620415 - international nuclear information system (inis)

0 7 1997 ENGINEERING DATA TRANSMITTAL of t

620415

2. To: (Rece

Dv ing Organizat ion)

istribution

5. Proj./Prog./Dept./Div.:

Tank 241-T-201/WasteManagement/PPC/AS8 . Or

Thissyst

1 1 . R«

For

3. From: (Originating Organization)

Production Planningand Control

6. Design Au tho r i t y / Design Agent/Cog.Engr. :

Jennifer L. Nuzum

g ina to r Remarks:

document is being released into the supporting documentera for re t r ievab i l i ty purposes.

ce iver Remarks: 11A. Design Baseline Document? [ J Yes [ X ] No

release.

15. DATA TRANSMITTED(A)

itemNo.

1

IB) Document/Drawing No.

HNF-SD-WM-DP-254

(C)SheetNo.

N/A

(D)Rev.No.

0

(E) Title or Description of DataTransmitted

Tank 241-T-201, Core192 AnalyticalResults for the FinalReport

4 . Related EDT No.:

N/A

7. Purchase Order No. :

N/A

9. Equip./Component No. :

N/A10. System/Bldg./Facility:

241-T-20112. Major Assm. Dwg. No. :

N/A13. Permit/Permit Application No.:

N/A14. Required Response Date:

08/07/97<F>

ApprovalDesig-nator

Q

(G)Reason

forTrans-mittal

2

(H>Origi-nator

Dispo-sition

1

(»Receiv-

erDispo-sition

1

16. KEY

Approval Designator [Pi

E. S. Q. D or N/A(see WHC-CM-3-5.See.12.7)

Reason tor Transmittal (G)

1. Approval 4. Review2. Release 5. Post-Review3. Information 6. Dist. (Receipt Acknow. Required)

(G)Raa-son

222

(H)Oisp.

111

Disposition (H) & (I)

1. Approved 4. Reviewed no/comment2. Approved w/comment S. Reviewed w/comment3. Disapproved w/comment 6. Receipt acknowledged

17. SIGNATURE/DISTRIBUTIONSee Approval Designator for required signatures)

(J) Name (K) Signature (L) Date (M) MSIN

Design Authori ty

Design Agent

Cog.Eng. J , L. Nuzui^p^^yU^i i^ i^1"*—~<?/u/<i"

Cog. Mgr. A. D. R i c e ^ / ^ ^ ^ ^fi~~ < f - ^ ^ * 7

Oft T. L. Tung ^ ^ ^ J ? r / ^ — ^ # / ^ / f ?

Safety

Env.

18.

Signature of EOT DafcOriginator

19.

N/A

Authorized Representative Date ^for Receiving Organization

(G)Rea-

(H)Disp. (J) Name (K) Signature (L) Date (M) MSIN

20.

A. rXJtice-^

Design Authority/ DateCognizant Manager

2 1 . DOE APPROVAL ( i f requiC t r l . No.

[3 Approved[] Approved w/comments[] Disapproved w/corrments

red)

BD-7400-172-2 CQ5/96) GEF097

B0-7400-17M

HNF-SD-WM-DP-254, Rev. 0

Tank 241-T-201, Core 192 Analytical Results forthe Final Report

Jennifer L. NuzumWaste Management of Hanford, Inc., Richland, WA 99352U.S. Department of Energy Contract DE-AC06-96RL13200

UC: 2070Charge Code: HD378Total Pages:

EDT/ECN: EDT-620415Org Code: 7576BB&R Code: EW 3120074

Key Words: Tank 241-T-201, 241-T-102, T-201, Core 192, AnalyticalResults, Final Report

Abstract: N/A

TRADEMARK DISCLAIMER. Reference herein to any specific commercial product, process, or service bytrade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply itsendorsement, recommendation, or favoring by the United States Government or any agency thereof orits contractors or subcontractors.

Printed in the United States of America. To obtain copies of this document, contact: DocumentControl Services, P.O. Box 950, Mailstop H6-08, Richland WA 99352, Phone <509> 372-2420;Fax <509) 376-4989.

DATE:

sjl Approval/

/ pate Release Stamp

Approved for Public Release

A-6400-073 (01/97) GEF321

HNF-SD-WM-DP-254, REV. 0

ANALYTICAL SERVICES

TANK 241-T-201, CORE 192ANALYTICAL RESULTS FOR THE FINAL REPORT

Project Coordinator: JENNIFER L. NUZUH

Prepared for the U.S. Department of EnergyOffice of Environmental Restoration

and Haste Management

by

222-S LaboratoryHaste Management of Hanford, Inc.

P.O. Box 700Rich!and, Washington


THIS PAGE INTENTIONALLY LEFT BLANK

ii


TABLE OF CONTENTS

Narrative 1

T-201 Sample Breakdown (Attachment 1) , 13

Sample Data Summary 26

Chain of Custody Forms 52

Photographs 63

Composite Worksheets 74

Sample Handling 82

Extrusion Worklist # 17770 (680) 84Extrusion Worklist # 17771 (681) 85Extrusion Worklist # 17772 (682) 86Extrusion Worklist # 17861 (691) 87Extrusion Worklist # 17862 (687) 88Extrusion Worklist # 17863 (688) 89Extrusion Worklist # 17864 (690) 90Extrusion Worklist # 17865 (692) 91Extrusion Worklist # 17866 (689) 92

Sample Preparations 93

Fusion Digest Worklist # 18077 (901, 919, 921) 95Fusion Digest Worklist # 18078 (920, 922, 923) 96Fusion Digest Worklist # 18531 (1248, 1255) 97Fusion Digest Worklist # 19308 (1753, 1754) 98

H20 Digest Worklist # 18079 (900, 915, 931) 99H20 Digest Worklist # 18081 (916, 917, 918) 100H20 Digest Worklist # 18534 (1251, 1257) 101

Acid Digest Worklist # 18533 (1250, 1256) 102

Acid Digest Worklist # 19175 (1250, 1256) 103

Bulk Density Worksheets 104

Inorganic Analysis Ill

Differential Scanning Calorimetry (DSC)DSC Worklist # 18271 (823) 113DSC Worklist # 18272 (834, 835) 120DSC Worklist # 18273 (836, 837) 127DSC Worklist # 18278 (899, 909) 135

iii


TABLE OF CONTENTS (Continued)

DSC Worklist # 18279 (910, 911) 141DSC Worklist # 18280 (912, 913) 148DSC Worklist # 18438 (796) 156DSC Worklist # 18439 (802, 803, 804, 805, 806, 807, 808, 809, 810,

811) 157DSC Worklist # 18621 (823, 833, 834, 835, 836, 837) 159DSC Worklist # 18622 (899, 909, 910, 911, 912, 913) 160DSC Worklist # 18915 (1246, 1253) 161DSC Worklist # 19452 (1246, 1253) 168

Thermogravimetric Analysis (TGA)TGA Worklist # 18274 (823, 833) 169TGA Worklist # 18275 (834, 835) 176TGA Worklist # 18276 (836, 837) 184TGA Worklist # 18281 (899, 909) 192TGA Worklist # 18282 (910, 911) 198TGA Worklist # 18283 (912, 913) 205TGA Worklist # 18906 (1246, 1253) 213

Specific Gravity Analysis (SpG)SpG Worklist # 18277 (823, 933, 834, 835, 836, 837) 220

Ion Chromatography (IC)IC Worklist # 18268 (1242, 1203) 229IC Worklist # 18269 (834, 835) 239IC Worklist # 18270 (836, 837) 248IC Worklist # 18311 (900, 915, 931) 258IC Worklist # 18312 (916, 917, 918) 270IC Worklist # 19089 (1251, 1257) . 283

Inductively Coupled Plasma Spectrophotometer (ICP)ICP Worklist # 18330 (823, 834, 835, 836, 837) 293ICP Worklist # 18367 (901, 919, 921, 920, 922, 923) 302ICP Worklist # 18589 (1203) 311ICP Worklist # 19341 (1250, 1256) 328

Total Inorganic / Total Organic (TICTOC)

TICTOC Worklist # 18896 (1246, 1253) . 336

Radiochemical Analysis 364

Total Alpha (AT)AT Worklist # 18267 (836, 837) 366AT Worklist # 18294 (901, 919) 374AT Worklist # 18295 (920) 382AT Worklist # 18364 (834, 1203) 389AT Worklist # 18444 (1242, 1259) 399

iv

HNF-SD-WH-DP-254, REV. 0

TABLE OF CONTENTS (Continued)

Gamma Energy Analysis (GEA)GEA Worklist # 19373 (1753, 1754) 407

Strontium 89/90 Analysis (Sr90)Sr90 Worklist #19370 (1753, 1754 434Sr90 Worklist # 19554 (1754) 444

This Document consists of pages 1 through 450. Pages ii, 2, 14, 27, 53, 64,75, 83, 94, 105, 112 and 365 were intentionally left blank.

TRADEMARKS:

Perkin-Elmer is a Registered Trademark of Research and Manufacturing Company,Inc. Mettler is a Registered Trademark of Mettler Electronics.


NARRATIVE

HNF-SO-WM-DP-254, REV. 0



222-S ANALYTICAL SERVICES

TANK 241-T-201, CORE 192,ANALYTICAL RESULTS FOR THE FINAL REPORT

This document is the final laboratory report for Tank 241-T-201. Push mode core segments wereremoved from Riser 3 between April 24, 1997, and April 25, 1997. Segments were received andextruded at 222-S Laboratory. Analyses were performed in accordance with Tank 241-T-201PushMode Core Sampling and Analysis Plan (TSAP) (Hu, 1997), Letter of Instruction for CoreSample Analysis of Tanks 241-T-201, 241-T-202, 241-T-203, and 241-T-204 (LOI) (Bell, 1997),Additional Core Composite Sample from Drainable Liquid Samples for Tank 241-T-201 (ACC)(Hall, 1997), and Safety Screening Data Quality Objective (DQO) (Dukelow, et al., 1995).

None of the subsamples submitted for total alpha activity (AT) or differential scanning calorimetry(DSC) analyses exceeded the notification limits stated in DQO. The statistical results of the 95%confidence interval on the mean calculations are provided by the Tank Waste RemediationSystems Technical Basis Group, and are not considered in this report.

Appearance and Sample Handling

One core of eight segments was expected from Tank 241-T-204. One core (Core 192) of eightsegments was obtained.

Attachment 1 illustrates subsamples generated in the laboratory for analysis and identifies theirsources. This reference also relates tank farm identification numbers to their corresponding222-S Laboratory sample numbers.

Core 192

Segments were removed from Tank 241-T-201, Riser 3, between April 24, 1997, and April 25,1997. All segments were received by 222-S Laboratory between April 25, 1997, and April 29,1997. Table 1 summarizes extrusion information.

Field Blank

A field blank was provided to 222-S Laboratory with Core 192. This sample was treated as adrainable liquid in accordance with TSAP.


Hydrostatic Head Fluid Blank

There was no indication of the use of hydrostatic head fluid (HHF) in sampling, nor a HHF blankprovided to 222-S Laboratory.

Core Composite

Two core composites were made from Core 192. A core composite was made from solidsegments 6-8 of Core 192 in accordance with LOI. Segments 2-5 consisted of drainable liquidmaterial with settled solids. A second core composite was made from the solid part of thesesamples in accordance with ACC. Core composite worksheets are included in this document.


Table 1. Sample Receipt and Extrusion Information for T-201, Core 188.

t IJfc - '1"

FieldBlank

192-01

192-02

192-03

192-04

192-05

192-06

192-07

192-08

. v 4 , -

FieldBlank

1

2

3

4

5

6

7

8

1' .- 1 ( > . . 1 !>.* i j < - f i< . t J t n -i

4/25/97

4/24/97

4/24/97

4/24/97

4/24/97

4/25/97

4/25/97

4/25/97

4/25/97

4/29/97

4/29/97

4/25/97

4/25/97

4/25/97

4/29/97

4/29/97

4/29/97

4/29/97

5/6/97

5/6/97

5/6/97

5/6/97

5/6/97

5/6/97

5/8/97

5/8/97

5/8/97

1 ',-

0.0

0.0

0.0

0.0

0.0

0.0

19.0

19.0

19.0

1 . JIt. , • o •>

248.6

268.6

248.2

280.4

252.0

272.9

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

198.3-LowerHalf177.9-UpperHalf

I87.5-LowerHalf200.3-UpperHalf

166.9-LowerHalf208.7-UpperHatf

V . t i l

Drainable liquid was clear and colorless with no organic layer.

Diainable liquid was pale yellow and slightly cloudy. No organic layer.

Drainable liquid was black and opaque. No organic layer. Settled blacksolid material was present in the collection jar after sitting several hours.

Drainable liquid was black and opaque. No organic layer. Settled blacksolid material was present in the collection jar after sitting several houre.



Solids were black and resembled a wet sludge.



* Approximate Inches Extruded


Analytical Results Summary

The Data Summary Table (Table 2) included in this report compiles analytical results associatedwith each subsample submitted in accordance with TSAP, LOI, and DQO.

Liquid subsamples prepared for analysis by an acid adjustment of the direct subsample areindicated by a "D" in the A# column of Table 2. Solid subsamples prepared for analysis byperforming a fusion digest are indicated by a "F" in the A# column of Table 2. Solid subsamplesprepared for analysis by performing a water digest are indicated by a"W" in the A# column ofTable 2. Solid subsamples prepared for analysis by performing an acid digest are indicated by an"A" in the A# column of Table 2.

Inorganic Analyses

Differential Scanning Calorimetry (DSC) Analysis

DSC analysis was performed on all direct subsamples. The exothermic energy based on dryweight of subsample was calculated for all subsamples. The average of the thermogravimetricanalysis (TGA) results for each subsamplewas used in the dry weight correction for thatsubsample.

DSC analysis results for all subsamples submitted were 0.00 Joules/g. There were no exceptionsto the quality control (QC) parameters stated in TSAP for these subsamples, nor any resultsexceeding the notification limits as stated in TSAP.

Thermogravimetric Analysis (TGA)

TGA was performed on all direct subsamples. TGA results were typically determined bysumming weight loss steps below 200°C. Weight loss steps above this were not used todetermine the result. More information may be obtained by examining the raw data. There wereno exceptions to the QC parameters stated in TSAP for these subsamples.

Density

Bulk density was performed on solid lower half segments and the core composites. Results frombulk density tests ranged from 1.13 g/mL to 1.39 g/mL. There were no QC parameters stated inTSAP for bulk density analysis.


Specific Gravity (SpG)

Specific gravity analyses were performed on direct liquid subsamples. There were no exceptionsto the QC parameters stated in TSAP for these subsamples.

Ion Chromatography (IC)

IC analysis was performed on direct liquid subsamples, solid subsamples and the core composites.For all subsamples save the core composites, only the QC for Br was reviewed for this report inaccordance with TSAP. There were no exceptions to the QC parameters stated in TSAP forthese subsamples.

For the core composite, only the QC for requested analytes (F, Cl, NO2> NO3, SO4, PO4, andOxalate) were reviewed for this report in accordance with LOI. Other opportunistic analyteresults are included in Table 2. These analytes do not have customer defined QC parameters andare not discussed.

Core Composite Sample S97T001251 had a relative percent difference (RPD) between sampleand duplicate of 34.8 for PO4 This elevated RPD is due to sample heterogeneity. Furtheranalysis was not requested.

The preparation blank for the core composites showed Cl and NO3 results above the detectionlevel. The levels of these analytes in the preparation blank are inconsequential when compared toresults for the sample, and do not impact sample data quality. A matrix spike was not performedon either core composite sample. At this time, the IC instrument is out of service. If furtheranalysis is requested, the results will be presented in a revision to this document.

Inductively Coupled Plasma Spectrophotometry (ICP)

ICP was performed on direct liquid subsamples, solid subsamples, and the core composites. Forall subsamples save the core composites, only the QC for Li was reviewed for this report inaccordance with TSAP. There were no exceptions to the QC parameters stated in TSAP forthese subsamples.

For core composite samples, only the QC for requested analytes (Al, Ba, Bi, Ca, Cr, Fe, La, Mn,Ni, P, K, Si, S, Na, Sr, and U) were reviewed for this report in accordance with LOI. Otheropportunistic analyte results are included in Table 2. These analytes do not have customerdefined QC parameters and are not discussed.


Core Composite Sample S97T001250 showed a RPD between sample and duplicate of 21.3,21.3,27.8, and 21.5 for analytes La, P, S, and Sr, respectively. RPD was caused by sampleheterogeneity and further analysis was not requested. In addition, spike recoveries reported inTable 2 for Bi, Ca, Cr, Fe, K, La, Mn, Na, P, Si, and Sr are invalid because the spikeconcentration (1 ppm) is too low in comparison to the sample concentration (less than 25%).Post spikes with an analyte level of 10 ppm were performed, and the resulting spike recoverieswere 97.3%, 103.2%, 100.8%, 94.1%, 100.5%, 101.5%, 102.5%, 100.6%, 99.8%, 101.5%, and99.7%, respectively. These calculations can be found in the raw data.

Core Composite Sample S97T001256 spike recoveries reported in Table 2 for Bi, Cr, Fe, K, La,Mn, and Na are invalid because the spike concentration (1 ppm) is too low in comparison to thesample concentration (less than 25%). Post spikes with an analyte level of 10 ppm wereperformed, and the resulting spike recoveries were 98.6%, 99.7%, 93.3%, 99.6%, 100.0%,100.2%, and 96.9%, respectively. These calculations can be found in the raw data.

The preparation blank for the core composites showed Ca, Na, and Si results above the detectionlevel. The levels of these analytes in the preparation blank are inconsequential when compared tothe results for the sample, and do not impact sample data quality.

Total Organic Carbon (TOC)

TOC analysis was performed on core composite subsamples. RPD between sample and duplicatewas 34.6 for the subsample S97T001253. Elevated RPD is due to inhomogeneity betweensample and duplicate. Further analysis was not requested.

Total Inorganic Carbon (TIC)

TIC analysis was performed on core composite subsamples. There were no exception to the QCparameters stated in LOI for these samples.

For all TIC analyses, a "Total Inorganic Carbon Analysis Report" worksheet is included as rawdata. Due to programming limitations with the TIC instrument software, the sample size listed onthis worksheet is incorrect. This value is not used in the final calculations (also included) and hasno bearing on the results in Table 2.


Radiochemistry Analyses

Total Alpha (AT) Analysis

AT analyses were requested for direct liquid subsamples and solid lower half segments. Allresults were below the total alpha activity notification limits.

Spike recovery for Drainable Liquid Segment 1 (S97T001203) was 62.3%. This low spikerecovery was consistent with the original analysis, and was caused by sample matrix interference.Rerun analysis was not requested.

Two of the preparation blanks showed AT results above the detection level. The level in thepreparation blank is inconsequential when considering the elevated counting error, and does notimpact sample data quality.

Gamma Energy Analysis (GEA)

GEA was performed on core composite subsamples. There were no exceptions to the QCparameters stated in LOI for these subsamples.

Strontium 90 (90Sr)

""Sr analysis was performed on core composite subsamples. RPD between sample and duplicatewas 124.0 for Sample S97T001754. Activity levels and RPD were consistent with previousanalyses. The preparation blank showed MSr results above the detection level. The level in thepreparation blank is inconsequential when considering the high counting error, and does notimpact sample data quality. Further reran analysis was not requested.


Procedures

Table 3 lists the analytical procedures used for performing sample analyses. Abbreviations foranalyses are defined in the table notes.

Table 3. Analytical Procedures

DSC

TGA

Bulk Density

AT

Sp.G

IC

ICP

TOC

Matrix

SolidLiquid

SolidLiquid

Solid

LiquidSolid

Liquid

LiquidSolid

LiquidSolid

Solid

Preparation1'inceilure

N/A

N/A

N/A

N/A+LA-549-141 Rev. F-0

N/A

N/A++LA-504-101RevF-0

N/A+++LA-505-163RevA-0

+LA-549-141 Rev F-0

N/A

•SlKllVM'v

l'» orrihire

LA-514-114 Rev. D-0 & D-l

LA-514-114 Rev. D-0 & D-l

LO-160-103 Rev. C-0

LA-508-101 Rev. G-0

LA-510-112Rev.D-l

LA-533-105 Rev. D-l

LA-505-151,Rev.E-lLA-505-161 Rev. C-l

LA-342-100 Rev. E-0

10


TIC

GEA

90Sr

Solid

Solid

Solid

N/A

+LA-549-141 Rev. F-0

+LA-549-141 Rev. F-0

LA-342-100 Rev. E-0

LA-548-121 Rev. F-0

LA-220-101 Rev. E-l

Notes:

N/ADSCTGAATSp.GICICPTOCTICGEA90Sr

++++++

not applicable (these are direct samples)differential scanning calorimetrythermogravimetric analysistotal alphaspecific gravityion chromatographyinductively coupled plasmatotal organic carbontotal inorganic carbongamma energy analysisstrontium 90

fusion digestwater digestacid digest

11


References

Dukelow, G. T., I W. Hunt, H. Babad, and J. E. Meacham, 1995, Tank Safety Screening DataQuality Objective, WHC-SD-WM-SP-004, Rev. 2, Westinghouse Hanford Company,Richland, WA 99352.

Hu, T.A., 1997, Tank 241-T-201 PushMode Core Sampling andAnalysis Plan,HNF-SD-WM-TSAP-130, Rev. 0, Lockheed Martin Hanford Corporation, Richland, WA99352.

Bell, K.E., 1997, Letter of Instruction for Core Sample Analysis of Tanks 241-T-201, 241-T-202,24J-T-203, and 241-T-204, Memo 74620-97-195, Lockheed Martin HanfordCorporation, Richland, WA 99352.

Hall, KM., 1997 Additional Core Composite Sample from Drainable Liquid Samples for Tank241-T-201, Memo 74620-97-199, Lockheed Martin Hanford Corporation, Richland, WA99352

Meznarich, H. K., 1995, Quality Assurance Plan for the 222-S Laboratories, WHC-SD-CP-QAPP-016, Rev. 0, Westinghouse Hanford Company, Richland, WA 99352.

12


T-201 SAMPLE BREAKDOWN (ATTACHMENT 1)

13



14

T-201Core:192Seg: Field BlankS97T000690

Attachment 1

DrainableLiquid

S97T000822

O1 S97T000823

S97T001242

S97T000824

71CO

9

oT3

33

T-201Core:192Seg: 1 (192-01)S97T000691

Attachment 1

DrainableLiquid

S97T000825

SSK!11 gg™»sra-oi TGA'1"

S97T000833

S97T001203

S97T000838

-pCO

9

33m

T-201Core:192Seg: 2 (192-02)S97T000680

Attachment 1

(£5=2,

DrainableLiquid

S97T000826

S97T000834 S97T000839

iCO

9

33

m

T-201Core:192Seg: 3 (192-03)S97T000681

Attachment 1

DrainableLiquid

S97T000827

QB.

S97T000835

S97T001259

S97T000840

03

a

6

sJO

m

o

T-201Core: 192Seg: 4 (192-04)S97T000682

Attachment 1

DrainableLiquid

S97T000828

S97T000836 S97T000841

i71

COI6

JO

o

1-201Core;192Seg: 5 (192-05)S97T000687

Attachment 1

DrainableLiquid

S97T000829

o

S97T000837 S97T000842

s9

o

33

o

T-201Core: 192Seg: 6 (192-06)S97T000688

Attachment 1

UpperHalf

LowerHalf

S97T000897 S97T000894

S97T000909

S97T000921

OOSE-01SAMPAMT1DSC-01DSC-02

S97T000904 S97T000899

FUSION01OOSE-02©ICP-F01©ALPHA01

S97T000931 S97T000901

S97T000898

S97T000900

T l

CO

a

a•u

3Jm

T-201Core:192Seg: 7 (192-07)S97T000692

Attachment 1

Upper

HalfLower

Half

S97T000902 S97T000895

W. OOSE-01SAM PAH T1OSC-01OSC-02TGA-01

S97T000911

FUSION01DOSE-02©ICP-F01

S97T000922

DOSE-01SAMPAMT1DSC-01DSC-02

S97T000906 S97T000910

FUS10N01DOSE-02©iCP-FOl@ALPHA01

S97T000916 S97T000919

S97T000905

H20DIG01 ^OOSE-02 T leic-oi ^

S97T000915

O-a

m

T-201Core:192Seg: 8 (192-08)S97T000689

Upper

HalfLowerHalf

S97T000903 S97T000896

tODOSE-01SAMPAMT1DSC-01DSC-02

S97T000913 S97T000908 S97T000912 S97T000907

FU9ON01DOSE-02@ICP-F016WLPHA01

S97T000923 S97T000918 S97T000920

K20DIG01DOSE-02©IC-01

S97T000917 7>

8i

m

o

Composited:

Segment: Grams;1 DL 0,02 DL 8,43 DL4 DL5 DL

15.717.330.S

T-201Core:192Composite:Drainable LiquidSegments 1-5

Attachment 1

S97T001252

S97T001253

FUSION01@GEVO2©SR90-01

S97T001754

S97T001254

S97T001256 S97T001257

7!COO

T3

33m

mM®

liiiiililliiSJ!!•

mmmiililliai!

•iiffliSiii

mi

iili

li

IlUillfHilii!

iiilliiiSiiiiiHSii!!

iJ:jj::;U::i::':.:;;;::::ii::.:.:.:.:

mmmm

iiHIl!

•III!iiiijiSiQii:

iiililHii:

jiiii

Si!!!!

ill!!!!:!!!

liliiliiili

ill!!!]!!!!

T-201Core: 192Composite: SolidSegments 6-8

Attachment 1

S97T001245

SAHPAHT1OOSE-01OSC-01

S97T001246

S97T001753

S97T001247

ACIOIGOI©KP-A01DOSE-02

S97T001250

H2ODIG01

DOSE-02

S97T001251


SAMPLE DATA SUMMARY


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HNF-SD-Wy-DP-254, REV. 0

'SS

•4-aug-1997 14:13:49•.-0002-1

Page:

CORE NUMBER: 192SEGMENT #: 1

Table 2. Data Summary TableT-201

SEGMENT PORTION: Drainable Liquid

Sample# RS97T000833S97T000833S97T000833S97T000833S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203S97T001203

A#

DDD

aDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDDD

AnalyteDSC Exotherm Dry CalculatedDSC Exotherm on Perkin ElmerSpecific Gravity% Water by TGA on Perkin ElmerSilver-ICP-Acid Dil.Alumimum-ICP-Acid Dil.Arsenic-ICP-Acid Dil.Boron-ICP-Acid Dil.Barium-ICP-Acid Dil.Beryllium-ICP-Acid Dil.Bismuth-ICP-Acid Dil.Calcium-ICP-Acid Dil.Cadmium-ICP-Acid Dil.Cerium-ICP-Acid Dil.Cobalt-ICP-Acid Dil.Chromium-ICP-Acid Dil.Copper-ICP-Acid Dil.Iron-ICP-Acid Dil.Potassium-ICP-Acid Dil.Lanthanum-ICP-Acid Dil.Lithium-ICP-Acid Dil.Magnesium-ICP-Acid Dil.Manqanese-ICP-Acid Dil.Molybdenum-ICP-Acid Dil.Sodium-ICP-Acid Dil.Neodymium-ICP-Acid Dil.Nickel-ICP-Acid Dil.Phosphorus-ICP-Acid Dil.Lead-ICP-Acid Dil.Sulfur-ICP-Acid Dil.Antimony-ICP-Acid Dil.Silicon-ICP-Acid Dil.Samarium-ICP-Acid Dil.Strontium-ICP-Acid Dil.Titanium-ICP-Acid Dil.Thallium-ICP-Acid Dil.Uranium-ICP-Acid Dil.Vanadium-ICP-Acid Dil.Zinc-ICP-Acid Dil.Zirconium-ICP-Acid Dil.Fluoride-IC-Dionex 4000/4500Chloride-IC-Dionex 4000/4500Nitrite-IC - Dionex 4000/4500Bromide by Ion Chromatoqraph

UnitJoules/g DryJoules/qSp.G.'/.ug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mL

Standard %n/a

96.0699.8299.4199.0096.6099.40100.298.00100.299.6095.6096.8093.6098.4094.40103.896.6097.6098.0097.4092.2096.4097.80101.6104.296.20100.096.0095.2093.2097.00101.697.8095.8099.2098.6099.6099.8097.8092.3798.35101.3101.2

Blankn/an/an/an/a

<1.00e-02<5.00e-02<1.00e-01<5.00e-02<5.00e-02<5.00e-03<1.00e-01<1.00e-01<5.00e-03<1.00e-01<2.00e-02<1.00e-02<1.00e-02<5.00e-02<5.00e-01<5.00e-02<1.00e-02<1.00e-01<1.00e-02<5.00e-02<1.00e-01<1.00e-01<2.00e-02<2.00e-01<1.00e-01<1.00e-018.70e-02<5.00e-02<1.00e-01<1.00e-02<1.00e-02<2.00e-01<5.00e-01<5.00e-02<1.00e-02<1.00e-02<1.20e-02<1.70e-02<1.08e-01<1.25e-01

Result0.00e+000.00e+00

1.05591.10

< 2.010< 10.10< 20.10< 10.10< 10.10< 1.010< 20.10< 20.10< 1.010< 20.10

7.0406.730

< 2.010< 10.104.30e+03< 10.10< 2.010< 20.10< 2.010< 10.102.66e+04< 20.10< 4.0202.44e+02< 20.10

37.30< 12.10

37.70< 20.10< 2.010< 2.010< 40.20<1.00e+02< 10.10< 2.010< 2.0104.18e+039.41e+023.10e+02<2.65e+02

Duplicate0.00e+000.00e+00

1.05490.95

<2.01e0<1.01e<2.01e<1.01e<1.01e<1.01e<2.01e<2.01e

J

<1.01e0<2.01e17.1606.790

<2.O1eO<1.01e1

4.26e+03<1.01e1<2.01e0<2.01e1<2.01e0<1.01e12.62e+04<2.01e1<4.02e0247.0

<2.01e137.0023.7044.20

<2.01e12.01e02.01e04.02e11.00e21.01 el2.01e02.01e0

4.24e+03989.0312.0

<2.65e2

Average0.00e+000.00e+00

1.05491.03n/an/an/an/an/an/an/anyan/an/a

7.1006.760n/an/a

4.28e+03n/an/an/an/an/a

2.64e+04n/an/a

245.5n/a

37.15n/a

40.95n/an/an/an/an/an/an/an/a

4.21e+03964.9311.1

n/a

RPD %0.000.000.090.16n/an/an/an/an/an/an/an/an/an/a1.690.89n/an/a0.93n/an/an/an/an/a1.52n/an/a1.22n/a0.81n/a15.9n/an/an/an/an/an/an/an/a1.434.970.64

n/a

Spk Rec %n/an/an/an/a

43.1095.00103.0101.098.7099.50102.096.0097.6095.50101.095.80104.093.60

-7.220e099.5095.0093.7097.9099.80

-4.740e2103.097.10104.095.2097.90107.0111.0102.099.5096.8098.9098.00101.0102.099.3097.29106.296.5193.04

Det Limitn/an/a

1.00e-02n/a

2.01010.1020.1010.1010.101.01020.1020.101.01020.104.0202.0102.01010.10100.010.102.01020.102.01010.1020.1020.104.02040.2020.1020.1012.1010.1020.102.0102.01040.20100.010.102.0102.01025.4536.06229.1265.1

Count ErrXn/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/a

4-aug-1997 14:14:21-0002-1


Page:



Sample# RS97T000834.S97TO00S34S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834

S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834S97T000834

A#

DDD0DDD

DDDDDDD0DD0»0

aDDDDDDDDDDDDDDD

AnalyteDSC Exotherm Dry CalculatedDSC Exotherm on Perkin ElmerSpecific Gravity% Water by TGA on Perkin ElmerSilver-ICP-Acid Dil.Aluminium-ICP-Acid Dil.Arsenic-ICP-Acid Dil.Boron-ICP-Acid Dil.Barium-ICP-Acid Dil.Beryllium-ICP-Acid Dil.Bismuth-ICP-Acid Dil.

Cadmium-ICP-Acid Dil.Cerium-ICP-Acid Dil.Cobalt-ICP-Acid Dil.Chromium-ICP-Acid Dil.Copper-ICP-Acid Dil.Iron-ICP-Acid Dil.Potassium-ICP-Acid Dil.Lanthanum-ICP-Acid Dil.Lithium-ICP-Acid Dil.Magnesium-ICP-Acid Dil.Manqanese-ICP-Acid Dil.Molybdenum-ICP-Acid Dil.Sodium-ICP-Acid Dil.Neodymium-ICP-Acid Dil.Nickel-ICP-Acid Dil.Phosphorus-ICP-Acid Dil.Lead-ICP-Acid Dil.Sulfur-ICP-Acid Dil.Antimony-ICP-Acid Dil.Selenium-ICP-Acid Dil.Silicon-ICP-Acid Dil.Samarium-ICP-Acid Dil.Strontium-ICP-Acid Dil.Titanium-ICP-Acid Dil.Thallium-ICP-Acid Dil.Uranium-ICP-Acid Dil.Vanadium-ICP-Acid Dil.2inc-ICP-Acid Dil.Zirconium-ICP-Acid Dil.Fluoride-IC-Dionex 4000/4500Chloride-IC-Dionex 4000/4500Nitrite-IC - Dionex 4000/4500

UnitJoules/g DryJoules/gSp.G.%ug/mLug/mLug/mLug/mLug/mLuq/mLug/mL

ug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLu.q/mLug/mLuq/mLuq/mLug/mLuq/mLug/mLug/mLuq/mLug/mLuq/mLug/mLug/mLug/mLug/mL

Standard %n/a

97.5499.8299.6096.2098.20101.699.8098.40100.299.60

99.0096.00101.098.00106.098.4099.0098.0097.2094.8097.20100.4101.2100.699.0099.2095.80100.294.0096.4099.8099.2097.6096.8096.4099.50100.8101.898.4097.2997.4798.71

Blankn/an/an/an/a

<1.00e-02<5.00e-02<1.00e-01<5.00e-02<5.00e-02<5.00e-03<1.00e-01

<5.00e-03<1.00e-01<2.00e-02<1.00e-02<1.00e-02<5.00e-02<5.00e-01<5.00e-02<1.00e-02<1.00e-01<1.00e-02<5.00e-02<1.00e-01<1.00e-01<2.00e-02<2.00e-01<1.00e-01<1.00e-01<6.00e-02<1.00e-01<5.00e-02<1.00e-01<1.00e-02<1.00e-02<2.00e-01<5.00e-01<5.00e-02<1.00e-02<1.00e-02<1.20e-02<1.70e-02<1.08e-01

Result0.00e+000.00e+00

1.05591.161.840

< 2.550< 5.100

2.740< 2.550<2.55e-01< 5.100

<2.55e-O1< 5.100< 1.020

6.820<5.10e-01< 2.5504.09e+03< 2.550<5.10e-01< 5.100<5.10e-01< 2.5502.58e+04

< 5.100< 1.0202.41e+02

< 5.10041.00

< 3.060< 5.100

55.90< 5.100<5.10e-01<5.10e-01< 10.20< 25.50< 2.550<5.10e-01<5.10e-014.48e+031.01e+032.29e+02


1.06191.051.840

<2.55e0<5.10eO2.620

<2.55eO<2.55e-1<5.10e0

<2.55e-1<5.10e0<1.02e06.850

<5.10e-1<2.55eO

4.14e+03<2.55eO<5.10e-1<5.10e0<5.10e-1<2.55eO2.60e+04<5.10e0<1.02eO240.0

<5.10eO40.10

<3.06eO<5.10eO54.00

<5.10e0<5.10e-<5.10e-<1.02e<2.55e<2.55e

<5.10e-<5.10e-4.38e+031.03e+03

232.0

Average0.00e+000.00e+00

1.05891.101.840n/an/a

2.680n/an/an/a

n/an/an/a

6.835n/an/a

4.12e+03n/an/an/an/an/a

2.59e+04n/an/a

240.5n/a

40.55n/an/a


4.43e+031.02e+03

230.7

RPD %0.000.000.570.120.00n/an/a

4.48n/an/an/a

n/an/an/a

0.44n/an/a1.22n/an/an/an/an/a

0.77n/an/a

0.42n/a

2.22n/an/a


2.261.961.30

Spk Rec %n/an/an/an/an/an/an/an/an/an/an/a

n/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/a

Det Limitn/an/a

1.00e-02n/a

5.10e-012.5505.1002.5502.550

2.55e-015.100

2.55e-015.1001.020

5.10e-015.10e-01

2.55025.502.550

5.10e-015.100

5.10e-012.5505.1005.1001.02010.205.1005.1003.0605.1002.5505.100

5.10e-015.10e-01

10.2025.502.550

5.10e-015.10e-01

13.3318.89120.0

Count Err%n/an/an/an/an/an/an/an/an/an/an/a

n/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/a

IO+3SS-Ze/uE/U

e/ue/ue/u%JJ3 lunoa

90-3£EUZ'9U£•£51£•££1*"ML6-8£L

E/U

E/U

e/ue/ue/uE/U

% :»a >|ds

Z'9lE/U

e/u

i r oE/U

% oda

90-389'8B/U

E/U

2 - l2ZTO+3£8'^E/U

abejSAV

90-si* -6O'SEI.Z3£SH>0'90ZW+3Z8-17Z36£-l>3}EO(ldna

90-396'L

E0+3£S"l>20+39EV

ZO+S6£-1>

Z0-»l l '8>

IO-38£"1>l0-90E-l>IO-»6£'1>IO-SSZ'1>>|UB)9

0S'S6SJ'66£6'»68Z'S619-1769Z'S6% pjEpUEJS

lo i / ionlu/Bniui/6nlui/bnlui/Bnlui/Bni iun

se)dwes p inbn Ul eqaiv0SW00OV xsuo.Kl-ol-sieiexo

00SWOOO* xauoio-31 Aq ajej ins00SW000* xauoio-3I-3iei|dsoi|d

OOS»/000» xauoia-DI Aq siEJliNqdejbojeuiojqo uoi Aq aptiuojg

ajAiBUV

H£8000126SHE8000U6S5E80001Z6SM80001Z6SW8000U6SW80001Z6S

H #3lduies


n n t z ^ c c c i z c ororo<o<o<ora<cffic c c c c ^ ^ ^

SS

•£•£•£•£

•it

31

IE3S

37

04-aug-1997 14:15:26-.-0002-1

Page: 11

Sample* RS97T000835S97T000835S97T000835S97T000835S97T000835S97T001259

A# AnalyteBromide by Ion ChromatographNitrate by IC-Dionex 4000/4500Phosphate-IC-Dionex 4000/4500Sulfate by IC-Dionex 4000/4500Oxalate-IC-Dionex 4000/450Alpha in Liquid Samples

Unitug/mLug/mLug/mLug/mLug/mLuCi/mL

Standard %95.7694.6195.7894.9399.2593.50

Blank1.25e-011.39e-011.20e-011.38e-011.05e-017.11e-07

Result<1.39e+024.33e+046.17e+02<1.53e+02<1.17e+028.49e-06

Duplicate<1.39e2

4.29e+04599.0

<1.53e2<1.17e2

8.33e-06

Averagen/a

4.31e+04607.9

n/an/a

8.41e-06

RPD %

n/a0.932.96n/an/a1.90

Spk Rec '/.n/an/an/an/an/an/a

Det Limit138.9154.4133.3153.3116.7

1.47e-06

Count Err%n/an/an/an/an/a

2.41E+01

04-aug-1997 14:15:29•-.-0002-1


Page: 12



Sample* RS97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836S97T000836

DDDDDDDDDDDDD0DD0DDDDDD0D0DDDDDDDDDDD

AnalvteDSC Exotherm Dry CalculatedDSC Exotherm on Perkin ElmerSpecific Gravity% Water by TGA on Perkin ElmerSilver-ICP-Acid Dil.Aluminium-ICP-Acid Dil.Arsenic-ICP-Acid Dil.Boron-ICP-Acid Dil.Barium-ICP-Acid Dil.Beryllium-ICP-Acid Dil.Bismuth-ICP-Acid Dil.Calcium-ICP-Acid Dil.Caditiium-ICP-Acid Dil.Cerium-ICP-Acid Dil.Cobalt-ICP-Acid Dil.Chromium-ICP-Acid Dil.Copper-ICP-Acid Dil.Iron-ICP-Acid Dil.Potassium-ICP-Acid Dil.Lanthanum-ICP-Acid Dil.Lithium-ICP-Acid Dil.Maqnesium-ICP-Acid Dil.Manganese-ICP-Acid Dil.Molvbdenum-ICP-Acid Dil.Sodium-ICP-Acid Dil.Neodymium-ICP-Acid Dil.Nickel-ICP-Acid Dil.Phosphorus-ICP-Acid Dil.Lead-ICP-Acid Dil.Sulfur-ICP-Acid Dil.Antimony-ICP-Acid Dil.Selenium-ICP-Acid Dil.Silicon-ICP-Acid Dil.Samarium-ICP-Acid Dil.Strontium-ICP-Acid Dil.Titanium-ICP-Acid Dil.Thallium-ICP-Acid Dil.Uranium-ICP-Acid Dil.Vanadium-ICP-Acid Dil.Zinc-ICP-Acid Dil.Zirconium-ICP-Acid Dil.Fluoride-IC-Dionex 4000/4500Chloride-IC-Dionex 4000/4500Nitrite-IC - Dionex 4000/4500

UnitJoules/g DryJoules/gSp.G.

%ug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLuq/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLuq/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLug/mLuq/mL

Standard %n/a

97.6899.8299.6096.2098.20101.699.8098.40100.299.6097.4099.0096.00101.098.00106.098.4099.0098.0097.2094.8097.20100.4101.2100.699.0099.2095.80100.294.0096.4099.8099.2097.6096.8096.4099.50100.8101.898.4092.3793.8092.46

Blankn/an/an/an/a

<1.fl0e-02<5.00e-02<1.00e-01<5.00e-02<5.00e-02<5.00e-03<1.00e-01<1.00e-01<5.00e-03<1.00e-01<2.00e-02<1.00e-02<1.00e-02<5.00e-02<5.00e-01<5.00e-02<1.00e-02<1.00e-01<1.00e-02<5.00e-02<1.00e-01<1.00e-01<2.00e-02<2.00e-01<1.00e-01<1.00e-01<6.00e-02<1.00e-01<5.00e-02<1.00e-01<1.00e-02<1.00e-02<2.00e-01<5.00e-01<5.00e-02<1.00e-02<1.00e-02

<1.210<1.720<10.90

Result0.00e+000.00e+00

1.06591.391.770

< 2.550< 5.100

3.810< 2.550<2.55e-01

8.880< 5.100<2.55e-01< 5.100< 1.020

8.120<5.10e-01< 2.5503.92e+03< 2.550<5.10e-01< 5.100

2.420< 2.5502.46e+04< 5.100< 1.0201.94e+02

< 5.10037.00

< 3.060< 5.100

62.50< 5.100<5.10e-01<5.10e-01< 10.20< 25.50< 2.550<5.10e-01<5.10e-014.28e+039.03et024.78e+02


1.05191.131.780

<2.55eO<5.10e04.220

<2.55eO<2.55e-1<5.10e0<5.10e0<2.55e-1<5.10e0<1.02e07.760

<5.10e-1<2.55eO

3.94e+03<2.55eO<5.10e-1<5.10e0

1.080<2.55eO2.48e+04<5.10e0<1.02e0199.0

<5.10e039.40

<3.06e0<5.10e064.00

<5.10e0<5.10e-1<5.10e-1<1.02e1<2.55e1<2.55eO<5.10e-1<5.10e-14.28e+03

896.0464.0

Average0.00e+000.00e+00

1.05891.261.775n/an/a

4.015n/an/an/an/an/an/an/a

7.940n/an/a

3.93e+03

n/an/an/a

1.750

n/a2.47e+04

n/an/a

196.5

n/a38.20

n/an/a


4.28e+03899.6470.8

RPD %0.000.001.320.280.56n/an/a10.2n/an/an/an/an/an/an/a

4.53n/an/a0.51n/an/an/a76.6n/a0.81n/an/a2.54n/a6.28n/an/a2.37n/an/an/an/an/an/an/an/a0.000.782.97

Spk Rec %n/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/a

. n/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/a

Det Limitn/an/a

1.00e-02n/a

5.10e-012.5505.1002.5502.550

2.55e-015.1005.100

2.55e-015.1001.020

5.10e-015.10e-01

2.55025.502.550

5.10e-015.100

5.10e-012.5505.1005.1001.02010.205.1005.1003.0605.1002.5505.100

5.10e-015.10e-01

10.2025.502.550

5.10e-015.10e-01

25.4536.06229.1

Count Err%n/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/a

LU

a.9QCO

20+300'SB/U

e/ue/uG/U

B/U

%JJ3 lunoo

S0-3.W8

rzzzL'ZbZ

8"}6ZI'592

B/U

B/U

e/ue/uB/U

B/U

% 39)1 >|ds

B/U

B/U

e/u6»"85£ ' le/u% ada

e/uB/U

B/U

S'«9

B/U

a6ejaAV

S-39Z-9>2S£2"2>2^£6"2>0-86S

E3S9-E>sieoLidna

S0-39»-£>EO+S£Z-Z>E0+3£6"E>SO+315'9W+^8»'ÊO+SS9-Z>

SO-=69V09'0l>06 -£l>

orzi>00'^l>09'2L>>iuBia

05 'E8S£H680-Z68S-£6W 0 6Wit,% pjBpueis

V/1 oniw/6n^ / 6 nliu/Bn10i/6nliu/enJiun

sald^BS p inb i i u\ Bqd}vOSVOOO^ xauoLQ-oi-eiBiBô

OOSV0001? xauoiQ-31 Aq .eieînsOOS»/000» xsuoia-OI-WUdsoiid

OOSWOOO* X3UO10-0I Aq 3JBJJ1NtjdejBorteiiiojqo uoi Aq epiuioua

95A1BUV #V

9E8000U6S9E8000U6S9E8000U6S9280001Z6S9E8000.U6S9£80001Z6S

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c c c c c c c c c c c c c c c c c c c

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SSS

in t/> <s>

04-aug-1997 14:16:34-0002-1

Page: 15

Sample* RS97T000837S97T000837S97T000837S97T000837S97T000837S97T000837

A# AnalyteBromide by Ion ChromatographNitrate by IC-Dionex 4000/4500Phosphate-IC-Dionex 4000/4500Sulfate by IC-Dionex 4000/4500Oxalate-IC-Dionex 4000/450Alpha in Liquid Samples

Unitug/mLug/mLug/mLug/mLug/mLuCi/raL

Standard %93.2190.7493.5892.0891.3582.50

Blank<12.60<14.00<12.10<13.90<10.60

7.69e-05

Result<2.65e+024.73e+047.33e+02<2.93e+02<2.23e+02<5.59e-05

Duplicate<2.65e2

4.79e+04643.0

<2.93e2<2.23e2<7.61E-5

n/a4.76e+04

688.1

n/an/an/a

RPD %n/a1.2613.1n/an/an/a

Spk Rec %91.17107.791.7493.5093.05n/a

Det Limit265.1294.8254.5292.7222.7

8.47e-05

Count Err%n/an/an/an/an/a

5.00E+02

to

'4-aug-1997 14:16:37-0002-1


Page: 16

CORE DUMBER: 192SEGMENT #: 6

SEGMENT PORTION: U Upper Half of Segment

Sample* RS97T000909S97T000909S97T000909S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921

S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000921S97T000931S97T000931S97T000931S97T000931S97T000931S97T000931

A#

Ji4JJJ

AnaLyteDSC Exotherm Dry CalculatedDSC Exotherm on Perkin Elmer% Water by TGA on Perkin ElmerSilver -ICP-FusionAluminium -ICP-FusionArsenic -ICP-FusionBoron -ICP-FusionBarium -ICP-FusionBeryllium -ICP-FusionBismuth -ICP-FusionCalcium -ICP-FusionCadmium -ICP-FusionCerium -ICP-FusionCobalt -ICP-FusionChromium -ICP-FusionCopper -ICP-FusionIron -ICP-FusionLanthanum -ICP-FusionLithium -ICP-FusionMagnesium -ICP-FusionManganese -ICP-FusionMolybdenum -ICP-FusionSodium -ICP-FusionNeodvmium -ICP-FusionPhosphorus -ICP-FusionLead -ICP-FusionSulfur -ICP-FusionAntimonv -ICP-FusionSelenium -ICP-Fusion

Samarium -ICP-FusionStrontium -ICP-FusionTitarn" urn-1CP-FusionThallium -ICP-FusionUranium -ICP-FusionVanadium -ICP-FusionZinc -ICP-FusionZirconium -ICP-FusionFluoride-IC-Dionex 4000/4500Chloride-IC-Dionex 4000/4500Nitrite-IC - Dionex 4000/4500Bromide by Ion ChromatographNitrate by IC-Dionex 4000/4500Phosphate-IC-Dionex 4000/4500

UnitJoules/g DryJoules/g'/.ug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/g

ug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/g

Standard %n/a

94.9098.7996; 2095.60102.499.0096.00100.899.40100.098.8095.60100.698.2096.6092.2097.0095.2098.6096.6099.60100.096.60100.896.6098.6094.8093.40

95.2096.2095.8094.0093.7099.8095.8096.8092.2096.8396.1496.4497.6495.96

Blankn/an/an/a

<1.00e-02<5.00e-02<1.00e-01<5.00e-02<5.00e-02<5.00e-03<1.00e-01<1.00e-01<5.00e-03<1.00e-01<2.00e-02<1.00e-02<1.00e-02<5.00e-02<5.00e-02<1.00e-02<1.00e-01<1.00e-02<5.00e-021.65e-01

<1.00e-01<2.00e-01<1.00e-01<1.00e-01<6.00e-02<1.00e-01

<1.00e-01<1.00e-02<1.00e-02<2.00e-01<5.00e-01<5.00e-02<1.00e-02<1.00e-02<1.20e-02<1.70e-02<1.08e-01<1.25e-01<1.39e-01<1.20e-01

Result0.00e+000.00e+00

69.98<2.22e+02<1.11etO3<2.22e+03<1.11e+03<1.11e+03<1.11e+029.18e+04<2.22e+03<1.11e+02<2.22e+03<4.44e+024.03et03<2.22e+028.66etO31.53e+04

<2.22e+02<2.22e+032.54e+04<1.11e+032.81e+04<2.22e+03<4.44e+03<2.22e+03<2.22e+03<1.33e+03<2.22e+03

<2.22e+038.84e+02<2.22e+02<4.44e+03<1.11e+04<1.11e+03<2.22e+02<2.22e+024.64e+039.76e+023.17e+02<3.02e+024.56e+041.22e+03


69.43<2.19e21.17e+03<2.19e3<1.09e3<1.09e3<1.09e2

9.03e+04<2.19e3<1.09e2<2.19e3<4.38e2

4.08e*03<2.19e2

8.60e+031.48e+04<2.19e2<2.19e32.45e+04<1.09e32.74e+04<2.19e3<4.38e3<2.19e3<2.19e3<1.31e3<2.19e3

<2.19e3832.0

<2.19e2<4.38e3<1.09e4<1.09e3<2.19e2<2.19e2

4.71e+03983.0317.0

<2.99e24.68e+041.16e+03

Average0.00e+000.00e+00

69.71n/an/an/an/an/an/a

9.10e+04n/an/an/an/a

4.06e+03n/a

8.63e+03' .50e+04

n/an/a

2.50e+04n/a

2.78e+04n/an/an/an/an/an/a

n/a858.0n/an/an/an/an/an/a

4.67e+03979.6316.9

n/a4.62e+041.19e+03

RPD %0.000.000.79n/an/an/an/an/an/a1.65n/an/an/an/a1.23n/a0.703.32n/an/a

3.61n/a2.52n/an/an/an/an/an/a

n/a6.06n/an/an/an/an/an/a1.500.710.00

n/a2.605.04

Spk Rec %

n/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/a

n/an/an/an/an/an/an/an/an/an/an/an/an/an/a

Det Limit

n/an/an/a

222.01.11e+032.22e+031.11e+031.11e+03

111.02.22e+032.22e+03

111.02.22e+03

443.0222.0222.0

1.11e+031.11e+03

222.02.22e+03

222.01.11et032.22e+032.22etO34.43e+032.22etO32.22e+031.33e+032.22e+03

2.22e+03222.0222.0

4.43e+031.11e+041.11e+03

222.0222.028.9541.01260.5301.5335.3289.5

Count Err%n/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/a

n/an/an/an/an/an/an/an/an/an/an/an/an/an/a

04-aug-1997 14:17:09..-0002-1

Page: 17

Sample*S97T000931S97T000931

R A#UU

AnalyteSulfate by IC-Dionex 4000/4500Oxalate-IC-Dionex 4000/4500

Unitug/gug/g

Standard %97.3198.68

Blank<1.38e-01<1.05e-01

V1

Result.63e+02.02e+03

Duplicate<3.31e21.12e+03

Average

n/a1.07e+03

RPD %n/a9.35

Spk Rec %n/an/a

Det Limit332253

93

Count Err%n/an/a

L Louer Half of Segment: L Louer Half of Segment

Sample* RS97T000894S97T000899S97T000899S97T000899S97T000900S97T000900S97T000900S97I000900S97T000900S97T000900S97T000900S97T000900S97T000901S97T000901S97T000901S97T000901S97T000901S97T000901S97T000901S97T000901S97I000901S97T000901S97T000901S97T000901S97T000901S97T000901S97T000901S97T000901S97T000901S97T000901S97T000901S97T000901S97I000901S97T000901S97T000901S97T000901S97T000901S97T000901S97T000901S97T000901S97T000901S97T000901S97I000901S97T000901S97T000901

A#

UUUUUVUVF

HFFFFFFFFFFFFFFFFFFFFFFFF

AnalyteBulk Density of SampleDSC Exotherm Dry CalculatedDSC Exotherm on Perkin Elmer% Water by TGA on Perkin ElmerFluoride-IC-Dionex 4000/4500Chloride-IC-Dionex 4000/4500Nitrite-IC - Dionex 4000/4500Bromide by Ion ChromatographNitrate by IC-Dionex 4000/4500Phosphate-IC-Dionex 4000/4500Sulfate by IC-Dionex 4000/4500Oxalate-IC-Dionex 4000/4500Silver -ICP-FusionAluminium -ICP-FusionArsenic -ICP-FusionBoron -ICP-FusionBarium -ICP-FusionBeryllium -ICP-FusionBismuth -ICP-FusionCalcium -ICP-FusionCadmium -ICP-FusionCerium -ICP-FusionCobalt -ICP-FusionChromium -ICP-FusionCopper -ICP-FusionIron -ICP-FusionLanthanum -ICP-FusionLithium -ICP-FusionMagnesium .-ICP-FusionManganese -ICP-FusionMolybdenum -ICP-FusionSodium -ICP-FusionNeodvmium -ICP-FusionPhosphorus -ICP-FusionLead -ICP-FusionSulfur -ICP-FusionAntimony -ICP-FusionSelenium -ICP-FusionSilicon -ICP-FusionSamarium -ICP-FusionStrontium -ICP-FusionTitaniurn-ICP-FusionThallium -ICP-FusionUranium -ICP-FusionVanadium -ICP-Fusion

Unitg/mLJoules/g DryJoules/g%ug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/gug/g

standard %

n/an/a

94.9098.7992.2096.8396.1496.4497.6495.9697.3198.6896.2095.60102.499.0096.00100.899.40100.098.8095.60100.698.2096.6092.2097.0095.2098.6096.6099.60100.096.60100.896.6098.6094.8093.4099.0095.2096.2095.8094.0093.7099.80

Blankn/an/an/an/a

<1.20e-02<1.70e-02<1.08e-01<1.25e-01<1.39e-01<1.20e-01<1.38e-01<1.05e-01<1.00e-02<5.00e-02<1.00e-01<5.00e-02<5.00e-02<5.00e-03<1.00e-01<1.00e-01<5.00e-03<1.00e-01<2.00e-02<1.00e-02<1.00e-02<5.00e-02<5.00e-02<1.00e-02<1.00e-01<1.00e-02<5.00e-021.65e-01<1.00e-01<2.00e-01<1.00e-01<1.00e-O1<6.00e-02<1.00e-01<5.00e-02<1.00e-01<1.00e-02<1.00e-02<2.00e-01<5.00e-01<5.00e-02

Result1.390

0.00e+000.00e+00

66.314.77e+031.00e+033.17e+02<2.78e+024.43e+045.54e+02<3.07e+021.08e+03

<2.04e+02<1.02e+03<2.04e+O3<1.02e+03<1.02e+03<1.02e+021.11e+05

<2.04e+03<1.02e+02<2.04e+03<4.08e+025.36e+03<2.04e+029.34e+031.59e+04

<2.04e+02<2.04e+032.95e+04<1.02e+032.70et04<2.04e+03<4.08e+03<2.04e+03<2.04e+03<1.22e+03<2.04e+03<1.02e+03<2:04e+031.17e+03

<2.04e+02<4.08e+03<1.02e+04<1.02e+03

Duplicate

n/aO.OOe+000.00e+00

64.764.40e+03

940.0298.0

<2.80e24.36e+04

680.0392.0984.0

<1.99e2<9.96e2<1.99e3<9.96e2<9.96e2<9.96e11.12e+05<1.99e3<9.96e1<1.99e3<3.98e25.39e+03<1.99e2

9.30e+031.75e+04<1.99e2<1.99e3

2.99e+04<9.96e2

2.70e+04<1.99e3<3.98e3<1.99e3<1.99e3<1.20e3<1.99e31.14e+03<1.99e31.21e+03<1.99e2<3.98e3<9.96e3<9.96e2

Average

n/a0.00e+000.00e+00

65.534.59e+03

972.0307.4

n/a4.40e+04

617.1n/a

1.03e+03n/an/an/an/an/an/a


5.38e+03n/a

9.32e+031.67e+04

n/an/a

2.97e+04

n/a2.70e+04

n/an/an/an/an/an/an/an/a


RPD 7,n/a0.000.002.378.076.196.18n/a1.5920.4n/a

9.30n/an/an/an/an/an/a0.90n/an/an/an/a0.56n/a0.439.58n/an/a1.35n/a0.00n/an/an/an/an/an/an/an/a

3.36n/an/an/an/a

Spk Rec %

n/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/a

• n/a

n/an/an/an/an/a

Det Limit5.00e-01

n/an/an/a

26.6637.77240.0277.8308.9266.6306.7233.3204.0

1.02e+032.04e+031.02e+031.02e+03

102.02.04e+032.04e+03

102.02.04e+03

408.0204.0204.0

1.02e+031.02e+03

204.02.04e+03

204.01.02e+032.04e+032.04e+034.08e+032.04e+032.04e+031.22e+032.04e+031.02e+032.04e+03

204.0204.0

4.08e+031.02e+041.02e+03

Count Err%n/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/an/a

04-aug-1997 14:17:41A-0002-1

Page: 18

Sample# RS97T000901S97T000901S97T000901

A#FFF

AnalyteZinc -ICP-FusionZirconium -ICP-FusionAlpha of Digested Solid

Unituq/gug/guCi/g

Standard %95.8096.80101.0

8 lank<1.00e-02<1.00e-02<4.64e-03

Result<2.04e+02<2.04e+026.32e-01

Duplicate<1.99e2<1.99e2

6.28e-01

Average

n/an/a

6.30e-01

RPD %n/an/a0.63

Spk Rec %

n/an/an/a

Det Limit204.0204.0

8.00e-03

Count Err%n/an/a

6.21E+00


C C C C C C C C C C E C C C C C C C C C C C C C C C C C C C C

88: o> at i

i i ; • £ • £ • £ • ;

• £ • £ • £ • £

ss-s

S S S

gg

•8-8

gggggggg 2 l l l


- . -- -_ -_ -_ - , -_ - -- ,_ ,». , . . . . w ,_ ,_ , , ,». , . . . ,»- . . . , ( Q ^ Q ( O { C ( D ^ ( C C O < 0 C Q ( C f l l <

• £ • £ • £

s

• <D a> i> at a

oi <D

as

§ § !

-S-S

gggggg gggg Sgggggg

47

04-aug-1997 14:18:48A-0002-1

Sample* RS97T000919S97T000919S97T000919

A#I-F^

AnalyteZinc -ICP-FusionZirconium -ICP-FusionAlpha of Diqested Solid

Unitug/3ug/guCi/g

Standard %95.8096.80101.0

Blank<1.00e-02<1.00e-02<4.64e-03

Result<2.08e+02<2.08e+025.98e-01

Duplicate<2.04e2<2.04e25.65e-01

Average

n/an/a

5.81e-01

RPD %n an/a5.67

Spk Rec %

n/an/an/a

Det Limit208.0208.0

8.00e-03

Count Err%n/an/a

6.42E+00


SS

I

•£•£

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: t t< s % SRi

S B ' S ?

- •§ •§

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IIs

~~

Ji i)

SS

8S3 3

sss SS SS SS ss SS SS

as

w t / > t / ) W ( n w w < n ass aa aas

SO

in

00+309"fB/UB/U

%jJ3 junoa

£0-800V0'90Z0"902

19'0808V60l'l6

ruB/U

B/U

/. m

850" LB/U

B/U

l0-399"623£0'2>23£0*2>

osri20+990"2>Z0+390-Z>

£0-300 -£Z0- s00' l>20-300"L>

w a

00 - f 608 "9608-S6•/. PJBPUBIS

B/jon6/6nB/Bni.iun

p l ios psissBla +o Bqdivuo isn j -d3 i - mntuoojtz

uoisnj -dDI- ouiz91A1BUV

1ii

0260001Z6S0260001Z6SOZ6000U6S

y #31 s


CHAIN OF CUSTODY FORMS

S2


THIS PAGE INTENTIONALLY LEFT BUNK

5 3

CHAIN-OF-CUSTODY RECORD FOR CORE SAMPLING

(8) Coek Social Numboi . 21-GfiacJlqtfon Survoy Data:

Ovor Top Oofla Hoto

Sltto DDBD Rato

Bottom DosoRato

Smoarablo Contamination

RCT"(HPTJ

(9) WELD

(Alplm) ()

(8oto'GommoJw

(SjQno^o)

(33) LABORATORY

/ ^ .T m SO

(HPT) / / ' ISIifnoturaJ

U t> INFORMATION {Include statemont oi laboratory toets to bo porformed.I

(A

(10) SJilpmont DoaoiiplFon

A. Wo/k Paohnflo Wumbof t V ?

0. Cnsk Soul Number ,., JJ7

0. Doto ond Tttrio Somf>for U>soatod , y^*

ME. Expootocf Llqutd Content . ,.yf w

G. Doao RaW Throuoh DtWt Strlno ^

H, Expootod Somplo Longth

-?6-0O3*OJ/foCf

/(J

HNF-SD-

IIS) Seal Intaot Upon Rgloaso?

• w°.

131) Soal Intact Upon Rncelpt?

I-Yos

pn>ant No.[ Yos D No

aul Data Consistent with tliis Rooord?

k Sod No. plo No.

j Whfto - Offloo o( Scmplo ManDflaniont Yollow - Roofplont of Sam|>lo Pink - Coro Sampling, S6-flC Goldanrod - Tank Pmrn Oporatlons, S4-43

(1) SW|

(4) Tmifc~ i"'3~ iJ.


*^5 (6J Soumsnl / (7] Cora / r*** (©I Cask Serial Nuntbar

Radiation Survey Data!

Over Top Doso Roto

Sido Dose Roto

BoKom Doso Rate

ontamination

OJ FIELD (33) LABORATORY

-<".. r>6 S

[Alphol'

/ £ ?(Boto-Gammat

BCTV(HPT)

<1O> Shtpmont DosotJpti'on

A. Work PaokaQo Number

B. Cask SDOI Numl>sr

<X Sampler Sorlol Numbor

D. Onto and Tlmu SompJor Unsofllod

E, Expected Ut[Uld Contant

__, F. Evpocted Solid Conlant

G, Ooso Rate Tliroiroh DtffJ String

H, Cxpaotctf Sornplo tongtd 1:(11) INFORMATION (Incfudo staternQni of Joljoralo/y tests to bo petformod.)

j i 6* boa) irttoct Upon ROIOODO?

Dwo

(31) SsoE Fntaot Upon Roooipt?

DNo '^hlnmont No»

021 Soal Dots Consistent with tills Rocord?

Cosk Soal No.

iY08 DNoSampfo bib.

D.No

WJifto - Oflioo of Samplo Monaoomant Yallow - Rocftitont of Sample Ptnk - Coro Sampling, S6-05 GoWonrcd - Tank Farm Opotettonsj S4-43 BC-6O00-3O9 W2»4]


(2) Samjilo Number

urvov

Ovor .Top Doso Rale

SJdo Doao

fibttom Dotfq Rato

Contamination

(61 Saomsnt. 'JL13) Suporvlsor

. |7)Coro (8) Cask Sorlal Numbai <L'-2fi\L •(33HABORATORY

*£ "2-C* g>i£i>-. . (Alphal,

(Bato-Sommirh

(Slsno«ife>/

(10) Shipment Description

A, Work Pooka go Number: ' '

B, Coak Seal Nuoib'or •

C. SomplorSorlnl Number

D. Dole and Time Sampler Unsoulod

B. BKfiootdtl Llqultf Content.

H Ekpooisd Solid Contortt; .

&. Dose-Oat<rTlifcugh Drlll'Strlno

H. Expootod Sampla Longlh

(11) INFORMATION. (Iticludo statatnontufJaboialori! Issts.talio poiicirmod.)

(321 Seal Data Consistent with (hte Retard?

DISTRIBUTION: White - Odloo of Sample Manaijamont Yollow - Roolplont of Sampb Pink - Cora Sampling, S6-»5 Goldonrod - Tank Form Operations, S4-43 BC-600O-309 (O;

(1)1

14)1


12) Sample Number . tic 7W&(6) Rlsot (6) So 3 •• V) Cora

7 •"'•'"

Radiation SurvoyDutas

Over Top Oaso ftaxe

Side Doso fiale

Bottom Doso Rato,

Smoarabte-

18) FIELD (33) U80RAT0RV

(Aioirn) 11. r ? (Alpha)-

ISlnnaturo) ( H P T ) . ..•

(10) Shlpmont DoDorl|>llon

A. Vfmk PboUbflt Numbo«

B. Cash: Seal Number

C. Somplar Sotlol Number.

'• Bi DolB-onti-Tlmo.Siimplcit-Unaontot)-

£.- EKpooled Uqlild. Content

G, Doso Roto Through Drill SUlntr

' H*. Expootod Semplo tongth *

( IS) Son! Intaot Upon ROIDOBO?

• Mo

(31) Son) Jntapt Upon Receipt?

ion! No.Yes D No

I32) Seal Data Conslatont with this Rocotd?

Seal No,

I

[(27) Hdln^?hod By {Sign and WflNT) /

iplo No.

Hi.u. n « i n a „( tta«.nt* MnMnnnmnnl V^llnui - Rfmtolnnt of SamiDlo Pink - Core Samollncf. S&*8B Ooidfitirod - Tank Pnmrt nnnrnrtn

CHAIN-OF-CUSTODV RECORD FOR CORE SAMPLING

. I?) SMp

MJTonk 'ffl ""'" ^ * . ' (8) Cask Serial

Radiation Survov Data: '

OVor Top Doso Roto

Side Ooeo Rato

Bottom DOSQ flato '

Smoorablo Contamination.

(91 FIELD (33) LABORATORV 110) Shlpmont Pesorlptlon

. A,- Wotk.Paakarje Numbor

B> Caak 8bal Number-

C. Sampler Serial Numbur

O. Baifo on* Time Sompfor Unseated1

. 6. .rjKpQateri.tlquld Contpnl.

G. Doeo Rato TlHOUfll] Drill1 String

H> fxpQotod-SampCo LQnath

(nHNPOflMA,TIQr*([nclU(Io,8lototnotir.

Yea

131} Soal Intact Upon flocwlpt?

• No#mont No.fveo DNO

(32I Seal Data Consistent with this Rocord?

Seal Ha.

JVbs~T

• NoNo,

Yea D Wo

JSTfllBUTION: Wlillo • Oirico of Samplo Manooomont Ydllow - Recipient of Semplo Pink • Coro SampUno, Si9-8E Goldonrad - Tank Farm Opetoilara, S4-13 BC'SOOO-909 (C2W4I

mont Numbof

" | ~~ niOl


(2) Sample Numbor AfA.-QS (3( Supoivi!1<,r fil:<.C-\

(5) Riser (6) Soomant 171 Cord IB! C!flBl< Snrlal Mimihur

JI Smvey Data;

Top Doao Roto

>OQQ Rato

m Do so Rate

rablo Contamination

49) FIELO

(Bo'.c-G

(HPTt (Signal

A. Work Packaao Ntimbor

fi, Cusk Seal Murnbor

C, Samplof Sorlal Mumtior

O. DetD nnu1 "TirfiQ Somplof

E, Exposed Liquid Content

F, EKpoctocl Solid Content

G, DOQO RatQ Through Drill StflnfJ

H. Cxpoctod So

OhMATION llncludo clotoinoill ol loliototory tosls (o bo pmformixl.)

