocenzene 14 5 Compound Not Detected.

20 : ,4-Dichlorobenzene 145 Compound Not Detected.

22 1,2-Dicr lorobenzene 146 Compound Not Detected.

23 2-Methylphenol 106 Compound Not Detected.

24 2,2'-ox> bis(1 -Chloropropane; 45 Compound Not Detected.

27 4 - Methylpnencl 108 Compound Not Detected.

28 N-Nic roso-cii - N- propylamine 70 Compound Not Detected.

2 9 Hexachloro*thane 117 Compound Not Detected.

30 Nitrobenzene 77 Compound Not Detected.

31 T sophorone 82 Compound Not Detected.

3 2 2-Nitr^phenol 139 Compound Not Detected.

33 2,4-Dimethylphenol 122 Compound Not Detected.

34 Bis (2 -chloroetboxy;methane 93 Compound Not Detected.

35 2,4 -Dichiorophenol 162 Compound Not Detected.

3 6 1.2,4-Tr ichlorobenzene 180 Compound Not Detected.

37 Napht ha 1en* 128 Compound Not Detected.

3 “ 4 • Ch 1 oroar.nine 127 Compound Not Detected.

2 9 Hexachic robutadiene 22 5 Compound Not Detected.

4 - Chiore - 3 -mithylphenoi 107 Compound Not Detected.

:--Mer.hy: r.a oh t ha 1 ene 1 4 J Compound Not Detected.

4 4 H e a c h 1 r .ocyc . opentaaiene ■> 7 *7 Compound Not Detected.

4 5 2 . -i . <? - T t : ch: c ropher.c.i i4 Compound Not Detected.

2 . 4 , 5 -Ti : cr. 1 oropher.o 1 1 3 5 Compound Not Detected.

m - -: -■> - i-s: Compound Not Detected.

: -r- 6 5 Compound Not Detected.

5 0 Compound Not Detected.

5 - ■■■■■■■■ ; 5 Compound Not Detected.

A :s-.a r.: hy : 5 2 Compound Not Detected.

5 3 1 3 - Compound Not Detected.

54 A-Tir-sp!- b.ene ■54 Compound Not Detected.

55 184 Compound Not Detected.

5 4 rent : 10 3 Compound Not Detected.

2 , 4 ■ D: r.: ■ 4 £ Compound Not Detected.

== D i ber.tor urar. 1 D 8 Compound Not Detected.

59 Oiethylphi.-.a 1 ar * 14 9 Compound Not Dec ected.

4 :• 4 -Ch1c:c y.-e 2 04 Compound Not Detected

r Compound Not Detected.

- : A' 1 1 - Compound Not De t ec t ed

•: J 4 . • C : r; : 9 4 Compound Not Detected.

N ■ ■' - res co-.oeoyycnoe • c, Compound No: Detected.

4 - ::rc;-:cp :>3Py: leto.e:' Compound No: Detected.

2 " 4 Do~po..::o NCI Detected.

! 2 -3 - Compoun;; N C Detected

:J : Cot:-, jun.-ri No: Detected.

• ; 7 = CO-U.'V.;;-.-; Detected.

7 .. ; ,: : a :: ; • - 7 rui- i.--

I

7


II QUANT SIG

Compounds

iMASS RT EXP RT I*EL RT

72 Di-n-butylphthalace 149 Compound Not Detected

74 Fluoranthene 202 Compound Not Detected


77 Butylbenzylphthaiate 149 Compound Not Detected

7 S 2,2'-Dichiorobenzidine 2 52 Compound Not Detected

1C bis:2•ethy1 hexyl) Pht halate 149 20.576 20.574 (0.996)

so Bento • a i a:-.:hracene 22S Compound Not Detected

u •Chryser.ej


5 2 Ci-n-cc:y1pht hala te 14 9 Compound Not Detected

C } Benzo 'bi fluoranthene 2 c o Compound Not Detected

c 4 5 e r. z o ' x i flu c: a r. t h e n e 252 Compound Not Detected

55 Renzo : a ) pyrene 252 Compound Not Detected

5 6 Inaeno:1,2,2 -cd;ovrene 276 Compound Not Detected

57 D: ber.zo (a . h > ant hracene 279 Compound Not Detected

2 2 fcer.zo ; u , h , i j pery 1 ene 276 Compound Not Detected

RESPONSE

74210

CONCENTRATIONS

ON-COLUMN FINAL


9510 (a)

QC Flag Legend

A -

Target compound detected Below Limit Of Quantitat Target compound detected exceeded maximum amount. Compound response manual

but, quantitated ion(BLOQ). but, quantitated

ly integrated.

amount

amount

i

Data File: .,,chern/5972hp60.1 /DF020312h60 . b/UJGl6228-1A60. dInjection Date: 12-MHR-2O02 14:28Instrument: 5972hp60.1Client Sample ID: SELF11

bound:^Number

4,6-T nbromophenol 118-79-6

Ion 329.60: Area: 319014 Height: 159390

$

1 - . 7-5 i J . 40 14.45 14.50 14.55 14.60 14.65 1 4.7Q 14.75 14.80 14.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20______ Min_____________________________________________________________

Ion 332.00: Hrea: 0 Height: 0

l

if'

14.50 14 70 14.77, 1 4 . 14.35 14.90 14.90 15.00 15.05 15.10 15.15 15.201-1: r, _____________________________________________________________________________________

■a: H*i--ht : 0

............. . - ________ __________7J..0

1 4.5b 1 4 . so 14.4,5 14. 7*0 1 4 . "5 14.80 14.35 14.90 14.95 15.00 15.05 15.1m 15.15 15.20 r '• i n

Data File: /chem/’5972hp60.i/DF020312A60*b/WG16228-lA60*d

Date : 12-MAR-2002 14:28

Cl lent ID; SBLKIIj

Instrument: 5972hp60 *i

Samp 1e I rjif o:

Volume Injected <.uL>: 1.0 Operator: 917

Column jg,u DE-5.fi.25 Column diameter: 0*32

7^ bis(2-ethylhexy1>Phthalate Concentration: 6*52 ug/L



LAB INSTRUCTIONS:

RECEIPT DATE: 3/8/02 0:00

CASE#:

CLIENT

SDG: WG16228

ID: SBLKII

SAMPLE DATE: DUE DATE:

COMPUCHEM#: WG16228-1


Injection Volume : 1.0

Extraction Date 10 / 02

DFTPP Filename DF020312A60

Sample Fjile Name___VVG16228-1 A60_i|

ANALYST (S): Injection917_________

Dilution Prep (if needed)_

Work-up Li /' ?

GC/MS DATE REVIEW

CONDITION CODE

Extraneous Peak Search Results:l|

Number of peaks found:

Number ol Hits found:

t'l/k


(/utility Assurance Notice (s) Number of Notices Required_____

Comments:

Disposition: \ Complete



[ ] Reinject Neat

[ ] Dilute ( X)

"tiCMS Rosier_______________________ Date ■' ! ^ Auditor_


L-Ob /£i Ur-/ o

Date

74 j

SVl -6/27/01: PTF

.iiiii T ii~i ri^n

ASSIGNED TO:

CnmpuChem

EXTRACT ION WORKSHEET

DA I K EXTRA' TED/POS I LD:

IMP ID NUMBER:2A"hD r

-079 S-lloi 7 / t/tT

j;:, SAMPLE;. , FINAL Adjusted DH' -_i.

SAMPLE >*„ ;JtjC SAMPLE ; -VOLUME: ; VOLUME A/N BASE V-rO'SA/i.COMMENTS -A (^-

NUMBER'. ' TYPE ' J____ (m|) ; v -y-.V -.y\ ■ A--'AQe/tr?- g- /OoO 1^ /A »2 ;

2_L_J__2. /ore _______ l.ft A h i2-i

* A> /tt* ______ 1.0 /.u \7- \_____________ a /OCa 1.0 /A, a i

/ /*£

/too ill lL \7.\ t// Qe- A? yAA

/? /too _Jji ! b |2 1’___________ ■/£. //e<o ■C JA 12.i- / /r

jo<rc \.o /L >2.11 .1_______IA-

/a to \-D Lh ns

)/ 7 /COO lo

/ £ \7\

\/r /OCC lo J.L tii

2 { < -^1- /coo • 1,0 /A (2.»

3/coo _____ lo /A 17 1

4 * S3 /ooo _______lo________ /A I2.i

s Gfr-irn-1 /COG III) /A I'M

ujefr/ozY~/ /OC0 1-0 IA Q.1 f-* £_x-fTSc'V- c /<. rJ

1

H H 1 //t’l1

0-—cA—

i/ll/-

01

1 ___ ■——

.2 ---------------------------------

>3 iMrfb'ZZtir-'lBLK

jm t'O 12.1A <] S' Z'

LCS /OOP l.o A G l-2-l *Add 1.0 ml. validation spike in I CS and SSs ualrss otherwise noted

S-VOL Acid /B/N 8270j, l)

NO. 393■ \ // ^ FINAL VOLUME VERIFIED: ‘-'"'U/l/| _______

SURROGATE AMT. 1.0 ml A/"A /

.____ ____►LOT . <3 7.71 t/

^—SUPERVISOR REVIEWED: : .... ' -------

NO. 3012/ 2021 VAI.il).SPIKE AMT. l/il 1.0ml 1.0 ml

LOT SURROGATE: & SPIKE ADDED BY:______________'.A-ll.-i________ ___ -

KD JYVAnalyst initials Extracted

Manu r and lol number of reagents/solvents used

!f\<^ C&Initials Dale

_____N2 Bottle up Witness .

W.^-Vo'b&x^___My/- ____RrMiiLW... JBr

FORM 1 CLIENT SAMPLE NO.1 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

Lab Name: COMPUCHEM Contract 8270CSBLKJG

Lab Code: LIBRTY Case No.: SAS No. SDG No.: QE1877

Matrix: ( soil/water) WATER Lab Sample ID WG16304-1

Sample wt/vol: 500 (g/mL) ML Lab File ID: WG16 304-lB60_9


% Moisture: decanted: (Y/N) Date Extracted:03/14/02

Concentrated Extract Volume: 500 (uL) Date Analyzed 03/14/02

In j action Volume: 1.0(uL) Dilution Factor: 1.0



108-S5-2-------- Phenol 10 u111-44-4-------- Bis (2 - chloroethyl) ether 10 u95-57-8----------2 - Chlorophenol 10 u541-73-1-------- 1,3 - Di chlorobenzene 10 u106 -45 - 7-------- 1, 4 -Dichlorobenzene 10 u95-50-1----------1,2 - Dichlorobenzene 10 u95-48-7----------2 -Methylphenol 10 u108-6 0-1-------- 2,2' -oxybis (1 -Chloropropane) 10 u106-44-5-------- 4 -Methylphenol 10 u621-64-7-------- N-Nitroso-di -N-propyl amine 10 u6 7- 72-1----------Hexac hi oroe thane 10 u98-95-3----------Nitrobenzene 10 u78-5 9 -1----------I sophorone 10 u38-75-5----------2 -Nitrophenol 10 u105-67- 9---------2,4 -Dimethyl phenol 10 u111-91-1-------- Bis (2-chloroethoxv) methane 10 u120- 8 3- 2-------- 2,4 -Dichlorophenol 10 u12 0 - 32-1-------- 1,2,4 - Tri chlorobenzene 10 uSl-20-3----------Naphthalene 10 u10 6 - 47- 8 -------- 4 - Chloroani 1 me 10 u8 7- 68- 3 ----------Hexachlorobutadiene 10 u5 9 -50 -7----------4 - Chloro - 3 - methylphenol 10 u91-57-6 ---------- 2 -Methvlnaphthalene 10 u77-47-4----------- Hexa chi orocycl open tadiene 10 u88 - 06 - 2 -----------2,4,6 -Trichlorophenol 10 u5 5- 95 -4-----------2,4,5 - Trichlorophenol 10 u91-5 8- 7----------- 2 -Chloronaphthalene 10 u8 5 - 74 - 4 -----------2- Nit roam line 20 u13 1 - 11 - 3----------D i me t hy 1 pn t ha 1 a t e 10 u60 6 - 2 0 - 2--------- 2, 5 - Di nitre toluene 10 u2 08 - 91-8--------- Acenaphthylene 10 u5 9 - 09 - 2 -----------3-Nit roamline 20 u8 - c 2 - v-----------Ac s n ci p b t b n -s 10 u

FORM I SV 8270C

FORM 1SEMIVOLATILE ORGANICS■ ANALYSIS DATA SHEET

CLIENT SAMPLE NO.

Lab Name: COMPUCHEM

Lab Code: LIBRTY[|


Sample wt/vol:

Level :i (low/med)

Moisture:


Contract:

Case No.: SAS No.:

WATER

500 (g/mL) ML

LOW

decanted: (Y/N)

Volume: 500(uL)

Inject ion Volume: 1.0(uL)

8270CSBLKJG

SDG No.: QE1877


Lab File ID: WG16 304-1B60_98 5

Date Received:




GPC Cl1eanup: (Y/N) N pH:



51-28-5----------2,4 -Dini trophenol 50 u100-02-7-------- 4 -Nitrophenol 20 u121-14-2-------- 2,4-Dimtrotoluene . 10 u132-64-9-------- Dibenzof uran 10 u84-6 6 - 2----------Diethylphthalate 10 u7005-72-3------- 4-Chlorophenyl-phenylether 10 u86-7 3 - 7----------Fluorene 10 u100-01-6-------- 4-Nit roaniline 20 u534-52-1-------- 4,6 - Di ni t ro - 2 - methylphenol 20 u8 6- 30-6----------N-Ni t rosodiphenyl amine (1) 10 u101-55-3-------- 4 - Bromophenv 1 - phenyl etEer 10 u118-74-1------- - Hexachlorobenzene 10 u8 7- 8 6 - 5----------Pentachlorophenol 20 u8 5-01-8----------Phenanthrene 10 u120-12-7-------- Anthracene 10 u86 - 74 - S----------Carbazole 10 u84 -74 -2----------Di - n - butylpht halate 10 u206-44-0-------- Fluoranthene 10 u129-00-0 -------- Pyrene 10 u8 5- 68-7----------Bu t v 1 be n z v 1D h t ha 1 a t e 10 u91-94-1----------3,3'-Dichlorobenzidine 20 u117-81-7-------- bis (2 - et hy lhexvl ) Phthalate 10 u5 6 - 55 - 3 ----------Benzo ( a ) ant hracene 10 u213-01-9-------- Chrvsene 10 u117-34-0-------- Di - n - octy Ipnt iiaiate 10 u2 0 5 - 99- 2.---------Benzo (b) fluoranthene 10 u

■ 2 0 7 - o 5 - 9-------- Benzo (k) 11 uorant hene 10 u10 u

19 3- 89-5-------- I nde no (1 , 2, 3- cd ) pyrene 10 u5 8 - 70 - 3 ----------Dibenzo (. a , n > ant hracene 10 u191-24-2-------- Benzo ig, n, i ) cerylene 10 u

(ll 1 Cannot be separated from Liphenvlamme

FORM I SV 8270C

74b

Data Filet /chem/5972hp60. i/DF020314B60,b/WG16304-*£0_985.d

Date : 14-HAR-2002 21:40

Client ID: SBLKJG

Sample Info;

Volume Injected (uL); 1,0

Column phase: J&W DB-5,625

Instrument; 5972hp60. i

Operator; 2319


•^r

Is--

2.4/6-Tribromcpheno1+

Data F i le: /chero/5972h|o60. i/DF020314BG0.ti/lClio304-lE£,0_?85..-J

Date : 14-MAR-2002 21:40

Client ID: SBLKJG

Sample Infos

Volume Injected <uL>: i.O

Column phases J&W DB-5.625


Operator: 2319


DL.O

r^-

Data File: /chem/5972hp60.i/DF020314B60,b/WG16304-1B60_985.dReport Date: 15-Mar-2030 11:04

Data file Lab Smp Id Inj Date Operator;Smp Infoi Misc Info Comment Method Meth Date Cal Date Als bottle Dil Factor Integrator Target Version:

CompuChem

Semivolatile Report SW-846 Method 8270C /chem/5 9 72hp6 0.i/DF020 314B6 0.b/WG16304 -1B6 0_985.d WG16304-1 Client Smp ID: SBLKJG14-MAR- 2 0 0 2 21:402319 Inst ID: 5 972hp6 0.i

/chem/5 972hp6 0.i/DF020314B60.b/8270Cv6.m15-Mar-2030 10:11 byrd Quant Type: ISTD0 3-MAR- 2 0 0 2 17:20 Cal File: HL020303A60.d3 QC Sample: BLANK1 . 00000

HP RTE Compound Sublist: OLM03.sub3 . 50



DF 1 1 . 00000 Dilution FactorVt ! 500.00000 Volume of final extract (uL)Vo ■ 500.00000 Volume of sample extracted (mLVi 1.00000 Volume injected (uL)

rpna Variabl Local Compound Variable

CONCENTRATIONS

v'u'A.‘i. S IG ON-COLUMN FINAL

pc^.s MASS FT EX? F.T PEL F.T RESPONSE ! NG) ( ug/L)

■ ■ ---.I-.--,-....-..-.-ip1 C. - 3 . i • 6 -.;? 7 -i.o c 0 ■ 86211

0000«r

2 lor.--- • 3 € : 0 . 2 r 4 ; 0.2 3 6 .1.000. 234309 40.0000

• - • ’ P: • * : - - ■ 16 4 -:2. n • ■:. ■ 6 4 ;. 0:01 205029 4 0 . 0000

4 Pi-rth 185 ■: oc-o; 416521 40.0000

. : 24 0 6 04 2 1 4 2 2 1 .0 0 ; 4 1 3220 40.0000

: ::: 2 6 4 2 2 '7; 253026 40.0000

: 12 0 2: : 74 c ’. 32346 t 6 4 6 6 9- 6 6.47

95 . 17 7 ■.e;= -..331: 166256 53 . 7044 5 3.70

3 2 ■■ . ' 6 - ■■ - - :. p 3 2 ■■ 147073 43 . 8084 4 3.81

: 7 “> : 2 . ; 7 :: : 368070 46 . 1753 4 6.18

■ r;-; :-;p:-- —: 3 3 0 : 4 7 6; ■.4 ■.'■■■ .1.104; 373476 1 4 4. 364 144 4

; - -rijr.T’:v 244 960805 75.0535 75 . 09

■■ ' V 3 4

....i ; ” ' n :

SIMILARITY

751±

Data File: /chem/5972hp60.i/DF020314B60.b/WG16304-1B60_985.d

Report Date: 15-Mar-2030 11:04

Compounds

UUANT SIG


CONCENTRATIONS

ON-COLUMN FINAL


19 1,3 -Dichlorobenzene 146 Compound Non Detected.

