Data Fila: /chem/5972hp60*i/DF020314B60*b/QE1877-3RBb0.d
Date : 14-MAR-2G02 22:59
Client ID: MU-8ARE
Sample Info:
Volume Injected <uL>: 1*0
Column phase: J&W DE-5*625
Instrument: 5972hp60*i
Operator: 2319
Column diameter: 0*32
CD■^T
30225964
Data Fi let /chem/5972hp60. i/DF02Ci3i4B60*b/QEl877-3RB&0*d
Date t 14-MAR-2002 22:59
Client ID: MW-8ARE
Sample Info:
Volume Injected CuL): 1*0
Column phase: J&W DB-5.625
Instrument: 5972hp60.i
Operator: 2319
Column diameter: 0.32
o
18 21 22
Data File: /chem/5972hp60.i/DF020314B60.b/QE1877-3RB60.dReport Date: 15-Mar-2030 12:14
CompuChem
Data file Lab Smp Id Inj Date'Operator Smp Info Misc Info Comment .Method Meth Date Cal Date Als bottle Dil Factor Integrator Target Version: 3.50
Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020314B60.b/QE1877-3RB60.d QE1877-3 Client Smp ID: MW-8ARE14-MAR- 2 0 0 2 22:592319 Inst ID: 5972hp60.i
/chem/5 9 72hp6 0.i/DF02 0314B6 0,b/82 70Cv6.m 15-Mar-2030 10:11 byrd Quant Type: ISTD0 3-MAR- 2 0 0 2 17:20 Cal File: HL020303A60.d51.00000HP RTE Compound Sublist: OLM03 sub
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
DFVtVoVi
1.00000 500.00000500.000001.00000
Dilution Factor Volume of final extract (uL) Volume of sample extracted (mL) Volume injected (uL)
Cpnd Variable Local Compound Variable
CONCENTRATIONS
OUANT SIG ON-COLUMN FINAL
Compounds MASS RT EX 7 RT REL RT RESPONSE ( NG) ( ug/L) SIMILARITY
* 1 1 , 4 - D i cdc: c/cer. crc.e - d4 152 8.13 9 -j o o o 90055 40.0000
: ■ .ir 13 6 10 2 8 8 1 0 . 235 ( 1 . 000 251806 40.0000
: -a:.: 164 13 . 3 3 7 : . 364 ::.0 0 0• 209733 40.0000
■i :i1 ‘ 1 5 5 c n 7 -.5 . 3 8“ t1.000 = 418204 40.0000
:6-'7 2 i: •:. o o: 437640 4 0 . 0000
: 1 . : 7 ■; : 1 7 v , ; dn • 336171 40.0000
: " 1 . - •: . 7, ' 742. 534190 186 405 1 c 5 4iAMJ ^
r Pr-.r.c' ■ c. 7 5 d 4 377 .1:5, i 33930 41.4158 41.42
: :■ • .i; 32 7.-7 7 = = 0; 97921 27 . 197 8 27.20 ■;r )
V :: l-Elucrodicdecv: 1 ~>Z 12 .: e i 229315 28 . i838 2 8.18 i R :
: 1 1 2 .4 ■. :■ :-:rop^nc; 3 3 0 14 .7^4 : 4. 7-1-9 -. 1.104 179627 9 1 . 0287 91.03 (Mi ’
244 13.78'.: 1 3 . 7 7 3 1 C . 9111 479876 39 . 5056 39.51 (R )
-94 Ccmpc ur.d Not. Detected
Els : u - cr.::r.y i 'Adde:' 3 3 Cohdcu r.c Noe Detected
'•-Chiorop.-icr.c.: 128 C Off; pc ur.a Not Detected
40a
Data File: /chem/5972hp60.i/DF020314B60.b/QE1877-3RB60.dReport Date: 15-Mar-2030 12:14
Compounds
19 1,3-Dichlorobenzene
2C 1,4-Dichlorobenzene
22 1.2-Dichlorobenzene
2 3 2 - Met hy lphe.no 1
24 2,2'-cxyb:s(1 -Chloropropane)
2~> 4 -MethylphencI
26 N-Nitroso-di-N-propylamine
29 Hexachloroethane
30 Nitrobenzene
31 Isophorone
32 2-Nitrophenol
33 2,4-Dimethylphenol
34 Eis (2-chloroethoxy)methane
35 2,4-Dichlorophenol
36 1,2,4-Trichlorobenzene
37 Naphthalene
38 4-Chloroani1ine
35 Hexachiorobutadiene
414-Chioro-3-methylphenol
4 2 2-Methy Inaphtha 1ene
44 Hexacnlorocyclopentadiene
4 5 2.4,6 -Trich1oropheno1
46 2,4,5-Trichioropheno1
5 1 2 , 6 - D i n 1 r o : o. u e:e
5 2 Ac e n a pr. t ny lent
5 3 3 - N: c roan i; r.e
54 Acenaphtheue
5 5 2 . 4 - Dm: : rop.oenc i
5 5 4 - N’: t ropner.o 1
5.7 2 , 4 • D: r.; t r o t c 1 u e n e
58 Pibenzofurar.
5 5 C'lethy 1 pht ha la t e
60 4 • Ch 1 oropheny 1 - pher.y i et.ner
51 ~luorene
6 2 4 • N11roan: 1 ::".e6 3 4 , 6 - D: r.: : ro - 2 - me t hy: pheno 1
6 4 N - N •. t msec •„oheny lamine
65 4 - Bromopher/.h - pher.y 1 et her
?7 Hexach:orober.zene
6? Pencach1oropheno1
7 C P h e n ant r. r e r, e
QUANT SIG
MASS RT EXP RT REL RT
146 Compound Not Detected
146 Compound Not Detected
146 Compound Not Detected
109 Compound Not Detected
45 Compound Not Detected
103 Compound Not Detected
70 Compound Not Detected
117 Compound Not Detected
77 Compound Not Detected
82 Compound Not Detected
139 Compound Not Detected
122 9.729 9.727 (0 . 946)
93 Compound Not Detected
162 Compound Not Detected
180 Compound Not Detected
128 Compound Not Detected
127 Compound Not Detected
225 Compound Not Detected
107 Compound Not Detected
14 2 Compound Not Detected
237 Compound Not Detected
196 Compound Not Detected
196 Compound Not Detected
162 Compound Not Detected
6 5 Compound Not Detected
1 6 3 Compound Not Detected
165 Compound Not Detected
152 Compound Not Detected
1 36 Compound Not Detected
154 Compound Not Detected
164 Compound Not Detected
109 Compound Not Detected
16 5 Compound Not Detected
CTi
Compound Not Detected
14 9 Compound Not Detected
2 04 Compound Not Detected
16 6 Compound Not Detected
138 Compound Not Detected
198 Compound Not Detected
169 Compound Not Detected
24 S Compound No: Detected
234 Compound Not Detected
2 6 6 Compound Detected
17 a Compound Not Detected
-.73 Compound N't t Detected
167 Compound Not Detected
149 Comccuud Not Detected
RESPONSE
35268
CONCENTRATIONS
ON-COLUMN FINAL
{ NG) ( ug/L)
18.8473 18.85
SIMILARITY
8188
40o
Data File: /chem/5972hp60.i/DF020314B60.b/QE1877-3RB60.dReport Date: 15-Mar-2030 12:14
Compounds
74 Fluoranthene
76 Pyrene
77 Butylbenzylphthalate
78 3,3'-Dichlorobenzidine
7 9 bis (2-ethylhexyl)Phthalate
8C Eenzoia)anthracene
SI Chrysene
3 2 C:-n-cct y1pnt ha late
63 Eenzo{b)f1uorant bene
34 Eenzo:k' fluoranthene
85 Eenzo (a •• pyrene
3 6 Indenc;1,2,3 -cd!pyrene
87 Dibenzcla , h)anthracene
38 Eenzo >g , h , : ) pery lene
QUANT SIG
MASS RT EXP RT 1REL RT
202 Compound Not Detected
202 Compound Not Detected
149 Compound Not Detected
252 Compound Not Detected
149 20.574 20.588 (0.998)
228 Compound Not Detected
228 Compound Not Detected
14 9 Compound Not Detected
252 Compound Not Detected
252 Compound Not Detected
252 Compound Not Detected
276 Compound Not Detected
278 Compound Not Detected
276 Compound Not Detected
RESPONSE
15356
CONCENTRATIONS
ON-COLUMN FINAL
( NG) ( ug/L) SIMILARITY
9304 (
QC Flag Legend
a
A
#
Target compound detected but, quantitated amount Below Limit Of Quantitation(BLOQ).Target compound detected but, quantitated amount exceeded maximum amount.Spike/Surrogate failed recovery limits.Compound response manually integrated.
404
Data File: /chem/5972hp60.1/DF020314B60.b/QE1877-3RB60.d Injection Date: 14-MAR-2002 22:59 Instrument: 5972hpb0.i Client Sample ID: MLI-8ARE
ouna: 2 Number:
-F luorophenol 367-12-4
Ion 112.00: Area: 534190 Height: 301504
1.8-m 1.6-
~ 1.4-
1.2 1.0
j 0.8 | 0.6 : 0.4-
0.2' 0.0-
5.55 5.60 5.65 5.70 5.75 5.80 5.85 5.90 5.95 6.00 6.05 6.10' 6.15 6.20 6.25 6.30 6.35 6.40 6.45 6.50Min
Ion 64.00: Area: Height: 0
5.55 5.60 5.65 5.75 5.80 5.85 5.90 5.95 6.00 6.05 6.10 6.15 6.20 6.25 6.30 6.35 6.40 6.45 6.50
MinIon 92.00: Area: Height: 0
1
5.55 5.60 5.05 5.70 5.75 5.80
i£b6.05 6.10 6.15 6.20 6.2 6.30 6.35 6.40 6.45 6.50
Data file: /chem/5972hp60.i/DF0203l4B60.b/QE1877-3RB60.dInjection Date: 14-MAR-2002 22:59Instrument: 5972hp60.iClient Sample ID: MU-8ARE
ound: 2.4.6-T nbromophenoiMumper: 116-79-6
T-
Ion 329.60; Area: 179627 Height: 116767
0.0-
1.1-
1 . o-
14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.BO 14.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20 15.25 iMin I
Ion 332.00: Area: 0 Height: 0
14.55 14.60 14.65 14.70 14.M l n
14.80 14.85 14.90 14.95 15.00 15.05 15.1':' 15.15 15.20 1e:
Height:
4
: 4.30 : 4 . ;.3 1 4.4H 14.45 14.50 14.55 14.60 14.65 14.70 1
40 0
’5 14.80 1-1.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20 15.25
Data Filar /ehem/5972hpb0*i/DF020314B60*b/QE1377-3RB60*d
Date : 14-MAR-2002 22:59
C1 i ant- ID MW-8ARE
■Sample InferVo 1 ume I n j acted <. uL): 1 * 0
Column phaser J&W DB-5*625
Instrument: 5972hp60*i
Operator: 2319
Column diameter: 0*32
33 2,4-Dimethylphenol Concentration: 18*85 ug/L
Data File; /chem/5972hp60*i/DF020314B60*b/QE1877-3RB60*d
Date : 14-MAR-2002 22:59
Client ID: MW-8ARE
Sample Info:
Volume Injected <u!_>: 1*0
Column phase: J&U DEs-5*625
Instrument: 5972tip60* i
Operator: 2319
Column diameter: 0*32
79 bis(2-et-hy lhexy 1 )Phthalate Concentration: 1*36 ug/L
CompuChema Division of Liberty Analytical Corp.
GC/MS SEM1-VOA WORKSHEET
LAB INSTRUCTIONS: PPS 985**'VOC 8260B TCL3CT.SUB**SVOC 8270C TCL3**D1SS. METALS-RPT. As,Cr,Cu & Pb~
FILTER & PRESERVE IN-HOUSE
RECEIPT DATE: 3/6/02 0:00 SAMPLE DATE: 3/5/02 14:30 DUE DATE: 3/18/02 0:00
CASES: Q1877 SDG: QE1877 COMPUCHEM#: QE1877-3 ,
CLIENT ID: MW-8A
ANALYSIS DESCRIPTION: SVOA-8270C
Injection Volume :IpL Dilution Prep (if needed)
Extraction Date___3______ 14____ /___02
DFTPP Filename_____ DF020314B60
Sample File Name_____ QEI877-3^B60______________ ____________
ANALYST (S): Injection2319 Work-up
GC/MS DATE REVIEW
CONDITION CODE ■
■ScfS
Extraneous Peak Search Results:
Number of peaks found: _____
Number of Hits found:________
Number of Surrogate Outliers:
(jualitv Assurance Notice (s)
Number of Nonces Required__
%.
i
Comments:
Disposition: [
[ ] Reinjection Required
ivf Re-extraction Required
[ ] Reinject Neat
[ ] Dilute! X).
=GC. MS Rc\ lew
Final Reportable Packaueis):
Date Z'1 Auditor Date
6) fcr / i'}
40 O'
SV1 -6/27/01: PTF
fyi * M
ASSIGNED TO:
KM I* II) NUMBER:
CompuChem
EXTRACTION WORKSHEET
SEMI-VOI.ATH.E WATER, Method 3510C for 8270C
3 ■ ITDATE F.XTRAL 'TED/POSTEl):
-079
J-' •/ 3::A.-Vy. v.,V;-:”7
SAMPLE FINAL Adjusted pHSAMPLE ‘.
-NUMBER//
ktiC SAMPLE:,
-•:; TYPE 3. VOLUME !■' 3.' (ml)
VOLUME____ 0"Q-
A/N BASE 7:7. COMMENTS ' T)
V
1^/r77-5'K\ hpQ_____ Of ly
'2.jr■^r '
«■* /
■»
1
\ 1 LI f)/0o.f \‘(c 12-5" /
3<6-0J -0-Z,
-X—[Z s / *,<*&} U'^ml kb< S\ f,T
41 /r <!
.£>ol_____OS yv
S/ lb‘ dl M..... IZf
0-----------------JTl 3'0d
OS yy iz- 5
1
1TTT 50^ 03 \.y ll-f
S
Spa 05 \ s V [2.5
9- ¥,
0 o0U 12. 5
73/" <7 V K 7^0 5 ”7 7*,- £ y-7'
0
/^£?22W f 1 ~5dD Of) /z-5 7 ._S7*yY 5-"" /<&
11'/OF K-77--?" <5oo Of Jo— \2-0
■ ................. / /
12-*dT^P*1 ^oc Os ..ia,o
13--------------
14l ft? _
IS \±_1
1(>k \
17
IH
l‘>
:oS'
21
--------------------- ,
23 !//0'1Q^ /y Ri.k^0 J \.y \z.g
24 LCS ~$Ud yoy
*Add 1.0 ml. validation spike to I.( S and SSs unless otherwise noted
S-VOL / Add B/N 8270
FINAL VOLUME VERIFIED:NO. 393 4 317 /,/ .SURROGATE AMT. 1.0 ml (17 7/7'^7
/ fLOT 5? 737- vY — SUPERVISOR REVIEWED: 7;'. ■ K/lU-^X
NO. 3012^ 2021 VALID.
SPIKE AMI l^JHnl 1.0ml 1.0 mlLOT
.jsSSi SURROGATE & SPIKE AUDI 1) lt\ : 7\)v / , 3 ) H ( l/U
Analyst initials Extracted
HtK^
Initials I )ale
Ma ,urer and lot number of reagents/solvcnts used
c £\y<b-
Bottle up Witncs*Initials Date
./Sk_Qti_
QUALITY ASSURANCE NOTICE
CompuChem ID# QE1877-3
Client ID# MW-8A
SDG # QE1877
Surrogate recoveries in the semivolatile fraction fell outside the established Quality Control limits in the analyses of both the original and repeated preparations of this sample. Results were comparable between the two analyses. Since all other QC criteria associated with these analyses were met, we have attributed the out-of - control surrogate recoveries to the particular sample matrix, rather than to deficiencies in the laboratory's analytical system.
Under some circumstances, depending on the client's requirements, both sets of data will be reported. When only one report is required, the analyst considers whether or not the repreparation was completed within holding time specifications in deciding which set of data to report. If holding times were met for both preparations, the analysis that appears to be the least affected by the sample matrix will be reported.
Reviewer's initials/ID /6 24
date 3-15-2002
QAN-VSV-4 S 0 10 0 1
411
FORM 1SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO.
Lab Name: COMPUCHEM
Lab Code: LIBRTY
Matrix: (soil/water)
Sample wt/vol:
Level: (low/med)
% Moisture: _______
Concentrated Extract
Injection Volume:
Contract:
Case No.: SAS No.:
WATER
1000 (g/mL) ML
LOW
decanted: (Y/N)
Volume: 1000(uL)
1.0(uL)
8270CMW - 9 A
SDG No.: QE1877
Lab Sample ID: QE1877-4
Lab File ID: QE1877-4A64
Date Received: 03/06/02
Date Extracted:03/08/02
Date Analyzed: 03/13/02
Dilution Factor: 1.0
GPC Cleanup: (Y/N) N pH:
CAS NO. COMPOUNDCONCENTRATION UNITS: (ug/L or ug/Kg) UG/L Q
108 -95-2-------- Phenol 10 u111-44-4-------- Bis (2 -chloroethyl) ether 10 u95-57-8----------2 - Chlorophenol 10 u541-73-1---------1,3 - Di chlorobenzene 10 u106-46-7---------1,4 - Dichlorobenzene 10 u95-50-1----------1,2 - Di chlorobenzene 10 u95-48-7----.----- 2 -Methyl phenol 10 u108-60-1---------2,2' -oxybis (1 -Chloropropane) 10 u106-44-5---------4 -Methyl phenol 10 u621-64-7-------- N-Ni t roso - di - N-propy 1 amine 10 u67-72-1----------Hexachloroethane 10 u98- 95-3 ----------Nitrobenzene 10 u78-59-1----------I sophorone -10 u88-75-5----------2 -Ni trophenol 10 u105-67-9-------- 2,4 -Dimethylphenol 10 u111-91-1-------- Bis(2 - chloroethoxy) methane 10 u120-83-2-------- 2,4 - Di chlorophenol 10 u120-82-1---------1,2,4 -Tri chlorobenzene 10 u91-20-3----------Naphthalene 10 u106-47- 8 -------- 4 - Chloroanil me 10 u87-63 - 3 ----------Hexachlorobutadiene 10 u59-5 0- 7----------4-Ch lor o-3 -methyl phenol 10 u91-57-6----------2-Methvlnaphthalene 10 u77-47-4----------Hexachlorocyclopentadiene 10 u88-06-2----------2,4,6 -Tnchlorophenol 10 u9 5- 95-4----------2,4,5 - Tri chlorophenol 10 u91-58-7----------2-Chloronaphthalene 10 u88-74-4----------2 - Ni t roanil ine 20 u131 -11 - 3---------Dimethylphthalate 10 u6 06-20-2-------- 2, 6-Dinitrotoluene 10 u2 0 8 - 9 6 - 8---------Acenaphthylene 10 u9 9 - 09 -2 ---------- 3 - Ni t roam 1 ine 20 u33-42-9----------Acenaphthene 10 u
FORM I SV 8270C
412
FORM 1SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO.
Lab Name: COMPUCHEM
Lab Code: LIBRTY
Matrix: (soil/water)
Sample wt/vol:
Level: (low/med)I
% Moisture: _______
Concentrated Extract
Injection Volume:
GPC Cleanup: (Y/N)
Contract:
Case No.: SAS No.:
WATER
1000 (g/mL) ML
LOW
decanted: (Y/N)
Volume: 1000 (uL)
1.0(uL)
N pH: ___
8270CMW - 9 A
SDG No.: QE1877
Lab Sample ID: QE1877-4
Lab File ID: QE1877-4A64
Date Received: 03/06/02
Date Extracted:03/08/02
Date Analyzed: 03/13/02
Dilution Factor: 1.0 '
CAS NO.CONCENTRATION UNITS:
COMPOUND (ug/L or ug/Kg) UG/L Q
51-28-5----------2,4 -Dinitrophenol 50 u100-02-7---------4 -Nitrophenol 20 u121-14-2-------- 2,4 - Dinitrotoluene 10 u132-64 -9-------- Dibenzofuran 10 u84-66-2----------Diet hylpht ha late 10 u7005-72-3------- 4 -Chlorophenyl-phenylether 10 u86-73-7----------Fluorene 10 u100-01-6---------4 -Nitroaniline 20 u534-52-1-------- 4,6-Dinit ro-2 -methylphenol 20 u86-30-6'--------- N - Nitro sod iphenyl amine (1) 10 u101-55-3-------- 4 -Bromophenyl - phenyl etHer 10 u118-74-1-------- Hexachlorobenzene 10 u87-86-5----------Pentachlorophenol 20 u85-01-8----------Phenanthrene 10 u120-12-7-------- Anthracene 10 u86-74-8----------Carbazole 10 u84-74-2----------Di-n - buty lpht ha late 10 u206-44-0---------Fluoranthene 10 u129-00-0-------- Pyrene 10 u85-68-7----------Butyl be nzylpht ha late 10 u91-94-1----------3,3' -Dichiorobenzidine 20 u117-81-7-------- bis (2-ethyl hexyl) Phthalate 10 u56-55-3----------Benzo (a) anthracene 10 u218-01-9-------- Chrysene 10 u117-S4-0-------- Di-n-octylphthalate 10 u205 - 9 9- 2-------- Benzo (b) tiuoranthene 10 u207-0 8- 9---------Benzo (k) tiuoranthene 10 u50-32- 8 ----------Benzo (a ) pvrene 10 u193- 3 9- 5-------- Indeno (1,2,3- cd) pyrene ■ 10 u53 - 70-3----------Dibenzo (a, h) anthracene 10 u191-24-2-------- Benzo (g , h , i ) perylene 10 u
(ll 1 Cannot be separated trom Diphenylamine
FORM I SV
4 'i V J_vJ
8270C
Sample Info:
Volume Injected CuL>: 1,0 Operator; 917
Column phase: RTX-5 Column diameter: 0.32
Data Fi le: /chem/5972hpt.4. i.-yDF020313Ht>4.b/uE1877-4A64,i'J
Date : 13-MAR-2002 15:34
Client ID; MW-9A Instrument: 5972hpti4.i '"•J" \—I
Sample Info:
Volume Injected <”uL>: 1*0 Operator: 917
Column phase: RTX-5 Column diameter: 0.32
Data Fi la: /chem/5972hp64. i/DF020313A64.b/QE1877-4A64.d
Date : 13-MAR-2002 15:34
Client ID: MU-9A Instrument: 5972hp64.i
41b
Data File: /chem/5972hp64.i/DF020313A64.b/QE1877-4A64.dReport Date: 14-Mar-2030 11:42
CompuChem
Data file Lab Smp Id Inj Date Operator Smp Infer Misc Info Comment ■ Method Meth Date Cal Date'
Semivolatile Report SW-846 Method 8270C /chem/5972hp64.i/DF020313A64.b/QE1877-4A64.d QE1877-4 Client Smp ID: MW-9A13-MAR- 2 0 0 2 15:34917 Inst ID: 5972hp64.i
/chem/5 9 72hp6 4.i/DF020313A64.b/82 70Cv6.m14-Mar-2030 11:17 byrd Quant Type: ISTD10-MAR- 2 0 0 2 17:23 Cal File: HLO20310A64.d
Als bottle :' Dil Factor: Integrator: Target Vers
101.00000 HP RTE ion: 3.50
Compound Sublist: OLM03.sub
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
DFVtVoVi
1.00000 1000.00000 1000.00000 1.00000
Dilution Factor Volume of final extract (uL) Volume of sample extracted (mL) Volume injected (uL)
Cpnd Variable Local Compound Variable
:ONCENTRATIONS
-vu’-iT o!G ON - COLUMN FINAL
. ^ MAS i R7 X : : RESPONSE { NG) i ug/Li SIMILARITY
: . .9 r. -J 5 2 r .24 6 6.24. 2 U 0 n 4 7 4 0.000 0
: 1- ■ \ 2 - 2 21 2 : . 22 i 2 j : ' : 1 j -59027 4 0.000 0
: Ac-carci ^1” 2 64 : 3. : u :: : 3 :• ■: . 710723 4 0.0 0 0 0
■, ' IBr ;; n o o • 1266904 4 0.0 0 0 0
-I ' ' •- 2 4 0 : 3 5-V : .• non) 1004780 40.0000
2 z> 4 . :: .v:; :: : = •:.:'. j ■ 638843 o o
112 •, 4 2- o 4 22 '■ 7 3 ?; 709688 72.7224 73 . ~2
- ; 5 9 7 74-: 7 ~s: • g j g c, i 636345 50 . 0936 5 0 . 10
’■ 6“ ■■■.' : 9 : e 1 - 3 g u 518337 4 3.57 9 2 4 3.58
, r • • - . - ; .. .. 7 2 • - _ •• - i ■> t g -j 4 7 . 8 S 7 9
121 641
4 7.86.
12 1 6: 1 : . ; . ■■ ■ 7:'-,:rr.v::c : '.4 .442 : 4 4 2 ~ : :> - ? i 870418 •• i
U' ' : 7-.y. : - 24 4 : 7 2 4; ;" - 7 2 '..595, 2297665 9 6 . 3 1 6 3 6.35
:■■■= • ' • =
■ " I'etecied
Selected IS
41b
Data File: /chem/5972hp64.i/DF020313A64.b/QE1877-4A64.dReport Date: 14-Mar-2030 11:42
Compounds
QUANT SIC
MASS EXP RT REL RT RESPONSE
CONCENTRATIONS
ON-COLUMN FINAL
{ NG) ( ug/L)
9 1,3-Dichlorobenzene 146 Compound Not Detected
0 1,4-Dichlorobenzene 146 Compound Not Detected
2 1,2-Dichlorobenzene 146 Compound Not Detected
3 2-Methylphenol 108 Compound Not Detected
4 2,2'-oxybis(1 - Chioropropane) 45 Compound Not Detected
7 4-Methylphenol 108 Compound Not Detected
.3 N-Niiroso-di-N-propylamine 70 Compound Not Detected
9 Hexacnloroethane 117 Compound Not Detected
G N i t robenzer.e 77 Compound Not Detected
I sophorone 82 Compound Not Detected
- 2 - Nitropnenci 139 Compound Not Detected
3 2.4-Dimethyl phenol 122 Compound Not Detected
4 Bisi2-chioroethoxy)methane 93 Compound Not Detected
5 2,4 -Dichlorophenoi 162 Compound Not Detected
, 2,4- Trichlorobenzene 180 Compound Not Detected
7 Naphtha ier.e 126 Compound Not Detected
4 -Ch1 Groani:ine 127 Compound Not Detected
9 Hexach1orobotadiene 225 Compound Not Detected
4 - Ch 1 ore - :• - me t hy 1 pheno : 107 Compound Not Detected
2 2 - Me thy • nap.ot ha 1 er.e 142 Compound Not Detected
Hexach•orocyciopen:adiene ~> 7 7 Compound Not Detected
3 2 . 4.5-7r. rr. 1 or ophenci 196 Compound Not Detected
6 2.4.5 -Tr:chioropnenol 1 96 Compound Not Detected
2 ■ Chioronaphtha lene 152 Compound Not Detected
9 2 - Nit rc an : 1 ir.e 6 5 Compound Not Detected
0 Dimethy:pheha 1 ate i 6 2 Compound Not Detected
2 . 6 -D: r.i t rotcluene 16 5 Compound Not Detected
2 Acenaphc hy; er.e 152 Compound Net Detected
; - N:: roar.: : :r.e 1 3 S Compound Not Detected
■; 1 54 Compound Not Detected
5 2.4-2". n: t r •: o h end 1 b4 Compound Not Detected
3 109 Compound Not Dec ected
7 2 . ; -11: n :: : *::■ uene 165 Compound Not Detected
1 6 S Compound Not Detected
: •' •'*•*•* • i v : >••••• i-iS' Compound Not Detected
o 4 -Chic reph-rry : ■ pr.eny 1 ether 204 Compound Not Detected
F ; uc: 156 Compound Not Detect ed
2 - : • ' ■ ■■:■■■■■ 13? Compound No: Detected
4 . : r.:' r- - - - m-t ry j pheno i - 9 z Co-pou.-.c No: Detected
■’ • • • • • • ..... - 1 - • ■ - - - :> ...... Detected
. :: r.'.-:'.y : •‘•I : 24 - Cc-vpo.;:- -N..V. D=:ec^ci
2 T V V, rr. v N;.t Detected
: 7 r Tcrcturz Nt \ 2>e: ect ed
-r :or?:-jr.r. Detected
Icmpvur : No: De t ected
: 4 9 Compound No: Detected
SIMILARITY
Data File: /chem/5972hp64.i/DF020313A64.b/QE1877-4A64.dReport Date: 14-Mar-2030 11:42
QUANT SIG
Compounds MASS
74 Fluoranthene 202
74 Pyrene 202
7 7 ButylbenzyIphtha late 14 9
7 3 2 . 3 ' - D: ch i.orobenzidine 2 52
79 bis:0-echyihexyi;Phtha late 149
30 Benzo >'a ; ant hracene 226
51 Chrysene 226
32 D:-n-ocr yiphtha late 14 5
33 Benzo(b)f1uoranthene 252
34 Benzoik’:luoranthene 252
85 Benzo1 a 1 pyrene 252
56 Indeno(1,2,3-cd)pyrene 276
57 D:benzo(a,h)anthracene 278
88 Benzo(g,n,i)perylene 276
CONCENTRATIONS
ON-COLUMN FINAL
RT EXP RT REL RT RESPONSE ( NG) ( ug/L)
Compound Not Detected
Compound Not Detected
Compound Not Detected
Compound Not Detected
Compound Not Detected
Compound Not Detected
Compound Not Detected
Compound Not Detected
Compound Not Detected
Compound Not Detected
Compound Not Detected
Compound Not Detected
Compound Not Detected
Compound Not Detected
SIMILARITY
QC Flag Legend
M - Compound response manually integrated.
418
Data File: /chem/5972hpb4.i/DF020313A64.b/QE1877-4A64.dInjection Date: 13-MAR-2002 15:34Instnument: 5972hp64.1Client Sample ID: MU-9A
#ouno: 2.4.6-TribromophenolMumper-: 118-79-b
Ion 329.60: Area: 670418 Height: 5747o5
14.00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.05 14.90 14.9;Min ■
Ion 332.00: Area: 0 Height: 0
1
0
rvinT
1 4 . 00 1 4.05 14.10 14. 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.85 14.90 14.9 _____ _______ M l n
Ion 141.00: Area: Heignt:
4 19l-.OO 14.05 1 -. i 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.30 14.75 14.80 14.S5 14.90 14.9
_____ ________ _ _ Min
CompuChema Division of Liberty Analytical Corp.
GC/MS SEMI-VOA WORKSHEET
LAB INSTRUCTIONS: PPS 985**VOC 8260B TCL3CT.SUB**SVOC 8270C TCL3**DISS. METALS-RPT. As,Cr,Cu & Pb»
FILTER & PRESERVE IN-HOUSE
RECEIPT DATE: 3/6/02 0:00 SAMPLE DATE: 3/5/02 13:50 DUE DATE: 3/18/02 0:00
CASE#: Q1877 SDG: QE1877 COMPUCHEM#: QE1877-4
CLIENT ID: MW-9A
ANALYSIS DESCRIPTION: SVOA-8270C
Injection Volume :1pL Dilution Prep (if needed)
Extraction Date___3___/___8/____ 02____
DFTPP Filename_____ DF0203 /■> A ________________
Sample File Name_____ QE1877-4 A i'<A-
ANALYST (S): InjectionQ( 1 Work-up4 / 7
GC/MS DATE REVIEW
CONDITION CODE
Extraneous Peak Search Results:
Number of peaks found: _
Number of Hits found: <P
Number of Surrogate Outliers:
Quality Assurance Notice (s)
Number of Notices Required____
Comments:
-GC/MS ReviewP61
Final Reportable Package! s):
Disposition: \/\ Complete
[ ] Reinjection Required
[ ] Re-extraction Required
[ ] Reinject Neat
[ ] Dilute ( X)
Date__Q / /4^.' Z- Auditor_
At y
Date / /
42 GSVI - 6/27/01: PTF
Analyst initials lxttactcTlKD i#* *,*($?
Mannjjirtiircr and lot nnmbrr or rmgrnls/solvf nts used libxb,.
D
(HIMw U" lS-u^
^\0^
VI-Initials <>?'«' | . \\LWhitt-
O-'i
\\ ilnr'A
• 3. Standards Data
a. Initial Calibration Data (Form VI SV)
b. Continuing Calibration Data (Form VII SV)
42
a. Initial Calibration Data
(Form VI SV)
If more than one instrument is used, forms shall be arranged in order by instrument. Multiple initial calibrations from the same instrument shall be in chronological order. Within each initial calibration, the standards are in order by level, from lowest to highest.
(1) Reconstructed Ion Chromatograms and quantitationreports for the initial (five-point) calibration;Spectra not required
(2) EICPs displaying each manual integration
FORM 6SEMIVOLATILE INITIAL CALIBRATION DATA
Lab Name: COMPUCHEM
Lab Code: LIBRTY Case No.:
Instrument ID: 5972HP60
Column: J&W DB-5.625 ID: 0.32
Contract: 8270C
SAS No.: SDG No.: QE1877
Calibration Date(s): 03/03/02 03/03/02
(mm) Calibration Time(s): 1401 1720
LAB FILE ID: RF10: HI020303A60 RF20: HK020303A60 RF50: HL020303A60RF80: HG020303A60 RF120: HJ020303A60RF160: HH020303A60
I COMPOUND
jPhenol
j Bis(2-chloroethyl)ether
|2 -Chlorophenol
|1,3-Dichlorobenzene
I 1,4 -Dichlorobenzene
| 1,2-Dichlorobenzene
|2-Methvlphenol
| 2,2'-oxybis(1-Chloropropane)
j 4-Methylphenol
|N-Nitroso-di-N-propylamine__
[Hexachloroethane
I Nitrobenzene
jIsophorone
| 2-Nitrophenol
^2 , 4-DimethylphenolBis(2-chloroethoxy)methane__
^,4 -Dichlorophenol
j1, 2 , 4-Trichlorobenzene
) Naphthalene
| 4 - Chloroanil me
j Hexachlorobutadiene
j 4 - Chloro-3-methylphenol
! 2 -Methylnaphthalene
i Hexachlorocyclopentadiene___
2,4,6-Trichlorophenol
; 2 , 4,5-Trichlorophenol
; 2 -Chloronaphthalene
2 -Ni t roan 11 me
. Dunethylphthalate
’2, 6- Dime rotoluene
Acenaphthylene
3 - Nit roam 1 me
Acenaphthene
2,4-Dinit rophenol
■ 4 -Nit rophenol
2 , 4 -Dmicrotoluene
Dibenzofuran
D i e t hylpnt ha 1ace
4 - Ch. 1 o r op he n v 1 - oheny1e t he r
FIuorene
4 - Mi t roanil me
4 , 6 - Dim t ro - 2 - me thy 1 phenol__
Ll-Nicrosodiphenylamine
Bromonher.v I - Dhenvlet her
RF10 | RF2 0 | RF5 0
1.279| 1.253 | 1.2600.916 | 0.869 j 0.8951.024 1.050 j 1.0401 . 380| 1.409| 1.3731.386 | 1.406| 1.4331.348 1.344 j 1.3340.862 0.794 0.7781.266 | 1.279| 1.2151.009 0.990| 0 . 9710.700 0.692 0.7200.617) 0.616 0.6170.468 | 0.470 0.4680.729 0.749 0.7320.222 | 0.235 0.2390.281 0.275| 0.2890.443 | 0.449 j 0.4700.405 0.412| 0.4150.484 0.486 | 0.4911.082 1 . 0 8 3 [ 1.1090.488 0 . 502 0.4950.384 0.392 0.4020.352 0.351 0.3600.826 0.842| 0.8470.277) 0.3 91 | 0.4750.410 0.421) 0.4270.450) 0.478 0.4761 . 167 j 1 . 174 j
1.1400.478) 0.469) 0.4601.632 1.606) 1.5970.340 0.3481 0.3451.9241 1.916) 1.8750.362) o. 3 t i; 0.3491.136 1.138) 1.0910.108) 0.170) 0.2100.260) 0.272) 0.2930.487) 0 . 5 0 5 j 0.5042.060) 2.060) 2.0901 . 8021 i . 778 i 1.7250 . 827: 0.322) 0.8561.543! 1 . 504 J 1.5590.365' 0.372 0.355C . 113 ! 0.137) 0 . 1660.532' 0.501) 0.5270.233: 0.234)
i0.296
FORM VI SV
RF8 0 RF120 RF160|
1.522| 1.408 1.5731.044| 0.967 1.0181.221j
1.084 1.1061.668| 1.521| 1.5971.650 j
1.489 1 . 552
1.567 1.463 1 . 528
1.008 0.916 | 0.939
1.522[ 1.389| 1.478
1.233 1.209 1.3190.913| 0.880| 0.9800.687| 0.627 j
0.6400.536 | 0.499| 0.535
0.868 0.795| 0.815
0.268 0.250 0.2560.339| 0.297 0.302
0.501| 0.468 0.4900.481j
0.448 0.4650.577 j
0.529 0.5511.285| 1.236 1.3380.519 j 0.492| 0.5100.436| 0.410| 0.4140.391j 0.368) 0.360
0 . 956| 0.899) 0.946
0.537) 0 . 522| 0.5570.480) 0.453 0.4510.544 | 0.450| 0.4761.331) 1.278) 1.3530.540 j 0.465 j
0.4871.684 | 1 . 589| 1.667
0 . 362 0.343 0.3462.122) 2 . 007 j
2.1270.396 j 0.355| 0.380
1.2321.216 j
1.2270.260| 0.274 0.2810.336) 0.305) 0.3120.5-44) 0 . 522 0.525
2.340) 2.237 2.298
1.792 1.695 1.7681.046)
1.082 j1.12 9
1.872 1 . 904 2.067
0.402 0.359 0.3760.192) 0.180 0.201
0.577 | 0.521) 0.540
0.320 0.300 0.314
FORM 6SEMIVOLATILE INITIAL CALIBRATION DATA
Lab Name: COMPUCHEM Contract: 8270C^ Lab Code: LIBRTY Case No.: SAS No.: SDG No.: QE1877
Instrument ID: 5972HP60 Calibration Date(s): 03/03/02 03/03/02
Column: J&W DB-5.625 ID: 0.32 (mm) Calibration Time(s): 1401 1720
LAB FILE ID: RF10: HI020303A60 RF20: HK020303A60 RF50: HL020303A60
RF80: HG020303A60 RF120: HJ020303A60RF160: HH020303A60
COMPOUND
1 !
j RFl0 |1
RF2 0 |
|
1
RF5 0 ]
1
RF8 0 |
1
RF120 |
1 .
RF160 j
Hexachlorobenzene- 1----------- 1 -
1 0.339|----------1 -
0.314|---------- 1 -
0.340|----------[
0.367|---------- 1
0.341| 0.345
Pentachlorophenol 1 1 0.060| 0.082 j0.124 0.108| 0.125
Phenanthrene | 1.244 | 1.191 | 1.226 | 1.297| 1.265| 1.303 j
Anthracene | 1.226 1.214 j 1.1801.345 j 1.300| 1.312 j
Carbazole 1.001| 0.982 j 0.988 | 0 . 977 j0.953
0.976 j
Di-n-butvlphthalate | 1.687| 1.6761 1.645 | 1.646 j 1.618| 1.558 |
Fluoranthene 1 1.452| 1.3981 1.416 1.498| 1.454| 1.478 j
Pyrene 1 1 - 539| 1 . 495 j1.407
1.410 j 1.364 j 1.395|
Butylbenzylphthalate | 0.813| 0.804 0.766 | 0.719 j 0.678| 0.665 j
3,3'-Dichlorobenzidine I 0.5881 0 . 578 I 0.556 j 0.601j 0.528 j 0.543 j
bis(2 -ethylhexyl)Phthalate
Benzo(a)anthracene
1.014 |
! 1.413|0 . 966
1.370
0.957 |
1.413
1.087 j
1.492
1.068
1.405
1.118 |
1.496 |
Chrysene | 1.246| 1.206 j 1.206) 1.390 1.295| 1.399 j
Di-n-octylphthalate ! 1.9081 1 . 961| 1.926 | 2.076 | 2.024 j 2.191|
fienjo(b)fluoranthene 1.670 1.735 1.780 1.614 1.778 1.772Benzo(k)fluoranthene 1.493 1.434 | 1.426 1.787| 1.565| 1.653|^enzo(a)pyrene 1 1.311J 1.309 1.360| 1.468 1.394 1.440|
Indeno{1,2,3 -cd)pyrene | 1.400| 1.409 1.455 1 . 585| 1.482 1.507Dibenzo(a,h)anthracene 1.204 1 . 223 | 1.246 | 1.386 j 1.307] 1.327|
Benzo (g,h,i)Dervlene 1.210 1.192] 1.237| 1.3291.232 j 1.248 j
2 -Fluoroonenol 1 1.168] 1.185]1.175 j
1.472| 1.285) 1 . 353|
Phenol -d5 1 1-3411 1.313 1 . 326| 1.6261.481j
1.530!-i i t robenzene - d 5 j 0.533| 0.5551 0 . 544 j
0.6300.566 j
0.6032 -Fluorobiphenvl | 1.487 | 1 . 452 | 1.509 j
1.690 1.552 1.6412,4,6-Tribromophenol 1 0.359] 0 . 356 | 0.369 |' 0.408| 0.385| 0.380|
Terphenvl - dl 4 ! 1.153| 1.152 1 . 104 | 1.112 | 1.065 1 . 074
1 I 1 1 L 1
FORM VI SV
42b
FORM 6SEMIVOLATILE INITIAL CALIBRATION DATA
Lab Name: COMPUCHEM
Ibab Code: LIBRTY Case No.:
Instrument ID: 5972HP60
Column: J&W DB-5.625 ID: 0.32
Contract: 8270C
SAS No.: SDG No.: QE1877
Calibration Date(s): 03/03/02 03/03/02
(mm) Calibration Time(s): 1401 1720
i I |COEFFICENT| %RSD | MAX %RSD |
| COMPOUND |CURVE
1
A1 !
1 |
OR R^2
1
OR R"2
i!Phenol | AVRG | 1.38262123 | 10.164| 30.000|
I Bis(2 -chloroethyl)ether | AVRG | 0.95149948| 7.328 j 50.000 j
I 2-Chlorophenol | AVRG |1.08768244 | 6.603 j 50.000 |
|1,3-Dichlorobenzenej AVRG |1.49149296 | 8.288 j 50.000 |
|1,4 -Dichlorobenzene AVRG |1.48614132 6 . 753 j 30.000 j
| 1,2-Dichlorobenzene ] AVRG j1.430519687.177
50.000 j
|2-Methylphenol | AVRG 0.88279077| 10.044| 50.000
|2,2'-oxybis(1-Chloropropane) | AVRG |1.35824442 | 9.154 j 50.000 j
| 4-Methylphenol | AVRG |1.12191017| 13.324 | 50.000
IN-Nitroso-di-N-propylamine AVRG 0.8142432115.412 j
50.000[Hexachloroethane AVRG 0.63413121 4.365 50.000]
I Nitrobenzene | AVRG |0.49613587 | 6.622 j 50.000|
! Isophorone AVRG 0.78125079| 7.037 | 50.000
!2 - Mitrophenol | AVRG 0.24498509 6.739| 30.000i2,4 - Dimethylphenol j AVRG |0.29725268 7.679 j
50.000ifiis(2 -chloroethoxy)methane | AVRG |0.47036592 | 4.766 j 50.000 j
4-Dichlorophenol AVRG 0.43771326| 7.237 30.000|
,2,4-Trichlorobenzene | AVRG |0.51966680 j 7.464 | 50.000 j
I Naphthalene | AVRG |1.18882358 9.414 j 50.000 j
| 4 -Chloroani1ine AVRG 0.501117602 . 327 j 50.000 j
1Hexachlorobutadiene AVRG 0.406467974 . 529 j 30.000 j
1 4 - Chioro- 3 - methyipheno1 AVRG0.36388041j
4.061 30.000!2-Methylnaphthalene AVRG 0.88611087 6.328 50.000|Hexachlorocyciopentadiene 1 AVRG j0.45977809| 23.344 j 50.000 j
| 2,4,6-Trichlorophenol | AVRG 0.44037909| 5.808 30.000j2 , 4 , 5 -Trichlorophenol AVRG 0.47942043 7.176 50.000|2-Chloronaphthalene j AVRG j1.24048523 7 . 386 | 50.000I 2 - Mi t roam line | AVRG |0.48307089| 6.061j 50.000 j
!Dimethylphthalate AVRG1.62928422 j 2.399 j
50.000i 2 , 6 -Dmitrotoluene 1 AVRG j 0.34731989 2.269 50.000 |
:Acenaphthvlene AVRG !1.99513515 j 5.460| 50.000 j
2 -Mitroanii me ] AVRG |0.36856462! 4 . 6 8 6 j50.000 j
iAcenaphthene | AVRG 1. 17336857 |5 . 054 j 30.000|
| 2 , 4 - Dim t rophenol AVRG 0.21721892 j 31.504 | 50.000 j
j4-Nitrophenol AVRG j 0.29640817 ! 9.319 j50.000
i2,4-Dinitrotoluene 1 AVRG j 0 . 51444 157 j 3.864 j 50.000 j
!Dibenzofuran j AVRG j 2.18080836 j 5.804 | 50.000|Diethvlphthalate AVP.G j 1.76004 093 j 2.347 | 50.0004 -Chlorophenyl-phenylether AVRG
jo.960394 9914.596 50.000
;Fluorene | AVP.G |1.7415124 5 13.556 j 50.000 j
■ 4 - M11 roan 11 me AVRG 0.37151963 4.467 50 . 000i 4,6-Dinitro-2-methylphenol j AVRG 0. 165524 15 j 19 . 534 50.000N-Mitrosodiphenvlamme AVRG j 0.53304301j 4.763 30.000j^- Bromophenyl-phenylether 1 AVRG
1
■ 0.30037256 4 . 743 |
1
50.000 |
42‘JFORM VI SV
FORM 6SEMIVOLATILE INITIAL CALIBRATION DATA
Lab Name: COMPUCHEM
Lab Code: LIBRTY Case
Instrument ID: 5972HP60
Column: J&W DB-5.625 ID:
No . :
0.32
Contract: 8270C
SAS No.: SDG No.:
Calibration Date(s): 03/03/02
(mm) Calibration Time(s): 1401
| COMPOUND
|Hexachlorobenzene____________
|Pentachlorophenol____________
|Phenanthrene__________________
|Anthracene__________
[Carbazole______________________
j Di-n-butylphthalate_________
|Fluoranthene__________________
|Pyrene
iButvlbenzylphthalate________
|3 , 3'-Dichlorobenzidine_____
|bis(2 - ethylhexyl)Phthalate
]Benzo(a)anthracene__________
|Chrysene
IDi-n-octylphthalate_________
i Benzo(b)fluoranthene______
^enzo (k) fluorantheneBenzo (a ) pyrene________________
nndeno (1-, 2 , 3 - cd) pyrene_____
|Dibenzo(a,hi anthracene_____
jBenzo(g,h,i)perylene________
[ 2 - Fluorophenol_______
!Phenol -dB______________
iNitrobenzene-d5______
! 2 - Fluorobipher.yl_____
[2,4,6-Tribromophenol
! Terphenyl -dl4_________
|COEFFICENT| %RSD | MAX %RSD |
|CURVE A11 1 1
o JO JO >to OR R"2 |
| AVRG1------------ 1 -|0.34115353|
----------- 14.917| 50.000|
AVRG 0.09986198 28.545 30.000[ AVRG 1.25457109 3.412 | 50.000
AVRG [1.26288145 5.138 j 50.000 |
| AVRG |0.97958834 | 1.615 | 50.000|
AVRG |1.63844566 2 . 833 | 50.000
AVRG 1.44942655 | 2.576| 30.000|
| AVRG |1.43498205| 4.674| 50.000 j
AVRG |0.74103360| 8.525| 50.000|
| AVRG 0.56586216 j 4.947 j 50.000 j
j AVRG j1.03496188 j 6.389 j 50.000 j
| AVRG j1.43168724 j 3.561j 50.000|
| AVRG 1.29031305 j 6.756 j 50.000|j AVRG |2.01431412 5.290
30.000 j
| AVRG i1.72500289| 3 . 975| 50.000|
AVRG 1.55965944 | 8 . 99750.000 j
j AVRG 1.38053463 4.770 30.000| AVRG |1.47314299 | 4.665[
50.000 j
AVRG 1.28224814 5.425 50.000|
J AVRG 1 . 24140639|
1 |3.817
150.000
AVRG
------------ 1-j 1 . 27288931 |
----------- 19.586 | 50.000
j AVRG 1.43636382 8.981| 50.000|
AVRG |0.57192015 ] 6 . 51550.000 j
| AVRG j1.55517124 I5.970| 50.000|
| AVRG j 0.376345195 . 123 50.000|
| AVRG 1.11023043 3 . 354|
1
50.000|
Average IP.SD test result.
Calculate Average %RSD: 9.784863472
Maximum Average %RSD: 15.00000000
Mote : Passes Average %P.SD Test.
QE1877
03/03/02
1720
Data File: /chem/5972hp60.i/DF020303A60.b/H1020303A60.d
Date J 03-MAR-2002 15:21
ooC\J
Client ID: SSTD010 Instrument: 5972hp60.i
Sample Info: SSTD010:2319
Volume Injected (uL>: 1,0 Operator: 2319
Column phase; J8.W DB-5.625 Column diameter: 0*32
/chom/5,372hpfcO, i 7DF020303A60.b/H1020303A60.d (Part 1 of 2)
7.0-i
6.8-:6.676.4- :6.2-;
6.0:5.8:
5.6- +
5.4- 7
Data File: /chem/5972hp60. i 7DF020303AC0, h/H 1020303A60. d
Date : 03-MAR-2002 15:21
Client ID: SSTD010
Sample Info: S3TD010:2319
Volume Injected (uL>: 1.0
Column phase: J8.W DB-5.625
Instrument; 5972hp60.i nC\J
Operator; 2319
Column diameter; 0*32
Data File: /chem/5972hp60.i/DF020303A60.b/HI020303A60.dReport Date: 04-Mar-2030 08:37
CompuChem
Data file : Lab Smp Id: Ini Date : Operator : Smp Info : Misc Info : Comment : Method Meth Date : Cal Date : Als bottle: Dil Factor: Integrator: Target Vers Processing
Semivolatile Report /chem/5972hp60.i/DF020303A60 SSTD0100 3-MAR- 2 0 0 2 15:21 2319SSTD010:2319
/chem/5972hp60.i/DF020303A60 04-Mar-2030 08:37 mikhael 0 3-MAR- 2 0 0 2 15:21 41.00000 HP RTE ion: 3.50Host: einstein
SW-846 Method 8270C .b/HI0203 03A6 0.d Client Smp ID: SSTD010
Inst ID: 5972np60.i
.b/8270Cv6.m Quant Type: ISTD Cal File: HI0203 03A60.d Calibration Sample, Level
Compound Sublist: all.sub
1
Concentration Formula: Amt DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
DF 1.00000 Dilution FactorVt 1000.00000 Volume of final extract (uL)Vo 1000.00000 Volume of sample extracted (mLVi 1.00000 Volume injected (uL)
:pnd Variable Local Compound Variable
AMOUNTS
1:-;AN. X; c CAL-AMT ON-COL
;-C. ■■-"■a ^ F.T =T r.EI . -:-:s?onse l NG ] ( NG) ST MI LAP. I TV
.. • - . .
5 2 7 4 2 4 0 . 0 0 0 0
.: .. 1 ' j : • : 4 0 . Of DO
i ; : ■ t ■; ; •- . ;;; - ; ' ' \ i; c i_ 40. or:.o
■■ h.TL';:.:- 22504 1 4 0 , •. I ) 0
. . . . ...... . : • • - nice :
• • 2 5 5 0 n 2 ■; 'j o o
117 ■ ■ ■ - '■ 2X15 \ 1 7 • 0 C 0 ? e- ■a:
277X5 17 .ooc o . 01 (a;
V T-X 2 04 C 2 : o. o o o o '= 0- is i
i t;. :. $ j 1 10.0000 2.26 (a.M)
:: : . 1 • • . : : e 15 15 C 1C . oooc 5 2 5 UM)
:: - 5 2 0 54 : o .ooo o 1 C1 . 2 -
■a ::b- •;i :• • : • •••-'?. :• •; x:: • 2 5 22 5 10 . 0000 0 5 0 9020 <a)
■ 4 4 7 1 ? i o .oo t 7 •' 5587 (a;
c■J
' - ^ - v C
Data File: /chem/5972hp60.i/DF020303A60.b/HI020303A60.dReport Date: 04-Mar-2030 08:37
QUANT SIG CAL-AMT ON-COL
■r-po^s MAS S RT EXP RT REL RT RESF3NSE ( NG) ( NG) SIMILARITY
1 5 Ben za Idehyde 77 7.472 7.472 :0.911) 16545 10 . 0000 12.64 83 J2
16 Phenol 94 7.641 7.541 : 0. 9 3 2; 26459 10.0000 8.77 (a)
1 n B is .2 - chloroer.hvl > ether 93 7.760 7 . 76C ;0 946) 18945 10.0000 9.23 (a)
l1: 2 - Ch ioropher.ol 123 7 . 844 7.344 (0.9571 21131 10.0000 9.17 8616(a)
14 6 8.098 9 . C 9 9 ■: 0.9 8 8 ) 28556 10.0000 3 . 9 1 (a)
2 '' 1 , t - D: :.t 1 zrzbenzene 14 5 3.216 5.21$ 1 002; 23663 10.0000 ; ^ 1
1Ber.zy - 3 : c :r.-: ; 1 08 3 .436 3.436 ■ 1 . 029) 13470 10.0000 6.93 ia)
:: 14 6 3.470 3.470 ;; . 033) 27877 . 10.0000 9.10 ( a )
I _• ; -Memvlpher.:: : os 3.639 3 . 639 :1. 054 ) 17828 10.0000 9.29 (a;
IS I . j ■ - oxyr.: a • 1 Ch .oropropar.e ' 46 3 . 666 ■9.556 ■ 1.056) 26199 10.0000 8 . 90 8239 (a)
106 3.676 8 376 ,1.9931 29875 10.0000 8.59 7535 (a.-
-Met ivy :pne:-o; 1 08' 3 .993' S . 393 : 1 . 3 5 I 20867 10.0000 8.50 (a)
2i 4-Metnyipheno; 109* $.893' 3 . S 9 3 (1.035) 20867 10.0000 8.50 (a)
13 - Nj c rose - d; - N - z ropy lam me 70 3 .876 3.376 (1.033) 14476 10.0000 8.09 7125 (a)
II Hexachlcroerhar.e 117 9.045 9.045 (1.103) 12766 10.0000 9.52 9204 (a)
H) Nitrobenzene 77 9.147 9.147 (0.832) 26677 10.0000 9.12 9091 (a)
Q O 9 . 570' 9 . 570 (0.923) 41553 10.0000 9.07 9597 (a)
•••••:•. . 1 3 9 9 . 705 9 . 70S (0.936) 12626 10.0000 8 .91 8857 (a!
2..; -i-^hvPPi-oi 12 2 9 . 7 9 C 9.790 (0.944) 16007 10.0000 9 . 13 3304 (a)
: 4 e.: s - - ■ c.n . ■: : t- mo■ net nane 93 9.942 9.942 (0.959) 25259 10.0000 9.27 8617 (al
162 10 i n c -. n i 2 ? ■ 0.977) 23106 10.0000 9.00 (a)
180 10.263 1C . 2 6 3 ! 0 . 9 9 0 ) 27574 10.0000 9.01 (a)
N'apn: 12 8 10 399 10.39 9 (1.003' 616 64 10.0000 8 . 76 9144 (a)P'
127 10.500 10 500 . 1 . 0 3 i 27809 10.0000 9 . 65 3784(ai
226 10.519 10.619 : 1.624 ) 21835 10.0000 9.33 9380 (a)
Papiolazrao 1 ‘ 11 .042 11 .04 2 (1.065) 4772 10.0000 9.59 8 6 8 3 ia)
~ ' '-'h b. : j ■■ "bylpt/n. : 107 11.36? 11 ■ 6 3 , 1.295; 20087 10.0000 9 . 57 9535 (a)
. I r..n! yr'.-r 142 11.600 ::. 600 (1.119) 47072 10.0000 9.08 (a)
' 4 "1 11.76? 11.759 : 1.: 3 5) 40190 1C.0000 9.60 (a)
2?7 11.867 11 5$7 (0. s a 5) 11S 70 10.0000 6.06 9457(a)
2 - •• • • : 12.:: : 2 . : 7 ! '■. -? 0 2 ' 17594 10.0000 9.16 (a)
■■■: 2 . . r -T:-: : ^ •; 2 , 1 7 5 12. -.7$ (C- . ■■07:- 19 310 10.0000 9.18 (a)
;: : . : ■ -i izn^.y. 12 .-12? :: . 2251 53773 10.0000 9.2: 3023 (a)
■; - :.t l-.r- ■: 2 :: .9$: 1:. 4 5 . 92 8) 5004 1 10.0000 9.05 (a;
:J . 9 33 -. 1 -1 : . 9 4 1; 4 1-001 20.0000 19.07 9160 (a;
. :: ■ ■■■■■■-.■■■..■ ■ 1 2 :• 5 . •..• 6 5 . 6 9935 10.0000 9.53 9503 la)
; . ■ : •; $ 1 ; : - 2 .7 ■-7 - 4: 14 5 0 4 1 0.0000 6 7?: 9610 (a)
; . A • c ■> 13.: O'" ■ ■ ' " ■ : . 6 2 : 3 2 4 9 ’ 10.0000 9 . : 5 953 0 ia)
■ ■ :■■■■■■■■; ■•>■■■■ ■ ■■■■■■ 1 3 6 6 • ■ ; $ :■ .:.$$$> 310 2 5 20.0000 10.09 3 7 5 5 »a )
■- : :. 4 ;• o r. *• 5; 4 3 6 9 10.0000 0 . -1 8 3 6 34 ■ -n)
: L. i ' ' ' • . : 3., ■ . $51 .. ■, 1 n , 2 310 3 50.0000 2 4 . 9 1 .a )
■ ■ : ■. . :rr . :: .1.019) 22255 20.0000 17.16 84 55 ; b)
■ . 5 1 ; • 7 -;; : :•. v 'I 926 i 20394 10.0000 3.39 3 5 7 1 ■ a)
: 3.3 : : . 7■■ ■ 1 . 029 :■ 9 3 3 1 5 10.0000 9.22 9 5 2 •. a )
1 4 9 1 4 . 2 0 b . _ . 0 5 3 1 77251 :o.nooo 1 0.0 ? 965 V
- - 4 . 4 1 ! ::.: 7 3: 35469 :0.0000 3 27 7 7 2 0 (a ;
1 ; 6615 9 10.000c S . 4 4 7752 (a)
43 i
Data File: /chem/5972hp60.i/DF020303A60.b/HI020303A60.dRetort Date: 04-Mar-2030 08:37
O’JANT SIG CAL-AMT ON-COL
CcTpour.ds MAS S FT EXP FT REL F.T RESPONSE i NG) ( NG) SIMILARITY
62 13 = * 4 425 11 07 4: 31319
19741
20.00C0 IS . IS 8439 (a)
8487 (a)62 6 . 6 - D: r. 17 ro - 2 - Techy 1 phenol 199 14.493 14.493 (C.902) 20.0000 13 . 95
N-Ni i roscdip'reny Lamir.e 16 9 - -j . 6 j. * 14 611 1C. 90?) 44603 10.0000 9 . SB &3Hla)
6 5 1,2- Dcpher.yl hydra z me 77 76740 1C.0000 10.24 9073
6 o 4 -Bromopheny 1 -pn.enylecher 243 15 2 71 15.271 : C . 9 5 0 ) 24103 10 . 0 0 0 0 9 . 36 9057 (a)
6 1 Hexachl or obenze.ne 264 15.372 15 .373 !C.957; 2 6 3 7 9 10.0000 9 . 67 9294(a)
6 6 Ac razine 2CG 15.542 15 . 542 '.0.967) 17522 10.0000 29.28 8 3 91
6 9 ? e r. c a c r. 1 c r o p h e i o • 253 15.728 IE.726 •■0.979) 673 1 20.0000 8 . 33 9197 (a)
~ z Phenan:. h.rer.e 179 16.100 16.100 ■ 1.002' 10423? 10.0000 9.71 (a)
7: Ancr.racene 176 16 . 1S 5 16.185 : 1 . 0 C 7 -i 102716 10.0000 9.47 a)
O Sarbazoie 167 16.472 16.472 : 1 . 025; S 3 8 32 10.0000 10.16 8799
7 1 Di- n •cutyipnthaiac e 14 9 17 064 17.064 . 052) 141315 10.0000 10.35 9' 7 9
7-1 Fluoranthene 202 13.198 13.199 11.133) 121651 10.0000 9.84 (a)
75 Benz idine 134 13 4 35 16.435 •' 0.3 9 1) 30206 20.0000 35.69 3605
7 6 Pvrer.e 2 02 1 3 6 04 18.604 (0.399) 124236 10 . 0000 10.6 3
77 Butyi benzylph.tha lace 14 Q 19 703 19.703 :0.953) 65605 10.0000 11 . 10 94 C 3
7 6 3,3' -DiC^Io:-orii:i:^i;^ 252 20.617 20.617 (0.997) 47517 10.0000 10.19 7 15 9 (a!
76 bis : 2 - ethyl he >:y ! 1 Phcr.j late 14 9 2 C 6 5 1 2 0.5 5 1 (0.998} 81841 10.0000 9.45 9 76 7 \a I
? ' Benzo ■ ar.chrncme 2 2 z u 0 6 6 3 20.666 {r- .999) 114093 10.0000 S 63 (a)
e. :3h: ys^ne 223 2 0 7 1 cj 2C . 719 1:.G02j 100603 10.0000 9.26 ; U ;
to - n - o"C y : pot t ■< .ate 14 9 11 . 14 9 21 .649 '0.929i 136015 10.0000 5 2? : 11
___Berizo ■ :.o f 1 tor a of r.ene 252 22 .4 76 22.415 t 0 . 9 5 4 ' 119026 10 . 0000 5 91 (a;
m Benco -. ' .■ : l oOFDor .-—ne 252 2 2 6 7 c 2 2 5 2 9 ; 0.95 7) 106362 10.0000 9 08 1 a)Wr Ber.z-c -a pyre:-.-:- 252 2 ? . 1 71 23.172 (0.994) 93455 10.0000 9.32 ia;
Inoeno ■ 1 . 2 . 1 - :d r-y: one 2 7 6 26-. 26 9 25 . 25 5 ■■ 1 . 127' 99794 10.0000 9.35 0 (aM)
f. 7 2 ; h-!'.: a , r. -.l:/. a "T-nO 2 7 3 2 4 ,31c. 2 •: 2 1 f ■ 1 . 129, 3 5 8 3 0 10.0000 9.22 8975 !a)
3- ^ n ■ * P- :V - -r.e 276 2 7. • Ai 2 " . 1 6 1 '1.166) 86228 10.0000 9.59 7750 1 a)
QC Flag Legend
a - Target compound detected but, quantitated amount Below Limit Of Quantitation(BLOQ).
M - Compound response manually integrated.
Data File: /chem/5972hp60 . 1 •,'DF020303m6i
Injection Date: 03-MhR-2002 15:21Instrument: 5972hp60.iClient Sample ID: S5TD010
ound:Mumper
Fluorcblphemy1 321 -ni.'- c:
P/H 1020303H6C . d
Ion 172.00: Hrea: 63770 Height: j6272
3.6- rrit7 4- oi
3.0-
2.8-
2.6-
2.4 -
4-
'J . P •
I
11 .80 11.65 1 1.90 11.95 12.00 12.05 12.10 12.15 12.20 12.25 12.30 12.35 12.40 12.45 12.50 12.55 12.60 12.65 12.70 12.7jM i n________________________________________________ _______ __________i
Ion 171.00: Hrea: 0 Height:
I
I
!
12.45 12.50 12.55 12.60 12.bp 12.70 12
ion i.-.
433
:i. :5 12.20 12.25 12.70 12.35 12.40 12.45 12.50 12.55 12.60 12.65 12.70 12.7■
Data Fiie: .•cnem/5?^2ho60.1/DF020' Injection Date: 03-MAR-2002 15:21
mst rument: 5972ho60.1
nt Sample ID: SSTDulu
Ouno: 2.4.6-Trloromopnenol
Number:
*60. b/H1020303A60.a
'?. 0-
3.5-
d.;.'- 7 . 5-
?. 0-
6.5-
6.0-
~ 5.5-;^ 5.0-
329.60: Area 5390 Heigrr 9915
o. o- 5.0-
I
1.5-
1. 0-
1 J - 35 M . 40 14.45 U.50 14.55 14.60 14.65 1*4! 70 14.75 14.30 14.85 14:90 14^95 15!oO 15^05 151 10 15.15 15.20 15.25 15.30 j_____ Min_________________________________________________________!
Ion 332.00: Area: 0 Heignt: 0 j
l i
7.5-
i
ii
'XI
14.95 15.00 15.05 15.10 15.15 15.20 15.25 1 5.;4.5'*: 14.55 1-1.50 14.65 14.'
43
/5 14.3'Ml
14 5 14.90 14.35 15.00 15.05 15.10 15.15 15.20 15.25 15.30
Data File: /chem/5972hp60.1 /DF020 Injection Date: 03-MAR-2002 15:21 Instrument: 5972hp6u.1
ent Samole ID: 55TD010
■uuno: Indenoi 1,2.3-ca .‘pyrene :■ r-hjmper; 193-39-5
703A60.b/HI020303A60.d
1 .6- I .5-
1. J-
. . J •
1.2-
1.1-
1.0-
0.9-
0.8-.
1 j .4 ■
0. 1 ••
25.50 25.53 '5.95 25 .
2.8-
Ion 276.00: Area: 99794 Height; 19584 <z-
•SJ
>0 26.05 26 ! 10 26.15 26.20 26.25 26.30 26.35 26! 40 26^45 26^50 26.55 26.60 26.65 26.70 26^75
___________________________ run_________________________________________________________________Ion 139.00: Area: 0 Height: 0
I
[Ii
i
0.4
'i.1 _’b . u5 Jo . 1 0 Jo . 15 26.20 jo . jo Jo . 30 jo . 75 26.4u 26.45 26.50 26.55 26.60 26.65 26.70 26.75 i-1 i r,
I-:n 2?7_iVi; Ar-?=i: <: nei-gnt: 0
435
i 11 n
26.40 26.45 26.50 26.55 26.60 26.65 2b. 70 26.75 |
(:<10~5>
Data File: 2chem/5972hp60, i2BF020303A60.b/HK020303060.d
Date : 03-MAR-2002 16:41
Client ID: SSTD020Instrument: 5972hp60*i ■L.O
Sample Info: SSTD020;23lS OOVolume Injected <uL>: 1.0
Operator; 2319Column phase: J&W DB-5,625
Column diameter: 0*32
8.28.07.8
7.6
7.4
7.2
7.0
6.86.66.4
6.26.05.8
5.6
5.4
5.2
5.0
4.8
4.6
4.4
4.2
4.0
3.8
3.6
3.4
3.2
3.0
2.8 2.6*
2.4-
2.0-
1.8
1.61.4
1.2- 1.0-
0.8- o.6-
0.4
7chsrn/5972hp60. i 2DF020303A60 .b7HK020303fl60. d (Part 1 of
•C4-
II J ■j M / __ jj1,
1.1'
L__J A},.14
Data File; /chem/S^hpSO. i/DF020303A60.b/HK020303A60.d
Date ; 03-MAR-2002 16;41
Client ID: SSTD020
Sample Info: SSTD02OJ231'?
Volume Injected <uL>: 1.0
Column phase: J8.W DB-5.625
Instrument: 5972hp60.i
Operator: 2319
Column diameter: 0.32
CO
.2-
.0-
.8-i
.6-
.4-i
.2-:
.0-
.8-:
.6-i,4-i
,0-
.8-
.6-
.4
.2
. 0-
,8
.6
.4
.2
.0
.8
.6
.4
.2 ,0
.8
.6
.4
.2
.0
.8
.6
.4
*0
*8 .6
* 4
/ch®m/5972hpio0 * i /DF020303A60 ♦ b/HK020303A60 ♦ d• +
CPirt 2 of 2)
7)ca>X
..__I1:3
I i_ _| .
19
Ul. I l
2117
Data File: /chem/5972hp60.1/DF020303A60.b/HK020303A60.dReport Date: 04-Mar-2030 08:38
CompuChem
Data file Lab Smp Id Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date Als bottle Dil Factor Integrator Target Ve
Semivolatile Report /chem/5 972hp6 0.i/DF02 03 0 3A6 0 SSTD0200 3-MAR- 2 0 0 2 16:41 2319SSTD020:2319
/chem/5 9 72hp6 0 04-Mar-2030 08 03-MAR-2002 16 61 . 00000 HP RTE
sion: 3.50
i/DF020303A60 38 mikhael 41
Processing Host: einstein
SW-846 Method 8270C .b/HK02 03 03A6 0.d Client Smp ID: SSTD020
Inst ID: 5972hp60.i
,b/8270Cv6.m Quant Type: ISTD Cal File*': HK020303A60 . d
Calibration Sample, Level:
Compound Sublist: all.sub
2
Concentration Formula Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
DF ■ 1 . 00000 Dilution FactorVt 1000.00000 Volume of final extract (uL)Vo ' 1000.00000 Volume of sample extracted (mLVi 1.00000 Volume injected (uL)
Variable Local Compound Variable
AMOUNTS
C'J.a:.-; s:g CAL-AMT ON-COL
po—.cs :-'A£3 RT rX? RT F:r:. RT RESPONSE MG' ( MG) SIMILARITY
1 : , •; - 2 ■. cb.; r. •• :>• - 18 2 • ■. 31232 40.000
: ::ophic,i : e:-.- :r ; J 1 4 : 1 1 . E 4 E- - . j 0 0 i 2 -1 3 2 & 6 4 0 0 0 0 -j
: /• -. .: •..... 16 4 : E ■ 4 7 : e m.7-; 133404 4 0. c c 3
■: :- = : -j : ■ ■ : . •; ■;7 : . :» 372421 40 . 0002
■■■ - ■: t-- iSii-li 4 0.0 c
. CP : ■: 4 IE E ' - :c. 303687 4. 0 0 j 0
” c - F:-.; : 1:: ■■ ' -c 7 4 1 5 4 C 6 ? 20 . 0:.,jO 16.34
- nit-,,.-.;: ■■ . viOi 5 9 3 5 3 2 0 . on0-0 ; 8 . 01
E2 ' :■ 674 83 C'G 10.22
u : ~ 2 : (:. 344 • " ~~ q • g • 2 0 ; 00 0 18.56 (M)
: : 1: . 4 . - 7 c E '• .4 ee 2 . -32 . iobj 1 0 /, c- F; 20.0 000 10 Q Q 'M)
: : 7-^: V 18 i 5 ; :1 650 ,c . 01::■ 203794 20.0000 20 . 74
: • :. y.1 E . •• 4 " E..:.:- ' . 4 2 0 ■ 8 5 3 4 9 2. 0000 10.96 V 4 0
j; no 7• : 5 /■: :iqt. 64147 20.0000 17 47 0735
43LL * 0- L
Data File: /chem/5972hp60.i/DF020303A60.b/HK020303A60.dReport Date: 04-Mar-2030 08:38
AMOUNTS
QUANT SIG CAL-AMT ON-COL
1 v Z-Me: nylrnenol24 Z,2' -oxyois ! . - Zh _o: opi'opar
25 Acetophenone26 3-Methyiphenoi
2 7 4 - Me:hy1 phenol
2 5 N • N: t no so - di - N - prccy iarir.e
MASS RT EX? RT REL RT RESPONSE ( NG) ( NG) SIMILARITY
? 7 7 473 7 473 : 0 . 9 11} 33619 20.0000 23.12 9147
94 7.642 7.642 (G.932! 57164 20.0000 17.81
93 7.761 7.761 IC.946 > 3S65e 20.0000 IS . 06
12 5 7.345 7.845 \ 0.9 SV 4 790S 20.000C 19.15 904 5
14 6 . 099 8 . 059 (0.988) 64261 20.oooe 13 .60
14 5 5.217 .5.217 (1.002) 54 163 20.0000 IS . 79
ice 43^ 3 . 4 37 (1 . 029! 28989 20.0000 17.93
14 6 £ 4^1 5.471 f1 . 033; 51297 20.0000 18.54
10b 8.640 8.440 f 1.054/ 36207 20.0000 17.57
4 5 £ . 5 5 7 - . 6 5 7 (1.056) 58326 20.0000 18 .44 8277
105 3.360 6 . £40 (1.080) 63079 20.0000 17.10 8101
ICS ' 8.894- S . S 5 4 (1.085) 45167 20.0000 17 . 19
103' 3 . 894 3 . 854 (1.085) 45167 20.0000 17.19
70 S . 877 8 . 877. (1.083) 31569 ■ 20.0000 16.61 7313
1 17 9 . 03 0 9.030 [1.101) 28082 20.0000 19.31 3 5 81
7 7 9 . 14 £ 9.148 (0.834) 57184 20.0000 18.74 c, 2 4 9
3 Z 9 . 554 ■' 9.554 i C . 923) 91094 20.0000 18 . 93 9135
: ? !■ c. 7 £ - 5.70 6 10.933 28631 20.0000 19.12 9 C 0 7
12 2 9.721 '1 751 '0.546) 334 99 20.0000 16.42 c 4 9 6
93 9 . 94 3 - J T V 0 . 9 6 1 J 5466? 20.0000 15.10 87 81
162 10.12? -..0,113 (0 . 979) 50059 20.0000 18.61
’ o f, '•0 2 64 10.264 (0.992) 55156 20.0000 18 . 51
123 10.400 10.400 (1.005) 131778 20.0000 17.98 937 3
127 10.484 1 0 . 4 2 4 ( 1 . 01 3 i 61137 20.0000 20.01 6 5 3 0
225 i;.-o; 1 -I . o 3 ; 1 . 025) 47740 20.0000 19.27 •b 7 9 3
1 12 1 1 . 06 2 1 1 . j 4 0 (1.069) 10087 20.0000 19.06 5 Oil
1C7 11 34 7 11 34 7 (1.056) 42712 20.0000 19.25
14 2 :: id ,1.121) 102471 20.0000 18 . 85
14 7 LI 7 7 2 ii 7-: '1.127) 84515 20.0000 19.23
i: t : 1 1 : " 2 :c 35J1 35875 2C . 0000 17.13 3 3 7 3
i:- 2 . 1 0 2 12.1 • 5 3 3 616 20.0000 19.01
1 9 -j 12.174 12 1 ' . . 17 ) 4 3358 20.0000 19.93
154 12 ; _• . J . *7 . 1 • 5 2 4 . 1 2 6 : 0 20.0000 18 .73 82 34
:5: 12.44" • •' • *7 ■3.527 107645 20.00CC 13.63
"3 3 . : i 3 6 0 4 5 40.0C00 3 8 4 8 9155
12 9 54 !- 5 54 .i.5-11 : 147244 20.0000 19.63 9 6 6 6
16 ■ : 0 7 1 • . 4 7 4 • 31 ->65 20.0000 20.05 96 6 C
1 4 . 1 . 5 £ 1 ■ 1 7 5 5 7 1 20.0000 13.98 8776
• ‘ . 5 V = 67988 40.0000 3 5.30 92 8 9
1 7. 4 4 •• : 335, 104 386 20 . G0C0 19.13 8 64 2
1 34 ■:.235^ 77532 10 0 0 C 0 77 . ?0
1 .I 9 1 • - 1 1.21 5; 4 9 5 6 £ 40.0000 3 6.65 £274
1 ■’ - 1 ): 2 r. ■ 4 4 3 0 0 2 0.000 0 19.55 3 7 7 9
: i -' . 1.22 • 183863 20.0000 * Q IT 54 92
; . : - . ; ‘ •: 1 . .5 5, 163037 20.0000 n : pi 964 1
7:4 : •;. :: 14. j :• 2 . : .'.'72; 7540G 20.0000 1 6 . 7 6 74 31
; ? 137881 20.0000 16 .91 7-42
43o
Data File: /'chem/5972hp6 0 . i/DF02 03 03A6 0 . b/HK0203 03A6 0 . dReport Date: 04-Mar-2030 08:38
6 2 4 - Uiz roan: 1 me
6 3 4.6- Cir.it: ro - 2 - mecnyiphenol
6 4 N’ - N i c rcsod: phe.ny lam: re
6 5 1.2- Cipheny 1 hydrazine
66 4 - Ercmcpner.yi -pnenylezhe:'
5 7 Hexazhicrcbenzene
69 Penzachiorophenoi
70 Phenant: hrene
7: Anthracene
72 Carbazole
7 3 Z i - n - cu t y i r: r. z ha 1 a z e
74 Flucrar.zhene
75 Benzidine
~7 Buzy 1 benzy 1 pr.zhaia z e
AMOUNTS
;ant sig cal-amt on-col
MASS F.T zXP RT REL RT RESPONSE { NG) f NG) SIMILARITY
138 14.426 14 .426 [1 . 074 ' 68288 40.0000 39.74 8431
198 14.494 14.494 (0.902) 51067 40 . 0000 33 . 14 8514
2 6 9 14.612 14 612 iG.909) 93305 2 C.0000 IS . 76 Q652
77 • 14 . 680 14.63e i 1.093) 167008 20.0000 20.71 944 1
243 15.272 15.272 t 0.9 = 0 ) 52913 20.9000 16.87 3754
294 15.374 15 374 (0.957 : 58578 2 0.0 0 0 0 18.43 9390
200 “ 15.543 15.54 5 (0.95'; 23259 20.0000 36.55 8577
2 66 1 5 729 15 729 ( 0 . 5 7 91 22176 4 0.0 0 0 C 2 6.03 66 32
I7E 16.101 16.101 fl.002, 221352 20.0000 16 . 91
173 1 6 . 1 o 6 1 6 . 18 6 ;i.007) 226073 20.00C0 16.98
167 16 .473 16.473 !1.025) 182857 20.0000 20 . 08 8901
149 l7.059 17.065 11.062) 312093 20.0000 20.48 9073
2 02 ie.:m 13.199 (1.133)■ 260326 20.0000 19.20
184 15.435 18.436 (0.991) 124999 40.0000 52 .65 S 516
2 02 i 8 6 0 5 16.505 1 0 . 899) 264401 20 . 0000 20.76
249 19 705 19.705 ;o.953; 142273 20.0000 21.86 9538
252 20.613 20.618 (0.997} 102181 20.0000 20.35 7153
149 20 652 20.652 (0.998) 170867 20.0000 18.40 9502
? O D 2 0.66 9 2 0 . 6 6 9 (0.999) 242315 20.0000 19 . 09
2 2 Q 2 C 7 2 0 20.7 2 C (1.C 02) 213297 20.0000 16.45
14 9 21 6 50 1: .650 (0.929) 297829 20.0000 19.31
252 22 4 79 22.473 (0.964 ) 263488 - 20.0000 ■ 20.25
252 22.530 2:.520 (0.967) 217746 20.0000 18.08
OC*l 23.173 23.173 '0.994) 198825 20.0000 13.91
2m; 26.252 26.252 11.126) 213949 20.0000 19.08 0 i’
2 7 8 2i. 3i-; 2 u . 3 1 5 ’1.129) 185740 20.0000 18 . 97 9006
276 2 7 15 2 2 7 ; 0 2 ' 1. 166) 181081 20.0000 19.20 7782
QC Flag Legend
M - Compound response manually integrated.
44 G
U - - L
Data "lie: cner.i /5972np50 .In.;,ec t ion Date : 03-MhF:-200! IP5trument: 5g72no60.i
?nr 5ampl
pound: 2- Number:
a ID: 3STD020
F laorompnenyl 321-60-3
DF020 jOGhdu . o''HK020303^60 . a
10:41
Ion 172.00: Ores: i_*oll6 heignt: 89762
3.0-
2.5-
I 1.30 11.35 11.90 11.95 12.00 12.05 12.10 12.15 12.20 12.25 12.30 12.35 12.40 12.45 12.50 12.55 12.60 12.65 12.70 12,
M l n ____________________Ion 171.00: Area : Height: 0
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441
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?mo i e
em/5'?72hG6l : 03-MhF:-2’ 72np60.i ID: 35TD021
DF020303A60.
16:^1
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. 90 25 . ':'5 26 . oo 26.05 26.10 26.15 26.20 26.25 26.30 26.35 26. *40 26.45 26.50 26.55 26.60 26.65 26.70 26.75
___________ M in_________ __________________________________________________________________Ion 133.00: Area Height: 0
55 26.40 26.4D 26.50 26.55 26.60 26.65 26.70 26.75
nt ;
44 •0 I J .
Id . 26.40 26.45 26.50 26.55 26.60 26.65 26 . ■ 0 26.7f,
<:<10~&>
Data File: 7chem/5972hp60. i/DF020303A60.b/HL0203C7AC.O.d
Date : 03-MAR-2002 17:20
Client ID: SSTD050 Instrument: 5972hp60.i
Sample Info: SSTD050:2319
Volume Injected CuLi; 1.0 Operator: 2319
Column phase: J&U DB-5.625 Column diameter: 0.32
/chem/5972hp60.i/DF020303A60.b/HL020303A60,d <Part 1 of O
1.5-
1.4-
1.3-
1.2-
1.1-
1.0-
^r
>T1
c>1>
0-I
Data File: 2chem/5572hp60. ir'BF020303ACO.b/HL020303A60.d
Date : 03-MAR-2002 17:20
Client ID; SSTD0G0
Sample Info: SSTD050:2319
Volume Injected <uL>: 1,0
Column phase; J8.W DB-5.625
/Chem/5972hp60.i/DF020303AC0.
_oInstrument: 5972hp60.i*=3"
Operator: 2319
Column diameter': 0,32
b/HL020303A60.d (Part 2 of 2)
1.5-
1.4-
1.3-
1.2-
1.1-
1.0-
0.9-
\s 0.8- orH
0.7-
0 . -
0.5-
0.4 -
m-P
i3?c<!■■C
+CMH75
I0/CHiIfl7)
18 1* 20
_JL^.j
0JH75
I<li
'll
<1*LL
17
Data File: /chem/5972hp60.i/DF020303A60.b/HL020303A60.dReport Date: 04-Mar-2030 08:38
Data file Lab Smp Id Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date Ais bottle Dil Factor Integrator
CompuChem
Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020303A60.b/HL020303A60.d SSTD050 Client Smp ID: SSTD0500 3-MAR- 2 0 0 2 17:202319 Inst ID: 5972hp60.i
SSTD050:2319
/chem/5972hp60.i/DF020303A60.b/8270Cv6.m 04-Mar-2030 08:38 mikhael Quant Type: ISTD0 3-MAR- 2 0 0 2 17:20 Cal File: HL020303A60.d7 Calibration Sample, Level:1 . 00000
HP RTE Compound Sublist: all.subTarget Version.- 3.50 Processing Host: einstein
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
DFVt
VoVi
1.00000'
1000.00000
1000 .00000
I . 00000
Dilution Factor Volume of final extract (uL) Volume of sample extracted (mL) Volume injected (uL)
Cpnd Variable Local Compound Variable
AMOUNTS
CAL-AMT ON-COL
NO,' NG,' S IMI 1AJ\ I > Y
■j :: :o 4C . 3 0 G 0
■; j . o o o
4- 0000
^ .0000
4 . .0000
; ■■. oooo
uG.0000
00.0000
s . 0 o o
5 0 . 0 0 C 0
00.0000
5 0 .of) 0 o
44b
Data File: iprt Date
/chem/5972hp60 . i./DF020303A60 . b/HL020303A60 .d: 04-Mar-2030 08:38
AMOUNTS
•jUANT S l o CAL-AMT ON-COL
^pounds MASS RT rv: :t Rc.L RT RESPONSe. 1 NG) ( NG) SIMILARITY
IE B'rr.zaloer.yde ii 7.460 7.460 '.0.911; 70853 50.0000 50.35 5 7 7 2
Phe-cl 54 7 . 646 7.546 ;0. 934 ■ 138897 50.0000 45.58
93 7.764 7 764 :0.94 8 : 98658 50.0000 47.05
2-Cr.:z,rc?r*".c: 12S 7.945 7.349 (C.959) 114660 50.0000 4 7.83 916
1 '■ 1.5 -Bichi: 14 5 8 . 103 8.103 .'0.9 9 Ci) 151325 50 . 0000 46 . 03
2‘ 1 , 4 - j Lchl : .-Db-.tzer.e 14 t 3.222 3.221 '1.004) 157907 50.0000 48.21
2: B^r.zy: aL"or,D'. 10? 6.441 3.441 11.051) 71419 50.0000 46.38
. I : . 2-2:-:-:o:-ors- = ?r;e 145 S . 475 a .'475 ; 1.035.) 147025 50.0000 4 6.63
2 3 2 - ‘\?zr.y : pr.e ad ' 1 0 9 S 627 8 . 627 '1.054' 85756 50.0000 44 . U8
24 2,2'-oxyci- 1•Ch1Dropropanei 45 & 6 6 1 3.661 : 1 .053' 133943 50.0000 44 . 74 8285
2: Aoecoonencne 1 0 5 c . 3 54 6.664 (1.093; 156762 50.0000 44 . 89 6141
2 5 ; - Me: ny:c:'.er,o : 10? ' D c- q q » . 3 9 9 11.087) 107022 50.0000 43.28
27 4 -Mecir/lphenoJ ICS' 8.653 3.898 (1.037) 107022 50.0000 43.28
2 : N- N: z roso - d: - X -orDp/: an: p.e 70 3.381 8.331 (1.035) 79303 50.0000 44 . 19 7343
1 1 7 5.733 5.03 3 :i. 10 3 ) 67965 50.0000 48.64 8877
: X:: 77 9 . 152 9 . 152 (0.884) 132650 50.0000 47.17 9268
: : :v:pAf: o::- 52 9.555, 5.553 (0 . 923) 207385 50.0000 46.82 9154
y : .• 5.692 (0.93 6) 57780 50.0000 48 .31 8564
12 2 9.795 5.795 :0.946? 31855 50.9000 48.58 8639
a 2a : • ••••.--. •• 9.947 9 . 94 7 (0.961) 133196 50.0000 49.96 9912
^ • :a.a : . : r 2 10 115 1 j . 11 6 ;0.977; 117516 50 . 0000 47.36
1 7 10.251 10.251 (0.930) 139256 50.0000 47.27
• t a 10.337 • x a 7 11.003) 314335 5 0 . 0 0 0 0 46.65 8742
1 2 7 10.433 10.438 (1.013) 140280 50.0000 49.39 8947
: ■ r. A >: n ~ A. : ■' ^ ■;r,.rj 2JL 1 'J 6 0 7 1 . 5 0 7 ; 1. 024 :■ 113878 50.0000 49.43 9159
a ::: D J -i ' 1 A 4 Q 24 022 5 C.0000 48.92 8736
a ' aa . 1 11.35: a . :• r.: ■ 1 . 0S6) 10190? 5 C . 0 0 0 0 4 9.40 8950
2 -X-: :v.';a:,ad r : 4 2 i 1 . 6 01 a:s ;:. 12 i: 240085 50.0000 47 . 80
■W ■ r.i:: .=!■ ■. ••: 1 : .774 77.. :; . 12 7 ■■ 192978 50.000C 47.83
P.-v.-, ■, - 7 • - '47 c 1: .575 ■2.584) 100430 50.0000 51.68 9364
2 •; . • -7r : ::••••:•. . 12 . 0 9 12 . 15 5 ■; . 10 0 1 9024 6 50.0000 48 .48
; i • 2': a-.-a' 12.1.6 ; 12. 182 ::.907; 100708 5 3.00C0 49.70
■ 1 . 1 ■ 12 417 12 4 17 ■ a-; 264 133 5 0.0000 4 6.47 9185
- - 2;. : DA-:; 12.; 51 12.421 ■- ■■ 241031 50.0000 45 . 97
4 •• : : . •••• 12.627 ■ a a aasa 100.000 95 27 906 ’.
1 2 : 2 . • •• 337590 50 . 0000 4 9.02 9 82 1
•: 1 :;. .-a.: 2 • 7 2 9 0 6 50.0000 49 . 66 9 0 ; 0
: 1 . 1 396345 50 . 0000 4 7 . 0 0 9 ? 9!
V.: . ■ 13 3 0 4 ; ? 2 5 4 : 775 : 147395 100 coc 94 . 62 9-79
■- AD;...A 5 4 15 4 f \ a . r . 1 '.24; 2 3. 0 5 ? 2 5 C . 0 0 0 0 9a .49 a-23
:-■ ; 1 3 . 5 3 " . : . 2 1 . 7 0 7 ; 22215? 250 000 2 .0
-., ■ - ? -■ 1 :■; 12 2 9-) 1 100 000 7 8.93 ;-717
■- ■■■■ s ; . 7 7 . .._ . J 5 106450 50.9000 4 8.96 •(916
- : • » : . • ' •; 1 0 2 8 ; 441621 50 . 0GCC 4 7 . C- i 7 3 4 9
1 4 .21' 1 . 0 = ? 314 6 14 50.0000 4 9.01 9645
;.: v: •• 1.072. 150877 50.0000 4 4 . D 6 7354
.4/ 1 ^ 2 , 3 2 9 5 5 e 5 3.000 0 4 4 . 7 7 1 9 6
44 i
Data File: /chem/5972hp60.i/DF020303A60.b/HL020303A60.dReport Date: 04-Mar-2030 08:38
Compounds
62 4 - N i troam i ins
63 4 , 6-Di.nit.ro-2 - methyl phenol
64 N-Nitrosodiphenylamine
55 1.2-Diphenylhydrasine
66 4 - BrcT.opr.eny 1 - phenylether
6" Hexacr.lo;'wbenzene
6 S At ra z me
65 Pentacn1drophenol
7 0 Phenar.t hrene
7 1 Anthracene
22 Carbazole
2 3 Di - .n - buty 1 pht ha I at e
n4 Fluoranthene
25 Benzldine
26 Pyrene
22 Buty1 benzylphtha late
2£ 3,3' -Dichiorobenzidine
2 5 b i s »’ 2 - e t h y 1 h r y i i F h t ha 1 a t e
QC Flag Legend
M - Compound response
amounts
u<-u-.T Sic CAL-AMT ON-COL
MASS RT EX? RT REL RT RESPONSE ( NG) ( NG) SIMILARITY
1 3 S 14 .447 14 .447 (1.076) 150242 100.000 95 . 66 . 8759
1?8 14.498 14.498 (0.903) 134057 100.000 100.0 9663
16? 14.616 14.616 (C.910) 213376 50.0000 49.43 7982
77 14-684 14.684 H.093 ) 365818 50.0000 49.35 9357
248 15.255 15.259 (0.950) 119926 50.0000 49 . 30 94 32
2 84 15 . 372 15.327 -'0 . 958 J 137774 50.0000 49.86 9617
20C 15.547 15.547 t'C.568) 16882 50.0000 32.62 9096
266 15.733 15.733 (0.980) 56378 100.000 91 . 15 8422
173 16 . 105 16 . 105 (1.0C3! 496674 50.GC00 48 . 83
179 16.189 16.199 (1.008) 477906 50.0CC0 46.72
167 16.477 16 .427 (1.026! 400210 50.0000 SO .44 9093
14 5 12.069 12.069 (1.063) 666310 50.0000 50.21 93 03
202 15.203 16.203 (1.134) 573470 50.0000 48.85
184 15 . 423 18.423 (0.890) 193938 100.000 89.28 3945
202 18.609 18.609 (0.899) 580941 50.0000 49.02
14? 19 . 208 19.208 (0.953) 316447 50.0000 51.71 9562
2 52 20.622 20.622 (0.997) 229753 50.0000 49.16 6 913
:■;? 20.656 2 0.6 5 6 (0.993) 395276 50.0000 46.25 504 3
225 20.673 20.673 ( 0 . 599) 593605 50.0000 49.36
223 20.723 20.723 (1.002) 497786 50.0000 46.71
14 5 21.654 21.554 (0.930) 679141 50.0000 47.80
T C *1 22.463 23.333 (0.565) 627S96 50.0000 51.61
2 52 22 . 5 34 22.534 '.C . 967) 502900 50.0000 45.72
252 23.127 2 3. 177 (0.995) 479685 50.0000 49.26
2 76 25.272 26 .272 il.123) 513015 50.0000 4 9.37 C iM) \
2 7 5 ~i s i 2 ' nr ' o ■j (1.130) 439434 50.0000 48 . 59 393 1
276 27.186 2 7 136 (1.167) 436122 50.0000 49.61 7709
manually integrated.
> - p - u L
Data ^lie: • chern/5'?72hp60. i/DFO: Infection Date*: 6;.-MhR-2002 i"7:! Instrumenr ; 5972hp60.i Client Sample ID: 3STD050
■ouncJ: 1 na~
Mumoei': 1:':<■ 1.2. 3-cd : pqr~ -3?-5
ipr 0 . p/h! 3h60.a
Ion 276.00: wrea: 51301
Oj r 4c-i
Height: 93704
6
i
2.5-
I .5-
1 .0-
26.1 26.2 26.3 26.4 26.5 26.6 26.7
__________________M m___________________________________________________ _Ion 139.00: Prea: 0 height: 0
Cy
i n
26.4 26.6 26.7
n r : 0
44o
26.5
Data File: /chem/5972: ;p60. i/DF020303A60.ti/HG020303A60.d
Date : 03-MAR-2002 14:01
Client ID: SSTD080
Sample Info: SSTD080:2319
Volume Injected CuD: 1.0
Column phase: J&W DE-5,625
/'chcm/'5972hpfe0. i 7DF020303AC.0.b/HG020303Af.0.d (Part 1 of 2)
2.3-;
2.2:
2.1:
2.0-
1.9:
1.8-
1.7-
1.6-
Inst rument: 5972hp60.i
Operator: 2319
Column diameter: 0.32
'...3
LO
Data File: 7chem/5972hp60. i/TiF020303A60.b/'HGC120303A6u.d
Date : 03'HAR-2002 14; 01
Client ID: SSTD080
Sample Info: SSTD080:2319
Volume Injected (uL): 1.0
Column phase: J&W DB-5.625
Instrument: 5972hp60.i
Operator: 2319
Column diameter: 0.32
7chem/5972hp60.i7DF020303A60.b/HC020303A60.d (Part 2 of 2>
ejtHTJI4*c
18 18
; ft. ,,i L. i i
1'4
451
Data File: /chem/5972hp60.i/DF020303A60.b/HGO20303A60.dReport Dace: 04-Mar-2030 08:37
CompuChem
Data file : Lab Smp Id: Inj Date : Operator : Smp Info : Misc Info : Comment : Method : Meth Date : Cal Date : Als bottle: Dil Factor: Integrator: Target Vers Processing
Semivolatile Report /chem/5972hp60.i/DF020303A60 SSTD08003-MAR- 2 0 0 2 14:01 2319SSTD080:2319
/chem/5 972hp6 0.i/DF020303A60 04-Mar-2030 OSM"7 mikhael 0 3 -MAR-2002 14:01OZ,
1.00000 HP RTE ion: 3.50Host: einstein
SW-846 Method 8270C .b/HG020303A60.d Client Smp ID: SSTD080
Inst ID: 5 9 72hp6 0.i
b/8 2 7 0 Cv 6.m Quant Type: ISTD Cal File: HG020303A60.d Calibration Sample, Level:
Compound Sublist: all.sub
4
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
^ DF 1.00000 Dilution Factorw 1000.00000 Volume of final extract (uL)^ Vo 1000.00000 Volume of sample extracted (mL)
Vi 1 . 00000 Volume injected (uL)
Cpnd Variable Local Compound Variable
AMOUNTS
0JAN7 Si 3 CAL-AMT ON-COL
' yrv.-r-nds MASS R: ' XK‘ -- RESPONSE ! NG) ' NG}
5697 3
224311
167^69
2: a: ? 9
359192
252595
56 7 E18
- ~ n ■ fi r,
759056
25408':.
•I 3 . :,ono
•; o . o c o o
•; n .0000
; o . o o u:
40.0000
4 0 . C 0 0 0
SO . 0000
9 0 . 0 0 0 0
6 0 . 0 0 0 0
9 0.00 0 0
50.0000
9 o .noo r.i
5:. ooco
60 0000
r. 7.00
) . 00
50 . 00
5 0.00
3 0.00
3 C . 0 0
SIMILAR I"":'
• . V,.- • .. i
Daca File: /chem/5972hp60.i/DF020303A60.b/HG020303A60.dReoorc Dace: 04-Mar-2030 08:37
"pc ar.ds
Ou.ANT BIB
MASS 3*T K>:r ?.T PEL ST RESPONSE
CAL- AMT
: no
ON-COL
( NG) SIMILARITY
5 Beroza iaer.yd* 77 7.477 7.477 C . 9 11: 109279 80.0000 90.00 9172P::erci'
94 7.542 n 6 4 6 10.9321 264357 80.0000 SO . 00
:7 Bis .2 - chizreezhyl - ezner 0 7 7 . 764 7 ">64 '0.946'. 181559 80.0000 6 3'. CO
:? 2 - 2h 1 orepner.c : 2 ? 7.842 7 54 ? ■'0.957! 212381 80.0000 8 C 0; 9038
-- i. 3 J l'i ch 1 c robbnCcna 145 8 . 103 a .101 ( 0 . 9 S 5 ;■ 290202 SO.0000 so. 00
1,4•Di chlorobenzene a 2 * r .221 i ’ rl u 2 ' 286972 30 . 0000 s 0.: 0
- - Benzy 1 a loc-noi i ■: s 8 . *i i. 5.441 '1 02 9.' 139546 80.0000 80.0:
^2 3,2- :■ i c h I o r c b e n z e r. €• 14 o 5.475 3.475 ;: . 0 3 3 i 272537 90.0000 so. oc
2 - m s c h v 2 d h e r. o I 109 3.644 0 c.p ■: 1 . 054 } 175420 SO.0000 80.00
24 I 2' • oxyc: s . 1 - Ch: oropropane '• 45 8.661 r> . 0 0 1 : 1 .0561 264702 80.0000 60.00 8334
~i ^ Acetophenone 1 0 5 8.361 5 . 0 S 1 ■: 1 . 082 ; 313697 SO 0000 80.00 7901
-■j 3 -Mezhylpnenol 108 • 8.393 ' S . 3 ? 5 1. s 51 214569 80.0000 80.00
7) -< 4 -Met ny:phenei 10 8- 6 i 9 S 3 3 0 S >' : .035) 214565 80.0000 SO . 00
--- N - N: t rose - d i - N - propyl amine 7 C ■ 8.331 5 . A 8 l i 1 . : 3 2 ) 158995 so.0000 80.00 704 5
H-e:-:a zh ■ ernetnare 9.033 9.233 '1 101) 119546 50.0000 80.00 8512
;• e Nitroner.zer.e 77 9 168 9.155 (0.356) 240569 80.0000 30.00 94 52
isochcror.e 5 2 ? . 5 7 > 9 .575 (0.925) 389565 80 . 0000 80.00 9440
12 ? 9 . 7 ; ^ 1 :3 .0.933) 120423 30.0000 30.00 9000
2.4-L:m~::.y.ph-:.:.; 12 2 9 . 7 94 5 .754 ■ 0.945) 152170 30.0000 eo. 00 8373
bis': - ::. i o c. : i o y ’ .7. e : h a- r' 3 9.-47 5 4 4 7 : 0 . 9 6 1 ) 224808 80.0000 so. 00 8 6 6 6
■- 2 4- Diceic roehene 2 ■ 'i 7 12 13 3 1 0 1 3 ' ;0.979) 215902 80.0000 80.00
170 10.258 10 . 266 :C.952!. 258805 80.0000 80.00
12 5 10.403 1 O' .403 11 . 0 0 5 i 576418 80.0C00 90 . 00 9411
4-Dhlorcan i 1 i:v- 12 7 12. 4 3 3 10.455 (1.013) 232715 80.0000 80.00 3932
;v Hfxacn 1 or :• r •: t -.v i 2ir 10.505 10 -yis (1.024) 19584? 30.0000 80.00 9766
-' _rtl‘r 1 . FI B'". 11 .757 — . 1 .072' 41473 8 0 . 0 0 0 0 80.00 8SP0 !M) 1
- : ? ■ "-.ioio- ; i ?■? 11.368 1:. IPS (1 . c 9 8 '< 175523 30.0000 80.00 9353
O-M^.hyinaphnhal-r.e 142 .00; 11 .505 (1.121! 428754 SO.0000 80.00
: - Mvi--1 14 2 : • .77-; : 1.774 (1.157) 339356 50.0000 h C . 00
: ' :yv: : •:. . 2 2 7 1. 4 ” 5 • ’ : 7 t l 2 . 6 4 1 1 a Q c 0 0 53.0000 80. 00 0 818
■; I.-;.- - T : : 2: r; :'r.-r.o 2 12.112 : .1:2 :c.902) 161030 ■SO . 0000 90 . 00
: . . b -T: :"::2c:-op:--;:-,2 1 2 . : 5 0 12 12 0 (•:. 50 7! 182767 3 0.0000 80.00
" ■■;.• *y* 1: ; 12.434 ‘.2.434 : : . 5 2 6 • 51 374 0 60.0000 30 . 00 8414
1 - Dh 2 :: 2 • :>.• 2 5 2 12.45 7 '.2.4-7 446753 30.0000 80.00
c " :: 654 ; . 54 2, -> ~4 i 7 160.000 16 0.0 9185
: i r.y 2 r." ' « 2 c ■ - - ; • • 2 2 2 4 " r .05-. 5 6 54 0 0 SC . OCCO ao. 00 9136
: ■■ 1. ■ . : -ip.:? 30.CC00 3 c. 0 c 93 5 5
:".: '.2.2 ■- ■ : :■? 30 0000 3 0 . 0 3 9 4 01
..2.05. • 265590 1 6 0.000 ::o.: 04 04
■-00 1 2 . ; 4 -■ 413711 = 0 -0000 5 0.3'".' r, ~i i ^
■ .-.v : ; '. 0 - _ . 0 2 4 J r ? 4 5 400.005 4 3’C . '■
, : p :■ i 2 " .2 1 2 1 • 2 2 5 1 z/j iSl.DOO 1 3 0 94 34
' • .• - ; ;• c 2 - 1 . 026■ n2-.11 6 0.000 Ci 0 *‘j Q "j 8774
:■■■■ •; 1 : : 7=5720 5 0.0 0 0 0 5 0 . 0 0 a z. c ’
•• * ~ -••••• r...................... • ■’ • . -r - . " ■ = • • ••■ k-‘ • • " - ■ u ■j 3 ^ c
2 - :-o I--::-.-::-..-'. c vr.y 2 -12ie : 2 2 •; 1 j • • 1 1.: ? :• > 1-.--2H 5 0 0 0 :.'M)\
F 1:: ; 4 -i : : ■■ 1 . 17 5' ^ 54 ' ^ 3 0 00'’° 50.00 ' 717 ‘
45o
Data File: ./chem/5 372hp6 0 . i/DF0203 03A6 0 . b/HG02 03 03A6 0 . d Report Date: 04-Mar-2030 08:37
5 2 4 . 4 - Dir.: z ro - 2 - nenhylphenoi
64 N -Nicrosodip.oer.yi amine
:: 1, 2-D:pher.yihynrazme
5 4 4 -5:G.mopr.eny: • yhenylecher
r e n t a c r. i o i' c- c n e n c .
I’d Pher.ar.chrer.e
7 I Anthracene
72 ■Taroazoic'
7 3 r: - r. - bucy; phc ha late
74 Fluoranthene
- Compound response
O'JANT SIC-
mass RT EX? RT EEL RT
13 S 14 .4 64 * 4 . 4 d -t
193 14.514 14 . 514 i 0 . 5 0 3 )
169 14.616 14 .616 (0 .905■
77 14.634 14.634 il.033»
2-i 3 15.276 15.276 ;C.951
2 9 4 15.177 :=.i77 : •: 9 5 7.'
2C0 15 . 'j 4 -j 15.54 o .' C . 36 7}
2 6 6 15 . " 3 15.. 73 3 : C . 5 7 9 )
17S 16.1.5 1 6 . 1C 5 I 1 . 002)
173 1 6 . 2 0 6 16.206 (1.008)
167 16.47_' 16.477 ' 1 . 02 5)
14 9 17 . 06 5 17.065 : 1 . J 6 2 )
202 16.215 18.219 (1.134)
184 13.439 IS 4 3 9 >' 0 . e 9 1)
2 0 2 18.603 18.605 ( 0 . S 9 9 )
i 4 y 19 . 708 15.70S (.0.95 3)
TCI 2 c 4 2 2 22 . 522 i 0 . 5971
1 4 9 2 l . 654 20.455 ■'0. 9 3 s ;
2 2°. 20.673 2 4 673 (0.999:
223 20 74 0 2 ■. 7-r 3 (1.002)
14 9 21 . 654 21.654 (0.529;
252 2 2.50 0 22.503
'•'CO 22.550 21.553 : D . 94 7 ;•
2 52 2 3 . 1 9 3 2 * . 1 5 3 < 0.5 9 5)
2 7 4 26.255 ~ -) ^ r. ; 1 . 113 i
779 2 5.55 o c . j i 0
274 27 ")";•) OU . 2 2 0 •. 1 . 1 A B '
manually intearaned.
AMOUNTS
CAL-AMT CN-COL
RESPONSE ( NG) ( NG) SIMILAR .’’TY
269615 160.000 : 4 . o c • 1 ?
251793 160.000 1 o. 0 8 r 1 :*
379012
ooooo
3 c. o 8 502.
599307 30.0000 8 0 0J 8716
209916 SO . 0000 80 . Or 8705
241003 30.0000 80 . GO 9295
2935 80.0000 30.00 S622
163090 160.000 160.0 9196
351323 80.0000 80.00
882630 SO . 0000 80.00
64 1447 30.0000 30.00 8673
1080618 80.0000 80.00 3915
983385 80 . 0000 80.00
281890 160.000 160.0 84 36
1013043 80.0000 80 . 00
516569 30.0000 30.00 9196
4 3 1S17 30.0000 30.00 7529
■30785 3 0 . 0 C 0 0 80.00 9574
1071777 SO.0000 3 0.00
993339 ' 80.00C0 80.00
1262937 30.0C00 eo. oo
932062 80.0000 8 0.00108 714 2' 90.0000 3 0.00
393373 SO.oooo 80.00
964633 30.0000 80.00 893 0
843146 80.0000 80.00 8902
608731 SC . OOOO 8 0.00 766 3
45 A
:=. rL If: .•Vnfm/nl^ZhjjGO. 1/DF020:
.]fct ign Data: OZ-h^F.-ZOOI 1*4:01=.r-• Ijfr^nr : 59~ ZhoOO . 1:enr '5amole ID: 53T0030
h£iU . ij/HGOZO JiU-jHf.O . d
"□ouna: 2.4. 6-Tr ibromoDnenoi
Nijmcier: 1 13-39-3
Ion 329.60: Area: 137100 Height: 6Jj51
1 .5
1.0
14.7 14.3Mm
14.9 15.0 15.1 15.2 15.3
Ion 332.00: Or Height:
15.1 15. 15.:
15.0 15.1 15.:
45
is.:
0
jjit =, v i ip: •• cnem-' 5'?72hp60 . Df 020303HbO. o •HG020393HbO . oInfection Date: 03-MhF-2002 14:01I r\~ t runenr : SO^lhoGO. iClient Sample ID: zbTDOOO
Ion 113.00: 'Area: JlJ7b Height: 145i
. 6'.
b-
10.9 11.0 11.1 11.2Min______________________
Ion 55.00: Hrea: 3095 Height: 3095
11.3 11.4 11.5
1
i cn
11 .3 11.4 11.5
■■ t: 244;
45b
11.2 11.3 11.511.4
J=i"3 'ii?: .• i:he<Ti./5972hp60. i- DrijZCGOZ-^bO. d/HGOIO^OjhoO . a Injection Date-: 03-HmF-2002 lJ:ui I n = t rument; 5972hp50.i
•=nr Samole [[i; 55TD080
ouno: *i-Ch loroonenu i -ijnenu 1 ether' lumper; ^0'J5-72-7
1 .9-
i. 6-
Ion 204.00; Hrea: 351265 Height: 19S273
rri
1 j . 0 14.1 14.2 14.3 14.4 m.5_____________________________________________M 1 n
14.b 14.7 14.8 14.?!