»qulef.od t;y (Signal ?mf)

QQ\ Intact Upon Release?

.Yoa Q No

131) Soul Iritaot Upon RtrcoliX?

a NOiont No.

• No

(32) Soul Data Consistent v/ltll (Ills Roooid?

Caek Soal Ho,

Myoi. D No

i . Ofllnn n( finmnln Urn Pink . f!r>*n RAmnllnn Bfi.flR ftnlilnntrui - *rnnl/ Pnr*n rtnnrntln*


(6) Sogmont . (7)Coio Ifx Cask SerEal Number _

a (ton burvey Data;

or Top DOEO Rato

do Dosa Rnta

•ttoni Oa3Q Rota

rioafubla Contamination

(9) FIELD (33) LABORATORY

rb A,-' (Alphal ()

RCT' .(HPTI {SkyiattiffCj^

{10) Shipment Dasorlptlon

Ai V?oik Pflokaga Number

B. Cask S»al Number

C. Sampler Serial Numb or

D. Date and Tima Somplor.Unsoaie

E. Exported Liquid Content

F. Expeotad Solid Contant

G. Dose Rato Through Drill String

H. Expoctod Sa

INFORMATION (Inalucls atAtomant of laboratory loats to ba pscfoimad.)

Flow Comrnonla

Point of Oilgln

! : llnqUlshMA/jSlop^

;e«nc|Ulshod ayTsiSS&d raiNT)

G| Soal (nlncl Upon Rolouao?

feTvlY O J DfJo

(311 Sad Intact Upon RoooipU

iYoo D N OShjpmonl Mfa,

ffifYne • • No

(32) $OQ! DA(Q Constetont wUU tHo Rooof<l)

gagk Sonl No.

KlYos D NO aVob • No

F1IBUTION: Whlto-- O«lon f»j Sjir>i|)»o Mnruiflomonf Yollc»w - Roolplnnt o Pink - Com S«nipliofl, S6-86

(1) Shlpmom

Mi Tonk )

CHAJN-OF-CUSTODY RECORD FOR CORE SAMPLING

(2) Snmplo Numboi / / ^ " ^ / (3) Supoivieor fit(3) Supo/vfeor ^

. (7}Ooro

Radiation Sufvoy Dalaj

Over Top Ooso Roto

Sfdo DOBD Roto

fioKom Dose Rato

SmoaratJfo Contamination

(HPT)

(11) INFORMATION jlnofudo sla

- <

<

<

lomont ol Jc

(91 FIELD

\ io .n <s.o

borotoiy foots

1

RCT' (" (HPT)

to bo po/foimod.)

(33) LABORATORY /

-k * flrisTfa %L/ j

£ « 33 A,

7 V telD'traWftf)

(10) Shlpmont Description

A, Vi».U Pnnkoqn Wlimhnr l>/5~^lfa-00} 0@

i ? /**/ 7 /

P, D«|n pr*'' TlTl^ ??nr«pl«^ tJttfffinlmf . ^ ^ . ^ V ^ ^ " T » C>/<. t>

F. .F^|.nct»«l 1 lf|iiM finnionr , J)^C^CJ

p, Fypnnrnrf Sollri r.ojilnnt . ef^C^/C/

C. Dunn Bntn ThrMlflh M i l Slrlnj "*V< • J / * / / £ / C T A

H. FvpnntnfJ R/impJf) l.nnfl(K . . . ' / , , •*•

=-SD

8( RoQoivoauDv fSln« end PRINT) /

( f 8 | Sonl Intact Upon Roloosa?

D N O

(di) Soal Intact Upon.Rocolj)t7

YOB D No

(32) Soai Duta Consfolant svitlt Ihls

sk Soul No. iNo.

IYOS O NO D NoiTRJBUTIOM; Wlifto - Offico.of SampFo Mahagomortt Yellow - Rociplant ol Samplo Pink > Coro Sumpttny, S6-05 Gofdatirod r Tnnfc Form Opo/attons,


(2) Samplo Numbo,

(6) Soflmont . Q (7) Coro / 9 2 (81 Cask Serial Numbar .,,&y"5.7,,,

tlon Survay Data:

or Top Doss Roto

a DOBO Ralo

ttom Doso RolQ

Contamination

[331 LABORATORY y

gnaturof /^\

(10) Shipment Description

A. Wotk Packago Number

B. Cask Scat Number

C. Samplor Serial Numbor

D. Dato and Time Sampler Unseated

E. Expootod Liquid Content

F. EKpeotod Solid Contartt.

G. Ooso Rnto Through Drill Slrino

H. Expootcd Sample Lotiflth

"J^P "? / '

<,£/°t.u

INI CI;K-.A:»ON iineludo Qiaiomont of laboratory tests to bo porfornwU

0) Sonl IntflOt Uport R

V<IS

(31) Soal Intnct Upon

• Mo

(32) Soal Data Cotiolslonl with this. Rooord?

S«nl No.

No • NOla No.

[Vos D No

-z-

ninlJTlnM: VJhttn . olfinn at Sumnln Monjinoinont Yollow - Roolplnnt of Samplo Pink • Coro SoniNllnn. SG-BG Goldontofl - Tnnk Form Oporntlona, S4-43 GC-0000.303 (02/94)


PHOTOGRAPHS



64


AX \


iA

\)

h'-


m

HNF-SD-WM-DP-254,FEV.0

-o if


COMPOSITE WORKSHEETS

74



75

Composite Worksheet.

Tank:

9O VID: &\-\ TQOO%»SAuger/Core: Aq^

Segment: s t>v.

Jar/Vial Size.\-g»5o mLInitial Weight:Final Weight: g q g , \ gNet Weight:

SampleID:.AugerTCore:

j Sample[I]):

Jar/Vial Size:Initial Weight:'Final Weight:Net Weight:

• a •

Jar/VialInitial WeW:Final Wcimt:Net Weight

0on Page

RC.

Jar//:Jar/Vial Size:Initial WeightyFinal Weight: "Net Weight:

sa.©

Special Instractions:

Page of

06/24/97 10:52 -a'ous o < J au*/

Oate:


Final Composite Calculation Sheet

Technician: H •

ATotal number of jsrs used to build .the composite:

' Composite Jar number: •) 1^3*4 Jar size: / . b

jar = t1) Sample from segraent j a r i2gT7^ to composite

2) Sample from.segment j a r )"^3,y| to composite

3) Sample from segment jar _Q2Tij. to composite.

4) Sample from segment jar \'3.(a\L\ to composite

Sample from segment jar iQC^D to composite

5) IS&tRRie from segment j a r to composite

7) Sample frbs^segraent j a r to composite

8) Sample from seomeftfcoar Ki A^ro composite

9) Sample from segment j a r ^ ~ ^ , ^ to composite

10) Sample from'segment j a r to o

11) Sample from segraent jar to composite

12) Sample from segment j a r

13) Sample from segment j a r ; to composite

14) Sample from segment jar _______ to composite

Jte jar

to.composite jar =

jar =

Total, grams collected in composite jar # \}%2>Li grams

78.

Composite Worksheet' •

Tank: -raoi

>5 Z> Auger/Core:Segment:

WtmsS] Sample ':

ID: SfrrrAu'ger7'Core: jSegment:

\<3

lartf:

i i * ^ SampleID:

\"5

Phoned 1 -Sample ^

Auger/Core:- \°>?Segment:-7 U.H

\ S 5

ID:Auger/

Segment:Jar//: Jut//; Jar//;

Jar/Vial Size: 0 5 6 mLInitial Weight:2^._L BFinal Weight: g j ^ . l \ gNet Weight: J ^

Jar/Vial Size: '^'oCi ;nLInitial Weight: Q T ^ . gFinal Weight:Net Weight: "

Jar/Vial Size: 3 s o mL Jar/Vial Size:jaSQjnLInitial Weight: '3&J, <? g Initial W e i g h t ^ ,ty gFinal Weight: I f t .^ g . Final Weight:'Net Weight: }(\Q g Net Weight:/

Cfi

.60

Tests: /

^ 1 ' Instructions:

Qq-i^oo^^S

Jar//:KJar/Vial Size:Final Weight:Initial Weight:Net Weight:__

HomogenizationTime (Min.):

gg (aftor fixxsil

sxib s a.

O^vw^xy'cA-vu s^w^

Page 1 of

C/5

9

33

m

o

BEST AVAILABLE COPY

06/23/97 ,14:27 ©509 373 5047 222S HAZMAT UNIT -»-»•» LAB DATA MGMT

HNF.SD-WM-DP-254, REV. 0

ig] 002

Technician:

6Total' number of jars used to build the composite:

Composite Jar number:. J^J^GST J a r s^ze:

1). Sample from segment jar K3Lc6 to composite jar =

. .2) Sample from segment jar JSkOtTto composite jar =

'V3).^ ' Sample from segment jar 1 3 4 1 ^ to composite jar •

4) Sample from segment jar i ^ k o ^ to composite jar

5) Sample frcra segment Sz<~ i^^isf to composite j?.r

grams

6)

7)

8)

Sample from segment jar-

pie from segment jar

segment jar

Sample froni\?gment jar

Sample from segmesit jar

Sample from segment

• _J5 2 2 _ 3r?*s

10)

11)

12) Sample from segment jar


14) Sample from' segment jar

15) Sample from segment-jar

16)• Sample from segment jar





Total grams collected in composite

to composite jar -

to' composite jar =

to composite jar =

to composite jar =

composite jar =

to composite jar =

to composite jar =

composite jar ••

_ to asmposite jar

_ t o

to composite

_ to composite jar

to composite jar

to composite jar

jar * Q_U>^ ~

S i


SAMPLE HANDLING

worklistrpt Version 2.1 05/15/9504/28/9710'49

LABCORE Data Entry Template for Worklist# 17770

Analyst: TVLC^ Instrument: BAOOO Book #

Method: LO-160-103

Worklist Comment:

GROUP

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

PROJECT

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

S

1

2

3

4

5

6

7

8

9

10

11

12

Rev/Mod v O

T-201 C192 SEG # 2

TYPE

INSTCHK01

INSTCHK02

SAMPLE

SAMPLE

SAMPLE

SAMPLE

SAMPLE

SAMPLE

SAMPLE

SAMPLE

SAMPLE

SAMPLE

SAMPLE*

S97T000680

S97T000680

S97T000680

S97T000680

S97T000680

S97T000680

S97T000680

S97T000680

S97T000680

S97T000680

0

0

0

0

0

0

0

O

0

0

HNF-SD-WM-DP-254, REV.

RISER 3 EXTRUSION

R A TEST

EXTRUD01

EXTRUD01

DLIQVOL1

DLIQUT01

EST.G/ML

EXTRUD01

LLIQUT01

NOTEBOOK

SLDVOL01

SLDWT-01

APPEAR01

ORGVOL01

MATRIX

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

I ACTUAL

$00.00 .

N/A

N/A

N/A

N/A

N/A

N/A r

N/A

N/A

N/A

N/A

FOUND DL

0,7, O I N/A

SOO-IS N/A

<s~

ft

0

UNIT

raL

9

g/mL

9

mL

9

mL

Final page for worklist # 17770

lalyst Signature_5Jl

D yst Signature Date lDate

Z)a/a Entry Comments:

Units shown for QC (SPK & STD) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number,R = Replicate Number, A = Aliquot Code.

worklistrpt Version 2.105/15/9504/28/9710-50

PaZe:


Analyst: Instrument: BA000 Book #

Method: LO-160-103 Rev/Mod HNF-SD-WM-DP-254, REV. 0Worklist Comment: T-201 C192 SEG # 3 RISER 3 EXTRUSION

GROUP PROJECT

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

An

S TYPE

1 INSTCHK01

2 INSTCHK02

3 SAMPLE

4 SAMPLE

5 SAMPLE

6 SAMPLE

7 SAMPLE

8 SAMPLE

9 SAMPLE

10 SAMPLE

11 SAMPLE

12 SAMPLE

S97T000681 0

S97T000681 0

S97T000681 0

S97T000681 0

S97T000681 0

S97T000681 0

S97T000681 0

S97T000681 0

S97T000681 0

S97T000681 0

TEST

EXTRUD01

EXTRUD01

DLIQV0L1

DLIQWT01

EST.G/ML

EXTRUD01

LLIQWT01

NOTEBOOK

SLDVOL01

SLDWT-01

APPEAR01

ORGVOL01

MATRIX ACTUAL FOUND DL UNIT

SOLID ZD-00 8D,Q\ N/A

SOLID

mL

g

g/mL

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

5)0,13 N/A

<25O

50O,tf

i./a

(4WFM-3/

K>7A


alyst Signature Dafe^AeXA^VoNrK^

Aaalyst Signature 'ate

^f

Z>afa Entry Comments:


worklistrpt Version 2.1 05/15/9504/28/9710:51 L A B C O R E

SD WM DP 246, nCV. Q'

E n t r y T e m p l a t e for Worklist# 17772

Analyst: Instrument: BAOOO Book # M A

Method: LO-160-103 Rev/Mod HNF-SD-Wy-DP-254, REV. 0

Worklist Comment: T-201 C192 SEG # 4 RISER 3 EXTRUSION

GROUP PROJECT

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

S TYPE

1 INSTCHK01

2 INSTCHK02

3 SAMPLE

4 SAMPLE

5 SAMPLE

6 SAMPLE

7 SAMPLE

8 SAMPLE

9 SAMPLE

10 SAMPLE

11 SAMPLE

12 SAMPLE

SAMPLE* R A

S97T000682 0

S97T000682 0

S97T000682 0

S97T000682 0

S97T000682 0

S97T000682 0

S97T000682 0

S97T000682 0

S97T000682 0

S97T000682 0

-TEST

EXTRUD01

EXTRUD01

DLIQVOL1

DLIQUT01

EST.G/ML

EXTRUD01

LLIQWT01

NOTEBOOK

SLDVOL01

SLDUT-01

APPEAR01

ORGVOL01


SOLID 7fifi°__ 90, 0 | N/A

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

ft'-"

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

^CQ, | 3 N/A

Q5O

hoi

<S

HkF-W-ftl

O)T>


Analyst Signature Date' Analyst Signature Date

Data Entry Comments:

Units shown for QC (SPK & STD) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number,R — Replicate Number, A = Aliquot Code.

worklistrpt Version 2.1 05/15/95 -HNF SD WM DP 216, REV. 0 Wf04/30/97 21-16 /-'H I

LABCORE Data Entry Template for Worklist# 17861Analyst: Instrument: BA000 Book I U / A

Method

Worklii

GROUP

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

1: LO-160-103 Rev/Mod

st Comment: T-201 Cl

PROJECT

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

S TYPE

1 INSTCHK01

2 INSTCHK02

3 SAMPLE

4 SAMPLE

5 SAMPLE

6 SAMPLE

7 SAMPLE

8 SAMPLE

9 SAMPLE

10 SAMPLE

11 SAMPLE

12 SAMPLE

92 SEG #

SAMPLE*

S97T000691

S97T000691

S97T000691

S97T000691

S97T000691

S97T000691

S97T000691

S97T000691

S97T000691

S97T000691

1 RISER


3 EXTRUSION

R A TEST

0

0

0

0

0

0

0

0

0

0

EXTRUD01

EXTRUD01

DLIQVOL1

DLIQUT01

EST.G/ML

EXTRUD01

LLIQUT01

NOTEBOOK

SLDVOL01

SLDUT-01

APPEAR01

ORGVOL01

MATRIX

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

! ACTUAL FOUND DL

26-0° J^O.D\ N/A

feofiO ScoAl N/A

N/A O^S D

N/A 'CAJ& ,G>

N/A I / 0r~

N/A CD^pUJfcC

N/A ^S>

N/A H K)f*-kro I

N/A t j

N/A SL

N/A CO~'pV^fc£_J

N/A (Si.

0

UNIT

ntL

q

q/mL

q

mi.

q

mL

Analyst Signature


ialyst Signature Date



37

-HNF-SB-WM-DP-246, REV,worklistrpt Version 2.1 05/15/9504/^0/07 91-77


Page: 1

Analyst: Instrument: BA000 Book#

Method: LO-160-103 Rev/Modi ?>0Worklist Comment: T-201 C192 SEG # 5 RISER 3 EXTRUSION

GROUP

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

PROJECT

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

S TYPE

1 INSTCHK01

2 INSTCHK02

3 SAMPLE

4 SAMPLE

5 SAMPLE

6 SAMPLE

7 SAMPLE

8 SAMPLE

9 SAMPLE

10 SAMPLE

11 SAMPLE

12 SAMPLE

SAMPLE*

S97T000687

S97T000687

S97T000687

S97T000687

S97T000687

S97T000687

S97T000687

S97T000687

S97T000687

S97T000687

R A TEST

0

0

0

0

0

0

0

O

0

0

EXTRUD01

EXTRUD01

DLIQV0L1

DLIQWT01

EST.G/ML

EXTRUD01

LLIQUTO1

NOTEBOOK

SLDVOL01

SLDWT-01

APPEAR01

ORGVOL01

MATRi:

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID


MATRIX ACTUAL FOUND

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

.TDl Q N/A

S>5O

\,O9

riWr- hj'Ri

Analyst Signature


ate ialyst Signature Date


Units shown for QC (SPK & STD) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number,R = Replicate Number, A ~ Aliquot Code.

worklistrpt Version 2.1 05/15/9504/30/9721:18


Analyst: Instrument: BA000 Book#

Method: LO-160-103 Rev/Mod 1? O

Worklist Comment: T-201 C192 SEG # 6

GROUP

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

PROJECT

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

S TYPE

1 INSTCHK01

2 INSTCHK02

3 SAMPLE

4 SAMPLE

5 SAMPLE

6 SAMPLE

7 SAMPLE

8 SAMPLE

9 SAMPLE

10 SAMPLE

11 SAMPLE

12 SAMPLE

SAMPLE!*

S97T000688 0

S97T000688 0

S97T0006S8 0

S97T000688 0

S97T000688 0

S97T000688 0

S97T000688 0

S97T000688 0

S97T000688 0

S97T000688 0

RISER 3 EXTRUSION

R A TEST

EXTRUD01

EXTRUD01

DLIQVOL1

DLIQUT01

EST.G/ML

EXTRUD01

LLIQWT01

NOTEBOOK

SLDVOL01

SLDWT-01

APPEAR01

ORGVOL01

MATRI)

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID


MATRIX ACTUAL FOUND

3O. CO N/A

N/A

IVKF-VJ-3I

g/mL

Analyst Signature 0 Date


Analyst Signature Date

Date Entry Comments:


workhstrpt Version 204/30/9721:19

Analyst: J

.105/15/95 "-TV

LABCORE Data

Method: LO-160-103 Rev/Mod

Entry Template

Instrument: BA000

Bo

^-l-iq-qi Page: 1

for Worklist# 17864

Book# ^i )fQ


Worklist Comment: T-201 C192 FIELD BLANK RISER 3 EXTRUSION

GROUP PROJECT

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

S TYPE

1 INSTCHK01

2 INSTCHK02

3 SAMPLE

4 SAMPLE

5 SAMPLE

6 SAMPLE

7 SAMPLE

8 SAMPLE

9 SAMPLE

10 SAMPLE

11 SAMPLE

12 SAMPLE

SAMPLE#

S97T000690

S97T000690

S97T000690

S97T000690

S97T000690

S97T000690

S97T000690

S97T000690

S97T000690

S97T000690

R

0

0

0

0

0

0

0

0

0

0

A TEST

EXTRUD01

EXTRUD01

DLIQVOL1

DLIQWT01

EST.G/ML

EXTRUD01

LLIQWT01

NOTEBOOK

SLDVOL01

SLDWT-01

APPEAR01

ORGVOL01

MATRIX

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

ACTUAL FOUND DL UNIT

faei.oo SOO' 13 N/A

N/A C>5O itlL

N/A y ^ l o / U 3

N/A / I ) CJ/mL

N/A COT^->Y^-^-A1-^_J

N/A S i q

N/A H"K)P~ K)"o I

N/A Ci l mL

N/A C^ q

N/A CO^^f^^—1_^-^—'

N/A ^ > ^ mL

An


alyst Signature Date•

Analyst Signature

flora £«»y Comments:

Units shown for QC (SPK & STD) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number,R = Replicate Number, A — Aliquot Code.

worklistrpt Version 2.1 05/15/9504/30/9721:20 L A B C O R E

•tlNf-OD-WM DP 246, REV. QPage: 1

Entry Template for Worklist# 17865

Analyst:

Method

Worklii

GROUP

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

JLJPI: LO-160-103 Rev/Mod

st Comment: T-201 CIS

PROJECT

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

S TYPE

1 INSTCHK01

2 INSTCHK02

3 SAMPLE

4 SAMPLE

5 SAMPLE

6 SAMPLE

7 SAMPLE

8 SAMPLE

9 SAMPLE

10 SAMPLE

11 SAMPLE

12 SAMPLE

Instrument:

U SEG # 7 RISER

SAMPLE*

S97T000692

S97T000692

S97T000692

S97T000692

S97T000692

S97T000692

S97TO00692

S97T000692

S97T000692

S97T000692

R A

0

0

0

0

0

0

0

0

0

0

BA000

3 EXTRUSION

- - -TEST

EXTRUD01

EXTRUD01

DLIQV0L1

DLIQUT01

EST.G/ML

EXTRUD01

LLIQUT01

NOTEBOOK

SLDVOL01

SLDWT-01

APPEARO1

ORGVOL01

MATRIX

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

Book # U A

HNF-SD-WM-DP-254,

ACTUAL FOUND DL

2P£ 9X>, 0 0 N/A

50ox>0 5oo, 12_ N/A

N/A ft

N/A XT

N/A O ^

N/A Cct^pUjA-c

N/A N)

N/A UWF-l0"5>i

N/A t O ] A

N/A 5BT" I O

N/A C^Yw^pU^K.-.

N/A S

REV.O

UNIT

mL

g

g/mL

g

mL

g

mL


st Signature ") Date " Analyst Signatdre '0 Date *



91

worklistrpt Version 2.1 05/15/9504,30/9721:21 L A B C Q R E

E n t r y T e m p i a t e f o r Worklist# 17866

Analyst: ~Z

Method: LO-160

Worklist Comm<

GROUP PROJECT

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

Z£--103 Rev/Mod

ait: T-201 C l

S TYPE

1 INSTCHK01

2 INSTCHK02

3 SAMPLE

4 SAMPLE

5 SAMPLE

6 SAMPLE

7 SAMPLE

8 SAMPLE

9 SAMPLE

10 SAMPLE

11 SAMPLE

12 SAMPLE

Instrument:

[ %0

92 SEG # 8 RISE

SAMPLE#

S97T000689

S97T000689

S97T000689

S97T000689

S97T000689

S97T000689

S97T000689

S97T000689

S97T000689

S97T000689

R A --

0

0

0

O

0

0

0

0

0

0

: BAO0O

ER 3 EXTRUSION

TEST

EXTRUD01

EXTRUD01

DLIQV0L1

DLIQUT01

EST.G/ML

EXTRUD01

LLIQUT01

NOTEBOOK

SLDVOL01

SLDWT-01

APPEAR01

ORGVOL01

MATRIX

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

Book# )OA

HNF-SD-WM-DP-254,

ACTUAL FOUND DL

&P° 8 a oo N/fl

Sf°'° 5O0.I2. N/A

N/A Cx

N/A Kl.

N/A 1$)

N/A C^KsftJJM^

N/A t i

N/A W-KF-U^i

N/A ^S

N/A 3 ~^rSU

N/A CO^-pLobo

N/A &>

REV.O

UNIT

mL

. 9

g/mL

9

ItlL

g

mL

4nalyst Si


lyst Signature Date lyst Signafu Date



92


SAMPLE PREPARATIONS



94

workUstrpt Version 2.1 05/15/9505/24/9706:04

-HNF°SB-WM-DP-246, REV. Page:

for Worklist# 18077

/ nalyst:

P Mhod

J<MTI: LA-549-141 Rev/Mod

Instrument:: FUS01

"'wfclist Comment: T-201 FUSION DIGEST C192S6UH.LH,

COUP

"7000311

'17000311

'17000311

17000311

17000311

17000311

•7000311

•7000311

•7000311

T7000311

T7000311

<>7000311

PROJECT

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

S TYPE

1 BLNK-PREP

2 SAMPLE

3 SAMPLE

4 DUP

5 DUP

6 SAMPLE

7 SAMPLE

a DUP

.5TO33 -9 DUP

10 SAMPLE

.41,17 -11 SAMPLE

12 DUP

13 DUP

SAMPLE*

S97T000901

S97T000901

S97T000901

S97T000901

S97T000919

S97T000919

S97T000919

S97T00O919

S97T000921

S97T000921

S97T000921

S97T000921

R

0

TL0

0

0

0f

0

0

L0

0

0

0

L0

A - •

F

F

F

F

F

F

F

F

F

F

F

F

• TEST

FUSION01

FUSION01

DOSE-02

FUSION01

DOSE-02

FUSION01

DOSE-02

FUSION01

DOSE-02

FUSION01

DOSE-02

FUSION01

DOSE-02

7LH

MATRIX

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLJP

SOLID

SOLID

SOLID

Book#


lad

ACTUAL FOUND

/ .2S0

N/A -3.6112

N/A ^ . O

2.w/a Awn

N/A lJl<CX

N/A ^..S~

/..S- AS-

N/A i.mN/A ^ - . O

DL

N/A

' N/A

N/A

N/A

N/A

N/A

N/A

UNIT

- 9 / 1

g/L

mrad/hour

. S/L

mrad/hour

g/L

mrad/hour

_ 9 A

mrad/hour

- S / L

mrad/hour

g/L

mrad/hour


Analyst Signature


Date

n /

OLJ

Units shown for QC (SPK & STD) may not reflect the actual units. DL = Detection limit, S — Worklist Slot Number,R — Replicate Number, A = Aliquot Code.

-HNF-SB WM-DP-246, REV.workttstrpt Version 2.105/15/95 '~'"1~l ' Page: 1


Analyst:

Method:: LA-549-141 Rev/Mod

Instrument:: FUS01

^orklist Comment: T-201 FUSION DIGEST C192S7UH,

raoup

V000311

•>7000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

PROJECT

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

S TYPE

1 BLNK-PREP

2 SAMPLE

3 SAMPLE

4 DUP

5 DUP

e SAMPLE

7 SAMPLE

8 DUP

SAMPLE*

S97T000920

S97T000920

S97T000920

S97T000920

S97T000922

S97T000922

S97T000922

9 DUP S97T000922

10 SAMPLE

11 SAMPLE -

12 DUP

13 DUP .

S97T000923

R A -

0 F

0 F

0 F

0 F

0 F

0 F

0 F

>je0 F

0 F

, ~v. -zso 4S97T000923 0 F

S97T000923

S97T000923

0 F

a.0 F

*

8UH.LH

• TEST .— MATRIX

FUSIOM01 SOLID

FUSION01

DOSE-02

FUSION01

DOSE-02

FUSION01

DOSE-02

FUSION01

DOSE-02

FUSION01

DOSE-02

FUSION01

DOSE-02

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

Book # Aj/ft


lad

ACTUAL

N/A

N/A

N/A

N/A

<o.'S

N/A

N/A

FOUND DL

<osJ.oSIA

J.03OD

<0.S"

J.O/L&

I.W8

N/A

N/A

N/A

N/A

N/A

•

N/A

N/A

UNIT

. 9/L

. 9/L

mrad/hour

mrad/hour

_9/L

mrad/hour

_9/L

mrad/hour

- 9 / 1 -

mrad/hour

3/L

mrad/hour

Final page for workli

Analyst Signature DitT Analyst Signature Date


Units shown for QC (SPK & SID) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number,R = Replicate Number, A — Aliquot Code.

'HNF-SD.WMiDP.246, REV. QfcjW?workUstrpt Version 2.105/15/95 I-VWI page:

o6/2S/97io:55 L A B C O R E D a t a E n t r y Template for Worklist# 18531

Analyst: ^

Method

Worklii

-GROUP

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

I: LA-549-141 Rev/Mod

it Comment: T-201 Fus

PROJECT

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

S TYPE

1 BLNK-PREP

2 SAMPLE

3 SAMPLE

\ DUP

5 DUP "

6 SAMPLE

7 SAMPLE

8 DUP

9 DUP

Instrument:

F-Dion Digest C192

SAMPLE*

S97T001248

S97T001248

S97T001248

S97T001248

S97T001255

S97T001255

S97T001255->

S97T001255

. R A - -

0 F>->' •—=

0 F

0 F

f- —=0 F

0 F

0 F

0 F

0 F

FUS01

Core Comps

TEST

FUSION01

' DOSE-02

FUSION01 yj

DOSE-02

FUSION01

DOSE-02

FUSI0H01

DOSE-02

lad

MATRIX

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

£

SOLID

Book # M//!

HNF-SD-WM-DP-254,

ACTUAL .fOUND Dl

/ ^ / ^ ^ - ^

N/A / • / ~r !(<?

N/A

i

N/A

N/A

N/A

N/A

N/A

N/A

REV.O

UNIT

g/L

g/L

mrad/hour

g/L

mrad/hour

g/L

mrad/hour

g/L

mrad/hour



Analyst Signal Date


9177-1'2 jg}/»P yUnits shown for QC (SPK & SID) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number,R = Replicate Number, A = Aliquot Code.

97

HNF-SD-WM-DP-254.REV.0LABCORE Data Entry Template for Worklist# 19308

Page:

Analyst:

MethodI: LA-549-141 Rev/Mod

Instrument:

F-0FUS01

WorkHst Comment: T-201 Fusion Digest C192 Core Comps

GROUP

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

PROJECT

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

S TYPE

1 BLNK-PREP

2 SAMPLE

3 SAMPLE

4 DUP

5 DUP

6 SAMPLE

•Iff1/7 SAMPLE

8 DUP

9 DUP

SAMPLE*

S97T001753

S97TOo'i753_

S97T001753

S97T001753

S97T001754

S97T001754

S97T001754

S97T001754

R A —

0 E,

0 F^,

0 F

O F .

fa/?0 F

O F ,

0 F

TEST—

FUSI0N01

FUSI0N01

— DOSE-02

7FUSION01

DOSE-02

FUSION01

DOSE-02

FUSION01

00SE-02

lad

MATRIX

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

Book#

ACTUAL

7N/A

N/A

IM1i f

N/A

N/A

FOUND DL

1.111-IfI.Wl

to

N/A

N/A

N/A

N/A

N/A

UNIT

g/L

g/L

mrad/hour

_ S/L

mrad/hour

g/L

mrad/hour

g/L

mrad/hour

Analyst Signature-^ Date


~?//7A7Signature Date

Data Entry Comments:7/n/<r\

Units shown for QC (SPK & STD) mas not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number,R = Replicate Number, A = Aliquot Code.

'-HNF=SB-V\rM-De=246r•-vklistrpt Version 2.105/15/95 / « / / j ^ .

2'97O6W LABCORE Data Entry Template for Worklist# 18079

^alyst :

7 ethod:

T'rtrkHsi

~-"XJP

.•7000311

77000311

77000311

•7000311

7/000311

"i'000311

T000311

HTJ00311

n'000311

97000311

S7000311

S7000311

LA-504-101 Rev/Mod

t Comment: T-201 H2

PROJECT

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

S TYPE

1 BLNK-PREP

2 SAMPLE

3 SAMPLE

4 DUP

5 DUP

6 SAMPLE

.S63O-7 SAMPLE

8 DUP

9 DUP

10 SAMPLE

11 SAMPLE

12 DUP

Instrument:

i F-C)

O DIGEST C192

SAMPLE*

S97T000900

H2O01

S6LH.UH 7LH

R A TEST

H2ODIG01

0 W

-^ /OOLS97T000900 0 U

S97T000900

S97T000900

S97T000915

—^>IOCS97T000915

S9n000»15

S97T000915

S97T000931

-> ;/0OS97T000931

S97T000931

13 DUP S97T000931

0 W/

0 U

O W

•>L.

0 u

0 W

L0 U

0 U

L0 U

0 W

L0 W

H200IG01

DOSE-02

H2OCIG01

DOSE-02

H20CIG01

DOSE-02

H20DIG01

DOSE-02

H2OOIG01

DOSE-02

H20OIG01

DOSE-02

lad

MATRIX

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

Book # til Pi

HNF-SD-WM-DP-254,

ACTUAL

/

N/A

N/A

V.9SO

N/A

N/A

S-.03Q

N/A

N/A

1/SL6

FOUND DL

JonV.9S0

V.9O3

<0,5

S-.t)3O

s:m

1 VSLO

<0.5vsm

<Q,S

N/A

<-&*

N/A

N/A

N/A

N/A

N/A

N/A

REV.O

UNIT

g/L

g/L

' mrad/hour

g/L

mrad/hour

9/L

mrad/hour

g/L

mrad/hour

g/L

tnrad/hour

. g/L

mrad/hour .

Final page for worfcttst # 18079

5


Signature Date

97

9,5-HI

" 'nits shown for QC (SPK & STD) may not reflect the actual units. DL = Detection Limit, S = Wotkltst Slot Number," = Replicate Number, A = Aliquot Code.

-i INr-SD WM DP 216, ^ / n•'•orklistrpt Version 2.1 05/15/95 Page: 1

C5/24/9? 06:05 L A B C Q R E D a t a E n t r y Template for Worklist# 18081

Final page for wor

Analyst SSignature Date

Dato finiry Comments:

' ^ y s t :

" Tethod

"""rklisi

1ROUP

•7000311

-7000311

•7000311

-7000311

•7000311

•7000311

•7000311

•7000311

•7000311

•7000311

•7000311

•7000311

LA-504-101 Rev/Mod

t Comment: T-201 H2

PROJECT

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

S TYPE

1 BLNK-PREP

2 SAMPLE

3 SAMPLE

4 DUP

5 DUP

6 SAMPLE

7 SAMPLE

8 DUP

9 DUP

10 SAMPLE

11 SAMPLE

12 DUP

13 OUP

Instrument:

3 DIGEST C192S

H2O01

7UH, 8UH,

SAMPLE* R A - — — T E S T

H20DIG01

S97T000916 0 W_% . IOO JtS97T000916 0 W

S97T000916 0 U

-=> . too JlS97T000916 0 U

S97T000917 0 H

-? -\dOJLS97T000917 6 H

S97T000917 0 W

S97T000917 0 W

S97T000918 0 W

S97T000918 0 U

S97T000918 0 W

-> . \oo 3-S97T000918 0 U

H2ODIG01

DOSE-02

H2ODIG01

DOSE-02

H20DIG01

DOSE-02

H2ODIG01

DOSE-02

H20DIG01

DOSE-02

H2ODIG01

OOSE-02

LH lad

MATRIX

SOLID

SOLID

SOLID

SOLIO

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID '

Book # til/ I)HNF-SD-WM-DP-254,

ACTUAL FOUND DL

1 .100 H/A

H/A 5-161

N/A J0ks^'

S.iol q.<\72•Cff.S iO.S

N/A V.«?8/

||/A^ J~-n?&

H/A 5-&Ko<O.B

N/A ^ - r d 5

S.cfK. *f.ta2>

H/A

it*, e/ts/iH/A

H/A

N/A

M/A

H/A

REV.O

UNIT .[

9/L

g/t.

mrad/hour

g/L ;

7 ' :mrad/hour ,-

9/L

7mrad/hour

/ L

mrad/hour

mrad/hour

9/L

mrad/hour

'Jnits shown for QC (SPK & STD) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number,R = Replicate Number, A = Aliquot Code.

1OO

voMstrpt Version 2.1 05,15,95

06,28,9710:56 L A B C O R E D a t a E n t r y Template for Worklist# 18534

Analyst: Instrument: H2O01 Book#

Method: LA-504-101 Rev/Mod HNF-SD-WM-DP-254, REV. 0Worklist Comment: T-201 H2O Digest C192 Core Comp lad

GROUP PROJECT

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

S TYPE

1 BLNK-PREP

2 SAMPLE

3 SAMPLE

4 DUP

5 DUP

6 SAMPLE

7 SAMPLE

8 DUP

9 DUP

S97T001251 0 H.

S97T001251 0 W

S97T001251 0 U

S97T001251 0 W

S97T001257 0 U

S97T001257 0 U

S97T001257 0 U

) ~^? . (&Z

S97T001257 0 W

---TEST

H2ODIG01

H2ODIG01

DOSE-02

H2ODIG01

DOSE-02

H20DIG01

DOSE-02

H2ODIG01

DOSE-02


SOLID _J_ O.IW N/A g/L

SOLID N/A ¥I9ZH) g/L

SOLID N/A ^ _ ^F^*^mrad/hour

SOLID 4.92X6 tf,%j4D N/A g/L

-COS / s—

SOLID . & j i f ^ '•-> N/A mrad/hour

SOLID N/A 6,!)LC£> g / L

SOLID N/A <C /Smrad/hour

SOLID 6,bU>O S.DIIO N/A g/L

SOLID Wfe < O N/A mrad/hour


Date Analyst Signature Date


Units shown for QC (SPK & STD) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number,

R = Replicate Number, A = Aliquot Code.

HNF-SD-WM-DP-254, REV. 0worklistrpt Version 2.105/15/95 . Page: 1

06/28/9710:55 L A B C Q R E D a t a ^ ^ T e m p l a t e for WorkUW 18533

Analyst:

Method:

• \

: LA-505-163 Rev/Mod

Instrument: ACD01

ft -0WorKlist Comment: T-201 Acid Digest C192

GROUP

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

PROJECT

T-201

T-201

T-201

T-201

T-20T

T-201 &

T-201

T-201 *•**

S TYPE

1 STD-PREP

2 BLNK-PREP

3 SAMPLE

4 SAMPLE

5 DUP

6 DUP

7 SAMPLE

8 SAMPLE

9 DUP

' ^ " D U P " " 1 ^

SAMPLE#

S97T001250

— 5 . O S OS97T001250

S97T001250- -=» .050S97T001250

S97T001256

S97T001256.

S97T001256

S97T001256

R A

0 A

JL0 A

0 AJi0 A

0 A

0 A

0 A

r-0 A

Core Comps

TEST

ACIDIG01

ACIDIG01

ACIDIG01

DOSE-02

ACIDIG01

DOSE-02

ACIDIG01

DOSE-02

ACIDIG01

DOSE-02

*

lad

MATRIX

SOLID

SOLID?.;

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

Book # uric -

ACTUAL

N/A

N/A

7.0S8

•*£

N/A

N/A

7.0/3.

FOUND

.OSO

7.068

<.S7. id

< 5

7.«/a

<.S

<S

DL

N/A

N/A

N/A

N/A

N/A

N/A

UNIT

. g/L

g/L

mrad/hour

g/L

mrad/hour

. g/L

mrad/hour

. g/L

mrad/hour


Analyst Signature7

Date 'AiSlyst Signature"

•7 /f/11

Date

Data Entry Comments: rifff. £> ;

Units shown for QC (SPK & STD) may not reflea the actual units. DL = Detection Limit, S = Worklist Slot Number,R = Replicate Number,. A = Aliquot Code.

102

•vqrklistrpt Version 2.105/15/95 HNF-SD-WM-DP-254, REV. 0 Page:fY7H)RIQ'7 W'tQ

LABCORE Data Entry Template for Worklist# 19175Analyst:

Method: LA-505-163 Rev/Mod

Instrument: ACD01 Book#

^orkDst Comment: ACIDIGOl (T-201 CORE 192 SEG CORE COMP SOLIDS,DL)

"7000311

"7000311

97000311

97000311

"7000311

"7000311

97000311

97000311

97000311

97000311

"7000311

"7000311

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

S TYPE SAMPLE* R A TEST MATRIX

1 BLNK-PREP ACIDIG01 SOLID

2 STD-PREP ACIDIG01 SOLID

3 SAMPLE S97T001250 0 A ACIDIG01 SOLID

4 SAMPLE^ S97T001250 0 A DOSE-02 SOLID

5 DUP S97T001250 0 A ACIDIGOl SOLID

6 DUP J S97T001250 0 A DOSE-02 SOLID

7 SPK S97T001250 0 A ACIDIGO1 . SOLID

8 SPK J S97T001250 0 A DOSE-02 SOLID

9 SAMPLE S97T001256 0 A ACIDIGOl SOLID

.2 3*.- .O6O

10 SAMPLE J S97T001256 0 A DOSE-02 SOLID

11 DUP S97T001256 0 A ACIDIG01 SOLID

12 DUP 0 S97T001256 0 A DOSE-02 SOLID

13 SPK S97T001256 0 A ACIDIG01. SOLID

14 SPK' O ' S97T001256 0 A DOSE-02 SOLID

ACTUAL FOUND DL

/ • .

UNIT

N/A g/L

ofc) N/A

.g/L

mrad/hour

H/A g/L

N/A mrad/hour

N/A g/L

t.r

N/A mrad/hour

g/L

mrad/hour

N/A g/L

N/A mrad/hour

N/A

LC i.r N/A mrad/hour


'Jnits shown for QC (SPK & STD) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number,.?. —• Replicate Number, A = Aliquot Code.


BULK DENSITY WORKSHEETS


THIS PAGE INTENTIONALLY LEFT BLANK.

105

Requestor:,

Tank:. Core:

. Seg: _Auger: _.Sample ID

Time (Mm;):

Jar/Vial -SizInitial Weight!Final;Net Weight;_

"Cone//:Final AInitialFinal Weight: _^2Jji__ gNet'Weight: 'nJJd>'Jl_ gSample ID:

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INORGANIC ANALYSES

1 1 1



112

worMistrptVersion^l 05/15/95 -"HNFSWArWeP^ - - - ™ / ^ .

osaamosM L A B C O R E D a t a E l j t r y T e m p l a t e for Worklist# 18271

Analyst: ?JM Instrument: DSCQ 3 Book#-

Method: LA-514-114 Rev/Mod _ J ^ 0 ' ' " _ HNF-SD-WM-DP-254, REV. 0

WorWist Comment: T201, DSC-01 Run under Nitrogen, skm

GROUP PROJECT S TYPE SAMPLE* R A TEST- MATRIX ACTUAL FOUND DL UNIT-

1 STD DSC-03 LIQUID dS-VS" £7 33%' H/A Joules/g

97000311 T-201 2 SAMPLE S97T000823 0 DSC-03 LIQUID H/A O Joules/g

97000311 T-201 3 DUP S97T000823 0 . DSC-03 LIQUID O O H/A Joules/g

97000311 T-201 4 SAMPLE S97T000633 0 DSC-03 LIQUID H/A D Joules/g'

97000311 T-201 5 DUP S97T000833 0 DSC-03 LIQUID O D H/A Joules/g


5>eAnalyst Signature 1)ate Analyst Signature Date


Units shown for QC (SPK & SID) may not reflect the actual units. DL - Detection Limit, S = Worklist Slot Number,R = Replicate Number, A = Aliquot Code.

113

workhstrpt Version 2.1 05/15/9505/23/9708:27

Page: I

for 18271

Analyst:


Instrument: DSCO *3 Book#

HNF-SD-WM-DP-254, REV. 0Worldist Comment: T201, DSC-01 Run under Nitrogen, skm

S TYPE SAMPLE* R A TEST MATRIX ACTUAL FOUND DL UNIT

1 STD DSC-01 LIQUID N/A Joules/g

2 SAMPLE S97T000823 0 DSC-01 LIQUID N/A ; Joules/g

3 DUP S97T000823 0 DSC-01 LIQUID N/A Joules/g

4 SAMPLE S97T000833 0 DSC-01 LIQUID N/A Joules/g

5 DUP S97T000833 0 DSC-01 LIQUID

97000311 T-201

97000311 T-201

97000311 r-201

97000311 T-201


tIHjpXs&ttnX.±& ^i Signature Date

H/A Joules/g


ita Entry Co,

-os.

Vnits shown for QC (SPK & STD) may not refkct the actual units. DL = Detection Limit, S = Worklist Slot Number,R = Replicate dumber, A = Aliquot Code.

-HNP-SD-WM-DP-246, REV. 0 Wfcfc


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Curve l: DSCFile info: SAM052707 Tue May 27 15:58:21 1997Sample Weight: 9.870 mgS97T000823 DUP

>2 S

<00)

X

350,0 -

325.0 -

300.0 -

275.0 -

25o!o -

225.0 -

200.0 -

175.0 -

150.0 -

125.0 -

100.0 -

75.0 -

50.0-

25.0 -

XIX2

Peak

Area

AH JHeight

Onset j

annJ-+£-—\-

49.466 *C

119.000 *C

109.944 *C

21111.292 mJ

2138.935 J/g

285.704vmW

100.697 *C

100.0 200.0I

N2 lOC/mini! JS:t 8 TIME1! 0.0 Bin BATE!: 10.0 C/ain

300.0

Temperature (*C)

400.0 \

PJ MCCOWNPERKIN-ELMER7 Series Thermal Analysis SystemTue May 27 15:59:14 1997

en9

o-a

4ti4P-SD WM DP 246, REV.


1

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(M«l)

s

Curve l: DSCFile info: SAM0S2709 Tue May 27 19:56:34 1997Sample Weight: 19.4B0 mgS97T000833DUP

150.0 -

100.0 -

50.0

"*•

Sej|

X

Hea

t

400.0 -

350.0-

300.0 -

250.0-

200.0 -

XIX2

Peak

Area

AHHeight

Onset

49.466151.200

A 120.472

1 37676.051

I 1934.089

327.152

I 103.216

•c•c•cmJ

J/gmW

•c

100.0

c>C3

200.0

N2 lOC/minU sgS:S g

300.0

Temperature (*C)0.0 nln RATEl: 10.0 c/nin

I : n I400.0

JD SPELUMANPERKIN-ELMER7 Series Thermal Analysis SystemTue May 27 20:23:07 1997

CO

9

33rn

I INr*OD-WM-DP-240rtiEVWHfefp?7worklistrpt Version 2.1 05/15/95 Page: 1

05/29/9709:49 L A B C O R E D a t a E n t r y T e m p l a t e f o r Worklist# 18272

Analyst: JD5> Instrument: DSCO Book# /2A//</g

Method: LA-514-114 Rev/ModHNF-SD-WM-DP-254, REV. 0

Worklist Comment: T201,DSC-01 Run under Nitrogen, skm

GROUP PROJECT

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

S TYPE SAMPLE* R A

1 STD

2 SAMPLE S97T000834 0

3 DUP S97T000834 0

4 SAMPLE S97T000835 0

5 DUP S97T000835 0

--TEST" .

DSC-03

DSC-03

DSC-03

DSC-03

DSC-03

MATRIX

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

ACTUAL

N/A

0

N/A

0

FOUND

0

O

0

r>

DL

' N/A

N/A

N/A

UNIT

Joules/g

Joules/g

Joules/g

Joules/g

Joules/g


SeeAnalyst Signature DateJ Analyst^Signature Date


Units shown for QC (SPK & SID) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number,R = Replicate Number, A - Aliquot Code.

120

worklistrpt Version 2.105/15/95

05/23/9708:28 L A B C O R E D a t a E n t r y T e m p i a t e for Worklist# 18272Page:

Analyst: Instrument: DSCO Book # \1

Method: LA-514-113 Rev/Mod P - 0

Worklist Comment: T201, DSC-01 Run under Nitrogen, skmHNF-SD-WM-DP-254, REV. 0

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

SnalystSi

S TYPE

1 STD

2 SAMPLE

3 DUP

4 SAMPLE

5 DUP

SAMPLE* R A TEST MATRIX ACTUAL FOUND DL UNIT

DSC-01 LIQUID N/A Joules/g

S97T000834 0 DSC-01 LIQUID N/A Joutes/g

S97T000834 0 DSC-01 LIQUID H/A Joules/g

S97T000835 0 DSC-01 LIQUID N/A Joules/g

S97T000835 0 DSC-01 LIQUID


Analyst Signature"

N/A Joules/g

Date

Data Entry

Units shown for QC (SPK & STD) may not reflea the actual units. DL = Detection Limit, S, = Worklist Slot Number,R = Replicate Number, A = Aliquot Code.

1 2 1

Curve 1: DSCFile info: IND052801 Wed May 28 18:56:59 1997Sample Weight: 11.990 rag12N14-B

5.0

0 . 0 -

HHtt

140.0

N2, EXOTHERM DOWN

145.0 150.0

0.0 *tn RATets 10.0 c/ntn

155.0 160.0

Tempepatupe C O

165.0 180.0

JD SPELLHANPEflKIN-ELMEB7 Series Thermal Analysis SystemNed May 28 18:58:50 1997

I 3

71 in

Curve 1: DSCFile info: SAM052804 Wed May 28 20:30:36 1997Sample Height: 19.340 mgS97T000834

cf

400.0 -

350.0 -

300.0 -

250.0 -

200.0 -

150.0 -

100.0 -

50.0-

XI

X2

Peak

Area

AH

Height

Onset

iJt |

55.066 *C

147.466 *C

A 117.486 *C

I 36735.373 mJ

1 1899.451 J/g

1 324.030 mH

102.411 *C

1_L———".—-^ "I

i i i i i

_ — —

i i100.0 aoo.o

o

2o

N2 10C/minS ^S:8 8 0.0 Bin HATEH 10.0 C/nin

300.0

Temperature (*C)

400.0

JO SPELLHANPERKIN-ELMER7 Series Thermal Analysis SystemNed May 28 21:15:55 1997

44NPSP-WM-Dr-24G,


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aI£

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124

Curve 1: DSCFile info: SAM052902 Thu May 89 01:17:55 1997Sample Height: 19.460 rag

S97T0O0B35DUP

in

f

Flow

Hea

t I

400.0 -

350.0 -

300.0 -

250.0-

200.0 -

150.0 -

100.0 -

50 .0 -

XI

X2Peak

Area

AH

Height

Onset

IJ\1 I

49.466 *C

140.000 *C

A 117.345 »C

1 37579.796 BJ

1 1931.130 J/g1 350.267 raW

1 103.189 *C

JH ~~~~

T1CO

o

3JsO

100.0T

200.0

N2 lOC/min

e3S:8 I 0.0 *ln BATGl: 10.0 C/mln

300.0

TeRiperature (*C)

t400.0

JD SPELLMANPERKIN-ELMER7 Series Thermal AnalThu May 29 01:20:55

Is System

Curve 1: DSCFile info: SAM052901 Wed May 28 23:58:56 1997Sample Weight: 16.340 mgS97T000B35

350.0 -

325.0 -

300.0 -

275.0 -

£ 250'. 0 -

a 225.0 -oC 200.0 -

® 175.0 -

150.0 -

125.0 -

100.0 -

75.0-

50.0 -

25.0-

XI 44.800 •CX2 151.200 *CPeak n 115.519 *CArea { 32342.666 mJAH JHeight /Onset

I

1979.355 J/g276.095 mW100.484 *C

-

i i \

_j-Z_ f—L—'—

1 1 i i i i i :i i100.0N2 lOC/min

el BOO:S § 0.0 Bin RATE!: 10.0 C/nln

200.0 300.0

Temperature (*C)

400.0

JO SPELLMANPEHKIN-ELMER7 Series Thermal Analysis SystemThu May 29 00: 28: 45 1997

%CO

9

3

C)

i

f 1

worklistrpt Version 2.105/15/95 .' Page:


Analyst: s )J?z>Method: LA-514-114 Rev/Mod

Instrument: DSCO 3 Book#


Worklist Comment: T201, DSC-01 Run under Nitrogen, skm

GROUP PROJECT

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

S TYPE SAMPLE# R A TEST--'

1 STD DSC-03

2 SAMPLE S97T000836 0 . DSC-03

3 DUP S97T000836 0 DSC-03

4 SAMPLE S97T000837 0 DSC-03

5 DUP S97T000837 0 DSC-03


LIQUID $8-45 rTi: "WV~ N/A Joules/g

LIQUID N/A O_ Joules/g

LIQUID Q V N/A Joules/g

LIQUID N/A O Joules/g

LIQUID O Q_ N/A Joules/9


See -firAnalyst Signature

JDate Date

5^C^*>VM STD fVLfA rJLue hHI

^irve

iih ain c

'Jcx

» i> / lAtorkli

Units shown for QC (SPK & SID) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number,R = Replicate Number, A = Aliquot Code.

127

worklistrpt Version 2.105/15/95 ^-j-HMT-ou-«»»« ~ . - • • , ^05/23/97OR-29

LABCORE Data Entry Template for Worklist# 18273Analyst: ,\fjjj


Worklist Comment: T201, DSC-01 Run under Nitrogen, skm

Instrument: DSCO 3

D-fl HNF-SD-WM-DP-254, REV. 0

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

Analyst

S TYPE

1 STD

2 SAMPLE

3 DUP

4 SAMPLE

5 DUP


DSC-01 LIQUID N/A Joules/g




S97T000837 0 DSC-01 LIQUID


Date Analyst Signature

N/A Joules/g

Date

j

Units shown for QC (SPK & STD) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number,R — Replicate Number, A = Aliquot Code.

Curve 1: DSCFile info: IND052801 Wed May 28 18:56:59 1997Sample Height: 11.990 mg

12N14_B

8

N2, EXOTHERM DOWN

Tggii i « : 8 8 TIME1!

SIGNATURE BELOW REPRESENTS CHEMICAL TECHNaOGIST/CHEMIST THATCOMPLETED/VEFflF^THE CAUBRATON/AMALYSIS <MPPSES/jigJO/JS^.

50.0-

45.0 -

40.0-

35\0 -

30 .0-

25.0-

20.0-

15.0-

10.0 -

5 . 0 -

0 . 0 -140

XIX2Peak

Area

AH

Height

Onset

y~-

i.0 145.0

157.733165.533161.039333.18427.78937.504

158.967

1150.0

•c

•c

mJ jjJ / g /

BlW . /

•c I

___ -+4——^—f~ ~~

i i i i T155.0 160.0 165.0 170.1)

_ _ • •

| J175.0 180

0.0 Bin HKTBU 10.0 O/»inTemperature (*C)

-pCO

o

o-v

I33

m

JD SPELLMANPERKIN-ELMER7 Series Thermal Analysis SystemThu May 29 00:35:23 1997

Curve 1: OSCFile info: SAM052903 Thu May 29 02:17: 36 1997Sample Weight: 20.270 mgS97T000836

ax

450.0 -

400.0 -

350.0 -

300.0 -

250.0 -

200.0 -

150.0 -

100.0 -

50 .0 -

XIX2PeakAreaAHHeightOnset

iAi i

44.800 *C

148.866 *C

A 118.011 *C

j l 40710.129 raJ

I 2008.393 J/g

I 360.614 mW

I 102.077 *C

Xx1

U|_—— "

1 1 1

\

• ^

I I 1 1

N2 IOC/rain

100.0 200.0

71

J3

3

31

-J

0.0 »ln RATE!: 10.0 C/mln

300.0

Temperature (*C)

400.0

JD SPELLMANPEBKIN-ELMER7 Series Thermal Analysis SystemThu May 29 03: 53: 20 1997

Curve 1: DSCFile info: SAM052904 ThU May 29 04: 42: 10 1997Sample Weight: 21.260 mgS97T000836DUP

400.0 -

350.0 -

300 .JO -

250.0 -

200.0-

150.0 -

100.0 -

50.0-

0.0-

XIX2Peak

Area

AHHeight

Onset

JL+£_ 1-

1 ' \

49.466 *C

148.866 *C

A 118.241 *Cjl 42995.502 oJ1 2022.366 J/g

1 375.068 mW

I 101.840 *C

—LH—

1 1 1

_ - - — • — "

— — —

1 1 (

N2 lOC/min

71

o

T3

13

P10

5

100.0

0.0 »ln RATE!: 10.0 C/aln

200.0 300.0

Temperature (*C)

400.0

JD SPEU.MANPERKIN-ELMER7 Series Thermal Analysis SystemThU May 29 08: 52 32 1997

Curve 1: DSCFile info: IND052904 ThU May 89 14:3£ 55 1997Sample Height: 11.990 mg

12N14B

N2.

fso

C

Hea

t

50.0-

45.0 -

40.0 -

35.0-

30.0-

25.0-

20.0-

15.0 -

10.0-

5.0-

o.o-

XIX2Peak

Area

AHHeight

Onset

y

1

158.033 *C

163.800 *C

160.716 *C |

331.778 mJ /

27.671 J/g I

39.367 mH /

158.714 4C /

/

. — '

1 1 1

V^ .

i

• — " ~

0)

CO

9:•in

3J

m140.0

EXOTfCRM DOWN

8:8 8 T1ME1S

145.0 150.0 155.0 160.0 165.0

Temperature (*C)

170.0 175.0 180.0

0.0 Bin RATE!: 10.0 C/mlnRA GREENPERKIN-ELMER7 Series Thermal Analysis SystemThu May 29 14:34:56 1997

Curve 1: DSCFile info: SAM052905 Thu May 29 19:22:34 1997Sample Weight: 21.010 mgS97T000837

450.0-

400.0 -

350.0 -

% 300.0 -

SC 250.0 -

^ 200.0-

150.0-

100.0 -

50.0-

XIX2Peak

Area

AHHeight

Onset

1A

4B.200 *C

155.400 *C

A 119.959 *C

I 43032.092 OlJ

I 2048.172 J/g

I 362.452 mW

1 102.354 »C

1 ^ \1 ^s1 ^v

_ '•"" 1 ' \

100.0 200.0

9 n

2

N2 IOC/raini ^S:8 8 T1Heis 0.0 aln RATBi: 10.0 C/atn

300.0

Temperature (*C)

400.0

JO SPELLMANPERKIN-ELMER7 Series Thernal Analysis SystemThu May 29 20: SS: OS 1997

-HNF-SD-WM-DP-246, REV,n-m-qi


oo

oo s

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•sat

1 3 4

worttistrptVersion2.105/15/95 """ - " " " • " • --™> •"— " - - 7 ^ 4 ^ ^ Page.


Analyst: Instrument: DSCO Book* l%Nli-0Method: LA-514-114 Rev/Mod D - HNF-SD-WM-DP-254, REV. 0WorkUst Comment: T201, DSC-01 Run under Nitrogen, skm

GROUP PROJECT

97000311 T-201

97000311 7-201

97000311 T-201

97000311 T-201

S TYPE SAMPLES R A TEST--'

1 STD OSC-03

2 SAMPLE S97T000899 0 DSC-03

3 DUP S97T000899 0 DSC-OS

4 SAMPLE S97T000909 0 DSC-03

5 DUP S97T000909 0 DSC-03


SOLID & & , l ( 6 off-.Ofi H/A Joules/g

SOLID H/A 0 Joules/g

SOLID 0 D H/A Joules/9

SOLID H/A O Joules/g

SOLID 6 ^


Analyst Si

H/A Joules/g

Date '


Units shown for QC (SPK & STD) may not reflect the actual units. DL - Detection Limit, S - Worklist Slot Number,R = Replicate Number, A = Aliquot Code.

135

Curve 1: DSCFile info: IND060501 Thu Jun 5 OS 39:22 1997Sanple Height: 11.99012N14-B

ng*%i£}£££EL0W REPRESENTS CHEMICAL TECHNOLOGIST/CHEfoiST THATCOMPLEIUWVEfflRBD THE CAUBRAnON/AhlALYSfS Ok P A G E S ^ i ^ X

4 0 . 0 -

3 5 . 0 -

SE 3 0 . 0 -

| 2 5 - °*i 20.0-

15.0-

10.0-

5.0-

XIX2Peak

Area

AHHeightOnset

L/ —

|

159.400 *C165.100 *C161.932 *C323.670 nJ j26.995 J/g /3 0 . 8 9 5 fflW /

159.705 »C /

i f i

3^——^^

05

3J

rno

140.0

N2, EXOTKEIW DOWN

145.0 150.0 155.0 160.0 165.0

Temperature (*C)

170.0 175.0 180.0

a.a »Jn HATBI: ta.o c/»ln

JD SPELLMANPERKIN-E1JCR7 Series Thermal Analysis SystenFri Jun 6 03:35:14 1997

-I INF SD WM DP-246, rtCV. 0 jf^


S S! £ k 5 £ S

S 8 8

5£S

^

o

i

•g

o

s

1 3 7

Curve 1: DSCFile Info: SAM060510 Thu JunSaople Height: 23.320 ngS97T0008990UP

5 23:28:12 1997

11u.

a

175.0-

150.0-

12510-

100.0-

75.0-

50.0-

25.0-

0.0-


iA

51.333155.400

A 118.233

•c•c•c

| 1 30015.675 mJI 11287.1221 1 141.605

1 1 97.772

1

\

\

_--V-

J/gvM

•c

c

CO

9

JO

m

o

i?

100.0 200.0

N2 10C/ninTIMB1: BAT"1:

300.0

Tenperatupe (*C)

400.0

OP BROMLEYPERKIN-EU4ER7 Series Theraal Analysis SistemFri Jun 6 00:16:20 1997

Curve 1: DSCFile info: SAM060511 Fri Jun 6 01:12:59 1997Saaple Nelght: 20.290 mgS97T000909SAM

50.0-

25.0 -

0..0-

~ -25.0 -

s| -50.0-

-75.0 -

-100.0 -

-125.0 -

-150.0 -i

XIX2PeakAreaHiHeightOnaet

| )

51.333 *C163.333 *C

I 118.409 *CA 29994.021 U1 \ 1478.266 J/g| 1 149.215 nMj \ 98.373 #C

1 1 • • . •

N2 lOC/ain'£. -53-8 S

7CO9

100.0

0.0 un mma 10.0 c/»in

200.0 300.0

Temperature (*C)

400.0

OP BROMLEYPERKIN-ELMER7 Series Thermal Analysis SyateaFri Jun 6 01:18:54 1997

Curve i: DSCFile Info: SAK060512 Fri JunSaaple Weight: 31.980 ngS97T000909DUP

0S 17:21 1397

S1-1

225.0-

200.0-

175.0 -

150.0-

125.0 -

100.0-

75.0-

50.0-

25.0-

0.0-

-25.0-

-50.0-

-75.0-

-100.0 -

X2PeakAreaAHHeightOnset

J

49.466 *C. 161.933 *CA 119.818 *CI 1 47830.378 BJI 1 1495.634 J/gI 1 268.929 UN1 106.916 *C

J

1— "^ """"

I-n

9o-a

33

S3

C3

T

N2 10C/nin£ JS-S 8 TXmit

100.0

o.o Bin BATBt lo.o e/aln

200.0 300.0

Teaperature (*C)

400.0

OP BROMLEYPERKXN-EUCR7 Ser ies Theraal Analysis SystenFri Jun 6 03:23:08 1997

Work,istrpt Version 2.1 05/15/95 °HNr*OD-WM DP 246,

06/03/9715:28 L A B C O R E D a t a E n t r y T e m p i a t e f o r Worklist# 18279

Analyst: Instrument: DSCO Book #

Method: LA-514-114 Rev/Mod HNF-SD-WM-DP-254, REV. 0Worklist Comment: T201, DSC-01 Run under Nitrogen, skm

GROUP PROJECT

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

S TYPE SAMPLE* R A —

1 STD

2 SAMPLE S97T000910 0

3 DUP S97T000910 0

4 SAMPLE S97T000911 0

5 DUP S97T000911 0

-TEST

DSC-03

DSC-03

DSC-03 •.

DSC-03

DSC-03

MATRIX

SOLID

SOLID

SOLID

SOLID

SOLID

ACTUAL

N/A

0

N/A

o

FOUND

0

0

o

0

DL

N/A

H/A

N/A

UNIT

Joules/g

Joules/g

Joules/g

Joules/g

Joules/g


Analyst Signature Date ^Analyst Signature Date


^•Units shovmfor QC (SPK & SID) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number,R = Replicate Number, A — Aliquot Code.

141

worklistrpt Version 2.105/15/9505/23/9709:45 L A B C O R E

Page:

E n t r y T e m p I a t e f o r Worklist# 18279

Analyst:


Instrument: DSCO Book#

HNF-SD-WM-DP-254, REV. 0Worklist Comment: T201, DSC-O1 Run under Nitrogen, skm

SAMPLE* R A TEST MATRIX ACTUAL FOUND

97000311

97000311

97000311

T-201

T-201

T-201

1

2

3

4

STD

SAMPLE

DUP

SAMPLE

S97T000910

S97T000910

S97T000911

0

0

0

DSC-01

DSC-01

DSC-01

DSC-01

SOLID Sb'•(£" otf-18 N/A Joules/g

SOLID M/A Joules/g

SOLID

SOLID N/A

97000311 T-201 5 DUP S97T000911 0 DSC-01 SOLID

.A**4M.ft{-



N/A Joules/g

Joules/g

H/A Joules/g


Data Entry Comments:EL. iU


Curve 1: DSCFile info: IND053001 Fri May 30 05:50:39 1997

Sample Height: 11.990 ng SIGNATURE BELOW REPRESENTS CHEMICAL TECHNOLOGIST/CHEMIST THAT12W4-B COMPLETED/VEFnRffi1THECAlBRATION/ANALVSfSONPAGESfi(lL.TO/SLZ-

IIIL.'

30

25

20

.0-

.0-

« •

.0-


161.700170.333164.598311.44925.97620.342162.121

•c•c

•c

J/g

nw•c

*

10.0-

5.0

o.o-

140.0T

145.0

N2, EXOTHEHM DOWN

S i « : 8 S TIME1!

150.0 155.0

0.0 ntn RATBl: 10.0 c/aln

160.0

Temperature (*C)

165.0 170.0 175.0

3•o! 3

SM FULTONPERKIN-aMER7 Series Thermal Analysis SystemFri May 30 05:81:59 1997

Curve 1: DSCFile info: SAM053005 Fri May 30 10:30:05 1997Sample Height: 16.320 ag

S97T000910

2

70.0 -

60.0-

50.0-

40'.0-

30.0-

20.0-

10.0-

0.0-

-10.0 -

-20.0 -

-30.0-

-40.0-

-50.0-

N2 IOC/Dinsoo:8 8

X2

Peak

Area

AH

Height

Onset

I

1A1 1

100

TIHEl: 0.0

52.

178.

\ 123.

/ \i498

/ \ 81

/ 1 *°

.0

nln HATE1:

733

733

073

767

296

246

\

\

to

•c•c•cmJ

J/g

•c

1 i 1200.0 300.0

Temperature (*C).0 C/min

I l 1400.0

SM FULTONPEF«IN-EUCR7 Series Thermal Analysis SystemFri May 30 12:29:11 1997

"Tl

CO

9_6-p

o

Curve 1: DSCFile info: SAH05300B Fri May 30 13:19:44 1997Sample Weight: 30.940 ragS97T000910 DUP

Iu.

N2 IOC/Bin•8:8 8

125.0-

100.0 -

—Z5.6-

_J25\fl»-

A A _V *h

-25.0-

-50.0-

-75.0 -

XI

X2Peak

Area

AHHeightOnset

\J\VI^~t—

51.333 'C. 181.533 *C

A 122.602 *C1 VU515.930 flU/ 1438.782 J/gI 1174.055 nW

101.145 *C

-J

100.0 200.0

0.0 Bin BATBl: 10.0 c/«ln

300.0

Temperature (*C)

I T400.0

SM FULTONPERKIN-ELMEB7 Series Thermal Analysis Sy:Fri May 30 13:20:11 1997

o-a

33

O

Curve 1: DSCFile info: SAM053007 Fri May 30 14:20:20 1997Sample Weight: 33.000 mgS97T000911

rf

1o

(0

200.0-

175.0-

150.0-

125.0 -

100.0 -

75.0-

50.0-

25.0-


///

I

/

49.466 *C168.466 *C

A 118.580 *C/ \ 42084.022 RU/ \ 1275.273 J/gj \ 154.477 mW

\ 79.134 *C ^

\ ^ ^ ^

HZ lOC/nin

£ «gS:8 8

c>

100.0 200.0

0.0 Bin RATE1: 10.0 C/Bin

300.0

Temperature (*C)

400.0

SH FULTONPERKIN-ELHEB7 Series Thermal Analysis SystemFri May 30 i5:17:18 1997

33

2

Curve l: DSCFile info: SAM05300B Fri May 30 IS 59:35 1997Sample Height: 25.140 ragS97T000911 DUP

50.0-j

25.0 -

0.0-

1 "25'° "atS -50.0-LL.

| -75.0 -

-100.0 -

-125.0 -

-150.0 -

-175.0 -

XIX2PeakArea

AHHeightOnset

I\Ai i

49.466 *C173.133 #C123.803 *C

35359.977 mJ1406.523 J/g

A 131.562 mW/ \ 98.863 *C

I \ •

I I I ! 1 1 I

o"0

100.0

N2 IOC/BinU 30.0 c TIME1: 0.0 aln HATei: 10.0 c/alnb fioo.o c

200.0 300.0 400.0

Temperature (*C) SM FULTONS LTOPEHKIN-EUCR7 Series Thermal Analysis SystemFri May 30 18:32:29 1997

workUstrpt Version 2.1 05/15/95 Page:


Instrument: DSC0 3Analyst: .jjy>

Method: LA-514-114 Rev/Mod D-O

Worldist Comment: T201, DSC-01 Run under Nitrogen, skm

Book#


GROUP PROJECT

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

S TYPE SAMPLE* R A TEST--

1 STD DSC-03

2 SAMPLE S97T000912 0 DSC-03

3 DUP S97T000912 0 . DSC-03 '•

4 SAMPLE S97T000913 0 DSC-03

5 DUP S97T000913 0 DSC-03

Analyst Signature


SOLID 38-'J<S 3~J. T-y N/A Joules/g

SOLID N/A 6 Joules/g

SOLID 0 O_ N/A Joules/g

SOLID N/A O Joules/g

SOLID O ^ N/A Joules/g


"Analyst S^nrftiire Date

i)oto ©ifry Comments:

Units shown for QC (SPK & SID) may not reflect the actual units. DL = Detection Limit, S = Worldist Slot Number,R = Replicate Number, A - Aliquot Code.