20 1,4-Dichlorobenzene 146 Compound Not Detected.

t>9 1,2-Dichlorobenzene 146 Compound Not Detected.

23 2-Methylphenol 106 Compound Not Detected.

24 2.2'-oxvbis(1-Chloropropane) 4 S Compound Not Detected.

27 4-Metnviphenol 106 Compound Not Detected.

23 N - N itrose -di-M- propylamine 70 Compound Not Detected.

29 Hexachioroethane 117 Compound Not Detected.

30 N i t rober.zene 77 Compound Not Detected.

31 T soohoror.e 32 Compound Not Detected.

32 2-NitroDhenol 139 Compound Not Detected.

33 2 4-Dimethy1oheno1 122 Compound Not Detected.

341

Bis (2 -cnloroethoxv>methane 93 Compound Not Detected.

3 5>1

2 . 4 -Dichloropnenol 162 Compound Net Detected.

"■,24 -Tr ichiorobenzene L30 Compound Not Detected.

11 Naphtha Lene1

128 Compound Not Detected.

127 Compound Not Detected.33

39 Hexachiorcbur adiene 225 Compound Not Detected.

4-Chloro-3-methylphenoi 107 Compound Not Detected.

42 7-M^thvlnaDhthalene 142 Compound Not Detected..

Hexacnlorocyclopentadiene 237 Compound Not Detected.

45 2,4 5-Trichioroohenol 156 Compound Not Detected.

- - 2,4,5-Trichlorophenol 196 Compound Not Detected.

2 - Ch I oror.aoht ha i ene 162 Compound Not Detected.1

2 -Nilroani1ine 6 5 Compound Not Detected.

so D met hy Ic-htha late 163 Compound Not Detected.

SIi

2 --Diniirotnuene 16 5 Compound Not Detected.

,iAcenaphthylene 152 Compound Not Detected.

- - N: t roar,:1 1 r.e 13b Compound Not Detected.

5 4 Acenaphthene 154 Compound Not Detected.

2 . 4 - Dm :t rcoheno : 104 Compound Not Detected.

Comoound Not Detected.5 o 4 - N;: rooneno 1

5 7 4 - l t ' c i c-1 j e r. e 16 5 Compound Nc-t Detected.

Compound Det ected.benzolu: u:‘

,, ^_r. Detected.i! i e t hy i or.t r.a .- e

. -U ■.. ;'.:-.er.'.-: e: her 2 7 4 Domonunci N at Detected

165 Comccun: Detected

1 3 6 Compour.:j No- Detected

• .. ....... „... ; Ht: lompeun: : Detected

j . - - .... letectec

24 5 Detected

2 c 5 Compoun t Detected

t .i N • Detectede r. t j z• c: l ;. - r. o . ** 5 -

-v. J. - 178 Com pour. •j No t Detected

. r- .. t Detected. Ar. t r. r a c e r.•*- *

Ccnocun n No t Detected

7 C: -n-buty-tr.a la-e 14 9 it Deteccec

.75'

Data File: /chem/5972hp60.i/DF020314B60.b/WG16304-1B60_985.dReport Date: 15-Mar-2030 11:04

I

i 'jvJANT S I ^

Compounds MASS RT EXP RT REL RT

74 F luoraritnene 2 02 Compound Not Detected


77 But ylbe'nzylphcha lace 14 9 Compound Not Detected

78 3,3' -Dichlorobenzidir.e 252 Compound Not Detected

79 bis(2-ethylhexyi)Phthalate 149 Compound Not Detected

80 Benzo (a,) anthracene 228 Compound Not Detected.

91 Chrysene 22 5 Compound Not Detected.

82 Oi - n- octyiphthalace 14 9 Compound Not Detected.

9 3 Benzo . b:fiuoranthene 252 Compound Not Detected.

84 Benzo :k)fiuoranthene 252 Compound Not Detected.

95 Benzo(a Jpyrene 252 Compound Not Detected.

86 Inaeno(1,2.3-cd)pyrene 276 Compound Not Detected.

87 Dibenzo(a,h)anthracene 278 Compound Not Detected.

B 8 Benzo(g,n,iiperylene 275 Compound Not Detected.

CONCENTRATIONS

ON-COLUMN FINAL

{ NG) I ug/L)

QC Flag 'Legend

M - Compound response manually integrated. i

similar:

i

i

•75

ll

Data File: /cnem/5972hp60.1/DF020314B60.b/UG16304-1B60_965.d Injection Date: 14-MAR-2002 21:40 I nstrument: 5972hp60.1 Client Sample 11D: SBLKJG

hound: 2"Number:

.4.6-Tribromophenol 1ll3-79-6

Ion 329.60: Area: 278476 Height: 132184

1 • 3-

1.2-

1.1-

1-0- 0.9-.

0.8- in 0.7-

? °'6-

0.5

0.4-

0.3-;

0.2- 0.1 - 0. 0 - —

14.30 14.3* 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.7' __________ H l n

14.80 14.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20 15.25


0.4

0.1

:4 . :o 14.35 14.40 14.45 14.50 14.55 14.60 1J.65 M . 70 14.75 14.60 14.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20 15.25IMj_n

Ion 141.00: Area; o neignt: 0

0. d75

4 15 14.40 14.45 14.50 14.5b 14,60 14.6b 4 14.75 14.80 14.85 14.90 14.95 15.00 15.05 lb.10 15.15 15.20 15.25M: n ______________________________ _______________

CompuCjhema Division of Libert) Analytical Corp.

! GC/MS SEMI-VOA WORKSHEET

I

LAB INSTRUCTIONS:

RECEIPT DATE: 3/14/02 0:00 SAMPLE DATE: DUE DATE:

CASE?: | SDG: WGI6304 COMPUCHEM #: WG16304-1

CLIENT ID: SBLKJG


Injection Volume :IpL Dilution Prep (if needed)l|

Extraction Date__ 3___/14____/___02

DFTPP Filename____ DF020314B60

Sample File Name____ WG16304-1 B60 „ ______________

ANAL.YST(S). Injection2310Work-up__________________________

GC/MS DATE REVIEW

CONDITION CODE

6^


Number of peaks found:

Number of Hits found:______ ______

Number of Surrogate Outliers_______

Quality Assurance Notice is) Q Number of Notices Required

i 1-------

/cDisposition: [ ^ Complete


j ] Re-extraction Required

[ ] Reinject Neat

| ] Dilute t X)

C comments.

-GC/MS Review_____ Date /N Auditor_

Final Reportable Packaeels): ^ rs*'

Date / /

75j

SV1 - 6/27/01: PTF

c. Laboratory Control Sample Data

Arranged in chronological order, by extraction date



757


CLIENT SAMPLE NO.

SIBLCSLab Name: COMPUCHEM

Lab Code: LIBRTY Case No.:}




% Moisture: decanted: (Y/N)

Contract: 8270C

SAS No.:



GPC Cleanup: (Y/N) N pH: ___

SDG No.: QE1877


Lab File ID: WG16194-2JB64_985

Date Received:





108-95-2---------Phenol 23111-44-4---------Bis (2 - chloroethyl) ether 3895-57-8----------2 - Chlorophenol 35541-73-1-------- 1,3 - Di chlorobenzene 25106-46-7-------- 1,4 - Dichlorobenzene 26S5-50-1----------1,2 - Dichlorobenzene 2695-4 3- 7----:----- 2 -Methylphenol 55108 -6 0-1-------- 2,2' - oxybis (1 - Chloropropane ) 40106 -44-5---------4 -Methyl phenol 100621- 6 4- 7-------- N-Nitroso-di - N-propylamine 5267 - 72 - 1 ----------Hexachloroethane 2593 - 95- 3 ----------Nitrobenzene 387 8 - 59- 1----------I sophorone 5133 -75 - 5 ----------2 -Nitrophenol 40105-67-9-------- 2,4 - Dimethyl phenol 36111-91-1-------- Bis (2 - chloroethoxy) methane 54120-8 3 - 2-------- 2,4 - Dichlorophenol 4412 0- 82-1-------- 1,2,4 -Trichlorobenzene 3191-20-3----------Naphthalene 32106 -47- 3 -------- 4 - Chloroani 1 me 7437 - 66 - 3 ----------Hexachlorobutaaiene 3159 -50 -7----------4 -Chloro- 3 -methylphenol 5891-57-6----------2 - Methylnaphthaiene 59

i 77 -47-4----------Hexachlorocyclopentadiene 32; 33 - 06 - 2 ----------2,4,6 -Trichiorop’nenoi 5395-95 -4----------2,4,5 -Trichlorophenol 6991-53-7----------2 - Chi oronapht ha lene 5033 - 74 - 4 ---------- 2 -Nitroaniline 79

j I 31-11-3-------- Dime t hy lpht ha late 736 06 -20-2-------- 2, 6 - Dmitro toluene 58

: 2 0 6 - 96 -3-------- Acenaphthylene 489?-09-2----------3 - Ni t roam 1 me 85

; b2 - 32 - 9----------Acenapnthene 441

FORM I SV 8270C

Lab Name:

Lab Code:


Sample wt/vol:

Level:1 (low/med)


Concentrated Extract Volume: 1000(uL)i

Inject.ion Volume: 1.0 (uL)



Lab File ID: WG16194-2JB64_985

Date Received:





CLIENT SAMPLE NO.

SIBLCSCOMPUCHEM

LIBRTY Case No.:

WATER

1000 (g/mL) ML

LOW

Contract: 8270C



51-28-5----------2,4-Dinit rophenol 150i 100-02 - 7-------- 4-Nitrophenol 29121-14-2-------- 2 , 4 - Dinitrotoluene 59

i 132 -64 - 9 -------- Dibenzofuran 73| 84 - 66 -2 ----------Diethylphthalate 71; 7005-72-3------- 4 -Chlorophenyl-phenylether 69,j 86-73 -7----------Fluorene 511 100-01-6-------- 4-Nitroanil ine 78l 534-52-1---------4,6 - Dinit ro- 2 - methylphenol 771 86 - 30-6 ----------N-Nitrosodiphenylamine (1) 69, 101-55-3---------4 - Bromophenyl - phenyletEer 71• 118-74-1-------- Hexa chlorobenzene 6137- 8 6- 5 ----------Pentachlorophenol 523 5-01-8----------Phenanthrene 5312 0-12-7-------- Anthracene 54

; 8 6- 74-8 ----------Carbazole 798 4- 74-2-----J--- Di-n-butylphthalate 70

.2 06 -44- 0 -------- Fluoranthene 53j 12 9 - 00 - 0 -------- Pyrene 52

1 1 85 - 65 - 7 ----------Butylbenzylphthalate 70t91-94-l----------3,3' - Dichiorobenzidine 451 117 - 31 - 7---------bis ( 2 - ethyl hexyl) Phthalate 75 B56 - 55 - 3 ----------Benzo (a) anthracene 53

j 54i 117-84-0-------- Di - n -octylphthalate 6 8

i2 0 r - 9 9 - 2-------- Benzo ! b) t1uoranthene 4 3

! - u / - -j - - -------- senzoi k i r i uorant nene 6 5 .! n-s - Benzo ( a ) pyrene 52

i 9 i - i a - r>-------- I ndeno (1,2,3- cd ) pyrene 64; s4 - 7u - 3----------Dibenzo (a, h) anthracene 53

i I :n -1- -2-------- Benzo' g , h , i! oervleneIJ____________ ._____________

52

i lZ - Cannot be separated irom DiphenylamineFORM I SV 8270C

753

Data File: /chem/5972hp64.i/DF020311B64.b/WG16194-2JB64_985.d

Date : 12-MAR-2002 04:27

Client ID; SIBLCS

Sample Info:


Column phase: RTX-5


<LO

Operator; 2319 r^-


Sample Info:


Column phase: RTM-5 Column diameter: 0,32

Data File: 7chem/5972hp64.i/DF020311B64.b/WG16194-2JB64_985.d

Date : 12-MAR-2002 04:27

Client ID: SIBLCS Instrument: 5972hp64.i

T9 Z

Data File: /chem/5972hp64.i/DF020311B64.b/WG16194-2JB64_985.dReport Date: 13-Mar-2030 12:57

CompuChem

Data file Lab Smp Id Inj Date Operator Smp Info Misc Info

Semivolatile Report SW-846 Method 8270C /chem/5 9 72hp64.i/DF02 0311B64.b/WG16194- 2JB6 4_98 5.d WG16230-2 Client Smp ID: SIBLCS12-MAR- 2 0 0 2 04:272319 Inst ID: 5972hp64.i

Comment Method Meth Date Cal Date Als bottle Dil Factior

Integrator Target Version: Processing Host:

/chem/5972hp64 12-Mar- 2 03 0 08 10-MAR-2002 17 111 . 00000 HP RTE

3 . 50einstein

i/DF020311B64.b/8270Cv6.m 15 mikhael Quant Type: ISTD 23 Cal File: HL020310A64.d

QC Sample: LCS




DFVt

VdVi

1.00000 Dilution Factor1000.00000 Volume of final extract (uL)1000.00000 Volume of sample extracted (mL)1.00000 Volume injected (uL)


CONCENTRATIONS

Compc ends MASg RT EX? RT REL RT RESPONSE

ON-COLUMN

( NG)

FINAL

( ug/L)

: 1 , 4 2: c c-.-i- i.; 2 52 5.2S-: -. :di ;:. ooo: 102221 40.0000

2 Nae::c r.A -. ■. . : i. - 353654 40.0000

Ac Tt.iip:', ■■ ■ -.-.r : • : 7. 2 7 1 £ 4 0 ■i 'J . 0 0 ‘ J V

4 Phena;:: 1 5 .1 - i ■ 5.4 = 2 ■. i.ooo; 546779 40.0000

vs-:'. 2 4 9 - : 1 . 000) 522377 40.0000

2 64 :• 2 - ; i.ooo: 306460 40.0000

:: 2 . i" ■■ -..4 55 ;c. 7si; 179437 54 . 0791 54.08

:■ : - -It 7 v 9. 7 (Q.oio i 151914 44.4033 4 4.40

N:: roco 6 2 5 . } C 9 (0.397} 164844 39.701 7 39.70

: c 2 -FI uor- ir.:?r.er.y\ 172 : : ii.; :10. S02.» 472192 52 . 1 370 52 . 14

; 1 : C . I . ■ 7 '■ r:■ ■

4 4 ■: 2 (2.0 0 9 ' 313166 114.421 114.4

' ' ? Terphe:' : • d *. •; 2' •' . - •> 7 (0.8951 851392 61 . 5 5 7 4 6 1 . 57

Pn-nc! Vi 7 7 7 : ~ . 7 74 10.941/ 8 6 0 21 23 . 1 593 2 3.16

: 7 5 : c • 2 :Ic:-oec.-.y '.•j: O'.'v (0 5 57’ 9 6 3 5 5 38 . 3972 3 8.40

SIMILARITV

«\

7 67


Compounds

18

1 9

20

22

23

24

2 9

30

31

32

33

34

3b

2 -Chlorophenoi

1.3- Dichlorobenzenei|


1,2-Dichlorobenzene

2-Methyl phenol

2,2'-oxybis(l'Chloropropane)

4 -Methylphenol N- Hitrojso - d i - N-propylamine

Hexachloroethane

Nitrobenzene

Isopherone

2-Nitrophenol

2.4- Dimethylphenol

3is(2 -chioroethoxy)methane

2,4 -Dich1orophenol

Naphtha 1 ene

4 - Ch 1 o roan: lire

Hexacr. 1 orobut ad i ene

4-Chicrc-i•methyipheno1

2 - Methvinapht ha 1enei!

He.xacn 1 oroc: inert a di er.e

2 - Ch 1 oror.aph: ha 1 ene

2 - Ni t roar.: 1 : re

A "■

3 - r;

D: r.:

I

CONCENTRATIONS

ANT SIG ON-COLUMN FINAL

MASS RT EXP RT REL RT RESPONSE ( NG) ( ug/L) SIMILARITY

128 0.012 8 . 010 (0.969) 121260 35 . 3038 35 . 30 8808 .