Ion 206.00: Hrea: 0 Heieht: 0
14.5 14.6 14.7 14.8
4 5 7
14.6 14.9i1 14 14.8
l-t.884
k- I
14.884
Data File: /chem75972hp60.i/'DF020303A60.b/HJ020303A60,d
Date : 03-MAR-2002 16:01
Client ID; SSTD120
Sample Info: SSTD120:2319
Volume Injected CuD: 1.0
Column phase: J&W DB-5.625
Instrument: 5972hp60.i
Operator: 2319
Column diameter: 0.32
:o
LD
Data File; roher',/5072hp60. i/DF020303A60.b/H;i020303H60.d
Date : 03-MAR-2002 16;01
Client ID; SSTD120 Instrument: 5072hp60.i
Sample Info: SSTD120:2319
Volume Injected <uL); 1.0 Operator: 2310
Column phase: J&W DB-5.G25 Column diameter: 0.32
0~)
LO
'vd'
/chem/'5072hpfc0. i/DF020303Afc0.b/HJ020303A60,d (Part 2 of 2>
LJ L
IS 10
1 I
Data File: /chem/5 9 72hp6 0 . i/DF020303A60 . b/'HJ02 03 03A60 . dReport Date: 04-Mar-2030 08:38
CompuChem
Data file : Lab Smp Id: Inj Date : Operator : Smp Info ■ : Misc Info : Comment : Method : Meth Date : Cal Date : Als bottle: Dll Factor: Integrator: Target Vers Processing
Semivolatile Report /chem/5972hp60.i/DF020303A60 SSTD12003-MAR- 2 0 0 2 16:01 2319SSTD120:2319
/chem/5972hp60.i/DF020303A60 04-Mar-2030 08:37 mikhael 0 3-MAR- 2 0 0 2 16:01 51.00000 HP RTE ion: 3.50Host: einstein
SW-846 Method 8270C .b/HJ02 03 03A6 0.d Client Smp ID: SSTD120
Inst ID: 5972hp60.i
b./8270Cv6 .m Quant Type: ISTD Cal File: HJ020303A60.d Calibration Sample, Level:
Compound Sublist: all.sub
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
DF 1.00000 Dilution Factor
vt. 1000.00000 Volume of final extract (uL)
P 1000 . 00000 Volume of sample extracted (mL)
\J r 1.00000 Volume injected (uL)
Cpnd Variable Local Compound Variable
1AMOUNTS
. LAN!' : G CAL-AMT ON-COL
is 1 v ,7 - ,7 RESPONSE : FJG) ( NG)
-.: ■ ■ - . i . 0 0 00
: :■ . ;;v
■ A.:-::.-,;:.:;::--..- - ■- ;' : 1 n i 0 3 9 4 d . 0 0 0 0
i.: , ■ ?. -< ■:-*:: . c . o o o o
2 : - • 377QP4 4 d . nnoo
- ' - um-ir :7c..-:; -C -
- ; . -!: • ■ • ■
::. - : : I2C.000 lib. 9
: .: :. 4 cio.coo ::0 7
. : 7- tc.-.r • i : . - - "• . .•: i I j 9 31r ? . 12 0. 00 C lib . 1
. ;■ ; .: 4:2. ■: b i 120.0 00 117.:
. •> " 1 3 '} 34 12 1 . '■ 0 '3 '14.;
5
oIMILAP.IT
46U
Data File: /chem/5972hp60 . i/DF020303A60 . b./HJ020303A60 . dReport Date: 04-Mar-2030 08:38
k'uA2'« : itij CAL-AMT ON-COL
^pounds MAS S ?.7 pv? RT REL RT RESPONSE 1 NG) ( NG) SIMILAR:TV
15 Ee-zal uehyie 77 7.475 7.473 . . 9:1, 137022 120.000 10 3.1 913 ■;
Phene: . 94 7.55 :■ 7.659 ' 0.934) 349394 120.000 115.9
• “ Bis 2 - cr. 1 or?-e:.:v/2 1 echer ? 2 7.77? 7 7 7 C ;c. 243: 239995 120.000 117.7
1? 2 - Ph ; :noche:n-n 12c 7.545 1 345 < n . .= 5 7 > 269075 120 00C ii7.:- 8937
Id 1 . 3 - 2:c;;io:-:oe:;:ete 1 -i 6 i.05R 5.000 .3.95=: 377599 1 2 0 0 C 0 119.4
2 3 1 , 4 - d: chic vicer.^ne 14 6 2' 7 3.217 *'1.0 1 2 3 0 9616 120.000 117.5
21 benzy: elcenol 10 2 = .457 3.437 (1 . 02 5■ 179201 120.000 119 . 1
2 2 1. 2 - D i chicrobenzene 14*5 5.471 9.471 ■'i 7 - 7 - 363165 120.000 119 . 9
2> 2-Mechylpeencl 10? 5 . 44 0 3 . 4 4 C '1.054: 227264 120.000 11 e. c
24 2,2' -oxybi 3 ' 1 - Cn 1 c-ropropane : 45 5 .'5 = 7 9.657 >1.054 344834 120.000 117.9 3 3 0 3
2; Acer opr.en cn- ICS 5 -7C 5 . 67"> 1.08 3 ; 426126 120.000 123.0 8 126
? ->:e:hy: phen.: 103 5. 8 55 3.994 (1.085- 300041 120.000 121.6
2 *■ 4 - Mec hv lpheno : 108 3 =74 p C Q ^ (1.085) 300041 120.000 121.6
2 9 N * N: c rose -hi- N - prepyiazn ne 7 0 5 .7 -7 6 .377 !1.033; 218470 120.000 121.6 0(m: \
23 Hexachloroe:bane 1 1 3.04 3.045 ( 1 i r> i 1 155699 120.000 117.1 9168
3 0 N ic robehzene 11 9 . 15 3 3.165 { G . 3 S 5 J 326256 120.000 117.5 94 2 9
33 sophoror.e 32 9,571. 3 . 5 ' 1 ( 0 . 525) 519393 120.000 119.0 9 3 57
12 • ' 139 3.704. 9.705 • r Q 1 ; 1 163244 120.000 120.4 2 Q 5
1? 2 . -1 - 2 : n-r, l hy 1 nneno 1 ' ? 7> 9.791 9 .791 (0.946) 193934 120.000 115.8 S 3 58
b:e :■-■■:n:.-,; :-rne-v ne:h.-,n.e 3 9.34 3 0. 00 5 (0.361.1 306241 120.000 118 .2 864 9
ll 2 . -xl v: re-: 162 12.123 . 125 ( f . y 7 5 ) 293058 120.000 119.6
122 1 C . J 6 4 10.264 (0.992:- 345713 120.000 118.6| --'I:-
122 10 -4 0 0 10 4 00 '.1.0 0 5 ■ 307511 120.000 120.0 9 3 6 3-
• i 7 10.001 :o.501 ■: 1. oi5) 321823 120.000 117.6 3917
12 He:-:enh:e:rr n i.nee 22 5 10.-2:;: ::. 4 2 c ' 1.026' 263238 120.000 119.3 922?
- - i 11.7 2 :• o > "> C. 1 [\ 072: 59011 120.000 123 . 1 88 95 (M! \
; 1 ry.::he:-.A i 11.=44 (1.093' 240720 120.000 120 . 1 9131
il 2 _ i. 5 :: 1.121: 587510 120.000 119.0
.n-. hn.m 142 • * 777 1 13 7! 468741 120.000 13 n . 8
lexnnh in ..■ y:. np , e ::: env 2 o 11-972 0.552, 252G74 120.000 13 2.3 866 3
; 2 2 , 4 . 6 - 7ri -h . ;: :pheec: : vh :: i - 12.1 24 ■O.OOl: 2 | r. 1 2 £ 120 000 121.3
2 •; . 5 7 I j: *. : o ; 2. : 12 17-3 (0.906) 217709 120.000 112.5
154 -2.43'; : 2 ■ 4 ■ ' '0 •} 7 4 ) 7 2 2-12 1 120.000 120.4 8195
•. - . y •••■•.•• v 2 :o o-: ; . 2 7 ' 517602 12L 000 119.5
"2 : 1 •' 11 " . V 4 1 •14 5 12 7 2 4 .:. 0 0 0 2 2*= .6 ?! ?7
I.--' . , “ ■ ■ : 1 ■" 1 - 7 -, 7 9 7 7 i 2 -. .000 . 115.1 555R
• 15555P :i . o o o 116.3 9 14 =
■ - : 5 2 555=55 .000 1 i 7 . = 54 7 7-
342850 h. 00 a 7 ? 9 57 = 7
: 4 A- ::. : 5 4 1 .004. 55755: : 20.ooo " 2 1 :-4 0 7
- - • ~........ -4 : - . 0 : 0 6 5 2 2 7 3 ■■■ 00.000 7 1 2
-■ A - .' r *> <, c, 7 £ r. 24 0. n:;o 24 1 7 -.b
- •; ;• , ;■ ; - . . -51. 2 :• 1 j -1 •'.) 12 0.?0 0 12.. 7 5 7
- :■ ■■ : : •: - 3 4 5 ' : 5. - v. 1.02 5 - 1:612 2 5 120.000 : 2 ' 2 3555
: ■; v :4 2 '■ 11 . i ■ 1. :■ = = . 3:9327 120.000 115. 3 9 14:
• ■; . p-nyhy n 7:4 • 7i 4: ■ .5 10 1 . O' 7 2 : 322516 12 0.00 0 12 7 2 M, \
:-6 * 1 . ~ 2 . 120 00? '23.7 7 0 7"
',-461
t ->. <-
Data File: /chem/5972hp60.i/DF020303A60.b/HJ020303A60.dReoort Date: 04-Mar-2030 08:38
AMOUNTS
quant s:g CAL - AMT ON-COL
L-~pounds MASS RT EXF RT REL RT RESPONSE [ NG) ( NG) SIMILARITY
52 4 -Nicroanilme 138 14 .477 14.477 11 . 0771 346S25 240.000 226 5 8 5 57
5 3 4,6-Dinicrc-2 -methy Ipnenol ■95 14.511 14 .511 (0.903 = 34 086 6 240.000 2 5 C . .: 7?7r
•5 4 N - N i c rosod l oh^nv: ar.i ne 16a 14 . 6 2 z 14.612 ■G.505) 492579 120 000 115.2 3682
3 5 1,2-liphenyl hydraoine 77 14.530 14 580 (1.052: 334159 120 000 11Q 8742
6 4 - Sromcpheny: - oner.y lecher t 4 0 15.272 15 2 72 T .550! 283947 12. J . 000 117.8 9291
'T Hexa c h. I o r obe;: - er.e 264 15 3=0 15.390 . 9 5 9' 322523 : 2 0 . 0 0 0 117.5 9 04 0
)9 At ratine 200 15 . 542 15.543 ' G . 16 7' 2356 120.000 5 . 51 8119 (a
•: 9 Pencachloropher.c: 266 15 . 720 15.729 : C . 7 5 205416 24 C. 000 261.7 8821
’’■? Fhenancr.renm 17$ 16.116 16 . 11 S : 1. eoi 1197263 120.COO 1 18 . S
2; Anthracene 1 7 S 16.2C3 1 6 . 2 C 3 (1.023■ 1230579 12C.000 120.4
22 CarbazcOe 16" 2 t 4 5 : ■ 16.450 :i. Q'Jr - 902314 120.000 117.1 q22 5
"•'3 D: - n - duty 1 phtna i at e 14 9 17.052 :7.032 •1.062: 1531388 120.000 119.3 9626
24 E1 u 0 r a n c h e n e 202 18.215 19 .215 '1.1341 1376284 120.000 118.6
?5 3enzid:ne 154 18.436 1 0 . 4 3 5 ( 0 . S 9 Cm 318184 240.000 149.6 8548
2-; Pvr^n- 2 C 2 ' 3 5 2 2 18.622 1 0 . 3 5 e ; 1406929 120.000 114 . 7
14 0 19 704 12.704 (0.952) 699859 120.000 113.2 9121
i.l-lcni::;-::::--. ? g '> 2 0 .618 2 C 1 4 ’ 0 . ? 9 6 1 545300 12 0.0 00 112.2 7961
O c-sll-hyl-v; Ph: r.a laz~ 14 0 ' 20.652 20.652 10.998) 1101654 120.0C0 119.6 9742
“••• Benzc :a ■ an.: hr icene 2 2 3 20.636 20.6S6 i 0 . 9 2 9 ) 1449464 120.000 116 . 1
:1 Chrysene •11: 20.726 20.736 i 1 . 0021 1336201 12 0.0C 0 116.6
c2 2: - n - c-c y ion:: n , lace 14 0 21 550 21.550 (0 . 929) 1682062 120.000 118 . 5
Benzo'b. : icon —nere 252 22 .4 55 n -1 .- c. g (0.965) 1477875 120.000 124 . 9m —
-> g g 22.547 22 54'' (0 967) 1301121 120.000 115.6
2 5 2 23.1=0 33.150 ( G . 5 9 5 1 1158573 120.00G 119.2
he Indenc ' I , nynene 2 7 6 26 302 2 6 . 3 02 (1.128) 1231963 120.000 119.1 8 7 04
^ 2 i ben.no : a . h ' anthracene 276 2 ^ 5 • 2p.’53 : 1 . 131 * 1065275 120 . GOO 110 . I 9 ?2o
Hence n.h. . . yler.e 224 2 7 2 3 : 2" 23.;. '1.1-8' 1 G 2 4 3 8 4 1 2 0 .0:0 117 . 9 7 6 52
QC Flag Legend
a - Target compound detected but, quantitated amount Below Limit Of Quantitation(BLOQ).
M - Compound response manually integrated.
Daio file: ' c hen•• 5972hc"-0.: ••'DF020503^60 . b/H JO. injection Dei : OD-^dF.'-DOOD i 8: 0 ii n = t nijmenr ; 5972n;jo0. *^l~nt Oamijle ID: 35TD1I'0
Mina : H-M i z rC'jo-oi -N-oroou 1 smi ne lumot* 1'' : 621
jwb0.d
Ion 70.00: Area: 218^70 Height: 110300
fv
N.cd
OD
3.70 8.-5 8.80 3.88 3.90 8.95 9.00 9.05 9.10 9,15 9.20 9.25 9.30 9.35 I______________________ M 1 n_______________________________________________________________________ |
Ion 130.00: Ores: 0 Height: 0 j
l
I
9.05 9.1 Jj 9.15 9.20 3.25 9.30 9.35
46 J
71. =' : . _-0 C.. :-5 9.99 9.05 9.10 9.15 9.20 9.25 9.30 9.35
Data File: 'charr,/5972hp60Inj^ction Date: 03-MhR-20' I ns t'' urgent : 5972np60.i
le^t Bampie' ID: S5TD120m'Ouna : 6 apro 1 ac t .an-i Hamper : L05-60-2
DF02016:01
■hdO.b/HJ020303060.d
Ion 113.00: Orea: 59011 Heignt: 151*48
m.j. .
1 .2
1 . 1
l
/
. 60 10.65 10.70 10.75 10.80 10.65 10.90 10.95 11.00 11.05 11.10 11.15 11.20 11.25 11.30 11.35 11.40 11.45 11.50 11.55
__________________ _ _______ Min ____________ .___________Ion 55.00: Orea Height: 4039
1.6
: : . i 5 11.20 11.25 11.30 11.35 1 1.40 11.45 11.50 1 1.55
46:;. 05 :;. :i.>* i:. 20 11.25 11.30 11.35 11. jo 11.45 11.50 11.55
J n t ■Si Inj* I ns*
i Tilt: cnem/5':'r2np>50•ct ion Date: 03~MhF.-20' rument: 5972fip60.i.'nt SamDle ID: S3TD120
1/DF02- 2 16: 0
ti/HJ' “O' 1h60 . a
Pfccuna: -:• NijUfOer :
.l’ilC'«"Oon*r.u 1 -ohenu let her '005-~2-7
Ion 204.00: wrea: 522916 Height: 365656
$
•7
TT ]
^ . o-
2.6-
2.4-
1.4-
1.0-
0.3-
0.6-
n. 4-
15.95 14.00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14^65 14^70 1^.75 14.80 14.85
__________________run_________________________________________________________________Ion 206.00: erea; 0 heignt.; 0
i or.
14.50 14.55 14.60 14.65 14.70 14.To 14.80 14.S5
46 0 !
0 ;j. 1J.50 14.55 14.60 14.65 14.70 14 '5 14.60 14.85; J “ ■=. i j
Data File: /chem/5972r,l-.C,0. i/DF020303A60,b/HH020303Af.0,d
Date J 03-MAR-2002 14:41
Client ID: SSTD160
Sample Info: SSTDlfcO^SlS1
Volume Injected <uL): 1,0
Column phase: J8.W DB-5.625
Instrument; 5972hp60*1 •_DCD
Operator: 2319
Column diameter: 0*32
Data File: /chem/5972hp60. i/DF020303A60.b/HH020303A60.d
Date : 03-MAR-2002 14:41
Client ID: SSTD160 Instrument: G972hp60. i
Sample Info: S3TD160:2319
Volume Injected <uL): 1.0 Operator: 2319
Column phase: J&W DB-5.625 Column diameter: 0*32
CD
7chem/5972hp60.i7DF020303A60.b/HH020303A60.d (Part 2 of 2>
5.2
5.0-
4.8-
4.6
4.4
4.2-
4.0
3.8
3.6-
3.4
3.0-
2.8-
2.6
2.4-
2.2-
2.0
1.8
1.6
1.4
1.2
1.0
0.8
0.6
0.4
0.2
LJ
IS
l—i’r>
..__ J l_J LJ
Data File: /chem/5972hp60.i/DF020303A60.b/HH020303A60.dReoort Date: 04-Mar-2030 08:37
"ompuChem
Data file :Lab Smp Id:Inj Date : Operator Smp Info :Misc Info : Comment : Method :Meth Date :Cal Date :Als bottle:Dil Factor: Integrator: Target Version: Processing Host:
Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020303A60.b/HH020303A60.d SSTD160 Client Smp ID: SSTD1600 3-MAR- 2 0 0 2 14:412319 Inst ID:SSTD160:2319
5972hp60.i
/chem/5972hp60.1/DF020303A60.b/8270Cv6.m 04-Mar-2030 08:37 mikhael Quant Type: ISTD0 3-MAR- 2 0 0 2 14:41 Cal File: HH020303A60.d.3 Calibration Sample, Level1.00000
HP RTE Compound Sublist: all.sub3 . 50einstein
Concentrat ion Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
DF 1.00000 Dilution Factor
A 1000.00000 Volume of final extract (uL)w 1000 . 00000 Volume of sample extracted (mL)
Vi 1.00000 Volume injected (uL)
Cpnd Variable Local Compound Variable
AMOUNTS
s;g CAL-AMT ON-COL
iCTpour.ds MASS ?T ^ ?T REL RT RESPONSE ‘ NG) ( NG)
. 1 .: cr.: l: • :4 E.I -.l- 7 - 3 2 0 40.0000
■- •' ""C" " : : u . o:o: 1 v ■> 1 5 -3 40.0000
: ••• • ••: ' • ••••" • : u ; ■■■:■: 0.7 '2 : .000: I 4 4 5 5 4 40.0000
? 7 - ■■ i. lo: : 2 B G 2 2 C 40.0C0C
* ?'y v v s -■ • :I ' : :.vo: 40.0000
* •' - i 3.. 2 64 /•: .'/ r: ■ i. ?• o i ■ 2 2 7 1 C 0 40 . 0000
“ ...- • • • ** - • -» - " =■ - ioO.OOO i7i . J
". 4; • ■ ': :• -. :• ?.: • 4624-f^ 1-30.0 0 0 155.3
• N : : • . : • ..-Hr 473S47 16C . 0 0 0 15 6.6
: or:-;-::.: 1 ~2 7 .. : n:: ■•.’4 306c 160.000 157.6
: :: • . ;. • ; •j ; • : ; -.••'• . •;. -5 :■ ■ . i 4 2 1 3 7 7 160 000 154.2
; ::: Teicr.-^r.v: : - - £ ■ . ;* 12 ■ 1 z' 5 g "> c 160.000 157.2
; ;• ■ 4 u - 1 . 4 £ c ' C . 4 2 3 ; 451572 160.000 146.£
•. 4 Yyr id:::-; : £ ; J f ;i ■:.427. /. L 0/22 160.CC0 145.4
SIMILARITY
468
Data File: /chem/5972hp60.i/DF020303A60.b/HH020303A60.dReport Date: 04-Mar-2030 08:37
.'CANT o _G CAL-AMT or;-col
-•impounds MASS R 4 EXP 2:7 REL ST RESPONSE 1 NG) ( ng: SIMILARITY
15 Eenzaldenvde ~7 7 . 4 7 n 7477 - ^ 1 ' ’ 148507 160.000 137 1 917?
54 7 . 663 7.663 to. 534J 49S843 150.000 162.6 ;r.
Bis:2-chioroe zh y 1) e ther 5 3 7 . 782 7 , 7 6 2 ;c. 44 8 ■ 320891 162.000 158 . :•
Is 2- Chic ropheno 1 128 7.64 9 7.349 , 0 . 9 5 7 ' 348818 16 0 0 00 152 . 1 8998
:v 1 . j - ■? u r. 1 c r' o be :l z e: i e 14 6 3 . 1C j 3.103 '0.535' 503465 16 C.000 15 6.=
IT :.<-::c,-.::.roh5n:w? i4G i.221 = ->2' ■:.00: 489474 160.200 155.1
i: Bezzyi alcohol 106 £ 4 4 1 S . 44 1 <1.0291 231243 150.000 152 . e
22 1 . 2 - Di cr. 1 orooer.zene 14 5 3.4'-' = 6 .475 ■1.033: 481611 160.000 1 5 S . 0
21 2 - Xethy • phenol 1 08 3 544 5.644 i 1.054: 296003 160.000 154.3
24 2,2'-oxyb:s<1 - Coloropropane) 4 5 3.641 3.661 (1.056) 466066 160.000 157.7 84 39
2 5 Acetophenone 10E 3.831 3.881 i 1.032) 547908 160.000 157.0 8318
2S :-Merhyipheno: 106 8 . 3 IE 3.915 '■l . 0671 415847 160.000 165.4 IA)
2 7 4 -Methy i'phencl 1 0 8 ' 3.915' 3.915. (1.OS 7) 415847 160.000 165.4 (A)
2 : N- N : z rose- d : -N - prepy Ian: ne 7 0 6.693 3.898 (2 .035) 309069 160.000 165.7 7697(A)
2 r Hrxacnioroezhar.e 117 5 . 050 5.050 11.103) 201941 150.000 154 .4 9174
K Nitrobenzene 77 9.16 9 5.169 (0.884 ) 419930 160.000 159 . S 9420
3; sophoror.e , 9 . 575 9.575 {c Q23) 639303 160.00C 154.9 9311
32 . 13 ;• 9.710 ,.viu ' 0 . 5 6 ) 200599 160 . 00G 156 . 1 8815
‘2 j. . 4 - 2: :".ez n.y . or.tz.o - i 7 -> 5.795 '■ . '>9 5 i 0 . 94 5, 237383 16 0.000 150.9 8 24 6
5. 54 7 ..- . 54 7 ,0.959) 334475 160.000 158 . 2 8703
25 :.-4-;':c:-;-:opi'-r’o; 15 2 1C . i 3- 3 " ' ■ 3 ? < 0 . 9 7 7 ) 364897 160.000 157 . 3
ISO 10.265 1 . 2 6 ■: ; 0 . 9 9 0 ) 4 32092 160.000 155 . 3
12 = 10.4:4 • .404 ( I .003) 1050011 160 . 000 16 3.3 9423{A}
; 2 7 1 C . 5 0 5 .505 : 1 . 013 ) 400235 160.00C 15 3.7 3 866
:= Hv:<ach:crob'.;ia-:: jne ") Z. 10.424 1 - :. 4 2 4 '1.0241 324514 150.000 155.7 9057
•;1 C 3 p i.1 a •: z a :c i : 2 11.114 : 1.114 :2.772) 67205 150.000 153.9 8745(M)
: 7 7 1 1 . 3 5 3 11.35- Oib! 2 2 2 Q 4 3 160.000 153 . 5 9038
5-:-:r^y2::i.p-: 142 11 . 4 0 5 1 1 .605 (1.119) 742760 160.000 159.2
■i. ; -.-■Jeznyln-.,I-:-::-. :42 1 1 . 7 74 11.774 .1.235; 55 16'74 150.C0C 153.3
4 4 hi ::r:y :1 rp-.-::: a : en- 2 37 07.: ::.272 '■1.664; 322032 160.000 162 . 9 8774(A)
18 2 . 4 . ■; - 1: i ;n 1 : . :2 . :: 7 ' ■! . 6 02 : 260699 160.000 15 5.0
2.4.1 -T: : ml : I-;.::-.---:-. : ! ; 1 2 .'I - 12.12:: 275594 160 . 900 149.4
: : ■ ••..•• . 15-; 12.437 1 2 . 4 3 4 0 . --2 5 905355 150.002 151.8 8C36(A)
■ir 2-2'. r;:-::-,:::-::::, 1-32 12.4 4 : :::. 4 - 7 72 - 752419 i sn n;yi 161.3 (A)
; •::.: no..:-.. : •: 12.'' 12 4 'I 'll 562270 320.230 3 0 3.5 5099
- - 12.271 964305 160.0-:)■ 0 15 9.2 5675
; ■ -7 ■ . *. r. 0 c 1 ") 150.100 156.3 5 14 3
. .2 - : 3 r. . .'-2 : 1- :■ c- 7 3 v 160 . .. 00 1 0 0.2 54 37 {A
: 7-3 ' 7 . : ■ 7 4 394 65 3 2 f.000 3::.; 5 3 4 0
'•••••••• '• * * 6 4 ■: . ■7 E 1 709733 I'D). 0 00 15 9.7 9612
h ■; -2 : nil vn.ph:::-. ■ . 1 1. 2 4 513925 0 0.000 832.2 (A
- - 1 ;■ - ■ : ■ ~ . 1 . ■ 2 0 . 0 1 r» c 3 2 0 . 0 00 1 n M. = 54 0t
h-i-hCL: -. ■ : . 7 -■ ■: '1 . 12 5 '• ; 0 37 6 6 1 6 C 0 0 2 15 7.2 3657
- ' : : •: :R = : J r . ■; : 0^5. 1 3 2 ° 2 S 3 160.000 i5B. 864 7
•• 2 : -rzh.y : :• - a ! i' •• 4 :■ 14 :: 11 ; 4 21: ■7.-27 - 7 2 "> 4 "• 7 16 0.000 15 8. 9 511 6
4 - 2 14 -. 14 4: ■ : .772 160.000 16 6 .:. 0 </■_
; r _ - . ... I i - ■; 1 ■ 7 : 1 1 2 5 5 54 1 r n . f: n c i7 . 9 7 3 2’ /•
^ 463T. - L/ - OL
O f ) III
Data File: ,/chem/5972hp60 . i/DFQ20303A60 . b/HH020303A60 . dReport Date: 04-Mar-2030 08:37
•yJAi. l SIC- CAL-AMT ON-COL
MASS RT EX? RT REX RT RESPONSE i NG) ( NG) SIMILARITY
•S2 4 - N i c r c a r.: I cr.e 13 8 r 4 .-id. . 1 . L' 7 0 . 434638 320.000 305.4 8655
h : 4 - -1 tr.: : rr. • 1 • T.-2Thypr.er.c 1 ns 14 532 14 5 32 ( :• . 9 04 ' 450216 320.000 327.4 8857 iA)
64 N •N: 7 rosea ipher.y-an ir.e 159 14 .633 1 4 c 3 3 • C . 9 11 604842 150.000 154.6 7663
7 7 14 . 584 14.534 • 1 .093.' 966239 160.000 154 . 7 3 724
6 4 4 -B:onopneoyi-phenylecher 245 15 . 276 15.276 U.SrUi 352443 160.000 153 . 6 9051
u" Hexac.-.ldrober.aer.e 234 15.395 15.395 : 0 . ;■ 5 0; 357119 160 . 000 155.1 9S36
Arrarme 2 00 15.547 15.547 'C.n-- 735 1 6 C.000 4 0.93 603 1 fH)
6 5 Peneacr. I orcpher.c 1 2 6 6 15.733 15.733 !C. s-u- 230411 320.000 321.1 9047(A!
7:- ?he:ianchrene 178 16 . 122 16.122 il.00 3 ■ 1460976 160.000 160.4 (A)
"■ A 178 16.207 15.207 a . 0 0 5 • 1470826 160.000 156.0
7 2 CarbazoLe 1 6 1 16.494 16.494 ■i 1 . 026 1094038 160.000 159.9 9258
7 3 Dbe: yir hzha lace X *1 it 1 7 035 17.086 (1.06 3'- 1746563 160.007 155.6 96 62
76 rlocrar.cnene ng-) 1 3 220 1 3 .220 (1.134) 1655770 160.000 159.9
n ns 13.4 r, C 1 8 . 4 4 C : C . 3 91) 343125 320.000 268 . 9 3 4 6 9
2 22 1 6 6 2 6 16.626 (0. 500 .1709263 160.00C 159 . 1
14 5 19.700 15.70? <0.953' 615064 160.000 153 . S 9121
2 5" 20.622 2 C . 6 2 2 1 0 . 9 9 7 i 664946 L60 . 000 151.3 7955
■■■■ 4 5 20.656 2 0 . 6 5 6 '0.?08i 1 3 6 9 6 0 6 160 . 000 16 2.3 9704(A)
r '. b--: a a:-.-, r.rae 22 c 2 0 6 5 7 20.690 : 1 . 0 0 0.1 1933405 160.000 160.2 (A’’
-■ 'Ihryeere 225 2 C . ^ 4 1 37.7q; t r g 1714299 1 60 . 000 160.5 (A)
S :• 2^.554 21.654 (9 . 92 0 2077607 160.000 164 . 3 (A)
-> 5 2 22.5CC 2:. sec (0.965) 1560505 160.000 167 . 6 (A)) — —
252 22.563 22 . 56b' ( C . 5 6 S ) 1557646 160.000 153.6
252 23.211 23.211 (10.9 9 6 } I 3 6 56 92 160.000 158 .4
■ vh: yyr-rr- 26.307 2S i 1 128; 1429387 160 . 000 155.9 6 956
• ' . - - 275 2 6 . 3 5 7 2 -j . 2 5 7 (1.131) 1 2 5 8 6 3 S 160.000 15 6.5 3 912
b-rrt u r.. ;::ry ,e:> 2 v •; 27.354 2 • . 2 t>4 '.1.165; 1133203 1 6 0.0 D 0 154.9 754 3
~}C Flag Legend
\ - Target compound detected xceeded maximum amount. ompound response manually integrated, aerator selected
but, quantitated amount
hit .an alternate compound
6 W
Dar.a "lie: .•'rntm.''5972ho60 . 1 '07020303^60 . t-,-HH020303H60 . d In iect ion l;=it.9: 03-HhF.'-200I 14:41 in=Tir'ijfnanr : 5'?72no60. i C^ent Barnol a . ID : 55TD160
Ound: Nijmo*
ipro 105
tarn
Ion 113.00: wrea: 67203 Height: 20272
ii
i1.4
1 'I'. 9 11.0 11.1 M l ri
ii.: 11.3 11.4 11.5
Ion 55.00: Mrea: O250O Haight: 32509
11.2 11.3 11.4 11.5
1 11.4
• n ;t r->jfn?nt : 5972ho60.i Ent Sample ID: S'STDlbd
Data F i let chern/j 972no6 0 . i / Dr" 02030 3*460 . b/HH020303Ob0 . dIniection Date: OD-H-'F.-2002 14;4l
:uncJ; nt razing* lumber; 1912-24-?
Ion 200.00: Hrea: 7*35 Height: -J45
u. o •
4 •
15.2 15.: 15.4 15.5
M i n15.C 15. 15.8 15.9 16.0
Ion 173.00: drea: Heignt: 0
15.8 15.9
47Z
15.7 15.8 15.9 16.0
Data File: ,/chem/B972hp6 0 . i/DF02 03 03 A60 . b/HM02 03 03A6 0 . dReport Date: 04-Mar-2030 12:46
Client Name:Sample Matrix: LIQUIDLab Smp Id: SSTDO8OVALLevel: LOWData Type: MS DATASpikeList File: 2ndSourcev2.spkSublist File: 2ndSourcev2.subMethod File: /chem/5972hp60 . i/D:Misc Info: 2ND SOURCE STANDARD
CompuChem
RECOVERY REPORT
Client SDG: DF020303A60 Fraction: SVClient Smp ID: SSTDO8OVAL Operator: 2319 SampleType: LCS Quant Type: ISTD
20303A60.b/827 0Cv6.m
SPIKE COMPOUNDAMOUNTADDEDNG
AMOUNTRECOVERED
NG
O,oRECOVERED LIMITS
13 N-Nitrosodimethyla 80.00 81.20 101.50 70-130; 14 Pyridine 80.00 77.15 96.44 70-130
15 Benzaldehyde 50.00 28.28 56.55* 70-13016 Phenol 80.00 83 . 85 104.81 70-13017 Bis(2-chloroethyl) 80.00 74.43 93.03 70-13018 2 -Chlorophenol 80.00 74.99 93.74 70-13019 1,3 - Diehlorobenzen 80.00 81.43 101.79 70-130
^ 20 1,4-Dichlorobenzen 80.00 80 . 85 101.06 70-130B 21 Benzyl alcohol 80.00 67.10 83.88 70-130^ 22 1,2-Dichlorobenzen 80 . 00 78.31 97.89 70-130
23 2-Methylphenol 80.00 79.25 99.06 70-13024 2,2' -oxybis(1- Ohio 8 0.00 77.98 97.47 70-13025 Acetoohenone 160.0 165.8 103.63 70-13027 4-Methvlphenol 80.00 78.86 98.57 70-1302 8 N-Nit ro s o-dl-N-p ro 8 0.00 81.38 101.72 70-13029 Hexachloroethane 80.00 82.64 103.30 70-1303 0 Nit rcbenzene 8 0.00 77.96 97.45 70-13031 isoDhcrone 8 0.00 84 . 10 105.13 70-1303 2 2 -Nitropnenol 8 0.00 78.17 97.71 70-1303 3 2 , 4 -Dimet hvlD’nenol 8 0.00 79.23 99.04 70-1303 4 B i s 2 - c h 1 oroe t hoxv 3 0.00 74.36 92.95 70-13035 2,4-Dichlorophenol 8 0.00 77.03 96.28 70-1303 6 1,2,4 -Trichloroben 8 C . 0 0 82 . 87 103.59 70-13037 Nachthalene 8 0.00 70.09 87.62 70-1303 6 4 -Chloroani!ine 3 0.0 0 76.03 ■ 95.10 70-1303 9 H e x a c h 1 c r c b u t a d i e n 8 0.00 8 5.53 106.92 70-1304 0 Caorolacta m 9 0.00 79.20 99.00 70-13041 4 - Chioro- 3-methvlp 3 0.00 74.58 93.22 70-1304 2 2 - Me t hv■naoht ha1 3 0.00 6 9.30 8 6.63 70-1304 3 1 -Methylnaphthalen 8 0.00 75.91 94.89 70-1304 4 Hexachlorocvclopen 80.00 70.14 87.67 70-1304 5 2,4,6 -Trichicrophe 8 0.00 78.99 98.74 70-1304 ■- 2,4,5 -Trichlordphe 8 0.00 74 . 04 92.55 7 0 - 13 0
Data File: /chem/5972hp60:1/DF020303A50.b/HM020303A60.dReport Dare: 04-Mar-2030 12:46
¥----------------- ----------
SPIKE COMPOUNDAMOUNTADDEDNG
AMOUNTRECOVERED
NG
o,0RECOVERED LIMITS
47 1,1'-Biphenyl 80.00 80.19 100.23 70-13048 2-Chloronaphthalen 80.00 95.81 119.76 70-13049 2-Nitroaniline 80.00 63 . 13 78.91 70 -1_> 050 Dimethylphthalate 801 00 73.14 91.43 70-13051 2,6-Dinitrotoluene 80.00 82.28 102.85 70-13052 Acenaphthylene 80.00 68.60 55.75 70-13053 3-Nitroaniline 80.00 66.74 83 .^3 70-13054 Acenaphthene 80.00 71.32 89.15 70-13055 2,4 -Dinit.rophenol 80.00 62.83 78.54 70-13056 4 -Nitrophenol 80.00 79.40 99.25 70-13057 2,4-Dinicrotoluene 80.00 78.78 98.47 70-13058 Dibenzofuran 80.00 69.55 86.93 70-13059 Diethylphthalate 80.00 73.05 91.31 70-13060 4 -Chloropheny1-phe 80.00 65.67 82.08 70-13061 Fluorene 80.00 67.32 84.15 70-13062 4-Nitroaniline 80.00 64.91 81.14 70-13063 4,6-Dinitro-2-meth 80.00 69.69 87.11 70-13064 N-Nitrosodiphenyla 200.0 165.5 82.76 70-13065 1,2-Diphenylhydraz 80.00 76.15 95.18 70-13066 4-Bromophenyl-phen 80.00 61.74 77.17 70-13067 Hexachlorobenzene 80.00 75.38 94.23 70-13068 Atrazine 80.00 166.9 208.67* 70-13069 Pentachlorophenol 80.00 66 . 91 83.64 70-130
™ 70 Phenanthrene 80.00 65.20 81.50 70-13071 Anthracene 80.00 68.40 85.50 70-13072 Carbazole 80.00 76.06 95 . 08 70-13073 Di-n-butylphthalat 80.00 71.62 89.52 70-13074 Fluoranthene 80.00 67.06 83 . 82 70-13075 Benzidine 160.0 112.4 70.25 70-13076 Pyrene 80.00 71.40 89.24 70-1307 7 Buty1benzv1phtha1a 80.00 79.27 99.08 70-13078 3,3'-Dichlorobenzi 80.00 68.65 85.81 70-13079 bis(2-ethvlhexyl)P 80.00 75.57 94.46 70-13080 Benzo(a)anthracene 80 . 00 71.68 89.60 70-13081 Chrvsene 3 0.00 73 . 16 91.45 70-130 |82 Di-n-octvlphthalat 8 0.00 73.88 92.35 70-13083 Benzo(b;fluoranthe 8 0.00 68.67 85.84 70-13084 Benzo(k)£lucranthe 30.00 80.67 100.84 70-1303 5 Benzo (a ) pvrer.e 30.00 71.57 8 9.46 70-1306 6 I n.deno (1,2,3- cd) dv 3 0.00 76.51 95.64 70-13087 Dibenzo(a,h)anthra 8 0 . 0 C 72.00 90.00 70-13038 Benzo!g,h,i;peryle 8 0.0 0 71.73 8 9.66 70-130
47-
<:tlO‘sb)
Data File: /chen/5972hp60. i/DF020303A60.b/HH020303H60.d
Date : 03-M8R-2002 18:01
Client ID: SSTD080VAL
Sample Info: SSTD080VAL:2319
Volume Injected (uL); 1.0
Column phase: J8.W DB-5.625
I ns tr-ument; 5972hpb0* i■-O
Is-
Operator: 2319
Column diameter: 0,32
Data Fi le; 7chem/5972hp60. i/DF020303660.b.'HM020.7n7A60,rj
Date : 03-MAR-2002 18:01
Client ID: SSTD080VAL
Sample Info: SSTD030VAL;2319
Volume Injected (uL>: 1.0
Column phase: J&W DB-5.625
Instrument: 5972hp60.i
Operator; 2319
Column diameter: 0.32
2.0-
1.9-
1.8-
1.7-
1.6-' 1.6- 1.4-
1.3-
1.2- - 1.1-
1.0-
7chem/5972hp60.i/DF0203C3A60.b/HM020303A60.d (Part 2 of 21
+<MtH■O
I•i5i/lT)
LJ
I
47b
Data File: /chem / 5 9 7 2hp6 0 . i /DFO 2 0 3 G 3 A6 G . b/'HMO 20303 AGO .d Report Date: 04-Mar-2030 12:46
CompuChem
Data file Lab Smp Id:Inj Date : Operator Smp Info :Misc Info : Comment : Method :Meth Date :Cal Date :Als bottle:Dil Factor: Integrator: Target Version: Processing Host
Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020303A60.b/HM0 2 03 03A6 0.d SSTD08OVAL Client Smp ID: SSTD080VAI03-MAR- 2 0 0 2 18:012319 Inst ID: 5972hp60.iSSTD0 8 OVAL:2319 2ND SOURCE STANDARD
,/chem/5 972hp6 0 . i/DFO2 03 0 3A6 0 .b/82 70Cv6 .m 04-Mar-2030 08:41 mikhael Quant Type: 0 3-MAR- 2 0 0 2 17:20 8
1.00000 HP RTE
3 . 50einstein
I STDCal File: HL020303A60.d QC Sample: LCS
Compound Sublist: 2ndSourcev2.sub
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
^ DF 1.00000 Dilution FactorA1000.00000 Volume of final extract (uL)
Vo' 1000.00000 Volume of sample extracted (mL)Vi 1.00000 Volume injected (uL)
Cpnd Variable Local Compound Variable
CONCENTRATIONS
-•jiv- 0N-COLUMN FINAL
iitpc;::'..:;' AT £yp RT RESPONSE J NO) ( ug/L) SIMILARITY
e: : 7 8 2 04
~ C i ^ 1
40.0400
: -‘.4 : • . •;i 1 5 j 0 4 4 4 0 . 0 2 0 0
r--....... . • J .
• 1’ ", : ■/. 7 = - ■ ■ D /i: 301900 40 . oono
- :: . -■e 2- ■: il :: a ■ : . 255315 40.0000
: ? N • A : i r ...ir. .. .* : c 1 22: 235703 21.2012 '4 1 .20 02 3 5
7 • 7 312555 77 . 14P-4 77.1 5 0 5 12
■- ' - :--L 7 35293 24.2753 23.23 8585(Hi
1 V . ..a:. 2 2 : J O 4 7 55.S551 53.83
" •: •••5-: 1 5 9 4 0 7 7 4 9 3 9 4 7i c. 0 4 5 8
- : :■ ■ 227442 51 .429 '3 51.43
- : ■ - . d: ; ; . ■ 2:4; 5 5 ' . 3 4 p ^ 8 C . 3 j
47/
Data File: /chem/5 972hp6 0 . i/DF02 03 03A60 . b,/HM02 03 03 A60 . dReport Date: 04-Mar-2030 12:46
..cnoo'jr.as
21 Benzyl alcohol
24 2.2'-"xynis:1-Chlcropropane)
2 H-xacn . z-tcez l-.cc.e
• ? N'.z I'oc-enzenr
lb 2 , 4 - Z: : h. o: z p h •= n o 1
1 “ Naphtha : ene
2UANT SI
MASS
10S
14 6
108 '
45
105
108/
*70,
139
CONCENTRATIONS
ON-COLUMN FINAL
107
:42
142
62.3313
79.4315
7 5 . 7 7 o j
5 3.545 C
72.0457
4 5 b — ;•
/1
o ; i1.? '
: 4 6 2 5 a
222311
75 1454
61 . 7350
75 . 331 7
166.935
7 9.40
7 5.73
69.55
. . 91
75 . 15
61 .74
E i EX? F.T RE L RT RESPONSE ( NG) ; ug/Li SIMILARITY
3 .439 3 .441 : 1 . 029 1 91670 67.1030 67 . 10
S .473 3.475 ! 2 t > 219032 73 .3150 78 . 31
5 . 559 3.627 ■. 1 056 ;■ 136784 79.2517 79.25
3.659- 3 .661 ; 1 0561 207069 77.9769 77 . 98 775C
8.679 3 8 c 4 11 03 3 ' 513702 165 . 913 16 5.3 8 7 6 2 (A}
- 3.696 3.393 ! 1 06 5'. 172963 78.856“ 78 . 86
/ 6 . 895 3.831 1 085) 129545 31 . 3762 81.38 0 (M)
9 . 04 b ? . 0 3 3 : 1 103 i 102461 62.64 28 92 . 64 32 32
3.167 d ' z. 2 : 0 884 : 198353 77.9580 77 . 96 53 58
9 . 573 c z j (0 923.1 336961 34.103C 94 . 10 3 .1 7
9 . 708 v .69? (0 936 ) 9321 1 73 . 1705 78.17 3293
9.793 ; . 795 ( 0 94 5) 1 20778 79.2290 79.23 8 1 9 6
9 . 962 3 . 94 7 (0 961) 179367 74 . 3582 74 . 36 8 7 a 9
10.121 A 116 . 0 577) 1'72S03 77.0278 77.03
1 0 . 2 6 4 10.251 990) 220863 S2.8744 82.87
10.402 : 0.357 ,1 0 0 3 1 427348 70.0949 70.09 9 14 0
20.503 i 0 . ~t 8 3 013) 195524 76.0821 76.08 8 I 3
10.621 1 0 . 607 ( 024 ) 173294 35.5323 85.53 916 3
ii . 112 1 1 . 063 1 0 7 2 ) 35157 79 . 1997 79.20 8 6 6 3
11.366 ::. 2 51 1 096 ) 139169 74 . 5772 74 . 58 84 56
11.602 11 . 5 0 c- • 11 9 • 314929 59 . 3022 69.30
11.775 11.7-4 . 125 : 278964 75.9148 75 . 91
11.3 :■ o 11.575. : r iss: 123895 70:1352 70.14 8 94 0
-.2.11 0 1 2 . . 3 5 (0 902 ; 133103 73 . 9886 78 . 99
12. 173 12.150 :o 0 27 • 1 358 2 5 74 . 0372 74 . 04
12.432 12.417 ; ■326 443999 80. 1864 30.19 y 07
12.466 47; : r, 52 8 ) 454303 95.3117 95.31
12.635 :-37 1 0 94 1: 116695 6 3 . 1289 63 . 13 39 9 2
12.973 ->55 56-5 > 456007 73 . 14 11 73 . 14 7-h?
1 3 . O'1 5 : ■ ■ 0 574 : 1 9 2 56 32.2811 92 .28 “y.-i12.15 3 '■ 0 552; 52.3 74 5 63.6016 6S . 50 :< 4 ■? 113.34 2 1 -• 3 4 4 ■ c 555 ■ ‘■■4 132 56.7437 6 6.74 - 2 9 9
0 (M'
-"56
\
:? 1 ■) t
jn:
5 3 06
5 1 9 :• < AF.'
LT/
t-
47o
j L
Data File: /chem/5972hp60.1/DF020303A60.b/HM020303A60.dReport Date: 04-Mar-2030 12:46
CONCENTRATIONS
:uant sig ON-COLUMN FINAL
-Ttpour.os MASS RT CA? .-\T RSL RT RESPONSE ( NG) ( ug/L) SIMILARITY
2 o r 1 6 . 7 ? 1 15.733 ,0.579. 52702 66.9126 66 . 91 0 fM) \
X ,v - 17 8 15.103 lo 105 (1.002) 645141. 65.1990 65.20
7 1 Ar. d h racer.3 176 16.204 16 189 ■1.008; 681281 68.3982 6 8.40
’’I Zazzazz ie 15 7 15.475 15 .477 :i.025: 5576SS 76.0649 76 . 06 0 7 02
7 I 0: - r. - r-u 2 y p.-;2 na lace 14 6 i7.06 n 17.06? .1.062! 925454 71. 6150 ■7 r q g Q P - 3
74 c iccrar.2her.re 202 1S . 2 01 15 2 0 ~ (1 . 13 3 ) 756615 67.0598 6 7.06
” Berziaine 164 16 .437 10.423 ■0.891) 223014 112.396 112.4 853 1
X Pyr-r.-X 2 02 18 . 6 C 7 1 6 . 6 C r 7 . 999) 773252 71.3956 71.40
Brry Icerzy'.zh: ha ; are 14 6 19.706 15 . 708 ? . 953) 443338 79.2673 .21 9191
1 8 2 , 2 ' •L,:cr.:orcben::dir.e 252 20.620 20.622 i 0.997) 293202 68.6520 6 8.65 7455
n'? ois 2 - ec hyihexy 1 > Fhz’r.a laze 14 S 20.654 20.656 ■ t .998) 590309 75.5704 75.57 9633
i'j Benzclaiamihracene 2 2 6 20.671 2 C.673 ■ 0. 999) 774575 71.6823 71.68
1 Chrysene 226 20.738 20.723 (1.002) 712495 73 . 1617 73 16
-■2 Di - n - C'C 2 y i p)'i2 ha 1 a c e 14 9 21.652 21.654 (0.929) 549890 73.8796 73.88
= i 2enzo:b; : 1 zozar.z here 252 22.498 22.483 (0.965) 756094 6 8 . 6 6 96 60 67
252 22.546 22 . 534 1 0.9 0 7 J 603084 80.6696 80.67
-5 Bcrze a zyrer- "| c o 23.191 2 ^ n 7 ■0.995; 630629 71.5657 71 5^
"■■■■ 1.2.1 pyrer- 2 7 5 26.237 26 .272 ; 1.12 e) 719409 76.5085 76.51 om; j
Ciherrc. a . z a r: h : acer-u 2 7 5 26 . 3 3S 26 323 (1.130) 599259 71.9967 7 2.00 9907
- - 5 --rz r -i. h. . r-rr-.-lmro 2 7 4 27.201 27.156 ; 1.16 7) 568354 71 . 7271 71.79 7678
lag Legend
A - Target compound detected but, quantitated amount exceeded maximum amount..
R - Spike/Surrogate failed recovery limits.M - Compound response manually integrated.
C a .<-V
1 ■ U V. (_
47c
j ate -lie: ■ * injection Date: 0! Instrument: 5972n: Client Sample ID:
1‘71'nrcCO. :/D^020: -MHF.-2002 18:01 60 . iS'STDOSO'vhL
i/Hm02Ci203*60 . a
jocund: H-Nitrg*o-di-N-propu1 am:ne Mumnen; 521-54-7
lor. 70.00: Hrea: 129p*45 Heignt: /c58*4
Tu<00
co
4.4-
4 . 0
1 .2-
8-
4-
.45 8.50 8.55 6.50 8.55 8. 6.75 8.80 8.05 8.90 8.95 9.00 9.05 9.10 9.15 9.20 9.25 9.30. 9.35
___ _______ Min ________ ________________________________________I on 130.00: nrea: Height: 0
9 . 'jO 9.05 9.10 9.15 9.20 9.25 9. jO 9.35
48Gr. 00 9.05 9.10 9.15 9.20 9.25 9.30 9.35
Iniectior: Date: OD-MwP-T'uuT 15; instrument: :59"'Dnp60.i I-ient Sample ID: SSTDOSOVAl
loounc: Pent sen loropnenol P Number-: 67-36-5
2.0-
1.3-
1 .6-
1 4-
0 . p H M020 30 3A 6 0. a
Ion 266.00: Area: 52/02 Height: 21533
mrv
IP
0.4-
15.35 II: i5.35 ’5.40 15.45 15.50 15.55 15.60 15.65 15.70 15.75 15.60 15.85 15.90 15.95 16.00 16.05 16.10 16.15 16.20 |
____________________ Min jIon 263.00: Area: 0 Height: 0
I
15.90 IS 16.00 16.05 16.10 16.15 16.20
481
15.6-j li'.'O !5.75 ! 5.60 15.85 15.90 15.95 16.00 16.05 16.10 16.15 16.20■; n
J-=ir.ri Fill?: jn;:>60 . : .'DF* 1in.lecticr. Dst-r; 03-MhF'-2002 18 In* fument: 5972no60 . 1
nr •Sample ID: 55tD080'./hl
10 unci : 4-n 11 rcipn*?r,cMump*1': iOO-92-7
HMOI'OjOj^qU . d
3.4-
lon 109.00: 90060 Height: ji*4787
1 . c-
1 .4 •
1 n !
0.3- ;
0.6- !
0.0 1 ;5 13.40 i 3.45 13.50 13.55 13.60 13.65 13.70 13.75 13.30 13.35 13.90 13.95 14.00 14.05 14.10 14.15
_______________________________ Min___________________________________________Ion 65.00: 0 Haight: 0
■D
l
55
Ion 13
35 13.9' 95 14.U0 14.05 14 14 . 15
4847. J = ; 3.75 13. £0 13.63 13.70 13.75 13.801 13.85 13.90 13.95 15.00 14.05 14.10 14.15
"..iect:on Dare: .;:7-mwF-2’002 Ic r.-= r rijrrienr : 5977'hp60 . : lient Semole ID: 557D0S0,,"'hL
O'jno: : ndeno c 1, 2. 3-c a ) pij rene nwr: 193-39-5
■•HMm1,03036>10.cI
Ion 276.00: Area: 719409 Height: 13*4901
03
Tr-j
I
. 30 29.89 29.9" 29.99 2b. 00 2b .05 26.10 26.15 26.20 26.25 26.30 26.35 26.40 26.45 26.50 26.55 26.60 26.65 26.70 26.75______ ___________ H i n ________________________________________
Ion loS.OO: Height: 0
l
'5 26.30 2>i . :3 . 40 26.45 26.50 26.55 26.60 26.65 26.70 26.75
48
_0 . '1*5 !•: . 10 2. 15 ii . 20 26.2o _'6 . j,0 26.33 26.40 26.45 26.50 26.55 26.60 26.65 26.70 26.75
COMPUCHEM ;t division ofLibcity Analytical Corp DATE ^ /
<;C7MS SEMIVOLATILE RUN LOG[UjC. INITIAL TIME Of TUNE___ /
TIME TUNE EXPIRES____.. / 3 A__
SIIII'T/S(A) .........(C).
LINKER /MIN HOP V £ ;'u
—
uEiE
X
iroPREVEN TIVE MAINTENANCE
C
T1DFILE NAME tE DATE TIME CLIENT ID# CASE/S DG# AMOUNT
INJECTEDCHEMIST COMMHNTS(E rc )/DlSI’OSn iunzcc )
oo^ -1 "Drs n Sc !■> A/cj z 5 O 'a / 7 AZ hPrf/'
.0 E • li 1 ‘l-- / ______________ _
\ 1 IL- l- ('. \> if tj / / / / C- y / *5 SfT)(, r\ t, ■ ■r s’7 0 5 /1 i'llh.v'c '5o s /Cn / / / /Hf \ 5 fb /A, t- s‘> e 2 j .
1 j-iL. n. Wi> .Vo z / / / S 7 / UVt’/o-p K ) u f\ ...
|~/jo <i 2 A Cu z / / l b u 1V ,> u . - ;_______________
hKKo l 0- Sc'1, Aoz / / ! l U i Zf fbc/r.
v 5 y c' 1 ‘/ -....... ..............
/ 'll. ti i C K S A6 L’ z / / i 7 Zo~ Zv 7
— s' 7 s <: c-
s /"/ A/o Z 1, Zv 5 /Vc / G________ 1 5 v l s sTf-.rA. . \/7 l\/ \ /
C- S~ / -■ ' A'_______________________
«) / /
10 / / H P <?az...........
11 / /
12 / /
13 / /
M / /
/15 /
10 / /
17 / / a/ ;
18 / / CT1 r
—
i
—10 / /
20 / /
21
■>2 / /
23 / /
/ /
Std. ID ft
I ,Ol it
Tune
a ‘j s
Analytical int. Std.
dJL&_
Column Type
[ ’■ f K
l
X1 s
SUPERVISOR APPROVAI
DATE o\‘6?1.0L'
. V'fepczz
~k C 'j L M/ ■ •*. V.) lie presence oj (lie Chemist's employee II) number. »>i signal me. on 1 his run |o^» attests that sii i*.I compliance \Mth die incdmd *■ M d’ ha-
occurred. Any SOP deviations require documentation hy the responsible chemist together with the chemist's initials and the initials o| du
lab supervisor and a OA department representative, si^ni tyiny approval ofthe deviation I-’’I l/,(l
FORM 6SEMIVOLATILE INITIAL CALIBRATION DATA
Lab Name: COMPUCHEM Contract: 8270C
k Lab Code: LIBRTY Case No. SAS No.: SDG No.: QE1877
Instrument ID: 5972HP64 Calibration Date (s) : 03/10/02 03/10/02
Column: RTX-5 ID: 0.32 (mm) Calibration Time(s): 1416 1723
LAB FILE ID: RF10 :
RF80 : HG020310A64 RF120
HI020310A64 RF20:
: HJ02 0310A6 4RF16 0
HK020310A64 RF50
: HH02 0310A64
: HL020310A64
1
COMPOUND
1
RF10 |
I .
1
RF2 0 |
1
1
RF5 0 |
I
1
RF8 0 |
|
1
RF120 |
|RF160
Phenol [ 1 . 579| 1.514 | 1.434 | 1.441| 1.413| 1 . 339|
Bis ( 2-chloroethyl)ether | 1.055 1.007 0.950 1 0.975 0 . 9631 0.974
2-Chlorophenol 1 1.396 1.360 1.341 1.335 1.327| 1.305
1,3-Dichlorobenzene | 1.658| 1.569| 1.529| 1.536| 1.506 | 1.467|
1, 4-Dichlorobenzene | 1.6511.616 j 1.549| 1.572| 1.492 j
1.469
1, 2-Dichlorobenzene [ 1.631 1.5691.520 j 1.509 j
1.490 1.483|
2-Methylphenol | 1.242 1.189| 1.170 1.116 1.156| 1.1582,2'-oxybis(l-Chloropropane)| 1.919|
1.861j 1.803] 1.783 | 1.776| 1.797|
4-Methylphenol | 1.361 1.3171.245 j 1.258 j
1.247 1.215|
N-Nitroso-di-N-propvlamine | 0.884 | 0.818| 0.777 ■0.767 0.787 | 0.784Hexachloroethane I 0.874 | 0.820 0.802 0.804 | 0.782 0.757|
Nitrobenzene | 0.370 j 0.340 j 0.338] 0.342 | 0.320 j 0.329]
Isophorone I 0.741 0.680 0.669| 0.665| 0.637 0.6462-Nitrophenol | 0.239 0.216 0.214 0.212 0.206 0.2022,4 -Dimethvlphenol | 0.355| 0.326 ] 0.319 0.312 0.304 0.302kis ( 2-chloroethoxv)methane ] 0.451| 0.413 | 0.399 j 0.399| 0.379| 0.370|
W, 4-Dichlorophenol | 0.3540.331j 0.331| 0.334 0.320| 0.317]
1, 2 , 4-Trichlorobenzene | 0.429 0.3960.393 j 0.380| 0.366 | 0.354
Naphthalene | 1.637 | 1.491 1.454] 1.423 1.337] 1.332
4 - Chioroari11ine 0.513] 0.461| 0.460 0.463| 0.440] 0.436Hexachlorobutadiene | 0.291 0.274 0.266
0.264 j0.253 0.247|
4-Chloro-3-methylphenol | 0.413 0 . 371 | 0.357] 0.368 0.350| 0.3492-Methylnaphthalene ] 0.814 0 . 722| 0.729 j 0.713 | 0.686 0.682Hexacnlorocyclopentadiene ] 0.408] 0.377] 0.394 | 0.410| 0.394| 0.395|
2 , 4,6-Trichlorophenol | 0.430 0.414 0.4040.415 j
0.384 0.3942 , 4,5 -Trichlorophenol | 0.470 0.424 0.434 0.437| 0.413 0.4122-Chloronaphthalene | 1.123| 1.100 1 . 027 | 1.Oil| 0.945 0 . 9512-Nitroanilme | 0.397 | 0 . 372 j
0.364 | 0.3651 0.356 | 0.350 |
Dimethylphthalate | 1.415 1.320] 1.254 1.221 1.167| 1.1452,6-Dinitrotoluene | 0.372] 0.348| 0.339 0.343 0.338 0.330Acenaphthvlene j 2.727] 2 . 588 j
2.429 2.373] 2.208] 2 . 127|
3-Nitroanilme 0.403] 0 . 3 6 6 | 0.356] 0.359| 0 . 358 | 0.350 |
Acenaphthene j 1.803; 1.659] 1 . 584 1.548 1.441] 1 . 319|
2 , 4 - Dmitrophenoi | 0.054 0.048 0.060 0.066 | 0.068 0.0694-Nit ropnenol | 0.231] 0.204 j 0.212 j 0.225] 0.221| 0.2101
2,4-Dinitrotoluene ] 0 . 552 i 0 . 501 | 0.493 | 0.478] 0.488 0.488]Dibenzofuran j 1.845] 1.699 1.608 1.560] 1 . 502 1.471Diethy1phtha la c e ! 1.706; 1.563 1.480 1.417| 1.394] 1.3434 -Ch1oropheny1-phenylecher 1 0 . 7S2 ] 0.723 j
0.699] 0.686 | 0.648| 0.622 |
Fluorene i 2.175] 2.032] 1.883]1.782 j
1.639 1.6024 - r.:i t roam 1 ine ] 0.408] 0 . 3 6 1 j 0.384] 0.373 0.375 0.3794 , 6 - Dim t ro - 2 - methylphenol 0 . 1 b | ■ 0.145 0.164 0 . 168 0.167 0.160]:: - Nit rosodipheny 1 amine 1 .0.513] 0 . 448 | 0.434] 0.420] 0.408] 0 . 391|
Bromophenyl-phenylether j 0.247]
|0.220
!
0.218]
10.203
10.193
1
0.192 |
W5FORM VI SV
FORM 6SEMIVOLATILE INITIAL CALIBRATION DATA
Lab Name: COMPUCHEM Contract: 8270C
Lab Code: LIBRTY Case No.: SAS No.: SDG No.: QE1877
Instrument ID: 5972HP64 Calibration Date (s) :: 03/10/02 03/10/02
Column: RTX-5 ID: 0.32 (mm) Calibration Time(s) : 1416 1723
LAB FILE ID: RF10 :
RF80: HG020 310A64 RF120
HI 02 0310A6 4 RF20:
HJ02 0 310A6 4RF16 0
HK020310A64
HH020310A64
RF5 O': HL020310A64
!
I COMPOUND
1
1
1
1
RF10 !
1
1 I
RF2 0 | RF5 0 1
1 . !
1
RF8 0 )
|
1
RF120 |
|
RF160 j
j-------------------- =------ :|Hexachlorobenzene
11----------- |
0.311|-------- I-----0.282|
10.268 |
----------- |0.247|
--------- | _0.233 | 0.224
|Pentachlorophenol 1 0.192 | 0.1660.173 j 0.176 j 0.169 j
0.166IPhenanthrene 1 1.845 j 1.623 j 1.507 j 1.396 j 1.299| 1.260|
|Anthracene 1 1.889[ 1.663 j1.565 1.431| 1.296 j 1.232 |
|Carbazole 1 1.171 1.044 | 1.018| 0.972| 0.9040.865 j
|Di-n-butvlphthalate 1 1.802| 1.598 j1.523 1.434 1.312] 1.263
I Fluoranthene 1 2.061j 1.816 j 1 . 769| 1.626) 1.535) 1.488)
j Pyrene 1 2 . 264 2 . 164 1.994 |1.818 j
1.679 1.590
I Butvlbenzvlphthalate 1 0.878| 0.819| 0.782 0.757| 0.694 | 0.689|
!3 , 3' -Dichiorobenzidine ... 1 0.629 0.575 0.554 | 0.524 j0.495
0.475 j
Ibis(2-ethylhexyliPhthalate I
1Benzo(a)anthracene !
1.337[
2.085 |
1.225)
1.872 |
1.19 3 |
1.798
1.114 |
1.716
1.038|
1.569
0 . 980|
1.513iChrysene 1 1 . 958 1.817| 1.717| 1.618| 1.451| 1.389iDi-n-octvlphthalate 1 2.469) 2.330| 2.364 | 2.286 j 2.131] 2.004j^enzo(b)fluoranthene 1 2.548) 2.359) 2.033 j 1.867 j 2.156| 1.909|Benzo(k)fluoranthene 1 2.014 1.939 2.156 2.160 1.642| 1.720^en:o (a) pyrene 1 1.897 1.745 1.736 1.683| 1.602 j
1.535|Indeno(1,2,3 -cd)pyrene 1 1.379) 1.302 1.264 1.178 1.155 1.090|
!Dibenzo(a,h)anthracene 11
1.675) 1.568 1.541 1.438 1.405 1.314)
j Benzo(q,h,i)pervlene 1 1.710 1 . 653| 1 . 618| 1 . 504 | 1.465 1.421]
1 2 -Fluorophenol 1 1.361 1.316
=====1
1.263 | 1.286 1.287 1.2771 Phenol-dS t 1.339) 1 . 758| 1.661| 1.665] 1.618) 1.607 )
! Nitrobenzene-d5 1 0.458) 0.436 0.442 0.429 0.419| 0.413 |
!2 -Fluorobiphen\T 11 1.520 1.422 | 1.334 1.312 | 1 . 210| 1.198]
: 2,4,6 -Tribromophenol 1 0.452 0.415] 0.412 0.402 0.375) 0.360Terphenyl-d!4 1
11.272) 1.158) 1.097) 1.010| 0.923] 0.893]
1 ) 1 1 1 1 1
FORM VI SV
FORM 6SEMIVOLATILE INITIAL CALIBRATION DATA
Lab Name: COMPUCHEM Contract: 8270C
Lab Code: LIBRTY Case No.: SAS No.: SDG No.: QE1877
Instrument ID: 5972HP64 Calibration Date(s) : 03/10/02 03/10/02
Column: RTX-5 ID: 0.32 (mm) Calibration Time(s): 1416 1723
1 |COEFFICENT| %RSD MAX %RSD ]
COMPOUND |CURVE
1
1 A1 |
| |
OR R~21
OR R~2 j
Phenol|------| AVRG | 1.45344780|
----------- |5.734 | 30.000 j
Bis(2 -chloroethvl)etherj AVRG 1 0.98746534 | 3 . 861j 50.000 j
2-Chlorophenol [ AVRG 1 . 344051842.321j
50.000
1, 3-Dichlorobenzene AVRG | 1.54422209 4.234 50.000|
1 , 4-Dichiorobenzene AVRG 1.55817949| 4 . 497| 30.000 j
1,2-Dichiorobenzene | AVRG | 1.53368056| 3.687 j 50.000 j
2-Methylphenol AVRG | 1.17202670 3.584 | 50.000
2,2'-oxybis(1-Chloropropane) AVRG 1.82351039| 3.052 j 50.000|
4-Methylphenol | AVRG |1.27392635 j 4.258 j 50.000 j
N-Nitroso-di-N-propylamine | AVRG jo.80287373 ! 5.402 j 50.000 j
Hexachioroethane AVRG 0.80639443 | 4.884 | 50.000 |
Nitrobenzene | AVRG 0.339861264.958 j 50.000 j
Isophoronej AVRG |0.67295879 5.485 j 50.000 j
2 -Nitrophenol AVRG 0.21456245 6.129 30.000
2,4-DimethvTphenol | AVRG |0.31978990| 6.156 | 50.000
£is (2 -chloroethoxy)methane AVRG [0.40165650 7.124 | 50.000k, 4-Dichlorophenol AVRG 0.33121894
3.934 j30.000
^,2,4- Tn chlorobenzene 1 AVRG 0.386223186.812 j
50.000
Naphthalene | AVRG j1.44 570691j 7.832 j 50.000 j
4 -Chloroanilme AVRG |0.46229995 | 5.921 50.000
Hexachiorobutadiene AVRGjo.26598517J
5.821 30.000
4 - Chioro-3 - methvlphenol AVRG [0.36798386 6 . 505 30.000|
2-Methvlnaphthalene | AVRG 0.72460592 6 . 616 | 50.000 j
Hexachiorocyclopentadiene AVRG 0.396223183 . 024 j 50.000 j
2,4,6-Trichlorophenol AVRG 0.40708278 [ 4 . 043 | 30.0002,4,5-Trichlorophenol | AVRG |0.43186681 4 . 979 j
50.0002 -Chloronaphtha 1ene
j AVRG1 1.02624724 [ 7 . 187 j 50.000 j
2 - Hitroam 1 ine ! AVRG 10.36736680 4.463 50.000Dimethvlphtha laze | AVRG 1 1.25397872 1 8.035 50.0002 , 6 - Dimtrotoluene | AVRG [0.34504949| 4 . 154 | 50.000Acenaphthylene | AVRG i2.40886410 1 9.377 j
50.000|
3 - Hi t roam line | AVRG 1 0 . 36 5264 00; 5.215 50.000 |
A.cenaphther.e | AVRG [ 1 . 55908773 10.804 30.000|
2,4-Dinitrophenol | AVRG |0.06102654j 13.919) 50.000 j
4-Nitrophenol 1 AVRG jo.21725178)4.688 50.000
2 , 4 - Dimtrotoluene | AVRG j 0. 50009479! 5 . 323 j 50.000 |
Dibenzofuran i AVRG i 1 . 61418043 [ 8.619[ 50.000Dle t hy1ph t ha 1a t e | AVRG j 1 . 48402924 [ 8.933 50.0004 -Ch1orophenyl-phenylether | AVRG |0.6933645S! 8.184 50.000|
riuorene i AVRG :i.35220534] 12.078 j 50.000 j
4 - Hi t roam 1 me 1 AVRG 0.38018555) 4.098 50.0004 , 5 -Dmitro- 2 - me t hvlphenol : v R G !0.16193990 | 5 . 334 | 50.000N-IJit rosod ip he nvl amine ; AVRG
i 0.43553311 j 9.834 j30.000
a - 3romopheny1 -pheny1ether i ’ T, V r.1 j ! 0.212194951
i
9 . 839 j
1
5 0.0 0 0 j
.1
48/FORM VI SV
FORM 6
SEMIVOLATILE INITIAL CALIBRATION DATA
Lab Name: COMPUCHEM Contract: 8270C
Lab Code: LIBRTY Case No.: SAS No.: SDG No.: QE1877
Instrument ID: 5972HP64 Calibration Date (s) :: 03/10/02 03/10/02
Column: RTX-5 ID: 0.32 (mm) Calibration Time(s) : 1416 1723
1 |COEFFICENT| %RSD | MAX %RSD |
COMPOUND |CURVE
1
A1 | OR R~2 OR R"2 |
Hexachlorobenzene1------| AVRG
1------------ 1 -| 0.26088302|
----------- 112.450| 50.000
Pentachlorophenol AVRG |0.17365523] 5.747 30.000
Phenanthrene | AVRG j1.48848182 | 14.776 | 50.000 j
Anthracene AVRG 1.5127839116.183 j 50.000 j
Carbazole | AVRG 0.9956973210.968 j 50.000 j
Di - n-butylphthalate AVRG |1.48863045| 13.305 50.000
Fluoranthene | AVRG j1.71594315| 12.345 j 30.000 j
Pvrene | AVRG 1.91825998 13.990| 50.000|
Butylbenzylphthalate AVRG |0.76979770| 9.502 j 50.000 j
3,3'-Dichlorobenzidine AVRG 0.54217088 10.400 50.000
bis(2-ethylhexvl)Phthalate | AVRGj 1.14804654 j 11.372 j 50.000 j
Benzo (a)ianthracene AVRGj1.75898011 |
11.907 50.000|
Chrvsene AVRG 1.65827586 13.08450.000 j
Di -n-octvlphthalate AVRG 2.26401888 7.452| 30.000
Benzo(b)fluoranthenej AVRG
2.14529204 | 12 . 400| 50.000 |
£en:o(k)fluoranthene | AVRG1.93865787 j 11.259 j
50.000Benzo(a)pyrene AVRG |1.69970922 7.409 30.000|^ndeno(1,2,3-cd)pvrene [ AVRG j1.22817824 | 8 . 660| 50.000|
Dibenzo(a,h)anthracene AVRG 1.49016952 | 8.687 j50.000
Benzo(q,h,l)pervlene AVRG|1.56267939 j 7.400 j
50.000
2 -Fluoroohenol
!=====
| AVRG
l==========l=
|1.29838103 j
=========1
2.723 | 50.000|
Phenol -d5 J AVRG 1.69126416 5.31650.000 j
Nit roben z ene-d5 AVRG 0.43289678 3.813 50.000
2 - rluorofcipnenvi AVRG 1.33263082 9.277| 50.0002,4,6 -Tribromophenol ] AVRG |0.40272334] 8.039| 50.000|
Terphenvl-dl4 AVRG 11.05889874 13.697 j50.000
I ! 1 ]
Average %RSD test result.
Calculate Average %RSD: 7.923093319
Maximum 1 Average %RSD: 15.00000000
Mote : Passes Average %P.SD Test.
48 c
FORM VI SV
CxlO^'t
Dfl'-a PiJ^i .•’chem/5972h|o64. j25F020310A64.b/H1020310A64 .d
Date : 10-MAR-2002 15:32
Client ID: SSTD010 Instrument; 5972hpb4* i '.OSample Info: COVolume Injected <uL): 1.0 Operator: 2319Column phase: RTX-5 Column diameter: 0*32
PI-j?nanthrene-dlO+
Data File: /chem/5972hp64. i/'DF020310A64.t./HI020310Afc4.d
Date : 10-MfiR“2002 15*32
Client ID: SSTD010
Sample Info:
Volume Injected <uL>: 140
Column phase: RTX-5
Instrument: 5972hp644i
Operator: 2319
Column diameter: 0432
■:.d
CD
Data File: /chem/5972hp64.i/DF020310A64.b/HI020310A64.dReport Date: ll-Mar-2030 14:32
CompuChem
Data file Lab Smp Id Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date Als bottle Dil Factor Integrator Target Version: Processing Host
Semivolatile Report SW-846 Method 8270C /chem/5972hp64.i/DF020310A64.b/HI020310A64.d
Client Smp ID: SSTD01015:32
Inst ID: 5 972hp64.i
SSTD010 10 -MAR-2 0 0 2 2319
/chem/5972hp64.i/DF020310A64.b/8270Cv6.mll-Mar-2030 14:32 frankson Quant Type: ISTD
15:32 Cal File: HI020310A64.dCalibration Sample, Level:
MAR-200210 41.00000 HP RTE
3 . 50einstein
Compound Sublist: all.sub
Concentration Formula: Amt * DF * Vt./ (Vo * Vi) * CpndVariable
Name Value Description
DF 1 . 00000 Dilution FactorVt 1000.00000 Volume of final extract (uL)Vo 1000.00000 Volume of sample extracted (mL)• 1.00000 Volume injected (uL)
Cpnd Variable Local Compound Variable
AMOUNTS
CAL-AMT ON
P7 exp e7 L RESPONSE ( NG) (
• 1 . . ^ P:-:-z: o:-.-::::-- i . 2 *1 % - 2 4 r . ICC' 224256 40.0000
* 0 Napb.t r.a • -tr.-j • c •• ' "5 ;; . 14 .• i v. i : -’■VC' 875539 40.0000
: AT*::*:::-!: n-r-v t : 4 4 e.v ••PC . 4179S0 4 C . 0000
4 r : : : c .4-o : iri 0C 0 i 1246632 40.0000
• -:y. ••••■ 24.' v •••. ') 0 0 i 1174122 40.0000
■■ :. . •;2: . ■ 0 r. 1 4 2 4 14 9 4 0.0 0 0 0
I • f-". • ■ 1.4 74 ■ ..793, 75212 10.0000
: ■■■ ~ "'cl "749 ’ 1 . 4 3 P ' 102100 10.0000
■■ r--r.l ,.4551 .00203 1 C . 0 0 0 0
1 / 3 • ; tcbcy '. 1 7 2 135; 1:564: j 902' 224782 10.0000
: 1: :V- V. :• 1 • 4.4V. 14 4 ' 1 ■ . . 0 9 9 : 49579 in QCOO
: . r Ti:-pr.c--y: 344 . = 5=: 372394 .10 . 0000
SI MI LAP I TV
i:: o o or
:0.3000
• 'J . 41
j C . 7 9
10.56
11.31
11.17
10 48
1 Ci . - 1
«\
f.v
49:
■0'7N-
_L
Data File: /'chem/'5972hp64 . i/'DF0203 10A64 . b/HI0203 10A64 . aReport Date: ll-Mar-2030 14:32
AMOUNTS
Compounds
QUANT SIG
MASS PT EXP RT REL RT RESPONSE
CAL-AMT
( NG)
ON-COL
( NG) SIMILARITY
15 Benzaldehyde 77 7 . 657 7.657 (0.926) 52799 10.0000 10 94 9431
16 Phenol 94 7.776 7 776 (0.941) 88548 10.0000 10.87
17 Bis (2 - chioroechy1)ether 93 7.911 7.911 (0.957) 59151 10.0000 10.53
10 2-Chlorophenol 12 S 8 . C12 3.012 (0.969) 78286 10 . 0000 10.35 8821
19 1,3-DichloroDenzene ■a 6 6.215 8.215 (0.994) 92975 10.0000 10.67
20 1,4 - Dicr. 1 crcoenzene 146 6.263 5.283 ■■ 1.002.' 92 5 S 1 10.0000 1C . 56
21 Benzyl alcohol ICS 3.469 3.469 (1.0251 47235 10.0000 10 . 52
22 1,2 - Dicn lorober.zene 14 6 8.570 8 . 570 (1.037) 91437 10.0000 1C . 58
23 2-Mechylphenoi 103 8.621 8.621 (1.043) 6 9 644 10 . 0000 10.60
24 2,2 ' -oxybis 1 - Chi ore-propane! 0.672 8.672 (1.049) 107604 10.0000 10.47 0 (M'
25 Acetophenone 105 9 075 6.37^ 11 - 074 ) 102237 10.0000 10.76 7924
26 3-Methylphenol 103 6.824 5 . 324 11 . 067' 7 6 3 14 10 . 0000 10.65
2 7 4 - Methy1phenoi 108 3 824 8 .324 (1 . 067) 76314 10 . 0000 10.65
2 6 N-Ni t roso-d: - N- propy 1 amine 70 8.875 8 . 375 (1 .074) 49581 10.0000 10.89 7583
2 9 Hexacnloroet nane ll7 9.010 9.010 (1 0^0) 48973 10.0000 10.76 9515
3C Nicrooenzene 77 9.126 9.120 (0.900) 81015 10.0000 10.66 9654
31 Isopnorone 32 9 . 45C 9.450 iO.932) 162211 10.0000 10.84 9333
3 2 2 -Nitrophencl 139 9 602 9 . 602 (0.947) 52359 10.0000 11.00 9300
3 3 2 . 4 - 2> l me t h y 1 p h e n z 1 • n 9 . 6 C 2 9.602 -0.947' 77790 10.0000 11 . 00 7878
34 3is » 2 -cr. 1 orcet hoxy ; methane 9 3 9.754 9 754 ;C . 962) 98711 10.0000 11.10 9458
35 2 . 4 - 211cr. 1 omphenc 1 -.62 5 q; n 9.940 (0 980' 77517 10.0000 10.57
3 6 1 . 2 . -4 - T r l o n.r o oe n z e r. e 1 s 0 1 0 . 0 7 6 1C. ; 7 5 '0.993; 93856 10 . 0000 11.07
? 7 Napnt na 1 er.e 1 2 3 10. 17 7 10 . 17*7 1 1 . 003) 358401 10.0000 11 . 18 9710
^36 4-Chioroar.;'. me 1 2 7 10.261 10.261 :i.012) 112295 10 . 0000 10.90 8198B: 6 Hexam i oroz-cz ad i er.e
225 10.413 10 4 13 »1.027) 6 3 5 62 10.0000 10.87 9279
•i C ._apro; acc am ■ i 3 10 701 10.701 (1 055; 25809 10.0000 10.13 9685
41 4-Ctioro-3-methyipnenc1 1 n 7 1 0 . 5 5 7 1 0 9 3 7 <1 . 078) 90477 10.0000 10.97 9531
4 2 2 - Met hynapnt na : er.e _ -1 w 11.225 :: .225 (1.107) 178261 10.0000 11.06
4 3 : -Metnvmacntna lene 14 2 11.41: 163442 10.0000 10.75
44 Hexa m 1 cI'ocyctpent ad :er.e 2.- 11.597 • • ;:i-j ; 0 . s a:: 63111 10.0000 10. 10 9064
45 2.4 v -Tr: rrmrocr-mn. 11 7 4 5 ■74 '< '0.692' 6 6 518 10.0000 10.42
:: ?:s 1 0 5 5 7 j 72661 10.0000 10.69
4- ! 1 S:-Sr.~:-.y ; r-; 12 ’ 7 • 1 2 . 0 7 0 ■ :■. : ■’' 204955 10.0000 11.00 7527
•«- 2- mmrmatmm:-:- : i .5 :: 12 12: -0?' I 7 3 4 6 9 10.0000 10.52
12 . : 41 12. .= 4 1 :0. 2i2; 6 13 3 5 10.0 >10 0 10 7Q 6605(a)
= : : :■ : - : 12 '■ 7 : 2 • V 14 3 • :: -.665 0 1C.oncc 11 23 5 15 £
z'. m r : : '.2 - '■ -*''4. 5 7 4 : 0.0000 1 0 . 4 7 s, 2 i F
• •" ■:• ■■■ ■ . r •i 2 1 3 3 7 I 0 . J 0 0 c 11.32 9215
5 } : ■ N* t : cor.: 1 : ■- ■= • ■"■■■ 1 : 1. 4 ■: 2 6 22 31 10.000 0 15.32 3253 (a)
i-—-: : 3 . 2 2 :■ -1 . : 14 ■ 2 7 8 5 3-0 10 . 0 0 o; 11.58 9 4 6 d
' ; • ' :: : : • ' • :; 23 - 1 ■ 2 5 4 r) 0 5 '■ 4.150? so.0000 42 50 (a )
-- .. . i: :■ : 3 ■ - :• ■ 1. 0 01 35677 10-000:: 10.40 7966 (a)
' •' • 2 3 1 . 5 0 7 - l 85324 10.00']0 10.91 3 6 3 S
;; —cr^ar. 1 5 . - 7 5 11 4 7 3 ■■1 22 2) 2.3 5 11 5 10.0000 11.35 94 99
53 C:etnvmh:h3 .'i--' :• ■■ - : I . 9 5 3: 263579 1 0.000 0 11.46 9759
; : ■ a: v: - no:' : 1 . 14 022 - 9 - a q -> 1 0 . 0 0 0 0 11.23 0 l M)
T. 1 Plur re:>_- : 14 ' 4 . •; • 1 5 7 • 336038 10.0000 11.74 77 22
\
\
49l
Data File: /chem/5972hp64.i/DF020310A64.b/HI020310A64.dReport Date: ll-Mar-2030 14:32
AMOUNTS
QC
MH
Flag Legend
■ Target compound detected but, quantitated amount Below Limit Of Quantitation(BLOQ).Compound response manually integrated.
■ Operator selected an alternate compound hit.
QUANT SIG CAL-AMT ON-COL
Compounds MASS RT EXP RT REL RT RESPONSE ( NG) ( NG) SIMILARITY
62 4 - Ni . roar.: line 138 14.116 14.116 (1.072) 63001 10.0000 10.54 921-1 (a)
63 4,6-Dinitro-2-methylphenol 198 14.166 14.166 (0.915) 52604 10.0000 10.10 5C11 (a)
6*4 N-Nitrosodiphenylamine 169 14 200 14.200 (0.917) 162531 10.0000 11.63 9145
65 1,2 -Diphenylhydrazine 77 14 .251 14 .251 (1.082) 265073 10.0000 ■1.37 9357
6 6 4 -Bromopheny1-phenyl ether 24S 14.775 14 . 775 (0.954) 78176 10.0000 11 . 55 84 7 B
67 HexachIorobenzene 284 15.029 15.029 (0 . 971) 98392 10.0000 11 . 92 9323
6 5 Acrazme 200 15.012 15.012 (D.969) 76049 10.0000 12.04 8600
59 Pentachlorophenol 2 6 5 15.282 15.282 (0.987) 6 0 96 6 10.0000 10.30 9489(a)
7 0 Phenanthrene 170 15.519 15.519 (1.002) 584255 10.0000 12.30
71 Anthracene 178 15 . 567 15.587 ■Cl . 007) 598331 10.0000 12 .45
72 Carbazole 167 15.790 15.79C (1.0201 370848 10.0000 11 .68 9385
73 Di-n-butvlphthalate 149 16 .229 16.229 (1.048) 570484 10.0000 12 . 01 9489
74 F1 uorantnene 202 17.277 17.277 (1.116) 652591 10.0000 11 . 95
75 5enz id l r.e 184 17.429 17 429 (0 873) 373491 20.0000 22.75 0528
7c Pyrene 202 17.533 17.583 i C 5 6 6; 6 644 54 1 0.0 0 0 0 11.97
77 Bury 1 ben.zy i pnt ha la c e 149 18.816 19.815 C . 94 2; 257690 10.0000 11 . 33 9644
70 3,3' •Dichlorobenzidine 252 19 . 847 19.847 (0.994 ) 184736 10.0000 11.60 754 1 (a)
bis ; 2 - e: r.y 1 nexy 1 Phr ha ir.e 14 9 1 5 7 96 19.796 ' C . ? 9 2 : 392596 10.0000 11 .69 9120
i *> Benzc .a ^rtr.tae-r.~ 22 t 19.932 1 a ; n (0.998! 612116 10.0000 11.77
Chrysen- 2 2° 1 9 9 9 5 -.9 999 ; 1 . 002) 574669 10.0000 11.83
j - '• • • C: :v 14 9 20.760 2C . 750 (0. 92 5) 386510 10.0000 1C . 96
9 3 Benzoin: iuorantnene 252 21 . 707 21 .707 (C.967) 398987 10.0000 12.09 (HI
e 4 = enzo ■ x . 252 21.741 21.741 >0.969) 315305 10.0000 10.25
iss Benzo ■ a < py: er.~ 252 22 . 332 22.332 (C.995: 296915 10.0000 11. 13
•ndeno•) .2. } - :d■pyrene 278 25.020 25.020 (1.114) 215885 10.0000 11 . 34 0 (M)
07 31 nenzc r>, n '• ant n:*acene 2 5.02 0 25.020 ! 1 . 1.14 J 262141 10.0000 11.35 8080
5 r Benzo q.r.. t.o-ryler.e 27- 25 . 832 *> c j 3 2 {1.151) 267641 10.0000 11.07 94 30
v
49
Data r-is; 'cm Injection Date I nst rument: 59
i lent Sample
ound: 2.4. Numoer': 11
em/59 72hp64 . : /' DF 020 : 10-Mm R-2002 15:3“72hp64 . 1
ID: 55TD010
6-Tr1bromopneno1^ _ 7* o _ tf,
0h64 . b-,-h I 1 Oh34 . c
Ion 329.60: Hrc^; 69579 Height: 43509
xt
■a4.2 ^
4.3-
4.
1.6-
1.5-
0.9-
0.6
1 4 . On 1 4.05 1 14.15 14.20 14 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.85 14^90 14.95 j
_________________ h i r. ______________________________________________________________1Ion 332.00: Hrea: 0 Height: 0
cp
:4 . ; t ;4 .60 14.65 14.70 14.75 14.80 14.85 14.90 14.95
Hei?nt: 0
494
Data F l le : /chem/5972ho64. 1 /DF020310A64 . b.'HI020310A64 . dInjection Date: 10-MAR-2002 15:32Instrument: 5972hpb4.1
Client Sample ID; 35TD010
oound : 2.2 ' -o>.uo 1 s i l-Chlor-npropane) Number: 108-60-1
Ion 45 .00: Area: 107604 Heignt: 55992
5.4-
5 1 •
4.8-
cvrv43CD
4.5-
4.2- ;
3.9-;
3.6-
3.3-ii
T ^ . U- i
;2.4-
1 .5 i i
1.5- i i
1.2- ji ii j
0.9- ; i
0.6 1
0.3-
0.0- -S.20 6.25 3.30 5.35 6. JO 3.-45 8.50 8.55 8.60 8.65 6
M i n
20 6.25 6.80 8.85 8.90 8.95 9.00 9.05 9.10 9.151
I on 1 21.00: Area: 0 Height: 0 1
9 . Ci
H _ 5
I !
! i ;II 1
»
5.5
| \
; 1
’ l :
i i i
1 i '
i 1i i| j
i i !
CO
1 1
l :
■5 :o 8.35 •• ' "• •: 5.-45 5.50 8 55 5.60 6.65 5."
M : r.
8.75 8.90 8.85 8.90 8.95 9.00 9.05 9.10 9.15
i nn --.00: Jro=,; Height: 0
49 j
’5 d.60 8.55 8.90 8.95 9.00 9.05 9.10 9.15
Data 71 ie : /chem/5972hp64. 1 /DF0203 10A64 . £>, H102031 0h64 . dInjection Date: 10-MAR-2002 15:32Instrument: 5972hp6J.lClient Sample tD: SSTDuiu
impound: *5 Numbe
4-ChiorophenuI-pheny1 ether r: 7005-72-3
o. ti-b. 4
6.0-
5.6-
5.2-
4 . o
4.4-
Ion 204.00: Area: 120382 Height: 72056
T ]
2.3
2.4
0.3- I
0.4-
13.55 1 3.00 13.65 13.70 13.75 13.'-30 13.35 13.90 13.95 14.00 14.05 14.IQ 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50
____ M;p______________________________________________________________________________________________________ •Ion 206.00: Area: C Heignt: 0 I
14.: 14.3 14.4 14.?
14.:
49 C
14.514.4
dData rile: •'i;nem/5972riC'6>4 • i ■' DF0203 10»-Injection Date: i0-MdR-2002 15:32Instrument: 5972np64.1Client Sample ID: SSTDOlO
Impound: Benzo* t>f1uon anthe fS thumper: 205-99-2
Ion 252.00: Mrea: 393887 Height: 135163
1 • D-
1.5-
1.4-
1 . 3-"
1.2- 1.1-
1.0-
0.2
0.1
?1.25 21 . 30 21.35 21 .40 21.45 21 .50 21.55 21.60 21.65 21 . 70' 21.75 21.80 21.65 21.90 21.95 22.00 22.05 22.10 22.15____________________________________________________ M l n_____________________________________________________________ _
ion 253 . ■ j> j: wrea: 35956 height: 28920
21 . 75 21.60 21.35 21 .90 21.95 22.00 22.05 22.10 22.15
-eight: 13445
4 9 74- Cl . c-' 2 i . c-5 21.60 2 1 . do 21. 75 21.60 21.85 21.90 21.95 22.00 22.05 22.10 22. 15
0h64.dData File: .-'chem/5972hp64. 1 ••'DF020310A64 . b.'Hin;Injection Date: 10-HAR-2002 15:32Instrument: 5972hp64.iClient Sample ID: 55TD010
*pound: Number
Indenoi1 : 193-39- 5
cd)pu rene
Ion 276.00
5.7-
5.4-
5.1-
4.d-
4.5
4.2-
3.9-
3.6-
3.3-
Area 15905 Height: 57896
inr-j
2.4-
1 .3-
1 .5
1.2-
0.9-
0.6-
24.55 24.60 24.65 24. "D 24.75 ?J. 80 24.85 24.90 24.95 25.00 25.05 25.10 25.15 25.20 25.25 25.30 25.35 25.40 25.45 25.50_____________________________________________________________________________________________________________________ M 1 n
‘ Inn 139.00: Area: 0 Height: 0
25.2 25.3 25.5
1 4r'
_________ 49b25.3 25.4 25.5
<:<10
Data File: /chem/5972hp64. i/DF020310A64 . 1:./HK020310A64. d
Date : 10-MAR-2002 1F,;46
Client ID: SSTD02v
Sample Info:
Volume Injected (ul_>: 1*0
Column phase: RTX-5
Instrument: 5972hp644i
CD
Operator: 2319
Column diameter: 0432
1.2-
/chem/5972hp64 *i/DF020310A64,b/HK0203l0A64 * d <Part 1 o*
_ UI .J L__■ J _ , J J-
Pk«s,nanthrene-dlO+
(.<10*6)
Data File: /chem/5972hr- :4. i/DF020310A64.b/HK02031C'H64.d
Date : 10-MAR-2002 16:46
Client ID: SSTD020 Instrument: 5'?72hp64.i
Sample Info:
Volume Injected (uL>: 1.0 Operator: 2319
Column phase; RTX-5 Column diameter: 0.32
1.2-
1.1-
1.0-
2chem/'5972hp64. i2DF020310A64,b/HK020310A64*d (Part 2 of 2)
+<MrH73
I
£
i..co
: ?) o i_o
Data File: /chem/5972hp64.i/DF020310A64.b/HK020310A64.dReport Date: ll-Mar-2030 14:32
CompuChem
Data file :
Lab Smp ' Id:
Inj Date :
Operator :
Smp Info :
Semivolatile Report /chem/5972hp64.i/DF020310A64 SSTD02010-MAR- 2 0 0 2 16:46 2319
Misc Info : Comment : Method : Meth Date : Cal Date : Als bottle: Dil Factor: Integrator: Target Vers Processing
/'chem/5 9 72hp6 4ll-Mar-2030 1410-MAR- 2 0 0 2 16 6
1.00000 HP RTE ion: 3.50Host: einstein
i/DF020310A64 32 frankson 46
SW-846 Method 8270C .b/HK02 0310A64.d Client Smp ID: SSTD020
Inst ID: 5972hp64.i
b/8270Cv6.m Quant Type: ISTD Cal File: HK020310A64.d Calibration Sample, Level:
Compound Sublist: all.sub
2
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
DF;VtVo
1.00000
1000.00000
1000.00000
1.00000
Dilution Factor Volume of final extract (uL) Volume of sample extracted (mL) Volume injected (uL)
Cpnd Variable Local Compound Variable
;«:t s:c-
amounts
CAL-AMT ON-COL
p p7 RSL FT RESPONSE i NGJ NG)
p t 6 4 : 1 ?00) 112: 40.0000
:: : 4 i 3 Z'-~ \ 4 51 b 9 2 40.0000
■ \ 0 ’• 211330 40.0000
: =. 4 r. < • 1 N 0 1 6 4 4 5 3 5 4 0.0 00 0
v ■ : L ■ 592360 40.0000
22.445 3 0 0 1 303690 4 0.0 0 0 0
1 7 3996 20 . 0000 20.16
* ~ 3 7 ; 3 ■ 5 3 7 02 2 0 . 0 0 0 0 2 0.71
:■ '0.3933 9 S 4 B 2 20.0000 20.24
. -; ■ :. 302 ■ 22I7Q0 20.0000 21 . 34
• g :> c >, 6 4 6 3 0 20.0000 2 0.63
17 -.6 7 1 0.6951 343060 20.0000 2 2 0 3
6.342 ■. ■:. 5 2 5 ■ 2 6 713 20 . 0000 19.55
4 ' 4 ■0.525) 4 5326 2 0 . 0 0 0 0 19.49
SIMILARITY
iM)\
56 13
34 *4 9
501
Dana File: /'chem/5 9 72hp64 . i/DF02 0310A64 . b/HK02 03 10A64 . dReport Date: ll-Mar-2030 14:32
AMOUNTS
v’JANT 513 CAL - AMT ON-COL
Compounds MASS RT EXP RT REL RT RESPONSE ( NG) 1 NG) SIMILARITY
15 Bengaldehyde 77 7 ..555 7 655 1' 0 . 52 6) 53499 20.0000 21.37 9423
16 Phenol . 94 7 . 774 7 . 774 (0.941) 84993 20.0000 20.77
17 Bisi2 -chlore-thy1)ether 93 7.529 7 . 909 [0.957) 5654 1 20.0000 20.24
19 2 - Ch loropner.c 1 125 3.011 8.311 (0.969) 76351 20.0000 20.22 3 9 3 1
1 5 1 . 3 - C i ch lor coenzer.e 14 c 3.213 e . 213 ,’0.994) 88086 20.0000 2 0.28
2>“ 1 , 4 • C i ch lorobenzene 14 6 9 . 2 e 1 e . 231 :. 002) 50729 20.000C 20 . 72
21 Benzyl aizcnzl 1 0 6 6.467 3.467 : 1 .025) 45119 20.0000 2 0 . .1 3
22 l . 2 • 2’:ch 1 crocenzene 14 4 7 . 3 55 6 ( 1 . -’37) 86109 20 . 0000 2C . 43
2 ? 2-Met pyIpheno 1 ■.0 5 5 .636 5 6 2 r> 1 . )45 ’■ 6 6 7 9 7 70 . 0000 20.29
2 4 2 . 2 1 -oxyms . 1 - Ch 1 oroprcpar.e) 95 8 6 7 C 6.67 0 ' 1.04 9 ) 104494 20.0000 20.37 • \
25 Acetophenone 125 3.873 5.373 ! 1 . '274 ) 99231 20.0000 20.79 8 12 0
26 3 -Methyl phenol 108 S . 822 9 . 222 (1.067) 73945 20.0000 20.53
27 4 - Me t hy Ipher.o 1 IDS 5 . 322 3 . 322 { 1 . 067 ) 73945 20.0000 20.55
26 N-Nitroso-d:-N-propylamine 7 0 3.873 5 . 373 (1.074 ; 45909 20.0000 20.24 7302
z? Hexarni oroet.nane : 7 9 . ooe 3.003 (1.090! 46058 20.0000 20.32 94 7 5
32 Si t rooer.zene 7 9 . 126 9 126 i0.900' 76734 20.0000 19.97 9663
i 1 1 sepr.crcne J 3 4 4 8 9.445 ,0.932-' 153599 20 0000 20.19 94 2 7
11 2 - STi t ropnenol 9.60 0 9.600 ,'C . 94 7 , 43698 20.0000 20.08 8235
1 4 Oimetnyiphenz; 122 2 6 00 9-iOC .0.947' 7 3 65 4 20.0000 20.39 7714
:6 5 is ■ 2 ■ znlcroe: n-r.xy - me: nan.e 3 757 9 . "’52 :0.=-.2 93202 20.0000 20.52 94 85
11 1 . 4 • 1 ; rr. 1 : o::ne:tc . 1 4 2 5. = :■. i 3; r, 0 ,i 1 7 4/46 20.000C 19.98
;• •; : 2,.; • T: i tone:', zer.e :: •: 7 2 It .273 -.0.39 3/ 89356 20.0000 20.57
121 10.173 .1.003' 336690 20.0000 20.65 9817| -----
'.2 7 1 ■: .259 11- . 2 5 9 1 . 012 1 104218 20.0000 19 94 3 33 3
2 2 6 10.42t 1 -: .: 2 3, 61905 20 . 0000 2 0 o 1 8 8 5 9
: - - 1 . 0 5 5 ■ 24563 20 . r’000 19 . 17 9 7 0 0
■> - ^tnyl pner.-t 1 1-• - - --- : -- • 2 5 : V*. 7 0 •• S 3 6 9 9 20.0000 20.02 9 616
:■ •••••• ..------ 11.2-3 :: ::: :: .107' 1 6 3 1 9 6 20 . 0000 19.97
,- 1 ■-■.-r;:-.-. .=:.=• : :: . c -1 - : 2;, 161741 20.0000 20 74
” -----r.^ :-j- 2 1 7 : : . ;=■=. : 1 5 5 5 :o.SS : : 5 8 768 20.0000 19.00 874 5
: ■; - - 7 r : ::-.l-:nFth-nol : :■; 1 1 77 11 747 ■ 0 . 5 9 2 '■ S 4 S 7 0 20.0000 20 . 32
: : 7- 11.514 66183 29.0000 19.68
-- ----- - 12 :41 1 2 . •; - ; : . ; 7 15:3-5: 20.0000 2 0.76 7 5 0c
4- 2 ■ 7 n 1 “ : f : ’dtp nt n t .-ne : 4 _ 12 :9 -c 171454 20.0000 21.44
-.V . 3 i: . 0 5 3 01 0 20.0000 20 22 96 3 :
‘ ■’ i “...... *. 2 6 7 ~ 205837 2 0.0000 2 1 .06 r, 1 ;
• - • : - r 1 2 . 2 - ■ - --'4 54 34 6 2 0.000 G 2 0. : .3 9 _•■;
-1 -.i-n-:n-:-.:nv. : 2 7 ■ 403563 ::o. 0000 2 1 5.3 9 7 r ■ j
1 - - : : : - 1 ■ - 5 7 0 0 3 :;o. 0000 24.17 3 4 9 5
-1.j. : - 256744 2 0 . 0 0 0 C 21. } 5 --- --•
: ■ - - ;;" ■ - ■. ■ ■ . :. 1 : ; - 22;: -.. 3 7 4 7 6 100.coo 7<; ;• 7
317 6] 2 0. coon 15.65 8 0 i 4 : a
....... f ' ■ - • 1 12 4' 7 8 1 0 3 20.0000 19.99
. ■ -- : ■ -: : 12: 264921 2 0.0 c 0 0 : 1.0 3 39 n
' : hy . y: ; n 11 ? ‘ • : : - ' .: '32 24 J 7 G 5- 2 C .0000 ::. 05
- ■; 7:.. -: j':-r.y --- v . ■; . - ; .; •, t .: '- - 4 ■ 112730 20 . 0000 2 0.89 0 IN!) \
-:i - . 4 ■ ; . 1 •' 7 114 5 F1‘ 2 0.0000 2 2 01 7 4 5:
50^
Data File: /chem/5972hp64.i/DF020310A64.b/HK020310A64.dReport Date: ll-Mar-2030 14:32
AMOUNTS
J OL’ANT SIC CAL-AMT ON-COL
ToT.poup.ds MASS RT EXP RT EEL RT RESPONSE ! NG) ( NG) SIMILARITY
!1 3 S 14.114 14.114 (1.072) 56308 20.0000 19.04 9208 (a)
6 3 , 0 - D:r. i ; ro • 2 - met hylphenol 193 14 . 164 14.164 (0.915) 48291 20.0000 16.01 8811 (a)
6*i N - N: t rbsod: phenyl am ne 169 14.196 14.199 (0.917) 148922 20.0000 20.56 9082
6 5 1,2- C ipher.y 1 hydrazine 77 14 . 249 14 249 (1.082) 248371 20.0000 21.26 9320
66 •; -Brcr.opheny 1 -phenyiezher 249 14.773 14 773 (0.954 ) 73156 20.0000 20.88 8855
17 H5>:a;n!u:-oUn:ene 2 5 4 15.044 15.044 (0.972) 93579 20.0000 21.72 8543
■3f\t ra z: ne 200 15.010 15.010 (0.959) 70399 20.0000 21.45 8324
5 ? P -r r. t a c n 1 o r c p h e n o: 2 6 6 15.23C IS .290 (0.937) 55185 20.0000 19.11 3625 (a)
70 Phenanz-hren-r 1 7 5 IS . 517 15 517 il.002 ) 539141 20.0000 21.36
' - /■viiti'.i'a ren.e 1-; IS.56S 15 . 5 6 5 a.007) 552453 20.0000 22 . 14
73 Carbazoie 15' IS.304 15.804 a. 021) 346871 20.0000 21.06 0 .< 2 2
7 3 u:-n- butv1chzha 2 a:e 24 9 16 227 Id . 227 (1.04 S ) 530934 20.0000 21.57 9616
2 02 17.275 17.275 (1.116) 6 •} 4 0 8 20.0000 21.30
7r ner.ziciV.-- 9 4 17 4 27 17.427 ■■ 0.5 " 3 : 389739 40.0000 46 . 02 3565
O Pv:-:,r i 2‘.’2.
11.661 .0.886; ■ 5 4 0 S 9 8 20.0000 22.74
14 6 16.614 15.514 (0.942) 242516 20.0000 21.34 96 3 2
252 19.845 19 84 5 (0.994) 17 C 324 20.0000 21 31 7620
h: = -e'rr.y'.i-.TXv: 1 Phzha ia:e '-4 5 19.794 19.7?4 '0.992) 362306 20.0000 21.51 9 2 1
- • Eer.zn anr. n rac^ne 2 2 5 15.930 19.930 ■0.3981 5544 07 20.0000 21 .33
O ::n:-y?e;T 2 2 a 1 3 oc: 19.997 : 1.002: 538192 20.0000 22 07
C 1: r: = 20.75c 2 0 7 5 9 •:o. 925 ■■ 353732 20.0000 20 76
:s: 21.705 21 7 0S iC . 967 ; 358176 20.0000 21.76 i H)_ . - . . I ... ....
251 21.739 21.73*. i 0 . 9 6 5 ; 294443 20.0000 20.46^ Be:'.::- ~>z 22.330 21 .: 5 C ' 0 . 9 9 5; 265C30 20.0000 20.63
2 5 0 1 5 25.019 (1.114' 197790 20.0000 21.34 'MM) \
--.I-.-.-.:" ■ - ■' : ' • J 7 3 :s.::s '1.114; 239:39 20.0000 21.19 S 0 s r
: c r . v-rv . 'mi 2 r 3 3 ‘ 23 . 6 ! ' 1 15 1' 251722 20.0000 21.37 94 -.-.9
i ac
I;Leaend
Target compound detected but, quantitated amount Below limit Of Quantitation(BLOQ).Compound response manually integrated.Operator selected an alternate compound hit.
501
I
I
Data' F i i•=>: /cnem.'‘59~,2hij64 . l /DF02031 Injection Date: i9-mhF-1'mm2 16:46Instrument: 5972hp64.i Client Samcle 'ID: S5TD020
bound: . rNunfrer
4 .
1 i
r i bromooheno1
o •'HK02031 '.'064 . d
4.5
4.2
Ion 329.60: ^rea: 6*46b6 Heignt: 4736b
iT
tr
3.6
3.3-
2.4-
2.1-
1.6-
i <=, - 1 .2
0.9-
1 4 . 'i 1 14 14.3 14.4 14.5 14.6 14.7 14.8 14.9
Mir.Ion 332.00: -"'ea: 0 Heignt: 0
1
a?
14.8 14.9
50414.5 14.6 14.7 14.3 14.9
i
Data file: •/chem/5?72np64. i.'D7020310h64Injection Date: 10-MhR-2002 16:46Instrument: 5972np64.:Client Sample ID: SSTD020
pound: : Number
2 ’ -o • ub i s1 1 -Ch loropropane J 106-50-1
5.1-
4.6-'
4.5-
4.2-
3.9-
3.6-
3.3-
3. 0-
b-,-Hr.'02031 O^d-4 . a
Ic-n 45.00: P.-'ea: 104494 Height: 51064
rCiT
ill
2.4-
2.1-
1 _ Q_
1.5-
1.2-
0.9-
3.2
I
i . 5
II
3.4 6.5 8!,6 317 8^8 8^9 9.0 9ll
___________________________________________________M in_____________________________________________________________________________________i_____________
Ion 121.00: Hr-ea: 0 Height: 0
"I '■6 ■
■x> •
i\
8. "5 3.30 8.Q5 5.90 6.95 9.00 9.05 9.10 9.15
I
2 ____ 50o•5. •;5 5. 70 8.75 6.80 6.85 8.90 8.95 9.00 9.05 9.10 9.15
m i r.
Client Sample'ID: 35TD020
Data File: /chem.'5972hp64.1 /DF0203 10064 . b/hh0203 10064 . dinjection Dat*: 10-MwR-2002 16:4*5Instrument; 5972hpb4.1
ound : 4-i_h ioropnem.) 1 - pheni.i 1 ether founder: "’005-72-3
Ion 204.00: Hrea: 112730 Height: 76232
*
5.2-.
4.0-
4.4-
4.0-
13.9 14.1Min
14.1 14.; 14.3 14.4 14.5
ion i’jo.Ut1: nrea Height: 0
Cc
1 4 . oo 14.10 14.15 14.20 14.25 14.70 14.35 14.40 14.45 14.50
I ht
- _;50b
: : . ' " 1 - . O'. : 4 . 05 14.;-;, l 4 . l 5 14.20 14.25 14.30 14.35 14.40 14.45 14.50
l
I
I
Dats File: .''ch~rri/5972r.p34 . 1 .<Injection Date: 1u-MmR-2002I ns t rument: 5972hp64.1
Client Sample ID: SSTD020
DF.
ound: Bemo < b > f luoranthene Mumper: 205-99-2
14 . p/Hr'.i.'i031 09»54 . d
1.5-.
1 .J-
1 . V
1.2-
Ion 252.00: area ;58176 Height: 134272
in , crv
OJ
0.9-
0.3-
0. b-
0
0.3- •
I
on 253.00:
21.7 21.8 21.9 22.0 22.1iM: r;____________________________________________________________________________________________
7rr35 Heignc: 23492
U*i
•Al
2 1.8 1
ion ii n 521
TSI
He:gr t: 1 'u
I
t
5021.9 22.0 22.1 !
Date* F 1 1 <=■: .''r hpm.''. 1 .•' DF 0203 iOHqU.p Hk 020310964.cInjection Date: 10-M9R-2002 16:46Instrument: 5972hp64.lClient Sample ID: S5TD020
pound : Inaeno( 1. 2, j--cd J py rene Number: 193-39-5
5.1-
•4.8-
4.5-
3.6-
2.4-
2.1-
1.3-
J . 5
1.2-
'3.9
Ion 276.00: Ores: 197790 Height: 52520
24.3 24.9 25. CMir
25.1 25. 25.3 25.4 25.5
Ion 133.00:
''5 25 . 10 25.1 5 25.20 25.25 25.30 25.35 25.40 25.45 25.50
50:3 o: J4 . r- 2 j . ,2 :u . r.r : 5. ;=. :D. ; -5 _ :5 25.20 25.25 25.30 25.35 25.40 25.45 25.50
Data File: /chem7597;hpf.4. i/DF021310A64 .b/HL020310A64 ,d
Date : 10-MAR-2002 17:23
Cl ient ID: SSTD050 Instrument; 5972hp64.i :.nSample Info: CD
Volume Injected (uL>: 1.0 Operator; 2319 LSD
Co1umn phase: RTX-5 Column diameter; 0*32
2chem/5?72hp64.i/DF020310A64.b/HL020310A64.d (Part 1 of 2>
2.0-1.9-
1.8-
1.7-
1.6-
1.5-
+CO
F'hj?nanthrene-diO+
C:<10
Data Pile: /chern/5'572hpe.4.i/IiF020310A64.b/HL020310lHb4.d
Date : 10-MAR-2002 17;23
Client ID: SSTD050
Sample Info;
Volume Injected (uL); 1*0
Column phase; RTX-5
/chem/’5972hp64.i/DF020310A64.b/HL020310A64.d (Part 2 of 2>
+OJ
Instrument; 5972hp64*1
Operator; 2319
Column diameter; 0*32
LO
i
Data File: /chem/5972hp64.i/DF020310A64.b/HL020310A64.dReport Date: ll-Mar-2030 14:32
CompuChem
Data file Lab Smp , Id Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date Als bottle Dil Factor Integrator Target Veit Processing
Semivolatile Report SW-846 Method 8270C /chem/5972hp64.i/DF020310A64.b/HL020310A64.d SSTDO50 Client Smp ID: SSTD05010-MAR-2 0 02 17:232319 Inst ID: 5972hp64.i
/chem/5972hp64.i/DF020310A64,b/8270Cvb.mll-Mar-2030 14:32 frankson Quant Type: ISTD10-MAR- 2 0 0 2 17:23 Cal File: HL020310A64.d7 Calibration Sample, Level:1.00000
HP RTE Compound Sublist: all.sub'ion: 3.50Host: einstein
3
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
NanVe Value Description
DF:VCVo'Vi,
1.00000
1000.00000
1000.00000
I . 0 0 0 0 0
Dilution Factor Volume of final extract (uL) Volume of sample extracted (mL) Volume injected (uL)
Cpnc Variab Local Compound Variable
AMOUNTS
CAL-AMT ON-COL
K 7 'r\ v Q t ~ RESPONSE t NG) ( NG)
11 ? 5 = o 40 .0C00
: :-wu. 4 4 2 3 7 rj 4 0.0000
u i U . 0 0 0 0
■:1: ■ 74 7772 40.0000
■3 3 3 1 3 7 40.0000
■■■■■■- 307230 4 0.0000
; •; 1 - 50.0000 46 . 6 4
50.0000
: -t 244^45 50.0000 51.12
5 2 0 12 I 50 . 0000 50.04
: 6 i 5 1 3 5 C . 0 0 0 C 51.10
•5269*55 50.0000 51.79
■ 6 *j..- 96 5 0 . C 0 C 0 49.42
' 4 . - 2 = • 1 1 6 - 2 2 5 0.000 C 4 5.75
511
I
/Data File: , Report Date :
hem/5972hp64.i/DF020310A64.b/HL020310A64.d11-Mar-203 0 14:32
Ezmpc zr.ds
51G
R . - X ? E - REL RT RESPONSE
AMOUNTS
CAL - AMT
i NG)
ON-COL
( NG) SIMILARITY
1 r1
Ser.za Ideh.yde 77 7.655 7.455 (0.925) 127916 50.0000 51.42 94 r
15 Phenol . 54 7.773 7 7 7 3 :C.941! 203581 50.0000 4 9 . j
17 3 is 12 - cr.lcrzet'r.yl: echer 53 7 90S 7 . SOS i0. 957) 134861 SO.0000 4 3 . 1■
15 2-Chioropheno1 1 2 S 8.010 6 .CIO (0.969) 190352 50.0000 4 9.9 = 9 919
- c, 1. 3 -Dich 1 orober.zene 14 5 8.212 8.212 (0.9941 217072 50.0000 4 9.51
2 0 I , 4 -Dicr.iorcoenzene 145 8 2 S 0 3.290 ,1.002) 219903 50.0000 4 9.70
-> i Benzyl alcohol 10 3 5.466 3.466 (1.025) 103013 50 . GJ00 48.02
2 2 : . 2 -D: or. 1 orobenzene 14 5 8.558 3.565 (1.037) 215798 50.0C. 00 49.55
2 1 2-Methviphenol 105 8 . 635 -.635 (1.045) 166121 50.0000 4 9.92 \2-; 2.2' - oxyb '.s'.'. - Ch 1 oropropane) 45 3.669 ° . 6 6 9 (1.C49) 256048 50.0000 49.45 0 (M ) \
2 5 Azet r-pr.er.one ICS 3 8 72 . 3 7 2 (1 . 0 7 4 ) 236090 50.0000 49.09 8494
2c 3 -Me: hy lpnenc ; 1 OP 3.838 - 9 3 8 (1.070) 176775 50.0000 48.87
2 7 4 -Mezhy 1 p.neno. 1 0 5 5.338 5.339 11.070) . 176775 50.0000 48.87 \25 N • N 11. rose - q: •N-propy1 an:ne 7 0 9 . S 7 2 8 . 972 i 1 . 074) 110300 50.0000 48.38 0 (M) V
2 0 He:<a-:r.: or-: n^ne 1 17 9.007 4 : 0 7 ( 1 . 090i 113815 50.0000 49.71 94 34
i .• 9.125 -. ::s ■'0 . 6 58 : 136678 5 0.0 0 0 C 49.72 95 92
i Isopnorzr.e 4 2 2.447 5.447 i C 9 3 0; 37QQ06 50 . 0000 49.71 94 5 0
i 2 2 - N i - : tcr-’i.;. 1 3 C, 5 55 5 9 5 r '••• 0 94 5> 118107 50.0000 4 9.77 326 1
5 ;■ 2.4-: : c,e: :\v 1 r;r.-.tc: 12 2 - V-> 0 . 94 5. 1 7 c 5 6 0 50.0000 49. 92 754^
3 4 h: ^ ; 2 -' net na ? 1 =- : ; 7?: 0 . 36 0'- 2 2 0 4 2 ^ 50.0000 49.62 9525
;5 2 . - 2; .t . -• :l •,! 142 ' . 9 -• 4 4 0 . ? 13 ; 163158 50.0000 5 0.0 C
992 : 217541 50.0000 50.88
1 002 . 804036 50.0000 50.29 9794
.01 o ■ 25-i 134 50.0000 49.71 3309
-2’’ ■ 14 1 R 8 50.000C 50.04 3 8 59
: . 055) V 0 3 0 0 50.0000 4 9.71 9553
277; 157374 50 . 0000 43.50 9732
■ 105) 4C3254 50.0000 50 . 32
■; ; • 12 3) j 3 4 6 5 6 50.0000 50 . 30
. 5 54 i C . 331; 153557 50.0000 49.69 8963
74 6 ■0 5 92 i 157780 50.0000 49.69
r: . c. 899; 169239 50.0000 50.24
7 9 1 7 . 47Q704 50 . 0000 50.37 7 5 7 4
:: r ■ 'j 9 2 0 i 400643 50.00GC 5 0.05
.3 5 ■■ 14 IS65 50.0000 4 9.51 52 7 0
•. 7-' c 4 • 489241 5 o . o c o o 50.02 9 3 9 7
. -• 1 .= 9 7 4 , 132126 50 . 0 00 0 4 5.09 9 3 34
7 W 3 547450 50.0v00 50.43 9673
9 94 : 129354 50 . C200 57,17 9 2 06
: 3 4 ■■ o 1 7 7 6 c 5 c . r, 200 5 0.30
' 1 7 ‘A 4 2 5 C . 0 0 C 247.6
'■12' = 266 3 5 0 1 0 0 0 4 6.9 0 7 24 4
■' 1 2 2 4 : :■ = i :■ e 51 0 0 0 0 4 9.2 7 -> - '<
' 1 024 ' c 2 S ri t '■ 5".0 0 0 2 4 5.5 9 0 9 r-
5 5 .■ 5 7 7 5 1 50.0090 4 5 . c - •j 7 54
: D ' 2 6 4 ci 50.0090 50.4.