CHr4r^SB--WM-DP-246Hmrkhstrpt Version 2.1 05/15/95

05/23/9709:47 L A B C O R E D a t a E n t r y T e m p l a t e for WorkUst# 18280

Analyst:


Instrument: DSCO Book#

Worklist Comment: T201, DSC-01 Run under Nitrogen, skmHNF-SD-WM-DP-254, REV. 0

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

S TYPE

1 STO

2 SAMPLE

3 DUP

4 SAMPLE

5 DUP

SAMPLE* R A TEST MATRIX ACTUAL FOUND. DL UNIT

DSC-01 SOLID H/A Joules/g

S97T000912 0 DSC-01 SOLID N/A Joules/g


S97T000913 0 DSC-01 SOLID H/A Joules/g

S97T000913 0 DSC-01 SOLID


Analyst Signature

N/A Joules/g

Date

i Entry Comments: __ .

L* scu^hs ou PSC-6).m Us/ft.


Curve 1: DSCFi le info: IND052904 Thu May 29 14:32 55 1997

Sample Height: 11.990 rag SIGNATURE BELOW REPRESENTS CHEMICAL TECHNOLOGIST/CHEMIST THAT12N14B C O < P L e E D / V E r a H ^ T H E C A U B R A T K > O N ^ JiV

5.0

0 . 0 -

11

Hea

t

50.0-

45.0-

40.0 -4

35.0-

30.0-

25.0-

20.0-

15.0-

10.0 -

XIX2

PeakAreaAHHeight

Onset

157.533164.500

160.716

332.625

27.742

39.388

158.714

•c•c•craJJ/g

mM•c

140.0 145.0

N2, EXOTHERM DOWN

150.0 155.0

0.0 Bin RATE1: 10.0 O/«Sn

160.0

Temperature (*C)

165.0 170.0 175.0

P

8oT3

"1

r i

180.0

RA GREENPERKIN-ELMER7 Series Thermal Analysis SystemFri May 30 01:09:26 1997

g

83

I

I INr-OD-WM-DP 216, REV.


SllsrCHLXcnxm

EOT1**

i

i *oo

S a

o o oO . . ** CXI, . * - X Ol•rt C O

•n <D OO r-l O> O Q. I— (MB)

1SI

Curve 1: DSCFile info: SAM053002 Fri May 30 01:17:44 1997Sample Height: 24.650 mgS97T000912DUP

Hen

250.0 -

225.0 -

200.0 -•

| 150.0 -

| 125.0 -

100.0 -

75.0-

50 .0-

25 .0 -

XIX2PeakAreaAHHeight

Oneet

/

\

1 I

49.466 *C

161.933 *C

A 123.032 •€/ 137949.837 nJ1 11539.547 J/gI 1 186.413 mWI 1 97.187 »C

1\

\ 1 1 1 1

N2 10C/min

«3§:8 8

1113

in

•x

5

100.0 200.0

0.0 Mn RATE1: 10.0 0/atn

300.0

Temperature (*C)

400.0

JO SPELLMANPEBKIN-ELMER7 Series Theraial Analysis SystemFri May 30 01:20:03 1997

Curve l : DSCFi le info: IMM53001 Fri May 30 05:50:39 1997Sample Weight: 11.990 rag12N14-B

3Cp, o

I

30.0-

25.0-

20.0-

15.0-

10.0-

5.0-

o.o-

XIX2Peak

Area

AHHeight

Onset

1

161.700 *C

170.333 *C

164.598 *C

311.449 jnj

25.976 J/g

20.342 raW

162.121 #C

1 1 1

jA///

v140 .0

N2. EXOT^eiM DOWN

886 ^"T3 "T_

145.0 150.0 155.0 160.0 165.0Temperature CO

170.0 175.0 180.0

0.0 »ln OKTSU 10.0 C/llnSM FULTONPERKIN-EUMER7 Series Thermal Analysis SystemFri May 30 05:51:59 1997

Curve 1: DSCFi le info: SAM053003 Fri May 30 06:5a 54 1997Saaple Height: 14.050 tugS97T000913

125.0-

eg eg *ikH~-5.aB2 J/g Onset 51.26 *C

N2 lOC/ninC/aln

Temperature (•c) SM FULTONPERKIN-ELMER7 Series Thermal Analysis SystemFri May 30 08:06:26 1997

Curve 1: DSCFile info: SAM053004 Fri May 30 09:14:41 1997Sanple Height: 38.970 mgS97T000913 OUP

1i

200.0-

175.0 -

150.0 -

125,0-

100.0 -

75.0-

50 .0 -

25 .0-

0 . 0 -

-25.0 -

-50 .0-

-75.0 T

100.0 -

125.0-

XIX2PeakArea

AH

Height

Onset

i

\f.——H

51.333 *C193.666 *C

m7.lA0 *CfeOt)B6.722 mJ/15*1.871 J/g/ 253.208 mW/ 105.882*0

1\ ^>\ ^^"^

— . ' • - • —

C)C J

o-o

1o

100.0 200.0

N2 lOC/minTSSii 0.0 aln BATE!: 10.0 c/ain

300.0

Temperature (*C)

400.0

SM FULTONPERKIN-ELMER7 Series Thermal Analysis SystemFri May 30 09:20:38 1997

^HNF-se-wM-or-240, no/ .worklistrpt Version 2.105/15/95 Page: 1

06/03/9708:00 L A B C O R E D a t a E n t r y T e m p l a t e f o r W o r k l i s t # 1 8 4 3 8

Analyst: DOh Instrument: DSCO 2- Book #

Method: feA^t^tlSHReWMe4- G?*> W* ? HNF-SD-WM-DP-254, REV. 0

Worklist Comment: DSC-02 T-202 liquid, -ppb

GROUP PROJECT S TYPE SAMPLE* I! A TEST MATRIX ACTUAL FOUND DL UNIT

97000318 T-202 1 SAMPLE S97T000796 0 DSC-02 LIQUID N/A V_ Joules/g Dry

97000318 T-202 2 DUP S97T000796 0 DSC-02 LIQUID 0 O N/A Joules/g Dry





156

worklistrpt Version 2.105/15/9506/03/9708.-02 L A B C O R E

"•HNT-SD-WM-DP-246,

T e m p l a t e f o r Worklist# 18439

Analyst: nphit

Instrument:

Worklist Comment: DSC-02 T-202 solid, -ppb

GROUP PROJECT

97000318 T-202

97000318 T-202

97000318 T-202

97000318 T-202

97000318 T-202

97000318 T-202

97000318 T-202

97000318 T-202

97000318 T-202

97000318 T-202

97000318 T-202

97000318 T-202

97000318 T-202

97000318 T-202

97000318 T-202

97000318 T-202

97000318 T-202

97000318 T-202

S TYPE

1 SAMPLE

2 DUP

3 SAMPLE

4 DUP

5 SAMPLE

6 DUP

7 SAMPLE

8 DUP

9 SAMPLE

10 DUP

11 SAMPLE

12 DUP

13 SAMPLE

14 DUP

15 SAMPLE

16 DUP

17 SAMPLE

18 DUP

SAMPLE* R A - - -

S97T000802 0

S97T000802 0

S97T000803 0

S97T000803 0

S97T000804 0

S97T000804 0

S97T000805 0

S97T000805 0

S97T000806 0

S97T000806 0

S97T000807 0

S97T000807 0

S97T000808 0

S97T000808 0

S97T000809 0

S97T000809 0

S97T000810 0

S97T000810 0

DSCO £_

TEST

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

Book # A//

HNF-SD-WM-DP-254,

MATRIX

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

ACTUAL

N/A

o

N/A

oN/A

O

N/A

oN/A

O

N/A

O

N/A

•6

N/A

o

N/A

o

FOUND

b

'O

V

0

O

ooo

TO

o

o

•o

o

o

o

O

O

O

f,REV.O

DL

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

N/A

UNIT

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry



1 5 7


worklistrpt Version 2.105/15/95 .,..,-.„.„ . . . . . ^,— , u , e

06/03/9708-02 IPtfL"!-)ll-(fl 'LABCORE Data Entry Template for Worklist# 18439

GROUP PROJECT S TYPE SAMPLES R A TEST MATRIX ACTUAL FOUND DL UNIT

97000318 T-202 19 SAMPLE S97T000811 0 DSC-02 SOLID N/A 5 Joules/g Dry

97000318 T-202 20 DUP S97T000811 0 DSC-02 SOLID d P N/A Joules/g Dry


..jfi .y/3/7' - _ ^ _ _ •flyst Signature Date' Analyst Signature Date



1 5 8

worklistrpt Version 2.105/15/95 ~ Page:

06/12/9707:17 L A B C O R E D a t a E n t r y Template for Worklist# 18621

Analyst:

Methoc

pph Instrument:

Worklist Comment: DSC-02 T-201 liquid, -ppb

GROUP

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

PROJECT

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

ViAjJ.

S TYPE

1 SAMPLE

2 DUP

3 SAMPLE

4 DUP

5 SAMPLE

6 DUP

7 SAMPLE

8 DUP

9 SAMPLE

10 DUP

11 SAMPLE

12 DUP

DSC0

SAMPLE* R A TEST--

S97T000823 0 DSC-02

S97T000823 0

S97T000833 0

S97T000833 0

S97T000834 0

S97T000834 0

S97T000835 0

S97T000835 0

S97T000836 0

S97T000836 0

S97T000837 0

S97T000837 0

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

Final page for

Aitalyst Signature Date1

2 Book # MA

HNF-SD-WM-DP-254,

MATRIX

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

worklist

ACTUAL FOUND

N/A "

O O

N/A £>

0 O

N/A a

0 <Q

N/A

0 °N/A ^

O o

N/A

O -o

# 18621

Analyst Signature

REV.O

DL

N/A

N/A

N/A

N/A

N/A

N/A

Date

UNIT

Joules/g

Joules/g

Joules/g

Joules/g

Joules/g

Joules/g

Joules/g

Joules/g

Joules/g

Joules/g

Joules/g

Joules/g

Dry

Dry

Dry

Dry

Dry

Dry

Dry

Dry

Dry

Dry

Dry

Dry




1 5 9

-14 -H-HC-6B-WM-DP-P46, RFV,

worklistrpt Version 2.1 05/15/95 Page: 1


Analyst:

Method: tAH&4 i n ppv/fcte

Instrument:

IT4 (1&% t*lit \a?

Worklist Comment: DSC-02 T-201 solid, -ppb

GROUP PROJECT

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

S TYPE

' 1 SAMPLE

2 DUP

3 SAMPLE

4 DUP

5 SAMPLE

6 DUP

7 SAMPLE

8 DUP

9 SAMPLE

10 DUP

11 SAMPLE

12 DUP

SAMPLE* R A - -

S97T000899 0

S97T000899 0

S97T000909 0

S97T000909 0

S97T000910 0

S97T000910 0

S97T000911 0

S97T000911 0

S97T000912 0

S97T000912 0

S97T000913 0

S97T000913 0

DSC0 *

TEST

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

DSC-02

Book # A/A


MATRIX

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

ACTUAL

N/A

O

N/A

oN/A

0

N/A

D

N/A

o

N/A

o

FOUND DL

n

O

0

D

oO

O

O

O

0

o

o

N/A

N/A

N/A

N/A

N/A

N/A

0

UNIT

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry

Joules/g Dry


lyst Signature Date' Analyst Signature Date




1 6 0

worklistrpt Version 2.1 05/15/9507/22/9708:11 L A B C Q R E


E n t r y T e m p l a t e f o r Worklist# 18915

Analyst: W\ Instrument: DSCO

Method: LA-514-114 Rev/Mod D-l

Worklist Comment:

GROUP PROJECT

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

s

1

2

3

4

5

T-201

TYPE

STD

SAMPLE

DUP

SAMPLE

DUP

DSC, RUN UNDER N2. RCJ

SAMPLE*

S97T001246

S97T001246

S97T001253

S97T001253

R A TEST

DSC-03

0 DSC-03

0 DSC-03

0 DSC-03

0 DSC-03

7S

MATRIX

SOLID

SOLID

SOLID

SOLID

SOLID

Book

ACTUAL

N/A

O

N/A

0

FOUND

O

D

D

DL

D * N/A

N/A

N/A

UNIT

Joules/g

JouLes/9

Joules/g

Joules/g

Joules/g


Analyst Signature ate Analyst Signature Oate/



workUstrpt Version 2.1 05/15/95 HNF-SD-WM-DP-254, REV. 0 Page:

06/25/9710:13 L A B C O R E D a t a E n t r y T e m p i a t e fOr.Worklist# 18915

A lalyst: Instrument: DSCO 3Method: LA-514-113 Rev/Mod , p ~ j

^'nrklist Comment: T-201 DSC, RUN UNDER N2. RCJ

97000311 T-201

'-000311 T-201

<'000311 . T-201

!'000311 T-201

S TYPE

1 STD

2 SAMPLE

3 DUP.

4 SAMPLE

5 DUP


DSC.-01 SOLID N/A Joules/g


S97T001246 0 DSC-01 SOLID N/A Joules/q

S9rT001253 0 Dsc-01 SOLID N/A Joules/g

S97T001253 0 DSC-01 SOLID . N/A Joules/g



''.'nits shown for QC (SPK & STD) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number,17 = Replicate Number, A = Aliquot Code.

1 6 2

Curve 1: DSCFile info: IOND071901 Sat Jul 19 07:20:05 1997Sample Weight: 21.590 mg

12N14-B

fci

140.0

N2, EXOTHERM DOWN

65.0 -

60.0 -

55.0 -

50.0 -

45.0 -

40.0 -

35.0-

30.0 -

25.0 -

20.0-

15.0-

10.0 -

5.0 -

0.0 -

XI

X2

Peak

Area

AH

Height

Onset

1

154.400

161.166

157.423

613.038

28.395

.52.194

154.841

1

•c

*°•c hmJ /

J/g /

m W / • •

•c . /

I

li ^—i —: — —— — — • ' ) • • • • • — — i •

i 1 ! T i ' 1 1

33

m

145.0 150.0 155.0 160.0 165.0

Temperature CO

170.0 175.0 180.0

0.0 min RATE*: 10.0 C/mlnRD MEYERSPERKIN-EIMER7 Series Thermal Analysis SystemSat Jul 19 19:14: SS 1997

Curve 1: DSCFile info: SAM071909 Sat Jul 19Sanple Weight: IB.480 sgS97T001246

19:54 1997

175.0-

150.0 -i

125.0-

100.0 -

75.0-

50.0-

XIX2PeakArea <AHHeight IOnset I

i/1 I

46.200 *C. 151.200 *C\ 109.486 *C\ 25019.554 Rji 1353.872 J/g1 123.709 RH1 88.315 *C

X i • 'i

x"TI

N2 IOC/Bin

«88:8 8

33

100.0 200.0

o.o «in nutma 10.0 c/am

300.0

Tei^erature (*C)

i i r400.0

RD MEYEHSPERKIN-ELMER7 Series Thermal Analysis SystemSat Jul 19 13: 00: 42 1997

Curve 1: DSCFile Info: SAM071910 Sat Jul 19 14:19:16 1997Sanple Height: 9.700 maS97T0012460UP

1

CA *

i

95.0-

90.0 -

85.0,-

80.0-

75.0-

70.0 -

65.0-

60.0-

55.0-

50.0-

45.0-

XIX2 .Peak AArea / \

m 1 \Height/ 1Onset/ I

/ /

Jj

39.666 *C142.333 *C96.176 *C

11356.596 BO yS1170.783 J/g yS

44.022 nH > ^58.229 »C > ^

> • r .

X

-n

O

100.0 200.0

N2 IOC/Binas.g o TXMBtt o.o am ntmtu 10.0 e/tain

300.0

Teaperature (*C)

1 1400.0

RO MEYERSPERKIN-ELMER7 Serle8 Theraial Analysis SystenSat Jul 19 IK 51:09 1997

Curve 1: DSCTile info: SAN071911 Sat Jul 19 15:20:30 1997Saaple Height: 10.470 agS97T001253

200.0-

175.0 -

150.0 -

125.0-

100.0 •

75.0-

50.0-

25.0-

XIX2PeakAreaAH iHeight

Onset I

/ 1

U_4-

44.800 *C. 127.866 *CI 108.733 *C

19464.763 «J1859.099 J/0152.420 RM91.208 *C in

P

30m

t

N2 lOC/aln. 0 O TXMKl:•0 O

100.0 200.0 i r r300.0 400.0

C O R0 MEYERSPERKIN-ELMER7 Series Theraal Analysis SysteaSat Jul 19 18:42 19 1997


ao

3

go;

io a S

25"

I5fc

is•PS

Sj J^ ott*-t

a. i^0

o

1S7

worklistrpt Version 2.1 05/15/95

07/22/9714:03 L A B C Q R E D a t a E n t r y Template for Worklist# 19452HNF-SD-WM-DP-254, REV. 0

" • ~ - Wt

Page: 1

Analyst:

Method: tAr5W

,M\O

Worklist Comment:

GROUP PROJECT

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

s

1

2

3

4

-Rev/Mc

Instrument:

DSC-02 T-201 comp solid.

TYPE

SAMPLE

DUP

SAMPLE

DUP

SAMPLE# R A - -

S97T001246 0

S97T001246 0

S97T001253 0

S97T001253 0

DSCO

-ppb

TEST--

DSC-02

DSC-02

DSC-02

DSC-02

3.

MATRIX

SOLID

SOLID

SOLID

SOLID

Book # A/#

ACTUAL

N/A

O

N/A

O

FOUND DL

D

O N/A

O

O N/A

UNIT

Joules/g

Joules/g

Joules/g

Joules/g

Dry

Dry

Dry

Dry


Salysl Signature Date Analyst Signature Date



R = Replicate Number, A = /

NINF-SD WM-DP-240, nEV.worklistrpt Version 2.1 05115195 Page: 105/28/9709-08


Analyst: "PJM Instrument:

Method: LA-514-114 Rev/Mod V-0

TGA0

Worklist Comment: T201, TGA-01 Run under Nitrogen.

GROUP PROJECT S TYPE

1 STD

97000311 T-201 2 SAMPLE

97000311 T-201 3 DUP

97000311 T-201 A SAMPLE

97000311 T-201 5 DUP

Book #-t#N-frS&- .

skm HNF-SD-WM-DP-254, REV.

SAMPLE* R A TEST MATRIX

TGA-03 LIQUID

S97T000823 0

S97T000823 0

S97T000833 0

S97T000833 0

TGA-03

T6A-03 =

TGA-03

TGA-03

LIQUID

LIQUID

LIQUID

LIQUID

ACTUAL FOUND DL

51-4 5i-oS*-*ik

N/A W. loi

1U8 <MM N/A

N/A Il.t*

tf.lt 10.16 N/A

0

UNIT

SS

X

%

y

%

See


-fzr SignAnalyst-Signature Date


Units shown for QC (SPK & STD) may not reflect the actual units. DL = Detection Limit, 5 = Worklist Slot Number,R = Replicate Number, A = Aliquot Code.

169

246, REV: 0 ^worklistrpt Version 2.1 05/15/95

05/23/9708:31 L A B C O R E D a t a E n t r y T e m p i a t e for Worklist# 18274Page:

Instrument: TGAO 03Analyst:

Method: LA-560-112 Rev/Mod.

Worfcfist Comment: T201, TGA-01 Run under Nitrogen, skm

Book#


GROUP PROJECT

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

S TYPE

1 STB

2 SAMPLE

3 DUP

4 SAMPLE

5 DUP

S97T000823 0

S97T000823 0

S97T000833 0

S97T000833 0

TEST--

TGA-01

TGA-01

TGA-01

TGA-01

TGA-01


LIQUID N/A X

LIQUID

LIQUID

LIQUID

LIQUID

N/A

N/A

N/A

N/A



Entry Cicm SJ

Units shown for QC (SPK & STD) may not reflect the actual units. DL = Detection Limit, S = Workttst Slot Number,R - Replicate Number, A = Aliquot Code.

1 7 0

3C

Curve 1: TGAFile info: TER052701 Tue May 27 06: 2 2 47 1997Sample Height: 27.183 mg97N8-A

100.0

90.0-

80.0-

70.0-

60.0

50.0-

40.0-

50.0

10C/MIN N2

XIX2

Yl ~~~~Y2

AY

23.134296.640

- ^ 9 9 . 9 8 540^932

-59.033

•c

•cHt.Ht.Ht.

%%%

o

100.0 150.0

Temperatupe (*C)

200.0 250.0

0.0 nln RATEl: 10.0 C/alnPJ MCC0WNPEflKIN-ELMER7 Series Thermal Analysis SystemNed May 28 08: 28: 23 1997

-po

i6-a

J3

S3o

Curve 1: TGAFile info: SAM052705 Tue May 27 14: 49: 09 1997Sample Weight: 10.116 mgS97T000823

110.0 -

100.0 -

90.0 -

80.0 -

70.0 -

60.0 -

50.0 -

40.0 -

30.0 -

20.0 -

10.0 -

0.0 -

-10.0 -

XIX2

Y2 \AY \

\

27.303 °C

134.477 *C

99.B70 Wt. %

0.188 Wt. %

-99.682 Wt. %

\

\ .

\ |

10C/MIN N2£ JS:t 8 TIME1:

13•0IP

5 "I"T| • 3

s•J

100.0I I r

0.0 min RATE1: 10.0 C/min

200.0 300.0

Temperature (*C)

400.0

PJ MCCOWNPERKIN-ELMER7 Series Thermal Analysis SystemTue May 27 15:03:01 1997

oT3

33

• HNF SD WM DP-246, REV. 0 ^ * %


coinin

&

I?o

•o

sii-t_J OUJ 10i cuz

OJSUJ 10o i cu>OHLI

"§aj

1—

*•*

a>cu

oM_a•i-t

w•rt(X.

M01

a.BCO

m

oo

mCO

2 § § o oto to

o o

8 Soo

oo

1 7 3

Curve 1: TGAFile info: SAM052708 Tue May 27 18:51:54 1997Sample Weight: 17.700 mgS97T000833

110.0 -

100.0 -

90.0 -

80.0 -

70.0-

60.0 -

50.0 -

40.0 -

30.0-

20.0 -

10 0 -

0.0-

XIk-X2

Y2

AY

1

24

x 181

\

\

A\\

i

.195

.537

.915

.818

^097

yV

1

•c•c

wt. %w t . %w t . %

\

1-]

1 1 1 I I I

10C/MIN N2SB.O C

BOO.O C

13

10

i n

100.0

0.0 mln HAT61: to.o C/min

200.0 300.0

Tempepatupe (*C)

400.0

JO SPELLMANPERKIN-ELMER7 Series Thermal Analysis SystemTue May 27 19:03:19 1997

ISI 5

33

o

Curve 1: TGAFile info: SAM052709 Tue May 27 19: 58: 49 1997Sample Weight: 17.923 mgS97T000833DUP

CD.wffi

3C

110.0 -

100.0 -

90.0 -

80.0-

70.0 -

60.0 -

50.0-

40.0 -

30.0 -

20.0 -

10 0 -

0.0-

XI

X2

Y2 \AY \

1

30.208 *C

169.546 *C

99.878 Wt. %

8.927 Wt. %

-90.951 Wt. %

\

\

\

\

\

I

1 1 1 1 1 1 1

10C/MIN N2

100.0

• 313

i

O.o mln RATE!: 10.0 c/nin

200.0 300.0

Temperature (*0

400.0

JO SPELLMANPERKIN-ELMER7 Series Thermal Analysis SystemTue May 27 20:28:21 1997

33

mo

workUstrpt Version 2.1 05/15/95 *fiNR8d=WM-PP 246, REV. O#feff_ r? Page:05/29/97 09'49 •

LABCORE Data Entry Template for Worklist# 18275Analyst: Instrument: TGAO Book#

Method: LA-514-114 Rev/Mod D-D

Worklist Comment: T201, TGA-01 Run under Nitrogen, skm


GROUP PROJECT

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

S TYPE SAMPLES R A TEST—

1 STD TOA-03

2 SAMPLE S97T000834 0 TGA-03

3 DUP S97T000834 0 . TGA-03

4 SAMPLE S97T000835 0 TGA-03

5 DUP S97T000835 0 TGA-03


LIQUID i ^ V &?./(> N/A %

LIQUID H/A Ql Jt? %

LIQUID Ql.lh ft. Of W/A %

LIQUID M/A 9 f SO %

LIQUID 1/ -SO $1.83 N/A %


Analyst Signature Date Analyst Signature Date


Units shown for QC (SPK & STD) may not reflect the actual units. DL - Detection Limit, S = Worklist Slot Number,R = Replicate Number, A = Aliquot Code.

worMstrptVersionl.! 05,15,95

05/23,9708:31 L A B C O R E D a t a E n t r y T e m p l a t e f o r Worklist# 18275

Analyst: Instrument: TGAO

Method: LA-560-112 Rev/Mod V-0 HNF-SD-WM-DP-254, REV. 0Worklist Comment: T201, TGA-01 Run under Nitrogen, skm

97000311 1-201

97000311 T-201

97000311 T-201

97000311 T-201

S TYPE SAMPLE* R

1 STD

2 SAMPLE S97T000834 0

3 DUP S97T000834 0

4 SAMPLE S97T000835 0

5 DUP S97T000835 0

TEST--

TGA-01

TGA-01

TGA-01

TGA-01

TGA-01

MATRIX ACTUAL FOUND

LIQUID

DL UNIT

N/A

LIQUID

LIQUID

LIQUID

LIQUID

N/A

N/A

N/A

N/A



2 Entry Comments:

£/nto shown for QC (SPK & SID) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number,R = Replicate Number, A = AUqUot Code.

177

Curve 1: T6AFi le info: TER052801 Wed May 28 19:19:02 1997Sample Height: 35.976 mg

s.

I

100.0 -

90.0-

80 .0 -

70.0-

XIX2

Yl

Y2

AY

6 0 . 0 -

5 0 . 0 -

40.0-

10C/MIN N2

25.266 *C297.055 *C

99.965 Ht. X

^.802 Ht. %

- 5 9 ^ 6 3 Ht. %

75.0 r125.0

o.o am RATEI: 10.0 c/oin

\ 1175.0

Temperature (*C) JO SPELLMANPEflKIN-ELMER7 Series Thermal Analysis SystemMed May 28 19:20:43 1997

33sa

Curve 1: TGAFile Info: SAM052804 Wed May 2B 20:30:52 1997Sample Height: 10.599 ingS97T000834

zCO

o

110.0-

100.0 -

90 .0-

B0.0-

70 .0 -

60.0 -

5 0 . 0 -

40 .0-

30 .0 -

20 .0 -

10.0 -

0.0 -

XI

X2

£\AY \

1

23.433 *C161.43B *C99.932 Ht.B.773 Ht.

-91.160 Ht.

\

\

\

\

\

\

1

1 1

XXX

\

\

\\

I 1 t i l l

lOC/MIN N2

100.0 200.0

O-O

33

o

C3"3

o

300.0

0.0 Bin RMTE1; 10.0 C/BlnTemperature (*C)

400.0

JO SPELLMANPERKIN-ELMER7 Series Thermal Analysis SystemWed May 28 21:10:45 1997 -


9mo

s

I— » * "H

o tu

oo oin

o

s

CIBCU

toc01

o

~ o

0) i-< O> (D CX t—3 *rt CD O)O I L CO W

(X '

1 8 0

Curve 1: TGAFile info: SAM052901 Wed May 28 23:58:30 1997Sample Height: 15.453 mgS97T000835

» 3

110.0 -

100.0 -

90.0-

80.0 -

70.0-

60.0-

50.0-

40.0 -

30.0-

20.0-

10.0-

0.0 -

XI

X2

Y2 \

AY \

26.486

166.851

99.890

8.092

-91.798

\

\

\

\

\

\

1

•c•c

Ht.

Ht.

Ht.

X

X

X

10C/MIN N2M =85:8 8 TIME1:

100.0 T I

0.0 am RATE!: 10.0 C/ain

200.0 300.0

Temperature (*C)

oC3

6

400.0

JO SPELLMANPERKIN-ELMER7 Series Thermal Analysis SystemThu May 29 00:23:43 1997

30

o

Curve 1: TGAFile info: SAM052302 Thu May 29 01:18:41 1997Sample Height: 10.717 mgS97T000835DUP

hGOW

uo.o-

100.0 -

90.0-

80.0-

70.0-

60.0 -

50.0-

40.0-

30.0-

20.0-

10.0 -

o . o -

XIX2

Y2 \AY \

1

24.501 *C162.294 *C99.897 Wt.8.068 Wt.

-91.829 Ht.

\

\

\

\

\

\I1 1

XXX

1

\

\

1 1 I I 1

10C/MIN N2S a§§:8 8 TIME1!

100.0

0.0 aln RATEl: 10.0 c/nln

200.0 300.0Temperature (*C)

400.0

JD SPELLMANPERKIN-ELMER7 Series Thermal Analysis SystemThu May 29 01:26:31 1997 -

s

Curve 1: DSCFile info: SAM052901 Wed May 28 23 58:56 1997Sample Weight: 16.340 mgS97T000835

350.0 -

325.0 -

300.0 -

275.0 -

Sf 250'.0 -

a 225.0 -

28 C 200.0 -

XI

X2Peak /

Area IAH /

Height 1Onset I

11I

44.800 *C

151.200 *C

115.519 »C

32342.666 mJ

1979.355 J/g

276.095 mW

100.484 *C

Bc>

f 3

IOC/rain2 0 0-° 300.0 400.0

Temperature (*c) JD SPELLMANJO SPELLMANPERKIN-ELMER7 Series Thermal Analysis SystemThu May 29 00:28:45 1997

cHftF-SD-WM-DP-246,worklistrpt Version 2.105/15/95 . - . - - p ^ _ }

05/30/9708:43 L A B C O R E D a t a E n t r y T e m p i a t e f o r Worklist# 18276

Analyst: ^J.DS> Instrument:

Method: LA-514-114 Rev/Mod D-0

Worklist Comment: T201,

GROUP PROJECT

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

S TYPE

1 STD

2 SAMPLE

3 DUP

4 SAMPLE

5 DUP

TGA0

TGA-01 Run under Nitrogen.

SAMPLE* R A ' - •

S97T000836 0

S97T080836 .0 . :

S97T000837 0

S97T000837 0

- - - - T E S T * - -

TGA-03

TGA-03

. ,.TGA-03 i

'TGA-03

TGA-03

3

skm

...

Book# f?/f<fA


MATRIX

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

ACTUAL FOUND DL

N/A %.3f

11.34 qi./3 R/A

N/A 7 0. ??

16 -f) <?o. 99 »/A

0

UNIT

%

%

%

%

%

See


Analyst Signature qDate

Malyst Signature Date

DgaEntry Comments:aUcc -h /of

J>

is *.


184

-HNF-SD-WM-DP-24G,

worklistrpt Version 2.1 05/15/9505/23,9708:32

18276

Analyst:

Method: LA=5i

Worklist Com

GROUP PROJECT

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

ment: T201,1

S TYPE

1 STD

2 SAMPLE

3 DUP

4 SAMPLE

5 DUP

Instrument:

od V-0

XJA-01 Run under

SAMPLE* R A -•

S97T000836 0

S97T000836 0

S97T000837 0

S97T000837 0

: TGAO

Nitrogen.

• TEST—

TGA-01

TGA-01

TGA-01

TGA-01

TGA-01

3

skm

. . .

Book# < i "7/ (

HNF-SD-WM-DP-254,

MATRIX ,

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

ACTUAL FOUND D

N/A

N/A

mREV. 0

IL UNIT

N/A %

%

N/A %

%

N/A %

final page for worklist # 18276


3 Entry


1 8 5

Curve 1: TGAF i l e info: TER052801 Ned May 2B 19:19:02 1997Sample Height: 35.976 mg97N8-A SIGNATURE BELOW REPRESENTS CHEMICAL TECHNaOGIST/GH8m»TtftlUr

COMPLETED/VER1REDTHECAUBRATION/ANALYSfSONPAGfeB/yfr 1 0 / ? / .

100.0

60.0-

50.0-

40.0-

175.0

1 I125.0 225.0 275.0

10C/MIN N2 Temperature (•©l: 30.o c TIMEl: 0.0 Bin RATE1: 10.0 c/alnsx SOO.O C

JD SPELLMANPERKIN-ELMER7 Series Thermal Analysis SystemTltu May 29 00:53:45 1997

Curve 1: TGAFile info: SAM052903 Thu Hay 29 02:25: 03 1997Sample Height: 20.299 mgS97T000836

06

•a «c4

110.0 -

100.0 -

90.0-

80.0-

70.0 -

60.0-

50.0-

40.0 -

30.0-

20.0-

10.0 -

0.0-

XIX2

Y2 \

AY \

1

29.787 *C

174.814 *C

\ 99.934 Wt.

\ 8.546 Wt.

-91.388 Wt.

\

\

\y

XXX

\

I 1

\

! 1 1 . t

10C/MIN N2

100.0

».o g TIHei: 0.0 Mln RATCls 10.0 O/»ln

200.0 300.0

Temperature (*C)

400.0

JD SPELLMANPERKIN-ELMEB7 Series Thermal Analysis SystemThu May 29 03:48:14 1997

CO

9

33

rn

(3

I 3

Curve 1: TGAFile info: SAM052904 Thu May 29 04:39:20 1997Sample Height: 21.641 mgS97T000836DUP

S?

i

110.0 -

100.0 -

90 .0-

80.0 -

70 .0-

60 .0-

50.0 -

40.0 -

30 .0-

20.0 -

10.0 -

0.0 -

XIX2

AY \

1

27.801 *C173.707 *C99.749 Ht. %8.620 Ht. %

-91.129 Ht. %

\

\

\

\

1

I I 1 1 1 1 1 1

10C/HIN N2

g «§S:8 %

100.0

T1HE1: 0.0 aln HATE1: 10.0 c/ain

200.0 300.0

Temperature (*C)

400.0

JD SPELLMANPERKIN-ELMER7 Series Thermal Analysis SystemThu May 29 08:58:14 1997

oT3

o

0)

wr i

Curve 1: TBAFile Info: TER052904 Thu May 29 14:47:22 1997Sample Height: 24.301 mg97N8-A

100.0 -

90.0-4

J 80.0 -

i 7°-° •£

60.0-

50.0 -

40.0-

XIX2

Y2AY

1

26.744 *C239.320 *C

- ^ 1 0 1 . 7 2 7 Wt.

^"N^oa wt.-59^M Wt.

\

1 1

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\

\

1

\

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10C/HIN N2TEHPtt a o o ' o E T I M S < :

-pCO

o

o•D

75.0 125.0 175.0

Temperature (*C)aln RATEl: 10.0 c/nin

225.0 275.0RA GREENPEBKIN-ELMEfl7 Series Thermal Analysis SystemThu May 29 14:47:51 1997

Curve 1: TGAFile info: SAM052905 ThU May 29 19: 22: 26 1997Sample Height: 20.536 mgS97T000837

110.0 -

100.0 -

90.0-

80.0-

* 70.0 -

60.0 -

S 50.0 -

40.0-

30.0-

20.0-

10.0 -

0.0-

XIX2

Y2 \AY

23.399173.10899.9608.973

\ -90.987

\

\

\

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\

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•cwt.Kt.Ht.

1

XXX

x.x\

10C/MIN N2

I100.0 200.0

T300.0

Tixei: o.o mm RATEI: IO.O c/ninTemperature (*C)

• 400.0

JO SPELLMANPERKIN-f3.MER7 Series Thermal Analysis SystemThu Hay 29 20:46:54 1997 .

x S!

30

2

Curve l: TGAFile info: SAM052906 Thu May 29 21:37:00 1997Sample Height: 20.390 tngS97T000837DUP

110.0 -

100.0 -

90.0-

80.0 -

* 70.0 -

Weig

ht

(W1

8 S

b

bt

i

40.0-

30.0-

20.0-

10.0 -

o.o-

XIX2

Y2 \AY

27.560 *C171.033 *C99.964 Wt. X8.969 Wt. X

\ -90.995 Wt. X

\

\ \

* ^ i 1

10C/MIN N2

100.0 i i r200.0 300.0

Temperature (*C)

CO

TXMEl: 0.0 uln HATEH to.o c/min

400.0

JD SPELLMANPEWIN-ELMEH7 Ser i e s Thermal Analysis SystemThu May 29 22:41:33 1997 \

33

o

workUstrpt Version 2.1 05/15/9506/05/9713:13

Page:


Analyst: Instrument: TGAO Book #

Method: LA-514-114 Rev/Mod t > - 0

Worklist Comment: T201, TGA-01 Rununder Nitrogen, skm"HNF-SD-WM-DP-254, REV. 0

GROUP PROJECT

97000311 Ti201

97000311 T-201

97000311 T-201

97000311 T-201

S TYPE SAMPLES R A TEST—

1 STD TGA-03

2 SAMPLE S97T000899 0 TGA-03

3 DUP S97T000899 0 TGA-03

4 SAMPLE S97T000909 0 TGA-03

5 OUP S97T000909 0 TGA-03

MATRIX ACTUAL FOUND

SOLID j~? .y SB.

SOLID M/A

DL UNIT

SB.hB N/A x

//aJ/ x

SOLID (ph-3/ Utf. 7b M/A %

SOLID N/A UI-98 %

SOLID b^-^S WjM3 N/A X


Analyst Signature


Units shown for QC (SPK & STD) may not reflect the actual units. DL = Detection limit, S - Worklist Slot Number,R = Replicate Number, A = Aliquot Code.

192

s.!'§

Si5m

I&

57:

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1 9 4

Curve 1: T6AFile info: SAM060510 Thu JunSample Height: 18.657 agS97T000899DUP

5 23:33:00 1997

i£

100.0-

90.0-

80.0-

70.0-

60.0-

50.0-

40.0-

30.0-

XIX2

\AY \

\\

.. .

28.369 *C152.295 *C99.709 Ht.34.950 Ht.-64.760 Ht.

\

\

1 "' I"""

XXX

— T 1 1 I t I /

1o•o

J3m

C3

(3

13

in

100.0 200.0 300.0 400.0

10C/MIN N2 Temperature (*C) OP BROMLEYfc JS-9 S TXMBI: o.o aln BATBt to.o c/min PSRKIN-EUCFit- no*.* e 7 serieB Theraal Analysis

Fri Jun 6 00:10:00 1997

500.0

Sy8tera


o(0

"8

ex - i

HNF-SD-WM-DP-254,

ID

C •

I'R i 8? 8 f

la

SP :" fc

-o Q

&

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3.

(X '4

1 9 7

worklistrpt Version 2.105/15/9506/03/9715:29

•44NF-SB -WM' DP 246,- REV. me Page:

18282

Analyst: InstrHinent: TGAO Book #

Method: LA-514-114 Rev/Mod HNF-SD-WM-DP-254, REV. 0Worklist Comment: T201,TGA-01 Run under Nitrogen, skm

GROUP PROJECT

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

S TYPE SAMPLE* R A TEST--

1 STO TGA-03

2 SAMPLE S97T000910 0 TGA-03

3 DUP S97T000910 0 TGA-03

4 SAMPLE S97T000911 0 TGA-03

5 DUP S97T000911 0 TGA-03

SOLID

SOLID

SOLID

SOLID

SOLID

59-4

N/A

K/A

fe5.6V

<*S>L,4

bO-<ib

N/A

N/A

N/A

%

2!

%

%

%


Sg: MkJid'fffS-^Analyst Signature yDate

hDate1'



vorUistrpt Version 2., 05/J5/9505/23/9709:50 for W 18282

Analyst: <5jMF~ Instrument: TGAO Book l

Method: LA-560-112 Rev/Mod ft-P HNF-SD-WM-DP-254, REV. 0

WorkBst Comment: T201, TGA-01 Run under Nitrogen, skm

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

2 SAMPLE S97T000910 0

3 DUP S97T00091O 0

4 SAMPLE S97T000911 0

5 DUP S97T000911 0

TEST MATRIX ACTUAL FOUND DL UNIT

TGA-01 SOLID N/A %

TGA-01 SOLID N/A . %

TGA-01 SOLID N/A %

TGA-01 SOLID N/A %

TGA-01 SOLID N/A %



Data Entry

Units shown for QC (SPK,& STD) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number,R = Replicate Number, A = Aliquot Code.

1 9 9

Curve 1: TGAFile info: TER053001 Fri May 30 06:00:29 1937Sample Weight: 17.77197N8-A

rag

T1

100.0

60.0-

50.0-

40.0-

XIX2

10C/MIN N2^ aoS'8 8 rxm)t

26.672 *C297.533 *C99.820 Ht. X41.182 Kt. %-59.630 Hfc. X

75.0 125.0 175.0

Temperature (*C)

275.0

SM FULTONPERKIN-ELMEH7 Series Thermal Analysis SystemFri May 30 06:07:33 1997

30

m,o 4-

I

Curve 1: TGAFile info: SAH053005 Fri May 30 10:32:29 1997Sample Height: IB.847 mgS97T000910

100.0

90.0-

80.0-

*, 70.0 -

60.0-

50.0-

40.0-

30.0-

10C/MIN N2

y aSSrg g TIMeis

36.203 *C155.298 *C99.737 Wt.36.220 Wt.-63.517 Wt.

100.0

0.0 ain RATS1: 10.0 o/nin

1 1 1200.0 300.0

Temperature (*C)

CQ

O

o-a

33

O

1 1 1400.0

SM FULTONPERKIN-ELMER7 Series Thermal Analysis SystemFri May 30 12:38:26 1997

Curve 1: TSAFile Info: SAM053006 Frl May 30 13:23:15 1997Sample Height: 20.020 mgS97T000910 DUP

© *>to §,

CD

100.0 -

90.0-

80.0-

70.0-

60.0-

50 .0-

40 .0 -

30 .0-

XIX2

S iY 2 \AY \

\

24.829 *C159.383 *C99.807 Ht.33.559 Ht.

-66,248 Ht.

\

\

N^j

XXX

lOC/MIN N2

CO

9.

DO

100.0

0.0 Bin RATE1: 10.0 C/»in

1 | p200.0 300.0

Temperature (*C)

400.0

SM FULTONPERKIN-HJCR7 Series Thermal Analysis SystemFri May 30 13:26:46 £997

Curve 1: T8AFi le info: SAM053007 Fri May 30 14:30:49 1997Sample Height: 21.652 rag•SB7T000010- DtJP

100.0 "

90.0-

jj 80.0-

~ 70.0-

m* 60.0"

50.0-

40.0-

30.0-

XIX2

A\>

29.916 *C

159.788 #C

99.812 »t.

34.169 Ht.

-65.643 Wt.

\

\

\

XX

x

s9

DOm

100.0 200.0 300.0 i T400.0

10C/MIN N2 Temperature (*C) SM FULTONl: ao.o c TIHBI: o.o win RATE*: IO.O Q/Bin PERKIN-ELMERB BO0-° ° 7 Series Thermal Analy8is Systea

Fri May 30 15:08:24 1997

Curve 1: TGAFile info: SAM053008 Fri May 30 IB: 01:00 1997Sample Height: 21.453 ngS97T000911 OUP

100.0

50.0-

40.0-

30.0 4T

26.379 *C155.262 *C99.898 Ht. X3.440 Ht. X.458 Ht. X

39

1

100.0

J 1

lOC/MIN N2i: as .o c TXxei: o.o mm RATK1: 10.0 c/alnB; fiOO.O C

200.0 300.0 400.0

Temperature (*C) SM FULTONFULTONPERKIN-ELMER7 Series Thermal Analysis SystemFrl May 30 18:24:51 1997

CO

o

o-a

I

worklistrpt Version 2.1 05/15/9506/03/9715:29

Page:


Analyst: •JVS Instrument: TGAO Bookl T7/I/8A

Method: LA-514-114 Rev/Mod t>-0 HNF-SD-Wy-DP-254, REV. 0


GROUP PROJECT

97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

S TYPE SAMPLES R A

1 STD

2 SAMPLE S97T000912 0

3 DUP S97T000912 0 : • •

4 SAMPLE S97T000913 0

5 DUP S97T000913 0

TEST

TGA-03

TGA-03

T6A-(B>

TGA-03

TGA-03

MATRIX

SOLID

SOLID

SOLID

SOLID

SOLID

ACTUAL

N/A

71.01

N/A

FOUND

1-a.of

DL

•" N/A

N/A

N/A

UNIT

%

%

%

X

Analyst Signature ate



Units shown for QC (SPK & STD) may not reflect the actual units. DL = Detection limit, S = Worklist Slot Number,R = Replicate Number, A = Aliquot Code.

woMstnpt Version 2.1 05/15/95 ittFSWWM-GMlSrRHMm^ p0V2?/07 00-50 • i~iH-~l I

LABCORE Data Entry Template for Worklist# 18283Analyst: ^ < A S Instrument: TGAO 3

Method: LA-560-112 Rev/Mod P ~ C >



97000311 T-201

97000311 T-201

97000311 T-201

97000311 T-201

S TYPE SAHPLE# R

1 STD

2 SAMPLE S97T000912 0

3 DUP S97T000912 0

4 SAMPLE S97T000913 0

5 DUP S97T000913 0

TEST

TGA-01

TGA-01

TGA-01

TGA-01

TGA-01

MATRIX ACTUAL FOUND

SOLID _ _ _ _ _

SOLID

SOLID

SOLID

DL UNIT

H/A %

N/A

SOLID


cJcutt^.jkti*Date Analyst {Signature Date

Entry Comments:

Units shown for QC (SPK & STD) may not reflect the actual units. DL = Detection Limit, S - Worktist Slot Number,R = Replicate Number, A = Aliquot Code.

Curve 1: TGAFile Info: TER052904 Thu >Sample Height: 24.301 mg97N8-A

29 14:47:22 1997

100.0 -

90.0-

J 80.0-

| 70.0 -

60.0 -

50.0-

40.0-

XIX2

Y2AY

26.744 *C297.055 *C

—.^101.727 Wt. %^""^4^812 Ht. %

-59^56 Ht. X

V\T

10C/MIN N2sg§:8 8 TIM8JJ

75.0T r

0.0 am RATE!: 10.0 C/mn

125.0 175.0

Temperature CO

i I i r225.0 275.0

RA GREENPERKIN-ELMER7 Series Thermal Analysis -SystemFri May 30 01:15:12 1997

CO

9

- IP

5 :

Curve i: TSAFile info: SAM053001 Thu May 29 23:57:17 1997Sample Height: 21.987 mg

S97T000912

100

nASO

80

a 70

1 .50

40

30

20

.0-

fi

.0

.0-

.0-

.0-

.0-

.0-

.0-

.0-

XIX2

Y 2 \AY \

\

25.505

169.898

99.843

27.755

-72.088

\

\

\

\

•c•cWt.

Ht.Ht.

J

XXX

x-T)

I

10C/MIN N2

100.0

0.0 Din RATEU 10.0 C/min

i r r200.0 300.0

Temperature (*C)

iso

i r400.0

JD SPEOMANPERKIN-ELMEH7 Series Thermal Analysis SystemFri Nay 30 00:33:16 1997

Curve l: T6AFile Info: SAM053002 Fri May 30 01:22: 57 1997Sample Height: 16.957 ntgS97T0009120UP

©

100.0 -

90.0-

80.0-

70.0-

60.0-

50.0-

40.0-

30.0-

ao.o-

XIX2

Y2\AY \

\

25.238 'C139.972 *C99.S51 Wt. X28.514 Wt. X-71,337 Wt. X

\

\

\

10C/MIN N2

• m,

av

100.0T

200.0

ae.o g TIMBI: o.o am RATOU 10.0 c/mxn

300.0

Temperature (*C) <J0

400.0

JD SreANPERKIN-ELMH17 Series Thernal Analysis SystemFrl May 30 05:35: 08 1997

Curve 1: TGAFile Info: TER053001 Fri May 30 06:00:29 1997Sample Weight: 17.771 mg97N8-A

100.0

90.0-

80.0-

70.0-

60.0-

50.0-

40.0-

I

26.672 'C297.533 *C

99.820 Wt. X41.182 Wt. %-58.638 Ht. X

75.0

10C/MIN N2U 3O-O c TIMS1: 0.0 "in RATE!: 10.0 C/Un

125.0 175.0

Tempepatupe (*C)

OCO

D9

225.0

SM FULTONPERKIN-EUER7 Series Thermal Analysis SystemFri May 30 06:07:33 1997

Curve l: TGAFile info: SAH053003 Fri Hay 30 07:04:26 1997Sample Height: 24.830 tagS97T000913

100.0

30.0-

20.0-

10C/MIN N2§:§ 8

33.538 *C177.622 *C99.718 Ht. X29.000 Ht. X-70.718 Ht. X

100.0!—

200.0

0.0 »in RATB1: 10.0 c/mm

1 1 —.. 300.0

Temperature (*C)

o-a

33

• 2

• j?

1 -j 1400.0

SM FULTONPERKIN-ELMER7 Series Tharoal Analysis SystemFri May 30 08:01:17 1997

Curve 1: T6AFile Info: SAM053004 Fri May 30 09:17:00 1997Sample Height: 23.654 ragS97T000913 D«

212

Hei

gh

t (H

t

100.0 -

90.0-

80.0-

70.0-

60.0-

50.0-

40.0-

30.0-

90.0-

XIX2

X 1

A Y \

\

33.172.

99.29.

-69.

\

\

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578181847956891

•c•cHt.Ht.Ht.

1

XXX '

100.0 200.0 300.0

10C/MIN N2 Temperature C OTEMPI: 3B.0 C TXMB1: 0.0 "in BATE!: 10.0 C/minTEMPK BOO.O C

i *CO

o

o

3d

.3if

400.0

SM FULTONPERKIK-€LMER7 Series Thermal Analysis SyateaFri May 30 09:27:30 1997

HNF-SD-WWi-DP-254, REV. 0worklistrpt Version 2.1 05/15/95 Page:

07/22/9708.-09 L A B C O R E D a t a E n t r y T e m p l a t e f o r Worklist# 18906

Analyst: fi.S)M Instrument: TGA0 3

Method: LA-514-114 Rev/Mod D - 1

Worklist Comment: T-201 TGA, RUN UNDER N2. RCJ

GROUP PROJECT S TYPE

1 STD

97000311 T-201 2 SAMPLE

97000311 T-201 3 DUP

97000311 T-201 4 SAMPLE

97000311 T-201 5 DUP

SAMPLE*

S97T001246

S97T001246

S97T001253

S97T001253

R A TEST

TGA-03

0 TGA-03

0 TGA-03

0 TGA-03

0 TGA-03

MATRIX

SOLID

SOLID

SOLID

SOLID

SOLID

Book# /03/i/££

ACTUAL

N/A

Co, %,

N/A

.83.^

FOUND DL UNIT

S&. fc W f N/A %

4.0 . - * b %

> Co<S.'8 5 ' N/A %

B3.W %

8 ? . * 8 N/A %

Analyst Signature


jate Analyst Signature



2 1 3

HNF-SD-WM-DP-254, REV. 0workUstrpt'Version 2.1 05/15/95


Analyst: lH|)ff)

Method: LA-560-112 Rev/Mod Q-

Instrument: TGAO 3 Book#

T/orklist Comment: T-201 TGA, RUN UNDER N2. RCJ

: 7000311 T-201

"7000311 T-201

'7000311 T-201

•7000311 T-201

S TYPE

1 STD

2 SAMPLE

3 DUP

4 SAMPLE

5 DUP

S97T001246 0

S97T001246 0

S97T001253 0

S97T001253 0

TEST--

TGA-01

TGA-01

TGA-01

TGA-01

TGA-01


SOLID . N/A

SOLID

SOLID

SOLID

SOLID .

N/A

N/A

N/A

N/A


Analyst Signature IJate

Units shownforQC (SPK & STD) may not reflect the actual units. DL - Detection Limit, S - Worklist Slot Number,f = Replicate Number, A = Aliquot Code.

2 1 4

Curve 1: TGAFile info: TER071901 Sat Jul 19 07:31:57 1997Sample Weight: 13.821 mg

%

Wei

ght

(

100.0 -

90.0-

80.0-

70.0-

60.0-

50.0 -

40.0-

XI

X2

Y"! "---•Y2

AY

23

295

- ^ ^ 99

^\41-581

.833

.449

.974

.302

^ 7 2

\

^pmvVERlffEDTHE CALIBRATION/ ANAUYSfS ON P A G E S ^ S I T O / ^ O

•c•cW t . %

Wt. %

W t . %

\

-nin9

-o

33

o

50.0 100.0

10C/MIN N20 . 0 min RATEl: 10 .0 C/mln

150.0

Temperature (°C)

200.0I

250.0

RD MEYERSPERKIN-ELMER7 Series Thermal Analysis SystemSat Jul 19 19:34:20 1997

Curve 1: TGA

File info: SAM071909 Sat Jul 19 IS 27:20 1997

Sample Weight: 19.624 mg

S97T001246

Weig

ht

(k

100.0-

90.0-

80.0-

70.0-

60.0-

50.0-

40.0-

30.0 -

XI

X2

Y 2 \

AY \

\

27.652162.27999.75839.502

-60.256

V

\

\

• cwt. %wt. %wt. %

10C/MIN N2

33

m

100.0

0.0 mln BATEIT 10.0 c/mln

1 I T200.0 300.0

Temperature (*C)

400.0

RD MEYERSPERKIN-ELMER7 Series Thermal Analysis SystemSat Jul 19 19:21:40 1997

Curve 1: T6AFile info: SAM071910 Sat Jul 19 14:16:39 1997Saaple Weight: 13.239 noS97T00M6BUP- i /

100.0 -

90.0-

R 80.0-4J

*• 70.0 •

£60.0-

50.0-

40.0-

30.0-

XI. X2

Y 2 \AY \

\

2515S9936

-62

.

\

\

\

\

.112 *C

.880 *C

.747 Wt.

.898 Ht.

.849 Ht.

^

XXX

Tl

a

oT3

33

m

100.0 0 r 0

10C/MIN N2S a?8"8 S TIM*t:

200.0 300.0

Temperature (*C) RD MEYERS

I400.0

PERKINaj€R7 Serle8 Thernal Analysis SystenSet Jul 19 18:55:06 1997

Curve l: T6AFile info: SAM071911 Sat Jul 19 IS: 28:32 1997Saaple Height: 10.334 «gS97T001253

110.0 -

100.0 -

90.0-

80.0-

SS70.0-g

g 60.0-

£ 50.0-

40.0-

30.0-

20.0-

10.0-

XIX2

Y2 \AY \

\

25.143.99.15.

-83.

\

\

\

235178839904936

•c•cNt.Nt.Ht.

XXX

10C/HIN N2

100.0

•z-n

oT3

33

o

0.0 mill RATE*: 10.0 C/Mlfl

200.0 300.0 400.0

Teaperatura CO BD MEYERSPERKIN-EWER7 Series Therul Analysis SysteaSat Jul 19 18:48:22 1997

Curve 1: T6AFile info: SAM071912 Sat dul 19 16:59:10 1997Saaple Height: 10.938 «gS97T001253DUP

24.408 *C151.881 *C99.770 Wt. %

12.489 Wt. X

-87.281 Mt. X

10C/MIN N2

XTtCOO

o"0

o

100.0 200.0 300.0

JR.8 S TXMK1: 0.0 «ln (UTU: 10.0 0/«lnTeaperatupe (*C)

T I I400.0

Ml »EYERSPERKIN-axER7 Series Theriwl Analysis SystesSat Jul 19 IK 45: 27 1997

worklistdata Version 1.0 05/15/96 Page:

05/29/9713:30

LABCORE Completed Worklist Report for Worklist# 18277

Analyst: rag Instrument: BA001 Book#

Method: LA S1Q-1\ XRev/Mod T>~\ HNF-SD-WWi-DP-254, REV. 0

Worklist Comment: T201, SPG Use a calibrated pipette, skm

Seq Type Sample* R A

1 sio

2 SAMPLE

3 DUP

4 SAMPLE

5 DUP

6 SAMPLE

7 DUP

8 SAMPLE

9 DUP

10 SAMPLE

11 DUP

12 SAMPLE

13 DUP

S97T000823

S97W0Q825

S97I000833

S97T00083S

S97T000834

597T00.0834

S97T000835

S97T000835

S97T000836

S97T000836

S97T000837

S97T000837

Test

SPC-01

SPG-01

SP5-01

SPG-01

SPG-flJ

SPG-01

SPG-01

SPG-01

SPG-01

SPG-01

SPG-01

SPG-01

SPG-01

Matrix Actual Found DL or Yield Unit

.1.395

0.997

««»a1.055

1.054

1.055

IMi

1.058

1.050

1.065

um1.057

1.071

».818 % Recovery

1.00e-002 Sp.G.

o«tofr m>1.00e-002 Sp.G.

0.OS5 RP8

1.00e-002 Sp.G.

0,56? SPB

1.00e-002 Sp.G.

« . ? » RPO

1.00e-002 Sp.G.

i.323 8PD

1.00e-002 Sp.G.

1.316 «PB

Final page for worklist# 18277

Analyst Signature Date Analyst Signature

Reviewer Signature Date

Date

Units shown for QC (BLK/BKG) may not reflect the actual units.

2 2 0

worklistrpt Version 2.105/15/9505/23/9708:44 L A B C O R E

IINPOD WM DP 216, REV. Q

E n t r y T e m p l a t e f o r Worklist# 18277

Analyst: R>

Method:LA-510-112

Worklist Comment:

Rev/Mod

T201, SPG

Instrument: BA001

O lUse a calibrated pipette.

Book # ^ 1

HNF-SD-Wy-DP-254,skm

\?M)b-AREV.O

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

97000311

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

T-201

S TYPE

1 STD

2 SAMPLE

3 DUP

4 SAMPLE

5 DUP

6 SAMPLE

7 DUP

8 SAMPLE

9 DUP

10 SAMPLE

11 DUP

12 SAMPLE

13 DUP

S97T000823 0

S97T000823 0

S97T000833 0

S97T000833 0

S97T000834 0

S97T000834 0

S97T000835 0

S97T000835 0

S97T000836 0

S97T000836 0

S97T000837 0

S97T000837 0

TEST--

SPG-01

SPG-01

SPG-01

SPG-01

SPG-01

SPG-01

SPG-01

SPG-01

SPG-01

SPG-01

SPG-01

SPG-01

SPG-01

MATRIX

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

LIQUID

FOUND DL UNIT

/• 3 1 5 H/A Sp.G.

cmN/A r^-^g?- OiCIO Sp.G.

N/A Sp.G.J.05S

N/A J~o55tf O.OiOsp.G.

Sp.G.LOBS'

N/A -f^oSSy- d.OIOsp.G.I. OS5 I.Ofol

i. essN/A

H/A

. Sp.G.

'. S P- G -

Sp.G.

H/A *-<tk^3- fliOJO Sp.G.

1 .058 UOSO

rl'0lc'/7/.C5I

H/A Sp.G.

Q.0IQ Sp.G.N/A / ?(.057 f.07l

4?V^i>? /'O'ft3~ N/A Sp.G.


Analyst Signature halystiSiSgnature



2 2 1

PLACE ANALYTICAL CARD IN BOX BELOW OR ATTACH TRAVELER


SPECIFIC GRAVITY:Type

STANDARD

Work List18277

Test CodeSPG-01

MatrixLIQUID

Sample #STD

Instrument CodeBA001

AnalystRAG

Date05/27/97

Tifne11:30 AM

Gross Weight (W2)Tare Weight (W1)Weight of Solution (W2-W1)Volume of Solution uLSpecific GravitySpecific Gravity (Average)

STANDARD1.50181.39650.1053

75.14001.40141.3954

Gross Weight (W2) = Wt. of vial + cap + cotton + solutionTare Weight (W1) = Wt. of vial + cap + cotton

Specific Gravity = [(W2-W1) * 1000 uL/mL] / [Vo

v RESULT vSpecific Gravity Average =

. of Solution uL

1.3951

STANDARD1.53901.43460.1044

75.14001.3894

* 1.000 g/mL]

Data Entry by: Date: 05/27/97Approved by: Date: *>/zi/t7Form510112L1 Rev. 1.1 Page 1 of 1

2 2 2



SPECIFIC GRAVITY : LA-510-112Type

SAMPLE

Work List18277

Test CodeSPG-01

MatrixLIQUID

Sample #S97T000823


AnalystRAG

Date05/27/97

Time11:30 AM

Gross Weight (W2)Fare Weight (W1)Weight of Solution (W2-W1)Volume of Solution uLSpecific GravitySpecific Gravity (Average)

Gross Weight (W2) = Wt. of vial + capTare Weight (W1) = Wt. of vial + cap +

SAMPLE1.49761.42270.0749

75.14000.99680.9975

+ cotton + solutioncotton

Specific Gravity = [(W2-W1) * 1000 uL/mL] / [Vol. of Solution uL

v RESULT vSpecific Gravity Average = 0.9971

REPLICATE1.51341.43840.075

75.14000.9981

* 1.000 g/mL]

Form510112L1 Rev. 1.1 Page 1 o fT '

2 2 3

WM



SPECIFIC GRAVITY : LA-510-112Type

SAMPLE

Work List18277

Test CodeSPG-01

MatrixLIQUID

Sample #S97T000833


AnalystRAG

Date05/27/97

Time11:30 AM


SAMPLE1.40861.32930.0793

75.14001.05541.0547

REPLICATE1.50941.43020.0792

75.14001.0540


Specific Gravity = [(W2-W1) * 1000 uL/mL] / [Vol. of Solution uL * 1.000 g/mL]




SPECIFIC GRAVITY : LA-510-112 (G-3f» ^ $ eri7c,[cr7

TypeSAMPLE

Work List18277

Test CodeSPG-01

MatrixLIQUID

Sample #S97T000834


AnalystRAG

Date05/27/97

Time11:30 AM


SAMPLE1.55111.47180.0793

75.14001.05541.0580


Specific Gravity = [(W2-W1) * 1000 uL/mL] / [Vol. of Solution i


REPLICATE1.40321.32350.0797

75.14001.0607

J L * 1.000 g/mL]

Data Entry by: Date: 05/27/97

Approved by: Date:Form 510112L1 Rev. 1.1

2 2 5



SPECIFIC GRAVITY : LA-510-112 (6=3)Type

SAMPLE

Work List18277

Test CodeSPG-01

MatrixLIQUID

Sample #S97T000835


AnalystRAG

Date05/27/97

Time11:30 AM


SAMPLE

Gross Weight (W2) = Wt. of vial + cap + cotton +Tare Weight (W1) = Wt. of vial + cap + cotton

Specific Gravity = [(W2-W1) * 1000 uL/mL] / [Vol.


1.50421.42470.0795

75.14001.05801.0540

solution

of Solution uL

1.0541

REPLICATE1.44341.36450.0789

75.14001.0500

* 1.000 g/mL]

Data Entry by: Date: 05/27/97

Approved by: Date:Form510112L1 Rev. 1.1 /

226PageM of 1

-WF^frVWl-DP-240,



SPECIFIC GRAVITY : LA-510-1124G-3tType

SAMPLE

Work List18277

Test CodeSPG-01

MatrixLIQUID

Sample #S97T000836


AnalystRAG

Date05/27/97

Time11:30 AM


SAMPLE

Gross Weight (W2) = Wt. of vial + cap + cotton +Tare Weight (W1) = Wt. of vial + cap + cotton

Specific Gravity = [(W2-W1) * 1000 uL/mL] / [Vol.


1.49091.4109

0.0875.14001.06471.0580

solution

of Solution uL

1.058

REPLICATE1.50471.42570.079

75.14001.0514

* 1.000 g/mL]

Form510112L1 Rev. 1.1 Page '1 of 1 "

227


HWF-SD-WM-DP-254, REV. 0

SPECIFIC GRAVITY : LA-510-112^G=3tType

SAMPLE

Work List18277

Test CodeSPG-01

MatrixLIQUID

Sample #S97T000837


AnalystRAG

Date05/27/97

Time11:30 AM


SAMPLE1.42811.34870.0794

75.14001.05671.0640


REPLICATE1.40351.32300.0805

75.14001.0713

Specific Gravity = [(W2-W1) * 1000 uL/mL] / [Vol. of Solution uL * 1.000 g/mL]


Data Entry by: _ Date: 05/27/97

Approved by: (T)XY\ Date:Form510112L1 Rev. 1.1 /

2 2 8

worklistdata Version 1.0 05/15/9606/12/9714:44 -HNF-SD-WM-1 w


Analyst: dpb Instrument: IC01

Method: IA 'd'33-/dr~Rev/Mod ]>-/

Worklist Comment: T201, @IC-01 skm

Book#


Seq Type Sampled R A Test Matrix Actual Found DL or Yield Unit

0 ©IC-QC CL QC 1

0 ©IC-QC BR QC 1

<1.70e-2

<1.25e-l

©IC-QC PO4 QC

0 OIC-QC OXALATE2 QC

0 ©IC-QC CL QC

MC-QC BR

©IC-QC PO4

QC 7.90e01

QC 5.89eO2

QC 5.45eO2

<1.05e-l

iiiiiili

7.77e+01

5.96a+02

5.50«+02

ug/mL

ug/mL

isiiiiiug/mL

98.354 % Recovery

lliilllllliiiiiiliiiil

101.188 % Recovery

100.917 % Recovery0 <3IC-QC OXRLATE2 QC 5.36eO2

'•'•i' '-'Q'.''.'.•'.'.'.'.-'' ® I C rr-O^i-' '•'•' ' - 'F ^' 0' 2v-'''-'°:-'-^"'-''ILIQ.UID v i ' ^ ' ; v ^ STi^ A;-^'' - ''•''•-''•''•-'•''•

0 @IC~ 01 CL~ 02 LIQUID JT/A

5.55e+02

8.780e+00

S97T001242 0 ©IC-01 PO4-02 LIQUID M/A <

S97T001242 0 @IC-01 0XALATE2 LIQUID

1.320O+00

| | | | | | | | i c j l | | | ;1.155e+00

103.545 % Recovery

0.187 ug/mL

1.375 ug/mL

1.320 ug/mL

1.155 ug/nL

S97T001242 0 OIC-01 BR-02 LIQUID <1.38eO

S97T001242 0 ©IC-01 PO4-02 LIQUID <1.32eO

S97T001242 0 ©IC-01 OXALATE2 LIQUID <1.16eO

S97T001203 0

S97T001203 0

265.100

254.500 ug/mL

111111111222.700 ug/mL

@IC-01 OXALATE2 LIQUID::i:;:#ics!pi1ts.iS::;iEfl1tfii::^

Uhto shown for QC (BLK/BKG) may not reflect the actual units.

.229

HNF-SD-WM-DP-254, REV. 0worklistdata Version 1.0 05/15/96 - | |jvj|

06/12/9714:44

Page:

LABCORE Completed Worklist Report for Worklist# 18268Seq Type Sample# R A

6 DUP

jMatrix Actual Found DL or Yield Unit39e+02 4.974 RPD

iiiiii

mmm

S97T001203

wmmm

m

I

0

wmmm

will

©IC-01

Ssfip.ijift.Siioiii

mmHIQXALA

F-02

mmmm

liiiliiiiil

LIQUID

mm

i l l l l :

,,,^:S..,

sot

^

5

i

5

11

I I

.74e

11

+ 0 1

m

l

97

•jSWv:'>myj>.;:v:i?£:jj'g

96

;:ss:M?>M;:Ls9'iSi

:•!§:;?!