14 6 8 .215 8.213 (0.994) 99454 25.2018 25.20 (Ml-

14b 8 .282 8 . 281 (1.002) 104046 26.1293 26 . 13 (M) \

146 8 . 570 9.568 (1.037) 103477 26.4015 26.40 (Ml \

109 8 .637 S . 636 (1.045) 163495 54.5867 54 . 59

45 8 . 671 8 . 670 (1.049) 184988 39.6968 39.700 (M! \

105 8 . 6 4 0 6.639 (1.0701 329904 101 . 336 101 . 3

70 8 .874 5.873 (1.074) 105919 51.6234 51 . 62 7152

117 9.009 9.008 (1.090) 51327 24 . 9068 24 . 91 9420

77 9 . 128 9 . 126 (0.098) 123246 37.8087 37.81 9727

32 9.449 9.448 (0.930) 326389 50.5670 50.57 94 70

139 9 . 601 9 . 600 (0.945) 82588 40.1313 40.13 8316

122 9 . 601 9 . 6 0 C (0.945) 11064 0 36.0718 36.07 7 351

9 3 9.753 9.752 (0.960) 207323 S3 . 8162 53 . 82 9528

162 5 . 939 9 . 938 (0.978) 141073 44 .4068 44.41

1 8 0 10.075 10 073 (0.9921 114208 3 0 . 3 3 0 3 30.63(Ml\

1 2 5 10.176 10.175 (1 . 002) 442021 31 . 8774 31 . 88 97 8 7

127 10.260 10.259 11.010) 327430 73.3439 7 3 84 8398

225 10 4 3 0 10.426 •: l .027) 77997 30.5732 30 . 57 8905

I 0 7 1 o . 9 3 7 1 0 9 3 (1 .077 1 203005 57 . 5173 57 52 9759

14 2 11.224 - 1 2 2 1 < 1 . 10 5 1 407390 58.6177 58 . 62

2 3 11 613 i: .59-; i 0 . 8 6 2 ' 86395 32.0838 32.0B 95 3 0

I 1 . 7 4 t 11 74"“ (0.892) 147590 53.3472 53.35

196 11.933 11.931 (0 . B99) 201313 68.5897 68 . 59

162 - -> 170 12.115 (0.920) 349265 50.0772 50 . 08

r c 12.357 12.355 ( 0 . 938) 196772 78 .8135 78.81 9 3 6 2

1 r:. T 12.675 12.677 (0.9631 618923 72.6246 72.62 94 76

!«5 12.547 12 84 6 ( 0.976 1 136045 58.0147 58.01 3505

• - 1 -> pee : "! 3f, 10.579) 778690 47.5652 47.57 9572

13.101 : • .0 = 2 (0.995) 211656 100.007 100.0 384 3

: 54 1 2 : i :■ 1 : 213 ' 1 .004) 466566 44 . 033 1 44 . 03 97 5 5 V

1 3 2 7 3 : 3 2 - ^ ;i.0081 62090 149.706 149.7(MJ ^

;o v 13.321 : 3 . 3 : s 2 0 12) 4 2636 28 . 8769 28.68 7375

;;; 13 . 32 ■ : i. C27) 200634 59.0322 59.03 8256

.=■; : • '1 0241 801652 73.0753 73.08 9029

: 1 0 54 1 719299 71 . 3188 71.32 9205

26 4 14 . 0 1 4 4 :2 : 064 1 326801 69 . 3520 69.35 7124

■■ •= - ■ 04 5 i 1 .067) 639064 5 0.7683 50.77 7 64 2

■: - : 5 ■ - - : (i 272; 202152 78.2362 78 . 24 9 9 97

0 - : - • • rv 91. 6 : 170943 77 .2223 7 7.22 92 3 6

■. : ;■ = 408875 68 . 654 3 6 8.65 ; ? i ■;

24 - : 0 2 54: 206945 7 1 . 34 57 7 1.35 3 4 0 4

2 - 4 •' '•. -72 , 2 1 6839 -0 . 3051 6 0 8 ! G •" ' “i2-. ■ :: 2-: : . - 124525 r12 . 4 6 0 _• 52 4 6 9114

:" - : : - i . : 2 • ; C 7 1 04 0 52.6393 52 . 64

: - :::;555 53.7038 5 3.70

■ - : '3 21.' 1079451 79.3092 79 3 1 9577


Compounds

7 3 Di-n-butylphchalate

74 Fluoranthene

76 Pyrene'

77 Bucylbenzylphchalate

78 3.3'-Diehlorobenzidine

79 bis:2-ethylhexyl)Phthalate

60 Bento 1 a)anthracene

5 2 D: - n - octy iphr.na late

83 Bento <r)fluoranthene

34 Bentoik)fluoranthene

S5 Bento(a)pyrene

So Indeno(1.2,3 *cd>pyrene

87 Dibento(a,h)anthracene

Q8 Bento(g,h,i)perylene

CONCENTRATICNS

QUANT SIG ON-COLUMN FINAL

MASS RT EXP RT REL RT RESPONSE ( NG) ( ug/L) SIMILARITY

14? 16 . 229 16 . 227 (1.048) 1418017 69.6355 69.69 9725

202 17.27.7 17.275 (1.116) 1241594 52.9328 52.93

2 02 17.659 17.698 (0.887) 1291697 51.5619 51.56

14 9 18 . 832 18.814 (0.943) 700167 69 . 6468 69 . 65 9 3 5 6

2 92 19.846 19.845 (0.994) 322116 45 .4938 45.49 8038

149 19.796 19.794 (0.992) 1128234 75.2516 75.25 944 8

2 2 9 19.931 19.930 (0.998) 1228664 53.4670 53 .49

225 2 C .016 20.014 (1 003' 1179935 54 .4850 54.49

149 20 . 776 20.775 *0.925) 1183819 68.2482 68.25

2 62 21.706 21 . 705 (0 . 967) 714 16 6 4 3 .4509 43 .45

252 21 . 757 21 . 756 (0.969) 959823 64 .6214 64 . 62

252 22.349 22.347 (0.995) 682969 52.4460 52 .45

276 25.054 25.052 (1.116) 599532 63.7143 63.71 7260

27b 25.037 25.035 (1.115) 602501 52.7726 52.77 8008

276 25.865 25.864 (1 . 152) 627523 52.4138 52.41 9351

QC Flag!Legend


1

I i

i

764

Data File: /chem/5972hp64.1/DF020311B64.b/WGl6194-2JB64_985.aInjection Date: 12-MAR-2002 04:27Instrument: 5972hp64.iClient Sample ID: SIBLCS

ound: 2

Number:

41 6-Tnbromophenol

118-79-6

Ion 329.60: Area: 313166 Height: 204378

2.0-

1.8-

1 .6-

1.4-

1.2-

1.0-

0.8'

0.6-

0.4-

0.2'

0.0-14.00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.85 14.90 14.95

________________________ ____ MinIon 332.00: Area: 0 Height: 0

1.9.

1.8-

1 .

1.6-

1.5-

1 . 4- I 1 . 3-

i.2- 1.1-

1.0-

0.9 ■

0.6-

0.7-

u. 6-

0.5-

0.4-

0.1-

0.2-.

0.1-

u n-14.00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.85 14.90 14.95]

i________________ ,Min_________________________________________________ ________ _________________________ I


76:J ;

14.00 |1 J .05 IJ . 10 1 J . !5 1 J . 20 1J .25 1 J . 30 14.35 14.40 1 J . 45 1 4.5.0 14.55 14.60 14.65 14.70 14,75 14.80 14.85 14.90 14.95 :j __ Min I

Data File: /chem/5972hp64.1/DF020311B64.b/UG16l94-2JB64_985.d Injection Date: 12-MAR-2002 04:27 Instrument: 5972hp64.1 Client Sample 11D: SIBLCS

#ound: 1.3-D 1chlorobenzene Number: 541-73-1

6.8-

6.4-

6.0-

5.6- ;

5.2-

4.8-

4'. 4-

4.0-

3.6-

■7

2.8-

2.4-

2.0-

1.6-

1.2-

Ion 146.00: Area: 99454 Height: 71968a

1 I

u. d-

0.4-,

/

i1i \

7.75 7.80 7.85 7.90 7.95 8.00 8.05 8.'l0

i8.15 8.20

Min8.25 8.30 8.35 8.40 8.45 8.50 8.55 B .60 8.65 8.70


4.5- ! i4.2- i li3.9- il n

| I , i

.80 7.65 '. 90 .95 8. no 8.05 B. 10 8.15 8.20 8. ____________ ____ M l n

8.30 8.35 8.40 8.45 8.50 8.55 8.60 8.65 8.701

Ion 111.00: Area: 0 Heignt: 0

l

1.4 ;

I

2.0

1 C;.

1 . 0-

".60 7.85 7.90 ".95 8.00 8.05 0.10 8.15 8.20 6.25 8.30 8.35 8.40 8.45 8.50 8.55 8.60 8.65 8.70

Mm

II

Data File: /chem/5972hp64.1/DF020311B64.b/LIG16194-2JB64_985.d Injection Date: 12-MAR-2002 04:27 Instrument: 5972hp64.i Client Sample! ID: SIBLC5

Mm*ound: 1

Numoer:. 4-Dichlorobenzene 1 Ob-46-7

6.8

6.4-

6.0

5.6-

5.2-

4.8-

4.4

4.0-

Ion 146.00: Area: 104046 Height: 64736

i hiI CD

I ;

. b-

2.4-'2.0-' ’

1.6-

1.2-

0.8,0.4- |

i •i •i i

/ ' 1

j \ •'

1

i /

L , i

7.80 17.85 7.90 7.95 8.00 8.05 0.10 8.'l5 8.20 8.25

Min8.30 8.35 8.40 8.45 8.50 8.55 8.60 B.65 8.70 8.75


4.5- iOD 1

n hi 14.2- 1

CD3.9- ‘ i 1 |

3.6- j;

1 ; |

i i

1 !! i

' 11 :

6-

3

(i- —\60 |7.85 7. or, 795 8.00 8.05 8.10 8.15 6.20 8.25 6.30 8.35 8.40 0.45 8.50 8.55 8.60 8.65 8.70 8.75

.__ MinIon 111.00: Area:

l

0 Height: 0

j Ii iI !j i ' i ' Ij 1

I !

767 !

8.1L 8.25 S. 30 8.35 6.40 8.45 0.50 8.55 8.60 8.65 8.70 6.75 Min

I

Data File: /chem/5972hp64.i/DF0203llB64.b/LJG16l94-2JB64_985.d Injection Date: 12-MAR-2002 04:27 Instrument: 5972hp64.1 Client Sample ID: 5IBLCS

ound: 1. Number:

2--Dichlorobenzene95-50-1

6. fi

fe. 4-

6.0- 5.6-'.

5.2-;

4.8-

4.4-

4.0-

3. fe

lon 146.00: Area: 103477 Height: 70171

0

1

~‘ T O.!

2.8-

2.4-

. 2.0- i i

i 1.6- f i] !

1

1.2- / I\ I

j

0.6- i \ 1 1

0.4-/

i \

3.10 a. 15 3.20 8.25 8.30 8.35 8.40 8.45 8.50 8.55 8 60 8.65 8.70 8.75 8.80 8.85 8.90 8.95 9.00 9.05Min


4.5- 1 CDa

4.2- CD

3.9-!!

8.10' 8.15 8.20 >.25 8.30 8.35 8.40 8.45 8.50 8.55 8.60 6.65 8.70 8.75 8.80 8.85 8.90 B.95M l n

I9.00 9.05 i


2.e-

o. 10

76 o

o.i.' o. .40 8.45 8.50 6.55 8.60 8.65 8.70 8.75 8.80 B.85 8.90 8.95 9.00 9.05M l ri

I

Data File: /chem/5972hp64. 1/DF020311B64.b/UJG16194-2JB64_985.d Injection Date: 12-MAR-2002 04:27 Instrument: 5972hp64.i Client Sample ID: 5IBLC5

ouna: 2,2j'-oxybis( 1-Chloropropane)

Mumper: 108-60-1

8.5-

8.0

7.5-

7.0- :

6.5-

6.0- ;

5.5- :

5.0- :

4.5- '

4.0-

3.5-

2.5-

Ion 45.00: Area: 184988 Height: 88448

f.\

CD

1.5-

1 .0-

0.5- 0.0-

8.20 8.25 3.30 3.35 8.40 B. 45 8.50 B.55 8.60 8.65 8.70 B.75 8.80 8.85 8.90 8.95 9.00 9.05 9.10 9.15Min _______ _________ __

1 . 7-

1.6-

1.5-

1.4-

1.3-'

i;:;:1 . Ci-

0. 9- 0.6-

O 7-


P k

I !

8.40 0.45 8.50 8.55 8.60 8.65 8.70 8.75 8.80 8.85 8.90 8.95K i n

9.00 9.05 9.10 9.15


i I

/ \:/ \:

' »£»“

■ CD

7 6 $

8.55 3.60 8.65 8.7vM i n

3.75 8.80 8.85 8.90 8.95 9.00 9.05 9.10 9,15

Data File: /chem/5972hp64.1 /DF020311B64 . b/UG16194-2JB64_985. dInjection Date: 12-MAR-2002 04:27Instrument: 5972hp64.1Client Sample ID: 5IBLCS

#ouna: 1.2M-TrichlorobenzeneNumber: 120-82-1

6.4- 6.0-

5.6'

5.2-

4.8-

4.4-

4.0-

3.6-'

3.2-2.0-

Ion 180.00: Area: 114208 Height: 65113

2.0-

1.6-

1.2-

0.8-

0.4-;

0.0-

9.60 9.65 9.70 9.75 9.80 9.85 9.90 9.95 10.00 10.05 10.10 10.15 10.20 10.25 10.30 10.35 10.40 10.45 10.50 10.55Min ___ ____

b. u-

5.6-


9.75 9.8C .85 9.90 9.95 10.00 10.05 10.10 10.15 10/20 10.25 10.30 10.35 10.40 10.45 10.50 10.55 M i n


77U

o—9.60 9.65 9.70 35 9.90 9.95 10.00 10.05 10.10 10.15 10.20 10.25 10.30 10.35 10.40 10.45 10.50 10.55 ;

Mm I

Data File: /chem/5972hp64.i/DF020311B64.b/ldG16194-2JB64_985.d Injection Date: 12-MAR-2002 04:2?Instrument: 5972hp64.1 Client Sample!ID: SIBLCS

ound: 2.4-DiniTropheno1

Number: 51-28-5

4.2-

3.9-^

3.6-

3.3-

3.0- ;

2 7"

2-4-

2.1-

1.8-

1.5-

1.2-

0.9-

0.6-

0.3-

0.0-

Ion 184.00: Area: 62090 Height: 41803

12.80 12.85 12.90 12.95 13.00 13.05 13.10 13.15 13.20 13.25 13.30 13.35 13.40 13.45 13.50 13.55 13.60 13.65 13.70 13.75Min _____ _________________ ____

2. 5Ion 154.00: Area: 0 Height: 0

.d'J i _ . o‘jj * •' .90 1 1.05 13.00 13.05 13.10 13.15 13.20 13.25 13.30 13.35 13.40 13.45 13.50 13.55 13,60 13.65 13.70 13.751

ion Gj.ijij: wrea: Height: 0

77 J_l

=, 1 3 70 ' 7 7=, 13.40 13.45 13.50 13.55 13.60 13.65 13.70 13.75

CompuChema Division ot" Liberty Analytical Corp.


LAB INSTRUCTIONS:

RECEIPT DATE:

CASE#: ' SDG:


COMPUCHEM#: /6' / f

CLIENT ID: J j fi [ C (,'ANALYSIS DESCRIPTION:

Injection jVolume :pL Dilution Prep (if needed)

Extraction Date___3 / /i /__0_Z___

DFTPP Filename t c \ / / /l C y-

Sample File Name (// /fV ■ / r

ANALYST (S): Injection2 1 / V_______________ Work-up/ 7

GC/MS DATE REVIEWI

CONDITION CODE


Number of peaks found: l\M

Number of Hits found:____Q

Number of Surrogate Outliers: (J)

(duality Assurance Notice (s) Number of Notices Required (jj

Comments:

Disposition: [ uj'Complete

[ 1 Reinjection Required

[ j Re-extraction Required

1 ] Reinject Neat

[ ' ] Dilute ( X)

Final Reportable Package! si

_ DmcJ. jJ f£. Auditor

_uj.(ri L \ciH- 2Flx-'~(

Date

77c

SV1 - 6/27/01: PTF

/

Analyst initials Extracted

53(/c&_KD

Initials" bate

l>I ionic up

Manufacturer and lot number of reagents/solvenls used

COM ' # '

\\ i I ness

mi 1l rsi


CLIENT SAMPLE NO.

'ii

Lab Name: COMPUCHEM Contract: 8270CSIILCS

Lab Code: LIBRTY Case No.: SAS No. : SDG No.: QE1877

Matrix: (soil/water)l

WATER Lab Sample ID: WG16228-2

Sample wt/vol : 1000 (g/mL) ML Lab File ID: WG16228-2A60

Level : (low/med) LOW Date Received:

% Mois ture : decanted: (Y/N) Date Extracted : 03/10/02

Concentrated Extract]

Volume: 1000(uL) Date Analyzed: 03/12/02

1Injection Volume: 1.0(uL) Dilution Factor: 1.0



. 108-95-2-------- Phenol 251 111-44-4---------Bis(2-chloroethyl)ether 69I 95-57-8----------2 - Chlorophenol 60541- 73 - 1 -------- 1,3 -Dichlorobenzene 58106-46-7---------1,4 -Di chlorobenzene 5995-50-1----------1, 2-Dichlorobenzene 5895-48-7----------2-Methylphenol 69

: 108-60-1-------- 2,2'-oxybis (1 -Chloropropane) 67106-44-5---------4-Methylphenol 100621 -64 -7-------- N-Nitroso-di -N-propylamine 69

| 67-72 - 1 ----------Hexachloroethane 6098 - 95- 3 ----------Nitrobenzene 6878-59-1----------I sophorone 68

; S3-75-5----------2-Nitrophenol 73J 105 - 67- 9---------2 , 4 - Dimethylphenol 25111-91-1-------- Bis(2 - chloroethoxy) methane 74

i 120-S3-2-------- 2,4 - Di chlorophenol 77; 120-82-1-------- 1,2,4 -Tri chlorobenzene 71

i 91-20-3----------Naphthalene 7610 6- 47- 3 -------- 4 - Chloroani 1 me 74

1 8 7- 68 - 3 ----------Hexachlorobutadiene 755 9 - 50- 7 ----------4 - Chloro - 3 - methylphenol 689 1-57 -6----------2 -Methylnaphthaiene 86-

1 77-47-4----------Hexachlorocyclopentadiene 66■ 3 3 - 06 - 2 ---------- 2,4,6 - Trich 1 orophenol 851 95 - 95-4----------2,4,5 - Tr i chlorophenol 1101 91-53-7----------2 - Chloronaphthalene 74

78131-11-3-------- Dime t hv ipht ha la te 88

[ 5 05 -2 0 - 2---------2,6 -Dimtrotoiuene 81] 2 03- 96 -8-------- Acenapht nylene 82■ 9 9- 0 9- 2----------3 -Nit roan 111 ne 75! 83 - 32 - 9 ----------Acenaphthene 8 7

FORM I SV 8270C

774


CLIENT SAMPLE NO.