■y , 1 4 7 , 7 3 4 3z 50.0000 5 0 =4 7 0 5'
51 c.
Data File: /chem/5972hp64.i/DF020310A64.b/HL020310A64.dReport Date: ll-Mar-2030 14:32
AMOUNTS
’ Q’JAi-i 31G CAL-AMT ON-GOL
Compounds MASS RT EX? RT REL RT RESPONSE ( NG) ( NG) SIMILARITY
6 2 4-Nitrear.lime 138 14.113 14.113 11.072: 149845 50.0000 50.53 9214
6 3 6 , 6 - Di ni t ro- 2 -methylphenol q - 14.130 14 180 * C.916 > 133572 50.0000 50.78 6717
64 N - N i t ros ed i pher.y lami ne 165 14.197 14 197 : 0 . 9171 352250 50.0000 49.77 6 8 3 0
65 1,2-Dipheny1hydrazine 11 14 . 24S 14 .248 (1.092) 585881 50.0000 50.11 9 515
6 6 4 - Brc-mopheny 1 • phenyl ether 24 6 14 . 772 14 . 772 (0.954) 177456 50.0000 51.46 8 922.
67 Hexach orober.zer.e 2 84 15.04 5 15.C43 (0.972) 218116 50.0000 51.47 9 6 C 9
6 S At razine 2 C 0 : 5 . 0 0 9 15.009 t0.969) 167227 50 . 0000 5 1.74 3 0 0 7
65 Per.tachiorotherc 1 264 15.279 15.279 iC.987) 140243 50 . 0000 •19 . 7 2 8 777
70 Phenanc h.rer.r :7S 15.514 15.516 (1.002; 1224268 50.0000 50. 63
71 Anthracene : 73 15 . 584 15 . 5S4 (1.007) 1271482 50.0000 51 . / 4
72 Carbazoie 167 15.803 15.503 (1.0211 826857 50.0000 51.12 9498
73 Di-n- butviphtna1 ate 145 16 226 16 . 226 (1.0481 1237206 50.0000 51.16 9 6 6 5
74 Fluoranthene 2 02 17.274 17.274 (1.116) 1436834 50.0000 51 . 55
75 5enz;cnre 1 84 it 427 1 7 . 427 (0.873) 556332 100.000 103 . 3 8649
76 Pyrene 202 17 6 8 C 1 7 . 6 8 C ; 0 . 8 8 6 ■■ 1503681 50.0000 51.93
Suty 1 be,r.iy > pr.i na ! a:e 14 5 18.313 18 .313 ;0.942; 589864 50.0000 50.82 9683
7 w 3 /■ - 7: c r. i c r 0 b e n z id i r e 252 19.844 19.344 iC. 994) 418034 50.0000 51 . 13 7836
79 o 1 s : 2 -et ny 1 n.-xy 1 ; Pnt ha la t e 149 19.793 19.793 ( 0.992) 899506 50.0000 51 . 96 929530 Ber.zo 'a!- an: rracene 223 19.529 ’9.929 (0.999) 1355883 50.0000 51.12
61 Cn ryse.ne 2 2 6 2 0 0 1 5 20.013 : 1 . 0 C 3 i 1294305 50.0000 51.76
92 Z: n ••ut v . t-.n: r.a . a t ~ '-4 6 20.774 :r. . '74 iC 925: 307967 50 . 0000 52.21
2 5 2 2 1 .704 2 1 7 04 ■ 0 9 6 7.. 780631 50.0000 4 7.38
2 52 21.7?- :i 7>; •. 0 . 5 6 5 •• 828139 50.0000 55.62 (
2 -1 2 22 3 2 5 2 2 3 2 9 .0 3 55': 6 66 8 09 SC .0000 51.03
2 7 5 25.0:4 25.034 ;1.115 ) 485486 50.0000 51.46 0 (
"i" C 1 oer.zr- r art hrar-rr-v 27 4 2 5.0 3 t 2 5 0 34 ■ 1. ; 15 ; . 591905 50.0000 51.71 8065
36 Renzo ■ 7 . n . ■_ :".n yr.e 2 7 4 25.646 25.646 (1.151) 521583 50.0000 51.79 94 17
(M)D \
QC flag,Legend
M - Compound response manually integrated.
bio
II
Data F 11 e: /chem/5972ho64 . 1 /DF020310964 . b-' HL.0203 10H64 . clInjection Date: i0-MhP-2002 17:23Instrument: 5?72no64 .Oiient Sample ID: 5STD050
? pound:
Mumper
2 ' - o ■ y b i 106-60-1
1 -Chloropropane '•
1.1-
1.0-
0.9-
0.9-
0.6 •
n.5-
,j 4.
on 45.00: 4rea: 256046 Height: 120376
(?•«r»'OZ
0.2-
0.1-
6.7' 3.3 3.4 6.5 o.c 3.7 S.8 8.9 9.0 9.1
______________________________________________________________________________ ________M 1 nIon 121.00: n^ea: 0 Heignt: 0
1
3.40 .5. 5.55 3.3 0 3.3 5 5.70 5.7-; 5. SO 6.85 8.90 3.95 9.00 9.05 9.10 9.15
5145.65 5.50 5.-5 S.80 6.85 6.90 3.95 9.00 9.05 9.10 9.15
M 1 n
Data F i 1 a : /chem/5972ho64 . 1 .'DF02031096*4. b/HL.1Injection Date: 10-MAR-2002 17:23Instrument: '5972ho64.iClient Sample ID: 55TD050
mpound: 5 Numoe
N-li 11 roei: '321-64
N-prnpu 1 am i ne
6.4-
4.9-
4.4-
4.0 -
3. b-
1 . b-
1.2.
0.8-
0310A64 . d
'0.00: Area: 110300 Height: 65240
airvCD
03
I
•5.4 c. 5 3.6 8.7 6.0 8.9 9.0 * I
____________________________________________________________________________ Min___________________________, Ion 130.00: Area: 0 Height: 0
I
I
I!I
' I
!
/
9.1 9.3
' • f 9.1
T'rv•r-
13
lgn:: u
c,
M i n
51 o
9.0 Q.i Q.2 9.3 ;
!
8.9
pound: 4-Chlo-opneny 1 -pheny letter Number: ?005-72-3
Ion 204.00: nrea: 272646 Height: 189974i . 9-
1.8-.
1 . ~
1.6
l .S';
1 .4-
1.3-;
1
1.1;
f 1 ■2 0.9-:
Data File: .• chem/5972'np&4 . 1 / DF02031 0964. b/HLOI‘0310964.0Injection Date: 10-MwR-2002 17:23Instrument: 5972hp64.iClient Sample ID: SSTD050
l
R-
0 . o
0.5-
0 . 4
13.7 13.9 13.9 M.O 14.1 14.2 14.3 14.4 14.5 I
________________________________________________ M i n____________________________________________________________________________ _____________Ion 206.00: 0 Height: 0
i
I
- I2.4 |
I
• 5 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50
neignr: 0
'5 14
o
:5 , 40 14.45 14.50
Data F: 1 a: .'cnem/5972hD64. 1. DFInjection Data: 1Q-MftR-2002 17Instrunent: 5?72hp64 . lClient Sample ID: 35TD050
029310964. b/H!_0203l0964 .d
pound: Benzo(k > Fluor anrnene r5 Mumper; 207-08-9
Ion 252.00: wrea: 828138 Height: 359300
2.0-
1.0-
1.6-
1 . 4-"
1 . 2
1.0-'
0.8-
0.6-
21.6 21.8 HI .9 22.0 22.1
Ion 253.00: 9rea: 16830' Heignt: 74332
>;•. _ 4
0. 0
J16‘
f
bl/1 1
Data File: cnem • = ?_,2hp64 . : •Injection Date: 10-l":2-
I nst rjnen r : ,5 ? “’I hp64 . 1 Client Sample ID: S5TD050
mpound: I ndeno . l.J.D-cd,1 pyrene :. Number; l?3-7?-5
1.2-
1.1-
1.0
0. ?••
o.a-
'64 . b- nL:
Ion 276.00: Area: 4b54S6 Height: 125664
*T
ui'.co
25.1 25.2 25.3 25.4
35 25.40 25.45 2';i. 50
'5lo
"<= i'i“ ?n 1"ic, 1 c, -c,25.20 25.25 25.30 25.35 25.40 25.45 25.:
Data File: /chem/5972hp64. i/DF020310fi64.tj/HG020310A£4.i-J
Date : 10-MAR-2002 14;16
Client ID: SSTD080 I nstrument: 597£hp6*4. i o~>
Sample Info: t—i
Volume Injected <uL>: 1.0 Operator: 2319 LO
Column phase: RTX-5 Column diameter: 0.32
Pbenanthrene-dlO+
Data File: 7chem/5972hp64. i7DF020310A64.b/HG020310A64.d
Date : 10-MAR-2002 14:16
Client ID: SSTD080 Instrument: 5972hp64.i
Sample Info;
Volume Injected <uL>: 1.0 Operator: 2319
Column phase: RTX-5 Column diameter: 0.32
C\J1-0
2chem/5972hp64.i7DF020310A64.b/HG020310A64.d (Part 2 of 2t
Data File: /chem/5972hp64.i/DF020310A64.b/HG02031CA64.dReport Date: ll-Mar-2030 14:32
CompuChem
SSTD080 10 -MAR- 2 0 0 2 2319
Data file Lab Smp ; Id Inj Date Operator Smp Info Misc Info Comment ■Method Meth Date Cal Date Als bottle Dil Factpr: 1.00000 Integrator: HP RTE Target Version: 3.50Processing Host: einstein
Semivolatile Report SW-846 Method 8270C /chem/5 972hp64.i/DF020310A64.b/HG02 0310A64.d
Client Smp ID: SSTD08014 : 16
Inst ID: 5972hp64.i
/chem/5 9 72hp64.i/DF02 0310A64,b/8 2 7 0Cv6.m ll-Mar-2030 14:32 frankson Quant Type: ISTD10-MAR-2002 14:16 Cal File: HG020310A64.d2 Calibration Sample, Level:
Compound Sublist: all.sub
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
uir
Vt
VcVi'
1.00000
1000.00000
1000 .00000
1.00000
Dilution Factor Volume of final extract (uL) Volume of sample extracted (mL) Volume injected (uL)
Cpnd Variable Local Compound Variable
AMOUNTS
•I CAN. ?i j cal-amt ON-COL
•• •• •• jZ X X- REL XT RESPONSE ; NG) i NG) SIMILARITY
r. i;.:- - 106:5 9 40.0000
2 N,v.y.: . i- 4 .■ :4 ■ 4 1 ? 2 1 C 40.0000
• Ac':;;.: : . : - / :■.> ■■ 2:-: j4 40.0000
4 3: : ' •- 4-:- .: . O . O C 4 4 0.0000
: :: : c 2 g 4 0.000 02::. •; : 4T. !; 4 0.0000 IHJ
1 - / . . :.2 - ;■ ■. 7 - 271242 5 o . o: c 0 a o . c c
- . - . 35362: ao. cooe 80.00
•- ■ : _ . c :■ r isss::- a o . c o o o 50.00
• •; 7 z n p c c C . 0 0 0 0 9 0.00
: : : •' *. • 4: 239975 9 0 . 0000 ao. oo
-■ ■ 1 2 G 5 0 2 5 80 0000 ao. oo
: 2 -- : 1 2 7 X 80 0000 a o.oo a 71 -j
.4 7 . : . : ; 4 b 9 8 0 . 0000 a o.oo 9 56 S
521
!I
Data File: /chem/5972hp64.i/DF020310A64.b/HG020310A64.dReport Date: ll-Mar-2030 14:32
Compounds
CUANT SIG
MASS
15 Eenzaidehytie
16 Phenol ,
17 Bis(2 -ch1o roe t hyi) e zher
IB 2-Ch1orophenoJ
15 1 , 2 - D: chlorobenzene
2-.' I , 4 -D: :hlororenrene
Benzyl alcc-nol
2 2 1.2 -Dichlorobenzene
21 2 - Met hy 1 phen.o 1
IN 2,2'-oxybis'1 - Chicropropane)
25 Acetophenone
26 3 -Methylpher.ol
27 4 -Methylpher.ol
2 8 N - N : t rose- - d ] - N - prop-y lam me
2 9 Hexachicroet har.e
'• 0 N: t rocer.zene
: 1 Isopncione
: 1 2 - N: z ropnenc :
77
?4
28
1 0 8
14 6
100
4 5
1 05
108
103
TQ
1 1 7
Nap.n: r.a
r. e x a c r.:
Capro:£
: rottr. ;«o : - r.-e
127
r'c
RT
7 . 776
7 .694
7.996
6.216
6.263
8 .469
3.571
5 . 638
9.672
?. . 37S
6 . 824
3 . 924
8 . 3^5
9.010
o • n g
3.602
5 . 7 04
AMOUNTS
CAL-AMT ON-COL
? RT RE L RT RESPONSE ( NG) NG) SIMILARITY
7 . 641 (n . 524 j 183909 90 . 0000 30 . 00 95 16
7 . 776 10 . 941) 306128 so . 0000 8 0 . 00
7 . 394 I 0 . 955) 207109 30 . 0000 00
7 . 996 (0 . 967) 233461 3 0 . 0000 a:- . 0 0 9 6 66
6 . 2 i ’3 . 994 ) 326246 5 0 0000 6'1 00
3 .25? ' 1 0 02 ' 333767 3 0 0000 8 5 0 0
3 4 o 5 1: 02 5) 1 6 9 6 6 1 0 0 0000 80 2 0
o 571 (i 0 3’’) 320414 6 0 0000 30 OO
0 6 3 3 (1 04 5' 237000 80 0000 80 00
8 672 :i 049' 378746 80 0000 80 00 9164
8 875 (i 074 ) 347948 80 0000 80 OC 8240
S 324 (1 067) 267213 80 0000 80 00
6 824 11 067) 267213 80 0000 80 00
•3 875 11 074) 162945 80 0000 80 00 7171
Q 010 11 0901 170719 80 0000 80 00 9517
G 22 9 ' 0 9 0 C 1 285815 80 . 0000 90 . 00 9672
•7 4 50 ■ c 932: 556109 80 . 0000 80 . 00 94 07
602 10 94 7 t 177032 80 . 0000 80 . 00 94 16
9 . 6 02 ;o 947 ; 260625 30 . 0000 80 . 00 7744
r 754 c 9 6 2.' 333480 80 . 0000 80 . 00 94 97
3 94 <' } 4 n •• 279037 80 . 0000 80 . 00
:. 075 . 0 593 ) 317936 30 . ocoo 80 . 00
: c. L7-7 ■ i. 003? 219022S 90. 0000 80 . 00 9689
1 o. :s: -:. 012 1 387424 80 . 0000 80 . 00 8203
4 1 3 'i. 027) 221086 80 . 0000 80 . 00 9393
10 7 16 V . 057) 9B014 30 . 0000 80 . 00 9722
K ■ 9 3 5 ■ 0 7 ? i 3 C 7 6 7 2 80 . 000c 80 . 00 97 32
•; - L < . 1 0 7 ) 596306 60 . 0 2 0 0 80 . 00
4 1 125 : 5 B 116 3 30 . 0 0 0 0 80 . 00
5 9 7 1; 243425 80 . 00 00 3 0 . 00 9 06 5
7 4 9 852 • 246461 80 . 0000 80 . 00
5 54 l-j a 5: 259845 30 . 0000 ec. 00
• r. ' 7; :• 17 '• 7C8392 80 . 0000 30 00 7 54 6
2 1 2 5 2 0 1 600948 30 0000 eo OC
: 2 : ; 1 ■ 5 ? 7 217120 SO 0000 8 0 00 96 34
12 ' -7 r. 36? ■ 725308 80 0 0 c 0 30 00 9365
2 -74 ■ 203S45 50 0 000 80 00 94 14
3 n •. v ; 1 1410309 a C 0000 80 OC 927 9
•a? 213346 b<:/. 000 8 9/. 5 5354
2 2 :-04. 5 2 015 3 = "■ 000 0 3 C 00 0 n 1 6
: " = : 15 7 5 5 O' 4 0C .000 4 0
1 2 ■ : :■ 5 7 :■ 0000 9 0 72:;
r. : ■ ■::a 2 a1;: c 0 0 0 a 5 -j 9 9 9 5
4 7.: 2 • 5 2 7 03 6 80 0 0 00 3 0 9552
- j 2 5 5. 542152 a; 0 0 0 0 as 9 0 9 7 5 5
'.4 ■ 4 0 7 4 12 a '1 C 0 0 0 b: DC
T ' 1 0 3 1 7 1 - ‘j 0 <j 0 0 OO 112':
sT
52
Data File: /chem/5972hp64.i/DF020310A64.b/HG020310A64.dReport Date: ll-Mar-2030 14:32
Compounds
QUANT s:g
MASS RT EXP RT REL RT RESPONSE
AMOUNTS
CAL-AMT
{ NG)
CN- COL
[ NG) SIMILARITY
6 2 4 - Nit roan: : ir-.e 133 14.116 14.116 f1.072 > 22 1 7 8 S SO.0000 80 00 9220
63 4 , 3 - Dm 11 ro - 2 - mo thy 1 phenol 19 8 14.164 14.184 (0.916) 212659 80.0000 90.00 3844
6 ‘l N-Nit rosoaipnen/iamine 16 9 14.201 14.201 ' C . 917) 530029 80.0000 80 00 3976
6 5 1,2-Dipnenv:hydra zine 77 14 . 251 14 251 (1 . 082 i 363349 30.0000 30.00 9422
6 6 4 -Bromophenyl-cheny1 ether 243 14.775 14.775 : 0.9 54) 256313 80.0000 90.00 3572
•3 7 H e :< a c h ir o r o benzene 23 4 15 . 02 9 15.029 (0.971) 3116 5 6’ 80.0000 60.00 916 7
3 9 At ra z i r.e :ac i; 16.012 (0.969■ 244606 30.0000 3 0.00 9 14 3
5 9 Pent ach ' c : jpr:-1 266 15.233 15.263 \ C.997) 221370 9 C . 0 0 0 0 30 . 00 3 6 3 0
7 0 Phenant’hrer.e m? 15.515 15.519 (1.002) 1763994 80 . 0000 80 . 00
71 An t h r a c e n e 1 7 S 15.537 15.597 11.007) 1807941 80.0000 80.00
7 ^ C3ixazoie 16 7 15 . 307 15.807 (1.021) 1227719 80.000C 80.00 9457
73 D i - n - bu t i pht ha late 14 9 16.229 16 . 229 (1.048) 1811649 80.0000 80.00 9543
74 Fluoranthene 2C2 17.278 17.278 (1.115) 2054576 80.0000 80.00
It Benzidine 184 17.430 17.430 (0.973) 1273220 160.000 160.0 3647
•X Pyrene 2 02 17.693 17.683 ( C . 5 8 6 ) 2167993 80.0000 80.00
77 Buty ibenzy 1 phtna ;ate 14 9 19.916 1 S . S 1 6 (0.942) 502911 80.0000 80.00 9673
7 6 3.3' -Dicn1crooen zidine 252 19.847 1 9 847 < 0.994 i 624855 80.0000 80.00 7917
1 c bis i 2 • ethv lhe>:v: . Phtna late 14 9 19.797 1 9 79 7 ■0.952: 1326967 80 . 0000 80.00 913 3
3 Benzo . a . an: racen.e 2 o - 1 9 9 3 2 19 -32 ■ C 9 9 S ; 2046890 30.0000 80.00
n Thr/anne 2 2 8 2 0 216 2 0 1 5 ;:. 003) 1929267 SO.0000 80.00
n —•i • n • y :iA.AT-r : ■; ■? :: 7-:o 2 0 .760 ■0.923; 1413191 80.0000 80.00
r :■ Benzc . .?■ : „ t:: rant n.ene 252 2 : 7 0 7 2 : ' 0 7 '0.965' 1154198 80.0000 80.00 : W
Benzc ■ x .- : .uz>r ant nmr.e 2 5 2. 21.74: 21 "41 ' 0.9 6 6 i 1335389 80 . 0000 80.00| Be.nzo a t y'. rr.-. 2 3 2 22.543 22.543 . C . 5 9 3 i 1040333 80.0000 80.00 • (HI
r ^ Inoeno • 1 . 2 . - : j . ovrere * 7 r "> C. ATS nr n : a ; 1 . 115 : 729107 80.0000 80.00 0 iM'
3-, Dibenzo a . r. ■ =mr nrazene 17- 25.036 25.038 '1.115) 830952 80.0000 80.00 82 81
*' 3 Benzc 3,:..: nervlene 2 ~ ~ 2 5 . 5 6 6 ' - A - •: 1 . 15 0 : 929697 80.0000 80.00 9 37 7I
QC Flag ^LegendI
A - Target compound detected but, quantitated amount exceeded maximum amount.
M - Compound response manually integrated.H - Operator selected an alternate compound hit.
523
D3ta File: ''chem/5972hp6 4 . i / DF 02031 0h64 . P/HG020310064 . dInjection Date: 10-MOR-2002 1*4:16Instrument: 5972hp64. iClient Samole' ID: 55TD080
ipound:I Number
Perglene-dl2 : 1520-96-3
' Ion 264.00: Prea: 309056 Height: 137792
ihi. j- 1
i* *j1 2- c'*
1.1.
IT’ . _U f
0.6-
> 0.5-
0.4
!j
1
21.95 22.00 22.05 22. 10 22.15 22.20 22.25 22.30 22,35 22.40 22.45 22.50 22.55 22.60 22.65 22.70 22.75 22.80 22.85 22.90
■_______ M i r.Ion 260.00: wrea: 6“596 heignt: 30464
• J i?n
3-
1 . o
i
;5 2? . •• j 22.45 22.50 22.55 22.60 22.65 22.70 22.75 22.80 22.85 22.90
o 22.60
— 522.70 22.75 22.80 22.85 22.90
i
!Data File: /dnem/5972hp64 . i /DFO Injection Date; l0-Mwp.-2002 14: Instrument: 5972hp64.i Client Sample ID: 3STD030
pouna: Number
4-'thlaropheny1-pheng17005-72-2
20310.lb
ether
Hb HG020310P64.a
Ion 204.00: nrea: 407612 Height: 259066
S
o
1.6-'
1.6-
ir', 1.4-
7 1.2-
1.0-
0.3-
0. o-
.55 13.60 13.65 13.70 13.75 13.80 13.85 13.90 13.95 14.00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50Min ___ ________ ___________ ___________ ______ ____________________________________
Ion 206.00: Hrea: 0 Height: 0
cd
14.2 *. 4
f
l
52 o
1 4 .14.3 14.4
I
Data File: /chem/5972hp64.1 /DF020310h64 . b/HG0203l0A64. dInjection Date: IO-MhR-2002 1*4:16Instrument: 5972np64.iClient Sample ID: S5TD080
pound: Benzo<b■fluoranthene Mumper: 205-99-2
Ion 252.00: 115*4198 neignt: 5076*40
4.8-
4.5-
4.2-
3.9-
2.4-
2.1-
2 . 9-
; .5-
1 .2-
0.9-
0.6-
0.0-------21.20 21. 30 21.35 21.40 21.45 21.50 21.55 21.60 21.65 21.70 21.75 21.80 21 .£5 21.90 21.95 22.00 22.05 22.10 22.15
____________________________________________________________ Min _______________________________________________________________________________
Ion 253.00: Area: 252200 Height: 111202
f«j
55 21 .90 21.95
i4
5.0
I
I
1.90 21.85 21 .90 21.95 22.00 22.05 22.10 22.15
I
Data F : i ? : . rhem-'S:i7 2'noh4 . i /DF020310064 . p.-'hi Injection Date: 1 0-M-F.-2002 14; 16 Instrument: 5?72hp6J.i Client Sample ID: 5STD090
Impound : Benzo < 5 ' py ne^
FS NurnDf': 50-32-6
10064 . d
Ion 2o2.00: Area: 1040333 Height: 399805
1 .2-
0 4 •
Ion 253.00: wrea: 224399 Height: 85064
3.5-
5 . >j
.60 ' .80
I
:5 22.40 22.45 22.50 22.55 22.60 22.65 22.7
527
i
usta File: ''chem/5972hp64 . 1 .'DF020310064 . b/HG0203 10h64 . dInjection Date: i0-MwF>2002 14:16Instrument: 597-2hpb4 . iClient Sample ID: S3TD080
impound WS Numb'
Indeno : 193-
a)pu rene
1 .;
Ion 236.00: Area: 328107 Height: 173577
cn >
1 .4-
1 . 3
1. U-
55 24.60 24.65 24 . “V. 24.75 24.00 24.85 24.90 24.95 25'.00 25.05 25.10 25.15 25.20 25.25 25.30 25.35 25.40 25.45 25.50;____ ______ _____ __________ ____ ___ M 1 r.__________ __________________________ _____________ ______
Ion 138.00: Area: Height: 0
!
•n
'5.5
\
52o
25.4 25.5
Data File: /chem/5972hp64.i/DF020310A64 .b/HJ020310AC4 . d
Date : 10-MAR-2002 let*'/?
Cl ient ID: SSTDlcO Instrument: 5972hp64* i :.nSample Info: C\JVolume Injected <uL>: lt0 Operator: 2319 ldColumn phase: RTX-5 Column diameter: 0.32
(xlO-
Data File: /chem75372hp64.i/DF020310A€.4,b/HJ020310AC4.d
Date : 10-MAR-2002 1C; 03
Client ID: SSTD120
Sample Info:
Volume Injected <uL>: 1,0
Column phase; RTX-5
Instrument: 5972hpC4.i
Operator: 2313
Column diameter: 0,32
4.1-
4.0- ;
3.9-:
3.8- i3.7- 1
3.6- i3.5- i
3.4- :3.3- j
3.2- :
3*1-1
3.OH2.9- 1
2.8- i
2.7- ;
2.6- i2.5- j
2.4- i
2.3- ; 2.2-!
■f 2.1-
2.OH
1.9- :
^ 1.8-;
1.7-1.6- i
1.5-1.4- 1
1.3- :
1.2-;
1.1- j
1.0-j
0.9H
0.8H
0.7-:
o.6::o.c-i6.4- ;
0.3-i
0.2-
/chem/5972hp64.i/DF020310A64.b/HJ020310A64.d (Part 2 of 2>
17 18 19
b3U
Data File: /chem/5972hpb4 . i/DF0203 10A64 . b/'H J02 0 3 10A64 . dReport D|ate : ll-Mar-2030 14:32
CompuChem
Data file Lab Smp Id Inj Datei Operator Smp Info Misc Info
Semivolatile Report /chem/5972hp64.i/DF020310A64 SSTD12010 -MAR-2002 16:09 2319
CommentMethod /chem/5972Meth Date Cal Date' Als bottle Dil Factor Integrator Target Vers
11-Mar- 2 03 1C-MAR-200 51 . 00000 HP RTE on: 3.50
hp6 4 0 14 2 16
Processing Host : emstein
i/DF020310A64 32 frankson 09
SW-846 Method 8270C .b/HJ020310A64.d Client Smp ID: SSTD120
Inst ID: 5972hp64.i
,b/8270Cv6.m Quant Type: ISTDCal File: HJ020310A64.d Calibration Sample, Level
Compound Sublist: all.sub
5
Concentration
Name
Formula: Amt
Value
* DF * Vt/(Vo * Vi)
Description
* CpndVariable
DF 1.00000 Dilution FactorVt, 1000.00000 Volume of final extract (uL)
4b Vo’ 1000.00000 Volume of sample extracted (mL)w Vi | 1 . 00000 Volume injected (uL)
Cpnd Variable Local Compound Variable
: 93557
■',292 4 5
■ 25 32 l
235222
-14S44
CAL-AMT
{ NG«
ON-COI,
( NG)
4 0.000G
4 0 . COCO
40.00‘-
4 0 . CO"; .'
. oc
40 . 0000
12 0 . 0 00 113.5
120 . 000 115.4
120.0C0 117.1
120 000 11 G . 3
i o c .ooo 115.2
12 J . 00 0 108.1
1 2 C . 0 0 C 11 9 . G
t J o o 115 . 5
■:A
I
531
$
Data File: /chem/5972hp64.i/DF020310A64.b/HJ020310A64.dReport Eiate : ll-Mar-2030 14:32
Compounds MASS
15 Benzaidenyde 77
16 Phenol 94
17 Bis:2-chloroethyl)ether S3
18 2-Chlorophenol 128
19 1.3 - Dichlorobenzene 146
20 1.4-Dichlorobenzene 146
21 Benzyl alcohol 10S
22 1.2-D:chiorobenzene 146
23 2-Methyipnenol 108
2 4 2,2' -oxycis ; 1 -Chloropropsne) 45
25 Acetophenone 105
26 3-Methylphenoi 10S
27 4-Metnylphencl 108
28 N - N11roso-dN-propylamine io
25 Hexachioroetbane 117
3G Nitrobenzene
3 1 Iscpnoror.e =2
AMOUNTS
CAL-AMT ON-COL
RT EXP RT REL RT RESPONSE ( NG) ( NG) SIMILARITY
7.642 7.642 : C.924 } 266817 120.000 115.8 9794
7 . 777 7.777 '0.54 1) 459392 120.000 1.1 7.5
7 . 912 7 912 (0.957) 313182 120.000 115.5
7.957 7 997 (0.967) 431539 120 000 11 r . 8 56 8 6
8 .217 8.217 (0.954) 499684 120.000 117 . 2
8 . 284 3.284 (1.002; 455146
oooo113 . 9
8.470 8.470 (1.025) 255545 120.000 110.3
8.572 6 . 572 (1.037; 484421 120.000 117.0
■'.539 9 .539 :i.045) 375924 120.000 118 .8
.■3.673 S . 6 7 3 (1.049) 577559 120.000 117 . 2 9110
8.876 8.876 (1.074) 536248 12 C.000 117.6 8803
0 . 642 8.842 (1.070) 405298 120.000 117.8
8.842 8 . 842 (1.070) 405298 120.000 117.8
8 . t 9 ' 8 . 893 (1.076) 255772 120.000 117.2 9171
a 3 -i 9.011 ■; 1 . 0 9 0 ) 254226 120.000 116.7 9522
9 1 3 C 9.130 10.900) 412249 120.000 112.9 9696
9.451 9.451 (0.532) 520376 120.000 113.7 94 36
9 6 03 r . s 0 3 iO.547} 264 942 120.000 115.1 8 4 6 6
5 5 0 3 9 . 603 ■0.947: 391585 120.000 114.6 7536 [
9.706 5.755 ■0 962' 438405 120.0C0 113 . 9 9509
-. 54: 5 . 34 : : o. 98 0■ 412119 12C.C0C 115.9
0 . '70 i . ; n 6 ■■0.993) 471217 120.000 114.9
■; 17 10.175 ■' 1 . 0 0 3 ■ 1722036 120.000 112.0 9714
0.262 10.262 . 012) 567085 120.000 114 . 1 S255
0 . A l i 10.415 .1.027: 325758 120 . OOC 115.0 9365
0 7 10.736 .1.358) 140902 120.000 114.6 9716
0.93 5 1 0 9 3 5 ;i.Q73) ■ 451013 120.000 113.6 9806
2 2- 11.226 !1.107) 383265 120.000 113 . 7
1 . 4 1: 11.412 (i.125; 341198 120.000 114.6
1 5 5- 11.5 9 3 ! 0 . 881 ) 360792 120.000 117.7 9162
1 .751 11 .750 10 .692) 351806 120.CC0 113.5
i . 5 : l 11.635 ■0.595; 378722 120.000 114 . 5
2 . 0 1 : 12 071 ip yj; 1027207 120.000 113.6 7575
:.:: i 12 12 2 ‘0.320) 865773 120.000 112.6
2 J 7 1 Z. ■■:. :• 3 ■-:.- 325632 120 . 000 116.2 9 3 2 -■■
2 . ■ - 12.6s.' 3. 1069125 120.000 113.2 9506
-. r-« 11.647 i i* a"; 2 CBS 11 :2C.000 117.3 84 7 V
i. - -• 1 2 . :i -7 r. \ 2J22751 125.000 112.3 9557
3. •27905 120.000 14 9.0 be?-:
::i 1 '• 2 2 l ' 1 . ■ 7.4 ' 1319556 i:■■■■. .ooc !l!.i
: 1 : . 7 7 3 ;l too. : 1 C 3 1 6 6 0 :J . 0 U 0 6 3 1 . ’•)
2 202770 1 7: ■ j . OOC 119.7 Sir 3
-• 7 -. 3 1.72". 4 4 5 3 1 0 15.0 . 000 116." 3 1 5 1
:. 4: : ■ . 4r-1 -;.: 1375412 12 0.000 112. j i ■ jn
:■ .T ' 77.- • ■' c 4 1 2 7 c 2 1 4 120 . 000 114.2 2 0 1
I . .1 4 ■. 1 . :) 6 4 ; 59-739 120.000 119. 6 0
•; ' • C r 1 -J 12 0 . OOC If: . 3 v 5 6 4
Data File: /chem/5972hp64.i/DF020310A64.b/HJ020310A64.dReport Date: ll-Mar-2030 14:32
AMOUNTS
1 s:g 'vAl - AM 1 ON-COL
Compounds ; MASS P.T ryp py PEL PT .RESPONSE : ng) { NG) SIMILARITY
o «: l.} B 14 117 14 . 117 :1.372- 343642 120.000 117. 3 29
c 3 6 . 6 - 2it.: t ro- 2 -T.er. hy 1 phene’ 1 ? 6 14 .18 5 14 1 S E • 0 . 9 16 • 315645 1 2 0 C 0 C 120.9 0
5-i N-Ninrosedlpheny1 amine 14 .215 14.215 (C.915 ) 762705 120.000 113.1 •; ■„ • 2
65 1,2-DiphenyIhydrazine 77 14 2 6 5 14.26? (1.083) 1255476 120.000 111 . 5 S 9 9 9
o 6 6 -Bromcpnenyl-pnenylecher 26 3 14 . 777 14 777 (0.954) 3 7IQS 120 000 .111.1 c s; 3
6 7 Hexachlorobenzene 286 15.047 15.047 (0.972) 447461 120.000 110.4 8 5 90
6 5 Atrazir.e 2 C 0 15.03 r 15.030 ! 0 . 5 7 1) 34 C 6?9 120.000 1 ■9 . 9 94 0 9
6 9 ? e r. c a c h. 1 o r c p h e r. o 1 ■HS 15.284 15.284 (0.987) 323286 120.000 115.1 8 8':..
7'} Phenar.ihrer.e 1 7 £ 15 . 520 15.520 (1.002) 24 911 “4 120.000 107 . 5
7; Ancnracene i 78 15 . 588 15.589 i 1 . 0 0 7 ) 2483918 120.000 106.3
7 2 Ca rba zo 2 e 16 7 15.908 15.80S (1.021) 1733802 120.000 111.0 9542
“U Di * n - bdeyIpht ha laze ■ 4 9 16.230 ■ 15.23 0 (1.043) 2514493 120.000 10 8. 1 9 6 6 6
P1 j o r 3 n c h e r. e 17.279 17.279 ! 1 . 116) 2942800 120.000 109.8
't Sens: z:r.e : 4 17.431 17.431 1 C . 8 7 3 '■ 1930020 240.000 228.2 8725
76 Pyrene , 2C2 1 7 701 17.701 :0.887) 3096955 120.000 109.6
11 Bu z y 1 be r zy: p.nz ha laze 14 9 15.917 16.917 ( 0.9421 1279313 120.000 110 . 3 9664
’t 1 J 2 5 2 19.643 s : 0.994. 913695 120.000 112.0 7906
ois -2 • e-.nyir.exy: J Pnzha laze 19.795 1 9 79? • 0.992! 1914934 120.000 111.5 9151
B e r. z ?. a a r. z m a c e n e 226 19.935 15.983 ■0.993: 2894006 120.000 109 .4
:'••• • 2 2r. 2 0 01 £ 21 Olr. (1.003) 2676624 120.000 108 6
14 9 2 0 . "• 7 8 2 0 77 l ; 0 . 9 2 5 ) 2051396 120.000 115 . 1
: Benzc c ■ : in: rant ner.e 2^-7 21.705 31. 7:: 5 [0.967; 2075039 120.000 122 . G (
-> 4 3tr.:;,k';:.»rjr,:h{w 25 2 21.755 21.739 •0.969) 1580562 120.000 104.6
Btnzz a py : £ 12 . 5 5 : ■ 0.9 95' 154 133 5 120.000 114.5Inder.o} : . 2 . ' r..i. pyrene
7 •. 5 ■: 2 5. ?5 6 ••1.116) 1112109 120 000 115.5 0 :
- ,, .. . > •; : “) c i C. P 1C •- ^; ■ • - i ; 1 1352076 120 000 8 367
9 315- - o : p-rv. -r::-.- j ~! :■ 2 t . r r. 4 2 4 ... : 4 j 1410258 120 . 000 115.3
QC FlaaiLegend i
M - Compound response manually integrated.H - Operator selected an alternate compound hit
i
i
53 J
Data Tila: .•'•ihem/5972hp64. 1 /DF020310A6- . p/H J0203 10964 . d I r,j ec 11 on [lata: iO-MhR-20C'2 16:09 Instrument: 5972hp64. 1
21ient Sample jp: 55^2120
Impound: 2.4,Is Number: 11
TriprnmophercI
I On '9.60 area 343433
a1
T
Height '44320
1.6-
1 . -J-lPo 1.2-
1.0-'
0.3-
0. a-
14.00 id.Of. id.:0 Id.15 1d.20 Id.25 14.30 14.35 14.40 id.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.85 14.90 14.95 ■
___________________________________________________________Min____________________________________________________Ion 332.00: area: 0 height: 0
' I
CD
14.45 Id.50 14.55 14.60 14.65 14.70 14.75 14.80 14.05 14.90 14.53
5^:a. JO ;d.~6 1 a . Jp I a. 50 14.55 14.60 1*4.65 14.70 14.75 14.30 14.65 14.90 14.95
:031C'w64.nData- File: .'cnerr- 59^21'o64 . 1 ■'
Injection Oat e: 1 0-M4R-2002Instrument; 5972hpo4.iClient Sample ID: 58TD120
mpound:5 Number
4-Dimethuionenol105-67-9'
nli
2.0
1.8-
1 . 6
1 .4-
.b-i.o--H.-02
Ion 122.00: ^rea: 391585 Height: 200158
okD
■T>
1.0
0.4-
9.35 9.-10 9.45 9.50 9.55 9.60 9.65 9.70 9.75 9.80 9.85 9.90 9.95 10.00 10.05
______________________________________ Min______________________________________________________________________ _______________Ion 107.00: Hrea: 229419 Heignt: 229419
rciO
O’-
1 .8
I|
I
9.0 3 9.70 9.75 9 . SO 9.85 9.90 9.95 1 0.00 10.05
Ion IC'I.I'O: wea: I '-66: 9 Mei*nt: 106819
b3b
9.90 9.9c. 1 0.00 10.0580 9.95
Data Fjie: ,'cHem/5972hp64. l ••'DF020310h64 . b/H J' Injection Date: iO-mhR-2002 16:0?Instrument: 5972np6J. :Client Sample ID: SSTD120
pound: 4-rnloropher>ul-phpnyleth~'rS Number: 7005-72-3
'0310*64. d
3.9-
3.6-
3.3-
3.0-
Ion 204.00: Area: 593738 Height: 412495
O
2.1-
1.8
1 .5
1.2
i*i a..’
0 n'
U. :■
.'i n... ____
.65 13. .'0 13.35 13.80 13.85 13.90 13.95 1- .00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50i
M i r ____________________________________________
Ion 206.00: nrea: Height: 0
I! 4 1 4 . n
53b
1 J.1 14.2 14.3 14.4 14.5
I
Lat 5 riie: 'cner, 5'r’. i -'■ 731Injection Date: i0-MwF:-2002 lb:0911*,« t rument : 5?72hp64. :Client Sample ID: 55TD120
. c-mCOI'OCIO^SJ.c
pound : - . 6-Din i r no-2-methy lpheno 1 S Number: 534-52-1
Ion 198.00: Orea: 319645 Height: 230920
$
1.9-
1 . 4
Ii
i
1 . 2-
1.0-
i j . 4 -
n. : •
l j 13.85 90 95 1 00 14.Q5 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65
_______________________M i n______________ _____________________________________1 an 51.00: Hrea: 0 Haight: 0
l
14.35 14.40 14.45 14.50 14.55 14.60 14.6-5
I
l
i
l14.25 14 :5 14.40 14.45 14.50 14.55 14.60 14.6514
Data File: /cnem/5972hp64.i/DFiInjection Date: IO-MhP-2002 16Instrument: 5972hp64.1Client Sample ID: S5T0120
pound:Mumper
Benzo '• b ) F luoranthene: 205-99-2
'031iQ
iJ . b/HJ020310m64 . d
| Ion 252.00: drea: ^0750j>9 Height: 629376
i6.0J
o?7 5- o
• T 1."•J
6.5-
6.0
5.5- ( ' ■■
5.0: . ■
in 4.5-
' 4.0 - ;
~ 3.5-: !
i7 |‘|.
2 5- i2.0- ! 1
1.5- ‘
0.5
21.25 2: . 30 2i .35 21.40 21.45 21.50 21.55 21.60 21.65 21.70 21.75 21 .SO 21.05 21.90 21^95 22.00 22.05 221 10 221 15
_____________________ M i n_________________________________________________________________Ion 253.00: jr-ea: 454365 Heignt: 138250
ip
1 . d
1 . 6
: 1
S5 21 . "0 21 . 75 2! . ?0 21 .85 21.90 21.95 22.00 22.05 22.10 22.15
>1; r_______________________________________________________________________________________________
II 1:01 ^ H r l fcn t; 56489
■X:
53 o
15 21.90 21.35 2;. 00 22.05 22.10 22.15
pound: Indeno<1.2.3-cd)pyrene Mumper: 193-39-5
Data File: /chem/5972hp64 . i .'BF02031 0h64 . b/H J020310064 . dInjection Date: 10-M£R“2002 16:09Instrument: 5972ho64.1Client Sample ID: S5TD120
! Ion 276.00: Area: 1112109 Height: 240268
<o2 4-' ID
o
' LP- . - - t • f.J
1.0-
1 . 4-ll"O 1.2 ■
1.0-
0.8-'
0.6-
i J . 4 •
0.0------24.55 24.60 24.65 24 . tyj 24.75 24.80 24.85 24.90 24.95 25.00 25.05 25.10 25 ! 15 25 ! 20 25.25 25.30 25.35 25.40 25.45 25.50
Min ___________________________lor. 138.00: 4rea: Helcht:
'5.2 25 4 2b.5
o4l>
560-
520
400
280
5325.4 25.5
LG
Data File: ^chem/5972hr ' 4 . i/DF020310A64 .b/HH0203K'A£.4 .d
Date : iO-HAR-200.2 1-1; 55
Client ID: SSTD160 Instrument: 5972hpb4.i
Sample Info:
Volume Injected (uL>: 1.0 Operator: 2319
Column phase: RTX-5 Column diameter: 0.32
/chem/5972hpb4.iXDF020310A64.b/HH020310Ab4*d (Part 1 of 2)
4.6-
4.4-
1-0
4.2-
4.0-
3.8-
3.6-
Pk^nar.thr^rie-dlO
Data File: r'chem/5972hp64, i /DF020310A64 ,b/HH020310A64 .d
Date : 10-MAR-2002 14:55
Client ID: SSTD160
Sample Info:
Volume Injected CuLl: 1.0
Column phase: RTX-5
Instrument: 5972hp64.i
Operator: 2319
Column diameter: 0.32
4.7-
4.6 4.5
4.4
4.3-:4.2- |
4.1
4.0 3.9
3.3- |
3.7
3.6-
3.5
3.4
■? ~2
3.2
3,1-i
2* to2.5
2.4
0 ~2
2.1
2. 0 1.‘?
1.3
1,71 .to
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.4
to. £ -0. l
/chett/5972hp£4. i/BF020310A64.b/HH<>20310A64.d (Part 2 of 2)
U tAj -I
l 16 17
■ 'J
18
aj -J L-----
'vf
1-0
)i
19
Data File: /chem/5972hp64.i/DF020310A64.b/HH020310A64.dReport Date: ll-Mar-2030 14:32
CompuChem
Data file Lab Smp Id Inj Date Operator Smp Info Misc Info Comment 'Method Meth Date Cal Date Als bottle Dil Factor Integrator Target Version: Processing Host:
Semivolatile Report SW-846 Method 8270C /chem/5972hp64.i/DF020310A64.b/HH020310A64.d SSTD160 Client Smp ID: SSTD16010-MAR- 2 0 0 2 14:552319 Inst ID: 5972hp64.i
/chem/5972hp64.i/DF020310A64.b/8270Cv6.m
ll-Mar-2030 14:32 frankson Quant Type: ISTD10-MAR- 2 0 0 2 14:55 Cal File: HH020310AS4.d3 Calibration Sample, Level:1.00000
HP RTE Compound Sublist: all.sub3 . 50einstem
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
DFVt
Vc
Vi
1.00000
1000.000001000.000001.00000
Dilution Factor Volume of final extract (uL) Volume of sample extracted (mL) Volume injected (uL)
Cpnd Variable Local Compound Variable
AMOUNTS
7 DAM 7 7 i _• CAL - AMT ON-COL
MASS Z-r ~ A ? 5 Z L .-. T RESPONSE : ( NG) SIMILARITY
- 2 ■■ " - .oo,a 109005 4 0.0 C 0 0
11.: •. : • • • u'.' ‘ 426344 j. o ocoo
• ; - j - : : . r.:; . 3 0 3 5 9 6 40 . C 000
=■ ■ 4 - ■ - 1 -.4 1 . . . C, . 632194 40.C 000
r : y -• :;' i.;:; 90706 5 40.1 0 0 0
22 . . • 220574 4 0.2 000
. . 251590 16.' . 000 159 . 4
.. 994203 15 . 000 157 . 2
. ■ : ■ ■ V ■■ - 702774 ic. 0 0 0 16 7. 0
■-■I.:-.:!- . : .. -- . . - 7 • 1455342 0 0 0 152 .7
-.4 ; ■ - 437753 .60. 000 151.3
. _ ... -■■■ . ■ ,05. 2 1 6 o 0 6 7 15 0 ooc 150 . 1
.; ;• 4 ; 4 - ■; =i 5, . 1 5 9 6 6 7 ] 6 C coo 15 7.-' 3 920
- ;■ •• <4 92 35 160 0 0 161. 0 94 95
Data File: /’chem/5972hp64.1/DF020310A64.b/HH020310A64.dReport Date: ll-Mar-2030 14:32
AMOUNTS
QUANT STG CAL-AMT ON-COL
Compounds MASS RT EM? RT Rs.L RT RESPONSE ( NG) ( NG) SIMILARITY
- ~ i r. 2 ci * 'i -f r. v " £• 7 7 7.656 7.353 (0.926' 334400 160.000 151 . 0 9390
>: Pher.ol 54 7.777 7.777 (0.941! 579549 160 000 154 . 1
5 1 7.512 7 . 512 0 . 957! 420937 160 000 159.9
16 2 - Cr.1 Drr.-pher.D ! 126 S . 0 1 3 3.012 ; r, 9 o o ;■ 563929 160 000 15 5.2 8 9 C 7
15 1, 3 - Ci rhlo-cb-nzer.e 14 5 3.216 5.216 (0.994) 6337Q5 160.000 156 . 3
2 0 1.4-Dicr.:orobenzene i 4 n 8.234 5 .234 (1 .002) 634701 160.000 154 . 6
2 1 Her. zyl alcohol 1 0 5 3.470 3 . 4 7 C (1.025) 326967 160.000 156 . 2
14 5 3.571 5.571 (1.037) 640709 16C.000 158 . 6
23 2-yetbylph-Dc; 10S 8.635 9.63? ; 1 . 04 5) 5 C 034 9 160.C00 163.0 (A)
24 2,2'- : s • 1 - Zr. :c repropane) 4 3 8.673 ?. . r 7 3 (1.04?) 77651C 160.0C0 160.6 9096(A)
-i ? Act; Dphe.po.pf 2 Q c 3 976 9.576 (1.074: 699933 160.000 155.1 9101
26 2 -MecnyIchenc 1 106 3 542 3 . 342 (1.0701 525099 160.000 157.2
2 ■■ -t ~ >‘er. ny . pher.o; 103 6.342 0.342 ( 1 . 070: 525099 1 6 0.0 C 0 157.2
a = N -.. ‘ 1 r. 5 r ■ d . - ,'py - a ("■ i 7 Z -07 4.992 '1.076; 338968 16C . 000 161.6 9 9 2 7 (A:
2 t HcXjT. '/ ;■ I — t to*.-- 1 1 n r 3 11 1.1:. 1 090 1 327077 160.000 15 5.2 94 92
: ::.-vcr-E.-..'e:-.- -.144 c. :• o o ■ 5 £ 1S 5 ~ 1 6 C . 0 0 C 15 7.1 9:; 3
- Isz-pr. r2 1 4 5 9 46" C . 9 3 0 . 1100836 160.000 157.6 94 9 9
1-1 2 -.‘.'iii'Dor'.er.t 3. ; :y 9 . 5 j 3 il . ? 4 5 ; 343734 160.000 156 . 1 8 5 1 4
2 4 - Di---:-:. r.y . pp--:- l 12 2 4.615 :. 94 7 ■ 514972 160.000 157.4 6 6 2 6
i4 Els 2-id . - i-'.-er.n-xy- ?.75 = 7 7 = = '0.960' 630469 160.000 154 . G 9 54 2
ir. ■: 161 2 ■ '34 : 5.-41 0.973- 541196 160.000 156 . 0
:• is: 10.074 : ; 7 4 (0.992: 603114 160.000 154 . 2
: ■ Na pr.: r.a .. -.-r.-z 126 . 177 12 177 . 1 . 002, 227HS7 160.000 154 . 7 974 3
| = 12*7 :o.23: 1 ‘ . 262 1.010) 743327 160.000 155.2 826”
r a:'-.. 2 2 5 10.414 1 0 4:4 11 025' 422026 160.000 154 . V 936?
i.j 10.752 10.7 5 2 ( 1 .056) 194337 160.000 157.8 95 95
- ■■■■■=•■• ■ . : r. 7 10.555 11 . 155 (1 0 7 p} 595061 160.000 155.9 897''.
■■I 2 142 11 2 2 6 11 2 2-. 1 . 10 5) 1164006 150 . 000 156.5
: ■ : - . - 11 4 12 :1 ■ 4 1 2 •. i - 1 C 9 502 0 1 6 0 . 0 0 0 15 3.7
11 30r ii • - • l q i. ; 475256 160 . 000 157 .0 9 G 0 i
;; -7V : y . : *. • 7 ~ 1 11 ’3 :: 3 921 470974 160.000 156.0
3-. . 1-3 * * 7 J 4 . . " .’ -1 : 399. 499943 160 . 00G 155.2
■■ ■■ ■ -S:- . 3 4 1 2 . :• 7 i i" 71 •: .• i_ 1334420 1 6 0 . 0 G C 15 3.8. •; r. -j q
■ - :: : nap . .a-: . 21 •2.122 i;. ::i •: • '? 2 •’ • 1154344 160.000 15 5.1
- '••• 33 i:. 2 = - 1 2 :: 5 •. 0 . ? 2 ■ ' 425580 250.00? 156 . 7 94 5 5
6 : y •••--■•; b.v ! -i: • - ^ c 13 -30 •: ? 41 ■■ 13 9 0 9 1 2 150 . 000 154 . ? 3 5 57
: - - O' . o 4 '711 32 1 6 G . G 0 C 15 7.0 7053
.y:- 12. :• i • 12 .••:; •; 2 160.09? 151.2 -723
-.3- :• ■■ . -79.' 4 z j 2 0 4 1 0 0 . 0 0 2 9 0.2 7-1 = 3 ' A ■
• 2. . ■■■■4 150153] 150 900 147.2 >4 7 :
i : :. ~ i a ■ •1 2 5 7 7 300 . O00 5:7. ;• (A)
1i •.::» 1 2 25556: i 6 0 . 0 C C 154 7 7 51 7
. .027. - “ 1 ^ 'j ■> 1 6 0 . 0 0 C :Si 0 2 0 7 ?■Ai
: t 1 ::■■■■■■:■ ; : 333 1 ■ 4 ■ 1 1756591 150.000 155.3 0 015
■ -- 1 ■■ 5 4 , 15 3 0 9: 16 0.0 c 155.7 9 3 8 9
■■ - 2 •; : 4 : i' ' : ■' 4 4 '■ 754740 1 6 0 . 9 C C 152 . 1 0 '.Ml
1 ■ 1 4 14 6 1 4 • 1 . 06 5■ 1945435 16 0 0 C 0 15) .5 7 355
\$0
54 j
t
Data File: /chem/5972hp64.i/DF020310A64.b/HH020310A64.dReport Date: ll-Mar-2030 14:32
TUAN. 5IG CAL-AMT ON-COL
Compounds mass RT EXP RT REL RT RESPONSE ( NGi t NG) SIMILARITY
62 4-N i zrcar. i 1 me 13 8 14.133 14.133 (1.073! 460576 160.000 161.3 9 2 51
6 3 4 , 6 - Ji n: z ro - 2 - mer r.y 1 phene ] 15? 14.154 14 .134 : 0 . 916) 4 0 4 6 0 3 160.000 155 . 9 0
54 N-Nitrpsodiphenylamine 16 5 14.215 14 .218 (0.918) 988884 160.000 154.4 8009
65 1,2 -Oipher.yih.ydrazine 77 14 .269 14.269 (1.083) 1651424 160.000 1:34 . 7 9175
5 6 4 -3romophen>': -pheny 1 ether 24 c 14.775 14 . 776 (C.954 ) 484539 160 0C0 IBS 4 8963
6 7 Hexach:crober.zene 284 15.045 15.C46 (0.972) 566716 160.000 15Z . 3 3 S 14
6 i Atrazme 200 15.030 15.030 *0.971) 415397 160.000 14 7.0 9384
6 5 Pencach I oropher.c i 266 15.2S3 15.283 (0.937) 420499 160.000 155 . 6 9010
7 c ? h e n a r. t h v e n e 176 15.520 15 . 520 !1.0C2} 3186075 16C.000 151.8
71 Ant h facer.e 173 15 . 587 IS.587 ! 1.007) 3115701 160.000 14 8.0
72 Carcazcle 167 15.807 15 . 3 0 7 i:.C2i) ■2186711 160.000 150. “ 9576
7 3 2 i - n - bury 1 phz La 1 at e 14 9 16.230 16.230 (1.043) 3194338 160.000 149.9 9 6 9 8
74 FI uoranmenc 2 02 17.27? 17.273 (1.116) 3763182 160.000 152 . 5
■b Benz:::- 1 34 17 .447 : 7 . 4 4 7 '0.374: 2467765 320.000 312.1 6234
u:ir 2 U 2 • i i r - 17.701 . 0 . 6 8 7 :■ 3362210 160.000 149 . 3
7" 3u t v 1 r?e n z y m m. n a : a z e 14 r 15.834 16.334 (0.543) 1672953 160.000 152.4 9098
m : . : cr. I orezenz : a ■ ne 25 2 19.348 ;5.348 (0.994) 1152883 160.000 152 . 1 8036
7[- ms 2-ezn.-m.-rxy. Pr.r.n;.. a - 14 9 19.797 15.797 0 . 992 ) 2379996 160.000 149.7 9261
4.: Benz: a. an: nr men.- ?■:. 1 3 v j 2 ' I; . 9 9 6 : 3673446 160.000 149.9
m Z:-mys-jnv _2c Z Z i 1 7- 21.01“ .1 0 C 3 ' 3372976 16 0. 300 14 7.9
n - ccm mm :.a . m t 2 i - 7 .; Z V 7 7 4 . 0 92 5: 2571762 160 . 000 14 5. 5.
- i nenzo :L mm: mzmm-r 1 5 Z 21 725 Z 1 ’mb •0.968i 2450242 160 . 000 16 1 . S
~4 5-mm: f mm ■ m.Z r.m- 252 1 7 c. j 21.753 • 0.9-59) 2207306 160.000 141.8 i
fc —n. ■) c. 2 7 7 e, p ::.?5= C . 9 9 5 : 1969998 160.000 152.6
f — ^ 2"-' 25.072 25 m2 -’ll 1398885 160.000 153.8 0 (
Cmenzr m n : amm.;-d ;-:m 2 7 6 25.072 2 5.;; 7 ? t:. i) 7) 1686525 160.COO 152.8 5 3 2 3
v. bm.z: u . . ; m-mm e:m 2 7 5 -> c q 11 f. 2 5 . 9 C C -.1.154: 182364 3 160.000 155.4 9213
«>\
QC
M
H
.aq jeaend
Target compound detected but, quantitated amount exceeded maximum amiount .Compound response manually integrated.Operator selected an alternate compound hit.
r
544
[ists File-: / :r.er>'i.,,5':|74.,r,p64 . 1 .'DF 02031 0h6j . t./HH0203l 0A64.0 Ii'i.J'&ct1 O'*' Date: lO-^R-r'X^ 1-5:53 instrument : 5972np64. :Client Sample ID: 53TD160
#pound: 2.4.6-Tr ipromopheno iNumber: 1i8-39-6
?.8-
Ion 329.60: Area: 437753 Height: 298709
ft
1.-5-
1 . 2-
m . q.
0 . 6
0.4-
14.00 14.05 14.;n ;4. ] 0 14.25 14.30 14.35 14.4m 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.05 14.90 14.95 j
Mir, __ ________lor 332.00: Area: -<ei fc'nt : 0
14.55 14.60 1 4.65 14.ro 14.75 14.80 14.83 14.90 14.95
54b4.75 14‘.SO 14.85 1 4 '. 9 ri 14'. 95
1
Data File: .• chem/59''2hp6j . i /DF020310064. b.'HH020310064. dInjection Date: 10-MOR-2002 14:55I nstrument: 5972hp64.iClient Sample ID: SSTD160
Impound : 4-Chloropheny l-pheny 1 ether S Number: 7005-72-3
5.4-
5.1:'
4.8-'
a 5-
Ion 204.00: Prea: 754740 height: 544170
£O
60 13.65 13.70 13.75 l3.SO 13.85 13.90 13.95 14.00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50'____________________________________________ M i n_______________________________________________________ __________ '
Ion 206.00: Onea: 0 Heignt: 0
14.5
11 h=irn' ;
54b14.3 14.4 14.5
261116
Data F 11 * ; /•: hem/59r2hp6- Injection Dale: 10-mwF:-2' Instrument: $972hpn4. 1
Client Sample ID: 5STD161
pouna : 4 . b-D in 11 r-p-2- Numper-: 534-52-1
i /DF 02031On 64. b''HH020310964. d '2 14: So
thylonenol
Ion 198.00: brea: 40*460t*
jheight:
v
1.8-
1 . 6-
ir. 1.4-
1 ■0_.
0.3-
0.6-
0.4-
0.2
13.70 13."8 13.80 13.SS 13.90 13.98 14.00 1-4.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 1
|Mmi'Ion 51.00: Or^a: 0 Height: 0
j . c 3. J- T
1 . O
> 4
I
I
■1-. 6
a
’5 14.00 14.05 14.10 : a.15 14.20 ia.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.05
in’*' 105.00: ---ea. 0 rteipr.t: 0
•j 8'
a
54 1
1-4. 3'5 14.30 14.35 14.40 14.45 14.5'.') 14.55 14.60 14.65
b-'HH02Q31 0h54 . djEtlS Fli~; 'crieF'.-'n'Pri'npn^ . 1 .• DF C!2'j3 1 C'Hn4 . injection Q*te: i0-mhR-2002 14:55InstI'umenr ; 5972hpb4.i Client Sample ID: SSTD160
kmpouna: 13 Humber*
Benro '■ k ) f 1 uoranthene : 207-08-9
9.8
Ion 282.00: Area: 2207506 Heignt: 958219
in
6.5-
6.0-
5.5-
1 4.5-
2 j.ij.
■“ 3.5-
2.5-
1. 0-
■; . ?■
21.28 21 . 30 21.75 21.40 2 1 . 45 21.50 21.55 21.60 21.65 21.70 21 . ?5 21.80 21.85 21.90 21.95 22.00 22.05 22.10 22.15 22.20
Min________________________________________________________________________________________________________________________ __________ __I on 253.00: brea: 478079 heignt: 208519
; ct. . ! m
. 48 .80 21 .55 21 .60 2: . 55 2 • . 21.75 21 .80 21 .85 21.90 21.95 22.00 22.05 22.10 22.15
•xS'
II
54822.10 22.15
t
Data File: .•'cnam/59':'2hp64 Injection Date; lO-MOR-20' Instrument: 5972hp64.l Client Sample ID: SSTDlbO
pound: Mumper
Indenof1 : 195-39
cd
i /OF020 '2 1J:55
pu nene
1 O^i
2 . d-
2.6
2.4-
,4 . b/Hu020310Pb4 .d
Ion 226.00: Hrea: 1496880 Height: 294306
CMr.
in: CM
1 . b-
LTi 1 • 6
S 1.4-'
1.2-
1.0-
0. 6
0.6
4
24.55 24.60 24.65 24 . ~0 24. ?5 24.80 24.85 24.90 24.95 25.00 25.05 25.10 25.15 25.20 25.25 25.30 25.35 25.40 25.45 25.50
H i n________________________________________________________________________________________________ _______ _________________________Ion 138.00: H^ea: 0 Heignt: 0
0 . ?
:5.4 25.3
460
54025.4 ■' 6 5
b. Continuing Calibration Data
(Form VII SV)
If more than one instrument is used, forms shall be arranged in order by instrument. If multiple continuing calibrations from the same instrument are used, they shall be in chronological order.
ti
i
(1) Reconstructed Ion Chromatograms and quantitationreports for all continuing (12-hour) calibrations; Spectra not required
(2) EICPs displaying each manual integration i
i
551
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Name: COMPUCHEM Contract: 8270C
Lab Code: LIBRTY Case No.: SAS No.: SDG No.: QE1877
Instrument ID: 5972HP60 Calibration Date: 03/12/02 Time: 1017
'Lab File ID: HG020312A60 Init. Calib. Date(s): 03/03/02 03/03/02
Init. Calib. Times: 1401 1720
GC Column: J&W DB-5.625 ID: 0.32 (mm)
COMPOU ID
|___ |RRF8 0.0 00|
RRF OR ORJ AMOUNT |AMOUNT
1 - 1
1
MIN |
RRF1
1
%D OR I
%DRIFT1
MAX %D OR
%DRIFT
CURV
TYPE
Phenol 1 1 . 3820000|1.2008222| 0.01 | -13.11| 20.00j AVRG
Bis ( 2 -chiloroethyl) ether | 0.9520000 0 . 9599782 0.01 I 0.84 50.00j AVRG
2-Chlorophenol 1 . 0880000 1.1040369 0.01 1.47 | 50.00 AVRG
1,3-Dichlorobenzene 1.4910000 1 . 5304621| 0.01 2.65 50.00 | AVRG
1,4 -Dichlorobenzene | 1.4860000 1.6051513 0.01 8.02 20.00 AVRG
1,2-Dichlorobenzene | 1.4310000|1.4978057| 0.01 j4.67 | 50.00
j AVRG
2-Methylphenol 0.8830000 0.8964040| 0.01 j1.52 50.00
j AVRG
2,2'-oxybis(1 -Chloropropane)
4-Methylphenol
j1.3580000|1.3558819 j
1 . 1220000|1.05980480.010.01 1
-0.16 -5.54 |
50.00
50.00
AVRG
AVRG
N-Nitroso-di- W- propylamine
Hexachioroethane
0.8140000 0.7984051 | 0.6340000 j0.7273466
0.050.01 j
-1.92 14.72 j
50.00
50.00
| AVRG j AVRG
Hit roben :ene 0.49600000.4643285 0.01 -6.38 50.00 AVRG
Jsophorone | 0 . 7810000 | 0.7513808 0.01 -3.79 50.00 AVRGB-Nitrophenol jo . 2450000 | 0.2498400
0.01 ■ 1.98 | 20.00 AVRGW, 4 - Dimethylphenol 0.2970000 0.2919625 j 0.01 j
-1.70] 50.00j AVRG
Eis ( 2 -chloroethoxy1 methane
2 , 4 - Dichiorophenol
[ 0.4700000| 0 . 4839004
0.4380000 0.4323532
0.01 j
0.01
2.96
-1.29
50.00
20.00
I AVRG
| AVRG
1,2,4-Trichlorobenzene | 0 . 5200000 0.5161232 0.01 -0.74 50.00j AVRG
Naphthalene i 1 . 1890000 1.2196058 0.01 2.57 50.00 AVRG4 - Chloroaniline 0 . 5010000 | 0.4843112 0.01 -3.33 50.00 AVRGHexachiorobutadiene
! 0.4060000 j 0.4212530 j0.01 3.76 20.00 AVRG
4 -Chloro ■ 3-methvlphenoij 0 . 3640000 jo.3220704
0.01 -11.52 20.00 AVRG2 -Methvlijiaphthalene 0.8860000 0 . 9245955 j 0.01 4.36 50.00 AVRGHexachiorocyclopentadiene
2,4,6-Trichlorophencl
0.4600000 0.4811605
[0.440000010.4038658[
0.05 1
0.01 j4.60
-8.21
50.00
20.00
AVRG j AVRG
2 , 4 , 5 - Tn chlorophenol 0.4790000 0.460644 3 0.01 — 3 .83 f 50.00 AVRG2 - Chi oroijiaoh t ha 1 ene 1 . 2400000 | 1 .2204 970 [ 0.01 -1.57 50.00 AVRG2 -Nitroaml me j 0 . 4S30000 j 0 . 4824943 | 0.01 -0.10 50 . 00 AVRGDimethy1phthalate i 1 . 62900 0 Oil. 518 317 4 i 0 . 01 1
-6 . 79 j50.00 AVRG
2 , 6 - D i n l .rotoluene | 0 . 347000010.3333067| 0 . 01 1 -3.95 50 . 00 | AVRG
Acenaphtlv/1 ene i 1 . 9950000 | 1 .8703 961 0.01 -6.24 50 . 00 AVRG3 - Hi t roan 11 me ; 0 . 3 6 9 0 0 0 0 [ 0 . 3 3 7 5 7 0 3 0.01 1 -6.52 50.00 AVRGAcenaphthene j 1 . 1730000 | 1 . 0784801 0.01 -8.06 20.00 | AVRG
2 , 4 - Dm 11 rop henol 0.2170000 | 0 . 1883675 0.05 j- 13 . 19 | 50.00 j AVRG
4-Nitrophenol 0.2960000 | 0.2992935 0.05 1 . 11 j 50.00 | AVRG
2,4- Dim u rotol nene [0. 514000 0(0. 5124825 0.01 -0.30 50 . 00 AVRGDibenzofuran. j2.1S10000l2.1805926| 0.01 -0.02 . 50.00 AVRGDiet hy1pH t ha1 at e ; 1 . 7 6 0 0 0 0 0 1 1 . 6 8 0 0 3 5 7 0.01) -4.54 50.00 AVRG4 -Chlorophenyl- phenyl etherFluorene |
iO. 96000OOjO. 9286261]
1 . 7420000! 1 . 7378112 |
0.01 1
0.01
-3.27 -0.24 |
50.00
50 . 00
| AVRG
j AVRG
J - N i t roan lime i U . d 7 j 0 ij (j L' 0 . 3 6 0 5 9 4 5 j 0.01 -3.06 5 0.00 AVRG^6 - Dim d ro - 2 - methylphenol ‘0.16 6 0 00 0'0.1500552! o. o i!
i
- 9.60 j
i5 0.00 | AVRG
a q e 1 o 'I J
FORM VII sv
b53
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Name: COMPUCHEM Contract: 8270C
Lab Code: LIBRTY Case No.: SAS No.: SDG No.: QE1877
Instrument ID: 5972HP60 Calibration Date: 03/12/02 Time: 1017
Lab File ID: HG020312A60 Init. Calib. Date(s): 03/03/02 03/03/02
Init. Calib. Times: 1401 1720
GC Column: J&W DB-5.625 ID: 0.32 (mm)
RRF80.000
| COMPOUND1
|RRF OR | OR [|AMOUNT j AMOUNT j
1 1 1
MIN |
RRF |
1
%D OR
%DRIFT1
MAX %D OR
%DRIFT
|CURV|
TYPE |
1 ||N-Nitrosodiphenylamine
1 110.5330000 0.4895377|
10.01 I
i-8.15| 20.00
|AVRGj
|4-Bromophenyl-phenylether
IHexachlorobenzene
| 0.300000010.2626789|| 0.3410000 j 0.3108058
0.01 I0.01 j
-12.44|
-8.85|50.00
50.00
|AVRG|
|AVRG|
IPentachlorophenol 0.1000000 0.1101310| 0.0510.13 j
20.00j AVRG|
1Phenanthrene |1.2540000|1.2258290| 0.01 | -2 . 25| 50.00|AVRG j
|Anthracene |1.2630000|1.2439978 | 0.01 | -1.50| 50.00 |AVRG|
| Carbazole 0.9800000|0.9122507 | 0.01-6 . 91j
50.00j AVRG j
iDi-n-butvlphthalate|1.6380000 j1.5921469 j 0.01 1 -2.80| 50.00
j AVRG
|Fluoranthene 1.4490000 1.4257731| 0.01 j -1.60 j20.00 AVRG |
|Pyrene | |1.4350000|1.3502826 | 0.01 j -5.90 j50.00 |AVRG|
|Butylbenzylphthalate |0.7410000 0.6995314 0.01-5.60 j
50.00 |AVRG|
!3,3'-Dichlorobenzidine |0 . 5660000 j 0.5708737 j 0.01 1 0.86 50.00j AVRG j
Lois(2 -ethylhexyl)Phthalate
Knzo (a) anthracene
1 . 0350000|1.1977421|
| 1.4320000 | 1.6669665|
0.01 j
0.01 1
15.72|
16.41[50.00
50.00
j AVRG|
|AVRG j
"hrysene | 1.2900000 1.2586506| 0.01 1 -2.43 50.00 AVRG|Di-n-octvlphthalate | 2.0140000|2.3464786 0.01 I 16.51| 20.00 |AVRG|
I Benzo(b)fluoranthene 1 . 7250000 | 1.7012509| 0.01 1 -1.38| 50.00j AVRG j
! Benzo(k) fluoranthene 1 . 5600000 2 . 0517998 0.01 1 31.52 50.00 AVRG| Benzo(a)pvrene i 1 . 3800000 | 1.5755806 0.01 14.17| 20.00 ] AVRG|Indeno(1J 2,3 -cd)pyrene 1 1 . 4730000 1.7135069| 0.01 1 16 . 33 j
50.00jAVRG|
IDibenzo(a,h)anthracene j1 . 2820000|1.5240366| 0.01 j 18.88 | 50.00jAVRG j
i Benzo(q,A,i)pervlene j1.2410000 j1.4501195|0.01 1 16 . 85 | 50.00 |AVRG|
1
i2 -Fluorophenol j 1 . 2730000 j1.06988950.01 -15.96 50.00
AVRG j
iPhenol - d5 i 1 . 4360000 | 1.3412205| 0 . 01 i -6 . 60 j50.00
|AVRG j
!Nitrobenzene-d5 0 . 5720000 0 . 5583855 0.01 -2.38 50 . 00AVRG j
1 2 - Fluoro&iphenvl | 1 . 5550000 1 . 4480327| 0.01 1 -6.88 50.00 AVRG| 2,4,6 -Tribromophenol | 0 . 3760000|0.3336466 0.01 -11.26 | 50 . 00 | AVRG
! Terphenyl- dll ! 1 . 1100000 | 1 . 0273398| 0 . 01 1 -7.45 50 . 00 AVRG |
page 2 ofFORM VII SV
b5o
CxlO-'fe)
Data File} /chem/5972hp60. i/DF020312A60.b.'HG020312A«>.d
Date } 12-MAR-2002 10:17
Client ID} SSTD080
Sample Info: SSTD080}917
Volume Injected <uL>: 1.0
Column phase: J&W DB-5.625
Instrument: 5972hp60. i
Operator: 917
Column, diameter: 0.32
■ J
LOLO
-Phmnanthrmnc-d1
Data File: /chem/5972hp60,i/DF020312A60,b/HG0203i2A60*d
Date : 12-MAR-2002 i0;17
Client ID: SSTD080 Instrument: 5972hp60.i _nSample Info: SSTD080:917 LOVolume Injected <uL): 1*0 Operator; 917 LOColumn phase: J&W DB-5*625 Column diameter: 0.32
Data File: /chem/5972hp60.i/DF020312A60.b/HG020312A60.dReport Date: 12-Mar-2030 10:50
Data file Lab Smp| Id Inj Date Operator Smp Info Misc Info Comment MethodMeth Date Cal Date Als bottle Dil Factor Integrator
CompuChem
Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020312A60.b/HG020312A60.d SSTD080 Client Smp ID: SSTD08012-MAR-2002 10:17917 Inst ID: 5972hp60.iSSTD080:917
/chem/5972hp60.i/DF020312A60.b/8270Cv6.m12-Mar-2030 10:50 mikhael Quant Type: ISTD 03-MAR-2002 17:20 Cal File: HL020303A60.d2 Continuing Calibration Sample1.00000
HP RTE Compound Sublist: all.subTarget Version: 3.50Processing Host: einstein
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Description
Dilution Factor Volume of final extract (uL) Volume of sample extracted (mL) Volume injected (uL)
Cpnd
Name1
Value
iDF 1.00000VtL 1000.00000Vo 1000.00000Vi 1.00000
Variable Local Compound Variable
AMOUNTS
CUANT SIG CAL-AMT ON-COL
Compounds MASS RT EXP RT REL RT RESPONSE ( NG) ( NG) SIMILARITY
' 1 1 , 4 - Dich io t ober.zene - d4 152 9.123 S . 123 (1 . 000) 100945 40.0000
* 2 Naohtha iene*d5 13 6 10.286 10.288 (1 . 000) 295932 40.0000
' 3 Acenapn z her.e • d I C 1 6 4 13.351 13 351 (1.000) 244221 40.0000
* 4 Phenan: 1 18 S 15.973 15.973 (1.000) 476283 40.0000
• 5 Chrvse:: e-d:- 240 20.608 20.408 <1.000) 517505 40.0000
.• n 'ervien - d i 2 264 23.163 23 163 (1 . 000) 375407 40.0000
opheno: 12 6 . 003 4.008 (0.740) 216000 80.0000 67.24
~ 6 Phenoi - dF 9 9 7 . 565 7.565 (0.931) 270779 80.0000 74 . 70
3 9 N11 robe n z e n e - d F 92 9.053^ 9 353
| 0 . 8 8 0 ) 331611 80.0000 78 . 11
cn:phenyl 172 12 156 12.166 (0.911) 7C7280 80.0000 74.49
3 30 14.756 14 755 (1.105) 162967 80.0000 70.92
" : 2 :erpher. 1 - d; 4 244 19.781 19.781 (0.911) 1063307 80.0000 74 . 03
so.: :~.eiby- aiine 42 3.369 3 369 (0.415) 346238 80.0000 91 . 99 8710
:4 ?yi-id:n 7 3 3.403 3.402 (0.4191 ■ 691561 80.0000 132.3 9175
Data Fi|le : /chem/5972hp60 . i/DF020212A60 . b/HG020312A60 . dReport Date: 12-Mar-2030 10:50
Compounds
IB Benzaldenyde
16 Phenol
17 Bis(2-chloroethyl'ether
16 2-Chlorophenol19 1, 3-DJchlorobenzene
20 1, 4-DJchlorobenzene
21 BenzyJ alcohol
I22 1,2-Drchlorobenzene
2 3 2 - Methylphenol
24 2 oxybis(1 -Chloropropane)
25 Acetophenone
26 3-Methylpnenoi
27 4-Methylphenol
28 N-Nitroso-di-N-propylamine
29 Hexachloroethane
30 Nitrobenzene
31 Isophorone
32 2-Nitrcpheno1
33 2,4-Dimethylpnenol
34 Bis(2-ch1oroethoxy)methane
35 2,4-DichlorzohenolI
36 1,2,4-Trichlorobenzene
i37 Naphthalene
35 4-Chloroani 1 me 39 HexachJorobutadiene
4u Caprolactam|
41 4 - Ch iorjo - -metny iphenoi
42 2 - Met h\j 1 naphtha 1 ene
4 3 1 - Met hyjlnapht ha 1 ene
4 4 Hexachlorocvc 1 ocer.t ad i eneJ
4 5 2 , 4 , n - .rich 11ropnencl
4 6
48
4 9
52
53
54
65
2,4 , 5 - T-r 1 ch i orophenoi
1,1'-Bipneny1
2 -Chlorcnaphtha 1ene
2 • N i t roar,: 1 : r.eI
0imet hvipntna ; at e
„ -
Acenaoht nyiene
2 -Nit roan:1ine
Acenaphthenei
2,4 -Pin:t roohenc1, ,,■ i.4 -Nit roonenoi, ,_„.j.............. _
Plben:::uran
Diet hvlohtha 1 a t e. i .t - ..or tor.envi • oneny : -
r ' 'r .uorene
ne r
AMOUNTS
QUANT SIG
MASS RT EX? RT REL RT RESPONSE
CAL-AMT
( NG)
ON-COL
( NG)
— —
77 7 . 396 7 396 (0.910) 115126 80.0000 ■ 71.45
94 7 . 599 7 599 (0.935) 242434 80.0000 69.48
93 7.700 7 700 (0.948) 1938 1C 80.0000 80.71
128 7.785 7 785 (0.958) 222894 80.0000 81.20
146 8.021 8 021 (0.988) 308985 80.0000 82.09
146 8 . 157 8 157 (1.004) 324064 80.0000 86.41
108 8 . 377 8 377 (1.031) 131809 80.0000 74.75
146 8.411 8 .411 (1.035) 302392 80.0000 83.76
108 8 . 580 8 580 (1.056) 180975 80.0000 81.23
45 8.597 8.597 (1.058) 273739 80.0000 79.86
105 8.800 8 800 (1.083) 321662 80.0000 80.44
108 ^8 . 834 ' 8 .834 (1.007) 213964 80.0000 . 75.57
1087 8 . 834x 8.834 (1.087) 213964 80.0000 75.57
70 8.817 8.817 (1.085) 161190 80.0000 78.44
117 8 . 969 8.969 (1.104) 146844 80.0000 91.76
77 9.087 9.087 (0.883) 275748 80.0000 74.87
82 9.493-/ 9.493 (0.923) 446218 80.0000 76.94
139 9 . 629 9 . 629 (0.936) 148371 80.0000 81.59
122 9.730 9.730 (0.946) 173306 80.0000 78.58
93 9 .882 9.882 (0.961) 287371 80.0000 82.30
162 10.069 10.069 (0.979) 256759 80.0000 79.02
130 10 187 10.187 (0.990) 306507 80.0000 79.45
128 10.322 10.322 (1 . 003) 724280 80.0000 82.07
127 1 0.424 10.424 (1.013) 287615 80.0000 77.32
225 10 542 10.542 (1.025) 250167 80.0000 82.91113 11 016
11 . 016 (1.071) 56348 SO . 0000 87.62107 11.237 11.287 11 . 097) 191266 80.0000 70.81
142 11.523 11.523 (1.120) 549084 80.0000 83.47
142 11.693 11.693 (1.136) 449345 8 C.0000 84 . 51
237 11.794 11.794 (0.883) 235019 80.0000 83.72
196 12.031 12.031 (0.901) 197265 80.0000 73.37• 196 • 12.116 12.116 ( 0 . 907) 224998 80.0000 76.87154 12.352 12 3 c ? ( 0. 9251 687495 80.0000 77.64162 12.386 12.33': (0.928) 596142 80.0000 78.71
6 5 12.572 12 . 5 f n 94 2 i 471341 160.000 159.8
163 1 J. . 6 i 4 12.594 ! 0 . 9 6 6 1 741610 80.0000 74 . 5516 6 ' ") 3 Q C 1 2 . - ? 5 iC.9T3; 162801 80.0000 76 . 77152 1 ? 114 1 ; ■ 1 4 • :'i o 3 2 913580 80.0000 75 . 0013 6 1 ? . 3 (J •: ■- :• . J 0 . 0 9 6 ) 329767 160.000 146.5
154 13.41b 1 J .415 ' 1 . 3 o 5 ' 525775 80.0000 73.53
194 13.486 : • ■: •' • 1 .010, 460033 400.000 346.915 1 j . 6 z 1 ‘ . T 2 ■ ■ 1 . 0 2 0 ) ■ 292375 160.000 161.6
- ^ c : 3. .'0- : 3 . F 2 6 1 .027; 250318 80.0000 79.70168 13.723 1 3 7 2 3 1.028i 1065093 80.0000 79.99
14? 14 12 ? 14.12? 1.058' 820600 80.0000 76.36204 ^ . t - S’ 14.315 1.072) 453580 80.0000 77.35
16 6 ✓ 14.315' 14 3 15 1 0 7 2' 348820 80.0000 7?.83
SIMILARITY
8667
8893
7957
8233
7256
8949
9080
9068
8615
8607
8686
8940
8894
9286
8717(M)
8726
8605
8524
9183
9285
9474
9589
5427
9178
82 00
8497
9514
9462
726 1
7739
i55/
Data File: /chem/5972hp60.i/DF020312A60.b/HG020312A60.dReport Date: 12-Mar-2030 10:50
Compounds
AMOUNTS
QUANT SIG CAL-AMT ON-COL
MASS RT EXP RT REL RT RESPONSE ( NG) i NG) SIMILARITY
62 4 -Nicroan j. i meI
63 4 , 6 - Dmic.ro • 2 -methyl phenoi
64 N- Nit: rosed i phenyl amine
65 1,2-Diphenyi'nydrazine
66 4-Bromophenyl-phenylether
6 7 Hexachlorobenzene
66 Acrazine I
69 Pentachlorophenol
70 Phenanthrene
71 Anthracene
72 Carbazole
73 Di - r. - butylpheha late
74 Fluoranthene
75 Benzidine76 Pyrene |
77 But ylbenzylphthalate
73 3,3'-Dichlorobenzidine7 9 bis(2 -eJhyIhexy1)Phtha 1 ace
60 Benzo(aJantoracene
91 Chrysene|
92 Di-n-octylphthaiate
P485
Benzo(b) f 1 uo: ar.c her.;
Benzo (k) f luor ar.c hene
Benzo(a:pyrene
Inaeno (!.2, } -~d)pyrene
O', benzo (*a . h : ancnracene Benzo ;a Jr.. : ; cc-rv 1 ere
138 14 . 383 14.383 (1.077) 352259 160.000 155.3
190 14 .433 14 .433 (0.904) 285875 160.000 145.0
16 9 14.535 14.535 (0.910) 466317 SO.0000 73 .47
77 14 .602 14.602 (1.094) 893482 80.0000 83.43
248 15.178 15.178 (0.950) 250219 80.0000 69.96
284 15.296 15.296 (0.958) 296063 00.0000 72.88
200 .15.465 15.465 (0.968) 17940 80.0000 19.68
266 15.651 15.651 (0.900) 209ei4 160.000 176.5
178 16.024 16.024 (1.003) 1167683 80.0000 78.17
178 16.108 16.108 (1.008) 1184990 80.0000 78.80
167 16.396 16.396 (1.026) 868979 80.0000 74 . 50
149 16.988 16.988 (1.064) 1516625 80.0000 77.74
202 18 . 121 18.121 (1.135) 1358143 80.0000 78.69
184 18.341 18 . 341 (0.890) 208629 160.000 61.34
202 18 . 510 18.510 (0.898) 1397556 80.0000 75.28
149 19.610 19.610 (0.952) 724022 80.0000 75.52
252 20.541 20.541 (0.997) 590860 80.0000 80.71
14 9 20.574 20.574 (0.998) 1239675 80.0000 92.58
228 20.593 20.591 (0.999) 1725327 80.0000 93 . 15
228 20.642 20.642 (1.002) 1302716 80.0000 78.04
149 21.556 ' 21 . 556 (0.931) 1761769 80.0000 93 . 19
252 22 . 368 22.368 (0.966) 1277323 80.0000 78.90
252 22.418 22.418 (0.968) 1540520 80.0000 105.2
252 23.044 23.044 (0.995} 1182968 80.0000 91 . 30
276 26.056 26.056 (1.125) 1286525 80.0000 93.05
270 26.107 26.107 (1.127) 1144268 60.0000 95.09
276 25 . 952 26 . 952 (1.164) 1088770 80.0000 93.45
8150
9064
8S77
9460
9312
9343
8571
8887
9047
9229
8561
9116
7095
9546
8729
8845
8014
QC Flag Legend
M - Compound response manually integrated.
55S
m
Data File: /chem/5972hp60. i/'DF0203l2A60.b/HG020312A60.d Injection Date: 12-MAR-2002 10:17 Instrument: 5972hp60 . i
lent Sample ID: S5TD0Q0
ipound: 2.4,6-Tribromophenoi Number: il0-79-0
1.0-
0.9-
o. s-;
0.7-
0.6-
0.
0.4-
0.3
0.2
0.1-
0.0-
Ion 329.60: Area: 162967 Height: 100792
IS
14.3 14.4 14.5 14.6 14.? 14.e 14.9 15.0 15.1 15.2
9.5
9.0
8.5
6.0-
7.5-7.0-
6.5
6.0-
5.5-
■ 5.0-
4.5-
4.0-
3.5- .
7.0- '
2.5-
2.0-
1 .5-
1 .0-
0.5-.
0.0 - -
14 .
Ion 332.00: Area: 0 Height: 0
:5 14 130 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20 I M i n
1 . 4-
1 .3-
1 .2-
1.1-
1.0-
. 9-
. 8-
. 6-
. 5-
. 4-
. 3-
. 1 -
14.25 1-
Ion 141.00: Area: 0 Height: 0
■J
14.35 14.40 i4 . -?5 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20
: /[Chem/597I!hp60.1/DF02Q31 2A60. b/HG020312h60 .d
Date: 12-MAR-2002 10:17Data file Inject LonInstrument: |5972hp60.i
lent Sampl'e ID: 5STD08
i■mpound : Capro 1 actam "AS Number: 105-60-2
j. u-
2.0-
2.6-
2. 4-
2.0-
1.3-
1.6-
1 . 4-
1.2-
1.0-
0.8-
Ion 55.00: Area: 28807 Height: 28807
if
s
10.8 10.9 11.0
M i n
11.1 11.2
/\! \
11.3 11.4 11.5
2.6-
: .8"
1 . b~
1 . 4-
1 . 0
i 0 ■ 3 ■
Ion 56.00: Area: 26546 Height: 26546
• 56 L
10.9 11.0Min
11.1 11.2 11.3 11.4 11.5
COMPUCHEM a division of Liberty Analytical Corp DATE 3 / / 2-/ ol INITIAL TIME OF TUNE S~Jv-i tm m omm/ni A Til I? DT TM 1 nr ___________ “------- —----
GC/MS SEMIVOLATILE RUN LOG TIME TUNE EXPIRES ? g S' /SHIFT/S(A)_k/_(B) (C)LINKER/METHOD g'JJj,.’
■Eit
tit :0PREVENTIVE MAINTENANCE /v^ p ...H
T
tD■; ■ FILE NAME; , LT--I
~ D''DATE TIME •.I cygNTiD# ;
-1 .......^ ' •CASE/SDG# AMOUNT
INJECTEDCHEMIST
---------------------------------------------U-J-, 'COMMHNTS(ETC.)/DISPOSlT[g^ P—
1 l)rv 'd a 3 h A Aq / -5 1 (L1 01 r/ AryV°> 4 m
______________________________ SJ"— /r?)
2 A/%0 lo3 HAdo / l / to n —^ -f rA q Kp J.- ^-LS- 1 y---- i-L/-'________________
3 S'C. H U-Q Ah 4 t i II os -I/1- 7 5r 2 / //------ V--------
1 ,04 U)fs)(/il3o-3Ah z / / II os f M c
5 UJA Uzlo-* ACv / / / |U?
6 Sc it6C-(oA(>v / / /
7 Sr ? 6bdo / / / nw —Tr~8 idfa/AziS ■ LAfjL / / / mS
- AT \/ AA i u u c—J—X------------------------------------------
9 /A 11^-2 A Aq_. / / / (<roz1
10 aaim L / / AW s?>p acttii11 / / / — t-wj--------------
-PTFlohiT {IftlDZH12 J- or
_/ / /7o7 '
13 GfltlO-*1/900 / /----- :----
/ ///?
14 /IPMOI-tO/jU, 4 / / Wiv-IZR15 a?iWhli?iuo L / / /fak P\U)~i3Q16
1 7
/ 'v
--- >
l"
__*___
/9/A> r<ioo-/3&____ Vt / V ^___ V
y
db\ - 4 ~ ’j'Ofi,18 / / k ----------19 / /
—20 / /
______21 / /___ __ ______ '
=----- ----------------—
22 /
23
24•
/ /
—---- /----/— -r y"
Std. ID tr
Lot #
Analytical
5" -3 ? (f-L/L
lnt. Std. Column Type
-x If-Cy r
SUPERVISOR APPROVAL3ilsto-7r
DATEO 5 X 'A"''
e presence of the Chemist s employee 11) number, or signature, on this run log attests that stiici compliance with the method's Sr
occurred. Any St^dcviations require documentation by the responsible chemist together with the chemist's initials and the initial
lab supervisor department representative, signifying approval of the deviation 12/1 1/til dc
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Name: COMPUCHEM Contract: 8270C
Lab Code: LIBRTY Case No.: SAS No.: SDG No.: QE1877
Instrument ID: 5972HP60 Calibration Date: 03/13/02 Time: 1312
Lab File ID: HG020313A60 Init. Calib. Date(s): 03/03/02 03/03/02
Init. Calib. Times: 1401 1720
GC Column: J&W DB-5-.625 ID: 0.32 (mm)
COMPOUND
Phenol_J____________________
Bis (2 - ch'loroethyl) ether
2 -Chlorophenol____________
1.3 -Dichlorobenzene_____
1.4 - Dich'lorobenzene_____1,2 -Dichjlorobenzene
. I2-Methylphenol2,2'-oxybis(1 -Chloropropane)
4-Methylphenol
[M-Nitroso-di-N-propylamine_
| Hexachloroethane______________
I Nitrobenzene
isophorone_________________ .
■-Nitrophenol
2 , 4 - Dimejthylphenol___________
Bis ( 2 - chjloroethoxy) rnethane_
2 , 4 - Dichlorophenol___________1,2,4 -Tr|ichlorobenzene
Naphthalene________________
4 - Chioroaniline___________
iHexachlorobutaaiene_____4 - Chloroj- 3 - methylphenol
2-Methylnaphthalene_____
Hexachlorocyclopentadiene 2 , 4 , 6 -Tr'ichlorophenol_____
4,5-Trdcnlorophenol
2 -Chloronaphthalene_
2 - Hi t roam 1 me______
Dimethy1phtha1 ate___
2,6- Dini|trotolnene_AcenaDhthvlene
i ' . --------:oar. 11 me
RRF OR
AMOUNT
■Nit:
Xcer.aphthenei
2 , 4 - D i n 11
4 - Hi t r ooh'' i
rophenolmol
: - Dim protolueneDibenzofuran
I ---Diethylphthalat
4 -Chlorophenyl- Fluorenel
onenvl ether
-Hit roan i 1 me
6-Dinitro-2-me thvlohenoi
1 . 0 .
1 . 1 . 1. 1 , 0 .
1 . 1 , 0 .
0 .
0 .
0 .
0 .
0 ,
0 , 0 .
0 .
1.
0 .
0 .
0 .
0 . 0 ,
0 .
0 . 1,
0 .
1. '! C.
.11.
I 0 .■ i 1.
i 0 .
>■
! o ,'h-
.11.
; o. 'll
.1°
! 0 .
3820000
9520000
0880000
4910000
4860000
4310000
8830000
3580000 1220000
8140000
6340000
4960000
7810000
2450000
2970000
4700000
4380000
5200000
1890000
5010000
4060000
3640000
8860000
4600000
4400000
4790000
2400000
4830000
6290000 3470000
9950000
3690000
1730000
2170000
2960000
5140000
1810000
7600000
9 6 0 0 0 0 0
7420000 3720000!
i 6 6 0 0 0 0
Daqe 1 of
RRF80.000
OR
AMOUNT
. 2278442
.8673226
. 1312333
.5968505
. 5874369
.4962370
.9473773
.2232542
. 0802883
. 7091428
. 7233980
. 4463165
.6969587
. 2454144
.2887574
.4251300
.4618499
. 5742556
.1563816
.4521012
.4734603
. 3475495
.9501716
. 5344338
. 4514415
. 5203548
.1843315
.4375715
. 5470646
.3388357
. 9069708
.3533331
.1826551
. 1967293
.3196374
.5228070
.2300703
.5732787
.9905059
.7087524
.3615634
.1478998
MIN
RRF
0.01 0.01 0.01
0.01 0.01
0.01 0.01
0.01 0.01
0.05
0.01 0.01
0.01
0.01
0.01 0.01 0.01 0.01 0.01 0.01 0.01
0.01 0.01
0.05
0.01
0.01 0.01
0.01
0.01
0.01
0.01
0.01
0.01 0.05
0.05
0.01 0.01
0.01
0.01
0.01
0.01
0.01
irD OR
kDRIFT
-11.15
-8.89
3 . 97
7.10
6 . 83
4 . 56
7.29
-9.92
-3.72
-12.88 14.10
-10.02 -10.76
0.17
-2.78
-9.55
5.44
10.43
-2.74
-9.76
16 . 62
-4.52
7.24
16.18
2.60
8.63
-4.49
- 9
- 5
_ 2 -4
. 40
. 03
. 41
-2.89
0.82
-9.34
7 . 98
1.71
2.25
, 931 R
-4
3
-1.91
-2.80
-10.90
MAX %D OR
%DRIFT
20.00
50.00
50.00
50 . 00
20.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
50.00
20.00
50.00
50.00
20.00
50.00
50.00
50.00
20.00
20.00
50.00
50.00
20.00
50 . 00
50.00
50.00
50.00
50.00
50.00
50.00
20.00
50.00
50 . 00
50.00
50 . 00
50.00
50.00
50.00
50.00
50 . 00
CURV
TYPE
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVP.G
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
FORM VII SV56l
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Name: COMPUCHEM Contract: 8270C
Lab Code: LIBRTY Case No.: SAS No.: SDG No.: QE1877
Instrument ID: 5972HP60 Calibration Date: 03/13/02 Time: 1312
Lab File ID: HG020313A60 Init. Calib. Date(s): 03/03/02 03/03/02
Init. Calib. Times: 1401 1720
GC Column: J&W DB-5.625 ID: 0.32 (mm)
| | RRF80.000 j i 1 1
l COMPOUND | P.RF OR | OR MIN | %D OR 1 MAX %D OR|CURV
J AMOUNT AMOUNT | RRF1%DRIFT
1%DRIFT TYPE
1i ----------
j N - N i t r o s odiphenylaminej -------- ------------- || 0.5330000 0.4765422 j
------10.01 [
-------- 1-10.591 2 0.0 0|AVRG
|4 -Bromophenyl-phenylether Jo.30000000.2703204[ 0.01 -9.89 50.00 AVRG
Hexachlorobenzene 0.3410000|0.3195736 0.01 1 -6.28| 50.00|AVRG
| Pentachl'orophenol 0.1000000|0.1148339| 0.05 I 14.83 | 2 0.0 0|AVRG
|Phenanthrene 1 . 2540000|1.1483615 0.01 | -8.42 50.00 AVRG
!Anthracene | 1.2630000 1.1493896 0.01 j -9.00| 50.00|AVRG
|Carbazole |0.98000000.8954495| 0.01 j -8.63 | 5 0.0 0|AVRG
|Di-n-but ylphthalate | 1.6380000 1.4562558| 0.01 j -11.10 | 5 0.0 0|AVRG
:Fluoranthene | 1.44 90000|1.4178103 | 0.01 -2.15| 20.00 jAVRG
|Pvrene | 1.4350000| 1 . 3974664 0.01 1 -2.62 50.00 AVRG
jButyl benzylphthalate | 0 . 7410000|0.6656803| 0.01 I -10.1650.00 j AVRG
i 3 , 3 ' -Dichlorobenzidine 0 . 5660000 0. 5777214 0.01 2.07 50.00 AVRGrtjis(2 - ethylhexyl)Phthalate 1 . 0350000 0 . 9965946 0.01 -3.71 5 0.0 0|AVRG
Benzo(a)anthracene | 1.4320000 1.6085199 0.01 12.335 0.0 0 jAVRG
iChrysene| 1 . 2900000 j1.2647011j 0.01 J -1.961 5 0.0 0|AVRG
Di-n-octvlphthalate 2 . 0140000 J 1.9020777[ 0.01 -5.56 | 20.00 AVRGBenzo(b)fluoranthene 1.7250000 1.6598364 | 0.01 -3.781 50.00|AVRG
Benzo(k)fluoranthene 1 . 5600000 1.7624998| 0.01 12.985 0.0 0 j AVRG
|Benzo(a)pyrene | 1.3800000|1.4738244 0.01 6.80 20.00 AVRGIndeno(1 2,3 -cd)pyrene 1.4730000 1 . 6969110 0.01 15.20| 50.00|AVRG
Dibenzo(a,h)anthracene 1 .2820000 1 .4997111 0.01 16.98 50.00|AVRG
Benzo(q,h,i)perylene 1 1 . 24100001 1 . 4097750| 0.01 1
113 .60 |
15 0.0 0|AVRG
i2-Fluorophenol 1 . 2730000 1.2161236J 0.01 -4.47 50.00 AVRGPhenol - dS 1.43600001.38361521 0.01 -3.65 50.00 AVRGUitroben zene-d5 j 0.572000010.5194193 | 0.01 i -9.191 5 0.0 0|AVRG
2 - Fluorobiphenyl ] 1 . 5550000|1.5298129j 0.01 -1.62 50.00 AVRG2,4,6-Tribromophenol | 0. 37 6 0000 J 0.4450193 ! 0.01 18.36 | 50.00|AVRG
Terpheny 1 - d 14 1 . 1 100000! 1. 1057504 1
i : :
0 . 01 1 -0.38
150.00 AVRG
1
iao!
FORM VII SV
b6 o
Data File: /chem/5972hp60.i/DF020313A60.b/HG020313A60.d
Date : 13-MAR-2002 13:12
Client ID: SSTD080 Instrument: 5972hp60.i
564
Sample Info: SSTD080;917
Volume Injected <uL)t 1*0 Operator: 917
Column phase: J&W DB-5*625 Column diameter: 0.32
Data File: /chem/5972hp60.i7DF020313A60.b/HG020313A60.d
Date : 13-MAR-2002 13;12
Client ID: SSTD080
Sample Info: SSTD080:917
Volume Injected <uL>: 1.0
Column phase: J8.W DB-5.625
Instrument: 5972hp60,i
Operator: 817
Column diameter: 0.32
■_o
CDLO
Data File: /chem/5972hp60.i/DF020313A60.b/HG020313A60.dReport Date: 13-Mar-2030 13:44
Data file Lab Smp Id Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date|Als bottle Dil Factor Integrator Target Version: Processing Host:
CompuChem
Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020313A60.b/HG020313A60.d SSTD080 Client Smp ID: SSTD08013-MAR-2002 13:12917 Inst ID: 5972hp60.iSSTD080:917
/chem/5972hp60.i/DF020313A60,b/8270Cv6.m13-Mar-2030 13:44 mikhael Quant Type: ISTD0 3-MAR- 2 0 0 2 17:20 Cal File: HL020303A60.d2 Continuing Calibration Sample1.00000
HP RTE Compound Sublist: all.sub3.50einstein
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value DescriptionI ____ ________________ _ ^
DFVtVoVi
1.00000
1000.00000
1000.00000
1.00000
Dilution Factor Volume of final extract (uL) Volume of sample extracted (mL) Volume injected (uL)
Cpnd Variable Local Compound Variable
AMOUNTS
QUANT SIG C.AL-AMT ON-COL
Compounds MASS RT EXP RT REL RT RESPONSE ( NG) ( NG)
• 1.4 -Lien ) orohenzene -d-i 162 8 . 163 8 . 153 (1.000) 8344 3 40.0000
• -> Nacr.L hd i 136 10.301 1 0 . 301 (1.000) 243315 40.0000
Acenacr. c •
16-i 13 . 380 "3 380 (1.000) 208182 40.0000
1 88 16.003 1 6 . 0 0 3 (1.000) 463513 40.0000
Chrysene • d2 2 24 0 20.638 -> p 6 3 8 (1.000) 498466 40.0000
:•••:.. • • -• -h'.: 264 23.209 2 8 . 206 a . o o o i 415406 40.0000
7 7 3-Flucro 112 6 . 038 =■. 03 = •, 0.7 4 1 i 202954 30.0000 76.43
:■ ; ?h-=.nc: -c 99 7 . 594 7 6 9 4 iO 932' 230906 80.0000 77.06
: = 82 9.06JK 08 3 10.802 j 252765 80.0000 72.66
•; :: 2 - F1 v c *■ c biphenyl 172 12.196 ■2 . 196 (0.911i 636959 80.0000 78.70
; :: 2 T r j r,romopnenol 330 14'. 734 734 (1.105) 185290 80.0000 94 . 60
3 .3 Terpr.-r.', -r-, 244 18.611 16 6 1 iO.911; 1102358 80.0000 79.68
s Gdirr.eir.y 4 2 )QC l a c (0.417; 307934 80.0000 98.98
1 y: :air; 79 3 .433 3 . ^ i (0.421) 309499 80.0000 71.61
SIMILARITY
(M) ^
9668
9339
56b
Data File: /chem/5972hp60.i/DF020313A60.b/HG020313A60.dReport Date: 13-Mar-2030 13:44
Zompounds
15 Benzaldehyde
16 Phenol
17
16
i ?
20
Bis(2-chloroethyl)ether
2-Chlorophenol
1.3-Dichlorobenzene
i i c h 1 ;,r ooenzer.e
21
22
23
24
25
Benzyl -alconolI
1.2-Dichlorobenzene
2 - Methy|lphenol
2,2' -oxybis : 1 -Chloropropane)
Acetophenone
2 6 3 - Me thyjl phenol
27 4-Methy-lpnenol
2 8 N-Nitroso-di-N- propyl amine
29 Hexachioroethane
30 Nitrobenzene
31 Isophorone
32 2-Nitrophenol
33 2,4 - Dimethy1pheno1I
3 4 Bis v 2 -chloroet noxy(methane
35 2,4 - Diehl oropnenoI
36 1,2.4 -Tr:chJ.orobenzene
40
4 3
Naphthalene
4 -Chioroam i '.ne
u .Hexach:orooutaaiene
Caprolact am
4 -ChI ore - 3 - met hy1pnenol2 - Met hvllnatnt na 1 ene
‘ I ']- Met hvl nachtna1ene
. :i ■ .
nexacr.. orocyc .opent a a lene
2,4,6-Trichiorophenol
46 2,4,5-:richlcrophenoi
4 1 1 , 1 ' - 3 i p h e n y 1
4 8 2 -Chioronaoht haiene2.Ni;roinihr.e
r ' Dine:r.v) r::: pa 1 a: a
.. . . _ T: - .. . - a : n : : rot: o i uene
a. Ac-j::apr.:
5? 4-N:troche.. _ „i
-- 1^.1" "l
55 Diethviiht
' i- .*1 - tr.ioro p n
u ene
- on-e ether
AMOUNTS
QUANT SIG CAL-AMT ON-COL
MASS RT EXP RT REL RT RESPONSE ( NG) ( NG) SIMILARITY
77 7.425 7.425 (0 . 911) 100794 80.0000 75.67 8700
94 7.611 7.611 (0.934) 204910 80.0000 71.04
93 7 730 7.730 (0.948) 144744 80.0000 72.92
128 7.814 7 . 814 (0.958) 188787 80.0000 83.20 8973
146 0 051 8 . 051 (0.988) 266492 80.0000 85.65
14 6 B 1B7 B . 1B7 (1.004 ) 264921 B0.0000 85.45
108 8 .390 8 . 390 (1.029) 105101 80.0000 72.10
146 6 .423 8.423 11.033) 249701 80.0000 83.68
108 / 8 6ioy 8.610 (1.056) 158104 80.0000 85.85
4 5' 8 610/ 3 . 610 (1.056) 204144 80.0000 72.05 7097
- 105 8 829 8 . 829 (1.083) 263285 80.0000 79.65 7865
108 ■' "Q 863 8.863 (1.087) 180285 80.0000 77.03
1 08/ - 8 863 8 . 863 (1.087) 180285 80.0000 77.03
70 8 829 " 8 . 829 (1.083) 118346 80.0000 69.67 0 (M) |
117 8 999 8 . 999 (1.104) 120725 80.0000 91.26 8972
77 9 117 9.117 (0.885) 217191 80.0000 71.97 8953
82 9 523 , 9.523 (0.924 ) 339161 80.0000 71.37 8815
139 9 658 9.658 (0.938) 119426 80.0000 80.14 8783
122 9 760 9.760 (0.947) 140518 80.0000 77.71 8647
93 9.895 9 . 895 (0.961) 206881 80.0000 72.31 7742
162 10.081 10.081 (0.979) 224750 80.0000 84.41
ISO 10.217 10.217 (0.992) 279450 80.0000 88.40
128 10.352 10.352 (1.005) 562730 80.0000 77.82 8979
127 10.454 10.454 (1.015) 220006 80.0000 72.17 8792
225 10.572 10.572 (1.026) 230400 80.0000 93 . 19 9122
113 11.046 11.046 (1.072) 45814 80.0000 86.94 8555(M)^
107 11.316 11.316 (1 . 099) 169128 80.0000 76.41 8707
142 11 553 11.553 (I.122) 462382 80.0000 85.78
142 11 722 11.722 (1.138) 371059 80.0000 85.16
237 11 824 11.824 (0.884) 222519 80.0000 92.99 9085
196 12.061 12.061 (0.901) 187964 80.0000 82.01
196 12 145 12.145 (0.908) 216657 80.0000 86.83
154 12 365 12.365 (0.924) 572659 80.0000 76.06 8290
162 12 399 12.399 (0.927) 493113 80.0000 76.38
65 12.602 12.602 (0.942) 364378 160 000 144 . 9 8852
163 12 907 12.907 (0.965) 644142 80.0000 75.96 9491
16 5 13.025 13.025 (G.973) 141079 80.0000 78.05 9566
152 13.127 25.12" iC.581; 793994 80.0000 76.46 9875
1 3 S 1 3 3 3 0 1 5 .530 ! 0.996) 298394 160.000 155 6 9191
15-5 13.446 13.446 (1.005) 492415 80.0000 80.63 8743
164 13.516 . 51£ a . 0 1 0 ) 409555 400 000 362.3
109 13.651 1 3 651 (1 .020) 266171 160.000 172.5 7983
16 5 13 736 i 3 . 7 3 6 ; 1 .027 J 217678 80.0000 81.30 8400
16 8 13 752 15.752 I 1.028) 928521 80.0000 81.81 94 39
149 14.155 14.155 : i. o 5 8 :■ 696693 80.0000 76 . 06 9374
204 ' 14.345/ 14.345 (1 . 072) 412411 80.0000 82.51 714 9
16b ' 14.345 , 711463 80.0000 78 . 50 7612
Data File: /chem/5972hp60 . i'/DF020313A60 .b/HG020313A60 .dReport Date: 13-Mar-2030 13:44
1
Compounds
QUANT SIG
MASS RT EXP RT REL RT RESPONSE
AMOUNTS
CAL-AMT
( NG)
ON-COL
( NG) SIMILARITY
62 4-Nitro aniline 138 14.412 14 .412 (1.077) 301084 160.000 155.7 7970
63 4,6-Dinitro-2-methylphenol 198 14 .463 14 .463 (0.904) 274214 160.000 143.0 8803
64 N-Nitrosodiphenylamine 169 14.565 14.565 (0.910) 441767 80.0000 71 52 8816
6£ 1,2-Diphenylhydrazine 77 14 .632 14 .632 (1.0941 725417 80.0000 ' "79.47 9238
6 6 4-Bromophenyl-phenylether 248 15.207 15.207 (0.950) 250594 80.0000 72 00 94 01
67 Hexachlorobenzene 284 15.326 15 . 326 lO.958 ) 296253 80.0000 74 94 9514
6£ At razine 200 15.495 15.495 (0.968) 15622 80.0000 17 61 8993
65 Pent achjlorophenol 266 15.681 15.681 (0.980) 212908 160.000 184 . 0 8900
70 Phenanthrene 178 16.053 16.053 (1.003) 1064561 80.0000 73.23
71 Anthracene 178 16.138 16.138 (1.008) 1065514 80.0000 72 81
72 Carbazole 167 16.425 16.425 (1 . 026) 830105 80.0000 73 13 8918
73 Di-n-butylphthalate 149 17.018 17.018 (1.063) 1349987 80.0000 71.10 9112
74 Fluoran :hene 202 18.151 18.151 (1.134) 1314347 80.0000 78.25
75 Benzidine 184 18.371 18.371 (0.890) 253628 160.000 77.42 8620
76 Pyrene 202 18.557 18.557 (0.899) 1393179 80.0000 77.91
Bu t y 1 be n z y 1 p h t ha 1 a t e 149 19.657 19.657 (0 "952) 663638 80.0000 71 87 9446
16 3,3'■Diehlorobenzldine 252 20.570 20.570 (0.997) 575949 80.0000 81 68 6930
79 bis(2-ethvlhexyl)Phthalate 149 20.604 20.604 (0.998) 993537 80.0000 77 03 9107
80 Benzo(a)anthracene 228 20.621 20.621 (0.999 > 1603585 80.0000 89.88
81 Chrysene 228 20.672 20.672 (1.002) 1260821 80.0000 78.41
82 Di-n-octylphthalate 14 9 21.585 21.585 (0.930) 1580269 80.0000 75 54
9 3 Benzo >b fluoranthene 252 22.414 22.414 (0.966) 1379012 ' 80.0000 76 98
Benzoik fluoranthene 252 22.465 22.465 (0.968) 1464306 80.0000 90.40
W Benzo(a)pyrene 252 23.091 23.091 (0.995) 1224471 80.0000 85.41
86 Indeno (1,2,3 -cdipyrene 276 26.136 ■ 26.136 (1.126) 1409814 80.0000 92 15 8540
87 Dibenzo < a . h)anthracene 278 26 . 187 26 . 187 (1.128) 1245978 80.0000 93.57 8610
86 Benzo(g h.i:pe ry1ene 276 27.033 27.033 (1.165) 1171258 80.0000 90.85 7460
QC Flag Legend
M - Compound response manually integrated.
Data File: /chem/5972hp60.i/DF020313A60.b/HG0203l3A60.d Injection Date: 13-MAR-2002 13:12 Instrument: 5972hp60.iClient Sample ID: SSTD080
pound: 2.4.6-Tribromophenol Number: 118-79-6
1.1-
1.0-
0.9-
>0.8-"
0.7-
u. d-
0.1-
0. u- -
Ion 332.00: Area: 0 Height: 0
14.4 14.5 1 *4.6 1*4.7 14.0Min
14.9 15.0 15.1 15.2
1 .4-
1 . 3-
1
1
1
0.9-
8-
Ion 141.00: Area: Height: 0
14.3 4.4
56 514.5 14.6 14.7 14.8 14.9 15.0 15.1 1!