2 6 6

2 8 8

S 0 7

U39

R P D

R P D

% Recovery

S97T001203 0 ©IC-01 NO3-02 LIQUID 5.94eO2 5.66a+02 95.286 % Recovery

S97T001203 0 ©IC-01 SO4-02 LIQUID 6.31o02 6.27e+02 99.366 % Recovery



e^fe


230

06/03/9714:52A-0004-1

-tWF-SD-WM-DP-246,

LABCORE Data Entry Template for Worklist# 18268Page:

Instrument: ICOAnalyst:

Method: LA-533-105 Rev/Mod;



S Type

1 CCB

2 CCV

3 SAMPLE

4 DOP

5 SAMPLE

6 DUP

1 SPK

Sample* R A Test

©IC-QC

aic-QC

Matrix

QC

QC

S97T001242 0 8IC-01 LIQUIDAnalytes Requested: BR-02 , CL-02

OXALATE2, P04-02

S97T001242 0 OIC-01 LIQUID

S97T001203 0 (SIC-01 LIQUIDAnalytes Requested: BR-02 , CL-02

OXALATE2, PO4-02

6roup# Project

97000311 T-201F-02 , NO2-02SO4-02

97000311 T-201F-02 ) HO2-02SO4-02

NO3-02

NO3-02

S97T001203 0

S97T001203 0

eic-oi

8IC-01

LIQUID

LIQUID


%Analyst Signature Date


S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code.

2 3 1

Date: 06/05/1997 20:01:06Sample Name: ELUENT BLANKData File : C:\DX\DATA\97060511.D01Method : C:\DX\METHOD\KIT.MET HNF-SD-WM-DP-254, REV. 0ACI Address: 1 System: 1 Inject#: 1 Detector:CDM-1Analyst : /^l.jjfL Column: AG4A/AS4A anion column

Calibration Volume "'Dilution Points Rate Start Stop Area Reject ,

External 1 1 3000 5Hz 0.00 10.00 30

*************************** peak Report: All Peaks ****************************

Pk.Num

123

RetTime

1.433.286.13

ComponentName

nitratesulfate

Concentrationug/ml

0.0000.090

-0.015

Hexght

222337

Area

129127593

Bl .Code

111

%Delta

0.921.77

Totals 0.075 82 849

US

0.10

0.08

0.06

0.04

0.02

0.00

-0.02

-0.04

-0.06

-0.08

-0.10

File: 97060511. D01 Sample: ELUENT BLANK

~i i—r~

JI ' '1

\\

~i i ] n~

2

nitrate

1

1

1 1 1 1 i 1

31 ' '4

' 1 '5

SUlfetG

1 1 j i 1

6I7

i i 1 , i

8 g ' ' 110

Minutes

2 3 2

Sample Name: STD 61N20-BData File : C:\DX\DATA\97060511.D02Method : C:\DX\METHOD\KIT.METACI Address: 1 System: 1 Inject#: 2 Detector:CDM-1Analyst : Column: AG4A/AS4A anion column

Date: 06/05/1997 21:58:30


Calibration Volume Dilution Points Rate Start Stop Area Reject

External

* * * * * 4

Pk.Num

12345678

1

****************

RetTime

1.101.611.892.783.154.595.927.79

ComponentName

fluoridechloridenitritebromidenitratephosphatesulfateoxalate

101 3000 5Hz 0.00 10.00

<r**** peak Renort: All Peaks

30

Concentrationug/ml

ight

13612054582355636228182552492734

Area

979110137435823729850490243777683149081

Bl.Code

11111111

%Delta

-1.790.84-2.081.83-2 .97-0.58-1.77-0.68

54.49477.652551.161596.361605.919549.550625.894554.841

Totals 3615.873 30836 301587

uS

9.0

8.0

7.0

6.0

5.0

4.0

3.0

2.0

1.0

0.0

-1.0

File: 97060511.D02 Sample: STD 61N20-B

nitratenitrite

I bromid1 I sulfate

i i I i I i i I I I I | I M I [ I I I I | I I I I | I I I I | I N I | I I I I |

4 5 6 7 8 9 10

Minutes

233' /

-1 IMF

Sample Name: S97T001242 SAM -Data File t C:\DX\DATA\97060511.D05Method : C:\DX\MBTHOD\KIT.METACI Address: 1 System: 1 Inject*: 5

Date: 06/05/1997 22:46:37


Analyst Column: AG4A/AS4A anion columnDetector:CDM-1

Calibration Volume ' Dilution Points Rate Start Stop Area Reject

External 1 11 3000 5Hz 0.00 10.00 30


Pk.Num

1234

RetTime

1.151.623.265.97

ComponentName

fluoridechloridenitratesulfate

Concentrationug/ml

0.3638.7801.953

15.441

Totals 26.537

Height

151755125985

2879

Area

3910528

86217788

29217

Bl.Code

1111

%Delta

2.981.670.31-0.88

uS

1.8

1.6

1.4

1.2

1.0

0.8

0.6

0.4

0.2

0.0

-0.2

File: 9706051LD05 Sample: S97T001242 SAM

fluoride fnitrate

I I I I i I I I I | i i I I | i i i i | i i i i

2 3 4 5

Minutes

"T "i i i ] i i i ••; r i ^ r~ i ""Pi i i i I

7 8 9 10

234

H4NF-SD-Wy-DP-g4G, REV.

Sample Name: S97T001242 DUP- Date: 06/05/1997 22:57:16Data File : C:\DX\DATA\97060511.D06Method : C:\DX\METHOD\KIT.MET HNF-SD-WM-DP-254, REV. 0ACI Address: 1 System: 1 Inject*: 6 Detector:CDM-1Analyst : Column: AG4A/AS4A anion column


External 1 11 3000 5Hz 0.00 10.00 30


Pk.Num

123

. 45

RetTime

1.151.451.613.265.97

ComponentName

fluoride

chloride •nitratesulfate

Concentrationug/ml

0.3600.0008.2522.32015.635 -

Height

1418

1723153

1001

Area

35105

98891142

18003

Bl.Code

11111

%Delta

2.98

1.260.31-0.88

Totals 26.568 2909 29174

US

1.8

1.6

1.4

1.2

1.0

0.8

0.6

0.4

0.2

0.0

-0.2

File: 97060511.D06 Sample: S97T001242 DUP

i I i i i

5

Minutes

| i i

6 10

2 3 5

H-H4F'UU-WltfHJr i ^

Sample Name: S97T001203 SAM -Data F i l e : C:\DX\DATA\97060511.D12Method : C:\DX\METHOD\KIT.METACI Address: 1 System: 1 In j ec t* : 12Analyst

Date: 06/06/1997 01:59:25

HNF-SD-WM-DP-254, REV. 0Detector:CDM-1

Column: AG4A/AS4A anion column

Calibration Volume Dilution Points Rate Start Stop Area Reject '

External 1 2121 3000 5Hz 0.00 10.00 30


Pk.Num

123456

RetTime

1.071.611.953.054.676.08

ComponentName

fluoridechloridenitritenitratephosphatesulfate

Concentrationug/ml

4176.901940.690310.153

47659.298757.607114.413

Totals 53959.061

Height

59041088

6922767

10397

30029

Area

387115835403

19983813121431

247530

Bl.Code

111l1X

%Delta

-4.171.261.04-6.261.160.88

File: 97060S1LD12 Sample: S97T001203 SAM

uS

40

30

20

10 fluoride

Isulfate

i

1 1 1

2I I I I ! I I I I I I I I I I I I I M I j I I I I—I

5 6 7 8 9 10

Minutes

Sample Name: S97T001203 DUP•-.Data File : C:\DX\DATA\97060511.D15Method : C:\DX\METHOD\KIT.METACI Address: 1 System: 1 Inject#: 15Analyst

Date: 06/06/1997 02:42:14




External 1 2121 3000 5Hz 0.00 10.00 30


Pk.Num

123456

RetTime

1.071.611.953.054.646.08

ComponentName


Concentrationug/ml

4242.028988.800312.082

47103.981694.118277.264

Totals 53618.273

Height

58531123

7022724

98136

30003

Area

393576133410

19734711782358

246784

Bl.Code

11111l

%Delta

-4.171.261.04-6.260.580.88

File: 97060511.D1S Sample: S97T001203 DUP

uS

40

30

20

10

nitrate

fluoride

sulfate

' ' I ' ' ' ' I ' ' ' '4 5

Minutes

10

237

Date: 06/06/1997 02:58:47

HNF-SD-WM-DP-254, REV. 0Sample Name: S97T001203 SPK •Data File : C:\DX\DATA\97060511.D16Method : C:\DX\METHOD\KIT.METACI Address: 1 System: l Inject#: 16 Detector:CDM-1Analyst : Column: AG4A/AS4A anion column


External 1 2121 3000 5Hz 0.00 10.00 30

*************************** peajc Report: All Peaks ****************************

Pk.Num

12345678

RetTime

1.071.591.872.753.034.595.927.73

ComponentName


Concentrationug/ml

5335.5982635.43410906.29711063.48059091.54311598.21212673.56111280.682

Totals 124584.807

Height

7829305254405252

28674200552952608

60155

Area

50384165174098932837

252080245027406647500

538874

Bl.Code

11111111

%Delta

-4.760.00

-2.770.61

-6.67-0.58-1.77-1.36

File: 97060511.D16 Sample: S97T001203 SPK

uS

40

30

20

10

nitrate

fluorideJ nitrite bromi<• chloric^

1 I1

1 I '2 5 6

Minutes

10

•238

worklistdata Version 1.0 05/15/960512919716:18

-HNF-SB-WM-DP 246, REV.


Analyst: krq Instrument: IC01

Method: />f-5"33 -/(XT Rev/Mod D - /


Book#


Seq Type Sample# R A Test Matrix Actual Found DL or Yield Unit

0 SIC-QC CL

©IC-QC BR QC 1 <1.25e-l

•SIC-QC PO4 QC 1 <1.20e-l

SIC-QC OXALATE2 QC

SIC-QC CL QC 7.9

ug/mL

ug/mL

iiiiiii

ug/mL

ug/mL

97.468 % Recovery

95.756 % Recovery

lllfillllllilll95.780 % Recovery

411111!4 DUP

0 ©IC-QC BR QC 5.89eO2 5.64e+02

0 SIC-QC PO4 QC 5.45e02 5.22e+02

0 SIC-QC OXALATE2 QC 5.32e02 5.28e+02 99.248 % Recovery

S97T000834 0 ©IC-01 CL-02 LIQUID M/A 1.012e+03 18.890 ug/mL

S97T000834 0 ©IC-01 OXALATE2 LIQUID H/A < 1.167e+02 116.700

S97T000834 0 ©IC-01 CD-02 LIQUID l*01e+03 1.03e+03 1*961

S97T0i

4.161

5 SAMPLE

5 SAMPLE

Si r SMIPliES

5 SAMPLE

5 SAMPLE

S97T000835 0 ©IC-01 CL-02 LIQUID H/A 9.105e+02 18.890

S97T000835 0 SIC-01 BR-02 LIQUID M/A < 1.389e+02 138.900

S97T000835 0 ©IC-01 PO4-02 LIQUID H/A 6.167e+02 133.300

r/A < 1.167e+02 116.700

RPD

RPD

ug/mL

5 0 @XC-01 OXALATE2 LIQUID

ug/mL

ug/mL

C/nto shown for QC (BLK/BKG) may not reflect the actual units.

239

worklistdata Version 1.0 05/15/96 Page: 205/29/9716:18 HNF-SD-WM-DP-254, REV. 0

LABCORE Completed Worklist Report for Worklist# 18269Seq Type Sampled R A Test Matrix Actual Found DL or Yield Unit6 DOP S97T000835 0 ©IC-01 CL-02 LIQUID 9.10e+02 8.79e+02 3.466 EPD

6 Dt?P S97T000835 0 ©IC-01 NO2-02 XJIQUZD 1«95O+02 2.060+02 5.486 RPD

6 DOP S97T000835 0 @IC-01 NO3-02 LIQUID 4.33e+04 4.29B+04 0.928 RPD

6 D0P S97T000835 0 @XC-01 SO4-02 XtZQtTXD <1 .53e2 <1,53©2 RPD



I, chut*Signatur^y Date


240

05/23/9707:33A-0004-1

page:


Analyst:y ^ ^ ^ ^/ / ^ ' <-"' ,

Method: LA- 533-105 Rev/Mod \ > - |

ICO I Book#

Worklist Comment: T201, @IC-01 skm HNF-SD-WM-DP-254, REV. 0

S Type Sample*

1 CCB

2 CCV

A Test Matrix

aic-QC QC

@IC-QC QC

3 SAMPLE S97T000834 0 • eIC-01 LIQOIDAnalytes Requested: BR-02 , CL-02

0XALATE2, PO4-02

4 DHP ,

5 SAMPLE

6 DUP

S97T000834 0 ' ©IC-01 LIQDID

S97T000835 0 e IC-01 LIQUIDA n a l y t e s R e q u e s t e d : BR-02 , CL-Q2

S97T000835 0

0XALATE2, PO4-02 , SO4-02

(SlC-01 LIQUID

Group# Project

97000311 T-201P-02 , NO2-02 , NO3-02SO4-02

97000311 T-201F-02 , NO2-02 , NO3-02


Analyst Signature TJate


S = WorkUst Slot Number, R = Replicate Number, A = Aliquot Code.

Sample Name: CCB • . '" ' ' Date : 05/24/1997 19 :06:01Data F i l e : C:\DX\DATA\9705245l'; D02 • UWC CH W/li n P » ! RFV flMethod -. C:\DX\METHOD\AOTOMEL.MET..;:.v.,.- MNI-&U-WWI-Ur-«W, ncv. uACI A d d r e s s ^ ^ S y s t e r r u , 1 I n j e c t * : 2 '."'-. Detector:CDM-1

^ C ^ ^ Column: AG4A/AS4A anion column

CaliiJ]/ /ration,

External

Pk.Num

1

RetTime

1.40

/Volume

1

ComponentName

Dilution Points Rate

1 3000 5Hz

****** pfeak Report: All

Concentrationtig/ml

.; o.boo

Totals ... O.OOO

Start

0.00

Peaks

He:

Stop

10.00

Lght

8

S

Area Reject

Area

31

31

30

Bl. %DeltaCode

1

File: 97052451.D02 Sample: CCB

Minutes

242

Sample Name: CCV 61N20-AData File : C:\DX\DATA\97052451.D03Method : C:\DX\METHOD\AUTOMEL.METACI Address: l^»§ystemi 1 Inject#: 3

Date: 05/24/1997 19:18:39



Calibration/yvoldistfe Dilution Points Rate Start Stop Area Reject

External 1 101 3000 5Hz 0.00 10.00 30


Pk.Num

12345678

RetTime

1.091.591.882.773.144.595.927.73

ComponentName


Concentrationug/ml

57.42776.978

537.420564.105

- 562.451522.268599.006527.547

Totals 3447.202

Height

13631919571752465852191550512324

29388

Area

1035710048424623522646770231347351146638

288146

Bl.Code

11111111

%Delta

-2.980.00-2.42-2.69-3.38-0.58-1.77-1.36

File: 97052451.D03 Sample: CCV61N20-A8.0

7.0

6.0

5.0

4.0

3.0

2.0

1.0

0.0

-1.0

nitrite[ bromi

nitrate

sulfate

oxalate

M | i i i i | i i i i | i i i i | n i i i i i i i | i i i i j i i i i i i i i i | i i i i i

1 2 3 4 5 6 7 8 9 1 0

Minutes

243

-HNF-3D-WM-DP-246,

Sample Name: S97T000834 SAMPLEData File •: C:\DX\DATA\97052461.D05 .Method : C:\DX\METHOD\AUTOMEL.METACI Address: i- .System:. 1 Inject*: 5

Date: 05/24/1997 20:10:20


Anal Column: AG4A/AS4A anion columnDetector:CDM-1

Calibration//volrane Dilution Points Rate Start Stop Area Reject— — — — ___. — __ — — _ -. — _ — — __. — — _________ — _ — — ._____________________

External 1 1111 3000 5Hz 0.00 10.00 30

*************************** peak Report: All Peaks ****************************P k .Num

1234567

R e tTime

1.051.591.933.034.646.087.89

ComponentName

fluoridechloridenitritenitratephosphatesulfateoxalate

Concentrationug/ml

. 4481.7421011.513229.295

48431.884•736.513109.85398.697

Totals .55099.497

Height

134572168

1 4 842177

2 1 01 1 4

32

58305

Area

8505712029

8 8 6416783

26801973

5 5 3

519961

B l .Code

1111111

%Delta

-5.950.000.35

-6.670.580.880.68

File: 9705246LD0S Sample: S97T000834 SAMPLE

uS

40

30

20

10

fluorideii1 chloride

llr1 | j T " | | ' | | | 1 ]

11_l111,

k i"

1' i

phosphate

1 1 M 1 1

sulfate oxalate.•• I 1 •

i i i | i i i i | i i i i | i i i i 1 i i i i

Minutes

Sample Name: S97T000834 DUPData File : C:\DX\DATA\97052451.D06Method : C:\DX\METHOD\AUTOMEL.METACI Address: t^. .Systeiru, 1 Inject*: 6Analyst

Date: 05/24/1997 20:22:59


Calibration

External


Dilution Points Rate Start Stop Area Reject

1 1111 3000 5Hz 0.00 10.00 30

•Pk. Ret ComponentNum Time Name

Concentrationug/ml

4381.9991031.475

. 232.077

.48156.295706.143130.951135.045

54773.986

Height

134042190150

4202719113438

58135

Area

8290312270

906414021

25582203844

515705

Bl.Code

1111111

%Delta

-5.360.000.35-6.870.000.880.68

1234567

1.061.591.933.034.616.087.89


Totals

File: 970524SLD06 Sample: S97T000834 DUP

uS

40

30

20

10

fluorideI

phosphate sulfate oxalate

I I I I 1 I I i I I I I I I I I I I I I I I I I I I I I I I I I I I i I M j I I I I [ I I I i1 2 3 4 5 6 7 8 9 10

Minutes

2 4 5

' HNr-GD-WM

Sample Name: S97T000835 SAMPLEData File : C:\DX\DATA\97052451.D08Method : C:\DX\METHOD\AUTOMEL.METACI Addrejas^-'i/Systepij? 1 Inject#: 8Anal

Date: 05/24/1997 20:48:18



Calibration/^Vol&ffe Dilution Points Rate Start Stop Area Reject

External 1 1111 3000 5Hz 0.00 10.00 30


Pk.Num

123456

RetTime

1.061.591.933.034.646.08

ComponentName


Concentrationug/ml

3916.803910.495194.704

43326.348616.66978.100

Totals 49043.118

Height

117351930124

38178173106

52247

Area

7304110813

636366551

21971628

454866

Bl.Code

1l111l

%Delta

-5.360.000.35

-6.870.580.88

File: 97052451.D08 Sample: S97T000835 SAMPLE40

30

uS

20

10

fluorideI

pho

I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I

1 2 3 4 5 6 7

Minutes

i i I i i i i | i i i i |

8 9 10

'~HNF°6e-WM-DP 246, REV.

Sample NameData PileMethodACI AddressAnalyst

S97T000835 DUPC:\DX\DATA\97052451.D09C: \DX\METHOD\AUTOMEL. MET

System: l^Inject*: 9 Detector:CDM-1Column: AG4A/AS4A anion column

Date: 05/24/1997 21:00:57


Calibration Volume di-^Dilution Points Rate Start Stop Area Reject

External 1 1111 3000 5Hz 0.00 10.00 30

*************************** peak Report: All Peaks ****************************.

Pk.Num

123456

RetTime

1.061.591.933.034.646.08

ComponentName


Concentrationug/ml

3834.337878.970206.069

. 42874.102599.04273.058

Totals 48465.578

Height

115931924123

37820166105

51731

Area

7132410434

718362193

21261573

448368

Bl.Code

111111

%Delta

-5.360.000.00-6.870.580.88

File: 97052451.D09 Sample: S97T00083S DUP

uS

40

30

20

10

fluoride

i chloridephosphate sulfate

i i i i I i i i i I i i i i I i i i i | i i i i | i i i i I i i i i | i i i i | i i i i | i i i i |

1 2 3 4 5 6 7 8 9 1 0

Minutes

247

worklistdata Version 1.0 05/15/9605/28/9714:31


Analyst: krq Instrument: IC02

Method: iA~&*5-}0£~ Rev/Mod h - /


HWF-SD-WM-DP-254, REV. 0


0 ©IC-QC CL QC 1 <1.72eO

0 ©IC-QC BR QC 1 <1.26el

0 ©IC-QC PO4 QC 1 <1.21el

0 OIC-QC 0XALATE2 QC 1 <1.06el

7.90e01 7.41a+01

0 ©IC-QC BR QC 5.89eO2 5.49e+02

0 @IC-QC PO4 QC 5.45eO2 5.10e+02

0 ©IC-QC OXALATE2 QC 5.32eO2 4.86e+02

©IC-QC CL

3 SAMPLE S97T00'

iR-02 LIQUID »/A < 2.651e+02

ug/mL

ug/mL

ug/mL

ug/mL

93.797 % Recovery

93.209 % Recovery

93.578 % Recovery

91.353 % Recovery

36.0G0 ug/mL

2G5.X00

S97T000836 0 @IC-01 OXALATE2 LIQUID IT/A < 2.227e+02

:;!;;s^i^ftjijS|iSiS|;s;:i::^

S97T000836 0 ©IC-01 BR-02 LIQUID <2.G5e2 <2.G5e2

0.778 RPD

RPD

S97T000S36 0 OIC-01 PO4-02 LIQUID G.51e+02 5.98e+02

S97T000836 0 ©1C-01 OXALATE2 LIQUID <2.23e2 <2.23e2

S97T000837 0 ©IC-01 CL-02 LIQUID H/A 9.674e+02

RPD

S97T000837 0 ©IC-01 BR-02 LIQUID N/A < 2.651e+02

36.060 ug/mL

265.100 ug/mL

254.500 ug/mL

222.700

lAwft1 shown for QC (BLK/BKG) may not reflect the actual units.


"-HNF-SD-WM DP 246, nEV.HNF-SD-WM" , REV. 0

LABCORE Completed Worklist Report for Worklist# 18270Seq Type Samples R A

6 DDP

6 DUP

Matrix ActualS97T000837 0 SIC-01 CL-02 L.

iliiiii ilii nEgSilHiii;!;!;liii

•lii

< 2 . 93e2

Found DL or Yield Unit4.350 RPD

0.862 RPD

103.729 % Recovery

IQUID 5,44e02 4.90e+02 90.074 % Recovery

S97T000837 0 ©IG-01 NO3-02 LIQUID 5.94eO2 S.40e+02 107.744 % Recovery

S97T000837 0 ©IC-01 SO4-02 LXQOID 6.31eO2 5.90e+02 93.502 % Recovery



ewer Signature (j Date'


2 4 9

05/23/9707:34A-0004-1

fe


Analyst: --y^^Tnstrument: ICO

Meihod: LA-533-105 Rev/Mod T > - |

WorkBst Comment: T201, @IC-01 skm

Book#


S Type

1 CCB

2 CCV

3 SAMPLE

4 DDP

5 SAMPLE

6 DUP

7 SPK

Samples R A Test

@IC-QC

@IC-QC

Matrix

QC

QC

S97T000836 0 @IC-01 LIQUIDAnalytes Requested: BR-02 , CL-02

OXALATE2, PO4-02

S97T000836 0 @IC-01 LIQUID

S97T000837 0 aIC-01 LIQUIDAnalytes Requested: BR-02 , CL-02

0XALATE2, PO4-02

Group# Prpject

97000311 T-201F-02 , NO2-02SO4-02

97000311 T-201F-02 , WO2-02SO4-02

NO3-02

S97T000837 0

S97T000837 0

OIC-01

©IC-01

LIQUID

LIQUID




2 5 0

Sample NameData FileMethodACI AddressAnal1

CCB :.*•:; Date: 05/24/1997 19:46:48C:\DX\DATA\97052401.D03C: \DX\METHOD\ANIONSA :MET HNF-SD-WM-DP-254, REV. 0

1 Inject*: 3 Detector:CDM-1Column: AG4A/AS4A anion column

Calibratio:

External


101 3000 5Hz 0.00 10.00 50

***** peak Report: All Peaks ****************************

Pk.Num

Ret ComponentTime Name

Concentrationug/ml

Height Area Bl. %DeltaCode

0.871.38

0.0000.000

Totals 0.000

4743

9 1

260244

503

0.08

0.07

0.06

0.05

0.04

US ° ° 3

0.02

0.01

0.00

-0.01

-0.02

File: 97052401. D03 Sample: CCB

2 5

Minutes

n10

SJGNATUBE ABOVE REPRESENTS CHEMICAL TECHNOLOGIST/CHEMIST TH&t-OM>LErE[VVERfRE0tHECAU8RATl0N/ANAU«fS ON P A S £ 2 S Z t i ~

2 5 1

-I INr-OD'WM-DP-240,

Sample NameData FileMethodACI AddressAnal

CCV 61N20-AC:\DX\DATA\97052401.D04C: \DX\METHOD\ANIONSA. MET

stem;,_,l Injects: 4

Date: 05/24/1997 19:59:26



blunfe' Dilution Points Rate Start Stop Area Reject

1 101 3000 5Hz 0.00 10.00 50

Pk.Num


Peak Report: All Peaks ****************************

Concentrationug/ml

ignt

99182321

2251906753945927159242271966

Area

4279906

8310502487563431143881199046381840803

Bl.Code

2211111111

%Delta

1.65

0.00-1.431.493.793.593.68-2.73

1 0.872 1.03 fluoride3 1.384 1.54 chloride5 1.84 nitrite6 2.73 bromide7 3.10 nitrate8 4.61 phosphate9 5.92 sulfate10 .7.73 oxalate

0.00054.5270.000

74.134503.369549.060539.097509.515581.161485.827

Totals 3296.690 32367 272391

File: 97052401.D04 Sample: CCV61N20-A

uS

I I I I I I I I I I I I I I I I I I I I -I I I I I I I I I I I I I I I I I I I I I I I I I I I I I

Minutes

2 5 2

HINrCDWM-DP-240rREVrData Reprocessed On 05/28/1997 14:19:4

Sample Name: S97T000836 SAMPLEData File : E:\DATA\97052401.D05Method : C:\DX\METHOD\ANIONSA.METACI Address: 1 System: 1 Injects: 5

Date: 05/24/1997 20:12:05


Analyst Column: AG4A/AS4A anion column


External 1 2121 3000 5Hz 0.00 10.00 50

P k .Num

12

. 345678

RetTime

0.871.031.541.833.044.615.977.84

ComponentName


Totals

eak Report: All Peaks ******

Concentration Heightug/ml

0.0004278.597

903.164477.577

44819.152651.138222.009

. -134.335

51217.301

8478261307

1 7 822856

787 124

32424

Area

3 1 839431

60029 2 2

1859959 3 19 7 93 8 1

• 234958

B l .Code

11111111

%Delta

1.650.00

-1.791.793.594.61

-1.38

uS

40

30

20

10

0

C

File.

i i i

>

97052401

f luoride

• i

|o h l ( j f f i fee

1 | l l 1 1 | 1

1 2

.D05 Sample:

nitrateI

If t Pf

I I i | I I I i | I

3 4

S97T000836

osphate sulfate

l l 1 | l l 1 1 | 1

5 6

SAMPLE

oxalate

i

*l 1 1 | ! 1 1 1 | 1 1 1 1 | 1 1 ) 1 |

7 8 9 10

Minutes

253

Sample Name: S97T000836 DUPData File : C:\DX\DATA\97052401.D06Method : C:\DX\METHOD\ANIONSA.METACI Address: 1^ §ystem^.,l Inject*: 6

Date:,

Analyst- Column: AG4A/AS4A anion column

20:24:43

'-254, REV. 0

Detector:CDM-l

Calibiration

External

Pk.Nutn

1234567

RetTime

0.871.021.541.833.044.615.97

1

ComponentName



2121 3000 5Hz

Concentrationug/ml

.= .•. o.oob

.:. 4277.930896.180

...-•: 464,11844179.621

598.099. 228.953

Totals 50644.901

Start Stop

0.00 10.00

Height

827738 '1331174

228027374

32274

Area Reject

50

Area Bl.Code

290394245954858

183125833

1015

231498

1111111

%Delta

00

-1134

.99

.00

.79

.79

.59

.61


uS

40

30

20

10

nitrate

fluoride

1 i 1phosphate sulfate

I I I I I I I I I > I 1 I I I I I I I I I 1 1 i I V I I 1 I I I I I I I I I ! [ I i I I I I I I I I

0 1 2 3 4 : 5 6 7 8 9 10

Minutes

254*"

>^46HRiWr&^e_'2._/y,£7_Sample NameData FileMethodACI AddressAnalyst

Calibr,

External

S97T000837 SAMPLE Date: 05/24/1997 20:37:21C:\DX\DATA\97052401.D07C: \DX\METHOD\ANIONSA. MET HNF-SD-WM-DP-254, REV. 0

Inject*: 7 Detector:CDM-1Column: AG4A/AS4A anion column


1 2121 3000 5Hz 0.00 10.00 50

Pk.Num


Concentrationug/ml

0.0000.000

4617.974967.426465.493

47255.608733.264240.2428.601

54288.609

Height

2293

84491413174

24274797452

34631

Area

165342

428096443865

19699410841073935

250709

Bl.Code

111111111

%Delta

1.65-0.43-1.791.563.594.61-2.05

1 0.212 0.873 1.03 fluoride4 1.53 chloride5 1.83 nitrite6 3.03 nitrate7 4.61 phosphate8 5.97 sulfate9 7.79 oxalate

Totals

File: 97052401.D07 Sample: S97T000837 SAMPLE

uS

40

30

20

10

nitrate

fluoride

I Iphosphate sulfate oxalate

I

5 6

Minutes

10

255.

h&P-246r

Sample NameData FileMethodACI Address

Date: 05/24/1997 20:49:59

HNF-SD-WM-DP-254, REV. 0S97T000837 DUPC: \DX\DATA\97052401 .D08C:\DX\METHOD\ANIONSA.METI^System: 1 Inject#: 8 Detector:CDM-1

' Column: AG4A/AS4A anion column

Calibration/p<fol\naer Dilution Points Rate Start Stop Area Reject

External 1 2121 3000 5Hz 0.00 10.00 50

Pk.Num

12345678

RetTime

0.871.021.531.833.034.615.977.84

ComponentName


***** peak Report: All

Concentrationug/ml

0.0004780.9311013.642461.917

47889.604643.485284.36843.563

Peaks ****

Height

9384541493171

24457769461

Area Bl. %DeltaCode

338444466760848

199873917

13011071

0.99-0.43-1.791.343.594.61-1.38

Totals 55117.510 34899 255553

US

File: 97052401.D08 Sample: S97T000837 DVP40

30

20

10fluoride

nitrate'I


5

Minutes

1 ' I '9 10

Sample NameData FileMethodACI Address:Analyst

Date: 05/24/1997 21:02:37

HNF-SD-WM-DP-254, REV. 0S97T000837 SPIKEC: \DX\DATA\97052401 .D09C: \DX\METHOD\ANI0NSA. MET

fstem:_l Inject#: 9 Detector:CDM-1Column: AG4A/AS4A anion column

Calibration

External


1 2121 3000 5Hz 0.00 10.00 50

Pk.Num


Peak Report: All Peaks ****

Concentration Heightug/ml .

Area Bl. %DeltaCode

1 0:872 1.03 fluoride3 1.53 chloride4 1,83 nitrite5 2.71 bromide6 3.01 nitrate7 4.61 phosphate8 5.92 sulfate9 7.73 oxalate

0.0005853.6272418.66410369.043.10847.75660184.3991Q836.11311926.72110008.178

1511082035668869541930586161940551943

58755459164924779732195

257151201666233740037

221111111

1.65-0.43-1.790.740.673.593.68-2.73

Totals 122444.502 6702.8 532221

US

File: 9705240LD09 Sample: S97T000837 SPIKE

40

30

20

10

nitrateI •

fluoride| nitrite1 I bromk1 chloride |

JLA

sulfate. phosphate |

I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I

2 3 4 5 6 7 8 9

Minutes

10

•257"'



Analyst: dpb

Method:

Instrument: IC01 Book#

Rev/Mod HNF-SD-WM-DP-254, REV. 0

Worklist Comment: T201, ©IC-01 skm


95.963 % Recove

iiiiii98.684 % Re

4 SAMPLE S97T000900 0 W ©XC-01

4 SAMPLE S97T000900 0 W ©IC-01

S97T000900 0 W ©IC-01 CL-02 SOLID 1.00e+03

PO4-02 SOLID 5.54e+02 6.80e+02

OXALATE2 SOLID 1.08e+03 9.84e+02

:^o"ivS:S;K^p^iD^S&sS;:

S97T000900 0 W @IC-01

S97T000900 0 W ©IC-01


2 5 8

HNF-SD-Wy-DP-254, REV. 0-HNF-SP-WM-DP-246,

LABCORE Completed Worklist Report for Worklist# 18311Seq Type Sampled R A Test Matrix Actual Found DL or Yield Unite SAMPLE SS7T00O91S 0 W ®IC-01 CL-02 SOLID H/A S.543e+02 37.180 ug/g

6 SAMPLE S97T000915 0 W ©IC-01 HO2-02 SOLID K/A 3.020e+02 236.200 ug/g

6 SAMPLE S97T000915 0 W OIC-01 HO3-02 SOLID H/A 4.326e+04 303.900 U9/S

6 SAMPLE S97T000915 0 W ©IC-01 SO4-02 SOLID N/A < 3.018e+02

7 DUP S97T000915 0 W @IC-01 P-02 SOLID 4.56e+03 4.56e+03

7 DtJP S97T000915 0 W ©IC-01 HO2-02 SOLID 3.02e+02 2.96e+02 2.007 RPD

T:;D^!;;::;;v-:-'S?9STb'b:io;9f5|;|||i|;;^

7 DOP S97T000915 0 W @IC-Q1 KTO3-02 SOLJD 4*33©+04 4.35^ + 04 0.461 RPD

7 DUP £977000915 0 W ©IC-01. SO4-02 SOLID <3•02^2 9.81^+02 KPD

7::;:DTO;:;:; ;:;i:::: ;>;; >;;;S9^K0o;o^ii5|s^

8 SAMPLE S97T000931 0 W @IC-01 P-02 SOLID H/A 4.637e+03 28.9S0 ug/g

8 SAMPLE S97T000931 0 W ©IC-01 MO2-02 SOLID M/A 3.167a+02 260.500 uS/9

8 SAMPLE S$7T000931 0 W ®XC-01 MO3-02 SOLID ' g/A 4.559s+04 335.300 tig/g

8 SAMPLE S97T000931 0 W ©IC-01 SO4-02 SOLID H/A 9.632-&+02 332.900 «g/g

9 DOP S97T000931 0 W ®IC-01 F-02 SOLID 4.64e+03 4.71&+03 1.497 RPD

9 DDP S97T000931 0 W @IC-01 HO2-02 SOLID 3.17e+02 3.17a+02 0.000 RPD

9 DDP S97T000931 0 W QIC-01 HO3-02 SOLID 4.56e+04 4.68<j+Q4 2.597 RPD

9 DUP S97T000931 0 W ©IC-01 SO4-02 SOLID 9.$3e+02 <3.31e2 RPD



R& iewer Signature


259

05/27/9713:48A-0004-1

c-HNF-SS-WM-DP-246, RE\A-QAtfe , P



Method: LA-533-105 Rev/Mod ~D - 1

Worldist Comment: T201, @IC-01 skm

Book#


S Type Sample* R A Test Matrix

1 CCB . SIC-QC QC

2 CCV 8IC-QC QC

3 BLNK-PREP @IC-01 SOLID

4 SAMPLE S97T000900 0 W @IC-01 SOLID. Analytes Requested: BR-02 , CL-02

OXALATE2, PO4-02

5 DUP S97T000900 0 W @IC-01 SOLID

6 SAMPLE S97T000915 0 W @IC-01 SOLIDAnalytes Requested: BR-02 , CL-02

OXALATE2, PO4-02

7 DUP S97T000915 0 W 8IC-01 SOLID

8 SAMPLE S97T000931 0 W 8IC-01 SOLIDAnalytes Requested: BR-02 , CL-02

0XALATE2, PO4-02

9 DHP S97T000931 0 W eIC-01 SOLID

Sroup# Project

97000311 T-201F-02 , NO2-02SO4-02

97000311 T-201F-02 , NO2-02SO4-02

97000311 T-201F-02 , NO2-02SO4-02

NO3-02


Date Analyst Signature Date


S = Worldist Slot Number, R = Replicate Number, A = Aliquot Code.

2 6 0

-HNF-SD WM'DP-246,

Sample Name: ELUENT BLANK • Date: 05/30/1997 07:39:58Data File : C:\DX\DATA\97052821.D01 .. . p F V «Method : C:\DX\METHOD\KIT.MET HNF-SD-WM-DP-254, REV. 0ACI Address: 1 System: 1 Inject#: 1 Detector:CDM-1Analyst /^^.,/,^JZ Column: AG4A/AS4A anion column

Calibration

External

Pk.Num

Dilution'Points Rate Start Stop Area Reject

1 3000 5Hz 0.00 10.00 30

*** Peak Report: All Peaks ****************************


Concentrationug/ml


3.25 nitrate6.13 sulfate

0.0900.095

Totals 0.185

22105

1261933

1 -0.101 1.77

127 2059

US

0.06

0.04

0.02

0.00

-0.02

-0.04

-0.06

-0.08

-0.10

-0.12

-0.14

File: 97052821.D01 Sample: ELUENT BLANK

1 10

Minutes

SIGNATURE AB0V6 REPRESENTS CHEMJCALTECHNDt^ST/CHEW^TT2;CC3MPl|TED/VERIFIED THE CALffiRATlON/ANAlY&S ON PAGES 7 / 7 0 '

Date: 05/30/1997 10:19:56

HNF-SD-Wy-DP-254, REV. 0Sample Name: SID 61N20-AData File : C:\DX\DATA\97052821.D05Method : C:\DX\METHOD\KIT.METACI Address: 1 System: 1 Inject#: 5 Detector:CDM-1Analyst. : Column: AG4A/AS4A anion column


External 1 101 3000 5Hz 0.00 10.00 30


Pk.Num

12345678

RetTime

1.101.611.892;793.164.645.977.84

ComponentName


Concentrat ionug/ml

54.374. 76.485522.509567.729579.526523.400613.846524.506

Totals 3462.374

Height

12771952539252135910191548322420

28910

Area

97679983

412473545948230231857534346366

289580

Bl.Code

11111111

%Delta

-1.791.26

-1.732.32-2.770.58-0.880.00

File: 97052821.D05 Sample: STD 61N20-A8.0

7.0

6.0

5.0

4.0

u S 3.0

2.0

1.0

0.0

-1.0

nitratenitrite bromtdi

sulfate

I I I | I I I I | I I I I | M I I | I I I I | I I U | I I I I | I I I I

: 3 4 5 6 7 8 9 1 0

Minutes

44NF-SS-WM-DP--246, REV.Sample Name: PREP BLANKData File : C:\DX\DATA\97052821.D06Method : C:\DX\METHOD\KIT.METACI Address: 1 System: 1 Inject#: 6 Detector:CDM-lAnalyst : Column: AG4A/AS4A anion column

Date: 05/30/1997 10:36:21



External 1 1 3000 5Hz 0.00 10.00 30

*************************** Peak Report: All Peaks ****************************

Pk.Num

2


1.68 chloride3.29 nitrate

Concentrationug/ml

-0.0000.101

Totals 0.101

Height

1834

53

Area

64222

286

Bl.Code

11

%Delta

5.441.33

File: 97052821.D06 Sample: PREP BLANK

US

0.8

0.6

0.4

0.2

-0.0

-0.2

-0.4

-0.6

-0.8

-1.0

chloride

Initrate

i

i i i i I i i i

1i i i I i

3

i | i i i i

5 (

Minutes

i i i i I i i i i i i I i i i i I9 10

2G3

Sample Name: S97T000900 SAMData File ": C:\DX\DATA\97052821.D09Method :ACI Address:Analyst :

C: \DX\METHOD\KIT. MET1 System: 1 Inject#: 9

Date: 05/30/1997 11:15:41


Column: AG4A/AS4A anion columnDetector:CDM-1

Calibration' Volume Dilution Points Rate Start Stop Area Reject

External 1 11 3000 5Hz 0.00 10.00 30

*************************** Report: All Peaks ***************************

Pk.Num

1234567

RetTime

1.071.621.953.094.696.137.95

ComponentName


Concentrationug/ml

23.6284.9721.568

219.3592.7440.7695.342

Totals 258.382

Height

62931065

6320024

6186

204

27797

Area

424895947373

175953831

16234092

231307

Bl.Code

1111111

%Delta

-4.171.671.38-5.031.731.771.36

File: 9705282LD09 Sample: S97T000900 SAM

uS

40

30

20

10 fluoride

n*

nitrate

i

1 phosphate sulfatep

i i i i I i i i i | i i i i | i i i i | i i i i | i i i i | i i i i | i i i i | i i i i | i i i i |

1 2 34 56 7 8 9 10

Minutes

Sample Name: S97T000900 DUPData File : C:\DX\DATA\97052821.D10Method : C:\DX\METHOD\KIT.METACI Address: 1 System: 1 Inject#: 10 Detector:CDM-1Analyst : Column: AG4A/AS4A anion column

Date: 05/30/1997 11:29:47



External 1 11 3000 5Hz 0.00 10.00 30

Pk.Num

1234567

RetTime

1.071.631.973.094.696.137.95

ComponentName


Concentrationug/tnl

21.5734.6081.463

213.6223.3361.9214.826

Totals 251.350

Peaks **************************

Height

557099354

1920387

174186

26267

Area

385415513297

171073107128893673

223057

Bl.Code

1111111

%Delta

-4.172.092.08-4.821.731.771.36


40

30

uS 20

10 fluoride

i chl°'ifete

nitrate

sulfate oxalate

3 4 5 6

Minutes

10

Sample Name: S97T000915 SAMData File : C:\DX\DATA\97052821.DllMethod : C:\DX\METHOD\KIT.METACI Address: 1 System: 1 Inject*: 11

Date: 05/30/1997 11:40:35




External 1 11 3000 5Hz 0.00 10.00 30

*************************** peak Report: All Peaks **********•********•*******:

Pk.Num

12345678

RetTime

1.071.631.973.094.696.136.727.95

ComponentName


oxalate

Concentrationug/ml

22.9304.800

. 1.519217.6032.9020.3010.0005.186

Totals 255.242

Height

61141031

6119829

638545195

27423

Area

411425742337

174458895

111011633965

228813

Bl.Code

11111111

%Delta

-4.172.092.08-4.821.731.77

1.36

File: 97052821.D11 Sample: S97T000915 SAM

40

30

US 2 0

10


I I I I •i 1—(—

3J-1-1 i-r-j 1 1 T 1 1 1

4 5 6

Minutes

8- i [

9i |

10

C-HNF-SB-WM-DP-246,

Sample Name: S97T000915 DUP Date: 05/30/1997 11:51:50

Data File : C:\DX\DATA\97052821.D12 .- „..

Method : C:\DX\METHOD\KIT.MET HNF-SD-WM-DP-254, REV. 0ACI Address: 1 System: l Inject#: 12 Detector:CDM-1Analyst : Column: AG4A/AS4A anion column


External 1 11 3000 5Hz 0.00 10.00 30


Pk.• Num

1234567

RetTime

1.071.621.963.094.696.137.95

ComponentName


Concentrationug/ml

23.6725.2361.534

225.5592.1665.0905.126

Totals 268.383

Height

6129108860

2034044276189

28126

Area

425726262349

181245596

63723917

241313

Bl.Code

1111111

%Delta

-4.171.671.73-5.031.731.771.36

File: 97052821.D12 Sample: S97T00091S DUP

uS

40

30

20

10

nitrate

fluonde

Iphosphate sulfate oxalate

I

i-p-i.

3 4 5 6

Minutes

i | i

7 10

2 6 7

Sample Name: S97T000931 SAMData File : C:\DX\DATA\97052821.D13Method : C:\DX\METHOD\KIT.METACI Address: 1 System: 1 Inject*: 13

Date: 05/30/1997 12:03:15




External 1 11 3000 5Hz 0.00 10.00 30

*************************** peak Report: All Peaks ***************************

Pk.Num

1234567

RetTime

1.071.631.973.094.696.137.95

ComponentName


Concentrationug/ml

21.1434.4521.444

207.893• • •• • 5 . 5 8 1

4.3924.667

Totals 249.573

Height

547495353

19044146222180

26070

Area

377205327283

166216198456053544

220679

Bl.Code

1111111

%Delta

-4.172.092.08-4.821.731.771.36

File: 97052821.D13 Sample: S97T000931 SAM

40

30

US 20

10 fluoride

I

nitrate

phosphate;pha oxalate

II I I I I j I M I I I I I I I I I I I I ! I I I I I I

1 2 3 4 5

Minutes

i i i i i i i i i I i i

i 7 8 9 10

Date: 05/30/1997 13:51:34

HNF-SD-WM-DP-254, REV. 0Sample Name: S97T000931 DUP-Data File : C:\DX\DATA\97052821.D14Method : C:\DX\METHOD\KIT.METACI Address: 1 System: 1 Inject#: 14 Detector:CDM-1Analyst : Column: AG4A/AS4A anion column


External 1 11 3000 5Hz 0.00 10.00 30

Pk.Num



Concent rat i onug/ml


1 1.07 fluoride2 1.62 chloride3 1.95 nitrite4 3.10 nitrate5 4.69 phosphate6 6.13 sulfate7 7.95 oxalate

21.6434.5131.456

214.7145.3101.1615.128

559398450

19442142137176

386745399292

172001187320543919

-4.171.671.38-4.621.731.771.36

Totals 253.925 26524 224212


40

30

US 20

10 fluoride


I I I I I I I I I I I I I I I I I I I I I I t I I I I I i I I I I I | I I ! I I I I I I I I I I I0 1 2 3 4 5 6 7 8 9

Minutes

10


-HNF-SD-WM DP


Analyst: rag

Method: z/y-

Instrument: IC02 Book#

Worklist Comment: T201, @IC-01 skraHNF-SD-WM-DP-254, REV. 0


SSi-flcsS

3 BLNK-PREP

3 BLHK-PREP

3 BtNK-PEEP

0 OIC-QC CL QC

0 ©1C-QC BR QC

0 ©IC-QC PO4 QC

0 ©IC-QC 0XALATE2 QC

0 OIC-QC CL QC

0 ©1C-QC BE QC

0 ©IC-QC PO4 QC

0 ©IC-QC OXAIATE2 QC

0 ©IC-01 CL-02 SOLID

1 <1.70e-2 ug/mL

<1.25e-l u 3 / m L

<1.20e-l ug/mL

5.45eO2 S.34a+02

5.32eO2 5.01e+02

1 4.20e-02

ug/mli

93.797 % Recovery

iiiiilililli;

94.228 % Recovery

97.982 % Recovery

94.173 % Reco

0.042 ug/g0 ©IC-01 BR-02 SOLID

0 @IC-01 PO4-02 SOLID

3 BLNK-PREP @IC-01 0XALATE2 SOLID

4 SAMPLE S9

4 SAMPLE S97T000916 0 W ©ICC-01 BR-02 SOLID

4 SAMPLE S97T000916 0 W @IC-01 PO4-02 SOLID

4 SAMP

36.660 ug/g

269.500 ug/g

258.700 ug/g

226,400 ug/g

illilliliiiiiiii2 . 3 0 1 RPD

S97T000916 0 W ©IC-01 PO4-02 SOLID 47.944 RPD

S97T000916 0 W ©1C-01 OXALATE2 SOLID 11.282 RPD

Units shown for QC (BLK/BKG) may not reflect the actual units. 2 7 0

HNF:SD:WM:DP-254, REV. 0worklistdata Version 1.0 05/15/9606/02/9714:43

LABCORE Completed Worklist Report for Worklist# 18312Seq Type Sample# R A Test Matrix Actual Found DL or Yield Unit6 SAMPLE S97T000917 0 W ©IC-01 CL-02 SOLID ST/A 1.015e+03 37.540 ug/g

6 SAMPLE S97T000917 0 W ©IC-01 NO2-02 SOLID N/A 4.999e+02 238.500 ug/g

6 SAMPLE S97T000917 0 W QIC-01 HO3-02 SOLID H/A 4.5388+04 307.000 ug/g

6 SAMPLE S97T000917 0 W ©IC-01 SO4-02 SOLID H/A 3.9698+02 304.800 ug/g

7 DOP S97T000917 0 W ©XC-01 F-02 SOLID 5.42e+03 5.01e+03 7.862 RPD

7 DUP S97T000917 0 W @IC-01 HO2-02 SOLID 5.00e+02 4>84e+02 3.252 RPD

7 DUP S97T0009X7 0 W ©IC-01 HO3-02 SOLID 4.54e+04 4.258+04 '6.598 RPD

7 DUP S97T000917 0 W @IC-01 SO4-02 SOLID 3.978+02 5.598+02 33.891 RPD

8 SPK S97T000917 0 W ©IC-01 F-02 SOLID 5.90e01 6.39e+01 108.305% Recovery

5.44802 4.828+02 88.603 % Recovery

8 SPK S97T00Q917 0 W ©IC-01 1703-02 SOLID 5.94eO2 6.418+02 107.912 % Recovery

8 SPK S97T000917 0 W @IC-01 SO4-02 SOLID 6.31802 5.8Se+02 92.868 % Recovery

p;|ii||o3;!;|9 SAMPLE S97T000918 0 W ©IC-01 P-02 SOLID H/A 5.224e+03 25.910 ug/g

9 SAMPLE

9 SAMPLE S97T000918 0 W ©IC-01 SO4-02 SOLID H/A 7.2688+02 297.900 «£f/S

10 DUP S97T000918 0 W @IC-01 F-02 SOLID 5.22e+03 5.17e+03 0.962 RPD

10 DUP S97T000918 0 W ©IC-01 NO2-02 SOLID 5.138+02 5.16e+02 0.583 RPD

10 DUP S97T000918 0 W @IC 0

1 9

.• ••:• ^":"'3

.229

.803

i-574^

WmmmmRPD

RPD

• • • j j P J p i S K 1 - : - : • . - > • ;.'.-.V:1 ••:•.•:•



R ^

'own for QC (BLK/BKG) may not reflect the actual units.

271

05/27/9713:49 Page:



Method: LA-533-105 Rev/Mod b - V


Book#(


S Type

1 CCB

2 CCV

3 BLNK-PREP

4 SAMPLE

Sample* R A Test

eic-QC

@ic-QC

@IC-01

S97T000916 0 W @IC-01Analytes Requested: BR-02

Matrix

QC

QC

SOLID

SOLID, CL-02

6roup# Project

5 DUP

6 SAMPLE

7 DDP

8 SPK

9 SAMPLE

OXALATE2, PO4-02

S97T000916 0 W @IC-01 SOLID

S97T000917 0 W OIC-01 SOLIDAnalytes Requested: BR-02 , CL-02

0XALATE2, PO4-02

S97T000917 0 W @IC-01 SOLID

S97T000917 0 W @IC-01 SOLID

S97T000918 0 W ©IC-01 SOLIDAnalytes Requested: BR-02 , CL-02

. 0XALATE2, PO4-02

S97T000918 0 W (SIC-01 SOLID

97000311 T-201F-02 , NO2-02SO4-02

97000311 T-201F-02 , NO2-02SO4-02

97000311 T-201F-02 , HO2-02SO4-02


ignature Date Analyst Signature Date

Data Entry

S = Wbrklist Slot Number, R = Replicate Number, A = AMquot Code.

272

•HNF SD WM DP 246, t

Sample Name: CCB Date: 05/30/1997 10:05:18Data File : C:\DX\DATA\97053001.D10 uuc on IW1I np « RFV 0Method : C:\DX\METHOD\ANIONS.MET HNF-SD-WM-DP-254, REV. 0ACI Address: 1 System: l Inject#: 10 Detector:CDM-1Analyst : ~ft^ „ /)„_ Vs» nCAQi

umn: AG4A/AS4A anion column


External 1 1 3000 5Hz 0.00 10.00 50


Pk. Ret ComponentNum Time Name

Concentration: ug/ml


1234

1.131.393.125.81

nitratesulfate

0.000.0.0000.1490.151

Totals 0.301

39225799

217

180128373

1491

2172

-1.581.81

US

0.16

0.14

0.12

0.10

0.08

0.06

0.04

0.02

0.00

-0.02

-0.04

File: 97053001.D10 Sample: CCB

5

Minutes

10

^ " 8 ^ 1 3 CHEMICAL TECHMOLOGtST/CFIEDTHECAUBRATIOWANALYaSCW PAGES,

2.73

DP 246, REV,

Sample Name: STD 61N20-AData File : C:\DX\DATA\97053001.DllMethod : C:\DX\METHOD\ANIONS.METACI Address: 1 System: 1 Inject#: 11Analyst

Date: 05/30/1997 10:18:11

HNF-SD-WM-DP-254, REV. 0Detector:CDM-l

anion column


External

Pk.Num

123456789

RetTime

0.881.021.531.832.713.074.515.817.57

1

ComponentName


101 3000 5Hz

Concentrationug/ml

0.00056.05074.131

. 508.104555.026579.773534.158620.818500.509

Totals 3428.570

0.00 10.00

Height

5218382285929156466386170150272253

34478

Area

1951019410502492293470047318209006826742019

283323

50

Bl.Code

221111111

%Delta

0.99-0.87-2.14-2.99-3.261.201.81-4.74

uS

18

16

14

12

10

8

6

4

2

File: 97053001.D11 Sample: STD 61N20-A

nitrite

I

fluoriot"™

f uI

I I phosphate •

l A Aoxalate

i i i i i > i • I i M I i [ i i n | i i i i | i i i i | i i i i | I i i i | i i i i |

3 4 5 6 7 8 9 10

Minutes

274

-HNT-SD-WM DP 246,

Sample Name: PREP BLANKData File : C:\DX\DATA\97053001.D12Method : C:\DX\METHOD\ANIONS.MBTACI Address: 1 System: 1 inject#: 12

Date: 05/30/1997 10:30:38



External 1 1 3000 5Hz 0.00 10.00 50

*************************** p6ak Report: All Peaks ******************


Concentrationug/ml


1.281.54 chloride3.13 nitrate

0.0000.0420.201

5498

126

Totals 0.243 2 7 9

451445803

11 0.001 -1.16

1698

uS

3.0

2.0

1.0

0 0

1.0

2.0

File:

i i i i

97053001.D12

chloride nil

1 j

f1 1 1 1 j I 1 1 1 1

Sample: PREP BLANK

rate

A

~~I 1 1 1 [ i 1 1 1 1 1 1 1 1 j I 1 ! 1 I I 1 1 1 1 1 1 I 1 j 1 1 1 T~

Minutes

275'

-HNF*SB»VtfM-BP-246, REV. 0 ftMz£

Sample Name: S97T000916Data File : C:\DX\DATA\97053001.D15Method : C:\DX\METHOD\ANIONS.METACI Address: 1 System: 1 Inject*: 15

Date: 05/30/1997 11:05:50




External 1 11 3000 5Hz 0.00 10.00 50

*************************** Report: All Peaks ****************************

Pk.Num

1234567

RetTime

1.031.531.833.034.535.817.63

ComponentName


Concentrationug/ml

24.5704.5992.367

20S.3661.9322.3673.284

Totals 244.485

Height

87681279164

2050947146192

31105

Area

440095889822

162759415

21883359

219441

Bl.Code

11ll11l

%Delta

1.65-0.43-2.14-4.521.801.81-4.07

File: 97053001.D15 Sample: S97T000916

uS

40

30

20

10fluoride

ph> sulfateI

Minutes

oxalateI

10

278

-HNF-SD-WM-Dr 246,

Sample Name:Data File :Method :ACI Address:Analyst :

S97T000916 DUPC:\DX\DATA\97053001.D14C: \DX\METHOD\ANIONS . MET1 System: 1 Inject#: 14

Date: 05/30/1997 10:53:09



External 1 11 3000 5Hz 0.00 10.00 50

Pk.Num


Peak Report: All Peaks ***•*

Concentration Heightug/ml

Area Bl. %DeltaCode


24.4734.5872.410

203.6043.0752.6223.586

83731283172

2019772

135195

438215873861

161262823

24423585

0.99-0.87-2.50-4.731.801.81-4.07

Totals 244.357 30426 218668


uS

40

30

20

10fluoride

I


I

' ' ' ' | '1

1 I ' ' ' '5

Minutes

10

277

Date: 05/30/1997 11:17:43

-SD-WM-DP-254 REV 0Sample Name: S97T000917Data File : C:\DX\DATA\97053001.D16Method : C:\DX\METHOD\ANIONS.METACI Address: 1 System: 1 Inject*: 16 Detector:CDM-1Analyst : -$,,„ Q, Mt^ <U Column: AG4A/AS4A anion column


External 1 11 3000 5Hz 0.00 10.00 50

Pk.Num

Peak Report: All Peaks


Concentrationug/ml


1 1.03 fluoride2 1.53 chloride3 1.82 nitrite4 3.02 nitrate5 4.53 phosphate6 4.967 5.81 sulfate8 7.63 oxalate

26.9765.0562.490

226.0491.5760.0001.9774.031

95771401184

224753144

127214

487136494933

180468288

106817993918

1.65-0.87-2.50-4.731.80

1.81-4.07

Totals 268.155 34053 243680

uS

40

30

20

10

0

C

File.

>

97053001.D16 Sample: S97T000917

nitrate

i

fluoride 1

i ft| e h l S8fee I phosphate sulfate

L i 1 ML M 1

, | i i i . | , . , i | i , i , | , . i i , | , , , , | i

1 2 3 4 5 61 ' 1

7

oxalate

i i i i | i . i i | i i i .

8 9 1

Minutes

278

-HNF-SD-WM DP

Sample Name: S97T000917DUP Date: 05/30/1997 11:28:46Data File : C:\DX\DATA\97053001.D17Method : C:\DX\METHOD\ANIONS.MET HNF-SD-WM-DP-254, REV. 0ACI Address: 1 System: 1 Inject#: 17 Detector:CDM-1Analyst : w } n n <M Column: AG4A/AS4A anion column

Calibration

External

Pk.Num

1234567

RetTime

1.031.531.823.024.515.817.63

Volume

1

ComponentName



11 3000 5Hz

Concentrationug/ml

25.3394.8072.448

214/9832.4182.8253.653

= » =

Start Stop

0.00 10.00

Height

89751339180

2115348150205

Area Reject

50

Area Bl.Code

45504 16164 1895 1

170961 1589 1

2643 13635 1

%Delta

1.65-0.87-2.50-4.731.201.81-4.07

Totals 256.473 32048 230392

File: 97053001.D17 Sample: S97T000917DUP

US

40

30

20

10

JL phosphate sulfate

3' I ' ' ' '

5

Minutes

oxalate

10

2 7 9

Data Reprocessed On 06/02/1997 08 :00^42

Sample Name: S97T000917SPKData File : E:\DATA\97053001.D18Method : C:\DX\METHOD\ANIONS.METACI Address: 1 System: 1 Inject#: 18

Date: 05/30/1997 11:39:27




External 1 11 3000 5Hz 0.00 10.00 50


Pk.Num

123456789

RetTime

0.891.031.531.832.713.004.515.817.57

ComponentName


Concentrationug/ml

0.00033.35712.61350.67553.664

290.10553.52560.57354.120

Totals 608.643

Height

4312258362484855265

28906157444352252

66842

Area

16161603165864495630647

237043191766102041722

512913

Bl.Code

111111111

%Delta

1.65-0.87-2.14-2.990.001.201.81-4.74

uS

File: 97053001.D18 Sample: S97T000917SPK

40

30

20

10

nitrateI

nitrite

phosphatesulfate

I I i | I I I i | I I I I | i

1 2 3I i | I I ! I | I I I i | : I I i | i

4 5 6 7

Minutes

~110

Sample Name: S97T000918Data File : C:\DX\DATA\97053001.D19Method : C:\DX\METHOD\ANIONS.MKTACI Address: 1 System: 1 Inject*: 19

Date: 05/30/1997 11:50:42


Analyst :*~JRasQ J\ Column: AG4A/AS4A anion column


External 1 11 3000 5Hz 0.00 10.00 50


eak Report: All

Concentrationug/ml

26.6245.2392.613

222,6601.8733.7043.917

266.630

Height

95911493207

2197636

200213

33717

Area

4801967361046

177549394

35183833

241094

Bl.Code

1111111

%Delta

1.65-0.43-2.14-4.731.201.81-4.07

1234567

1.031.531.833.024.515.817.63

fluorxdechloridenitritenitratephosphatesulfateoxalate

Totals

File: 97053001.D19 Sample: S97T000918

US

40

30

20

10

fluoride

nitrate

i

hosphate sulfate

Ioxalate

i

> I I I I I I M I I I I I I I I I I I N I I I I I I I I I I I I j I1 2 3 4 5 6 7

Minutes

i i i i i i i i

8 9 10

2 8 1

-HNf-SD-WM-DP-240, FID/.Data Reprocessed On 06/02/1997 08:01:52

Sample Name: S97T000918 DUP Date: 05/30/1997 14:02:25Data File : E:\DATA\97053001.D22Method : C: \DX\METHOD\ANIONS. MET HNF-SD-WM-DP-254, REV. 0ACI Address: 1 System: 1 Inject#: 22 Detector:CDM-1Analyst : Column: AG4A/AS4A anion column


External 1 11 3000 5Hz 0.00 10.00 50


Peak Report: All Peaks

Concentrationug/ml

S *****'

eight

350276

91161366190

2142631

193198

Area

151461917

456786336979

171317336

27513635

Bl.Code

221111111

%Delta

-0.33-2 .60-3 .930 .110.000 .88

-4 .74

123456789

001112457

.61

.71

.01

.50

.79

.97

.45

.76

.57


0.0000.000

25.4284.9362 .540

215.3991.7122 .9333.652

Totals 256.601 33145 248094


uS

40

30

20

10

nitrate

phosphate sulfate

Minutes

2 8 2

worklistdata Version 1.0 05/15/9607/10/9715:45 HNF-SD-WM-DP-254, REV. 0


Analyst: pjm Instrument: IC01 Book#

Method: ^A^3~/fly~Rev/Mod t>-/



1 CCB 0 ©IC-QC CL QC 1 <;1.70e-2

1 CCB 0 ©IC-QC BR QC 1 <1.25e-l

1 CCB 0 ©IC-QC PO4 QC 1 ^1.20e-l

1 CCB 0 ©IC-QC OXALATE2 QC 1 <1.05e-l

2 CCV 0 @IC-QC CIi QC 7.S0&01 8.Q4&+01

ng/inL

ug/aL

ug/wL

ug/mL

102.772 % Recovery

2 CCV

&IC-QC BR QC

©IC-QC PO4 • pC

©IC-QC OXALATE2 QC

3 BLHK-PREP

3 BLHK-PREP

5 . 4 5 e O 2 5 . 3 5 e + 0 2

2;i<3^>:Vi:;:;?::!;::;;!:;i^^

2 CCV

0 ' ©IC-01 CL-02 SOLID 1 1.90e-02

0 ©IC-01 BR-02 SOLID 1 <1.25e-l

3 BLHK-PREP 0 ©IC-01 PO4-02 SOLID 1 <1.20e-l

3'BLNK-PREP 0 aiC-01 OXALATE2 SOLID 1 <1.05a-l

4 SAMPLE S97T001251 0 W ©IC-01 CL-02 SOLID H/A 1.063e+03

4 SAMPLE S97T001251 0 W ©IC-01 BR-02 SOLID- H/A < 2.790e+02

103.336 % Recovery

•'•'••i 0-l'*'347'°-'°^§ °-'-R o!cc*veKV''''''

98.165 % Recovery

98.311 % Recovery

0.019 ug/g

::mMfyWMmMiWSi

ug/g

37.950

4 SAMPLE S97T001251 0 W OIC-01 OXALATE2 SOLID

279.100 ug/g

267.900 ug/g

234.400 ug/g

2.791 RPD

S97T001251 0 W ©IC-01 PO4-02 SOLID

5 DOP S97T001251 0 W @IC-01 OXALATE2 SOLID 0.873 RPD

•^i^MiW^m^.


283

HNF-SD-WM-DP-254, REV. 0worklistdata Version 1.0 05/15/96 Page: 207/10/9715:45

LABCORE Completed Worklist Report for Worklist# 19089Seq Type Sampled R A Test Matrix Actual Found DL or Yield Dnit6 SAMPLE S97T001257 0 W ©IC-01 CL-02 SOLID K/A 8.292e+02 36.960 ug/g

6 SAMPLE S97T00X257 0 W @IC-01 1302-02 SOLID H/A 2.8876+02 234.700 ug/g

6 SAMPLE S97T001257 0 W SlC-01 HO3-02 SOLID H/A 4.212e+04 302.200 ug/g

6 ; : ; & ^ P E ' E ; & ^

6 SAMPLE S97T001257 0 W ©IC-01 SO4-02 SOLID M/A 1.082e+03 300.000 ug/g

7 DUP S97T001257 0 W ©IC-01 F-02 SOLID 4.29e+03 4.30e+03 0.233 RPD

7 DUP S97T001257 0 W (&IC-01 NO2-02 SOLID 2.89d+02 3.02d+02 4.399 RPD

7|^TO|;:;;:-:::;;;t;:;^|^T^o^2i7^^

7 DUP S97T001257 0 W @IC-01 NO3-02 SOLID 4,21e+04 4-24e+04 0.710 RPD

7 DDP S97T001257 0 W ®IC-01 SO4-02 SOLID 1.08e+03 <3.03«2 • RPD



0 7 InkyR^yiewer Signature fj Date'


284

07/02/9717:29A-0004-1


LABCORE Data Entry Template for Worklist# 19089Page: 1

Instrument: ICOAnalyst: fe&Method: LA-533-105 Rev/Mod / ) - /


Book#

S Type

1 CCB

2 CCV

3 BLNK-PREP

Samplett R A Test

@IC-QC

@IC-QC

aic-oi

4 SAMPLE S97T001251 0 W @IC-01Analytes Requested: BR-02

Matrix

QC

QC

SOLID

SOLID, CL-02

OXALATE2, PO4-02

5 DDP S97T001251 0 W feIC-01 SOLID

6 SAMPLE S97T001257 0 W @IC-01 SOLIDAnalytes Requested: BR-02 , CL-02

OXALATE2, PO4-02

7 DOP S97T001257 0 W @IC-01 SOLID

6roup# Project

97000311 T-201F-02 , NO2-02SO4-02 -

97000311 T-201F-02 , NO2-02S04-02

NO3-02


7/6/97Analyst Signature T)ate


S = Worklist Slot Number, R - Replicate Number, A = Aliquot Code.

285

HNF-SD-WM-DP-254, REV. 0===:s === = === ===s==:=:==::= = :=

Sample Name: CCB ELUENT BLNK Date: 07/06/1997 02:14:28Data File : C:\DX\DATA\97070511.D09Method : C:\DX\METHOD\KIT.METACI Address: 1 System: 1 Inject#: 9 Detector:CDM-1Analyst : / / / , ,"3-.. ,£ , Column: AG4A/AS4A anion column

Calibration V#lv{jhe dilution Joints Rate Start Stop Area Reject

Internal 1 1 3000 5Hz 0.00 10.00 30

•I-************************** peak Report: All Peaks ****************************

:?k.'"Turn

1

RetTime

9.60

ComponentName

Concentrationug/ml

0.000

Totals 0.000

Height

12

12

Area

188

188

Bl. %DeltaCode.

1

0File: 97070S11.D09 Sample: CCB BLUENTBLNK

0.03

N I I I I N I | U I I I I I I I I

0 1 2 3 4N I | U I I I I I I I I I I I I I I I I I I I H I |

£ ^

286


Sample Name: CCV 72N20DData File : C:\DX\DATA\97070511.Dll

C:\DX\METHOD\KIT.MET1 System: 1 Inject*: 11

Date: 07/06/1997 02:26:48

MethodACI AddressAnalyst Column: AG4A/AS4A anion column

Detector:CDM-l


Internal 1 101 3000 5Hz 0.00 10.00 30

*************************** Peak Report: All peaks ****************************

?k."Turn

12345678

RetTime

1.101.591.872.753.114.455.767.52

ComponentName


Concentrationug/ml

60.08980.396

570.578609.316602.049535.259637.958524.299

Totals 3619.944

Height

14431961577456086318193254172427

30880

Area

1087210499451673813250159237257832246347

303223

Bl.Code

l1l11111

%Delta

-1.790.00-2.770.61

-4.41-3.47-4.42-4.08

File: 97070511.D11 Sample: CCV 72N20D

sulfate

Minutes

2 8 7

Sample Name: BLNK -PREPData File : C:\DX\DATA\97070511.D12Method : C:\DX\METHOD\KIT.METACI Address: 1 System: 1 Inject*: 12


Date: 07/06/1997 02:49:48

Detector:CDM-1Analyst Column: AG4A/AS4A anion column


Internal 1 1 3000 5Hz 0.00 10.00 30

**************************** peak Report: All Peaks ****************************

MumRet Component

Time NameConcentration

ug/mlHeight Area Bl. %Delta

Code

File: 97070511.D12 Sample: BLNK-PREP

uS

1.341.65 chloride3.21 nitrate

1.0

0.8

0.6

0.4

0.2

-0.0

-0.2

-0.4

-0.6

-0.8

-1.0

0.0000.0190.141

95380

38309555

11 3.351 -1.33

Totals 0.160 142 903

1 1 1 1

D

chloride

I/""

" " 1 "1 2

nitrate

I• k

' ' I ' ' '3

1 I "4

i i 1 i i

5' ' | ' '

6i i | i i

7i i 1 i i

8. > 1 i .