Matrix: (soil/water) WATER1

Sample; wt/vol: 1000 (g/mL) ML

Level :; (low/med) LOW

% Moisture: _______


Injection Volume:

GPC Cleanup: (Y/N)

decanted: (Y/N)

Volume: 1000(uL)

1.0(uL)

N pH : ___

8270C

SDG

Lab Sample ID:

Lab File ID:

Date Received:

Date

Date

Dilution

SIILCS

No.: QE1877

WG16228-2

WG16228-2A60

Extracted:03/10/02

Analyzed: 03/12/02

Factor: 1.0



51-2 8- 5----------2,4 -Dinitrophenol 34 J10 0- 02-7---------4 -Nitrophenol 38121-14-2-------- 2,4-Dinit ro toluene 78

1 132 - 64 -9---------Dibenzofuran 9184 -66 -2 ----------Diethylphthalate 86

j 7005-72-3 ------- 4-Chloropheny1-phenylether 96| 86 -73 -7--------- Fluorene 941 100-01-6-------- 4 - Nitroaniline 80: 5 34 - 52-1---------4,6 - Dim t ro - 2 - methylphenol 64.86 -30- 6 ----------N- Ni trosodi phenyl amine (1) 81(101-55-3---------4 - Bromophenyl - phenyl etHer 88: 118-74 -1-------- Hexachlorobenzene 81.87-86-5----------Pentachlorophenol 83

■ 35-01-8----------Phenanthrene 87112 0-12-7---------Anthracene 91

i '36 - 74 -8 ----------Carbazole 100i 34 - 74 - 2 ----------Di -n-butylphthalate 83I 20 6 - 44-0-------- Fluoranthene 92‘12 9- 00 - 0 -------- Pyrene 788 5- 6 8 - 7----------Butyl benzylphtnalate 69

j 51-94-1----------3,3' -Dichlorobenzidine 33: 11 7 - 8 1-7-------- bis(2-ethylhexyl)Phthalate 81 B

94:2IS-'j1-5-------- Chrysene 91'117-34 - 0---------Di - n - octy lp'nt ha late 78i z c d - - 2-------- Benzo ( b ) 11 uoranc hene 79

| j2 u / d e - Benzo ( k) f luoranthene 110i do - j2 - 8----------Benzo (a) pyrene 89

1 153 -39-5------ - - Indeno(1,2,3-cd)pyrene 8297

! l 51 -1- - 2-------- Benzo • g, h, i) perylenei )

96

- Cannot De separacec from DiphenylamineFORM I SV 8270C

7 7 o

Data Fi le: /chem/5972hp60* i/DF0203'12A604b/UG16228-2A60td

Date J 12-MAR-2002 15:08

Client ID: SIILC3

Sample Info:

Volume Injected <uL>: 1*0

Column phase: J&W DE-5*825

Instrufient: 5‘:-172hpb0« i

Operator: 017


. _U

■=Ebeaanthrene-ctLQ

Data File: /chem/5972hp80* i/BF020312At-0.b/MGl&228-2fibO,d

Date : 12-HAR-2002 15:08

Client ID: SIILCS

Sample Info:


Column phase; J8.W DB-5.S25

Instrument: 5972hpb0. l

Operator: 917


4.0-

3,9-i

3.8- ;

3.7- i

3.6-i

3.6- i

3.4- i

3.3- .

3.Z-

3.It

3.0- i

2.9- :

2.8- i

2.7-

2.6r

2.5-

2.4- i

2.3- i

2.2-i

2.1- i

2.0 -j

1.9- i

1.8- i 1.7-i

1.6- i

1.5

1.4-

1.3

1.21.1- i

l.o-;

0.9-

0.8

0.7-1

O.b-i

0.6

0.4-

0.3

0.2

0.1

2chem/5972hp60.i/DF020312A&0,b/WGlb22 2Ab0.d (Part 2 of 2)

19 2418 21

77


CompuChem

Data file Lab Smp id Inj Date( Operator Smp Info Misc Info Comment [ Method Meth Date Cal Date

Semivolatile Report SW-846 Method 8270C /chem/5 9 72hp6 0.i/DF020312A60.b/WG16228-2A60.d WG16 2 2 8-212-MAR- 2 0 0 2 15:08 917

Client Smp ID: SIILCS

Inst ID: 5 972hp6 0.i

/chem/5972hp60.i/DF020312A60 13-Mar-2030 09:03 byrd 0 3-MAR- 2 0 0 2 17:20

b/8270Cv6.mQuant'Type: ISTDCal File: HL020303A60

Als bottle: 9 QC Sample: LCSDil Factor: 1. 00000Integrator: HP RTE Compound Sublist: OLM03Target Version : 3.50Processing Host: einstein

iConcentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable

Namei

Value Descript ion

DF i1.00000 Dilution Factor

vt ; 1000 . 00000 Volume of final extract (uL)^ Vo 1 1000.00000 Volume of sample extracted (mL)

1 . 00000 Volume injected (uL)


CONCENTRATIONSyUANT SIG ON-COLUMN FINAL

7,„o„:s | MASS rt rt eel rt RESPONSE ( NG) ( uq/L)

* I 1 , 4 - 2:ch:d rc recce. 152 E 14 2 3.123 : : . 20:1 ; 90344 4 0 . 0000• 2 Napht ha iene - a? I 36 I : . 2 5 : 12.233 : 1 .0 2 Li 237905 40.0000

- ci I 0 164 ■2.372 1•.551 ; I .00 0: 193219 4 0 . 0000- d: j i a 9 :;.ooo: 398121 40.0000

t Ch:-ys~::e-dI2 U *» t' 20.RR7 p::..;cr LLr.- 4 97122 4 0.0000yiK;;:: ^ 2 3.1 3 2 :. 3 . 1 •' . 1 :• C 0 ' 420215 40.0000

I "I 2 • F 1 co:'Opr;-5:-. r.: 1 : : 6.:2” ■- '740 225227 79.7326 79.73: r Ph-i-o:-..:? o t -■ • - 174227 53.7046 53.70: • —e::- • d 7 52 v . •• .-...E: 249971 73.4870 73.45t i - j - F : c o v z'~ : z :i ••'V. : 7 2 12.122 1 .. 1 • • r 1 534468 77.5023 77.90

:: v ■ T: Jc:-c to;;;-:-: .cc c 1 . 1 ■ i 350060 214.563 2 i 4 . 5244 17 “ -: ' : 211 1 2 3 02 3 ? 74.5654 74 ^7

:} •; 7906:.’ 24 9569 25.00V y-.r : ■ p::?: V ... .... _..;r 6 5 . 7 ] 5 7 t S . 7 2

sub

SIMILARITY

&

77 o


CONCENTRATIONS


Compounds MASS RT EXP RT REL RT RESPONSE ( NG) ( ug/L) SIMILARITY

IS 2-Chlorophenoi 128 7.804 7.785 (0.958) 147787 60 . 1582 60 . 16 COCD O O'.

15 1,3-Oichlorobenzene 146 8.040 8 . 021 (0 . 988) 194018 57.5946 57.59

20 1,4-Dichlorobenzene 146 8 . 176 8 . 157 (1.004) 196435 58 . 5220 58.52

22 1,2-Dichlorobenzene 146 8.413 8.411 (1.033) 188020 58 . 1930 58.19

23 2-Methy1phenol 108 8.599 8.580 (1.056) 138153 69.2883 69.29

24 2,2' -o>:y cis(l-Chloropropane) 45 8.599 8 . 597 (1.056) 204291 66.5935 66 . 59 7053

27 4-Methylpnenol 108 8 . 852 8 . 834 (1.037) 262349 103 534 10 3.5

23 N-Niz roso-di-M-propylamine 70 8.836 8.817 (1.085) 126029 68 . 52 94 6 8.53 74 14

25 Hexach•oroechane 117 8 . 988 8.969 (1 . 104) 86298 60.2535 60.25 8 94

3 0 Nitre-her. :ene 77 5.105 5.087 (0.885) 199468 67.5972 6 7.6 0 S S 8 5

3 1 I sophorc 82 5.512 9.493 (0.924 ) 318148 68 .4692 63 .47 £ 7 8 4

3 2 2 -N:7roo ie.".o! 1 c 5.54? 9.625 (0.5381 106634 73.1634 73.13 . 8 7 3 0

3; h.y ipneno : 12 2 9 . 74 9 9 . 7 3 C (0 947! 44 023 24.9006 2 4.90 3 3 09

3 4 Bis i2-ch c.roetnoxy)met hane 9 . 834 9.882 (0.961) 207851 74 .2972 74.30 7752

2— h . crophenc: 162 10.071 10.069 (0.979) 199931 76 . 7975 76 . 60

"-.2,1-7: ■:r. iorober.zene 180 10.206 10.187 (0.992) 220405 71.3104 71.31

37 Nap:-.: ha i 126 10.341 10 . 322 (1.005) 537680 76.0436 76.04 8 8 99

3 3 4 - Chic rear.: i ir.e 127 10.443 10 . 424 (1.015) 221956 74.4704 74.47 8884

?. 3 r. e x a c h 1 c ■obut ad i ene 225 10.561 10 . 542 (1.026) 180594 74.7022 74 . 70 9198

41 4 -Chic ro 107 11.306 11 . 287 (1.099) 148042 68 .4042 68.40 8758

4 2 2•Methyinapht halene 142 11.542 11.523 (1.122) 452577 85.8738 85.87

i • 'oeve iooer.tad iene 237 11.813 11.754 ( 0.884 ) 145960 65.7197 65 . 72 9109

45 2.4.4-Tr 155 12.050 12.031 i0 . 901! 180268 34 .7427 84 . 74

^ : - ch lo ropher.c l 195 12.118 12.116 (0.906 1 249235 107.622 107.6

iaph.: ha len- 162 12.388 12.366 !0.927) 440676 73 . 5424 7 3 . 54

4 5 2 - N : : r car.: line 65 12.574 12.572 (0.941) 182020 78 . 004 3 7 8.00 8 64 3

5 " r>: me c h y l p n : n a a: e 15 j 12.356 12 . 394 (0.965) 693106 80 . 0670 88.07 9502

5 l 2 , -j - D . n : * 155 13.014 12 . 9 9 5 '.0.573) 1 3 5 6 4 5 80.8508 3 0.65 956 6

1 52 13.116 13.114 .0.981) 791019 82.0776 82.08 6 5 54

r? ‘ : ■ 1 1C 1 3 . 3 C 2 13.3 0 0 ■■0.955) 134055 75.2973 7 5.30 3 97 9

5 4 154 13.420 12 .41? '1.004' 494668 67.2749 87.27 8 5 O' 3 '■ R :

2r J rep;-.e:-.c 1 • a ^ 13.433 13.486 ; 1 . 0 0 9 ; 35984 34 .2951 3 4 . 0 iaM)

• ; : : : 1 0 9 13.64C : 3. 2: '1 .020) 54 114 37.7946 37 . "79 0 ' M 1

145 :: 70; ■3.706 :: 025: 194008 73.0717 7 3.07 h 6 5 3

i- : :: 12.715. 1 2 . ~22 1 02 7 555464 51 . 0615 9 1.08 8 1 b 6

■5 I ■ ■ ■-■if '.4.14 = : 4 . : 2 1- ■1.056' 7 3. C: 0 3 6 0 5 . 8 6 S 3 35.8-? 9 4 4 2

304 : i . 3 2 -i 14. : 1 ?. : . ' 7? 446344 0 6 . 2 12 2 :•? .:: ' 7 34 4

" L ■ : 1 14. 1 :. 784371 54 .425 2 54.4 j r 52

: 3 r ■; . .■• r . ■; ■ - :■ : 4 3 0 5 3 7 c- . 7 1 2 1 75.7 1 r 4 4 ?

: :■1 : -. ? ■ : 0 5 5 14 6 4 .289 a 64.2 r :■■.■■:

. : K5-; '■4 .32: '. 0::. •t 2 7 6 1 0 -0 .5?:-:: 3 : 4 :

- : : ■ 24 r : r : - :• = - 2637Q4 = 3 . 2067 fc "> 1

• 7 _ *> • 1 ?. 3.: 1 1 r 2 3 6 0.553- 273363 30 6545 = 0.,E 5 0 n 4

: nenc 2 4-3 1 5 6 7 •• ■- b . ; : ■ 0 5 6 0; 5 2 6 3 7 3 3 MIS 8 2.14 C L. 1 1

17 5 it 1 •> . ':2.; ::.002) 1037-49 S 7 . 12 0 1 3 7.12

! A:-hva:--: 1 7 z 1 12 7 :’.'S .1.00 8 ■ 1146573 51.2167 91 .29

; 6 7 1 4 4 1 : : 2 : 1 . 025 . : 0 1 3 6 S 5 102 94 3 10 2.5 5 1 0 3

779

I


CONCENTRATIONS



73 Di-n-butylphthalate 15 9 17 . 007 16.908 (1 .063) 1353807 83 . 0175 83.02 9396

7 4 Fluoranthene 202 18 . 123 16.121 (1.133) 1326000 91.9162 91 . 92

76 Pyrene ! 202 16 . 529 18.510 (0.898) 1397417 78.3568 78 .36

77 Butylbensylpht ha lace 15? 19 . 629 15.610 (0.952) 635814 69.0382 59.04 9072

79 3,3' -Dicrilcrobenzidme 252 20.553 20.551 (0.996) 234433 33.3354 33.34 7507

75 bis•2 - ethylhexyl)Phchalace 155 20.576 20.575 (0.998) 1041515 00.9726 80.97 8975

SC Bento i a:anthracene 228 20.610 20.591 (0.999) 1665509 93.6043 9 3.60

81 Chrvsene 223 2 0.6 61 20.652 (1.002) 1461953 91 . 1665 91 . 17

9 2 Di-n-octvlphthalate 159 21.575 21 . 556 (0.931) 1651215 78 . 0306 78 . 03

83 Benzo(b)fluoranthene 252 22.387 22.368 (0.966) 1427352 78.7644 78.76

65 Benzo(k)fluoranthene 252 22.537 22.516 (0.968) 1741525 106.289 106 . 3

85 Bento(a)pyrene 252 23.063 23 . 055 (0.995) 1292027 89.0867 89.09

86 Indeno(1,2,3 -cd)pyrene 276 26.092 26.056 (1.126) 1272205 82.2055 82.21 8526

87 Dibenzo\a,hi anthracene 2 7 S 26.152 26.107 (1.128) 1302869 96.7202 96.72 8670

86 Benzoig,h,i)perylene 276 26 . 988 26.952 (1.164) 1254235 96 . 1730 96 . 17 7381

QC Flag Legend

Targejt compound detected but, quantitated BeloW| Limit Of Quantitation (BLOQ) .Targejt compound detected but, quantitated exceeded maximum amount.Spike1/Surrogate failed recovery limits. Compound response manually integrated.

amount

amount

780

Data File: /chem/5972hp60.i/DF020312A60.b/UG16228-2A60.dInjection Date: 12-MAR-2002 15:08Instrument: 5972hp60.iClient Sample 'ID: SIILCS

ound: 2 Number:

4.6-Tribromophenol 118-79-6

Ion 329.60: Area: 390060 Height: 227369

: 2,2- itft |

2.0-; 1Tt

1.8-

1.6-

1.4- |

LH 1.2-

0.6- ! ; i

0.4 |[

0.2- ;i 1

1-1.25 14.'30 14.35 14.4Ci14.45 14.50 14.55 14.60 14.65 14!.70 14 ^75 14.80 14185 14^90 14^95 15^00 15^05 15.10 is'l5 15.20Hi n i


1.8-

1.6-

L

4.4m 14.45 1J.50 14.55 14.60 14.65 14.70 14.75 14.80 14.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Mir-I_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

Ion 141.00: wrea: 0 neight: 0

1 4.55 14..-.- : 4 .5 ; j . -o 14.-5 14.80 14.55 i 4 . Qm 14.95 l 5.00 15.05 15.1'.' 15.15 15.20

Data File: /chem/5972hp6C'. i/DF020312A60.b/UG16228-2A60.dInjection Data: 12-MAR-2002 15:03Instrument: 5972hp60.iClient Sample 'ID: bllLCS

ouno: 2

Mumper:J-Dmitr opnenol

1.6

1.5

1.4

1.3-

1.2

1 . 1-

1.0

Ion 184.00: Area: 35984 Height: 16150

0.4-

0.3

0.2-

0.1

13.05 13.10 13.15 13.20 13.25 13.30 13.35 13.40 13.45 13.50 13.55 13.60 13.65 13.70 13.75 13.80 13.85 13.90 13.95 _______________ _____ M l n

Ion 154.00: Area: 0 Height:

1.4.li l

1.0-

I 3.00 1 3.03 : 3.:0 13.13 13.20 13.25 13.30 13.3d 13.40 13.45 13.50' 13.55 13.60 13.65 13.70 13.75 13.80 13.85 13.90 1 3.95'___________ _____________________________________ M i n

Ion oS.OO: Area: 0 Heijtru: 0

178

40 13.45 13.50 13.55 13.60 13.65 13.70 13.75 13.80 13.85 M i n

13.90 13.95

Data File: /ch'em/5972hpb0.i/DF020312A60.b/UGl6228-2A60.dInjection Date: 12-MAR-2002 15:08Instrument: 5972hp60.iClient Sample ID: SIILCS

4-Nitrophenol100-02-7

1 .c

1

Ion 109.00: Area: 54114 Height: 24472

Q<

rn-

!