Min
Data File: /chem/5972hp60.i/DF020313A60.b/HG0203l3A60.d Injection Date: 13-MAR-2002 13:12 Instrument: 5972hp60.1 Client Sample ID: SSTD060
>ound: N-Nitroso-di-N-propylamine
Number: 621-64-7
5.1-
4.B-
4.5- .
4.2-
3.9-
3.6-
3.3-
3.0-
2.7-
2.4-
2.1-
1 .3-
1.5-
1.2-
0.9-;
0.6-
0.3-
0 0-'
Ion 70.00: Area: 118346 Height: 53832
l\
/ ,i
6.5 8.6 8.7 8.8Min
8.9 9.0 9.1 9.2 9.3
1.2-
1.1-
Ion 130.00: Area: 0 Height: 0
1.0-
fi
o. 5-;
0.4-
0.3-
0.2-
0.1-
0.0-8.5 B.6 8.7 8.8
Min8.9 9.0 9.1 9.2 9.3
8.5
5-
Ion 42.00: Area: 0 Height: 0
9.0 9.1
57G9.3
COMPUCHEM a division of Liberty Analytical Corp DATE 3_/ii_/P^lNITIAL TIME OF TUNE__X2^l£___ SHIFT/S(A)_^__ (B)(C)
GC/MS SEMIVOLATILE RUN LOG TIME TUNE EXPIRES_ LINKER/METHOD Ally;
COMPUCHEM .LOGBOOK 4 V(4) 4 (5972hp60)nr\ r*n ddcv/cxitiv/c maimtfkiavirr o / —ftet
KEr
PREVENTIVE MAINTENANCE xi/^r-/ -------------------------------------------------------------------------- LU_iUr
cTl
FILE NAME rTeD
DATE TIME CLIENT ID# CASE/SDG# AMOUNTINJECTED
CHEMIST COMMENTStETC )/DISI’OSlT[Qti p--..
1 ? o ^ (3 A £ u / 3 ;/J ; oi lid dfrAt_____ i ya9 ___ ^ZJ_____ ro) /c7
2 flh/o / iv / / i A/fj / V / 1J i A ?S77l^c-____*-----
______ 1______
3 \>)h,)h i / f-1 .A/o / / / / .3 53. ev/U/~ ZZ.ZT r^F ___ \ (a4
4 (nJAv/rG L 5T- / / / 3 ________| M jb __ ___'■‘■In 1 / V r < _5 / / / / S'/5 MUj -?v A hi
6 Ae ivm- teftbo / / / 15b* Kvo-tec
7 Cos fail-1 w A(/o / / / lbV3> Mw-hA
8 he isn- iSAU / / / Hi* S
9 be i<6T)- It? AGo 7 / / ns* Mt/o - K A
10 be fa'll -\1 Abo7 ■ / / iSSM iv\w- ng
11 file i *11-1ft f\Uo / / / 131H Moj -/b>*
12 befall- Ki Abo / / / hSS tovJ.- i^ife N / \13 i/\3t7i\(>3£i 1-1 AG° 7 / / Sgcici \> VA^XvisaS 7*\\
14 V06tl(>3‘»I^A^ / / PUS b'53bLy<> 1/
15 / / / 315* CaapIuj E,±2>}?
16 GFl&Tl-WCAfo 7 // / (Mud - JeA Qf fall
17 6)Fm>2/NAb° 7 / 7 ;>sn MvaJ - ?o £> s7___ s a
18 / /___ —-
19 / /
20 / / ^ , 7 ||^ 3 ^
21 / /P7O
22 / /
23 ■------ - /
24 / /•
Tune
Std-ID-#----------- C S' 0 •
Lot U s' L {s
STANDARDS Analytical Ini. Std.
V? 7 r_____
Column Type SUPERVISOR APPROVAL
-J7-u—7m~—ua:i:e__ ____
The presence ol the Chemist's employee II) ninnher, or signature. on I his run lop altcsts that si riel conipluiucc with i ho method . S' > I ‘ lu
occurred. Any SOI’ deviations require documentation by the responsible ehenusl logclhci with ihe eheinisl's iin 1 ials. ami ihe iniii ii■, >.| il
lab supervisor and a OA department represemalive. signifying approval of ihe deviation I .VI I ml dee
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Name: COMPUCHEM Contract: 8270C
lLab Code: LIBRTY Case No.: . SAS No.: SDG No.-. QE1877
Instrument ID: 5972HP60 Calibration Date: 03/14/02 Time: 2054
Lab File ID: HG020314B60 Init. Calib. Date(s): 03/03/02 03/03/02
Init. Calib. Times: 1401 1720
GC Column: J&W DB-5.625 ID: 0.32 (mm)
COMPOUND |RRF OR
I AMOUNT
I|Phenol 1___________________
I Bis(2 -chloroethyl)ether_
1
-Chlorophenol_3-Dichlloroben:
j,, j-un.ni'uiuui;ii^ene1 , 4 - Di chllorobenzene
1 , 2 - Di chllorobenzene
2-Methylphenol
1.3820000
0.9520000
1.0880000
1.4910000
1.4860000
1.4310000
-oxybis(1-Chloropropane)
|4-MethylphenolI N-NitrosoJ-di - N - propylamine__
|Hexachloroethane
!Nitrobenzene
0.8830000
ophorone__________^Hi trophenol______
4 -Dimethylphenol|Bis(2-chlbroethoxy)methane__
,4-Dichlorophenol_
,4-Trichlorobenzenei 1 : ____!Naphthalene___________________
i 4 - Chi oroam 1 me_____________
.Hexachlorobutadiene________
I 4 -Chloro- 3 -methvlDhenol, | ---2-Methylnaphthalene________
He.xa chi orocycl open tadiene
■ 2 , 4 ,■ 6 - Tr i chi orophenol_____
;2 , 4, 5 -Trichiorophenol_____
2 -Chloronaphthalene________
' 2-Nitroanil me__________
■Dimethylphthalate
2,6- Dmi trot clue ne_________■ Acenaphtrvj-lene_______________
3 - Hit roan illne
.-.cenaphthen-
- Dmitrophr i - N11ropheno1
,4 - Din: loluen-Dibenzofuran
methylphthalat
4 - Chiorophen Flucrene I
- phenvlether
.H11 roan 111 n-
b - uin. 11 ro - 2 - me t hvl phenol
raqe 1 c:
1.3580000 1.1220000
0.8140000
0.6340000
0.4960000
0.7810000
0.2450000
0.2970000
0.4700000
0.4380000
0.5200000
1.1890000
0.5010000
0.4060000
0.3640000
0.8S60000
0.4600000
0.4400000
0.4790000
1.2400000
0.4830000
1.6290000
0.3470000
9950000
3690000
1 3 0 0 0 0
217 0 0 0 0
2 9 6 0 0 0 0
5140000
2 . 1 8 1 0 0 0 0
i . / 6 0 0 0 0 0
0.96 0 000 0
1 . 7420000
0. 3 "" 2 0 0 0 0
0 . 1 6 o 0 0 0 0
|RRF80.000[ 1 ] 1 1
1 OR 1 MIN | %D OR 1 MAX %D OR|CURV|
AMOUNT1 j
RRF %DRIFT 1
I
%DRIFT |TYPE j
1 |
| 1.2750753 |------ 10.01 I
-------- 1-7.74
----------- |----- |20.00|AVRG|
|0.8755671| 0.01 1 -8.031 50.00|AVRG|
1.11011500.01 j 2.03 j 5 0.0 0|AVRG|
j1.6373799 j 0.01 j 9.82 j 50.00|AVRG|
1 . 5998988 0.017.66 j
20.00 AVRG
|1.5359906| 0.01 1 7.34 j 5 0.0 0|AVRG|
|0.9068195| 0.01 1 2.70 j 5 0.0 0|AVRG|
1.1937974 | 0.01 -12.0950.00 j AVRG|
1,1.0953021| 0.01 i-2.38|
50.00|AVRGj
|0.7133376 0.05 -12.37 50.00 AVRGjo.7421203 j
0.01 17.05 50.00|AVRG|
i 0 . 4382909| 0.01 1 -11.63 j 50.00jAVRG)
0.6846384) 0.01 -12.34| 50.00 AVRG
0.2407559 0.01 -1.73 2 0.0 0|AVRG|0.2769714 j 0.01 1 -6.74 j 50.00|AVRG|
0.4023271 0.01 - 14.40| 50.00 AVRG|
0.4600051j 0.01 [ 5.02 20.00 AVRG
0 . 5643432 0.01 8.53 50.00 AVRGj1.1397945 0.01 -4.14) 50.00 AVRG0.4297048 j 0 . 01 j -14.23 5 0.0 0|AVRG]0.4613911j 0 . 01 j 13 . 64 j 2 0.0 0 j AVRG j|0.3461601 1 0.01 -4.90 20.00 AVRG0.9192144 | 0.01 3.75 50.00 AVRG0.4473442 | 0.05 -2.75) 5 0.0 0|AVRG|
j 0.4297655 0 . 01 1 -2.33 20.00 AVRG
0.4557583 0.01 1-4 . 85 j 5 0.00 AVRG j
1.1247789| 0 . 01 1 -9.29| 5 0.0 0 .j AVRG |
|0.4269821 0.01 1 - 11.60 | 50.00 AVRG|
|1.4134 548 | o. oi j -13.23) 5 0.0 0|AVRGI
I0.3222148 ! 0 . 01 1 -7 . 14 | 50.00 AVRG|) 1.81 3 784 2 i 0 . 01 1 -9.08 50.00|AVRG
)0.3262621) 0 . 01 j-11.58)
5 0.0 0 j AVRG j
1 1 . 11^4 3 669 | 0.01 -5.00 20.00 AVRGlo.1856698) 0.05 -14.44 50.00)AVRG
i 0.3208015| 0.05) 3.38) 5 0.00)AVRG j
j 0.4 8 2 6 1 3 0 0.01 -6.11) 50.00 AVRG
2 . 137821-7 0.01 1 -1.98 50.00 AVRG[
I 1 . 6 1 3 5 0 3 0 |0 . 01 j
-8.32) 50.00)AVRG|
0 .9886520 0 . 01 [ 2 . 98 | 50.00 AVRGjl.7789175 0 . 01 j 2.12 50.00 AVRG| 0. 3076896 | 0 . 01 1 -17.29) 50.00|AVRG|
j0.1538125]
j 10.01)
[-7.34
150.00 AVRG
1 1
FORM VII SV 57c
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Name: COMPUCHEM Contract: 8270C
Lab Code: LIBRTY Case No.: SAS No.: SDG No.: QE1877
Instrument ID: 5972HP60 Calibration Date: 03/14/02 Time: 2054
Lab File ID: HG020314B60 Init. Calib. Date(s): 03/03/02 03/03/02
Init. Calib. Times: 1401 1720
GC Column: J&W DB-5.625 ID: 0.32 (mm)
i j |RRF8 0.0 0 0| 1 1 1 1
J COMPOUIID | P.RF OR OR MIN | %D OR 1 MAX %D OR j CURV|
i |AMOUNT AMOUNT |
1 i
RRF j
|
%DRIFT 1
1
%DRIFT jTYPE|
1 i1 ||N-Ni trosodiphenylamine
1 1 | 0.5330000 0.4876334 |
------ 10.01 I
-------- j-8.511
----------- |----- |20.00|AVRG|
I 4-Bromophenyl-phenylether | 0.3000000 j0.2951585| 0.01 | -1.611 50.00 jAVRG|
|Hexachlorobenzene | 0.3410000|0.3303247 j 0.01 1 -3.13 1 50.00 j AVRG|
|Pentachlorophenol 0 . 1000000 0.1177405 0.0517.74 j 20.00 AVRG|
|Phenanthrene | 1.2540000 1.1727415| 0.01 | -6.4850.00|AVRG j
Anthracene | 1.2630000|1.2627789| 0.01 I -0.02| 5 0.0 0 j AVRG|
! Carbazole 0 . 9800000 0.9256850 0.01 -5.54 50.00 AVRG|
!Di-n-but;Tphthalate j1.6380000 1 . 5508453| 0.01 -5.32 50.00|AVRG
! Fluoranthene | 1.4490000I1.5026635| 0.01 1 3 . 70 | 2 0.0 0 jAVRG|
| Pyrene 1.4350000 1.3087822 0.01 -8.80 50.00 AVRG|
]Butylben::\Tphthalate 0.7410000 0.6061015| 0.01 1 -18.20| 50.00|AVRG|
1 3,3' -Dichlorobenzidine 0 . 5660000|0.5614097 0.01 1 - 0.81 j 5 0.0 0|AVRG j
Hfiis ( 2 - etfivlnexvl) Pnthalate j1.0350000|1.0530921| 0.01 1 1.75 | 50.00|AVRGj
Bfenzo(a)anthracene | 1 .4320000 1.6387461| 0.01 1 14.44| 50.00 AVRG“hrysene 1.2900000 1.3561748 j 0.01 1 5 . 13 j 50.00|AVRG|
|Di-n-oct;Tphthalate 2 . 0140000 J 2.1167437 0.01 5.102 0.0 0 j AVRG j
; Benzo(b)fluoranthene [1.7250000 1 . 9346295 0.01 12.15 50.00 AVRG
Benzo(k)fluoranthene j 1 . 5600000 1.7494808 0.01 12.15 50.00|AVRG
i Benzo(a)pyrene 1 . 3800000 1.5472874 0.01 1 12.12 | 20.00|AVRG|
; Indeno i 1 2,3 - cd)pyrene i 1.4730000|1.7093933 j 0 . 01 1 16.05| 5 0.0 0|AVRG|
1Dibenzo(a,h)anthracene |1.2820000 1.5231834 0.01 18 . 81| 50.00 AVRG1 Benzo(a,
,
:, i)pervlene j 1 . 2410000 | 1 . 4 311206 | 0.01 1 15.32] 50.00 AVRG
j 2 - Fluorophenol t 1 . 2730000 j1.2073047 j 0.01 1 -5.16 50.00 AVRG;Phenol-d5
j 1 . 4360000 j 1 . 3727927 10.01 - 4 . 4 0 | 50.00 AVRG
! Hicroben: ene-d5 i 0 . 5720000|0.5252068 0.01 -8.18] 50.00 AVRG’ 2 - Fluorobipher.yl i 1 . 5550000|1.5076698 j 0 . 01 i -3.04 j
5 0.0 0 j AVRG|
2 . 4 , 6 - T r bromophenol 0.3 7 6 0000 0.4124754| o. oi! 9.70 5 0.0 0 j AVRG
Terphenyl -di A | 1 . 1100000 j 1 . 0347666
! ! I0.01
1-6.78
150.00 AVRG
I |
FORM VII SV
574
Data File: 7chem/5972hp60. i7DF020314B60.b/HC020314E60.d
Date : 14-MAR-2002 20;54
Client ID: SSTD080
Sample Info: SST0980:2319
Volume Injected (uL>: 2.0
Column phase: J8.W BB-5.625
Instrument: 5972hpb0.i
Operator: 2319
Column diameter: 0.--2
4.3- ;4.2- i
4.1-:
4.0; 3.9-i
3.8-1
3.7-; 3.6-i
3.5-i
3.4- ;3.3- 1
2,s;O J j
2.6-:
2.1-i
2.0-i
> 1.9-
l.s-:1.7-i
1.6-
1.5;
1.4-i
1.3-:
1.2; 1.1; i .0-;
0.,4_-.
0.3-
0.1-
0.0 -
7ch*m/5972hp60.i/BF020314B60*b/HC020314B60.d (Part 1 of 2)
VjC
oa>
o
o
u.'■‘J
liJ■75
Ir,
•1>Cl
VJ
b 7
Q
ntH
.1L , \j ij . Uj . .ill19 10
oLO
II
14
'..O
r—
LO
ij
i1
,<J
15 ih
Data File: 7chem/5972hp60. i/DF020314B60.b/HG020314B60.d
Date : 14-MAR-2002 20:54
Client ID: SSTD030
Sample Info: SSTD080:2315
Volume Injected (uL); 2.0
Column phase: JiU DB-5.625
Instrument: 5972hp60.i
Operator: 2319
Column diameter: 0.32
LO
r^-
LO
4.3- i
4.2- i4.1- 1
4.O'
3.9-:
3.8- 1 3.7-j
3.6
3.5
3.4- ;3.3- 1
3.2- i3.1
3.0
2.9
2.8
2.7
2.6
2.5-
2.42.3- i
2.2
2.1- j
2.0
1.9- i
1.8
1.7
1.6
1.5- j
1.4 1.31.2- 1
1.1
1.0
0.9
0.8
0.7
0.6-
0.4
0
20
0.1
16
7chem25972hp60.i/DF020314B60.b/HC020314E60.d (Part 2 of 2>
17 18 19 20 21
Data Fi Report
le: /chem/5972hp60.i/DF020314B60.b/HG020314B60.d Date: 14-Mar-2030 21:31
CompuChem
Data fi Lab SmpInj Date Operator Smp Info Misc Info Comment Method Meth Da Cal Da Als bot Dil Fac Integra Target Process
Semivolatile Report SW-846 Method 8270C le : /chem/5 9 72hp6 0.i/DF020 314B60.b/HG02 0 314B6 0.d Id: SSTD080 Client Smp ID: SSTD080
14-MAR-2002 20:542319 Inst ID: 5972hp60.iSSTD080:2319
/chem/5972hp60.i/DF020314B60.b/8270Cv6.m14-Mar-2030 21:31 naegler Quant Type: ISTD0 3-MAR-2002 17:20 Cal File: HL020303A60.d2 Continuing Calibration Sample1.00000
HP RTE Compound Sublist: all.subVersion: 3.50ing Host: einstein
te : e : tie : tor : tor:
Concent rat ion Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
D'F 1.00000 Dilution Factorv|t
1000.00000 Volume of final extract (uL)
A o 1000.00000 Volume of sample extracted (mL)
w i 1.00000 Volume injected (uL)
Cpnd Va riable Local Compound Variable
AMOUNTS
Ggan-; s:g CAL-AMT ON - COL
Compounds :v.ss 9T rvp py F.EL RT RESPONSE [ NG) ( NG)
ch 1 Dtcb-.-n - d-i 15: ‘1 . j 0 0 i 91913 40.0000
; 3-7 : i - 5 i ■ :4 5 '1.0 f j 7. 272010 40.0000
1 n 4 . /y .:. :• il- o! 242509 40.0000
. -y-n ' 1 . C•■0 i 495405 40.0000
r --.rvs- 7 .• :-y ■::: i 7 o: 579436 40.0000
:■■■ ■ ;. :■ ■; :: ; - v • ; - - 45P410 4 0 . Ohft
7 7.it;.,- i:i . -22 . 7 4 0- 221934 8 0.000 0 7 5 9 -.
•: ■il.. - z-,z ( 0 92-1 : 252355 90 . Oi.iOO 7 n 4 h
tr.z-j-.w-Si 4 7 -'0.832) 295723 6 0.0 0 C 0 73.47
:h:;v::v::yl 7 o ^ G: . ? 11 -■ 7 312J 7 30.0000 77 . 56
: 3 2- 14 . ::.: c 5.- 20005S 3 0.0 0 C 0 97 . 63: ::: T-i-p-jyl - : : 144 > 77- 14.775 1159162 30.0000 74 . 56
osodir-d-.by : :■ ’.9.416) 353083 eo. oooo 10 4.5
14 Pyrid: Cd 7v j ; 7 -.4 20: 353333 90.0000 76.43
SIMILARITY
b
964 3
9395
577
fa
Data File: /'chem/5 972hp6 0 . i/DF02 0314B6 0 . b/'HG02 03 14B6 0 . d Report Date: 14-Mar-2030 21:31
AMOUNTS
CUANT SIG CAL-AMT o o o tn
ompounds MASS RT EXF RT RE' RT RESPONSE ( NG) ( NG) SIMILARITY
15 Benzaldehvde 77 7.409 7.409 (0.911) 127371 60 . 0000 66 . 31 8580
16 Phenol 9-1 7 . 556 7.596 (0.933; 234392 SO.0000 73.75
17 Bis 12 -chloroethyl)ether 93 7.714 7 . 714 (0.948; 160952 80.0000 73 . 62
18 2 -Chroropheno1 123 7.799 7,799 (0.958: 204068 90 . C000 81 . 65 8965
*9 1,3-Dichicrober.zene 146 8 . 035 3 . 0 3 5 ■'0 9 8 9! 300993 30.0000 97.33
i.ehloroter.zene 1 4 c 3 . 1 54 8 . 154 (1.002: 294103 8 0 . 0 0 0 0 S 6 . 12
2: Benzy ) alcohol 104 8.374 6 . 374 '.1.029 123291 8 0 . 0 0 0 0 76.79
2 2 1 2 -D :en1c rooenzere 14 6 8.409 8 . 408 a . 033i 282355 80.0000 85.90
22 2 - Met nv 1 oheno 1 109 / 8 .544^ 8.594 (1.056) 166697 80.0000 82 . 18
2* 2.2 - oxyDis ■ 1 - ;_r.ioropropane ‘ •is' 8 5 2- 4 / 8.594 11 . C 5 6 .' 219451 60.0000 70.31 7 J 5 6
25 Acetophenone ✓ 105 3.914 ^ S.814 (1 . 083) 294264 80.0000 80.82 7756
2 6 3 -Methylphenol 105 - ✓ 8 . 647 8 . 647 (1.087) 201345 80.0000 78.10
27 4-Methylphenol 108 * ' 8.847 8.847 (1.087) 201345 80.0000 78.10
2 8 N-Nit rose-di-N-propylamine , 70 8.814' 8.814 (1.083) 131130 80.0000 70.09 0 (M)
29 Hexachlorosthane 117 8 . 966 3 . 966 (1.102) 136421 80.0000 93 .62 8046)it N ’ * mn~ ^ r- 77 9 . 101 9 . 101 (0.8 e 5 J 238439 80.0000 70.67 3895
31 Isoohcrone £ 2 9 . 507 ✓ 9.507 (0.924) 372457 80.0000 70.11 8762
3 2 2 -N l zrooheno1 13 9 5.543 3.543 (0.937) 130976 80.000C 76.62 8809
3} 2 . A ■ LuzetnyIphenoi 122 9.727 7.727 (0.945) 150678 80.0000 74 . 54 7970
3:s :2 ch 1 crce: r.cxy; rezhane 9 9.87? 9. S?9 (0.961) 21SS74 90.000C 69.43 7698
3 $ 2 . A - D ch 1 c ropner.o 1 ' 4 7 10 06 6 10.056 (0.979) 250252 80.0000 84 . 07
M i 7 .i • . --- 7:ich1crooenzene 180 10.201 10.201 (0.992) 307014 80.0000 66.88
37 Naph:.ya 1 ene 12S 10.336 ■10.336 (1.005) 620071 80.0000 76 . 70 8986
3!? 4 - Cl"! 1 croa: 1; re 127 1C.438 1 0 .438 11.015) 233768 80.0000 68 .60 3559
39 Hexach 1 orer-ueazi er.e |
225 10.539 1C . 539 11 . 025) 251006 80.0000 90.81 84 16
•1C Caprolactamr i 113 11.030 11 . 030 11.072) 31907 80.0000 54 . 16 8314
ro-j--n-jthylphenj' 1 0 7 11.30 0 11.300 ;i.059; 188318 80.0000 76.10 3775
2•Me f y iraphtha ler-- 14 2 11.537 11.537 i 1 .122) 500071 80.0000 82 . 99
i - y : rapntr.a 1 ene 142 11.707 11 .707 (1.138) 411619 80.0000 84 .50
i -i H s x a c . 2 3 7 11 . 3 0 S 11 . 303 (0.884) 216970 80.0000 77.84 9284
4T. 3 <■ ■ ■
I":' ^ ch 1 ere phene 1 i 9 6 12.04S 12.045 '0.9 01, 208444 80.0000 78.07
4 -j " 4 5 Czioricrcpren.t; 15? 12.113 : 2 . 1 1 ? i 0.9 0 6 < 221051 80.0000 76.05
: pr.or.y : ■:54 12 . 543 1 2 2 4 5 •.0.924) 632222 80.0000 72.08 e382
fc _ . 142 '•2 4 - '• 1 2 . 6 3 :. 5 2 7; 545538 80.0000 72.54
4 5 2 - N : t r oar.: ! : r.c 61 12.556 '.0.94 2) 414198 160 000 141.4 6995
y Ip:-.Is-.- 12.551 2 . 2 5 : 10.5 5 5i 685551 80.C000 69.40 9481
’ 2 . 0 0 5 ' 5 0 n 9 ' C c 7 2 ; 156280 80 . 0000 74 . 22 9533
... i. I'.thy i *) ii- : ? . 11 ■ • '1 u 3 1 ] 979718 80.0000 72.73 8 8 7 6
can : 1 ; r.e 125 12.214 15.314 • C . v o i 316486 160.000 141 .6 9243
t-i Arena-. ::v:-. = nv 12 4 15 *..•.4:5 -.004. 540483 8C . 0000 75 . 98 9364 ■
n:t roe non-! 144 :: : : '; . r. i o 450266 4 L 0.0 0 0 341.5
3 ti 4 -..; r. ; : 3 . •: 5 i 1 5.25: : 1 . 12:. 3 1118 9 1 f 0.0 0 0 ; 73 . 2 7 5 9 9
;. i rcr.v .2.7:.' : 1:1 1 ".■227: 234076 3 3.0000 75.05 7853
•.5.7 7 1 i . 7 i 7 ; 1 . 0 2 3 • 10 3 68 8 2 p. n . o o o n 78.42 9 3 7 6
-■= 19 " 14 142 (1.058. 732578 80.0000 73.34 9 3 90
, ,r..l - _• / ' ' 14.52' 1.072; 479514 80.0000 8 2. 25 7113
: • 14 3 2 3 ' ’4 2 - : 1 . 072: 862307 30.0000 81 . 72 7339
Data File: /chem/5972hp60.1/DF020314B60.b/HG020314860.d Report Date: 14-Mar-2030 21:31
AMOUNTS
QC Flag Legend
M - Compound response manually integrated.
y'UANT S2o CAL-AMT ON-COL
Compounds MASS RT IX? RT REL RT RESPONSE i NG) ( NG) SIMILARITY
12 4-NilroaniIine13 8 14.396 14 396 a.077i 298470 160.000 132.5 3219
6 3 4 . 6 - 0 i r. 11 ro - 2 - mechv In-heno I 198 14.447 14 447 i 0 . 504 .) 304798 160.000 148.7 8779
6A N-Nitrosediohenviamine 169 14.549 14.549 (0.910: 483152 80.0000 73.18 8322
6 5 1.2 -OiohenvIdvdrazine 77 14.616 14 .616 : 1 . 0 94 ) 796739 80.0000 74.93 ■ 9124
ii 4 - Brcmpoher.v 1 - Dnenvlecher 243 15.192 15.192 ! 0.9501 292446 80.0000 78 . 61 9673
67 Hexachlorobenzene 294 15.310 15.3 1 0 (0.958; 327289 00.0000 77.46 9185
63 Atra: i ne 200 15.479 15.479 (C.568) 10502 80.0000 11.16 8997
69 Pen.tachiorophenol 2 6 6 15 . 665 15 . 6 d 5 ( 0.9 h 0 233317 16C, . 000 188 . 6 8503(M)
7Q Phenanchrene 178 16 . 037 16.037 (1.003: 1161964 80.0000 74 . 73
Ar.chraesne 178 16.122 16.122 (1 . 003- 1251174 80.0000 79.99
~>2 Carba zole 167 16.410 16.410 (1.0261 917178 80.0000 75.60 9187
7 i n 2 -- buc’/iphcha late 14 9 17.002 17.002 (1.053: 1536593 SO.OOCO 75.72 928 3
74 Fluoranthene 202 13.110 10.113 (1.133! 1488854 80.0000 32.94
75 Benzidine 134 18 .355 18 . 355 (0.890) 277868 160.0C0 72.96 8103. _ 1
7-3 pyrene 202 1 8 524 18.524 (0 . 898 } 1516711 80.0000 72 . 96
11 B’-cyi jenzvl one ha lace 14 9 1 9 624 19 . 624 (0.952) 702394 8 C.0000 6 5.43 504 1
73 2,3'- 2 i cn1orobenzidine 252 20 555 20.555 (0.987) 650602 80.0000 79.37 6 613
7 9 b1s ' 2 -echy1nexy1:?hc ha lace 149 20.588 20.588 (0.998) 1220399 80.0000 81.40 S 9 6 4
= S-r;c ! a ) a n r. n r a c e r: e 22 8 20 605 20.605 10.599) 1899097 80.0000 91 . 57
6I Chrvs ere 2 2 S 20.655 20.65o (1.002' 1571633 80.0000 84 . 08
= : : 0,__ • , 145 2 ■ 570 21 . 570 (0.931) 1940673 80.0000 84 . 07
6 2 Pen z o : : ur.'rantnene 252 22 332 22.382 (0.966) 1773707 80.0000 89.72
i '< ) f 1 uoranchene 252 22.432 22.432 (0.969) 1603959 80.0000 89.74
i „ ( a 5 r.y ren~ 2 52 23 058 23 . 05S (0.955) 1418584 80.0000 8 9.66
56 Inden o • 1 . 2 , j —I'd ) pyrene 276 26 007 26.087 (1 . 126) 1567206 80.0000 92.83 8760
-7 .0: be:'. 17 3 26 137 26.127 (1.128) 1396485 80.0000 95.03 8745
j; 9 o n z 276 27.000 2 7 . n 0 0 ( 1 . 165) 1312080 30.0000 *2 .23 7388
>
ol3 y
57S
Data File: /chem/597.40060. 1 / DF02031-IB60. b/ HG020314B60 . dInjection Date: 14-MAR-2002 20:5*3Instrument: 5972hp60.lClient Sample ID: 5STD030
i
ompouna: 2.4,6-Trlbramophenol 9S Number: 118-79-6
1 . 1-
1.0*
0.?:
0.8:
0.7-'
u. 6 -
0.5-
0.4*
o.3-;
0.2-
0.1-
0.0—H.:
Ion 329.60: Area: 200058 Height: 109896
kn
14.4 14.5 14.6 14.7 14.8 14.9 15.0 15.1 15.4
1.0-
0.9-
0.6-
0.7’
0.6-
Ion 4.32.00: Area: 0 Height: 0
14.4 14.7 14.8M i n
14.9 15.0 15.1 15.2
1 .5-
1.3-
1 . 1
ion 141.00: Area: Height:
! 1
14.9 15.0 15.1y"
Data File: .•'chem./5972np60.1 .'DF020314B60. o.'HG0203 14E6Q. oInjection Date: 14-MAR-2002 20:54Instrument:|5972hp60.1
Client 5amole ID: SSTD030
ompouna: N pS Number:
Nitroso-dl-N-propy 1 amine 521-64-7
6.0-
5.6-
5.2-
4.0-
4.4-
4.0-
3.6-
3.2- '
2.8-
2.4-
n.O-
1.6-
1.2-
0.8-
0.4-
0.0--
Ion 70.00: Area: 131130 Height: 61720
TCD
0D-
/ l
8.5 8.3Min
8.9 9.0 9.1 9.2 9.3
1.2-
1 • It
1.0
0.9-.
0.8-
0.5 '
0.4
0.1-
0.0 -
Ion 130.00: Area: Helght: 0
9.0 9.1
0.8-
6.9 9.1 9.3
10 •'
Lompound: Pentachlorophenol kCAS Number: 87-66-5
Data File: .'chem/59?2hp60 . l / DF 02031 4 360 . b/HG020314B60 . dInjection Date: 14-MAR-2002 20:54Instrument^: 5972hp60. lClient Sample ID: SSTD080
i
1.2-.
1.1-
1.0-'
0. 9-
0.8-
0.7-
0.6-
0.5:
0.4-'
0.3-
0.2-
0.1-
n n~—15.2
Ion 266.00: Area: 233317 Height: 124965
$
15. 15.4 15.5 15.6 15.7 15.8 15.9 16.0 16.1Min
3.0-
7.5-
6.5-
b. 0-
5.5-
5.0-
w~ 4.5-
4.U
3.5'
I .5-
1.0-
0.5-
0.0 -
Ion 268.00: Area: 80179 Heignt: 80179
i£sO
15. j 15.! 15.6 15.9 16.0
I Of. 26-4.00: A ro 5: 7S067 Heiznt: 7B067
15 15.6 15.7
M i nlb.1!
COMPUCHEM a i. vision of Liberty Analytical Corp DATE
GC/MS SEMIVOI ATILI: RUN LOG
COMPUCHEM .LOGBOOK 4 V(4) 4 (5972hp60)
/ )M/0^ INITIAL TIME OF TUNE__2<Vbi
TIME TUNE EXPIRES 03 S
SHIFT/S(A)(B) .(C)
LINKER /METHOD__ C
PREVENTIVE MAINTENANCE (Oon-c
C ' T l0: FILENAME; • k ■'T
> D •■ DATE TIME Z* , :GLlENtID# CASE/SDG# AMOUNT
INJECTEDCHEMIST COMMENTS(ETC.)/DISPOSITION^^~-
1 / y 1 IH7 o; Soil TFTfP _ c?5I5 Li )ScD-LcDy
2 |46iO)H ELo / / / SST^oftsC 4/3 y/06i|L£oM-l£U / / / X 0 S?>Ll^36s utL4 U6) z / / S3 6 LcS 4/5 / Q&ivn-sfc&fro / Mw-%A Ifc'n Hf^se/.Vr rf l ^Z5/-
6 Qe nm-s< g(/o2
' / MiaI-uS 4/7 / b /lb/o> CXVfr Mvu-ZiB apnon
8 « ;&)yw»mo / / <00 5^ Alto - i9 / / otF2 F733Z
10 / SL / / 6^/7 owFV f?3 221 1 / / CZ-5? ) AK12 L<rWJ'-H&Jb z / / 04l? 1
13 P?3?z-/sm> z / / OTP 3/ -
14 4 lumj> / / oHOs*
15 nv?- /mo fk / / 0433 CftfF?16 / mvi-nfibLo SL / / (%/7 WF3t,Pt)L
____ \17 / Tl /^1/
N \?Ol^
18 ----- 7“ /------ flbl - » To^e ____ —19 / /20 / /21 / / ———-— 5 /
22 / /23
---- —~ ----L‘---- 7 /
----aA24 ----- A--/------
Std. ID tt
TuneSTANDARDS
Analytical
Hbll
Int. Std. Column Type
yh
Lot tt 3l2lS -g-ysb'H-
3*-^ DATE
SUPERVISOR APPROVAL
The presence of the Chemist's employee II) number, or signature, on this run log attests that strict compliance with the method's Si >1' ha-,
occurred Any SOP deviations require documentation by the responsible chemist together with the chemist's initials and the umiak oi i1,.
lab supervisor and a QA department representative, signifying approval of the deviation , ?:■ i/n; a,.
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Name: COMPUCHEM
Lab Code: LIBRTY Case No.:
Instrument ID: 5972HP64
Lab File ID: HG020311A64
Contract: 8270C
SAS No.: SDG No.: QE1877
Calibration Date: 03/11/02 Time: 0855
Init. Calib. Date(s): 03/10/02 03/10/02
Init. Calib. Times : 1416 1723
•—1
0uuo
,umn: RTX-5 ID: 0.32 (mm)
1
1 COMPOU
1
1
MD
|___ |RRF80.000|
RRF OR | OR
|AMOUNT |AMOUNT |
1 i |
1 1
MIN |%D OR |MAX %D ORRRF |%DRIFT j %DRIFT
l i
1 1
|CURV| j TYPE j
1 l1----------1 Phenol
__ |----------- |------------ | .j 1.4530000|1.3750083 j
----- 1 __0.01 |
------1------5.371 20.00 |AVRG|
1 Bis (2 - ch'loroethvl) ether | 0.9870000 I 0.9678347| 0.01 1 -1.94 | 50.00 |AVRG|
| 2 -Chlorophenol| 1.3440000 j1.3378068 j 0.01 j -0.46 j
50.00j AVRG j
| 1,3 -Dichlorobenzene I 1.5440000|1.5053199 0.01 -2.50 50.00|AVRG j
| 1,4-Dichlorobenzene |1.5580000 j1.5087010| 0.01 1 -3.16 20.00 |AVRG|
| 1,2-Dichlorobenzene|1.5340000 j1.4831560| 0.01 I -3.31| 50.00
|AVRG j
! 2-Methylphenolj1.1720000 1.1752022 j 0.01 1 0.27 | 50.00
j AVRG
| 2 , 2' -oxybis(1 -Chloropropan
|4-Methvlphenol
e) 1.8230000|1.7884050|]1.2740000 j1.2270109|
0.010 . 01 1
-1.90 -3 . 69|
50.00
50.00
|AVRG|
|AVRG|
|N-Nitroso-di-N-propylamine
|Hexachloroethane
__ 0.80300000.78429090.8060000|0.7866033
0.05
0.01
-2 . 33 j
-2.41j50.00
50.00
|AVRG|
| AVRG
!Nitrobenzene |0.3400000 0.3524220| 0.01 3.65 50.00jAVRG '
Jjlsophorone |0.6730000|0.6543315 | 0.01 1 -2.77 50.00 |AVRG|
B-Nitrophenol 0.2150000 0.2096179 0: 011 -2.50 20.00 AVRGW, 4 - Dimethylphenol |0.3200000|0.3189410 0.01 1 -0.33| 50.00 |AVRG|
)Bis(2 - chloroethoxy)methane
2,4 -Dichlorophenol
__ 0.40200000.3752985
| 0.3310000 0.3137093|0.01
0.01
-6.64 |
-5.22
50.00
20.00
j AVRG j
AVRG1 1, 2 , 4 - Trichlorobenzene 0.3860000 | 0.3640747 0.01 1 -5.68 50 . 00 AVRG |
1 Naphthalene 1.4460000 1 .43295490 . 01 j -0 . 90| 50.00 |AVRG|
|4 -Chloroaniline| 0.4620000|0 .4635959 j 0.01 1 0.34) 50.00 )AVRG|
1 Hexachlorobutadiene | 0.2660000|0.2515176| 0.01 1 -5.44| 20.00j AVRG|
! 4-Chloro 13 -methvlphenol 0 . 3680000|0 . 3701861j0.01 0.59) 20.00 AVRG |
j2-Methvlnaphthalene ] 0 . 7240000 0.6882150 0.01 1 -4.94 50.00AVRG j
|Hexachlorocyclopentadiene
! 2,4,6 -Trichlorophenol
S 0.3960000|0.4023036j
0.4070000 0.4109771
0.05)0.01 j
1.72 |
0.98
50.00
20.00
|AVRG| AVRG j
; 2,4,5-Tr ichlorophenol | 0.4320000|0.4324343 0 . 01 I 0.10 50.00 AVRG2-Chloronaphthalene 1 . 0260000 1.0233779[ 0.01 -0.26| 50.00 | AVRG
2 - Mitroaniline j0.3670000|0.3652370| 0 . 01 1-0.48 j
50.00 |AVRG|
1 Dimethylphthalate j1 . 2540000 1 . 2669037 0.01 1 . 03 | 50.00 |AVRG|
2,g-Diniurotoluene| 0 . 3450000| 0. 3444937 j
0.01 -0.15 50.00 | AVRG
:Acenaphthylene 1 2 . 4090000 12.3553686 0 . 01 1 -2.18 50.00 AVRG. 3 - Mi t roam 1 me i 0.3650000|0.3£18 763} 0 . 01 1 - 0.86| 50.00 [AVRG|
■Acenaphthene 1.5590000|1.4453141 0.01 -7.23 20.00 | AVRG
2 , 4 -Dmitrophenol 0.0610000j0.0678740 0.05 11.27 50.00 |AVRG|4-Mitrophenol i 0 . 2170000 i 0 . 2 154058 1 0.05 j
-0.73| 50.00 |AVRG1
2,4-Dinitrotoluene |0.5000000i 0.5007911! 0.01 1 0 . 16 | 50 . 00 AVRG |
Dibenzofuran | 1 . 6140000 j1 . 5663238 0 . 01 j -2.95 50.00AVRG j
D i e t hy 1 p!i t ha 1 a t e 1 1 . 4340000 1 1 . 4 539740 j0 . 01 1 -2.021 50.00 | AVRG
4 - Chlorophenyl-phenylether Fluorene |
(0.693000010.6747008)! 1 . 8 5 2 0 0 0 0 j1.8500119|
0.01 |
o. oi |
-2.64 |
-0.11
50.00
50.00
j AVRG|
AVRG |
_4 - N11 roan 111ne 1 0 . 3800000 ! 0.3839842j 0.01 1 1 . 05 | 50 . 00|AVRG j
^ 6 - D i n i Jro - 2 - me t hvl oheno 11
; 0. 1620000 i 0.1713274 j
i _ ! 10.01
15.76
i50.00 AVRG |
1 1
orFORM VII SV 584
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab
ILab
Name :
Code :
COMPUCHEM
LIBRTY Case
Instrument ID: 5972HP64
Lab Fi le ID: HG020311A64
GC Column : RTX-5 ID :
Contract: 8270C
No.: SAS No.: SDG No.: QE1877
Calibration Date: 03/11/02 Time: 0855
Init. Calib.. Date (s) :: 03/10/02 03/10/02
Init. Calib. Times: 1416 1723
0.32 (mm)
[ | [RRF8 0.0 0 0| i 1 1 1
j COM POUT- ID RRF OR OR | MIN | %D OR 1 MAX %D OR|CURV|
! |AMOUNT AMOUNT
1 1 1RRF
t
%DRIFT 1
1
%DRIFT TYPE)
| |' 1|N-Nitrosodiphenylamine
i----------- j------------ 1|0.4360000|0.4269002 J
------10 . 01 I
-------- 1-2 . 091
----------- |----- |20.00|AVRG|
j 4-Bromophenyl-phenyletherjo.2120000) 0.2077959| 0.01 1 -1.98 50.00 AVRG|
Hexachlorobenzene1 0.2610000 j 0.25725231 0.01 i -1.44 j 50.00 AVRG|
! Pentachlorophenol 0.1740000 | 0.1739961j 0.05 1 -0.00 j 20.00 AVRG|
]Phenanthrene | 1.4880000|1.4449910 0.01 | -2.89 j50.00 AVRG
|Anthracene 1 . 5130000 1.4528678 | 0.01 j-3.97 50.00|AVRG|
iCarbazole | 0.9960000|0.9662441j 0.01 j -2.99] 50.00 jAVRGj
!Di-n- but \ lphthalate | 1.4890000 1.4738923| 0.01 1 -1.0150.00 j AVRG|
Fluoranthenej1 . 7160000 j1.6882611j 0.01 j
-1.6220.00|AVRGj
:Pyrene 1.9180000 1 . 8749487 0.01 -2.24| 50.00 AVRG
j Butylbenz •■/lphthalate | 0 . 7700000 | 0 . 7440325| 0.01 1 -3 . 37 | 5 0.0 0|AVRG|
|3,3'-Dichlorobenzidine| 0.5420000 j 0.5080123 |
0.01 1 -6.27 50.00|AVRG|
^2 is(2-etl ylhex’.T) Phthalate 1.1480000 1 . 1179279 0.01 -2.6250.00 j AVRG j
(a ) anthracene ) 1 . 7590000 | 1 . 7380184 | 0.01 j -1.191 5 0.0 0 jAVRG j
■Phx'ysene 1.6580000 1 . 5977958 0.01 1 -3 . 63 | 50.00 AVRG|
j Di - n-oct;. lphthalate 2 . 2640000 2.1753928) 0.01 -3.91 20.00|AVRG
! Bento (b) fjluoranthene )2.1450000 2 . 3078830 0.01 7.59 50.00 AVRG! Benzo ! k ) fjluoranthene )1.9380000|1.7480163 0.01 -9.80 50.00 AVRG
■ Bento ' a'p yrenej 1 . 7000000 j 1 . 6625427 j
0.01 -2.20 20.00 AVRGIndeno ! 1, 2,3 -cd)pyrene 1 . 2280000 1 . 1978155 0.01 -2.46 50.00 AVRG
:Dibento !a ,h)anthracene| 1.4 900000 j1.444 3789|
0.01-3.06 j 50.00 AVRG j
|Bento (g,h ,iiperylene | 1.5630000 | 1 . 5249788 ) 0.01 ] -2.43 | 5 0.0 0|AVRG|
;2 -Fluorcphenol 1.2980000 1 . 2764316 0.01 -1.66 50.00 AVRG, Phenol -dS j1 . 6910000 | 1 . 6216721 | 0.01 1 - 4 . 10 j 50.00)AVRGj
: tli trobenz e n e - d 5 ) 0.4 3 30000! 0.4174573 0.01 -3.59 50.00)AVRG2 - FTuorobiphenvl ■1.3330000jl.352?710 0.01 1.50 50.00 AVRG2 , 4 , 6 - T r r bromophenol 0.*1030000 j 0. 3 96 6 S2 2 j 0.01 j -1.56 j 50.00 AVRG j
Terphenyi -dll j 1 . 0 5 9 0 0 0 0 ) 1 . 0 1 0 0 2 3 0 !i ! i
0 . 01 [
1
-4.62)
I
5 0.0 0|AVRG|
1 1
FORM VII SV
<:<10~6)
Data File: /chem/5972hP64.i/DF020311A64.b/HG020311A64.d
Date : ll-MAR-2002 08:55
Client ID: SSTD080 Instrument: 5972hp64. i LOSample Info: SSTD080;2070 OOVolume Injected <uL): 1.0 Operator: 2070 LO
Column phase; RTX-5 Column diameter: 0.32
Data File: /chem/5972hp64.i/DF020311A64.b/HG0203ilA64.d
Date : ll-MAR-2002 08:55
Client ID: SSTD080
Sample Info: SSTD080:2070
Volume Injected <uL>: 1.0
Column phase: RTX-5
Instrument: 5972hp64.i
Operator: 2070
Column diameter: 0.32
ooLO
* *ISTD DIFFERENCE REPORT**
Inj ection
Inj ection
Date
Date
of Current CCAL:
of Previous CCAL:
ll-MAR-2002 08:55
10-MAR-2002 14:16
Maximum %Difference of ISTD: + 100 Minimum %Difference of ISTD:
ISTD Name Current CCAL Previous CCAL % DiffArea Area
1,4-Dichlorobenzene-d4 105735 106189 -0.4Naphthalene-d8 414967 418210 -0.8
Acenaphthene-dlO 285056 297124 V4.1Phenanthrene-dlO 592430 631561 -6.2
Chrysene-dl2 562509 596220 -5.7
¥Perylene-dl2 300075 309056 -2.9
Retention time must fall within +/- 30 seconds (0.5)
ISTD Name Current CCAL Previous CCAL AbsoluteRT RT Difference
1,4-Dichlorobenzene-d4 8.249 8.266 0.017Naphthalene-d8 10.143 10.143 0.000
Acenaphthene-dlO 13.152 13.169 0.017Phenanthrene-dlO 15.485 15.485 0.000
Chrysene-dl2 19.949 19.966 0.017Perylene-dl2 22.434 22.451 0.017
-50
PASSESPASSESPASSESPASSESPASSESPASSES
PASSESPASSESPASSESPASSESPASSESPASSES
588
Data File: /chem/5972hp64.i/DF020311A64.b/HG020311A64.dReport Date: ll-Mar-2030 09:26
Data file Lab Smp Id Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date|
Als bottle Dil Factor Integrator Target Version: Processing Host:
CompuChem
Semivolatile Report SW-846 Method 8270C /chem/5972hp64.i/DF020311A64.b/HG020311A64.d SSTD080 Client Smp ID: SSTD080ll-MAR-2002 08:552070 Inst ID: 5 972hp64.iSSTDO 80:2 0 7 0
/chem/5972hp64.i/DF020311A64,b/8270Cv6.mll-Mar-2030 09:26 mikhael Quant Type: ISTD10-MAR-20 02 17:23 Cal File: HL020310A64.d2 Continuing Calibration Sample1.00000
HP RTE Compound Sublist: all.sub3.50einstein
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
DF 1.00000 Dilution Factor
_ Vt 1000.00000 Volume of final extract (uL)Vo 1000.00000 Volume of sample extracted (mL)Vi 1.00000 Volume inj ected (uL)
Cpnd Var iable Local Compound Variable
AMOUNTSQUANT SIG CAL-AMT ON -COL
Compounds MASS RT EXP RT REL RT RESPONSE ( NG)' ( NG)
- 1 1,4 - Dietilorobenz ene-d4 152 0.249 8.249 (1.000) 105735 40.0000* - Naphtha 1ene-dS 136 10.143 10.143 (1.000) 414967 40.0000
3 Acenapht he ne-d10 164 13.152 13.152 (1.000) 285056 40.0000• 4 Fhenant nrene-d10 188 15.485 15.485 (1.000) 592430 40.0000
s Chryserv > - d:: 2 4 0 19 . 94 9 19.94 9 (1.000) 562509 40.0000Perviene-dlI 264 22.434 2 2.4 34 (1.000) 300075 40.0000
: 7 2 - Fluor. >ohenoi 112 6 . 4 5 7 6.457 (0.783) 269927 80.0000 78 658 Pheno1 - d5 9 9 7 . 7 4 2 7.742 (0.939) 342935 80.0000 76.71
5 9 Nit robentene- dr 8 2 9 095 3 . 095 (0 . 897] 346462 80.0000 77 . 15S 10 2-Fluorobi phenyli r 1 172 11 . 8e4 11 . 804 (0.904) 771345 80.0000 81.223 :: 14.454 14.454 (1.099) 226159 80.0000 78.80- : ~i Terphen1 • 1 - d 11 244 17.652 17.852 (0.895) 1136294 80.0000 76 . 31
1 1 N -Nit rosedimethr 1 amine 4 2 4 . 327 4.327 ( 0.525) 100269 80.0000 79.4511 Pyndin- 7* - ■327 4.327 (0 . 525) 175431 80.0000 80.18
SIMILARITY
8 84 0
9411
Data File: /chem/5972hp64.i/DF020311A64.b/HG020311A64.dReport Date: ll-Mar-2030 09:26
AMOUNTS
QUANT SIG CAL-AMT ON-COL
Compounds MASS RT EXP RT REL RT RESPONSE ( NG) ( NG) SIMILARITY
15 Benzaldehyde 77 7.641 7.641 (0.926) 182826 80.0000 78.95 9710
16 Phenol 94 7.776 7.776 (0.943) 290773 80.0000 75.68
17 Bis(2-chloroethyl)ether 93 7.894 7.894 (0.957) 204668 80.0000 78.41
182-Chlorophenol 128 7 . 996 7.996 (0.969) 282906 80.0000 79.63 9323
19 1,3-Dichlorobenzene 146 8.199 8.199 (0.994) 318330 80.0000 77.98
20 1,4-Dichlorobenzene 146 8.283 8.283 (1.004) 319045 80.0000 77.46
21 Benzyl alcohol 100 8.452 8.452 (1.025) 162485 80.0000 77.59
22 1,2-Dichlorobenzene 146 8.554 8.554 (1.037) 313643 80.0000 77.36
23 2-Methylphenol 108 8.621 8.621 (1.045) 248520 80.0000 80.22
2 4 2,2'-oxybis (1 - Chioropropane) 45 8 . 672 8.672 (1 ..051) 378194 80.0000 78.46 9006
25 Acetophenone 105 8.858 8.858 (1.074) 344398 80.0000 f!6.93 9239
26 3 -Methylphenol 108 8.824 8.824 (1.070) 259476 80.0000 77.05
27 4-Methylphenol 108 8.824 8.824 (1.070) 259476 80.0000 77.05
28 N-Nitrose-di-N-propylamine 70 8 . 875 8.875 (1.076) 165854 80.0000 78 . 15 8492
29 Hexachloroethane 117 9.010 9.010 (1.092) 166343 80.0000 78.04 9379
30 Nitrobenzene 77 9.129 9.129 (0.900) 292487 80.0000 82.96 9283
31 Isophorone 82 9.450 9.450 (0.932) 543052 80.0000 77.79 9178
32 2-Nitrophenol 139 9.602 9.602 (0.947) 173969 80.0000 78.16 8442
33 2,4-Dim -1 hylpheno1 122 ■ 9.602 9.602 (0.947) 264700 80.0000 79.79 8456
34 Bis[2 -chloroethoxy]methane 93 9.737 9.737 (0.960} 311473 80.0000 74.75 9462
25 2,4•DichloroDhenol 162 9 . 923 9 . 923 (0.978) 260358 80.0000 75.77
36 1,2,4-Trichlorobenzene 180 10.075 10.075 (0.993) 302158 80.0000 75.41
■^3 7 Naphthalene 128 10.177 10.177 (1.003) 1189258 80.0000 79.29 9319^H3 6 4 - Chloroani 1 me 127 10.261 10.261 (1.012) 384754 80.0000 80.22 7545
3? Hexachlorobucadiene |
225 10.413 10.413 (1.027) 208743 80.0000 75.65 9362
40 CaDrolactam |
113 10.718 10.718 (1.057) 93949 80.0000 79.92 9664
4 1 4 -Chlore - 3 -methylphenol 107 10.938 10.93S 11.078) 307230 80.0000 80.48 9218
42 2 -Methyjlnaphtha 1 ene 142 11.208 11.208 (1.105) 571173 80.0000 75.98
4 3 1-Met hyl napht halene 142 11.394 11 . 394 (1.123) 534977 80.0000 74.58
44 Hexach1orocyclopentadiene 237 11.597 11 . 597 (0.882) 229646 80.0000 81.33 9604
45 2,4,6-Trichlorophenol 196 11.749 11.749 (0.893) 234303 80.0000 80.77
46 2,4,5-Ti ichlorophenol 196 11 . 817 11 .817 (0 . 898) 246536 80.0000 80.11
47 l.i'-Eipheny1 154 12.053 12 053 (0.916) 672680 80.0000 78.78 7597
4 8 2 - Ch 1 o ror;at-hr na me1 h 162 12.104 12.104 (0.920) 583440 80.0000 79.78
4 9 2 -Nltro ini; me 65 12 . 34 1 12.341 ! 0.938) 208226 160.000 159.1 9503
50 D:methy1 -pht ha late 163 12.679 12 679 (0.964) 722277 80.0000 80.82 0804
r. • -> r. . o ^ -- roio1jene 165 12.831 12.831 (0.976) 196400 80.0000 79.87 9274
5 2 Acer..ich•
- hylone 152 12.399 12.8 9'? (0.981 ) 1343394 80.0000 78.26 8903
6 3 3 - N i 11 t”::;ne 138 13.095 1 3 03 5 (0.9951 206310 160.000 158 . 5 9159
54 Arenaph -hen e 154 13.220 12.220 (1.005) 824561 80.0000 74 .21 8962
5 5 2,4 -Dlr -1 rophene: 184 13 .254 13.254 (1 .008! 193479 400.000 444 . 9
5 6 4 - Ni tropher:o i 109 13.304 1 3 304 [ 1.012) 122806 160.000 158 . 6 7625
6 7 2 , 4 - 2-1 r. ~ r:h oh.ene 165 13.507 I 3 507 (1.027) 235507 80.0000 80 . 11 8725
58 Dibenzo "ut an 165 13.474 1 3 4 74 (1.024) 892980 80.0000 77.63 9193
5 t u: e tn y 1 p h r n a 1 a c e 149 13.862 13 B 6 2 (1.054) 828928 80.0000 78.38 9551
6. 4 - Ch 1 orc-phery i - phenyl ether 2 C4 i 3 . 9 5 9 1 3 998 (1.064) 384655 80 . 0000 77.85 7476
•r : riot v v r. 16 6 14.043 1 4 04 3 (1.063) 1054714 80 . 0000 T9 . 91 7525
5 9 G
Data File: /chem/5972hp64.i/DF020311A64.b/HG020311A64.dReport Date: ll-Mar-2030 09:26
i
Compounds
QUANT SIG
MASS RT EXP RT REL RT RESPONSE
AMOUNTS
CAL-AMT ON-COL
( NG) ( NG) SIMILARITY
62 4-Nitroani1ine 138 14.116 14.116 (1.073) 218914 160.000 161.6 8758
63 4,6-Dinitro-2-methylphenol 198 14 .167 14.167 (0.915} 202999 160.000 169.3 9422
64 N-Nitrosodiphenylamine 169 14.201 14.201 (0.917) 505817 80.0000 78.39 8113
65 1,2-Diphenylhydrazine 77 14 . 251 14.251 (1.084) 846132 80.0000 79.20 9353
66 4-Bromophenyl-phenylether 248 14.758 14.758 (0.953) 246209 80.0000 78.34 .9666
67 Hexachlorobenzene 284 15.029 15.029 (0.971) 304808 80.0000 78.89 9456
6 31
Atrazine 200 15.012 15.012 (0.969) 234997 80.0000 79.75 9163
69 Pentachlorophenol 266 15.283 15.283 (0.987) 206161 160.000 160.3 7691
70 Phenanthrene 178 15.519 15.519 (1.002) 1712112 80.0000 77.66
71 Anthracene 178 15.570 15.570 (1.005) 1721445 80.0000 76.83
72 Carbazole 167 15.790 15.790 (1.020) 1144864 80.0000 77.63 9621
73 Di-n-butylphthalate 149 16.229 16.229 (1.048) 1746356 80.0000 79.21 9083
74 Fluoranthene 202 17.261 17.261 (1.115) 2000353 80.0000 78.71
7 S_ . .. 1Benzidine 184 17.413 17.413 (0.873} 1203807 160.0.00 148 7 8821
76 Pyrene 202 17.683 17.683 (0.886) 2109351 80.0000 78.19
77 ButyIbenzylphthalate 149 18.816 18.816 (0.943) 837050 80.0000 77.32 9192
78 3,3'-Dichlorobenzidine 252 19.830 19.830 (0.994) 571523 80.0000 74.96 8084
79 bis (2-ethylhexyl)Phthalate 149 19.780 19.780 (0.992) 1257689 80.0000 77.90 9433
80 Benzo (a)janthracene 228 19.915 19.915 (0.998) 1955302 80.0000 79.05
31 Chrysen* 228 19.999 19.999 (1.003) 1797549 80.0000 77.08
82 Di •n -oct y lphchalate 149 20.760 20.760 (0.925) 1305562 80.0000 76.87
93 Benzo{b) fluorant hene 252 21.690 21.690 (0.967) 1385076 80.0000 86.06
ft4 Benzo (k) f 1 uoranthene 252 21.741 21.741 (0.969) 1049072 80.0000 72.13P
Benzo(a) pyrene 252 22.333 22.333 (0.995) 997775 80.0000 78.25
3 6 1 ndeno(1 ,2.3-cdipyrene 276 25.021 25.021 (1.115) 718869 80.0000 78.02 0 (M)
87 Dibenzo a,hiant hracene 278 25.021 25.021 (1.115) 866844 80.0000 77.54 8247
8 8 Benzo(a, h,l)perylene 276 25.849 25.849 (1.152) 915216 80.0000 78.07 9281
QC Flag -.egend
M - Comp Dund response manually integrated.
3- //- „ l
Data File: /chem/5972hp64.i/DF020311A64.b/HG020311A64.d Injection Date: ll-MAR-2002 08:55 Instrument: 5972hp64 . i
COMPUCHEM a division of Liberty Analytical Corp DATE 3 / // Id INITIAL TIME OF TUNE off b 2. SH1FT/S(A) (B)(C)
GC/MS SEMIVOLATILE RUN LOG TIME TUNE EXPIRES 2 51 LINKER/METHOD___* y 'COMPUCHEM .LOGBOOK 4 YYY 4 (5972hp64)
T1 fTl PREVENTIVE MAINTENANCE/VrY\ t,
(CT(
FILENAMEo*TED
DATE TIME CLIENT ID# CASE/SDG# AMOUNTINJECTED
CHEMIST COMMENTSIPTC VlMpU^lTft tNLO 'cj-
1 1)(-X> LC '7) H A /jL / 5 1H161 7? 3 z "jtrryf_
i_x4Z 4/ 33cZ /.A
2 T nfaviv\K A/c- 7 / / <7 S's'r S'iZbt.Sn__.
3 J/il(HL. hkU / / / oci3i iTU/rra_____ ___0 /-/' t Q v- I______ 1 uP
4 / C\b o_7 1- 1 t a s| / / IV l 1 7) u//c Qpp 2 C- <Z’ 2 4 7?_____^ ‘ fr - /t- X (■____________ :______
5 7 (T) ? U-7 L ? h rl. / / ^R/Ao PP t- f___ ____ i_^____ aLc___ i 1___________
6 / 33 ?d7i ?l"Wu ViT / / ill 7 t-ei/Aotv ^ ____Ali
7 (T) All, // / \7!<i m.-t- c ^ c' K
8 / It ft A- 7.?> h6u tH / / 11 <TV _________ 1 A/ t ___A-tS:_____
9 Gj S.'i 11 (*& t -v-T?/Av / / / I 3 2 'if __________ UlldL A
10 r~\?(sn / / / / 4 o S' /S Ccf/C’ t'JCfyt l/a )) L ___z_____
11 / c?)■>(,')% .rT)Mv im / / >442 K L'JP 2 S'___
12 (Z?C 73 S'VpU,/ / / /r z 4/---------------------------
13 /OIM- Wa/i, / / / S 5" 7 OU l Ao nr’2 7 /7 tL
14 4046 >4^ ADH / / / l4>64 £»oC^>lAO LA 3^10
15 4U4S2 -H3 At»4/
-/ nn
16 / -5/UW xu/ / DM*> u 4\j oj>
17 / L04£>' C> Alh m / / OSotMiiol
18 U346> -744 4 / / / 03>3U4uo^.
19 4uM6;>ZA(H z / / IW 0<>o4H uo3
20 LA 34^/ / /
_____ __0^0^4 Wo3D
21 / mor
/ s!//uo4 4
\J____
N/
22
23
/ /
/ /----- ^73------3)mIO
24 ----------r —
STANDARDS / * ^ /Tune Analytical hit. Std. Column Type SUPERVISOR APPROVAL ZZ-./j'AZ
StdrlD#---Z-SA ------ k > -•---- _______________________ DATE'ZjjJ.io > _____________________ __________
Lot #-— ^ C 3 /3 2 '6 /_____ __S i S \ V( I he presence of the Chemist's employee II) numhci. or srgnrmne. on this rim log attests that strict compliance with the method's St H
occurred Any SOP deviations require documentation by the responsible chemist together with the chemist s initial-, and the initials -
Idh supervisor aru^if,)A department represeritatue siuriil) ine approval ol the deviation __ I I .'o.;(i|
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Name: COMPUCHEM
Lab Code: LIBRTY Case Instrument ID: 5972HP64
Lab File ID: HG020311B64
Contract: 8270C
No.: SAS NO.: SDG No.: QE1877
Calibration Date: 03/11/02 Time: 2253
Init. Calib. Date(s): 03/10/02 03/10/02
Init. Calib. Times: 1416 1723
GC Column: RTX-5 ID: 0.32 (mm)
COMPOUND
Phenol_J____________________Bis (2 - chjloroethyl) ether
Chlorophenol_
1, 3-Dichlorobenzene_ 1,4 -DiclJlorobenzene_
1,2- Dich'lorobenzene_
2-Methvlphenol_______
2,2' -oxybis(1 -Chloropropane) 4 - Methyllphenol
N-Ni trosjo-di - N - propylamine__
Hexachioroethane
Nitrobenzene
Isophorone
Nitrop'henoi
thylphenol_4 -Dime
|Bis(2 -ch j2,4-Dich
|1,2,4-Tr j Naphthal
! 4 - Chi oro'ani line
loroethoxy)methane_
lorophenol___________
ichlorobenzene_
ene
| Hexachlorobutadiene_____
| 4-Chloro-3-methylphenol_
| 2-MethyLnaphthalene_____
Hexachiorocyclopentadiene
i 6 - Tr
5 - Tr
ichlorophenol_
ichlorophenol
j 2 -Chloronaphthalene_
! 2-Nitroani1ine
;Dimethylphthalate_2,6 -Dinijtrotoluene
'■ Acenaphthylene______! 3-Nitroajnil me_
1 A.cenaphthene___
2,4 -Dinijtropnenol
4 -Nitrop'henoi_____
! 2 , 4 -Dmi|trotoluene
; Dibenzofuran
! Diethylp'hthalate_____________
| 4 -Chloropheny1 - phenylether i Fluorenel
i 4 - Nit roam line. i
6-Dinitro-2-methvlohenol
page 1 of 2
|RRF80.000| 1 1 1 1
RRF OR | OR | MIN %D OR 1 MAX %D OR|CURV|
AMOUNT |AMOUNT |
1 |RRF
j%DRIFT
1
%DRIFT jTYPE
1 I
1.4530000|1.4288473|----- i0.01 I
-------- 1-1.66 1 2 0.0 0|AVRG|
0.9870000 I 0.9319326 j0.01 -5.58 50.00 AVRG]
1.3440000|1.2835053| 0.01 1 -4 . 50| 5 0.0 0|AVRG j
1.5440000|1.4632976 | 0.01 j -5.23 j 50.00|AVRG|
1.5580000|1.4927116| 0.01 -4.192 0.00 AVRG j
1.5340000 1.4513183 j 0.01 1 -5.39| 50.00|AVRG|
1.1720000|1.1246352 | 0.01 j -4.04 j 5 0.0 0 jAVRG|
1.8230000|1.7604245| 0.01 -3.435 0.00 AVRG j
1.2740000 1.2347748 j 0 . 01 1 -3.08 | 5 0.0 0|AVRG
0.8030000|0.7450387 0.05 1 -7.22 j 50.00 j AVRG
0.8060000|0.7630464 | 0.01 1 -5.33 | 5 0.0 0|AVRG|
0.3400000 0.3503588 | 0.01 3.05 | 5 0.0 0 j AVRG
0.6730000|0.6693175 0.01 1 -0.55 j 50.00]AVRG|0.2150000|0.2121352 j 0.01 1 -1.33
2 0.0 0|AVRG j
0.3200000 0.3120055| 0.01 1
1 to o 50.00 AVRG
0.4020000|0.4105081 0.01 j 2 . 12 1 50.00|AVRG|
0.3310000 0.3376091 0.01 2.00 20.00 AVRG0.3860000 0.3810025 | 0.01 1 -1.29 50.00 AVRG|
1.4460000|1.4735112 0.01 1 1.90 | 50.00|AVRG|
0.4620000|0.4780432 I 0.01 1 3 . 47 j 5 0.0 0|AVRG j
0.2660000|0.2634745 | 0.01 1 -0 . 95 | 2 0.0 0|AVRG|0.3680000 0.3647257 j
0.01 -0.89| 20.00 AVRG0.7240000|0.7112745 0.01 -1 . 76 | 50.00 AVRG0.3960000|0.3675725 | 0.05 1 -7 . 18| 50.00|AVRG|
0.4070000 0.4156495 | 0.01 2.12 | 20.00|AVRG|
0.4320000 | 0.4243734 | 0.01 ■ -1.76 50.00)AVRG]
1.0260000 j1.0308065 j 0 . 01 1 0.47 | 50.00|AVRG|
0.3670000 0 . 3725542 0.01 1 1 . 51 | 50.00 AVRG1.2540000 1.2582962 1 0.01 0.34 50.00 AVRG0.345000010.3419095| 0 . 01 1 - 0.90| 5 0.0 0|AVRG)
2.4090000 2.3558S10 0.01 1 -2.20 50.00 AVRG0.3650000|0.3619142 0.01 -0.84 50.00 AVRG1.5590000|1.5356203 | 0 . 01 1 -1 . 50| 2 0.0 0|AVRG|
0.061000010.0600705 0.05 -1.525 0.0 0 jAVRG
0.2170000|0.2001577 0.05 -7.76 50.00 AVRG0.5000000|0.5006206 | 0.01 1
0.12 j50.00|AVRG|
1.6140000|1.5783827 j 0 . 01 1 -2 . 21 | 50.00|AVRG
1.4840000|1.4485386 | 0.01 -2.39 50.00)AVRG
0.6930000|0.6786956 J 0.01 j -2.06 50.00 AVRG[
1.8520000|1.8147222 | 0 . 01 1 -2.01 5 0.0 0|AVRG|
0.33000000.3698028 0.01 to CTi
CO 50.00 AVRG|
0. 16 20000i0.1618847 j
i 1
0 . 01 11
-0.07|
1
50.00 AVRG|1 1
FORM VII SV
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Name: COMPUCHEM Contract: 8270C
I Lab Code: LIBRTY Case No.: SAS No.: SDG No.: QE1877
Instrument ID: 5972HP64 Calibration Date: 03/11/02 Time: 2253I
Lab File ID: HG020311B64 Init. Calib. Date(s): 03/10/02 03/10/02
Init. Calib. Times: 1416 1723
GC Column: RTX-5 ID: 0.32 (mm)
1 | |RRF8 0.0 0 0| 1 1 1 1
| COMPOUND |RRF OR OR MIN | %D OR MAX %D OR|CURV|
1
|AMOUNT AMOUNT
1 1 1
RRF |
1%DRIFT
1
%DRIFT |TYPE|
| i
|N-Nitrosodiphenylamine | 0.4360000 I 0.4252453 |----- 10.01 I
-------- 1-2.471
----------- 1 — i2 0.0 0|AVRG|
1 4 -Bromophenyl-phenylether ] 0.2120000|0.2045793] 0.01 j -3.50] 50.00|AVRG|
|Hexachlorobenzene | 0.2610000 0.2538997| 0.01 -2.72[ 50.00 AVRGiPentachlorophenol 0.1740000|0.1662047 0.05 -4.48 | 20.00|AVRG
I Phenanthrene 1.4880000 1.4072421| 0.01 I -5.43 50.00|AVRG|
iAnthracene | 1 . 5130000|1.4303164| 0.01 j -5.46 | 50.00|AVRG j
Carbazol 0 I 0 . 9960000|1.0017379| 0.01 0.58 5 0.0 0|AVRG
I Di - n - butivlphthalate 1.4890000 1.4193083 0.01 1 -4.68| 5 0.0 0 j AVRG
!Fluoranthene 1 . 7160000 1.6799277| 0.01 1 -2.10| 20.00 j AVRG|
i Pyrene j 1 . 9180000|1.8215947 j 0.01 1 -5.03] 50.00]AVRG]
!Butvlben zvlphthalate jO.7700000 0.7258042 0.01-5.74 j 50.00|AVRG
!3,3'-Dichlorobenzidine 0 . 5420000 | 0.5545583| 0.012.32 j 50.00|AVRG
1 bis(2-ethvlhexvl)Phthalate | 1 . 1480000 j 1 . 1003856 j0.01 -4.15 50.00|AVRG|
hpnzo(a)Anthracene j 1 . 7590000 1.6720496 0.01 -4.945 0.00 AVRG j
PFhrysene j 1 . 6580000 | 1 . 5703507 0.01 1 -5.29 5 0.0 0|AVRG|
1Di-n-octylphthalate 2 . 2640000|2.1379883 | 0.01 j -5.56| 2 0.0 0|AVRG j
Benzo(b) fluoranthene2 . 1450000|1.7689854 j
0.01 -17.53| 50.00 AVRG|
!Benzo(k) fluoranthenej1 . 9380000|2.3180102| 0.01 1 19.61j 50.00|AVRG|
! Benzo (a) pvrene j1.7000000 1.6622862 0.01 -2.22 | 20.00|AVRG|
!Indeno(1 , 2,3 -cd)pyrene | 1 . 2280000|1.1811904| 0.01-3 . 81j 50.00|AVRG j
!Dibenzo( a,h)anthracene | 1 . 4900000 1.4441409| 0.01 -3.08 | 5 0.00 AVRG j
| Benzo i g, h, l)perylene | 1 . 5630000 j 1.5193161 0.01 -2 . 79| 50.00|AVRG|
i 2 - Fluorophenol 1 . 2980000 1 . 2760461 0.01 -1 . 69| 5 0.0 0 j AVRG
: Phenol -d 5 1 . 6910000 1.6267774 0 . 01 1 -3 . 80| 5 0.0 0|AVRG
Nitroben zene-d5 0.43300000.44585451 0.01 2.97 | 50.00 jAVRG
[•J
I—*
c 0 d biphenvl j1 . 3330000 1 . 3289473 | 0 . 01 1 - 0.3 0 j 5 0.0 0 j AVRG|
:2,4,6-Tr ibromophenol 0.4030000(0.3861743 0.01 j -4.18 50.00 AVRG|
1Terpheny 1 -dll 1 . 0590000|0.99011981 1 1
0.011
-6.501
50.00 AVRG
1 1
a o erORM VII SV
59b
Data Files /chemr,5972hp64. i /BF020311B64. b/HG020311B64. d
Date S ll-MAR-2002 22:53
Client IDS SSTD080 Instrument: 5972hp64.i >-
Sample Info: SSTD080S2319 CJ^
Volume Injected <uL>: 1.0 Operator; 2319 LO
Column phase: RTX-5 Column diameter: 0.32
Phenanthrene-dlO-
Data File: /chem/5972hp64.i/DF020311B64.b/HG0203UB64.d
Date t ll-MAR-2002 22:53
Client ID: SSTD080
Sample Info: SSTD080:2319
Volume Injected <uL>: 1.0
Column phase: RTX-5
Instrument; 5972hp64.i lO
cnOperator: 2319 LO
Column diameter: 0,32
Data File: /chem/5972hp64.i/DF020311B64.b/HG020311B64.dReport Date: ll-Mar-2030 23:20
Data file Lab Snip Id Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal DateAls bottle Dil Factor Integrator
CompuChem
Semivolatile Report SW-846 Method 8270C /chem/5972hp64.i/DF020311B64.b/HG020311B64.d SSTD080 Client Smp ID: SSTD080ll-MAR-2002 22:53 2319SSTD080:2319
Inst ID: 5972hp64.i
/chem/5972hp64 ll-Mar-2030 23 10-MAR-2 0 02 17 2
1.00000
HP RTE Target Version: 3.50Processing Host: einstein
i/DF020311B64 20 naegler 23
. b/8270Cv6.m Quant Type: ISTD Cal File: HL020310A64.d Continuing Calibration Sample
Compound Sublist: all.sub
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
DF 1.00000 Dilution Factor
Vt 1000.00000 Volume of final extract (uL)p
Vo 1000.00000 Volume of sample extracted (mL)
Vi 1.00000 Volume injected (uL)
Cpnd Var iable Local Compound Variable
AMOUNTS
QUANT SIG CAL-AMT Oh -COL
Compounds MASS RT EXP RT REL RT RESPONSE ( NG) ( NG)
{1,4-DicHlorcbenzene -d4 152 S . 264 8.264 (1.000) 123003 40.0000
-Naphtha l'er.e - cl S 136 10.158 10.158 (1.000) 450795 40.0000
• T Acenaphi her.e-dlC' 164 13 167 13.167 (1.000) 321474 40.0000
*T Phenanzhrene -d 1 0 188 15.483 15 ‘1 3 3 (1 .000) 666326 40.0000
Chrvser.e -d)2 240 19.963 : 9 . 56 3 !I .000) 642652 40.0000
* 6 Perviene'
- d 1 2 264 22.445 2 2.44 9 i1 .0 0 0) 350874 40.0000
7 2 ■ r \uorocrteno1 j-
112 6.456 6.455 (0.781) 313915 80 - 0000 78 62
C - Pheno!•d5 99 7.757 7.757 (0.939) 400197 80.0000 76 95
N:2 rober z e r. o - a 5 82 5.105 6 . 10 9 (0.697) 401978 80.0000 82.39
. 0 2 -F1uorofc•ohenv1i
17 2 11 . 8 S 2 1!.582 (0.902) 854444 80.0000 79.78
: : i lbr omophenc 3 30 14 .466 1 4 .4 69 i 1 .099) 248290 80.0000 76.71
c ; 2 : erpher.\ 2 - d: 4 244 1 7 . S 6 7 17.567 (0.695) 1272605 80.0000 74 . 00
'■ : N - N11 rosco i met nv larrl
ine 42 4.542 4.342 (0.525) 116554 80.0000 79 . 39
‘.4 ?yv \ d : r.f 7 c. 4 2 2 F 4.325 : C.5 2 3) 203742 80.0000 80.05
SIMILARITY
(M) |
8711
9454
frO
59 S Mo>-
Data File: /chem/5972hp64.i/DF020311B64.b/HG020311B64.dReport Date: ll-Mar-2030 23:20
Compounds
15
16
17
10
19
20
21
22
2 3
24
25
26
27
26
29
30
3 1
7
33
34
39
4 0
43
44
45
4 6
4 7
4 5
49
Benzaldehyde
Phenol |
Bis (2-ch'loroet hyl)ether
2-ChlorophenolI
1, 3 -Dich'lorobenzeneI
1,4 -Dich'lorobenzeneI
Benzyl alcoholI
1,2 -Dichlorobenzene
2- Methylphenoli
2,2'-oxybis{1-Chloropropane)
Acetophenone
3- Methylphenol
4- Methylphenol
N-Nitroso-di-N-propylamine
Hexachioroethane
Nitrobenzene
1 sophorone
2-Nitrophenol
2.4- Dimethylphenol
Bis (2 -chloroethoxv)methaneI
2.4- Dichlorophenol
1.2.4- Trichlorobenzene
Naphthalene
4 -Chloroaniline
HexachlorobutadieneI
Caprolactam
4 - Ch 1 c ro J- 3 - met hy 1 pheno 1
2-Methyl naphthalene
1-Methvinaphthaiene‘ I
Hexachlorocyclopentad:ene
2.4.5- Tnchlo rooheno 1
2,4,5-TrichloroohenolI
- , 1 ' - B i pher.y 1
2 -Ch1oronaphtha 1ene
2 - N i t roar, i 1 i nei
D i me t h y 1 p n t ha 1 a t et
2,6 - D i n : t r c t o 1 u e n e!
Acenaphthylene
3 - Ni t ro-'.n L1 : r.cI
Acenauhthene■ i
2 . 4 - P j n 11 rophe r.o 1
4 -Nitropheno1
2 . 4 - Dm: tret o in ene Dibenzoilran
Diethyip h t na i at -
4 - Ch I oropher.y 1 - phenyl ether
Fluorene
AMOUNTS
QUANT SIG CAL-AMT ON-COL
MASS RT EXP RT REL RT RESPONSE ( NG) ( NG) SIMILARITY
77 7.639 7 .639 (0.924) 206263 80.0000 76.57 9764
94 7.774 7.774 (0.941) 351505 80.0000 78.65
93 7.909 7.909 (0.957) 229261 80.0000 75.50
128 8.010 8.010 (0.969) 315750 80.0000 76.40 8907
146 8.213 8.213 (0.994) 359980 80.0000 75.81
146 8 .281 8.281 (1.002) 367216 80.0000 76.64
108 8.467 8.467 (1.025) 185510 80.0000 76.15
146 8.568 8.568 (1.037) 357033 80.0000 75.70
108 8.636 8 . 636 (1.045) 276667 80.0000 76.77
45 8.670 8.670 (1.049) 433075 80.0000 77.23 9063
105 8 . 873 8 . 873 (1.074} 403904 80.0000 77.55 8639
108 8 . 839 8.839 (1.070) 303762 80.0000 77.54
108 8.839 8.839 (1.070) 303762 80.0000 77.54
70 8 . 873 8.873 (1.074 ) 183284 80.0000 74.24 0 (M)
117 9.008 9.008 (1.090) 187714 80.0000 75.70 9488
77 9.126 9.126 (0.898) 315880 80.0000 82.47 9707
82 9.448 9.448 (0.930) 603450 80.0000 79.57 9454
139 9.600 9.600 (0.945) 191259 80.0000 79.10 8394
122 9.600 9.600 (0.945) 281301 80.0000 70.05 7495
93 9.752 9.752 (0.960) 370110 80.0000 81.76 9538
162 9 . 938 9 . 938 (0.978) 304385 80.0000 81.54
180 10.073 10.073 (0.992) 343508 80.0000 78.92
128 10.175 10.175 (1.002) 1328503 80.0000 81.54 9764
127 10.259 10.259 (1.010) 430999 80.0000 82.72 8206
225 10.428 10.428 (1.027) 237546 80.0000 79.24 8793
113 10.732 10 . 732 (1.057) 107053 80.0000 83.83 9501
107 10.935 10.935 (1.077) 328833 80.0000 79.29 9776
142 11 .223 11.223 (1.105) 641270 80.0000 78.53
142 11.409 11.409 (1.123) 617137 80.0000 79.20
237 11 . 595 11.595 (0.881) 236330 80.0000 74.22 8926
196 11 . 747 11 . 747 (0.892) 267241 80.0000 81.68
196 11 . 831 11.831 (0.899) 272850 80.0000 78.61
154 12.066 12.068 (0.917} 768624 80.0000 79.82 7592
162 12.119 12.115 (0.920) 662755 80.0000 80.36
65 12.355 12.355 (0.938) 239533 80.0000 31.13 9292
163 12.677 12.677 (0.963) 809019 80.0000 80.28 9463
165 12.346 12.346 (0.976) 219830 80.0000 79.27 8272
152 12.396 ' o q £ (0 . 979) 1514709 80.0000 78 . 24 9610
133 1 3 . 0 8 2 13 . 082 \0 . 994) 232692 800.000 92.97 9421
154 15.213 13.218 (1 .004) 987324 80.0000 70.80 9654
184 13.268 13 .268 f'l. 008 )193111 400.000 393.7
109 13.319 13.319 (1.012) 128691 00.0000 73.71 8006
165 13.522 1 3 5 2 2 (1.027) 321873 80.0000 80.08 8199
163 13.43? 13.458 (1.024 ) 1014818 80.0000 78 .23 9023
14 5 13.860 1 3 . 650 (1.053) 931335 80.0000 78.09 9710
2 04 1 4 . C 1 2 14.?12 (1.064) 436366 30.0000 78.31 0 (M)
18 6 14.045 14.046 (1.067) 1166772 00.0000 78.38 7662
ft)
60U
b. Continuing Calibration Data (Form VII SV)
If more than one instrument is used, forms shall be arranged in order by instrument. If multiple continuing calibrations from the same instrument are used, they shall be in chronological order.
(1) Reconstructed Ion Chromatograms and quantitationreports for all continuing (12-hour) calibrations; Spectra not required
(2) EICPs displaying each manual integration
551
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Name: COMPUCHEM Contract: 8270CLab CcJde : LIBRTY Case No.: SAS No.: SDG No.: QE1877
Instrument ID: 5972HP60 Calibration Date: 03/12/02 Time: 1017
Init. Calib. Date(s): 03/03/02 03/03/02
Init. Calib. Times: 1401 1720
GC Column: J&W DB-5.625 ID: 0.32 (mm)
Lab Fi le ID: HG020312A60
I
COMPOUND
Phenol |
I Eis(2 -chloroethvl)ether
| 2 -Chlorophenol_______| 1, 3 -Dichl!orobenzene_
j1,4-Dichiorobenzene_
j 1,2-Dichiorobenzene_
|2-Methvlphenol_______
12,2'-oxybis(1 -Chloropropane)
; 4-Methvlphenol________________
j U-Nitroso-di-N-propylamine_
jHexachlonoethane
Nitrobenzen
sophorone____
Mitrophenol_
, _ , 4-Dimethylphenol___________! B i s ( 2 - chlloroe t hoxy} me t hane
i 2 , 4 -Dichilorophenol___________
; 1 , 2 . 4 -Trilchlorobenzene
| Naphthalene
: -Chloroanilme I
l Hexachloi'obutadiene_____
i 4 -Chloro-j3 -methvlphenol
2-Methylnaphthalene_____
Hexachlorocyclopentadiene 2 , 4 , 6 - Tr ilchlorophenol
5-TrJchioroDhenoi
2 - Chloronaphchalent
2 - N11 roa ni1ine_____
Dimethylphthalate_
2,2'Dmitrotoluene
Acenaphthylene_____
2 - Nit roan i 1 me
Acenaphthene_______2 , 4 -Dmidrophenol
4 -Nit rophenoI_____
: - umi drotol uene I
Dibenzofuran
D i e c h yl p h t h a 1 a t e_____________
4 -Chiorophenyl -phenyiet’ner Fluorenej
. - Ni t roan 11 me; -Dinidro- 2 - me thvlphenol
I _ _ ;iage 1 o
1 |RRF80.000| 1 1
|RRF OR 1 OR | MIN | %D OR 1 MAX %D OR
AMOUNT AMOUNT | RRF %DRIFT | %DRIFT|
| 1 . 3820000 | 1 . 20082220.01 j -13.11j
20.00
0 . 9520000jo. 9599782
0.01 0.84 50.00|1.0880000 1.1040369| 0.01 1.47 50.00| 1.4910000 j1.5304621j 0.01 j 2.65 j
50.00
1.4860000j 1.6051513| 0.01 j
8.02 20.00
1.4310000 1.4978057| 0.01 4.67 50.00i 0.8830000 | 0.8964040 j 0.01 1 1.52 | 50.00| 1.3580000 j1.3558819 j 0.01 j -0.16 j
50.00
1.1220000| 1.0598048 j 0.01 1 -5 . 54 | 50.00
| 0.8140000 | 0 . 7984051 0.05 1 -1.92 | 50.00| 0.6340000 j 0.7273466 0.01 j
14.72 50.00
0.4960000 0.4643285) 0.01 -6.38 50.00j0.7810000 j 0.7513808| 0.01 j -3 . 79 j
50.00|0.24 50000 0.2498400 j
0.01 1.98 20.00
0.29700000.2919625 j
0.01 -1.70] 50.00
0.4700000 0.4839004 0.01 2.96 50.00
0.4380000 | 0.4323532 0.01 1 -1 . 29| 20.00
0.5200000 0.51612320.01 j -0.74 | 50.00
] 1 . 1890000j 1 . 2196058 j
0.01 2.57 50.00jO.5010000 0.4843112 0.01 -3.33 50.00j 0.4060000 | 0.4212530 j 0.01 j 3 . 76 j
20.00|0.3640000 j 0 . 3220704 j 0.01 1 -11 . 52 | 20.00
0.8860000 0.9245955j 0.01 4.36 50.00|0.4600000 0.4811605 0.05 1 4.60 50.00
0.4400000 0.40386580.01 j -8 . 21| 20.00
0.47900000.4606443j 0.01 j
-3.83 50.00|1.2400000 |1.2204970) 0.01 -1 . 57 j 50.00
0.4830000| 0.4824943 j 0 . 01 1 -0.10 50.00
1.6290000 ! 1. 518 3 174 ) 0.01 j-6.79 50.00
|0.3470000 10.3333067) 0.01 j -3.95) 50.00j1.9950000 | 1 . 8703951 o. oi j -6.24 50.00j0 . 3690000 10.3375703 0.01 -8.52 50.00
1.1730000 1.0784801 ] 0.01 -8.06 20.00
0.2170000 jO.1883675 0 . 05 j- 13 . 19| 50.00
| 0 . 2960000 |0.2992935 | 0 . 05 1 1 . 11 | 50 . 00jo.5140000
0.5124825 0.01 -0.30 50.00
2.1810000 12.1805926 0.01 - 0.02 j . 50.00j1.7600000 j1 . 6800357 j
0.01 -4.54 50.0010.9600000 | 0 . 3236261|
0 . 01 j -3 . 27 j50 . 00
j 1 . 7420000| 1 .7378112 i
0.01 1 -0.24 50.00! 0.3720000 j 0.360 594 5 j 0.01 -3 . 06| 50.00
10.1660000 )0.1500552 j 0.01) - 9.6 0 j50.00
CURV
TYPE
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVRG
AVP.G
AVRG
55,FORM VII SV
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Nabe: COMPUCHEM Contract: 8270CLab Cojde : LIBRTY Case No.: SAS No.: SDG No.: QE1877
Instrument ID: 5972HP60 Calibration Date: 03/12/02 Time: 1017
Lab File ID: HG020312A60 Init. Calib. Date(s): 03/03/02 03/03/02
Init. Calib. Times: 1401 1720
GC Column: J&W DB-5.625 ID: 0.32 (mm)
I COMPOUND
N-Nitrosodiphenylamine____
4-Bromophenyl-phenylether_
Hexachlorobenzene
Pentachlgrophenol
Phenanthrene______
Anthracene_________
Carbazole
Di-n-butvlphthalateFluorantLene__________Pvrene I
Butylbenzylphthalate___
3,3'-Dichlorobenzidine
is (2 - ethylhexyl)Phthalate
enzo (a)anthracene___________
hrvsene
|Di-n-octylphthalate____
| Benzo(b)fluoranthene___
! Benzo(k)fluoranthene___
| Benzo(a)pyrene___________; Indeno(1J2,3 -cd)pyrene
1Dibenzo(a,h!anthracene_
i Benzo(g,h,l)perylene___
2 -Fluorophenol_
Phenol - d5
|Nitrobenzene-d5_______
I 2 -Fluorobiphenyl
| 2,4,6 -Tribromophenol
: Terohenvl-dl4
|RRF80.000| 1 1 !
RRF OR | OR | MIN | %D OR 1 MAX %D OR|CURV
AMOUNT AMOUNT |
| iRRF %DRIFT
1%DRIFT TYPE
1 10.5330000|0.4895377|
------10.01 I
-------- 1-8.151
----------- 1 —20.00|AVRG
0.3000000 I 0.2626789| 0.01 1 - 12.441 50.00|AVRG
0.3410000 0.3108058| 0.01 1 -8.855 0.0 0 j AVRG
0.1000000|0.1101310 0.05 j 10.13 | 2 0.0 0|AVRG
1.2540000 1.2258290] 0.01 -2.255 0.0 0 j AVRG
1.2630000|1.2439978 | 0.01 1 -1.50| 50.00|AVRG
0.9800000 0.9122507 0.01 1 -6 . 91| 5 0.0 0|AVRG
1.6380000|1.5921469| 0.01- 2.8 0 j 50.00|AVRG
1.4490000|1.4257731 | 0.01 1 -1.60| 2 0.0 0 j AVRG
1.4350000|1.3502826 | 0.01 1 -5.90 | 50.00|AVRG
0.7410000|0.6995314 | 0.01 1 -5.60| 50.00|AVRG0.5660000 j 0.5708737 0.01 1 0.86 j 5 0.0 0 j AVRG
1.0350000 1.1977421 | 0.01 15.72 50.00|AVRG
1.4320000|1.6669665 | 0.01 1 16.41| 50.00 jAVRG
1.2900000|1.2586506 0.01 -2 . 43 | 5 0.0 0 j AVRG
2.0140000 2.3464786 | 0.01 1 16.51j 2 0.0 0 jAVRG
1.7250000 1.7012509| 0.01 j-1.38 50.00 AVRG
1.5600000 2.0517998 0.01 31.52| 50.00|AVRG
1.3800000|1.5755806 | 0.01 1 14.172 0.0 0 jAVRG
1.4730000 1.7135069 j 0.01 j16.33 50.00 AVRG
1.2820000 | 1. 5240366 j 0.01 j18.88 | 50.00 jAVRG
1.2410000] 1 . 4501195| 0.01 1 16 . 85 j 50.00 jAVRG
1 . 2730000 1.0698895j0.01 1
-15.96 j 50.00 jAVRG
1.4360000|l.34122051 0.01 i-6.60 | 5 0.0 0 j AVRG
0 . 5720000 | 0.5583955i 0.01 j -2.38 | 50.00|AVRG1.5550000|1.44 80327 j 0.01 1 - 6 . 8 8 j 5 0.0 0|AVRG
0.3760000 0.3336466 0.01 -11.26 50.00 AVRG1.110 0 0 0 0 | 1 .0273398! 0.01 1 -7.45! 50.00 IAVRG
page 2 o f 2FORM VII SV
b5 j
Data Filet /chem/5972hp60.i,'DF020312A60.b,'HG020312A60.d
Date t 12-MAR-2002 10:17
Client ID: SSTD080 Instrument: 5972hp60.i ‘ J"
Sample Info: SSTD080J917 LO
Volume Injected <uL); 1.0 Operator: 917 LO
Column phase: J&W DE-5.825 Column diameter: 0,32
-Ph.sn.ar> fchr • ■=■ r. a
j
Sample Info: SSTD0801917
Volume Injected <uL>: 1.0 Operator: 917
Column phase: J8.W DB-5.625 Column diameter: 0.32
Data File: /chem/5972hp60.i/DF020312A60.b/HG020312A60.d
Date : 12-MAR-2002 10;17
Client ID: SSTD080 Instrument: 5972hp60.i
.5
5b
Data File: /chem/5972hp60.i/DF020312A60.b/HG020312A60.dReport Date: 12-Mar-2030 10:50
CompuChem
Data fi Lab Smp jId Inj Date Operator Smp Info Misc Info Comment{ MethodMeth DateCalAls
Date bottlle
Dil Facdor Integrator
Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020312A60.b/HG020312A60.d SSTD080 Client Smp ID: SSTD08012-MAR-2 002 10:17917 Inst ID: 5972hp60.iSSTD080:917
/chem/5 9 72hp6 0.i/DF020312A60.b/8270Cv6.m12-Mar-2030 10:50 mikhael Quant Type: ISTD03-MAR-2002 17:20 Cal File: HL020303A60.d2 Continuing Calibration Sample1.00000
HP RTE Compound Sublist: all.subTarget Version: 3.50Processing Host: einstein
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
DFVtVoVi
1.00000
1000.00000
1000.00000
1.00000
Dilution Factor Volume of final extract (uL) Volume of sample extracted (mL) Volume injected (uL)
Cpnd Variable Local Compound Variable
AMOUNTS
CUANT SIG CAL-AMT ON-COL
Conpcur.ds MASS RT EXP RT REL RT RESPONSE ! NG) ( NG) SIMILARITY
* 1 1 , 4 - D i c r lot ober.zene • d4 152 6 . 123 9.123 (j.000) 100945 40.0000
• 7 Naohc ha! e n e - d 6 13 5 10.238 10.288 (1.000) 296932 40.0000
3 Acenaphcr
her.o • d 1 C 164 13.351 13.351 (1.000) 244221 40.0000
4 P h <° p. a n z r r e n e - d 1 C 18 8 15.973 15.973 (1.000) 476283 40.0000
• Chrysene - a; 24 G 20.608 20 60S (1.000) 517505 40.0000
• 'Je rv i ene -dll 2 64 23.163 23.163 (1.000) 375407 40.0000
: 7 - . 112 6 . 003 6 008 (0.740) 216000 80.0000 67.24
r 3 Phene 1 - d'5 59 7 . 565 7.565 (0.931; 270779 80.0000 74 . 70
3 9 Nilroben z e n »"■ • b 62 5 . 0 5 3 ? . 353 '0.880' 331611 80.0000 78.11
1C e.pner.y. 172 12.166 12. 146 (0.911) 707280 80.0000 74 .49
; ; ; - -“ ■ ‘ 1 r 3 3 G 14.755 14 . 755 (1.105) 162967 80.0000 70.92 (M)
: -.2 Terpheny . .. .--a-- 244 i 3 . 7 S 1 13.751 (0.911) 1063307 80.0000 74 . 03
^ 7 u... _ 42 3.365 3 . 3 6 9 (0.415) 346238 80.0000 91 . 99 8710
14 Pyridine 7 :■ 3.403 i' .403 (0.419) 691561 80.0000 132.3 9175
Data Fi e:
Report Date
/chem/5 972hp6 0.i/DF02 0312A60.b/HG02 0 312A6 0 . d : 12-Mar-2030 10:50
Compounds
15
16
17
18
19
20
21
2 2
23
24
25
26
2128
29
30
31
32
33
34
35
3 6
39
4 u
4 1
42
4 3
4 4
9enzaldehyde Phenol|
Bis (2-chloroethyl)ether
2-Chlorophenol
1.3- Dichlorobenzene
1.4- Dichlorobenzene Benzyl|alcohol
1,2-Dichlorobenzene
2-Methylphenol
2,2'-oxybis (1-Chloropropane)
Acetophenone
3 -Meth^lpneno 1
4 - Met h\jlphenol
N-Nit roso-di-N-propylamine Hexachlbroethane
Nitrobenzene
Isophor.one
2-Nitrophenol
2.4- Dimethylphenol
Bis(2-chloroethoxy)methane
2.4- Dichlorophenol
1.2.4- TrichlorobenzeneI
Naphtha 1ene
4 -Chloroani i me
Hexachlorobutadiene
Caprolactam
4 -Chloro - 3-methylphenol
2-Methylnaphthalene
1 -Methyinaphtha 1ene
Hexachlorccyc 1 oper.t arii ene
2,4,5 -Trichicroohenol
46 2,4,S-Trichiorophenol
47 1.1'-B:pheny1
48 2 -Chloronaphtha 1ene
4 9 2 - Ni t roar, .line
r-C Dimethv l'ont r.a late
52 Acenapht-ny1ene
53 3 - Nit roar.: : : ne
54 Acer.apht her.e
55 .4 - Din: t ropheno1
5 6 4 -Nitrophenoi
5 5 Dibenzcr’jran
59 Dietr.y Lpht ha 1 at e
6 0 4 -Ch1oropheny1 -pheny1et he r
6 1 F *. u o r e n e
AMOUNTS
QUANT SIG
MASS RT EX? RT REL RT RESPONSE
CAL-AMT
t NG)
ON-COL
( NG)
77 7 .396 7 . 396 (0.910) 115126 80.0000 71 .45
94 7.599 7.599 (0.935) 242434 80.0000 69.48
93 7.700 7.700 (0.948) 19381G 80.0000 00.71
128 7 . 785 7.785 (0.958) 222894 80.0000 81.20
146 6.021 8 . 021 (0.988) 308985 80.0000 82.09
146 8.157 B . 157 (1.004) 324064 80.0000 86.41
108 8.377 8 . 377 (1.031) 131809 80.0000 74 . 75
146 8.411 8.411 (1.035) 302392 80.0000 83.76
108 8.580 8 . 530 (1.056) 180975 80.0000 81.23
45 8 . 597 8.597 (1.058) 273739 80.0000 79.86
105 8 . 800 8 . 800 (1.083) 321662 80.0000 80.44
108 S 8.834 -" 8 . 834 (1.087) 213964 80.0000 . 75.57
108/ 8 . 834x 8.834 (1.087) 213964 80.0000 75.57
70 8 . 817 8.817 (1.085) 161190 80.0000 78.44
117 8 . 969 8 . 969 (1.104) 146844 80.0000 91.76
77 9 087 9.087 (0.883) 275748 80.0000 74.87
82 9.493 ✓ 9.493 (0.923) 446218 80.0000 76.94
139 9.629 9.629 (0.936) 148371 80.0000 81.59
122 9 730 9.730 (0.946) 173386 80.0000 78.58
93 9 882 9 . 392 (0.951) 287371 80.0000 82.30
162 10.069 10.069 (0.979) 256759 80.0000 79.02
130 10.187 10.187 (0.990) 306507 80.0000 79.45
128 10 . 322 10.322 (1.003) 724280 80.0000 82.07
127 1C.424 10.424 (1.013) 287615 80.0000 77.32
225 10.542 10.542 (1.025) 250167 80.0000 82.91
113 11.016 11.016 (1.071) 56348 80.0000 87.62
107 11 . 287 11.287 (1 . 097) 191266 80.0000 70.81
142' 11.523 11.523 (1.120) 549084 80.0000 83.47
14 2 11 . 693 11.593 (1.136) 449345 8 C.0000 84 . 51
237 11.794 11.794 (0.883) 235019 80.0000 83.72
195 12.031 12.031 (C.901) 197265 80.0000 73.37
196 12.116 12.116 (0.907) 224998 80.0000 76.87
1 54 12 . 352 12 3 c. 7 (0.925! 687495 80.0000 77.64
162 12 . 386 12.3-0 10.928) 596142 80.0000 78 .71
65 12.5^2 .2 5 n f 0 94 2' 471341 160.000 159.8
16 3 12.694 .2.694 i G . 9 6 6 1 741610 80.0000 74 . 55
16 5 12 9 ° 5 . 2 . v ? 5 ,2.973; 162801 80.0000 76 . 77
152 13.114 ■’ :: -i '0 ‘iiZ) 913580 80.0000 75 . 00
13 8 : 3.3 o ■: : 0.c 96) 329767 160 . 000 14 6.5
154 1 -i 4 • - 5 ^ -. C 1.005) 526775 90.0000 73.53
1 84 13 .486 ? . 4 36 i. o i o; 460033 400.000 346 . 9
109 u . o z , 292375 160.000 161.6
165 :: 3 . 7 06 1 .027) 250318 80.0000 79.70
168 13.723 -.723 1 .028i 1065093 80.0000 79.99
14? 14.12'.- 4.129 1.058' 820600 80.0000 76.36
204 ^ 4 . 3 1 6 1 .072: 453580 80.0000 77 . 35
1 6 6 ✓ ^.315/ 4.315 1.072) 848820 80.0000 79.83
SIMILARITY
8667
8893
7957
8233
7256
8949
9080
9068
8615
8607
8686
8940
8894
9286
8717 <M)
8726
8605
8524
9183
9285
9474
9589
9427
9173
8200
8497
9514
9462
726 1
7739
• 55 /'
Data FiLe: /chem/5972hp60.i/DF020312AGO.b/HG020312A60.d
Report Date: 12-Mar-2030 10:50
AMOUNTS
QUANT SIG CAL-AMT ON-COL
Compounds j MASS RT EXP RT REL RT RESPONSE ( NG) ( NG)
6 2 4-Nitroaniline 138 14.383 14 .333 (1.077) 352259 160.000 155.3
63 4 , 6 - Dir.it ro- 2 -me thy 1 phenol 198 14 .433 14.433 (0.904) 285875 160 000 145.0
64 N-Nitresodiphenylamine 16 9 14 . S35 14 535 (0.910) 466317 60.0000' 73.47
65 1,2 - Diphenylhydrazine 77 14.602 14 .602 (1.094) 893482 80.0000 83.43
6 6 4 -Bromophenyl•phenylether 248 15.178 15.178 (0.950) 250219 80.0000 69.96
67 Hexach1orobenzene 284 15.296 15.296 (0.958) 296063 80.0000 72.88
68 Atrazine 200 . 15.465 15.465 (0.968 ) 17940 80.0000 19.68
69 Pentachlorophenol 266 15.651 15 651 (0.980) 209814 160.000 176.5
7 0 Phenanthrene 178 16.024 16.024 (1.003) 1167683 80.0000 78.17
71 Anthracene 178 16.108 16.108 (1.008) 1184990 80.0000 78.80
72 Carbazoie 167 16.396 16.396 (.1.026) 868979 80.0000 74 . 50
7 3 Di-n-butylphthalate 149 16.988 16.988 (1.064 ) 1516625 80.0000 77.74
74 Fluoranthene 202 18.121 18.121 (1.135) 1358143 80.0000 78.69
75_ . 1Benziame 184 13 . 341 18.341 (0.890) 208629 160.000 61.34
76Pyrene J
202 18.510 18 . 510 (0.898) 1397556 80.0000 75.28
77 Buty1 benzylphtha late 14 9 19.610 19.610 (0.952) 724022 80.0000 75.52
73 3, 3' - Dichlorobenzidine 252 20.541 20.541 (0.997) 590860 80.0000 80.71
7 9 bis (2 - ethylhexyl ) Phthalate 149 20.574 20.574 (0.998) 1239675 80.0000 92.58
? 0Ber.zo la Jar.thracer.e
■ 223 20.591 20.591 (0.999) 1725327 80.0000 93 . 15
8 1 Chrysenej 228 20.642 20.642 (1.002) 1302716 80.0000 78.04
82 Di-n-octylphthaiate 149 21 . 556 ' 21.556 (0.931) 1761769 80.0000 93 . 19
Benzo I b; v luorant her.a 252 22.368 22 .368 (0.966) 1277323 80.0000 78.90
W' Benzo (k) 51 uorar.t her.e 252 22 .413 22.418 (0.968) 1540520 80.0000 105.2
85 Benzo ia:pyrene 2 52 23.044 23.044 (0.995) 1182968 80.0000 91.30
36I ndeno (l|, 2 , 3 - cd) py rene
276 26.056 26.056 (1.125) 1286525 80.0000 93.05
7 D: benzo (a , h ; ant nr acer.e 278 26.107 26.107 (1.127) 1144268 80.0000 95.09
6? Benzo (a , r. : oc-rv 1 er.e 27 6 26.952 26.952 (1.164 ) 1088770 80.0000 93.45
QC Flag begend
M - Compound response manually integrated.
SIMILARITY
8150
9064
8577
9460
9312
9343
8571
8887
9047
9229
8561
9116
7095
9546
8729
8845
8014
55b
m
^^iS
Data File: /chem.'5972hp60.:/DF020312860.P/HG020312660.d Injection Dajte: 12-M8R-2Q02 10:1?
Instrument: 59?2hp60.i
lent Sample ID: S5TD080
pound: 2-,9 . b-Tr ibromophenoi ftS Mumper: 118-79-6
1.0-
0.9-
0.0-
0.7-
0 . b-
0.5-
Ion 329.60: Area: 162967 Height: 100792
is
0.4-;
ii
. 0.3-1 i
I
• 0.2- 1i1
1l
0.1-J I
\
14.3
)
14.4 19.5 14.6 14.7
Min
14.0 14.9 15.0 15.1 15.2
Ion 332.00: Area: 0 Height: 0
9.5- ;
9.0 •'
8.5-
8.0-
^ 7.5-
!
i\i i
il
6.5
6.0-
5.5
5.0- '
4 .5-
4.0- :
3.5-
2.0-
1.5-
1 .0-
0.5-:
r, m n-_14 .
I i
:5 14.'30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.05 14.90 14.95 15.00 15.05 15.10 15.15 15.20________ 1_____________________________________________________________________________Min_____________________________________________________________________
I Ion 141.00: ffrea: 0 Height: 0
1 . 4-
1 . 3-
1 .2-
1.1-
1.0-
j. 9-
). 8-
. b-
s-
/■ 5\5S
14.30 14.55 14.4-1 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.00 14.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20
i Min
Data File: /chem/5972hp60.1. Infection Date: 12-MAR-2002Instrument: 5972hp6u.i Client Sample ID: SSTD080
mpound: Caprolactam AS Number: 105-60-2
''DF020312h60 . b/HG020312A60. d
10:17
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Nalme :
Lab Code:
Instrument
COMPUCHEM
LIBRTY Case
ID: 5972HP60
Contract: 8270C
No.: SAS No.:
Calibration Date: 03/13/02
SDG No.: QE1877
Time: 1312
Lab File ID: HG020313A60 Init . Calib. Date (s) 03/03/02 03/03/02
l Init . Calib. Times: 1401 1720GC ColLmn: J&W DB-5.625 ID:
0.32 (mm)
COMPOUND
|Phenol 1_________
Bis (2 -chloroeth',I
| 2-Chlorophenol_
1)ether
3 - Dichlorobenzene_
4 -Dichlorobenzene_
,2 - Dichlorobenzene
-MethylphenolJ 2 , 2 ' -oxybis!1-Chloropropane)
I 4-Methvlphenol
|N'Nitroso-di-N-propylamine
! Hexachloroethane_____________
I Nitrobenzenel l----------------------Ksophororie______________________.
^■-Nitrophenol
I 2,4-Dimethylphenol___________| Bis ( 2 - chlloroethoxy) methane
| 2 , 4 - Di chllorophenol___________
I 1, 2 , 4 -Tri! chlorobenzene
|Naphthalene________________
! 4 - Ohio roam 1 me___________
i Hexachlorobutadiene_____j 4 - Chloro-j3 -methvlphenol
| 2-Methvlnaphthalene_____
! Hexachlci]ocyclopentadiene_ 1 2 , 4 , 6 - Tr ijchlorophenol _
2,4 5 - Tr iichlorophenol_
-Chloronaphthalene___
■ 2 - Ni t roani 1 me_____
' Dimethylphthalate_; 2 , 6 - Dim drotoluene_
i Acenaphthylene_____
: 3 -Hitroan.il me_____
: Acenaphtnene________! 2 , 4 - Dim tlrophenol_
■ i -Mitroph^enol
2,4-Dmic rotoiuene_
1 Dibenzofuran
Diethylph ! 4 - Chloropjh
;Fluorene
tnalate
;nvl-ohenvlether
-Hit roan1
6 - Dim t
Ll me
>-2 -methvlohenol
oaqe of 2
| |RRF80.000| I 1 1 1
RRF OR OR MIN | %D OR 1 MAX %D OR|CURV|AMOUNT jAMOUNT |
1 1 1
RRF |
|
%DRIFT 1
1
%DRIFT |TYPE|
1 |1 1 1 | 1.3820000 | 1.2278442 |
----- |0.01 |
-------- 1-11.151
----------- |----- j20.00|AVRG|
j 0 . 952000010.8673226| 0 . 01 I -8.89] 50.00|AVRG|j1.0880000 j1.1312333| 0.01 1 3 . 97 | 50.00|AVRG j
1.4910000 j1.5968505 0.01 1 7.10 j 5 0.0 0 jAVRG|
1 . 4860000 1 . 5874369 0.01 1 6.832 0.00 AVRG j
| 1.4310000|1.4962370| 0.01 1 4.56] 50.00]AVRG|
0.8830000| 0.9473773 [ 0.01 1 7.29 | 50.00|AVRG|
1.35800001.2232542 0.01 1 -9.92| 50.00 AVRGj1.1220000|1.0802883 | 0.01 1 - 3.72| 50.00jAVRG|
0.8140000 0.7091428 j 0.05 j -12 . 88| 50.00jAVRG|
| 0.6340000|0.7233980 0.01 14.10| 5 0.0 0 j AVRG
j0.4960000 j0.4463165 | 0.01 1 -10.02 | 5 0.0 0 j AVRG
|0.7810000|0.6969587| 0.01 1 -10.76 | 5 0.0 0 j AVRG j
|0.2450000 0.2454144 0.01 j 0.17 | 2 0.00 AVRG j
| 0.2970000|0.2887574 0.01 -2.7850.00|AVRGj
0.4700000 j0.4251300 |0.01 -9.55
5 0.0 0 j AVRG|
0.4380000 0.4618499 0.01 5.44 20.00|AVRG
0 . 5200000 0 . 5742556 0.01 10.43 50.00 AVRG1.1890000 j1.1563816 0.01 j -2.74 | 50.00 AVRG
i 0.5010000 j 0.4521012| 0.01] -9.76] 50.00]AVRG|
| 0.4060000 0.4734603| 0.0116.62 j 20.00 AVRG|
0.3640000|0.3475495 0.01 -4.52| 2 0.00 AVRG j
| 0.8860000|0.9501716| 0.01 1 7.24] 5 0.0 0 jAVRG]
[0.4600000 0.5344338 0.05 1 16.18 j 50.00 AVRG j
0 . 4400000 0.4514415 0.012 . 60 j 20.00|AVRG|
j 0.4790000 0.5203548 0.01 8.63] 50.00 AVRG1 . 2400000|1.1843315 j
0 . 01 I -4.49| 5 0.0 0|AVRG j
1 0 . 4830000 0.4375715 0.01) -9.40] 50.00]AVRG
i 1 . 6290000 j 1. 5470646 j 0.01 -5.03 50.00]AVRG
|0.3470000|0.3388357| 0.01] -2.35] 5 0.0 0 jAVRG|
| 1 . 9950000|1.9069708 j 0.01 1 -4 . 41 | 5 0.0 0|AVRG
! 0 . 3690000 0 . 3533331 0.01 -2.89 50.00 AVRGj 1 . 1730000 1 . 1826551
0.01 0.82 20.00 AVRGj0 . 2170000|0.1967293| 0.05] -9.34 j 5 0.0 0|AVRG|
| 0.2960000 | 0.3 196374| 0.05 7 . 98 | 5 0.0 0 AVRG! 0 . 5140000|0.5228070 0.01 1.71 50.00 AVRG1 2 . 1810000|2.2300703] 0.01] 2.25]
50.00 jAVRG|
1 . 7600000 jl.6732787 0.01 -4.93 50.00 AVRG0 . 9 50000010.9905059 j 0.01 3.18 5 0.0 0|AVRG
j 1 . 7420000 | 1 . 7087524 0.01 -1.91 50.00 AVRG|jo. 372000010.36156341
0 . 01 1 -2 . 80| 50.00|AVRG]
] 0. 1660000|0.1478998 j 0.01 1
1
-10.90]
1
5 0.00 AVRG j
1 !