91 ' 110

Minutes


Sample Name: S97T001251 SMPLData File : C:\DX\DATA\97070511.D14Method : C:\DX\METHOD\KIT.METACI Address: 1 System: 1 Inject#: 14

Date: 07/06/1997 04:34:28



Internal 1 11 3000 5Hz 0.00 10.00 30


?k.:*T>im

1234567

RetTime

1.071.591.923.034.485.877.63

ComponentName


Concentrationug/ml

24.7955.2381.524

232.1481.8031.3375.660

Totals 272.504

Height

67051123

6522059

38140227

30356

Area

447486264341

186889449

22474350

245287

Bl.Code

1111111

%Delta

-4.760.00-0.35-6.87-2.89-2.65-2.72

File: 97070511.D14 Sample: S97T001251 SMPL

uS

phosphate sulfate

I I

1 ' '4. > 1 i i

5i i | i i

6i t | i i

7i i | i i

8i i | i i

91 ' 110

Minutes

289


= =::=:= = = =: Date: 07/06/1997 04:45:08Sample Name: S97T001251 DUPData File : C:\DX\DATA\97070511.D15Method : C:\DX\METHOD\KIT.METACI Address: 1 System: 1 Inject*: 15 Detector:CDM-lAnalyst : Column: A64A/AS4A anion column

"•ilibration Volume Dilution Points Rate Start Stop Area Reject

Internal 1 11 3000 5Hz 0.00 10.00 30



Concentrationug/ml



25.4355.3951.578

245.8412.5826.1875.658

68641155

6322720

63295237

459956452381

198686765

75804349

Totals 292.676 31397 264206

File: 9707051LD15 Sample: S97T001251 DUP

US

40

30

20

10fluoride

nitrateI •

r-r i i

2


I

I T | I I I I | .

4 5 9

1111111

10

-4.760.420.00

-6.67-2.31-2.65-2.72

Minutes

'290


Sample Name: S97T001257 SMPLData File : C:\DX\DATA\97070511.D16

\ \ \

Date: 07/06/1997 04:55:51

Method :ACI Address:Analyst :

\ \C:\DX\METHOD\KIT.MET1 System: 1 Inject#: 16

Column: AG4A/AS4A anion columnDetector:CDM-1


External 1 11 3000 5Hz 0.00 10.00 30

I************************** peak Report: All Peaks ****************************

Pk.Num

1234567

RetTime

1.071.611.933.044.515.877.68

ComponentName


Concentrationug/ml

21.7154.1961.461

213.1145.7295.4770.878

Totals 252.569

Height

562690652

2014716326927

27191

Area

388115022295

17064220446798472

224084

Bl.Code

1111111

%Delta

-4.760.840.00-6.46-2.31-2.65-2.04

File: 970705U.D16 Sample: S97T001257 SMPL

US

40

30

20

10 fluoride

sulfateI

oxalateI

I I I j I I I I I I I N j I I I I | I I I I | I I I I J I I I I I I I I I I I I I I j I I I I j1 2 3 4 5 6 7 8 9 10

Minutes

2 9 1


Sample Name: S97T001257 DUP Date: 07/06/1997 05:06:32Data File : C:\DX\DATA\97070511.D17Method : C:\DX\METHOD\KIT.METACI Address: 1 System: 1 Inject#: 17 Detector:CDM-1Analyst : Column: AG4A/AS4A anion column


External 1 11 3000 5Hz 0.00 10.00 30

>************************** peak Report: All Peaks ****************************

Pk.Num

123456

RetTime

1.071.611.933.034.485.87

ComponentName


Concentrationug/ml

21.5714.2581.512

212.4785.5501.482

Totals 246.852

Height

559193159

19946149132

26806

Area

385365095333

17010219712406

218444

Bl.Code

111111

%Delta

-4.760.840.35-6.67-2.89-2.65

File: 9707051LD17 Sample: S97T001257DUP

US

40

30

20

10

nitrate

fluoride

chlo: phosphate sulfate

I

i I i < i i I

5 6Minutes

7 8 10

2 9 2

* •

05/28/9712:15A-0004-1


Analyst: j(jw> Instrument: ICPOlA M.J-VH1 Book#

Method: LA-505-H*/l& Rev/Mod C~/

Worklist Comment: ICP T-201 (DIRECT)HNF-SD-WM-DP-254, REV. 0

S Type Sample# R A Test Matrix

1 ICV SICP-QC QC

2 ICB ©ICP-QC QC

3 LLS ©ICP-QC QC

4 ICSA ©ICP-QC QC

5 ICSAB ©ICP-QC QC

6 SAMPLE S97T000823 0 D ©ICP-D01 LIQUIDAnalytes Requested: AG-D-01 , AL-D-01

BE-D-01 , BI-D-01CR-D-01 , CU-D-01MG-D-01 , MN-D-01P-D-01 , PB-D-01.SM-D-01 , SR-D-01ZN-D-01 , ZR-D-01

7 DUP S97T000823 0 D ©ICP-D01 LIQUID

8 CCV ©ICP-QC QC

9 CCB ©ICP-QC QC


BE-D-01 , BI-D-01CR-D-01 , CU-D-01MG-D-01 , MN-D-01P-D-01 , PB-D-01SM-D-01 , SR-D-01ZN-D-01 , ZR-D-01


12 SAMPLE S97T000835 0 D ©ICP-D01 LIQUID

Group# Proj ect

97000311 T-201AS-D-01 , B-D-01

CD-D-01K-D-01NA-D-01SB-D-01

CA-D-01FE-D-01MO-D-01S-D-01TI-D-01 TL-D-01

97000311 T-201AS-D-01 , B-D-01CA-D-01FE-D-01MO-D-01S-D-01

TI-D-01

CD-D-01K-D-01NA-D-01SB-D-01TL-D-01

BA-D-01CE-D-01LA-D-01ND-D-01SE-D-01U-D-01


CO-D-01LI-D-01NI-D-01SI-D-01V-D-01


97000311 T-201



293

-HNF-SD-WM-DP-05/28/9712:15A-0004-1 HNF-SD-WM-DP-254, REV.10


S Type Sample* R A Test MatrixAnalytes Requested: AG-D-01 , AL-D-01

EE-D-01 , BI-D-01CR-D-01 , CU-D-01MG-D-01 , MN-D-01P-D-01 , PB-D-01SM-D-01 , SR-D-01ZN-D-01 , ZR-D-01


14 CCV ©ICP-QC QC

15 CCB ©ICP-QC QC

IS SAMPLE S97T000836 0 D ©ICP-D01 LIQUIDAnalytes Requested: AG-D-01 , AL-D-01

EE-D-01 , BI-D-01CR-D-01 , O7-D-01MG-D-01 , MN-D-01P-D-01 , PB-D-01SM-D-01 , SR-D-01ZN-D-01 , ZR-D-01

17 DUP S97T000836 0 D 8ICP-D01 LIQUID

18 SERDIL S97T000837 0 D SICP-D01 LIQUID


BE-D-01 , BI-D-01CR-D-01 , CU-D-01MG-D-01 , MN-D-01P-D-01 , PB-D-01SM-D-01 , SR-D-01ZN-D-01 , ZR-D-01


21 SPK S97T000837 0 D ©ICP-D01 LIQUID

22 ICSA ©ICP-QC QC

23 ICSAB ©ICP-QC QC

Group# Proj ectAS-D-01 , B-D-01 , BA-D-01CA-D-01FE-D-01MO-D-01S-D-01TI-D-01

CD-D-01K-D-01NA-D-01SB-D-01TL-D-01

97000311 T-201AS-D-01CA-D-01FE-D-01MO-D-01S-D-01TI-D-01

B-D-01CD-D-01K-D-01NA-D-01SB-D-01TL-D-01

CE-D-01LA-D-01ND-D-01SE-D-01U-D-01


97000311 T-201AS-D-01 , B-D-01 , BA-D-01CA-D-01 , CD-D-01 , CE-D-01FE-D-01 , K-D-01 , LA-D-01MO-D-01 , NA-D-01 , ND-D-01S-D-01 , SB-D-01 , SE-D-01TI-D-01 , TL-D-01 , U-D-01


CO-D-01.LI-D-01NI-D-01SI-D-01V-D-01




294

Page: 3A non4 i


S Type Sample# R A Test Matrix Group# Project24 CCV ©ICP-QC QC

25 CCB SICP-QC QC



3-3

S V 7T&o Vb ^3S

$11TOOoo%%S 1}

Siffoooo %fy JH

,l-/o ,,1-10

,hiu

, X-IO

,2-/0

JUfSl

Si

Jl

S'ISi

SISI

SIO


S = Worklist Slot Number, R — Replicate Number, A = Aliquot Code.

2 9 5

05/28/97 10:29 ©509 372 2929 WESTINGHOUSB

HNF-SD-WM-DP-254, REV. 0' na lys is Report Summary

HNF SD-WM-DP-g46i REV.

Wed 05-28-97 11:19:05 AM

->-» S1U-924 ZOOW

page 1

Sample Name File Method Date Time OpID Type Mode

1 ICV2 ICB3 LLS4 I OS A5 ICSAB6 S97TOOOO8237 S97TO00823 D8 CCV9 CCB

-te-11 S97T000834-12 S97T0O0834 D13 S97T000835-14 CCV 115 CCB~116 S97TOOO835 D17 S97TOOO836-18 S97T000836 D19 S97T000837"L20 S97T000837-21 S97T000837 D22 S97T000837~A23 S97T000837~X24 S97T000837~AX25 ICSA26 ICSAB27 CCV 228 CCB~2

970528A970528A970528A970528A97O528A970528A970528A970528A970528A

ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2

970S28A970528A970528A970528A97O528A970528A97O528A970528A970528A970528A970528A970528A970528A970528A97O528A970528A97O528A970528A

ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2

05/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/9705/28/97

CONCCONCCONCCONCCONCCONCCONCCONCCONCCONGCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONC

n

or-;?-? 7 fr 77000

SIGNATURE ABOVE REPRESENTS CHEMICAL TECHNOLOGIST/ICOMPLETED/VERIFIED THE CAU8RATI0WANALYS1S ON PA

29.S

OOOOOOHHOOOOOOOOO OOOOOOOOO OOOOOCOCOCOCOOO CO 00 03

Ul OJ 03 (J> 00 W • .fc-h-'- (-*t

3 3 > >OOCdoooocoofOCO

O - • • [ - » •

441->|~'UJ 03

o* o- oo•

ooOOOO

3 03 00

^ 3 H ^ I HUHoooooOt-ii-ioooOOOOOO OOOOOOOOO OOO00 CO 00 CO 00 CO CQCOQ3W W W W W {JOJli

SO" O Ul * • - O\*J^^}- MDO O

hJOC000MtO4>uiO*>CO|~>l-1l-1

I U l l U l I I I • I I Ul I I t

ODMWHH^H

3H>OOMOOOO030toco

w

O H O O M - • ^ M W W O J f O H W C O U i 000000*00

O- OOHO-OOONOOO

OOU). OHO- OCX-1h'tO^OOM'OMCOUit' O ^ 4 O

•OI-'WtOUiOOOH-*O W M W J H J

• P - -

o- **• oo-OMf-OMOOh'O

<J\ OJ CO

O- ^OHPOOOl-1' OOO- OOOOOlOUOO HMWOtOIOOPOHH

0 'A3H '

05/28/97 10:30 ©509 372 2929 ...,.., . . . V p T I N G T O U S E ^ „;»?;> JO-924 200W E1004

Analysis Report

// Sample Name

22 S97T000837 A23 S97T000837~X24 S97T000837~AX25 ICSA26 ICSAB27 CCV 228 CCB~2

# Sample Name

1 ICV2 ICB3 LLS4 ICSA5 ICSAB6 S97T00008237 S97T000823 D8 CCV9 CCB

T^Jsy / ruuuojj t:11 S97T000834"12 S97T000834 D13 S97T000835"14 CCV 115 CCB~116 S97T000835 D17 S97T000836"18 S97T00O836 D19 S97T000837~L20 S97T000837"21 S97TOOO837 D22 S97T0OO837~A23 S97T000837~X24 S97T000837~AX25 ICSA26 ICSAB27 CCV 228 CCB~2

# Sample Name


-10 G97T0OO033 L

Averages

Bi

62.89-15.105140.-.0325-.01884.972-.0344

Cu

5.300.0006.0189-.0104.4886.0076.01085.375.0002

.0475

.0171

.03815.393.0005.0254.0616-.0046.2837.0096.045854.01.23495140.-.0102.48505 .412-.0006

Mg

4.742.0027.2040241.6244.63.6643.6794.774-.0032

—. 3493

Ca

51.18-5.2385001.244.0245.64.919-.0021

Eu

-.0035.0001.0005-.0313-.0299.0133.0129-.0041-.0007

:-.U19Z-.0728-.0648-.0344-.0040-.0011-.0783-.0528-.0323-.2477-.0521-.0417-.0615-.7835-3.887-.0322-.0336-.0040-.0011

Mn

4.862.0002.0201-.0056.4445.0164.01864.863-.0003

1 IIMI -OU-I

Wed 05-28

Cd

50.15-.08745000..0001.92684.929.0005

Fe

4.919-.0010.097398.9499.83.0008.00044.953-.0004, JJD?.0308-.01141.1935.004.0005.0933.6234.2321.1267.3442.344651.002.1455045.99.7999.814.953.0000

Mo

5.019.0004.1015-.0086-.0082-.0050-.00045.034-.0023.0019—

rvivi u r MLH'

-97 11:19

Ce

49.47-.85195080..0018.00864.865.0011

K

4.953.1427.4796.1964.1339.7502.91814.924.0516/,-] 1 nHil?.~

4093.4136.3738.4.953.07193772.3920.3939.4059.4036.4036.4081.4029.9034..1462.12334.886.1618

Na

5.063-.0039.2039196.5199.74.3034.3125.142.006625650.

O, ncvrBi

:05 AM

Co

51.08.72955017..0007.46735.046.0018

La

4.903.0005.1018-.0043-.0045.0001.00274.999.0005

—. 4437—-.0305-.05374.2124.979-.0008.29042.3721.049.8790.75081.11853.34.90235094.-.0056-.00504.971.0002

Nd

5.032.0048.2059.0053.0041-.0004.00275.125.0030.1099

page 3

Cr

55.495.0945020.-.0029.46424.912-.0009

Li

4.863.0000.0213.00211.014.0003.00134.926

-.0384-.0382.02574.954-.0007-.0319-.0001.0127-.0953-.0190.038550.91-.44565194..00151.0105.004-.0010

Ni

4.947.0053

Q.0538-.0042.9148.0122.00914.941.0010 .„.2773 M

11 S97T000834" -.0433 .0139 .0494 25780. .0232 .0266

2 9 8

ODHHWWMWMWtflKfinoWWW!OOOO'0 4J>0'0v0WO^«5OO^^'0

OOOOOOOOOHhOOO<ooooooooo oooooooooooo ooo03 0002 00 00 03 03 00 03 03 03 03

U O ^ O JCOUi-J03IJOUi0^N3NS4> 0 3 O U>

0 O

oo io iooot-nc>

OOWOO

oo030tO 03

[ W

OÔOOOOHiOWOOHONOO

'W OC\ I-1

lO-JOOOOWOtS

4- OOKO-

33i3HHHHH3 | HHOOOOOOOOh'HOO

OOOOOOOOO OOOOOOOOOOO OO

3 00 03 CO 03 0 3 0 3 03 03 COCO

>a tr*a a

J J W H P ONWvJWOOOOOOOOOCOÔO

- Ul« • Ulf-'Ul I Ul' 1O- O O O - !-'|-lO"*JI-1J-lO- • I-**OOOOvOO- s l O « W s l O O O - s l OhJvO'»J<Ti-P*^00|-'COO\Ui03COOvO*Of- J ^—1|—• j>-» U) O> * J CO «JtO O Cf» O Ul Ul W

• J^- . UiHUi i • t-1- • I • Ul- iO- 1OOO- O- I-1- P M - O- H*-o^Motoio- i-1 mo\\o*•(->ootooLJ Ul W m * • Ô h-1 fO CO O to 03 O N3 to vo Ul-JfO^-»EO. CO £* [-»o^ VO1-0 * • CO M - J O O

CO ^ «J

0 'A3H '

05/28/97 10:

Analysis Report

# Sample Name

1 ICV2 ICB3 LLS4 ICSA5 ICSAB6 S97TOOOO8237 S97T000823 D8 CCV9 CCB

11 S97T000834"12 S97T0O0834 D13 S97TOOO835"14 CCV 115 CCB~116 S97T000835 D17 S97T000836~18 S97T000836 D19 S97T00O837-L20 S97T000837"21 S97T000837 D22 S97T000837~A23 S97T000837-X24 S97TOOO837~AX25 ICSA26 ICSAB27 CCV 228 CCB~2

:'/ Sample Name


i.l S97T000834"1.2 S97T000834 D13 S97T000835"14 CCV 115 CCB~116 S97T000835 D17 S97T000836-18 S97T000836 D1.9 S97TO00837~L2.0 S97T000837",21 S97T000837 D

32 SS09 372

Averages

Sm

4.957-.0014.2173.0004-.0058-.0291-.01805.058-.0037rO134—-.8042-.5526-.20265.032-.0131-.9420-.1598-.0887-2.649-.5237-.221950.82-8.5915113.-.0055-.00525.033-.0131

V

5.037-.0000.1047-.0023.4685-.0064-.00535.069-.0015Q77Q

-.1923-.1847-.07145.112-.0023-.1875-.0952-.0640-.5377-.1047-.0893

2929

Sr

4.884.0001.0205.0022.0021.0895.09104.981-.0001

.0579

.0500

.10234.973-.0001.0223.0634.0440.0149.0473.060950.38-.05155114..0022.00214.970-.0001

y

.0046-.0001.0006.0062.0059-.0009-.0008.0044-.0005

01r 1-.0363-.0345-.0152.0046-.0006-.0429-.0284-.0089-.1351-.0341-.0233

WKfc

Wed 05-2S

Th

-.0010.0067.0021-.0106-.0126.0087.0116-.0041.0028

.0040

.1742

.5375

.0012

.0074

.3100

.4335-.20832.039.5703.4429-.03485.04610.09.0008-.0039-.0020.0084

Zn

5.089.0006.0220.0056.9741.1210.12235.074-.0005

.2875

.1821

.52875.145.0004.1756.1400.0187.1389.1464.0866

1-97 11:19

Ti

4.836.0005.0202.0014.0017-.0005.00004.900.0003. 0319.0374.0147.02874.927.0003.0271.0399.0240.0747.0296.041249.89.28765108..0012.00204.909.0003

Zr

4.920-.0005.0202-.0030-.0050-.0071-.00664.979-.00210"' ""

-.1554-.1646-.07734.990-.0031-.1365-.1301-.0638-.7224-.1741-.1285

:0S AM

Tl

4.817-.0049.4270-.0052.0021.0153.03294.821.0040. 1428-1.582.2967-.10654.880-.0097-.2696-1.263-.2245-.2232-.6954.273248.40-4.4665008..0100.09394.801-.0088

u-yz4 zuuw ,

page 5

U

9.948-.0036.5414.1241.1178-.0455-.019910.13-.0248 jv-1.409 '*g*.8227-3.545-1.83410.12-.0548-2.4301.1012.108

. -11.39-4.292-1.626103.7-40.7010260..0972.093510.11-.0547

f

igiooe

-rINF-SD-

6•p<L71

r ? f ?7

m< •

o

300

05/28/97 10:33 "Or50M 372 zaza nuMim.iiuuoo -»-•-» • » - •'-HNF-SB-WM DP 246, REV.

Analysis Report

# Sample Name

22 S97T000837 A23 S97T000837~X24 S97T000837~AX25 ICSA26 ICSAB27 CCV 228.CCB~2

Averages

V

51.63-1.7475053.-.0035.46785.072-.0023

Y

.0279-.42244.314.0058.0060.0040-.0006

Wed 05-28

Zn

52.30.01694995..0071.97975.071-.0003

-97 11:1

Zr

50.54-2.0795063.-.0058-.00454.956-.0032

page 6

" 2

Of-mi

301

05/30/9708:30A-0004-1

, 7JCTPage:


Analyst: ^

Method: LA-5O5-3^I7161 Rev/Mod

Instrument: ICB§r Book#

5Worklist Comment: T-201 (SOLID FUSION DIGEST)


S Type Sample# R A Test Matrix

1 ICV ©ICP-QC QC

2 ICB ©ICP-QC QC

3 LLS SICP-QC QC

4 ICSA ©ICP-QC QC

5 ICSAB ©ICP-QC QC

6 PREPBLKTJA / ©ICP-F01 SOLID

Group# Proj ect

7 SAMPLE S97T000901 0 P ©ICP-F01 SOLIDAnalytes Requested: AG-F-01 , AL-F-01

BE-F-01CR-F-01MN-F-01S-F-01TI-F-01

BI-F-01Ctr-F-01MO-F-01SB-F-01TL-F-01

97000311 T-201AS-F-01 , B-F-01CA-F-01FE-F-01NA-F-01SB-F-01U-F-01

CD-F-01LA-F-01ND-F-01SI-F-01V-F-01

BA-F-01CE-F-01LI-F-01P-F-01SM-F-01ZN-F-01

CO-F-01MO-F-01PB-F-01SR-F-01ZR-F-01

S97T000901 0 F (SICP-F01 SOLID

S97T000919 0 F ©ICP-F01 SOLIDAnalytes Requested: AG-F-01 , AL-F-01


BI-F-01CU-F-01MO-F-01SB-F-01TL-F-01

97000311 T-201AS-F-01 , B-F-01CA-F-01FE-F-01NA-F-01SE-F-01U-F-01

CD-F-01LA-F-01ND-F-01SI-F-01V-F-01


CO-F-01MG-F-01PB-F-01SR-F-01ZR-F-01

S97T000919 0 F SICP-F01 SOLID

11 SAMPLE S97T000921 0 F ©ICP-F01 SOLIDAnalytes Requested: AG-F-01 , AL-F-01

BE-F-01 , BI-F-01CR-F-01 , CU-F-01MN-F-01 , MO-F-01

97000311 T-201AS-F-01 , B-F-01 , BA-F-01 ,CA-F-01 , CD-F-01 , CE-F-01 , CO-F-01FE-F-01 , LA-F-01 , LI-F-01 , MG-F-01NA-F-01 , ND-F-01 , P-F-01 , PB-F-01



302

05/30/9708:30A-0004-1

HNF-SD-WM-DP-254, REV. 0HNF-3D-WM-DP-246, REV. 0 f

-7-Page:


S Type Sample* R A Test Matrix Groupt ProjectS-F-01 , SB-F-01 , SE-F-01 , SI-F-01 , SM-F-01 , SR-F-01TI-F-01 , TL-F-01 , U-F-01 , V-F-01 , ZN-F-01 , ZR-F-01

12 DUP

13 CCV

14 CCB

S97T000921 0 F OICP-F01 SOLID

©ICP-QC QC

9ICP-QC

\S- PREPBLKTJA ' ©ICP-F01

16 SERDIL S97T000920 0 F OICP-F01

QC

SOLID

SOLID

17 SAMPLE S97T000920 0 F (9ICP-F01 SOLIDAnalytes Requested: AG-F-01 , AL-F-01

BE-F-01 , BI-F-01CR-F-01 , CU-F-01MN-F-01 , MO-F-01S-F-01 , SB-F-01TI-F-01 , TL-F-01

97000311 T-201

18 DUP

19 SPK

20 CCV

21 CCB

22 SAMPLE

S97T000920 0 F ©ICP-F01 SOLID

S97T000920 0 F ©ICP-F01 SOLID

©ICP-QC QC

OICP-QC

S97T000922 0 F ©ICP-F01Analytes Requested: AG-F-01


QC

SOLID, AL-F-01, BI-F-01, CU-F-01, MO-F-01, SB-F-01, TL-F-01

AS-F-01CA-F-01FE-F-01NA-F-01SE-F-01

B-F-01CD-F-01LA-F-01ND-F-01SI-F-01

BA-F-01CE-F-01LI-F-01P-F-01SM-F-01

97000311 T-201AS-F-01 , B-F-01CA-F-01FE-F-01NA-F-01SE-F-01

CD-F-01LA-F-01

U-F-01SI-F-01V-F-01


CO-F-01MG-F-01PB-F-01SR-F-01

U-F-01 , V-F-01 , ZN-F-01 , ZR-F-01

CO-F-01MG-F-01PB-F-01SR-F-01ZR-F-01

23 DUP S97T000922 0 F ©ICP-F01 SOLID

24 SAMPLE S97T000923 0 F ©ICP-F01 SOLIDAnalytes Requested: AG-F-01 , AL-F-01

BE-F-01 , BI-F-01CR-F-01 , CU-F-01MN-F-01 , MO-F-01

97000311 T-201AS-F-01 , B-F-01CA-F-01 , CD-F-01FE-F-01 , LA-F-01NA-F-01 , ND-F-01

BA-F-01 ,CE-F-01 , CO-F-01LI-F-01 , MG-F-01P-F-01 , PB-F-01



05/30/9708:30A-0004-1


s

25

26

27

28

29

Type

DUP

ICSA

ICSAB

CCV

CCB

Sample* R A

S97T000923 0 F

TestS-F-01TI-F-01

©ICP-F01

©ICP-QC

©ICP-QC

SICP-QC

OICP-QC

Matrix, SB-F-01, TL-F-01

SOLID

QC

QC

QC

QC

Group# ProjectSE-F-01 , SI-F-01 , SM-F-01 , SR-F-01U-F-01 , V-F-01 , ZN-F-01 , ZR-F-01

Signature



Date

Hf

Analyst Signature v Date

9z-z ~

Data Entry Comminf£ -

ft^r SSrf +.

S = Worklist Slot Number, R = Replicate Number, A — Aliquot Code.

Q509 372 2929 WESTINGHOUSE

Analysis Report

# Sample Name

Summary

File

Thu 05-29-97 02:17:16 FM

MO-924 200W

page 1

1 ICV2 ICB3 LLS4 ICSA5 ICSAB6 PREPBLKTJA7 S97T0009018 S97TOOO9O1 D9 S97TOOO919-10 S97T000919 D11 S97TOOO921"12 S97TO00921 D13 COV14 CCB15 PREPBLKTJA16 S97TOOO92O L17 S97T000920"18 S97T000920 D19 S97T000920~A20 S97T000920~X21 S97TOOO92O~AX22 00V 123 CCB~124 S97T00092225 S97T00O922 D26 S97T000923"27 S97T000923 D28 ICSA29 ICSAB30 CCV 231 CCB~"2

Method Date Time OpID Type Mode

970529B970529B970529B970529B970529B970529B970529B970529B970529B970529B970529B970529B970529B970529B970529B970529B970529B970529B970529B970529B970529B"970529B970529B970529B970529B97O529B970529B970529B970529B970529B970529B

ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2

05/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/9705/29/97

sY7Tooo<?/<?

12:1612:2012:2312:2612:2812:3212:3812:4112:4612:4912:5212:5513:0413:0813:1113:1513:1713:2013:2413:3213:3513:4413:4713:5013:5313:5613:5914:0414:0714:1014:14

DKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKSDKS

Q

jjQQsSssssQQ

gsssssQQSSssQQQQ

CONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONC

J-.lf.11

9

6

&O

ABOVE REPRESENTS CHEMICAL TECHNOLOGIST/C r-THAT

3 0 5

05/29/97 13:24

Analysis Report

S509 37Z 2929.

Averages Thu 05-29-97 02:17:16 PM page 2

# Sample Name Ag Al

12345.678910111213141516171819202122232425262728293031

#

123456789101112131415161718

ICVIOBLLSICSAICSABPREPBLKTJAS97TO0O9O1S97TOOO9O1 DS97T000919"S97TOOO919S97T000921"S97T000921CCVCOBPREPBLKTJAS97TOOO92OS97100O920"S97T000920S97T000920"

_D

_D

L

D"A

S97T000920~XS97T000920"CCV 1CCB~LS97T000922S97T000922-S97T000923"S97T000923ICSAICSABCCV 2CCB~2

;AX

D

D

Sample Name

ICVICBLLSICSAICSABPREPBLKTJAS97T0OO901S97T000901S97T000919"S97T000919S97TOOO921"S97T000921CCVCCBPREFBLKTJAS97TO00920S97T000920"S97T000920

D

D

D

L

D

4.813.0005.0210.0020.9625.0007.0355.0356.0169.0105-.0052-.01724. 919.0000-.0003.0656.0252.024837.03-.05223553.4.890.0026.0501.0125.0069.0003.0025.96084.885-.0001

;i

4.969.0035.1528-.0114-.0340.0093222.4230.0183.3195.8169.6169.15.100-.0166.0058156.9157.6152.9

4.783-.0109.0831239.9240.7-.0052-.5930-.5803-.3516.0500.09212.2004.900-.0088-.0121 '-3.663-.3695.098839.46-5.7673939.4.859-.0104.02231.992.0561-.4000241.3241.04.848-.0235

Ca

5.004.0067.2186253.4254.3.00622.3392.4281.9422.0471.4691.6915.127.0054.00181.6811.7111.237

5.115.0120.2188-.0038.0356.0102.5700-.4155.2606-.0864.5371.04485.256.0006.00433.709.0161.327243.841.5644088.5.218.0131.6686-.2555.2220.2384.0067.01655.197.0132

Cd

4.936-.0002.0104.0006.9392-.0003.0032.0027. 0225.0512-.0364.00255.038.0005-.0005.0407.0021.0428

4.954.0010.0995-.0014.0047.0030-.0139.1089.0469.1078.1685.02625.063.0010.0015-.0991. 1250-.099640.18.00464129.5.028.0070. 2092.1048.2063.1256-.0058.00165.029.0045

Ce

4.777-.0007.1978.0106.0130-.0016-.1518.0143-.0473.0997-.0589-.10624.964.0013-.0044-.6074-.0527-.0848

4.801-.0001.0988.0001.4687.0001.1227.1286.0599.0558.0874.08214.993-.0001.0002.0868.0892.085339.57.07844023.4.931-.0001.0853.0877.0898.0864.0001.46934.916-.0001

Co

5.026.0011.0445.0004.4686.0017.0805.0415.0527.1676.0788.05545.128.0007-.0004.2091-.1047-.0210 .

5.035-.0002.0104-.0003.4776-.0000-.0034-.0126-.0107-.0034-.0016-.00895.153-.0000-.0002-.0634-.0070.002240.93-.10924060.5.098.0000-.0016-.0051-.0161-.0125-.0001.48075.106-.0002

Cr

4.906-.0006.0217-.0033.4734-.000310.7911.1010.0810.117.4427.6435.015.0007.00015.8415.7795.812

05/29/97 13:25

Analysis Report

# Sample Name

19 S97T00092O A20 S97T000920-X21 S97T000920~AX22 CCV 123 CCB~124 S97T00092225 S97T000922 B26 S97T000923"27 S97T000923 D28 ICSA29 ICSAB30 CCV 231 CCB~2

// Sample Name

1 ICV2 ICB3 LLS4 ICSA5 ICSAB6 PREPBLKTJA7 S97T0009018 S97TOOO9O1 D9 S97TOOO919"

10 S97T000919 D11 S97TO0O921"12 S97TOOO921 D13 CCV14 CCB15 PREPBLKTJA16 S971000920 L17 S97T000920"18 S97TOOO92O D19 S97T000920~A20 S97T000920~X21 S97T000920~AX22 CCV 123 CCB~124 S97T00092225 S97T000922 D26 S97T000923"27 S97T000923 D28 ICSA29 ICSAB30 CCV 231 CCB~2

© 5 0 9 372

Averages

Bl

199.9144.44245.5.050-.0129209.4122.0182.2172.8-.0100.00705.018.0051

Cu

4.831-.0006.0162-.0106.4365-.0001.0973.0516.2800.0174.0260.01664.988-.0010.0001.0728-.0521.017139.80-.08963779.4. 909.-.0004.0113.1151.0279-.0056-.0106.43924.905-.0007

2929

Ca

43.04.92744142.5.091.00312.2682.3961.5641.324253.7252.55.119.0072

Eu

-.0010.0013.0022-.0505-.0495.0014.0649.0703.0582.0505.0483.0647-.0022.0013.0016.1679.0471.0406.0399.2079-1.491-.0013.0005.0437.0699.0745.0805-.0508-.0460-.0007.0014

_WESTINGH0USE . ->->->

<J-Udp_ci|ai ii vi - O O

-4A/IVrt HP,.wvo, 1 (bVi

Thu 05-29-97 02:17:16 PM

Cd

40.89.04414021.4.985.0004-.0052.0532-.0059-.0525.0023.93814.990.0001

Fe

4.610-.0020.090193.7693.93.001918.7919.1517.6717.8715.9916.114.724-.0012.00268.6518.5238.00946.788.2263790.4.680-.001516.179.6947.8919.86994.1493.794.669-.0015

Ce

39.141.0114027.4.862.0008.0333.0477.0739.1711..0098-.00144.841-.0007

K

4.894-.1188.4491.0094.0880

Q331.013330.12530.13530.13760.13850.12890.4.694-.1413

Q577.117910.17620.16790.17750.17730.21760.4.961-.087614130.20030.20030.19890..0077.22574.777.0025

Co

41.41-.23324113.5.090-.0007.1143.1161.0783.0164.0001.46635.090.0022

La

4.855-.0007.1010-.0051-.0055-.000232.0736.0041.8944.9728.2627.665.038-.0002-.000240.5540.0939.2280.7239.884059.4.938-.001242.8839.7830.1429.17-.0057-.00514.929-.0004

M0-924 200W

t'~/^r^?~7page 3

Cr

46.505.5834049.4.973.000510.1410.365.5945.529-.0022.47144.981-.0002

LI -

4.757.0013.0224.0037.9736.0007.0451.0651.0402.0352.0251.07014.919.0010.0017.1251.0252.015238.90.19993971.4.854.0005.0202.0602.0602.0552.0035.97994.838.0018

D3

O

3 0 7

05/29/97 13:26 Q509 372 2929 JVESTINUHULSE. ..->->-> nu-»z« zuun

AINF-SD WM DP 246, REV. Qi

Analysis Report

# Sample Name

1 ICV2 ICB3 LLS4 ICSA5 ICSAB6 PREPKLKTJA7 S97T0009O18 S97T0O0901 D9 S97T0OO919"

10 S97TOO0919 D11 S97T000921"12 S97T0O0921 D13 CCV14 CCB15 PREPBLKTJA16 S97T000920 L17 S97T000920"18 S97T000920 »19 S97T000920~A20 S97T000920~X21 S97T000920~AX22 CCV 123 CCB~124 S97T00092225 S97TOOO922 C26 S97T000923"27 S97T000923 D28 ICSA29 ICSAB30 CCV 231 CCB~2

// Sample Name

1 ICV2 ICB3 LLS4 ICSA5 ICSAB6 PREPBLKTJA7 S97T0009018 S97T000901 D9 S97T000919":.O S97T000919 D1 S97T000921r.2 S97T000921 D:.3 ccv:.4 CCB1.5 PREPBLKTJA1.6 S97TOOO92O L17 S97T000920J.8 S97TOOO92O D

Averages

Mg

4.926.0006.2045252.0252.5-.0025.5217.6029.3398.6925.5700.51705.049-.0017.0006.4784.4763.376540.25-.82514198.5.010.0037.6124.5356.3304.2666253.4253.24.979.0062

P

5.039-.0082.3912.0142-.0040- 00766.9318.0907.2987.9985.6165.5835.129-.0052-.00486.9166.2985.666

Mn

4.831.0004.0207-.0055.4471.001859.3461.5265.0966.9346.9845.934.944.0004.003650.2649.1548.5291.6950.044084.4.906.000631.9013.7210.7219.05-.0055.44464.900.0006

Pb

4.830-.0036.2101.01461.005-.0193-.1697-.2425-.3961.2037-.4709-.37404.913.0036-.0095-.5908-.3785.1032

Thu 05-29-97 02:17

Mo

4.983-.0001.1008-.0105-.0091-.0029-.0091-.0563-.1129-.0576-.0014-.09605.106-.0001.0009-.1597-.0335-.001941.46-.87244102.5.058-.0021-.0734-.0498-.0573-.0651-.0111-.01385.050-.0015

S

4.932-.0027.2020-.0432-.0487-.0148.0234-.3757-.3065-.3891-.7395-.44914.952.0049-.0134-2.032-.2767-.3676

Na

4.999.0142.2115192.1192.5.078054.3755.5054.4555.4151.8651.265.135.0147

Q.165158.1357.1955.7198.7556.724040.5.085.008252.7257.4956.7254.79193.6192.95.073.0168

Sb

4.740.0014.1105.0072-.0154-.0014-.2677-.1386.0540.1939.1469-.25064.864.0075.01571.046-.0932-.1307

:16 PM

Nd

4.829-.0015.1988.0033.0018-.0017.0213-.0395.0025.0072-.0296-.07695.012-.0027-.0017.0824-.3520-.131040.04-.80443905.4.916-:0005.0204.0450.0669.0605.0002-.00144.906.0007

Se

4.671.0425.2497.0248.0091.04502.3091.9681.9531.7332.2642.3664.767.0630.05598.3951.7072.111

page 4

Nl

4.923-.0022.0390.0020.9210

Q.530634.7676.4861.6051.7078.7742.114.992-.0050

Q.265338.9037.8536.2579.0836.384051.4.991-.008719.0496.4426.9629.45.0027.92694.974-.0049

Si

4.951.0057.1392.0083.0118.02301.7802.3542.2903.1601.7977.5535.058.0053.02203.7052.4862.484

77

9s

-254,

mo

308

Analysis Report

# Sample Name

19 S97T000920 A20 S97T000920~X21 S97T000920"AX22 CCV 123 CCB~124 S97T0O092225 S97T0O0922 D26 S97T000923"27 S97T000923 D28 ICSA ~29 ICSAB30 CCV 231 CCB~2

# Sample Name

1 ICV2 ICB3 LLS4 ICSA5 ICSAB6 PREPBLKTJA7 S97T0009018 S97T0O0901 D9 S97T000919~10 S97T0OO919 D11 S97T000921-12 S97T000921 D13 CCV14 CCB15 PREPBLKTJA16 S97TO00920 L17 S97T00092O"18 S97T000920 D19 S97T00O920~A20 S97TOOO92O~X21 S97TOOO92O~AX22 CCV 123 CCB—1.24 S97T00092225 S97T000922 D26 S97T000923"27 S97TOOO923 D28 ICSA29 ICSAB30 CCV 231 CCB~2

Averages

P

49.335.8474178.5.106-.00887.8538.0196.4606.093.0116.01765.102.0074

Sm

4.759.0222.2282.0254.0172.0184.6302.8669.6066.3433.4688.65214.949.0181.02042.596.4515.281439.793.1333895.4.857.0090.3066.6652.86111.066.0171.01254.846.0208

—n

Pb

40.28-7.4774048.4.894.0004-.4878-.4475-.5221-.7695.0265.98294.869-.0130

Sr

4.813.0003.0205.0020.0020.00032.3492.4941.6091.6111.6331.5584.986.0002.00041. 6181.5761.55641.301.6064001.4.895.00011.8641.9281.4771.413.0020.00204.889.0004

w-au-vvwThu 05-29

S

40.55-5.1664058.4.985-.0038-.5022-.7472-.4754-.4828-.0529-.05764.997-.0129

Th

.0399-.0033-.0086-.0039-.0044.0036.0275-.0237.0893.0451.0725-.1926.0361.0004-.0009-.0757.2020.2594.4648-.007431.79.0320-.0015.1474.2753.0894.0299-.0071-.0024.0328-.0052

I-fcT-ie Ori

-97 02:17

Sb

39.34' -1.0144138.4.794.0010.3378.2551-.1318-.0708-.0006.00114.789-.0003

Ti

4.788-.0005.0189.0008.0005-.0002.0228.0329.0232.0230.0334.05284.947-.0003-.0004-.0489-.0384.128639.82-.10294107.4.862-.0003.0023.0453.0236.0026.0005.00084.858-.0010

:16 PM

Se

40.6120.923980.4.757.05981.8252.6772.3662.694.0041.00654.765.0589

Tl .

4.698-.0184.3782.0292.0361-.0309-2.118-1.546-.3444-.9340-1.395-1.4214.861-.0471-.0268-5.127-1.862-.630937.55-21.563949.4.843-.0103-1.141-1.051-1.093-1.507.0061.05634.794-.0256

page 5

Si

44.233.0734236.5.029.00342.1507.7185.1252.331.0031.00825.027.0071

U

9.370.0716.5980-.0104-.0109-.0344-1.689-.7320-2.039-2.828-2.210-.59719.706.0640-.0828.3372-3.840-3.52774.145.8167798.9.536.0341-2.534-2.929-2.066-1.804-.0223-.03229.504.0796

05/29/97. 13:28

Analysis Report

// Sample Name

Q509 372 2929 WESTINGHOUSJK -»->-» M U - » Z 4 ZUUff

Averages

¥

4.989.0044.1093.0045.4712.0034.1647.1767.1429.1179.1361.19115.116.0034.0049.3773.0840.108241.41.69354092.5.057.0021.0946.1795.1769.2174.0036.46915.057.0042

Y

.0056

.0009

.0016

.0075

.0074

. 0008

.0361

.0324

.0266

.0237

.0266

.0356

.0054

.0008

.0009

.1123

.0177

.0208

.0713

.22244.075.0054.0005.0204.0366.0426.0425.0074.0072.0056,0009

Thu 05-29

Zn

4.791- . 0000.0205.0040.9316-.0040-.2200-.4649-.2468-.3249-.4421-.21364.856.0006-.0020-.0822.1624.226940.03-.20463876.4.850-.0004-.1079-.6052-.1752-.1855.0044.93014.855-.0003

-97 02;l

Zr

4.836.0028

Q.0251.0004-.0004.0013.0913.0942.0560.0601.0732.10704.989.0022.0028.1581.0500.029840.09.14924072.4.911.0012.0368.0587.1028.1223-.0009-.00134.908.0022

page 6

1 ICV2 ICB345678910111213141516171819202122232425262728293031

LLSICSAICSABPREPBLKTJAS97T00O901S97T000901S97T000919"S97T000919S97T0OO921:S97T000921CCVCCBPREPBLKTJAS97T000920S97T000920"S97T000920S97T000920"

_D

D

D

_L

D"A

S97T000920~XS97T000920"CCV 1CCB'lS97T000922S97T000922S97T000923"S97T000923ICSAICSABCCV 2CCB~2

"AX

D

D

3 1 0

06/10/9711:55A-0004-1

Page:


Analyst:

Method:

Worklist

JjtSv0 Instrument:

LA-505-151/4« Rev/Mod E-

Comment: ICP T-201 (DIRECT)

ICP01

L_Book* tt*M


s1

2

3

4

5

6

7

8

9

10

1 1

12

13

Type

ICV

ICB

LLS

ICSA

ICSAB

SERDIL

SAMPLE

DUP

SPK

ICSA

ICSAB

CCV

CCB

Sample*

S97T001203

S97T001203

R

0

0

A

D

D

Test

©ICP-QC

©ICP-QC

©ICP-QC

.©ICP-QC

©ICP-QC

©ICP-DO1

©ICP-D01Analytes Requested: AG-D-01

S97T001203

S97T001203

0

0

D

D

BE-D-01CR-D-01MG-D-01P-D-01SM-D-01ZN-D-01

©ICP-DO1

8IICP-D01

©ICP-QC

©ICP-QC

©ICP-QC

©ICP-QC

Matrix

QC

QC •

QC

QC

QC

LIQUID

LIQUID, AL-D-01, BI-D-01, CU-D-01, MN-D-01, PB-D-01, SR-D-01, ZR-D-01

LIQUID

LIQUID

QC

QC

QC

QC

Group# Project

97000311 T-201, AS-D-01, CA-D-01, FE-D-01, MO-D-01, S-D-01, TI-D-01

, B-D-01, CD-D-01, K-D-01, NA-D-01, SB-D-01, TL-D-01

, BA-D-01, CE-D-01, LA-D-01, ND-D-01, SE-D-01, U-D-01

, CO-D-01, LI-D-01, NI-D-01, SI-D-01, V-D-01



3 1 1

A 0004 7LABCORE Data Entry Template for Worklist# 18589

S Type Sample* E A Test Matrix Group# Project


Analyst Signature Date Analyst Signature ^ Date

HNF-SD-WM-DP-254, REV.0

y/<70 -go. <?f '/•


S = Worldist Slot Number, R = Replicate Number, A = Aliquot Code.

3 1 2

06/10/97 10:33 Q.50.9 372 2929 WESTINGHOUSE MO-924 2001V B)002

FileIdentity 1: ICV Identity 2: Quatity Control

"*3sk name : OPTIMA

-Tnple Weight : 1.0000 Solution Volume : 1.00

:n-Peak Integrations .- 3 off-peak Integrations : 1

9:52 AH June 10, 1997

HNF-SD-WM-DP P

"ian* -D.

1 R.S.D.

'<?an

5.D.

'< R.S.O.

'•can" . 0 .

X R.S.D.

'••ssn

T.O.

X R.S.D.

^'ean

' .£>.

K R.S.D.

Zr

(ppm)

4.885

0.016

0.333

Zn

(ppm)4.986

0.0140.282

Ce

(ppm)

4.676

0.022

0.466

Ho

(ppmi4.889

0.022

0.442

Sb

tppco)

4.661

0.037

0.794

Sr

Cppm)

4.887

0.023

0.479

Hi

(Pfxn)4.811

0.013

0.278

Sm

Cppm)5.078

0:025

0.499

Ag

Cppm)

4.952

0.015

0.305

V

<ppm)

4.977

0.016

0.314

Bi

(pprn)

4.979

0.054

1.083

La

tppra)

4.903

0.018

0.372

6a

Cppm)

4.904

0.027

0.548

Pb

<ppm)

4.801

0.031

0.637

Be

<ppm)

5.008

0.018

0.357

Si

Cppm)

4.851

0.023

0.472

Fe

(ppm)

4.832

0.024 .

0.492

p

(ppm)

5.001

0.060

1.194

Ti

<ppm)

4.795

0.019

0.400

nCppm)

4.958

0.004

0.083

Al

Cppm)

4.828

0.018

0.380

Ca

(ppm)

4.783

0.015

0.318

S

(ppm)

4.756

0.O16

0.327

Cd

(ppm)4.841

0.013

0.264

Co

Cppm)

4.925

0.007

0:138

Cr

(pptn)

4.721

' 0.011

0.230

Mg

(ppm)

4.614

, 0.005

0.114

S

(ppm)

5.008

0.026

0.517

Cu

Cppm)

5.187

0.035

0.672

Hd

(ppm)

5.213

0.031

0.589

As

Cppm)

4.965

0.0060.111

K

(ppm)

4.882

0.088

1.810

L i

(ppm)4.866

0.082

1.688

U

(ppm)

9.855

0.040

0.404

Ha

Cppm)

5.078

0.078

1.545

«n

(Ppm)

4.824

0.015

0.304

SIGNATURE ABOVE REPRESENTS CHEWCAlTECHNGLOGISTrtCOMPLETEDWERIRED THE CALIBRATIOWAMAiYSIS ON PAGESs

3 1 3

0509 372 2929 WESTINGHOUSE MO-924 200W

I den t i t y 1 : ICB Identity 2: Quality Control

Task name : OPTIMA

'airple Weight : 1.0000 Solution Volume : 1.00

'n-Peak Integrations : 3 Off-Peak Integrations : 1

9:59 AH June 10, 1997


*'ean

: .D .

% R.S.O.

*'ean

- . 0 .

% R.S.O.

Mean

' .D.

% R.S.D.

*'ean

<*'.D.

•: R.S.D.

vean

r .D.

K R.S.D.

Zr

(ppm)

0.002

0.001

34.677

Zn

Cppm)

0.001

0.000

35.420

Ce

Cppm)

-0.030

0.006

19.992

Mo

Cppm)

-0.002

0.001

87.820

Sb

(ppm)

0.087

0.034

38.950

Sr

(ppm)

-0.000

0.000

19.245

Hi(ppm)

0.000

0.001

355.500

Sm

(ppm)0.012

0.003

22.382

AgCppm)

-0.002

0.000

20.329

V

Cppm)

-0.001

0.000

26.027

Bi

Cppm)0.022

0.005

23.341

La

(ppm)

0.005

0.000

0.071

Ba

Cppm)-0.000

0.000

41.660

Pb

Cppm)0.002

0.005

219.381

Be

Cppm)-0.000

0.000

45.577

Si

Cppm)

0.007

0.002

28.402

Fe

Cppm)

0.002

0.001

26.260

P

Cppm)

0.006

0.003

49.898

Ti

Cppm)

0.001

0.000

19.323

Tl

Cppm)-0.007

. 0.020

285.447

Al

Cppm)

-0.032

0.007

22.691

Ca

(ppm)0.004

0.000

0.897

S

(ppm)

0.006

0.003

49.369

' ' Cd

(ppm)

0.001

0.000

47.173

Co

(ppm)

0.004

0.002

43.152

Cr

(ppm)

0.004

0.001

14.284

Hg

(ppm)

0.000

0.000

0.008

B

Cppm)-0.000

0.001

460.435

Cu

Cppm)

-0.001

0.000

24.688

lid

(ppm)-0.008

0.010

114.609

As

(ppm)

0.006

0.006

101.056

K

(ppm)

0.057

0.004

6.545

Li

(ppm>-0.000

0.000

39.692

U

(ppm)

0.076

0.008

10.811

Ha

Cppm)

-0.005

0.001

24.737

Hn

(ppm)

-0.001

0.000

14.246

314

•S509 372 2929

dentity 1: LLS Identity 2: Quality Control

"ask name : OPTIMASample Weight : 1.0000 Solution Volume : 1.00

On-Peak Integrations : 3 Off-Peak Integrations : 1

WESTINGHOUSE MO-924 200W

10:01 AM June 10, 1997


lean

5.0.

% R.S.D.

lean

S.O.

X R.S.O.

Mean

S.D.

X R.S.D.

Mean

S.O.

% R.S.O.

Mean

S.D.

X R.S.D.

Zr

(ppm)

0.024

0.001

2.353

Zn

(ppm)

0.022

0.000

0.022

Co

(ppm)

0.158

0.009

5.505

Ho

<ppm)0.097

0.001

0.740

Sb

(ppm)0.193

0.041

21.261

Sr

(ppm)

0.020

0.000

0.187

Wi

(ppm)

0.043

0.003

7.011

Sm

(ppm) .0.228

0.006

2.484

Ag

(PF"O0.023

0.000

0.945

V

(ppm)

0.100

0.001

1.217

Si

(ppm)

0.203

0.006

3.061

La

Cppm)0.109

0.002

1.742

8a

(ppm)

0.099

0.000

0.27-8

Pb

(ppm) .

0.180

0.004

2.384

Se

(ppm)

0.011

0.000

2.610

Si

(ppm)

0.201

0.002

0.788

fe

(ppm)0.100

0.002

1.790

P .

(Ppm) .0.430

0.010

2.253

Ti

(ppm)0.021

0.000

0.865

Tl

(ppm)0.354

0.015

4.191

Al

(ppm)

0.075

0.004

4.689

Ca

(ppm)

0.212

0.001

0.281

S

(ppm)

0.206

0.006

2.8?4

Cd

(ppm)

0.010

0.001

7.043

Co

(ppm)

0.040

0.O02

4.693

•cr

(ppm)

0.021

0.000

0.392

Kg

(ppm)

0.203

0.001

0.264

B

(ppn»0.106

0.002

2.222

Cu

(ppcn)

0.019

0.000

1.005

Hi

(ppm)

0.191

0.007

3.540

As

(ppm)

0.198

0.003

1.716

K

(PFW

0.591

0.005

0.823

Li

(ppm)

0.020

0.000

0.769

U

(ppm)

0.548

0.034

6.220

Ha

(ppm)

0.197

0.001

0.634

Hn

(ppm>

0.019

O.000

0.962

3 1 5

Of

Identity 1

Task name

i/10/97 10:;15 Q 5 0 9

: ICSA Identity 2: Quality: OPTIMA

"ample Ueight : 1.0000

On-Peak Integrations : 3

(lean

".D.

'A R.S.D.

Mean

S.D.

V. R.S.D.

Hean

S.D.

% R.S.O.

Hean

5.0.

: ; R . S . D .

Jiean

• 5 . 0 .

% R.S.D.

Zr

Cppm)0.006

0.001

10.433

In

Cppm)0.005

0.000

3.744

Ce

Cppm)

-0.027

0.004

16.303

Ho

(ppm)

-0.000

0.001

360.642

Sb

(ppm)

0.054

0.032

58.441

372 2929

Control

Solution Volume : 1Off-Peak Integrations :

Sr

(ppn)0.0020.0002.014

Ki

(ppm)0.0080.001

. 8.259

Sm

(ppm)0.0680.0057.154

Ag

Cppm)0.000

0.000

116.280

V

(ppm)

-0.002

0.001

21.804

Bi

Cppm)0.006

0.011

176.847

La

(ppm)0.014

0.001

5.110

Ba

(ppm)

0.001

0.000

4.804

Pb

Cppm)

-0.007

0.013

176.923

Bo

(ppal)

0.002

0.000

0.207

10:04 AH

:oo1

siCppm)

0.043

0.002

4.600

Fe

(ppm)

94.290

0.066

0.070

P

Cppm)

0.012

0.010

88.204

Ti

Cppm)

0.002

0.000

9.283

T l

Cppm)

-0.004

0.009

213.055

WESTINGHUUS]

June 10, 1997

Al

Cppro) "195.691

0.560

0.286

Ca

Cppm)99.918

0.096

0.096

S

Cppm)

-0.001

0.008

674.548

Cd

Cppm)0.000

0.000

243.087

3 •»->-• MO-924 200W

HNF-SD-WM-DP-254, REV

Co

(ppm)

-0.002

0.002

104.620

Cr

Cppm)

0.001

0.001.

164.156

Kg(ppm)

97.177

0.117

0.121

B

Cppm)

0.011

0.001

8.413

Cci

Cppm)

-0.002

0.000

8.513

Nd.

Cppm)

0.013

0.003

20.083

As

Cppm)

0.003

0.003

108.803

K

Cppm)

-0.053

0.017

32.744

L i

Cppm)-0.000

0.000

45.296

U

Cppm)0.171

0.027

15.625

Na

Cppm)185.184

0.859

0.464

Mn

Cppm)

-0.002

0.000

9.082

311

.WESTINGHOUSB. ->->-> MO-924 200W

-HNF-SD-WM-DP-246,

EJ006

Identity 1: ICSAB Identity 2: Quality Control

Task nsme : OPTIHA

''ample Height : 1.0000 Solution Volume : 1.00

""-Peak Integrations : 3 Off-Peak Integrations : 1

10:09 AH June 10, 1997


Hean

S.D.

Y. B.S.O.

Mean

S.D.

X R.S.D.

Mean

S.D.

% R.S.D.

Hean

s.D.

•i R.S.O.

Mean

S.D.

y. R.S.D.

Zr

tppm)

-0.003

0.002

57.536

zn

(ppm)

0.962

0.003

0.273

Ce

Cppm)

0.026

0.018

71.861

Ho

Cppm)

-0.004

0.002

46.988

5b

(ppm)0.069

0.033

48.478

Sr

Cppm)

0.002

0.000

7.282

Hi

(ppm)0.944

0.004

0.403

Sm

(ppm)

0.020

0.015

72.669

Ag

Cppm)

1.010

0.001

0.111

V

<ppn)0.485

0.001

0.180

B!

(ppm)

-0.010

0.003

25.211

La

Cppm)

0.001

0.001

57.168

Ba

Cppm)

0.498

0.002

0.498

Pb

Cppm)

0.927

0.025

2.668

Be -

(ppm)

0.488

0.002

0.440

Si

(ppm)

0.015

0.002

16.100

Fe

Cppm)

93.002

0.070

0.075

P

Cppm)

0.051

0.004

7.917

T i

Cppm)

-0.000

0.001

112.294

T l

(ppnO

0.020

0.050

244.277

At

(ppm)

196.428

0.828

0.421

Ca

(ppre)

98.780

- 0.392

0.397

sCppm)

0.001

0.011

1284.742

Cd

(ppm)

0.951

0.004

0.376

Co

(ppm)

0.485

0.005

1.084

Cr

(ppm)

0.481

0.001

0.180

Kg

(ppm)

96.191

0.389

0.405

B

(ppm)

0.010

0.001

5.073

Cu

CppnO0.494

0.003

0.509

Nd

Cppm)

0.006

0.004

64.784

AS

(ppm)

-0.000

0.007

3700.009

K

(ppm)

-0.060

0.016

26.412

L i

Cppm)

0.966

0.005

0.527

U

(ppm)

-0.046

0.064

139.294

Na

Cppm)

185.438

1.055

0.569

Mn

(ppm)

0.474

0.000

0.104

3 1 7

06/10/97 10:40 ©509 372 2929

Identity 1 : S97T001203J. Ident i ty 2 : acid d f I . , . 0 5 - 1 0 - 2 - 8

"ask name -. OPTIHA

'ample Height : 1.0000 Solution Volume : 1005.00


10:47 AH June 10, 1997


•'ean

' . 0 .

X R.S.D.

v-.m

' . D .

V R.S.D.

I'^an

3.0 .

Si R.S.D.

l<»an

!' D.

K R.S.D.

»'>?nS D.

s; R.S.D.

zr(ppm)

2.154

O.570

26.453

Zn

(ppm)

0.900

0.20823.055

Ce

(ppm)

-25.646

7.026

27.397

Mo

<ppm)2.093

0.865

41.302

sb(ppm)123.92927.39022.102

Sr

(ppm)-0.1520.075

49.487

Hi<ppm)

0.1392.208

1585.104

Sm

(ppro)

17.415

5.558

31.914

Ag

Cppm>

0.188

0.770

409.887

V

(pom)-1.716

0.532

31.000

Bi

CppnO33.505

7.274

21.709

La

(ppcn)2.516

1.43757.108

Ba

(ppm)0.194

0.154

79.373

Pb

(ppra)

-6.517

7.727118.559

Be<PPm)

-0 .146

0.410

281.551

Si

(ppm)

77.252

1.4761.910

Fe

(ppm)

-4.694

0.53211.342

P

<ppm)

258.904

3.578

1.382

Ti

(ppm)

0.305

0.458

150.357

Tl

(ppm)

-52.039

11.956

22.975

Al(ppm)-26.472

3.313

12.515

Ca

(ppm)

0.489

0.039

7.873

S

<PfM>38.786

3.476

8.962

Cd

(ppm)

1.966

0.30915.732

Co

(ppm)8.716

3.253

37.319

Cr

(ppm)7.452

0.466

6.256

MS(ppm>

2.407

0.000

0.002

B

(ppnD-0.183

0.726

395.544

Cu

(ppm)

' -0.8120.371

45.710

«d(ppm)-14.620

0.8415.753

As

(ppm)

-2.004

1.927

96.124

K

(ppm)

4270.808

28.209

0.661

Li

(ppm)

-0.217

0.182

83.904

U

(ppm)

64.609

20.92732.391

No

(ppm)

27184.805

156.484

0.576

Mn

(ppm)

-1.559

0.179

11.470

3 1 8

06/10/97 10:41 ©509 372 2929 WESTINGHQUSE HO-924 Z00W

Identity 1: S97T001203 Identity 2: add d1l.,.05-10 ml

"ask name : OPTIMA

•sample Weight : 1.0000 Solution Volume : 201.00


10-.51 AH June 10, 1997


"ean

S.D.

'•'• R.S.D.

*'ean

T.D.

X R.S.D.

• .D.

'< R.S.D.

l">an

S 0 .

% R.S.D.

I'^an

P.D.

i'. R.S.D.

Zr

Cppm)

-0.443

0.099

22.440

Zn

<ppm)

0.391

0.032

8.083

Ce

(ppm)

-8.315

1.517

18.241

Ho

(ppm)

-0.104

0.240

229.712

Sb

(ppm)

10.670

8.114

76.044

Sr

(ppm)

-0.022

0.000

O.OOO

Ni

(ppm)

0.022

0.408

1876.865

sm(Ppm)

-3.066

0.929

30.294

Ag

(ppm)

-0.042

0.015

35.701

V

<ppm) ;

-0.571 :

0.166 ;

29.093

Bi

(ppm)

2.492

0.364

14.600

La

(ppm)0.985

0.144

14.645

Ba

Cppm)

0.039

0.015

39.686

Pb

(ppm)

-2 .989

0.771

25.776

Be

(ppm)

-0.067

0.027

40.514

Si

CppnO

37.747

0.484

1.283

Fe

(ppm)

-8.463

0.070

0.832

P

(ppm)

243.719

3.316

1.361

Ti

(ppm)

-0.096

0.023

24.201

Tl

(ppn>)

-8.234

1.523

18.498

Al

(ppm)

-5.919

0.587

9.925

Ca

(ppm)

4.027

0.013

0.332

S

(ppm)

37.340

0.726

1.944

Cd

(ppm)

-0.016

0.093

571.693

Co

(ppm)

7.039

0.354

5.028

Cr

(ppm)6.730

0.076

1.131

Mg

(ppm)

0.575

0.020

3.535

B

(ppm)

2.019

0.170

8.437

Cu

(ppm)

-0.236

0.O32

13.345

Nd

(ppm)

-3.066

1.605

52.353

As

(ppm)

1.592

0.479

30.115

K

(ppm)

4295.268

33.798

0.787

Li

(ppm)

0.029

0.017

57.713

U

(ppm)

-18.617

4.339

23.309

Ka

(ppm>26597.575

121.750

0.458

Mn

(ppm)

-0.292

0.035

12.160

319

10:41 ©509 372 2929

Identity 1: S97I0012Q3J) Identity 2: acid di l . , .05-10 mlTask name : OPTIMASairple Weight : 1.0000 Solution Volume : 201.00On-Peak Integrations : 3 Off-Peak Integrations : 1

10:54 AM June 10, 1997


Mean

S.D.

% R.S.D.

Mean

S.D.

% R.S.D.

Mean

S.D.

X R.S.D.

Mean

S.D.

% R.S.D.

"ean".D.X R.S.D.

Zr

(ppm)

0.130

0.130

100.184

Zn

(ppm)

0.394

0.035

8.8(51

ce<ppm)

-0.078

1.016

1301.206

Mo

(ppm)

0.042

0.192

455.313

• S b

(ppm)23.6949.387

39.620

Sr

CppnO

0.022

O.OOS

34.641

Hi

(ppm)

1.228

0.319

25.985

sm(ppm)

0.9190.697

75.835

Ag

(ppm)

0.293

0.109

37.408

V

(ppm)

0.069 ;0.126

181.517

Bi

<ppm)

4.761

2.61154.838

La

(ppm)-0.2480.287

115.732

Ba

(ppm)0.1260.015

12.211

Pt>

(ppra)1.9981.800

90.071

Be

(ppm)0.0320.055

170.613

Si

(ppm)44.2210.4290.971

Fe(ppm)

-8.4830.4745.592

p

(ppm)

246.958

2.817

1.141

Ti

(ppm)0.141

0.059

42.159

Tl

(Ppm)2.2292.589

116.156

Al

(ppm)

-3.471

0.079

2.278

Ca

(ppm)

0.392

0.015

3.937

S

(ppm)

36.969

0.529

1.4S1

Cd

(ppm)0.377

0.135

35.769

Co

(PPm)7.159

0.383

5.347

Cr

(ppm)6.789

0.141

2.074

«9

(ppm)

0.458

0.020

4.440

B

(ppm)2.3850.0823.449

Cu

(ppm)-0.077O.078

101.609

Hd

(ppm)0.1331.280

963.961

As

(ppm)-0.5660.240

42.399

K

(ppm)4261.349

23.7770.558

Li

(PPm)

0.135

0.038

28.346

U

(ppm)

3.725

0.504

13.522

Na

(PPm)

26173.706

171.067

0.654

Mn

(ppro)-0.352

O.036

10.154

320

06/10/97 10:42 Q509 372 2929

e, REV.Identity 1 : S97T0Q1203_A Identity 2: acid dU. , .05-10 ml

Task name : OPTIMA

Sample Weight : 1.0000 Solution Volume : 201.00


10:57 AM June 10, 1997


I lean

5.D.

% R.S.D.

"ean

S.D.••'. R.S.D.

''^an

" -D.

:< R.S.O.

!' D.

X R.S.D.

man

S D.

S R.S.D.

Zr

(ppm)199.662

0.369

0.185

Zn

(ppm)204.915

0.361

0.176

Ce

(ppm)192.031

1.865

0.971

Mo

(ppm)

200.667

0.980

0.488

Sb

<ppm)214.922

10.698

4.978

Sr

(pptn)

199.979

0.173

0.086

Ni

<ppm)195.133

1.138

0.583

Sra

(ppm)204.842

0.555

0.271

Ag

(ppm)86.587

0.554

0.640

V '.

(ppm)203.386

0.139

0.068

Bi

(ppm)205.933

2.242

1.089

La

(ppm>199.969

1.141

0.571

Ba

(ppm)198.340

0.248

0.125

Pb

<ppm)

191.397

3.583

1.872

Be

(ppm)199.931

0.383

0.191

Si

(ppm)261.644

0.251

0.096

Fe

(PpnO

188.067

1.204

0.640

p

<ppm)453.204

2.230

0.492

Ti

,(PP<n)194.654

0.144

0.074

U

(ppm)198.800

3.895

1.959

Al

(ppm)

191.036

1.894

0.991

Ca

(ppn)

192-921

0.299

0.155

S

(ppm)

234.213

1.694

0.723

Cd

(ppm)

196.203

0.326

0.166

Co

(ppm)

209.337

0.663

0.317

Cr

(ppm)

199.310

0.227

0.114

Mg

(ppm)

188.315

0.1280.068

8

(ppm)203.228

0.556

0.274

Cu

(ppm)

209.324

0.189

0.090

Nd

(ppm>

206.258

1.819

0.882

As

(ppm)

207.348

2.945

1.421

K(ppm)

4280.759

9.436

0.220

Li

(ppm)

190.876

0.173

0.091

U

(ppm)

393.556

3.922

0.997

No

(ppm)

25644.358

42.676

0.166

Mn

(ppm)

196.687

0.342

0.174

221

06/10/97 10:43 ®509 372 2929 WESTINGHOUSE -»->-> MU-824 zuuw

Identity 1: S97T001203_X Identity 2: acid di I . , .05-10-1-9

Task name : OPTIMA

Sample Height : 1.0000 Solution Volume : 2010.00


11:01 AW June 10, 1997


Mean

S.D.% R.S.D.

'nan

?.D.X R.S.D.

lean

S.D.

:; R.S.D.

Mean

" . 0 .

',', R.S.D. •

vean

" : .D.

% S.S.D.

Zr

(ppni)6.301

1.74427.678

Zn

(ppm)

0.102

0.806

788.481

Ce

(ppm)-90.143

7.1237.901

Ho

(ppcn)

-1.884

1.961

104.092

sb

<ppm>

94.102

12.43413.213

Sr

(ppm>0.087

0.272312.250

Ni

(ppm)

-2.901

4.889168.538

Sm

(PpnO58.001

9.96817.187

Ag

<ppm>3.181

0.736

23.136

V

(ppm)-3.261

1.829

56.089

Bi

(ppm)22.637

9.361

41.355

La

<ppm)14.216

3.78026.593

Ba

(ppm)

0.2520.341

135.218

Pb

Cppra)

8.297

16.794

202.404

Be

<ppm)

0.2080.0073.526

Si

<ppm)101.011

0.3750.371

Fe

(ppm)

-4.1704.884

117.122

p

Cpptn)

284.16517.8646.286

Ti

(ppm)

2.716

0.1254.585

TL

(ppm)-97.756

36.75337.597

Al

<ppm)

-47.9507.712

16.083

Ca

<ppm)

-3.693

0.2045.521

S

(ppnO41.6954.875

11.692

cd(ppm)

-0.170

1.417

833.823

Co

(ppm)

8.8943.768

42.364

Cr

(ppm)2.848

2.269

79.673

Hg

(ppnO

5.4000.203

3.765

B

(ppm)

-1.0372.211

213.089

Cu

(ppm)

-2.3810.178

7.475

Nd

(ppm)

-0.864

10.7931248.521

As

(ppm)

-5.197

13.144252.905

K

(ppm)

4179.48512.313

0.295

Li

(ppm)

-0.2900.302

104.114

U

(ppm)

266.293

39.00914.649

Na

Cppm)

27748.222

24.771

0.089

Mn

(ppm)

-2.0950.005

0.235

3 2 2

06/10/97 10:43 Q509 872 2929 WESTINGHOUSE

Identity I : S97T001203_AX Identity 2: acid dil.,.05-10-1-9Task name : OPTIMASan-ple Ueight : 1.0000 Solution Volume : 2010.00On-Peak Integrations : 3 off-Peak Integrations : 1

11:04 AH June 10, 1997


MeanS.D.% R.S.D.