J •

13. 15‘ 1 3.20 13.25 1

1

13.35 13.40 13.45 13.50 13.55 13.60 13.65 13.70 13.75 13.80 13.65 13.90 13.95 14.00 14.05 14.10Min


C'J‘JD

ro

1:5 13.40 13.45 13.50 13.55 13.60 13.65 13.70 13.75 13.80 1

H i n_____________________________ion 139.00: Hr-ea: 0 Height: 0

85 13.90 13.95 14.00 14.05 14.10

78 J

:• 13.60 1 3.65 1 3.70 13.75 1 3.60 13.65 1 3.90 13.95 14.00 U . 05 14. in Hi n _ ___ _____ _______________

CompuCherra Divisionof Liberty Analytical Corp.

GC/MS SEMI-VO A WORKSHEET

LAB INSTRUCTIONS:

RECEIPT DATE: 3/8/02 0:00 SAMPLE DATE: DUE DATE:

CASE#: ' SDG: WGI6228 COMPUCHEM #: WG16228-2

CLIENT ID: S1ILCS


Injection Volume :1.0pL Dilution Prep (if needed)

Extractionj Date___3___/10____/__02

DFTPP Filename DF0203 I2A60! ~ ------------------------------------t

Sample File Name___WG16228-2 A60

ANALYST(S): Injection917 Work-up4/ ?

GC/MS DATE REVIEW

CONDITION CODE


Number off peaks found:

Number of Flits found:

r/A

Number of Surrogate Outliers: ______

.1

Quality Assurance Notice (s)Number of Notices Required_____^

Comments:

Disposition: [ / Complete/c

Reinjection Required

Re-extraction Required

Reinject Neat

Dilute( X)

#GC/MS Review/•nyi-- Date p / 4


Auditor

Q-J u if- ^ &6<~>

Date / /

784

SVl - 6/27/01: PTF

assigned TO: A O/C

SA'bo

( ompuChem


SKMI-V01.AHLF. WATER, Method 3S10C. for 8270C DA I K EXTRA' I KD/POS I I I):

o oi ...........

* r;A , SAMPLE FINAL Adjusted pH ' : CO

SAMPLE

NUMBER \ -

lijc SAMPLE':.;,

i-'type ■'* VOLUME

(ml)

VOLUME

(ml)

■ A/N BASE COMMENTS 1^-

Qe/fr?7- s- /coo \-0 /£ 12^ / 9/ore ______ l.o y, i> \l\

/<> ZOO* _____ Lc /.u 1^ i___________/___

/CO a l.e U. 12-1/ A

/0<0 0 Id lU 12-1 Qc£-i? '/i*' •$

>3 /coo .0----f—u-----------

/ (q iM

//c<o ■0---- / v----------

J.L 12.i

/r JCfc 1-0 / L »2.1/______u

/coo \ 'O 1.h 12. i

n /COG to / (p 12 (

/r z COO 1-0 / L til7 W

/ooc • 1.0 l L 12. <

lA/(si(rJ7,ZXC-~S /etc l.o —r*~/ (p 12-1

Z S 5> /OOO Vo /.b 12 i

Qt-r 1777-1 ICO® l.o Al 1)1JCCfd lo JA d.i r - > *~n*FA* E /

) H____ ——"

)T -------------

___——

2 -------- :--------------

3 lo/irlkBLK

jm t‘0 4 L 12.1*_________ 3

LCS /Coe 1.0 A & (L t ''Add 1.0 ml. validation spike In I ( S and SSs unless otherwise noted _

S-VOL Add ; B/N 8270FINAL VOLUME VLRIUKI): <—.............. ........NO. 393

- Is/ ^

SURROGATE AMT. 1.0 ml A/“——-

LOT d/n V/7^-------------

SLPFRMSOK REVIEWL I): ^ ......... ....... ITr-r.-.. ...NO. 3012/ 2021 VALID.

SPIKF. AMT. L^ml 1.0ml 1.0 ml s?ry - - ^ it aI —LOT Ito/thT SLRROGATE & SPIKE ADDED 113 : ^ > >1 _(______ _____

Initials Dale

Analyst initials Extracted ' 'l ' KD (^\N2 'M ^ Bottle up MA Witness _________' .

MBnu^r and lot number of reagcnts/solvents used J-TBf\li^ 'Ctlb'W -Vt) sU^ - ____fsjt> IT “ T7i ^ 5V

CA ..11

FORM 1 CLIENT SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

1i

^^Lab Name: COMPUCHEM Contract 8270CSJGLCS

^^^Lab Code :LIBRTY Case No.: SAS No. SDG No.: QE1877

Matrix: (l|

soil /'water) WATER Lab Sample ID WG16304-2

Sample wt/voT: 500 (g/mL) ML Lab File ID: WG16304-2B60_9


1% Moisture: decanted: (Y/N) Date Extracted:03/14/02

|Concentrated Extract Volume: 500 (uL) Date Analyzed 03/14/02

Injection Volume: 1.0 (uL) Dilution Factor: 1.0

GPC Cleanup: (Y/N) N

■ CAS NO.

pH:


108-95-2-------- Phenol 27111-44-4---------Bis (2 -chloroethyl) ether 4495-57-8----------2 - Chlorophenol 42541-73-1-------- 1, 3 -Di chlorobenzene 3910 6- 4 6 - 7-------- 1,4 - Dichlorobenzene 4195-50-1----------1,2 - Di chlorobenzene 4195-48-7----------2-Methylphenol 56108-6 0-1-------- 2,2' -oxybis (1 -Chloropropane) 42106-44-5-------- 4-Methylphenol 99621-64-7-------- N-Nitroso-di -N-propylamine 4567-72-1----------Hexachloroe thane 4598-95-3----------Nitrobenzene 4278-59-1----------Isophorone 4688-75-5----------2 -Nitrophenol 50105-67-9-------- 2,4 - Dimethyl phenol 46111-91-1-------- Bis(2 - chloroethoxy) methane 52120-83-2-------- 2,4 - Di chlorophenol 52120- 3 2-1-------- 1,2,4 -Tri chlorobenzene 5091-20-3----------Naphthalene 5210 6 - 47- 8 -------- 4 - Chloroan l line 5587- 6 8- 3 ----------Hexachlorobutadiene 5359-50-7----------4 - Chi or o - 3 - methyl phenol 5591-57-6----------2-Methyinaphtnalene 6277 - 4 7-4 ----------Hexachlorocvclopentadiene 458 8 - 06-2----------2,4,6 - Tr ichiorophenol 5795-95-4----------2,4,5 - Tri chlorophenol 7791- 58-7----------2 - Chloronapht halene 518 8 - 74-4----------2 -Nitroanii ine 54131-11-3-------- Dime thy lphthaiate 65606 - 20 - 2 -------- 2 , 6 - Dinitrotoluene ■592 0 8 - 9 6 - 8---------Acenaphthylene 629 9- 0 9 - 2---------- 3 - Nit roan i line 58

60

FORM I SV 8270C

78b

CLIENT SAMPLE NO.FORM 1SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

Lab Name: COMPUCHEM

Lab Code: LIBRTY

Matrix: (soil/water)]

Sample wt/vol:

Level:’ (low/med)I

% Moisture : _______


Injection Volume:

Contract:

Case No.: SAS No.:

WATER

500 (g/mL) ML

LOW

decanted: (Y/N)

Volume: 500(uL)

1.0(uL)

8270CSJGLCS

SDG No.: QE1877


Lab File ID: WG16304-2B60_985

Date Received:





1 CAS NO. COMPOUNDCONCENTRATION UNITS: (ug/L or ug/Kg) UG/L Q

51-28-5----------2,4 - Dinit rophenol 18 J100-02-7-------- 4 -Ni t rophenol 41121-14-2-------- 2,4-Dinit ro toluene 59132-64-9-------- Dibenzofuran 6484-66-2----------Diethylphthalate 647005-72-3------- 4 - Chlorophenyl - phenyl ether 6636-73-7----------Fluor ene 6610 0- 01-6---------4 -Nitroani 1 ine 62534-52-1-------- 4, 6-Dinit ro-2 - methyl phenol 528 6 - 30- 6 ----------N-Nitrosodiphenyl amine (1) 60101-55-3---------4 -Bromophenyl -phenyletEer 65118-74-1---------Hexachlorobenzene 588 7- 36 -5----------Pentachlorophenol 553 5-01-8----------Phenanthrene 6512 0-12-7-------- Anthracene 703 6 - 74- 3 ----------Carbazole 783 4 - 7 4 - 2----------Di-n-butylphthalate 672 06 -44- 0 ---------Fluoranthene 7012 9 - 00 -0------- -Pyrene 6285-68-7----------Butyl be nzylpht ha late 6191-94-1----------3,3' -Dichlorobenzidine 31

i 117-81-7-------- bis(2 - ethyl hexyl) Phthalate 6456 - 55 - 3 ----------Benzo (a) anthracene 73

1 213-01-9-------- Chrysene 69! 117 - 34 - 0-------- Di - n - octyl phthalate 64! 205 - 9 9 - 2---------Benzo (b) f luoranthene 71207 - 03 - 9 -------- Benzo(k) fluoranthene 66,30-52-8----------Benzo la) pyrene 65

60■ n 3 - 70 - 3----------Dibenzc (a , h i anthracene 71191-24-2---------Benzo (g , h , l ! perylene 70

iCannoc be separated from Diphenylamine

FORM I SV 8270C

787

Data File: /chem/5972h|ofcO. i/DF020314B60.b/WG16304-2B60_985.d

Date : 14-MAR-2002 22:19

Client ID: SJGLCS

Sample Info:

Volume Injected <ul_>: 1.0


Instrument: 5972hp60« i

Operator: 2319


/ )

oor-~-

Client ID; SJGLCS Instrument: 5972hp60.i

Sample InfoJ

Volume Injected <uL>: 1,0 Operator: 2319

Column phase; J&W DB-5.62C Column diameter: 0.32

Data rile: /chem,'5972hp60. i/DF020314BGO.b/UG16304-2B60_985.d

Date : 14-MAR-2002 22:19

2chem/5972hp60. i/DF020314B60.b/'WG16304-2B60_985,d (Part 2 of

Data File: /chem/5972hp60.i/DF020314B60.b/WG16304-2B60_985.d Report Date: 15-Mar-2030 11:07

CompuChem

Data file : Lab Smp Id: Inj Date) :

Operator : Smp Info. : Misc Info : Comment i Method < :Meth Date : Cal Date . :Als bottle: Dil Factor: Integrator: Target Vers Processing

Semivolatile Report /chem/5972hp60.i/DF020314B60 WG16304-2 14-MAR-2002 22:19 2319

/chem/5 9 72hp6 0.i/DF02 0 314B6 015-Mar-2030 10:11 byrd 0 3 -MAR-2002 17:20 41.00000 HP RTE ion: 3.50Host: einstein

SW-846 Method 8270C .b/WG16304-2B60_985.d Client Smp ID: SJGLCS

Inst ID: 5972hp60.i

.b/8270Cv6.m Quant Type: ISTD Cal File: HL020303A60.d QC Sample: LCS



Cpnd

..oirpo-if


DF J 1.00000 Dilution Factorvt: 500.00000 Volume of final extract (uL)Vo ■ 500.00000 Volume of sample extracted (mL)Vi 1.00000 Volume injected (uL)

•1


1'I

5 :

QUANT SIG

MASS f: EXF FT PEL FT RESPONSE

CONCENTRATIONS

ON-COLUMN FINAL

( NG) ( ug/L)

•; -2 : r.o-ir.e ■ A A 5 2 - ; - 1 9 3 6 7 5 4 0.0000

j •; - : 2 6 '• 2 4 3 40.0000

6 4 1 ' 225735 4 :. 00CO

-:r i ■■■ " " 1 . ' Ad 3 08 : 4 0 . 0000

..v. 2 ;• 5 7 A A •; o. oooo

264 2 : : 7 • A 3 a 0 2 7 n . o o o o

1 '.2 - . '22 : 2 2 2 8 7 2 3 69.6483 6 9.65

■ir.ol - -if 9r. 7- 201712 59.9632 5 5 . 9 6

5 7 ■r.0-3" ■3T . ES2: i80286 4 8 . 4 b 1 5 4 5.45

Piucr-chipher.'.-i 12. i s: 6: 494715 b6 .4933 .49

4 . r -Try ■3"' : 4 7- 6 • ': . ■. o s i 333373 157.311 1^7.3'1

r-vnvMy.-u:-; 244 '.i.Tii ’ 7 ? ■ 1? Oil) 878046 59.0462 5 5.05

54 7 r. r. l 7 . n-i 1 C . 9 3 3 ! 86406 26 . 6945 .26.69

s • i r.v; :• -v: 7 7 4 7 *:•: '0.943) 97224 4 3 . 6297 4 3.63

SIMILARITY

t< m)

' 790


QUANT SIG

expounds MASS R T

IB 2 - Chlorophe.nol 123 7 . 793

19 1 ,3-Dichlorobenzene 146 8.035

20 1,4 -Dichlorobenzene 146 9 . 153

22 1,2-Dichlorobenzene 146 9.407

23 2-Mechylphenci 108 8.576

24 2,21 -oxybis(1 - Chioropropane) 45 S . 593

27 4 -Methy 1'pher.ol 108 8.847

28 N - Ni troso-di-N-propyl amine 70 8.813

29 Hexach1oroethane 117 8 . 965

30 Nitrobenzene 77 9.101

31 Isophorone 82 9.507

32 2-Nitrophenol 139 9.642

33 2,4-Dimethylphenol 122 9.727

34 Bis(2-chloroethoxy)methane 93 9.879

35 2.4-Dichlorophenol 162 10.065

6 1.2,4-Trichlorobenzene 180 10.200

7 Naphtha i ene 128 10.336

3 6 4 -Chloroam 1 me 12 7 10.437

5 Hexach:qrobuta d:ene 225 10.539

5 -Chloro- 3 - met hy; pr.eno: 107 1 i 300

1 Met hy :|napht n-:« 1 ene 14 2 11.537

4 4 11.0 08

12 0444 5 2 , 4 . 5 - 7r : cr. 1... roc hero 1 196|

1,4.5- 7:': m ; oropheno : - 9 6 12 ’12r

. 1 o 2 12.303

2 - N: t roar.: 1 ; r- 6 5 l2.S6i

51 Dimethylpr.c ha la: -r 15 3 12. s; o

= ; 165 ::.oo?

b.: Arer.aph: h.y ! ene : 52 13.110

5' '• N: t roar : 1 * r.e 1 • £ 13 2 96

1 54

56

, , -1.1 hi-,...,-1 c 4 13.482

13.635

r 7 2 . 4 - D: n : t r; t ;. i r-me ■ 3 702

5£ 2 : rente : iv. r 168 ; } 7 1 ?

=■? 14 9 2 4. 142

4 - l'h 1 oropher.y; - pr-my l e: ne r 2 C 4 , 1 ?5 : rorene 14 T ~> -.

■-2 1 * ' 4 3 7 0

19? .4 4 3 :.

■- N: : restv-me

- - .. : ■.2

1 : .ill

.... !_• '7 0 5 4 4 7

. ...__ J..... : - = : ? : 21

" :I'-i r. - 15 7 1 5- 4 >

CONCENTRATIONS

ON-COLUMN FINAL

REL RT RESPONSE ( NG J ( ug/LI SIMILARITY

(0.953) 107566 42.2270 42.23 8994

(0.9801 137612 39.3961 3 9 . 4 0

f 1.002 ' 242074 4 0 . 9199 40.82

(1.0331 137351 41 . 1466 4 1.15

(1.054) 115566 55.3972 55.90

11.0561 134323 42.2270 42.23 7178

(1.087) 259880 98 . 9113 98 . 91 ((1.083) 86264 45.2369 4 5.24 0 (M) 1

(1.102) 66857 45.017? 45.02 8092

(0.835) 134339 41.6181 41 .62 9 94 2

(0.924) 235208 46.2746 46.27 8900

(0.937} 78909 49.5071 49.51 3915

(0 . 946) 88511 45.7670 45.77 8067

(0.961) 157839 51.5774 51.58 7826

(0.979) 148416 52.1161 52 . 12

(0.992) 166672 49.8883 49.89

(1.005) 401625 51 . 9259 51.93 9 04 0

(1.015) 179215 54.9687 54 . 97 8 6 7 6

(1.025- 139302 52.6759 52.66 8 3 3 7

(1.099) 130514 55 . 1289 5 5.13 9326

:i.122) 3 6 8 S 1 3 62 . 2388 62 . 24

(0.894) 115318 44 . 5415 44 . 54 9 3 52

(0.901) 142385 57 .4188 57.42

(0.905) 206637 76.5434 76.54

(0.9271 355669 50 . 9179 50.92

(0.940) 145252 53.7660 53 . 77 07 9?