FORM VII SV56.0
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Name: COMPUCHEM
Lab Code: LIBRTY Case
Instrument ID: 5972HP60
Lab File ID: HG020313A60
Contract: 8270C
No.: SAS NO.: SDG No.: QE1877
Calibration Date: 03/13/02 Time: 1312
Init. Calib. Date(s): 03/03/02 03/03/02
Init. Calib. Times: 1401 1720
GC Column: J&W DB-5.625 ID: 0.32 (mm)
COMPOUND
| N-Nitrosodiphenylamine____
|4-Bromophenyl-phenylether
IHexachlorobenzene
Pentachlorophenol_
Phenanthrene
j Anthracene_
ICarbazole] Di-n-but’j’lphthal
Fluoranthene_____Pvrene I
ate
|Butylbenzylphthalate
j 3 , 3 ' -Dicnlorobenzidine
is(2-etnvlhexvl)PhthalateI'nzo(a)anthracene_
bhrysenej_____________
!Di-n-octvlphthalate____
|Benzo(b)fluoranthene___
!Benzo(k)fluoranthene___
Benzo(a)pyrene___________j Indeno {1 ,j2 , 3 - cd) pyrene^
|Dibenzo(a,h)anthracene
;Benzo(g,h,llperylene _
1 2 - FI uoropjhenol
Phenol -d5'
Nitrobenzene-d5_______
2 -Fluorobiphenyl
2 , 4,6 -Tribromopheno1
Terohen'.’l - dl 4
|RRF8 0.000 | 1 1 1 1
RRF OR OR . J MIN | %D OR 1 MAX %D OR|CURV
AMOUNT J AMOUNT |
| |
RRF j
1
% DR. I FT I
1
%DRIFT |TYPE|
0.5330000|0.4765422j------10.01 1
-------- 1-10.591
----------- 1 — |2 0.0 0|AVRG|
0.3000000 0.2703204 0.01 1 -9.89| 5 0.0 0 j AVRG
0.3410000|0.3195736 | 0.01 1 -6.28| 5 0.0 0|AVRG j
0.1000000 0 .'1148339 0.05 i 14.83| 20.00|AVRG|
1 . 2540000 1 . 1483615| 0.01 -8.42 5 0.0 0|AVRG
1.2630000|1.1493896 0.01 1 -9.00 50.00|AVRG|
0.9800000|0.8954495| 0.01 1 -8.63| 5 0.0 0|AVRG|
1.6380000|1.4562558 0.01 1 -11.10 j50.00 AVRG
1 . 4490000 1.41781030.01 j -2.15| 20.00 j AVRG|
1.4350000|1.3974664 j 0.01 1 - 2.62 j 50.00|AVRG|
0.7410000 0.6656803 0.01 1 -10.16 50.00 AVRG0 . 5660000 j 0.5777214 j
0.01 2.07| 50.00 AVRG1.0350000 j 0.9965946 0.01 -3.71 50.00|AVRG|
1 . 4 320000|1.6085199| 0 . 01 1 12 . 33| 50.00 jAVRG|
1.2900000 1.2647011 0.01 -1.96 50.00 AVRG2 . 0140000 | 1 . 9020777 0.01 1 -5.56 20.00 AVRG1.7250000 | 1.6598364. 0.01 -3.78| 50.00|AVRG|
1.5600000 1.7624998 j 0.0112.98 j 5 0.0 0 j AVRG j
1 . 3800000 | 1 . 4738244 0.01 6.802 0.0 0 jAVRG
1.4730000 1.6969110 0.01 1 15.20| 50.00|AVRG|1.2820000 j1.4997111j
0.01 1 16.98| 50.00|AVRG|
1.2410000 | 1.4097750 0.01 13.6050.00 jAVRG
1.2730000|1.2161236 | 0.01 1 -4.475 0.0 0|AVRG j
1. 436 0 0 0 0 | 1 .3836152| 0.01 1 -3.65 | 50.00 AVRG|
0. 5720000 j 0. 5194193 0.01 -9.19 50.00 AVRG1 .5550000|1.5298129 j 0.01 -1.62| 50.00 AVRG0.3760000|0.44 50193 ! o. oi! 18.36 | 50.00|AVRG j
1 . 1100000i 1. 1057504 |
' i
0 . 01 1
11
-0.38
150.00 AVRG
1 1
of 2FORM VII SV
Data File: /chem/5972hp60.i/DF020313A60.b/'HG020313A60.d
Date : 13-MAR-2002 13:12
Client ID: SSTD080
Sample Info: SSTD080:917
Volume Injected <uL>: 1.0
Column phase: J&U DB-5.625
Instrument: 5972hp60, iCD
Operator: 917LO
Column diameter: 0,32
Data File: /chem/5972hp60.i/DF020313A60.b/HG020313A60.d
Date : 13-MAR-2002 13:12
Client ID; SSTD080 Instrument; 5972hp60.i
Sample Info: SSTD080:917
Volume Injected <uL); 1.0 Operator: 917
Column phase; J4.W DB-5,625 Column diameter: 0.32
-O
CD
LO
Data File: /chem/5972hp60.i/DF020313A60.b/HG020313A60.dReport Date: 13-Mar-2030 13:44
CompuChem
Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020313A60.b/HG020313A60.d SSTD080 Client Smp ID: SSTD08013-MAR-2 0 02 13:12917 Inst ID: 5972hp60.iSSTD080:917
Data file Lab Smp Id Inj Date |
Operator Smp Info Misc Info Comment !Method I
Meth Date Cal Date J
Als bottle Dil Factor Integrator Target Version: 3.50Processing Host: einstein
/chem/5972hp60.i/DF020313A60.b/8270Cv6.m13-Mar-2030 13:44 mikhael Quant Type: ISTD0 3-MAR-2002 17:20 Cal File: HL020303A60.d2 Continuing Calibration Sample1.00000
HP RTE Compound Sublist: all.sub
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
DFVtVoVi
1.00000
1000.00000
1000.00000
1.00000
Dilution Factor Volume of final extract (uL) Volume of sample extracted (mL) Volume injected (uL)
Cpnd Variable Local Compound Variable
AMOUNTS
QUANT SIG CAL-AMT ON-COL
ompounas MASS RT EXP RT REL RT RESPONSE ( NG) ( NG) SIMILARITY
1 1. 4 - 0 i c h crooenzer'.e - d4 152 8 153 0.153 (1.000) 83443 40.0000
2 NachLhrt i cP.-r - d i 136 10.301 10.301 (1.0C0) 243315 40.0000
164 13 . 360 13.380 (1.000) 208182 40.0000
1 59 16 00 3 16 00 7 467617
- 24 0 20.636 2 0.6 38 (1.000) 498466 40.0000
- • - 264 23.205 23.206 (1.000) 415406 40.0000
7 2 -cc roc he PC': 112 6.03- ■,0.741; 202954 80.0000 76.43
-■ Pher.cl-dB 9 9 ■7 594 " 5 94 i0.932 1 230906 80.0000 77.06
82 9.0 8 3-'' 5 . 0 b 3 (0.882) 252765 80.0000 72.66
2 - Fluorcb: oceny I 172 12.196 12. 156 (0.911) 636959 80.0000 78.70
brOTopneno1 330 1 4 764 14 .704 (1.105) 185290 80.0000 94.60 (M)
- d - 4 244 1 6 S i : iO.911; 1102358 80.0000 79.68
’2 1 'CiC, ; i 3 c. (0.417; 307934 80.0000 98 . 98 9668
- PvriQi-e 79 *> 4 3’ 3 4 73 (0.421) 309499 80.0000 71.61 9339
Data File: /chem/5972hp60.i/DF020313A60.b/HG020313A60.dReport Date: 13-Mar-2030 13:44
Compounds
15
16
17
1 o
1 i
2 0
21
23
24
25
2 6
27
26
2 9
3 0
31
32
•j i
34
35
36
2 9
40
4 3
4 5
4 1
4 fc
Benzaldehyde
Phenol jBis i 2 -chloroethy1)ether
2-Chlorophenol
1.3- DichlorobenzeneI
1.4- Dichlorobenzene
Benzyl alcoholI
1'. 2-DichlorobenzeneI
2- Methylphenol
2,2'-oxybis11 -Chloropropane)
Acet oohenone‘ I
3- Metnyipneno-
4- Methylphenol
N-Nitroso-di-N-propylamine
Hexachloroethane
Nitrobenzene
1sophorone
2-Nitrophenol
2.4- Dimethylphenol
Bis v2-cnloroethoxv)methanei
2.4- Diehl oropnenol
1.2.4 -Tr:chlorcbenzenei
Naphtha ler.e
4•Ch1oroani1ineu h,i .
HexachloroDutaaiene
Caprolactam
4 • Ch loro- ; • mecnv ; oh endI
2 -Methyin.apntnalene
1 - Methy1 naphtha!ene
Hexach. 1 orocyc open tad lene
2 , 4 , 6 - Tr ich 1 ot'ophenoi
2.4.5 -Trich1orophenoi
1.1'-Biphenvl1 ‘
2 - Cnioronaoh.tha 1 ene
D:met r. y 1 p n t n a 1 a t e
2,6 -u:nit roto1uene
■t-ir.io rocner. v i - one n: e t ne rr
AMOUNTS
QUANT SIG CAL-AMT ON-COL
MASS RT EXP RT REL RT RESPONSE ( NG) ( NG) SIMILARITY
77 7.425 7.425 (0.911) 100794 80.0000 75.67 8700
94 7.611 7.611 (0.934) 204910 80.0000 71.04
93 7 730 7.730 (0 . 948) 144744 80.0000 72.92
128 7.814 7.814 (0.958) 188787 80.0000 83.20 8973
146 8 051 8 . 051 (0.988) 266492 80.0000 85.65
146 8 187 8.187 (1.004 .' 264921 80.0000 85.45
108 8 390 8 . 39C (1 . 029) 105101 80.0000 72.10
146 8 .423 6.423 11.033) 249701 80.0000 83.68
108 / 8.610/ 8.610 (1.056) 158104 80.0000 85.85
4 5' 8.610/ 8 . 610 (1.056) 204144 80.0000 72.05 7097
105 6 829 8 . 829 (1.083) 263285 80.0000 79.65 7865
108 ■ '8 863 8 . 863 (1.087) 180285 80.0000 77.03
108' - 8.863 8 .863 (1.087) 180285 80.0000 77.03
7 0 8 829 - 8 . 829 (1.083) 118346 80.0000 69.67 0 (M)|
117 8 999 8.999 (1 . 104) 120725 80.0000 91.26 8972
77 9 117 9 . 117 (0.885) 217191 80.0000 71.97 8953
82 9 52 3, 9.523 (0.924) 339161 80.0000 71.37 8815
139 9 658 9.658 (0.938) 119426 80.0000 80.14 8783
122 9 760 9.760 (0.947) 140518 80.0000 77.71 8647
93 9.895 9.895 (0.961) 206881 80.0000 72.31 7742
162 10.081 10.081 (0.979) 224750 80.0000 84.41
180 10.217 10.217 (0.992) 279450 80.0000 88.40
128 10 352 10.352 (1.005) 562730 80.0000 77.82 8979
127 10.454 10.454 (1.015) 220006 80.0000 72.17 8792
226 10.572 10.572 (1.026) 230400 80.0000 93.19 9122
113 11.046 11.046 (1.072) 45814 80.0000 86.94 8555(M)^
107 11.316 11 . 316 (1 . 099) 169128 80.0000 76.41 8707
142 11 553 11.553 (1.122) 462382 80.0000 85.78
142 11 722 11.722 (1.138) 371059 80.0000 85.16
237 11 S24 11.824 (0.884) 222519 80.0000 92.99 9085
196 12.061 12.061 (0.901) 187964 80.0000 82.01
196 12.145 12.145 (0.908) 216657 80.0000 86.83
154 12 365 12 . 365 (0.924) 572659 80.0000 76.06 8290
162 12 399 12.399 (0.927) 493113 80.0000 76 . 38
6 5 12 .602 12.602 (0.942) 364378 160 000 144 . 9 8852
16 3 12 907 12.907 !0.965) 644142 80.0000 75.96 9481
16 5 13 025 18.025 (0 . 973) 141079 80.0000 78.05 9566
152 13 127 13.127 it.981j 793994 80.0000 7 6.46 9975
138 1 3 3 3 0 1 • • "J 0 (0 996) 2 9e 3 94 160.000 155.6 9191
- 54 . 3 . -ii 8 (1 .005i 492415 80.0000 80.63 8743
184 13.516 (1.010) 409555 400 000 362.3
109 1 3 65 1 12.651 (1.020) 266171 160 000 172.5 7983
165 13.73b 1 3 7 3 6 i 1 . 027; 217678 80.0000 81.30 8400
168 13 752 1 3 . 752 ( 1.028) 928521 80.0000 81.81 94 39
149 14.15? 14 . 159 (1 .053) 696693 30.0000 76.06 3374
204 ' 14.345/ 14.345 (1 .072) 412411 80.0000 82.51 7149
166 ' 14.34 5 , 14.345 :: .C 72) 711463 80.0000 • 78.50 7612
Data File:
Report Date
/chem/5972hp6 0 . i'/DF020313A60 . b/HG020313A60 . d: 13-Mar-2030 13:44
Compounds
62
63
64
65
6 6
& /
6 &
65
70
72
73
74
75
76
~>l
7 6
79
80
31
82
93
rfss86
87
I4 -Ni troar.i line
4.6-Dinitro-2-methylphenol
N-Nitrosodiphenylamine
1,2-Diphenylhydrazine
4 -Bromophenyl- phenylecherHexachlbrobenzene
Atr3Zirie
Pentachloropnenoi Phenantlhrene
Anthracene
Carbazoie
Di-n-butylphthalate
Fluoranthene
Benzidine Pyrene j
Butylbenzylphthalat e
3,3'-Dichiorobenzidinej
bis(2 - ethyl hexyl)phthalat eI
Benzo(aianthracene
Chrysene
Di-n-octylphtnalate
Benzo(b)iiucranthene
Benzoik)f1uorantheneI
Benzo(a)pyrene
Indeno(1,2,3-cd)pyrene
Dibenzo(a,h)anthracene
8 8 Benzo(gJ h, :;perylene
QC Flag Legend
QUANT SIG
MASS
138
198
169
77
248
284
200
266
178
178
167
149
202
184
202
149
252
14 9
228
22S
149
252
252
252
276
273
276
RT EXP RT REL RT
14.412 14
14.463 14
14.565 14
14.632 14
15.207 15
15.326 15
15.495 15
15.681 15
16.053 16
16.138 16
16.425 16
17.018 17
18.151 18
18.371 18
18.557 18
19.657 19
20.570 20
20.604 20
20.621 20
20.672 20
21.585 21
22.414 22
22.465 22
23.091 23
26.136 ■ 26
26.187 26
27.033 27
.412 (1.077)
.463 (0.904)
565 (0.910)
.632 (1.094)
207 (0.950)
.326 (0.958)
.495 (0.968)
.681 (0.980)
.053 (1.003)
.138 (1.008)
.425 (1.026)
.018 (1.063)
151 (1.134)
371 (0.890)
.557 (0.899)
.657 (0.952)
.570 10.997)
.604 (0.998)
.621 (0.999)
672 (1.002)
585 (0.930)
.414 (0.966)
.465 (0.968)
091 (0.995)
136 (1.126)
187 (1.128)
.033 (1.165)
M - Compound response manually integrated.
RESPONSE
301084
274214
441767
725417
250594
296253
15622
212908
1064561
1065514
830105
1349987
1314347
253628
1393179
663638
575949
993537
1603585
1260821
1580269
1379012
1464306
1224471
1409814
1245978
1171258
AMOUNTS
CAL-AMT ON-COL
( NG) ( NG)
160.000
160.000
80.0000
80.0000
80.0000
80.0000
80.0000
160.000
80.0000
80.0000
80.0000
80.0000
80.0000
160.000
80.0000
80.0000
80.0000
80.0000
80.0000
80.0000
80.0000
80.0000
80.0000
80.0000
80.0000
80.0000
80.0000
155.7
143.0
71.52
79.47
72.00
74 . 94
17.61
184.0
73.23
72.81
73.13
71.10
78.25
77.42
77.91
71.87
01.68
77.03
89.88
78.41
75.54
76.98
90.40
85.41
92.15
93.57
90.85
SIMILARITY
7970
8803
8816
9238
9401
9514
8993
8900
8918
9112
8620
9446
6930
9107
8540
8610
7460
56 y
pounp: 2.4.b-Trlpromophenol Numper : ljlS— 7*9—6
Data File: /chem/5972hp60.i/DF0203l3A60.b/HG020313A60.dInjection Date: 13-MAR-2002 13:12Instrument: 5972hp60.1Client Sample ID: S5TD080
Ion 141, no: *^rea :
1 . 4-
1 .
1
1
1
Cl
Height: 0
0.1-
14. 14.4 14.5 14.b 14.; 14.6 14.9 15.0 15.1
/ \
5SS
Data File: /che‘m/5972hp60. i/DF020313A60.b/HG020313A60.dInjection Date:| 13-MAR-2002 13:12
Instrument: 59712hp60.iClient Sample I'D: SSTD080
lound: N-Nitroso-di-N-propy 1 amine jNumber: 621'-64-7
5.1-
4.B-
4.5-
4.2-
3.9-;
3.6-
3.3-
3.0-
2.4-
2.1-
1.8-
1 ■
1.2-
0.9-
0.6-
0.3-
0.0-
Ion 70.00: Area: 110346 Height: 53832
! I
8.4 8.5 6.6 8.7 8.0Min
8.9 9.0 9.1 9.2 9.3 j
1.2- 1 - 1-
1.0- 0. o-'
.8-
0.7-
0.6-
0.5;
0.4-
0.3-
•0.2-
0.1-
0.0-
Ion 130.00: Area: Height: 0
8.5 8.6 8.7 8.8Min
8.9 9.0 9.1 9.2 9.3
Ion 42.00: Area: 0 Height: 0
/ \
d. 8 Min
3.9 9.0 9.1 9.2
57 G9.3
Data File: /chem/5972hp60.i/DF020313A60.d/HG0203l3A60.dInjection Date: 13-MAR-2002 13:12Instrument: 5972hp60.iClient Sample ID: SSTD080
ouna: Caprolactam Number: ll05-b0-2
1.3-
1.2
1 . r
1.0'
0.9-
0.8
0.7
0.6
0.5-
0 . 4-
0.3-
0.2-
0.1-
0.0-
Ion 113.00: Area: 45814 Height: 13537
/f
:/Ii I
L
10.6 10. 10.8 10.9 11.0Min
11.1 11.2
2.0-
1 .0-
1 . b-
4-
1.2-
: Tio 1.0
! x
r o.8-
0,6-
0.4-
0.2-
0.0-
Ion 55.00: Area: 15298 Height: 15298
\ in\^r o
L-,
'\
10 . 10.8 10.9 11.0
M i n11.1 LI.2 11.3 11.4 11.5
1 . b-
1.5-.
1 .4-:1.3-
1 .1-
1.0-'.
0 . ?-■ . 8-
. 6-
. 5-
0.0--
Ion 56.00: Area: 13300 Height: 13300
' UT'
;o !b
i10.6 10.9 11.0
Min11.1 11.2
57j±
11.3 11.4 11.5
COMPUCH EM a division of Liberty Analytical Corp DATE 3 //J/el INITIAL TIME OF TUNE / In $ SHIFT/SIA)^ (D)(C)
GC/MS SEMIVOLATILE RUN LOG TIME TUNE EXPIRES0 c, 0 h LINKER /METHOD a 7 7y
COMPUCHEM .LOGBOOK 4 V(4) 4 (5972hp60)m m DDC\/CK!TI\/C N/( AIKITPKIAWPF*i
ikEP
PREVENTIVE MAINTE:nance... _________________________; v1
cT FILENAME ItT DATE TIME CLIENT ID# CASE/SDG# AMOUNTTxirerTcn
CHEMIST COMMENTS(ETC )/DISPOSIT(QfcL pv-..t ------------------------------------------ LC5—
1 ? o ^ (3 A 7 c / 3 7 7 Ho9 ypnAA uJP ___ <ln SV' A! : /C3
2 H fiio > i -! \ An,-) / / / (3ii S f f/3 o ? c^------
______ i______
3 U (it Hj v / f- ~*> A Ac/ / / 1 353 1 F77 I
4 (aJ/’7 // '( L ^ AA\; / / / 7] 3 ________ jiM sj)- ________ l_________---d-w, , t l Sr '■ r . .■'■ _
5 7 1 -XA A Ao / / / isrii ajlv-.’v
6 AtS IMY-)- / / / 1SSS KaMSC
7 A(jo / / / loss Mv-o -im A
8 £)£ OT- Pika / / / nii S
9 lHm- lfe/%07 / / nss Mm-KA___
10 71 / / iSSH iv\w- ns
1 1 &£l<lTn-lk f\Uo / / / l‘>H MuO -/S 3*
12 ^ AOo / / / hbs MvJ- IAS 7_________ N13 \- \(\b° 7 / / Poss S&LIC3 v> VA^XovaS
14 / PUS bTOLcS
15 / / / Pl^S cmPluj
16 fiFl«n-W(/\6a 7 / . / IMl/d - ?cA Qf ^11
17 Q Fm>2flA</o 7 / P$lS N\uJ - ?o & 4/___ d, ^______
18 ____ z___Z_____'—
19 / /
20 / /21 / /22 / /23 —7 7
/ /
Std. ID H
Lot U
Tune
(C- s
STANDARDS Analytical Inrjstd.
------- ■----
7 'I S'Sc.
Column Type SUPERVISOR APPROVAL
J r H-. :L• ! ;i A- V - i>-vu: . . _ j*//s/> .
The presence ol the Chemist's employee II) number, or signature. on III is run log nrtesis thru slnel compliance with ilie method ■. S' 'I' li:>
occurred Any SOI’ deviations require doaimentalion hy (he responsible chemist together with the chemist's initials and the initial'. ni ill
lab supervisor and a QA department representative, sigmlying approval of the deviation | .VI | /ti! dee
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Name:
'Lab Code :
COMPUCHEM
LIBRTY Case
Instrument ID: 5972HP60
Lab File ID: HG020314B60
GC Column: J&W DB-5.625
Contract: 8270C
No.: SAS No.: SDG No.: QE1877
Calibration Date: 03/14/02 Time: 2054
Init . Calib. Date (s) :: 03/03/02 03/03/02
Init . Calib. Times: 1401 1720
0 . 32 (mm)
i
COMPOUND
___________ L_________ '______________
|___ |RRF80.000|
\RRF OR | OR |
AMOUNT |AMOUNT |
1 I 1
1
MIN |
RRF |
1
1
%D OR 1
%DRIFT |
1
MAX %D OR
%DRIFT
j CURV
| TYPE
Phenol | | 1.3820000|1.2750753|------|0.01 |
-------- |-7.74| 20.00 | AVRG
Bis(2 -chlbroethyl)ether 0.9520000|0.8755671 0.01 j -8.03 j50.00 | AVRG
2 -Chlorophenol |1.0880000|1.1101150| 0.01 [ 2.03 | 50.00 | AVRG
1,3LDichlorobenzene |1.4910000|1.6373799| 0.01 1 9.82 [ 50.00 | AVRG
1,4-Dichlorobenzene |1.4860000|1.5998988 | 0.01 1 7.66 20.00 | AVRG
1,2-Dichlorobenzene |1.4310000|1 . 5359906 | 0.01 I 7.34 | 50.00 | AVRG
2-Methvlphenol |0.8830000|0.9068195 | 0.01 1 2.70 | 50.00 | AVRG
2,2'-oxybjis(1-Chloropropane)
4-Methvlphenol
1 . 3580000 1.1937974 |1.1220000|1.0953021 |
0.01 j
0.01 1
-12.09|
-2 . 38 |50.00
50.00
| AVRG
| AVRGN-Ni t roso j- di - N- propylamine
Hexachloroethane
|0.8140000 0.7133376 j
j0.6340000]0 . 7421203 |0.05 10 . 01 j
-12.37|
17.05 |50.00
50.00
| AVRG
| AVRG
Nitrobenzene |0.4960000 0.4382909| 0.01 1 -11.63 50.00 | AVRG
fcophorone 0.7810000|0.6846384 0.01 j -12.34| 50.00j AVRG
^pNitrophenol | 0.2450000|0.2407559 j 0.01 I -1.73| 20.00 | AVRG
4 -Dimethylphenol 0.2970000|0.2769714 j 0.01 1 -6.74 50.00 | AVRGBis(2 - chibroethoxv)methane
2,4-Dichlorophenol
|0.4700000|0.4023271
0.4380000 0.4600051 |0.010.01 1
-14.40
5.02 |
50.00
20.00
| AVRG
AVRG1,2,4-Trichlorobenzene
0.5200000 0.5643432 j0.01 I 8.53 50.00 AVRG
Naphthalene i1 .1890000 i 1.1397945 j 0.01 1 -4.14] 50.00j AVRG
4 -Chloroaniline | 0. 5010000 0.4297048 | 0.01 1 - 14 .23 | 50.00j AVRG
Hexachlorobutadlene |0.4060000 0.4613911 0.01 13.64 20.00 AVRG4-Chloro-3-methvlphenol 10.3640000 j 0.3461601 I 0.01 1 -4.90 | 20.00 | AVRG
2-Methylnaphthalene i0.8860000 0.91921441 0.01 3 . 75 | 50 . 00 AVRGHexachlorocycloper.cadiene
2,4,6-Trichlorophenol
|0.460000C|0.4473442|
j 0.4400000 0.4297655
0 ] C 5 1
0.01]
-2.75] - 2 . 3 3 j
50.00
20.00
| AVRG
AVRG2,4,5-Trichlorophenol 0.4790000 0.4557583 | 0.01 1 -4.85 50.00 | AVRG
2 -Chloronaphthalene |1.2400000 J 1.1247789| 0.01 1 -9.29| 50.00 | AVRG
2 -Nitroaniline |0.4830000 0.4269821 | 0.01 -11.60 50.00 | AVRG
Dimethylphthalate |l.6290000|l.4134548] 0.01] -13.23] 50 . 00 | AVRG
2 , 6 -Dmitrotoluene 10.347000010.3222148! 0.01 1 - 7.14| 50.00 | AVRG
Acenaphthylene |1.9950000|1.813 784 2 j 0.01 I -9.08j 50.00 AVRG1 * Hit roani 1 me |0.3690000|0.3262521] 0.01 1 -11.58] 50.00 | AVRG
Acenaphthene ] 1 . 1730000 ! 1. 114 3569 ] 0.01 1 -5.00 20.00 | AVRG
2 , 4 - Dinitrophenol !0.2170000!0.1355693 0.05] -14.44 50 . 00 | AVRG
- H11 rophenol ;0.2960000 j 0.3208015 0.05 8 . 38 | 50.00 AVRG2 , 4 - Dim trotoluene 0. 5140000 j 0.4826130 0.01 1 -6.11 50.00 AVRGEiibenzof uran ]2.1810 0 0 0|2.1378217j 0.01 1 -1.98] 50 . 00 ] AVRGDiethylphthalate ! 1. 7600000]!.613503 0| 0.01 1 -8.32 50.00 AVRG4 -Cnlorophenyl-phenylether Fluorene |
|0.9600000!0.9886 520 j
| 1. 7420000| 1. 7789175 j0.010.01 i
2.98]
2 . 12 |50.00
50.00
| AVRG
| AVRGi t roani 1 i ne !0.3720000|0.3076896 0.01 -17.29 50 . 00 | AVRG- Dim tro - 2 - methvlphenol 0.1560000|0.1538125]
!. i 1
0 . 01 1
1
-7.34]
150.00 | AVRG
raae i oi> 2 573FORM VII SV
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Name: COMPUCHEM Contract: 8270C
Lab Code: LIBRTY Case No.: SAS No.: SDG No.: QE1877
Instrument ID: 5972HP60 Calibration Date: 03/14/02 Time: 2054
Lab File ID: HG020314B60 Init. Calib. Date(s): 03/03/02 03/03/02
Init. Calib. Times: 1401 1720
GC CoIumn : JScW DB-5.625 ID: 0 . 31 (mm)
1| COMPOU
iND RRF OR
AMOUNT
jRRF80.000|
1 0R
AMOUNT | (
1
MIN |
RRF1
1
%D OR 1
%DRIFT1
MAX %D OR
%DRIFT
j CURV
TYPE
' ||N-Nitrosodiphenylamine
|-----------| 0.5330000 1 0.4876334 |
------10.01 |
-------- 1-8.51| 20.00
jAVRG|
| 4 -Bromophenyl-phenvlether
| Hexachlorobenzene
|0.3000000
0.3410000
0.2951585 I
| 0.3303247
0.01 I
0.01
-1.61 -3.13|
50.00
50.00
|AVRG|
AVRG |
i Pentachlorophenol | 0.1000000 | 0.1177405| 0.05 1 17.74| 20.00 |AVRG|
| Phenanthrene j1.2540000 1.1727415| 0.01 | -6.48 | 50.00 | AVRG
!Anthracene 1 . 2630000 | 1.2627789 0.01 j-0.02 50.00 |AVRG|
iCarbazolej 0.9800000 | 0 . 9256850| 0.01 1 -5.54| 50.00
|AVRG j
i Di-n-butylphthalate |1.6380000 | 1 . 5508453| 0.01 1 -5 . 32 | 50.00 AVRG |
i Fluoranthene |1.4490000 1 . 5026635 0.01 3.70 20.00|AVRG j
|Pyrene | j1.4350000 |1 . 3087822 | 0.01 1 -8.80] 50.00j AVRG|
J Butylben z vlphthalate 0.7410000 |0.6061015 0.01 -18.20 50.00 AVRG13,3'-Diclilorobenzidine 0.5660000 |0.5614097 0.01 -0.81 50.00 AVRGgeis ( 2 - etlWl hexyl) Phthalate
Mbnzo(a)anthracene|1.0350000
|1.4320000
|1.0530921 j1.6387461|
0.01 1 0.01 j
1.75
14.44
50 . 00
50.00
| AVRG jAVRG|
^hrysene | 1.2900000 |1.3561748 0.01 5.13 50.00 |AVRG|
I Di-n-octvlphthalate |2.0140000 2.1167437 0.01 1 5.10 20.00 AVRG |
jBenzo(b)fluoranthene 1 . 7250000 1.9346295| 0.01 1 12.15| 50.00 |AVRG|
1Benzo(k) fluoranthenej1 . 5600000 (1.7494808 | 0.01
12.15 j50.00
|AVRG j
iBenzo (a)pvrene 1.3800000 |1.5472874 0.01 12.12 20.00 AVRG1Indeno(1 ,j 2,3 -ca)pvrene j1.4730000
j1.7093933 |0.01 1 16.05| 50.00 |AVRG j
!Dibenzo( a ,h)anthracene 1 . 2820000 1.5231834 0 . 01 1 18.81 50.00jAVRG j
]Benzo iq,H, 1)pervlene | 1 . 24 10000 j 1.4311206 j 0.01 15.32 50.00 AVRG
j 2 -rluorc
i
phenol 1 . 2730000 1.2073047 0.01 -5.16 50.00 |AVRG|
jPhenol -d5 1.4360000 1.3727927 0.01 -4.40 50.00 1 AVRG
] Hitroben z ene-d5 10.5720000 (0.52520681 0.01 j -8 . 18 j50.001AVRG
: 2 - Fluorobyphenol j1.5550000 |1.5076698 0.01 -3.04) 50 . 00 |AVRG|
2 , -J , 6 - Tr i brorr.ophenol 10.3760000 |0.4124754 | o. oi! 9.70 50.00 | AVRG
1 7e rphenv 1 - d I 4 j1.1100000 [ 1 . 0347666 | 0.01 -6.78 50.00 AVRG| I 1 1 1
!nacre 2 of 2
FORM VII SV
Data File: /'chem/5g72hp60.1/DF020314B60.1VHG02031-4E60 d
Date : 14-MAR-2002 20:54
Client ID: SSTD080
Sample Info: SSTD080;2319
Volume Injected <uL): 2.0
Column phase: J&W DB-5.825
Instrument: 5972hp60.i
Operator: 2310
Column diameter: 0.32
'-O
r"-
LO
<:<10~6>
Data File: /chem75972hp60.i/DF020314B60.b/HG020314B60.d
Date : 14-MAR-2002 20:54
Client ID: SSTD080
Sample Info: SSTD080:2319
Volume Injected (uLl: 2.0
Column phase: JS.W DB-5.625
Instrument; 5972hp60,i
Operator; 231?
Cc» 1 urnn d i amet er : 0 ♦ 32
;_0
r-LD
4.34.2
4.1
4.0- i 3.93.8
3.7-i
3.6- i
3.5-:
3.4
3.3- 1
3.2- ;3.1 J
3.0
2.9
2.82.7
2.62.5
2.4- j
2.3
2.22.12.0- i
1.9-j
1.81.7-
1.61.5- ;1.41.3-
1.21.1-
1.0 0,9-
0.8 0.7
0.6-
0.5-
0.4- 0.3
~0T2'
0.1 UL
7chem/5972hp60, i/DF020314E60,b/HG020314B60.d (Part 2 of 21
Lj J
16 17 18 19 20 21
Data File: /chem/5972hp60.i/DF020314B60.b/HG020314B60.dReport Date: 14-Mar-2030 21:31
CompuChem
| Semivolatile Report SW-846 Method 8270CData file : /chem/5972hp60.i/DF020314B60.b/HG020314B60.d Lab Smp|Id: SSTD080 Client Smp ID: SSTD080
Inj Date : 14-MAR-2002 20:54Operator : 2319 Inst ID: 5972hp60.iSmp Info : SSTD08 0:2319 Misc Info :Comment I :Method j : /chem/5972hp60.i/DF020314B60.b/8270Cv6.m
Meth Date : 14-Mar-2030 21:31 naegler Quant Type: ISTDCal Date : 03-MAR-2002 17:20 Cal File: HL020303A60.dAls bottle: 2 Continuing Calibration SampleDil Factor: 1.00000Integrator: HP RTE Compound Sublist: all.subTarget Version: 3.50Processing Host: einstein
Concent ration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name1
Value Description
iDF 1.00000 Dilution Factorvi 1000.00000 Volume of final extract (uL)vo 1000.00.000 Volume of sample extracted (mL)
W 1.00000 Volume injected (uL)
Cpnd Va riable Local Compound Variable
AMOUNTSC'UANT s:g CAL-AMT ON-COL
Compounds MASS K. £:■:? ET F.EL FT RESPONSE ( MG) ( NO
* 1 1 , 4 - D :h 1 or r.hen zi 151 0 1 3 7 5 . 1 J ~ 1 . 0 0 0 . 91913 40.0000- Nnpr.ih : 3-i : <: . .1 .f; 5 i. .15 5 DDL. 272010 40.0000
- 6 4 12.254 1 2 . 3 v 4 .1 300; 242509 40.0000:r = . •= ' 1 •' 0 01 495405 40.0000
cv ill. 24... V. : 1 •?0 ; 579435 40.000'
■> J-?.:-.:: 11 5 •' "22 ' 2Z 221534 8 0 . 0 0 2 0 7 5 . y 8i ■ 1 J - 7 i ; 252355 80 . (-00 0 78.48
:b C z 3 2 ) 235723 S0.00CO 73.47*: • ' - . v . , . ,. . . ........... . • : • j
* ‘ “ 1 ^ 1 : | ;• •. c i'—. ct: ;r: 14." •• : 1 4 . 7 •: 5 ,; . 15 ; 200055 30.0000 37.69- 4 1 - 7 7- -.775 "' 1 ■ 1199152 30.0000 74.56
N-.l: i - = --.i — r.y 1 2 :.ir: ‘ '■ .415' 358085 80.0000 104 . 514 1 4 1 7 j.417 ■ 0 . 4 I L : 353833 90.0 0 C 0 7 6.4 2
SIMILARITY
2643
5 3 8 5
fa
577
Data Fijle : /chem/5972hp60.i/DF020314B60.b/HG020314B60.dReport 'Date: 14-Mar-2030 21:31
Compounds
==a,a“=““r===”““===a15 Benzaldenyde
16 Phenol17 B i s 12 -jch ioroethyl) ether
13 2-Chlorophenol19 1 . j -Dilchiorobenzene
. “*■''"r—iOIOCen“er*<r2: BenzvJ alcohol
2 3 2 - Methv i ohenoi
2« 1.2 -oxyo 1 s : 1 ->_nloropropane)
25 Acetophenone
26 ?-Methylphenol
27 4-Methylphenol
2 8 N-Nitroso-di-N-prcpy1 amine2 9 HexachJloroethane
3C Nitrobenzene
3i IsoDhcrcn?
I .3 2 2 - N 11 ropnenoi
3, - - J•4 e: s : 2 -pr.: orc-et hoxy 1 xetnane
3 7 t.'aph: na lene
3 9 A - 2!: 1 o roa r. 1 . in —
39 Hexach 1 ore rntzaz 1 er.e
4 C i. 3 d rc i c t (i ~j..o_
•t ^ N ; t roa.n 1 . : z-
AMOUNTS
UANT SIG CAL-AMT ON-COL
MASS RT EX F R: REL RT RESPONSE ( NG) ( NG) SIMILARITY
R7 7.409 7.409 (0.911) 127371 80.0000 86 . 31 8580
94 7 . 59c 7 59b (0.933) 234392 30.0000 73 . 78
93 7 714 7.714 i0 943) 160952 90.0000 73 . 62
128 7 7 9 9 7 7 9 9 (0.958) 204053 50.C000 81.65 3965
146 9 . 035 8.035 ■0 988) 300993 30.0000 3 7.8:-
14 5 9.154 8.154 r1.002' 294103 SO.000c 36.12
10S 9 . 3 7 4 9 . 374 '.1.029' 123291 80 - 0000 76.79
'.4 6 S 4 09 8.408 ! 1 . C 3 3 ) 232355 80.0000 85.90
103 /0 '.')i 8 . 594 (1.056) 166697 80.0000 82.18
as' - - / 8.594 (1.056) 219451 80.0000 70.31 "7056
:os 8.814 ^ 3.914 (1.083) 294264 80.0000 80.82 7756
105 ' '8.847 8 . 847 (1.087) 201345 80.0000 78 .10
109 ' 8 847 8 . 847 (1.037) 201345 80.0000 78.10
, 70 8.814' 8.814 {1.ce 3) 131130 80.0000 70.09 0 (M)
117 8 . 966 3 . 966 (1.102) 136421 80.0000 93 .62 8046
77 3 . 101 9 . 101 (0.885) 238439 80.0000 70 . 67 8895
5 2 9 . 507 ✓ 9.507 (0.924) 372457 80.0000 70. 11 3762
13 9 9.643 9 . 64 3 (0.937; 130976 so.000c 78.62 8809
:cc q 72 7 2.727 1 r . 94 6 ) I 50678 so.oooc 74 . 54 7970
9 3 5 .879 9.379 (0.961) 218S74 80.OOOC 6S .43 7688
16 2 10 Goo 10.066 (0.979) 250252 80.0000 84 . 07
180 10.201 1 0.2 0 J (0.992) 307014 80.0000 86.88
128 10.336 10.336 (1.005) 520071 80.0000 76 . 70 8986
12 7 10.438 1 0 . 4 3 3 : 1.nisi 233768 30.0000 68.60 8559
225 10.539 1 C . 5 3 9 (1.025) 251006 80.0000 90.81 8416
113 11 .030 11.030 (1.072) 31907 80.0000 54 . 16 8314
107 11 . 300 1I.300 (1.099) 188318 80.0000 76 . 10 8775
142 11 .537 11.537 {1 . 122) 500071 80.0000 82 . 99
142 11 .707 11.707 (1.138) 411619 80.0000 84 . 50
237 1 1 .BOB 11.303 (0.384) 216970 80.0000 77.84 9284
1 96 :2.04 5 1 2 04 E '0 9 011 203444 80.0000 78 . 07
: = - 12 11 12.113 ( n 5 0b '< 221051 80.0000 76.05
: 5 4 :: .M-- 12.2 4 9 (0 924) 632222 80.OOCO 72 . 08 3382
-.4: 1 2 . 3 1' 1 2 . 5 2 :;. .527; 545538 30.0000 72.54
Z - 1 2 . 5 r c ’0 c 4 ^) 414158 16 0 . C 0 0 14 1.4 8895
:ii 12.531 1 2 . : T-1 ', • 9 6 5 . 585551 80.0000 69.40 9481
: ' 5 1 : . 0 0 5 1 :■. 009 ('1.973; 156280 80.0000 74 . 22 9533
1 D 2’ 13.111 *.".11: ■' 0 . 5 £ 1 i 379718 80.0000 72.73 8376
13 3 :: r.4 --.Jit 1 -j . : v 6 i 316486 160.000 141.6 9243
154 12 415 .4 1 j ' 1 • 0 04) 540488 8 C.0000 75.96 9 3 64 '
- ^ 4 1 • 5 ■; ;:-v 450266 4 C 0.0 0 0 3 41.9
1 :• 435 = : 1. : 2: ’ 311189 160 . 000 173 . 2 7989
19 5 12 .":' : ?. 7 2: 1 . .'<27; 234076 5 D . 0 0 0 0 75 . 05 7853
: 4 1 3 7 7 7 1 : . V 7 523; 1036882 30.0000 7 8.42 9376
'• 4 4 . : 4 ■ • • • • ; 1. 0 5 6: 782578 80.0000 73.34 9 3 90
X 14.12^ • i . 0 7 2) 479514 80.0000 32 25 7113
: 5 6 • • ^ 1 '1 / , 17- .'1 .072 : 862807 30 . OOCO 81 .72 7339
57b\
fiJ
Data File: /chem/5972hp60.1/DF020314B60.b/HGO20314B60.dReport Date: 14-Mar-2030 21:31
COfTDCUDdS
64
6 5
4-Nitroan:1ineI
4 , 6 - 31 r. i t r
N-Nizrosodiphe
necnyIpneno:
mine
1.2•Dipheny1hydra 21ne
4 -Eromophenvl-onenviezher|
Hexachlorobenzene
45 Per.zachioropneno 1
70 Phenanzhrene
71 Ar.zhr.acene72 CarbJzole
Di -n-bnzyiphthalat-f
F1 uorancheneQ !..
Benziame
IUANi 5IG
MASS
13 5
158
169
77
243
294
200 266
1 7S
178
167
14 9
202
134
AMOUNTS
CAL-AMT ON-COL
EX? RT REL NG) NG) SIMILARITY
14 .396
14 .447
14 .549
14.616
15.192
15.310
15.475
15.665
16 . 037
16.122
16.410
17.002
19.119
16 . 355
14 . 396
14 .447
14.54 9
14 .616
15.192
15.310
15.479
15.665
16 . 037
16 . 122
16.410
17.002
18.118
18 . 355
;l.077i
(0. 904.1
(0.910':
(1 . 094)
( 0.9 5 0 i
(0. 953 :
(0.968)
(0.980)
(1.003'(1.009
(1.0261
(1 . 0 6 3 ’•
(1 . 133)
(0.890)
298470
304798
483152
796739
292446
327289
10582
233317
1161964
1251174
917178
1536593
1488854
277868
160.000
160.000
80.0000
30.0000
80.0000
80.0000
80.0000
16 C.000
80.CG00
80.0000
80.00C0
80.OOCO
80.0000
160.0C0
132.5
148 . 7
73.18
74.93
78 . 61
77 .46
11.16
18 8.6
74 . 78
79.99
75.60
75.12
82.94
72 . 96
QC Flag Legend
M - Compound, response manually integrated.
8219
8779
8322
9124
9673
9185
8997
8508(M) >
9107
9293
7 6 202 1 . 5 2 4 10.524 (0.998) 1516711 80.0000 72.96
77 Buzyibenz y1pnz ha laze 149 19.624 19.624 (0.952) 702394 8 C.0000 6 5.43 9 04 1
7 9 3,3'- r,;.- v- 252 20.555 20.555 (0.997) 650602 90.0000 79.37 6 u 13
7 5 b: s 1 2 -et:- / i ne:*:y i ' Pnz ha laze 14 y 20.586 20.568 (0.996) 1220399 80.0000 81 .40 8 964
•3 G 1 a ) a n z h i' a c e n e 22S 20.605 20.605 (0.999) 1899097 80.0000 91.57
Chrvs 228 20.656 20.656 (1.002) 1571533 30.0000 34 . 08
14 9 2 ■ 5 7 n 2' 570 (0 0 71) '•94 06 7 3 80 0000 84 07
5 ez 0 ■r,-: ( noranzhene 252 22.332 "'2 3 82 (0.966) 1773707 80.0000 89 . 72
? 4 3jr o'"' 1 ! f luoranzhene 252 22.432 2 2 4 3 2 (0.968) 1603959 80.0000 89.74
3; E^nzc "'f- • 252 23.056 23 . 058 (0.995) 1418534 80.0000 8 9.66
1j naeno• .. 3 . 3 - c d 1 pyrene 276 26.037 26.087 (1.126) 1567206 80.0000 92 . 63 -9 76 0
bet. .h 2 7? 26.137 26.137 (1.128: 1396485 80.0000 95.03 8745
Z'.‘- , . . ' ue : y 276 27.00-' 27.000 (1.165) 1312080 SO . 0000 y2.23 7 3 8 P
571
ompound: z[4,6-Tribromophenol
A5 Mumper: 110-?9-6
Data File: .•'chem./597iripri0.1 /DF020314B60 . t?/ HG020314860. dInjection Date: 14-MAR-2002 20:54Instrument: | 59?2hp60. lClient Samole ID: 537D030
1.1-
1.0-
0.9-
0.0- 0.7-
0.6 -
0.5-'
0.4-
0.3-
0.2~
0.1-
0.0—
Ion 329.60: Area: 200056 Height: 109896
14.4 14.5 14.6 14.7 14.8 14.9Min______________________
15.0 15.1 15.
1.0-
0.9-
0.8-
0.7-
0.6-
0.5-
n 4.
Ion j>32.00: Area: 0 Height: 0
14.7 14.8M l n
14.9 15.0 15.1 15.2
Ion 141.00: Area: Height: o
,§84ZT
in. a 15. o 15.1
Data File: [••'cnem/5972hp60.1 /DF02031*4660. P/HG02031*4660. aInjection Date: 14-mhR-2002 20:5*4Instrument;1 5972hp60.iClient Sample ID: SSTDuQO
ompound: r4—r4it roso-dl-N-propg1 am in* k'S Number;! 621-64-7
I
6.0-
5.6-
5.2-
4.0-
4.4- '
4.0-
3.6-
3.2-
2.8-.
2.4-
2.0- .
1.6-
1.2-
0.8-
0.4*
0.0--
Ion 70.00: nrea: 131130 Height: 61720
©<D'
8.5 3.6 8.0Min
8.9 9.0 9.1 9.2 9.3
1.2-
1 . 1-
1 - 0-.
0.9-.
0.8-
0.6-
0.5-.
0.4-
0.1-
0 i'i -
Ion 130.00: Hrea: Height: 0
= . 3M .
9.0 9.1
j.8
j.5
I
0.0- -6.5 . Ci 8.9 9.1 9.3
Data File: /chem/5972hp60 . i .'DF020314 660 . b/ HG02031 *4560 . dInjection Date: 14-MAR-2002 20:54Instrument: 5972hp60.iClient Sample ID: S5TD080
Compound: kCAS Number
Rentachlorophenol : 87-66-5
1.2-
1.1'
1.0-
0.9-
0.3-
0.7-
0.6-
0.5-;
0.4-
0.3-
0.2-
0.1-
0.0—
Ion 266.00: Area: 23^317 Height: 1249b5
!£
15.4 15.5 15.6 15.'
Mm15.8 15.9 16.0 16.1
\5-
6.5-'
5.5-
5.0-
1.0
0.5-;
0.0
O . b 6.4-
Ion 268.00: Area: 30179 Height: 30179
15.4 15.6 15.7 15.9 16.0 16.1
I or-. Heignt: 78067
15.9 16.0 165Sr
COMPUCHEM a uiv ision of Liberty Analytical Corp DATE
GC/MS SEMI VOLATILE RIJN LOG
/ 14/0*4 INITIAL TIME OF TUNE
TIME TUNE EXPIRES S 1
SHIFT/S(A)CC)
LINKER /METHOD__ L-...................
at
• a a PREVENTIVE MAINTENANCE tOon*_/ O
i 0 ------------------------------------------------- -
aD
V FILE NAME; . J '%>.1 d-
DATE Z TIME 7- LTGLjJENTlD# CASE/SDG# AMOUNT - INJECTED
CHEMIST COMMENTS(ETC.)/DlSPOSITION_r^- •
1 / ^ 7 IM7 4; »>oSI ’DFt/’P •?5>I5u)
:2 H-61O)M gt.o / / / — i
3 / / / S?>LU:36s VlAAxosZ> )m L
4 Vo 6n IU5oH O &(/° z / / S756 L<-S vl/
5 / / |V\uj-%A cZVr.h-ir-l
6 qb i%n- sc 2 7 /7 4/
7/ b 7ib7o> AuJ - c^/rS aFiinn
8 < l&M'n-W&o / / 00 5^
9 1 / / CfiffFZ R32?
10 / si / / 62/7 09/9 FY FP32Z
1 1 / / 625?t At?
12 k'&lUW ~H&jb z / /! A5&
13 Fz3n-ism> z / / cm avr-3114 / ?tb n-iumj> / /
15 nizi- niti&o £ / / man
16 / FWl-lWbLO ?L / / PUS C,qFF3/.DdP_______ X
17 / F?s?7-msnui /(N47 C/MFfN V
18 --------f—-7---------- r>bl - < • TrDne ___ _______
19 / / u
20 / /77<T^
21 / / __----------------------------
22 / /
23 ----- "’f/
■■ ------zsT24 --------A--7---------
Std. ID ft
Tune Analytical
Hbil
Int. Std.
S'yo
Column Type
Lot ft
date
_______O -
SUPERVISOR APPROVAL_,3Zs/o2-
The presence of the Chemist s employee ID number, or signature, on this run log attests that stne'l compliance with the niciliod s St il1 li occurred Any SOP deviations require documentation by the responsible chemist together with the chemist s initials and the initials m i lab supervisor and a QA department representative, signify ing approval of the deviation . ;,-j i m; ,i. L
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Name: COMPUCHEM Contract: 8270C
Lab Code: LIBRTY Case No.: SAS No.: SDG No.: QE1877
Instrument ID: 5972HP64 Calibration Date: 03/11/02 Time: 0855
Lab File ID: HG020311A64 Init. Calib. Date(s): 03/10/02 03/10/02| Init. Calib. Times: 1416 1723
GC Column: RTX-5 ID: 0.32 (mm)
COMPOtND |RRF OR
|AMOUNT
|
|RRF80.000|1 OR j
AMOUNT |
| |
1
MIN |
RRF |
1
1
%D OR 1
%DRIFT |
1
MAX %D OR
%DRIFT
CURV j
|TYPE|
Phenol | 1.4530000 |1.3750083| 0.01 | -5.37| 20.00|AVRG j
Eis (2 - chlloroethyl) ether | 0.9870000 0.9678347 0.01 -1.94 50.00j AVRG j
2 -Chlorophenol | 1.3440000 | 1.3378068 j 0.01 1 -0.46| 50.00 |AVRG|
1, 3 -Dichlorobenzene 1.5440000j1.5053199 j 0.01 j -2.50| 50.00
j AVRG j
1 , 4 -Dichlorobenzene [1.5580000 1 . 5087010 0.01 -3.16 20.00j AVRG j
1, 2 - Dichlorobenzene 1.5340000 | 1.4831560| 0.01 1 -3 . 31| 50.00 AVRG |
2-Methylphenol [1.1720000 | 1.1752022 j 0.01 I 0.27 j50.00
jAVRG|
2,2' -oxybis(1 -Chloropropane)
4-Methvlphenol
|1.8230000
1.2740000
1.7884050 [1.2270109|
0.010.01 1
-1.90
-3.69
50.00
50.00
AVRG | AVRG j
N-Nitroso-di-N-propylamine__
Hexachioroethane
|0.8030000
|0.8060000
0.7842909 j
[0.7866033|
0.05 1
0.01 1-2.33 -2.41|
50.00
50.00
AVRG j
j AVRG|
Nitrobenzene |0.3400000 | 0.3524220 0.01 ■ 3 . 65| 50.00jAVRG j
Jsophorone |0.6730000 0.6543315 0.01 -2.77 50.00j AVRG j
fc-Nitrophenol |0.2150000 | 0.2096179| 0 . 01 1 -2.50| 20.00|AVRG j
W, 4-Dimethvlphenol 0 . 3200000 0.3189410 0.01 1 -0.33 50.00 AVRG
Bis (2-chloroethoxy)methane
2,4-Dichlorophenol
| 0.4020000
0.3310000
| 0.3752985
| 0.3137093
0.01 j
0.01
-6.64 |-5.22 j
50.00
20.00
|AVRG| j AVRG j
1,2,4-Trichlorobenzene 0.3860000 0 . 3640747 0.01-5.68 j
50.00j AVRG j
Naphthalene j 1 . 4460000 1 .4329549 0.01 -0.90 50.00 AVRG4 - Chloroanil me 0.4620000 | 0.4635959 0.01 1 0.34 | 50.00 | AVRG
Hexachlorobutadiene | 0.2660000 | 0 . 2515176 | 0.01 1 -5.44| 20.00|AVRG j
4 -Chloro 3-methylphenol [0.3680000 | 0 . 3701861 | 0.01 j 0.59 j20.00 [AVRG|
2-Methvlnaphthalene | 0 . 7240000 0.6882150[ 0.01 -4.94 | 50.00 ]AVRG|
Hexachlorocyclopentadiene
2,4,6 -Trichlorophenol
0.3960000I 0.4070000
| 0 . 4028086 j 0 . 4109771j
0.050.01 I
1.720.98 |
50.00
20.00
AVRG j
|AVRG|
2 , 4 , 5 - T r ichlorophenol [0.4320000 0 . 4324343 0.01 0.10 50.00|AVRG j
2 -Chlororiaphthalene j 1 . 0260000 1.0233779[ 0 . 01 [ -0.26 50.00 AVRG2 - 111 t roani 1 me 0 . 3670000 [0.3652370| 0.01 -0.48| 50.00 |AVRG|
Dimethyl bhthalate | 1 . 2540000 | 1 .26 6 9037[ 0.01 1 1 . 03 | 50 . 00 |AVRG|
2 , 6 - D i n i rotoluene 0.3450000 [0.3444937 0.01] -0.15| 50.00 |AVRG|
Acenaphth y lene [ 2 . 4090000 [2 . 3563686 J 0.01 -2.18 50.00j AVRG
3 - Mitroan 11 me | 0 . 3650000 | 0 . 3 £ 1 8 7 6 3 | 0.01 1 -0.86| 50.00 |AVRG|
Acenaphthene 1.5590000 1 . 446314 1 0.01 1 - 7.23| 20.00 AVRG |
2 , 4 -Dini prophenol 0 . 0610000 |0.06’78’740| 0 . 05 1 11.27| 50.00 AVRG4 -NitrophJenol [0.2170000 I 0.2154068 0.05 -0.73 50.00 AVRG2,4-Dinit rotoluene 10 . 5000000 10.5007911] 0 . 01 1 0 . 16 | 50.00
jAVRG|
Dibenzofuran |1.6140000 ■ 1 . 5663238 1 o. oi [ -2.95 50.00 |AVRG|
Diethylpntha late 11.4840000 ! 1 . 4 539740 j0.01 -2.02 50 . 00 AVRG [
4 -Chloropheny1 -phenylether Fluorene 1
i 0 . 6930000
[1.8520000
; 0 . 5 14 7 0 0 8 j
[ 1 . 8500119 [
0 . 0 1 1 0 . 01 j
-2.64 - 0.11J
50.00
50.00
j AVRG j
AVRG |
4-Nitroan lime 10.3300000 •0.3339842j 0.01 1.05 50.00 AVRG |^ 6 - D i n i ro- 2 -methylphenol : 0.1620000
1
i 0 . 1713274 [
! !0.01
1
5.76 [
150.00 [ AVRG
FORM VII SV 584
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Name: COMPUCHEM Contract: 8270C
|Lab Code: LIBRTY Case No.: SAS No.: SDG No.: QE1877
Instrument ID: 5972HP64 Calibration Date: 03/11/02 Time: 0855
Lab File ID: HG020311A64 Init. Calib. Date(s): 03/10/02 03/10/02
Init. Calib. Times: 1416 1723
GC Column: RTX-5 ID: 0.32 (mm)
1 1
COMPOUND1 1
| 1
RRF OR |AMOUNT
1
|RRF80.000| OR j
AMOUNTi |
1
MIN |
RRFI
1
%D OR 1
%DRIFT1
MAX %D OR
%DRIFT
CURV
TYPE
' ||N-Nitrosodiphenvlamine
-- 1-----------| 0.4360000
|------------ || 0.4269002|
------ 10.01 |
-- =---- 1-2.09| 20.00 | AVRG
j 4 -Bromophenyl-phenylether
I Hexachlorobenzene__ 0.2120000
| 0.26100000.2077959
| 0.2572523|0.010.01 1
-1.98]
-1.44
50 . 00
50.00
AVRG | AVRG
!Pentachlorophenol 0.1740000 0.1739961| 0.05 -0.00 20.00j AVRG
! Phenanthrene 1.4880000 1.4449910| 0.01 -2.89 50.00 [ AVRG
I Anthracene | 1.5130000 | 1.4528678 0.01 | -3.97 | 50.00 | AVRG
i Carbazole I 0 . 9960000 | 0 . 9662441j0.01 I -2.99| 50.00 | AVRG
! Di-n-but’ilphthalate 1.4890000 1.4738923| 0.01 -1.01| 50.00j AVRG
! Fluoranthene 1.7160000 1.6882611 0.01-1.62 j
20.00 AVRG:Pvrene I | 1 . 9180000 | 1.8749487 0.01 -2.24 50.00 AVRG
!Butvlbenz ylphthalate 0.7700000 0.7440325| 0.01 1 -3.37 50.00 | AVRG|3,3'-Dichlorobenzidine 0.5420000
0.5080123 j 0.01 j-6.27 50.00
j AVRG
ysis (2 - etliylhexyl) Phthalate Anzc (a) anthracene
| 1 . 1480000
i 1 . 7590000
| 1.1179279|
| 1 . 7380184
0.01 1
0.01
-2 . 62 |
-1.19150.00
50.00
| AVRG
AVRGRirvsene | 1 . 6580000 1.5977958 0.01
- 3 . 63 j50.00 AVRG
[ Di - n - oct\- lphthalate 2.2640000 2.1753928 0.01 - 3.91| 20.00 AVRGBenzo(b) £ 1uoranthene 2 . 1450000 2.3078830 0.01 1 7.59 50.00 | AVRG
!Benzo(h)£ luoranthene 1.9380000j1.7480163 |
0.01 1 -9.80 50.00 | AVRG
:Benzo ! a!p vrenej1.7000000 1.6625427 j
0.01) -2.20 20.00 | AVRG
|Indeno(1 : 2,3 -cdipyrene j1.2280000 j1.1978155 0.01 -2.46 50.00 AVRG:Dibenzo(a ,h)anthracene 1.4900000 1.4443789 0.01 -3.06 50.00
j AVRG
Benzo (g,h ,i)pervlene 1 . 5630000 1.5249788 0.01 -2.43 50.00 | AVRG1
2 -Fluorophenol !1.2980000 | 1.2764316 | 0.01 1 -1.66| 50.00 | AVRG
Phenol -d5 |1.6910000 1.6216721 0.01 -4.10 50.00j AVRG
Nitrobenz e n e - d 5 0.4330000 ! 0.4 174 573 0.01 -3.59 50.00 [ AVRG
2 -Fluorob iphenvl | 1.3330000 1.3529710 0.01 1.50 50.00 j AVRG
2 , 4 , o - T r i oromooiienol 0.4030000 ! 0 . 3956922 j 0 . 01 j - 1.56 | 50.00 AVRGTerphenyI -dl4 | 1 . 0590000 i 1 . 01002 30 j 0.01 -4.62 50.00 AVRG
1 i i i I 1
FORM VII SV
58b
y c:<i<y6>
Data File; 2chem/5972hp64.i/DF020311A64.b^HG020311A64.dDate : ll-MAR-2002 08:55Client ID: SSTD080Sample Info: SSTD080:2070Volume Injected <uL): 1.0Column phase: RTX-5
Instrument: 5972hp64.i
Operator: 2070 Column diameter: 0.32
LO
ooLO
Sample Info: SSTD080:2070Volume Injected <uL>: 1.0 Operator: 2070
Column phase: RTX-5 Column diameter: 0.32
Data File: /chem/5972hp64.i/DF020311A64.b/HG020311A64.d
Date : ll-MAR-2002 08}55
Client ID: SSTD080 Instrument: 5972hp64.i
587
* * ISTD DIFFERENCE REPORT**
Injection Date of Current CCAL: ll-MAR-2002 08:55
Injection Date of Previous CCAL: 10-MAR-2002 14:16
Maximum %Difference of ISTD: + 100 Minimum %Difference of ISTD:
ISTD Name Current CCAL Previous CCAL % DiffArea Area
1,4-Dichlorobenzene-d4 105735 106189 -0.4Naphthalene-d8 414967 418210 -0.8
Acenaphthene-dlO 285056 297124 + 4.1Phenanthrene-dlO 592430 631561 -6.2
Chrysene-dl2 562509 596220 -5.7
¥Perylene-d!2 300075 309056 -2.9
within +/- 30 seconds (0.5)
Current CCAL Previous CCAL AbsoluteRT RT Difference
1,4-Dichlorobenzene-d4 Naphthalene-d8
Acenaphthene-dlO Phenanthrene-dlO
Chrysene-dl2 Perylene-dl2
8 249 8 266 0 01710 143 10 143 0 00013 152 13 169 0 01715 485 15 485 0 00019 949 19 966 0 01722 434 22 451 0 017
Retention time must fall
ISTD Name
i
-50
PASSESPASSESPASSESPASSESPASSESPASSES
PASSESPASSESPASSESPASSESPASSESPASSES
588
Data File: /chem/5972hp64.i/DF020311A64.b/HG020311A64.dReport Date: ll-Mar-2030 09:26
Data file Lab Smp id Inj Datej
Operator Smp Info]
Misc Info Comment j
Method | Meth DateCal DateAls bottle Dil Factor Integrator
CompuChem
Semivolatile Report SW-846 Method 8270C /chem/5972hp64.i/DF020311A64.b/HG020311A64.d
SSTD080ll-MAR-2002 08:55 2070SSTD080:2070
Client Smp ID: SSTD080
Inst ID: 5972hp64.i
/chem/5 972hp64 ll-Mar-2030 09 10-MAR-20 02 17 2
1.00000 HP RTE
Target Version: Processing Host:
3.50einstein
i/DF020311A64.b/8270Cv6 .m26 mikhael Quant Type: ISTD23 Cal File: HL020310A64.d
Continuing Calibration Sample
Compound Sublist: all.sub
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
DF 1.00000 Dilution Factor^ vt 1000.00000 Volume of final extract (uL)■ Vo 1000.00000 Volume of sample extracted (mL)W vi 1.00000 Volume injected (uL)
Cpnd Variable Local Compound Variable
Compounds
QUANT SIG
MASS RT EXP RT REL RT RESPONSE
AMOUNTS
CAL-AMT
( NG)
ON-COL
( NG) SIMILARITY
• 1 1,4-Dichlorober:zene-d4 152 0.249 8.249 (1.000) 105735 40.0000
• 2 Naphthalene-d6 136 10.143 10.143 (1.000) 414967 40.0000
. •> Acenaph’ h n e - a 10 164 13.152 13.152 (1.000) 285056 40.0000
• 1 Phenanthrene-dlC 188 15.485 15.485 (1.000) 592430 40.0000
• E> Chrysene - d ■ 2 24 0 19.949 1 9 94 9 (1.000) 562509 40.0000
' Pervleru - d ; 2 264 22.434 22.434 (1 . 000) 300075 40.0000
2 7 2 -Fluorochenci 112 6.457 6.457 (0 . 783) 269927 80.0000 -j
CD (J\i_n
6 Phenol-dS 95 7.742 7 74 2 (0.939) 342935 80 . 0000 76.71
5 9 Nitrobenzene-dB 8 2 9.065 9.095 (0.897) 346462 80.0000 77.15
S 10 2 -Fluoroblpheny1 172 11.884 11 . e84 (0.904) 771345 80.0000 81.22
? 11 2 , 4 , 6 - Tr ibroitoohenol 330 14 . 454 14.454 (1.099) 226159 80.0000 78.80
;• 12 Terphenyl-d!4 24 4 17.852 17.852 (0.855) 1136294 80 . 0000' 76 31
I 1 N - N11 rosed imet hy laini ne 4 2 4 . 327 4.327 ( 0.525) 100269 80 . 0000 79.45 8840
M Py r id l n« 7 5 4.327 4 . 327 (0.525) 175431 80.0000 8 0.18 9411
Data File: /chem/5972hp64.i/DF020311A64.b/HG020311A64.dReport Date: ll-Mar-2030 09:26
Compounds
15 Benzaldehyde
16 Phenol j
17 Bis(2-chloroethyl)ether
18 2-Chlorophenol
19 1,3 - DichlorobenzeneI
20 1,4-Dichlorobenzene21 Benzyl Llcohol
22 1,2-Dichlorobenzene23 2-Methyjlphenol
24 2,2' -oxybis(1 -Chloropropane)
25 Acetophenone26 3 - Met hyjlphenol
27 4-Methylphenol
28 N-Nitroso-di-N-propylamine
2 9 Hexachl'o roe thane
30 Nitrobenzene
31 Isophorone32 2-NitrJphenol
33 2,4-Dimethylphenol
34 Bis(2-chloroethoxy)methane
35 2,4 -Dichloroohenoli
36 1,2,4-Ijr ic h loro benzene
.37 Naphthalene|3 S 4 • Chlorjoani 1 me
3 9 He >: a c h ll o r o b u t a diene
40 Caprolactam
41 4-Chioro-3-methylphenoll|
42 2 - Methy 1 naphtha 1ene
43 1-Methy1 naphthalene4 4 Hexachllorocyclopentadiene
45 2,4,6-Trichlorophenol
46 2,4,5-Trichlorophenol ■17 1.1' -Eijphenyl
4 8 2 - Ch 1 o ronaphc n.a 1 ene|
4 9 2 • N: t roar.: 1 i ne
5 0 Dimethy1pht ha late
: 1 j e n e
rer.ann5 : 3 - N l t r 'ian.: 1: ne
J .Acen.apht ne ne
5 5 2.4 - D i :• • t rooheno:
.1
56 4 -N11rophenoi
• o toluene
5 8 Dibenzofurar.
na la: e
.er.y 1 - phenyl ethe
AMOUNTS
QUANT SIG
MASS RT EXP RT REL RT RESPONSE
CAL-AMT
( NG)
ON-COL
( NG) SIMILARITY
77 7.641 7.641 (0.926) 182826 80.0000 78.95 9710
94 7.776 7.776 (0.943) 290773 80.0000 75.68
93 7.894 7.894 (0.957) 204668 80.0000 78.41
128 7.996 7.996 (0.969) 282906 80.0000 79.63 9323
146 8.199 8 . 199 (0.994) 318330 80.0000 77.98
146 8.283 8.283 (1.004) 319045 80.0000 77.46
108 8.452 8.452 (1.025) 162485 80.0000 77.59
146 8.554 8.554 (1.037) 313643 80.0000 77.36
108 8 . 621 8.621 (1.045) 248520 80.0000 80.22
45 8.672 8 . 672 (1.051) 378194 80.0000 78.46 9006
105 8.858 8.858 (1.074) 344398 80.0000 hs . 93 9239
108 8 . 824 8.824 (1.070) 259476 80.0000 77.05
108 8 . 824 8 . 824 (1.070) 259476 80.0000 77.05
70 8.875 8.875 (1.076) 165854 80.0000 78.15 8492
117 9 . 010 9.010 (1.092) 166343 80.0000 78.04 9379
77 9.129 9.129 (0.900) 292487 80.0000 82.96 9283
82 9.450 9.450 (0.932) 543052 80.0000 77.79 9178
139 9.602 9.602 (0.947) 173969 80.0000 78.16 8442
122 9.602 9.602 (0.947) 264700 80.0000 79.79 8456
93 9.737 9.737 (0.960) 311473 80.0000 74 . 75 9462
162 9.923 9.923 (0.978) 260358 80.0000 75.77
180 10.075 10.075 (0.993) 302158 80.0000 75.41
128 10.177 10.177 (1.003) 1189258 80.0000 79.29 9319
127 10.261 10.261 (1.012) 384754 80.0000 80.22 7545
225 10.413 10.413 (1.027) 208743 80.0000 75.65 9362
113 10.718 10.718 (1.057) 93949 80.0000 79.92 9664
107 10.938 10.938 (1.078) 307230 80.0000 80.48 9218
142 11.208 11.208 (1.105} 571173 80.0000 75.98
142 11.394 11.394 (1.123) 534977 80.0000 74 . 58
237 11.597 11 . 597 (0 . 882) 229646 80.0000 81.33 9604
19b 11.749 11 .749 (0.893) 234303 80.0000 80.77
196 11.817 11 .817 (0.898) 246536 80.0000 80.11
154 12.053 12.053 (0.916) 672680 80.0000 78.78 7597
162 12.104 12.104 (0.920) 583440 80.0000 79.78
65 12.341 12.341 (0.938) 208226 160.000 159.1 9503
16 3 12.67? 12.679 (0.964 ) 722277 80.0000 80.82 8804
165 12.831 12.831 (0.976 ) 196400 80.0000 79.87 9274
152 12.899 12 8 0 9 n . 9 9 1 ) 1343394 80.0000 78.26 8903
138 13.085 13.085 (0 . 995 1 206310 160.000 158 . 5 9159'
154 13.220 1 3 . 220 (1 . 005) 824561 80.0000 74 .21 8962
184 13.254 13.254 (1.008! 193479 400.000 444 . 9
109 13.304 13.304 (1.012) 122806 160.000 158.6 7625
165 13.507 13.507 11.02 7 J 285507 80.0000 80. 11 8725
168 13.474 13.4 74 (1 . 024) 892980 80.0000 77.63 9193
149 13 . 962 1 3 562 (1.054) 028928 ' 80.0000 78.38 9551
204 13.996 I 3 . 9 9 S (1.064) 384655 80 . 0000 77.85 7476
164 14 .048 14.048 (1.066) 1054714 80 . 0000 7 9 . 91 7 525
59
Data File: /chem/5972hp64.i/DF020311A64.b/HG020311A64.dReport Date: ll-Mar-2030 09:26
»
Compounds
QUANT SIG
MASS RT EXP RT REL RT RESPONSE
AMOUNTS
CAL-AMT
( NG)
ON-COL
( NG) SIMILARITY
62 4-Nitroaniline 138 14.116 14.116 (1.073) 213914 160.000 161.6 8758
6 3 4 , 6-Dinitro-2-methylphenol 198 14 . 167 14 . 167 (0.915) 202999 160.000 169.3 9422
64 N-Nitrosodipheny1amine 169 14.201 14.201 (0.917) 505817 80.0000 78.39 8113
65 1,2-Diphenylhydrazine 77 14.251 14.251 (1.084) 846132 80.0000 79.20 9353
6 6 4-Bromophenyl-phenylether 248 14.758 14.758 (0.953) 246209 80.0000 78 34 9666
67 Hexachlorobenzene 284 15.029 15.029 (0.971) 304808 80.0000 78.89 9456
69 Atrazine 200 15.012 15.012 (0.969) 234997 80.0000 79.75 9163
. 69 Peneachlorophenol 266 15.283 15.283 (0.987) 206161 160.000 160.3 7691
70 Phenanthrene 178 15.519 15.519 (1.002) 1712112 80.0000 77.66
71 Anthracene 178 15.570 15.570 (1.005) 1721445 80.0000 76.83
72 Carbazole 167 15.790 15.790 (1.020) 1144864 80.0000 77.63 9621
73 Di-n-butylphthalate 149 16.229 16.229 (1.048) 1746356 80.0000 79.21 9083
74 Fluoranthene 202 17.261 17.261 (1.115) 2000353 80.0000 78.71
75 Benzidine 184 17.413 17.413 (0.873) 1203807 160.000 148.7 8821
76
77
Pyrene |
Butylbenzylphthalate
202
149
17 . 683
18 . 816
17.683
10.816
(0.886)
(0.943)
2109351
837050
80.0000
00.0000
78.19
77.32 9192
78 3,3'-Dichlorobenzidine 252 19.830 19.830 (0.994) 571523 80.0000 74.96 8084
79 bis (2-ethylhexyl)Phthalate 149 19.780 19.780 (0.992) 1257689 80.0000 77.90 9433
80 Benzo(a! ant nracene 228 19.915 19.915 (0.998) 1955302 80.0000 79.05
81 Chrysene 228 19.999 19.999 (1.003) 1797549 80.0000 77.08
82 Di -n-oct •/lphtha late 14 9 20.760 20.760 (0.925) 1305562 80.0000 76.87
83 Benzo(b) f luoranthene 252 21.690 21.690 (0.967) 1385076 00.0000 86.06
■^4 B e n z o i k ) fluoranthene 252 21.741 21.741 (0.969} 1049072 80.0000 72.13
P Benzo la) pyrene 252 22.333 22.333 (0.995) 997775 80.0000 78.25
86 I ndeno(1 , 2,3■cdipyrene 276 25.021 25.021 (1.115} 718869 80.0000 78.02 0 (M)
37 Dibenzo a,n)anthracene 273 25.021 25.021 (1.115) 866844 80.0000 77.54 8247
98 Benzo !a, h,i)peiy1ene 276 25.849 25.349 (1.152) 915216 80.0000 78.07 9281
QC
M -
Flag
Comp
Liegend
3und response manually integrated.
3- //- „ l
Data File: /chem/5972hp64.i/DF020311A64.b/HG020311A64.dInjection Date: ll-MAR-2002 08:55Instrument: 5972hp64.iClient Samplej ID: S5TD0B0
lound: 2,4'.6-Tribromophenol Number: ljl0-79-6
Data File: /chem/5972hp64.1/DF020311A64.b/HG020311A64.d Injection Date: ll-MAR-2002 08:55 Instrument: 5972hp64.i
COMPUCHEM a division of Liberty Analytical Corp DATE 3 / // Wl INITIAL TIME OF TUNE O# y ? SH1FT/S(A) (B)(C)
GC/MS SEMIVOLATILE RUN LOG TIME TUNE EXPIRES 2 o > LINKER /METHOD St ^COMPUCHEM .LOGBOOK 4 YYY 4 (5972hp64)
Tl [T1 PREVENTIVE MAINTENANCE/Vw f_______________________________________________________________
£CTE
FILE NAMEotTED
DATE TIME CLIENT ID# CASE/SDG# AMOUNTINJECTED
CHEMIST COMMENTS! PTC j/lM'blfiTibNLO
1 l)ro l c l l( A Zu / .5 >H >61 T) Att/1 i_i4L ________Z7 -rzv- - /.-A
2 —* If A/<7 / / / oS st ^sr7>,^u___
3 JA/lAlU-IrUu / / / 0C(?l rfd/cjA______ (/A/1 V /V.- t 1
4 / (7h 0-7 7- 1ta/c S| / / IV i i ^u//C OCC 2 0-__ £? 24 7 ?____ _____ f~ - n. x r______________________
5 7 fD ? U-7 r. ? h l\A(i f|- / / ‘*<4% ^r/Z^q pc' s ____ z_z___________t o____________
6 / r?) 70.1 j- ihAfa Kf / / i/3'7 A 1-J.Uouv ! 6 /____Z-i-
7 ZTZcTUcYi AC// /7/ / / ?/V ZcifC Gt.c- l ^ z K
8 / TH / / 12 ‘TO __________ ^ /i j_ ___Z-X______
9 (a)Ailld Zv-PAZv / / / / 3 7 5 ___________ 1 H<>p ^______________________
10 rr)7 0.n-ib?A& / / / / If 0 s' fidfCnuu ifr'hL___i-Z.A-
1 1 fTnoos .sT) Mv in / / '44-2 vv-Pf'Go c?p 2 S'
12 (Z? U 73 / / / /r /A________ _______:
13 (a)Z> /0/U- TiVM, / / / s'vr '5nt 4a cit’2. ~) /~1 t L
14 lAWSa-'VSAun 4 / / lu>^ D>»CSiAO
15 IA3MS2 -H3 A(*HZ
■/ no 02 ou^uo'-f
16 / lms2 -S/UW JU/ / HMfe Ojo L 3ct oj>
17 / m/ / 0 ia o l
18 / / / 02oL>MUO^
19 UuMO-fcAld z / / IW 02OGHU03
20 IA240 -AH / / /
________
V l» 0 2o6>H Wo3D
21 / I/I 2 Aid mor
/ <!' 0 >^u^| WoM 4\J
s/
22 ---------L_
/
_J----------
/-------------------------------------------- ------------------
24 t___2=_i______ —
STANDARDS -4 yTune Analytical lilt. Std. Column Type SUPERVISOR APPROVAL ZZvZZ ^
StdHD-ft-------- -------------------------------------------------------------------------------- --ZZ^sV-A--------------- DA-FE/l(o >_________________________
Lot # llAiS. ■— C 3 /> Z * a I_______ ___S 1 \ f, \^. The presence of the Cheinisi's employee II) number. or signntuic. on this run log attests iliat .and compliance vnih ilie method •. M »l'
occurred Any SOI’ deviations require documentation by the responsible chemist tngethei with the chemist's initials ami ihc initials «
lab supervisor aij^i (,)A department representative, signifying nppiovnl of the deviation I I Oo/nl
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab
Lab
Name :
Code :
COMPUCHEM
LIBRTY Case
Instrument ID: 5972HP64
Lab File ID: HG020311B64
Contract: 8270C
No.: SAS NO.: SDG No.: QE1877
Calibration Date: 03/11/02 Time: 2253
Init. Calib. Date(s): 03/10/02 03/10/02
Init. Calib. Times: 1416 1723
GC Col umn : RTX - 5 ID: 0.32 (mm)
iI COMPOUND
|Phenol |
|Bis(2 -chioroethyl)ether
J 2 -Chlorophenol I 1, 3-Dichiorobenzenei 1 --------------|1,4-Dichiorobenzene
I 1,2-DichiorobenzeneI | -----------j2'Methylphenol |2,2 ' -oxyEis(1 -Chloropropane)
[4-Methylphenol
|N-Nitroso-di-N-propylamine__
IHexachloroethane
[Nitrobenzene
Isophorone___-Nitrophenol
, 4-Dimethylphenol___________
Bis(2 -chloroethoxy)methane_
2 , 4-Dichlorophenol
1,2,4-Trichlorobenzene
|Naphthalene
I 4 - Chioroaniline___________
IHexachlorobutadiene1 I -----i 4-Chloroi3-methvlohenol
| 2-Methylnaphthalene_________
| Hexachlorocyclopentadiene_j 2,4,6 -Trichlorophenol______
'2,4,5-Trichlorophenol______
2-Chloronaphthalene_________
j2 - Nit roani1ine________________
|Dimethvlphthalate____________
;2 , 6-Dinitrotoluene__________
iAcenaphthylene
- 3-Nitroani 1 me________________
!Acenaphthene__________________
;2,4 - DiniDrophenol____________
I 4-Nitrophenol_________________
! 2,4-Dinitrotoluene__________
! Dibenzofuran___________________
iDiethylphthalate_____________
4 -Chlorophenyl-phenylether ] FluoreneJ
i 4 -Nitroariil me
6-Dinibro-2-methvlohenol
page 1 oE 2
(RRF8 0.000 | 1 1 1 1
RRF OR 1 OR | MIN | %D OR 1 MAX %D OR|CURV|j AMOUNT |AMOUNT |
1 I
RRF j
1
%DRIFT 1
1
%DRIFT |TYPE|
1.4530000
1----------- 1| 1.4288473|
------10.01 1
-------- 1-1.661
----------- 1 — |2 0.0 0|AVRG|
| 0.9870000 0 . 9319326 0.01 -5.58 50.00 AVRG| 1.3440000 j1.2835053 | 0.01 1 -4.50 | 50.00 AVRG|
| 1 . 5440000 1.4632976 j 0.01 1 -5.23| 50.00|AVRG j
j1.5580000 |1.4927116 0.01 1 -4.19 j 20.00 jAVRG|
|1.5340000 j1.4513183 j 0.01 1 -5.39| 50.00|AVRGj
|1.1720000 1.1246352 | 0.01 1 -4.04| 5 0.0 0|AVRG
1.8230000 1.7604245 0.01-3.43 j 50.00 AVRG|
1.2740000 1.2347748| 0.01 -3.08 50.00 AVRG
|0.8030000 |0.7450387 | 0.05] -7.22| 50.00]AVRG|
|0.8060000 |0.7630464 0.01 j -5.33 j 50.00|AVRG
|0.3400000 0.3503588 | 0.01 3 . 05 | 5 0.0 0 j AVRG
(0.6730000 |0.6693175| 0.01 j -0.55| 5 0.0 0 jAVRG|
j 0.2150000 10.2121352 0.01 j -1.33 | 20.00|AVRG|
0.3200000 0.3120055| 0.01 -2.505 0.0 0 j AVRG j
0.4020000 0.4105081 0.01 1 2.12 5 0.0 0|AVRG|
| 0 . 3310000 |0.3376091 0.01 j 2.00 | 20.00|AVRG|
|0.3860000 j 0.3810025| 0.01 1 - 1.2 9 j 5 0.0 0 j AVRG j
1.4460000 1.4735112 0.01 1 1.. 90 | 50.00 AVRG|
(0.4620000 (0.4780432 | o . o i ( 3 . 4 7 j 50.00[AVRG(
|0.2660000 (0.2634745 0.01 -0.9520.00 jAVRG j
0.3680000 0.3647257 | 0.01 -0.89 20.00 AVRG|0.7240000 |0.7112745 | 0.01 1 -1.76 50.00 AVRG|0.3960000|0.3675725| 0.05 1 -7 . 18 | 5 0.0 0|AVRG j
|0.4070000 |0.41564 95 | 0.012.12 j
20.00 AVRG
0.4320000 0.4243734 0.01 -1.76] 50.00 AVRG|1.0260000 (1.0308065( 0 . 01 1 0.47 | 50.00|AVRG||0.3670000 |0.3725542 0.01 1.51 50.00|AVRG
|1.2540000 1.2582962 0.01 1 0 . 34 | 50.00 AVRG(0.3450000 j 0. 3419095 | 0.01 j -0 . 90 j
50.00]AVRG|
(2.4090000 |2.3558810 | 0.01 ( -2 . 20| 5 0.0 0|AVRG|
(0.3650000 0.3619142 0.01 -0.84 50.00 AVRG
1.5590000 (1.5356203 0.01 -1.50( 20.00]AVRG
(0.0610000 (0.0600705| 0 . 05 1 - 1.52| 50.00(AVRG|
0.2170000 (0.2001577 0.05 -7.76 5 0.0 0|AVRG(0.5000000 (0.5006206 0.01 1 0.12 50.00 AVRG|]1.6140000 1 . 5783827 j 0.01 -2.21 50.00 AVRG|1.4840000 | 1 . 4485386 | 0.01 1 -2 . 39| 5 0.0 0|AVRG|i0.6930000 0.57S6956| 0.01 - 2.06 | 50.00 j AVRG|
(1.8520000 1 . 8147222 | 0.01 1 -2.01 50.00 AVRG10.3800000 I 0.3698028 | 0.01 1 -2 . 68| 50.00(AVRG|!0.1620000i0.1618847 j
! i i
0.01 1
1
- 0.07 j
1
5 0.0 0 jAVRG|
1 1
FORM VII SV59 j
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Name: COMPUCHEM Lab cLde: LIBRTY Case No.
Instrument ID: 5972HP64
Lab File ID: HG020311B64
Contract: 8270C
SAS No.: SDG No.: QE1877
Calibration Date: 03/11/02 Time: 2253
Init. Calib. Date(s): 03/10/02 03/10/02
Init. Calib. Times: 1416 1723
gc co: .umn: RTX-5 ID: 0.32 (mm)
1| COMPOL
i1
ND
1___
j RP.F OR
AMOUNT
| P.RF8 0.000 |
OR|AMOUNT I
1 |
1
MIN |
RRF |
I
%D OR %DRIFT |
1
MAX %D OR
%DRIFT
jCURvj
j TYPE
|N-Nitrosodiphenylamine““ 1-----------
[0.4360000|----------- || 0.4252453 |
------I0.01 |
-------- 1-2.47| 20.00 AVRG
| 4 - Bromophenyl -phenvlether
| Hexachlorobenzene
|0.2120000
0.2610000
| 0.20457930.2538997 j
0.010.01 1
-3 . 50|
-2.72]50.00
50.00
AVRG |AVRG j
I Pentachl'orophenol |0.1740000 | 0 . 1662047| 0.05 1 - 4.4 8 | 20.00|AVRG j
!Phenanthrene 1.4880000 1.4072421| 0.01 j -5.43 j50.00
jAVRG j
iAnthracene I 1.5130000 | 1.4303164 j0.01
-5.46 j50.00 | AVRG
|Carbazol e 0.9960000 1.0017379 0.01 I 0.58 | 50.00j AVRG|
|Di-n- but vlphthalate |1.4890000 1.4193083| 0.01 1 - 4 .68 j 50.00|AVRG j
;Fluoranthene |1.7160000 1 . 6799277 | 0.01 -2.10 | 20.00jAVRG j
| Pvrene 1.9180000 | 1 . 8215947 0.01 -5.03 50.00IAVRG j
! Butylben'zylphthalate 0.7700000 | 0.7258042 0.01 -5.74 50.00 AVRG |
! 3 , 3' -Dichlorobenzidine i0.5420000 | 0.5545583| 0.01] 2.32] 50.00 |AVRG]
!bis(2-ethvlhexyl)Phthalate ^enzo(a)anthracene
|1.1480000
1.7590000
| 1 . 1003856 j
| 1.6720496 j0.01 I
0.01
-4 . 15|
-4.94
50.00
50.00
|AVRG| jAVRG j
PPhrysene 1.6580000 1 . 5703507 0.01 -5.29| 50.00 | AVRG
]Di-n-octvlphthalate 2.2640000 2 . 1379883 0.01 -5.56] 20.00 ] AVRG
Benzo(b)fluoranthene 2.1450000 1 . 7689854 0.01 1 -17.53 50.00j AVRG|
!Benzo(k) fluoranthene I 1.9380000 | 2.3180102 | 0.01] 19.61 50.00jAVRG|
| Benzo(a)pvrene j1 . 7000000 | 1.6622862 j 0.01 j-2.22 20.00
AVRG j
! Indeno (1 l2 , 3 - cd)pvrene 1.22800001 . 1811904 j
0.01] -3.81 50 . 00 AVRG!Dibenzo(a,h)anthracene 1 .4900000 1.4441409
0.01 j-3.08 50.00 AVRG
i Benzo ig, n,i)pervlene 1 . 5630000 1.5193161 0.01 -2.79 50.00 AVRG1
i 2 -Fluorophenol ! 1 . 2980000 | 1 . 2760461 0.01 -1.69 50.00AVRG j
: Phenol - dS 1 . 5910000 1.6267774 0.01 -3.80 50.00 AVRG |1 Mitrobenzene-d5 | 0.4330000 j 0 . 4458545 0.01 2.97 50.00 AVRG■ 2 - r luorotpiphenyl j1 . 3330000 1.3289473| 0.01 -0.30 50.00 AVRG2 , 4,6 -Tribromophenol 0.4030000
|0 . 3861743 j0.01 -4 . 18 | 50.00 | AVRG
ierpher.v 1 - dl 4 | 1 . 0590000 ]0.9901198] 0.01 1 - 6.5 0 | 50.00j AVRG
1 [ 1
oaqe
FORM VII SV
59b
<:<10A6>
Data Filet /chem/5972hp64. iXDF020311B64. b/HG020311B64. d
Date : ll-MAR-2002 22:53
Client ID: SSTD080
Sample Info: SSTD080:2319
Volume Injected (uL): 1+0
Column phase: RTX-5
Instrument: 5972hp64,i
Operator: 2319
Column diameter: 0.32
cnLD
3.1- j
3.0- i
2.9-i
2.8- i
2.7- :
2.6-:
2.5- ;
2.4- ;
2.3-j
2.2- j
2.1- i
2.0- i
1.9- j
l.s-i
1.7- ;
1.6- ;
1.5- j
> 1.4-1
1*3-:
1.2- i
1.1- i i.o-i0.9-i
0.8-i
0.7-;
0.6-i
0.5-j
0.4-1
/chem/5972hp64,i/DF020311B64.b/HC020311B64,d (Part 1 of 21
Phenanthrene-dlO+
Data File: /chem/5972hp64. i/DF020311B64.b/HG020311B64.d
Date : ll-MAR-2002 22:53
Client ID: SSTD080
Sample Info: SSTD080:2319
Volume Injected (uL>: 1.0
Column phase: RTX-5
Instrument: 5972hp64.i ;oCD
Operator: 2319 LO
Column diameter: 0.32
Data File: /chem/5972hp64.i/DF020311B64.b/HG020311B64.dReport Date: ll-Mar-2030 23:20
CompuChem
Semivolatile Report SW-846 Method 8270C /chem/5972hp64.i/DF020311B64.b/HG020311B64.d SSTD080 Client Smp ID: SSTD08011-MAR-2 0 02 22:532319 Inst ID: 5972hp64.iSSTD080:2319
Data file Lab Smp id
Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date|
Als bottle Dil Factor Integrator Target Version: Processing Host:
/chem/5 972hp64.i/DF020311B64.b/8270Cv6.m ll-Mar-2030 23:20 naegler Quant Type: ISTD10-MAR-20 02 17:23 Cal File: HL020310A64.d2 Continuing Calibration Sample1.00000
HP RTE Compound Sublist: all.sub3.50einstein
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name I
Value Description
DF 1.00000 Dilution Factor^ vt 1000.00000 Volume of final extract (uL)■ Vo 1000.00000 Volume of sample extracted (mL)^ Vi 1.00000 Volume injected (uL)
Cpnd Variable Local Compound Variable
AMOUNTS
Compounds
QUANT SIG
MASS RT EXP RT REL RT RESPONSE
CAL-AMT
( NG)
ON-COL
{ NG)
* L 1,4-Dich lorebenzene-d-i 152 8 . 264 0 . 264 (1 .000) 123003 40.0000
. 2 Naoncha 1‘
ere-d3 13d 10 . 150 10 . 158 (1 . 000) 450795 40.0000
* 2 Acer.aphr 164 13 . 167 1 3 167 (1 . 000) 321474 40.0000
Phenanohrene-d 1 01
186 15.433 !5 . 4 8 3 .ooo) 666326 40.0000
Chryse,, . -i i 240 19.943 1'.' . 3 4 i 1 1 .0001 642652 40.0000
• Pervlene•
-di: 264 22.449 -> ■? 44 9 ( 1 .000) 350874 40.0000
f 7 1 - r iuoroohencd r
112 6.455 455 (0.781) 313915 80.0000 78.62
C C Pher.o 1 - d c. 9 9 7 . 757 7 . 757 (0.939) 400197 80.0000 76.95
Ns z rebar. car.o - d£ 82 9.109 : 0 9 (0.£97} 401978 80.0000 CDru
1 19 2 -Fiuoro b i pheny1 172 11.882 882 (0 . 902) 854444 80.0000 79.78
-■ ;; lbromopnenol 330 1 4 4 69 14 . 4 5 9 (1 .099) 248290 80.0000 76.71
5 : 2 1 - d : 4 244 1 7.547 : 7 . eo-; (0.395) 1272605 80.0000
oCD
N-N:crosodinethvlam:na1
4 1 4.342 4 . 34 2 (0.525) 116554 80.0000 79.39
P y r i c i r. a 7 9 4.224 4 . 3 2 5 (0.523) 203742 80.0000 80.05
SIMILARITY
8711
9454
(Mi j
flO
59 b) h\o/-
Data File: /chem/5972hp64.i/DF020311B64.b/HG020311B64.dReport Dalte: ll-Mar-2030 23:20
Compounds
15
16
17
18
13
20
21
23
2425
26
27
2 B
29
30
34
4 0
4 2
4 3
44
4 1
4 8
4 9
50
Benzaldehyde Phenol J
Bis {2-chloroethy1)ether
2 -Chlorophenol
1.3- DichlorobenzeneI
1.4- DichlorobenzeneI
Benzyl alcohol I
1,2-Dichlorobenzene
2- Methylphenol
2,2'-oxybis(1-Chloropropane)
Acetophenone
3- Methylphenol
4- Methylphenol
N-Nitroso-di-N-propylamine
Hexachloroethane
Nitrobenzene
1 sophorone
2 -Nit rophenol
2.4- DimethyIphenolBis (2-chlbroethoxy)methane
2.4- DichJorophenol
1.2.4 - Trilchlorobenzene
Naphthalene
4-Chloroanilme
Hexachlorobutadiene
Caprolactam4 - Chioro-jj ■ methylphenol
2-Methylnapht halene
1-Methy1 naphthalene
Hexachiorocyc1ooentadieneI
2,4,0- TriJch lorophenol2.4.5 -TrJchlorophenol1 . 1' - £ ipller.y 1
2 - Chi orenapht ha 1ene
2 - N i t roam 1 i ne
Dimethvipnthalate' \
2,6-Dimtrotoiuene
Acenaphthy1ene
3 - N j t ro-i n : 1 i ne
Acenapht’neneI
2,4 -D: :u drocheno1J '.4 -Nit rophenoi
Dibe;--zo: Jrar-
Diet hv ipht ha late‘ I
4 - Ch i oropher.y 1 - phenyl et iter
F1corone
AMOUNTS
QUANT SIG
MASS RT EXP RT REL RT RESPONSE
CAL-AMT
( NG)
ON-COL
( NG) SIMILARITY
77 7.639 7.639 (0.924 ) 206263 80.0000 76.57 9764
94 7.774 7.774 (0.941) 351505 80.0000 78.65
93 7.909 7.909 (0.957) 229261 80.0000 75.50
128 8 . 010 8.010 (0.969) 315750 80.0000 76.40 8907
146 8.213 8.213 (0.994) 359980 80.0000 75.81
146 8.281 8.281 (1.002) 367216 00.0000 76.64
108 8.467 8.467 (1.025) 185510 80.0000 76.15
146 8 . 568 8.568 (1.037) 357033 80.0000 75.70
108 8 . 636 8.636 {1.045) 276667 80.0000 76.77
45 8.670 8.670 {1.049) 433075 80.0000 77.23 9063
105 8.873 8.873 (1.074) 403904 00.0000 77.55 8639
ioe 8 . e39 8.839 (1.070) 303762 80.0000 77.54
108 8.839 8 . B 3 9 (1.070) 303762 80.0000 77.54
70 8.873 8.873 (1.074) 183284 80.0000 74.24 0 (M)
117 9.008 9.008 (1.090) 187714 80.0000 75.70 9488
77 9 . 126 9 . 126 (0.898) 315880 80.0000 82.47 9707
82 9.448 9.448 (0.930) 603450 80.0000 79.57 9454
139 9.600 9.600 (0.945) 191259 80.0000 79.10 8394
122 9.600 9.600 (0.945) 281301 80.0000 78.05 7495
93 9.752 9.752 (0.960) 370110 80.0000 81.76 9538
162 9.938 9 . 938 (0.978) 304385 80.0000 81.54
180 10.073 10.073 (0.992) 343508 80.0000 78.92
128 10.175 10.175 (1.002) 1328503 80.0000 81.54 9764
127 10.259 10.259 (1.010) 430999 80.0000 82.72 8286
225 10.428 10.428 (1.027) 237546 80.0000 79.24 8793
113 10.732 10.732 (1.057) 107053 80.0000 83.83 9501
107 10.935 10 . 935 (1.077) 328833 80.0000 79.29 9776
142 11.223 11 . 223 (1.105) 641278 80.0000 78.53
142 11.409 11.409 (1.123) 617137 80.0000 79.20
237 11 .595 11.595 (0.881) 236330 80.0000 74.22 8926
196 11 . 747 11 . 747 (0.892} 26724 1 80.0000 81.68
196 11.831 11.831 (0.899) 272850 80.0000 78.61
154 12 . 068 12.068 (0.917) 768624 80.0000 79.82 7592
162 12.119 12.119 (0.920) 662755 80.0000 80.36
6 5 12.355 12.355 (0.938) 239533 80.0000 81.13 9292
163 12 . 677 12 . 677 (0.963) 809019 80.0000 80.28 9463
155 12.646 12.346 (0.976) 219830 80.0000 79.27 8272
152 12 . 996 12.996 (0.979) 1514709 80.0000 78 . 24 9610
1 35 13 .082 13.062 (0.994) 232692 800.000 92.97 9421
154 13.218 12 . 2 1 B (1 . 004) 987324 so. OOOC 78. eo 9654
184 1 3 . 2 6 S 13.268 (1.008) 193111 400.000 393 . 7
109 13 . 319 13.315 (1.012) ■ 128691 80.0000 73.71 8086
16 5 i 3 522 13.522 (1.027) 321873 80.0000 80.08 8199
163 13.499 13.496 (1.024) 1014818 80.0000 78.23 9023
14 9 1 3 . 8 6 0 13.350 (1.053) 931335 00 . 0000 78 . 09 9710
2 04 ■ c 14.012 (1.064) 436366 80.0000 78.31 0 (M)
16 6 14.04 6 14.046 (1.067) 1166772 80.0000 78 . 38 7662
fu
60:J 2>WW
Data File: /chem/5972hp64.i/DF020311B64.b/HG020311B64.dReport Date: ll-Mar-2030 23:20
Compounds
QUANT SIG
MASS RT EXP RT REL RT RESPONSE
CAL-AMT
( NG)
ON-COL
( NG) SIMILARITY
62 4-Nitroaniline 138 14.114 14.114 (1.072) 237764 80.0000 77.82 9061
63 4,6-Dinitro-2-methylphenol 198 14.181 14.181 (0.916) 215736 80.0000 79.97 9208
64 N-Nitrosodiphenylamine 169 14.198 14.198 (0.917) 566704 80.0000 78.08 8785
65 1,2-Diphenylhydrazine 77 14.249 14.249 (1.082) 953497 80.0000 79.14 9523
6 6 4 -Bromophenyl-phenylether 248 14.773 14.773 (0.954) 272633 80.0000 77.13 8927
67 Hexachlorobenzene 284 15.044 15.044 (0.972) 338360 80.0000 77.86 8632
68x • 1Atrazine 200 15.027 15.027 (0.971) 260062 80.0000 78.47 9199
69 Pentachjlorophenol 266 15.280 15.280 (0.987) 221493 80.0000 76.57 8941
70 Phenanthrene 178 15.517 15.517 (1.002) 1875364 80.0000 75.63
71 Anthracene 178 15.585 15.585 (1.007) 1906114 80.0000 75.64
72 Carbazole 167 15.804 15.804 (1.021) 1334968 80.0000 80.49 9546
73 Di-n-butylphthalate 149 16.227 16.227 (1.048) 1891444 80.0000 76.27 9718
74 Fluoranthene 202 17.275 17.275 (1.116) 2238759 80.0000 78.32
75 Benzidine 184 17.427 17.427 (0.873) 1156391 160.000 125.0 0749
76 Pyrene 202 17.698 17.698 (0.887) 2341303 80.0000 75.97
77 Butylbenzylphthalate 149 18.814 18.814 (0.942) 932879 80.0000 75.43 9713
78 3,3' -Dichlorobenzidine 252 19.845 19.845 (0.994) 712776 80.0000 81.83 7889
79 bis (2-ethylhexyl}Phthalate 149 19.794 19.794 (0.992) 1414330 80.0000 76.68 9233
80 Benzo(a)anthracene 228 19.930 19.930 (0.998) 2149092 80.0000 76.05
81 Chrysene 228 20.014 20.014 (1.003) 2018378 80.0000 75.76
82 Di-n-octylphtha late 14 9 20.775 20.775 (0.925) 1500329 80.0000 75.55
83 Benzo(b}fluoranthene 252 21.705 21.705 (0.967) 1241382 80.0000 65.97
Benzo(k)fluoranthene 252 21 . 756 21.756 (0.969) 1626659 80.0000 95.65
Benzo(a ipyrene 252 22.347 22.347 (0.995) 1166506 80.0000 78.24^^86
Indeno (1,2,3-cd)pvrene1
276 25.052 25.052 (1.116) 828898 80.0000 76.94 0
87 Dibenzo(a,h)anthracene 278 25.035 25.035 (1.115) 1013423 80.0000 77.53 8370
88 Benzo(g i h,i}perylene 276 25.864 25.864 (1.152) 1066177 80.0000 77.78 9408
QC Flag Legend
M - Compound response manually integrated.
f|0
601
COMPUCHEM a division of Liberty Analytical Corp DATE 3 / \ > / 0.3- INITIAL TIME OF TUNE___ SH1FT/S(A) (B) 7 (C)GC/MS SEMIVOLATILE RUN LOG TIME TUNE EXPIRES o c> LINKER /METHOD
ltlftlpo
PREVENTIVE MAINTENANCE j\)c>4(L
CTtFILENAME ftT
EO
DATE TIME CLIENT ID# CASE/SDG# AMOUNTINJECTED
CHEMISTCOMMLNTS(F.TC.)/DISPO^jp^
1 t)Fo?o/ B 'll 1 OB DPtFF
— -7<xt SCD-Lcb
2 tA6n o > *» 5> 11 BoW/ / / 7^33 J. l
T / / 2$3l 6?cfiUo5 U 13
4z
l?7 1? Ooc& OJoOHUok \1
5 / U ZLSt-n&fo JI / / 6- it S'£ 7 o L(+ (,1 o 7
6 Utb-C?. -z
/ / 0121 ^ l o (AO V
7 i\ ik. S'? _ S7fl/v/ / / 0! r<? £2 £ r.' 7 <1 Un S"
1 [V Z tS7 -6sttL<r / / / <ytu 0 2 o 7 C 7/ r; /
9 1 -/Tj/Uz./ / i Oil)62 o 0 it. Q o L
Jio[aJ Cn t (/(ft! - TjTjAr- / / / 0 ) ^7 01 0 (s i,(' 1) i rfi c /
1 1 U/h/6tz
/ / DO 7 ZT/^ (C5 v'ak0 C1- S'
12 / it/ i c y o v W V - 6i u/T- C ttl /Z Ci: 22 cj •-(_
1 3 / 7<EL
/ / C flf 1 M i7-Fu2( _ I hi
14 / £i \ii - iFJu 5L / / o£nt U-l H'aJ 00 l C L 3 2.2
1 57
E 2 7 / > - ) ft it / / 0 ^ s( A A t~ 1/5
16 / E?u?_ i Ftc rL/ / 6 ) 5 1 C F A r
17 / F17 1/ - Ci xL / / o K___C Z A rui;
s ✓ \ r18 '/f f,) 2lo c - irAOu / / / etc S" Hu. C->uT. Ehl /A C7 22 n u Q/ 2
19 / 7} (D ? / nk. - 2liA^k lL / / a (fli H 0 - G- U'7- 11V>/ / 2 X
20 (.1 7 ti T2 - 1/ / >7
u----------oW
^ L 0 Z L U 1; £ U ? L S~? J21 ______L_ T
____ _ -22 / / ______ FoA .3-/Z-0 L
_________ _ --------------------
23 / /_
24_ . ~77./.
... .
Std. ID ft
Tuneloii
Analytical
-■. <7?S 7
Int. Std.
___y
Column Type
ftTx -b
SUPERVISOR APPROVAL .DATE___3A-^U
Lot ft5)1*5 5)^
I he presence ot the Chemist’s employee II) number, m signature. on this mn log attests that si net compliance with the me tin "l s )l li.ii
occurred Any SOP deviations require documentation by the responsible chemist together with the chemist s initials ;uui the initials o[ the
lab supervisor and a OA department representative, signilymg approval ot the deviation. (i l dee
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Name: COMPUCHEM
Lab Code: LIBRTY Case
Instrument ID: 5972HP64
Lab File ID: HG020313A64
Contract: 8270C
No.: SAS No.: SDG No.: QE1877
Calibration Date: 03/13/02 Time: 0956
Init. Calib. Date(s): 03/10/02 03/10/02
Init. Calib. Times: 1416 1723
GC Column RTX-5 ID: 0.32 (mm)
I COMPOUND |RRF OR
I AMOUNT
| Phenol__I| 1.4530000| Bis { 2 -ch'loroe thyl) etherj 0.9870000 j 2 -Chiorophenolj 1 . 3440000
j 1, 3 -Dichllorobenzenej 1 . 5440000
1,4 -Dichllorobenzenej 1.5580000
1 1, 2 - Dichllorobenzene'| 1 . 5340000
j 2 -Methvljphenolj 1.1720000
j 2,2'-oxybis(1 -Chloropropane) j1.8230000
| 4 - Me thyl phenolj 1.2740000
|N-Nitroso-di-N-propylamine__|0.8030000
IHexachloroethane 1 )|Nitrobenzene_____
IIsophorone________
i-Nitrophenol_______
:, 4-Dimethylphenol
Bis(2 -chjloroethoxy)methane_
2,4 -Diehlorophenol___________
j1,2,4-Trichlorobenzene_
!Naphthalene
4-Chloroaniline___________
Hexachlorobutadiene_____4 -Chloroj- 3 -methylphenol
2-Methylnaphthalene_____
!Hexachlorocyclopentadiene_I 2 , 4 , 6-Trichlorophenol_____
: 2,4 ,5-Trichlorophenol_____
!2-Chloronaphtha1ene________
' 2 - Nit roan lime_______________
Dime t hy1ph t h a1a t e___________
2,6 - Dim trotoluene_________
■ Acenaphthylene_______________
3-Nitroaniline
Acenaphthene__
I 2,4-Dinitrophenol
| 4 -Nitrophenoi_______
!2 , 4-Dinitrotoluene 1 |1Dibenzofuran________
IDiethylphthalate___
: 4 -Chloropheny 'Fluorene |
- pherivle t he r
: -Nitroani1ine I- Dim t ro - 2 - met nvlohenol
page 1 o
| 0.8060000
| 0.3400000
|0.6730000
|0.2150000 j0.3200000
0.4020000 |0.3310000
| 0 . 3860000 j 1 . 4460000
|0.4620000j0.2660000
j 0.3680000
j0.7240000
| 0.3960000
| 0.4070000
| 0 . 4320000
! 1 . 0260000
0.3670000
; 1 . 2540000 j0.3450000
j 2 .4090000 j 0 . 3650000
j 1 . 5590000
| 0.0610000 jo.2170000
jo.5000000
|l.6140000
j 1 . 4840000
■0.6930000
j1.3520000
10.3300000
0.1620000
|RRF80.000 | 1 1 1 1
1 OR | MIN | %D OR 1 MAX %D OR|CURV|
|AMOUNT | RRFi%DRIFT
1
%DRIFT TYPEj
1.4397790|0.01 j
-0.9120.00|AVRGj
0 . 9141643 j 0.01 j-7.38
5 0.0 0|AVRG j
j1.2938858 0.01 1 -3.73 | 50.00 jAVRG
j1.4731548I 0.01 j -4.59 j 50.00 jAVRG j
1.5080776 0.01 -3.2020.00 j AVRG j
|1.4652527 0.01 -4 . 48| 50.00 AVRG|
1.0669099| o. oi | -8.97 j 5 0.00 AVRG j
1.6512777 j 0.01 j-9.42
50.00|AVRG j
|1.1709711| 0.01 1 -8.09| 50.00|AVRG|
|0.7155306 0.05 1 -10.89|50.00 j AVRG j
jo.7663317 0.01 j -4.92 | 50.00 j AVRG j
0.3568400| 0.01 j 4.95 j 50.00jAVRGj
jo.6538337j 0.01 j -2.10 j 50.00 j AVRG j
0.2255032 j0.01 4.88 20.00 AVRG
|0.3211349 0.01 0.35 50.00 AVRG|0.4 046702 0.01 0.66 50.00|AVRG|
0.3299363 0.01 -0.32 20.00 AVRG
0.3884482 0.01 1 0.63 | 50.00 j AVRG j
| 1 . 4601014 j0.01 0.98 50.00 AVRG
|0.4794892 0.01 3.78 | 50.00 AVRG
0.2717179 0.012 . 15 j 20.00|AVRG
j 0.3443585 j 0.01 j -6 . 42 | 2 0.0 0 j AVRG j
0.6950783 j 0.01 1 -3.99 j50.00 AVRG
|0.45563790.05 j 15.06 | 50.00 AVRG
0.42597170.01 j
4.66 20.00 AVRG|0.4416700| 0.01 1
2 . 24 j 50.00 j AVRG j
|1.06427940 . 01 j 3 . 73 j 5 0.0 0|AVRG|
i0. 3600090 1 0.01 -1.90 50.00 AVRG! 1 . 2426044 | 0.01 -0.91 50.00 AVRGj 0 . 3 3 1 3 5 5 7 0.01 1 -3.95 5 0.0 0|AVRG|
j2 . 3562358 j 0 . 01 1 -2 . 19 j 50.00|AVRG|
j 0 . 32 34 94 6 0.01 -11.37 50.00 AVRG: 1 . 3979094 0.01 -10.33 20.00 AVRG| 0.0614193 0.05 0.69 50.00 AVRGj0.214318lj 0.05 j
-1 . 24 | 5 0.0 0 j AVRG|
| 0.4 516069 0.01-9.68 j 5 0.00 AVRG j
j 1 . 5369302| 0.01-4.78 j 5 0.00 AVRG j
j 1 . 4003320 0.01-5.64 j 5 0.00 AVRG j
0 . 6 6 8 9 7 9 9 | 0.01 j -3 . 47 j 5 0.0 0 j AVP.G 1
jl.7331799! 0.01 -6.42 5 0.0 0 j AVRG j
i0.314 33 75 ! 0.01 - 1 7 . 2 8 | 50.00 AVRG
1 0. 1678505 I
! j
0.01 J
13.61
1
5 0.0 0|AVRG
1 !
FORM VII SV60/'
FORM 7BSEMIVOLATILE CALIBRATION VERIFICATION SUMMARY
Lab Name: COMPUCHEM
Lab Code: LIBRTY Case
Instrument ID: 5972HP64
Lab File ID: HG020313A64
GC Column: RTX-5 ID:
Contract: 8270C
No.: SAS No.: SDG No.: QE1877
Calibration Date: 03/13/02 Time: 0956
Init. Calib. Date(s): 03/10/02 03/10/02
Init. Calib. Times: 1416 1723
0.32 (mm)
] 1
j COMPOUND1 1
i 1 _
|___ |RRF80.000]|RRF OR | OR j
|AMOUNT jAMOUNT |
1 1 1
1
MIN |
RRF |
1
1
%D OR 1
%DRIFT I
|
1
MAX %D OR|CURV
%DRIFT |TYPE
|1 iIN-Nitrosodiphenylamine
I 11 0.4360000 0.4140995|
----------- |0.01 I
---------------- |-5.02|
--------------------- |----------20.00|AVRG
!4-Bromophenyl-phenylether
|Hexachlorobenzene
|0.212000010.2223332 |
0.2610000|0.2485915 |
0.01 1
0.01 1
4.87 j
-4.75
50.00|AVRG 5 0.0 0 j AVRG
| Pentachllorophenol |0.1740000|0.1716925[ 0.05 1 -1.33| 2 0.0 0|AVRG
iPhenanthrenej1.4880000|1.3325226 | 0.01 | -10.45| 50.00 jAVRG
|Anthracene |1.5130000|1.4127003 | 0.01 I -6.63 | 50.00|AVRG
1Carbazole 0.9960000 0.8634642 | 0.01 I -13.31j 5 0.0 0 j AVRG
|Di-n-butiylphchalate 1.4890000|1.3337870 | 0.01 1 -10.42| 5 0.0 0|AVRGI Fluorantlhene 1.7160000 1.5570159| 0.01 - 9.2 6 | 2 0.0 0 j AVRG
|Pyrene|1.9180000|1.9991696 j 0.01 1 4.23] 5 0.0 0 j AVRG
[Butylberizvlphthalate j 0.7700000 j 0.7563360 j0.01
-1 . 77 j 50.00 jAVRG
|3,3'-Dichlorobenzidine |0.5420000|0.5467303 | 0.010.87 j 50.00 jAVRG
Mpis (2 - et'hylhexyl) Phthalate kenzo (a ) ^anthracene
|1.1480000|1.0855520|
|1.7590000 1.7345633
0.01 j
0.01 j-5.44|
-1.39
50.00 jAVRG
5 0.0 0|AVRGChrysene 1.6580000 1.6363928 | 0.01 -1.301 5 0.0 0 j AVRG
j Di-n-oct /lphthalate 2.2640000|2.1436980 0.01 1 -5.31 20.00 AVRG|Benzo(b) fluoranchene 2.1450000 2.1523610 0.01 0.341 5 0.0 0|AVRG
!Benzo (k} fluoranthene |1.9380000|1.9126477 | o. oi! -1.31 | 5 0.0 0|AVRG
t Benzo(a) pvrene i1.7000000|1.7032079 | 0.01 1 0.19 j 2 0.0 0 j AVRG
!Indeno (1 ,2, 3 -cd)pyrene j 1.2280000 | 1 . 1778233 0 . 01 j-4.09 50.00 AVRG
!Dibenzo( a,h)anthracene |1.4900000|1.4512775| 0.01 1 -2.60 j 50.00 jAVRG
1Benzo(g, i,i)perylene |1.5630000 1 . 5155586 0.01 1 -3.04 | 50.00|AVRGj 1
i2 -Fluorophenol |1.2980000|1.3243293 | 0.01] 2.03 | 50.00|AVRG
!Phenol-d5 1.6910000 1.6025778 | 0.01 -5.23 5 0.0 0|AVRG
iMitrobenzene-d5 | 0.4330000|0.44 3 7773 1 0.01 1 2.49] 5 0.0 0 j AVRG
:2 -Fluorobiphenvl | 1 . 3330000 | 1.3594772 0.01 1 1.99] 50.00|AVRG
12,4,6-Tribromophenol j 0.4030000|0. 3871519 j 0.01 -3 . 93| 50.00 AVRGTerpheny 1 - d 14 i 1 . 0590 000|1. 1633097| 0.01 1 9.85 | 5 0.0 0|AVRG
! ! i 1 I
page 2 of 2FORM VII SV
C:<106)
Data Filet /chem/5972hp64.i/DF020313A64.b/HG020313Ai't.d
Date t 13-MAR-2002 09:56
Client ID: SSTD080
Sample Info: SSTD080:917
Volume Injected (uL>; 1.0
Column phase: RTX-5
Instrument: 5972hp64,i
Operator; 917
Column diameter: 0.32
oCD
z'4:
5.2-
5.0- :
4.8-
4.6^
4.4^
4.2- j
4.0-
3.8-
3.6-
3.4- :
3.2-
3.0-
2.8- |
2.6-
^ 2.4-;
2.2- ;
2.0:
1.3:
1.6-
1.4-
1.2- ;
l.o:
0.8-
0.6-
---0T4~-
0.2-
/chem/5972hp64.iXDF020313A64,b/HG020313A64,d (Part 1 of 2)
+00*0
I4!