'fian

S.0.

"• R.S.D.

Mean•~.D.

:; R.S.D.

Mean

" . D .5; R.S.O.

'•'^an' . D .

' 8 .S.D.

Zr

(ppm)19738.770

1.7580.009

Zn

(ppm)18817.293

10.488

0.056

Ce

(ppm)19374.048

64.197

0.331

Ho

Cppm)18796.361

12.8150.068

Sb

(ppm)

19931.96112.9350.065

Sr

Cppm)19785.170

33.5690.170

Hi

<ppm)19011.637

14.054

0.074

sm

(ppm)20643.349

26.8520.130

AS(ppm)

18107.177

40.6190.224

V

(ppm>19376.486

27.624

0.143 ,

Bi

<ppm)19884.584

30.7470.155

La

<ppm)19985.633

18.694

0.094

Ba

Cppm)19892.990

68.2120.343

Pb

(ppm)19555.631

104.2730.533

Be

Cppm)19710.523

22.197

0.113

Si

<PpnO21161.322

68.764

0.325

Fe

(ppo)19342.596

52.925

0.274

P

(ppm)

19657.158

139.5910.71O

Ti

(PPm)

19418.998

8.6000.044

Tl

(ppn»

20557.74154.319

0.264

Al

(ppm)19327.829

21.981

0.114

Ca

(ppm)

19763.67815.616

0.079

S

(ppm>18443.178

97.5640.529

Cd

(ppm)19054.141

32.0000.168

Co

(ppm)18834.089

48.9350.26O

Cr

(ppm)18569.685

28.532

0.154

M9

(PPm)18723.123

12.3550.066

B

(ppm)19892.017

23.5690.118

Cu

(ppm)19667.540

31.215

0.159

Nd

(ppm)

21204.958

50.9610.240

AsCppm)

19086.546

12.957

0.068

K

(ppm) .23961.339

56.6760.237

Li

(ppm)

19671.113103.501

0.526

U

(ppm)

40017.02863.724

0.159

Na

(ppm)

46323.831

242.139

0.523

Hn

(ppm)

19051.352

39.0330.205

323

TO*5UH ay 2 zyzw

Identity 1: ICSA Identity 2: Quality Control

Task name : OPTIMA

Sample Weight : 1.0000 Solution Volume : 1.00

On-Peak Integrations ; 3 Off-Peak Integrations : 1

11:11 AH June 10, 1997 ' ' '


Mean

S.D.

X R.S.D.

MeanS.D.

% R.S.D.

Mean

S.O.

% R.S.O.

lean

S.D.

X R.S.O.

Mean

% S.S.D.

Zr

(ppm)

0.005

0.002

33.717

Zn

(ppm)

0.006

O.001

8.154 .

Ce

(ppra)

-0.000

0.004

2043.024

Mo

(ppm)

0.000

0.001

528.507

Sb

(ppm)

0.082

0.011

13.&49

Sr

(ppm)

0.0020.000

4.767

Ni

(ppm)

0.0060.001

23.083

Sm

Cppm)

0.061

0.006

9.690

Ag

(ppm)0.014

0.001

4.432

V

(ppm)

-0.001 •

0.000

37.010

Bi

(ppm)

-0.019

0.008

44.012

La

(ppm)0.007

0.002

26.405

Ba

(ppm)

0.002

0.000

8.445

Pb

(ppm)-0.023

0.008

32.684

Be

(Ppm)

0.003

0.000

4.520

Si

(ppm)

O.048

0.001

1.0S4

Fe

(ppm)96.037

0.201

0.209

P

(ppm)

0.026

0.00934.758

Ti

(ppm)

. 0.001

0.000

19.239

Tl

(ppm)-0.013

0.018

144.898

AL

(PPm)

203.599

1.454

0.714

Ca

(ppm)

98.997

0.099

0.100

s(ppm)

0.004

0.005

135.189

Cd

(ppm)

0.002

0.001

40.110

Co

(ppm)

0.005

0.002

32.494

Cr

(ppm)

0.005

0.003

63.366

Kg

(ppm)

95.996

0.140

0.146

B

(ppm)

0.015

0.001

3.720

Cu

(ppm)

-0.001

0.000

16.194

Nd

(ppm)0.011

0.007. 67.976

As

(ppm)

0.018

0.003

18.777

K

(ppm)

0.065

0.016

24.970

L i

(ppm)

0.001

0.000

31.909

U

(ppm)

0.123

0.035

28.349

No

(ppm)

181.075

0.759

0.419

Hn

(PP«i)

-0.003

0.000

7.187

324

Identity 1: ICSAB Identi ty 2: Quality Control

Task name : OPTIMA

Sample Weight : . 1.0000 Solution Volume : 1.00

On-Peak Integrations : 3 Off-peak Integrations : 1

11:14 AM June 10, 1997


Mean

S.O.

% R.S.D.

Mean

S.D.

% R.S.D.

Mean

S.D.

X R.S.O.

Mean

S.O.

X R.S.O.

Hean

'~.D.

:: R.S.O.

Zr

(ppra)

0.002

0.001

52.713

Zn

(ppm)

0.962

0.006

0.619

Ce

(ppm)

-0.029

0.008

28.924

Mo

(ppm>

-0.003

0.001

30.679

Sb

(ppm)0.077

0.005

6.751

Sr

Cpprn) ;

0.002

0.000

6.818

« i

(ppm)

0.950 :

0.006 .

0.679

Sm

(ppm)

0.065

0-010

14.521

Ag

(ppm) :

1.017

0.003 :

0.249

V

(ppm)0.482 !

- o.ooo :0.098 :

i i i

(ppm)

• -O.004

0.009

222.630

La

(ppm)

0.011

0.001

13.243

Ba

<ppm>0.498

0.001

0.150

Pb

(ppm)0.931

0.031

3.334

Se

(ppm) •

0.490

0.000

0.055

Si

(ppm)

0.045

0.007

16.018

Fe

(ppm)

94.759

0.183

0.193

P

(ppm)

0.028

0.011

39.658

Ti

(ppm)

0.001

0.000

17.929

n(ppm)

-0.021

0.015

70.629

Al

(ppm)

207.279

1.925

0.929

Ca

(ppm)

99.707

0.105

0.105

S

(ppm)

-0.007

0.010

146.407

Cd

Cpptn)

0.952

O.008

0.792

Co

(ppm)

0.477

0.002

0.375

Cr

(ppm)

0.479

0.005

0.965

Hg

(ppm)

95.848

0.377

0.393

5

CppnO

0.014

o.ooo2.286

Cu

(ppm)

0.495

O.001

0.120

Kd

(ppm)

0.012

0.011

92.327

As

(ppm)

0.006

0.009

148.867

K

(ppm)

-0.037

0.012

33.203

L i

(ppm)

0.923

0.006

0.658

u(ppm)

0.138

0.044

31.860

Ha

(ppm)

185.469

1.252

0.675

Hn

(ppm)

0.475

0.001

0.281

3 2 5

IioIdentity 1: CCV Identity 2: Quality Control 11:18 AM June 10, 199/Task name : OPTIMASample Height : 1.0000 Solution Volume : 1.00 HNF-SD"WM-DP-254, REV. 0On-Peek Integrat ions : 3 Off-Peak i n t e g r a t i o n s : 1

Mean

S.O.

% R.S.D.

Mean

S.O.-

% R.S.D.

lean

S.O.

X R.S.D.

Mean

S.D.

X R.S.D.

J^an- . 0 .

~ R.S.D.

zr(ppm)

4.866

0.008

0.171

Zn

<ppoi)4.833

0.012

0.257

Ce

(ppm)

4.652

0.026

0.560

Ho

<ppm)

4.734

0.015

0.311

Sb

(ppm)4.810

0.038

0.782

Sr :

(ppm)4.894

0.008

0.163

Hi

(ppm)4.701

0.018

0.373

Sm

(ppm)

5.150

0.004

0.083

Ag

<ppm)

4.852

0.008

0.166

V

(ppm)4.884 :

0.014

0.287

Bi

(ppm)

4.916

0.021

0.420

La

CppnO4.908

0.010

0.212

Ba

(ppm)

4.930

0.005

0.108

Pb

(ppm)

4.693

0.011

0.230

Be

(ppm)4.991

0.007

0.145

Si

(ppm)4.772

0.013

0.268

Fe

(ppm)4.802

0.015

0.317

P

(ppm)

4.876

0.030

0.606

Ti

(ppm)

4.713 .

0.011

0.225

Tl

(ppm)

4.907

0.023

0.464

AL

(ppm)4.771

0.008

0.167

Ca •

(pfOT)

4.816

O.004

0.082

s(PFfiO

4.657

0.031

0.660

Cd

(pptn)

4.726

0.009

0.189

Co

(ppm)

4.773

0.014

0.283

Cr

(ppm)

4.568

0.014

0.298

Hg(ppm)

4.501

0.015

0.341

B

(ppm)4.992

0.014

0.286

Cu

(ppm)

5.233

0.005

0.090

Hd

(ppm)5.366

0.021

0.400

As

(ppm)

4.871

0.016

0.338

K

(ppm)4.924

0.024

0.497

L i

(ppm)

4.938

0.026

0.535

U

(pF*n)10.050

0.037

0.365

Ha

(ppm)

5.212

0.017

0.333

Hn

(ppm)4.711

0.008

0.166

3 2 6

•3509 372 2929 MO-924 200W

identity 1: CCBiask name : OPTIMASample Weight :On-Peak Integrations : 3

Identity 2: Quality Control

1.0000

11:26 AH June 10, 1997

Solution Volume :Off-Peak Integrations

1.001


MeanS.D.% R.S.D.

MeanS.O.% S.S.D.

MeanS.O.% R.S.D.

MeanS.D.X R.S.D.

MeanS.D.% R.S.D.

Zr(ppm)

0.0040.002

48.462

ZnCppn)

0.0000.000

844.028

Ce(ppm)-0.0600.016

27.531

Ho(ppm)-0.0000.001

192.439

Sb(ppm)

0.0660.029

44.209

Sr

(ppm)-0.0000.00057.735

Mi(ppm)

0.0010.002

175.886

Sm(ppm)

0.0330.011

34.387

Ag

(ppm)0.0020.00155.695

V(ppm)-0.0040.001

28.921

Bi

(Pf<n)0.023

0.00836.189

La(ppm)

0.0040.00250.622

Be(ppm)-0.0010.00050.942

Pb<ppm)-0.0010.016

1878.975

Be(ppm)-0.000

0.00030.848

Si(ppm)

0.0080.003

34.492

Fe(ppm)-0.0050.002

43.351

P

(ppm)0.0290.00518.057

Ti(ppm)

0.0010.001

38.314

Tl

(ppm)-0.0310.036

116.608

Al(ppm)-0.0350.00822.143

Ca(ppm)

0.0050.0001.376

S(ppm)

0.0030.002

65.841

Cd(ppm)

-0.0000.00088.193

Co

(ppm)0.0020.0000.543

Cr

(ppnO-0.0000.003

685.514

Kg(ppm)

0.0010.000

21.419

B

(ppm)0.0000.002

690.620

Cu(ppm)

-0.0020.00129.767

Nd

Cppm)-0.0070.00575.495

As<ppm)

-0.001O.002

303.808

K(ppm)

0.0590.01017.112

Li

<PPm)-0.001

0.00025.240

U

(ppm)0.1140.063

55.481

Na(ppm)-0.0010.003

458.341

Mn(ppm)-0.002O.00010.018

3 2 7

07/16/9711:35A-0004-1



Analyst: J(W Instrument: ICPOi-h

Method: LA-505-451/161 Rev/Mod C~l

Page: i

Book#

jinnWorklist Comment: ICP T-201 (SOLID ACID DIGEST)

S Type Sample# R A

1 ICV

2 ICB

3 LLS

4 ICSA

5 ICSAB

6 PREPSTDTJA

7 PREPBLKTJA

8 SERDIL S97T001250 0 A

9 SAMPLE S97T001250 0 AAnalytes Requested:

10 DUP S97T001250 0 A

11 SPK-PREDIG S97T001250 0 A

S97T00125S 0 A

13 CCB

14 SERDIL

15 SAMPLE S97T0012S6 0 AAnalytes Requested

Test

©ICP-QC

©ICP-QC

©ICP-QC

©ICP-QC

OICP-QC

©ICP-A01

©ICP-A01

SICP-A01

©ICP-A01: AG-A-01BE-A-01CR-A-01MG-A-01P-A-01SM-A-01ZN-A-01

©ICP-A01

SICP-A01

©ICP-QC

©ICP-QC

©ICP-A01

©ICP-A01i AG-A-01

Matrix

QC

QC

QC

QC

QC

SOLID

SOLID

SOLID

SOLID, AL-A-01, BI-A-01, CU-A-01, MN-A-01, PB-A-01, SR-A-01, ZR-A-01

SOLID

SOLID

QC

QC

SOLID

SOLID, AL-A-01

Group# Proj ect

97000311 T-201AS-A-01 , B-A-01 , BA-A-01CA-A-01 , CD-A-01 , CE-A-01FE-A-01 , K-A-01 , LA-A-01MO-A-01 , NA-A-01 , ND-A-01S-A-01 , SB-A-01 , SE-A-01TI-A-01 , TL-A-01 , U-A-01

CO-A-01LI-A-01NI-A-01SI-A-01V-A-01

97000311 T-201AS-A-01 , B-A-01 , BA-A-01



328

07/16/9711:35A-0004-1

HNF-SD-WiW-DP-254, REV. 0

LABCORE Data Entry Template for Worklist# 19341Page:

S Type Sample# R A Test Matrix Group# ProjectBE-A-01 , BI-A-01 , CA-A-01 , CD-A-01 , CE-A-01 , CO-A-01

FE-A-01 , K-A-01 , LA-A-01 , LI-A-01MO-A-01 , NA-A-01 , ND-A-01 , NI-A-01S-A-01 , SB-A-01 , SE-A-01 , SI-A-01TI-A-01 , TL-A-01 , D-A-01 , V-A-01

CR-A-01MG-A-01P-A-01SM-A-01ZN-A-01

CU-A-01MN-A-01PB-A-01SR-A-01ZR-A-01

S97T001256 0 A SICP-A01 SOLID

17 SPK-PREDIG S97T001256 0 A ©ICP-A01 SOLIDfiktuf

18 ICSA 9ICP-QC QC

19 ICSAB •

20 CCV

21 CCB

©ICP-QC QC

©ICP-QC QC

©ICP-QC QC

01-/1,-11An Signature Date

~Q . / , ; « / . J F I

srn00 iifr-i hhl-1

91'Ml

A?

1-1

fIf

HIfO

P,iff

IiIrt,



. f /4 tiA turn



3 2 9

HNF-SD-WM-DP-254.REV.0

n.@£y£FA~..f>-><n =

ic- (Zg-XZF-l,* .*«*

3 3 0

07/16/97 10:08 © 5 0 9 372 2929 . WESTINGHOUSE -><-> MO-924 200W

HNF-SD-WM-DP-254, REV. 0Wed 07-16-97 11:03:41 AM page 1P lalysis Report

// Sample Name

Summary

File Method Date Time OpID Type Mode

1 ICV2 ICB3 LLS4 ICSA5 ICSAB6 PREPSTDTJA7 PREPBLKTJA8 S97T001250 L9 S97TOO125O"

10 S97T001250 D11 S97T001250~S12 S97T001250~X13 S97T001250~~AX14 CCV ~15 CCB16 S97T001256 L17 S97T001256""18 S97T001256 D19 S97T0O1256~S

21 S97T001256~X22 S97T001256~~AX23 ICSA24 ICSAB25 CCV 126 CCB~2.

970716A970716A970716A970716A970716A97O716A970716A970716A970716A970716A97O716A970716A970716A970716A970716A970716A. 970716A970716A970716A97071GA-970716A970716A970716A970716A970716A970716A

ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP2ICP21CP2

-lessICP2ICP2ICP2ICP2ICP2ICP2

07/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/9707/16/97

CONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONCCONC

CONCCONCCONCCONGCONCCONC

SIGNATURE ABOVE REPRESENTS CHEMICAL TECHNOLOGIST/CtCOMPkETEOVERIFtED THE CALIBRATION/ANALYSIS ON PAGES^

3 3 1

07/16/97 10:09 © 5 0 9 372 2929 . WESTINGHOUSE -»->-> MO-924 200W

HNF-SD-WM-DP-254, REV. 0dialysis Report Averages Wed 07-16-97 11:03:41 AM page 2

'/ Sample Name Al Ba

1 ICV2 ICB3 IXS4 ICSA5 ICSAB6 PREPSTDTJA7 PREPBLKTJA8 S97T00125O L9 S97T001250"

10 S97T0O125O D11 S97T001250~S12 S97T001250~X13 S97T001250~AX14 CCV15 CCB16 S97T001256 L17 S97T001256-18 S97T001256 D19 S97T001256~S20 S97T001256~X21 S97T001256~X22 S97T001256~AX23 rCSA24 ICSAB25 CCV 126 CCB~2

>i Sample Name

5.055.0001.0230.0020.9703.6002-.0001.0246.0338.0296.5892.0069382.55.124.0007.0157.0117.0116.5801.0011.003687.36.0381.98695.130.0004

Bi

4.942.0095.1074244.4244.54.825

Q.1422.6927.5470.50395.510.7880397.75.048-.0034.4525.4148.39694.906.0477.521498.60248.2245.95.052.0073

Ca

5.239-.0157.1812-.0385-.05985.038-.0050-.3893.0301.03895.202-.1849407.35.307-.0196-.0861-.0156-.01154.851-.0170-.2505101.2-.0370-.01855.337-.0150

;d

5.109.0002.0102.0017.94384.762.0005.0196.0104.01234.840.0356402.15.155.0001.0016.0017.00504.505-.0020-.006299.33.0029

5.049.0000.1030-.0046-.00564.961

Q.7257.8219.8579.93305.995.9130404.85.124-.0015.4655.4521.61215.538.0542.4452100.5-.0025-.00275.154-.0046

Ce

5.034.0053.2123.0068.00815.025-.0001.4370.4804.38045.615.0877412.15.178-.0080.0773.1012.10714.842.0085.0491101.5.0082

5.050.0001.1013.0001.48274.901.0011.3252.3185.27005.236.3233413.45.232-.0001.1053.1017.10624.756. 0108.1053102.7. 0001.48885.275.0000

Co

5.070.0059. 0461.0027.47674.955.0032.1211.0449.05205.033.2170402 . 55.133.0023.0250.0102.01214.670.0037.016899.63.0060

5.206.0002.0108.0005.48745.038.0008.0080.0003.00144.970.0160403.15.297.0001.0013.0003.00014.803.0002.0044100.6.0005.49025.330.0002

Cr

5.139.0015.0237-.0013.47294.839.007830.4229.4426.4244.0130.65433.95.201.00028.5908.0918.51111.50.88168.719108.4-.0020

1 ICV2 ICB3 LLS4 ICSA5 ICSAB6 PREPSTDTJA7 PREFBUCTJA8 S97T001250 L9 S97TOO125O"

10 S97T001250 D11 S97T001250-S12 S97T001250TC13 S97TOO125O~AX14 CCV15 CCB16 S97T001256 L17 S97T00125.6"18 S97T001256 D19 S97T001256-S20 S97T001256~X21 S97T001256~X22 S97T001256~AX23 ICSA ~

5.159-.0039.2081.0207-.01074.837.0127694.2669.2577.9883.7699.81089.5.272.0019109.4102.0107.491.6811.14110.4209.0-.0160

5.132.0015.1980254.5253.55.004

Q.12667.2357.0825.88313.967.204420.15.226-.00141.6021.5231.5966.052.16131.592103.1260.1

07/16/97 :

'nalysis Report

// Sample Name

©509 372 2929 _.WESTINGHOUSE •*->-> MO-924 200W

HNF-SD-WM-DP-254.REV.0Averages Wed 07-16-97 11:03:41 AM page 3

Bi Ca Cd Ce Co • Cr

H1004

242526

it

l2345678910111213141516171819"2"0~212223242526

#

123456789

1011121314151617

ICSABCCV 1CCB~2

Sample Name

ICVICBLLSICSAICSABPREPSTDTJAPREPBLKTJAS97T001250 LS97T001250~S97T001250 DS97TO01250~SS97T001250TCS97T001250~AXCCV ~CCBS97TOO1256 LS97TO01256"S97T001256 DS97TO01256~SSy /TDOlz^O 2vS97T001256~XS97T001256~AXICSAICSABCCV 1CCB~2

Sample Name

ICVICBLLSICSAICSABPREPSTDTJAPREPBLKTJAS97TO01250 LS97T0O1250"S97T001250 DS97T001250~SS97T001250~XS97T001250~AXCCVCCBS97T0O1256 LS97TOO1256"

-.00955.240.0086

Cu

4.856.0004.0182-.0082.44834.404

Q.0116.0077.0003-.00214.388.0254370.04.995.0003-.0071-.0066-.00984.184roDUb-.006491.83-.0084.44915.023.0012

Mg

5.154.0104.2128253.3252.74.828.02091.5171.8201.5487.4271.232422.65.271-.0079.2821.3184

257.95.251-.0008

Eu

.0024

.0007

.0009-.0151-.0107.0019-.0009.0550.0637.0499.0845.0421.2534.0019-.0002.0110.0121.0132.0132flfli '

. UUJ.H

.0021.0549-.0207-.0168.0022-.0002

Mil

4.994.0005.0205-.0057.44914.738.0031222.8253.0209.6364.9223.0632.85.083.000034.8736.10

.95035.150-.0008

Fe

4.769-.0003.094493.9693.774.560.039056.0854.3048.7975.8956.37432.84.852-.000910.9110.3310.8513.021 11411.10104.495.5594.664.857-.0009

Mo

5.054.0015.1036-.0108-.00954.791.0023-.0421.-.0534-.04354.959-.0538401.85.128.0008-.0058-.0080

.01535.204.0003

K

5.003.2008

Q.6438.3306.01684.995.136627.7426.1124.0640.5521.94424.05.161.018922.4921.1220.5424.61

21.20120.8.0654.21184.974-.0045

Na

4.936.0033.1891197.5199.95.068

Q1.016180.4176.5160.9246.6181.1583.65.061.0111133.7129.0

.48025.123.0039

L a •

5.il3.0010.1039-.0047-.00365.044.0016146.1143.5116.1189.5146.4552.55.249-.001931.5830.6431J953O.;86o,, ."lift 7JT£OV32.18132.2-.0047-.00325.282-.0005

Nd :

5.125. 0002.2066.0019. 00024.952.0007.0135.0497.04814.978.0517398;.95.257-.0006.0034.0087

.48025.210.0021

LI

5.079.0039.0205.00181.0224.976-.0011-.0118-.0005.00004.935-.0188404.25.232-.0007-.0041-.0013-.00094.756

n n n A ••

-.0106100.1.00201.0115.256-.0001

Ni

5.109.0051.0376-.0079.93554.954.00153.5253.4423.1369.5753.520407.15.108.0015.7380.6312

333

07/18/97 :

Analysis Report

it Sample Name

Q 5 0 9 372 2929 WESTINGHOUSE •?-•-» MO-924 200W

HNF-SD-WM-DP-254, REV. 0 \Averages

Mg

Wed 07-16-97 11:03:41 AM page 4

Mo Na . Nd • ' Ni

18 S97T001256 D19 S97TOO1256-S

- 20 S97T001250~

.31904.829.0291

38.3335.923.5S3

-.00844.787

124.3128.9

.0006 13.48

.01034.698.0041

.67295.204.0040

212223242526

if.

12345678910111213141516171819

212223242526

It

1234567891011

S97T001256TS:S97T001256~AXICSA ~ICSAB00V 1CCB~2

Sample Name

ICVI0BLLSICSAICSABPREPSTDTJAPREPBLKTJAS97T001250 LS97T001250-S97T001250 DS97T001250~SS97T001250~XS97T001250~AXCCVCCBS97.T001256 LS97T001256"S97T001256 DS97TOO1256~SG9yT00X25C—XS97T001256~XS97T001256~AXICSA ~ICSABCCV 1CCB32

Sample Name

ICVICBLLSICSAICSABPREPSTDTJAPREPBLKTJAS97T001250 LS97T001250~S97T001250 DS97T001250-S

.2653104.4257.6255.15.280.0000

P

5.038-.0166.3989.0303.00314.679.002126.3526.2721.3038.3625.34424.55.022-.01106.8986.7356.96410.60

6.880105.7.0149-.01495.072-.0103

Sm

4.943.0062.2048-.0137-.02304.864-.0161-.2159-.0992-.08414.745

34.98135.2-.0059.45205.050-.0000

Pb

5.121.0338.2155.03641.0184.689.0115.7722.65381.5645.640.6814407.45.191-.00301.5901.4961.5735.768l^SO

1.627101.5.04431.0135.177.0211

Sr

4.990.0001.0207.0019.00184.878.00096.5946.4605.23213.19

-.023199.57-.0110-.01035.134.0000

S

4.937.0146.2061-.0518-.04724.827

Q.0858.8489.5496.41555.401.1073386.64.957-.0046.3205.2999.28745.003Q 347.443196.75-.0556-.03924.973.0030

Th

.1044

.0036

.0030-.0075-.0003.1011.0057.1609.0624.0602.1607

136.7233.6200.2199.35.299.0004

Sb

4.812.0043.1036.0105.01204,733.0120-.2450-.3336-.27124.648-.2326406.84.871-.0026-.0384-.0412-.02964.726

.0117100.9.0086.01034.919.0052

Ti

4.890.0000.0209.0009.00074.456.0012.0581.0529.05104.722

-.017098; 45.0003.00265.279.0033

Se ;

4.921.0217.2263.0566.02424.523.0419.6463.2486.22844.8921.210392.3

.4.987. 01!94.1298. 04:41. 05:494. 3850340.396897.36.0487.04715.029.0357

Tl ;

4.814-.0213.4106.0547.06234.558.0138-.3889-.1735-.12114.250

.6786100.2.0053.93905.157-.0076

Si

4.897.0058.1628. 0036-.00076.584

Q2.01110.4410.299.09519.8910.58416.54.961.00167.8977.4506.39712.18 jn 117 . /]

. UJ.J / Ul

7.946108.7.0068.00184.963-.0004

U

9.606.0257.5266.0719.05189.526-.0459-.2380.1032.07129.699

W-77

334

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HNF-SD-WM-DP-254, REV. 0 Page


Analyst: jds Instrument: CARB2 Book#

Method: lftiAZ~lOO Rev/Mod

Worklist Comment: T-201 TICTOC. RCJ

Seq Type Sample* R A Test Matrix Actual Found DL or Yield Unit

i-^ii^K'i:i'S:Kt3i#::^1 BLNK 0 STICT0C1 TOC-02 SOLID 1 6.10E+0 6.100 Ug/g

2 STD 0 ©TICTOC1 TOC-02 SOLID 3.00E+03 2.84E4-3 94.667 % Recovery

S97T001246 0 ©TICTOCl TOC-02 SOLID 3.03E+2 3.04E+2

5 SPK S97T001246 0 ©TICTOCl TOC-02 SOLID 1.00E+02 7.99E+01 79.900 % Recovery

6 SAMPLE S97T001253 0 OTICTOCl TOC-02 SOLID H/A 1.56E+02 40.000 ug/g

7-SS^;SS;;:;::j:;i;;i|;;:S!S^

7 DUP S97T001253 0 ©TICTOC1 TOC-02 SOLID 1.56E+2 1.10E+2 34.536 RPD

8 SPK S97T001253 0 ©TICTOCl TOC-02 SOLID 1.00E+02 1.06E+02 • 106.000 % Recovery





336

- HNF-SD-WM-DP-254, REV. 0 Page:

LABCORE Data Entry Template for Worklist# 18896Analyst:


Instrument: CARB2

Worklist Comment: T-201 TICTOC. RCJ

S Type

1 BUNK

2 STD

3 SAMPLE

4 DUP

5 SPK

6 SAMPLE

7 DUP

8 SPK

Sample* R A Test

STICTOC1

©TICTOCl

S97T001246 0 aTICTOClAnalytes Requested: TIC-02

S97T001246 0

S97T001246 0

(STICTOCl

@TICTOC1

S97T001253 0 @TICTOC1Analytes Requested: TIC-02

S97T001253 0

S97T001253 0

OTICTOC1

. (8TICTOC1

Matrix

SOLID

SOLID

SOLID, TOC-02

SOLID

SOLID

SOLID, TOC-02

SOLID

SOLID

Grouptt Project

97000311 T-201

97000311 T-201


Date



337

HNF-SD-Wy-DP-254, REV. 0WORKBOOK PAGE: BLANK1TIC/TOC : LA-342-100 (E-0) SOLIDS

TypeBLNK

Work List18896

- Test Code@TICTOC1

MatrixSOLID

Batch Number97002975

Rerun0

Sample PrepN/A

Sample*

Instrument CodeCARB1

Prepared ByLCM

ChemistRWS

AnalystJDS

Date Complete07/09/97

Analysis Date07/02/97

Analysis Time05:00 PM

Sample PointT-201

Sample Size in g (SS)Dilution Factor (DF)

ug of Carbon in Sample (C1)ug of Carbon from Baseline (C2)

ug of Carbon = |C1-C2|

Method Detection Limit in ug/g

ug of Carbon

TIC0.0000

•• • . • ' . > : • . • ' . - : i . '

10.29.8

TIC

5

4.00E-01

TOC0.0000

> v ' ;;... .-. 1

36.430.3

TOC

40

6.10E+00

hnterea by.ISignature ot Chemist: Date: ~7/l4 /H 7BLANK.WB1 REV 1.0

I:\342100\OUT\TT18896.WB1

33S

07/09/97 17:16:04


WORKBOOK PAGE: STD2

TIC/TOC : LA-342-100 (E-0) LIQUIDSTypeSTD

Work List18896

Test Code©TICTOC1

MatrixLIQUID


Rerun0

Sample PrepN/A

Sample #


Prepared ByLCM

ChemistRWS

AnalystJDS




Sample PointT-201

Sample Size in mL (SS)Dilution Factor (DF)

Final Coulometer Reading in ug (C1)ug of Carbon from Baseline (C2)

Standard Book NumberStandard Value (ug/ml)

QC Actual in ug/mL = Standard Value (ug/mL)

QC Found in ug/mL = (C1 - C2) * DF / SSQC Found in ug/mL for TIC = 5 if C1 < C2

QC Found in ug/mL for TOC = 40 if C1 < C2

% Recovery = QC Found / QC Actual * 100

Method Detection Limit in ug/mLQC Actual in ug/mLQC Found in pg/mLPercent Standard Recovery

TIC 1 TOC1.0000

1

557.19.8

25N12A602

0.20001

598.330.3

26N12A3000

TIC

56.02E+025.47E+02

90.9

TOC

403.00E+032.84E+03

94.7

Huaia Entered ay: uate: cr/7uy/y/lltjignature ot Chemist: Date: -7/{4-/37STANDARD.WB1 REV 1.0

I:\342100\OUT\TT18896.WB1

33907/09/97 17:16:36


WORKBOOK PAGE: S

TIC/TOC : LA-342Type

SAMPLE

Work List18896

Test Code©TICTOC1

MatrixSOLID


Rerun0

Sample PrepN/A

Sample #S97T001246


Prepared ByLCM

ChemistRWS

AnalystJDS




Sample PointT-201

AM3

-100 (E-0) SOLIDSSample Size in g (SS)Dilution Factor (DF)

Mg of Carbon in Sample (C1)(jg of Carbon from Baseline (C2)

|jg of Carbon/g = (C1-C2) * DF / SS|jg of Carbon/g for TIC = 5 if C1 < C2

ug of Carbon/g for TOC = 40 if C1 < C2


ug of Carbon/g

TIC

0.06231

61.49.8

TOC

0.06231

49.230.3

TIC

5

8.28E+02

TOC

40

3.03E+02

Data Entered By: LQM Date: 07/09/97

Signature of Chemist: S2l I) Date: ~7/\4/c{7SAMPLE.WB1 REV 1.0

I:\342100\OUT\TT18896.WB1340

07/09/97 17:17:06

WORKBOOK PAGE: D

TIC/TOC : LA-342TypeDUP

Work List18896

Test Code©TICTOC1

MatrixSOLID


Rerun0

Sample PrepN/A

Sample #S97T001246


Prepared ByLCM

ChemistRWS

AnalystJDS




Sample PointT-201

HNF-SD-WM-DP-254, REV. 0UP4

-100 (E-0) SOLIDSSample Size in g (SS)Dilution Factor (DF)

|jg of Carbon in Sample (C1)ug of Carbon from Baseline (C2)

Known ug of C from Original Sample

ug of Carbon/g = (C1-C2) * DF / SSug of Carbon/g for TIC = 5 if C1< C2



ug of Carbon/g

TIC

0.30511

251.19.8

8.28E+2

TOC

0.30511

12330.3

3.03E+2

TIC

5

7.91 E+02

TOC

40

3.04E+02

Data Entered By:

Signature of Chemist: PulSU^LCM Date:

Date:

07/09/97

7/Af/47SAMPLE.WB1 REV 1.0

l:\342100\OUT\TT18896.WB1 07/09/97 _ - - 17:17:52

WORKBOOK PAGE: SPIKE5

TIC/TOC : LA-342-100 (E-0)


SOLIDSTypeSPK

Work List18896

Test Code©TICTOC1

MatrixSOLID


Rerun0

Sample PrepN/A

Sample #S97T001246


Prepared ByLCM

ChemistRWS

AnalystJDS



Analysis Time05:00 PN1

Sample PointT-201

Sample Vial DataSample Size in g (SS)

Final Coulometer Reading in jjg (C1)Spiked Vial Data

Sample Size in g (SPK SS)Amount of Spike Std. in mL (SPK VOL)

Final Coulometer Reading in ug (C2)Spike Book Number

Spike Standard Value in ug/ml (SPK CONC)

TIC0.0623

61.4

TOC0.0623

49.2||

0.30670.500

570.225N12A

602

Percent Spike Recovery = (C2 - C1 * (SPK SS) / SS) / ((SPK CONC) *

QC Actual in ug/mL = Spike Value (ug/mL)QC Found in ug/mL = (Percent Spike Recovery)*(QC Actual) /100

QC Actual in ug/mLQC Found in ug/mLPercent Spike Recovery

TIC

6.02E+025.36E+02

89.0

0.30670.100

48226N12A

3000

(SPK VOL)) * 1

TOC

3.00E+032.40E+03

79.9

Data Entered By: LCM Date: 07/09/97

Signature of Chemist: Date:SPIKE.WB1 REV 1.1

I:\342100\OUT\TT18896.WB1 07/09/97 3 4 2 17:18::17:18:35


WORKBOOK PAGE: SAM6

TIC/TOC : LA-342-100 (E-0) SOLIDSType

SAMPLE

Work List18896

Test Code@TICTOC1

MatrixSOLID


Rerun0

Sample PrepN/A

Sample #S97T001253


Prepared ByLCM

ChemistRWS

AnalystJDS




Sample PointT-201


|jg of Carbon in Sample (C1)|jg of Carbon from Baseline (C2)

ug of Carbon/g = (C1-C2) * DF / SSIjg of Carbon/g for TIC = 5 if C1 < C2



ug of Carbon/g

TIC

0.32951

603.19.8

TOC0.3295

1

81.830.3

TIC

5

1.80E+03

TOC

40

1.56E+02


Signature of Chemist: Date: 9/14/9 7SAMPLE.WB1 REV 1.0.

l:\342100\OUT\TT18896. WB1 07/09/97 O/J T> 17:19:45


WORKBOOK PAGE: DUP7

TIC/TOC : LA-342-100 (E-0) SOLIDSTypeDUP

Work List18896

Test Code@TICTOC1

MatrixSOLID


Rerun0

Sample PrepN/A

Sample #S97T001253


Prepared ByLCM

ChemistRWS

AnalystJDS




Sample PointT-201


|jg of Carbon in Sample (C1)ug of Carbon from Baseline (C2)

Known ug of C from Original Sample

ug of Carbon/g = (C1-C2) * DF / SSug of Carbon/g for TIC = 5 if C1 < C2



ug of Carbon/g

TIC || TOC

0.31171

589.89.8

1.80E+3

0.31171

64.730.3

1.56E+2

TIC I TOC

5

1.86E+03

40

1.10E+02

Data Entered By: Date: 07/09/97

Signature of Chemist: (ZtAJ Date: ISAMPLE.WB1 REV 1.0

l:\342100\OUT\TT18896.WB1 07/09/973 4 4 17:20::17:20:26

HNFSD-WM-DP-254, REV. 0


TIC/TOC : LA-342-100 (E-0) SOLIDSTypeSPK

Work List18896

Test Code@TICTOC1

MatrixSOLID


Rerun0

Sample PrepN/A

Sample #S97T001253


Prepared By .LCM

ChemistRWS

AnalystJDS




Sample PointT-201

Sample Vial DataSample Size in g (SS)

Final Coulometer Reading in |jg (C1)Spiked Vial Data

Sample Size in g (SPK SS)Amount of Spike Std. in mL (SPK VOL)

Final Coulometer Reading in ug (C2)Spike Book Number

Spike Standard Value in ug/ml (SPK CONC)

TIC0.3295

603.1

0.23640.500

742.325N12A

602

Percent Spike Recovery = (C2 - C1 * (SPK SS) / SS) / ((SPK CONC) *

QC Actual in ug/mL = Spike Value (ug/mL)QC Found in ug/mL = (Percent Spike Recovery)*(QC Actual) /100

QC Actual in ug/mLQC Found in ug/mLPercent Spike Recovery

TIC

6.02E+026.19E+02

102.9

TOC0.3295

81.8

0.23640.100

375.226N12A

3000

(SPK VOL)) * 1

TOC

3.00E+033.17E+03

105.5


Signature of Chemist: Date: 7//4-/91SPIKE.WB1 REV 1.1

I:\342100\OUT\TT18896.WB1 07/09/97 17:21:32

HNF-SD-WM-DP-254, REV. 0TIC- TOTAL INORGANIC CARBON ANALYSIS REPORT

TICTOC REV 2.0-< « BLANK ANALYSIS > »

Sample: BASE

Sample Size =Dil Factor =Blank ID # =Blank Value =

== Reading =====123456789

10•11

12131415161718192021

. 22

Date :

1 UL1BASEN/A

Analysis Time0.511.011.502.002.503.003.504.004.505.005.506.006.507.007.508.008.509.009.50

10.0010.5011.00

07/0.2/97 Time: 07:53:43

Analyst : JD SPELLMANMin Readings = 2 2Max Readings = 2 2% Difference = 10

===== Coulometer ===== % Difference ==0.601.201.802.402.802.903.403.704.204.605.005.505.806.306.907.307.808.208.609.009.40

• 9.80

0.0050.0033.3325.0014.293.45

14.718.11

11.908.708.009.095.177.948.705.48.6.414.884.654.44

' 4.264.08

BLANK VALUE = 9.8 micrograms carbonBLANK FACTOR = 9.8 / 10.99799 = +8.9E-01 ug/min Carbon

SIGNATURE BELOW REPRESENTS CHEMICAL TECHNOLOGIST/CH£MtST THAT,CGMPLETED/VEFttFIED THE CALI8RATI0N/ANALYSIS ON PAGES,;

Sample Run By:aim

3 4 6

Sample: BASE

HNF-SD-WM-DP-254, REV. 0TOC- TOTAL ORGANIC CARBON ANALYSIS REPORT

TICTOC REV 2.0< « BLANK ANALYSIS > »

Date:


Reading ====123456789

10111213141516171819202122

1 UL1BASEN/A

Analysis Time0.511.011.512.002.503.003.504.004.505.005.506.00'6.507.007.508.008.509.00 •9.50 .

10.0010.5011.00

07/02/97 Time: 08:37:59


=== Coulometer ==== % Difference ==1.703.708.30

14.0017.6020.0021.2022.5023.4024.0024.4025 .0025.6026.00

. 26.4027.4027.9028.4028.9029.4029.9030.30

0.0054.0555.4240.7120.4512.005.665.783.852.501.642.402.341.54 .

' • 1.52

3.651.791.761.731.701.671.32

BLANK VALUE = 3 0.3 micrograms carbonBLANK FACTOR = 30.3 / 10.99799 =. +2.76E+00 ug/min Carbon

<<<< WARNING - BLANK VALUE EXCEEDS 1.5 ug/min Carbon!!!!!>>>>

Sample Run By:JD SPELLMAN 11111

347


TICTOC REV 2.0

Sample: STD


== Reading ====123456789

10111213141516 .171819202122

Date: 07/02/97

1 uL1

.89 ug/minute C

Analysis Time ====0.511.011.512.002.503.003.504.004.505.005.506.006.507.007.508.008.509.009.50

10.0010.5011.00

Time: 08:51:00

Analyst : JD SPMin Readings = 2 2Max Readings = 2 2% Difference = 10

Coulometer ==== % Difference0.609.40

109.90265.80406.50481.30521.60539.40546.00548.50549.80550.80551.70552.30553.00553.70554.30555.10555.50556.00556.60557.10

0.0093.6291.4558.6534.6115.547.733.301.210.460.240.180.160.110.130 .130.110.140.070.090.110.09

USER INPUT BLANK VALUEBLANK VALUE = 9.788207 micrograms carbonBLANK FACTOR = 9.788207 / 10.99799 =

SAMPLE RESULTS:( 557.1 - 9.789022 )(1)/(1)( 557.1 - 9.789022 )(!)/(!)(12) =

+8.9E-01 ug/min Carbon

+5.473E+02 g/L Carbon+4.561E+01 Molar Carbon


348

HNF-SD-WW-DP-254, REV. 0TOC- TOTAL ORGANIC CARBON ANALYSIS REPORT

TICTOC REV 2.0

Sample: STD Date: 07/02/97 Time: 09:11:12

Sample Sxze =Dil Factor =Blank ID # =Blank Value =

== Reading =====123

. 4S6789

10111213141516171819202122

1 uL1

2.76 ug/minute C

Analysis'Time ====0.511.011.512.002.503.003.504.004.505.005.506.006.507.007.508.008.509.009.50

10.0010.5011.00

Analyst :Min ReadingsMax Readings% Difference

JD SP= 22= ' 22= 10

Coulometer ==== % Difference1.70

14.10197.50458.20545.40573.90583.20587.00588.80589.70590.80591.90592.50.593.50594.30594.80595.50596.00596.70597.20597.70598.30

0.0087.9492.8656.9015.994.971.590.650.310.150.190.190.100.170.130.080.120.080.120.080.080.10

USER INPUT BLANK VALUEBLANK VALUE = 30.35444 micrograms carbonBLANK FACTOR = 30.35444 / 10.99799 = +2.8E+00 ug/min Carbon

SAMPLE RESULTS:( 598.3 - 30.3568 )(1)/(1) = +5.679E+02 g/L Carbon( 598.3 - 30.3568 )(1)/(1)(12) = +4.733E+01 Molar Carbon« « WARNING - BLANK VALUE EXCEEDS 1.5 ug/min Carbon! !!!!>>»


349

HMF-SD-WM-DP-254, REV. 0TIC- TOTAL INORGANIC CARBON ANALYSIS REPORT

- TICTOC REV 2.0

Sample: BLK


== Reading ====. 123456789

10111213141516171819202122

Date

1 UL1

.89 ug/minute

Analysis Time0.511.011.512.042.543.043.544.044.545.045.546.046.547.037.538.038.539.039.53

10.0310.53 .11.03

Time: 09:29:04


Coulometer ===0.600.901.401.902.302.703.303.804.204.705.205.606.106.507.107.607.908.408.809.309.80

10.20

= % Difference0.00

33.3335.7126.3217.3914.8118.18

. 13.169.52

10.649.627.148.206.158.456.583.805.954.555.385.103.92

USER INPUT BLANK VALUEBLANK'VALUE = 9.788207 micrograms carbonBLANK FACTOR = 9.788207 / 10.99799 =

SAMPLE RESULTS:( 10.2 - 9.818301 )(1)/(1)( 10.2 - 9.818301 )(!)/(!) (12) =


+3.82E-01+3.18E-02

g/L CarbonMolar Carbon


350


TICTOC REV 2.0

Sample: BLK Date: 07/02/97 Time: 09:43:34

Sample Size =Dil FactorBlank ID'# =Blank Value =

== Reading =====123456789

1011121314151617.1819202122

1 uL1

2.76 ug/minute C

Analysis Time ====0.511.011.512.002.503.003.504.004.50 .5.005.506.006.507.007.508.008.509.009.50

10.0010.5011.00


JD SP= 22= 22= 10

Coulometer ===== % Difference0.501.001.305.9014.1020.2023.1025.0027.002a.2029.2030.1031.2031.6032.3032.9033.8034.2034.9035.4036.1036.40

0.0050.0023.0811 .SI58.1630.2012.557.607.414.26.3.422.993.531.272.171.822.661.172.011.411.940.82

. USER INPUT BLANK VALUEBLANK VALUE = 30.35444 micrograms carbonBLANK FACTOR = 30.35444 / 10.99799 = +2.8E+00 ug/min Carbon

SAMPLE RESULTS:( 36.4 - 30.35444 )(1)/(1) = +6.05E+00 g/L Carbon( 36.4 - 30.35444 )(1)/(1)(12) = +5.04E-01 Molar Carbon<<<< WARNING - BLANK VALUE EXCEEDS. 1.5 ug/min Carbon!!!!!>>>>


351


TICTOC REV 2.0

Sample: S97S97T001246 Date: 07/02/97 Time: 10:58:48


Reading =====123456789

10111213141516171819202122

1 uL1 •

.89 ug/minute C

Analysis Time ===0.511.011.502.002.503.003.504.00 .4.505.005.506.00 .6.507.007.508.008.509.009.50

10.0010.5011.00


JD SP= 22= 22= 10

= Coulometer ===== % Difference0.601.505.7016.4028.9039.0044.7048.5051.2052.7054.1055.0055.9056.6057.4058.2058.6059.2059.7060.4060.9061.40

0.0 060.0073.6865.2443.2525.9012: 757.845.272.852.59' 1.641.611.241.391.370.681.010.841.160.820.81


SAMPLE RESULTS:( 61.4 - 9.788968 )(1)/(1)( 61.4 - 9.788968 )(!)/(!) (12) =


+5.16E+01+4.30E+00



352


TOC- TOTAL ORGANIC CARBON ANALYSIS REPORTTICTOC REV 2.0

Sample: S97T001246 Date: 07/02/97 Time: 11:19:33

Sample Size =Dii FactorBlank ID # =Blank Value =

Reading ====123456789

10• ii

1213141516171819"202122

1 uL1

2.76 ug/minute C

Analysis Time ====0.511.011.512.002.503.003.504.004.505.005.506.00'6.507.007.508.008.509.009.50

10.0010.5011.00


JD SP= 22= 22= 10


13.0024.2030.1033.6036.2038.0039.3040.6042.0042.6043.6044.5045.1045.7046.4047.4047.4048.1048.6049.20

0.0094.8770.0046.2819.6010.427.184.743.313.203.331.412.292.021.331.311.512.110.001.461.031.22

USER INPUT BLANK VALUEBLANK VALUE = 30.35444 mxcrograms carbonBLANK FACTOR = 30.35444 / 10.99799 = +2.8E+00 ug/min Carbon

SAMPLE RESULTS:( 49.2 - 30.35175 )(1)/(1) = +1.88E+01 g/L Carbon( 49.2 - 30.35175 )(1)/(1)(12) • ' . +1.57E+00 Molar Carbon<<<< WARNING - BLANK VALUE EXCEEDS 1.5 ug/min Carbon!!!!!>>>>


35a


TICTOC REV 2.0

Sample: S97T001246DUP Date: 07/02/97 Time: 11:32:43


Reading =====123456789

10111213141516171819202122

1 uL1

.89 ug/minute C

Analysis Time ===0.511.011.502.002.503.003.504.004.505.005.506.006.507.007.508.008.509.009.50

10.0010.5011.00


JD SP= 22= 22= 10

= Coulometer ==== % Difference0.801.505.00

18.8049.3096.70

149.90189.70218.70233.10239.50242.10244.10245.20246.00246.90247.90248.30249.10249.90250.60251.10

0.0046.6770.0073.4061.8749.0235.4920.9813.266.182.671.070.820.450.330.360.400.160.320.320.280.20


SAMPLE RESULTS:( 251.1 - 9.788098 ) (1)/(1)( 251.1 - 9.788098 )(!)/(!) (12) =




354


TICTOC REV 2.0



Reading ====123456789

10111213141516171819202122

1 UL1

2.76 ug/minute C

Analysis Time ====0.511.011.512.002.50

.3.003.504.004.505.005.506.006.507.007.508.008.509.009.50

10.00. 10.5011.00


JD SP= 22= 22= 10


17.0042.9064.3078.2087.0093.2098.60

103.00106.10109.30111.90114.20116.60 • .117.60118.50119.50120.40121.20122.20123.00

0.0092.3161.7660.3733.2817 .7710.116.655.484.272.922.932.322.012.060.850.760.840.750.660.820.65


SAMPLE RESULTS:( 123 - 30.35175 )(1)/(1) = +9.265E+01 g/L Carbon( 123 - 30.35175 )(1)/(1)(12) = +7.721E+00 Molar Carbon< « < WARNING - BLANK VALUE EXCEEDS 1.5 ug/min Carbon! !!!!>>»


355


TICTOC REV 2.0

Sample: S97T001246SPK Date: 07/02/97

Sample Size =Dil FactorBlank ID # =Blank Value =

Reading ====123456789

1011121314.1516171819202122

1 uL1

.89 ug/minute

Analysis Time0.511.011.512;002.503.003.504.004.505.005.506.006.50

. 7.007.508.008.509.009.50

10.0010.5011.00

Time: 13:44:04


Coulometer ===1.70

21.70109.50220.70320.30399.60462.30505.80534.70548.60554.90558.40560.60562.10563.50564.80565.90566.80567.70568.90569.40570.20

= % Difference0.00

92.1780.18

• 50.3931.1019.8413.568.605.402.531.140.630.390.27

• . 0.250.230.190.160.160.210.090.14

USER INPUT BLANK VALUE .BLANK VALUE = 9.788207 micrograms carbonBLANK FACTOR = 9.788207 / 10.99799 =

SAMPLE RESULTS:( 570.2 - 9.788968 )(1)/(1)( 570.2 - 9.788968 )(!)/(!)(12) =


+5.604E+02+4.670E+01



356





Reading ====123456789

10111213141516171819202122

1 UL1

.2.76 ug/minute C

Analysis Time ====0.511.011.512.002.503.003.504.004.505.005.50 '

e.oo• 6.50

7.007.508.008.509.009.50

10.0010.5011.00

Coulome1.60

39.20122.00256.90339.10373.40391.60405.00416.10425.10432.40439.80446.00451.80456.70461.30466.00470.10474.10477.10479.60482.00

Time: 13:57:04


;er ===== % Difference ==0.00

95.9267.8752 . 5124.249.194.653.312.672.121.691.681.391.281.071.001.010.870.840.630.520.50


SAMPLE RESULTS:( 482 - 30.3568 )<1)/(1). = +4.516E+02 g/L Carbon( 482 - 30.3568 ) (1)/(1) (12) = +3.764E+01 Molar Carbon« « WARNING - BLANK VALUE EXCEEDS 1.5 ug/min Carbon! !!!!»»

Sample Run By:JD SPELLMAN 11U1

357


TIC- TOTAL INORGANIC CARBON ANALYSIS REPORTTICTOC REV 2,0



Reading ====123456789

10111213141516171819202122

1 uL1

.89 ug/minute C


JD SP= 22= 22= 10

Analysis Time ===== Coulometer ==== % Difference0.511.011.512.002.503.003.504.004.505.005.506.006.507.047.548.048.549.049.53

10.0310.5311.03

1.102.5015.6094.40

243.40384.20484.20541.20569.40582.70588.50591.80594.10595.70596.90598.10599.10600.00600.60601.50602.20603.10

0.0056.0083.9783.4761.2236.6520.6510.534.952.280.990.560.390.270.200.200.170.150.100.150.120.15


SAMPLE RESULTS:( 603.1 - 9.819931 )(1)/(1)( 603.1 - 9.819931 )(!)/(!) (12) =




358


TICTOC REV 2.0



Reading ====1 •

23456789

10111213141516171819202122

1 UL1

2.76 ug/minute C

Analysis Time =====0.511.011.502.002.503.003.504.004.505.005.506.006.507.007.508.008.509.009.50

10.0010.5011,00

Analyst : JD SPMin Readings = 2 2Max Readings = 2 2% Difference = 10

Coulometer ===== % Difference0.402.709.30

20.2035.7047.7055.5060.6064.4066.5069.0070.8072.4073.7075.4076.3077.3078.4079.3080.4081.0081.80

0.0085.1970.9753.9643.4225.1614 . 058.425.903.163.622.542.211.76

• • 2.25

1.181.291.401.131.370.740.98


SAMPLE RESULTS:( 81.8 - 30.35175 )(1)/(1) = +5.14E+01 g/L Carbon( 81.8 - 30.35175 )(1)/(1)(12) = +4.29E+00 Molar Carbon« « WARNING - BLANK VALUE EXCEEDS 1.5 ug/min Carbon!! !!!»>>


359


TICTOC REV 2.0



Reading ====123456789

101112131415161718192021

. 22

1 uL1

.89 ug/minute C

Analysis Time ===0.511.011.512.002.503.003.504.004.505.00-5.506.006.507.007.508.008.509.009.50

10.0010.5011.00


JD SPELLMAN= 22= 22= 10

= Coulotneter ==== % Difference ==0.601.40

16.4096.40

230.90374.20472.70531.60560.50572.60577.40580.00581.90583.10584.30585.10586.00586.80587.50588.30589.00589.80

0.0057.1491.4682.9958.2538.3020.8411.085.162.110.830.450.330.210.210.140.150.140.120.140.120.14


SAMPLE RESULTS:(.589.8 - 9.788968 )(1)/(1)( 589.8 - 9.788968 )(!)/(!) (12) =




360,




Sample Size =D.il FactorBlank ID # =Blank.Value =

Reading ====123456789

10111213141516171819202122

1 UL1

2.76 ug/minute C

Analysis Time ====0.511.011.512.002.503.003.504.004.505.005.506.006.507.007.508.008.509.009.50

10.0010.5011.00


JD SP= 22= 22= 10

Coulometer ==== % Difference0.701.203.6012.1024.8034.3039.2043.7046.3050.4053.1054.2055.8056.8058.3059.2060.2061.2062.3062.9063.9064.70

0.0041.676S.6770.2551.2127.7012.5010.305.628.135.082.032.871.762.571.521.661.631.770.951.561.24

USER INPUT BLANK VALUEBLANK VALUE = 3 0.35444 micrograms carbonBLANK FACTOR = 30.35444 / 10.99799 = +2.8E+00 ug/rain Carbon

SAMPLE RESULTS:( 64.7 - 30.35697 )(1)/(1) = +3.43E+01 g/L Carbon( 64.7 - 30.35697 )(1)/(1)(12) = +2.86E+00 Molar Carbon<<<< WARNING - BLANK VALUE EXCEEDS 1.5 ug/min Carbon!!!!!>>>>

Sample Run By:JD SPELLMAN

361

inn


TIC- TOTAL INORGANIC CARBON ANALYSIS REPORTTICTOC REV 2.0

Sample: S97T001253SPK Date: 07/02/97 Time: 15:57:37


Reading ====123456789

10111213141516171819202122

1 UL1

.89 ug/minute C

Analysis Time ====0.511.011.512.002.503.003.504.004.505.005.506.006.507.007.508.008.509.009.50

10.0010.5011.00


JD SE= 22= 22= 10

Coulometer ==== % Difference83.30

340.90560.90670.00708.10720.50724.90726.70728.00729.70730.90732.20732.90734.30735.30 • •736.40737.40738.40739.40740.40741.50742.30

0.0075.5639.2216.285.381.720.610.250.180.230.160.180.100.190.140.150.140.140.140.140.150.11


SAMPLE RESULTS:( 742.3 - 9.788098 )(1)/(1)( 742.3 - 9.788098 )(!)/(!) (12) =




362

HNF-SD-WM-DP-254, REV. 0TOC- TOTAL ""ORGANIC CARBON ANALYSIS REPORT

TICTOC REV 2.0



Reading ====123456789

101112131415IS171819202122

1 UL1

2.76 ug/minut

Analysis Time0.511.011.502.002.503.003.50

.4.004.505.005.506.006.507.007.508.00

. 8.509.009.50

10.0010.5011.00

Time: 16:10:53

Analyst : JD SPELLMANMin Readings = 2 2Max Readings = 2 2% Difference = 1 0

Coulometer ===== %37.20118.10246.40316.70340.60348.60352.80356.20358.40360.30362.00363.60365.10366.40367.70 • .369.00369.60370.80371.80372.80374.00375.20

Difference0.00

68.5052.0722.207.022.291.190.950.610.530.470.440.410.350.350.350.160.320.270.270.320.32


SAMPLE RESULTS:( 375.2 - .30.35394 ) (1) / (1) = +3 ..448E+02 g/L Carbon( 375.2 - 30.35394 )(1)/(1)(12) = +2.874E+01 Molar Carbon<<<< WARNING - BLANK VALUE EXCEEDS 1.5 ug/min Carbon!!!!!>>>>


363


RADIOCHEMICAL ANALYSES

3 6 4

worklistrad Version 1.005/09/9605/27/9709:25

HNF-SD-WM-DPPage;


LABCORE Completed RadChem Report for Worklist#: 18267

Analyst: dpb Instrument: AB16 Book#

Method: Rev/Mod

Worklist Comment: T201, ©ALPHAOl, S.S. by Ludlum. Std=1.0mL skm

SeqType Sample* R A "TST Matrix Actual Found DL or Yield Unit

SIB

STD

SOU

BLNK

SAMPLE

SAMPLE

DUP

EOS

SAMPLE

SAMPLE

POP

DPP

S97T00083'

S97TO0Q83

3975:00083

S97T000831

S97T00083'

S97T000S3

S9.7TO.0&83'

0

0

00

0

00

D

00

0

©ALPHAGl

©ALPHA01

©ALPHA01

VAiJfQitU X

©ALPHA01

ffiWCPSAOl&ALPHA01

»ALPEA019ALPHA01

«ALPBA01

AiPHAOl

ALPffiWl

teems

LIQOTDALPBA01E LIQUID

ALPHAOiE

ALPHAO1

ALPHA01

AX.PSAOXE

ALPHA01

ALPHA.OJ.E

W W W

LIQUID

LIQUID

LIQUIDLIQUID

I.IQUIOLIQVID

LIQUID

2.00E-04

X

1.00

X.OOE-fOO

<3.46E-51^00

H/A <

S/A

<S.55B-S

i.oo

1.65E-4

7-fiSE-S

1.03E+02

3.97E+00

S.OOE+02

<6.26E-5

S.OOE+02

5.59E-05

5.00E+02<7.61B-5

§ 0OBtP2

82.. 500

103.000

2.370

<i.0e+000

500*000

847.0e-007

O.OQ+000

500 fOO

% Reco

uCi/mL

uCi/nL

% Ct.RPD

% Ct.

uCi/mL

% Ct.EPD



Reviewer signature Date


3 S S

05/23/97 07:1SA-0004-1

F-SD-WM-DP-254, REV. 0-HNF SD-WM DP 246, n C V r ^ y ^ g - 7

for WorkliLABCORE Data Entry Template for list# 18267

Analyst: t> f 8 Instrument: ABOO Book# 1 1 BMethod: LA-508-101 Rev/Mod G~°

Worklist Comment: T201, ©ALPHAOl, S.S. by Ludlum. Std=1.0mL skm

S Type

1 STD

2 BLNK

3 BLNK/BKG

4 SAMPLE

Sample# R A Test Matrix

(8ALPHA01 LIQUID

©ALPHA01 LIQUID

SALPHAOl LIQUID

S97T000836 0 SALPHA01 LIQUIDAnalytes Requested: ALPHA01 , ALPHA01E

Group# Proj ect

5 DUP

6 SAMPLE

7 DUP

S97T000836 0 I8ALPHA01 LIQUID

S97T000837 0 ©ALPHA01 LIQUIDAnalytes Requested! ALPHA01 , ALPHA01E

97000311 T-201

97000311 T-201

S97T000837 0 ©ALPHA01 LIQUID


Analyst ojgaature ite



367


AT: LA-508-101 (E-1)

STD

SB^fWorkitiistssHMS18267

AT

fmma&tfiaiimm(BALPHA01

LIQUID

97002299S^tSSRerunSiiKi» !>

0jligsSamplsBropvi^sji

N/A

SSg^S.ampl<y{S!SM«WL18267

SMInstfumentJS.odasS,WB27806

^^^ProparddjBy^f^SEH

ggseachemistsesrstSLF

W«&naly.s««sw»DPB

K£SPa}eie,ornple,te;3RS05/26/97

^^^\na(ysijSiDatois^^05/26/97

04:40 AM

£pS?SaTOPl6{Poinjtr'l^3&T-201

LA-508-113(B-0) STANDARDDETECTOR NUMBERDISH SIZE ( 1 , 2 , or 6 ) (MS)GROSS COUNTS (GC)COUNT TIME In MINUTES (CT)BACKGROUND In cpm (BKG)SAMPLE SIZE In mL (SS)DILUTION FACTOR (DF)STANDARD BOOK NUMBER (Std BN)EFFICIENCY FACTOR (EFF)Lc, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATEStandard Value In uCi/mLconcentration in pCi/L -Replicate Concentration in uCi/L =AVERAGE CONCENTRATION in uCi/L =

Rs (Sample Count Rate) = (TC/CT) -BKGALPHA TOTAL uCi/L = Rs * 1000mUL* DF / ( EFF *

STANDARD162

301830

0.231.000

179B56

0.2683100.370

2.00E-041.69E-O11.61E-01

1.6490E-01

REPLICATE16

22889

300.23

1.0001

79B560.268336.070

SS * 2220000dpm/uCi)ALPHA TOTAL |iCMnL = ALPHA TOTAL uCi/L / 1000mL/LRelative Counting Enor = [ [{The Square Root of TC+BKG •CT) / {TC - BKG • C T ) | 1 * 1.96 MOODetection Levels and Less Than Values are determined from Procedure LA-508-002.

ALPHA TOTAL CONCENTRATION in pCi/mL = 1.65E-O4

RELATIVE COUNTING ERROR = 3.7%

DETECTION

LEVEL

8.38E-07

pCi/mL

Analyst: Date: 26-May-97

Signature of Chemist: Date:STANDARD.WB1 Rev. 1.0

3SS

-HNF-SB-WM-DP 246, REV.

WORKBOOK PAGE: BLANK2

AT: LA-508-101 (E-1) LIQUIDS

(SALPHA01

a;|nstr.ume.Dt\Cpciet5WB2780S

agAnaiysis Date-aft?05/26/97

DETECTOR NUMBER( 1 , 2 , o r 5 )

ROSS COUNTS(MS)

COUNT TIME In MINUTES(GC)

BACKGROUND In cpmSAMPLE SIZE In nlL

(BKG)

DILUTION FACTOR(SS)(DF)

DIGEST DILUTION FACTOR (DDF)EFFICIENCY FACTOR (EFF)Lc, Rmax, or Rs.lSAWPLE RATE) as APPROPRIATE

Blank Concentration In uCi/LReplicate Concentration In jiCi/LAverage Concentration In |iCi/L 7.6872E-02

HNF-SD-WM-DP-254, REV. <

Rs (Sample Count Rate) = (TC/CT) -BKGALPHA TOTAL uCi/L = Rs * 10OOmL/L • DF • DDF / ( EFF * SS * 2220000dpm/uCi)ALPHA TOTAL pCi/mL = ALPHA TOTAL uCI/L / 1000mULRelative Counting Error = [ |(The Square Root of TC + BKG * CT) / (TC - BKG * CT)| ] * 1.96 * 100Detection Levels and Less Than Vaiues are determined from Procedure LA-506-002.

ALPHA TOTAL In uCi/mL (Average)

RELATIVE COUNTING ERROR

DETECTIONLEVEL

3.47E-05HCi/mL


Signature of Chemist:

3 6 9


AT:LA-508-101!W»Typ.e»i««

SAMPLE

JSSSWfork L ls t^Sg18267

AT

jg^SSrestiCptleiW*@ALPHA01

sSsfiMatrix^fewLIQUID

ifiBatch;Numberivi.97002299

0

S&SampleJêp^sN/A

S97T000836ÎnstninientiCode^

WB27806g£%Pr$pa.rgd^Byeg&&

SEH

i P££he..mist M">SLF

«t«Analy;st««ftDPB

*S.Date;Coniplete5'*05/26/97

Ânaly.sis4DAteW05/26/97

Ânjatysis^rjme^04 40 AM

sSSampferloiotSB;T-201

(E-1) LIQUIDSDETECTOR NUMBERDISH SIZE ( 1 , 2 , or S ) (MS)GROSS COUNTS (GC)COUNT TIME In MINUTES (CT)BACKGROUND In cpm (BKG)SAMPLE SIZE in mL (SS)DILUTION FACTOR (DF)DIGEST DILUTION FACTOR _{DDF)EFFICIENCY FACTOR (EFF)Lc, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE

SAMPLE

162

430

0.231.000

1011

0.26830.204

Blank Concentration in uCi/L <Replicate Concentration In |iCi/L <Maximum Concentration in uCi/L <

3.46E-023.46E-O2

3.4646E-02

Rs (Sample Count Rate) = (TC/CT) -BKG

ALPHA TOTAL uOi/mL = ALPHA TOTAL |lOi/L / lOOOmL/LRelative Counting Error = [ |(The Square Root of TC +BKG

REPLICATE

1624

300.23

1.000101

10.2683

0.204

•CT) 1 (TO-BKG*CT)|]*1.96*100Detection Levels and Less Than Values are determined from Procedure LA-508-002.

ALPHA TOTAL in (lCi/mL (Maximum) = < 3.46E-05

LESS Than Value was Determined from Lc.

RELATIVE COUNTING ERROR 500.0%

DETECTIONLEVEL

8.47E-05liCi/mL

Analyst- Date: 26-May-97

Signature of Chemist:SAMPLE. WB1 Rev. 1.0

3 7 0


AT:LA-508-101

DUP

18267

^ggAJfOfa'B'-V^s*AT

SSSTest.Codeggs@ALPHA01

SJSSNlaJrixjSEJsSLIQUID

&BiatchiNumber$^97002299

0

^3ample^Prep"^KN/A

S97T000836^n,stru1m£nt\C,p,c(e^t

WB27S06^$f?kreparecLBy'3"££

SEH

SLFgjgj^Analysttpggjjgj

DPBs^Date Completesa

05/26/97&£A.n,aJy£is,.Date3£$

05/26/97S«iAnaiysisH.ime,»«!6

04 40 AM§£?SarQPI&R^pint5^:

T-201

(E-1) LIQUIDS3ETECTOR NUMBERDISH SIZE ( 1 , 2 , or 5 ) (MS)GROSS COUNTS (QC)COUNT TIME in MINUTES (CT)BACKGROUND in cpm (BKG)SAMPLE SIZE in mL (SS)DILUTION FACTOR (DF)DIGEST DILUTION FACTOR (DDF)EFFICIENCY FACTOR (EFF)-c, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE

Blank Concentration in uCi/L <Replicate Concentration in uCi/L <Maximum Concentration in uCi/L <

Rs (Sample Count Rate) = (TC/CT) -BKGALPHA TOTAL flOIL - Rs * 10OOmL/L * DF * DDF / ( EFIALPHA TOTAL uCi/mL = ALPHA TOTAL uCi/L / 1000mL/LRelative Counting Error = [ IfThe Square Root of TO + BKG

DUP

162

1130

0.231.000

1011

0.26830.369

6.26E-023.46E-02

6.2633E-02

REPLICATE

1624

300.23

1.000101

10.2683

0.204

*SS*2220000dpm/uCi)

•CT) / (TC-BKG*CT)|]'1,98*100Detection Levels and Less Than Values are determined from Procedure LA-508-002.