(0.965' 594980 64.8518 64 . 85 9720

i0.573) 115360 58.9951 58 . 99 9526

(0 . 981 1 691364 61.5391 61.54 36 3 1

10.995) 120549 58.0853 58 . 09 ?)4 1

(1 . 0 04 1 305151 59.9060 5 9.81 3?L1

i 1 . 0091 22009 17.9939 17.99 ■riK' 1

: 1 . 020) 68351 41 . 3117 4 1.31 0 i M ) ^

1 1.02 5) 169557 53 .5324 58.53 5 7 01

; 1 . 027) ■'90035 64 . 3347 64.33 0558

1 ' 0C = , 034528 64 . 0545 64.05 > 5 1 4

'1 C 7 2 j 356697 66.3276 66.33 7 3 94

11.072; 643155 6 6.0 9 5 C 66.10 7 7 2 5

••*: .070) 1289C 3 61.6160 61.62 3510

(0.903) 96922 51 .6946 51 68 0 8 01

‘1.9 0 9 ;■ 359719 5?.577? 5 9.5 3 0 0 34

‘ 0 .550) 219884 64.6275 64 .63 9556

'0.9531 223940 57 . 0537 5 7.55 9 12 9

' 0 . 9 7 5 j 62254 5 d . 0 -j 6 6 55 04 V 0 0 i

: 1 . C ■ j 2 1 924525 65.0552 ro 0 -J

,1 •? • \ 0 ; 1 C 'J 2 4 5 9 70 07?0 7 0 0 6

1 1 .026. 665653 7 0. . 0 0 : 7 3 . (J 2 0 2 1 7

EXP RT

7 . 799

8 . 035

3 . 154

3.408

8.594

8.594

8.847

3.814

8.966

9 . 101

9 . 507

9.643

9.727

9 . 379

10.066

10.201

10.336

1C.438

10.539

11 . 3 0 0

11.537

11.808

12 . 045

12 113

1 2 30 3

12.586

12.091

i3.009

13.111

13.314

13.415

1 5 . 5 0 0

13 6 3 5

13.72 0

13.737

14 . ■ 4 3

• .• t -> o

14.325

1 '1 . 3 96

14.545

• c. tj 2

. -

791


CONCENTRATIONS

Compounds |

• QUANT SIG


ON-COLUMN

( NG)

FINAL

( ug/L) £>IMILAE ITV

731

Di-n-butylphthalate 149 17.001 17.002 (1.063) 1245152 67.0926 67.09 9488

74 Fluoranthene 202 18.118 18 .118 (1.133) 1149221 69.9989 70.00

76 Pyrene 202 19.524 18 . 524 (0.898) 1188249 61 . 3249 61.82

77 Butylbenzylphtha late 149 19.624 19.624 (0.952) 602055 60.6598 60.66 9171

7 S 3,3'- Diehlorobenzidine 252 20.537 20.555 (0.996) 234427 30.9314 3 0.93 7662

79 bis f 2 - ethylhexyl)Phthalate 149 20.590 20.5 3 S (0.9 99) 986104 63.9239 63.92 90S2

80 Benzo(a)anthracene 225 20.605 20.605 (0.999) 1401357 73.OS 08 73.08

81 Chrysene. 228 2 0 . 656 20.656 11.002) 1195250 69. 1613 69.16

92 Di -n -octy1phtha 1 at e 149 21.569 21 . 570 (0.931) 1404514 63.5429 63 . 54

8 3 Benzo /b) £ I unrar.thene 252 22.151 22.362 (0.966) 1340374 70.8115 70.81

84 Benzo(hi fluoranthene 252 22.4 32 22.432 (0.968) 1126072 65.7967 65 . SO

96 Benzo!a)pyrene 252 23.05 8 23.058 (0.995) 987804 65.2065 65.21

3 b Indeno(1,2.3-cal pyrene 276 26.069 26.087 (1.125) 974627 60.2922 60.29 3785

87 Dibenzo{a,h)anthracene 278 26.137 26.137 (1.128) 998796 70.9860 70.99 8610

88 Benzo(g,h,i)perylene

m |

276 26.983 27.000 (1.164) 953409 69.9895 69.99 74 3 7

QC Flag Legend



f

79^

Data File: 'cnem.- 5972hp60.1 .-'DF020314E60 . b/UG 16304-2B6O_385. dInjection Data: 14-MAP-2002 22:19Instrument: 5972hpb0.1Client Sample. ID: 5JGLCS

pound: 2.4‘, 6-TribromophenolNumber: 118-79-6

1.6- 1.5- 1.4-1

1.3-

l .2-;

1.1-

i .0-:

Ion 329.60: Area: 333373 Height: .164124

0.8-

0.7-

0.6-

0.5-0.4-

0.3-

0.2-

0.1-

n. ui_

14.3 14.5 14.6 14. 14.8 14.9 15.0 15.1Min

15.2

1.6-'

1.5-

1 .4-

1.3-

I1-1-

1.0-

0.9-

0.6-

Ion 332.00: Area: 0 Height: o

> 0.6-

! 4.5 14.Q 15.0 15. 1 i5.:

IQn 141.00; ne i gnr. : 0

14.5 14.7 14.8

M i r i14.9 15.0 15.1

•793.15.2

Data File: .'cnem/5972hp60.1 /DF020314B60.b/tdGl6304-2B60_985.dInjection Date: 14-MAR-2002 22:19Instrument: 59?2hp60.1Client Sample ID: SJGLCS

pound: N-Nitroso-di-N-propylam me S Mumper: 621-64-7

4.8-

4.5-

4.2-

3.9-

3 . D"

3.3-

3 0-

Sch

Ion 70.00: Area: 86264 Height: 5052

lO o

2.1-

r '•*-

I 1.5-

i 1-2'

I 0.9-I 0.6-'

0.3-

: o.o-8.4 8.5 8.6 8.7 8.8

Min

8.9 9.0 9.1 9.2 9.3


a.-;

0.5

n n3.5 8.1 3.3

Mm8.9 9.0 9.1

Ion 42.00: Area: 0 Height:

79-‘-t-

8.3M 1 r.

9.1

Data File: /chem/5972hp60.1/DF020314B60.b/UGl6304-2560_9B5.dInjection Date: 14-MAR-2002 22:19Instrument: 5972hp60.1Client Sample ID: SJGLCS

•

ipound: 2.4-DimtrophenolNumoer: 51-23-5

9.0-Ion 184.00: Area: 22009 Height: 9008

8.0- 7.5-;

o. z>- 6.0-

5.5-

5.0-

4.5- :

4.0-3.5-

3.0- '

2.5- ;

2.0- ;

1.5-

1.0-

0.5-

0.0--T13.1 13.2 13.3 . 13.4 13.5 13.6

____Min_________________13.7 13.8 13.9 14.0•


13.3 13.4 13.5M l n

13.6 13.1 13.8 13.9


79:13.8 13.9 19.0 :

Data File: /chem/5972hp60.1 /DF020314B60 . b/UGl6304-2B60_985. dInjection Date: 14-MAR-2002 22:19Instrument: 5972hp60.1Client 5ample,!lD: SJGLCS

# ound: 4-NitrophenolNumber; 100-02-7

2.8-

2.6-

2.4-

2.2-

2.0

1.8-

1.6-

1.4-

1.2-

1.0-.

0.8-

0.6-

0.4-

0.2-

im m io

Ion 109.00: Area: 68951 Height: 29656

ni1

13.2 13.3 13.4 13.5 13.6Min

13.7 13.8 13.9 14.0 14.1

!

Ion 65.00: Area: 0 Height: 0i

1 . u-

0.9-

ili)

ii1

0.8- ■Ii

W: i1

'i

~ O'. 6. in '1

i

"z. ij . 5 i

0.4 i'1

0.3 i\

0.1

-1 IT-

r“

; \

il 13 • r 13.3 13.4 13.5 13.6m i n

13.7 13.8 13.9 1 4 . ij 14.1

Ion ;39.00

1.1-

S' 0.?

'5; 0.0-

0.7-

0.6

13.6 ID."1Min

13.8 13.9 14.0 14 . 1



LAB INSTRUCTIONS:

RECEIPT DATE: 3/14/02 0:00

CASE#:


SDG: WGI6304 COMPUCHEM#: WG16304-2

CLIENT ID: SJGLCS


Injection Volume :

I

Extraction Date __

DFTPP Filename

IpL

_/14____ /___ 02

DF020314B60

Sample File Name WG 16304-2 B601

ANALYST (S): Injection2319__________

Dilution Prep (if needed)_

Work-up

GC/MS DATE REVIEW-

CONDITION CODE

c^


Number of peaks found: ____Hk

Number of Hits found: ____

Number of Surrogate Outliers:_____ f_

Quality Assurance Notice (si Number of Notices Required 9

IComments:

Disposition: [•'^Complete



[ ) Reinject Neat

[ | Dilute! X)

-GC/MS Review

Final Reportable Packauets):

Date A L Auditor

b-> ^/C~}o<S - - 9i'(^]

Date

. 797SVl -6/27/01: PTF

Manj ^irrr and lot number of re age nts/solvcnts used

C b\3H_

N*qv\....l.

d. Matrix Spike Data



799


CLIENT SAMPLE NO.

Lab Name COMPUCHEM




Level:' (low/med) LOW

% Moisture: decanted: (Y/N)

Contract: 8270C

SAS No.:

MW-13BMS

Concentrated Extract Volume:


1000(uL)

GPC Cleanup:

CAS NO.

(Y/N) N pH:

SDG No.: QE1877








11 108- 95-2--------Phenol 25111-44-4--------Bis ( 2 - chloroethy 1) ether 45

, 95-57-8---------2 - Chlorophenol 45j 541 - 73 - 1--------1, 3-Dichlorobenzene 39106-46-7--------1,4 - Dichlorobenzene 4195-50-1---------1,2 -Di chlorobenzene 4195-4 8 - 7--- ----- 2 -Methylphenol 56

1 10 8 - 60-1--------2,2' -oxybis (1 -Chloropropane) 43106-44-5--------4 -Methylphenol 89621-64-7--------N-Nitroso-di -N-propylamine 4467-72-1---------Hexachloroethane 41

1 98 - 95- 3 ---------Nitrobenzene 44. 78 - 59- 1 ---------Isophorone 44i 88-75- 5---------2-Nitrophenol 48j 105 -67-9--------2,4 -Dimethylphenol 33111-91-1--------Bis (2 - chloroethoxv) methane 47

: 120-83 -2 --------2 , 4 - Dichlorophenol 501 120- 3 2-1--------1,2,4 - Tri chlorobenzene 46' 91-20-3---------Naphthalene 4910 6- 47-8--------4 - Chloroani 1 ine 52

i 8 7 - 68 - 3 ---------Hexachlorobutadiene 47! 59- 5 0 - 7---------4 - Chioro - 3 - methylphenol 52J 91-57-6---------2 -Methylnaphthalene 5577-47-4---------Hexachlorocyciopentadiene 46

; 83- 06-2--------- 2,4,6 - Tri chlorophenol 56| 95- 9 5- 4---------2,4, 5-Trichlorophenol 74■ 81-58-7---------2 - Chloronapht halene 451 38 - 74 -4 ---------2 -Nitroani line 53131-11-3--------Dimethylphchalate 61

1 606 -20 -2 --------2 , 6 -Dimtrotoluene 54208 - 86 - 8 --------Acenaphthylene 52

; 9 8 - 08 - 2 --------- 3 -Nicroaniline 54J 8 5 - J .j - 8---------Acenaphthene 56'

80 i

FORM I SV 8270C


CLIENT SAMPLE NO.


Lab Code: LIBRTY Case No.: SAS No.:|




% Moisture: ______

Concentrated ExtractI

Injection Volume:

GPC Cleanup: (Y/N)

decanted: (Y/N)

Volume: 1000(uL)

1.0(uL)

N pH : ___

8270CMW-13BMS

SDG No.: QE1877








J 51-28-5---------2,4 - Dinitrophenol 42 Ji 100-02-7--------4-Nitrophenol 401 121-14-2--------2,4-Dinitrotoluene 57132-64-9--------Dibenzof uran 59

; 84-66-2 ---------Diethylphthalate 627005-72-3-------4 -Chlorophenyl-phenylether 6286-73 -7---------Fluorene 59100-01-6------- 4 -Nitroaniline 64534-52-1------- 4, 6-Dinit ro- 2 - methyl phenol86 - 30- 6 ---------N-Nitrosodiphenylamine (1)

6160

i i 01-55 -3------- 4 -Bromophenyl -phenyletEer 62i 118-74-1--------Hexachlorobenzene 58| 87 -86 - 5 ---------Pentachlorophenol 64: 85-01-3---------Phenanthrene 6812G-I2-7--------Anthracene 6886 - 74 -8---------Carbazole 7884 - 74 - 2---------Di - n - butylphthalate 62206-44 -0--------Fluoranthene 72

: 12 9- 00 - 0--------Pyrene 628 5- 68-7---------Butyl be nzylphthalate 5491-94-1---------3,3' - Diehl orobenzi dine 29

| 117-81-7--------bis ( 2 - ethylhexvl) Phthalate 61 B> 56 - 55 - 3 ---------Benzo ( a ) anthracene 75

i , 218-01-9--------Chrysene 67j 117-84-0--------Di - n-octylpnthalate 61| 2 Or - 9 9 - 2--------Benzo ( b) fluoranthene 66i , 2 0 7-08 - 9 ---------Benzo (k) fluoranthene 751 5 0-32 - 8 ---------Benzo (a ) pyrene 70; 1 e J - 3 9 - 5--------Indeno (1,2,3- cd) pyrene 64

; 3 - 70 - 3---------Dibenzo (a , h} anthracene 761 : 19 1-24-2--------Benzo \ g , h , i) perylene 75

I

1 ) Cannot be separated from DiphenylamineFORM i SV 8270C

I

j

801

Data F i la: /chem/5972hp60« i/DF020313A60*bAJGl&228-3A604d

Date : 13-MAR-2002 13;53

Client ID: MW-13BMS Instrument: 5S72hpbO*i :'vj

Sample Info: oVolume Injected <uL): 1*0 Operator: 517 ooColumn phase: J&W DB-5+62C Column diameter: 0*32

<xlO~7>

Data File; /'chem25972hp60. i2DF020313A60.b/UG16228-3A60.d

Date : 13-MAR-2002 13:53

Client ID: MW-13BMS

Sample Info:


Column phase: J8>U DB-5.625


Operator: 917

Column diameter; 0,32

/chem/5972hp60.i/DF020313A60.b/WC16228-3AC0.d (Part 2 of 2)

4.4-4.3- 1

4.2!4.1- 14.0- j

3.9-j 3.8-1

3.7- ;3.6- j3.5- j3.4- 1

3.3- :3.2- :3.1- :3.0- i 2.9!2.8- 1

2.7- :2.6- !

2.5- j2.4- 12.3- 12.2- !

2.1- 1> 2.0!1.9-11.8- :

1.7-:

1.6! 1.5!1.4- 1

1.3! 1.2!

1.1-1 l.o-i

0.9! 0.8-;

0.7-; 0.6!

0.5-: 0.4-i 0.3! 0.2-:

o.i-

•1<

+C’JtHT*i«ll'.0

l',

Jl I A19

ooo

21


Data file Lab Smp Id Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date Als bottle Dil Factpr Integrator

CompuChem

Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020313A60.b/WG16228-3A60.dWG16 228- 313-MAR-2002 917

13 : 53Client Smp ID: MW-13BMS

Inst ID: 5 972hp60.i

/chem/5 9 7 2hp6 014-Mar - 2 03 0 08:48 0 3-MAR- 2 0 0 2 17:20 31.00000 HP RTE

Target Version: 3.50Processing Host: einstein

i/DF020313A60.b/8270Cv6.mbyrd Quant Type: ISTD

Cal File: HL020303A60.dQC Sample: MS





Vt 1000.00000 Volume of final extract (uL)

Vo 1 1000.00000 Volume of sample extracted (mL

w Vi

[

1 . 00000 Volume injected (uL)

Cpnd Var

1

iable

1

Local Compound Variable

CONCENTRATIONS

vUANT s:g • ON- COLUMN FINAL

•1'CTlpGUr .is MASS RT EXP ST REL RT RESPONSE 1 NG) ug /L)

: : ..:-D:cr

i

e - d 4 152 2.154 ■- .15 2 •: 1 0 0 0 : 102773 40.0000

aph:ha: 1 3 6 1 0 0 2 : ' 2 2 1 '1.0 0 0. 270986 40.0000

■ ; rec.ap.-. t 1 ' 3 - ; ■ ' t c : '1 .000' 232629 40.0000

* 4 ? .tenant rL-e-d:.'

1 5 C 'J ‘.6 " C ' il .000 j 469344 40.0000

r : hrysene 24 0 2 2.6 } - 5 2.5 2 2 ■ 1 . 000. 567335 4 0 . 0 0 0 0

2 64 2 1.2'.' 22.2 i •> 0CD. 457017 40.0000

7 ; Fin: 5 . "I r - 6 2 - ■. 0 .743- 725357 215.656 2 1 ; . 7

r ? T bene '. • z 5 ’•• •; 2 2 5 5 6 0 60.7987 6 0.80

: ; • • h:r-.;.ry: v :-■■■ :: 45126? 54.3171 54 . 3 2

7 • i : •' ■- 4 . ~ ; 7-.; 1.10 5 38=765 1 7 7 . 6 2 4 -.ii •;

•/: t ner. ••••; . 2 : - :; '0.011: 1 0 5 8 3 0 3 67 y420 6 7.84

.T ...... . -;.