.-Jr 1 brorfopheno 1
Data File: /chem/5972hp64.i/DF020313A64.b/HG020313ft64.d
Date : 13-MAR-2002 09:56
Client ID: SSTD080
Sample Info: SSTD080:917
Volume Injected (uL): 1.0
Column phase: RTX-5
Instrument: 5972hp64,i
Operator: 917
Column diameter: 0,32
CO
Data File: /chem/5972hp64.i/DF020313A64.b/HG020313A64.dReport Date: 13-Mar-2030 10:27
CompuChem
Data file Lab Smp jId
Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date Als bottle Dil Factior Integrator
Target Version:
Semivolatile Report SW-846 Method 8270C /chem/5972hp64.i/DF020313A64.b/HG020313A64.d
SSTD08013-MAR-2002 09:56 917SSTD080:917
Client Smp ID: SSTD080
Inst ID: 5972hp64.i
/chem/5972hp64.i/DF020313A64 13-Mar-2030 10:27 mikhael 10-MAR-2002 17 2
1.00000 HP RTE
23
Processing Host:3.50einstein
, b/8270Cv6.m Quant Type: ISTD Cal File: HL020310A64.d Continuing Calibration Sample
Compound Sublist: all.sub
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description,
DF 1.00000 Dilution Factorvt 1000.00000 Volume of final extract (uL)
W Vo 1000.00000 Volume of sample extracted (mL)Vi 1.00000 Volume injected (uL)
Cpnd Var Lable Local Compound Variable
AMOUNTS
QUANT SIG CAL-AMT ON -COL
Co:.'pounds MASS RT EXP RT REL RT RESPONSE ( NG) ( NG)
* 11.4-Dich lorober.ee ne-d4 1 52 3.240 9.240 ( 1 . 000 290555 40.0000
* 2 Naphthalene-d3 136 10.132 10.132 (1 . 000 1028482 40.0000
* 3 Acenaphchene-dl9 164 13.139 13.139 (1.000) 667461 40.0000
* 4 Phenar.ch rene-dlO 189 15.470 15.470 f 1 . C 0 C ) 1280056 40.0000
• 5 Chrysene 240 19.947 19.947 ( 1 . 000) 980906 40.0000
• • Pervlene -d ■ 2 [
264 22.4 1 3 2 2 .4 1 3 (1 . COO 1 547673 40.0000
t 7 2 -F1uorophenoi 112 6.450 6.450 (0.783) 769581 80.0000 81.60
$ 8 Phenol-d5 99 7.75C 7.750 (0.941) 931274 80.0000' 75 80
5 9 Nicroben zene dS 82 9 . 085 ' 5.035 (0 . 997) 912834 80.0000 82 01
2 10 2 - Fluorob; phenyl 172 11.856 11.355 (0.902) 1814796 80.0000 81 .61
1 : 2,4 . 6 - T rl .ibromooneno* 330 14.457 14.457 (1. 100) 516831 80.0000 76 91
? 12 Terpheny 1 - d 14 244 17.835 17.835 (0.894) 2282195 80.0000 87.89
' I 3 N - N i L r o s odimer.ny1 ami ne 42 4.355 4.355 (0.528) 280370 80.0000 80 . 85
14 Pyridine 7 5 4.335 4 .333 .(0 . 526) 508730 80.0000 84.61
SIMILARITY
i ’
86 90
9402
0 L
Data File: /chem/5972hp64.i/DF020313A64.b/HG020313A64.dReport Date: 13-Mar-2030 10:27
AMOUNTS
QUANT SIG CAL-AMT ON-COL
Compounds MASS RT EXP RT REL RT RESPONSE l NG) ( NG) SIMILARITY
115 Benzaldehyde 77 7.632 7.632 (0.926) 471878 80.0000 74.16 9667
16 Phenol 94 7.767 7.767 (0.943) 836670 80.0000 79.25
17 Bis(2-chloroethyl)ether 93 7.886 7 . 886 (0.957) 531230 80.0000 74.06
18 2-Chlorophenol 128 7 . 987 7.987 (0.969) 751890 80.0000 77.01 9296
19 1,3- Dichlorobenzene 146 8 .190 8.190 (0.994) 856065 80.0000 76 - 32
20 1,4-DIl hlorobenzene 146 8.274 8.274 (1.004) 876359 80.0000 77.43
21 Benzyl alcohol 108 8.460 8.460 (1.027) 444713 80.0000 77.28
22 1,2 -Dichlorobenzene 146 8.544 8.544 (1.037) 851473 80.0000 76.43
23 2-Meth> lphenol 108 8.612 8.612 (1.045) 619992 80.0000 72.82
24 2,2'-oxybis(1-Chloropropane) 45 8 . 663 8.663 (1.051) 959574 80.0000 72.44 8969
25 Acetophenone 105 8 . 848 8 848 (1.074) 883268 80.0000 71.80 9434
26 3-Methylphenol 108 - 8 . 815 ^ 8.815 (1.070) 680463 80.0000 73-53
27 4-Methylphenol 108 ' 8.815 / 8.815 (1.070) 680463 80.0000 73.53
28 N-Nitroso-di-N-propylamine 70 8 . 865 8 865 (1.076) 415802 80.0000 71.30 8009
29 Hexachloroethane 117 9.000 9 000 (1.092) 445323 80.0000 76.03 9256
30 Nitrobenzene 77 9 . 119 9.119 (0.900) 734007 80.0000 84.00 9419
31 Isophorone 82 9.440-/ 9.440 (0.932) 1355300 80.0000 78.33 9229
32 2-Nitrophenol 139 9.592 9.592 (0.947) 463852 80.0000 84.08 8460
33 2,4-Dimethylphenol 122 9 . 592 9.592 (0.947) 660563 80.0000 80.34 8463
34 Bis(2 -chloroethoxy)methane 93 9.744 9.744 (0.962) 832392 80.0000 80.60 9289
3 5 2,4 -Dichlorophenol 162 9 . 913 9 . 913 (0.978) 678667 80.0000 ‘ 79.69
3 6 1,2,4 -Tnchlorobenzene 180 10.065 10.065 (0.993) 799024 80.0000 80.4G
^^7 Naphthalene 128 10.166 10.166 (1.003) 3003376 80.0000 80.80 9299
8 <1 -Chloroani 1 me 127 10.250 10.250 (1.012) 986292 80.0000 82.97 7628|
39 Hexachlorobutadiene 225 10.402 10.402 (1.027) 558914 80.0000 81.72 9248
40 Caprolactam 113 10.723 10.723 (1.058) 210501 80.0000. 72.25 9645
41 4-Chloro-3-methylpheno1 107 10.926 10.926 (1.078) 708333 80.0000 74.86 949042 2-MethyJnaphthalene
142 li 196 11.196 (1.105) 1429751 80.0000 76.744 3 1-MethyJnaphthalene
142 11 382 11 . 382 (1.123) 1360957 80.0000 76.55
4 4 Hexach lorocvc loper.tadiene 237 11.585 11.585 (0.882' 608241 80.0000 92.00 9538
45 2,4,6-* "i: ch 1 cropheno 1 196 11.737 11 . 737 (0.893) 568639 80.0000 83.71
46 2,4 , 5 - 7r,i ch lorophenoi 196 11 805 11 . 805 (0.898) 589595 80.0000 81.82
4 7 1,1'- B lpheny1 154 12.041 12.041 (0.916) 1643165 80.0000 92.18 7549
4 8 2 -Chloronaphthalene 162 12.092 12.092 (0.920) 1420730 80.0000 82.96
4 9 2 - Nit roam line 65 12 328 12 . 328 (0.938) 480584 80.0000 78.40 9590
SC Dimethy1 phtha late 163 12 666 12 . 6 6 6 (0.964) 1658780 80.0000 79.27 8945
51 2 , 6 • Dmi t rotoluer.e 165 12.818 12.818 (0.976) 442334 80.0000 76.83 9409
52 Acenapht hylene 152 12 .885 12 . 886 (0.981) 3145391 80.0000 ■ 78.25 9930
5 5 3 - N : t roam 1 i ne 138 13.071 13.071 (0.995) 431840 600.000 83.10 9247
54 Acenapnt hene 164 13 207 13.207 (1.005) 1866100 80.0000 71.73 9079
55 2,4 -Dir.i tropheno1 134 13.240 13 .240 (1.008) 409950 400.000 402.6
5 6 4 -N11rophenol 109 1 3 308 1 3 3 08 (1.013) 286098 80 . 0000 78.92 0 (M) |
57 2,4 - Dinitrotoluene 165 13 .494 13 .4 94 (1.027) 602860 80.0000 72.24 8941
5S D:ber.zot 1u ran 168 13.460 13.460 (1.024) 2051682 80.0000 76.17 9239
59 Diethylphthaiace 14 9 13.343 13.843 (1.054) 1869334 80.0000 75.49 9737
60 4 • Chioropr.eny 1 -pher.yiether 204 1 3 934 13.984 (1.064 ) 093036 80.0000 77.19 7526
Fluor-- 16 6 14.034 14.034 (1.066) 2313660 80.0000 74 . 86 7689
Data File: /chem/5972hp64.i/DF020313A64.b/HG020313A64.dReport Date: 13-Mar-2030 10:27
Compounds
62 4-Nitroaniline63 4,6-Dinitro-2 -methylphenol64 N-Nitrosodiphenylamine 6 5 1,2-Diphenylhydrazine66 4-Bromophenyl-phenylether67 Hexachlorobenzene68 Atrazine69 Pentachlcrophenol70 Phenanthrene71 Anthracene72 Carbazole73 Di-n-butylphchalace74 Fluoranthene75 Benzidine76 Pyrene j77 Butylbenzylphthalate78 3,3'-Dichlorobenzidine79 bis(2-ethylhexyl)Phthalate\80 Benzo(a)anthracene81 ChryseneI82 Di-n-octylpnthalateI83 Benzo(b)fluoranthene
I84 Benzo(k)fluoranthene
:|5 Benzo(a)pyrene
86 Indeno(1,2,3-cd)pyreneI
87 Dibenzofa,h)anthracene
88 Benzo(g J h,i)perylene
QC Flag Legend
AMOUNTS
QUANT SIG CAL-AMT ON-COL
MASS RT EXP RT REL RT RESPONSE ( NG) ( NG) SIMILARITY
138 14.102 14.102 (1.0731 419616 80.0000 66.14 9496
198 14 . 169 14.169 (0.916) 429716 80.0000 82.92 8104
169 14.136 14.186 (0.917) 1060141 80.0000 76.04 9298
77 14 .237 14.237 (1.084) 1790238 80.0000 71.57 9429
249 14.761 14.761 (0.954) 569198 80.0000 93.82 7468(H)
284 15.014 15.014 (0.971) 636422 80.0000 76.23 9617
200 14.997 14.9? 7 (0.969) 472577 80.0000 74.23 8405
266 15.267 15.267 (0.987) 439552 80.0000 79.10 8305
178 15.504 15.504 (1.002) 3411407 80.0000 71.62
178 15.571 15.571 (1.007) 3616671 80.0000 74.71
167 15.774 15.774 (1.020) 2210565 80.0000 69.38 9341
149 16.213 ■ 16.213 (1.048) 3414644 80.0000 71.68 9498
202 17.261 17.261 (1.116) 3986135 80.0000 72.59
184 17.413 17.413 (0.873) 2006051 160.000 142.1 8436
202 17.666 17.666 (0.886) 3921995 80.0000 83.37
149 18.798 18.798 (0.942) 1483789 80.0000 78.60 9393
252 19 . 828 19.828 (0.994) 1072582 80.0000 80.67 7550
149 19.778 19.778 (0.992) 2129649 80.0000 75.65 9010
228 19 . 913 19.913 (0.998) 3402887 80.0000 78 .89
228 19.997 19.997 (1.003) 3210295 80.0000 78.94
149 20.741 20.741 (0.925) 2348091 80.0000 - 75.75
252 21.686 21.686 (0.968) 2357580 80.0000 80.26
2 52 21 . 720 21.720 (0.969} 2095011 80.0000 78.93 ■
252 22.311 22.311 (0.995) 1865602 80.0000 80.16
276 24.997 24.997 (1.115) 1290124 80.0000 76.72 0 (M) I
276 24.960 24.980 11.115) 1589651 80.0000. 77.91 6391
276 . 25.808 25.808 (1-151) 1660061 80.0000 77.59 9184
M - Compound response manually integrated.H - Operator selected an alternate compound hit
^•^6 1 J
? tl - oLj ^
Round: 2.4J6-Tribromophenol Number: 118-79-6
Data File: /chern/5972hp64. i /DF020313A64. b/HG020313A64. dInjection Date: 13-MAR-2002 09:56Instrument: 5972hpb4.i
^ent SamplejlD; 55TDOBO
13.95 14.00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.85 14.90
__ « _____ ____ _______ Min ______ ________________________ ________________________
JPfmpound: 4-Ni trophenol CPS Number: fl00-02-7
Data Fiio; /cherri/5972hpb4.1/DF020313A64. b/HG0203l 3P64 . dInjection Date: 13-MPR-2002 09:56Instrument: 5972hp64.1
Mkient Sample ID: SSTDOSO
Ion 109.00: Area: 286098 Height: 142857
12.9 13.0 13.1 13.2 13.3
Ion 65.00: Area:
13.4
Height: 0
13.5 13.6 13.7 13,8
3.0-
I i
! \
12.85 12.90 12.95 13.00 13.05 13.10 13.15 13.20 13.25 13.30 13.35 13.40 13.45 13.50 13.55 13,60 13.65 13.70 13.75M i n
5.1-
4.0-
3.9-
3.6-
3.3-'
3.0-
. . d '
1.5-
1 .2- 0.9-
0.6-
0.3-
0.0—-12.SO 12.35
Ion 139.00: Area: 0 Height: 0
61;j
12.90 .00 13.05 13.10 13.15 13.20 13.25 13.30 13.35 13.40 13.45 13.50 13.55 13.60 13.65 13.70 13.75
Data File: /chem/5972hp64. j. /DFG20313A64. b/HG0203l3A64. dInjection Date: 13-MAR-2002 09:56Instrument: 5972hp64.i
lent Sample ID: SSTD08U
pound: 4-Bromopheny1-phenylether "S Number: l;0l-55-3
2. u-
1.8-
1.6
1.0-
0.8-
Ion 141.00: Area: 117975 Height: 117975
• 61U
i j .= 1-4.0 i4.a 14.9 15.0 15.1 15.2Min
Data File: /cnem/5972hp64.1 /DF020313A64. b/HG020313A64. dInjection Date: 13-MAR-2002 09:5bInstrument: 5972hp64.i
lent Sample ID: SSTD080
pound: Indeno<1.2.3-cd)pyrene S Number: i93-39-5
if1;b
3. O'
2.0
2.6
2.4
c . e.
2.0
1.8
1.6
1.4
1.2
1.0-
0.8-
0.6-
0.4-
0.2-
0.0----24.5
Ion 276.00: Area: 1290124 Height: 310642.ft
2-4.6 2-4.; 24.8 24.9 25.0
_______ Min25.1 25.2 25.3 25.4 25.5
1.0-
0.9;
C;
0.6-
0.5-'
0.4-
0.3-
0.2-
0.1-'
0.0----24.5
Ion 138.00: Area: 0 Height: 0
co \ m/?/ i
/ I
24.7 24.8 24.9 25.0 25.1 25.2 25.3 25.4 25.5
950-
900-.
850-
800-
750-
700-
650-
600-
550-
500-
450-
4 00-
350- 300-'
50-
00-
150-
1 CO-
50-
n -•---24.5
Ion 227.00: Area: Heignt: 0
61774.6 24.: 74.6 24.9 25.0 25.1 25.2
_____________Min25.3 25.4 25.5
COMPUCHEM a division of Liberty Analytical Corp DATE 3 / (l / 0 ? INITIAL TIME OE TUNE___ (iRjj.____ SHIIT/S(A) ...(C)
SEMIVOLATILE RUN LOG TIME TIJNE EXPIRES___ ? j_J>'L LINKER /METI101) M n ^COMPUCHEM LOGBOOK 4 YVY 4 (5972hp64) "
rn m _______ ______________»>1
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INJECTEDCHEMIST COMMHN TS(1:1C 1/i JISp^CPl’KlN
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20 / 7z_______£A-S- ) i vV
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23
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-std-i p-ff "7'p-3-b—
Lot It T 2 £ ^ S'
Analytical Int. Std.
-(rrM------licr
-iVZii!_____CzsZa
Column Type SUPERVISOR APPROVAL.
/ 7// ?7?:, date: i7/T/°z
4^7
c * >2. ^ w-1 he presence ol ihe Chemist’s employee 11) number, or signature, on this urn toy; attests that slnet compliance with the method\ S( )i
occurred. Any SOI1 deviations require documentation b\ the responsible chemist together with the chemi.-d'^mmtials ami the initials i lab supcrvisor^^^kOA department representative, siumlvmp appioval of the deviation I I/2MU .
4. Raw QC Data
a. DFTPP Data
b. Blank Data
c. Laboratory Control Sample Data
d. Matrix Spike Data
e. Matrix Spike Duplicate Data
619
a. DFTPP Data
For each 12-hour period, per instrument utilized, include:
- Bar Graph spectrum and Tabulated Relative Abundances
- Mass listing
- Reconstructed ion chromatogram
- Tailing Factors for Benzidine and Pentachlorophenol
- Determination of DDT Breakdown
62 G
Data F11*: /chem/5972hp60*i/DF020303A60 *b/BF020303A60*d
Date : 03rMAR-2002 13:38
[Client ID: DFTPP
Sample Info: DFTFF';231 T1
Volume Injected <uL): 2.0
Column phase: JSJ-J DBS*625
Instrument: 5972hp60 *i
Operator: 2319
Column diameter: 0*32
Data F1 le: /chem/5972hp6o. i/DF020303A60.b/DF026303A60*d
Date : 03-MAR-2002 13:33I
Client ID: DFTF'P
Sample Info: DFTPP:2319
Volume Injected CuL>: 2*0
Column pfjiase: J?.-W BB5.625
Instrument: 5972hp60.i
Operator: 2313
Column diameter: 0*32
f
Data File: DF020303A60*d
Spectrum: Avg. Scans 122-124 < 7*11), Background Scan 113
Location of Maximum: 133*00
Humber of points: 100
m/2 Y m/z Y m/z Y
1
m/z Y
11 1
78. 00 403 1 105*00 304 181.00 274 1 255.00 17640 1
39*00 1834 107.00 5153 135.00 768 256.00 2522 1
4?. 00 287 103.00 754 186.00 4542 258.00 1376
50.00 7943 110*00 7746 137.00 1417 265.00 510
51.00 21313 111.00 1365 139.00 259 273.00 469
54.00 1107 117.00 9688 192.00 353 274.00 1565
53.00 452 113.00 358 193.00 236 275.00 7623 1
57*00 993 122.00 236 196.00 787 276.00 829 1
33.00 422 123.00 620 198.00 32408 277.00 771 1
39 * oo 18o53 127*00 11339 199.00 2222 1 296.00 3149 1
73.00 274 123.00 957 204.00 1296 1 297,00 332 1
74.00 2527 129.00 6634 205.00 2222 1 303.00 247 1
75.00 3120 130.00 537 206*00 3019 1 315.00 291 1
73.00 1132 135.00 294 207.00 1136 1 323.00 607 1
77 O'.' 17152 141.00 999 203.00 230 334.00 496 1
1
73. Ov 1139 147.00 533 217.00 2576 365.00 1214 1
79.00 1332 143.00 1924 221.00 934 1 372.00 352
30.00 1207 15A.00 700 223.00 393 423.00 1140 1
31*o.. 1402 131.00 263 224.00 4694 441.00 432
33.0- 333 165.00 236 225.00 1237 442.00 23912
91. ■11 ■ 304 167.00 2707 237.0o 2661 443.00 4397 1
-<2. 7945 163.00 1343 223.00 230 444.00 335 1
93."-' “o 175.00 742 229.00 ■ c:r, 1
99. 1073 177.00 244 1 244.00 3637 1 1
11 11.1 1' 040 179..-,0 1639 1 245.1"'' 367 1 I
1 '
v ■■4. 7,,. 180.00 879 1 246.00 9 1 1
Dat* F i 1 o; /■:tern•'0972hp60.1 ,-'DF020303A60.b/DF020303A60. d
Date : 03-NAR-2002 13:38
Client ID: DFTF’P Instrument: 5972hp'60.i
Sample Info: DFTPP:2319
.Volume Injected CuL); 2.0 Operator: 2318
Column phase: J8.U DB5.625 Column diameter: 0.32
/chem/5972hp60.i/DF0203O3A60.b/DF020303A60.d
2.0-
1.9-
1.8-
1.7-
1.6-
1.5-
1.4-
1.3-
1.2-
1.1-
■r>
CvJ
CO
u.i 11 .-i L . 7 1 1 £.
TAILING FACTOR and DEGRADATION SUMMARY RESULTS
EjECAFLUOROTRIPHENYLPHOSPHINE Ion Abundance/Ratio Criteria Chart
Kon 1 Abundance Criteria | Base Peak Other | Test
n.98 Ba^se Peak, 100% relative abundance 100.00 PASSSI 3|o - 80% of mass 198 67.33 PASS68 Less than 2% of mass 69 0.00 ( 0.00) PASS69 Ma ss 69 relative abundance 57.56 PASS70 Le ss than 2% of mass 69 0.00 ( 0.00) PASS
127 2 5 - 75% of mass 198 36.68 PASS197 0 - 1% of mass 198 0.00 PASS199 5 - 9% of mass 198 6.86 PASS275 1 0 - 30% of mass 198 23.52 PASS365 Greater than 0.75% of mass 198 3.75 PASS441 Present, but less than mass 443 1.33 ( 9.82) PASS442 4p - 110 % of mass 198 73.78 PASS443 15 - 24% of mass 442
l13.57 ( 18.39) PASS
TAILING ANALYSIS SUMMARY
Compound1
Tail Factor Max Allowed Test |
Pentachlorophenol 1.8 5.0 PASSBenzidine 2.0 3.0 PASS
DDT DEGRADATION BREAKDOWN ANALYSIS SUMMARY
^ Compound Response %Breakdown Max Allowed Test |
4,4-DpT 527898 N/A4,4-DpE 0 0.0 20 . 0 PASS4,4 -DDD 17289 3 . 2 20.0 PASS
4,4-DDD - DDE 17289 3 . 2 20 . 0 PASS
Tuning Sample, /chem/5572hp60 . 1 ,/DFO 2 0 3 0 3 A6 Q . b/DF020303A60 . d/DFO 2 0 3 0 3 A6 0 .d
** + PASSED ***
62
TAILING FACTOR and DEGRADATION SAMPLE AND GRAPHIC REPORT
ort Date: 03/04/2030 12:51
Analyzed: /chem/5972hp60.i/DFO20303A60.b/DF020303A60.d/DF020303A60.dDatafileMethod Used: /chem/5972hp60.i/DFQ20303A60.b/dftpp8270C.m Inst: 5972hp60Injection Date: 03-MAR-2002 13:38 Sample Info: DFTPP DFTPP:2319 Misc Info:
Operator: 2319
1 . 1
HP MS DFOiOSOS^bO.d_
r- I
't.t
iC*D*V.'•jt.cy-
i !'
cr.t Z( .r.j-.jr.ro 'X> cerooro . -Irl
EooroCD O- c_ —Or- cto -r—C-J'.D COO c • _■
-L.'< DTT11 ;>.a ii. 11.6 12.?’ 12.4
03/04/2030 12:51Report Date:
Datafilem
Sam
Analyzed: /'chem/5972hp60 . i/DF020303A60 .b/DF020303A60 .d/DF020303A60 .dthod Used: /chem/5972hp60.i/DF020303A60.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972haction Date: 03-MAR-2002 13:38 ODeratof:
ample Info: DFTPP DFTPP-.2319 Misc Info:
h'F Mj DF020o03h60 . a. Ion 266.00
Ion 266
Tailinq Factor =■ 1.83899
! j b ! 3.4
!1 2.8
I
i 2.4
'm onI <
•2 1.0 !- i-6-
!:- 1.4.
) 1.2-
i 1.0 j 0.0
j 0.6- j 0.4-
I _1_ 0.0
HP H5 DF020303A60._d. Ion 266.00
inkD
6.35 6J40 6.45 6.50 .55 6.60 6.65 6.70 6.75 6.t~ 1 mj (Min)_________
hF- m0 DFu2'j31.,3^6i
j 6.35 6.90 6.95*
____________________ i—. d, jean mq; h,. 65‘J min
6.40 6.50 6.60 6.70 6.60 6.90
Timp (Min)
r'entachlorccnenoi
Exp. R7 ’ound RT
iass
ailma
6.639
t a c t o r
Factor
Ratio
10 0. 0 0
?e n t a e h1o rophe no 1 OK
: M a x. i m u m A11 o w e d = ^
62
Reoort Date: 03/04/2030 12:51
Datafile] Analyzed: /chem/5972hp60.1/DF020303A60.b/DF020303A60.d/DF020303A60
^ifcthod Uised: /chem/5 972hp6 0 . i/DF0203 03A6 0 . b/df tpp8270C . m/BrkDwnTF . m Inst:(■jection Date: 03-MAR-2002 13:38 Operator:
sample I Misc Inf
nfo: DFTPP DFTPP:2 319O :
if MS DF020303Ht,u.a„ Ion 184.00 HP MS DF020303h60^ Ion 184.00
:on 184
Tailing Factor = 2.03209
i. i-
1 . o-'
o. 9-;
0.8-
0.7-
0.6-
0.5-
0.4-
•0.3
0.2-
0 1 -
0.08.30 8.35 8.40 8.45T i m*= i M i n )
8.50 8.55 3.60 3.65 !.]
8.10 8.20 6.30 8.40 8.50Tim*? (Min )
HP MS DF020.: 034P0. cl. Scan 197 8.b59 min.184-
160 190 200
.'UP1
_ea Ratio
:enziame OK
.d5 972h
. 60
628
Report: Dane: 03/04/2030 12:51
matafile Analyzed: /chem/5972hp6C.1/DFC20303A60.b/DF020303A60.d/DF020303A60.d
hod Used: /chem/5 972hp6 0 . i/'DF02 03 03A6 0 . b/df tpp8270C :m/BrkDwnTF . m Inst: r3"A2hection Date: 03-MAR-2002 13:38
Sample Info: DFTPP DFTPP:2319 Misc Info:
Operator:
HP M5 DF0-C'30i-fHDL-. C. Ion 235.00
Ion 235
IS o.2i
3 IS 354 tc:
Area Ratio
>7305 100.00
62
pore Date: 03/04/2030 12:51
Datafile Analyzed: /chem/5972hp60.1/DF020303A6C' .b/DF020303A60 . d/DF020303A60 ^k:hod Used: /chem/5 972hp6 0 . i/DF0203 03A6 0 . b/df tpp8270C . m/BrkDwnTF . m Inst: ^^iection Date: 03-MAR-2002 13:38 Operator:
DFTPP:2 319Sample Info: DFTPP Mi sc Info:
HP MS Dr,i- '.'yj JiHhl.l . Inn 235.0C
ion 1 ^ S
X'
0.5
i'1 _ 4
a.o2 0.35 D.tfo 3.Hi a.H4
_ __________ ______ T i mo ( M^_njHP MS 07020303960.d. Scan
H' 9.00 9.0j> 9.06 9.09 9.12 9.15
32: 3.951 mm.
9.16 9.21
263
Vi 231
317
1
630
.d5 9 7 2 h
>por: Jfi I 03/Q4/2C30 12:51
Uacaflie Analyzed: /chem/5972hp60.1/DF020303A60.b/DF020303A60.d/DF020303A60^^khod Used: /chem/5972hp60.i/DF02Q303A60.b/dftpp8270C.m/BrkDwnTF.m Inst: ^BFjection Date: 03-MAR-2002 13:38 Operator:
Sample Info: DFTPP DFTPP:2319 Misc Info:
HP M5 DF020303H60.d. Ion 246.00
Ion 246
4-:- P.4 3 3.4b 3.49 3.52
' ' ' hp"mV d’fozo:
.58 6.61 S.b4 8.67 8.70 8.73 8.76 8.79 8.52 3.35•U n> ^rear. 210: 3.578 min.
■'"20?
r, q q n
Area Ratio
0 0.00
210
631
.d5972h
a.83 •
a Q D:
I or. 235.
5.0-
4-
6-
1.
? . 30 0 . J’j 9.50 9l m ■=■ -Mm'1
HP Mf. jF 0 :-h60,J, Ion 435.00
ccl
Compound: 4,4'-DDT
Quant Mass: 235
RT: 9.340
Area: 527898
Compound: 4,4'-DDD
Quant Mass: 235
RT: 8.951
Area: 17289
V . 1
I
90' M :
9 . i 0 9
JP
Compound: 4,4'-DDE
Quant Mass: 245
RT:. 0.000
Area: 0
.onoounc
T
riON BREAKDOWN ANALYSIS SUMMARY
Response %3reakdown Max Allowed Test |
R27398 N/A0 !
0 . 0 20.0 PASS17289! 3 . 2 20 . 0 PASS
; 17239 i ■Q n 20.0 PASS
PASSED *** DDT BREAKDOWN TEST 632:
Data Filet /chem/5972hp60.i/DF020312A60.b/DF020312A60,d
Date : 12-MAR-2002 08:51 l
Client i'd: DFTPP
Sample Info: DFTPP;917
Volume Injected <uL): 2*0I
Column phase: J&U DB5.625
1 Decaflucrotriphenylphosphine
Instrument: 5972hp60.i
Operator: 917
Column diameter: 0*32
4*8
4*6
4.4
4.2
4.0
3.8
3.6
3.4
3.2
3.0
2.8-
2.6-
2.4-
2.2-
2.0
1.8
1.6
1.4 ! 1.2'
1.0-
0.8-
O.b-
0.4-
0.2-
o.oJ
Avg. Sc-ans 118-120 < 7.04), Background Scan 116. 198''"
,-51
77
,t l:
44N/255
A17
167\
I i II I I il, I ill I. .i ljl.il I , J.lli J ,i,l I
/275
224
il li.i , I II I....
X323
j, I,, I.
365^
40O^ .
60 80 100 120 140 160 180 200 220 240 260 280 300 320 340m/z
360 380 400 420 440
X RELATIVE
m/e ION ABUNDANCE CRITERIA ABUNDANCE
193 1 Base Peak, 100X relative abundance 1 100.00 1
1 51 1 30.00 - 30.00* of mass 198 1 63.46 1
6 8 1 Less than 2.00X of mass 69 1 0.00 < 0.00) 1
1 69 1 Mass 69 relative abundance 1 43.77 1
70 1 Less than 2.00X of mass 69 1 0.00 ( 0.00) 1
1 127 1 25.00 - 75.00* of mass 198 1 30.61 1
l 197 1 Less than 1.00X of mass 193 t 0,00 1
1 199 1 5.00 - 9.00* of mass 198 1 6.93 1
1 275 1 10.00 - 30.00X of mass 198 1 27.25 1
I 365 1 Greater than 0.75X of mass 193 1 4.72 1
l 441 I Present, but less than mass 443 1 10.63 i
1 442 1 40.00 - 110.00X of mass 193 1 66.87 !
1 443 1 15.00 - 24.00* of mass 442 1 12.61 ( 13.85) 1
633
Data Fi le: /chem25972hp60« i/DF020312A60.b/’DF020312A60.d
Date : 12-MAR-2002 08:51
Client ID: DFTPP Instrument: 5972hp60.i
Sample Info: DFTPP:917
Volume Injected CuL): 2.0 Operator: 917
Column phase: J8.W DB5.625 Column diameter: 0.32
Data File: DF020312A60.d
Spectrum: Avg. Scans 118-120 ( 7.04), Background Scan 116
Location of Maximum: 198.00
Number of points: 164
m/z Y m/z Y m/z
*
Y m/z Y
*
1 37.00 208 1 127.00 14914 1 191.00 217 1 259.00 376 1
1 38.00 855 1 128.00 1340 1 192.00 977 1 265.00 1054 1
1 39.00 2261 1 129.00 9323 1 193.00 894 1 273.00 967 1
1 49.00 307 1 130.00 814 1 196.00 1192 1 274.00 3022 1
1 50*00
1
12400 1 134.00
*
408 1 198.00 48720 1 275.00 13276 1
* * *
1 51.00 30920 1 135.00 727 1 199.00 3375 1 276.00 1582 1
1 52*00 1519 1 136.00 233 1 200.00 249 1 277.00 1780 1
1 5b.00 599 1 137.00 421 1 203.00 489 1 278.00 271 1
1 57*00 1104 1 141.00 1590 1 204.00 2355 1 285.00 225 1
1 61.00 200 1 142.00 330 1 205.00 3970 1 293.00 269 1
* *
1 62.00 438 1 143.00 197 1 206.00 13092 1 296.00 6199 1
1 63.00 793 1 146.00 244 1 207.00 1665 1 297.00 731 1
1 69.00 21320 1 147.00 289 1 208.00 533 1 303.00 486 1
1 73.00 516 1 148.00 3708 1 209.00 192 1 314.00 241 1
1 74.00 4338 1 149.00 351 1 210.00 259 1 315.00 563 1
1 1 *
1 75.00 4126 1 153.00 530 1 211.00 452 1 316.00 291 1
1 76.00 1927 1 154.00 196 1 215.00 178 1 323.00 1206 1
1 77.00 27712 1 155.00 816 1 217.00 4635 1 324.00 248 1
1 73.00 1901 1 156.00 1046 1 218.00 507 1 327.00 297 1
1 79.00 2376 1 158.00 179 1 221.00 1531 1 334.00 806 1
* 1 1
1 80.00 1430 159.00 175 222.00 560 1 335.00 228 1
1 81.00 1743 160.00 428 223.00 1012 1 346.00 338 1
1 32.00 373 161.00 726 224.00 3570 352.00 354 1
1 36.00 824 165.00 710 225.00 2054 353.00 266 1
1 91.00 472 167.00 6120 227.00 5066 354.00 325 1
*
1 92.00 576 168.00 2834 223.00 541 365.00 . 2301 1
1 93.00 5494 169.00 260 229.00 691 366.00 349 1
i 9e.oo 4498 172.00 208 231.00 217 372.00 594 1
99.00 2093 173.00 275 234.00 309 402.00 232 1
101.00 776 174.00 426 235.00 313 403.00 294 1
1044 00 646 175.00 1219 236.00 246 421.00 213 1
105.00 651 176.00 249 237.00 235 422.00 256 1
107.00 7039 177.00 510 241.00 223 423.00 1931 1
103.00 339 179.00 2702 242.00 429 424,00 299 1
no.oo 9055 130.00 1442 244.00 6480 441.00 5177 1
Data F11 a: /chem/5972hp60 . i /DF020312A60. b/DF020312A60. cl
Date : 12-MAR-2002 08:51
Client ID: DFTPP Instrument: 5972hp60.i
Sample Info: DFTPP:917
Volume Injected <uL): 2.0 Operator: 917I
Column phase: J8.U DB5.625 Column diameter: 0.32
Data File: DF020312A60.d
Spectrum: Avg, Scans 118-120 < 7.04), Background Scan 116
Location of Maximum: 198.00
Number of points: 164
m/z Y n/z Y n/z Y n/z
*
Y
+ * +
1 111.00 1517 1 181.00 514 1 245.00 791 1 442.00 32576 1
1 117.00 15728 1 184.00 205 1 246.00 1882 1 443.00 6143 1
1 118.00 997 1 185.00 1192 1 247.00 308 1 444.00 468 1
1 122.00 599 1 186.00 7293 1 255.00 30688 1 1
1 123.00 787 1 187.00 2290 1 256.00 4475 1
1
1
1+
1 124.00 242 1 188.00 212 1 257.00 359 1 1
1 125.00 201 1 189.00 468 1 258.00 2712 1 1
<xl
0~6)
Data File: /chem/5972hp60.i/DF020312A60.b/DF020312A60.d
Date : 12-MAR-2002 08:51
Client ID: DFTPP Instrument: 5972hp60,i
Sample Info: DFTPP:917
Volume Injected <uL>: 2.0 Operator: 917
• 6
3b
TAILING FACTOR and DEGRADATION SUMMARY RESULTS
DECAFLUOROTRIPHENYLPHOSPHINE Ion Abundance/Ratio Criteria Chart
(Ion | Abundance Criteria Base Peak Other Test
198 B'ase Peak, 100% relative abundance 100.00 PASS51 30 - 80% of mass 198 63.46 PASS68 Less than 2% of mass 69 0.00 ( 0.00) PASS69 Mass 69 relative abundance 43.77 PASS70 L'ess than 2% of mass 69 0.00 ( 0.00) PASS
127 25 - 75% of mass 198 30.61 PASS197 0 - 1% of mass 198 0.00 PASS199 5 - 9% of mass 198 6.93 PASS275 10 - 30% of mass 198 27.25 PASS365 Greater than 0.75% of mass 198 4.72 PASS441 Present, but less than mass 443 10.63 ( 84.27) PASS442 40 - 110 % of mass 198 66.87 PASS443 15 - 24% of mass 442 12.61 ( 18.85) PASS
TAILING ANALYSIS SUMMARY
Compound |Tail Factor Max Allowed | Test
Pentachlorophenol 2.2 5.0 PASSBenzidine
i0.0 3 . 0 PASS
DDT DEGRADATION BREAKDOWN ANALYSIS SUMMARY
^ Compound Response %Breakdown Max Allowed Test
4,4-DDT 901952 N/A4,4-DDE 0 0.0 20.0 PASS4,4 -DDD 0 0.0 20.0 PASS
4,4-DDD + DDE1
0 0.0 20.0 PASS
Tuning Sample, /chem/5972hpS0.i/DF020312A60.b/DF020312A60.d/DF020312A60.d
*** PASSED ***
■ 63/
TAILING FACTOR and DEGRADATION SAMPLE AND GRAPHIC REPORT
port Date: 03/12/2030 10:53
Datafile Analyzed: /chem/5 9 72hp60.i/DF020312A60.b/DF02 0312A60.d/DF020312A60.d Method Used: /chem/5972hp60.i/DF020312A60.b/dftpp8270C.m Inst: 5972hp60 Injection Date: 12-MAR-2002 08:51 Operator: 917Sample Info: DFTPP DFTPP:917 Misc Info:
5.2-
5.0-
4.6-
4.6- '
4.4- ;
4.2-
4.0-
3.8-
3.6-
3.4-
3.0-
2.8-
2.6-
:.u-
1 .8-
1 -6-.
1 . 4-
1 .2-
1.0-
0.8-
0.6-'
0.4-in
0.2- 12
0.0- <-
HP MS DF020312A60 *-d
C' C'J|JD CD TV j |
garni ^ i tgicEtD) tnjrt/yj il brerfo
Eg* UJUJ1JOMT*03 IP
0)co•*->ai
"o **45 oirc\Dinn -< cmt Cftflj cnrvqvHatr co c CD U-CcrjO ^(\r7T^JP >£> Is*
<-• r<u c>jin <7> a\ co cn rccmo•-h m inn co o w-o\ro
uo CDJ
o or v un
ip CMiCW'JNk CN|CQ-4
b . 8 8.0 8.4 8.8
Time (Min)9.: 9.6 10.0 10.4 10.8 11.2 11.6 12.0 12.4
• 63o
Report Date: 03/12/2030 10:53
0atafile Analyzed: /chem/5972hp60.i/DF020312A60.b/DF020312A60.d/DF020312A60.d■fethod Used: /chem/5972hp60.i/DF020312A60.b/dftpp8270C.m Inst: 5972hp60
njection Date: 12-MAR-2002 08:51 Operator: 917Sample jlnfo: DFTPP DFTPP:917
Misc Info:
5.1-
4.8-
4.5-
4.2-
3.9-
3.6-
3.3-
3.0- '
£. . > ”2.4-
2.1-
1.8-
1.5-
1 ■
0.9-
0.6-
0.3-
n 0--
HP MS DF0203l2A60.d
6.8 6.9 7.0Time (Min)
7.1 \2 7.3 7.4 7.5
1.0-
0.9-
0.6-
0.7-
0.6-
0.5-.
0.4-
0.3-
0.2-
o. i
0.0-
HP MS DF020312A60.d. Scan 119: 7.043 min. ,"'"198
255
51 ! 275s
127
186 ,'296
, 323.•365
403
1 00 140 16C 180
:l.i. _ .
260 280 300 320 340 360 380 400 420
444
S.440
DECAFLUOROTRIPHENYLPHOSPHINE Ion Abundance/Ratio Criteria Chart
I on | Abundance Criteria Base Peak Other Test
198 Base Peak, 100% relative abundance 100.00 PASS51 30 - 80% of mass 198 63.46 PASS68 Less than 2% of mass 69 0.00 ( 0.00) PASS69 Mass 69 relative abundance 43.77 PASS70 Less than 2% of mass 69 0.00 ( 0.00) PASS
j 127 25 - 75% of mass 198 30.61 PASS197 0 - 1% of mass 198 0.00 PASS199 5 - 9% of mass 198 6 . 93 PASS
j 275 I 0 - ’30% of mass 198 27.25 PASSl65 eacer than 0.75% of mass 198 4 . 72 PASSr41 Pi esenc, but less than mass 443 10.63 ( 84.27) PASS1442 40 - 110% of mass 198 66 . 87 PASS443
----
1 5 - 24% of mass 442 12.61 ( 18.85) •TO7
Report Date: 03/12/2030 10:53
« Datafile Analyzed: /chem/5972hp60.i/DF020312A60.b/DF020312A60.d/DF020312A60.d Method Used: /chem/5972hp60.i/DF020312A60.b/dftpp8270C.m/BrkDwnTF.m Inst: 59
lniection Date: 12-MAR-2002 08:51 Operator:Inst: 5 9 7 2 h
.njection Date: 12-MAR-2002 08:51 Sample jlnfo: DFTPP DFTPP:917 Misc In'fo:
Operator:
Report
Datafil let hod "nj ecti
Sample Misc In
1.3-
1.2-
1 . It
1.0-
0.9-
0.6-
0.7-
0.6-
0.5-
0.4-
0.3-
0.2-
0.1 •.
e Analyzed: /chem/5972hp60.i/DF020312A60.b/DF020312A60.d/DF020312A60.dUsed: /chem/5 972hp6 0.i/DF02 0312A6 0.b/dftpp8 2 7 0C.m/BrkDwnTF.m Inst: 5972h
on Date: 12-MAR-2002 08:51 Operator:Info: DFTPP DFTPP:917 f o :
Date: 03/12/2030 10:53
HP MS DFC20312A60.d. Ion 184.00
Ion 184
Tailing Factor =j 0.00000
ij .
0.00 s.i:
i.i-
0.4-
8.10 8.15 S.20 8.25 0.30Time (Min)
1.3-
1.2g
1. It
1.0-j 0.9-_
0.8-
[n 0.7~
0.6-
0.5-i
0.4-f
0.3-1
0.2~
o. i-;
0.0--
HP MS DF020312Ab0^, Ion 184.00
8.35 8.40 8.45 0.50 8.55 8.00 8.10 8.20 8.30Time (Min)
8.40 8.50
HP MS DF020312Ab0.d. Scan 193: 8.295 min.184-",
158 .'25“
186 • 213239v
120 180 200 220 240 260 280
Senziaine i
Exp. RT Found RT
Mass
3.3978.295
Area Ratio
162361 100.00
tailing factor for Benzidine OK
Filing Factor = 0.0 Maximum Allowed 3 . 0641
If Tailing Factor < 1.0, then it is assumed that the peak is not ‘tailing and a Tailing Factor of zero is reported.
Report Date: 03/12/2030 10:53
tafile Analyzed: /chem/5972hp60.i/DF020312A60.b/DF020312A60.d/DF020312A60.dthod Used: /chem/5972hp60.i/DF020312A60.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h
njection Date: 12-MAR-2002 08:51 Operator:Sample Info: DFTPP DFTPP:917 Misc Into:
8.0-
7.5- :
7.0/
6.5-
6.0-:
5.5r
5.0-
•1.5-
4 .Or
3.5-
3. Or
2.5-
2.0-
i .5-;
1.0-
0.5-
n n-~
HP MS DF020312A60.d. Ion 235.00
Ion 235
0.94 8.97 9.03 9.06 9.09 9.12 9.15 9.10 9.21 9.24 9.27 9.30 9.33 9.36 9.39 9.42 9.45 9.40 9.51 9.54__________________ Time (Min)
6.4-
6.0-ke-
4.8-
4.4-
4.0-
— 2.6- u"l
7 2.8-
50
>.8-
4,4'-DDT
Exp. RT Found RT
Mass
235
HP MS DF020312A60.d. Scan 249: 9.243 min."-235
165
199
136
121.1 14m 160 10'J 20um .<■ z
212
282 ,284 •319 354.^50
260 200 300 320
9.3629.243
Area Ratio
•01952 100.00
Report Date: 03/12/2030 10:53
^atafile Analyzed: /chem/5972hp60.i/DF020312A60.b/DF020312A60.d/DF020312A60.dt hod Used: /chem/5972hp6 0 . i/DF02 03.12A60 . b/df tpp8270C . m/BrkDwnTF . m Inst: 5972h
rnjection Date: 12-MAR-2002 08:51 Operator:Sample Info: DFTPP DFTPP:917Misc Info: »
HP H5 DF020312H60. d. Ion 235.00
6.6-
6.4-
6.0-
5.6-
5.2-
4.8-
4.4-
4.0
3.6-
3.2/2.8- :
2.4- 2.0-'
1.6- "
1.2- ' 0.8-'
0.4-
Ion 235
. \
0.0- —--------s. ro 6.73 8.76 8.
73
•1 .0-
0.9-
u. 8 -
■ pr.
— 0.0-
“ 0.5-'
0.3
4,4'-DDD
-o e-
Fxo. RT = 8.989Found RT 0 .000
Mass Area
9 0 c; o
T l me (Min)HP MS DF020312060.a. Scan 234: 8.989 min.
207
281
160 220 260
Ratio
0 . 00
64 j
Report Date: 03/12/2030 10:53
+Analyzed: /chem/5972hp60.i/DF020312A60.b/DF020312A60.d/DF020312A60.d sed: /chem/5972hp60.i/DF020312A60.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h
tafile hod U
jection Date: 12-MAR-2002 08:51 Operator:Sample Info: DFTPP DFTPP:917 Misc Info:
1 . 4-
1 . 3-
1.1-
1.0'
0.9-
0.8
:S 0.7-
0.6-
0.5-
n, 4-'
0.3-
0.2-
0.1
0.0----3.28
950-
00-
300-
750
700
450- 4 00 •
350-300-'
250-
150-
HP MS DF0203l2A60.d. Ion 246.00
Ion 246
31 3.34 0.37 3.40 3.43 3.46 8.49 8.52 3.55 8.58 0.61 8.64 0.67 8.70 8.73 8.76 8.79 8.82 8.85 0.88______________ ___________ _________ Time (Min) __ ____________________ _____
HP MS DF020312h60.d. Scan 210: 8.583 min.207,
120 1 40 150 160 170 180 190 200
4' - DDE
Exp. R7 = 3.583Found RT = 0.000
Mass Area Ratio
0 0.00
• 644
HP M5 DF02Col2H60fd„ Ion 235.00
9.00 9.10 9.20 9.30| Time (Min)_____
9.40 9.50
HP MS DF020312A60.d, Ion 235.00
.5-.
.0-;
5-
0-
5-!
0-:
5-
0-
5-
.0-
. 5-
.0-
.5-
.0-
.5-
.0— 8.
L70 8.80 9.90 9.00 9-. 10 9
| T i me (Min'.20
HP MS DF020312H60.d. Ion 246.00
1.4-
1 .3-.
1.2-
1.1-
1.0-.0.9-:
0.8-
0.7-:
0.6-
0.5-
0.4-
0.3-.
0.2-
0.1-'
0.0-' - 8. 8.50 8.60
Time (Min)8.70 0.80
Compound: 4,4'-DDT
Quant Mass: 235
RT: 9.243
Area: 901952
Compound: 4,4'-DDD
Quant Mass: 235
RT: 0.000
Area: 0
Compound: 4,4'-DDE
Quant Mass: 246
RT: 0.000
Area: 0
DDT DEGRADATION BREAKDOWN ANALYSIS SUMMARY
Compound Response %Breakdown Max Allowed Test
4,4-DDT4,4 -DDE
9019520 0.0 20.0
N/APASS
4,4-DDD 0 0 . 0 20.0 PASS^,4 -DDD + DDE 0 0.0 20.0 PASS
TUNE SAMPLE
ir-k-k-k’k'k’k'kir'k-k-k'k'k
*** PASSED *** DDT BREAKDOWN TEST
Data File: 7chem/5972hp60.i/'DF020313A60.b/DF020313A60.d
Date : 13-MAR-2002 12:09
Client ID: DFTPP|
Sample Info: DFTPP:917
Volume Injected (uL): 2.0
Instrument: 5972hp60.i
Operator: 917
Data File: 7chem/5972hp60.i/DF020313A60.b/DF020313A60.d
Date : 13-MAR-2002 12:09I
Client ID: DFTPP
iSample Info: DFTPP:917
Volume Injected <uL): 2.0
Instrument: 5972hp60.i
Operator: 917
Column phase: J&W DB5.6251
Column diameter: 0.32
#
Data File: DF029313A60.d
Spectrum; Av/g* Scans 119-121 ( 7.06), Background Scan 117
Location of Maximum; 198*00
Number of points; 261
m/z Y m/z Y m/z Y m/z •<
**■
1 36 * 00 38 1 125.00 267 196.00 1282 1 275.00 11290 1
t 37.00 270 1 127.00 15296 198.00 48032 276.00 1450 1
1 38.00 671 1 128.00 1369 199.00 3453 277.00 1610 1
1 39.00 2013 1 129.00 9106 200.00 255 278.00 207 1
1 42*00 34 1 130.00 789 201.00 139 1 282.00 39 1
+ *
1 43*00 141 1 131.00 145 202.00 111 283.00 117 1
I 45*00 41 1 132.00 85 203.00 568 284.00 71 1
1 43*00 463 1 133.00 35 204.00 2213 1 285.00 196 1
1 50.00 10681 1 134.00 287 205.00 3699 1 286.00 37 1
1 SI. 00 27872 1 135.00 641 206.00 13336 289.00 62 1
+ +
1 52*00 1341 1 136.00 314 207.00 1569 1 290.00 40 1
1 53*00 37 1 137.00 448 208.00 617 293.00 202 1
i 55*00 238 1 138.00 65 209.00 159 294.00 119 1
[ 56.00 605 1 139.00 45 210.00 246 1 296.00 5506 1
t 57.00 942 1 140.00
1
158 211.00 563 297.00 683 1
*
1 53,00 36 1 141.00 1494 213.00 52 298.00 47 1
1 81.00 200 1 142.00 363 215.00 188 301.00 75 1
1 82.00 353 1 143.00 336 216.00 34 303.00 450 1
1 63.00 735 1 144,00 75 217.00 4578 304.00 113 1
l 64.00 99 t 146*00
*
332 218.00 514 1 308.00 81 1
*
1 65.00 216 1 147.00 171 219.00 58 309.00 48 1
1 67.00 44 f 148.00 3096 221.00 1378 310.00 65 1
1 63 00 19832 1 149.00 485 222.00 524 313.00 46 1
1 70.00 95 1 150.00 69 223.00 63 314.00 214 1
l 73.00 313 1 151.00 121 224.00 7985 315.00 534 1
1
l 74.00 4062 1 152.00 69 225.00 1899 316.00 292 1
i 75.00 3324 1 153.00 522 227.00 4925 321.00 96 1
1 76.00 1907 1 154,00 331 228.00 641 323.00 1217 1
I 77 00 26096 1 155.00 829 229.00 824 324.00 183 1
1 73*00 1740 1 156.00 1091 1 230.00 85 1 327.00 288 1
' 1 *
\ 73.00 2436 ! 157.00 159 1 231.00 217 1 328.00 127 1
l 30 00 1303 1 158.00 335 1 232.00 42 1 332.00 105 1
l 31 00 1621 1 159.00 218 1 233.00 63 1 333.00 33 1
i 32 * 'J'v1 383 1 160.00 5«6 1 234.00 240 1 334.00 779 1
1 244 1 161.00 631 1 235.00 268 1 335.00 166 164 i
Data File: /chem,'5972hp60.i/DF020313A60.b/DF020313A60.d
Date : l3pMAR-2002 12:09
Client ID: DFTPP
Sample Info: DFTPP:917Volume Injjected CuL): 2.0
Column phase: J8.W DB5.625
Instrument: 5972hp60.i
Operator: 917
Column diameter: 0.32
Data File: DF020313A60.d
Spectrum: Avg. Scans 119-121 ( 7.06), Background Scan 117
Location of Maximum: 198.00
Humber of points: 261
m/z V m/z Y m/z Y m/z Y
85.00 220 162.00 172 236.00 214 341.00 84
86.00 642 i 163.00 62 237.00 270 346.00 251
87.00 193 i 165.00 726 238.00 40 347.00 37
88.00 45 167.00 5396 239.00 202 1 352.00 392
89,00 35 168,00 2638 240.00 117 353.00 266
91.00 413 169.00 304 241.00 165 1 354.00 310
92.00 386 170.00 139 242.00 442 355.00 149
93.00 5199 171.00 145 244.00 5706 365.00 2344
94.00 308 i 172.00 312 245.00 676 1 366.00 299
95.00 119 173.00 363 246.00 1676 371.00 101
96.00 115 174.00 696 i 247.00 268 1 372.00 585
98.00 4574 175.00 1118 248.00 76 373.00 113
o o 2063 176.00 270 249.00 139 383.00 163
100.00 203 177.00 587 250.00 37 1 384.00 34
101.00 790 179.00 2533 251.00 40 390.00 55
103.00 312 180.00 1348 252.00 96 391.00 43
104.00 713 181.00 598 253.00 137 1 401.00 49
105.00 672 182.00 83 255.00 26896 402.00 202
107.00 6774 183.00 49 i 256.00 3816 403.00 304
108.00 863 184.00 243 257.00 34 404.00 104
110,00 9042 185.00 1183 258.00 2493 421.00 244
111.00 1562 186.00 6910 259.00 325 422.00 260
112.00 236 187.00 1970 260,00 55 423.00 1631
113.00 107 188.00 246 261.00 56 424.00 317
115.00 55 139.00 748 263.00 37 441.00 2106
117.00 16001 190,00 109 265.00 1103 442.00 31728
118.00 1020 191.00 246 266.00 38 443.00 6135
120.00 67 192.00 828 271.00 56 444.00 484
122.00 558 193.00 940 272.00 131
123.00 826 194.00 130 273.00 915
124.00 342 195.00 79 274.00 2608 1
(x!0A6)
Data File: /chem/5972hp60.i/DF020313A60.b/DF020313A60.d
Date : 13-MAR-2002 12:09
Client ID: DFTPP
Sample Info: DFTPP:917
Volume Injected <uL): 2.0
Column phase: J&W DB5.625
Instrument: 5972hp60.i
Operator: 917
Column diameter: 0.32
■:r>
'=3'
co
TAILING FACTOR and DEGRADATION SUMMARY RESULTS
D:ECAFLUOROTRIPHENYLPHOSPHINE Ion Abundance/Ratio Criteria Chart
Son | Abundance Criteria Base Peak Other= = = = = + Test |
198 Base Peak, 100% relative abundance 100 .00 PASS51 3 0 - 80% of mass 198 58.04 PASS68 Le ss than 2% of mass 69 0.00 ( 0.00) PASS69 Mass 69 relative abundance 41.29 PASS70 Less than 2% of mass 69 0.20 ( 0.48) PASS
127 2 5 ' 75% of mass 198 31.84 PASS197 0 - 1% of mass 198 0.00 PASS199 5 ' 9% of mass 198 7.19 PASS275 1 0 - 30% of mass 198 23.50 PASS365 Greater than 0.75% of mass 198 4.88 PASS441 Present, but less than mass 443 4.38 ( 34.33) PASS442 4jo - 110 % of mass 198 66.06 PASS443 15 - 24% of mass 442 12.77 ( 19.33) PASS
TAILING ANALYSIS SUMMARYl
Compound1
Tail Factor Max Allowed Test
Pentachiorophenol 1.9 5.0 PASSBenzidine
i2.0 3.0 PASS
DDT DEGRADATION BREAKDOWN ANALYSIS SUMMARY
* Compound Response %Breakdown Max Allowed Test
W 4,4 -DDT . 762064 N/A4,4 - DDE 0 0.0 20.0 PASS4,4 -DDD 2380 0.3 20.0 PASS
4,4-DDD + DDE 2380 0.3 20.0 PASS
Tuning Sample, /chem/5972hp60.i/DF020313A60.b/DF020313A60.d/DF020313A60.d
PASSED
65:J
TAILING FACTOR and DEGRADATION SAMPLE AND GRAPHIC REPORT
ort Date :i
03/13/2030 14:02
Datafile1 Analyzed: /chem/5972hp60.i/DF020313A60.b/DF020313A60.d/DF020313A60 . d Method Used: /chem/5972hp60.i/DF020313A60.b/dftpp8270C.m Inst: 5972hp60 Injection Date: 13-MAR-2002 12:09 Operator: 917Sample Info: DFTPP DFTPP:917 Misc Info:
651
Report Date: 03/13/2030 14:02
Datafile Analyzed: /chem/5972hp60.i/DF020313A60.b/DF020313A60.d/DF020313A60.d^tethod Used: /chem/5972hp60.i/DF020313A60.b/dftpp8270C.m Inst: 5972hp60^■jection Date: 13-MAR-2002 12:09 Operator: 917
Sample Info: DFTPP DFTPP-.917Misc Info:
HP MS DF0203l3A60.d
3.6-
3.3-
3.0-
2 7-
2.4-
2.1-
1.0-
1.5-
1.2-
0.9-
0.6-
0.3-'
0.0-
/ \CM
ro
b. b___I
6.8 6.9 7.0 7.1Time (Min)
7.2 7.3 7.4 7.5
1.1-
1.0-
i0.9-
0.8-
0.7-
0.6-
0.5-
0.4-
0.3-
0.2-
0.1-
HP MS DF020313A60.d. Scan 120: 7.058 min. >-198
255
442-,
275
18b ! - 1 .296. 148 i
. I'li , „,i ii ..
j . 323
.... 1.
60 100 120 140 160 180 200 220 2-40 260 280 300 320 340 360m/z
-365403.
380 400 420 440
DECAFLUOROTRI PHENYLPHOSPHINE Ion Abundance/Ratio Criteria Chart
Ion | Abundance Criteria Base Peak Other Test |
198 Base Peak, 100% relative abundance 100.00 PASS51 30 - 80% of mass 198 58.04 PASS68 Less than 2% of mass 69 0.00 ( 0.00) PASS69 Mass 69 relative abundance 41.29 PASS70 Less than 2% of mass 69 0.20 ( 0.48) PASS
127 25 - 75% of mass 198 31.84 PASS197 0 - 1% of mass 198 0.00 PASS199 5 - 9% of mass 198 7.19 PASS275 10 - 30% of mass 198 23.50 PASS365 Greater than 0.75% of mass 198 4.88 PASSto1 Present, but less than mass 443 4.38 ( 34.33) PASSP12 4 o| - 110% of mass 198 66 . 06 PASS443 15 - 24% of mass 442 12.77 ( 19.33) PASS-
Report Date: 03/13/2030 14:02
Datafile Analyzed: /chem/5972hp60.i/DF020313A60.b/DF020313A60.d/DF020313A60.d
Report Date: 03/13/2030 14:02
Datafile Analyzed: /chem/5972hp60.i/DF020313A60.b/DF020313A60.d/DF020313A60.d^^:hod Used: /chem/5972hp60.i/DF020313A60.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h^^^jection Date: 13-MAR-2002 12:09 Operator:
Sample Info: DFTPP DFTPP-.917Misc Info:
HP MS DF0203l3A60.d, Ion 184.00
Ion 184
Tailing Factor =! 1.99576
1.3
1.2^
i. i-:
1.0-
0.9-
0.8-
<P 0.7-
0.6-i
V 0.5-
0.4
0.3-j
0.2^
o. 1-; o.o-
HP MS 07020313960^. Ion 1B4. 00
8.10 0.20 0.30 0.40Time (Min)
0.50 8.60
HP MS DF020313A60.d, Scan 194: 8.310 min.184""',
rf\. o-
0.9-
o.e-
0.7-
0.6
0.5-
(j,4-
0.5-
0.1
Benzidine
Exp. RT Found RT
Mass
184
ii/ 130156
100 160
8.3978.310
Area
196518
Ratio
100.00
Tailing factor for Benzidine OKm
ling Factor = 2.0
186
■! 01
180 200
.207 239.
220 240
.257281.
I
260 280
Maximum Allowed = 3.0
31313
300
65-
Report Date: 03/13/2030 14:02
m
Sarr
Datafile Analyzed: /chem/5972hp60.i/DF020313A60.b/DF020313A60.d/DF020313A60.d kthod Used: /chem/5 972Hp6 0 . i/DF02 0313A6 0 . b/df tpp82 70C . m/BrkDwnTF . m Inst: 5972h ectio'n Date: 13-MAR-2002 12:09 Operator:
ample Info: DFTPP DFTPP:917Misc Info:
HP MS DF020313860.Q. Ion 235.00
6.8-
6.4-
6.0-
5.6-
5.2
4.8-
4.4-
4.0-
3.6-
2. d\
2.4-
2.0-
1.6-
1.2-
0.8-
0.4-
0.0-
Ion 235
: \
1 /• /
/ l1
\ i
9.12 9.15 9.18 9.21 9.24Time
9.27(Min)
9.30 9.33 9,36 9.39 9.42 9.45 9.48 9.51 9.54 9.57
HP MS.DF0203l3Hb0.d. Scan 251: 9.274 mn."-235
m8-
2. 1
1.3-
1.5-
4,4'-DDT
Exp. RT Found RT
Mass
23 5
165
199
136
100 120 140 160 lbO 200
212
282. ,•286 -319 35-1 360 I
220 240 260 280 300 320 340 360 I
9.3629.274
Area
762064
Ratio
65::o
100.00
Report Date: 03/13/2030 14:02
«Datafile Analyzed: /chem/5972hp60.i/DF020313A60.b/DF020313A60.d/DF020313A60.d
.thod Used: /chem/5972hp60.i/DF020313A60.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h ection Date: 13-MAR-2002 12:09 Operator:
ample Info: DFTPP DFTPP:917Misc Info:
HP HS DF020313A60rd, Ion 235.00
600-
560
520
480-
4 4f>
400
360
320-
280-
240-
200-
160-
120-
80-
40-
Ion 235N'
I
iV-
8.26 3.29 8.82 8.85 8.88 8.91 8.94 8.97 9.00 9.03 9.06 9.09 9.12 9.15 9.18 9.21 9.24 9.27 9.30 9.33_________________________________ Time (Min)
HP MS DF020313A60.d. Scan 237: 9.037 min."‘"••207
✓281
176
147235
193
85
100
111
120 140 160
; I! Iin i
ii'i liill ;l.; ,!i;i
180 200 220
i |
240
•251
260
311
345
3.47
280 3001 I 1
340
I i
4,4'-DDD
Exp. RT Found RT
Mass
235
8.9899.037
Area Ratio
2380 100.00
65b
Report Date: 03/13/2030 14:02
Datafile Analyzed: /chem/5972hp60.i/DF020313A60.b/DF020313A60.d/DF020313A60.d^tethod Used: /chem/5972hp60.i/DF020313A60.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h^Bjjection Date: 13-MAR-2002 12:09 Operator:Sample Info: DFTPP DFTPP:917
Misc Info:
5.1-
4.8-
4.5-
4.2-
3.9-
3.6-
T T
3.0-
2.4-
2.1-
1.8-
1.5;
1.2;
0.9-
0.8;
0.3-
HP MS DF020313A60.CJ. Ion 246.00
Ion 246
8.28 el 31 8.34 8.37 8.40 8.43 8.46 8.49 8.52 8.55 0.58 8.61 8.64 8.67 8.70 8.73 8.76 8.79 8.82 8.85 8.08 I
I_________________ ________ _Time < Min) ____ _
A9'
950-
q 00- 50-
'80':'
750
700-
650-:
600-.
550-
500-
■_ 4 50-
400 :
350-
300-
250-
nn
HF MS DF0203l3A60.d. Scan 210: 8.580 min.207--5
28 K
,244
1B4
150;: :10 j 133
100-iij i;
50-/: ■'
0-','40 6'J 80 10' ' 120
4,4'-DDE
Exp. RT 8.583Found RT = 0.000
Mass Area Ratio
24 6 0 0.00
140 180 1Q0 200 220m/z
283
240 260 280 300 320
3.55
I !
340
65
6.0-
5.6-
5.2- 4.B-
i 4 . 4-I4.0-
3.6-
3.2- :
2. a-;2.4-:
2.0-
1.6-
1.2-
0.8-
Ci. 4-
0.0--
HP MS DF020313P60.^i. Ion 235.00
CM
CP
9.10 9.20 9.30______ T ime lMin >
9.40 9.50
HP MS DF020313060kJ. Ion 235.00
520-
480-
440-
400-
360-
320-
200-
240-
200-
160-.
120-
00
40-I
8.80 8.90 9.00 9.10 9.201Time (Min)
9.30
HP MS- DF02031 3060 . d. Ion 246.00
' o. ou i M l n j
8.80
Compound: 4,4'-DDT
Quant Mass: 235
RT: 9.274
Area: 762064
Compound: 4,4'-DDD
Quant Mass: 235
RT: 9.037
Area: 2380
Compound: 4,4'-DDE
Quant Mass: 246
RT: 0.000
Area: 0
DDT DEGRADATION BREAKDOWN ANALYSIS SUMMARY
Compound Response %Breakdown Max Allowed Test
4,4 - DDT 762064 N/A4, 4-DDE 0 0.0 20.0 PASS4,4-DDD 2380 0.3 20.0 PASS4,4-DDD + DDE 2380 0.3 20.0 PASSm
TUIUNE SAMPLE★ ★★★★★★★★★★★★★ *** PASSED ***'k'k'k'kir'k'k'k'k'k'kic'k'k
DDT BREAKDOWN TEST
658
Delta F i
Date :
Client
Sample
le: /chem/5972hp60
'14-MAR-2002 20:31
ID: DFTPP
Info: DFTPP:231'?
Volume Injected (uL) 0
i/DF020314B60.b/DF020314B60.d
Column phase: J&W DB5.625
Data File: DF020314B60.d
Spectrum: Avg. Scans 118-120
Location of Maximum: 193.00
Humber of points: 258
Instrument: 5972hp60.i
Operator; 2319
Column diameter: 0*32
7.04), Background Scan 116
\
1
m/z Y m/z Y m/z Y m/z Y
1
1 3b ♦ 00 41 119.09 87 190.00 132 1 273.00 931 1
1 77 no 404 120.00 75 191.00 336 l 274.00 2777 1
1 38*00 1090 122.00 79? 192,00 920 1 275.00 11835 1
I 39.00 3063 123.00 1026 153.00 in? 1 276.00 1703 1
1 40.00 143 124.00 446 1 134.00 182 1 277.00 1635 1
,1 1
1 41.00 97 125.00 316 1 136.00 1472 1 278.00 269 1
1 43.00 66 127.00 18488 1 193.00 53376 1 279.00 41 1
l 44.00 57 123.00 1508 1 199.00 3524 1 283.00 159 1
1 45.00 109 129.00 10838 1 200.00 296 1 284.00 108 1
1 48.00 35 130.00 1024 1 201.00 15? 1 285.00 265 1
*1 1 1 *
1 49,00 92 1 131.00 223 1 203.00 560 1 290.00 39 1
1 . 1614b 1 132.00 66 1 204.00 2461 1 292.00 44 1
1 51.00 40064 1 133.00 41 1 205.00 4172 1 293.00 287 1
1 52.0';' 2121 1 134.00 336 1 206.00 13963 1 294.00 38 1
1 57 - 1 • < 49 1 135.00 906 1 207.00 2078 I 296.00 5696 1
+ 1 1 1
1 55.0'..' 272 136.00 335 1 208.00 717 1 297.00 820 1
1 5»:. ■ 782 137.00 517 1 209.00 231 1 298.00 51 1
1 57.00 1315 138,00 111 1 210.00 265 1 301,00 45 1
1 58.00 32 139.00' 70 1 211.00 707 1 302.00 68 1
i 57 140.00' 134 212.00 93 l 303.0c 456 1
i 61.00 4 0 0 141.00- 213.00 51 1 304.00 134
1 0.1'. 00 0.09 142.00' 497 215.00 263 1 308.00 97
1 05.0' c,5b 143.00' 315 217.00 4674 | 313,00 36
1 0.4 . 124 144.00 103 218.00 605 1 314.00 ;ii
! 05 <Vi 204 146.00 383 219.00 43 1 315.00 593
; 8;•. i>-i 92 147.00 1107 1 221.00 150" l 316.00 235 1
j 69.00 20.0.88 143.00' 4273 1 222.00 61? 1 321.00 166 1
i 73, .ii, 5"?0> l 149.00 (i 44 1 224.On 9012 t 323.00 1302 1
1 74.0".' 5498 1 150.00 92 1 225. 2526 i 324.00 182 1
1 75. no 5304 1 151.00' 171 1 227.00 5409 1 326.00 45 1
273? 1 152.00 ?3 l 223.00 *2- 4 4> 1 327.00 341
77..;,,, 37253 l 153.0.0' 651 l 229 Oo 921 1 328 00 132
78.■ " ■ 2348 I 154.''O' 334 ; 23':*. 00 90 1 332 00 114
. 743^ 1 155.. .0 1162 1 231.-'0 704 1 333.00 99
IS 19 1 156.00 1239 1 233.00 77 1 334 00 CO 7
Data File-: /chem/5972hp60.1 /DF020314B60. b/BF0203l4B60.d
Date : 14-MhR-2002 2o:3l
Client ID: DFTPP
Cample Info: DFTPP:231?
Volume Injected <uL): 2.0
Column phase J8.U DBS.625
Data File: DF020314B60.d
Spectrum: Avg. Scans 118-120
Location of Maximum: 198*00
Number of points: 258
Instrument: 5972hp60.i
Operator: 2319
Column diameter: 0.32
7.04), Background Scan 116
m/z V m/z Y m/z Y m/z Y
1 1 *
31.00 2309 1 157.00 170 1 234.00 299 335.00 211
82 00 559 1 158.00 269 235.00 272 341.00 169
33.00 332 159.00 194 236.00 238 346.00 353
35.00 354 160.00 698 237.00 341 352.00 382
ob. 00 1115 161.00 716 239.00 219 353.00 261
37.00 272 162.00 142 24-). 00 151 354.00 343
38.00 121 163.00 92 241.00 212 355.00 50
91.00 613 165.00 832 242.00 509 365.00 2589
92.00 707 167.00 7014 244.00 6317 366.00 326
93.00 7355 168.00 3447 245.00 399 371.00 110
1
94.00 373 1 169.00 406 1 246.00 1803 I 372.00 671
87 1 170.00 137 247.00 358 373.00 171
96. 00 1*3 1 171.00 184 248.00 61 383.00 186
:'o. 6391 1 172.00 363 1 249.00 159 l 384.00 35
9?. Oo ii c- 3 1 173.00 399 251.00 65 390.00 54
1
100.00 213 1 174.0':- 790 252.00 47 392.00 33
101.00 981 1 175.00 1461 253.00 175 402.00 241
103.00 4 43 1 176.00 252 255.00 23792 403.00 356
104.00 941 177.00 745 256.00 4216 404.00 72
105,00 808 179.00 3176 257.00 93 421.00 299
106.00 35 180.00 1572 ! 253.00 2520 422.00 S3
107.00 8958 131.00 816 259.00 371 423.00 2022
103.00 1056 132.00 75 260'. 00 56 424.00 351
110.0>-> 12196 133.0':' 67 261.00 38 1 425.00 45
111.00 2117 184.00 265 1 264.00 31 i 441.00 6795
1
112.00 33u 135.00 1485 1 V.5 00> 1101 1 442.00 33944
113.00 114 1 136.'-:":' 3830 1 266.00 223 i 443.00 7680
114.00 5i i IS 7..JO 2621 1 27'). 00 46 1 444.00 581
117.00 22416 l 138.',":' 301 1 271.00 139 .
113.00 1423 1 139.00 301 [ to 6F- 1 I
<s xio-
Instrument; 5*'"172hp60. i
Operator; 231*3
Column diameter; 0*32
,V:hem/59?2hpbO. i/BF020314B60,b/DF020314B60.d5.2-
5.0-
4.8-
4.6-
4.4-
4.2-
4.0- ;
3.8-
3.6-
3.4-
Data File: /’chem/5972hp60.i/DF020314B60.b/DF020314B60.d
Date : 14-HAR-2002 20:31
Client ID: DFTPP
Sample Info; IiFTPP;2319
Volume Injected <uL); 2*0
Column phase; J&W DB5.625
. v Jco
CjD
3.0-
2.0 -
l. y -
1.6-
1,4-
1.2-
0.4-
1' ■. 5 1«\8 11.1 11.4 11.7 12.0 1 2. »:•
TAILING FACTOR and DEGRADATION SUMMARY RESULTS
DECAFLUOROTRIPHENYLPHOSPHINE Icn Abundance/Ratio Criteria Chart
^Ion Abundance Criteria Base Peak Other Test |
*198Base Peak, 100% relative abundance 100.00 PASS
51 30 - 80% of mass 198 75.06 PASS68 Less than 2% of mass 69 0.00 ( 0.00) PASS69 Mass 69 relative abundance 50.01 PASS70 L'ess than 2% of mass 6 9 0.00 ( 0.00) PASS
127 25 - 75% of mass 198 34.64 PASS197 0 - 1% of mass 198 0.00 PASS199 5 - 9% of mass 198 6.60 PASS275 10 - 30% of mass 198 22.27 PASS365 Greater than 0.75% of mass 198 4.85 PASS441 Present, but less than mass 443 12.73 ( 88.48) PASS442 <10 - 110 1 of mass 198 72.96 PASS443 15- 24% of mass 442 14.39 ( 19.72) PASS |
+ = = = =
TAILING ANALYSIS SUMMARYl
Compound Tail Factor Max Allowed Test
Pentachlorophenol 0.8 5.0 PASSBenzidine
i0.0 3.0 PASS
j
DDT DEGRADATION BREAKDOWN ANALYSIS SUMMARY1
Compound Response %Breakdown Max Allowed Test
4,4-DDT 962075 N/A4,4-DDE 867 0.1 20.0 PASS4,4 -DDD 61380 6 . 0 20.0 PASS
4,4-DDD + DDE 62247 6 . 1 20.0 PASS
Tuning Sample, /chem/5972hp60.i/DF020314B60.b/DF020314B60.d/DF020314B60.d
*** PASSED ***
66 j
TAILING FACTOR and DEGRADATION SAMPLE AND GRAPHIC REPORT
Report Date: 03/14/2030 22:06
Datafile Analyzed: /chem/5972hp60.i/DF020314B60.b/DF020314B60.d/DF020314B60.dMethod Used: /chem/5972hp60.i/DF020314B60.b/dftpp8270C.m Injection Date: 14-MAR-2002 20 :31 Operator: 2319Sample!Info: DFTPP DFTPP:2319
Misc Info:
Inst: 5.972hp60
HP M5 DF020314B60 ,,d
•• i-no r n'c « d — lIC' •: .••'C- ODD • • D~TT• r
"D ;■£> iRFC-I' — i'< J iID irn'lDirUTN: lY1>
<yz' c-irv-r •£. g- TjD -k -Lr j rTTU“ O iDD -76 -^l
rj, km-, r. can
d . d (Mid)
9.6 10.0 10.4 10.8 LI.2 11.6 12.0 12.4
664
Report Date: 03/14/2030 22:06
Datafi le Analyzed: /chem/5 972hp6 0 . i/DF020314B60 . b/DF020314B60 . d/DF020314B60 . .1 Used: /'chem/5 9 72hp6 0 ,i/DF020314B60.b/dftpp8270C.m Inst: 5972hp60
ion Date: 14-MAR-2002 20:31 Operator: 2319Info: DFTPP DFTPP:2319
Misc Info:
5.1-
4.3-
4.5-
4.2- '
3.9-
3. b-
3.0-
2.1-
1 . 8-
1.5-
1 . 2-
HP M5 DF020314B60.d
6.9 7.0Tim^ < Min)
M ’.2 \5
HP MS DF020314B60.d. Scan 119: 7.041 min. 1 96'
148 .296
365
j o r ■■ r0 : 20 140 160 2 60 .".'00 220 240 260m.-' c
280 300 320 340 360 350 40
DEC LUOROTRIPHENYLPHOSPHINE ion Abundance/Ratio Criteria Chart
lor. Abundance Criteria Base Peak Other Test |
193 Base Peak, 100% relative abundance 100.00 PASSD 2 3 0 30% of mass 198 75.06 PASS6 3 L ,6SS than 2% of mass 69 0.00 { 0.00) PASS6 9 Mass 65 relative abundance 50.01 E^ASS7 0 Less than 2% of mass 65 0.00 ( 0.00) PASS
127 — 75% of mass 19B 34 . 64 PASS1 2 7 Q 1% of mass 198 0 . 00 PASS1 9 9 5 5% of mass 198 5 . 60 PASS2 75 1 0 30% of mass 19S 22.27 PASS3 6 5 Urea ter than 0.75% of mass 198 4.85 PASS441 ■'ves ere, but less than mass 443 12.73 8 3 .43) PASS
’ A *-i *1 -1 o' - 11C% of mass 198 72 . 96 PASS4 ~ 3 1 2 3 4? c I m ca. s s 'i-t 14.39 19.72) .PASS
----- +66b
Report Date: 03/14/2030 22:06
dDatafi'le Analyzed: /'chem/5 9 72hp6 0.1/DF020 314B60 . b/DF02 0314B6 0 . d/DF02 0314B60 . dMethod] Used: /chem/5972hp60.i/DF020314B60.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h
(Injection Date: 14-MAR-2002 20:31 Operator:Sample]Info: DFTPP DFTPP:2319
Misc Info:
4
3-.
3-
3.4
5.1-
4.6-
4.5-
riF ms DFij2u3l4560.d. Ion 266.00
Ion 266
Tailinq Factor .= 0.82149
6.0-
5.6-
5.2- '
4.8-
4.4-
4.0-
3.6
3.2-
2.8-
2.4- ;
2.0-
1.6:
1.2-
0.8-
0.4-
HP MS DF020314B60.jjJ, Ion 266.00
6.55 6.60T : me •: M 1 n )
6.65 6.70 6.75 6. SC' 6.35 6.90 10.0-i :--------- ——— ----
6.30 6.40 6.50 6.60Time (Min)
6.80 6.90;
HP MS DF020j14B60.d. Scan 93: 6.601 min.
Fentacn
,202230.
180 190 200 240 250
i;!
i iiil
II:Hi2
111!.
"i 2?n
Exp. RT = Found
jpneno ^
6.639
Mass Area
2 o o 110 2 0
Tail me rector f o
l1ing Factor =
12 Talia Tail ina Factor
Rat io
100.00
Pentachlorophencl OK
3 Maximum Allowed = 5.0
o T z p r oit is assumed that the peak is not tailing and ■sported. m-
bbo
Dace: 03/14/2030 22:06Report
Datafile Analyzed: /chem/5972hp60 . i/DF020314B60 . b/DF020314B60 . d/DF020314B60 . ,:i Method j Used: /chem/5972hp60.i/DF02 0314B6 0.b/dftpp8270C.m/BrkDwnTF.m Inst: b 9 ~'2h
njection Date: 14-MAR-2002 20:31 Operator:Sample{Info: DFTPP DFTPP:2319
Misc Info:
9.5-9.0- :
8.5- ;
3.0- ;
7.5- .
7.0-
6.5-
6.0-
5.5-
5.0- .
4.5- .
4. o-:3.5- .
3.0- '
2.5-
2.0-
1 .5-
1.0
0.5
0.0-------
HP MS DF020314B60.a. Ion 184.00
Ion 184
Tailing Factor ;= 0.00000
HP MS DF020314B60JJ. Ion 184.00Onco
8.10 3. n 3.25 S.30Tlme (Min >
3.35 8.40 8.45 8.50 3.55 e.60
5
5
4
4
3
3.0
2.5-
2.0-
1.5-
1.0-'
0.5-:
0. u-:
HP MS DF02C 314560.d. Scan 194: d.309 min. 104‘,
o.o- 6.4-
6.0-
5.6-
5 . eL-
4.8 4.4
-j 4 . •
2.3
cenziame l_ _i
Exp. Rj. = Found RT
Mass
184
8.357
3.305
"ai 1 ina
Area
164610
factor for 3
Factor = 0.0
Ratio
100.00
enzidine OK
Maximum Allowed = 3.0
8.10 8.20 8.30 8.-40 8.50 8.80;Time (Min) _______ _ :
239. 231 .
280 300
If Tailing Factor < 1.0, then it is assumed that the peak is not -t£ijCl£ng and a Tail ina Factor of zero is reDorted . UU ,
Report Date: 03/14/2030 22:06
Datafile Analyzed: /chem/5972hp60.i/DF020314B60.b/DF020314B60.d/DF020314B60 .Method Used: /chem/5972hp60.i/DF020314B60.b/dftpp8270C.ra/BrkDwnTF.m Inst: r_njection Date: 14-MAR-2002 20:31 Operator:Sample]Info: DFTPP DFTPP:2319
Misc Info:
5
5-
HF MS DF020314860.d. Ion 235.00
Ion 235
P.06 9.09 9.12 9.15 9.18 9.21 9.2-4 9.27 9.30 9.33 9.36 9.39 9.42 9.45 9.43 9.51 1______ Time (Min) ________________________ _________ __
HP MS DF020314860.d. Scan 250: 9.257 min.• • '235 ’’,
199
240 260 2d'
- DDT
219
ixr . a
Fount
Mass Area Ratio
; 2 0 75 10 0.00
666
.d5972h
.54
1 0 0.0 0
Report.
^^iyi
m
Method
Dace: 03/14/2030 22:06
Datafile Analyzed: /chem/5972hp60.i/DF020314B60.b/DF020314B60.d/DF020314B60.dUsed: /chem/5972hp60.i/DF020314B60.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h
r njection Date: 14-MAR-2002 20:31 Operator:Sample| Info: DFTPP DFTPP:2319
Misc Info:
5. J-
5.1-
4.8-
4 . 5-
4.2-3.9- '
3.6-
3.3-
3 n-
2.1-
1 *3-.
1.5-
1.2-
0.9 0. 6
HP M5 DF020314B60.d. Ion 235.00
Ion 235
a.5-
5-
5
•*T 4
5.61 8.64 8.62 8.30 8.33 8.76 S.7Q 8.82 3.85 8.88 8.91 8.94 8.97 9.00 9.03 9.06 9.09 9.12 9.15 9.18___________ T ime (Hin)________ ___ ______ ______ ________ ___ ________________
HP MS DF020314B60.d. Scan 228: 8.805 min.2b3""’
5-. !!
103 ,281
317345
240 260 280 300
380 384
I 380
4,4'-DDD =======L
Exp. RT Found RT
Mas;
235
.98 9 ! 8 5o .
Area Ratio
61380 100.00
66i
Reoort Date: 03/14/2030 22:06
Datafile Analyzed: /chem/5 972hp6 0.i/DF02 0314B60.b/DF02 0314B60.d/DF02 0314B60.dMethodJused: /chem/5972hp60.i/DF020314B60.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h ‘njection Date: 14-MAR-2002 20:31 Operator:ample|Info: DFTPP DFTPP:2319
Misc Info:
800-
750-
700-
650-'
600-
550-'
500-
450-
4Q0’
300-
250-
200-
I50r
100-
50-
hP mS 0F020314B6U. d. Ion 246.00
Ion 246
O'J'J-
560-
520-
401.'
J4ij
•400
360 ■
260
240
160
1 20
30 •
25 8.28 3.31 8.3*4 3.37 8.40 3.43 8.46 0.49 8.52 8.55 8.58 8.61 8.64 8.67 8.70 8.73 8.76 3.79__ Time (Min; _____________________
HP MS DF020314E60.d. Scan 205: 8.495 min.207-
•246
281- 316
12510"
I 328
j:j!|i'll!
240 260 280 220
4,4'-DD
txp . Found RT
Mass
246
8.583 8 .495
Area Ratio
3 6 7 10 0.00
67G
7.0-
5.0-
- . 0-
2.0-
2.0-
1 .0-'
4. 5-
4.2-
2 G-
9.00 9.10 9.20 9.30___ Time (Min)_____
HP m3 DFu20314Ef6u . Ion
i £CD
9.40 9.50
'35.00
Compound: 4,4'-DDT
Quant Mass: 235
RT: 9.257
Area: 962075
Compound: 4,4'-DDD
Quant Mass: 235
RT: 8.885
Area: 61380
0.9-
0.6
0.3-
650-
600-
550 ■
50 '0 -
4 50
400
350
l ft.= : M i n )
314660^*5. Ion 046
t
9.10
250
200
Compound: 4,4'-DDE
Quant Mass: 246
RT: 8.495
Area: 867
DDT D^GRADATiOl BREAKDOWN ANALYSIS SUMMARY-=========================================-=============+
Comocund | Resoonse I ^Breakdown I Max Allowed I Test I+
4,4 - DDT 962075 N/A4,4-DDE 867 0 . 1 20.0 PASS4,4-DDD 61330 6 . 0 20.0 PASS4,4-DDD - DDE 6 2 2 4 7 6 . 1 20.0 PASS
+
■k'k'k^-k-k-k'ir-k-k-k-k-k-k
RLE *** PASSED *** DDT BREAKDOWN TEST
67
Data F i 1 a; /char«-i/5?72hpl.:'4. i/DF020310A64 *b/DF0203'10ft64 .d I
Date : iojt1AR-2002 13:53
Client ID: DFTPPI
'sample Info: DFTPP:231?I
Volume In,iacted m.jLJ j j*•:>
Co I umn phii.e; J-'M'J DE5 * C25
1 Dae af 1 ucrotr i pheny 1 pho = f-4'i i na
Operator: 231?
Column diameter: 0*32
I nstrument: 5?72hp64*i
Instrument: 5972*hp64. i
Dat b F11 ■=•: .•'•:.h*M/5972hp64. i,''E1Fv2,",31vh^4.6/1^020310864*<:Ji
Date : lOj-MAP.-zoo/ 13:53
Client ID1: DFTPP
ISample Info: DFTPP:231?
Volume IrJieoted ’.uL>: 2,0 Operator': 231?
Column phk=e: i;,W PBS.625 Column diameter: 0.32
Data File: DF020310A64.d
Spectrum: Avg. Scans 185-187 ( 8*17), Background Scan 182
Loeaticn of Maximum: 193,00
Numk«?r of points: 274
>1/Z "■| m/z Y m/z Y m/z Y
1 *1 , 36.00 32 1 12?.00 35416 1 200.00 862 233.« 463 1
1 37*00 534 1 130,00 2?07 1 201,00 766 284,CO 166
1 38.00 1371 131.00 562 1 203,00 1087 235.CO 4S4 1
1 38.00 7424 132.00 276 1 204.00 5265 286.CO 70 1
1 45.00 104 133,00 82 1 205.00 8343 283. CO 32 1
1 + *
1 4?. 00 777 134.00 1013 1 206.00 36230 1 290.CO 74 1
1 50.00 24072 135.00 2530 1 207.00 4323 1 231. CO 70 1
1 51 * oo 35936 136.00 1131 1 203,00 1376 1 292,CO 117 1
I .... ', 4383 137.00 1235 1 203.00 437 1 293,CO 645 1
J 53 * 00 20 7 133.0.0 261 1 210.00 747 1 294.CO 13S 1
1 r.p, ,-Vi 1 138.00 195 1 211.00 1543 1 236.CO 3322 1
! ro i ii"i 2278 f 140.00 412 1 213.00 75 1 237. CO 1337 1
1 i r,7 5Si2S 1 141.00 4314 l 215.00 416 1 293,CO 71 11 l
61. Ou 105.5 1 142.00 1375 1 217.00 . 10601 1 301,CO 104 11
02.00 1247 143.00 961 1 218.00 113? 1 302,CO 165 t
1
1 63.00 31S1 144.00 253 1 219.00 10? 303,CO 1006 1
1 64.v11 483 145.00 271 l ..... . ?.,17 304,CO 221 1
1 05.00 ■15--.4 146.00 SO? 1 227.00 2344 303.CO 11? 1
1 67.01'1 11 147,0.':. 1894 1 224 00 ■ i-i^c; -- 309.CO 80 1
1 C?.o,'. 1''6582 143.00 5233 l 225.‘''0 5020 310.CO 115 1
1
t 7'.'.'.".' 2'23 148.'".' 1060 1 227.Ou 8941 313.CO 0 7
1 T7. O'"1 150.no 296 1 223. O'-1 120; 714. Cv 416
i 74 ■ ::3-‘'' 1 151. ■'.■ • 492 l 229. • * 1701 315.‘ 1076
i t r . •,, , 123C4. 152.00 138 1 23'.'. 255 316.00 530
i 4273 153.00 123- : 23l..,0 666 317.CO S3
1
i 77. v ’ "r476-'1 i 154.uO 876 1 232. ■ >0 ■86 721.CO 258 1
: 5.,-ic 155. OO- 2030 : 277.00 122 1 323.CO 3094 1
! 70 . , n • 6138 ! « rlk:, . 1, 1 28ii : 3 74 . 5 1 324.CO 536 1
1 s 4'>86 1 157.on 670 1 275.nn . -07 1 327.CO 645 1
1 31.0., 5721 1 153. 46" 1 2 3n. 4 27 1 328 CO 254 1
! i 1512 1 15?.'"-. 53’ 9 1 27-V.n 583 1 332. CO1 I'd 8 1
1 12vi: 1 160.0' ■ 1-27 1 27:'.”0 34 1 333 ~,/'1 260 1
1 24 . • . 15 1 161. ■ 17-41 ’ 279 ■ •v 747 1 334,CO 1353 1
i ,::rri . 1172 1 102..>, 4 72 1 24 0 00 237 1 !■ 1-Zj . 463
1 1737 1 1. 189 ! I-U . ■ " 4 5t 1 341.CO 462 1
Data F i 1 ■=•; /cher-i. '5972hp64* i/DFO20310H64 *1:i/DF020310h64 . d
Hat* : lo-jMftR-2002 13:53
IIlent ID: DFTFPI
Sample Inty;.; DFTPP;2319
"‘o 1 urn* I n j f *d (. uL): 2. u
Column ph-i-H; 3Ul DE5.625
Operator: 2319
Column diameter; 0.32
Instrument: 59721*ip64.i
Data File: DF020310A64.d
Spectrum: Hvg. Scans 185-187 C 8.17), Background Scan 182
Locat of Maximum: 198.00
Humlrer of points: 274
*i/Z v m/z V m/z V
1
m/z Y
1+ +
1 87.00 594 1 164.00 213 1 242..00 1022 t 342.CO 36 1
i ss.oo 7*33 1 165.00 1736 ! 243. 00 1196 1 346.00 612 i
1 S'?, oo 192 1 166.00 1193 1 244. 00 16536 1 347.CO 94 1
1 91.00' 1447 1 167.00 3362 1 245. 00 2259 1 352,CO 933 i
1 1405 1 168.00 3774 1 246. 00 3039 1
*
353. CO 571 f
*
1 93.00 11.351 l 169,00 686 1 247. 00 565 1 354.CO 1024 1
[ 94.00 ^*-.7 1 170.00 316 1 248. 00 111 1 355.CO 199 1
1 95.00 146 1 171.00 301 1 249. 00 577 1 365.CO 4125 i
1 96.00 355 1 172.00 691 1 250. 00 97 1 366.CO 552 1
1 98. CO.- S513 1 173.00 858 1 251. 00 102 1
1
370.CO 94 1
*1 1
1 53*0 1 174.00 1607 1 00 130 1 371. CO 205 1
1-‘1.00 27->l 1 175.00 2792 1 “'57 00 264 1 372.CO 1733 t
i 102. .-o 198 1 176.00 830 1 •or.r, no 75736 l 373.CO 359 1
' 103.oo 1150 1 177.00 1622 1 256. 00 10989 f 333.CO 355 i
i iv4 .0"? 2153 1 178.00 195 1 257. 00 804 1 384*CO 99 1
1 1
1' ‘5 *1 2-’73 1 179.00 6273 1 258. •0 4506 1 390,CO 134 1
! l1 '7.1111 242O0- t 180.00 3904 1 “ P,v. 00 677 1 391.CO 146 1
1 1-S.oO 7789 1 181.00 1901 t 260. 00 109 1 392.CO 38 I
110.00 43520 1 132.00 32" 1 261. 00 97 1 401.CO 92 1
] 111.00' -13 l 187.00 203 1 264. 00 145 1 402.CO 646 1
1 112. ::81 1 184.00 230 1 “'i: 5 .00 1952 1 403.CO 1037 1
] 113."':' 71" 1 135.00 2706 i 266..'■'0 421 1 404.CO 260 1
■ 1 1 [T , ,, . 199 l 186.00 19934 267..00 36 1 421.CO 847 1
' 24712 1 137. O'". 567 4 1 270,. Ov 7o 1 422.CO 730 1
1 US."' 1"1" 1 1S-3.0, 1200 ■ 271. 137 1 423.CO 7135 1
1 119.00 144 1 1-;.o. 263 1 273 .V'J 2452 1 424.CO 1356 1
120.00 295 t 191.00 c-2" 1 274 .■•■0 ►2-678 1 425.CO 110 1
i 121.00- ?? 1 192.0- 2142 1 -.■TP, 36240 1 441.CO 19496 1
1 132.'V. 106.9 1 193.00 1980 ! 2"6 . 00 4790 1 442.CO 134843 1
1 123 tVi 25-4 5 1 194.no 42" 1 27" . oo 2957 1
1
443.CO 26104 l
1 124.0-'- 1270 1 195.00 224 1 273 . oo 473 1 444. CO- 2409 1
1 125. ■■■■ l.;r,:. 1 196.vv 4 f 55 1 279 . O'O 75 1 445.CO 121 1
i 127.'." ■ "3152 1 ■ 193.00 131952 1 231 .0'-' 73 1 1
12-:.'"' 0117 1 1 11951 ! l-"’4 1 1
674
Dat a Fi le: /chem/5972hp64.i/DF020310AC.4,b/DF020310fl64.d
Date : 10-HAR-2002 13:53
Client ID: DFTPP Instrument: 5972hp64.i COSample Info: DFTPP;2319 h-Volume Injected <uL)j 2.0 Operator: 2319 CDColumn phase: J&W DBS.625 Column diameter: 0.32
/chem/5972hp64*i/DF020310A64 * b/DF020310A64.d
5*b:
5.4-
5*2-
5,0-
4.8-
4,6-
4.4-
4,2-
ui
2.4 -
2. 0 -
i. s
1 , b ^
1.4-|
1.2-
1 * 0 -
b , ‘o b . 9 7 * S 8.1 8.4
i I j “ kJr'.
1 * 2 10. 5 l" 11.1 11.4 11.7 12.- L 2.7 12.0 li 13*84
TAILING FACTOR and DEGRADATION SUMMARY RESULTS
DECAFLUOROTRIPHENYLPHOSPHINE Ion Abundance/Rati.o Criteria Chart
H--------^°n | Abundance Criteria Base Peak Other | Test
*98Base Peak, 100% relative abundance 100.00 PASS
51 3 0 - 80% of mass 198 47.23 PASS68 Le ss than 2% of mass 69 0.00 ( 0.00) PASS69 Ma ss 69 relative abundance 58.59 PASS70 Lejss than 2% of mass 69 0.12 ( 0.21) PASS
127 25 - 75% of mass 198 42.95 PASS197 0 - 1% of mass 198 0.00 PASS199 5 - 9% of mass 198 6.57 PASS275 1 0 - 30% of mass 198 19.92 PASS365 Greater than 0.75% of mass 198 2.27 PASS441 Present, but less than mass 443 10.72 ( 74.69) PASS442 40 - 110 % of mass 198 74.12 PASS443 15 - 24% of mass 442
i14.35 ( 19.36) PASS
TAILING ANALYSIS SUMMARYi
Compound
PentachiorophenolBenzidine
Tail Factor Max Allowed Test
0 . 0 5.0 PASS0.8 3 . 0 PASS
DDTiDEGRADATION BREAKDOWN ANALYSIS SUMMARY
| Compound Response %Breakdown Max Allowed Test
B 4,4-DDT
W 4,4-DDE2311475
1256 0.1 20.0N/APASS
| 4,4-DDD 19 8 4 4 0 . 9 20.0 PASSi 4,4-DDD * DDE
I21100 0 . 9 20.0 PASS
= = = = == H
Tuning Sample, /chem/5972hp64.i/DF020310A64.b/DF020310A64.d/DF020310A64.d
*** PASSED ***
67b
TAILING FACTOR and DEGRADATION SAMPLE AND GRAPHIC■REPORT
ort Date: 03/11/2030 08:43
Datafile Analyzed: /chem/5972hp64.i/DF020310A64.b/DF0 20310A64.d/DF020310A64.d Method Used: /chem/5972hp64.i/DF020310A64.b/dftpp8270C.m Inst: 5972hp64Injection Date: 10-MAR-2002 13:53 Sample Info: DFTPP DFTPP:2319 M i s c Info:
Operator: 231.9
5.6-
5.4-.
HP MS DF020310P64.d
ii'-i 'Hi—m
•r COf-.-C-C' JJf-'IT J
oj rr*7-nnnF'-: t n .,?/
67
Report Da te: 03/11/2030 08:43
Qaraf ile Analyzed: /chem/5972hp64.1./DF020310A64 . b/DF020310A64 . d/DF020310A64 .d •hod Us|ed: /chem/5 972hp64 . i/DF02 0310A64 . b/df tpp82 70C . m Inst: 5972hp64 ^^ection; Date: 10-MAR-2002 13:53 Operator: 2319
Sample In'fo: DFTPP DFTPP:2319 Misc Info:
2.6-
HP M5 DF0203iG464.d
n.
1 . b
1.2-;
0.6
0. 4-
8.0 8.1 8.2 Tim-? 'Min.1
8.3 3.4 3.5 8.6
HP MS DF020310A64.d. bean 186: 8.170 min. 198
255
275
323
340 330 380 400
DECAFLuOROTRIPHENYLPHOSPHINE Ion Abundance/Ratio Criteria Chart
I on Abundance Criteria Base Peak Other Test |
1 9 S j S a s e Peak, 100% relative abundance 100.00 PASS51 3 0 80% of mass 198 47.23 PASS31 Les s than 2% of mass 69 0.00 ( 0.00) PASS
6 9 Mas s 69 relative abundance 58.59 PASS70 Less than .2% of mass 69 0.12 ( 0.21) PASS
127 25 75% of mass 19 8 42 . S5 PASS197 1 o 1% of mass 198 0.00 PASS1 ? 5 | 5 9% of mass 198 6.57 PASS
i n 30% of mass 198 19.92 PASSGre ater than 0.75% of mass 193 2.27 PASS
Rl! sent, but ^ =ss than mass 443 10.72 ( 74.69) PASSia? ! 40 - i :J O Cl- IT; cl S S J. 9 5 74.12 PASS44 3 | 15
ii q, _ .c _ __ _ « .1 ^jL ~t 'o C i. :. i ci br 4 % Z 14.35 ( 19.36)
= = = +
445
44m
.592
Report Date: 03/11/2030 0S:43
:afile Analyzed: /chem/5972hp64.1/DF020310A64.b/DF020310A64.d/DF020310A64.d Ipoa Used: /chem/5972hp64.1/DF020310A64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h rect ion! Date : 10-MAR-2002 13:53 Operator:
Sample Info: DFTP? DFTPP:2319 Mi sc Info!:
HP M'z DF020310H6*1 . d. Ion
Ion 266
Tailinq Factor* = 0.00000
i.
i.
0.3
Time- < Mi.00 3.05 8.10
HP M'S DF020 b 1 0h6-i . d. Scan 165: 7.615 min.
HP MS DF020310H6J Ion 266.00
.60 7.70 7.90 7.9STime (Min)
3.1'!
- :-:p .' c-cnd
7.830
7.31b
toe' i
Rat ic
100.00
;wea = n
Tailing Factor < 1.0, then it is assumed that the peak is not tailing and Tailmo Factor of zero is retorted.
^ Uh
03/11/2030 08:43report Date:
atafile Analyzed: /chem/'5972hp64 . i/DF020310A64 . b/DF020310A64 . d/DF020310A64 ,thod Used: /chem/5 972hp64 . i/DF020310A64 . b/df tpp82 70C . m/BrkDwnTF . m Inst:action Date: 10-MAR-2002 13:53 Operator:
ample Info: DFTPP DFTPP:2319 isc Info:
n? MS D F t'j'.'S 1 uhcM . d , Ion 18*4.0'. HP MS DF020310h6*4 r$. Ion 184.00CM
Ion 184
Tailing Factor = 0.79167
b. 6-
6. 4- 6. 0-'
5.6-
5.2z
4.8-
4.4- ; 4. o-:
3. b
3.2
2.8-
2.4-
2.0-
. 6-
.5'!' 9.55( h : n )
HP~S~
?. 60
DF020:
9.65 9. 9.80 9.30 9.40 9.50 9.60Time (Min)
1 0w64 ' 1S4
. d. Scan 266: 9.522 min.
; cr-7 ■yi 34 1 355
300 340 p60 ;>80
Rat: io
0 0
i :~.a e n zidine
Maximum Allowed = 3.0
Cl
1.0. then it is assumed that the peak is not zero is retorted.
.d5 9 7 2 h
680tailing and
XtiCGT b' J> 1/2030 08:43
Datafile Analyzed: /chem/5972hp64.1/DF020310A64.b/DF020310A64,d/DF020310A64.dod Usjed : /chem/5 972hp64 . i/DF020310A64 . b/'df tpp8270C . m/BrkDwnTF . m Inst: 5972h
ectionl Date: 10-MAR-2002 13:53 Operator:
fo: DFTPP DFTPP:2 319Sample In Mi sc Info
HP MS DP'j203l0H64.d. Ion Z'j5.00
Ion 235
.o.4j 10.65 10.66 10.71 10.74 10.: T i m.-r (Min)
10.bO 10.63 10.86 10.69 10.92 10.95 10. '48 11.01 11.04
HP Mb DP 020310wP,4 . a . Scsn 338: 10.74>j min.
105
r oun 4. U . / *4
Area Ka o
0 0
68
;DOr' ace
m
03,'ll/'2030 03:4:
Datafile thod U jection mple I sc Inf
Analyzed: /chem/5972hp64.1/DF020310A64.b/DF020310A64.d/DF020310A64
M:
;a : / chem/ 5 9 72hpS4 . i,/DF02 0 310A64 .b/'dftpp8270C. m/BrkDwnTF . m Date: 10-MAR-2002 13:53 Operator:
Inst :
nr o o :
DFTPP DFTPP:2 319
HP M5 DF02G3 1 0h64 . cJ. Ion 235.00
Ion 235
ii o. ■’ 3 10.11 10.14 10.17 10.70 10.23 10.26 10.29 10.32 10.35 10.38 10.41 10.44 10.47 10.50 1C
„ ,, - — T 1 me '• H 1 n ) _____._ _____ ________ __ _____________________HF m3 DF020310064 . d . 5c-an 309: 10.249 min.
318
34i; 36'.'
;• :-\;no3 0
a Ratio
100.00
681
i
i
.d5 9 7 2 h
.53
405
Dace: 03/11/2030 03:43Rerx
Datafile Analyzed: /chem/5972hp64.i/DF020310A64.b/DF020310A64.d/DF020310A64 thod Used: /chem/5972hp64.i/DF020310A64.b/dftpp8270C.m/BrkDwnTF.m Inst:mjection Date: 10-MAR-2002 13:53
Sample Info: DFTPP DFTPP:2319 Wise Inf'o:
Operator:
HP MS DF020310A64.a. Ion 246.00
Ion 246
l
10. o;
JoU: y./oy min,
281.
316 358
2d1.1 JdO
•-••ass
7 9 075 9
ea Ratio
D 6 10 0. 0 0
,d5 972h
10.05
4
400
68 j
— 0.5-
Compound: 4,4'-DDT
Quant Mass: 235
RT: 10.740
Area: 2311475
h F M 5
1 . 0-
10.30 10.70 10.
F \ m-? f, M i n '
DF020310OK4 4ji. Ion
10.00 ~*hF’"’Tb
F i mo •; M : f !>31 O^O- ,-c
iO.JO 10.50
Compound: 4,4'-DDD
Quant Mass: 235
RT: 10.249
Area: 19844
Compound: 4,4'-DDE
Quant Mass: 246
RT: 9.759
Area: 1256
DDT DEGRADATION BREAKDOWN ANALYSIS SUMMARY
TL
Compound j Response %Breakdown I Max Allowed!Test
,1*-£,4 - DDT j 2311475 i i N/A
4 ,4-DCjE i 12 5 6 | 0.1 | 20 . 0 PASS4 , 4-DD>D | 1 9 3 4 4 0.9 20 . 0 PASS4-DDD + DDE ; o r “i r. r | 0.9 20.0 PASS
. ZL CD CD■TIP + ★ * d ; .Qs"?: * * + DDT BREAKDOWN TEST 684
Data File: /chem/5972hp64. i/DF020311A64.b/DF020311A64.d Date : llj-MAR-2002 08:32
,Client ID: DFTPPI
Volume Injjected CuL>: 2,0
Instrument: 5972hp64,i
40 60 80 100 120 140 160 180 200 220 240 2m/z
60 280 300 320 340 360 380 400 420 440
X RELATIVE
m/e ION ABUNDANCE CRITERIA ABUNDANCE
I 198 Base Peak, 100# relative abundance 1 100*00 1
1 51 30*00 - 80*00# of mass 198 1 50.10 1
1 68 Less than 2*00# of mass 69 1 0.00 < 0.00) 1
1 6'? Hass 69 relative abundance 1 61.28 1
1 70 Less than 2*00# of mass 69 1 0.30 < 0.49) 1
1 127 25.00 - 75.00* of mass 198 1 43.64 1
1 l'?7 Less than 1*00# of mass 198 1 0,00 1
1 1?'? 5.00 - 9.00* of mass 193 1 6.75 !
1 10.00 - 30.00* of mass 193 1 20.20 1
1 Creater than 0.75# of mass 198 1 2.29 l
! 441 Present, but less than mass 443 1 10.15 i
1 442 40.00 - 110.00* of mass 193 1 69.71 1
9 1 447 15*00 - 24*00?* of mas ^ 442 1 13.23 < 18.97) 1
*
CD
CO
L.V
Data File: /chem/5972hp64.i/DF020311A64.b/DF020311A64.d
Date : llyMAR-2002 08:32
|Client ID: DFTPP
Sample Info: DFTPP:2070
Instrument: 5972hp64.i
Volume Injected <uL); 2,0 Operator: 2070
Column phase J8.W DB5.625 Column diameter: 0,32
Data File; DF020311A64.d
Spectrum: Avg. Scans 184-186 < 8.16), Background Scan 181
Location of Maximum: 198.00
Number of points: 227
I
i
m/z Y m/z Y m/z Y m/2 Y
11 1 1 1
1 36.00 19 116.00 339 1 180.00 1615 1 257.00 360 1
1 37.00 264 i 117.00 10172 1 181.00 817 1 258.00 1823 1
1 38.00 700 i 118.00 708 1 182.00 105 1 259.00 241 1
1 39*00 3419 119.00 256 1 184.00 2 1 265.00 911 1
1
1
41*00 . 111 120.00 96 1 185.00 1172 1 266.00 112 1
1 1
1 45.00 227 122.00 707 1 186.00 8443 1 271.00 68 1
1 49*00 273 i 123.00 1091 187.00 2392 273.00 959 1
1 50.00 10887 124.00 523 1 189.00 438 274.00 2771 1
1 51*00 39152 125.00 436 190.00 80 1 275.00 15786 1
I 52.00 2012 127.00 34104 191.00 309 276.00 2154
1 53.00 73 128.00 2683 192,00 832 277.00 1164 1
1 55.00 206 129.00 14904 193.00 860 278.00 174
1 56.00 1335 130.00 1282 1 194.00 201 1 281.00 174 1
1 57.00 2884 131.00 291 1 195.00 119 1 282.00 276 1
1 53.00 83 132.00 67 196.00 1931 283.00 300
.