ALPHA TOTAL in uCi/mL (Maximum) = < 6.26E-05

LESS THAN Value was Determined from Rmax.


DETECTIONLEVEL

8.47E-05HCi/mL

{/ system;exit}yes~

Analyst:

Signature of Chemist:SAMPLE.WB1 Rev. 1.0 508101 ML (/

/if 1 1 DPB

SLF

Date: 26-May-97

Date: T/ZP-/1-?-

3 7 1

HNF-SD-WM-DP-254, REV. 0WORKBOOK PAGE: SAM6

DP 216, [ O . Ofl

AT : LA-508-101

SAMPLE

g^Worililsti*18267

AT»SRa7nr|nR

®ALPHA01

LIQUID

97002299oK-SifeSRerunip.jS;',,

0

N/A

S97T000837

!;ln.s.truipentcpde,jWB27806

^!ill»t$pa|${feiiXBiIjfesSEH

aapcnamfstws*-SLF

DPBKDate Complete;*:.

05/26/97

^^naiysis'.pat6^£OS/26/97

l^^aly&i^liime^t'04:40 AM

T-201

(E-1) LIQUIDSDETECTOR NUMBER0JSHSIZE ( 1 , 2 , o r 5 ) (MS)GROSS COUNTS (GC)COUNT TIME In MINUTES (CT)BACKGROUND In cpm (BKG)SAMPLE SIZE in mL (SS)

DIGEST DILUTION FACTOR (DDF)EFFICIENCY FACTOR (EFF)Lc, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE

Blank Concentration in uCi/L <Replicate Concentration in uCi/L <Maximum Concentration In uCi/L <

Rs (Sample Count Rate) = (TC/CT) -BKG

SAMPLE

162

1030

0.231.000

10.2683

0.329

5.59E-023.53E-02

5.5862E-02

REPLICATE

1627

300.23

1.000

10.2683

0.208

ALPHA TOTAL uCot = Rs • lOOOmL/L * DF • DDF / ( EFF * SS * 2220000dpm/uCi)ALPHA TOTAL uCi/mL = ALPHA TOTAL pCi/L / lOOOmL/LRelative Counting Error = [ |(The Square Root of TC + BKG * CT) / (TC - BKG * CT)| 1 * 1.96 * 100Detection Levels and Less Than Values are determined from Procedure LA-508-002.

ALPHA TOTAL in uCi/mL (Maximum) = < S.59E-0S



DETECTION

LEVEL

8.47E-05

uCi/mL

{/system;e*it}yes~

Analyst:

Signature of Chemist:SAMPLE.WB1 Rev. 1.0

Pate: 26-May-97

372

HNF-SD-WM-DP-254, REV. 0WORKBOOK PAGE: DUP7

5 -q 7

AT : LA-508-101

DUP |C

• • " • • • • • +18267 |C

AT |S

SALPHA01 |[

LIQUID |L

• • •WH97002299 IE

0 |K

(E-1) LIQUIDSETECTOR NUMBERISH SIZE ( 1 , 2 , or S )ROSS COUNTSOUNT TIME In MINUTESIACKGROUND In cpmAMPLE SIZE In mLHLUTION FACTORIGEST DILUTION FACTORFFICIENCY FACTORc, Rmax, or R»,(SAMPLE RATE) as APPROPRIATE

lank Concentration in pCI/L

laxlmum Concentration In 11CI/L

(MS)(GC)(CT|

(BKG)|SS)(DF)

(DDF)(EFF)

<

<

DUP

162S

300.23

1.000101

10.2G830.204

3.46E-02

7.6083E-02

REPLICATE

162

1330

0.231.000

1011

0.26830.449

s (Sample Count Rate) = (TC / CT) - BKGJ.PHA TOTAL uCi/L = Rs * 10OOmL/L • DF * DDF / ( EFF * SS " 2220000dpm/MCi)tLPHA TOTAL uCi/mL = ALPHA TOTAL uCi/L /10OOmL/L

e Counting Error = [ |(The Square Root of TC + BKG * CT) / (TC - BKG * CT)| ] * 1.96 * 100jDetection Levels and Less Than Values are determined from Procedure LA-508-002.

L TOTAL In uCi/mL (Maximum)


\TIVE COUNTING ERROR



373

44NF-SD WM DP-246,worklistrad Version 1.0 05/09/9605/29/9714:05

Page: 1


Analyst: scl

Method:

Instrument: AB15 Book#


Worklist Comment: T201, @ALPHA01 Deter s.s. by Ludlum. Std= l.OmL skm

Matrfc Actual Found DL or Yield UnitSeq Type Sample# R A Test

SAMPLE

SAMPLE

DUP

DOT

SAMPLE

SAMPLE

DI3P

DPP

ALPSA01 SOLID

©ALPHA01 ALPHA01E SOLID

QXUPBM1 ALPHftOi SOLID1 0 QALPHA01 ALPHA01E SOLID

0 >flI>EHAQl ALPHA01 SOLID

297T0009O1 0 F OALPHAOl ALPHA.01 SOLID

297T6Q09O1 0 I? <&ALPHA<)1 ALPttAOlB SOLID

S97T000901 0 P ©ALPHAOl ALPHAO1 SOLID

S97I0009Q1 0 V «AL»HAO1 HJHA01E SOLID

S97T000919 0 F ©ALPHA01 ALPHA01 SOLID

S97T0009IS 0 P *ALPHA0X ALPBAO1E SOLID

S97T000919 0 F ©ALPHA01 ALPHA01 SOLID

SS7TO0 095-9 O ? «AI»PHA01 ALPHA,Q1E SOLID

2.00E-041.00

2.02E-4

3.29E+00

<4.S4E-3

3.59E+02

1.76E+00

6.21E+00

6.28E-1

Ct. Erro

5.98E-01

359.000

1.760

806. Oo- 005 \iCi./g

O.Oe+QOD % Gt. Erxor

0.635 RPD

6-100 % Ct. JElWO

822.0B-005 uCi/g

O.Ge+000 % Ct. Ert-OK

5.675 BPD

6,530 % Ct. Ereo



KevieVver Signaturegiia Date


3 7 4

05/27/9708:08A-0004-1

Analyst:

SD WM DP 246, REV. jL*L


S.L __Instrument: ABOO

Rev/Mod dh -1>

/O Book#

Method: LA-508-101 Rev/Mod &,** HNF-SD-WM-DP-254, REV. 0

Worklist Comment: T201, ©ALPHAOl Deter s.s. by Ludlum. Std= LOmL skm


1 STD @ALPHA01 SOLID

2 BLNK-PREP ©ALPHA01 SOLID

3 BLHK/BKG ©ALPHA01 SOLID

4 SAMPLE S97T000901 0 F ©ALPHA01 SOLIDAnalytes Requested: ALPHA01 , ALPHA01E

Group# Project

5 DUP

6 SAMPLE

7 DUP

S97T000901 0 F ©ALPHA01 SOLID

S97T000919 0 F ©ALPHA01 SOLIDAnalytes Requested: ALPHA01 , ALPHA01E

S97T000919 0 F ISALPHA01 SOLID

97000311 T-201

97000311 T-201


(-Analyst Signature st Signature



HNF-SD-WM-DP-254, REV. 0 -44NF»SB-WM-DP-246, REV.

WORKBOOK PAGE: STD1

AT:LA-508-101 (E-1)

18294

AT

LIQUID

97002333

LA-508-113(B-0) STANDARD•DETECTOR NUMBERJDISH SIZE ( 1 , 2 , or 5 )GROSS COUNTS

JCOUNT TIME in MINUTES•BACKGROUND In cpmJSAMPLE SIZE In mL•DILUTION FACTOR(STANDARD BOOK NUMBEREFFICIENCY FACTOR

(MS)(GC)(CT)

(BKG)(SS)(DF)

(Std BN)(EFF)

ILc, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE•Standard Value in pCi/mL(Concentration in pCi/L•Replicate Concentration in uCi/LJAVERAGE CONCENTRATION in pCi/L

=

STANDARD152

369730

0.171.000

179B56

0.2701123.0S3

2.00E-042.0SE-011.98E-01

2.0170E-01

REPLICATE162

357030

0.171.000

179B560.2701

118.830

JRs (Sample Count Rate) = (TC/CTJ-BKGALPHA TOTAL uCi/L = Rs M000mL/L * DF / ( EFF * SS * 2220000dpm/(jCi)ALPHA TOTAL uCi/mL = ALPHA TOTAL pCi/L / 1000mL/L

itive Counting Error = [ |(The Square Root of TC + BKG * CT) / (TC - BKG * CT)| ] * 1.96 * 100etection Levels and Less Than Values are determined from Procedure LA-508-002.

T-201

M.PHA TOTAL CONCENTRATION in (iCi/mL 2.02E-04

&TIVE COUNTING ERROR 3.3%

Analyst: MCB Date: 29-May-97

Signature of Chemist: SLF Date:STANDARD. WB1 Rev. 1.0 508101 ML

I:\508101\OUT\18294.WB1


WORKBOOK PAGE: BIANK2

AT : LA-508-101 (E-1) SOLIDS

f BLNK-PREP

AT

I @ALPHA01

I S0LID

\ 97002333

1 0

miDETECTOR NUMBERJDISH SIZE ( 1 , 2 , or 5 )

•GROSS COUNTSCOUNT TIME in MINUTES

(SAMPLE SIZE in mL

I DIGEST GRAMS of SOLIDS / LM EFFICIENCY FACTOR

(MS)(GC)(CT)

(SS)

(Dfl/L)(EFF)

||Lc, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE

Ipiank Concentration in uCi/g^[Replicate Concentration in uCi/g

Maximum Concentration in uCi/g<<

BLNK-PREP152

1130

0.500

2.01220.27010.197

3.59E-034.64E-03

4.6432E-03

REPLICATE1527

30

0.500

2.01220.27010.255

N/A

HitWL18294

]|RS (Sample Count Rate) = (TC / CT) - BKGALPHA TOTAL uCi/g = Rs * lOOOmL/L * DF / ( EFF * SS * Dg/L * 2220000dpm/(jCi)

iRelative Counting Error = [ |(The Square Root of TC + BKG * CT) / (TC - BKG * CT)| ] * 1.96 * 100"(Detection Levels and Less Than Values are determined from Procedure LA-508-002.

M.PHA TOTAL in pCi/g (Maximum)

LESS THAN Value was Determined from Rs.

puaMH/ompleteaai05/29/97 RELATIVE COUNTING ERROR

< 4.64E-03

358.8%8.06E-03jjCi/g

05/28/97


Signature of Chemist: Date:BLANK. WB1 Kev. 1.0

I:\508101\OUTU8294.WB1377

05/29/97

NNr-SU-WM-LWORKBOOK PAGE: SAM4

AT:LA-508-101HMWHTHyffrrniiHWHH1 SAMPLE

I 18294

I AT

iiMsaJitoiije^rtlT (SALPHA01

I SOLID

JP-Z54, REV. 0 S D W f . D p 2 4 g _o

(E-1) SOLIDSDETECTOR NUMBERDISH SIZE ( 1 , 2 , or 5 ) (MS)GROSS COUNTS (GC)COUNT TIME in MINUTES (CT)BACKGROUND in cpm (BKG)SAMPLE SIZE in mL (SS)DILUTION FACTOR (DF)DIGEST GRAMS of SOLIDS / L (Dg/L)EFFICIENCY FACTOR (EFF)Lc, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE

REV-QMfc^-? l

SAMPLE152

107830

0.170.500

112.01220.270135.763

|MfeJP.WNurn&sr!!!||1 ^ 9 7 0 0 2 3 3 3

0

FUSION01

Ps97Tb60901

1 MCB

MfeEchamistMa| SLF

ISWDatetCornpJeSeS1 05/29/97

05/28/97

Blank Concentration in uCf/gReplicate Concentration in uCi/gAverage Concentration in pCi/g

Rs (Sample Count Rate) = (TC / CT) - BKGALPHA TOTAL uCi/g = Rs * 10OOmL/L * DF / ( EFF * SS

6.52E-016.12E-01

6.3204E-01

REPLICATE152

101230

0.170.500

112.01220.270133.563

* Dg/L * 2220000dpm/uCi)

Relative Counting Error = [ |(The Square Root of TC + BKG" CT) / (TC - BKG • CT)| ] * 1.96 • 100Detection Levels and Less Than Values are determined from Procedure LA-508-002.

ALPHA TOTAL in [jCi/g (Average) = 6.32E-01


DETECTIONLEVEL

8.06E-03MCi/g


Date: SVst/99-Signature of Chemist: SLFSAMPLE. WB1 Rev. 1.0 508101ML

378IA508101\Oimi 8294.WB1

HNF-SD-WM-DP-254, REV. 0 RFV

WORKBOOK PAGE: DUP5

AT:LA-508-10'

| DUPMSKtorkiLisHHSS

18294

AT

«lite?Mo.d8Ste| @ALPHA01

•HHatrixiiliSOLID

wmmimmmm97002333

o ^ ^ ^[ F U S I O N 0 1 ^ _

S97T000901

I V V B 2 6 8 7 2

[ MCB

| SLF .

SCL

05/29/97

05/28/97IHtAnalvsisyJime:^

11:40AM

r T-201

(E-1) SOLIDSDETECTOR NUMBERDISH SIZE ( 1 , 2 , or 5 ) (MS)GROSS COUNTS (GC)COUNT TIME in MINUTES (CT)

SAMPLE SIZE in mL (SS)DILUTION FACTOR (DF)DIGEST GRAMS of SOLIDS / L (Dg/L)EFFICIENCY FACTOR (EFF)Lc, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE

DUP152

104830

0170.500

112.05840.270134.763

Blank Concentration in pCi/gReplicate Concentration in |iCi/gAverage Concentration in |iCi/g

Rs (Sample Count Rate) = (TC/CTJ-BKGALPHA TOTAL (jCi/g = Rs * lOOOmL/L * DF / ( EFF * SS

6.20E-016.36E-01

6.2795E-01

REPLICATE152

107630

0170.500

112.05840.270135.697

* Dg/L * 2220000dpm/|jCi)

Relative Counting Error = [ |(The Square Root of TC + BKG • CT) / (TC - BKG * CT)| ] * 1.96 * 100Detection Levels and Less Than Values are determined from Procedure LA-508-002.

ALPHA TOTAL in |jCi/g (Average) 6.28E-01


DETECTIONLEVEL

7.88E-03MCi/g


Signature of Chemist: Date:SAMPLE.WB1 Rev. 1.0 508101 ML

3 7 9

I:\508101\OUTY18294.WB1

HNF-SD-WM-DP-254, REV. 0WORKBOOK PAGE: SAM6

AT: LA-508-101 (E-1) SOLIDS|B^gg-yP?8a^â-|,DETECT0R NUMBER[ SAMPLE

18294

I ATteHlestiCpdesfe| @ALPHA01ffllfliffi'M liiMillfîyM| SOLID

tosJctaNurn.bfisteI 97002333

I 0

teample^re.pj«

| FUSION01

I S97T000919I WB26872

I MCB

| SLF

• SCLIÊaJMCornplaiBiS| 05/29/97

ba»n.alysis.PateSF 05/28/97WKftnalvsifliHEIhifiStiBE

11:40 AMMKSaimplfeBoiiyB^| T-201

DISH SIZE ( 1 , 2 , or 5 ) (MS)GROSS COUNTS (GC)COUNT TIME in MINUTES (CT)BACKGROUND in cpm (BKG)SAMPLE SIZE in mL (SS)DILUTION FACTOR (DF)DIGEST GRAMS of SOLIDS / L (Dg/L)EFFICIENCY FACTOR (EFF)Lc, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE

Blank Concentration in uCi/gReplicate Concentration in uCi/gAverage Concentration in pCi/g

Rs (Sample Count Rate) = (TC/CT)-BKGALPHA TOTAL uCi/g = Rs * lOOOmL/L * DF / ( EFF " SS

Relative Counting Error = [ |(The Square Root of TC + BKG

SAMPLE152

94630

0.170.500

111.97280.270131.363

5.83E-016.12E-01

5.9786E-01

REPLICATE152

99330

0.170.500

111.97280.270132.930

' Dg/L * 2220000dpm/jjCi)

* CT) / (TC - BKG * CT)11*1.96 * 100Detection Levels and Less Than Values are determined from Procedure LA-508-002.

ALPHA TOTAL in pCi/g (Average) = 5.98E-01


DETECTIONLEVEL

8.22E-03IiCi/g

inalyst: Date: 29-May-97

signature of Chemist: SLF Date: S7vt nf-SAMPLE.WB1 Rev. 1.0

3 8 0

I:\508101\OUTO8294.WB1

HNF-SD-WM-DP-254, REV. 0 DP 216, REV^gfeWORKBOOK PAGE: DUP7

(E-1) SOLIDSDETECTOR NUMBERDISH SIZE J_1 , 2 , or S )GROSS COUNTSCOUNT TIME In MINUTESBACKGROUND In cpmSAMPLE SIZE In mLDILUTION FACTORDIGEST GRAMS of SOLIDS / LEFFICIENCY FACTOR

(MS)(GC)(CT)

(BKG)(SS)(DF)

(Dg/L)(EFF)

Lc, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE

Blank Concentration In uCi/gReplicate Concentration In uCi/gAverage Concentration in uCi/g

DUP152

96130

0.170.500

112.01320.270131.863

5.81 E-015.50E-01

5.6521 E-01

REPLICATE152

91030

0.170.500

112.01320.270130.163

(Sample Count Rate) = (TC / CT) - BKGPHA TOTAL uCi/g = Rs * 1000mL/L * DF / EFF * SS * Dg/L • 2220000dpm/uCi)

Native Counting Error = [ |(The Square Root of TC + BKG * CT) / (TC - BKG " CT)| ] * 1.96 * 100itection Levels and Less Than Values are determined from Procedure LA-508-002.

HA TOTAL in (jCi/g (Average) 5.65E-01 DETECTIONLEVEL

LATIVE COUNTING ERROR 6.6%8.05E-03

MCi/g

Analyst: Al It SCL Date: 29-May-97

Signature of Chemist: T^ SLF Date:SAMPLE.WB1 Rev. 1.0

3 8 1l:\50ai01\OUTMS294.WB1

worklistrad Version 1.0 05/09/9605/29/9712:57

0, REV,


Analyst: scl

Method: Rev/Mod



Worklist Comment: T201, @ALPHA01 S.S. by Ludlum. Std=1.0mL, Spk=0.1mL skm


SID

STD

BLKK-PRBP

BLNK-PREP

BLNK/BKG

SAMPLE S97T000920

S97TOQQS20

S97T000920

S97T000920

S97T000920

SAMPLE

DUP

DOT

ALPSAOi SOLIU

0 ©ALPHA01 ALPHA01E SOLID

0 SALPHA01 ALPSA01 SOLID

0 ©ALPHA01 ALPHA01E SOLID

0 9XUBS&01 AL5SA01 SOLID

0 F OALPHA01 ALPHA01 SOLID

0 f SALPHAOl ALPHA01E SOLID

0 F 0ALPHAO1 ALPHA01 SOLID

0 F 0ALE-HAO1 ALPHA02B SOLID

0 F 9ALPHA01 ALPHA01 SOLID

2,002-04

1.00 3.41E+00

3.4SE-3

1.38E+02

2.44E4-Q0

1.15E+00

4.60B+00

9.66E-1

4.96E+00

2.12E-02

94.000

3.410

34.5006-004

138.000

2.440

735.0e-005

O.Oe+QQO

% Ct. Erro

uCi/g

BLHK/SKG

uCi/g

% Ct. Bwwr

80.608 % Recovery



J7«to shown for QC (BLK/BKG) may not reflect the actual units.

382

05/27/970&09 -HNF SB ^ ^ ^

"""•' LABCORE Data Entry Template for Worklist# 18295

Analyst: s.U Instrument: ABOO II Booltf

Method: LA-508-101 Rev/Mod 6r~o HNF-SD-WM-DP-254, REV. 0

Worklist Comment: T201, ©ALPHA01 S.S. by Ludlum. Std=1.0mL, Spk=0.1mL skm

S Type Sample# R A Test Matrix Group# Project

1 STD • OALPHA01 SOLID

2 BLNK-PREP (SALPHA01 SOLID

3 BLNK/BKG SALPHA01 SOLID

4 SAMPLE S97T000920 0 F OALPHA01 SOLID ' 97000311 T-201

Analytes Requested: ALPHA01 , ALPHA01E

5 DUP S97T000920 0 F (8ALPHA01 SOLID

6 SPK S97T000920 0 F ©ALPHAOl SOLID


Analyst Signature Date • Anajyst Signature _ / Date



3 8 3

HNF-SD-WM-DP-254, REV. 044NF SD-WM-DP-246, REV. 0

WORKBOOK PAGE: STD1

AT : LA-508-101 (E-1)

STD

LA-508-113 (B-0) STANDARDDETECTOR NUMBERDISH SIZE

ATiPoflrtSBBBi DILUTION FACTOR

@ALPHA01

N/A

WL18295

szc

1,2 , or 5 )COUNTS

(MS)(GC)

COUNT TIME in MINUTESBACKGROUND in cpm

(CT)(BKG)

SAMPLE SIZE in mL (SS)

STANDARD BOOK NUMBER(DF)

(StdBN)EFFICIENCY FACTORLc, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE

(EFF)

Standard Value in uCi/mLConcentration in uCi/L

345630

0.2692115.070

2.00E-04

Replicate Concentration in uCi/LAVERAGE CONCENTRATION in uCi/L 1.8845E-01

300.13

79B56I0.2692

110.1701

Rs (Sample Count Rate) = (TC / CT) - BKGALPHA TOTAL uCi/L = Rs * 10OOmL/L * DF / ( EFF * SS * 2220000dpm/uCi)ALPHA TOTAL uCi/mL = ALPHA TOTAL uCi/L / lOOOmL/LRelative Counting Error = [ |(The Square Root of TC + BKG * CT) / (TC - BKG * CT)| ] * 1.96 * 100Detection Levels and Less Than Values are determined from Procedure LA-508-002.

ALPHA TOTAL CONCENTRATION in MCi/mL DETECTIONLEVEL

VE COUNTING ERROR 3.4%6.66E-07MCi/mL

02:30 PM

T-201

Analyst: Date: 29-Mav-97

Signature of Chemist: Date: S~/Z1 /^9-STANDARD.WB1 Rev. 1.0 508101ML '

3 8 4I:\508101\OUT\18295.WB1

__. , . . „ „ __UMC.on.\A/UJiD.O/l«WORKBOOK PAGE: BLANK2

AT: LA-508-101

BLNK-PREP

18295

AT

@ALPHA01Sg^S§Mairix<Sj?3pg>

SOLIDKB.atchJNurnbefll

97002334

0S^Samp,(e';,I?rep$gii

N/Agggg^SaitjpJgj^Kig^WL18295Jslns.trurnen.ttCp.deg

WB27807^^Rreparejd^y^^

szc^{^ChemistgiisSiii

SLF

Hî">fAn'aly.stf;Sg^SCL

i&DateiCompleteigj05/29/97

Ânalysis, afegi^05/28/97

jgÂnalysisjTimelgS02:30 PM

^Satppteôinti^T-201

(E-1) SOLIDSDETECTOR NUMBERDISH SIZE ( 1 , 2 , or 5 ) (MS)GROSS COUNTS (GC)COUNT TIME in MINUTES (CT)BACKGROUND in cpm (BKG)SAMPLE SIZE in mL (SS)DILUTION FACTOR (DF)DIGEST GRAMS of SOLIDS / L (Dg/L)EFFICIENCY FACTOR (EFF)Lc, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE

Qc\/ n Wtf?

BLNK-PREP

142

1030

0.130.500

111.99240.26920.203

Blank Concentration in pCi/gReplicate Concentration in uCi/gAverage Concentration in |jCi/g

Rs (Sample Count Rate) = ( T C / C T ) - B K G

3.76E-033.14E-03

3.4489E-03

REPLICATE

1429

300.13

0.50011

1.99240.2692

0.170

ALPHA TOTAL uCi/g = Rs * lOOOmL/L * DF / ( EFF * SS * Dg/L * 2220000dpm/uCi)

Relative Counting Error = [ |(The Square Root of TC + BKG * CT) / (TC - BKG * CT)| ] * 1.96 * 100Detection Levels and Less Than Values are determined from Procedure LA-508-002.

ALPHA TOTAL in [iCi/g (Average) 3.45E-03


DETECTIONLEVEL

7.35E-03(iCi/g

Analyst: l$Cl Date: 29-May-97

Signature of Chemist: SLF Date:BLANK;WBI Rev. 508101 ML

l:\508101\OUT\18295. WB1

38505/29/97 12:57:19

HNF-SD-WM-DP-254, REV. 0 -HNE-SB-WM-DP 246, REV.WORKBOOK PAGE: SAM4

AT : LA-508-101 (E-1) SOLIDS

SAMPLE

ALPHA01

SOLID

FUSION01

SBE&SS97T000920

WB27807

szc

DETECTOR NUMBERDISH SIZEGROSS COUNTS

1 , 2 , o r 5 ) JMSj

COUNT TIME in MINUTES(GC)

ACKGROUND in cpmJCJi

SAMPLE SIZE in mL(BKG)

(SS)DILUTION FACTOR (DF)DIGEST GRAMS of SOLIDS / L (Dg/L)EFFICIENCY FACTORLc, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE

(EFF)

SAMPLE14

182430

0.130.500

111.99240.269260.670

Blank Concentration in uCifgReplicate Concentration in uCi<g 1.18E+00Average Concentration in pCi/g

REPLICATE

192430

0.130.500

1.99240.269264.003

Rs (Sample Count Rate) = (TC / CT) - BKGALPHA TOTAL uCi/g = Rs * 10OOmUL * DF / (EFF * SS * Dg/L * 2220000dpm/uCi)

Relative Counting Error = [ |(The Square Root of TC + BKG * CT) / (TC - BKG *CT) | ] * 1.96* 100Detection Levels and Less Than Values are determined from Procedure LA-508-002.

SLF ALPHA TOTAL in uCi/g (Average) 1.15E+00

05/29/97 RELATIVE COUNTING ERROR 4.6%

DETECTIONLEVEL

7.35E-03

05/28/97

02:30 PM

T-201

[Analyst:

ISignature

SCL Date: 29-May-97

signature of Chemist: SLF Date: S~/e 7/9?-SAMPLE.WB1 Rev. 1. 508101ML

I:\508101\OUTO8295.WB1


WORKBOOK PAGE: DUP5

AT : LA-508-101 (E-1)

WM DP 2^6, REV. 0 «**•

SOLIDS

18295

mrimhtomd@ALPHA01

mmammoem«S.ampl6sRr.epjjjjg

FUSION01

S97T000920

WB27807

SZC

SLF

SCL

05/29/97

DETECTOR NUMBERDISH SIZE ( 1 , 2 , or 5 ) (MS)GROSS COUNTSCOUNT TIME in MINUTES

(GC)

BACKGROUND in cpmJCT1

SAMPLE SIZE in mL(BKG)

DILUTION FACTOR (DF)DIGEST GRAMS of SOLIDS / LEFFICIENCY FACTOR

(PB'L)(EFF)

Lc, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE

DUP

161530

0.130.500

112.02120.269253.703

3lank Concentration in uCi/3Replicate Concentration in uCitgAverage Concentration in pCi/g

9.54E-019.6597E-01

REPLICATE

157530

0.130.500

112.02120.269252.370

Rs (Sample Count Rate)ALPHA TOTAL uCi/g

= (TC /CTJ-BKGRs • 1000mUL * DF / (EFF * SS * Dg/L * 2220u00dpm/uCi)

Relative Counting Error = [ |(The Square Root of TC + BKG * CT) / (TC - BKG * CT)| ] * 1.96 * 100Detection Levels and Less Than Values are determined from Procedure LA-508-002.

ALPHA TOTAL in (iCi/g (Average) 9.66E-01


DETECTIONLEVEL

7.25E-03

05/28/97

02:30 PM

T-201


Signature of Chemist: SLF Date:SAMPLE.WB1 Rev. 1.

3 8 7I:\508101\OUTO8295.WB1


WORKBOOK PAGE: SPK6

AT:LA-508-101(E-1) LA-508-113(B-0) SPIKED SAMPLEDETECTOR NUMBER

SPIKE

14REPLICATE

14DISH SIZE 1,2 , or 5 (MS)TOTAL COUNTS (TC) 39587 40087COUNT TIME in MINUTES (CT) 30 30BACKGROUND in cpm (BKG)SAMPLE VOLUME in mL (Spiked Vial) (SS) 0.500 0.500SAMPLE DILUTION FACTOR (Spiked Vial) (DF) 11 11DIGEST GRAMS of SOLIDS / L (Dg/L) 1.9924 1.9924

Matrjxf j t S f f SPIKE VOLUME in mL (SVol) 0.100 0.100SPIKE DILUTION FACTORSPIKE BOOK NUMBER (Spk BN) 131B43 131B43SPIKE VALUE in nCi/mL (SVal) 2.6293E-02 2.6293E-02INSTRUMENT EFFICIENCY FACTOR (EFF) 0.2692 0.2692SAMPLE + SPIKE |iCi/g (S+S) 2.44E+01 2.47E+01AVERAGE or MAXIMUM uCi/g in SAMPLE 1.1518E+00

Rs (Sample Count Rate) = (TC / CT) - BKGSAMPLE + SPIKE (jCi/g = Rs * 10OOmL/L * DF / ( EFF * SS * Dg/L *2220000dpm/pCi)QC ACTUAL = SValQC FOUND = (((S+S MCi/g - SAMPLE pCi/g) * ((SDF/(SVol*1000))/(DF/SS/Dg/L))))

ERCENT SPIKE RECOVERY = (QC FOUND / QC ACTUAL) *100

QC ACTUAL 2.63E-02QC FOUND 2.12E-02AVG. PERCENT SPIKE RECOVERY 80.5%

Analyst: SZC Date: 29-May-97

Signature of Chemist: SLF Datejr/zi/15SPIKE.WB1 Rev. 1.0 508101ML

I:\508101\OUTYI8295.WB1

woMistdata Version 1.005/15/96 Page:06/04/9714:26


Analyst: dpb

Method:



Worklist Comment: Use .500 mL sample size. Rerun #2. SLF


1 STD

1 STD

2 1BLNK

2 BLNK

3 BLMK/BRS

4 SAMPLE

4 SAMPLE

5 DOT

5 DTO

8 SAMPLE

8 SAMPLE

9 DOT

9 SUP

10 SPK

S97T000834 0

S97TO00834 0

S97T000834 0

8371000834 O

S97T001203 0

S97IO012O3 O

S97T0012O3 0

S37I001203 0

S97T001203 0

0ALPHAO1 SLPHAOl LIQUID

©ALPHA01 ALPHA01B LIQUID

®AL5HA0i At-EBAOl LlfitrtB

9ALPHA01 ALPHA01E LIQUID

«ft£*SAQi Maeatoi LIQUID

©ALPHA01 ALPHA01 LIQUID

dALPHAOl ALPHA01B LIQtTlD

©ALPHA01 ALPHA01 LIQUID

«%LPHA01 ALPHfiOlB LIQUID

OALPHA01 ALPHA0I LIQUID

^ALPHAOl ALPHA01E LIQUID

©ALPHA01 ALPEA01 LIQUID

^ALSHAOX ALPH&01E LIQUID

9ALPHA.01 ALPHA01 LIQUID

1.91S-4

3.39E+0Q

5.00E+0:

1.15E+0)

7.96E-0*

2.55E+01

9.41E-I

2,335-t-Q;

1.05B-0!

2.29E+01

8.96E-6

95.500 % Recovery

3.390 % Ct. Erro

tiCi/na.

500.000 uCi/ML

1.150 StMK/BKGf

..33e-006 uCi/mL

% Ctt,

16.695 RPD

23-.300 % Ct. E

.336-006 uCi/mL

% Ctt.

15.827 RPD

23.300 % Ct. SxfKa

62.357 % Recovery





06/04/9713:54A-0004-1


Analyst: Instrument: ABOO Book#

Method: LA-508-101 Rev/Mod HNF-SD-WM-DP-254, REV. 0Worklist Comment: Use .500 mL sample size. Rerun #2. SLF

S Type

1 STD

2 BLNK

3 BLNK/BKG

4 SAMPLE

5 DUP

8 SAMPLE

9 DUP

10 SPK

Sampled R A Test Matrix

8ALPHA01 LIQUID

©ALPHA01 LIQUID

(SALPHA01 LIQUID

S97T000834 0 ©ALPHA01 LIQUIDAnalytes Requested: ALPHA01 , ALPHA01E

Groupft Project

S97T000834 0 OALPHA01 LIQUID

S97T001203 0 OALPHA01 LIQUIDAnalytes Requested: ALPHA01 , ALPHA01E

97000311 T-201

97000311 T-201

S97T001203 0

S97T001203 0

®ALPHA01 LIQUID

SALPHA01 LIQUID


Analyst Signature Date Analyst Signature jptate



390

06/03/9708:39A-0004-1

Page: 1


Analyst: D/E> Instrument: ABOO 1^

Method: LA-508-101 Rev/Mod Q-o


Book#.



1 STD ©ALPHA01 LIQUID

2 BLNK @ALPHA01 LIQUID

3 BLHK/BKG @ALPHA01 LIQUID

Grouptt Project

4

S

8

9

10

SAMPLE

DUP

SAMPLE

DUP

SPK

S97T000834 0Analytes Requested:

S97T000834 0

Analytes Requested:

S97T001203 0Analytes Requested:

S97T001203 0

S97T001203 0

SALPHA01ALPHA01

(8ALPHA01

ALPHA01

©ALPHAOlALPHA01

SALPHA01

©ALPHA01

LIQUID, ALPHA01E

LIQUID

, ALPHA01E

LIQUID, ALPHA01E

LIQUID

LIQUID

97000311 T-201

97000311 T-201

Signgture Date


O\3oAnalyst Signatur^/ Date

Data Entry Comments.122 IvilrAf

A i/ jo I \"c A Ir^-

•fro

S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code. •£«•<. .-fclc.W-

HNF-SD-WM-DP-254, REV. 0WORKBOOK PAGE: STD1

AT:LA-508-101 (E-1) LA-508-113 (B-O) STANDARD

W&S&KJmfif&lSMMm. BACKCROUND In cpm

ftStCCKIsaPPBt DILUTION FACTOR@AUPHA01"

8gj . 'BatchiNumbei»i iS Standard Value In uCI/mL

DETECTOR NUMBER

GROSS COUNTS

; 1 , 2 , or 5 ) JMSj

COUNT TIME In MINUTES(GC)(CT)

(BKG)SAMPLE SIZE In niL _(SSi

[DF)STANDARD BOOK NUMBEREFFICIENCY FACTOR

(Std BN)

Lc, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE(EFF)

Concentration In uCM.licate Concentration In uCi/L

AVERAGE CONCENTRATION In uClfL 1.9057E-01

179B56

Rs (Sample Count Rate) = (TC / CT) - BKG

ALPHA TOTAL uCi/L = Rs * lOOOmL/L * DF / ( EFF * SS * 2220000dpm/uCi)ALPHA TOTAL uCi/mL = ALPHA TOTAL uCi/L / lOOOmL/LRelative Counting Error = [ |(The Square Root of TC + BKG * CT) / (TC - BKG * CT)| ] * 1.96 * 100Detection Levels and Less Than Values are determined from Procedure LA-508-002.

ALPHA TOTAL CONCENTRATION In


DETECTION

LEVEL

6.64E-07MCi/mL

Analyst: Date: 04-Jun-97

Signature of Chemist:STANDARD.WB1 Rev. 1.0

3 9 2

HNF-SD-WM-DP-254, REV. 0WORKBOOK PAGE: BLANK2

^4NF-SD4rVM-DR=24grfrEVr

AT: LA-508-101•s&t-sTypomsim

BLNK* j f » WorkiListJflSi?

18364

w AY^orjj.Bi7aat*AT

s\ n Test GQdejssM'I'ALPHAOI

iii- «i MatrixwjgsLIQUID

^CBatch Numb«resf97002408

•"•Xijb'RerurWagff-0

i*^,Saniplesgr.epSVSN/A

^I^SampJ.6 $$Ste.'£WL18364

WB26872

SEH

SsiSRCJieniist.sffisSSLF

^ ^ f A n a J y s t ^ ^ ^ 1

DPB

jaDateiepjiip.lgteSj06/04/97

SKAnalysIsjRateJf?06/04/97

gggAnafysfs^nme ^01 -30 AM

T-201

(E-1) LIQUIDSDETECTOR NUMBERDISH SIZE ( 1 , 2 , or 5 )GROSS COUNTSCOUNT TIME In MINUTESBACKGROUND in cpmSAMPLE SIZE in mLDILUTION FACTORDIGEST DILUTION FACTOREFFICIENCY FACTOR

(MS)(GC)(CT)

(BKG)(SS)(DF)

(DDF)(EFF)

Lc, Rmax, or Rs.(SAMPLE RATE) as APPROPRIATE

Blank Concentration In uCi/LRsplicate Concentration in uCi/LMaximum Concentration in uCi/L


<<<

ALPHA TOTAL uCi/L = Rs * 10OOmL/L " DF " DDF / ( EFFALPHA TOTAL gCi/mL = ALPHA TOTAL uCi/L/ 1000mULRelative Counting Error = [ |(The Square Root of TC +BKG*

BLNK

1526

300.13

0.50011

0.27010.243

8.11E-045.12E-04

8.1069E-04

REPLICATE

1523

300.13

0.50011

0.27010.154

* SS * 2220000dpm/uCi)

CT) / (TC-BKG*CT) | ] *1 .96*100Detection Levels and Less Than Values are determined from Procedure LA-508-002.

ALPHA TOTAL in uCi/mL (Maximum)



= <8.11E-07

500.0%

DETECTIONLEVEL

uCi/mL


Signature of Chemist:BLANK.WB1 Kev. 1.0 508101 ML

3 9 3

HNF-SD-WM-DP-254, REV. 0WORKBOOK PAGE: SAM

AT: LA-508-101$£'». * *i y^^^^M

SAMPLEv,.V Work^LiSfcig^fe

••6564'.-"HAT or(.TB«,?j>S!l#

ATV * Je st c o c t e ^ ^

IMJALPHAOI

Î^^^Matfix^^^^^LIQUID

iiaSatchxtJumbetilS97002408

SSgaSSSKerunigjsas;0

ggS.Sample/f?rep'g!v$N/A

^ ^ S a ( n p l e # J r t ^ ^S97T000834

Silnstrurnem»code?<1

WB26872Jjl^lêparjBC^Byt^f^

SEH

i3^g%Ctiemist>iKWSLF

^ ^ ^ A n a i y s ^ ^ ^DPB

SiDate. completes;?06/04/97

SjjAnalysissOate«06/04/97

Ân^ly^STJme^01 30 AM

^&âmpl.6&&pirit3&>:T-201

(E-1) LIQUIDSDETECTOR NUMBERDISH SIZE ( 1 , 2 , or 5 ) (MS)GROSS COUNTS (GC)COUNT TIME In MINUTES (CT)BACKGROUND In cpm (BKG)SAMPLE SIZE In mL (SS)DILUTION FACTOR (DF)DIGEST DILUTION FACTOR (DDF)EFFICIENCY FACTOR (EFF)Lc, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE

SAMPLE

152

8130

0.130.500

11

0.27012.570

Blank Concentration In uCi/LReplicate Concentration In uCi/LAverage Concentration In iiCI/L


8.57E-037.35E-03

7.9606E-03

REPLICATE

152

7030

0.130.500

11

0.27012.203

ALPHA TOTAL uCi/L = Rs * 10OOmL/L * DF * DDF / ( EFF " SS * 2220000dpm/uCi)ALPHA TOTAL uCi/mL = ALPHA TOTAL uCi/L/1000mL/LRelative Counting Error = [ ((The Square Root of TC + BKG "CT) 1 (TC - BKG *CT)11*1.96* 100Detection Levels and Less Than Values are determined from Procedure LA-508-002.

ALPHA TOTAL in uCi/mL (Average) = 7.96E-06


DETECTIONLEVEL

1.33E-06uCi/mL

{/ system;exit}yes~

Analyst:


Date: 04-Jun-97

3 9 4

HNF-SD-WM-DP-254, REV. 0WORKBOOK PAGE: OUP5

AT:LA-S08-101 (E-1) LIQUIDS

@ALPHA01

LIQUID

n i ^ ; . ^ f f Replicate Concentration in |iCi/L

WB26872

ETECTOR NUMBER( 1 , 2 , or 5 )

GROSS COUNTS(MS)

COUNT TIME In MINUTES(60)(CT)

(BKG)SAMPLE SIZE In mL (SS)DILUTION FACTORDIGEST DILUTION FACTOR

(PF)

EFFICIENCY FACTOR_JDDFj

Lc, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATEJEFF)

&g

3lank Concentration in uCI/L

ftveraga Concentration in uCi/L 9.4059E-03

Rs (Sample Count Rate) = (TC I CT) - BKGALPHA TOTAL uCi/L = Rs " 10OOmL/L * DF * DDF / ( EFF * SS * 2220000dpm/uCi)ALPHA TOTAL uCi/mL = ALPHA TOTAL uCi/L/1000mL/LRelative Counting Error = [ |(The Square Root of TC + BKG * CT) / (TC - BKG * CT)H * 1.96 * 100Detection Levels and Less Than Values are determined from Procedure LA-508-002.

ALPHA TOTAL In |iCi/mL (Average) 9.41 E-06


{/system;exit}yes~

Analyst:


Date: 04-Jun-97

3 9 5

HNF-SD-Wy-DP-254,REV.O

WORKBOOK PAGE: SAM6

AT: LA-508-101

SAMPLES " , WOrKJ-jStTS),^

18364^•ATfOGIB #^fi-*

AT

W§fr,est codes?*@ALPHA01

LIQUIDSSBatcJi.flurnberSii

97002408

a*SSlier.UD«ra80

0SampieprepÂ<N/A

gg^j&SampJe^gî*S97T001203

'ans.trunagjit.Qpde;WB26872

mmssssssmmSEH

SLF$§>iiÂnaly.st^!££*s

DPB

SiSD.ate;C,oijipletej»S06/04/97

SS5fA.nalysls Date^s*06/04/97

SsfAgalystssTirne^01:30 AM

l^&SaRipjeft&oijitjtsc^T-201 ,

(E-1) LIQUIDSDETECTOR NUMBERDISH SIZE ( 1 , 2 , or 5 ) (MS)GROSS COUNTS (GC)COUNT TIME In MINUTES (CT)BACKGROUND in cpm (BKG)SAMPLE SIZE in mL (SS)DILUTION FACTOR (DF)DIGEST DILUTION FACTOR (DDF)EFFICIENCY FACTOR (EFF)Lc, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE

SAMPLE

152

11330

0.130.500

11

0.27013.637

Blank Concentration in uCi/LReplicate Concentration in uCI/LAverage Concentration in pCi/L


1.21 £-028.91 E-03

1.0518E-02

REPLICATE

152

8430

0.130.500

11

0.27012.670

ALPHA TOTAL pCi/L = Rs * 1000mL/L * DF * DDF/ ( EFF " SS * 2220000dpm/uCi)ALPHA TOTAL uCi/mL = ALPHA TOTAL uCi/L/ 1000mL/LRelative Counting Error = [ |(The Square Root of TC + BKG*CT) / (TC- BKG * C T ) l l * 1.96 MOODetection Levels and Less Than Values are determined from Procedure LA-508-002.

ALPHA TOTAL in pCi/mL (Average) = 1.05E-05


DETECTION

1.33E-06HCi/mL

{/system;exit}yes~

ftnalyst:


Pate: 04-Jun-97

3 9 6

HNF-SD-WM-DP-254, REV. 0WORKBOOK PAGE: DUP7

AT: LA-508-1013gf£i^rypej^$33£f-^

DUP§gg$$|Worl£L)st§i§gti£

18364

AT

@ALPHA01

&^RMa,trj!<3M%LIQUID

|ggatcrj,NuinbeiS97002408

£gg&&&ei:un$!|$jjt§530

^Sampleif^reps-^N/A

^BÔ^Saniple^M^^S97T001203

Slnstmrnentfiocle,sWB26872

^g^repated;.By^^SEH

SLF

06/04/97

^gAnaiy^s'JQê1^06/04/97

Ânaly&is^Tinieg^01.30 AM

^9(Sarr)pt9:Ppint^§T-201

(E-1) LIQUIDSDETECTOR NUMBERDISH SIZE ( 1 , 2 , or 5 ) (MS)GROSS COUNTS (GC)COUNT TIME in MINUTES (CT)BACKGROUND In cpnl (BKG)SAMPLE SIZE in mL (SS)DILUTION FACTOR (DF)DIGEST DILUTION FACTOR (DDF)EFFICIENCY FACTOR (EFF)Lc, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE

DUP

152

8730

0.130.500

11

0.27012.770

Blank Concentration In uCi/LReplicate Concentration in uCi/LAverage Concentration In uCl/L

Rs (Sample Count Rate) = (TC/CTJ-BKGALPHA TOTAL uCi/L = Rs • 10OOmL/L * DF • DDF / ( EFIALPHA TOTAL uCi/mL = ALPHA TOTAL uCi/L/1000mULRelative Counting Error = [ |(The Square Root of TC + BKG

9.24E-038.68E-03

8.9612E-03

REPLICATE

152

8230

0.130.500

11

0.27012.603

•SS"2220000dpm/MCi)

•CT) / (TC- BKG-CT)! 1*1.96Detection Levels and Less Than Values are determined from Procedure LA-508-002.

ALPHA TOTAL in MCilmL (Average) 8.96E-06


•100

DETECTION

LEVEL

1.33E-06

HCi/mL

{/ system;e»t}yes~

Analyst:


Date: 04-Jun-97

3 9 7

HNF-SD-WM-DP-254, REV. 0WORKBOOK PAGE: SPK8

AT : LA-508-101 (E-1) LA-508-113 (B-0) SPIKED SAMPLE

MMKKaMMKSPK

18364

AT

MHTra^ocLsiHHe@ALPHA01

LIQUID

•tlBaicJilrJutriberli97002408

0

gs,sampi5.Biepjpg*N/A

@Sj§S§K$>flrj[ipJe 1$$$&j£.S97T001203

1 l.i)4t£yrn6ntaQQrJe&WB26872

^Rrgp.arad'By.<S3SEH

SLF

DPBi3g£U<uti,vuiiiP~l4«,l&3$£

06104197

ggAnalysis,Date5s«06/04/97

®i;Analysliinm.eaa01 30 AM

'SH^SarDPUSRolot^^iT-201

DETECTOR NUMBERDISH SIZE 1 , 2 , or 5 (MS)TOTAL COUNTS (TC)COUNT TIME In MINUTES (CT)

SAMPLE VOLUME In mL (Spiked Vial) (SS)SAMPLE DILUTION FACTOR (Spiked Vial) (OF)DIGEST DILUTION FACTOR (DDF)SPIKE VOLUME In mL (SVol)SPIKE DILUTION FACTOR (SDF)SPIKE BOOK NUMBER (Spk BN)SPIKE VALUE In uCi/mL (SVal)INSTRUMENT EFFICIENCY FACTOR (EFF)SAMPLE* SPIKE pCI/mL (S+S)AVERAGE or MAXIMUM pCI/mL In SAMPLE |

Rs (Sample Count Rate) = (TC/CT)-BKG

SPIKE

152

2760630

0.50011

0.1001

131B432.6292E-02

0.27013.07E-03

1.2853E-05

SAMPLE + SPIKE uCi/mL = Rs" D F ' D D F / (EFF*SS *2220000dpm/uCiQC ACTUAL = SVal

REPLICATE

152

3171430

0.50011

0.1001

131B432.6292E-02

0.27013.53E-03

QC FOUND = (((S+S uCi/mL - SAMPLE pCi/mL) * <(SDF/SVol)/(DF*DDF/SS))))PERCENT SPIKE RECOVERY = (QC FOUND / QC ACTUAL) "100

QC ACTUAL =QC FOUND =AVG. PERCENT SPIKE RECOVERY =

2.63E-021.64E-02

62.5%

ftnalyst: Date: 04-Jun-97

Signature of Chemist:SP1KE.WB1 Rev. 1.0

398


-tiNF-SB-WM DP-246, Page:


Analyst: slh

Method:

Instrument: AB15HNF-SD-WM-DP-254rRBfr«

Rev/Mod


Seq Type Sample# R A Test Matrix Actual

1 STD

1 STD

Z BLKK

2 BLKK

3 BLSK/BKS

4 SAMPLE

4 SAMPLE

5 DOT

5 DOT

6 SAMPLE

6 SAHP&R

7 DUP

7 DOT

S97T001242

597T001242

S97T001242

S97T001242

S97T0O1259

39*71001253

S97T001259

S97T00125S

©ALPHA01

6ALPHA01

©ALPHA01

(SALPHA01

©ALPHA01

ALPBA01 iXCUID

ALPHAO1E LIQUID

ALPHA.W LIQUID

ALPHA01E LIQUID

ALJPH&Oi LIQUID

ALPHA01 LIQUID

ALPHA01E LIOOTD

ALPHA01 LIQUID

ALPH&01S LIQUID

ALPHA01 LIQUID

ALREAOiB ilQrai)

ALPHA01 LIQUID

ALPHA01S LIQUID

2.00E-04

1.00

Found DL or Yield Unit

1.87E-4 93.500

3.41E+00 3.410 % Ct. Ecro

<7.liE-7 ud/nd.

5.00E+02 500.000 uCi/mL

l,08E+00 1.080 J6LNK/BK<5

1.21E-06 147.Oe-008 uCi/mL

9.62B+01 0.06+000 % Ct. XtXOX

<6.56E-7 RPD

5,OOE+02 500-000 % Ct. %XXO

8.49E-06 147.Oe-008 uCi/mL

2.41B+01 0.06+000 % Ct. ErrO*

8.33E-6 1.902 RPD

2.512+01 25.100 % Ct.. EtftO



Reviewer Si Date


3 9 9

06/04/9714:04A-0004-1


KAnalyst: Sri W Instrument: ABOO





1 STD @ALPHA01 LIQUID

2 BLNK SALPHA01 LIQUID

3 BLNK/BKG SALPHAOl LIQUID

4 SAMPLE S97T001242 0 ©ALPHAO1 LIQUIDAnalytes Requested: ALPHAO1 , ALPHAO1E

Group# Proj ect

5 DUP

6 SAMPLE

7 DUP

S97TOO1242 0 LIQUID

S97T001259 0 SALPHAO1 LIQUIDAnalytes Requested: ALPHA01 , ALPHA01E

97000311 T-201

97000311 T-201

S97T001259 0 SALPHA01 LIQUID


Ana^st Signature

JDate


S = Worklist Slot Number, R - Replicate Number, A = Aliquot Code.

HNF-SD-WM-DP-254, REV. 0WORKBOOK PAGE: STD1

AT:JLAJ08-101(£-1)Type

J ' 1~Work"List"'1S444

"AfVtS"*AT

_ TestCode '

Ma'tflx"LIQUID"

Bdtih Number

"Rerun"b

LA-508-miB^O) STANDARDDETECTOR NUMBERDISH SIZE ( 1 , 2 , or 5 )GROSS COUNTSCOUNT TIME in MINUTESBACKGROUND in CpmSAMPLE SIZE in mLDILUTION FACTORSTANDARD BOOK NUMBEREFFICIENCY FACTOR

(MS)(GC)(CT)

(BKG)(SS)(DF)

(Std BN)(EFF)

Lc Rmax, or Rs,(SAMPLE RATE) as APPROPRIATEStandard Value in uCi/mLConcentration in uCi/LRcplicite Concentration in uCi/L =AVERAGE CONCENTRATION in uCi/L

=

STANDARD152

331030

0.171,000

179BS6

0.2701110.163

2.00E-041.84E-011.90E-01

1.8689E-01

REPLICATE152

342430

0.171.000

179B560.2701

113.963

_ .AJA, _ . ••• i simple Count Rate) = (TC/CTJ-BKGSample 5 " v P-A. TOTAL jjCi/L = Rs * lOOOmL/L * DF / ( EFF * SS * 2220000dpm/|iCi)

„ BH-ISW— ^ 'LPHATOTALuCi /mL = ALPHA TOTAL uCi/L / lOOOmL/L""insirui'lienf CO0e" •». - t . o Counting Error = [|(The Square Root of TC + BKG *CT) / (TC - BKG *CT)| 1*1.96*100

>"BZuC72 Lt i - " on Levels and Less Than Values are determined from Procedure LA-508-002.Prepared By

CJO""CnenTist"'""''"

SLFAnalyst

~ _ SLHDate Compjete' *

06/11(07Analysis Odtp'

06/11/97"Analysii Timi>_

"*"Sah>pie Point 'r-201

ALPH A TOTAL CONCENTRATION in uCi/mL =

RELATIVE COUNTING ERROR =

1.87E-04

3.4%

DETECTIONLEVEL

7.37E-07yCi/mL


Signature of Chemist: SLF Date: i/ll /MSTANDARD.WB1 Rev. 1.0

4 0 1I:\508101\OUT\1M44.WB1

HNF-SD-WM-DP-254, REV. 0 ^

WORKBOOK PAGE: BLANK2

AT: LA-508-101 (E-1) LIQUIDS'DETECTOR NUMBERDISH SIZE ( 1 , 2 , or 5 ) (MS).GROSS COUNTS

18444 ^COUNT TIME In MINUTES(GC)

ATf or TB"?AT

Test Code

(CT)•BACKGROUND In cpmSAMPLE SIZE In mL

(BKG)(SS)

DILUTION FACTOR, @ALPHA01' Matrix

" L.JQUID' "jBatch'Muinber

__97002491Riru"n~ '" Roj

0 JMa§ jiriple P'fSp "' i

" N/A~ "K

DIGEST DILUTION FACTORIEF'FICIENCY FACTOR

(DF)(DDF)

•Lc Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE(EFF)

300.17

0.500

Blank Concentration in uCULplicate Concentration in |iCi/L 7.11E-04ximum Concentration in uCi/L 7.1125E-04

REPLICATE

0.500

0.2701

£. mpla Count Rate) = (TC /CT)-BKG»-Pr-\ TOTAL uCi/L = Rs * 1000mL/L * DF * DDF I ( EFF * SS * 2220000dpm/uCi)

_ JJJVI_ •--r~K\ TOTAL uCi/mL = ALPHA TOTAL uCi/L/ lOOOmL/L"instrumenVddde"'^ li.e Counting Error = [ |(The Square Root of TC + BKG*CT) / (TC-BKG*CT)] ]*1.96*100

WB>6S72 ^ ' t . • on Levels and Less Than Values are determined from Procedure LA-508-002.Prepared By i

C"hemis7SLF_ ALPHA TOTAL in MCi/mL

" AtMlyst(Maximum) < 7.11E-07

"Date Complete06/11/97


Analysis Time"

""Sample PoTn't'.T-201 _ j



DETECTIONLEVEL

1.47E-06

Analyst: SLH Date: 11-Jun-97

Signature of Chemist: SLF Date: if ItBLANK. WB1 Rev. 1.0

I:\508101\OUT\18444.WB1


WORKBOOK PAGE: SAM4

. c

T:LA-508-101(E-1) LIQUIDStype

SAMPLFWorkLi i t

18444ATorTB?

ATTeM CorteigALPHAOt

MatrixLIQUID

DETECTOR NUMBER'DISH SIZE ( 1 , 2 , or 5 )GROSS COUNTS

.COUNT TIME In MINUTES'BACKGROUND in cpmSAMPLE SIZE In mL

^DILUTION FACTOR ;

DIGEST DILUTION FACTOR

[EFFICIENCY FACTOR"Lc Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE

Batch Number97002491Rerun

0

gBlank Concentration In uCi/L

Replicate Concentration In uCi/LAverage Concentration In uCr/L

(MS)(GC)(CT)

(BKG)(SS)(DF)

(DDF)(EFF)

SAMPLE15

21830

0.170.500

11

0.27010.430

1.43E-039.90E-04

1.2119E-03

REPLICATE152

1430

0.170.500

11

0.27010.297

N/A | F , i'ample Count Rate) = (TC/CTJ-BKG'Sample* ' - L =1IA TOTAL uCi/L = RsMOOOmUL'DF'DDF/ ( EFF * SS * 2220000dpm/uCi)

,.®??I00™?lf? ....,'" !HA TOTAL uCi/mL = ALPHA TOTAL uCi/L/1000mUL' tr'lStfumeil't"Cod'p" R. .live Counting Error = [ |(The Square Root of TC + BKG * CT) / (TC - BKG* CT)[ ] * 1.96* 100

WB26872 I - oton Levels and Less Than Values are determined from Procedure LA-508-002.Prepared By

I

SLFAnalyst

SLH

0Gl11;97

Analysis' DateOG/11/97

Analysis'*ime " Jr _ 12 30 AM' Sample Point' ' ,

T-201

ALPHA TOTAL in MCi/mL (Average) =

I

I

jRELATIVE COUNTING ERROR

1.21E-06

96.2%

DETECTIONLEVEL

1.47E-06(jC'i/mL


Date: £,//!Signature of Chemist: SLFSAMPLE.WB1 Rev. 1.0 508101 ML

4 0 3I:\508101\OUT\18444.WB1

HNF-SD-WM-DP-254, REV. 044NF-SD WM DP-246,WORKBOOK PAGE: DUP5

AT: LA-508-101 (E-11.Tyes_DUP

Woriulist18444

""AYorTB"?___ AT__ _"Test Code*

LIQUIDS:DETECTOR NUMBERDISH SIZE ( 1 , 2 , or 5 ).GROSS COUNTS

(MS)

!COUNT TIME In MINUTES(GC)(CT)

BACKGROUND in cpmSAMPLE SIZE In mL

(BKG)(SS)

EFFICIENCY FACTOR

DILUTION FACTOR@ALPHA01 IDIGEST DILUTION FACTORMatrix"LIQUID "

Batch Number97002491Re'run *

o

(DF)(DDF)(EFF)

.Lc Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE

15

300.17

0.500

0.2701

Blank Concentration in pCULRpplicate Concentration In pCi/L 6.56E-04

•Maximum Concentration in uCi/L

ample Count Rate) = (TC/CT)-BKGI^LFHA TOTAL uCi/L = Rs * 1000mUL * DF * DDF / ( EFF * SS * 2220000dpm/uCi)

j • P IA TOTAL uCi/mL = ALPHA TOTAL uC&t/1000mL/LV 'ative Counting Error = [ |(The Square Root of TC + BKG * CT) / (TC - BKG * CT)| ] * 1.96* 100'_Lti otion Levels and Less Than Values are determined from Procedure LA-508-0O2.

~" Sample Pr<>pN/A

Sample #S97T00r242

tiis'tf umiWB2G872 _

Prepared By j

"_"ciieniist" """SLF " 'ALPHA TOTAL in nCi/mL (Maximum)

AiiaTyst" ]_SLH _ ! LESS Than Value was Determined from Lc.

Date Complete"OC/11/97

6.5597E-04

REPLICATE15

300.17

< 6.56E-07


DETECTIONLEVEL

1.47E-06uCi/mL

06/11i97

J2 30AM JSample Point "!

T-201

Analyst: /) /I SLH Date: 11-Jun-97

Signature of Chemist: SLFSAMPLE.WB1 Rev. 1.0 508101 ML

I:\508101\OUT\18444.WB1

HNF-SD-WM-DP-254, REV. 0 44NF-SB-WM DP-246,-i5-qi

15(MS)(GC) 80

BACKGROUND in cpmJCJ1

AMPLE SIZE In mL(BKG) 0.17 0.17

(SS) 0.500(DF)

(DDF)(EFF) 0.2701 0.2701

WORKBOOK PAGE: SAMS

AT : LA-508-101 (E-1) LIQUIDSType [DETECTOR NUMBER

SAMPLE fDISH SIZE ( 1 , 2 , or 5 )' Work" List GROSS COUNTS

18444 COUNT TIME in MINUTES"ATorTB?'

" ATTe<it Codp ' _.DILU riON FACTOR

~SALPHA0f DIGEST DILUTION FACTOR_JSatriX EFFICIENCY FACTOR

LIQUID^ ] _ Lc, Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE" Bati-.hftumbcr" "- •

97002491 jBljnK Concentration in uCI/L =

Rerun Replicate Concentration in nCi/L0 Aver ;ge Concentration in uCi/L

Sj'inpie Pr^pJf N/A •>. iample Count Rate) = (TC / CT) - BKG

Sample ff !-M P ik TOTAL MCi/L = Rs * lOOOmL/L * DF * DDF / ( EFF * SS * 222«X»dpm/uCi)- ..S2?,T00?i59.. I ' " " ' ATOTALMCi/mL = ALPHA TOTAL uCi/L/1000mL/Lihstniinent*Co<te j^.'-v./e Counting Error = [ |(The Square Root of TC + BKG * CT) / (TC - BKG * CT)| ] * 1.96 *

WB26872 I t.ction Levels and Less Than Values are determined from Procedure LA-508-002." Prepared By

2.497

8.4942E-03

2.597

SLF 'ALPHA TOTAL in MCi/mL (Average)""Analyst"' ""

SLHDate Complete '

8.49E-06

06/11/97 RlAnalysis Date "\

06/11i97 m __ {AnalysiVTlmp *

_12J0AM _ _Sample Point ~ '

ELATIVE COUNTING ERROR 24.1%

DETECTIONLEVEL

1.47E-06uCi/mL

Analyst: SLH Date: 11-Jun-97

Signature of Chemist: Date:

SAMPLE.WB1 Rev. 1.0 508101 ML

f:\508101\OUTY18444.WB1


-WORKBOOKPAGE: DUP7

AT:LA-508-10_ _ Type

DUPWork'tiiV

18444' " AT'orTB?""

'ATTest'Code"'

"@ALPHA01

JflalrixLIQUID

" 'BatchNumber"*~ 97002491

Ro'runp

^ Simple Prep " _JN/A~ " \~ c: jmple Count Rate) = (TC /CT) -BKG

Sample M ' "A11 - * TOTAL uCi/L = Rs * 1000mL/L * DF * DDF / ( EFF * SS * 2220000dpm/MCc). »., .??7 .T .0 ,°HM , . * l-^TOTALuCi/mL = ALPHATOTAL|iCi/L/1000mL/L' lnstriime'm"cdd<> "•?• \ue Counting Error = [ |(The Square Root of TC + BKG * CT) / (TC - BKG * CT)| ] * 1.96* 100

1 (E-1) LIQUIDS:DETECTOR NUMBER•DISH SIZE ( 1 , 2 , or 5 )GROSS COUNTS

(COUNT TIME In MINUTESBACKGROUND In cpmSAMPLE SIZE In mLDILUTION FACTORDIGEST DILUTION FACTORIEFFICIENCY FACTORILC Rmax, or Rs,(SAMPLE RATE) as APPROPRIATE:Blank Concentration In uCI/LReplicate Concentration in pCi/LAverage Concentration in uCi/L

(MS)(GC)(CT)

(BKG)(SS)(DF)

(DDF)(EFF)

DUP15

28530

0.170.500

11

0.27012.663

8.88E-O37.77E-03

8.3275E-03

REPLICATE15

27530

0.170.500

11

0.27012.330

WB26872Prepared By

_ CJOfchem'i'st

SLF'"""Analyst

SLHDate'Complete '

06/11107Analysts'datc'

06/11/97 __AnjiysisTimc

12 30AM_Sample Point

T-201

c r ion Levels and Less Than Values are determined from Procedure LA-508-002.

ALPHA TOTAL in uCi/mL (Average) 8.33E-06


DETECTIONLEVEL

1.47E-06HCifmL

Analyst: A(\ I SLH Date: 11-Jun-97

Signature of Chemist: Date:SAMPLE.WB1 Rev. 1.0 508101 ML

I:\508101\OUTO8444.WB1

HNF-SD-Wy-DP-254, REV. 0 page: 1


•worklistrad Version 1.0 05/09/9607/23/9708:43

Analyst: rdm

Method:

Instrument: GEA04 Book#

Rev/Mod

Worklist Comment: T201, ©GEA-02, STD: l.OmL, SAM SIZE: see traveler skm

Seq Type Sample* R A Test Matrix Actual Found DL or Yield Unit

1 STD

1 STD

1 STB

1 STD

2 BLNK-PSEP

2 BLNK-PREP

2 SLSK-PRSP

2 BLHK-PREP

2 StMJMStS*

3 SAMPLE

3 SAMPLE

3 SAMPLE

3 SAMPLE

3 SAMPLE

3 SAMPLE

3 SAMPLE

3 SAMPLE

3 SAMPLE

4 DUP

4 DUP

4 DUP

4 DOT

4 DOP

4 DOT

4 DUP

4 DUP

4 DUP

4 SUP

5 SAMPLE

5 SAMPLE

5 SAMPLE

5 SAMPLE

5 SAMPLE

5 SAMPLE

5 SAMPLE

S SAMPLB

5 SAMPLE

5 SAMPLE

6 DUP

6 DUP

S97T001753

S97T0017S3

S97T001753

S97T001753

S97T001753

8STS>3<inS3

S97T001753

£971001753

S97T001753

S97TO017S3

S97T001753

S97TQ01753

S97T001753

S97T001753

S97T001753

S97TQ01753

S97T0017S3

S97T0G17S3

S97T001753

S97T001753

S97T0017S4

S97TOG1754

S97T001754

S97T001754

S97T001754

S97TOQ1754

S97T001754

S97TQ01754

S97T001754

S917TOQ17S4

S97T001754

S97T001754

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

Q

0

0

0

0

0

0

F

$

F

P

F

F

F

F

¥F

V

F

S1

F

FF

F

•8

F

*

F

V

F

*

F

9

F

IF

F

9GEA-02

SGEA-02

<&3EA*02

9SEA-02

@GBA-Q2

9GEA-02

•SGEA-02

QGEA-02

®GEA*O2

@GBA-02

«6SA-O2

©GEA-02

«GEA^O2

«GEA~02

«&EA-»£2

©GEA-02

(&GEA-02

«6EA^02

«GEA-02

^BA-02

©GEA-02

*«E&-02

©GEA-02

«6&A«02

«GBA-02

<3GSA--02

©GEA-02

(&GBA-02

©GRA-02

<SGEA-O2

©GEA-02

©GEA-02

•9GEA-O2

©GEA-02

0GSA-O2

©GEA-02

©GEA.-C2

©GEA-02

®GEA*02

COfiO-02

CO60-02E

CS13702

SOLID

SOLID

SOLID

CS13702E SOLID

C0M-Q2

CS13702

Etn5402

EU15502

AM24102

CO60-02

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

C0efl-02B SOLID

CS13702

CS13702E

EU15402

EtT15402S

EU15502

EO155Q2K

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

AH24X02 gvuAu

AK24102B SOLIDCO60-02 SOLID

CQ60-02S SOLID

CS13702

EU1S402

SOLID

SOLID

SOLID

BUXS402S SOLIB

EU15502 SOLID

EO15S02E SOLID

AM24102 SOLID

AH24102E SOLID

CO60-02

CO60-02E

CS13702

SOLID

SOLID

SOLID

CS13702E SOLID

EU15402

BO1S402S

EU15502

EO15502E

AH24102

AM24102E

CO60-02

CO60-02S

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

6.2896-03

1

5.773d-03

1

1

1

I

1

1

H/A <

H/A

N/A

, N/A

N/A <

K/A

H/A <

H/Ai i

K/A

<6.34e-3

1

4.81e-02

1

<1.81e-2

1

<1.46e-2

1

<3.46e-2

1

H/A <

w/a.H/A <

H/A

H/A <

H/A

H/A <

H/A

H/A <

K/A

<4.52e-3

X

6*216-03

0.740

5.9»e-03

0.950

<fi.21e-3

<1.03e-2

<1.70o*-2

<1.44e-2

6.3436-03

n/a4.807e-02

13-6

1.815e-02

a/a1.464e-02

a/a

a/a<5.66e-3

n/a

4.33e-02

20.1

<1.86e-2

n/a

<1.39o-2

n/a<2.93e-2

itt/a

4.5196-03

»/a8.471e-03

fl/a

1.3546-02

n/a1.069e-02

a/a2.0506-02

n/a

<4.37e-3

n/a

9S.744

0.740

103.478

0.950

634.3e-005

0.06+000

O.Oe+000

0.O6+000

181.56-004

0.064-000

146.46-004

o.oe+ooo

0.064-000

10.503

20.100

451.96-005

0.06+000

847.1e-005

0.06+000

135.46-004

0.064000

106.9e-004

O.Os+000

205.0e-004

0.06+000

% Reeovaty

% Ct Error

% Kectivery

% Ct Error

uCi/g

uCi/g

UCi/g

uCi/g

Ud/g

uCi/g

% Ct. Error

uCi/g

% Ctl. EtfTOK

uCi/g

% ct. E«or

uCi/g

% Ct. Erxor:

uCi/g

% Ct. EtrorRPD

% Ct ErSor

RPD

% Cfc EtrOJf

RPD

% Ct. Ertfot

EPD

% Ct ErKor

RPD

% Ct Enroa?

uCi/g

% Ct. EridK

uCi/g

% Ct. Error

uCi/g

% Ct. Error.

uCi/g

% Ct. Error

uCi/g

% Ct. Erior

RPD

% Ct Error

Onto shown for QC (BLK/BKG) may not reflect the actual units.