,4

111577 4 5.20.; 5444

SIMILARITY

0

804


CONCENTRATIONS


Compounds MASS RT EXP KT REL RT RESPONSE ( NG) ( ug/L) SIMILARITY

IS 2-Chlorophenol 128 7.815 7.814 (0.950) 127698 45.2541 45.25 S 8 0 9

1 9 1, 3 - Di ch'l orobenzene 146 8 . 052 8 . 051 (0 . 988) 151430 39.1351 39 . 14

20 1,4-Dichlorobenzene 146 3 . 187 8.187 (1.004) 158041 4 0 . 9907 40.99

2 7 1,2 -Dichiorobenzene 146 8.424 8.423 (1.033) 151152 40.7282 40.73

23 2-Met hy1pheno1 I0S 8.610 S . 6 1 0 (1.056 ) 127415 55 . 6339 55.63

24 2,2'-oxyb;s(1 - Chioropropane! 4 5 S . 6 1 0 8.610 11.0 5 6 ) 152136 43 . 1747 42.17 0 (M)

2 n 4 - Met hyIpheno: 108 8.864 S . 8 *d 3 (1.087J 258965 88.9731 36 . 97

2k N - N i t roso • d: - N - propy i am i ne 70 3 . 530 8 . 829 (1.083) 92489 43.7836 43 .78 0 (M)

29 H e a c h 1 o r oe t ia n. e 117 9 9 S 9 8.599 (1 . 104) 66780 4 0.5922 4 0.59 8965

3 j N:z rcbenzene 77 9 . ne 9.117 (0.885) 151B91 4 3 . 8944 43.8? 3910

I sodhe rone 32 9 . 524 9 C, 7 T (0.9241 236329 43.7385 4 3.74 3 9 12

32 2 - Nt rophs:'.o 13 9 9 . 559 9 . 658 10.938 ) 81844 47 . 8988 47.90 8 7 3 S

33 2,4- Dimet hy Ipheno 1 12 2 9.751 9 . 750 (0.947; 59206 33 . 3807 33 . 33 555 0

34 B;s(2 - ch. I or oe t hoxy)methane 9 3 9 . 896 9.895 (0.961) 153898 46.9110 46.91 7 7 96

3 5 2,4 -D:ch1o rophenol 162 10.082 10.061 (0.979) 154003 50.4449 50.44

36 1,2,4-TricnIorobenzene 180 10.217 10.217 (0.992) 167465 46.2037 46.20

32 Napht ha ler.e 128 10.353 10.352 (1.005) 407399 49.1338 49.13 9902

3 3 4 - Ch loroar. i I i ne 127 10.454 10.4 54 (1.015) 182739 52.2840 52 .28 3792

39 Hexachlorobutadiene 225 10.573 10.572 (1.026} 133598 47.1250 47.12 9228

4 1 4 - Chlorc j- 3 - met hy 1 pheno 1 107 11.317 11.316 (1.099) 131569 51.8409 51.84 8757

4 2 2-Metnylnaphthalene 142 11.554 11.553 (1.122) 337038 54 . 5341 54 . 53

44 nexach 1 oro.cycaopentad er.e 237 11 . 825 11.924 (0.884) 123234 46.0870 46.09 9181

4 5 2,4,6 -7richiorophenol 196 12.062 12.061 (0.901) 143176 55.9036 55.90

2,4,5 -Trich1orooheno1 196 12.129 12.145 (0.906) 206592 74 . 0957 74 . 10m 2-Chloronaphtnalene 162 12.400 12.399 i 0 . 927i 327053 45.3339 45.33

2 - N: t roar, i 1 i r.e 6 5 12.585 12.602 (0.941) 148931 53.0115 53.01 9634

50 Dimethylphthalate 163 12.907 12.907 (C.965) 581956 61.4 171 o 1 . 4 2 9577

= 3 16 5 13.C26 13.025 (0.973) 108462 53 . 7062. 53.71 9570

3 4 rtcenaonzhv' -r-r ’ C ”1 13 .12 7 13 1 2 7 . 9 6 1 ■- 608529 52 .4451 52 .45 8560

5 3 : Z '.5.313 .: • •’0.995. 116691 54 .44 02 54 .44 8 9 6 6

=-- Aoer.apr.thr:-.-:- 154 13.432 13. 4 4 5 0 C'- 4 i 3 7 S 7 5 S 55 . 5039 55 . 50 867 1

• - •••"•' : = • 156 1 3.50 0 : • 6 66 • TAC| ; 53459 42.3174 42.32 (a )

5 5 : 9 .662 5 5 5 : 22 0 694 57 4 0.2926 4 0.29 0 (M;

5 7 - 6 5 13.7: v • 1 . 0 2 5 170446 56.9701 56.97 8 6 0 3

5- : l oc::zo: 6i - c ~ -.6 -62 : . o: - 746369 53.8 8 7 S 58 .89 9219

5 • 16 9 : 4 . 1 5 9 ■■ - '■ 6 -■ .1 . 0 6 , 631357 61 .6806 61.68 94 4 8

2 04 1 4 3 4 3 : 9 . : 4 5 . : .072 344854 61.7421 61.74 7 34 7

h'.u.trer.e i I 4 4 14.345 '■ 6 ■ ; 6 6 :: . 2 600441 59.2843 59.29 774 6

1 5 -4.35- 4.;. • 1 . 5 7 137611 63.5895 63 . 69 6 1 0 0

4 , 4 ■ Din: t: -1: - met zy 1 p::~r.:: 1 1 9 5 14 .44" 14 ' : '1.5 C 3 ; 113525 61 . 2875 61.29 07 34

:~9 • •• .:. :• i o, 273393 5 9 . 9553 5 9.96 644 5

o.. _L'.. . . . . .. • - ■ ■ 24 4 1 5 . 2 t r 1--2" • 0 . 9 5 0 1 217489 61.9727 61.97 cue

7 _ “• *i 1 3 3 2 7 1: . 5 5 - 1 231053 57 . 9676 5 7.97 ^ j '

■■ ■- P-Uochiorcy:.-:-: 6 16 662 : 6 : . •; 5 . 74 52 1 6 3 . 9707 63 . 67 3,V,i

: 7 = 14.054 1 •. 5 '• 1 . j C 990602 67.5814 57 . 59

1 7 c. . • : :■ = ’ 1 . 0 0 8■ 9 9 S 5 06 67 . 6724 67.67

"■ 2 1 4,7 i •: 4:. •; •;L ' • .02 -1 690421 77.7992 77.90 3 919

f

8 Ob

Data File: /chem/5972hp60.i/DF020313A60.b/WG16228-3A60.dReport Date: 14-Mar-2030 09:,44

CONCENTRATIONS

Compounds

QUANT SIG

MASS P.T EXP RT REL RT RESPONSE

ON-COLUMN

( NG)

FINAL

( ug/L) SIMILARITY

73 Di-n-but yiph trial ate 149 17.018 17.018 (1.063! 1185619 61 . 9350 61.94 9067

74 Fluoranthene 202 18.152 18.151 (1.134) 1216087 71.8111 71 . 81

76 Pyrene 202 18.558 IS . 557 (0.899) 1268974 62.3482 52.35

77 Bu t yibe n z y1ph t ha 1a t e 149 19.641 19.657 (0.952) 569702 54.2035 54 .20 8 9S2

79 3,3' -Dichlorobenzidme 252 20.571 20.570 (0.997) 235416 29.3321 29 . 33 64 95

7 c, bis(2 - ethyl hexyl)Phthalate 14 9 20.605 20.604 (0.998) 888339 60.5162 6 0.52 8 9 3 1

3 0 Benzo(a)anthracene 223 20.622 20.621 ( 0.999) 1529456 75 . 3153 75 . 32

81 Chrysenej 228 20.673 20.672 (1.002) 1221904 66.7666 66 . a

82 Di-n-oc bylphthaiate 145 21.536 21.585 (0.930) 1399036 60.7396 60.79

9 3 Benzo(b)fluoranthene 252 22.415 22.414 (0.966) 1295117 65.7123 65.71

34 Benzo(k)fluoranthene 252 22.466 22.465 (0.968) 1341450 75 . 2787 75 . 28

85 Benzo(a j pyrene 252 23.092 23.091 (0.995) 1111647 70.4770 70.48

35 Indeno(1,2,3-cdI pyrene 276 26 . 120 26.13b (1 . 125) 1078614 64 . 0839 64 . 08 8673

37 Dibenzo(a,h)anthracene 278 26 . 171 26.187 (1.128) 1118309 76.3339 76.33 8714

83 Eenzo(g,h,i)oervlene 276 27.034 27.023 (1.165) 1064672 75.0636 75.06 7395

QC Flag Fegend

Target compound detected but, quantitated amount Below Limit Of Quantitat ion(BLOQ) .Target compound detected but, quantitated amount exceeded maximum amount.Compound response manually integrated.

I

80 )

Data File: /chem/5972hpb0 . i /DF020313H60 . b/bJGl6228-3A60. dInjection Date: 13-MAR-2002 13:53Instrument: 5972hp60.iClient Sample ID: MW-13BMS

N,und:

'Number2-F l-'uoropnenol : 367-12-4

Ion 112.00: Area

5.4-

5.1-4.8-4.5-4.2-3.9-

725367 Height

©'£i|

! i

559800 1

i

2.4

2. 1-

1.8-

1 .5 1 . I-

fi Q.

5.3 5.9 6.0 6.1 6.2 6.3 6.4 6.5________________________Min_______________________________________________________


6.0--

5.6-

5.2-.

— 3.6-'IP

~ 2.8

1

b

T1

6.4 6.5

I on 92.00 : *-) r e =i: 0 Meleht: 0

1

1

I

0. 1 80 ?

i

5.9 U o.1 6.2 6.3 6.4 6.5i n

i;

it

'IH

Data File: /chem/5972hp60.1/DF020313A60.b/LJGl6228-3A60.dInjection Date|: 13-MAR-2002 13:53Instrument: 5972hp60.1Client Sample ID: MU-13BMS

|ound:fNumber

2.4. ‘6-T r ibromophenol : 118-79-6

2.4-

2.0-

1.8-

1.6-

1 . J

Ion 329.60: Area: 388769 Height: 241399

$c\.rj

I

1 . v

14.3 1 14.4 14.5 14.6 14.: 14.8 14.9 15.0 15.1 15.2Min


1.4-

L"1 •

14.4 14.5 14.6 14.7 ; 4.6 ; 4. •? 15.0 15.1 15.1'

J____________________________________________________________________________ N ; r- __________________________! Ion 141 . ■ j ij: Prea: 0 Heisrt: u

l'

80

1 5 . L'Mr,

Data File: .■,chem/5972hp60.1 /DF020313A60. b/UG16228-3A60. dInjection Date[: 13-MhR-2002 13:53Instrument: 5972hp60.iClient Sample ID: MU-13BM3

Aund: :■lumber

2 ’--ovybis< 1-Chloropropane > 1 'Jb-bU-1

6.0-

5.6-

5.2-;

4.8-

4.4-

4.0:

Ion 45.00: Area: 152136 Height: 63640 Q43 '

i •ODI

1.0-

1 .2

' j . 8

6.4 8.5 8.6 8.7 8.8 8.9 9.0 9.1____________________ Min__________________________________________________________


CD

1 . 1

I onMl

8.8 8.9

Helgnt; 0

1

l

80 b

i'llQ 18.8 6.9

Data File: /chem/5972hp60. i/DF020313A60. b/UIG16228-3A60. dInjection Date: 13-MAR-2002 13:53Instrument: 5972hpb0.lClient Sample ID: MU-13BMS

#und: N-Nitroso-dl-N-propy1 amine■Jumper : 621 -64-7

4.5-

4.2-

3,9-

3.6-

3.3- '

3,0-

Ion 70.00: Area: 92439 Height: 45360

CD

qd-

2.1-

1.6-

1.5-

1.2-' 0.9-

0.6- 0.3-

0.0-

"8.4 8.5

/ J;

3.6 8.7 0.8Min

8.9 9.0 9.1 9.2 9.3

3.5

#

e.4


8.6 9.1

Ion 42.00: he l gnt. : 0

81

d . 3

M i n9.1 9.3

Data File: /ch'em/59?2hp60. i/DF020313A60.b/UG16228-3A60.dInjection Date: 13-MAR-2002 13:53Instrument: 5972hp60.1Client Sample [ID: MU-13BMS

hound: 4-Nitrophenol

■Number: 100-02-7

1.6

1 . 6

1

1 . 1

Q

Ion 109.00: Area 6945:aU5l»rn

Height: 33448

! i

4 13.5 13.6 13.7_______________________Min____________________

Ion 65.00: Area: 0 Height

13.8

0

13.9 14.0

in

■£i

rn

14.1

1 . 5 17.6 13.7 13.0 13.9 14.0 14.1__________________________________M I :‘i_________________________________________________________________________________________________________________________

Ion 179.00: Area: 0 height: 0

i

811

13.9 1 4 . A 14 . 1

[


GC/MS SEIVD-VOA WORKSHEET

LAB INSTRUCTIONS: QE1877-12 FOR QCI

RECEIPT DATE: 3/8/02 0:00 SAMPLE DATE: DUE DATE:i

CASE#: SDG: WG16228 COMPUCHEM#: WG16228-3

CLIENT ID: MW-13BMS


Injection Volume :1.0pL Dilution Prep (if needed)I

Extraction Date___3___/10____/__02

DFTPP Filename DF0203 / 3 A C t?

Sample File Name u-1 /-? / j- i i £' - 7 A a

ANALYST (S): Injectioncf / 1_________________ Work-up<7 ( 7

GC/MS DATE REVIEW

CONDITION CODE


Number of peaks found: _____ S'/^L.

Number of Hits found:_______

Number of Surrogate Outliers:'i

Quality Assurance Notice (s)Number of Notices Required §

Disposition: [/] Complete



[ ] Reinject Neat

[ ] Dilute ( X)

Comments:

#GC/MS Review

Final Reportable Package(s):

Date 3 //</■' l' Auditor

td ^ /L 2TT -3 xj/g' o

Date / /

812

S VI - 6/27/01: PTF

assigned ro: Af

kKbo

^c_

C (impuC'hcm


SF.MI-VOI.ATII.E WATER, Method 3510C for 8270C DA I I lXIKO IED/POSI I D:

■' ........ ~ -V. ■^' 0^

SAMPLE , FINAL Adlusted bH . V—ISAMPLE NUMBER ;J

$C SAMPLE , •A i-TYPE ; • S

’i: /VOLUME .

(mlJ

VOLUME

(ml)A/N base ; comments oo

Q^/ir?7- $■ /eo& ____ IP AG 12.;

: 1- /ore _______ l.n A 6 i2 1/£>£& ____ 1.0 Au l-z i/ ^

/OOa 1.0 I.L \2\* /coo Id A U 17.1 Qc-i? ^

/?- /coo .. .6 / b |2 (

ft //a<o •C LL 12 |

if jo<rc 1.0 AU >?.l

> _______ U- /bCO\d

/ h 12.i

. / 7 /CC €U

/ (r i‘Z-1■ 1 I*

/QCC U 7i, Ml

2 V /f /COG • 1.0 / c (2.»

i Mr/i'zZfcy /etc l.o }. b 12-14 > / s s /Oco Vo AU 12 <qtriihi-i

/CO® ItO Ai n. 1<ry7h/ozY-f Joev 1-0 A 6 Q-1 ( c x-dccm c _ ____

/ __^

8 rl 1 l />

9JTTTUj; -

0

1 __ ,-—-------

.2 ~ — -!3 LvirKp ZZi'-l

Blk jm M JU \i\14 J S' Z' LCS /COO 1.0 / (# rJ-( *Add 1.0 ml. validation spike to 1 ( S and SSs unless otherwise noted

S-VOL Acid 8270FINAL VOLUME VERIFIED: ]________ ___

NO. 393- is/ ^

__SURROGATE AIMT. 1.0 ml A/~■v i'

•--------- .---- rLOT KH/11 7^---------------

SltPERVISOR REVIEWED: ^ ------- ............... '..... .......NO. 3012/^ 2021 VALID.

SPIKE AMT. LTml 1.0ml 1.0 ml 170LOT T07/1T Sl'RROtiA l E & SPIKE ADDED 1)V: ^ _____

Analyst initials. Extracted

Manul^Hr

KD JYYN2 Dottle \N'i (ness

Initials I )aie

#. Initials Date /

r and lot number of reagcnts/solvents used ~ CT 17 1 i ^ ,1 I __ ^ -^ £_______

e. Matrix Spike Duplicate Data



814


CLIENT SAMPLE NO.

Lab Name: COMPUCHEM

Lab Code: LIBRTY


Sample wt/vol:

Level: (low/med)

% Moisture: ______


Injection Volume:

Contract:

Case No.: SAS No.:

WATER

1000 (g/mL) ML

LOW

decanted: (Y/N)

Volume: 1000(uL)

1.0(uL)

8270CMW-13BMSD

SDG No.: QE1877










108-95-2--------Phenol 12111-44-4--------Bis(2 -chloroethyl) ether 3095-57-8---------2 - Chlorophenol 28541-73-1--------1,3 -Di chlorobenzene 26106-46-7--------1,4 - Dichlorobenzene 2795-50-1---------1,2 - Di chlorobenzene 2695-4 8- 7---------2 -Methyl phenol 3410 8 - 60-1--------2,2' -oxybis (1 -Chloropropane) 2910 6- 44-5--------4 -Methylphenol 51621-6 4- 7--------N-Nitroso-di - N-propvl amine 3067-72-1---------Hexachloroethane 289 8 - 95- 3 ---------Nitrobenzene 307 8-59 -1--------- I sophorone 3283 -75-5---------2 -Nitrophenol 3310 5-67- 9--------2,4 - Dime thy lphenol 25111-91-1--------Bis (2 - chloroethoxy) methane 34120 - 33- 2 --------2,4 -Dichlorophenol 351 20- 82-1--------1,2,4 -Trichiorobenzene r?-J91 - 20-3---------Naphthalene 351 0 6 - 4 7 - 5 --------4 - Chloroani 1 ine 40

i 8 7 - 5 3 - 3 ---------Hexachiorobutadiene 341 5 9 -50 -7---------4 - Chloro - 3 - met hylphenol 37; 91-57-6---------2 -Methylnaphthalene 40I 77-47-4---------Hexachlorocyclopentadiene 30■ 88 - 06-2---------2,4,6 - Tri chlorophenol 40‘ 9 5- 95-4---------2,4,5 - Tri chlorophenol 5591-58-7---------2-Chloronaphthalene 33

• 33 -74 -4 ---------2-Nitroamlme 3 8131 - 11 - 3--------Dimethylphthalate 45

40208 - 96 - 8 --------Acenaphthylene 389 5-03-2---------3 - N11 roa n 111 ne 40

.8 3- 82-0---------Acenapnthene 40

FORM I SV 8270C

81b


CLIENT SAMPLE NO.

i1

Lab Name-. COMPUCHEM Contract:





% Moisture: ______ decanted: (Y/N)



8270CMW-13BMSD

SDG No.: QE1877









51-28-5---------2,4 -Dinitrophenol 20 J100- 02-7--------4 -Nitrophenol 21

1 121-14-2--------2,4-Dinitrotoluene 42: 132-64 - 9--------Dibenzofuran 4284-66-2---------Diet hylpht ha late 44