1 61.00 497 133.00 48 1 198.00 78152 284.00 85 1
1 62*00 550 134.00 448 199.00 5273 285.00 181
1 63.00 1433 135.00 1050 200.00 363 1 293.00 258 1
1 64.00 207 136*00 450 1 201.00 325 296.00 4014 1
1 65 * 00 745 i 137.00 570 1 203.00 493 297.00 587 1
1
1 67.00 149 140.00 179 204.00 2182 303.00 468 1
1 69.00 4733S 141.00 1752 205.00 3813 1 304.00 126 1
I 70.00 233 1 142.00 600 1 206.00 15594 1 314.00 143 1
1 73.00 341 1 143.00 407 1 207.00 1982 315.00 393 1
1 74.00 3723 1 144.00 69 1 208,00 486 316.00 197 1
1
1 75.00 5943 1 145.00 75 1 209.00 183 321.00 105 1
l 76.00 1789 1 146.00 323 1 210.00 330 323.00 1294 1
1 77,00 34512 1 147.00 863 1 211.00 663 1 324.00 209 1
1 78.00 2134 1 148.00 2156 1 215.00 157 1 327.00 234 1
1 7':1.00 2631 1 149.00 453 1 216.00 337 1 328.00 103 1
1
1 SO. 00 1981 1 150.00 87 1 217.00 4447 l 332.00 81 1
1 31.00 271S 1 151.00 216 I 213.00 553 1 334.00 812 1
1 82.00 677 1 153.00 585 1 221.00 3835 1 335.00 185 1
1 33.00 593 1 154.0') 466 1 223.00 947 1 341.00 162 1
1 35.00 444 1 155.0') 872 1 224.00 8604 1 346.00 211 1
686
Data File: /chem/5972hp64.i/DF020311A64.b/DF020311A64.d
Date : ll-MAR-2002 08:32
Client ID: DFTPP
Sample Info: DFTPP:2070
Volume Injected <uL>: 2.0
Column phase: J8.U DB5.625
Operator: 2070
Column diameter; 0.32
Instrument: 5972hp64.i
Data File: DF020311A64.d
Spectrum; Avg. Scans 184-186 ( 8.16), Background Scan 181
Location of Maximum: 198.00
Humber of points: 227
m/z . Y m/z Y m/z Y m/z Y
11 1
1 86.00 888 156.00 1312 1 225.00 2157 1 352.00 331 1
l 87*00 394 157.00 286 227.00 3736 1 353.00 198 1
1 88.00 81 1 158.00 375 i 228.00 546 1 354.00 373 1
1 91.00 779 1 159,00 256 i 229.00 693 1 355,00 93 1
92.00 680 160.00 572 231.00 227 365.00 1790 1
93.00 4750 161.00 803 234.00 175 1 366.00 187 1
94.00 405 162.00 243 235.00 181 371.00 71 1
95*00 70 I- 163.00 71 236.00 135 372.00 663 1
96.00 263 165.00 761 237.00 218 373.00 153 1
98.00 3473 166.00 546 i 239.00 114 1 383.00 142 1
99.00 2503 167.00 3398 240.00 82 402.00 238
100*00 254 168.00 1764 i 241.00 165 403.00 431 1
101*00 1383 169.00 286 i 242.00 455 404.00 132 1
103.00 558 170.00 86 i 243.00 465 421.00 297 1
104.00 905 171.00 86 244.00 7050 1 422.00 263 1
1
105.00 882 172.00 295 245.00 913 423.00 2853 1
107.00 10174 1 173.00 350 246.00 1180 424.00 552 1
103.00 1584 174.00 675 247.00 186 1 441.00 7934 1
110.00 21536 175.00 1165 249.00 282 1 442.00 54480 1
111.00 3093 176.00 393 i 253.00 218 1 443.00 10337 1
1 1 1
112.00 372 177.00 786 1 255.00 32256 1 444.00 962 1
113.00 75 1 179.00 2708 ! 256.00 4692 1 1
68/'
(xlO)
Data File: /chem/5972hp64.i/DF020311A64.b/DF020311A64.d
Date : ll-MAR-2002 08:32
Client ID: DFTPP
Sample Info: DFTPP:2070
Volume Injected (uL): 2*0
Column phase: J&W DB5.625----------------- " /chem/5972hp64. i /DF020311A64. b/DF020311A64. d
3.0-1
2,9-j
2.8-j
2.7-j
2.6-j
Instrument: 5972hp64.i
Operator: 2070
Column diameter: 0.32
2.5- :2.4- j
2.3- j
2.2- j
2.1-:
2.0-; i.9-i
1.8-j
1.7-j
1.6- 11.5- j
1.4- ;
1.3- ;
s:a.
rtO.C
T) C <b
. .C C_
5 5*7 6.0 6*3 6*6 6.9 7.2 7.5 7*8 8.1 3*4 8.7 9.9 10.2 10*5 10.3 11.1 11.4 11.7 12.0 12.
:oooCO
5 1
I TAILING FACTOR and DEGRADATION SUMMARY RESULTS
>nm
DECAFLUOROTRIPHENYLPHOSPHINE Ion Abundance/Ratio Criteria Chart
| Base Peak Other |Test|Abundance Criteria
198 Base Peak, 100% relative abundance 100.00 PASS51 30 - 80% of mass 198 50.10 PASS68 Less than 2% of mass 69 0.00 ( 0.00) PASS69 Mass 69 relative abundance 61.28 PASS70 Less than 2% of mass 69 0.30 ( 0.49) PASS
127 2 5 - 75% of mass 198 43.64 PASS197 0 - 1% of mass 198 0.00 PASS199 5 - 9% of mass 198 6.75 PASS275 1 0 - 30% of mass 198 20.20 PASS365 Greater than 0.75% of mass 198 2.29 PASS441 Present, but less than mass 443 10.15 ( 76.75) PASS442 4 0 - 110 % of mass 198 69.71 PASS443 1 5 - 24% of mass 442 13.23 ( 18.97) PASS
TAILING ANALYSIS SUMMARY
Compound Tail Factor Max Allowed Test
Pentachllorophenol 0.6 5.0 PASSBenzidine
i0.7 3.0 PASS
DDt| DEGRADATION BREAKDOWN ANALYSIS SUMMARY
^ Compound Response %Breakdown Max Allowed Test
4,4-DDT 1050204 N/A4,4-DDE 1721 0.2 20.0 PASS4,4 -DDD 9898 0.9 20.0 PASS
4,4-DDD + DDE1
11619 1.1 20.0 PASS
+
Tuning Sample, /chem/5972hp64.i/DF020311A64.b/DF020311A64.d/DF020311A64.d
PASSED
68
TAILING FACTOR and DEGRADATION SAMPLE AND GRAPHIC REPORT
ort Date : 03/11/2030 09:27
Datafile Analyzed: /chem/5 972hp64.i/DF02 0311A64.b/DF02 0311A64.d/DF020311A64.d Method Used: /chem/5972hp64.i/DF020311A64.b/dftpp8270C.m Inst: 5972hp64 Injection Date: ll-MAR-2002 08:32 Operator: 2070Sample Info: DFTPP DFTPP:2070 Misc Info:
690
Report Date: 03/11/2030 09:27
Datafile■Analyzed: /chem/5972hp64.i/DF020311A64.b/DF020311A64.d/DF020311A64.d^fcthod Used: /chem/5972hp64.i/DF020311A64.b/dftpp8270C.m Inst: 5972hp64^Jrjection Date: ll-MAR-2002 08:32 Operator: 2070
Sample Info: DFTPP DFTPP:2070Misc Info:
Report Date: 03/11/2030 09:27
Datafile
m
Analyzed: /chem/5972hp64.i/DF020311A64.b/DF020311A64.d/DF020311A64.d.thod Used: /chem/5972hp64.i/DF020311A64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972hection Date: ll-MAR-2002 08
DFTPP DFTPP:207032
Tample Info Misc Info:
Operator:
Exp. RT Found RT
Mass
266
7.8307.804
Area
42191
Ratio
100.00
Tailing factor for
filing Factor = 0
If Tailing Factor a Tailing Factor
Pentachlorophenol OK
.6 Maximum Allowed = 5.0
< 1.0, then it is assumed that the peak is not ta^^L'rig and of zero is reported.
Report Date: 03/11/2030 09:27
Exp. RT = 9.550Found RT = 9.512
Mass Area Ratio
184 454615 100.00
Tailing
i ling
factor
Factor
for Benzidine OK
= 0.7 Maximum Allowed 3.0
If Tailjing Factor < 1.0, then it is assumed that the peak is not t^Qlijng and
a Tailing Factor of zero is reported.
Report Date: 03/11/2030 09:27
Datafile Analyzed: /chem/5972hp64.i/DF020311A64.b/DF020311A64.d/DF020311A64.d
•thod Used: /chem/5972hp64 . i/DF020311A64 . b/df tpp8270C . m/BrkDwnTF . m Inst: 5972h jection Date: ll-MAR-2002 08:32 Operator:
Sample Info: DFTPP DFTPP:2070 Misc Info:
Found RT
M ass
2 3 F
10.729
Area Ratio
1050204 100.00
694
Report Date: 03/11/2030 09:27
Datafile! Analyzed: /chem/5 972hp64.i/DF020311A64.b/DF02 0311A64.d/DF020311A64.dJfcthod Used: /chem/5972hp64.i/DF020311A64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972hWPjection Date: ll-MAR-2002 08:32 Operator:
Sample Info: DFTPP DFTPP:2070Misc Irif'o:
4,4'-DDDi
Exp. Rif Found RT
Mass
235
10.28010.239
Area Ratio.
9898 ' 100.00
6 9 b
«taf ile : Analyzed: /chem/5972hp64 .i/DF020311A64.b/DF020311A64.d/DF020311A64.dkhod Used: /chem/5972hp64.i/DF020311A64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h
section Date: ll-MAR-2002 08:32 Operator:Sample Info: DFTPP DFTPP:2070 Misc Info:
Report Date: 03/11/2030 09:27
Exp. RT, = 9.790Found RT| = 9.748
Mass
246
Area Ratio
1721 100.00
69b
9.50 9.80 9.70 9.80 9.90 10.00l| T i me- < M1 n )
Compound: 4,4'-DDT
Quant Mass: 235 RT: 10.729Area: 1050204
Compound: 4,4'-DDD
Quant Mass: 235 RT: 10.239Area: 9898
Compound: 4,4'-DDE
Quant Mass: 246
RT: 9.748Area: 1721
DDT DEGRADATION BREAKDOWN ANALYSIS SUMMARY
Compound Response %Breakdown Max Allowed Test
4.4- DDT4.4- DDE
10502041721 0.2 20.0
N/APASS
4,4-DDD 9898 0.9 20.0 PASS4,4-DDD + DDE 11619 1.1 20.0 PASS
TUNE SAMPLE *** PASSED *** DDT BREAKDOWN TEST 69 7
Data Filet .'chem/5972hp64.i/DF020311B64.b/DF020311B64.d Date : 1i|mAR-2002 22:30
.Client ID: DFTPP
Sample Info: DFTPP:2319
Volume Injected CuL>: 2.0
Instrument; 5972hpfe4.i
Operator: 2319
Column phase: J&W DB5.625 Column diameter: 0.32
Data File: /chem/5972hp64.i/DF020311B64.b/DF020311B64.d
Date t lljMAR-2002 22:30
Client ID: DFTPP Instrument: 5972hp64.i
Sample Info: DFTPP:2319
Volume Injected <uL)r 2.0 Operator: 2319
Column phase: J&U DB5.625 Column diameter: 0.32
]| Data File: DF020311B64.d
Spectrum: Aug, Scans 184-186 < 8.16), Background Scan 182
Location of Maximum; 198.00
I Number of points: 259
m/z Y m/z Y m/z Y m/z Y
11 1 1
1 37.00 502 1 122.00 1510 i 189.00 1085 i 275.00 29688 1
1 38.00 1360 i 123.00 2234 i 190.00 224 i 276.00 4034 i
1 39.00 6449 1 124.00 1180 i 191.00 445 i 277.00 2518 i
1 45.00 96 i 125.00 795 i 192.00 1701 i 278.00 396 i
1 49*00 535 l 127.00 66784 i 193.00 1559 i 281.00 186 i
11 1 1 1
1 50.00 21216 1 128.00 5315 1 194.00 387 i 282.00 12 i
1 51*00 74752 1 129.00 29880 1 196.00 3725 283.00 491 1
1 52.00 3731 130.00 2593 198.00 147520 i 284.00 202 i
1 53 * 00 132 131.00 508 199.00 10148 285.00 436 1
1 56,00 2089 132.00 88 i 200.00 674 292.00 75 i
11
1 57.00 4961 133.00 140 201.00 622 i 293.00 381 i
1 60*00 72 134.00 877 203,00 977 i 294.00 223 i
1 61*00 1042 135.00 2023 i 204.00 4192 i 296.00 8180 i
1 62.00 1144 136.00 980 205,00 7521 297.00 1176 i
1
1
63,00 2923 137.00 1177 206.00 29680 i 301.00 67 i
1 64*00 425 138.00 273 207.00 4023 i 302.00 104
1 65.00 1253 139.00 182 208.00 1056 i 303.00 940 i
1 68.00 53 i 140.00 405 209.00 321 304.00 252 i
1 69.00 90392 141.00 3391 210.00 368 i 308.00 226 i
1
1
70,00 138 142.00 1238 211.00 1331 i 309.00 67 i
1 1
1 72,00 7 143.00 788 1 213.00 70 i 310.00 93 i
1 73.00 645 1 144.00 13? 1 215.00 355 1 314.00 385 i
1 --J o o 7096 1 145.00 228 l 217.00 8722 1 315.00 902 i
75.00 11014 i 146.00 800 i 218.00 1092 i 316.00 456 i
76.00 3295 1 147.00 1684 1 221.00 6651 t 321.00 283 i
1 1 1 1
1 77*00 65360 i 148.00 4408 1 223.00 1874 f 323.00 2608 i
1 78 * 00 4429 1 149.00 469 1 224.00 16324 i 324.00 450 i
1 79,00 5114 1 150.00 294 1 225.00 4236 1 327.00 554 1
80.00 3475 1 151.00 367 1 227.00 7460 i 328.00 295 i
81,00 4780 1 152.00 307 1 228.00 1020 1 332.00 160 !
1 1 1 1
32.00 1125 1 153.00 1099 1 229.00 1404 i 333.00 195 1
S3,00 90S l 154.00 875 1 230.00 216 1 334.00 1625 1
84.00 12 1 155.00 1814 1 231.00 578 1 335.00 424 1
85.00 477 1 156.00 . 2430 1 233.00 74 1 341.00 373 i
86,00 1430 1 157.00 537 1 234.00 444 1 342.00 83 1
Data File: /chem/5972hp64, i /DF020311B64. b/DF020311B64, d
Date : ll-MAR-2002 22:30
kClient ID: DFTPP
^Sample Info: DFTPP:2319
Volume Injected <uL): 2.0
Column phase: J&W DB5.625
Instrument: 5972hp64,i
Operator: 2319
Column diameter: 0.32
Data File: DF020311B64.d
SpectrumJ Avg* Scans 184-186 < 8.16), Background Scan 182
Location of Maximum: 198.00
Number of points: 259
m/z Y m/z Y m/z Y
1
m/z Y
1+ 1 1
1 87.00 888 1 158.00 573 1 235.00 469 1 346.00 599 1
1 88.00 302 1 159.00 506 1 236.00 354 1 347.00 82 1
1 89.00 190 1 160.00 1004 1 237.00 538 1 352.00 781 1
1 91.00 1062 1 161.00 1529 1 239.00 308 1 353.00 522 1
1 92*00 1174 1 162*00 415 1 240.00 212 1 354.00 817 1
*+ + 1 1
i 93.00 9544 1 163.00 197 1 241.00 390 1 355.00 136 1
1 94*00 438 1 164.00 212 1 242.00 887 1 365.00 3425 1
1 95.00 33 1 165.00 1214 243.00 978 1 366.00 500 1
1 96*00 238 1 166.00 1022 1 244.00 13619 1 371.00 162 1
1 98.00 7102 1 167.00 6946 245.00 1843 1 372.00 1437 1
** *
1 99*00 5037 1 168.00 3382 246.00 2541 373,00 403 1
1 100 * 00 491 1.169.00 561 247.00 533 383.00 371 1
l 101.00 2800 1 170.00 243 248.00 69 1 384.00 92 1
1 102.00 103 1 171.00 268 1 249.00 560 1 390.00 161 1
1
+
103.00 1040 1 172.00
1
625 251.00 150 1 391.00 105 1
*
I 104.00 1802 1 173.00 721 252.00 153 392.00 69 1
1 105.00 1718 1 174.00 1351 253.00 337 1 402.00 571 1
1 106.00 88 1 175.00 2370 255.00 62976 1 403.00 856 1
1 107.00 20528 1 176.00 894 1 256.00 9235 1 404.00 239 1
1 108.00 3282 1 177.00 1206 1 257.00 678 1 421.00 726 1
1
1 110.00 41904 1 178.00 326 253.00 3770 1 422.00 644 1
1 111.00 6063 1 179.00 5245 1 259.00 607 1 423.00 5603 1
1 112.00 573 1 180.00 3253 1 261.00 67 1 424.00 1075 1
l 113.00 310 1 181.00 1624 1 264.00 87 1 425.00 69 1
1 115.00 218 1 182.00 290 1 265,00 1669 1 441.00 15234 1
. .1
1 117.00 20568 1 183.00 189 1 266.00 279 1 442.00 104120 1
1 118,00 1520 1 184.00 298 1 271.00 151 1 443.00 20504 1
1 119.00 130 1 135.00 2263 1 272.00 96 1 444.00 1912 1
1 120.00 322 1 186.00 16220 1 273.00 2047 I 445.00 83 1
1 121.00 125 1 187.00 4608 I 274.00 5248 1
_____ znu____
TAILING FACTOR and DEGRADATION SUMMARY RESULTS
DECAFLUOROTRIPHENYLPHOSPHINE Ion Abundance/Ratio Criteria Chart
tffen| j Abundance Criteria | Base Peak Other |Test|
198 Base Peak, 100% relative abundance 100.00 PASS51 30 - 80% of mass 198 50.66 PASS68 Less than 2% of mass 69 0.04 ( 0.06) PASS69 Mass 69 relative abundance 61.26 PASS70 Less than 2% of mass 69 0.13 ( 0.21) PASS
127 25 - 75% of mass 198 45.26 PASS197 6 - 1% of mass 198 0.00 PASS199 5 - 9% of mass 198 6.88 PASS275 10 - 30% of mass 198 20.12 PASS365 Greater than 0.75% of mass 198 2.32 PASS441 Present, but less than mass 443 10.32 ( 74.28) PASS442 40 - 110 % of mass 198 70.57 PASS443 15 - 24% of mass 442
ii13.90 ( 19.70) PASS
TAILING ANALYSIS SUMMARY
Compound Tail Factor Max Allowed Test
Pentachlorophenol 2 . 1 5.0 PASSBenzidine
■i0 . 0 3.0 PASS
DDT DEGRADATION BREAKDOWN ANALYSIS SUMMARY
^ Compound Response %Breakdown Max Allowed Test
^ 4,4-DDT2067201 N/A
4,4 -DDE 3857 0.2 20.0 PASS4,4 -DDD 17219 0.8 20.0 PASS
4,4-DDD + DDE 21076 1.0 20.0 PASS
Tuning Sample, /chem/5972hp64.i/DF020311B64.b/DF020311B64.d/DF020311B64.d
*** PASSED ***
7 Oi
TAILING FACTOR and DEGRADATION SAMPLE AND GRAPHIC REPORT
ort Date : 03/11/2030 23:29
Datafile.Analyzed: /chem/5972hp64.i/DF020311B64.b/DF020311B64.d/DF020311B64.d Method Used: /chem/5972hp64.i/DF020311B64.b/dftpp8270C.m Inst: 5972hp64 Injection Date: ll-MAR-2002 22:30 Operator: 2319Sample Info: DFTPP DFTPP:2319 Misc Info:
703
Report Date: 03/11/2030 23:29
Jection Date: ll-MAR-2002 22:30 Operator: 2319
Sample Info: DFTPP DFTPP:2319 Misc Info:
Datafile 'Analyzed: /chem/5972hp64.i/DF020311B64.b/DF020311B64.d/DF020311B64.dkhod Used: /chem/5972hp64.i/DF020311B64.b/dftpp8270C.m Inst: 5972hp64
198 Base Peak, 100% relative abundance 100.00 PASS51 30 - 80% of mass 198 50.66 PASS68 Less than 2% of mass 69 0.04 ( 0.06) PASS69 Mass 69 relative abundance 61.26 PASS70 Less than 2% of mass 69 0.13 ( 0.21) PASS
127 25 - 75% of mass 198 45.26 PASS197 0 - 1% of mass 198 0.00 PASS199 5- 9% of mass 198 6.88 PASS275 id - 30% of mass 198 20.12 PASS^6 5 Greater than 0.75% of mass 198 2.32 PASSm Present, but less than mass 443 10.32 ( 74.28) PASSW4 2 40 - 110% of mass 198 70.57 PASS44 3 15; - 24% of mass 442 13.90 ( 19.70)
Report Date: 03/11/2030 23:29
Datafile|Analyzed: /chem/5972hp64.i/DF020311B64.b/DF020311B64.d/DF020311B64.d J^ihod Used: /chem/5972hp64.i/DF020311B64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h ^Hjjection Date: ll-MAR-2002 22:30 Operator:
Sample Info: DFTPP DFTPP:2319 Misc Info:
Pentachlorophenol
Exp. RT Found RTl
7.830 7.803
Mass Area Ratio
266 93234 100.00
Tailing
fil ing
factor
Factor
for Pentachlorophenol OK
= 2.1 Maximum Allowed 5.0
70 j
Report Date: 03/11/2030 23:29
Datafile;Analyzed: /chem/5972hp64.i/DF020311B64.b/DF020311B64.d/DF020311B64.d
• hod Used: /chem/5972hp64.i/DF020311B64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972hection Date: ll-MAR-2002 22:30 Operator:
Sample Info: DFTPP DFTPP:2319 Misc Info:
Exp. RT i = 9.5 50Found RT 1 = 9.527
Mass Area Ratio
184 ( 924932 100.00
Tailing factor for Benzidine OK
ling Factor = 0.0 Maximum Allowed = 3.070ou
If Tailing Factor < 1.0, then it is assumed that the peak is not tailing and a Tailing Factor of zero is reported.
Report Date: 03/11/2030 23:29
^^jection Date: ll-MAR-2002 22:30 Operator:
Sample Info: DFTPP DFTPP:2319 Misc Info:
Datafile|Analyzed: /chem/5972hp64.i/DF020311B64.b/DF020311B64.d/DF020311B64.dhod Used: /chem/5972hp64 . i/DF02 0311B64 . b/df tpp8270C . m/BrkDwnTF. m Inst: 5972h
Found RT = 10.744
Mass Area Ratio
235 1 2067201 100.00
Datafile[Analyzed: /chem/5972hp64.i/DF020311B64.b/DF020311B64.d/DF020311B64.d Jfcthod Used: /chem/5972hp64.i/DF020311B64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h ^Hectiori Date: ll-MAR-2002 22:30 Operator:
Sample Info: DFTPP DFTPP:2319 Misc Info:
Report Date: 03/11/2030 23:29
i . l-
1.0-
0.9-
0.8-
0.7-
0.6- 0.5-
0.4-
0.3-
0.2-
0.1-
0.0-
HP MS DF020311B64.d. Ion 235.00
Ion 235
9.96 9.99 10.02 10.05 10.00 10.11 10.14 10.17 10.20 10.23 10.26 10.29 10.32 10.35 10.38 10.41 10.44 10.47 10.50 10.53____________________________________________ ___Time (Min)
1 • It
: .0-
ro.9-;
0.8-
0.7-
0.6-;
ly 0.5-
56"'HP MS DF020311B64.d. Scan 309: 10.254 min.
i i
il0.4-
0.3-' ii
l j0.2- I;
0.1- o.o- ■l!'1
40
■•129 207 205..
165
IliU.i! !
jil.. . I,
■105
I.
. 235
/297340,
-355 405\
60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400___________________m/z_____________________________________________________
4,4'-DDD
Exp. RT = 10.280Found RT = 10.254
Mass Area Ratio
235 17219 100.00
70S
Report Date: 03/11/2030 23:29
^Jgection Date: ll-MAR-2002 22:30 Operator:
Sample Info: DFTPP DFTPP:2319 Misc Info:
Datafile 1 Analyzed: /chem/5972hp64.i/DF020311B64.b/DF020311B64.d/DF02 0311B64.d^jfchod Used: /chem/5972hp64.i/DF020311B64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h
Found RT
Mass
246
9.764
Area
3 8 57
Rat io
100.00
70
0.6-M , 4 -
9.50 9.00 9.^0 9. SO 9.90 10.00T ijn? ( M i n ) _____ __________
Compound: 4,4'-DDT
Quant Mass: 235
RT: 10.744Area: 2067201
Compound: 4,4'-DDD
Quant Mass: 235 RT: 10.254Area: 17219
Compound: 4,4'-DDE
Quant Mass: 246 RT: 9.764
Area: 3857
J
i
DDT!DEGRADATION BREAKDOWN ANALYSIS SUMMARY
Compoundi
Response %Breakdown Max Allowed|Test
4,4 - DDT 2067201 N/A4,4 - DDE 3857 0.2 20.0 PASS4,4 - DDD 17219 0.8 20.0 PASS4,4-DDD + DDE 21076 1.0 20.0 PASS
TUNE SAMPLE *** PASSED *** DDT BREAKDOWN TEST71G
Data File; /'chem/'5972hp64 +i/DF020313A64.b/DF020313A64.d
Date ; 13-MAR-2002 09:32
Client ID: DFTPP
Sample Info: DFTPP:917
i|Volume Injected (uL); 2.0
Column phase: J&l-I DB5.625
1 Decaflucrotriphenylphosphine
Instrument: 5972hp64.i
Operator: 917
Column diameter: 0.32
1.5
1.4
' 1.3
1.2
1.1
1.0
0.9-
0.8-
0.7-
0.6-
0.5
|o.4
0.3
0.2
0.1
0.0-
Avg. Scans 184-186 < 8.15), Background Scan 181 19&^
■N
/77 127\
167\
<j.l . .11 IlLv.i JLni I.. i./i Li, I
44;N
■255
/224
I.. i.ll I .1. ..I!
29:N,323 365\
( | N |L ..k .. .,11 ,Lu ..I . I. II. Ii ..l .. .Ik iJl.
40 60 80 100 120 140 160 180 200 220 240 260m/z
280 300 320 340 360 380 400 420 440
1 RELATIVE
nr/t* ION ABUNDANCE CRITERIA ABUNDANCE
1 198 1 Base Peak, 100X relative abundance 1 100.00
1 51 1 30.00 - 80.001 of mass 198 1 49.46
CO 1 Less than 2.OCX of mass 69 1 0.00 < 0,00) 1
1 69 1 Hass 69 relative abundance 1 60.72 1
1 70 1 Less than 2.00X of mass 69 1 0.26 < 0.43) 1
1 127 1 25.00 - 75.001 of mass 198 1 42.36 1
1 197 1 Less than 1.00X of mass 198 1 0.00 1
1 199 1 5.00 - 9.00X of mass 198 6.94 1
1 275 1 10.00 - 30.00X of mass 198 1 22.78 1
1 365 1 Greater than 0.75X of mass 193 1 2.99 1
1 441 1 Present, but less than mass 443 ! 13.68 1
1 442 1 40.00 _ 110,OCX of mass 193 i 91.28 1
1 443
*
1 15.00 - 24.00X of mass 442
*
1 17.94 < 19.65)
* *
■ 711
Data File /chem/5972hp64 * i /DF020313A64 * b/DF0203l3A64.d
Date : ll3-MAR-2002 09:32
Client ID DFTPP Instrument: 5972hp64.i
Sample Info: DFTPP:917
Volume Injected CuL): 2*0 Operator: 917
Column phase: J&W DB5.625 Column diameter: 0.32
Data File: DF020313A64.d
Spectrum: Avg. Scans 184-186 < 8.15), Background Scan 181
Location of Maximum: 188.00
Number of points: 281
m/z Y n/z Y m/'z Y n/z Y
*
1 37*00 481 124.00 1112 1 188.00 10618 282.00 72
1 38*00 1478 125.00 858 1 200.00 744 283.00 483
1 38.00 7087 127.00 64784 1 201*00 611 284.00 224
1 40.00 273 128.00 5187 1 203.00 1057 285.00 536
1 41.00 173 128.00 30864 1 204.00 4868 1 288.00 105
+ + +
1 44.00 78 130.00 2604 1 205.00 8188 1 290.00 74
1 45.00 274 1 131.00 515 1 206.00 33136 1 282.00 88
1 48.00 762 1 132.00 268 1 207.00 4443 1 283.00 646
1 50.00 22048 1 133.00 81 1 208.00 1186 1 284.00 142
1 51.00 75640 1
*
134.00 881 1 209.00 371 1 286.00 10054
1 *
1 52.00 3832 1 135.00 2211 1 210.00 388 1 287.00 1386
53.00 222 1 136.00 818 1 211.00 1425 1 288.00 81
55.00 478 1 137.00 1055 1 212.00 115 1 301.00 87
56.00 2574 1 138.00 232 1 213.00 68 1 302.00 138
57.00 5321 i 138.00 170 1 215.00 384 1 303.00 1040
*
58.00 266 1 140.00 354 1 216.00 278 1 304.00 314
1 59.00 88 1 141,00 3722 1 217.00 8855 1 308.00 126
1 61.00 1033 1 142.00 1208 1 218.00 1180 1 308.00 81
1 62.00 1144 I 143.00 805 1 218.00 78 1 310.00 88
1 Uy w o o 2S23 1 144.00 256 ! 221.00 6853 1 313.00 88
1
1 64.00 401 1 145.00 217 223.00 2226 1 314.00 438
1 65.00 1239 1 146.00 689 224.00 18848 1 315.00 1138
1 66. C»o 178 1 147.00 2026 225.00 4716 1 316.00 572
1 67.00 111 1 148.00 5187 227.00 8778 1 317.00 88
1 69.00 92S72 1 149.00 886 228.00 1166 1 321.00 242
1 *
1 70.00 400 1 150.00 260 229.00 1732 1 323.00 3288
1 73.00 518 1 151.00 471 230.00 240 1 324.00 583
1 74.00 7478 1 152.00 254 231.00 601 1 325.00 78
1 75.00 11266 1 153.00 1187 232.00 85 1 327.00 686
1 76.00 3662 1 154.00 812 233.00 88 1 328.00 284
r„-i 63696 1 155.0>) 1828
78.00 4347 1 156.00 2734
79.00 5567 I 157.00 494
80.00 3717 ,1 158.00 711
31.00 5093 !1 159.0':* 482
234.00 548 1 328.00 71
235.00 563 1 332.00 275
236.00 388 1 333.00 214
237.00 583 t 334.00 2007
233.00 68 1 335.00 501
■ 71c
Data File: /chem/5972hpiS4.
Date : 13-MAR-2002 09:32
Client ID: DFTPP
i/DF020313A64.b/DF020313A64 *d
Instrument: 5972hp64,i
Sample Info: DFTPP:917
Volume Injected CuL): 2*0
Column phase: J&W DBS,625
Operator: 917
Column diameter: 0*32
i
I
i
Data File: DF020313A64,d
Spectrum: Avg. Scans 184-186 < 8,15), Background Scan 181
Location of Maximum: 198,00
Number of points: 281
m/z Y m/z Y m/z Y m/z Y
1 +
1 S2.00 1321 1 160.00 1201 1 239.00 323 1 341.00 383 1
1 83.00 1053 1 161.00 1664 1 240.00 244 1 342.00 104 1
1 84,00 153 1 162.00 512 1 241.00 453 1 346.00 698 1
1 85.00 925 1 163.00 214 1 242.00 999 1 347.00 103 1
1 86,00 1743 1 164,00 203 1 243.00 1066 1 352.00 928 1
1 87.00 657 1 165.00 1577 1 244.00 15672 1 353.00 611 1
1 88.00 307 1 166.00 1108 1 245.00 2006 1 354.00 986 1
1 89.00 170 1 167.00 7649 1 246.00 3019 1 355.00 265 l
1 91.00 1174 1 168.00 3682 1 247.00 598 1 365.00 4570 1
1 92.00 1375 1 169.00 669 1 248.00 95 1 366.00 543 1
*+ * * *
1 93.00 10780 1 170.00 240 1 249.00 556 1 370.00 72 1
1 94,00 495 1 171.00 297 1 250.00 103 1 371.00 223 1
1 95.00 254 I 172.00 638 1 251.00 117 1 372.00 1873 1
1 96.00 309 1 173.00 827 1 252.00 133 1 373.00 338 1
1 98.00 8168 t 174.00 1444 1 253.00
1
361 1 383.00 374 r
*1 *
1 99.00 5134 1 175.00 2544 1 255.00 72152 1 384.00 133 1
1 100.00 479 1 176.00 753 1 256.00 10740 1 390.00 213 i
1 101.00 2711 1 177.00 1471 1 257.00 840 1 391.00 155 1
1 102.00 219 1 178.00 253 1 258.00 4496 1 392.00 101 i
I 103.00 1029 1 179.00 5802 1 259.00 709 1 401.00 86 i
*+ * 1 *
1 104.00 1926 1 180.00 3425 1 260.00 88 1 402.00 676 1
i 105,00 1865 1 181.00 1728 1 261.00 111 1 403.00 1035 1
1 107.00 21712 ! 182.00 280 1 264.00 134 1 404.00 310 1
I 108.00 3143 1 183.00 158 1 265.00 2009 1 421.00 932 i
I 110.00 40S24 1
*
184.00 248 I 266.00 239 1 422.00 896 1
* 1 *
1 111.00 6164 1 185.00 2583 1 267.00 162 1 423.00 7515 1
! 112.00 835 1 186.00 18600 1 270.00 93 1 424.00 1416 1
I 113.00 271 1 137.00 5099 1 271.00 134 1 425.00 118 1
1 115.00 177. 1 189.00 1259 I 273.00 2198 1 441,00 20912 1
1 117.00 23984 1 190.00 228 1 274.00 6197 1 442.00 139584 1
1
1 118.00 1618 1 191.00 698 1 275.00 34840 1 443.00 27432 1
1 119.00 262 1 192.00 1819 1 276.00 4769 1 444.00 2567 1
1 120.00 250 1 193.00 1813 1 277.00 3196 1 445.00 115 1
' 121.00 83 1 194.00 410 1 273.00 571 1 I
; 122.00 1572 1 196.00 4025 1 279.00 86 1 i
i
■ 71 o
Data File: /chem/5972hp64.i/DF020313A64.b/DF020313At.4.d
Date : 13-MAR-2002 09:32
Client ID: DFTPPl|
Sample Info: DFTPP:917
Volume Injected iuLi: 2.0
Column phase: J8.U DB5.625
Instrument: 5972hp64.i
Operator: 917
Column diameter: 0.32
o
Data File: DF020313A64*d
Spectrum: Avg* Scans 184-186 ( 8*15), Background Scan 181
Location of Maximum: 198*00
Number of points: 281
m/z m/z m/z m/z
I 123*00 2372 I 198*00 152896 I 281*00 86 I
■ 714
(xlO)
Sample Info: DFTPP:917
Volume Injected <uL): 2.0 Operator: 917
Column phase: J8.W DB5.625 Column diameter: 0.32
Data File: /chem/5972hp64. i/'BF020313A64.b/,DF020313A64.d
Date : 13-MAR-2002 09:32
Client ID: DFTPP Instrument: 5972hp64.i -O —1 h~-
13.5 13.8
TAILING FACTOR and DEGRADATION SUMMARY RESULTS
DECAFLUOROTRIPHENYLPHOSPHINE Ion Abundance/Ratio Criteria Chart
►"nAbundance Criteria Base Peak Other Test |
198 Base Peak, 100% relative abundance 100.00 PASS51 30 - 80% of mass 198 49.46 PASS68 Less than 2% of mass 69 0.00 ( 0.00) PASS69 Mass 69 relative abundance 60.72 PASS
70 Less than 2% of mass 69 0.26 ( 0.43) PASS
127 25 - 75% of mass 198 42.36 PASS197 1 0 - 1% of mass 198 0.00 PASS199 5 - 9% of mass 198 6.94 PASS275 10 - 30% of mass 198 22.78 PASS365 Greater than 0.75% of mass 198 2.99 PASS441 Present, but less than mass 443 13.68 ( 76.25) PASS442 40 - 110 % of mass 198 91.28 PASS443 15 - 24% of mass 442 17.94 ( 19.65) PASS
TAILING ANALYSIS SUMMARY
#:
Compound |Tail Factor | Max Allowed | Test
Pentachilorophenol 0.0 5.0 PASSBenzidine
,i0.5 3.0 PASS
DDT DEGRADATION BREAKDOWN ANALYSIS SUMMARY
^ CompoundResponse %Breakdown Max Allowed Test
4,4-DDT 2411404 N/A4,4-DDE 2329 0.1 ■20.0 PASS4,4- D.DD 21021 0.9 20.0 PASS
4,4-DDD + DDE 23350 1.0 20.0 PASS
Tuning S ample, /chem/5972hp64.i/DFO20313A64.b/DF020313A64.d/DF020313A64.d
PASSED
71b
I
TAILING FACTOR and DEGRADATION SAMPLE AND GRAPHIC REPORT
port Date : 03/13/2030 10:34
Datafile Analyzed: /chem/5972hp64.i/DF020313A64.b/DF020313A64.d/DF020313A64.d Method Used: /chem/5972hp64.i/DF020313A64.b/dftpp8270C.m Inst: 5972hp64Injection Date: 13-MAR-2002 09:32 Operator: 917Sample Ijnfo: DFTPP DFTPP:917 Misc Info:
iI
• 711
iO
Report Date: 03/:.3/2030 10:34
atafile Analyzed: /chem/5972hp64.i/DF020313A64.b/DF020313A64.d/DF020313A64.d thod Used: /chem/5972hp64.i/DF020313A64.b/dftpp8270C.m Inst: 5972hp64
bisection Date: 13-MAR-2002 09:32 Operator: 917Sample Info: DFTPP DFTPP:917 Misc Info:
6. * *4-.
6.0' 5.b:
5.2-'
4.0-
4.4-
4.0- '
3.6-
HP MS DF0203i3Ab‘4.d
2.8-2.4-
2.0- 1.6-1.2-
0.8- 0.4-
/ \
_L2_CS 8.0 8.1 8.2
T imp (Min?_______8.3 8.4 8.5 8.6
HP MS DF020313A64.d. Scan 185: 8.151 nun.442-0
. 6-
il:::
9 9.
2.0- 1.8-
1 .6-
1 .4-
1-0.
0.6-0.6-0.4-
69
'51
136
; 148
40 60 SO 100 1J
• 198
255.
275.
,296■ 323 .365
403,
140 160 100 200 220 240 260 280 300 320 340 360 380 400 420
1440
I Ion
DECAFLUOROTRIPHENYLPHOSPHINE Ion Abundance/Ratio Criteria
| Abundance Criteria I Base Peak Other
198 51 686970
127 19 7199 275
.6 5 1
4 4 2 44 3
Base Peak, 100% relative abundance 30 - 80% of mass 198
Less than 2% of mass 69 Mass 69 relative abundanceLess than y '■ of mass 692505
id
75% of mass 1981% of mass 198 9% of mass 198
30% of mass 198 Greacer chan 0.75% of mass 198 Present, but less than mass 443 40 - 110% of mass 198 15 - 24% of mass 442
100.00 49.46 0.00
60.72 0.26
42.36 0.00 6.94
22.78 2 . 99
13 . 68 91.28 17.94
( 0.00)
( 0.43)
76.25)
19.65)
Report Date: 03/13/2030 10:34
atafile Analyzed: /chem/5972hp64.1/DF020313A64.b/DF020313A64.d/DF020313A64.d fethod Used: /chem/5972hp64.i/DF020313A64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h
rijection Date: 13-MAR-2002 09:32 Operator:Sample Info: DFTPP DFTPP:917 Misc Info:
5.4-
5.1:
4.6-
4.5- ;
•4.2-
3.9-
3.6-
3.3-
3.0-
2.4-
2.1- i .b-;
1.5T
1.2- 0.9-
0.6- 0.3-
0.0- -
HP M5 DF020313A64.d. Ion 266.00
Ion 266
Tailing Factor .'= jp . 00000
.50 .55 7.60 7.65 70 7.75 7.80 7.85Time (Min)
7.90 .95 8.00 3.05 8.10
4.8
4.5
4.23.9
3.6
3.3
3.0
2.7
2.4-
2.1-1.8
1.5-
1.2- 0.9-
0.6- 0.3-
0.0-7
HP MS DF0203l3A64x£jl, Ion 266.00
CD
.50 7.60 7.70 7.80Time (Min)
7.90 8.00 9.10
HP MS DF020313A64.d. Scan 164: 7.796 min.
4.5- '"•266
3.9-
3.6-
3.3-
3.0-
2.1- 1 .3-
1 .5-
1 .2 0.9-
9.6-
165
; i 202.95
130i ,
60
•
3’ 118 i. I
169
.... ii20?
111,!.'
90 100 120 140 160 180
________ ____________ ______ m/z______________ ___200
,-730
I. M. 11 I .
220 240
Pentachlorophenol
I!
260
281
280
Exp. RT| Found RT
Mass
7.8307.796
Area Ratio
266 , S8740 100.00
I^^iling factor for Pentachlorophenol OK
^R_ling Factor = 0.0 Maximum Allowed = 5.0
If Tailing Factor < 1.0, then it is assumed that the peak is not t'ail4iVg and a Tailing Factor of zero is reported.
Report Date: 03/13/2030 10:34
ga^aWn
ataf ile Analyzed: /chem/5 972hp64.i/DF02 0313A64.b/DF02 0313A64.d/DF020313A64.d thod Used: /chem/5972hp64.1/DF020313A64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h
njection Date: 13-MAR-2002 09:32 Operator:Sample Info: DFTPP DFTPP:917 Misc Info:
Benzidine
Exp. RT:| =
Found RT =9.550 9.502
Mass | Area Ratio
184 1026092 100.00
•iling 'factor for Benzidine OK
iling Factor = 0.5 Maximum Allowed = 3.0
If Tailing Factor < 1.0, then it is assumed that the peak is not ’tZi2.iLng and
a Tailing Factor of zero is reported.
Report Date: 03/13/2030 10:34
tafile1 Analyzed: /chem/5972hp64.i/DF020313A64.b/DF020313A64.d/DF020313A64.dthod Used: /chem/5972hp64.i/DF020313A64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h
njection Date: 13-MAR-2002 09:32 Operator:Sample Info: DFTPP DFTPP:917 Misc Info:
HP MS DF020313A64.d. Ion 235.00
1.4-;i .3-:
i.i-
1.0- 0.9'
0.8- 0.7-
0.6- 0.5-
0 4-
0.3
Ion 235o
0.1-
0.0--
r-1.0-'
0.9-
0.8-
0.7-
0.6-
0.5-
0.4-
0.3-
10.4- 10.47 10.50 10.53 10.56 10.59 10.62 10.65 10.68 10.71 10.74 10.77 10.80 10.83 10.86 10.89 10.92 10.95 10.98 11.01 1 Time (Min)I HP MS DF020313A64.d. Scan 337: 10.710 min.
235-",
165
199
,50
4,4'-DDT
Exp. RT Found RT
248 319 354.
30 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
.405)29
400 420
10.770 10.718
Mass
235
Area Ratio
2411404 100.00
Report Date: 03/13/2030 10:34
Datafil'e Analyzed: /chem/5972hp64 . i/DF020313A64 . b/DF02 0313A64 . d/DF02 0313A64 . d Method Used: /chem/5972hp64.i/DF020313A64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972b
Injection Dace: 13-MAR-2002 09:32 Operator:Sample :Info: DFTPP DFTPP:917 Misc Info:
i .4-
1.3-
1.2-
1.1-
1 - 0-
0.9-£ 0.8-' ;2 0.7-
■ ~ 0.6-
0.5-
0.4-
0.3-
0.2-
0.1 -
0.0 - —
Ion 235
HP MS DF020313A64.d. Ion 235.00
,/\
I \
1 \
9 . ?:• '9 9A 9.99 10.02 10.05 10.08 10.11 10.14 10.17 10.20 10.23 10.26 10.29 10.32 10.35 10.38 10.41 10.44 10.47 10.50 10.52 ________ Time (Min) ________________
HP MS DF020313H64.d. Scan 308: 10.228 min.
1.8-
1.6-
; . 4
1.0-
0.8-
0.6-
0.4-
4,4'-DDD
Exp. RT Found RT
,20?235
129
120 140 150
199
mmIi . ,i. t:
180 200
281.
I I 310...340.
. 355 405
In
240 260 280 300 320 340 360 380 400
10.280 in ioq
Mass
235
Area Ratio
21021 100.00
■722
Report Date: 03/13/2030 10:34
tafile Analyzed: /chem/5972hp64.i/DF020313A64.b/DF020313A64.d/DF020313A64.dthod Used: /chem/5972hp64.i/DF020313A64.b/dftpp8270C.m/BrkDwnTF.m Inst: 5972h
njection Date: 13-MAR-2002 09:32 Operator:Sample Info: DFTPP DFTPP:917 Misc Info:
HP MS DF020313A6<4 .d. Ion 2-46.00
1 . 7 1.61.5-
i . -*• 1 3-
ion 246
i . i- i. 0-.
0.9-
0.0- 0.7-
0.6-i0.5-
0.4-
0.3-
0.2-.
0. It 0.0-'
! \
9.45i
1.1-
1.0-
0.9-
0.8-
9.48 9.51 9.54 9.57 9.60 9.63 9.66 9.69 9.72 9.75 9.78 9.91 9.84 9.8? 9.90 9.93 9.96 9.99 10.02_______ ____ ________ Time (Min) ___
HF MS DF020313964.d. Scan ^79: 9.739 min.
*r 0.6-
7 0 5-
0.4- 73
0.3-
191 .jr- ' c' a j
n ?1 76
0.0An 120 140 160 160 200
4,4'-DDE
Exp. RTi = 9.790Found RT = 9.739.
Mass Area Ratio
246 2 3 2 9 100.00
253.
201-
310341 .355
405
ih i
•723
HP- MS DF02031 3964 Ion 235.00
1.5-
1 .2- 1.1- 1.0- 0.9-
0.0- 0.7-;
0.6- 0.5-.
0.4-
0.3-
0.2-
0.1- 0.0-
10.50 10.60 10.70 10.80 10.90 11.00r Time (Min) ___________________
1.2
1.1-
1.0-
0.9-;
0.8-
0.7-
0.6-
0.5-
0.4-
0.3-
0.2-
0.1-
0.0-4
1.5-
1 . 4-
1 . 3-
1 .2- 1.1-
1.0- 0.9 ' 0.8-' 0.7- 0.6- 0.5 (J. 40.3-
HP MS DF020313H64Ion 235.00
OT
I 1 !
10..00 10.10 10.20 10.30 10.40 10.50_____ ,_______ T i me (Min)________________________
HP MS 0^020313064^. Ion 246.00
? . 50 50 9.70 9.80 9.90 10.00T i ne (Mm)
Compound: 4,4'-DDT
Quant Mass: 235
RT: 10.718
Area: 2411404
Compound: 4,4'-DDD
Quant Mass: 235
RT: 10.228
Area: 21021
Compound: 4,4'-DDE
Quant Mass: 246
RT: 9.739
Area: 2329
DDT DEGRADATION BREAKDOWN ANALYSIS SUMMARY
Compound Response ^Breakdown |Max Allowed|Test|
4,4-DDT 2411404 N/A4,4-DDE 2329 0 . 1 20.0 PASS4,4-DDD 21021 0 . 9 20.0 PASS4,4-DDD + DDE
l. 23350 1.0 20.0 PASS
TUNE SAMPLE★ ★★★★★★★★★★★★★ *** PASSED *** DDT BREAKDOWN TEST•x-k-k-k'k'k-klric'k’k’k'kli: ■724
b. Blank Data
Arranged in chronological order, by extraction date.
- Tabulated Results (Form I SV)
- Tentatively Identified Compounds (Form I SV-TIC)
- Reconstructed Ion Chromatogram and quantitation report
- Target compound spectra with lab-generated standard
spectra
- Quantitation/Calculation of TIC concentrations
- GC/MS library search spectra for TICs
725
' FORM
SEMIVOLATILE ORGANICS1ANALYSIS DATA
CLIENT SAMPLE NO.SHEET
.
|Lab Name: COMPUCHEM
Lab Code: LIBRTY
Contract 8270CSBLKIB
Case No.: SAS No. SDG No.: QE1877
Matrix: (soil/water) WATER Lab Sample ID WG16194-1
Sample wt/vol: 1000 (g/mL) ML Lab File ID: WG16194-1JA6 4_S
Level : (low/med) LOW Date Received
% Moisture: decanted: (Y/N) Date Extracted:03/08/02
Concentrated Extract Volume: 1000(uL) Date Analyzed 03/11/02
Injection Volume: 1.0(uL) Dilution Factor: 1.0
GPC Cleanup: (Y/N) N pH:
CAS NO. COMPOUNDCONCENTRATION UNITS: (ug/L or ug/Kg) UG/L
i 10 8-9 5-2---- ----Phenol 10 Ui| 11 1-4 4-4---- ----Bis(2 -chloroethyl)ether 10 u95 -57 -8----- ----2 -Chlorophenol 10 u
!54 1-7 3-1---- ----1,3-Dichlorobenzene 10 uj 10 6-4 6 -7---- ----1,4 -Dichlorobenzene 10 uS 5 -50 - 1----- ----1,2-Dichlorobenzene 10 u95 -48 -7----- ----2-Methylphenol 10 u
| 10 8-6 0-1---- ----2,2'-oxvbis(1-Chloropropane) 10 u10 6-4 4-5---- ----4-Methylphenol 10 u,62 1-6 4-7---- ----N-Nitroso-di-N-propylamine 10 u1 67 -72 - 1----- ----Hexachioroethane 10 u98 -95 - 3 ----- ----Nitrobenzene 10 u7 8 -59 -1----- ----Isophorone 10 u
:i n n'| O o -75 -5----- ----2-Nitrophenol 10 u10 5 - 6 7-9---- ----2,4 - Dimethylphenol 10 u11 1 - 9 1-1---- ----Bis(2 -chloroethoxy)methane 10 u
! i 2 10 u12 0-3 2-1---- ----1,2,4-Trichlorobenzene 10 u91 -20 ----Naphthalene 10 u
:l 10 6 -4 7 _ p___ ----4 -Chloroani1ine 10 u■ 8 7 -68 _ d _ _ _ _ _ ----Hexachlorobutadiene 10 u
,i 5 9 - 5 0 _ 7 _ _ _ _ _ ----4 -Chloro- 3 - me t hy1phenol 10 u] j. - 2 - 6----- ----2-Methylnapnt ha1ene 10 u,77 -47 - 4----- ----Hexachlorocyclopentadiene 10 uSB - Q ^ ----2,4,6-Trichlorophenol 10 u
i 95 - 9 5 _4----- ----2,4,5 -Trichlorophenol ■ 10 u; q i -5 8 -7----- ----2-Chloronaphthalene 10 u:.B8 - 74 -4----- ----2 -Nitroanil me 20 u1 1 " _L 1_3---- ----Dimethylphthalate 10 u6 0 6 - 2 0-2---- ----2,6-Dinitrotoluene 10 u'2 0 S - 9 r<o - o _ _ - _ ----Acenaphthylene 10 u
I 8 2 - 0 5 - - “ “ - “ ----3 - Mi t roam line 20 u- 10 u
FORM I SV 8270C
72u
FORM 1SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO.
Lab Name: COMPUCHEMil
Lab Code: LIBRTY Case No.:
Contract: 8270C
SAS No.:
SBLKIB
Matrix;
Sample!
Level:
Moisture:
(soil/water) WATER
wt/vol: 1000 (g/mL) ML
(low/med) LOW
decanted: (Y/N)
Concentrated Extract Volume:
Injection Volume: 1.0(uL)
GPC Cleanup: (Y/N) N pH:
1000(uL)
SDG No.: QE1877
Lab Sample ID: WG16194-1
Lab File ID: WG16194-1JA64_985
Date Received: _______ _
Date Extracted: 03/0.8/02
Date Analyzed: 03/11/02
Dilution Factor: 1.0
( 1
CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
51-28-5----------2,4 -Dini trophenol 50 U100-02-7---------4 -Ni trophenol 20 u121-14-2-------- 2,4 - Dinit rot oluene 10 u132-64-9---------Dibenzofuran 10 u84-66-2----------Diethylphthalate 10 u70 0 5- 72-3------- 4-Chlorophenyl-phenylether 10 u86-73-7----------Fluorene 10 u100-01-6---------4 -Nitroanil ine 20 u534-52-1-------- 4,6-Dinit ro-2 - methylphenol 20 u86-30-6----------N-Nitrosodiphenyl amine (1) 10 u101-55-3---------4 -Bromophenyl - phenyl ether 10 u118-74-1-------- Hexa chlorobenzene 10 u87-8 6- 5----------Pentachlorophenol 20 u85-01-8----------Phenanthrene 10 u12 0-12-7-------- Anthracene 10 u86-74-8 ----------Carbazole 10 u8 4- 74-2----------Di-n-butylphthalate 10 u2 0 6- 44-0---------Fluoranthene 10 u129-00 - 0-------- Pyrene 10 u85-68-7----------Butylbenzylphthalate 10 u91-94-1----------3,3' -Dichlorobenzidine 20 u117-81-7---------bis ( 2 - et hvlhexvl ) Phthalate 0 . 9 J56 - 55 - 3 ----------Benzo (a) anthracene 10 ' u213-01-9---------Chrysene 10 u117-84-0---------Di-n-octylphtnalate 10 u205- 99-2---------Benzo (b) fluoranthene 10 u2 0 7 -08- 9---------Benzo ( k ) f iuoranthene 10 u50 - 32 -8 ----------Benzo (a; ovrene 10 u19 3 - 39-5-------- Indeno (1,2,3- cd ) pyrene . 10 u
15 3 - 70 - 3 ----------Dibenzo (a , h .■ anthracene 10 u191 - 24 - 2------- - Benzo (q , h , t ) oerviene 10 u
Cannot be separate : roffi L FORM I SV
72 i
8270C
Data File: /chem/5972hp64.i/DF020311A64.b/WG16194-lJA64_985.d
Date : ll-MAR-2002 09:32
Client ID: SBLKIB
Sample Info:
Volume Injected (uL>: 1*0
Column phase: RTX-5
Instrument: 5972hp64.i
Operator: 917
Column diameter: 0.32
cvir--
(:<10~6>
Data File: /chem/5972hp64.i/DF020311A64.b7WG16194-lJA64_985.d
Date : ll-MAR-2002 09:32
Client ID; SBLKIB Instrument: 5972hp64.i O')Sample Info: CVJVolume Injected (uL): 1.0 Operator: 917
Column phase: RTX-5 Column diameter: 0.32
Data File: /chem/5972hp64.i/DF020311A64.b/WG16194-1JA64_985.dReport Date: 13-Mar-2030 09:51
Data file Lab Smp Id Inj Date Operator Smp Info Misc Info
CompuChem
Semivolatile Report SW-846 Method 8270C /chem/5 972hp64.i/DF020311A64.b/WG16194-1JA64_985.d WG16194-1 Client Smp ID: SBLKIB11-MAR-2 002 09:32917 Inst ID: 5972hp64.i
Comment ; Method \ Meth Date Cal Date1 Als bottjle
Dil Factor IntegratorTarget Version: 3.50
/chem/5972hp64 . i/DF020311A64 . b/82-70Cv6 . m 12-Mar-2030 12:00 respass Quant Type: ISTD 10-MAR-2002 17:23 Cal File: HL020310A64.d3 QC Sample: BLANK1.00000HP RTE Compound Sublist: OLM03 sub
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name ValueI
Description
D^jvtvo!
Vi
1.00000 1000.000001000.000001.00000
Dilution Factor Volume of final extract (uL) Volume of sample extracted (mL) Volume injected (uL)
Cpnd Variable Local Compound Variable
CoT.pGG
CONCENTRATIONS
nds
C’UANT SIG
MASS F.T e:-:f F.T REL RT RESPONSE
ON-COLUMN
l NG)
FINAL
( ug/L)
i .i , -i - Dico.oronenr.en~ - a4 52 5 . 2 n 1 S . 24 9 (1.000) 98611 4 0.0000
Naphtha e n e - d 8 125 10.128 10.142 ; i.000) 379742 40.0000
Acenaoh he-c-.n: 16 4 12 . 1A~> 12.152 (1.000' 272997 40.0000
Phenar.t hre:':rr - d 1 S 5 15.460 15 4 o 5 11.000) 554445 40.0000
Chrysene ■ h 1 24 0 19.944 ; 9 Q 4 9 ; i ,ooo) 450039 40.0000
2^-i 22 .4 29 22.434 1 1 .0001 242083 40 . 0000
j . r ; :jor ::: 5 4 5 2 - : 0 . 7 S 1) 245885 76 .8183 76.82
Ph^r.o: • i E 9 5 7 7 5 4 7 7 7 ; 0 . 5 3 9 ) 221615 53 . 1523 53.15
Nltrcr-c 52 ;. o 7 . 2 3 1 C . 897; 181134 4 4 .0745 44 . 07
: - r 1 '.it, I. l p ."i v: ■.. ; : v: 11 v' :: ■ ;s-; . 0 904' 421100 46 .2996 4 6.30
::. 4 -j - t 2 2 r; 1 4 4 5 4 ' 1 . 10 o ■■ 372293 135.450 135.5
v - i 1 4 :s4 1 7 . r 7 ■■■ iDi ■ 0.3951 1049356 88 . 0802 88 . 08
Pher.c ; *•; c u r. d Not Detected
3 : s : 2 - c 9 2 Compound Not Detected
Z -Ch.orophrr-c •. o - Cor.i: our.d Not Detected
SIMILARITY
\
&
73G
Data File: /chem/5972hp64.i/DF020311A64.b/WG16194-1JA64_985.dReport Date: 13-Mar-2030 09:51
QUANT SIG
Compounds MASS RT EX? RT REL RT
19 1,3-Dichlorobenzene 146 Compound Not Detected
20 1,4-Dichlorobenzene • 146 Compound Not Detected
22 1,2-Dichlorobenzene 146 Compound Not Detected
23 2-Methylphenol 108 Compound Not Detected
24 2,2'-oxybis(1-Chloropropane) 45 Compound Not Detected
27 4-Methylphenol 108 Compound Not Detected
28 N-Nit rose-di-N-propylamine 70 Compound Not Detected
29 Hexachloroethane 117 Compound Not Detected
301
NitroDenzene 77 Compound Not Detected
31 Isophorone 82 Compound Not Detected
32 2-Nitrophenol 139 Compound Not Detected
33 2.4-Dimethyl phenol 122 Compound Not Detected
34 Bis(2-chloroethoxy)methane 93 Compound Not Detected
35 2,4-Dichioropheno1 162 Compound Not Detected
36 1,2,4- Tnchlorobenzene 180 Compound Not Detected
37 Naphthalene 128 Compound Not Detected
38 4-Chioroanil:ne 127 Compound Not Detected
35 Hexachlorooutadiene 225 Compound Not Detected
41 4 -Chloro - 3-methy 1phenol 107 Compound Not Detected
42 2-MethyInaphchalene 14 2 Compound Not Detected
4 4 Hexachlcrocyclopentadiene 2 3 7 Compound Not Detected
45 19c Compound Not Detected
4 6 2,4.5 -Tr:ch1oropheno 1 156 Compound Not Detected
__ 49 2-Chlornnaphthalene 162 Compound Not Detected
2 - N i t roa mime 65 Compound Not DetectedWiO
Dimet hyipnt ha 1 at e 1 6 3 Compound Not Detected
5 1 2,6 - Dm: t rotoluene 165 Compound Not Detected
52 AcenaDht hv 1 er.e 152 Compound Not Detected
53 5 -Nitroan:1:ne T_ 7 Q Compound Not Detected
54 Acenaphthene 154 Compound Not Detected
c c. 2 . 4 - Dim t rophenoi 184 Compound Not Detected
56 4 -Nin rophero1 109 Compound Not Detected
57 2.4-Dinitrotoluene 16b Compound Not Detected
56 Dibenzot u r an 1 6 8 Compound Not Detected
5 5 Dietnyipntha late 1 4 5 Compound Not Detected
60 4 -Chlcrobhenvi-phenviether 2 04 Compound Not Detected
6'; r 1 u o r e ri e ■■ir. Compound Not Detected
6 2 4-N:trcan:;:ne 1 36 Compound Not Detected
6 3 4 6 - D l r. it ro - 2 - met hy ’ phene 1 1 9 ? Compound Not. Detected
44 N-Nit re sod:pneny i ami re 16 5 Com,pound Not Detected
in 4 -Bromopheny: -phenyiether 2 4". Comnc unci Net Det ected
4 7 Hexachlorobenzene 264 Comooun-d Detected
6? Pentachicropheno: 2 6 r Comcourd N 71 Detected
7 0 Pnenar.: rrene : Cc-T.:;'-. Not Detected
7 Antnra :en- 7W \ : Detected
7 2 Carbazo j‘e : 6 7 Dcrpcur.i Det ected
7 3 Di - n - but y: pnt ha 1 ate : 4 5 i Detected
RESPONSE
CONCENTRATIONS
ON-COLUMN FINAL
( NG) ( ug/L) SIMILARITY
731
Data File: /chem/5972hp64.i/DF020311A64.b/WG16194-1JA64_985.dReport Date: 13-Mar-2030 09:51
ipounds
QUANT SIG
MASS RT EXP RT REL RT
74 Fluoranthene 202 Compound Not Detected
76 Pyrene 202 Compound Not Detected
77 Butylbenzylphthalate 149 Compound Not Detected
78 3,3'-Dichlorobenzidine 252 Compound Not Detected
79 bis (2-ethylhexyl)Phthalate 149 19.775 19.780 (0.992)
80 Benzo(a)anthracene 228 Compound Not Detected
61 Chrysene 228 Compound Not Detected
82 Di-n-octylphthalate 14 9 Compound Not Detected
9 3 Benzo (t>) fluoranthene 252 Compound Not Detected
84 Benzo lk 'fluoranthene 252 Compound Not Detected
85Benzo i a' i pyrene
1252 Compound Not Detected
86 1 ndeno f'l,2,3-cd'pyrene 276 Compound Not Detected
87Dibenzoji a , h i anthracene
270 Compound Not Detected
33 Benzo igi, h, i) perylene 276 Compound ■Not Detected
RESPONSE
CONCENTRATIONS
ON-COLUMN FINAL
( NG) ( ug/L) SIMILARITY
9136 (a)
QC Flag Legend
a - Target compound detected but, quantitated amount Below Limit Of Quantitation(BLOQ).
M - Compound response manually integrated.
i
Data File: 7chem,'5972hp64. i/DF020311A64.b/UG16194-lJA64_985.d
Date : ll-MAR-2002 09:32
Client ID: SBLKIB I nstrument: 5972Vip64. i
Sample Info:
Volume Injected (uL): 1.0
Column phase: RTX-5
Operator: 917
Column diameter: 0.32
Data File: /chem/5972hp64.1/DF020311A64.b/UGl6l94-lJA64_985.dInjection Date: ll-MAR-2002 09:32Instrument: 5972hp64.1Client Sample ID: 5BLKIB
ipound: 2.4.6-TribromophenolHumber: l'lB-79-6
; 2.0i
i i.8i: 1.6i
1.4-
1.2-'iDio 1.0-
0.8-
i 0.6-
0.4-
! 0.2-
Ion 329.60: Area: 372293 Height: 204815
$
! i
14.00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14Min
50 14.5514^60 14!. 65 14^70 14^75 m'sO 14.85 14.90 14.95
2.0-
Ion 332.00: Area: 0
\
Height: 0
1.8-
1.6-
1.4-
1.2-
1.C-
0.8-
0.6-
0.4-
0.2-
0.0»14.00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.05 14.90 14.95
______ _____ M i n
6.0- " . 5
i.O6.5-
6. 0-5.5-
5.0-
4.5
4.0-
3.5
3.0-
2.5-
1 on i4i.00: 0 Height: 0
0.5-
n,0-----'--1 4 . u'o 1 - 5 14,10 14.15 14.20 ;4.; 14.40 14.45 14.50 14.55 14.60 14.65 14.20 14.75 14.80 14.85 14,90 14.95:
M i n
CompuChema Division of Libertv Analytical Corp.
i
GC/MS SEMI-VOA WORKSHEET
\
LAB INSTRUCTIONS:
RECEIPT DATE: SAMPLE DATE: DUE DATE:
CASE#: i SDG: COMPUCHEM#: - I j
CLIENT ID: Sgif //J
ANALYSIS DESCRIPTION:
Injection Volume :[pL Dilution Prep (if needed)
Extraction Date J / S' / C ?
DFTPP Filename h f~7? I o 7 II A Jk
Sample File Name jj & !6 / f U - / JA /(/
ANALYST (S): Injection' I H__________________ Work-upw 7
GC/MS DATE REVIEW
iCONDITION CODE
3ft
Extraneous Peak Search Results:
Number o|f peaks found:
Number of Hits found: _ (£L
Number of Surrogate Outliers:
jOualin Assurance Notice (S)
Number of Notices Required _I
Comments:
m
Disposition: [ vf^omplete
[ ] Reinjection Required
[ ] Re-extraction Required
[ ] Reinject Neat
f ] Dilute) X)
=GC MS Review
Final Reportable Package)s):
i
Auditor Date / /
\,\G\ fa ,
- 73
SVI -6/27/01: PTF
FORM 1SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO.
Lab Name: COMPUCHEM Contract:
Lab Code: LIBRTY Case No.: SAS No.:
Matrix: (soil/water) WATER
Sample wt/vol: 1000 (g/mL) ML
Level: (low/med) LOW
% Moisture: _______ decanted: (Y/N)
Concentrated Extract Volume: 1000(uL)
Injection Volume: 1.0(uL)
GPC Cleanup: (Y/N) N pH:
8270C
SDG
Lab Sample ID:
Lab File ID:
SBLKII
No.: QE1877
WG16228-1
WG16228-1A60
Date Received:
Date Extracted:03/10/02
Date Analyzed: 03/12/02
Dilution Factor: 1.0
CONCENTRATION UNITS:CAS NO. COMPOUND ■ (ug/L or ug/Kg). UG/L Q
108-95-2 - - 111-44-4--95 - 57- 8 ------541-73-1- - 106-46-7--95- 50 - 1 ------9 5-48-7------1 0 8 - 6 0 - 1 - - 106-44-5 - - 621-64-7--67-72 - 1------98 - 95 - 3 ------7 8-59-1------
i 8 8-75-5------105- 67-9 - -111-91-1-- 120-83-2-- 120-S2-1-- 91-20-3------106- 47-3 —
: 8 7 - 6 S - 3------59-50-7------
' 91-5 7-6------77 - 47 -4 ------
I 9 5- 95 -4 ------51-58-7------
i; 8 8 - 74 -4 --
; 606-20-2-- 2 0 8 - 9 6 - S - -
; 9 9 - 09-2 ------
- - Phenol ____________________- - Bis(2-chloroethyl)ether- - 2 -Chlorophenol --1,3 - Dichlorobenzene --1,4-Dichlorobenzene --1,2 -Dichlorobenzene- -2-Methylphenol ___________--2,2' -oxybis(1 -Chloropropane)- - 4 -Methylphenol______________--N-Nitroso-di-N-propylamine--Hexachloroethane --Nitrobenzene- -Isophorone --2 -Nitrophenol --2,4-Dimethylphenol- - Bis(2 -chloroethoxy)methane --2,4-Dichiorophenoi --1,2,4-Trichlorobenzene--Naphthalene- -4 -Chloroani1ine--Hexachlorobutadiene --l-Chloro-3-methylphenol- - 2-Methylnaphthalene ______- -Hexachlorocyc1opentadiene- - 2,4,6 -Trlchlorophenol --2,4,5-Trichlorophenol- - 2 -Chloronaphthalene- - 2 - N11 roan ill re_____--Dime t hy1pht haIa t e- - 2 , 6 - D i n i t ro t o 1 u e ne- - Acenaphthylene --3-Nitroaniiine --Acenaththere
10 u10 u10 u10 u10 u1.0 u10 u10 u10 u10 u
.10 u10 u10 ■ u10 u10 u10 u10 u10 u10 u10 u10 u10 u10 u10 u10 u10 u
■ 10 u20 u10 u10 u10 u20 u10 u
73b
FORM 1SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
Lab
Lab
Name :i|
Code :
COMPUCHEM
LIBRTY Case No.:
Contract: 8270C
SAS No.:
CLIENT SAMPLE NO.
SBLKII
SDG NO.: QE1877
Matrix: (soil/water) WATERi[
Sample wt/vol: 1000 (g/mL) ML
Level (low/med) LOW
% Moisture: _______ decanted: (Y/N)
Concentrated Extract Volume: 1000(uL)
[|Injection Volume: 1.0(uL)
Lab Sample ID: WG16228-1
Lab File ID: WG16228-1A60
Date Received:
Date Extracted:03/10/02
Date Analyzed: 03/12/02
Dilution Factor: 1.0
GPC Cleanup: (Y/N)
j- CAS NO.
N pH :
COMPOUNDCONCENTRATION UNITS: (ug/L or ug/Kg) UG/L Q
I
/ 11T
51-28-5------100-02-7- - 121-14- 2- - 132-64-9--84 - 66 -2------7005-72-3-86 - 73 - 7------100-01 -6- -
534-52-1--3 6 - 30 -6 --1 0 1 - 5 5 - 3 - - 1.1 8 - 74 - 1 - - 37-86-5---85-G1-8------120 - 12 - 7 - -8 6- 74- 8 ------8 4 -74 - 2 ------206 -44 - 0 - - 129-00- 0- -3 5 -66 - 7 ------91-94-1------117-91-7--
205-99-2--207-08-9--5 0 - 32 - 8 ---1 93 - 3 9 - 5 - -
1 9 1 - 2 4 - 2 - -
- Can riot
.---2,4-Dinitrophenol___________-- 4-Nitrophenol_______________-- 2,4-Dinitrotoluene-- Dibenzofuran________________-- Diethylphthalate-- 4 -Chlorophenyl-phenylether-- Fluorene __________________-- 4-Nitroaniline ~-- 4,6-Dinitro-2-methylphenol-- N-Nitrosodiphenylamine (1)-- 4 -Bromopheny1 -phenyletEer_-- Hexachlorobenzene___________-- Pentachlorophenol___________-- Phenanthrene_________________-- Anthracene-- Carbazole ____________-- Di-n-butylphthalate-- Fluoranthene_________________-- Pyrene_______ ________________-- Butylbenzylphthalate-- 3,3'-Diehlorobenzidine-- bis(2 - ethyl hexyl)Phthalate-- Benzo(a)anthracene__________-- Chrysene __________________-- Di-n-octylphthalate-- Benzo(b)fluoranthene_______-- Benzo(k)fluoranthene_______-- Benzo(a)pyrene _____________-- Indeno(1,2,3-cd)pyrene-- Dibenzo(a,h)anthracene_____-- Benzofg,h,i)perylene_______
separated trom Diphenvlamine FORM I SV■'
50 U20 U10 U10 u10 u10 u10 u20 u20 u10 u10 u10 u20 u10 u10 u10 u10 u10 u10 u10 u20 u
7 J10 u10 u10 u10 u10 u10 u10 u10 u10 u
8270C
73/
Data File: /chem/5872hp60. i/DF020312A60 * b/WGl£>228-lA&0 . d
Date : 12-MAR-2002 14;28
Client ID: SBLKII
Sample Info:
Volume Injected <uL>: 1.0
Column phase: J&W DB-5.625
Instrument: 5972hp60,i
Operator: 817
Column diameter: 0.32
00
COr~-
Data File: /chem/5972hp60. i/DF020312A&0. h/NGlb228-lAbO*d
Date : 12-MAR-2002 14:28
Client ID: SBLKII
Sample Info:
Volume Injected <uL): 1*0
Column phase: J&W DB-5*625
I nstrument: 5972hp60 * 1
cr>Operator: 917
Column diameter: 0*32
Data File: /chem/5972hp60.i/DF020312A60.b/WG16228-1A60.dReport Date: 13-Mar-2030 09:53
Data file Lab Smp Id Inj Date Operator Smp Info ■ Misc Info Comment Method Meth Date Cal Date | Als bottle Dil Factor Integrator
CompuChem
Semivolatile Report SW-846 Method 8270C /chem/59 72hp6 0.i/DF020312A60.b/WG16228 -1A60.d WG16228-1 Client Smp ID: SBLKII12-MAR- 2 0 0 2 14:28917 Inst ID: 5972hp60.i
/chem/5972hp60.i/DF020312A60.b/8270Cv6.m13-Mar-2030 09:03 byrd Quant Type: ISTD0 3-MAR- 2 0 0 2 17:20 Cal File: HL020303A60.d8 QC Sample: BLANK1.00000HP RTE Compound Sublist: OLM03.sub
Target Version: 3.50Processing Host: einstein
Concentration Formula: Amt * DF * Vt/(Vo * Vi) CpndVariable
Name Value Description
DF 1 1.00000 Dilution Factorvt '! 1000 . 00000 Volume of final extract (uL)vo: 1000.00000 Volume of sample extracted (mL)
# Vi 1 . 00000 Volume injected (uL)
Cpnd Variable Local Compound Variable
CONCENTRATIONSQUANT SIG ON-COLUMN FINAL
CLT.t'OUC.DS MASS : Zj \ p p7 EEL ?.T RESPONSE ( NG) ( ug/L)
'.r-d4 152 0 . ■ 4 1 r.: 2: {: .00.?} 9 7 0 3 S 40.0000• 1 6 : . 2 e :..2 = - • 1 . 0 0 C ; 2 3 9 5 2 3 4 C.0000
* ;■ .:-.c~GDpci:'e::-- d 1 ; :• j o • : '] o :'i : • c q i • c. 40 0000: E :• 2: ; E.. 7 : o: } ? 12 9 0 4 0.0000
IN '2 i ■ : . : ;• C:: 440199 40.00002o-; 2 ■ : ~: :: 4 1 4 2 8 n 4 C 0000
. r . t:: : 2 2 - . ■.: = 7 4 '.)' 2 7-5010 89.3364 89.34• V ~ ■ T ■ i ■0. ?311 208307 59.8929 5 9.89
:• ~ 2 ■ - ■ V . 8 -;. : 21116 2 61 .6570 6 1 . 6 6T ' r - .:c y .::v : 72 : 7 : :• = ■ :■■■; .'■.PH; 464030 599390 59 . 94
- \ ~ 1 4 7 i - T . " - V 1 . 104 , 319014 170.283 170.3: :: 7* 244 : f. 7 -. ' 0 . Oil. 3 92 515 73.0486 73.05
Cent c ; : Getect^d.v: N:
SIMILARITY
I AM) |
740
Data File: /chem/5972hp60.i/DF020312A60.b/WG16228-1A60.dReport Date: 13-Mar-2030 09:53
w
Compounds
QUANT SIG
MASS RT EX? RT REL RT RESPONSE
CONCENTRATIONS
ON-COLUMN FINAL
( NG) ( ug/L) SIMILARITY
18 2 ' Chloro'phenol 12S Compound Not Detected.
19 1 , 3-Dichloirocenzene 14 5 Compound Not Detected.
20 : ,4-Dichlorobenzene 145 Compound Not Detected.
22 1,2-Dicr lorobenzene 146 Compound Not Detected.
23 2-Methylphenol 106 Compound Not Detected.
24 2,2'-ox> bis(1 -Chloropropane; 45 Compound Not Detected.
27 4 - Methylpnencl 108 Compound Not Detected.
28 N-Nic roso-cii - N- propylamine 70 Compound Not Detected.
2 9 Hexachloro*thane 117 Compound Not Detected.
30 Nitrobenzene 77 Compound Not Detected.
31 T sophorone 82 Compound Not Detected.
3 2 2-Nitr^phenol 139 Compound Not Detected.
33 2,4-Dimethylphenol 122 Compound Not Detected.
34 Bis (2 -chloroetboxy;methane 93 Compound Not Detected.
35 2,4 -Dichiorophenol 162 Compound Not Detected.
3 6 1.2,4-Tr ichlorobenzene 180 Compound Not Detected.
37 Napht ha 1en* 128 Compound Not Detected.
3 “ 4 • Ch 1 oroar.nine 127 Compound Not Detected.
2 9 Hexachic robutadiene 22 5 Compound Not Detected.
4 - Chiore - 3 -mithylphenoi 107 Compound Not Detected.
:--Mer.hy: r.a oh t ha 1 ene 1 4 J Compound Not Detected.
4 4 H e a c h 1 r .ocyc . opentaaiene ■> 7 *7 Compound Not Detected.
4 5 2 . -i . <? - T t : ch: c ropher.c.i i4 Compound Not Detected.
2 . 4 , 5 -Ti : cr. 1 oropher.o 1 1 3 5 Compound Not Detected.
m - -: -■> - i-s: Compound Not Detected.
: -r- 6 5 Compound Not Detected.
5 0 Compound Not Detected.
5 - ■■■■■■■■ ; 5 Compound Not Detected.
A :s-.a r.: hy : 5 2 Compound Not Detected.
5 3 1 3 - Compound Not Detected.
54 A-Tir-sp!- b.ene ■54 Compound Not Detected.
55 184 Compound Not Detected.
5 4 rent : 10 3 Compound Not Detected.
2 , 4 ■ D: r.: ■ 4 £ Compound Not Detected.
== D i ber.tor urar. 1 D 8 Compound Not Detected.
59 Oiethylphi.-.a 1 ar * 14 9 Compound Not Dec ected.
4 :• 4 -Ch1c:c y.-e 2 04 Compound Not Detected
r Compound Not Detected.
- : A' 1 1 - Compound Not De t ec t ed
•: J 4 . • C : r; : 9 4 Compound Not Detected.
N ■ ■' - res co-.oeoyycnoe • c, Compound No: Detected.
4 - ::rc;-:cp :>3Py: leto.e:' Compound No: Detected.
2 " 4 Do~po..::o NCI Detected.
! 2 -3 - Compoun;; N C Detected
:J : Cot:-, jun.-ri No: Detected.
• ; 7 = CO-U.'V.;;-.-; Detected.
7 .. ; ,: : a :: ; • - 7 rui- i.--
I
7
Data File: /chem/5972hp60.i/DF020312A60.b/WG16228-1A60.dReport Date: 13-Mar-2030 09:53
II QUANT SIG
Compounds
iMASS RT EXP RT I*EL RT
72 Di-n-butylphthalace 149 Compound Not Detected
74 Fluoranthene 202 Compound Not Detected
76 Pyrene 202 Compound Not Detected
77 Butylbenzylphthaiate 149 Compound Not Detected
7 S 2,2'-Dichiorobenzidine 2 52 Compound Not Detected
1C bis:2•ethy1 hexyl) Pht halate 149 20.576 20.574 (0.996)
so Bento • a i a:-.:hracene 22S Compound Not Detected
u •Chryser.ej
228 Compound Not Detected
5 2 Ci-n-cc:y1pht hala te 14 9 Compound Not Detected
C } Benzo 'bi fluoranthene 2 c o Compound Not Detected
c 4 5 e r. z o ' x i flu c: a r. t h e n e 252 Compound Not Detected
55 Renzo : a ) pyrene 252 Compound Not Detected
5 6 Inaeno:1,2,2 -cd;ovrene 276 Compound Not Detected
57 D: ber.zo (a . h > ant hracene 279 Compound Not Detected
2 2 fcer.zo ; u , h , i j pery 1 ene 276 Compound Not Detected
RESPONSE
74210
CONCENTRATIONS
ON-COLUMN FINAL
( NG) ( ug/L) SIMILARITY
9510 (a)
QC Flag Legend
A -
Target compound detected Below Limit Of Quantitat Target compound detected exceeded maximum amount. Compound response manual
but, quantitated ion(BLOQ). but, quantitated
ly integrated.
amount
amount
i
Data File: .,,chern/5972hp60.1 /DF020312h60 . b/UJGl6228-1A60. dInjection Date: 12-MHR-2O02 14:28Instrument: 5972hp60.1Client Sample ID: SELF11
bound:^Number
4,6-T nbromophenol 118-79-6
Ion 329.60: Area: 319014 Height: 159390
$
1 - . 7-5 i J . 40 14.45 14.50 14.55 14.60 14.65 1 4.7Q 14.75 14.80 14.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20______ Min_____________________________________________________________
Ion 332.00: Hrea: 0 Height: 0
l
if'
14.50 14 70 14.77, 1 4 . 14.35 14.90 14.90 15.00 15.05 15.10 15.15 15.201-1: r, _____________________________________________________________________________________
■a: H*i--ht : 0
............. . - ________ __________7J..0
1 4.5b 1 4 . so 14.4,5 14. 7*0 1 4 . "5 14.80 14.35 14.90 14.95 15.00 15.05 15.1m 15.15 15.20 r '• i n
Data File: /chem/’5972hp60.i/DF020312A60*b/WG16228-lA60*d
Date : 12-MAR-2002 14:28
Cl lent ID; SBLKIIj
Instrument: 5972hp60 *i
Samp 1e I rjif o:
Volume Injected <.uL>: 1.0 Operator: 917
Column jg,u DE-5.fi.25 Column diameter: 0*32
7^ bis(2-ethylhexy1>Phthalate Concentration: 6*52 ug/L
CompuChema Division of Liberty Analytical Corp.
GC/MS SEMI-VOA WORKSHEET
LAB INSTRUCTIONS:
RECEIPT DATE: 3/8/02 0:00
CASE#:
CLIENT
SDG: WG16228
ID: SBLKII
SAMPLE DATE: DUE DATE:
COMPUCHEM#: WG16228-1
ANALYSIS DESCRIPTION: SVOA-8270C
Injection Volume : 1.0
Extraction Date 10 / 02
DFTPP Filename DF020312A60
Sample Fjile Name___VVG16228-1 A60_i|
ANALYST (S): Injection917_________
Dilution Prep (if needed)_
Work-up Li /' ?
GC/MS DATE REVIEW
CONDITION CODE
Extraneous Peak Search Results:l|
Number of peaks found:
Number ol Hits found:
t'l/k
Number of Surrogate Outliers:
(/utility Assurance Notice (s) Number of Notices Required_____
Comments:
Disposition: \ Complete
[ ] Reinjection Required
[ ] Re-extraction Required
[ ] Reinject Neat
[ ] Dilute ( X)
"tiCMS Rosier_______________________ Date ■' ! ^ Auditor_
Final Reportable Package! s):
L-Ob /£i Ur-/ o
Date
74 j
SVl -6/27/01: PTF
.iiiii T ii~i ri^n
ASSIGNED TO:
CnmpuChem
EXTRACT ION WORKSHEET
DA I K EXTRA' TED/POS I LD:
IMP ID NUMBER:2A"hD r
-079 S-lloi 7 / t/tT
j;:, SAMPLE;. , FINAL Adjusted DH' -_i.
SAMPLE >*„ ;JtjC SAMPLE ; -VOLUME: ; VOLUME A/N BASE V-rO'SA/i.COMMENTS -A (^-
NUMBER'. ' TYPE ' J____ (m|) ; v -y-.V -.y\ ■ A--'AQe/tr?- g- /OoO 1^ /A »2 ;
2_L_J__2. /ore _______ l.ft A h i2-i
* A> /tt* ______ 1.0 /.u \7- \_____________ a /OCa 1.0 /A, a i
/ /*£
/too ill lL \7.\ t// Qe- A? yAA
/? /too _Jji ! b |2 1’___________ ■/£. //e<o ■C JA 12.i- / /r
jo<rc \.o /L >2.11 .1_______IA-
/a to \-D Lh ns
)/ 7 /COO lo
/ £ \7\
\/r /OCC lo J.L tii
2 { < -^1- /coo • 1,0 /A (2.»
3/coo _____ lo /A 17 1
4 * S3 /ooo _______lo________ /A I2.i
s Gfr-irn-1 /COG III) /A I'M
ujefr/ozY~/ /OC0 1-0 IA Q.1 f-* £_x-fTSc'V- c /<. rJ
1
H H 1 //t’l1
0-—cA—
i/ll/-
01
1 ___ ■——
.2 ---------------------------------
>3 iMrfb'ZZtir-'lBLK
jm t'O 12.1A <] S' Z'
LCS /OOP l.o A G l-2-l *Add 1.0 ml. validation spike in I CS and SSs ualrss otherwise noted
S-VOL Acid /B/N 8270j, l)
NO. 393■ \ // ^ FINAL VOLUME VERIFIED: ‘-'"'U/l/| _______
SURROGATE AMT. 1.0 ml A/"A /
.____ ____►LOT . <3 7.71 t/
^—SUPERVISOR REVIEWED: : .... ' -------
NO. 3012/ 2021 VAI.il).SPIKE AMT. l/il 1.0ml 1.0 ml
LOT SURROGATE: & SPIKE ADDED BY:______________'.A-ll.-i________ ___ -
KD JYVAnalyst initials Extracted
Manu r and lol number of reagents/solvents used
!f\<^ C&Initials Dale
_____N2 Bottle up Witness .
W.^-Vo'b&x^___My/- ____RrMiiLW... JBr
FORM 1 CLIENT SAMPLE NO.1 SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: COMPUCHEM Contract 8270CSBLKJG
Lab Code: LIBRTY Case No.: SAS No. SDG No.: QE1877
Matrix: ( soil/water) WATER Lab Sample ID WG16304-1
Sample wt/vol: 500 (g/mL) ML Lab File ID: WG16 304-lB60_9
Level : (low/med) LOW Date Received
% Moisture: decanted: (Y/N) Date Extracted:03/14/02
Concentrated Extract Volume: 500 (uL) Date Analyzed 03/14/02
In j action Volume: 1.0(uL) Dilution Factor: 1.0
GPC Cleanup: (Y/N) N pH:
CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
108-S5-2-------- Phenol 10 u111-44-4-------- Bis (2 - chloroethyl) ether 10 u95-57-8----------2 - Chlorophenol 10 u541-73-1-------- 1,3 - Di chlorobenzene 10 u106 -45 - 7-------- 1, 4 -Dichlorobenzene 10 u95-50-1----------1,2 - Dichlorobenzene 10 u95-48-7----------2 -Methylphenol 10 u108-6 0-1-------- 2,2' -oxybis (1 -Chloropropane) 10 u106-44-5-------- 4 -Methylphenol 10 u621-64-7-------- N-Nitroso-di -N-propyl amine 10 u6 7- 72-1----------Hexac hi oroe thane 10 u98-95-3----------Nitrobenzene 10 u78-5 9 -1----------I sophorone 10 u38-75-5----------2 -Nitrophenol 10 u105-67- 9---------2,4 -Dimethyl phenol 10 u111-91-1-------- Bis (2-chloroethoxv) methane 10 u120- 8 3- 2-------- 2,4 -Dichlorophenol 10 u12 0 - 32-1-------- 1,2,4 - Tri chlorobenzene 10 uSl-20-3----------Naphthalene 10 u10 6 - 47- 8 -------- 4 - Chloroani 1 me 10 u8 7- 68- 3 ----------Hexachlorobutadiene 10 u5 9 -50 -7----------4 - Chloro - 3 - methylphenol 10 u91-57-6 ---------- 2 -Methvlnaphthalene 10 u77-47-4----------- Hexa chi orocycl open tadiene 10 u88 - 06 - 2 -----------2,4,6 -Trichlorophenol 10 u5 5- 95 -4-----------2,4,5 - Trichlorophenol 10 u91-5 8- 7----------- 2 -Chloronaphthalene 10 u8 5 - 74 - 4 -----------2- Nit roam line 20 u13 1 - 11 - 3----------D i me t hy 1 pn t ha 1 a t e 10 u60 6 - 2 0 - 2--------- 2, 5 - Di nitre toluene 10 u2 08 - 91-8--------- Acenaphthylene 10 u5 9 - 09 - 2 -----------3-Nit roamline 20 u8 - c 2 - v-----------Ac s n ci p b t b n -s 10 u
FORM I SV 8270C
FORM 1SEMIVOLATILE ORGANICS■ ANALYSIS DATA SHEET
CLIENT SAMPLE NO.
Lab Name: COMPUCHEM
Lab Code: LIBRTY[|
Matrix: (soil/water)
Sample wt/vol:
Level :i (low/med)
Moisture:
Concentrated Extract
Contract:
Case No.: SAS No.:
WATER
500 (g/mL) ML
LOW
decanted: (Y/N)
Volume: 500(uL)
Inject ion Volume: 1.0(uL)
8270CSBLKJG
SDG No.: QE1877
Lab Sample ID: WG16304-1
Lab File ID: WG16 304-1B60_98 5
Date Received:
Date Extracted:03/14/02
Date Analyzed: 03/14/02
Dilution Factor: 1.0
GPC Cl1eanup: (Y/N) N pH:
CAS NO.CONCENTRATION UNITS:
COMPOUND (ug/L or ug/Kg) UG/L Q
51-28-5----------2,4 -Dini trophenol 50 u100-02-7-------- 4 -Nitrophenol 20 u121-14-2-------- 2,4-Dimtrotoluene . 10 u132-64-9-------- Dibenzof uran 10 u84-6 6 - 2----------Diethylphthalate 10 u7005-72-3------- 4-Chlorophenyl-phenylether 10 u86-7 3 - 7----------Fluorene 10 u100-01-6-------- 4-Nit roaniline 20 u534-52-1-------- 4,6 - Di ni t ro - 2 - methylphenol 20 u8 6- 30-6----------N-Ni t rosodiphenyl amine (1) 10 u101-55-3-------- 4 - Bromophenv 1 - phenyl etEer 10 u118-74-1------- - Hexachlorobenzene 10 u8 7- 8 6 - 5----------Pentachlorophenol 20 u8 5-01-8----------Phenanthrene 10 u120-12-7-------- Anthracene 10 u86 - 74 - S----------Carbazole 10 u84 -74 -2----------Di - n - butylpht halate 10 u206-44-0-------- Fluoranthene 10 u129-00-0 -------- Pyrene 10 u8 5- 68-7----------Bu t v 1 be n z v 1D h t ha 1 a t e 10 u91-94-1----------3,3'-Dichlorobenzidine 20 u117-81-7-------- bis (2 - et hy lhexvl ) Phthalate 10 u5 6 - 55 - 3 ----------Benzo ( a ) ant hracene 10 u213-01-9-------- Chrvsene 10 u117-34-0-------- Di - n - octy Ipnt iiaiate 10 u2 0 5 - 99- 2.---------Benzo (b) fluoranthene 10 u
■ 2 0 7 - o 5 - 9-------- Benzo (k) 11 uorant hene 10 u10 u
19 3- 89-5-------- I nde no (1 , 2, 3- cd ) pyrene 10 u5 8 - 70 - 3 ----------Dibenzo (. a , n > ant hracene 10 u191-24-2-------- Benzo ig, n, i ) cerylene 10 u
(ll 1 Cannot be separated from Liphenvlamme
FORM I SV 8270C
74b
Data Filet /chem/5972hp60. i/DF020314B60,b/WG16304-*£0_985.d
Date : 14-HAR-2002 21:40
Client ID: SBLKJG
Sample Info;
Volume Injected (uL); 1,0
Column phase: J&W DB-5,625
Instrument; 5972hp60. i
Operator; 2319
Column diameter: 0.32
•^r
Is--
2.4/6-Tribromcpheno1+
Data F i le: /chero/5972h|o60. i/DF020314BG0.ti/lClio304-lE£,0_?85..-J
Date : 14-MAR-2002 21:40
Client ID: SBLKJG
Sample Infos
Volume Injected <uL>: i.O
Column phases J&W DB-5.625
Instrument: 5972hp60.i
Operator: 2319
Column diameter: 0.32
DL.O
r^-
Data File: /chem/5972hp60.i/DF020314B60,b/WG16304-1B60_985.dReport Date: 15-Mar-2030 11:04
Data file Lab Smp Id Inj Date Operator;Smp Infoi Misc Info Comment Method Meth Date Cal Date Als bottle Dil Factor Integrator Target Version:
CompuChem
Semivolatile Report SW-846 Method 8270C /chem/5 9 72hp6 0.i/DF020 314B6 0.b/WG16304 -1B6 0_985.d WG16304-1 Client Smp ID: SBLKJG14-MAR- 2 0 0 2 21:402319 Inst ID: 5 972hp6 0.i
/chem/5 972hp6 0.i/DF020314B60.b/8270Cv6.m15-Mar-2030 10:11 byrd Quant Type: ISTD0 3-MAR- 2 0 0 2 17:20 Cal File: HL020303A60.d3 QC Sample: BLANK1 . 00000
HP RTE Compound Sublist: OLM03.sub3 . 50
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
DF 1 1 . 00000 Dilution FactorVt ! 500.00000 Volume of final extract (uL)Vo ■ 500.00000 Volume of sample extracted (mLVi 1.00000 Volume injected (uL)
rpna Variabl Local Compound Variable
CONCENTRATIONS
v'u'A.‘i. S IG ON-COLUMN FINAL
pc^.s MASS FT EX? F.T PEL F.T RESPONSE ! NG) ( ug/L)
■ ■ ---.I-.--,-....-..-.-ip1 C. - 3 . i • 6 -.;? 7 -i.o c 0 ■ 86211
0000«r
2 lor.--- • 3 € : 0 . 2 r 4 ; 0.2 3 6 .1.000. 234309 40.0000
• - • ’ P: • * : - - ■ 16 4 -:2. n • ■:. ■ 6 4 ;. 0:01 205029 4 0 . 0000
4 Pi-rth 185 ■: oc-o; 416521 40.0000
. : 24 0 6 04 2 1 4 2 2 1 .0 0 ; 4 1 3220 40.0000
: ::: 2 6 4 2 2 '7; 253026 40.0000
: 12 0 2: : 74 c ’. 32346 t 6 4 6 6 9- 6 6.47
95 . 17 7 ■.e;= -..331: 166256 53 . 7044 5 3.70
3 2 ■■ . ' 6 - ■■ - - :. p 3 2 ■■ 147073 43 . 8084 4 3.81
: 7 “> : 2 . ; 7 :: : 368070 46 . 1753 4 6.18
■ r;-; :-;p:-- —: 3 3 0 : 4 7 6; ■.4 ■.'■■■ .1.104; 373476 1 4 4. 364 144 4
; - -rijr.T’:v 244 960805 75.0535 75 . 09
■■ ' V 3 4
....i ; ” ' n :
SIMILARITY
751±
Data File: /chem/5972hp60.i/DF020314B60.b/WG16304-1B60_985.d
Report Date: 15-Mar-2030 11:04
Compounds
UUANT SIG
MASS RT EXP RT REL RT RESPONSE
CONCENTRATIONS
ON-COLUMN FINAL
( NG) ( ug/L) SIMILARITY
19 1,3 -Dichlorobenzene 146 Compound Non Detected.
20 1,4-Dichlorobenzene 146 Compound Not Detected.
t>9 1,2-Dichlorobenzene 146 Compound Not Detected.
23 2-Methylphenol 106 Compound Not Detected.
24 2.2'-oxvbis(1-Chloropropane) 4 S Compound Not Detected.
27 4-Metnviphenol 106 Compound Not Detected.
23 N - N itrose -di-M- propylamine 70 Compound Not Detected.
29 Hexachioroethane 117 Compound Not Detected.
30 N i t rober.zene 77 Compound Not Detected.
31 T soohoror.e 32 Compound Not Detected.
32 2-NitroDhenol 139 Compound Not Detected.
33 2 4-Dimethy1oheno1 122 Compound Not Detected.
341
Bis (2 -cnloroethoxv>methane 93 Compound Not Detected.
3 5>1
2 . 4 -Dichloropnenol 162 Compound Net Detected.
"■,24 -Tr ichiorobenzene L30 Compound Not Detected.
11 Naphtha Lene1
128 Compound Not Detected.
127 Compound Not Detected.33
39 Hexachiorcbur adiene 225 Compound Not Detected.
4-Chloro-3-methylphenoi 107 Compound Not Detected.
42 7-M^thvlnaDhthalene 142 Compound Not Detected..
Hexacnlorocyclopentadiene 237 Compound Not Detected.
45 2,4 5-Trichioroohenol 156 Compound Not Detected.
- - 2,4,5-Trichlorophenol 196 Compound Not Detected.
2 - Ch I oror.aoht ha i ene 162 Compound Not Detected.1
2 -Nilroani1ine 6 5 Compound Not Detected.
so D met hy Ic-htha late 163 Compound Not Detected.
SIi
2 --Diniirotnuene 16 5 Compound Not Detected.
,iAcenaphthylene 152 Compound Not Detected.
- - N: t roar,:1 1 r.e 13b Compound Not Detected.
5 4 Acenaphthene 154 Compound Not Detected.
2 . 4 - Dm :t rcoheno : 104 Compound Not Detected.
Comoound Not Detected.5 o 4 - N;: rooneno 1
5 7 4 - l t ' c i c-1 j e r. e 16 5 Compound Nc-t Detected.
Compound Det ected.benzolu: u:‘
,, ^_r. Detected.i! i e t hy i or.t r.a .- e
. -U ■.. ;'.:-.er.'.-: e: her 2 7 4 Domonunci N at Detected
165 Comccun: Detected
1 3 6 Compour.:j No- Detected
• .. ....... „... ; Ht: lompeun: : Detected
j . - - .... letectec
24 5 Detected
2 c 5 Compoun t Detected
t .i N • Detectede r. t j z• c: l ;. - r. o . ** 5 -
-v. J. - 178 Com pour. •j No t Detected
. r- .. t Detected. Ar. t r. r a c e r.•*- *
Ccnocun n No t Detected
7 C: -n-buty-tr.a la-e 14 9 it Deteccec
.75'
Data File: /chem/5972hp60.i/DF020314B60.b/WG16304-1B60_985.dReport Date: 15-Mar-2030 11:04
I
i 'jvJANT S I ^
Compounds MASS RT EXP RT REL RT
74 F luoraritnene 2 02 Compound Not Detected
76 Pyrene 202 Compound Not Detected
77 But ylbe'nzylphcha lace 14 9 Compound Not Detected
78 3,3' -Dichlorobenzidir.e 252 Compound Not Detected
79 bis(2-ethylhexyi)Phthalate 149 Compound Not Detected
80 Benzo (a,) anthracene 228 Compound Not Detected.
91 Chrysene 22 5 Compound Not Detected.
82 Oi - n- octyiphthalace 14 9 Compound Not Detected.
9 3 Benzo . b:fiuoranthene 252 Compound Not Detected.
84 Benzo :k)fiuoranthene 252 Compound Not Detected.
95 Benzo(a Jpyrene 252 Compound Not Detected.
86 Inaeno(1,2.3-cd)pyrene 276 Compound Not Detected.
87 Dibenzo(a,h)anthracene 278 Compound Not Detected.
B 8 Benzo(g,n,iiperylene 275 Compound Not Detected.
CONCENTRATIONS
ON-COLUMN FINAL
{ NG) I ug/L)
QC Flag 'Legend
M - Compound response manually integrated. i
similar:
i
i
•75
ll
Data File: /cnem/5972hp60.1/DF020314B60.b/UG16304-1B60_965.d Injection Date: 14-MAR-2002 21:40 I nstrument: 5972hp60.1 Client Sample 11D: SBLKJG
hound: 2"Number:
.4.6-Tribromophenol 1ll3-79-6
Ion 329.60: Area: 278476 Height: 132184
1 • 3-
1.2-
1.1-
1-0- 0.9-.
0.8- in 0.7-
? °'6-
0.5
0.4-
0.3-;
0.2- 0.1 - 0. 0 - —
14.30 14.3* 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.7' __________ H l n
14.80 14.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20 15.25
Ion 332.00: Area: Height: 0
0.4
0.1
:4 . :o 14.35 14.40 14.45 14.50 14.55 14.60 1J.65 M . 70 14.75 14.60 14.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20 15.25IMj_n
Ion 141.00: Area; o neignt: 0
0. d75
4 15 14.40 14.45 14.50 14.5b 14,60 14.6b 4 14.75 14.80 14.85 14.90 14.95 15.00 15.05 lb.10 15.15 15.20 15.25M: n ______________________________ _______________
CompuCjhema Division of Libert) Analytical Corp.
! GC/MS SEMI-VOA WORKSHEET
I
LAB INSTRUCTIONS:
RECEIPT DATE: 3/14/02 0:00 SAMPLE DATE: DUE DATE:
CASE?: | SDG: WGI6304 COMPUCHEM #: WG16304-1
CLIENT ID: SBLKJG
ANALYSIS DESCRIPTION: SVOA-8270C
Injection Volume :IpL Dilution Prep (if needed)l|
Extraction Date__ 3___/14____/___02
DFTPP Filename____ DF020314B60
Sample File Name____ WG16304-1 B60 „ ______________
ANAL.YST(S). Injection2310Work-up__________________________
GC/MS DATE REVIEW
CONDITION CODE
6^
Extraneous Peak Search Results:
Number of peaks found:
Number of Hits found:______ ______
Number of Surrogate Outliers_______
Quality Assurance Notice is) Q Number of Notices Required
i 1-------
/cDisposition: [ ^ Complete
[ ] Reinjection Required
j ] Re-extraction Required
[ ] Reinject Neat
| ] Dilute t X)
C comments.
-GC/MS Review_____ Date /N Auditor_
Final Reportable Packaeels): ^ rs*'
Date / /
75j
SV1 - 6/27/01: PTF
c. Laboratory Control Sample Data
Arranged in chronological order, by extraction date
- Tabulated Results (Form I SV)
- Reconstructed Ion Chromatogram and quantitation report
757
FORM 1SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO.
SIBLCSLab Name: COMPUCHEM
Lab Code: LIBRTY Case No.:}
Matrix: (soil/water) WATER
Sample wt/vol: 1000 (g/mL) ML
Level: (low/med) LOW
% Moisture: decanted: (Y/N)
Contract: 8270C
SAS No.:
Concentrated Extract Volume: 1000(uL)
Injection Volume: 1.0(uL)
GPC Cleanup: (Y/N) N pH: ___
SDG No.: QE1877
Lab Sample ID: WG16230-2
Lab File ID: WG16194-2JB64_985
Date Received:
Date Extracted:03/08/02
Date Analyzed: 03/12/02
Dilution Factor: 1.0
CAS NO. COMPOUNDCONCENTRATION UNITS: (ug/L or ug/Kg) UG/L Q
108-95-2---------Phenol 23111-44-4---------Bis (2 - chloroethyl) ether 3895-57-8----------2 - Chlorophenol 35541-73-1-------- 1,3 - Di chlorobenzene 25106-46-7-------- 1,4 - Dichlorobenzene 26S5-50-1----------1,2 - Dichlorobenzene 2695-4 3- 7----:----- 2 -Methylphenol 55108 -6 0-1-------- 2,2' - oxybis (1 - Chloropropane ) 40106 -44-5---------4 -Methyl phenol 100621- 6 4- 7-------- N-Nitroso-di - N-propylamine 5267 - 72 - 1 ----------Hexachloroethane 2593 - 95- 3 ----------Nitrobenzene 387 8 - 59- 1----------I sophorone 5133 -75 - 5 ----------2 -Nitrophenol 40105-67-9-------- 2,4 - Dimethyl phenol 36111-91-1-------- Bis (2 - chloroethoxy) methane 54120-8 3 - 2-------- 2,4 - Dichlorophenol 4412 0- 82-1-------- 1,2,4 -Trichlorobenzene 3191-20-3----------Naphthalene 32106 -47- 3 -------- 4 - Chloroani 1 me 7437 - 66 - 3 ----------Hexachlorobutaaiene 3159 -50 -7----------4 -Chloro- 3 -methylphenol 5891-57-6----------2 - Methylnaphthaiene 59
i 77 -47-4----------Hexachlorocyclopentadiene 32; 33 - 06 - 2 ----------2,4,6 -Trichiorop’nenoi 5395-95 -4----------2,4,5 -Trichlorophenol 6991-53-7----------2 - Chi oronapht ha lene 5033 - 74 - 4 ---------- 2 -Nitroaniline 79
j I 31-11-3-------- Dime t hy lpht ha late 736 06 -20-2-------- 2, 6 - Dmitro toluene 58
: 2 0 6 - 96 -3-------- Acenaphthylene 489?-09-2----------3 - Ni t roam 1 me 85
; b2 - 32 - 9----------Acenapnthene 441
FORM I SV 8270C
Lab Name:
Lab Code:
Matrix: (soil/water)
Sample wt/vol:
Level:1 (low/med)
% Moisture: _______ decanted: (Y/N)
Concentrated Extract Volume: 1000(uL)i
Inject.ion Volume: 1.0 (uL)
SAS No.: SDG No.: QE1877
Lab Sample ID: WG16230-2
Lab File ID: WG16194-2JB64_985
Date Received:
Date Extracted:03/08/02
Date Analyzed: 03/12/02
Dilution Factor: 1.0
FORM 1SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO.
SIBLCSCOMPUCHEM
LIBRTY Case No.:
WATER
1000 (g/mL) ML
LOW
Contract: 8270C
GPC Cleanup: (Y/N) N pH:
CAS NO. COMPOUNDCONCENTRATION UNITS: (ug/L or ug/Kg) UG/L Q
51-28-5----------2,4-Dinit rophenol 150i 100-02 - 7-------- 4-Nitrophenol 29121-14-2-------- 2 , 4 - Dinitrotoluene 59
i 132 -64 - 9 -------- Dibenzofuran 73| 84 - 66 -2 ----------Diethylphthalate 71; 7005-72-3------- 4 -Chlorophenyl-phenylether 69,j 86-73 -7----------Fluorene 511 100-01-6-------- 4-Nitroanil ine 78l 534-52-1---------4,6 - Dinit ro- 2 - methylphenol 771 86 - 30-6 ----------N-Nitrosodiphenylamine (1) 69, 101-55-3---------4 - Bromophenyl - phenyletEer 71• 118-74-1-------- Hexa chlorobenzene 6137- 8 6- 5 ----------Pentachlorophenol 523 5-01-8----------Phenanthrene 5312 0-12-7-------- Anthracene 54
; 8 6- 74-8 ----------Carbazole 798 4- 74-2-----J--- Di-n-butylphthalate 70
.2 06 -44- 0 -------- Fluoranthene 53j 12 9 - 00 - 0 -------- Pyrene 52
1 1 85 - 65 - 7 ----------Butylbenzylphthalate 70t91-94-l----------3,3' - Dichiorobenzidine 451 117 - 31 - 7---------bis ( 2 - ethyl hexyl) Phthalate 75 B56 - 55 - 3 ----------Benzo (a) anthracene 53
j 54i 117-84-0-------- Di - n -octylphthalate 6 8
i2 0 r - 9 9 - 2-------- Benzo ! b) t1uoranthene 4 3
! - u / - -j - - -------- senzoi k i r i uorant nene 6 5 .! n-s - Benzo ( a ) pyrene 52
i 9 i - i a - r>-------- I ndeno (1,2,3- cd ) pyrene 64; s4 - 7u - 3----------Dibenzo (a, h) anthracene 53
i I :n -1- -2-------- Benzo' g , h , i! oervleneIJ____________ ._____________
52
i lZ - Cannot be separated irom DiphenylamineFORM I SV 8270C
753
Data File: /chem/5972hp64.i/DF020311B64.b/WG16194-2JB64_985.d
Date : 12-MAR-2002 04:27
Client ID; SIBLCS
Sample Info:
Volume Injected <uL): 1.0
Column phase: RTX-5
Instrument: 5972hp64.i
<LO
Operator; 2319 r^-
Column diameter: 0.32
Sample Info:
Volume Injected <uL>: 1.0 Operator: 2319
Column phase: RTM-5 Column diameter: 0,32
Data File: 7chem/5972hp64.i/DF020311B64.b/WG16194-2JB64_985.d
Date : 12-MAR-2002 04:27
Client ID: SIBLCS Instrument: 5972hp64.i
T9 Z
Data File: /chem/5972hp64.i/DF020311B64.b/WG16194-2JB64_985.dReport Date: 13-Mar-2030 12:57
CompuChem
Data file Lab Smp Id Inj Date Operator Smp Info Misc Info
Semivolatile Report SW-846 Method 8270C /chem/5 9 72hp64.i/DF02 0311B64.b/WG16194- 2JB6 4_98 5.d WG16230-2 Client Smp ID: SIBLCS12-MAR- 2 0 0 2 04:272319 Inst ID: 5972hp64.i
Comment Method Meth Date Cal Date Als bottle Dil Factior
Integrator Target Version: Processing Host:
/chem/5972hp64 12-Mar- 2 03 0 08 10-MAR-2002 17 111 . 00000 HP RTE
3 . 50einstein
i/DF020311B64.b/8270Cv6.m 15 mikhael Quant Type: ISTD 23 Cal File: HL020310A64.d
QC Sample: LCS
Compound Sublist: OLM03.sub
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
DFVt
VdVi
1.00000 Dilution Factor1000.00000 Volume of final extract (uL)1000.00000 Volume of sample extracted (mL)1.00000 Volume injected (uL)
Cpnd Variable Local Compound Variable
CONCENTRATIONS
Compc ends MASg RT EX? RT REL RT RESPONSE
ON-COLUMN
( NG)
FINAL
( ug/L)
: 1 , 4 2: c c-.-i- i.; 2 52 5.2S-: -. :di ;:. ooo: 102221 40.0000
2 Nae::c r.A -. ■. . : i. - 353654 40.0000
Ac Tt.iip:', ■■ ■ -.-.r : • : 7. 2 7 1 £ 4 0 ■i 'J . 0 0 ‘ J V
4 Phena;:: 1 5 .1 - i ■ 5.4 = 2 ■. i.ooo; 546779 40.0000
vs-:'. 2 4 9 - : 1 . 000) 522377 40.0000
2 64 :• 2 - ; i.ooo: 306460 40.0000
:: 2 . i" ■■ -..4 55 ;c. 7si; 179437 54 . 0791 54.08
:■ : - -It 7 v 9. 7 (Q.oio i 151914 44.4033 4 4.40
N:: roco 6 2 5 . } C 9 (0.397} 164844 39.701 7 39.70
: c 2 -FI uor- ir.:?r.er.y\ 172 : : ii.; :10. S02.» 472192 52 . 1 370 52 . 14
; 1 : C . I . ■ 7 '■ r:■ ■
4 4 ■: 2 (2.0 0 9 ' 313166 114.421 114.4
' ' ? Terphe:' : • d *. •; 2' •' . - •> 7 (0.8951 851392 61 . 5 5 7 4 6 1 . 57
Pn-nc! Vi 7 7 7 : ~ . 7 74 10.941/ 8 6 0 21 23 . 1 593 2 3.16
: 7 5 : c • 2 :Ic:-oec.-.y '.•j: O'.'v (0 5 57’ 9 6 3 5 5 38 . 3972 3 8.40
SIMILARITV
«\
7 67
Data File: /chem/5972hp64.i/DF020311B64.b/WG16194-2JB64_985.dReport Date: 13-Mar-2030 12:57
Compounds
18
1 9
20
22
23
24
2 9
30
31
32
33
34
3b
2 -Chlorophenoi
1.3- Dichlorobenzenei|
1.4- Dichlorobenzene
1,2-Dichlorobenzene
2-Methyl phenol
2,2'-oxybis(l'Chloropropane)
4 -Methylphenol N- Hitrojso - d i - N-propylamine
Hexachloroethane
Nitrobenzene
Isopherone
2-Nitrophenol
2.4- Dimethylphenol
3is(2 -chioroethoxy)methane
2,4 -Dich1orophenol
Naphtha 1 ene
4 - Ch 1 o roan: lire
Hexacr. 1 orobut ad i ene
4-Chicrc-i•methyipheno1
2 - Methvinapht ha 1enei!
He.xacn 1 oroc: inert a di er.e
2 - Ch 1 oror.aph: ha 1 ene
2 - Ni t roar.: 1 : re
A "■
3 - r;
D: r.:
I
CONCENTRATIONS
ANT SIG ON-COLUMN FINAL
MASS RT EXP RT REL RT RESPONSE ( NG) ( ug/L) SIMILARITY
128 0.012 8 . 010 (0.969) 121260 35 . 3038 35 . 30 8808 .