407

v/orklistrad Version 1.005/09/96

07/23/9708:43

Page:



t>eq lypefi DUP

> DUP

6 WS6 DUP

6 DUP

6 DUP

6 t>m

6 DUP

Sample? K AS97T001754

S97T001754

S97T001754S97T001754

g97TQ017S4

S97T001754

S97rO01754

S97T001754

0

0

0

0

0

©GEA-02

OGEA-02

©GBA.-02

@OEA-02

-SGEA.-02

©GEA-02

lest MatrixCS13702 SOLID

CS13702E SOLID

EU15402 SOLIDEO15402E SOLID

KO1S502 SOLIC

EU15502E SOLID

AH243.02 SOLID

AM24102H SOLID

Actual<S.47e-3

I

<1.07a.*2

1

<2.05e-2

1

Jbound1.23e-02

n / a

<1-046-2

n/a

<2.O7e*2

n / a

UJL or Yield UnitRPD

KPD

% Ct Error

RPD

% Ct Error

&PD

% Ct Error

Comments Section:Comments for sample# S97T001753 and test @GEA-02 .

DL=0 = > n/a.





LABCORE Data Entry Template for Worklist# 1937307/17/9713:56 paoe-A-0004-1

Analyst: f-W> Instrument: GEAOO Boofcf 15$5j

Method: LA-548-121 Rev/Mod f "O

Worklist Comment: T201, ©GEA-02, STD: l.OmL, SAM SIZE: see traveler skm

S Type Sample# R A Test Matrix Groupl Project

1 STD @GEA-02 SOLID

2 BLNK-PREP ©GEA-02 SOLID

3 SAMPLE S97T001753 0 P SGEA-02 SOLID 97000311 T-201Analytes Requested: AM24102 , AM24102E, CO60-02 , CO60-02E, CS13702 ,

CS13702E, EU15402 , EU15402E, EU15502 , EU15502E

4 DUP S97T001753 0 F ©GEA-02 SOLID

5 SAMPLE S97T001754 0 F (8GEA-02 SOLID 97000311 T-201Analytes Requested: AM24102 , AM24102E, CO60-02 , CO60-02E, CS13702 ,

CS13702E, EU15402 , EU15402E, EU15502 , EU15502E

6 DUP S97T001754 0 F ©GEA-02 SOLID

Final page for worklisty# 19373

Snalyst Signature Date Analyst Sigriature/1""" Uate



4 0 9

1NF-SD-WM-DP-254, REV. 0


********************************************************************************* 222-S Laboratory Counting Room 18-JUL-1997 16:42:53.60 *********************************************************************************

>>>>>>>>>> SAMPLE INFORMATION <<<<<<<<<<Worklist #: 19373Sample ID: WL19373-STD Removed by:Sample Size: 1.00000E-03 LDilution Factor: 1.00000E+00

>>>>>>>>>> COUNT INFORMATION <<<<<<<<<<Detector ID: GEA4File Number: dka300:[spec.GEA4]4g4487.cnfGeometry: 41Count Time: 0 02:30:00.00 secReal Time: 0 02:30:29.72 secDead Time: 0.3%

>>>>>>>>>> ANALYSIS INFORMATION <<<<<<<<<<Sample Count Time:Decayed to:Standard Deviations:Analysis Library:Analyst:Background Subtract:

18-JUL-1997 14:11:48.8618-JUL-1997 14:11:48.862ENVGEAGLDKA3 0 0:[SPEC.GEA4]4 GBACK

>>>>>>>>>> CALIBRATION INFORMATION <<<<<<<<<<Date of last energy calibration: 10-DEC-1996 08:01:41.61Date of last efficiency calibration: 10-DEC-1996 08:21:14.07********************************************************************************

Post-NID Peak Search Report

It Energy Area FWHM Channel Left Pw %Err

00000

59.46661.55*1173.12*1332.401730.31

330579174445240489

44

1.031.431.771.851.14

119.221323.242346.342664.883460.74

1171315233726553456

71619199

61.61.01.11.0

57.9

Fit Nuclides ActivityuCi/L

AM-241CS-137CO-60CO-60

0.1005.986.196.23

410

Summary of Nuclide ActivitySample ID : WL19373-STD

HNF-SD-WM-DP-254, REV. 0Page : 2

Acquisition date : 18-JUL-1997 14:11:48Total number of lines in spectrum 5Number of unidentified lines 1Number of lines tentatively identified by NID 4 80.00%

Nuclide Type

NuclideCO-60CS-137

Hlife5.27Y30.00Y432.2-&¥-

Wtd MeanUncorrected

Decay uCi/L1.00 6.212E+001.00 5.984E+001.00

Wtd MeanDecay Corr

uCi/L6.212E+005.984E+001.001E-01

Decay Corr 2-Sigma2-Sigma Error %Error Flags

0.046E+00 0.740.057E+00 0.950.G1GE-04 &i^0-

Total Activity : 1.230E+01 1.230E+01

Grand Total Activity 1.230E+01

Flags: "K" = Keyline not found"E" = Manually edited

1.230E+01

= Manually accepted= Nuclide specific abn. limit

411

Minimum Detectable Activity ReportSample ID : WL19373-STD

Nuclide

BE-7NA-22NA-24K-40CR-51MN-54CO-56CO-57CO-5 8FE-59SE-75SR-85Y-88NB-94ZRNB-95RU-103RURH-106AG-108mCD-109AG-110MSN-113TE-123mSB-124SB-125TE-125m1-131CS-134BA-140LA-140CEPR-144EU-152EU-154EU-155HG-203TL-208BI-212PB-212BI-214PB-214RA-224RA-226AC-228TH-228TH-229PA-233UTH-233PA-234MTH-234U-235NP-237NP-239

BckgndSum

3273.360.150.

2578.3467.2149.2155.3589.1965.2187.3932.2697.

69.2232.1808.2802.2027.1766.3383.2540.3419.3792.2006.3501.3329.3302.2063.2324.

109.3686.165.360.3396.3765.3860.1867.4612.2425.3754.4376.4462.2980.3614.3342.3587.4254.2176.3125.4427.3541.3438.

Energy(keV)

477.591274.531368.551460.75320.08834.83846.76122.06810.781099.25264.66514.011836.06871.09724.18497.08621.93722.9488.03

65.7.76391.69159.00602.73427.89109.27364.48604.70537.311596.21133.51

1408.011274.51105.31279.20277.36727.18238.63609.31351.92240.99186.10911.2184.3788.47

312.17245.341001.0363.29185.7186.48106.12

HNF-SD-WW-DP-254, REV. 0Page : 3

Acquisition date : 18-JUL-1997 14:11:48MDA

(uCi/L)

1.7002E-011.3514E-029.9343E-033.7118E-011.2223E-012.3320E-022.3639E-029.2912E-032.1919E-025.1623E-021.8844E-021.7848E-028.5163E-032.4595E-024.3629E-021.8603E-023.5658E-012.0712E-022.9730E-012.1951E-022.3200E-029.5267E-031.7509E-025.5653E-022.9177E+001.6830E-021.7831E-026.8170E-029.8085E-031.4167E-014.8062E-023.9250E-023.9342E-021.3886E-021.8031E-012.9213E-012.5126E-024.2361E-021.5555E-012.7365E-012.6206E-011.1041E-019.4241E-014.2842E-02

1707E-020055E+015839E-021205E-015873E-021200E-02

3.7995E-02

4 1 2

HNF-SD-WM-DP-254, REV. 0Minimum Detectable Activity Report (continued) ' Page : 4

' " ' " 18-JUL-1997 14:11:48Sample ID

Nuclide

PU-239AM-243

: WL19373-STD

BckgndSum

3711.3541.

Acquisition date

Energy(keV)

129.3074.67

MDA(uCi/L)

1.2399E+022.5465E-02

413

* 222-S Laboratory Counting Room 18-JUL-1997 19:18:34.71

HNF-SD-WM-DP-254, REV. 0Removed? by:

>>>>>>>>>> SAMPLE INFORMATION <<<<<<<<<<Worklist #: 19373Sample ID: WL19373-BLKSample Size: 7.50000E-04 LDilution Factor: 1.00000E+00

Detector ID:File Number:Geometry:Count Time:Real Time:Dead Time:

COUNT INFORMATION <<<<<<<<<<GEA4dka300:[spec.GEA4]4g4488.cnf410 02:30:00.00 sec0 02:30:06.58 sec0.1%

>>>>>>>>>> ANALYSIS INFORMATION <<<<<<<<<<18-JUL-1997 16:47:52.6118-JUL-1997 16:47:52.612ENVGEAGLDKA3 0 0:[SPEC.GEA4]4 GBACK

Sample Count Time:Decayed to:Standard Deviations:Analysis Library:Analyst:Background Subtract:

>>>>>>>>>> CALIBRATION INFORMATION <<<<<<<<<<Date of last energy calibration: 10-DEC-1996 08:01:41.61Date of last efficiency calibration: 10-DEC-1996 08:21:14.07



00000

661.58*934.34969.08*1595.441730.48

- 145687510151

1.311.501.558.511.83

1323.301868.781938.273191.003461.09

13181864193331813452

1110

74.681.3

11105.92419

51.973.0

Fit Nuclides

CS-137

ActivityuCi/L

1.996E-02

4 1 4

Summary of- Nuclide ActivitySample ID : WL19373-BLK

HNF-SD-WM-DP-254, REV. 0 Page : 2Acquisition date : 18-JUL-1997 16:47:52

Total number of lines in spectrum 5Number of unidentified lines 2Number of lines tentatively identified by NID 3

Nuclide Type :

60.00%

Nuclide HlifeiO.OOY

Wtd Mean Wtd MeanUncorrected Decay Corr Decay Corr 2-Sigma

Decay uCi/L uCi/L 2-Sigma Error %Error Flags-3n •1.490E-

Total Activity

Grand Total Activity

Flags:

1.996E-02

1.996E-02

K" = Keyline not foundE" = Manually edited

1.996E-02

1.996E-02

"M" = Manually accepted"A" = Nuclide specific abn. limit

41S

ICOiH

>OO<•P — I I I I I I I 1 I I 1 1 I I I I I 1 I I I I I 1 I + I I I I I 1 I I 1 I I I I I I I I I 1 I + I ! I IfO j fT1 fT1 prl M f r i f t j FT1 M M M PI fT1 fT1 M fT1 frl FT1 rTl TT1 TT1 TT1 rT1 FT1 fT1 M TT1 M fri] FO M f r i M M TT1 rT1 fT1 FT1 fT1 fr1 M P1*! TT1 Tr1 M pri (VI f f l M TT1 M M

*^ rfj ^ ^ c\j p** f*1* cr t^ cr ô in *^ r*11* ro ^H in f o co CN * ^^ f^ co ^ * o in co c^ in r—H CO in r * fo ^H O in in r**" {**• co o^ in CN **d* in in ro co 3* ^J* p"* a\ ro

•H ^ ^

1 3

U

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epo

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LK

ro

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X!C g£? 3

U

m

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Nuc

li

vocsirjvor-roinroôirio^rHcn^ro^cOfHvor^c^

j o ro o ro & a\ o oo -31 o I-H <-H <T\ ai a> ro ro co o <-t CN m «-c o co o CN co CN o

CTt ro t—tcoc r i o ro ro - ^ rLnm ôo<^CN3*c j H i n rococNCS'^ j < ' d i ' v t < i ^cococr tco f y i i ^ t ' i ! 3 ' r-CN ^* *~ " ^ ô r** co o*\ C3 in i-n ^ * i c^ i CD CD t^ T^ CN CN CN CN r*~i co ^J* ^J1 I tn in tn c^ CD *^ r~i t-n CH CN CN CN CN CN CO C^ CO CO in ô

,1A(...<_ HNF-SD-WM-DP-254, REV. 0Minimum-'Detectable Activity Report (continued) Page : 4Sample ID : WL19373-BLK Acquisition date : 18-JUL-1997 16:47:52

Bckgnd Energy MDANuclide Sum (keV) (uCi/L)NP-239 987. 106.12 2.7366E-02PU-239 1081. 129.30 8.9939E+01AM-241 757. 59.54 5.2791E-02AM-243 1142. 74.67 1.9422E-02

417

******** *i<c * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * *

* 222-S Laboratory Counting Room 18-JUL-1997 22:13:35.96 *********************************************************************************

>>>>>>>>>> SAMPLE INFORMATION <<<<<<<<<<Worklist #: 19373Sample ID: S9700T1753-SAMSample Size: 7.50000E-04 LDilution Factor: 1.00000E+00

HNF-SD-WM-DP-254, REV. 0Removed by:

fVerified by:


>>>>>>>>>> ANALYSIS INFORMATION <<<<<<<<<<Sample Count Time: 18-JUL-1997 19:42:53.03Decayed to: 18-JUL-1997 19:42:53.03Standard Deviations: 2Analysis Library: ENVGEAAnalyst: SEHBackground Subtract: DKA300:[SPEC.GEA4]4GBACK



It Energy

59.21661.60*727.07*1630.421729.58

Area FWHM Channel Left Pw %Err

167680842646

1.48 118.731.38 1323.351.69 1454.260.95 3260.960.75 3459.28

1151318144932573454

8 70.212 18.610103.19 79.610 47.0


AM-241CS-137

6.731E-029.362E-02

Summary of Nuclide ActivitySample ID : S9700T1753-SAM


Total number of lines in spectrum 5Number of unidentified lines 2Number of lines tentatively identified by NID 3 60.00%

Nuclide Type

Nuclide HlifeCS-137 30.00Y•AM 241 432.20Y

Wtd MeanUncorrected

Decay uCi/L1.00 9.362E-021 .go 6.731E-02

Wtd MeanDecay Corr

uCi/L9.362E-026.731E-02

Decay Corr 2-Sigma2-Sigma Error %Error Flags

1.741E-02 18.604 . 724E-P2 70.19

Total Activity 1.609E-01 1.609E-01 ~7/

Grand Total Activity 1.609E-01

Flags: "K" = Keyline not found"E" = Manually edited

1.609E-01

"M1

"A1= Manually accepted= Nuclide specific abn. limit

419

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WUlUJUMUJtOWtOWMPHPPOOUiUKJl I i fc i l iUHtOWMtOHHOO ! O I fo UlUlOU>C0 -JCr»tfi»PJ if* CO H- H* 3

D O

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O. I H-

•aI—1 O t O U tOh-itOCOO^tO^JtOMl-JtOrf=»HJtJlU1<r>CAjl-'iC!>0>l-1Cocy\ *0<7\tfc»^100CDtJll0C0OC0t—'OOCOCOtt^CotOifc* •—-M ^

b is•§ ?

i i i i + i i"Y Y T Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y + Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y — rt cn~ ~>ooooooooooooooooooooooooooooooooooooo fl> £>

to H" to to to ^ ^

m

? o

Minimum-Detectable Activity Report (continued) HNF-SD-WM-DP-254, REV. 0 p a g e . 4

Sample ID : S9700T1753-SAM Acquisition date : 18-JUL-1997 19:42:53

Bckgnd Energy MDANuclide Sum (keV) (uCi/L)

NP-239 1011. 106.12 2.7701E-02PU-239 1043. 129.30 8.8360E+01AM-243 1209. 74.67 1.9977E-02

421

'4, HfcV. 0***^**V************************************************************************** 222-S Laboratory Counting Room 19-JUL-1997 00:50:16.58 *********************************************************************************

>>>>>>>>>> SAMPLE INFORMATION <<<<<<<<<<Worklist ft: 19373Sample ID: S97T001753-DUP Removed hyjSample Size: 7.50000E-04 LDilution Factor: 1.00000E+00

>>>>>>>>>> COUNT INFORMATIONDetector ID: GEA4File Number: dka300:[spec.GEA4]4g4491.cnfGeometry: 41Count Time: 0 02:30:00.00 secReal Time: 0 02:30:06.64 secDead Time: 0.1%

>>>>>>>>>> ANALYSIS INFORMATION <<<<<<<<<<Sample Count Time: 18-JUL-1997 22:19:32.55Decayed to: 18-JUL-1997 22:19:32.55Standard Deviations: 2Analysis Library: ENVGEAAnalyst: SEHBackground Subtract: DKA300:[SPEC.GEA4]4GBACK



t

00000

Energy

185.47*661.51*969.31*1592.661729.94

Area

160626955866

FWHM

1.491.401.641.582.02

Channel

371.201323.171938.733185.423460.02

Left

3681318193331813452

Pw

713141019

%Err

78.320.191.748.556.1

Fit Nuclides

RA-226CS-137

ActivityuCi/L

0.1788.630E-02

422

Summary of Nuclide ActivitySample ID : S97T001753-DUP


Total number of lines in spectrum 5Number of unidentified lines 2Number of lines tentatively identified by NID 3

Nuclide Type :

60.00%

Nuclide HlifeCS-137 30.00YRA-22C 1000.001*-

Wtd MeanUncorrected

Decay uCi/L1.00 8.630E-02

—3~-O0 1.784E-01—

Wtd MeanDecay Corr

uCi/L8.630E-021.784E-04-

Decay Corr 2-Sigma2-Sigma E r r o r %Error F lags

1.737E-02 20.121.398E-01 78.35

Total Activity : 2.647E-01 2.647E-01

Grand Total Activity : 2.647E-01

Flags: "K"11E"

Keyline not foundManually edited

2.647E-01

"M" = Manually accepted"A" = Nuclide specific abn. limit

423

gco

S)PHi-'WMPi-'HpHHHlMt

l~'OO*i Ui U1 ife W WO vD CO H W

C O ] a a i W mU1 (Ji O O3 -J

in s

3 3•O P-

en X

3 2

CD cM

o o(5

•• rtn> •

co n^D rti-3 tyO f~-Ofi)

Ln OCo rtI H-D <G h-

>cnt/icr\cof-jttia>h-icjcri3-JCJf-1cnCOVDh-'NJil^coNJa\CTi-J-J X 'S• 1—i o if )ti [ O l o O t O O ^ A O O C O f r ^ ] (DfD

< 1-1

TDoI-Jrt

OSP-O

I I I [ t + 1 [ 1 i I f I I f I I I 1 I I I I Ioooooooooooooooooooooooo

W t W W t

I I I I I I I I I I I { I I I I I I I I> o o o o o <

I I I 1 I

rtp-o3

rt

00I

Gtr1

I

0)

Minimum Detectable Activity Report (continued) HNF-SD-WM-DP-254, REV. 0p a g e . 4Sample ID : S97T001753-DUP A c q u i s i t i o n d a t e : 18-JUL-1997 22:19i32


PU-239 1031. 129.30 8.7868E+01AM-241 931. 59.54 5.8422E-02AM-243 1197. 74.67 1.9873E-02

4 2 5

* * * * * * ie-kii * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * *

* 22"2-S Laboratory Counting Room 19-JUL-1997 03:34:31.91 *********************************************************************************

>>>>>>>>>> SAMPLE INFORMATION <<<<<<<<<<Worklist S: 19373 HNF-SD-WM-DP-254, REV. 0Sample ID:Sample Size:Dilution Factor:

S97T1754-SAM1.00000E-03 L1.00000E+00

Removed by:

2131 in


>>>>>>>>>> ANALYSIS INFORMATION <<<<<<<<<<Sample Count Time: 19-JUL-1997 01:03:50.87Decayed to: 19-JUL-1997 01:03:50.87Standard Deviations: 2Analysis Library: ENVGEAAnalyst: MBBackground Subtract: DKA300:[SPEC.GEA4]4GBACK



It Energy

62.90661.68*1378.21*1509.241729.10

Area FWHM Channel Left Pw %Err

131163593954

1.47 126.091.46 1323.511.50 2756.511.61 3018.581.87 3458.33

1231317275030133452

7 76.812 68.515 99.610 78.713 47.6

Fit Nuclides

CS-137

ActivityuCi/L

1.679E-02

4 2 6

Summary of Nuclide ActivitySample ID : S97T1754-SAM

i imr-ou-»¥l\«-ur-ii04, HfcV. 0Page : 2

Acquisition date : 19-JUL-1997 01:03:50

Total number of lines in spectrum 5Number of unidentified lines 3Number of lines tentatively identified by NID 2 40.00%

Nuclide Type :

Nuclide HlifeiO.UOY"

Wtd Mean Wtd MeanUncorrected Decay Corr Decay Corr 2-Sigma

Decay uCi/L uCi/L 2-Sigma Error %Error Flags"1.00 1.679E-02 1.679E-0:; 1.14QB 02 -68.46

Grand

Flags: "

Total Activity :

Total Activity :

1.

1,

.679E-02

.679E-02

K" = Keyline not foundE" = Manually edited

1.

1.

"M""A"

679E-02

679E-02

= Manu= NuclManually acceptedNuclide specific abn. limit

427

Minimum-Detectable Activity ReportSample ID : S97T1754-SAM

Nuclide

BB-7NA-22NA-24K-40CR-51MN-54CO-5 6CO-57CO-5 8FE-59CO-60SE-75SR-85Y-88NB-94ZRNB-95RU-103RURH-106AG-108mCD-109AG-110MSN-113TE-123mSB-124SB-125TE-125m1-131CS-134BA-14 0LA-140CEPR-144EU-152EU-154EU-155HG-203TL-208BI-212PB-212BI-214PB-214RA-224•RA-226AC-228TH-228TH-2297A-233•JTH-2337A-2 34MTH-234U-235MP-237

BckgndSum

503.164.112.

2456.838.312.292.

1035.258.221.142.932.643.51 .

248.348.463.350.338.969.347.6.27.

1080.377.577.939.668.380.351.80.

1029.110.164.968.932.906.390.

1397.900.

1115.1204.1255.553.

1099.938.851.

1034.247.858.

1256.1085.

Energy(keV)

477.591274.531368.551460.75320.08834.83846.76122.06810.78

1099.251332.50264.66514.01

1836.06871.09724.18497.08621.93722.9488.03

657.76391.69159.00602.73427.89109.27364.48604.70537.31

1596.21133.51

1408.011274.51105.31279.20277.36727.18238.63609.31351.92240.99186.10911.2184.3788.47

312.17245.34

1001.0363.29

185.7186.48

HNF-SD-WIW-DP-^M. HfcV. UPage : 3

Acquisition date : 19-JUL-1997 01:03:50

MDA(uCi/L)

6.7675E-029.2393E-038.6365E-033.6241E-016.0711E-029.0657E-038.8892E-035.0307E-038.1177E-031.6844E-028.9566E-039.2632E-038.8152E-037.3827E-038.4009E-031.9474E-027.6831E-031.5085E-019.2142E-031.6051E-018.2672E-031.0068E-025.1255E-037.7211E-032.2916E-021.5634E+007.6603E-037.7812E-032.6982E-028.5120E-037.5475E-023.9642E-022.6845E-022.1187E-026.9738E-038.8235E-021.3566E-011.3924E-022.6004E-028.5239E-021.4465E-011.4003E-014.8208E-025.2383E-012.2897E-021.5601E-025.0009E+001.5803E-022.7080E-018.5195E-035.0866E-02

428

Minimum'Detectable Activity Report (continued) ' ' Page : 4Sample ID : S97T1754-SAM A c q u i s i t i o n d a t e : 19-JUL-1997 01:03:50


NP-239 981 . 106.12 2.0467E-02PD-239 1034. 129.30 6.6004E+01AM-241 798. 59.54 4.0625E-02AM-243 1182. 74.67 1.4817E-02

429

* * * * * * *-A" * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * *

* 222-S Laboratory Counting Room 19-JUL-1997 09:06:34.73 *********************************************************************************

SAMPLE INFORMATION <<<<<<<<<<19373S97T001754-DUP1.00000E-03 L1.00000E+00

Worklist tf:Sample ID:Sample Size:Dilution Factor:

Removed by:

Verified by:COUNT INFORMATION <<<<<<<<<<

Detector ID: GEA4File Number: dka300:[spec.GEA4]4g4495.cnfGeometry: 41Count Time: 0 02:30:00.00 secReal Time: 0 02:30:06.63 secDead Time: 0.1%

>>>>>>>>>> ANALYSIS INFORMATION <<<<<<<<<<Sample Count Time: 19-JUL--1997 06:35:51.83Decayed to: 19-JUL-1997 06:35:51.83Standard Deviations: 2Analysis Library: ENVGEAAnalyst: GLBackground Subtract: DKA300:[SPEC.GEA4]4GBACK

>>>>>>>>>> CALIBRATION INFORMATION <<<<<<<<<<Date of last energy calibration: 10-DEC-1996 08:01:41.61Date of last efficiency calibration: 10-DEC-1996 08:21:14.07

********************************************************************************



0000

5586619641764

.31

.67*

.74

.4 9*

782368051

1.35 1116.781.54 1323.481.87 1929.582.24 3529.12

111413181925

6 67.411 48.69 64.9


CS-137 2.437E-02

3518 20104.4

430

Sugary of Nuclide Activity HNF-SD-WM-DP-254, REV. 0 p a g e , 2

Sample ID : S97T001754-DUP Acquisition date : 19-JUL-1997 06:35:51

Total number of lines in spectrum • 4Number of unidentified lines 1Number of lines tentatively identified by NID 3 75.00%

Nuclide Type :Wtd Mean Wtd MeanUncorrected Decay Corr Decay Corr 2-Sigma

Nuclide Hlife Decay uCi/L uCi/L 2-Sigma Error %Error FlagsCS-137 ' 30.00Y 1.00 2.437E-02 2.437E-02 1.186E-02 48.65

Total Activity : 2.4 37E-02 2.437E-02

Grand Total Activity : 2.437E-02 2.437E-02

Flags: "K" = Keyline not found "M" = Manually accepted"E" = Manually edited "A" = Nuclide specific abn. limit

431

Minimum Detectable Activity ReportSample ID : S97T001754-DUP

Nuclide

BE-7NA-22NA-24K-40CR-51MN-54CO-56CO-5 7CO-58FE-59CO-60SE-75SR-85Y-88NB-94ZRNB-95RU-103RURH-106AG-108mCD-109AG-110MSN-113TE-12 3mSB-124SB--125TE~125m1-131CS-134BA-14 0LA-14 0CEPR-144EU-152EU-154EU-155HG-20 3TI.-20831-212PB-21231-214?B-214.1A-2243A-226AC-228TH-228TH-2 2 9PA-23 3UTH-233PA-234M"H-234U-235MP-237

BckgndSum

487.187.118.

2576.819.291.231.

1037.226.203.133.948.702.61.

253.329.489.354.326.964.338.616.

1089.418.586.

1003.7 00.4 18 .457 .63.

1083.134.187.919.927 .928.383.

1368.918,

1155.1157.1301.546.

1172.956.856.

1019.24 1 .898.

1300.1090.

.09

.18

Energy(keV)

477.591274.531368.551460.75320.08834.83846.76122.06810.781099.251332.50264.66514.011836.06871.724.497.08621.93722.9488.03

657.76391.69159.00602.73427.89109.27364.48604.70537.311596.21133.51

1408.011274.51105.31279.20277.36727. 18238.63609.31351.92240.99186.10911.2184.3788.47312.17245.341001.0363.29185.7186.48

HNF-SD-WM-DP-254, REV. 0 Page . 3Acquisition date : 19-JUL-1997 06:35:51

MDA(uCi/L)

6.6616E-029.8401E-038.8516E-033.7100E-016.0035E-028.7645E-037.9389E-035.0357E-037.6251E-031.6163E-028.6609E-039.3403E-039.2010E-038.0403E-038.4841E-031.8938E-027.8917E-031.5159E-019.0557E-031.6006E-018.1644E-039.9762E-035.1472E-038.1168E-032.3096E-021.6149E+007.8385E-038.1547E-033.0684E-027.5861E-037.7423E-024.3624E-022.8614E-022.0646E-026.9552E-038.9252E-021.3447E-011.3781E-022.6253E-028.6734E-021.4183E-011.4254E-014.7903E-025.4045E-012.3108E-021.5641E-024.9656E+001.5627E-022.7698E-018.6650E-035.1002E-02

4 3 2

. . HNF-SD-WM-DP-254, REV. 0Minimum Detectable Activity Report (continued) Page : 4Sample ID : S97T00I754-DUP Acquisition date : 19-JUL-1997 06:35s51

Bckand Energy MDANuciide S.-:, (keV) (uCi/L)NP-239 924. 106.12 1.9879E-02PU-239 1096. 129.30 6.7906E+01AM-241 818. 59.54 4.1116E-02AM-243 1177. 74.67 1.4782E-02

433


HNF-SD-WM-DP-254, REV. 0 Paê:


Analyst:

Method:

scl Instrument: AB12

Rev/Mod

Worklist Comment: T201, @SR90-01 S.S.

SeqType

1 STO

1 STD

1 STD2 BLHK-PREP

2 8LNK-PREP

2 BLNK-PREP

3 BLNK/BKQ

4 SAMPLE

4 SAMPLE

5 PW

5 DOT

5 DUP6 SPK

7 SAMP1B

7 SAMPLE7 SAMPLE

I»W8 DOT

9 SPK

Sample,? R A

897X00X753S97T001753S97T001753S97T001753S$7TO0l?S3S97T001753

S97T001754397T001754

S97T001754S97T0O1754

0

0

00

0

0

0

a 3

0 I

0 1

0 I

0 I

0 I

0 I

o i

0 I0

0 F

by Ludlum.

Test Matrix Actual

SSR90-01 SR90-01 SOLID

0SR9O-O1 SR90-01C SOLID

9SR90-01 SR9Q-01B SOLID

9SR90-01 SR90-01 SOLID

®SR90-O3, SR90-01C SOLID

(9SR90-01 SR90-01E SOLID

3SR90-O1 SR90-01 SOLID

®SR90-*01 SR90-01C SOLID

&SR90-01 SR90-01E SOLID

©SR50-01 SR30-01 SOLID©SR90-01 SR90-01C SOLID

9SR90u01 SRÔÔIE SOLID

®SR90-01 SR90-01 SOLID

9SR90-01 SR90-01C SOLID

«SR90-01 SR90-0IB SOLID

aSR90-01 SR90-01C SO1-IDaSR90-01 SR90-01E SOLID

©SR90-O1 SR90-01 SOLID

Final

2.35E-03100

1.00

10 01.00

1

K/A

N/A

1.37B-J100

1.002.39E-03

N/A

W/A

1001.00

2.39S-03

page for

Std:1.0ml

Found

2.39B-38.88E+011.38E+00<9.95E-49-89B+013.30E+021.15E+00

8.94E+014.14E+001.45S-3,

9.02E+013.93E+002.42E-03

9.03E+017.11E+00

9.56B+011.59E+012.44E-03

Book#

Spk:1.0mL

DL or Yield

100.00088.8001*380

95.900330.000

1-156

0.06+0000.0e+000

5>$74 R90.2003,930

101.255

0.0e+000

skm

Unit

% Recovery% Recovery% Cfc. Srrouci/sr% Recovery

uCi /gBLJWt/BKfi

% Recovery

% Ct . Er ro r

I'D% Recovery

% Cnt Er r

% Recovery

% Recovery

O,Oe+000 % Cfc. Brroc124 912 RDri

95.60015.900

102.092

% Recovery% Cut Er r

% Recovery

worklist# 19370



434

07/17/9713:37 HNF-SD-WM-DP-254, REV. 0

A-0004-i LABCORE Data Entry Template for Worklist# 19370

Analyst: S- L Instrument: AB00 /p? Book#

Method: LA-220-101 Rev/Mod.

Worklist Comment: T201, ©SR90-01 S.S. by Ludlum. Std: 1.0ml, Spk:1.0mL skm

S Type Sample# R A Test Matrix Group# Project

.1 STD ©SR90-01 SOLID

2 BLNK-PREP SSR90-01 SOLID

3 BLNK/BKG ©SR90-01 SOLID

4 SAMPLE S97T001753 0 F ©SR90-01 SOLID 97000311 T-201

Analytes Requested: SR90-01 , SR90-01C, SR90-01E

5 DUP S97T001753 0 F (8SR90-01 SOLID

6 SPK S97T001753 0 F OSR90-01 SOLID



8 DUP S97T001754 0 F (8SR90-01 SOLID

9 SPK S97T001754 0 F ©SR90-01 SOLID

Final page for worklist/ 19370




4 3 5


WORKBOOK PAGE: STD1Sr-89/90 : LA-220-101 (D-1), 102 (E-3), 104 (D-1) LIQUIDS STANDARD

DETECTOR NUMBER CARRIER ADDED in mL (CVA) 1.000STD TOTAL COUNTS JTCJ 20334 SROSS WEIGHT (W2)

COUNT TIME in MINUTES (CT) TARE WEIGHT (W1) 7.575719370 BACKGROUND in cpm (BKG) NET WEIGHT 0.0888

West! SAMPLE VOLUME in mL@SR90-01 DILUTION FACTOR

JSSJ 1.000 (DT) 2.62(DF)

DIGEST DILUTION FACTOR DDFLIQUID SAMPLE COUNT RATE (RsJ 2030.10 SR-90 EFFICIENCY FACTO (C1)

j^Batch NuniBefBS CRITICAL LEVEL (Lc) 1.09 Y-90 EFFICIENCY FACTOR (C2) 0.466097003494 TIME OF SEPARATION JSTJ 13:18 Rmax

(SD) 07/22/97 DETECTION LIMIT (Ld) 2.28TIME OF COUNT (TOC) 15:55 Sr-89/90 CONC. in uCi/L 2.3894E+00DATE OF COUNT

N/A STANDARD BOOK #(DOC) 07/22/97

t n S l e ' i « i B STANDARD VALUE in uCi/mL 2.3895E-03WL19370

iSS|n3trunient,C.6'de'$:WB27811

SEH

SAC

SCLB.DatfeC6m'plete'-;M Detection Levels

Sample Count Rate (Rs) = (Total Counts (TC) / Count Time (CT)) - Background in cpm (BKG)Sr-89/90 CONC in uCi/mL REPLACE RS WITH RMAX IF RS<=LCAND RS>=O OR REPLACE RS WITH LC IF RS<O

RS*DF*DDF*1000/((C1+C2*(1-e to the power of ((-natural log 2)/64.2*DT)))*SS*REC*2220000)NOTE: 64.2 = Half Life for Y-90 and Rec. = Fractional Carrier Recovery ((W2-W1) / (CVA * 0.1000))Relative Counting Error = The Square Root of ((TC + BKG * CT) / (TC - BKG * CT)*1.96)Percent Carrier Recovery = (Net Weight / Expected weight) * 100NOTE: Expected weight = CVA * 0.1

and Less Than Values are detennined from Procedure LA-508-002.Delta Time (hours) = ((DOC - SD) * 24) + (TOC - ST) /100

07/22/97 Sr-89/90 CONCENTRATION 2.39E-03 MCi/mL

03:20 PM RELATIVE COUNTING ERROR 1.4%

T-201 PERCENT CARRIER RECOVERY 88.8%

DETECTIONLEVEL

2.68E-06pCi/L

Analyst: SCL

Signature of Chemist: SA- SAC Date: Z.J 4J, i?STANDARD.W81 REV 2.0

I:\22010N\OUTYI9370.WB1 07/23/97 08:14:10


WORKBOOK PAGE: BLANK2LA-220-101/D-1 Sr-89/90 : LA-220-101 (D-1), 102 (E-3), 104 (D-1)

»BatcH-.Nurober^H CRITICAL LEVEL

JSristrumerifSode?!;.WB27811

SEH

SAC

SCL

07/23/97

07/22/97

03:20 PM

T-201

Sample Count Rate (Rs) = (Total Counts (TC) / Count Time (CT)) - Background in cpm (BKG)Sr-89/90 CONC in uCi/g Replace RS with RMAX if RS<=Lc and RS>=0 or Replace RS with Lc if RS<0

1000*DF/((C1+C2*(1-e to the power of ((-natural log 2)/64.2*DT)))*SS*(Dg/L)*REC*2220000)NOTE: 64.2 = Half Life for Y-90 and Rec. = Fractional Carrier Recovery ((W2-W1) / (CVA * 0.1000))Relative Counting Error = (The Square Root of (TC + BKG * CT) / (TC - BKG * CT))*1.96Percent Carrier Recovery = (Net Weight / Expected weight) * 100

tysimm&l NOTE: Expected weight = CVA * 0.1

Detection Levels and Less Than Values are determined from Procedure LA-508-002.lurs) = ((DOC - SD) * 24) + (TOC - ST) / 100

Sr-89/90 CONCENTRATION < 9.95E-04 liCi/gLESS THAN Value was Determined from Rmax.


>ERCENT CARRIER RECOVERY 88.9%

DETECTIONLEVEL

1.37E-03

Analyst: SCL 23-JUI-97Signature of Chemist:

BLANK.WB1REV2.0

Date: f?

437l:\22010N\OUT\19370.WB1 07/23/97 08:14:11

HNF-SD-WMI-DP-254, REV. 0WORKBOOK PAGE: SAM4Sr-89/90 : LA-220-101 (D-1), 102 (E-3), 104 (D-1)

mmmmmmmSAMPLE

wmmtmmut19370

®SR90-01

wtmmamm.SOLID

97003494

BSgBSRerBnlWIife0

SKS3iti'p'ie*<BJ%BffifeFUSION01

?SS,Si»;Sam'pte"#KS*SiS97T001753

glhstrufnentiCbdKSiWB27811

SSSPre'parediBySig*SEH

CMRPHMSMMMSAC

SCLiSfeDatetCo.rnpleteggi

07/23/97!||!Khalysis;DafeiS3®

07/22/97tMA'rialysfe'TimeSisi

03:20 PMjSf};Sample:Boiritl?*g

T-201

DETECTOR NUMBERTOTAL COUNTSCOUNT TIME in MINUTESBACKGROUND in cpmSAMPLE VOLUME in mLDILUTION FACTORDIGEST FACTOR (g/L)SAMPLE COUNT RATE

TIME OF SEPARATIONDATE OF SEPARATIONTIME OF COUNTDATE OF COUNT

(TC)(CD

(BKG)

DF(D9 /L

(Rs)

(Lc>(ST)(SD)

(TOO)(DOC)

122340

103.3

1.0001

1.947230.70

13:1807/22/97

17:0507/22/97

CARRIER ADDED in mLGROSS WEIGHTTARE WEIGHTNET WEIGHTDELTA TIME (HOURS)

IHKlilli^K•MMHHMSR-90 EFFICIENCY FACTOR

RmaxDETECTION LIMITSr-89/90 CONC in uCi/g

(CVA)<W2)(W1)<W3)(DT)

(C1)

(C2)

(Ld)

Sample Count Rate (Rs) = (Total Counts (TC) / Count Time (CT)) - Background in cpm (BKG)Sr-89/90 CONC in uCi/g Replace RS with RMAX if RS<=Lc and RS>=0 or Replace RS wth Lc if RS<0

RS*1000*DF/((C1+C2'(1-e to the power of ((-natural log 2)/64.2*DT)))*SS*(Dg/L)*REC*2220000)NOTE: 64.2 = Half Life for Y-90 and Reo. = FractionRelative Counting Error = (The Square Root of (TC +

SAMPLE1.000

7.61137.52190.0894

3.78

SB!0.4180

N/A2.28

1.3673E-01

al Carrier Recovery ((W2-W1) / (CVA * 6.1000))BKG * CT) / (TC - BKG * CT))*1.96

Percent Carrier Recovery = (Net Weight / Expected weight) * 100NOTE: Expected weight = CVA * 0.1Detection Levels and Less Than ValueDelta Time (hours) = ((DOC - SD) * 24;

Sr-89/90 CONCENTRATION

are determined from Procedure LA-508-002.+ (TOC-ST)/100

1.37E-01 uCi/g


PERCENT CARRIER RECOVERY 89.4%

DETECTIONLEVEL

1.35E-03uCi/g

Analyst: SCL 23-JUI-97Signature of Chemist:

SAMPLE.WB1REV2.0

l:\22010N\OUT\19370. WB1

4 3 807/23/97 08:14:11

HNF-SD-WM-DP-254, REV. 0WORKBOOK PAGE: DUPSSr-89/90 : LA-220-101 (D-1), 102 (E-3), 104 (D-1)

WB27811

SEH

SAC

SCL

07/23/97

03:20 PM

T-201

Sample Count Rate (Rs) = (Total Counts (TC) / Count Time (CT)) - Background in cpm (BKG)Sr-89/90 CONC in uCi/g Replace RS with RMAX if RS<=Lc and RS>=0 or Replace RS with Lc if RS<0RS*1000*DF/((C1+C2*(1-e to the power of ((-natural log 2)/64.2*DT)))*SS*(Dg/L)*REC*2220000)NOTE: 64.2 = Half Life for Y-90 and Reo. = Fractional Carrier Recovery ((W2-W1) / (CVA * 0.1000))Relative Counting Error = (The Square Root of (TC + BKG * CT) / (TC - BKG * CT))*1.96'eroent Carrier Recovery = (Net Weight / Expected weight) * 100

NOTE: Expected weight = CVA * 0.1Detection Levels and Less Than Values are determined from Procedure LA-508-002.Delta Time (hours) = ((DOC - SD) * 24) + (TOC - ST) /100

Sr-89/90 CONCENTRATION pCi/g



DETECTIONLEVEL

1.29E-03MCi/g

Analyst: SCL

Signature of Chemist:SAMPLE.WB1REV2.0

2.3. 7«A?)

l:\22010N\OUTM 9370.WB1

4 3 907/23/97 08:14:11



Sr-89/90 : LA-220-101 (D-1), 102 (E-3), 103 (E-2), 104 (D-1)tmmmpvamms

SPK

19370

(gSR90-01»»SJMatrix«W,«

SOLIDgBatch; Numbers

97003494

0jSSSampleJJrepsS'-

FUSION01SHSample;#KriSR

S97T001753£.lnstrument,,Codejf

WB27811WPrepared-By^s^

SEH

SACKS#Analyst8*iWf

SCLSDateiComplete:^

07/23/97KAi)alysisjDate.W

07/22/97fgArialysisjjIjmeyf?

03:20 PM«S.ampteRoiot*

T-201

DETECTOR NUMBERTOTAL COUNTSCOUNT TIME in MINUTESBACKGROUND In cpmSAMPLE VOLUME in mLDILUTION FACTORDIGEST FACTOR (g/L)TIME OF SEPARATIONDATE OF SEPARATIONTIME OF COUNTDATE OF COUNTDELTA TIME (hours)

(TC)(CT)

(BKG)(SS)

DF(D 9'L)

(ST)(SD)

(TOC)(DOC)

(DT)

1224004

103.3

1.0001

1.94713:23

07/22/9718:55

07/22/975.53

CARRIER ADDED in mL

GROSS WEIGHTTARE WEIGHTNET WEIGHT% CARRIER RECOVERYSPIKE VOLUME in mLSPIKE DILUTION FACTORSPIKE BOOK NUMBERSPIKE VALUE in uCi/mLSR-90 EFFICIENCY FACTORY-90 EFFICIENCY FACTORSr uCi/g IN SAMPLESr-89/90 CONC. in uCi/g

(CVA)

(W2)(W1)(W3)

(Rec)(Spk Vol)(Spk DF)(Spk BN)(Spk Val)

(C1)(C2)

(Sri)(Sr2)

(Note: If there is not enough sample for an analysis type INS in the Count Time result cell.)

Sample Count Rate (Rs) = (Total Counts (TC) / Count Time (CT)) - Background in cpm (BKG)Sr-89/90 CONC. in (iCi/gRS*DF/((C1 +C2*(1-e to the power of ((-natural log 2)/64.2*DT)))*SS*Dg/L*(1 L/1000mL)*(REC/100)*2CSC Actual in uCi/mL = Spk ValQC Found in pCi/mL = (Sr2 - Sr1) * ((Spk DF/Spk Vol* 1000 mL/L) / (DF/SS/(Dg/L)))Percent Carrier Recovery = (Net Weight / Expected Weight)* 100Spk val = value taken from RCTABLE and then decayed using a % life of 29.1 yearsNOTE: 64.2 = Half Life for Y-90NOTE: Expected Weight = CVA*0.1Percent Spike Recovery = (QC Found / QC Actual) * 100Delta Time (hours) = ((DOC-SD)*24) + (TOC-ST)/100

QC Actual in uCi/mL = 2.39E-03QC Found in uCi/mL = 2.42E-03Percent Spike Recovery = 101.4%

SPIKE1.000

7.69477.60450.090290.2%1.000

186B56

2.3895E-030.41800.4660

1.37E-11.3816E+00

220000)

[Analyst: SCL 23-Jul-97

•4

440l:\22010N\OUTM 9370. WB1 07/23/97 08:14:11


WORKBOOK PAGE: SAM7Sr-89/90 : LA-220-101 (D-1), 102 (E-3), 104 (D-1)

mmmmmsmSAMPLE

19370

@SR90-01

SOLID

WSBatch-Mumiemm97003494

SNKRerUMMK&go

DETECTOR NUMBERTOTAL COUNTSCOUNT TIME in MINUTESBACKGROUND in cpmSAMPLE VOLUME In mLDILUTION FACTOR

DIGEST FACTOR (g/L)SAMPLE COUNT RATECRITICAL LEVELTIME OF SEPARATIONDATE OF SEPARATIONTIME OF COUNT

BBSSnjplS'Brie^ft W DATE OF COUNTFUSION01

SS8Si-:Sample"#gKgj)S97T001754

sg.lristrurnent'Gb*def^WB27811

iSSPreparedsBy.-SiWiiSEH

WKChern ls tWf tSAC

SSSKAnalystMiSKSCL

Kpate Completefem!

07/23/97

SSTArjalysisDateSSsi07/22/97

iSAnWsislim'eiiSt03 20 PM

SjS'SampieTRoinfife4!T-201

(TC)(CT)

(BKG)(SS)

DF

(Ug/L(Rs)(Lc)(ST)(SD)

(TOC)(DOC)

1286310

3.31.000

1

1.98282.00

1.0913:23

07/22/9719:07

07/22/97


SR-90 EFFICIENCY FACTORY-90 EFFICIENCY FACTORRmaxDETECTION LIMITSr-89/90 CONC in uCi/g

(CVA)(W2)(W1)(W3)(DT)

HMmsuwP(C1)

(C2)

(Ld)


RS*1000*DF/((C1+C2*(1-e to the power of ((-natural log 2)/64.2*DT)))*SS*(Dg/L)*REC*2220000)

SAMPLE1.000

7.59027.49990.0903

5.73

nm0.4180

0.4660N/A2.28

4.6277E-02

NOTE: 64.2 = Half Life for Y-90 and Rec. = Fractional Carrier Recovery ((W2-W1) / (CVA * 0.1000))Relative Counting Error = (The Square Root of (TC + BKG * CT) / (TC - BKG * CT))*1Percent Carrier Recovery = (Net Weight / Expected weight) * 100NOTE: Expected weight = CVA * 0.1Detection Levels and Less Than ValueDelta Time (hours) = ((DOC - SD) * 24


»are determined from Procedure LA-508-002.+ (TOC-ST)/100

4.63E-02

.96

pCi/g



DETECTIONLEVEL

1.29E-03MCi/g

Analyst: Date: 23-Jul-97

Signature of Chemist: SAC 2-3 •?„/, f)SAMPLE.WB1 REV 2.0

4 4 1I:\22010N\OUT\19370.WB1 07/23/97 08:14:11

HNF-SD-Wy-DP-254, REV. 0WORKBOOK PAGE: DUP8Sr-89/90 : LA-220-101 (D-1), 102 (E-3), 104 (D-1)

TOTAL COUNTS (TC) 234 SROSS WEIGHT (W2) 7.6386COUNT TIME in MINUTES (CT) TARE WEIGHT (W1) 7.5430

19370 BACKGROUND in cpm (BKG) NET WEIGHT (W3) 0.09S6SAMPLE VOLUME In ItlL (SS) 1.000 DELTA TIME (HOURS) (DT)

@SR90-01 DILUTION FACTORIGEST FACTOR (g/n (Dg/L 1.984

SOLID SAMPLE COUNT RATE (Rs) 20.10 SR-90 EFFICIENCY FACTOR (CD 0.4180:RITICAL LEVEL (Lc) 1.09 Y-90 EFFICIENCY FACTOR (C2)j

97003494 TIME OF SEPARATIONTE OF SEPARATION

JSJj 13:23 RmaxDETECTION LIMIT

N/A(SD) 07/22/97 (Ld) 2.28

TIME OF COUNT (TOC) Sr-89/90 CONC in pCi/fl 1.0664E-02

FUSION01y r e p t t g g DATE OF COUNT (DOC) 07/22/97

WB27811

SAC

SCL

07/23/97

07/22/97

03:20 PM

T-201

Sample Count Rate (Rs) = (Total Counts (TC) / Count Time (CT)) - Background in cpm (BKG)Sr-89/90 CONC in uCi/g Replace RS with RMAX if RS<=Lc and RS>=0 or Replace RS with Lc if RS<0RS*1000*DF/((C1+C2*(1-e to the power of ((-natural log 2)/64.2*DT)))*SS*(Dg/L)*REC*2220000)NOTE: 64.2 = Half Life for Y-90 and Reo. = Fractional Carrier Recovery ((W2-W1) / (CVA * 0.1000))Relative Counting Error = (The Square Root of (TC + BKG * CT) / (TC - BKG * CT))*1.96Percent Carrier Recovery = (Net Weight / Expected weight) * 100NOTE: Expected weight = CVA * 0.1

Detection Levels and Less Than Values are determined from Procedure LA-508-002.Delta Time (hours) = ((DOC - SD) * 24) + (TOC - ST) /100

Sr-89/90 CONCENTRATION 1.07E-02 pCi/g



DETECTIONLEVEL

Analyst: SCL Date: 23-Jul-97

Signature of Chemist: SACSAMPLE.WB1REV2.0

I:\22010N\OUT\19370.WB1 07/23/97 08:14:11


WORKBOOK PAGE: SP1KE9

Sr-89/90 : LA-220-101 (D-1), 102 (E-3), 103 (E-2), 104 (D-1)

SPK

19370

«STest,Code-§te@SR90-01

gBE&rilatriKigjjjgj&tSOLID

HBRtorirNuitib.erife!97003494

SMfXRerurHfer-0

!KSample»erepSj-FUSION01

W&Sample-ftV,*-S97T001754

glnstrumentjCodeaWB27811

^Prepared BfeS%SEH

«*Chemislii£gg»-SAC

jSKPTAnalystWC;SCL

SsRate, Completed07/23/97

^Analysis Datefcfe07/22/97

*8maJysisuTimeS(s03:20 PM

T-201

TOTAL COUNTSCOUNT TIME in MINUTESBACKGROUND in cpmSAMPLE VOLUME in mLDILUTION FACTORDIGEST FACTOR (g/L)TIME OF SEPARATIONDATE OF SEPARATIONTIME OF COUNTDATE OF COUNTDELTA TIME (hours)

(TC)(CT)

(BKG)(SS)

DF

(Dg/L)(ST)(SD)

(TOC)(DOC)

(DT)

2299810

3.31.000

11.98213:23

07/22/9721:20

07/22/977.95

CARRIER ADDED in mL

GROSS WEIGHTFARE WEIGHTNET WEIGHT% CARRIER RECOVERYSPIKE VOLUME in mLSPIKE DILUTION FACTORSPIKE BOOK NUMBERSPIKE VALUE in uCi/mLSR-90 EFFICIENCY FACTORY-90 EFFICIENCY FACTORSr uCi/g IN SAMPLESr-89/90 CONC. in |iCi/g

(CVA)

<W2)(W1)(W3)

(Rec)(Spk Vol)(Spk DF)(Spk BN)(Spk Val)

(C1)(C2)

(Sr1)<Sr2>


Sample Count Rate (Rs) = (Total Counts (TC) / Count Time (CT)) - Background in opm (BKG)Sr-89/90 CONC. in uCi/gRS*DF/((C1 +C2'(1-e to the power of ((-natural log 2)/64.2*DT)))*SS*Dg/L*(1 L/1000mL)*(REC/100)*2QC Actual in uCi/mL = Spk ValQC Found in uCi/mL = (Sr2 - Sr1) * ((Spk DF/Spk Vol* 1000 mL/L) / (DF/SS/(Dg/L)))Percent Carrier Recovery = (Net Weight / Expected Weight)* 100Spk val = value taken from RCTABLE and then decayed using a J4 life of 29.1 yearsNOTE: 64.2 = Half Life for Y-90NOTE: Expected Weight = CVA*0.1Percent Spike Recovery = (QC Found / QC Actual) * 100Delta Time (hours) = ((DOC - SD) * 24) + (TOC - ST) /100

QC Actual in pCi/mL = 2.39E-03QC Found in pCi/mL = 2.44E-03Percent Spike Recovery = 101.9%

iPIKE

7.73667.64690.089789.7%1.000

186B56

2.3895E-030.41800.4660

4.63E-21.2751E+00

J20000)

[Analyst: Date: 23-Jul-97

l:\22010N\OUT\19370.WB14 4 3

07/23/97 08:14:12

worklistdata Version 1.005/15/9607/31/9711:03 HNF-SD-WM-DP-254, REV. 0

Page:


Analyst:

Method:

Worklist

Seqt>pe

1 StD

1 STD

1 STB

2 BLNK-PREP

2 BUnMNtg?

2 BLHX-PREP

3 BtHK/BKG

i SSMPOS

4 SAMPLE

5 £02

5 DUP

5 DUP

6 SPK

dpb Instrument:

Rev/Mod

AB12

Comment: RR#2 T201 Use 5mL sample. Use

Sample* R A

S97TQ017S4

S97T001754

S97T0017S4

S97T001754

S97T0017S4

0

0

0

0

0

0

0

0 V

0 F

0 *

0 F

0 P

Test Matrix

«SR90-01 SR90-01 SOMC

©SR90-01 SR90-01C SOLID

«6R9Q-Q1 SR90*01B SOXttt>

«SR90-01 SR90-01 SOLID

^SR^O- O^L SR90'*01C SOLXD

9SR90-O1 SR90-01E SOLID

ASR90-01 SR90-01 SOLID

«SR90*01 SR90-01C SOLID __

0SR9O-O1 SR90-01B SOLID _

«SR9Q-01 SR90-01 SOILED

OSR90-01 SR90-01C SOLID

©3R90-01 SR90-Q2B SOLtD

Actual

2.35fi~0i

100

1.00

1

100

1.00

1

N/A

100

1,00

Book#

lmL'STD as spike, sac

Found

2.52E-3

9.09E+01

1.24E+00

6.73E-4

S.92E+01

3.69E+01

2.5OE+O0

2.82E+00

1.17E-2

8.94E+01

S.97E+00

DL or Yield Unit

105.439

90.900

1.240

0.001

89.200

36.900

2.500

123.523

89.400

5.970

103.766

% Recovery

% Recovery

% Cfc. Brro

uCi/g

% Seeovery

uCi/g

uCi/g

% Ct. Error

RPD

% Recovery

% Cnt. Err

% Recovery



Reviewer "Signature

Analyst Signature

f7

Date

• / /


444

HNF-SD-WM-DP-254, REV. 007/28/9715:44


Analyst: 1)P& Instrument: ABOO IP- Book# OoS


Worklist Comment: RR#2 T201 Use 5mL sample. Use lmL STD as spike, sac

S Type Samplet R A Test Matrix Groupt Project

1 STD SSR90-01 SOLID

2 BLNK-PREP ©SR90-01 SOLID

3 BLNK/BKG ©SR90-01 SOLID



5 DUP S97T001754 0 F SSR90-01 SOLID

S SPK S97T001754 0 F ©SR90-01 SOLID


Analyst Signature Da Arialyst Signature Date

^ 7/s,/?7




WORKBOOK PAGE: STO1Sr-89/90 : LA-220-101 (D-1), 102 (E-3), 104 (D-1) LIQUIDS

STD TOTAL COUNTS (TC) GROSS WEIGHT (W2) 7.5970COUNT TIME in MINUTES (CT) TARE WEIGHT (W1) 7.5061BACKGROUND In cpm (BKG) NET WEIGHT (W3) 0.0909SAMPLE VOLUME in mL (SS) 1.000 16.80DILUTION FACTOR (DF)DIGEST DILUTION FACTOR DDFSAMPLE COUNT RATE (Rs) 2517.20 SR-90 EFFICIENCY FACTO (C1) 0.4180CRITICAL LEVEL JLc) Y-90 EFFICIENCY FACTOR (C2)TIME OF SEPARATION JSTJ 22:50 Rmax N/ADATE OF SEPARATION (SD) 07/29/97 DETECTION LIMIT (Ld) 2.62TIME OF COUNT (TOC) Sr-89/90 CONC. in pCi/L

OTP)e;ere"B» DATE OF COUNT (DOC) 07/30/97STANDARD BOOK #STANDARD VALUE in uCi/mL 2.3883E-03

WL19554gln'3trum.erit.C.oae;sJ

WB27811

SEH

SAC

Sample Count Rate (Rs) = (Total Counts (TC) / Count Time (CT)) - Background in cpm (BKG)Sr-89/90 CONC in uCi/mL REPLACE RS WITH RMAX IF RS<=LCAND RS>=O OR REPLACE RS WITH LC IF RSO

RS*DF*DDF*1000/((C1+C2*(1-e to the power of ((-natural log 2)/64.2*DT)))*SS*REC'222OOO0)NOTE: 64.2 = Half Life for Y-90 and Rec. = Fractional Carrier Recovery ((W2-W1) / (CVA • 0.1000))Relative Counting Error = The Square Root of ((TC + BKG * CT) / (TC - BKG * CT)*1.96)Percent Carrier Recovery = (Net Weight / Expected weight) * 100NOTE: Expected weight = CVA * 0.1Detection Levels and Less Than Values are determined from Procedure LA-508-002.Delta Time (hours) = ((DOC - SD) • 24) + (TOC - ST) /100

07/30/97 Sr-89/90 CONCENTRATION 2.52E-03 MCi/mL

05:00 AM RELATIVE COUNTING ERROR 1.2%

T-201 'ERCENT CARRIER RECOVERY 90.9%

DETECTIONLEVEL

2.62E-06uCi/L

Analyst: 31-Jul-97Signature of Chemist: SAC

STANDARD.WB1 REV 2.0

4 4 6l:\22010NVOU1M 9554.WB1 07/31/97 09:51:12

HNF-SD-WM-DP-254, REV. 0WORKBOOK PAGE: BLANK2LA-220-101/D-1 Sr-89/90 : LA-220-101 (D-1), 102 (E-3), 104 (D-1)

• K B i g m ^ a W t DATE OF COUNT

WB27811

SEH

07/31/97

07/30/97

05:00 AM

T-201

Sample Count Rate (Rs) = (Total Counts (TC) / Count Time (CT)) - Background in cpm (BKG)Sr-89/90 CONC in (jCi/g Replace RS with RMAX if RS<=Lc and RS>=0 or Replace RS with Lc If RS<0

*1000*DF/((C1+C2*(1-e to the power of ((-natural log 2)/64.2*DT)))*SS*(Dg/L)*REC*2220000)NOTE: 64.2 = Half Life for Y-90 and Rec. = Fractional Carrier Recovery ((W2-W1) / (CVA * 0.1000))[elative Counting Error = (The Square Root of (TC + BKG * CT) / (TC - BKG * CT))*1.96

Percent Carrier Recovery = (Net Weight / Expected weight) * 100NOTE: Expected weight = CVA * 0.1

Detection Levels and Less Than Values are determined from Procedure LA-508-002.irs) = ((DOC - SD) * 24) + (TOC - ST) / 100

Sr-89/90 CONCENTRATION uCi/g



DETECTIONLEVEL

2.67E-04uCi/g

Analyst: DPB Date: 31-Jul-97Signature of Chemist: SAC Date:

BLANK.WB1 REV 2.0

I:\22010N\OUT\19554.WB1447

07/31/97 09:51:12


WORKBOOK PAGE: SAM4Sr-89/90 : LA-220-101 (D-1), 102 (E-3), 104 (D-1)mmsmrypsmmm

SAMPLE

dmwormsmmm19554

^mTest.CodtfSSM@SR90-01

SOLID

mmswtMM97003680

2

FUSION01

wmmmWMm®S97T001754

•BsWrRenftCpdeKWB27811

SEH

SAC

DPB!»aMSPomplet8gg>

07/31/97i^fthalysis'DateSiS

07/30/97

ifcaiWSmliiH05 00 AM

T-201

DETECTOR NUMBERTOTAL COUNTSCOUNT TIME in MINUTESBACKGROUND in cpmSAMPLE VOLUME in mLDILUTION FACTORDIGEST FACTOR (g/L)SAMPLE COUNT RATECRITICAL LEVELTIME OF SEPARATIONDATE OF SEPARATIONTIME OF COUNTDATE OF COUNT

(TC)(CT)

(BKG)(SS)

DF(Dg/L

(Rs)(Lc)(ST)(SD)

(TOC)(DOC)

124961

104.4

5.0001

1.982491.70

1.2622:50

07/29/9717:50

07/30/97


•manmHSR-90 EFFICIENCY FACTOR

Y-90 EFFICIENCY FACTORRmaxDETECTION LIMITSr-89/90 CONC in uCi/g

(CVA)(W2)(W1)<W3)(DT)

mumwXBm(C1)<C2)

(Ld)


RS*1000*DF/((C1 +C2*(1-e to the power of ((-natural log 2)/64.2*DT)))*SS*(Dg/L)*REC*2220000)

SAMPLE1.000

7.61677.52710.0896

19.00

imsi1111110.41800.4660

N/A2.62

4.9450E-02

NOTE: 64.2 = Half Life for Y-90 and Rec. = Fractional Carrier Recovery ((W2-W1) / (CVA * 0.1000))Relative Counting Error = (The Square Root of (TC + BKG * CT) / (TC - BKG * CT))*1.96Percent Carrier Recovery = (Net Weight / Expected weight) * 100vIOTE: Expected weight = CVA • 0.1Detection Levels and Less Than ValueDelta Time (hours) = ((DOC - SD) * 24


are determined from Procedure LA-508-002.+ (TOC-ST)/100

4.95E-02 uCi/g



DETECTIONLEVEL

2.63E-04pCi/g

Analyst:

Signature of Chemist: Date:SAMPLE.WB1REV2.0

4 4 8I:\22010N\OUTO9554.WB1 07/31/97 09:51:12

HNF-SD-Wfvi-DP-254, REV. 0

WORKBOOK PAGE: DUP5Sr-89/90 : LA-220-101 (D-1), 102 (E-3), 104 (D-1)

i£Batch NurnbLr ^ j - CRITICAL LEVEL97003680 [TIME OF SEPARATION

SEH

SAC

DPB

Sample Courit Rate (Rs) = (Total Counts (TC) / Count Time (CT)) - Background in cpm (BKG)Sr-89/90 CONC in uCi/g Replace RS with RMAX if RS<=Lc and RS>=0 or Replace RS with Lc if RS<0RS*1000*DF/((C1 +C2*(1-e to the power of ((-natural log 2)/64.2*DT)))*SS*(Dg/L)*REC*2220000)NOTE: 64.2 = Half Life for Y-90 and Rec. = Fractional Carrier Recovery ((W2-W1) / (CVA • 0.1000))Relative Counting Error = (The Square Root of (TC + BKG * CT) / (TC - BKG * CT))*1.96'eroent Carrier Recovery = (Net Weight / Expected weight) * 100

NOTE: Expected weight = CVA" 0.1Detection Levels and Less Than Values are determined from Procedure LA-508-002.

SPate^Comple te ;^ Delta Time (hours) = ((DOC - SD) * 24) + (TOC - ST) /10007/31/97

07/30/97

05:00 AM

T-201




DETECTION

2.63E-04MCi/g

Analyst: DPB 31-JUI-97

Signature of Chemist: SACSAMPLE.WB1 REV 2.0

4 4 9t:\22010N\OUTYI9554.WB1 07/31/97 09:51:13


WORKBOOK PAGE SPIKE6

Sr-89/90 : LA-220-101 (D-1), 102 (E-3), 103 (E-2), 104 (D-1)iSM&ffliii

SPKSs8&IHQSgrFps|j£%'.i

19554ggKT.est Code>8I'S

@SR90-01^g#)Matnx^a*S5f

SOLIDHBa'tctf Number^

97003680

2SRSampleiErepSag

FUSION01SSi$t;Sarn pie fejii>»

S97T001754SJnstrument'Codej

WB27811»l?repared;BygSS

SEH

SAC

DPB

07/31/97gXfnalysis.Datesli

07/30/97jJgAnaly.sis;Timel»J

05:00 AMiUSample'vEointig;

T-201

DETECTOR NUMBERTOTAL COUNTSCOUNT TIME in MINUTESBACKGROUND in cpmSAMPLE VOLUME in mLDILUTION FACTORDIGEST FACTOR (g/L)TIME OF SEPARATIONDATE OF SEPARATIONTIME OF COUNTDATE OF COUNTDELTA TIME (hours)

(TC)(CT)

(BKG)(SS)

DF(D g/L)

(ST)(SD)

(TOC)(DOC)

(DT)

1229525

104.4

5.0001

1.98222:50

07/29/9718:10

07/30/9719.33

CARRIER ADDED in mL

GROSS WEIGHTTARE WEIGHTNET WEIGHT% CARRIER RECOVERYSPIKE VOLUME in mLSPIKE DILUTION FACTORSPIKE BOOK NUMBERSPIKE VALUE in uCi/mLSR-90 EFFICIENCY FACTORY-90 EFFICIENCY FACTORSrpCi/g IN SAMPLESr-89/90 CONC. in uCi/g

(CVA)

<W2)(W1)(W3)

(Rec)(Spk Vol)(SpkDF)(Spk BN)(Spk Val)

(C1)(C2)

(Sri)(Sr2)


Sample Count Rate (Rs) = (Total Counts (TC) / Count Time (CT)) - Background in cpm (BKG)Sr-89/90 CONC. in uCi/gRS*DF/((C1 +C2*(1 -e to the power of ((-natural log 2)/64.2*DT)))*SS*Dg/L*( 1L/100OmL)*(REC/100)*2QC Actual in uCi/mL = Spk VaiQC Found in uCi/mL = (Sr2 - Sr1) * ((Spk DF/Spk Vol* 1000 mL/L) / (DF/SS/(Dg/L)))Percent Carrier Recovery = (Net Weight / Expected Weight)' 100Spk val = value taken from RCTABLE and then decayed using a % life of 29.1 yearsNOTE: 64.2 = Half Life for Y-90NOTE: Expected Weight = CVA*0.1Percent Spike Recovery = (QC Found / QC Actual) * 100Delta Time (hours) = ((DOC - SD) * 24) + (TOC - ST) /100

QC Actual in uCi/mL = 2.39E-03QC Found in uCi/mL = 2.48E-03Percent Spike Recovery = 103.8%

SPIKE1.000

7.67947.591

0.088488.4%1.000

186B56

2.3883E-030.41800.4660

4.95E-22.9970E-01

220000)

[Analyst: DPB

450

l:\22010N\OUTO 9554.WB1 07/31/97 09:51:13

DISTRIBUTION SHEET

ToDistribution

FromProduction Planning & Control

Project Title/Work OrderHNF-SD-WH-DP-254, Rev. 0 "Tank 241-T-201, Core 192 AnalyticalResults for the Final Report"

Name MSINText Withall Attach

Page 1 of 1

Date: 08/07/97

EDT NO.: EDT-620415

ECN NO.: N/A

EDT/ECNONLY

DE&S Hanford. Inc.J. E. Meacham

U.S. Department of Energy. RLC. A. Babel

Lockheed Martin Hanford Corp.J. N. AppelK. G. CarothersT. A. HuT. J. KelleyM. J. KupferJ. B. SchafferL. A. StaufferJ. A. VoogdA. E. Young

Lockheed Martin Services. Inc.Central Files

Los Alamos Technical AssociatesM. T. Ellsworth

Pacific Northwest National LaboratoryS. J. HarrisK. L. Silvers

Waste Management of Hanford. Inc.D. C. HetzerJ. L. NuzumK. L. PowellC. M. SeidelLTIC

SGN Eurisys Services Corp.B. A. Higley

Defense Nuclear Federal Safety BoardRich Tontodonato625 Indiana Ave. N. W.Washington D.C. 20004

S7-14

S7-54

G3-21R2-11R2-11S7-21H5-49R2-12R2-11H5-03Rl-10

A3-88

X

X

X

X

1

XX

XXXXX

T6-06

K7-22K9-08

S6-31T6-06T6-04T6-04T6-03

H5-27

* Needs only releasing paperwork, not a copy of the released document.

620415 - international nuclear information system (inis)

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