, 7005-72-3-------4 -Chlorophenyl-phenylether 43■ 86-73 -7---------Fluorene 41100-01-6--------4 -Nitroaniline 43

■ 534-52-1--------4,6 - Dmitro - 2 - me thy lphenol 4185-30-6---------N-Nitrosodi phenyl amine (1) 43101-55-3--------4 - Bromophenyl - phenyl etHer 46118-74-1--------Hexachlorobenzene 42

: 87- 86 - 5---------Pentachlorophenol 39; 85-01-8---------Phenanthrene 46120-12-7--------Anthracene 4886 -74 -8---------Carbazole 56

1 84 -74 -2 ---------Di-n-butylphthalate 46I 206 -44 - 0 --------Fluoranthene 51' 12 9 - 00- 0 --------Pvrene 46■ 8 5- 68-7---------Butyl be nzylpht ha late 4291-94-1---------3,3'- Dichlorobenzidine 24

| 117-81-7--------bis ( 2 - et hvl hexvl) Phthalate 44 B'< 56-55- 3 ---------Benzo (a) anthracene 51218-01-5--------Chrysene 50

■ 117-84-0--------Di - n -octyl phthalate 4 3205- 9 9- 2--------Benzo(b) fluoranthene 4 9207-03-S--------Benzol k) fluoranthene 48

, 50- 32-8---------Benzo ( a) pyrene 49193-3 5 - 5--------Indeno (1, 2 , 3 - cd) pyrene 46

1 5 2 - 70-3---------Dibenzo (a, h) anthracene 53191-24-2--------Benzo (g , n , i) perylene 54

(1)1 Cannoc be separated from DiphenylamineFORM fsv J 8270C

81b

Data Filet /chem/5972hp60* i/DF020313A60,fc'/UG16228-4A60*d

Date : 13-MAR-2002 14:33

Client ID: MW-13BHSD

Sample Info:

Volume Injected <uL): 1*0

Column phase: J&W BB-C,62C


Operator: 017


oo

Data Fi let /chem/5972hp60. i/DF020313H0O.b/l-JGlF228-4fi60.d

Date : 13-MAR-2002 14:33

Client ID: MW-13BMSD Instrument; 5972hp6'

Sample Info:

Volume Injected (uL): 1.0 Operator: 917

Column phase: J8.W DB-C.625 Column diameter: 0

'O

—I

oo


CompuChem

Data file Lab Smp Id Inj Date Operator 1 Smp Info 'Misc Info Comment Method Meth Date Cal Date 'Als bottle Dil Factor Integrator Target Version: Processing Host

Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020313A60.b/WG16228-4A60.d WG16228-4 Client Smp ID: MW-13BMSD13-MAR- 2 0 0 2 14:33917 Inst ID: 5972hp60.i

/chem/5972hp60.i/DF020313A60.b/8270Cv6.m14-Mar-2030 08:48 byrd Quant Type: ISTD

MAR-2002 17:20 Cal File: HLO20303A60.dQC Sample: MSD

0341.00000 HP RTE

3.50einstein




DFVtVoVi

1.00000

1000.00000

1000 . 00000

1.00000



CONCENTRATIONS

J vUANT S1G ON-COLUMN FINAL

Tern pour, .is '|1

MASS RT EX? RT REL RT RESPONSE i NG) [ ug/L) SIMILARITY

1'. • '.i -i 9 . 1S4 9 i S "J ■; 1 . COO 1 102078 40.0000

* 2 Naphtha:ere - ' 1 r. 1 .'I i r> :c 3 o i !l . 0 0 0) 261671 40.0000

• Aoeraprtrerv-i:; : b4 ■ -> ■; c - -. i 7 a ' 1 . 0C0 1 216443 4 0.0000

4 Pnvrartrren-r-'i: ■ : s ? : 6 . 0 04 4 . 0 0 3 : 000 : 43575S 40.0000

; ■ i::: : 2 ;-3 3 2 2 ‘ ■ 4 3 coo ■ 514923 0000 .

•r

2 44 : 3. 2:' 21 3: = KiO ■ 437127 40 . 0000

. - - 2 • 74 ■ , 352397 : 1 7 . 720 117.7 (EM)

" - 9 2 7 2 4 26.933- 23 . 5 3

5 .■ N : ' : :■ v: ■; : - • . i 2 . 129222 34.5397 3 4 54

;■ ■ F - :■ .. . : . 2 1 : 2 ••• “ •• : 2 ■ V; C 7 1 4 25.5=7; 3 6 6 r

:• 3 •: : 4 . 7 - •: va; 1 01 . 229553 1 1C 723 112.7 1 n 1

; : - - : :: Oil: 639355 44.7303 4 4 7 9

7 421 50 1 1 . 3573 11 9 6

7 7 : - . " : . 0 0 4 ; 72233 25.7684 2 5.77

813


CONCENTRATIONS



18 2-Chloropnenoi 128 7.815 7.814 (0.958) 78569 28.3059 28 .31 904 6

15 1,3-Dichiorobenzene 146 8.052 8 . 051 (0 . 988) 99920 26.251S 26 .25

20 1.4-Dichiorobenzene 146 8.171 8.187 (1.0021 102851 27 . 1192 27 . 12

o o :.2 -Dichlorobenzene 14 6 8.424 8.423 (1.033) 96612 26.4646 26.46

-> 2-Methylphenol 1 0 5 3.594 5.610 {1.054) 75683 33.594 5 33 59

24 2.2' - envois . i - Cr. iorepropane ; 4 5 3.611 5.610 [1.056! 99606 28 . 7366 2S . 74 72 1 3

2 7 4 -Methy 1 phenol 10 3 5 . S 6 4 3.863 (I.067) 146947 51 . 3252 51 . 33

28 N -N it roso - d: - N propy lam i ne 70 8 830 8.929 \ 1 .083) 61820 29.7511 29.75 0

2 5 Hexachlor oethane 117 9.000 8.999 (1.104) 44797 27.6820 27.58 3964

3 U Nitrobenzene 77 5.118 9.117 (0 . 885) 97498 30.0400 30.04 9010

31 lsophorone 82 9 . 524 9.523 (0.924) 165164 32 . 3169 32 . 32 8 968

32 2-Nitroohenol 135 9.659 9 . 653 (0.938) 52575 32.8053 32.81 8852

■j 3 2,4-Dimethylphenol 122 9.744 9.760 (0.946) 48931 25.1630 25.16 8009

34 Bis(2 -chloroethoxy) methane 93 9 .896 9 . 895 (0.961) 104881 34 . 0852 34 . 09 7824

3 5 2,4 -Dichlorophenol 162 10.082 10.081 (0.979) 98930 34 . 54 96 34 . 55

36 1,2,4 -Tnchlorobenzene 180 10.218 10.217 (0.992) 112680 33 . 1456 33 . 15

37 Naphtha 1ene 128 10.353 10.352 (1.005) 269409 34 . 64 17 34 . 64 9030

3 8 4-Chlcroaniline 127 10.455 10.454 (1.015) 130693 39 . 8673 39.87 8679

35 Hexachiorobutadiene 2 2 S 10.556 10.572 (1 . 025) 89610 33 .7004 33 . 70 8417

4 -Chloro -?- methy1 oneno 1 107 11.317 11.316 (1.099) 88453 37 . 1585 37.16 9178

42 2 - Methy 1 naphthaiene 142 11.554 11.553 (1.122) 229266 39.5509 39.55

44 Hexach:orocyc1openc adiene 2 3 7 11.625 11.824 (0.684 ) 75797 30.4663 3 0.47 9244

156 12.062 12.061 '0.9011 95727 40.1721 40.17

2 , 4 , 3 - Tr : cr. 1 ore phene 1 15 6 12.129 12.145 '0.906: 142003 54 . 7391 54 . 74m 2 - Ch'.oronapntr.aiene 16 2 12 . 4 c c 12. 395 (0.927: 222561 33 .1569 33 . 16mm-. 2 - N: troan: 1 me 6 5 12.586 12.602 «'C .941) 98427 37.6548 37.65 6903

~ C' D: me t hy 1 pr.r :-a a t e i = ’ : 2 9 o c 12.9C7 '0.9651 397672 45 . 1298 45. 13 9725

-r. 2 . 5 - D: r : i rot i • tier.- 16 5 12.005 ■ i i - •0.972) 75276 40.0533 4 0.05 9016

A :er.ar.:'.: ny ; e:v.- 152 - -. : -j ^ • - ' ~i~ i 0 . 5 S 1 ) 407296 37 . 7272 37.73 3656

i :■ 3 -N :: roar.: mn 3 5 ■ • •: ■ S *J ■) C\ •0.595) 79195 39 . 7050 39.71 9104

r •; iE.y : ; . 11 r ' 1 . 0 0 4 : 251249 39.5718 39 . 57 8 94 7

: i is-; 1 ; . 5 •'; 0 -.3 s:-.' : . 00 5' 2 3 74 9 20.2052 20.21

r : o :■ i :■ 5 2 1 : . r 1 :. o20■ 34 364 21.4380 21.44 c

= 7 2 . 4 -Dm:: not t j .en-_- 13 7:' - : 7 16 1.02 5 117147 42 . 0835 4 2.0 8 374 2

2 r 165 : ,->bz : - . ^27 452502 4 1 . 7356 4 1.74 3 4 5 8

5 5 Diet ny 1 pm: r.a . ate 14 5 ; E ■ ■: i r- :• . 1'rV 423429 44 .4605 4 4.46 9108

4 - Ch : c r tphery ) -pm iemer 224 1 4 3 4-: :4 :;e : -.72• 2 2 2 6.7 4 42.34 85 42.35 736 3

Klvcrem :s; ■ 4. 4 - ■.4.345 : . 2 7 2 388383 4 1 . 214 5 41.21 7 3 30

: 1 C • 4 3 7'. ■ ■' 5 ; 2 : a 71 3 74 18 43.4846 4 3.48 8426

4 , 6- Dm: : no- 5 - me: ny 1 plieno 1 155 e y : 4 4 6 3 74 321 4 1 . 2159 4 1.22 Q i'.') »

N' ■ ■:: t rosed : pn.eny ! am: ::e 1 6 v : - ■ r -4 '• c; 2 i :•: :• 248063 42.7183 42.72 965S

_ *i z 1 5 . 2 ' r . . ... • 15. ■so:-7-: 45 . 9550 4 t . 9 6 .' -)..7 294 1 2 . :2 T : t - "EE 157668 42.4237 42.42 i' ' "i

2 5 : 1 ?• 5 r 2 . 4 2 7 } r, 39.277? 3 9 2C> 3 512

j| ' •. n z : • : ■; ■ ■ : 6 3 3 1 4 t 46.3259 4 6.33

' *71- ■ : • - : . "r- ■? 6 4 7 i 3 48.3155 48.32

6 “ : 4 :• • ; 2: 2 : 0 2 •; , 6 Q n 9 h c 56 . 3145 56 . 31 9 0 97

82 G


CONCENTRATIONS

ipounds

QUANT SIG


ON-COLUMN

( NG)

FINAL

( ug/L) SIMILARITY


74 Fluoranthene 202 18 . 152 18 . 151 (1.134) 812746 51.4723 51.47

16 Pyrene 202 18.541 18 . 557 (0.898) 848785 45.9424 45.94

11 Butylbenzylphthalate 14 9 19.641 19.657 (0.952) 400151 41 . 9420 41.94 5118

78 3,3'- Dichlorobenzidine 252 20.554 20.570 (0.996) 174886 24 . 0053 24 . 01 7628

79 bis (2-ecnylhexyl)Phthalate 149 20.605 20.604 (0.998) 588320 44.1522 44 . 15 8753

80 Bento(a)anthracene 228 20.622 20.621 (0.999) 941310 51 . 0678 51 . 07

81 Chrysene 228 20.673 20.672 (1 . 002) 831703 50.0652 50.07

32 Di-n-octylphtha late 149 21.586 21.585 (0.930) 938992 42 .6567 42.66

83 Benzo (b). £ luorant hene 252 22.398 22.414 (0.965) 929721 49 . 3191 49.32

8 4 Benzo (k'fluoranthene 252 22.449 22.465 (0.967) 812396 47.6640 47.66

95 Benzo(aipyrene 252 23.092 23 . 091 (0.995) 743238 49.2644 49.26

8 6 Indeno(1,2,3 - cd) pyrene 276 26 . 120 26 . 136 (1.125) 742359 46 . 1128 46.11 34 71

67 Dibenzo(a,h)anthracene 278 26 . 171 ' 26 . 187 (1 . 128) 735942 52.5199 52.52 8704

68 Benzo(g,h,i)peryiene . 276 27.017 27.033 (1.164) 732509 53 . 9947 53 . 99 7493

QC Flag Legend


R - Spike/Surrogate failed recovery limits.M - Compound response manually integrated.

82i

Data file: .•,chem-',5572hp60.1 /DF020313h60 . b/ldG16226-4A60. dInjection Date': 13-MAR-2002 14:33Instrument; 5972hp60.iClient Sample ID: MW-13BMSD

ii'und: 2-F liorpphenol 'bumper: 307-12-4

Ion 112.00: Area: 382397 Height: 31545ts

5.63 5.75 5.80 5.85 5.90 5.95 6.00 6.05 6.10 6.15 6.20 6.25 6.30 b. 35 6.40 6.45 6.50Min

Ion 64.00: Area: 0 Height: 0opmo

uj

R RR R I 5.80 5.8 Ci O . r'J b. 05 6.10 6.15 6.25 6.30 6.35 6.40 6.45 6.50

Ion 92.00: Hr-ea: Helgnt:

•iii

5.85 5.9',Min

6.25 6 o.35 6.4m 6.4' 6.506.10 6.15

cund: 2.4,b-Tr1bromopheno1 Number: lll8-79-b

Data File: •/chern/5972hp60. i/DF020313A60.b/WGl622B-4A60.dInjection Date|: 13-MAR-2002 14:33Instrument: 5972hp60.iClient Sample jlD: MW-13BM5D

1 ■

1 • 1-

Ion 329.60: Area: 229563 Height: 125934i&CDis.ri*-?

1-4.30 lU.35 1-4.-40 14.-45 14.50 14.55 14.60 14^65 14.70 14.75 14^80 14.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20 15.25 'I________________________ Min

Ion 332.00: Area: Height:

1 - . ‘.K . 75 1-.40 1-.4C 1 4. =.r. 14.55 14.60 14.05 M.^o 14 . ?5 14.80 14.35 14.90 14.95 15.00 15.05 15.10 15.15 15.20 15.25I _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ M i r

Ion 141.0 heignr: n

Data File: .',chem/5972hp60 . 1 /DF020313A60 . b/UG16228-4A60 . dInjection Date': 13-MAR-2002 14:33Instrument: 5972hp60.1Client Sample ID: MU-13BMSD

,ound: mbe

N-Ultroei•: 621-64

di-N-propyl amine

4.2'

3.9-

3.6-

3.3-'

3.0-

Ion 70.00 rea 61820

rtlCD

IS

Height 42046

1

4 . J

8. JO 6.45 6.50 8.55 8.60 8.65 8.70 8.75 8.80 8.85 8.90 8.95 9.00 9.05 9.10 9.15 9.20 9.25 9.30______________________________________________ M i n___________________________________________________________


iT.i*Js

CD

6 . J? 6.50 6. t-5 8.60 5.65 6.70 8.75 8.80 5.65 8.90 6.95 9.00 9.05 9.10 9.15 9.20 9.25 9.30 * I_______________ M i r. __________________________________________________________________________

I on. 4~.00: Ar-e=>: 0 Hei^nt; ij

•l:o

3. SO 8.85 8.90 3.95 0.00 9.05 9.10 9.15 . 20 y.,j5 9.30M i n

Data File: /chem '5?72hp60. 1 /DF02C313h60. b.'WGl6228“4M60.dInjection Date: 13-MhF:-2002 14:33Instrument: 5972np60.1Client Sample ID: MU-13BMSD

puna: Plumber

4-Nit ropnenol

Ion 109.00: Area: 34364 Height: 15714cuip

n

13.35 13.40 13.45 13.50 13.55 13.60 13.65 13.70 13.75 13.80 13.65 13.90 13.95 14.00 14.05 14.10Min

Ion 65.00: Area: Height:

.40 13.45 13.50 1 o.55 Ij.60 !o.65 13.70 13.75 13.80 13.85 13.90 13.95 14.00 14.05 14. K run

I

82 o

5 13.50 13.55 13.60 13.65 13.70 13.75 1 3 1 30 13.85 13.90 13.95 14.00 14.05 14 ’. l 0

Min

CompuChema Division1 of Liberty Analytical Corp.


LAB INSTRUCTIONS: QE1877-12 FOR QC

RECEIPT1 DATE: 3/8/02 0:00 SAMPLE DATE: DUE DATE:

CASE#: ! SDG: WG16228 COMPUCHEM#: WG16228-4

CLIENT ID: MW-13BMSD


Injection Volume :1.0pL Dilution Prep (if needed)

Extraction Date___3___/10____/__02

DFTPP Filename DF0203 / J ,A £ 0

Sample File Name___U/Y-T / / / ^ 5T - w A S6'

ANALYST (S): Injection"I / 1_________________ Work-up

GC/MS DATE REVIEW

CONDITION CODE


Number of peaks found: r-'fi'

Number o^f Hits found:


Oualit> Assurance Notice (s) Number of Notices Required (P

Disposition: y ] Complete


f ] Re-extraction Required

[ ] Reinject Neat

[ ] Dilute ( X)

Comments: A J1 w-s VL Cuvr^.-J* S l-yc i

Us, > ■

-GC/MS ReviewDate A /V A ud itorDate//


;(P C- /£ 2 xf-iy/ZCO

82o

SVI -6/27/01: PTF

ASSI(.NKI) TO:

removal assessment report - appendix g -lab data sheets

Documents