14 6 8 .215 8.213 (0.994) 99454 25.2018 25.20 (Ml-
14b 8 .282 8 . 281 (1.002) 104046 26.1293 26 . 13 (M) \
146 8 . 570 9.568 (1.037) 103477 26.4015 26.40 (Ml \
109 8 .637 S . 636 (1.045) 163495 54.5867 54 . 59
45 8 . 671 8 . 670 (1.049) 184988 39.6968 39.700 (M! \
105 8 . 6 4 0 6.639 (1.0701 329904 101 . 336 101 . 3
70 8 .874 5.873 (1.074) 105919 51.6234 51 . 62 7152
117 9.009 9.008 (1.090) 51327 24 . 9068 24 . 91 9420
77 9 . 128 9 . 126 (0.098) 123246 37.8087 37.81 9727
32 9.449 9.448 (0.930) 326389 50.5670 50.57 94 70
139 9 . 601 9 . 600 (0.945) 82588 40.1313 40.13 8316
122 9 . 601 9 . 6 0 C (0.945) 11064 0 36.0718 36.07 7 351
9 3 9.753 9.752 (0.960) 207323 S3 . 8162 53 . 82 9528
162 5 . 939 9 . 938 (0.978) 141073 44 .4068 44.41
1 8 0 10.075 10 073 (0.9921 114208 3 0 . 3 3 0 3 30.63(Ml\
1 2 5 10.176 10.175 (1 . 002) 442021 31 . 8774 31 . 88 97 8 7
127 10.260 10.259 11.010) 327430 73.3439 7 3 84 8398
225 10 4 3 0 10.426 •: l .027) 77997 30.5732 30 . 57 8905
I 0 7 1 o . 9 3 7 1 0 9 3 (1 .077 1 203005 57 . 5173 57 52 9759
14 2 11.224 - 1 2 2 1 < 1 . 10 5 1 407390 58.6177 58 . 62
2 3 11 613 i: .59-; i 0 . 8 6 2 ' 86395 32.0838 32.0B 95 3 0
I 1 . 7 4 t 11 74"“ (0.892) 147590 53.3472 53.35
196 11.933 11.931 (0 . B99) 201313 68.5897 68 . 59
162 - -> 170 12.115 (0.920) 349265 50.0772 50 . 08
r c 12.357 12.355 ( 0 . 938) 196772 78 .8135 78.81 9 3 6 2
1 r:. T 12.675 12.677 (0.9631 618923 72.6246 72.62 94 76
!«5 12.547 12 84 6 ( 0.976 1 136045 58.0147 58.01 3505
• - 1 -> pee : "! 3f, 10.579) 778690 47.5652 47.57 9572
13.101 : • .0 = 2 (0.995) 211656 100.007 100.0 384 3
: 54 1 2 : i :■ 1 : 213 ' 1 .004) 466566 44 . 033 1 44 . 03 97 5 5 V
1 3 2 7 3 : 3 2 - ^ ;i.0081 62090 149.706 149.7(MJ ^
;o v 13.321 : 3 . 3 : s 2 0 12) 4 2636 28 . 8769 28.68 7375
;;; 13 . 32 ■ : i. C27) 200634 59.0322 59.03 8256
.=■; : • '1 0241 801652 73.0753 73.08 9029
: 1 0 54 1 719299 71 . 3188 71.32 9205
26 4 14 . 0 1 4 4 :2 : 064 1 326801 69 . 3520 69.35 7124
■■ •= - ■ 04 5 i 1 .067) 639064 5 0.7683 50.77 7 64 2
■: - : 5 ■ - - : (i 272; 202152 78.2362 78 . 24 9 9 97
0 - : - • • rv 91. 6 : 170943 77 .2223 7 7.22 92 3 6
■. : ;■ = 408875 68 . 654 3 6 8.65 ; ? i ■;
24 - : 0 2 54: 206945 7 1 . 34 57 7 1.35 3 4 0 4
2 - 4 •' '•. -72 , 2 1 6839 -0 . 3051 6 0 8 ! G •" ' “i2-. ■ :: 2-: : . - 124525 r12 . 4 6 0 _• 52 4 6 9114
:" - : : - i . : 2 • ; C 7 1 04 0 52.6393 52 . 64
: - :::;555 53.7038 5 3.70
■ - : '3 21.' 1079451 79.3092 79 3 1 9577
Data File: /chem/5972hp64.i/DF020311B64.b/WG16194-2JB64_985.dReport Date: 13-Mar-2030 12:57
Compounds
7 3 Di-n-butylphchalate
74 Fluoranthene
76 Pyrene'
77 Bucylbenzylphchalate
78 3.3'-Diehlorobenzidine
79 bis:2-ethylhexyl)Phthalate
60 Bento 1 a)anthracene
5 2 D: - n - octy iphr.na late
83 Bento <r)fluoranthene
34 Bentoik)fluoranthene
S5 Bento(a)pyrene
So Indeno(1.2,3 *cd>pyrene
87 Dibento(a,h)anthracene
Q8 Bento(g,h,i)perylene
CONCENTRATICNS
QUANT SIG ON-COLUMN FINAL
MASS RT EXP RT REL RT RESPONSE ( NG) ( ug/L) SIMILARITY
14? 16 . 229 16 . 227 (1.048) 1418017 69.6355 69.69 9725
202 17.27.7 17.275 (1.116) 1241594 52.9328 52.93
2 02 17.659 17.698 (0.887) 1291697 51.5619 51.56
14 9 18 . 832 18.814 (0.943) 700167 69 . 6468 69 . 65 9 3 5 6
2 92 19.846 19.845 (0.994) 322116 45 .4938 45.49 8038
149 19.796 19.794 (0.992) 1128234 75.2516 75.25 944 8
2 2 9 19.931 19.930 (0.998) 1228664 53.4670 53 .49
225 2 C .016 20.014 (1 003' 1179935 54 .4850 54.49
149 20 . 776 20.775 *0.925) 1183819 68.2482 68.25
2 62 21.706 21 . 705 (0 . 967) 714 16 6 4 3 .4509 43 .45
252 21 . 757 21 . 756 (0.969) 959823 64 .6214 64 . 62
252 22.349 22.347 (0.995) 682969 52.4460 52 .45
276 25.054 25.052 (1.116) 599532 63.7143 63.71 7260
27b 25.037 25.035 (1.115) 602501 52.7726 52.77 8008
276 25.865 25.864 (1 . 152) 627523 52.4138 52.41 9351
QC Flag!Legend
M - Compound response manually integrated.
1
I i
i
764
Data File: /chem/5972hp64.1/DF020311B64.b/WGl6194-2JB64_985.aInjection Date: 12-MAR-2002 04:27Instrument: 5972hp64.iClient Sample ID: SIBLCS
ound: 2
Number:
41 6-Tnbromophenol
118-79-6
Ion 329.60: Area: 313166 Height: 204378
2.0-
1.8-
1 .6-
1.4-
1.2-
1.0-
0.8'
0.6-
0.4-
0.2'
0.0-14.00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.85 14.90 14.95
________________________ ____ MinIon 332.00: Area: 0 Height: 0
1.9.
1.8-
1 .
1.6-
1.5-
1 . 4- I 1 . 3-
i.2- 1.1-
1.0-
0.9 ■
0.6-
0.7-
u. 6-
0.5-
0.4-
0.1-
0.2-.
0.1-
u n-14.00 14.05 14.10 14.15 14.20 14.25 14.30 14.35 14.40 14.45 14.50 14.55 14.60 14.65 14.70 14.75 14.80 14.85 14.90 14.95]
i________________ ,Min_________________________________________________ ________ _________________________ I
Ion 141.00: Area: Height: 0
76:J ;
14.00 |1 J .05 IJ . 10 1 J . !5 1 J . 20 1J .25 1 J . 30 14.35 14.40 1 J . 45 1 4.5.0 14.55 14.60 14.65 14.70 14,75 14.80 14.85 14.90 14.95 :j __ Min I
Data File: /chem/5972hp64.1/DF020311B64.b/UG16l94-2JB64_985.d Injection Date: 12-MAR-2002 04:27 Instrument: 5972hp64.1 Client Sample 11D: SIBLCS
#ound: 1.3-D 1chlorobenzene Number: 541-73-1
6.8-
6.4-
6.0-
5.6- ;
5.2-
4.8-
4'. 4-
4.0-
3.6-
■7
2.8-
2.4-
2.0-
1.6-
1.2-
Ion 146.00: Area: 99454 Height: 71968a
1 I
u. d-
0.4-,
/
i1i \
7.75 7.80 7.85 7.90 7.95 8.00 8.05 8.'l0
i8.15 8.20
Min8.25 8.30 8.35 8.40 8.45 8.50 8.55 B .60 8.65 8.70
Ion 140.00: Area: 0 Height: 0
4.5- ! i4.2- i li3.9- il n
| I , i
.80 7.65 '. 90 .95 8. no 8.05 B. 10 8.15 8.20 8. ____________ ____ M l n
8.30 8.35 8.40 8.45 8.50 8.55 8.60 8.65 8.701
Ion 111.00: Area: 0 Heignt: 0
l
1.4 ;
I
2.0
1 C;.
1 . 0-
".60 7.85 7.90 ".95 8.00 8.05 0.10 8.15 8.20 6.25 8.30 8.35 8.40 8.45 8.50 8.55 8.60 8.65 8.70
Mm
II
Data File: /chem/5972hp64.1/DF020311B64.b/LIG16194-2JB64_985.d Injection Date: 12-MAR-2002 04:27 Instrument: 5972hp64.i Client Sample! ID: SIBLC5
Mm*ound: 1
Numoer:. 4-Dichlorobenzene 1 Ob-46-7
6.8
6.4-
6.0
5.6-
5.2-
4.8-
4.4
4.0-
Ion 146.00: Area: 104046 Height: 64736
i hiI CD
I ;
. b-
2.4-'2.0-' ’
1.6-
1.2-
0.8,0.4- |
i •i •i i
/ ' 1
j \ •'
1
i /
L , i
7.80 17.85 7.90 7.95 8.00 8.05 0.10 8.'l5 8.20 8.25
Min8.30 8.35 8.40 8.45 8.50 8.55 8.60 B.65 8.70 8.75
Ion 148.00: Area: 0 Height: 0
4.5- iOD 1
n hi 14.2- 1
CD3.9- ‘ i 1 |
3.6- j;
1 ; |
i i
1 !! i
' 11 :
6-
3
(i- —\60 |7.85 7. or, 795 8.00 8.05 8.10 8.15 6.20 8.25 6.30 8.35 8.40 0.45 8.50 8.55 8.60 8.65 8.70 8.75
.__ MinIon 111.00: Area:
l
0 Height: 0
j Ii iI !j i ' i ' Ij 1
I !
767 !
8.1L 8.25 S. 30 8.35 6.40 8.45 0.50 8.55 8.60 8.65 8.70 6.75 Min
I
Data File: /chem/5972hp64.i/DF0203llB64.b/LJG16l94-2JB64_985.d Injection Date: 12-MAR-2002 04:27 Instrument: 5972hp64.1 Client Sample ID: 5IBLCS
ound: 1. Number:
2--Dichlorobenzene95-50-1
6. fi
fe. 4-
6.0- 5.6-'.
5.2-;
4.8-
4.4-
4.0-
3. fe
lon 146.00: Area: 103477 Height: 70171
0
1
~‘ T O.!
2.8-
2.4-
. 2.0- i i
i 1.6- f i] !
1
1.2- / I\ I
j
0.6- i \ 1 1
0.4-/
i \
3.10 a. 15 3.20 8.25 8.30 8.35 8.40 8.45 8.50 8.55 8 60 8.65 8.70 8.75 8.80 8.85 8.90 8.95 9.00 9.05Min
Ion 148.00: Area: 0 Height: 0
4.5- 1 CDa
4.2- CD
3.9-!!
8.10' 8.15 8.20 >.25 8.30 8.35 8.40 8.45 8.50 8.55 8.60 6.65 8.70 8.75 8.80 8.85 8.90 B.95M l n
I9.00 9.05 i
Ion 111.00: Area: 0 Height: 0
2.e-
o. 10
76 o
o.i.' o. .40 8.45 8.50 6.55 8.60 8.65 8.70 8.75 8.80 B.85 8.90 8.95 9.00 9.05M l ri
I
Data File: /chem/5972hp64. 1/DF020311B64.b/UJG16194-2JB64_985.d Injection Date: 12-MAR-2002 04:27 Instrument: 5972hp64.i Client Sample ID: 5IBLC5
ouna: 2,2j'-oxybis( 1-Chloropropane)
Mumper: 108-60-1
8.5-
8.0
7.5-
7.0- :
6.5-
6.0- ;
5.5- :
5.0- :
4.5- '
4.0-
3.5-
2.5-
Ion 45.00: Area: 184988 Height: 88448
f.\
CD
1.5-
1 .0-
0.5- 0.0-
8.20 8.25 3.30 3.35 8.40 B. 45 8.50 B.55 8.60 8.65 8.70 B.75 8.80 8.85 8.90 8.95 9.00 9.05 9.10 9.15Min _______ _________ __
1 . 7-
1.6-
1.5-
1.4-
1.3-'
i;:;:1 . Ci-
0. 9- 0.6-
O 7-
Ion 121.00: Area: 0 Height: 0
P k
I !
8.40 0.45 8.50 8.55 8.60 8.65 8.70 8.75 8.80 8.85 8.90 8.95K i n
9.00 9.05 9.10 9.15
Ion 77.00: Area: 0 Height: 0
i I
/ \:/ \:
' »£»“
■ CD
7 6 $
8.55 3.60 8.65 8.7vM i n
3.75 8.80 8.85 8.90 8.95 9.00 9.05 9.10 9,15
Data File: /chem/5972hp64.1 /DF020311B64 . b/UG16194-2JB64_985. dInjection Date: 12-MAR-2002 04:27Instrument: 5972hp64.1Client Sample ID: 5IBLCS
#ouna: 1.2M-TrichlorobenzeneNumber: 120-82-1
6.4- 6.0-
5.6'
5.2-
4.8-
4.4-
4.0-
3.6-'
3.2-2.0-
Ion 180.00: Area: 114208 Height: 65113
2.0-
1.6-
1.2-
0.8-
0.4-;
0.0-
9.60 9.65 9.70 9.75 9.80 9.85 9.90 9.95 10.00 10.05 10.10 10.15 10.20 10.25 10.30 10.35 10.40 10.45 10.50 10.55Min ___ ____
b. u-
5.6-
Ion 182.00: Area: 0 Height: 0
9.75 9.8C .85 9.90 9.95 10.00 10.05 10.10 10.15 10/20 10.25 10.30 10.35 10.40 10.45 10.50 10.55 M i n
Ion 145.00: Area: 0 Height: 0
77U
o—9.60 9.65 9.70 35 9.90 9.95 10.00 10.05 10.10 10.15 10.20 10.25 10.30 10.35 10.40 10.45 10.50 10.55 ;
Mm I
Data File: /chem/5972hp64.i/DF020311B64.b/ldG16194-2JB64_985.d Injection Date: 12-MAR-2002 04:2?Instrument: 5972hp64.1 Client Sample!ID: SIBLCS
ound: 2.4-DiniTropheno1
Number: 51-28-5
4.2-
3.9-^
3.6-
3.3-
3.0- ;
2 7"
2-4-
2.1-
1.8-
1.5-
1.2-
0.9-
0.6-
0.3-
0.0-
Ion 184.00: Area: 62090 Height: 41803
12.80 12.85 12.90 12.95 13.00 13.05 13.10 13.15 13.20 13.25 13.30 13.35 13.40 13.45 13.50 13.55 13.60 13.65 13.70 13.75Min _____ _________________ ____
2. 5Ion 154.00: Area: 0 Height: 0
.d'J i _ . o‘jj * •' .90 1 1.05 13.00 13.05 13.10 13.15 13.20 13.25 13.30 13.35 13.40 13.45 13.50 13.55 13,60 13.65 13.70 13.751
ion Gj.ijij: wrea: Height: 0
77 J_l
=, 1 3 70 ' 7 7=, 13.40 13.45 13.50 13.55 13.60 13.65 13.70 13.75
CompuChema Division ot" Liberty Analytical Corp.
GC/MS SEMI-VOA WORKSHEET
LAB INSTRUCTIONS:
RECEIPT DATE:
CASE#: ' SDG:
SAMPLE DATE: DUE DATE:
COMPUCHEM#: /6' / f
CLIENT ID: J j fi [ C (,'ANALYSIS DESCRIPTION:
Injection jVolume :pL Dilution Prep (if needed)
Extraction Date___3 / /i /__0_Z___
DFTPP Filename t c \ / / /l C y-
Sample File Name (// /fV ■ / r
ANALYST (S): Injection2 1 / V_______________ Work-up/ 7
GC/MS DATE REVIEWI
CONDITION CODE
Extraneous Peak Search Results:
Number of peaks found: l\M
Number of Hits found:____Q
Number of Surrogate Outliers: (J)
(duality Assurance Notice (s) Number of Notices Required (jj
Comments:
Disposition: [ uj'Complete
[ 1 Reinjection Required
[ j Re-extraction Required
1 ] Reinject Neat
[ ' ] Dilute ( X)
Final Reportable Package! si
_ DmcJ. jJ f£. Auditor
_uj.(ri L \ciH- 2Flx-'~(
Date
77c
SV1 - 6/27/01: PTF
/
Analyst initials Extracted
53(/c&_KD
Initials" bate
l>I ionic up
Manufacturer and lot number of reagents/solvenls used
COM ' # '
\\ i I ness
mi 1l rsi
FORM 1SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO.
'ii
Lab Name: COMPUCHEM Contract: 8270CSIILCS
Lab Code: LIBRTY Case No.: SAS No. : SDG No.: QE1877
Matrix: (soil/water)l
WATER Lab Sample ID: WG16228-2
Sample wt/vol : 1000 (g/mL) ML Lab File ID: WG16228-2A60
Level : (low/med) LOW Date Received:
% Mois ture : decanted: (Y/N) Date Extracted : 03/10/02
Concentrated Extract]
Volume: 1000(uL) Date Analyzed: 03/12/02
1Injection Volume: 1.0(uL) Dilution Factor: 1.0
GPC Cleanup: (Y/N) N pH:
CAS NO. COMPOUNDCONCENTRATION UNITS: (ug/L or ug/Kg) UG/L Q
. 108-95-2-------- Phenol 251 111-44-4---------Bis(2-chloroethyl)ether 69I 95-57-8----------2 - Chlorophenol 60541- 73 - 1 -------- 1,3 -Dichlorobenzene 58106-46-7---------1,4 -Di chlorobenzene 5995-50-1----------1, 2-Dichlorobenzene 5895-48-7----------2-Methylphenol 69
: 108-60-1-------- 2,2'-oxybis (1 -Chloropropane) 67106-44-5---------4-Methylphenol 100621 -64 -7-------- N-Nitroso-di -N-propylamine 69
| 67-72 - 1 ----------Hexachloroethane 6098 - 95- 3 ----------Nitrobenzene 6878-59-1----------I sophorone 68
; S3-75-5----------2-Nitrophenol 73J 105 - 67- 9---------2 , 4 - Dimethylphenol 25111-91-1-------- Bis(2 - chloroethoxy) methane 74
i 120-S3-2-------- 2,4 - Di chlorophenol 77; 120-82-1-------- 1,2,4 -Tri chlorobenzene 71
i 91-20-3----------Naphthalene 7610 6- 47- 3 -------- 4 - Chloroani 1 me 74
1 8 7- 68 - 3 ----------Hexachlorobutadiene 755 9 - 50- 7 ----------4 - Chloro - 3 - methylphenol 689 1-57 -6----------2 -Methylnaphthaiene 86-
1 77-47-4----------Hexachlorocyclopentadiene 66■ 3 3 - 06 - 2 ---------- 2,4,6 - Trich 1 orophenol 851 95 - 95-4----------2,4,5 - Tr i chlorophenol 1101 91-53-7----------2 - Chloronaphthalene 74
78131-11-3-------- Dime t hv ipht ha la te 88
[ 5 05 -2 0 - 2---------2,6 -Dimtrotoiuene 81] 2 03- 96 -8-------- Acenapht nylene 82■ 9 9- 0 9- 2----------3 -Nit roan 111 ne 75! 83 - 32 - 9 ----------Acenaphthene 8 7
FORM I SV 8270C
774
FORM 1SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO.
Lab Name: COMPUCHEM Contract:
Lab Code: LIBRTY Case No.: SAS No.:
Matrix: (soil/water) WATER1
Sample; wt/vol: 1000 (g/mL) ML
Level :; (low/med) LOW
% Moisture: _______
Concentrated Extract
Injection Volume:
GPC Cleanup: (Y/N)
decanted: (Y/N)
Volume: 1000(uL)
1.0(uL)
N pH : ___
8270C
SDG
Lab Sample ID:
Lab File ID:
Date Received:
Date
Date
Dilution
SIILCS
No.: QE1877
WG16228-2
WG16228-2A60
Extracted:03/10/02
Analyzed: 03/12/02
Factor: 1.0
CAS NO.CONCENTRATION UNITS:
COMPOUND (ug/L or ug/Kg) UG/L Q
51-2 8- 5----------2,4 -Dinitrophenol 34 J10 0- 02-7---------4 -Nitrophenol 38121-14-2-------- 2,4-Dinit ro toluene 78
1 132 - 64 -9---------Dibenzofuran 9184 -66 -2 ----------Diethylphthalate 86
j 7005-72-3 ------- 4-Chloropheny1-phenylether 96| 86 -73 -7--------- Fluorene 941 100-01-6-------- 4 - Nitroaniline 80: 5 34 - 52-1---------4,6 - Dim t ro - 2 - methylphenol 64.86 -30- 6 ----------N- Ni trosodi phenyl amine (1) 81(101-55-3---------4 - Bromophenyl - phenyl etHer 88: 118-74 -1-------- Hexachlorobenzene 81.87-86-5----------Pentachlorophenol 83
■ 35-01-8----------Phenanthrene 87112 0-12-7---------Anthracene 91
i '36 - 74 -8 ----------Carbazole 100i 34 - 74 - 2 ----------Di -n-butylphthalate 83I 20 6 - 44-0-------- Fluoranthene 92‘12 9- 00 - 0 -------- Pyrene 788 5- 6 8 - 7----------Butyl benzylphtnalate 69
j 51-94-1----------3,3' -Dichlorobenzidine 33: 11 7 - 8 1-7-------- bis(2-ethylhexyl)Phthalate 81 B
94:2IS-'j1-5-------- Chrysene 91'117-34 - 0---------Di - n - octy lp'nt ha late 78i z c d - - 2-------- Benzo ( b ) 11 uoranc hene 79
| j2 u / d e - Benzo ( k) f luoranthene 110i do - j2 - 8----------Benzo (a) pyrene 89
1 153 -39-5------ - - Indeno(1,2,3-cd)pyrene 8297
! l 51 -1- - 2-------- Benzo • g, h, i) perylenei )
96
- Cannot De separacec from DiphenylamineFORM I SV 8270C
7 7 o
Data Fi le: /chem/5972hp60* i/DF0203'12A604b/UG16228-2A60td
Date J 12-MAR-2002 15:08
Client ID: SIILC3
Sample Info:
Volume Injected <uL>: 1*0
Column phase: J&W DE-5*825
Instrufient: 5‘:-172hpb0« i
Operator: 017
Column diameter: 0,32
. _U
■=Ebeaanthrene-ctLQ
Data File: /chem/5972hp80* i/BF020312At-0.b/MGl&228-2fibO,d
Date : 12-HAR-2002 15:08
Client ID: SIILCS
Sample Info:
Volume Injected <uL>: 1,0
Column phase; J8.W DB-5.S25
Instrument: 5972hpb0. l
Operator: 917
Column diameter: 0,32
4.0-
3,9-i
3.8- ;
3.7- i
3.6-i
3.6- i
3.4- i
3.3- .
3.Z-
3.It
3.0- i
2.9- :
2.8- i
2.7-
2.6r
2.5-
2.4- i
2.3- i
2.2-i
2.1- i
2.0 -j
1.9- i
1.8- i 1.7-i
1.6- i
1.5
1.4-
1.3
1.21.1- i
l.o-;
0.9-
0.8
0.7-1
O.b-i
0.6
0.4-
0.3
0.2
0.1
2chem/5972hp60.i/DF020312A&0,b/WGlb22 2Ab0.d (Part 2 of 2)
19 2418 21
77
Data File: /chem/5972hp60.i/DF020312A60.b/WG16228-2A60.dReport Date: 13-Mar-2030 09:57
CompuChem
Data file Lab Smp id Inj Date( Operator Smp Info Misc Info Comment [ Method Meth Date Cal Date
Semivolatile Report SW-846 Method 8270C /chem/5 9 72hp6 0.i/DF020312A60.b/WG16228-2A60.d WG16 2 2 8-212-MAR- 2 0 0 2 15:08 917
Client Smp ID: SIILCS
Inst ID: 5 972hp6 0.i
/chem/5972hp60.i/DF020312A60 13-Mar-2030 09:03 byrd 0 3-MAR- 2 0 0 2 17:20
b/8270Cv6.mQuant'Type: ISTDCal File: HL020303A60
Als bottle: 9 QC Sample: LCSDil Factor: 1. 00000Integrator: HP RTE Compound Sublist: OLM03Target Version : 3.50Processing Host: einstein
iConcentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Namei
Value Descript ion
DF i1.00000 Dilution Factor
vt ; 1000 . 00000 Volume of final extract (uL)^ Vo 1 1000.00000 Volume of sample extracted (mL)
1 . 00000 Volume injected (uL)
Cpnd Variable Local Compound Variable
CONCENTRATIONSyUANT SIG ON-COLUMN FINAL
7,„o„:s | MASS rt rt eel rt RESPONSE ( NG) ( uq/L)
* I 1 , 4 - 2:ch:d rc recce. 152 E 14 2 3.123 : : . 20:1 ; 90344 4 0 . 0000• 2 Napht ha iene - a? I 36 I : . 2 5 : 12.233 : 1 .0 2 Li 237905 40.0000
- ci I 0 164 ■2.372 1•.551 ; I .00 0: 193219 4 0 . 0000- d: j i a 9 :;.ooo: 398121 40.0000
t Ch:-ys~::e-dI2 U *» t' 20.RR7 p::..;cr LLr.- 4 97122 4 0.0000yiK;;:: ^ 2 3.1 3 2 :. 3 . 1 •' . 1 :• C 0 ' 420215 40.0000
I "I 2 • F 1 co:'Opr;-5:-. r.: 1 : : 6.:2” ■- '740 225227 79.7326 79.73: r Ph-i-o:-..:? o t -■ • - 174227 53.7046 53.70: • —e::- • d 7 52 v . •• .-...E: 249971 73.4870 73.45t i - j - F : c o v z'~ : z :i ••'V. : 7 2 12.122 1 .. 1 • • r 1 534468 77.5023 77.90
:: v ■ T: Jc:-c to;;;-:-: .cc c 1 . 1 ■ i 350060 214.563 2 i 4 . 5244 17 “ -: ' : 211 1 2 3 02 3 ? 74.5654 74 ^7
:} •; 7906:.’ 24 9569 25.00V y-.r : ■ p::?: V ... .... _..;r 6 5 . 7 ] 5 7 t S . 7 2
sub
SIMILARITY
&
77 o
Data File: /chem/5972hp60.i/DF020312A60.b/WG16228-2A60.dReport Date: 13-Mar-2030 09:57
CONCENTRATIONS
QUANT SIG ON-COLUMN FINAL
Compounds MASS RT EXP RT REL RT RESPONSE ( NG) ( ug/L) SIMILARITY
IS 2-Chlorophenoi 128 7.804 7.785 (0.958) 147787 60 . 1582 60 . 16 COCD O O'.
15 1,3-Oichlorobenzene 146 8.040 8 . 021 (0 . 988) 194018 57.5946 57.59
20 1,4-Dichlorobenzene 146 8 . 176 8 . 157 (1.004) 196435 58 . 5220 58.52
22 1,2-Dichlorobenzene 146 8.413 8.411 (1.033) 188020 58 . 1930 58.19
23 2-Methy1phenol 108 8.599 8.580 (1.056) 138153 69.2883 69.29
24 2,2' -o>:y cis(l-Chloropropane) 45 8.599 8 . 597 (1.056) 204291 66.5935 66 . 59 7053
27 4-Methylpnenol 108 8 . 852 8 . 834 (1.037) 262349 103 534 10 3.5
23 N-Niz roso-di-M-propylamine 70 8.836 8.817 (1.085) 126029 68 . 52 94 6 8.53 74 14
25 Hexach•oroechane 117 8 . 988 8.969 (1 . 104) 86298 60.2535 60.25 8 94
3 0 Nitre-her. :ene 77 5.105 5.087 (0.885) 199468 67.5972 6 7.6 0 S S 8 5
3 1 I sophorc 82 5.512 9.493 (0.924 ) 318148 68 .4692 63 .47 £ 7 8 4
3 2 2 -N:7roo ie.".o! 1 c 5.54? 9.625 (0.5381 106634 73.1634 73.13 . 8 7 3 0
3; h.y ipneno : 12 2 9 . 74 9 9 . 7 3 C (0 947! 44 023 24.9006 2 4.90 3 3 09
3 4 Bis i2-ch c.roetnoxy)met hane 9 . 834 9.882 (0.961) 207851 74 .2972 74.30 7752
2— h . crophenc: 162 10.071 10.069 (0.979) 199931 76 . 7975 76 . 60
"-.2,1-7: ■:r. iorober.zene 180 10.206 10.187 (0.992) 220405 71.3104 71.31
37 Nap:-.: ha i 126 10.341 10 . 322 (1.005) 537680 76.0436 76.04 8 8 99
3 3 4 - Chic rear.: i ir.e 127 10.443 10 . 424 (1.015) 221956 74.4704 74.47 8884
?. 3 r. e x a c h 1 c ■obut ad i ene 225 10.561 10 . 542 (1.026) 180594 74.7022 74 . 70 9198
41 4 -Chic ro 107 11.306 11 . 287 (1.099) 148042 68 .4042 68.40 8758
4 2 2•Methyinapht halene 142 11.542 11.523 (1.122) 452577 85.8738 85.87
i • 'oeve iooer.tad iene 237 11.813 11.754 ( 0.884 ) 145960 65.7197 65 . 72 9109
45 2.4.4-Tr 155 12.050 12.031 i0 . 901! 180268 34 .7427 84 . 74
^ : - ch lo ropher.c l 195 12.118 12.116 (0.906 1 249235 107.622 107.6
iaph.: ha len- 162 12.388 12.366 !0.927) 440676 73 . 5424 7 3 . 54
4 5 2 - N : : r car.: line 65 12.574 12.572 (0.941) 182020 78 . 004 3 7 8.00 8 64 3
5 " r>: me c h y l p n : n a a: e 15 j 12.356 12 . 394 (0.965) 693106 80 . 0670 88.07 9502
5 l 2 , -j - D . n : * 155 13.014 12 . 9 9 5 '.0.573) 1 3 5 6 4 5 80.8508 3 0.65 956 6
1 52 13.116 13.114 .0.981) 791019 82.0776 82.08 6 5 54
r? ‘ : ■ 1 1C 1 3 . 3 C 2 13.3 0 0 ■■0.955) 134055 75.2973 7 5.30 3 97 9
5 4 154 13.420 12 .41? '1.004' 494668 67.2749 87.27 8 5 O' 3 '■ R :
2r J rep;-.e:-.c 1 • a ^ 13.433 13.486 ; 1 . 0 0 9 ; 35984 34 .2951 3 4 . 0 iaM)
• ; : : : 1 0 9 13.64C : 3. 2: '1 .020) 54 114 37.7946 37 . "79 0 ' M 1
145 :: 70; ■3.706 :: 025: 194008 73.0717 7 3.07 h 6 5 3
i- : :: 12.715. 1 2 . ~22 1 02 7 555464 51 . 0615 9 1.08 8 1 b 6
■5 I ■ ■ ■-■if '.4.14 = : 4 . : 2 1- ■1.056' 7 3. C: 0 3 6 0 5 . 8 6 S 3 35.8-? 9 4 4 2
304 : i . 3 2 -i 14. : 1 ?. : . ' 7? 446344 0 6 . 2 12 2 :•? .:: ' 7 34 4
" L ■ : 1 14. 1 :. 784371 54 .425 2 54.4 j r 52
: 3 r ■; . .■• r . ■; ■ - :■ : 4 3 0 5 3 7 c- . 7 1 2 1 75.7 1 r 4 4 ?
: :■1 : -. ? ■ : 0 5 5 14 6 4 .289 a 64.2 r :■■.■■:
. : K5-; '■4 .32: '. 0::. •t 2 7 6 1 0 -0 .5?:-:: 3 : 4 :
- : : ■ 24 r : r : - :• = - 2637Q4 = 3 . 2067 fc "> 1
• 7 _ *> • 1 ?. 3.: 1 1 r 2 3 6 0.553- 273363 30 6545 = 0.,E 5 0 n 4
: nenc 2 4-3 1 5 6 7 •• ■- b . ; : ■ 0 5 6 0; 5 2 6 3 7 3 3 MIS 8 2.14 C L. 1 1
17 5 it 1 •> . ':2.; ::.002) 1037-49 S 7 . 12 0 1 3 7.12
! A:-hva:--: 1 7 z 1 12 7 :’.'S .1.00 8 ■ 1146573 51.2167 91 .29
; 6 7 1 4 4 1 : : 2 : 1 . 025 . : 0 1 3 6 S 5 102 94 3 10 2.5 5 1 0 3
779
I
Data File: /chem/5972hp60.i/DF020312A60.b/WG16228-2A60.dReport Date: 13-Mar-2030 09:57
CONCENTRATIONS
QUANT SIG ON-COLUMN FINAL
Compounds MASS RT EXP RT REL RT RESPONSE ( NG) ( ug/L) SIMILARITY
73 Di-n-butylphthalate 15 9 17 . 007 16.908 (1 .063) 1353807 83 . 0175 83.02 9396
7 4 Fluoranthene 202 18 . 123 16.121 (1.133) 1326000 91.9162 91 . 92
76 Pyrene ! 202 16 . 529 18.510 (0.898) 1397417 78.3568 78 .36
77 Butylbensylpht ha lace 15? 19 . 629 15.610 (0.952) 635814 69.0382 59.04 9072
79 3,3' -Dicrilcrobenzidme 252 20.553 20.551 (0.996) 234433 33.3354 33.34 7507
75 bis•2 - ethylhexyl)Phchalace 155 20.576 20.575 (0.998) 1041515 00.9726 80.97 8975
SC Bento i a:anthracene 228 20.610 20.591 (0.999) 1665509 93.6043 9 3.60
81 Chrvsene 223 2 0.6 61 20.652 (1.002) 1461953 91 . 1665 91 . 17
9 2 Di-n-octvlphthalate 159 21.575 21 . 556 (0.931) 1651215 78 . 0306 78 . 03
83 Benzo(b)fluoranthene 252 22.387 22.368 (0.966) 1427352 78.7644 78.76
65 Benzo(k)fluoranthene 252 22.537 22.516 (0.968) 1741525 106.289 106 . 3
85 Bento(a)pyrene 252 23.063 23 . 055 (0.995) 1292027 89.0867 89.09
86 Indeno(1,2,3 -cd)pyrene 276 26.092 26.056 (1.126) 1272205 82.2055 82.21 8526
87 Dibenzo\a,hi anthracene 2 7 S 26.152 26.107 (1.128) 1302869 96.7202 96.72 8670
86 Benzoig,h,i)perylene 276 26 . 988 26.952 (1.164) 1254235 96 . 1730 96 . 17 7381
QC Flag Legend
Targejt compound detected but, quantitated BeloW| Limit Of Quantitation (BLOQ) .Targejt compound detected but, quantitated exceeded maximum amount.Spike1/Surrogate failed recovery limits. Compound response manually integrated.
amount
amount
780
Data File: /chem/5972hp60.i/DF020312A60.b/UG16228-2A60.dInjection Date: 12-MAR-2002 15:08Instrument: 5972hp60.iClient Sample 'ID: SIILCS
ound: 2 Number:
4.6-Tribromophenol 118-79-6
Ion 329.60: Area: 390060 Height: 227369
: 2,2- itft |
2.0-; 1Tt
1.8-
1.6-
1.4- |
LH 1.2-
0.6- ! ; i
0.4 |[
0.2- ;i 1
1-1.25 14.'30 14.35 14.4Ci14.45 14.50 14.55 14.60 14.65 14!.70 14 ^75 14.80 14185 14^90 14^95 15^00 15^05 15.10 is'l5 15.20Hi n i
Ion 332.00: Area: 0 Height: 0
1.8-
1.6-
L
4.4m 14.45 1J.50 14.55 14.60 14.65 14.70 14.75 14.80 14.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20
_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Mir-I_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
Ion 141.00: wrea: 0 neight: 0
1 4.55 14..-.- : 4 .5 ; j . -o 14.-5 14.80 14.55 i 4 . Qm 14.95 l 5.00 15.05 15.1'.' 15.15 15.20
Data File: /chem/5972hp6C'. i/DF020312A60.b/UG16228-2A60.dInjection Data: 12-MAR-2002 15:03Instrument: 5972hp60.iClient Sample 'ID: bllLCS
ouno: 2
Mumper:J-Dmitr opnenol
1.6
1.5
1.4
1.3-
1.2
1 . 1-
1.0
Ion 184.00: Area: 35984 Height: 16150
0.4-
0.3
0.2-
0.1
13.05 13.10 13.15 13.20 13.25 13.30 13.35 13.40 13.45 13.50 13.55 13.60 13.65 13.70 13.75 13.80 13.85 13.90 13.95 _______________ _____ M l n
Ion 154.00: Area: 0 Height:
1.4.li l
1.0-
I 3.00 1 3.03 : 3.:0 13.13 13.20 13.25 13.30 13.3d 13.40 13.45 13.50' 13.55 13.60 13.65 13.70 13.75 13.80 13.85 13.90 1 3.95'___________ _____________________________________ M i n
Ion oS.OO: Area: 0 Heijtru: 0
178
40 13.45 13.50 13.55 13.60 13.65 13.70 13.75 13.80 13.85 M i n
13.90 13.95
Data File: /ch'em/5972hpb0.i/DF020312A60.b/UGl6228-2A60.dInjection Date: 12-MAR-2002 15:08Instrument: 5972hp60.iClient Sample ID: SIILCS
4-Nitrophenol100-02-7
1 .c
1
Ion 109.00: Area: 54114 Height: 24472
Q<
rn-
!
J •
13. 15‘ 1 3.20 13.25 1
1
13.35 13.40 13.45 13.50 13.55 13.60 13.65 13.70 13.75 13.80 13.65 13.90 13.95 14.00 14.05 14.10Min
Ion 65.00: Area: 0 Height: 0
C'J‘JD
ro
1:5 13.40 13.45 13.50 13.55 13.60 13.65 13.70 13.75 13.80 1
H i n_____________________________ion 139.00: Hr-ea: 0 Height: 0
85 13.90 13.95 14.00 14.05 14.10
78 J
:• 13.60 1 3.65 1 3.70 13.75 1 3.60 13.65 1 3.90 13.95 14.00 U . 05 14. in Hi n _ ___ _____ _______________
CompuCherra Divisionof Liberty Analytical Corp.
GC/MS SEMI-VO A WORKSHEET
LAB INSTRUCTIONS:
RECEIPT DATE: 3/8/02 0:00 SAMPLE DATE: DUE DATE:
CASE#: ' SDG: WGI6228 COMPUCHEM #: WG16228-2
CLIENT ID: S1ILCS
ANALYSIS DESCRIPTION: SVOA-8270C
Injection Volume :1.0pL Dilution Prep (if needed)
Extractionj Date___3___/10____/__02
DFTPP Filename DF0203 I2A60! ~ ------------------------------------t
Sample File Name___WG16228-2 A60
ANALYST(S): Injection917 Work-up4/ ?
GC/MS DATE REVIEW
CONDITION CODE
Extraneous Peak Search Results:
Number off peaks found:
Number of Flits found:
r/A
Number of Surrogate Outliers: ______
.1
Quality Assurance Notice (s)Number of Notices Required_____^
Comments:
Disposition: [ / Complete/c
Reinjection Required
Re-extraction Required
Reinject Neat
Dilute( X)
#GC/MS Review/•nyi-- Date p / 4
Final Reportable Package! s):
Auditor
Q-J u if- ^ &6<~>
Date / /
784
SVl - 6/27/01: PTF
assigned TO: A O/C
SA'bo
( ompuChem
EXTRACTION WORKSHEET
SKMI-V01.AHLF. WATER, Method 3S10C. for 8270C DA I K EXTRA' I KD/POS I I I):
o oi ...........
* r;A , SAMPLE FINAL Adjusted pH ' : CO
SAMPLE
NUMBER \ -
lijc SAMPLE':.;,
i-'type ■'* VOLUME
(ml)
VOLUME
(ml)
■ A/N BASE COMMENTS 1^-
Qe/fr?7- s- /coo \-0 /£ 12^ / 9/ore ______ l.o y, i> \l\
/<> ZOO* _____ Lc /.u 1^ i___________/___
/CO a l.e U. 12-1/ A
/0<0 0 Id lU 12-1 Qc£-i? '/i*' •$
>3 /coo .0----f—u-----------
/ (q iM
//c<o ■0---- / v----------
J.L 12.i
/r JCfc 1-0 / L »2.1/______u
/coo \ 'O 1.h 12. i
n /COG to / (p 12 (
/r z COO 1-0 / L til7 W
/ooc • 1.0 l L 12. <
lA/(si(rJ7,ZXC-~S /etc l.o —r*~/ (p 12-1
Z S 5> /OOO Vo /.b 12 i
Qt-r 1777-1 ICO® l.o Al 1)1JCCfd lo JA d.i r - > *~n*FA* E /
) H____ ——"
)T -------------
___——
2 -------- :--------------
3 lo/irlkBLK
jm t‘0 4 L 12.1*_________ 3
LCS /Coe 1.0 A & (L t ''Add 1.0 ml. validation spike In I ( S and SSs unless otherwise noted _
S-VOL Add ; B/N 8270FINAL VOLUME VLRIUKI): <—.............. ........NO. 393
- Is/ ^
SURROGATE AMT. 1.0 ml A/“——-
LOT d/n V/7^-------------
SLPFRMSOK REVIEWL I): ^ ......... ....... ITr-r.-.. ...NO. 3012/ 2021 VALID.
SPIKF. AMT. L^ml 1.0ml 1.0 ml s?ry - - ^ it aI —LOT Ito/thT SLRROGATE & SPIKE ADDED 113 : ^ > >1 _(______ _____
Initials Dale
Analyst initials Extracted ' 'l ' KD (^\N2 'M ^ Bottle up MA Witness _________' .
MBnu^r and lot number of reagcnts/solvents used J-TBf\li^ 'Ctlb'W -Vt) sU^ - ____fsjt> IT “ T7i ^ 5V
CA ..11
FORM 1 CLIENT SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
1i
^^Lab Name: COMPUCHEM Contract 8270CSJGLCS
^^^Lab Code :LIBRTY Case No.: SAS No. SDG No.: QE1877
Matrix: (l|
soil /'water) WATER Lab Sample ID WG16304-2
Sample wt/voT: 500 (g/mL) ML Lab File ID: WG16304-2B60_9
Level : (low/med) LOW Date Received
1% Moisture: decanted: (Y/N) Date Extracted:03/14/02
|Concentrated Extract Volume: 500 (uL) Date Analyzed 03/14/02
Injection Volume: 1.0 (uL) Dilution Factor: 1.0
GPC Cleanup: (Y/N) N
■ CAS NO.
pH:
COMPOUNDCONCENTRATION UNITS: (ug/L or ug/Kg) UG/L Q
108-95-2-------- Phenol 27111-44-4---------Bis (2 -chloroethyl) ether 4495-57-8----------2 - Chlorophenol 42541-73-1-------- 1, 3 -Di chlorobenzene 3910 6- 4 6 - 7-------- 1,4 - Dichlorobenzene 4195-50-1----------1,2 - Di chlorobenzene 4195-48-7----------2-Methylphenol 56108-6 0-1-------- 2,2' -oxybis (1 -Chloropropane) 42106-44-5-------- 4-Methylphenol 99621-64-7-------- N-Nitroso-di -N-propylamine 4567-72-1----------Hexachloroe thane 4598-95-3----------Nitrobenzene 4278-59-1----------Isophorone 4688-75-5----------2 -Nitrophenol 50105-67-9-------- 2,4 - Dimethyl phenol 46111-91-1-------- Bis(2 - chloroethoxy) methane 52120-83-2-------- 2,4 - Di chlorophenol 52120- 3 2-1-------- 1,2,4 -Tri chlorobenzene 5091-20-3----------Naphthalene 5210 6 - 47- 8 -------- 4 - Chloroan l line 5587- 6 8- 3 ----------Hexachlorobutadiene 5359-50-7----------4 - Chi or o - 3 - methyl phenol 5591-57-6----------2-Methyinaphtnalene 6277 - 4 7-4 ----------Hexachlorocvclopentadiene 458 8 - 06-2----------2,4,6 - Tr ichiorophenol 5795-95-4----------2,4,5 - Tri chlorophenol 7791- 58-7----------2 - Chloronapht halene 518 8 - 74-4----------2 -Nitroanii ine 54131-11-3-------- Dime thy lphthaiate 65606 - 20 - 2 -------- 2 , 6 - Dinitrotoluene ■592 0 8 - 9 6 - 8---------Acenaphthylene 629 9- 0 9 - 2---------- 3 - Nit roan i line 58
60
FORM I SV 8270C
78b
CLIENT SAMPLE NO.FORM 1SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: COMPUCHEM
Lab Code: LIBRTY
Matrix: (soil/water)]
Sample wt/vol:
Level:’ (low/med)I
% Moisture : _______
Concentrated Extract
Injection Volume:
Contract:
Case No.: SAS No.:
WATER
500 (g/mL) ML
LOW
decanted: (Y/N)
Volume: 500(uL)
1.0(uL)
8270CSJGLCS
SDG No.: QE1877
Lab Sample ID: WG16304-2
Lab File ID: WG16304-2B60_985
Date Received:
Date Extracted:03/14/02
Date Analyzed: 03/14/02
Dilution Factor: 1.0
GPC Cleanup: (Y/N) N pH:
1 CAS NO. COMPOUNDCONCENTRATION UNITS: (ug/L or ug/Kg) UG/L Q
51-28-5----------2,4 - Dinit rophenol 18 J100-02-7-------- 4 -Ni t rophenol 41121-14-2-------- 2,4-Dinit ro toluene 59132-64-9-------- Dibenzofuran 6484-66-2----------Diethylphthalate 647005-72-3------- 4 - Chlorophenyl - phenyl ether 6636-73-7----------Fluor ene 6610 0- 01-6---------4 -Nitroani 1 ine 62534-52-1-------- 4, 6-Dinit ro-2 - methyl phenol 528 6 - 30- 6 ----------N-Nitrosodiphenyl amine (1) 60101-55-3---------4 -Bromophenyl -phenyletEer 65118-74-1---------Hexachlorobenzene 588 7- 36 -5----------Pentachlorophenol 553 5-01-8----------Phenanthrene 6512 0-12-7-------- Anthracene 703 6 - 74- 3 ----------Carbazole 783 4 - 7 4 - 2----------Di-n-butylphthalate 672 06 -44- 0 ---------Fluoranthene 7012 9 - 00 -0------- -Pyrene 6285-68-7----------Butyl be nzylpht ha late 6191-94-1----------3,3' -Dichlorobenzidine 31
i 117-81-7-------- bis(2 - ethyl hexyl) Phthalate 6456 - 55 - 3 ----------Benzo (a) anthracene 73
1 213-01-9-------- Chrysene 69! 117 - 34 - 0-------- Di - n - octyl phthalate 64! 205 - 9 9 - 2---------Benzo (b) f luoranthene 71207 - 03 - 9 -------- Benzo(k) fluoranthene 66,30-52-8----------Benzo la) pyrene 65
60■ n 3 - 70 - 3----------Dibenzc (a , h i anthracene 71191-24-2---------Benzo (g , h , l ! perylene 70
iCannoc be separated from Diphenylamine
FORM I SV 8270C
787
Data File: /chem/5972h|ofcO. i/DF020314B60.b/WG16304-2B60_985.d
Date : 14-MAR-2002 22:19
Client ID: SJGLCS
Sample Info:
Volume Injected <ul_>: 1.0
Column phase: J&W DB-5.625
Instrument: 5972hp60« i
Operator: 2319
Column diameter: 0.32
/ )
oor-~-
Client ID; SJGLCS Instrument: 5972hp60.i
Sample InfoJ
Volume Injected <uL>: 1,0 Operator: 2319
Column phase; J&W DB-5.62C Column diameter: 0.32
Data rile: /chem,'5972hp60. i/DF020314BGO.b/UG16304-2B60_985.d
Date : 14-MAR-2002 22:19
2chem/5972hp60. i/DF020314B60.b/'WG16304-2B60_985,d (Part 2 of
Data File: /chem/5972hp60.i/DF020314B60.b/WG16304-2B60_985.d Report Date: 15-Mar-2030 11:07
CompuChem
Data file : Lab Smp Id: Inj Date) :
Operator : Smp Info. : Misc Info : Comment i Method < :Meth Date : Cal Date . :Als bottle: Dil Factor: Integrator: Target Vers Processing
Semivolatile Report /chem/5972hp60.i/DF020314B60 WG16304-2 14-MAR-2002 22:19 2319
/chem/5 9 72hp6 0.i/DF02 0 314B6 015-Mar-2030 10:11 byrd 0 3 -MAR-2002 17:20 41.00000 HP RTE ion: 3.50Host: einstein
SW-846 Method 8270C .b/WG16304-2B60_985.d Client Smp ID: SJGLCS
Inst ID: 5972hp60.i
.b/8270Cv6.m Quant Type: ISTD Cal File: HL020303A60.d QC Sample: LCS
Compound Sublist: OLM03.sub
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Cpnd
..oirpo-if
Name Value Description
DF J 1.00000 Dilution Factorvt: 500.00000 Volume of final extract (uL)Vo ■ 500.00000 Volume of sample extracted (mL)Vi 1.00000 Volume injected (uL)
•1
Variable Local Compound Variable
1'I
5 :
QUANT SIG
MASS f: EXF FT PEL FT RESPONSE
CONCENTRATIONS
ON-COLUMN FINAL
( NG) ( ug/L)
•; -2 : r.o-ir.e ■ A A 5 2 - ; - 1 9 3 6 7 5 4 0.0000
j •; - : 2 6 '• 2 4 3 40.0000
6 4 1 ' 225735 4 :. 00CO
-:r i ■■■ " " 1 . ' Ad 3 08 : 4 0 . 0000
..v. 2 ;• 5 7 A A •; o. oooo
264 2 : : 7 • A 3 a 0 2 7 n . o o o o
1 '.2 - . '22 : 2 2 2 8 7 2 3 69.6483 6 9.65
■ir.ol - -if 9r. 7- 201712 59.9632 5 5 . 9 6
5 7 ■r.0-3" ■3T . ES2: i80286 4 8 . 4 b 1 5 4 5.45
Piucr-chipher.'.-i 12. i s: 6: 494715 b6 .4933 .49
4 . r -Try ■3"' : 4 7- 6 • ': . ■. o s i 333373 157.311 1^7.3'1
r-vnvMy.-u:-; 244 '.i.Tii ’ 7 ? ■ 1? Oil) 878046 59.0462 5 5.05
54 7 r. r. l 7 . n-i 1 C . 9 3 3 ! 86406 26 . 6945 .26.69
s • i r.v; :• -v: 7 7 4 7 *:•: '0.943) 97224 4 3 . 6297 4 3.63
SIMILARITY
t< m)
' 790
Data File: /chem/5972hp60.i/DF020314B60.b/WG16304-2B60_985.dReport Date: 15-Mar-2030 11:07
QUANT SIG
expounds MASS R T
IB 2 - Chlorophe.nol 123 7 . 793
19 1 ,3-Dichlorobenzene 146 8.035
20 1,4 -Dichlorobenzene 146 9 . 153
22 1,2-Dichlorobenzene 146 9.407
23 2-Mechylphenci 108 8.576
24 2,21 -oxybis(1 - Chioropropane) 45 S . 593
27 4 -Methy 1'pher.ol 108 8.847
28 N - Ni troso-di-N-propyl amine 70 8.813
29 Hexach1oroethane 117 8 . 965
30 Nitrobenzene 77 9.101
31 Isophorone 82 9.507
32 2-Nitrophenol 139 9.642
33 2,4-Dimethylphenol 122 9.727
34 Bis(2-chloroethoxy)methane 93 9.879
35 2.4-Dichlorophenol 162 10.065
6 1.2,4-Trichlorobenzene 180 10.200
7 Naphtha i ene 128 10.336
3 6 4 -Chloroam 1 me 12 7 10.437
5 Hexach:qrobuta d:ene 225 10.539
5 -Chloro- 3 - met hy; pr.eno: 107 1 i 300
1 Met hy :|napht n-:« 1 ene 14 2 11.537
4 4 11.0 08
12 0444 5 2 , 4 . 5 - 7r : cr. 1... roc hero 1 196|
1,4.5- 7:': m ; oropheno : - 9 6 12 ’12r
. 1 o 2 12.303
2 - N: t roar.: 1 ; r- 6 5 l2.S6i
51 Dimethylpr.c ha la: -r 15 3 12. s; o
= ; 165 ::.oo?
b.: Arer.aph: h.y ! ene : 52 13.110
5' '• N: t roar : 1 * r.e 1 • £ 13 2 96
1 54
56
, , -1.1 hi-,...,-1 c 4 13.482
13.635
r 7 2 . 4 - D: n : t r; t ;. i r-me ■ 3 702
5£ 2 : rente : iv. r 168 ; } 7 1 ?
=■? 14 9 2 4. 142
4 - l'h 1 oropher.y; - pr-my l e: ne r 2 C 4 , 1 ?5 : rorene 14 T ~> -.
■-2 1 * ' 4 3 7 0
19? .4 4 3 :.
■- N: : restv-me
- - .. : ■.2
1 : .ill
.... !_• '7 0 5 4 4 7
. ...__ J..... : - = : ? : 21
" :I'-i r. - 15 7 1 5- 4 >
CONCENTRATIONS
ON-COLUMN FINAL
REL RT RESPONSE ( NG J ( ug/LI SIMILARITY
(0.953) 107566 42.2270 42.23 8994
(0.9801 137612 39.3961 3 9 . 4 0
f 1.002 ' 242074 4 0 . 9199 40.82
(1.0331 137351 41 . 1466 4 1.15
(1.054) 115566 55.3972 55.90
11.0561 134323 42.2270 42.23 7178
(1.087) 259880 98 . 9113 98 . 91 ((1.083) 86264 45.2369 4 5.24 0 (M) 1
(1.102) 66857 45.017? 45.02 8092
(0.835) 134339 41.6181 41 .62 9 94 2
(0.924) 235208 46.2746 46.27 8900
(0.937} 78909 49.5071 49.51 3915
(0 . 946) 88511 45.7670 45.77 8067
(0.961) 157839 51.5774 51.58 7826
(0.979) 148416 52.1161 52 . 12
(0.992) 166672 49.8883 49.89
(1.005) 401625 51 . 9259 51.93 9 04 0
(1.015) 179215 54.9687 54 . 97 8 6 7 6
(1.025- 139302 52.6759 52.66 8 3 3 7
(1.099) 130514 55 . 1289 5 5.13 9326
:i.122) 3 6 8 S 1 3 62 . 2388 62 . 24
(0.894) 115318 44 . 5415 44 . 54 9 3 52
(0.901) 142385 57 .4188 57.42
(0.905) 206637 76.5434 76.54
(0.9271 355669 50 . 9179 50.92
(0.940) 145252 53.7660 53 . 77 07 9?
(0.965' 594980 64.8518 64 . 85 9720
i0.573) 115360 58.9951 58 . 99 9526
(0 . 981 1 691364 61.5391 61.54 36 3 1
10.995) 120549 58.0853 58 . 09 ?)4 1
(1 . 0 04 1 305151 59.9060 5 9.81 3?L1
i 1 . 0091 22009 17.9939 17.99 ■riK' 1
: 1 . 020) 68351 41 . 3117 4 1.31 0 i M ) ^
1 1.02 5) 169557 53 .5324 58.53 5 7 01
; 1 . 027) ■'90035 64 . 3347 64.33 0558
1 ' 0C = , 034528 64 . 0545 64.05 > 5 1 4
'1 C 7 2 j 356697 66.3276 66.33 7 3 94
11.072; 643155 6 6.0 9 5 C 66.10 7 7 2 5
••*: .070) 1289C 3 61.6160 61.62 3510
(0.903) 96922 51 .6946 51 68 0 8 01
‘1.9 0 9 ;■ 359719 5?.577? 5 9.5 3 0 0 34
‘ 0 .550) 219884 64.6275 64 .63 9556
'0.9531 223940 57 . 0537 5 7.55 9 12 9
' 0 . 9 7 5 j 62254 5 d . 0 -j 6 6 55 04 V 0 0 i
: 1 . C ■ j 2 1 924525 65.0552 ro 0 -J
,1 •? • \ 0 ; 1 C 'J 2 4 5 9 70 07?0 7 0 0 6
1 1 .026. 665653 7 0. . 0 0 : 7 3 . (J 2 0 2 1 7
EXP RT
7 . 799
8 . 035
3 . 154
3.408
8.594
8.594
8.847
3.814
8.966
9 . 101
9 . 507
9.643
9.727
9 . 379
10.066
10.201
10.336
1C.438
10.539
11 . 3 0 0
11.537
11.808
12 . 045
12 113
1 2 30 3
12.586
12.091
i3.009
13.111
13.314
13.415
1 5 . 5 0 0
13 6 3 5
13.72 0
13.737
14 . ■ 4 3
• .• t -> o
14.325
1 '1 . 3 96
14.545
• c. tj 2
. -
791
Data File: /chem/5972hp60.i/DF020314B60.b/WG16304-2B60_985.dReport Date: 15-Mar-2030 11:07
CONCENTRATIONS
Compounds |
• QUANT SIG
MASS RT EXP RT REL RT RESPONSE
ON-COLUMN
( NG)
FINAL
( ug/L) £>IMILAE ITV
731
Di-n-butylphthalate 149 17.001 17.002 (1.063) 1245152 67.0926 67.09 9488
74 Fluoranthene 202 18.118 18 .118 (1.133) 1149221 69.9989 70.00
76 Pyrene 202 19.524 18 . 524 (0.898) 1188249 61 . 3249 61.82
77 Butylbenzylphtha late 149 19.624 19.624 (0.952) 602055 60.6598 60.66 9171
7 S 3,3'- Diehlorobenzidine 252 20.537 20.555 (0.996) 234427 30.9314 3 0.93 7662
79 bis f 2 - ethylhexyl)Phthalate 149 20.590 20.5 3 S (0.9 99) 986104 63.9239 63.92 90S2
80 Benzo(a)anthracene 225 20.605 20.605 (0.999) 1401357 73.OS 08 73.08
81 Chrysene. 228 2 0 . 656 20.656 11.002) 1195250 69. 1613 69.16
92 Di -n -octy1phtha 1 at e 149 21.569 21 . 570 (0.931) 1404514 63.5429 63 . 54
8 3 Benzo /b) £ I unrar.thene 252 22.151 22.362 (0.966) 1340374 70.8115 70.81
84 Benzo(hi fluoranthene 252 22.4 32 22.432 (0.968) 1126072 65.7967 65 . SO
96 Benzo!a)pyrene 252 23.05 8 23.058 (0.995) 987804 65.2065 65.21
3 b Indeno(1,2.3-cal pyrene 276 26.069 26.087 (1.125) 974627 60.2922 60.29 3785
87 Dibenzo{a,h)anthracene 278 26.137 26.137 (1.128) 998796 70.9860 70.99 8610
88 Benzo(g,h,i)perylene
m |
276 26.983 27.000 (1.164) 953409 69.9895 69.99 74 3 7
QC Flag Legend
a - Target compound detected but, quantitated amount Below Limit Of Quantitation(BLOQ).
M - Compound response manually integrated.
f
79^
Data File: 'cnem.- 5972hp60.1 .-'DF020314E60 . b/UG 16304-2B6O_385. dInjection Data: 14-MAP-2002 22:19Instrument: 5972hpb0.1Client Sample. ID: 5JGLCS
pound: 2.4‘, 6-TribromophenolNumber: 118-79-6
1.6- 1.5- 1.4-1
1.3-
l .2-;
1.1-
i .0-:
Ion 329.60: Area: 333373 Height: .164124
0.8-
0.7-
0.6-
0.5-0.4-
0.3-
0.2-
0.1-
n. ui_
14.3 14.5 14.6 14. 14.8 14.9 15.0 15.1Min
15.2
1.6-'
1.5-
1 .4-
1.3-
I1-1-
1.0-
0.9-
0.6-
Ion 332.00: Area: 0 Height: o
> 0.6-
! 4.5 14.Q 15.0 15. 1 i5.:
IQn 141.00; ne i gnr. : 0
14.5 14.7 14.8
M i r i14.9 15.0 15.1
•793.15.2
Data File: .'cnem/5972hp60.1 /DF020314B60.b/tdGl6304-2B60_985.dInjection Date: 14-MAR-2002 22:19Instrument: 59?2hp60.1Client Sample ID: SJGLCS
pound: N-Nitroso-di-N-propylam me S Mumper: 621-64-7
4.8-
4.5-
4.2-
3.9-
3 . D"
3.3-
3 0-
Sch
Ion 70.00: Area: 86264 Height: 5052
lO o
2.1-
r '•*-
I 1.5-
i 1-2'
I 0.9-I 0.6-'
0.3-
: o.o-8.4 8.5 8.6 8.7 8.8
Min
8.9 9.0 9.1 9.2 9.3
Ion 130.00: Area: Height: 0
a.-;
0.5
n n3.5 8.1 3.3
Mm8.9 9.0 9.1
Ion 42.00: Area: 0 Height:
79-‘-t-
8.3M 1 r.
9.1
Data File: /chem/5972hp60.1/DF020314B60.b/UGl6304-2560_9B5.dInjection Date: 14-MAR-2002 22:19Instrument: 5972hp60.1Client Sample ID: SJGLCS
•
ipound: 2.4-DimtrophenolNumoer: 51-23-5
9.0-Ion 184.00: Area: 22009 Height: 9008
8.0- 7.5-;
o. z>- 6.0-
5.5-
5.0-
4.5- :
4.0-3.5-
3.0- '
2.5- ;
2.0- ;
1.5-
1.0-
0.5-
0.0--T13.1 13.2 13.3 . 13.4 13.5 13.6
____Min_________________13.7 13.8 13.9 14.0•
Ion 154.00: Area: 0 Height: 0
13.3 13.4 13.5M l n
13.6 13.1 13.8 13.9
Ion 63.00: Area: 0 Height: 0
79:13.8 13.9 19.0 :
Data File: /chem/5972hp60.1 /DF020314B60 . b/UGl6304-2B60_985. dInjection Date: 14-MAR-2002 22:19Instrument: 5972hp60.1Client 5ample,!lD: SJGLCS
# ound: 4-NitrophenolNumber; 100-02-7
2.8-
2.6-
2.4-
2.2-
2.0
1.8-
1.6-
1.4-
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CompuChema Division of Liberty Analytical Corp.
GC/MS SEMI-VOA WORKSHEET
LAB INSTRUCTIONS:
RECEIPT DATE: 3/14/02 0:00
CASE#:
SAMPLE DATE: DUE DATE:
SDG: WGI6304 COMPUCHEM#: WG16304-2
CLIENT ID: SJGLCS
ANALYSIS DESCRIPTION: SVOA-8270C
Injection Volume :
I
Extraction Date __
DFTPP Filename
IpL
_/14____ /___ 02
DF020314B60
Sample File Name WG 16304-2 B601
ANALYST (S): Injection2319__________
Dilution Prep (if needed)_
Work-up
GC/MS DATE REVIEW-
CONDITION CODE
c^
Extraneous Peak Search Results:
Number of peaks found: ____Hk
Number of Hits found: ____
Number of Surrogate Outliers:_____ f_
Quality Assurance Notice (si Number of Notices Required 9
IComments:
Disposition: [•'^Complete
[ ] Reinjection Required
[ ] Re-extraction Required
[ ) Reinject Neat
[ | Dilute! X)
-GC/MS Review
Final Reportable Packauets):
Date A L Auditor
b-> ^/C~}o<S - - 9i'(^]
Date
. 797SVl -6/27/01: PTF
d. Matrix Spike Data
- Tabulated Results (Form I SV)
- Reconstructed Ion Chromatogram and quantitation report
799
FORM 1SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO.
Lab Name COMPUCHEM
Lab Code: LIBRTY Case No.:
Matrix: (soil/water) WATER
Sample wt/vol: 1000 (g/mL) ML
Level:' (low/med) LOW
% Moisture: decanted: (Y/N)
Contract: 8270C
SAS No.:
MW-13BMS
Concentrated Extract Volume:
Injection Volume: 1.0(uL)
1000(uL)
GPC Cleanup:
CAS NO.
(Y/N) N pH:
SDG No.: QE1877
Lab Sample ID: WG16228-3
Lab File ID: WG16228-3A60
Date Received: 03/08/02
Date Extracted:03/10/02
Date Analyzed: 03/13/02
Dilution Factor: 1.0
COMPOUNDCONCENTRATION UNITS: (ug/L or ug/Kg) UG/L Q
11 108- 95-2--------Phenol 25111-44-4--------Bis ( 2 - chloroethy 1) ether 45
, 95-57-8---------2 - Chlorophenol 45j 541 - 73 - 1--------1, 3-Dichlorobenzene 39106-46-7--------1,4 - Dichlorobenzene 4195-50-1---------1,2 -Di chlorobenzene 4195-4 8 - 7--- ----- 2 -Methylphenol 56
1 10 8 - 60-1--------2,2' -oxybis (1 -Chloropropane) 43106-44-5--------4 -Methylphenol 89621-64-7--------N-Nitroso-di -N-propylamine 4467-72-1---------Hexachloroethane 41
1 98 - 95- 3 ---------Nitrobenzene 44. 78 - 59- 1 ---------Isophorone 44i 88-75- 5---------2-Nitrophenol 48j 105 -67-9--------2,4 -Dimethylphenol 33111-91-1--------Bis (2 - chloroethoxv) methane 47
: 120-83 -2 --------2 , 4 - Dichlorophenol 501 120- 3 2-1--------1,2,4 - Tri chlorobenzene 46' 91-20-3---------Naphthalene 4910 6- 47-8--------4 - Chloroani 1 ine 52
i 8 7 - 68 - 3 ---------Hexachlorobutadiene 47! 59- 5 0 - 7---------4 - Chioro - 3 - methylphenol 52J 91-57-6---------2 -Methylnaphthalene 5577-47-4---------Hexachlorocyciopentadiene 46
; 83- 06-2--------- 2,4,6 - Tri chlorophenol 56| 95- 9 5- 4---------2,4, 5-Trichlorophenol 74■ 81-58-7---------2 - Chloronapht halene 451 38 - 74 -4 ---------2 -Nitroani line 53131-11-3--------Dimethylphchalate 61
1 606 -20 -2 --------2 , 6 -Dimtrotoluene 54208 - 86 - 8 --------Acenaphthylene 52
; 9 8 - 08 - 2 --------- 3 -Nicroaniline 54J 8 5 - J .j - 8---------Acenaphthene 56'
80 i
FORM I SV 8270C
FORM 1SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO.
Lab Name: COMPUCHEM Contract:
Lab Code: LIBRTY Case No.: SAS No.:|
Matrix: (soil/water) WATER
Sample wt/vol: 1000 (g/mL) ML
Level: (low/med) LOW
% Moisture: ______
Concentrated ExtractI
Injection Volume:
GPC Cleanup: (Y/N)
decanted: (Y/N)
Volume: 1000(uL)
1.0(uL)
N pH : ___
8270CMW-13BMS
SDG No.: QE1877
Lab Sample ID: WG16228-3
Lab File ID: WG16228-3A60
Date Received: 03/08/02
Date Extracted:03/10/02
Date Analyzed: 03/13/02
Dilution Factor: 1.0
CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
J 51-28-5---------2,4 - Dinitrophenol 42 Ji 100-02-7--------4-Nitrophenol 401 121-14-2--------2,4-Dinitrotoluene 57132-64-9--------Dibenzof uran 59
; 84-66-2 ---------Diethylphthalate 627005-72-3-------4 -Chlorophenyl-phenylether 6286-73 -7---------Fluorene 59100-01-6------- 4 -Nitroaniline 64534-52-1------- 4, 6-Dinit ro- 2 - methyl phenol86 - 30- 6 ---------N-Nitrosodiphenylamine (1)
6160
i i 01-55 -3------- 4 -Bromophenyl -phenyletEer 62i 118-74-1--------Hexachlorobenzene 58| 87 -86 - 5 ---------Pentachlorophenol 64: 85-01-3---------Phenanthrene 6812G-I2-7--------Anthracene 6886 - 74 -8---------Carbazole 7884 - 74 - 2---------Di - n - butylphthalate 62206-44 -0--------Fluoranthene 72
: 12 9- 00 - 0--------Pyrene 628 5- 68-7---------Butyl be nzylphthalate 5491-94-1---------3,3' - Diehl orobenzi dine 29
| 117-81-7--------bis ( 2 - ethylhexvl) Phthalate 61 B> 56 - 55 - 3 ---------Benzo ( a ) anthracene 75
i , 218-01-9--------Chrysene 67j 117-84-0--------Di - n-octylpnthalate 61| 2 Or - 9 9 - 2--------Benzo ( b) fluoranthene 66i , 2 0 7-08 - 9 ---------Benzo (k) fluoranthene 751 5 0-32 - 8 ---------Benzo (a ) pyrene 70; 1 e J - 3 9 - 5--------Indeno (1,2,3- cd) pyrene 64
; 3 - 70 - 3---------Dibenzo (a , h} anthracene 761 : 19 1-24-2--------Benzo \ g , h , i) perylene 75
I
1 ) Cannot be separated from DiphenylamineFORM i SV 8270C
I
j
801
Data F i la: /chem/5972hp60« i/DF020313A60*bAJGl&228-3A604d
Date : 13-MAR-2002 13;53
Client ID: MW-13BMS Instrument: 5S72hpbO*i :'vj
Sample Info: oVolume Injected <uL): 1*0 Operator: 517 ooColumn phase: J&W DB-5+62C Column diameter: 0*32
<xlO~7>
Data File; /'chem25972hp60. i2DF020313A60.b/UG16228-3A60.d
Date : 13-MAR-2002 13:53
Client ID: MW-13BMS
Sample Info:
Volume Injected <uL>: 1.0
Column phase: J8>U DB-5.625
Instrument: 5972hp60.i
Operator: 917
Column diameter; 0,32
/chem/5972hp60.i/DF020313A60.b/WC16228-3AC0.d (Part 2 of 2)
4.4-4.3- 1
4.2!4.1- 14.0- j
3.9-j 3.8-1
3.7- ;3.6- j3.5- j3.4- 1
3.3- :3.2- :3.1- :3.0- i 2.9!2.8- 1
2.7- :2.6- !
2.5- j2.4- 12.3- 12.2- !
2.1- 1> 2.0!1.9-11.8- :
1.7-:
1.6! 1.5!1.4- 1
1.3! 1.2!
1.1-1 l.o-i
0.9! 0.8-;
0.7-; 0.6!
0.5-: 0.4-i 0.3! 0.2-:
o.i-
•1<
+C’JtHT*i«ll'.0
l',
Jl I A19
ooo
21
Data File: /chem/5972hp60.i/DF020313A60.b/WG16228-3A60.dReport Date: 14-Mar-2030 09:44
Data file Lab Smp Id Inj Date Operator Smp Info Misc Info Comment Method Meth Date Cal Date Als bottle Dil Factpr Integrator
CompuChem
Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020313A60.b/WG16228-3A60.dWG16 228- 313-MAR-2002 917
13 : 53Client Smp ID: MW-13BMS
Inst ID: 5 972hp60.i
/chem/5 9 7 2hp6 014-Mar - 2 03 0 08:48 0 3-MAR- 2 0 0 2 17:20 31.00000 HP RTE
Target Version: 3.50Processing Host: einstein
i/DF020313A60.b/8270Cv6.mbyrd Quant Type: ISTD
Cal File: HL020303A60.dQC Sample: MS
Compound Sublist: OLM03.sub
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
DF 1.00000 Dilution Factor
Vt 1000.00000 Volume of final extract (uL)
Vo 1 1000.00000 Volume of sample extracted (mL
w Vi
[
1 . 00000 Volume injected (uL)
Cpnd Var
1
iable
1
Local Compound Variable
CONCENTRATIONS
vUANT s:g • ON- COLUMN FINAL
•1'CTlpGUr .is MASS RT EXP ST REL RT RESPONSE 1 NG) ug /L)
: : ..:-D:cr
i
e - d 4 152 2.154 ■- .15 2 •: 1 0 0 0 : 102773 40.0000
aph:ha: 1 3 6 1 0 0 2 : ' 2 2 1 '1.0 0 0. 270986 40.0000
■ ; rec.ap.-. t 1 ' 3 - ; ■ ' t c : '1 .000' 232629 40.0000
* 4 ? .tenant rL-e-d:.'
1 5 C 'J ‘.6 " C ' il .000 j 469344 40.0000
r : hrysene 24 0 2 2.6 } - 5 2.5 2 2 ■ 1 . 000. 567335 4 0 . 0 0 0 0
2 64 2 1.2'.' 22.2 i •> 0CD. 457017 40.0000
7 ; Fin: 5 . "I r - 6 2 - ■. 0 .743- 725357 215.656 2 1 ; . 7
r ? T bene '. • z 5 ’•• •; 2 2 5 5 6 0 60.7987 6 0.80
: ; • • h:r-.;.ry: v :-■■■ :: 45126? 54.3171 54 . 3 2
7 • i : •' ■- 4 . ~ ; 7-.; 1.10 5 38=765 1 7 7 . 6 2 4 -.ii •;
•/: t ner. ••••; . 2 : - :; '0.011: 1 0 5 8 3 0 3 67 y420 6 7.84
.T ...... . -;.
,4
111577 4 5.20.; 5444
SIMILARITY
0
804
Data File: /chem/5972hp60.i/DF020313A60.b/WG16228-3A60.dReport Date: 14-Mar-2030 09:44
CONCENTRATIONS
QUANT SIG ON-COLUMN FINAL
Compounds MASS RT EXP KT REL RT RESPONSE ( NG) ( ug/L) SIMILARITY
IS 2-Chlorophenol 128 7.815 7.814 (0.950) 127698 45.2541 45.25 S 8 0 9
1 9 1, 3 - Di ch'l orobenzene 146 8 . 052 8 . 051 (0 . 988) 151430 39.1351 39 . 14
20 1,4-Dichlorobenzene 146 3 . 187 8.187 (1.004) 158041 4 0 . 9907 40.99
2 7 1,2 -Dichiorobenzene 146 8.424 8.423 (1.033) 151152 40.7282 40.73
23 2-Met hy1pheno1 I0S 8.610 S . 6 1 0 (1.056 ) 127415 55 . 6339 55.63
24 2,2'-oxyb;s(1 - Chioropropane! 4 5 S . 6 1 0 8.610 11.0 5 6 ) 152136 43 . 1747 42.17 0 (M)
2 n 4 - Met hyIpheno: 108 8.864 S . 8 *d 3 (1.087J 258965 88.9731 36 . 97
2k N - N i t roso • d: - N - propy i am i ne 70 3 . 530 8 . 829 (1.083) 92489 43.7836 43 .78 0 (M)
29 H e a c h 1 o r oe t ia n. e 117 9 9 S 9 8.599 (1 . 104) 66780 4 0.5922 4 0.59 8965
3 j N:z rcbenzene 77 9 . ne 9.117 (0.885) 151B91 4 3 . 8944 43.8? 3910
I sodhe rone 32 9 . 524 9 C, 7 T (0.9241 236329 43.7385 4 3.74 3 9 12
32 2 - Nt rophs:'.o 13 9 9 . 559 9 . 658 10.938 ) 81844 47 . 8988 47.90 8 7 3 S
33 2,4- Dimet hy Ipheno 1 12 2 9.751 9 . 750 (0.947; 59206 33 . 3807 33 . 33 555 0
34 B;s(2 - ch. I or oe t hoxy)methane 9 3 9 . 896 9.895 (0.961) 153898 46.9110 46.91 7 7 96
3 5 2,4 -D:ch1o rophenol 162 10.082 10.061 (0.979) 154003 50.4449 50.44
36 1,2,4-TricnIorobenzene 180 10.217 10.217 (0.992) 167465 46.2037 46.20
32 Napht ha ler.e 128 10.353 10.352 (1.005) 407399 49.1338 49.13 9902
3 3 4 - Ch loroar. i I i ne 127 10.454 10.4 54 (1.015) 182739 52.2840 52 .28 3792
39 Hexachlorobutadiene 225 10.573 10.572 (1.026} 133598 47.1250 47.12 9228
4 1 4 - Chlorc j- 3 - met hy 1 pheno 1 107 11.317 11.316 (1.099) 131569 51.8409 51.84 8757
4 2 2-Metnylnaphthalene 142 11.554 11.553 (1.122) 337038 54 . 5341 54 . 53
44 nexach 1 oro.cycaopentad er.e 237 11 . 825 11.924 (0.884) 123234 46.0870 46.09 9181
4 5 2,4,6 -7richiorophenol 196 12.062 12.061 (0.901) 143176 55.9036 55.90
2,4,5 -Trich1orooheno1 196 12.129 12.145 (0.906) 206592 74 . 0957 74 . 10m 2-Chloronaphtnalene 162 12.400 12.399 i 0 . 927i 327053 45.3339 45.33
2 - N: t roar, i 1 i r.e 6 5 12.585 12.602 (0.941) 148931 53.0115 53.01 9634
50 Dimethylphthalate 163 12.907 12.907 (C.965) 581956 61.4 171 o 1 . 4 2 9577
= 3 16 5 13.C26 13.025 (0.973) 108462 53 . 7062. 53.71 9570
3 4 rtcenaonzhv' -r-r ’ C ”1 13 .12 7 13 1 2 7 . 9 6 1 ■- 608529 52 .4451 52 .45 8560
5 3 : Z '.5.313 .: • •’0.995. 116691 54 .44 02 54 .44 8 9 6 6
=-- Aoer.apr.thr:-.-:- 154 13.432 13. 4 4 5 0 C'- 4 i 3 7 S 7 5 S 55 . 5039 55 . 50 867 1
• - •••"•' : = • 156 1 3.50 0 : • 6 66 • TAC| ; 53459 42.3174 42.32 (a )
5 5 : 9 .662 5 5 5 : 22 0 694 57 4 0.2926 4 0.29 0 (M;
5 7 - 6 5 13.7: v • 1 . 0 2 5 170446 56.9701 56.97 8 6 0 3
5- : l oc::zo: 6i - c ~ -.6 -62 : . o: - 746369 53.8 8 7 S 58 .89 9219
5 • 16 9 : 4 . 1 5 9 ■■ - '■ 6 -■ .1 . 0 6 , 631357 61 .6806 61.68 94 4 8
2 04 1 4 3 4 3 : 9 . : 4 5 . : .072 344854 61.7421 61.74 7 34 7
h'.u.trer.e i I 4 4 14.345 '■ 6 ■ ; 6 6 :: . 2 600441 59.2843 59.29 774 6
1 5 -4.35- 4.;. • 1 . 5 7 137611 63.5895 63 . 69 6 1 0 0
4 , 4 ■ Din: t: -1: - met zy 1 p::~r.:: 1 1 9 5 14 .44" 14 ' : '1.5 C 3 ; 113525 61 . 2875 61.29 07 34
:~9 • •• .:. :• i o, 273393 5 9 . 9553 5 9.96 644 5
o.. _L'.. . . . . .. • - ■ ■ 24 4 1 5 . 2 t r 1--2" • 0 . 9 5 0 1 217489 61.9727 61.97 cue
7 _ “• *i 1 3 3 2 7 1: . 5 5 - 1 231053 57 . 9676 5 7.97 ^ j '
■■ ■- P-Uochiorcy:.-:-: 6 16 662 : 6 : . •; 5 . 74 52 1 6 3 . 9707 63 . 67 3,V,i
: 7 = 14.054 1 •. 5 '• 1 . j C 990602 67.5814 57 . 59
1 7 c. . • : :■ = ’ 1 . 0 0 8■ 9 9 S 5 06 67 . 6724 67.67
"■ 2 1 4,7 i •: 4:. •; •;L ' • .02 -1 690421 77.7992 77.90 3 919
f
8 Ob
Data File: /chem/5972hp60.i/DF020313A60.b/WG16228-3A60.dReport Date: 14-Mar-2030 09:,44
CONCENTRATIONS
Compounds
QUANT SIG
MASS P.T EXP RT REL RT RESPONSE
ON-COLUMN
( NG)
FINAL
( ug/L) SIMILARITY
73 Di-n-but yiph trial ate 149 17.018 17.018 (1.063! 1185619 61 . 9350 61.94 9067
74 Fluoranthene 202 18.152 18.151 (1.134) 1216087 71.8111 71 . 81
76 Pyrene 202 18.558 IS . 557 (0.899) 1268974 62.3482 52.35
77 Bu t yibe n z y1ph t ha 1a t e 149 19.641 19.657 (0.952) 569702 54.2035 54 .20 8 9S2
79 3,3' -Dichlorobenzidme 252 20.571 20.570 (0.997) 235416 29.3321 29 . 33 64 95
7 c, bis(2 - ethyl hexyl)Phthalate 14 9 20.605 20.604 (0.998) 888339 60.5162 6 0.52 8 9 3 1
3 0 Benzo(a)anthracene 223 20.622 20.621 ( 0.999) 1529456 75 . 3153 75 . 32
81 Chrysenej 228 20.673 20.672 (1.002) 1221904 66.7666 66 . a
82 Di-n-oc bylphthaiate 145 21.536 21.585 (0.930) 1399036 60.7396 60.79
9 3 Benzo(b)fluoranthene 252 22.415 22.414 (0.966) 1295117 65.7123 65.71
34 Benzo(k)fluoranthene 252 22.466 22.465 (0.968) 1341450 75 . 2787 75 . 28
85 Benzo(a j pyrene 252 23.092 23.091 (0.995) 1111647 70.4770 70.48
35 Indeno(1,2,3-cdI pyrene 276 26 . 120 26.13b (1 . 125) 1078614 64 . 0839 64 . 08 8673
37 Dibenzo(a,h)anthracene 278 26 . 171 26.187 (1.128) 1118309 76.3339 76.33 8714
83 Eenzo(g,h,i)oervlene 276 27.034 27.023 (1.165) 1064672 75.0636 75.06 7395
QC Flag Fegend
Target compound detected but, quantitated amount Below Limit Of Quantitat ion(BLOQ) .Target compound detected but, quantitated amount exceeded maximum amount.Compound response manually integrated.
I
80 )
Data File: /chem/5972hpb0 . i /DF020313H60 . b/bJGl6228-3A60. dInjection Date: 13-MAR-2002 13:53Instrument: 5972hp60.iClient Sample ID: MW-13BMS
N,und:
'Number2-F l-'uoropnenol : 367-12-4
Ion 112.00: Area
5.4-
5.1-4.8-4.5-4.2-3.9-
725367 Height
©'£i|
! i
559800 1
i
2.4
2. 1-
1.8-
1 .5 1 . I-
fi Q.
5.3 5.9 6.0 6.1 6.2 6.3 6.4 6.5________________________Min_______________________________________________________
Ion 64.00: Area: 0 Height: 0
6.0--
5.6-
5.2-.
— 3.6-'IP
~ 2.8
1
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T1
6.4 6.5
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1
1
I
0. 1 80 ?
i
5.9 U o.1 6.2 6.3 6.4 6.5i n
i;
it
'IH
Data File: /chem/5972hp60.1/DF020313A60.b/LJGl6228-3A60.dInjection Date|: 13-MAR-2002 13:53Instrument: 5972hp60.1Client Sample ID: MU-13BMS
|ound:fNumber
2.4. ‘6-T r ibromophenol : 118-79-6
2.4-
2.0-
1.8-
1.6-
1 . J
Ion 329.60: Area: 388769 Height: 241399
$c\.rj
I
1 . v
14.3 1 14.4 14.5 14.6 14.: 14.8 14.9 15.0 15.1 15.2Min
Ion 332.00: Area: 0 Height: 0
1.4-
L"1 •
14.4 14.5 14.6 14.7 ; 4.6 ; 4. •? 15.0 15.1 15.1'
J____________________________________________________________________________ N ; r- __________________________! Ion 141 . ■ j ij: Prea: 0 Heisrt: u
l'
80
1 5 . L'Mr,
Data File: .■,chem/5972hp60.1 /DF020313A60. b/UG16228-3A60. dInjection Date[: 13-MhR-2002 13:53Instrument: 5972hp60.iClient Sample ID: MU-13BM3
Aund: :■lumber
2 ’--ovybis< 1-Chloropropane > 1 'Jb-bU-1
6.0-
5.6-
5.2-;
4.8-
4.4-
4.0:
Ion 45.00: Area: 152136 Height: 63640 Q43 '
i •ODI
1.0-
1 .2
' j . 8
6.4 8.5 8.6 8.7 8.8 8.9 9.0 9.1____________________ Min__________________________________________________________
Ion 121.00: Area: 0 Height: 0
CD
1 . 1
I onMl
8.8 8.9
Helgnt; 0
1
l
80 b
i'llQ 18.8 6.9
Data File: /chem/5972hp60. i/DF020313A60. b/UIG16228-3A60. dInjection Date: 13-MAR-2002 13:53Instrument: 5972hpb0.lClient Sample ID: MU-13BMS
#und: N-Nitroso-dl-N-propy1 amine■Jumper : 621 -64-7
4.5-
4.2-
3,9-
3.6-
3.3- '
3,0-
Ion 70.00: Area: 92439 Height: 45360
CD
qd-
2.1-
1.6-
1.5-
1.2-' 0.9-
0.6- 0.3-
0.0-
"8.4 8.5
/ J;
3.6 8.7 0.8Min
8.9 9.0 9.1 9.2 9.3
3.5
#
e.4
Ion 130.00: Area: 0 Height: 0
8.6 9.1
Ion 42.00: he l gnt. : 0
81
d . 3
M i n9.1 9.3
Data File: /ch'em/59?2hp60. i/DF020313A60.b/UG16228-3A60.dInjection Date: 13-MAR-2002 13:53Instrument: 5972hp60.1Client Sample [ID: MU-13BMS
hound: 4-Nitrophenol
■Number: 100-02-7
1.6
1 . 6
1
1 . 1
Q
Ion 109.00: Area 6945:aU5l»rn
Height: 33448
! i
4 13.5 13.6 13.7_______________________Min____________________
Ion 65.00: Area: 0 Height
13.8
0
13.9 14.0
in
■£i
rn
14.1
1 . 5 17.6 13.7 13.0 13.9 14.0 14.1__________________________________M I :‘i_________________________________________________________________________________________________________________________
Ion 179.00: Area: 0 height: 0
i
811
13.9 1 4 . A 14 . 1
[
CompuChema Division of Liberty Analytical Corp.
GC/MS SEIVD-VOA WORKSHEET
LAB INSTRUCTIONS: QE1877-12 FOR QCI
RECEIPT DATE: 3/8/02 0:00 SAMPLE DATE: DUE DATE:i
CASE#: SDG: WG16228 COMPUCHEM#: WG16228-3
CLIENT ID: MW-13BMS
ANALYSIS DESCRIPTION: SVOA-8270C
Injection Volume :1.0pL Dilution Prep (if needed)I
Extraction Date___3___/10____/__02
DFTPP Filename DF0203 / 3 A C t?
Sample File Name u-1 /-? / j- i i £' - 7 A a
ANALYST (S): Injectioncf / 1_________________ Work-up<7 ( 7
GC/MS DATE REVIEW
CONDITION CODE
Extraneous Peak Search Results:
Number of peaks found: _____ S'/^L.
Number of Hits found:_______
Number of Surrogate Outliers:'i
Quality Assurance Notice (s)Number of Notices Required §
Disposition: [/] Complete
[ ] Reinjection Required
[ ] Re-extraction Required
[ ] Reinject Neat
[ ] Dilute ( X)
Comments:
#GC/MS Review
Final Reportable Package(s):
Date 3 //</■' l' Auditor
td ^ /L 2TT -3 xj/g' o
Date / /
812
S VI - 6/27/01: PTF
assigned ro: Af
kKbo
^c_
C (impuC'hcm
EXTRACTION WORKSHEET
SF.MI-VOI.ATII.E WATER, Method 3510C for 8270C DA I I lXIKO IED/POSI I D:
■' ........ ~ -V. ■^' 0^
SAMPLE , FINAL Adlusted bH . V—ISAMPLE NUMBER ;J
$C SAMPLE , •A i-TYPE ; • S
’i: /VOLUME .
(mlJ
VOLUME
(ml)A/N base ; comments oo
Q^/ir?7- $■ /eo& ____ IP AG 12.;
: 1- /ore _______ l.n A 6 i2 1/£>£& ____ 1.0 Au l-z i/ ^
/OOa 1.0 I.L \2\* /coo Id A U 17.1 Qc-i? ^
/?- /coo .. .6 / b |2 (
ft //a<o •C LL 12 |
if jo<rc 1.0 AU >?.l
> _______ U- /bCO\d
/ h 12.i
. / 7 /CC €U
/ (r i‘Z-1■ 1 I*
/QCC U 7i, Ml
2 V /f /COG • 1.0 / c (2.»
i Mr/i'zZfcy /etc l.o }. b 12-14 > / s s /Oco Vo AU 12 <qtriihi-i
/CO® ItO Ai n. 1<ry7h/ozY-f Joev 1-0 A 6 Q-1 ( c x-dccm c _ ____
/ __^
8 rl 1 l />
9JTTTUj; -
0
1 __ ,-—-------
.2 ~ — -!3 LvirKp ZZi'-l
Blk jm M JU \i\14 J S' Z' LCS /COO 1.0 / (# rJ-( *Add 1.0 ml. validation spike to 1 ( S and SSs unless otherwise noted
S-VOL Acid 8270FINAL VOLUME VERIFIED: ]________ ___
NO. 393- is/ ^
__SURROGATE AIMT. 1.0 ml A/~■v i'
•--------- .---- rLOT KH/11 7^---------------
SltPERVISOR REVIEWED: ^ ------- ............... '..... .......NO. 3012/^ 2021 VALID.
SPIKE AMT. LTml 1.0ml 1.0 ml 170LOT T07/1T Sl'RROtiA l E & SPIKE ADDED 1)V: ^ _____
Analyst initials. Extracted
Manul^Hr
KD JYYN2 Dottle \N'i (ness
Initials I )aie
#. Initials Date /
r and lot number of reagcnts/solvents used ~ CT 17 1 i ^ ,1 I __ ^ -^ £_______
e. Matrix Spike Duplicate Data
- Tabulated Results (Form I SV)
- Reconstructed Ion Chromatogram and quantitation report
814
FORM 1SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO.
Lab Name: COMPUCHEM
Lab Code: LIBRTY
Matrix: (soil/water)
Sample wt/vol:
Level: (low/med)
% Moisture: ______
Concentrated Extract
Injection Volume:
Contract:
Case No.: SAS No.:
WATER
1000 (g/mL) ML
LOW
decanted: (Y/N)
Volume: 1000(uL)
1.0(uL)
8270CMW-13BMSD
SDG No.: QE1877
Lab Sample ID: WG16228-4
Lab File ID: WG16228-4A60
Date Received: 03/08/02
Date Extracted:03/10/02
Date Analyzed: 03/13/02
Dilution Factor: 1.0
GPC Cleanup: (Y/N) N pH:
CAS NO.CONCENTRATION UNITS:
COMPOUND (ug/L or ug/Kg) UG/L Q
108-95-2--------Phenol 12111-44-4--------Bis(2 -chloroethyl) ether 3095-57-8---------2 - Chlorophenol 28541-73-1--------1,3 -Di chlorobenzene 26106-46-7--------1,4 - Dichlorobenzene 2795-50-1---------1,2 - Di chlorobenzene 2695-4 8- 7---------2 -Methyl phenol 3410 8 - 60-1--------2,2' -oxybis (1 -Chloropropane) 2910 6- 44-5--------4 -Methylphenol 51621-6 4- 7--------N-Nitroso-di - N-propvl amine 3067-72-1---------Hexachloroethane 289 8 - 95- 3 ---------Nitrobenzene 307 8-59 -1--------- I sophorone 3283 -75-5---------2 -Nitrophenol 3310 5-67- 9--------2,4 - Dime thy lphenol 25111-91-1--------Bis (2 - chloroethoxy) methane 34120 - 33- 2 --------2,4 -Dichlorophenol 351 20- 82-1--------1,2,4 -Trichiorobenzene r?-J91 - 20-3---------Naphthalene 351 0 6 - 4 7 - 5 --------4 - Chloroani 1 ine 40
i 8 7 - 5 3 - 3 ---------Hexachiorobutadiene 341 5 9 -50 -7---------4 - Chloro - 3 - met hylphenol 37; 91-57-6---------2 -Methylnaphthalene 40I 77-47-4---------Hexachlorocyclopentadiene 30■ 88 - 06-2---------2,4,6 - Tri chlorophenol 40‘ 9 5- 95-4---------2,4,5 - Tri chlorophenol 5591-58-7---------2-Chloronaphthalene 33
• 33 -74 -4 ---------2-Nitroamlme 3 8131 - 11 - 3--------Dimethylphthalate 45
40208 - 96 - 8 --------Acenaphthylene 389 5-03-2---------3 - N11 roa n 111 ne 40
.8 3- 82-0---------Acenapnthene 40
FORM I SV 8270C
81b
FORM 1SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
CLIENT SAMPLE NO.
i1
Lab Name-. COMPUCHEM Contract:
Lab Code: LIBRTY Case No.: SAS No.:
Matrix: (soil/water) WATER
Sample wt/vol: 1000 (g/mL) ML
Level: (low/med) LOW
% Moisture: ______ decanted: (Y/N)
Concentrated Extract Volume: 1000(uL)
Injection Volume: 1.0(uL)
8270CMW-13BMSD
SDG No.: QE1877
Lab Sample ID: WG16228-4
Lab File ID: WG16228-4A60
Date Received: 03/08/02
Date Extracted:03/10/02
Date Analyzed: 03/13/02
Dilution Factor: 1.0
GPC Cleanup: (Y/N) N pH:
CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q
51-28-5---------2,4 -Dinitrophenol 20 J100- 02-7--------4 -Nitrophenol 21
1 121-14-2--------2,4-Dinitrotoluene 42: 132-64 - 9--------Dibenzofuran 4284-66-2---------Diet hylpht ha late 44
, 7005-72-3-------4 -Chlorophenyl-phenylether 43■ 86-73 -7---------Fluorene 41100-01-6--------4 -Nitroaniline 43
■ 534-52-1--------4,6 - Dmitro - 2 - me thy lphenol 4185-30-6---------N-Nitrosodi phenyl amine (1) 43101-55-3--------4 - Bromophenyl - phenyl etHer 46118-74-1--------Hexachlorobenzene 42
: 87- 86 - 5---------Pentachlorophenol 39; 85-01-8---------Phenanthrene 46120-12-7--------Anthracene 4886 -74 -8---------Carbazole 56
1 84 -74 -2 ---------Di-n-butylphthalate 46I 206 -44 - 0 --------Fluoranthene 51' 12 9 - 00- 0 --------Pvrene 46■ 8 5- 68-7---------Butyl be nzylpht ha late 4291-94-1---------3,3'- Dichlorobenzidine 24
| 117-81-7--------bis ( 2 - et hvl hexvl) Phthalate 44 B'< 56-55- 3 ---------Benzo (a) anthracene 51218-01-5--------Chrysene 50
■ 117-84-0--------Di - n -octyl phthalate 4 3205- 9 9- 2--------Benzo(b) fluoranthene 4 9207-03-S--------Benzol k) fluoranthene 48
, 50- 32-8---------Benzo ( a) pyrene 49193-3 5 - 5--------Indeno (1, 2 , 3 - cd) pyrene 46
1 5 2 - 70-3---------Dibenzo (a, h) anthracene 53191-24-2--------Benzo (g , n , i) perylene 54
(1)1 Cannoc be separated from DiphenylamineFORM fsv J 8270C
81b
Data Filet /chem/5972hp60* i/DF020313A60,fc'/UG16228-4A60*d
Date : 13-MAR-2002 14:33
Client ID: MW-13BHSD
Sample Info:
Volume Injected <uL): 1*0
Column phase: J&W BB-C,62C
Instrument: 5972hp60*i
Operator: 017
Column diameter: 0*32
oo
Data Fi let /chem/5972hp60. i/DF020313H0O.b/l-JGlF228-4fi60.d
Date : 13-MAR-2002 14:33
Client ID: MW-13BMSD Instrument; 5972hp6'
Sample Info:
Volume Injected (uL): 1.0 Operator: 917
Column phase: J8.W DB-C.625 Column diameter: 0
'O
—I
oo
Data File: /chem/5972hp60.i/DF020313A60.b/WG16228-4A60.dReport Date: 14-Mar-2030 09:46
CompuChem
Data file Lab Smp Id Inj Date Operator 1 Smp Info 'Misc Info Comment Method Meth Date Cal Date 'Als bottle Dil Factor Integrator Target Version: Processing Host
Semivolatile Report SW-846 Method 8270C /chem/5972hp60.i/DF020313A60.b/WG16228-4A60.d WG16228-4 Client Smp ID: MW-13BMSD13-MAR- 2 0 0 2 14:33917 Inst ID: 5972hp60.i
/chem/5972hp60.i/DF020313A60.b/8270Cv6.m14-Mar-2030 08:48 byrd Quant Type: ISTD
MAR-2002 17:20 Cal File: HLO20303A60.dQC Sample: MSD
0341.00000 HP RTE
3.50einstein
Compound Sublist: OLM03.sub
Concentration Formula: Amt * DF * Vt/(Vo * Vi) * CpndVariable
Name Value Description
DFVtVoVi
1.00000
1000.00000
1000 . 00000
1.00000
Dilution Factor Volume of final extract (uL) Volume of sample extracted (mL) Volume injected (uL)
Cpnd Variable Local Compound Variable
CONCENTRATIONS
J vUANT S1G ON-COLUMN FINAL
Tern pour, .is '|1
MASS RT EX? RT REL RT RESPONSE i NG) [ ug/L) SIMILARITY
1'. • '.i -i 9 . 1S4 9 i S "J ■; 1 . COO 1 102078 40.0000
* 2 Naphtha:ere - ' 1 r. 1 .'I i r> :c 3 o i !l . 0 0 0) 261671 40.0000
• Aoeraprtrerv-i:; : b4 ■ -> ■; c - -. i 7 a ' 1 . 0C0 1 216443 4 0.0000
4 Pnvrartrren-r-'i: ■ : s ? : 6 . 0 04 4 . 0 0 3 : 000 : 43575S 40.0000
; ■ i::: : 2 ;-3 3 2 2 ‘ ■ 4 3 coo ■ 514923 0000 .
•r
2 44 : 3. 2:' 21 3: = KiO ■ 437127 40 . 0000
. - - 2 • 74 ■ , 352397 : 1 7 . 720 117.7 (EM)
" - 9 2 7 2 4 26.933- 23 . 5 3
5 .■ N : ' : :■ v: ■; : - • . i 2 . 129222 34.5397 3 4 54
;■ ■ F - :■ .. . : . 2 1 : 2 ••• “ •• : 2 ■ V; C 7 1 4 25.5=7; 3 6 6 r
:• 3 •: : 4 . 7 - •: va; 1 01 . 229553 1 1C 723 112.7 1 n 1
; : - - : :: Oil: 639355 44.7303 4 4 7 9
7 421 50 1 1 . 3573 11 9 6
7 7 : - . " : . 0 0 4 ; 72233 25.7684 2 5.77
813
Data File: /chem/5972hp60.i/DF020313A60.b/WG16228-4A60.dReport Date: 14-Mar-2030 09:46
CONCENTRATIONS
QUANT SIG ON-COLUMN FINAL
Compounds MASS RT EXP RT REL RT RESPONSE ( NG) ( ug/L) SIMILARITY
18 2-Chloropnenoi 128 7.815 7.814 (0.958) 78569 28.3059 28 .31 904 6
15 1,3-Dichiorobenzene 146 8.052 8 . 051 (0 . 988) 99920 26.251S 26 .25
20 1.4-Dichiorobenzene 146 8.171 8.187 (1.0021 102851 27 . 1192 27 . 12
o o :.2 -Dichlorobenzene 14 6 8.424 8.423 (1.033) 96612 26.4646 26.46
-> 2-Methylphenol 1 0 5 3.594 5.610 {1.054) 75683 33.594 5 33 59
24 2.2' - envois . i - Cr. iorepropane ; 4 5 3.611 5.610 [1.056! 99606 28 . 7366 2S . 74 72 1 3
2 7 4 -Methy 1 phenol 10 3 5 . S 6 4 3.863 (I.067) 146947 51 . 3252 51 . 33
28 N -N it roso - d: - N propy lam i ne 70 8 830 8.929 \ 1 .083) 61820 29.7511 29.75 0
2 5 Hexachlor oethane 117 9.000 8.999 (1.104) 44797 27.6820 27.58 3964
3 U Nitrobenzene 77 5.118 9.117 (0 . 885) 97498 30.0400 30.04 9010
31 lsophorone 82 9 . 524 9.523 (0.924) 165164 32 . 3169 32 . 32 8 968
32 2-Nitroohenol 135 9.659 9 . 653 (0.938) 52575 32.8053 32.81 8852
■j 3 2,4-Dimethylphenol 122 9.744 9.760 (0.946) 48931 25.1630 25.16 8009
34 Bis(2 -chloroethoxy) methane 93 9 .896 9 . 895 (0.961) 104881 34 . 0852 34 . 09 7824
3 5 2,4 -Dichlorophenol 162 10.082 10.081 (0.979) 98930 34 . 54 96 34 . 55
36 1,2,4 -Tnchlorobenzene 180 10.218 10.217 (0.992) 112680 33 . 1456 33 . 15
37 Naphtha 1ene 128 10.353 10.352 (1.005) 269409 34 . 64 17 34 . 64 9030
3 8 4-Chlcroaniline 127 10.455 10.454 (1.015) 130693 39 . 8673 39.87 8679
35 Hexachiorobutadiene 2 2 S 10.556 10.572 (1 . 025) 89610 33 .7004 33 . 70 8417
4 -Chloro -?- methy1 oneno 1 107 11.317 11.316 (1.099) 88453 37 . 1585 37.16 9178
42 2 - Methy 1 naphthaiene 142 11.554 11.553 (1.122) 229266 39.5509 39.55
44 Hexach:orocyc1openc adiene 2 3 7 11.625 11.824 (0.684 ) 75797 30.4663 3 0.47 9244
156 12.062 12.061 '0.9011 95727 40.1721 40.17
2 , 4 , 3 - Tr : cr. 1 ore phene 1 15 6 12.129 12.145 '0.906: 142003 54 . 7391 54 . 74m 2 - Ch'.oronapntr.aiene 16 2 12 . 4 c c 12. 395 (0.927: 222561 33 .1569 33 . 16mm-. 2 - N: troan: 1 me 6 5 12.586 12.602 «'C .941) 98427 37.6548 37.65 6903
~ C' D: me t hy 1 pr.r :-a a t e i = ’ : 2 9 o c 12.9C7 '0.9651 397672 45 . 1298 45. 13 9725
-r. 2 . 5 - D: r : i rot i • tier.- 16 5 12.005 ■ i i - •0.972) 75276 40.0533 4 0.05 9016
A :er.ar.:'.: ny ; e:v.- 152 - -. : -j ^ • - ' ~i~ i 0 . 5 S 1 ) 407296 37 . 7272 37.73 3656
i :■ 3 -N :: roar.: mn 3 5 ■ • •: ■ S *J ■) C\ •0.595) 79195 39 . 7050 39.71 9104
r •; iE.y : ; . 11 r ' 1 . 0 0 4 : 251249 39.5718 39 . 57 8 94 7
: i is-; 1 ; . 5 •'; 0 -.3 s:-.' : . 00 5' 2 3 74 9 20.2052 20.21
r : o :■ i :■ 5 2 1 : . r 1 :. o20■ 34 364 21.4380 21.44 c
= 7 2 . 4 -Dm:: not t j .en-_- 13 7:' - : 7 16 1.02 5 117147 42 . 0835 4 2.0 8 374 2
2 r 165 : ,->bz : - . ^27 452502 4 1 . 7356 4 1.74 3 4 5 8
5 5 Diet ny 1 pm: r.a . ate 14 5 ; E ■ ■: i r- :• . 1'rV 423429 44 .4605 4 4.46 9108
4 - Ch : c r tphery ) -pm iemer 224 1 4 3 4-: :4 :;e : -.72• 2 2 2 6.7 4 42.34 85 42.35 736 3
Klvcrem :s; ■ 4. 4 - ■.4.345 : . 2 7 2 388383 4 1 . 214 5 41.21 7 3 30
: 1 C • 4 3 7'. ■ ■' 5 ; 2 : a 71 3 74 18 43.4846 4 3.48 8426
4 , 6- Dm: : no- 5 - me: ny 1 plieno 1 155 e y : 4 4 6 3 74 321 4 1 . 2159 4 1.22 Q i'.') »
N' ■ ■:: t rosed : pn.eny ! am: ::e 1 6 v : - ■ r -4 '• c; 2 i :•: :• 248063 42.7183 42.72 965S
_ *i z 1 5 . 2 ' r . . ... • 15. ■so:-7-: 45 . 9550 4 t . 9 6 .' -)..7 294 1 2 . :2 T : t - "EE 157668 42.4237 42.42 i' ' "i
2 5 : 1 ?• 5 r 2 . 4 2 7 } r, 39.277? 3 9 2C> 3 512
j| ' •. n z : • : ■; ■ ■ : 6 3 3 1 4 t 46.3259 4 6.33
' *71- ■ : • - : . "r- ■? 6 4 7 i 3 48.3155 48.32
6 “ : 4 :• • ; 2: 2 : 0 2 •; , 6 Q n 9 h c 56 . 3145 56 . 31 9 0 97
82 G
Data File: /chem/5972hp60.i/DF020313A60.b/WG16228-4A60.dReport Date: 14-Mar-2030 09:46
CONCENTRATIONS
ipounds
QUANT SIG
MASS RT EXP RT REL RT RESPONSE
ON-COLUMN
( NG)
FINAL
( ug/L) SIMILARITY
73 Di-n-butylphthalate 149 17.019 17.018 (1.063) 812536 45.5224 45.52 9236
74 Fluoranthene 202 18 . 152 18 . 151 (1.134) 812746 51.4723 51.47
16 Pyrene 202 18.541 18 . 557 (0.898) 848785 45.9424 45.94
11 Butylbenzylphthalate 14 9 19.641 19.657 (0.952) 400151 41 . 9420 41.94 5118
78 3,3'- Dichlorobenzidine 252 20.554 20.570 (0.996) 174886 24 . 0053 24 . 01 7628
79 bis (2-ecnylhexyl)Phthalate 149 20.605 20.604 (0.998) 588320 44.1522 44 . 15 8753
80 Bento(a)anthracene 228 20.622 20.621 (0.999) 941310 51 . 0678 51 . 07
81 Chrysene 228 20.673 20.672 (1 . 002) 831703 50.0652 50.07
32 Di-n-octylphtha late 149 21.586 21.585 (0.930) 938992 42 .6567 42.66
83 Benzo (b). £ luorant hene 252 22.398 22.414 (0.965) 929721 49 . 3191 49.32
8 4 Benzo (k'fluoranthene 252 22.449 22.465 (0.967) 812396 47.6640 47.66
95 Benzo(aipyrene 252 23.092 23 . 091 (0.995) 743238 49.2644 49.26
8 6 Indeno(1,2,3 - cd) pyrene 276 26 . 120 26 . 136 (1.125) 742359 46 . 1128 46.11 34 71
67 Dibenzo(a,h)anthracene 278 26 . 171 ' 26 . 187 (1 . 128) 735942 52.5199 52.52 8704
68 Benzo(g,h,i)peryiene . 276 27.017 27.033 (1.164) 732509 53 . 9947 53 . 99 7493
QC Flag Legend
a - Target compound detected but, quantitated amount Below Limit Of Quantitation(BLOQ).
R - Spike/Surrogate failed recovery limits.M - Compound response manually integrated.
82i
Data file: .•,chem-',5572hp60.1 /DF020313h60 . b/ldG16226-4A60. dInjection Date': 13-MAR-2002 14:33Instrument; 5972hp60.iClient Sample ID: MW-13BMSD
ii'und: 2-F liorpphenol 'bumper: 307-12-4
Ion 112.00: Area: 382397 Height: 31545ts
5.63 5.75 5.80 5.85 5.90 5.95 6.00 6.05 6.10 6.15 6.20 6.25 6.30 b. 35 6.40 6.45 6.50Min
Ion 64.00: Area: 0 Height: 0opmo
uj
R RR R I 5.80 5.8 Ci O . r'J b. 05 6.10 6.15 6.25 6.30 6.35 6.40 6.45 6.50
Ion 92.00: Hr-ea: Helgnt:
•iii
5.85 5.9',Min
6.25 6 o.35 6.4m 6.4' 6.506.10 6.15
cund: 2.4,b-Tr1bromopheno1 Number: lll8-79-b
Data File: •/chern/5972hp60. i/DF020313A60.b/WGl622B-4A60.dInjection Date|: 13-MAR-2002 14:33Instrument: 5972hp60.iClient Sample jlD: MW-13BM5D
1 ■
1 • 1-
Ion 329.60: Area: 229563 Height: 125934i&CDis.ri*-?
1-4.30 lU.35 1-4.-40 14.-45 14.50 14.55 14.60 14^65 14.70 14.75 14^80 14.85 14.90 14.95 15.00 15.05 15.10 15.15 15.20 15.25 'I________________________ Min
Ion 332.00: Area: Height:
1 - . ‘.K . 75 1-.40 1-.4C 1 4. =.r. 14.55 14.60 14.05 M.^o 14 . ?5 14.80 14.35 14.90 14.95 15.00 15.05 15.10 15.15 15.20 15.25I _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ M i r
Ion 141.0 heignr: n
Data File: .',chem/5972hp60 . 1 /DF020313A60 . b/UG16228-4A60 . dInjection Date': 13-MAR-2002 14:33Instrument: 5972hp60.1Client Sample ID: MU-13BMSD
,ound: mbe
N-Ultroei•: 621-64
di-N-propyl amine
4.2'
3.9-
3.6-
3.3-'
3.0-
Ion 70.00 rea 61820
rtlCD
IS
Height 42046
1
4 . J
8. JO 6.45 6.50 8.55 8.60 8.65 8.70 8.75 8.80 8.85 8.90 8.95 9.00 9.05 9.10 9.15 9.20 9.25 9.30______________________________________________ M i n___________________________________________________________
Ion 130.00: Area: 0 Height: 0
iT.i*Js
CD
6 . J? 6.50 6. t-5 8.60 5.65 6.70 8.75 8.80 5.65 8.90 6.95 9.00 9.05 9.10 9.15 9.20 9.25 9.30 * I_______________ M i r. __________________________________________________________________________
I on. 4~.00: Ar-e=>: 0 Hei^nt; ij
•l:o
3. SO 8.85 8.90 3.95 0.00 9.05 9.10 9.15 . 20 y.,j5 9.30M i n
Data File: /chem '5?72hp60. 1 /DF02C313h60. b.'WGl6228“4M60.dInjection Date: 13-MhF:-2002 14:33Instrument: 5972np60.1Client Sample ID: MU-13BMSD
puna: Plumber
4-Nit ropnenol
Ion 109.00: Area: 34364 Height: 15714cuip
n
13.35 13.40 13.45 13.50 13.55 13.60 13.65 13.70 13.75 13.80 13.65 13.90 13.95 14.00 14.05 14.10Min
Ion 65.00: Area: Height:
.40 13.45 13.50 1 o.55 Ij.60 !o.65 13.70 13.75 13.80 13.85 13.90 13.95 14.00 14.05 14. K run
I
82 o
5 13.50 13.55 13.60 13.65 13.70 13.75 1 3 1 30 13.85 13.90 13.95 14.00 14.05 14 ’. l 0
Min
CompuChema Division1 of Liberty Analytical Corp.
GC/MS SEMI-VOA WORKSHEET
LAB INSTRUCTIONS: QE1877-12 FOR QC
RECEIPT1 DATE: 3/8/02 0:00 SAMPLE DATE: DUE DATE:
CASE#: ! SDG: WG16228 COMPUCHEM#: WG16228-4
CLIENT ID: MW-13BMSD
ANALYSIS DESCRIPTION: SVOA-8270C
Injection Volume :1.0pL Dilution Prep (if needed)
Extraction Date___3___/10____/__02
DFTPP Filename DF0203 / J ,A £ 0
Sample File Name___U/Y-T / / / ^ 5T - w A S6'
ANALYST (S): Injection"I / 1_________________ Work-up
GC/MS DATE REVIEW
CONDITION CODE
Extraneous Peak Search Results:
Number of peaks found: r-'fi'
Number o^f Hits found:
Number of Surrogate Outliers:
Oualit> Assurance Notice (s) Number of Notices Required (P
Disposition: y ] Complete
[ ] Reinjection Required
f ] Re-extraction Required
[ ] Reinject Neat
[ ] Dilute ( X)
Comments: A J1 w-s VL Cuvr^.-J* S l-yc i
Us, > ■
-GC/MS ReviewDate A /V A ud itorDate//
Final Reportable Package! s):
;(P C- /£ 2 xf-iy/ZCO
82o
SVI -6/27/01: PTF