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WHC-EP-0733Revision 1

" High-LevelWasteTank• RemediationTechnology

Integration Summary

C. R. DeLannoyC. SusieneEnserchEnvironmental,Incorporated

K. M. FowlerPacificNorthwestLaboratory

W. M. RobsonLawrenceLivermoreNationalLaboratory

J. M. CruseWestinghouseHanfordCompany

DatePublished

July 1994

Prepared for the U.S. Department of EnergyOffice of Technology Development

(_ Jl_'ti_ P.O. Box1970

Htfflf01tl_]llll_tllly Richland,Washington99352

Ha,nfordOpera_onsandEngineeringContxactorforthe.=>.ueparffnentof EnergyunderContractDE-AC06-87RL10930

Approved for PublicRelease p_t_;=_i__

MIC-EP-0733, Rev. 1Impact Level 4

Document Tttle: Htgh Level Waste Tank RemedtattonTechnology Integration Summary

Prepared by: K. II. FowlerW. 11. RobsonC. R. DeLannoyC. Sustene

/1_ 11.-Cruse_" - Dal_e "

- . _/Y • • . / /App,,,o,.e,,.: __, _..,K.,_S8. _../J_,'f;/R. L. GtTchrtst, Hanager Danceu rTechnology Demonstration Programs

RELEASE AUTHORIZATION

i i i, ii i iii i i, .,,,i .,

Document Number: WHC-EP-0733, Revision1

Do©ument Title: High-Level Waste Tank Remediation Technology IntegrationSummery

Release Date:July 15, 1994

iii i ., m|l IHI i iiii i i1,1 i ,., .i =. ,

41. 41..IF 4. ,I. 41. _ 41. 41. 41. 41. 41. ,I.

This document was reviewed following theprocedures described in WHC-CM-3-4 and is:

APPROVED FOR PUBLIC RELEASE

i1,1 iii i , iiii ii ii , ,i

WHC Information ReleaseAdministrationSpecialist:

_/_, /_Z_S"_4,.__ H.N. Boston 7/15/94(Signature) (Date)

A-6001-4,00 (07/94) MEF256

WHC-EP-0733REV I

HIGH LEVELWASTETANKRENEDIATIONTECHNOLOGYINTEGRATIONSUMMARY

ABSTRACT

The U. S. Department of Energy's Environmental Restoration and Waste

Management and Technology Development Programs are engaged in a number of

projects to develop, demonstrate, test, and evaluate new technologies to

support the cleanup and site remediation of more than 300 underground storage

tanks containing over 381,000 n_ (100 million ga7) of liquid radioactive mixed

waste. Significant development is needed within primary functions and in

determining an overall bounding strategy. This document is an update of

continuing work to summarize the overall strategy and to provide data

regarding technology development activities within the strategy. It is

intended to serve as an information resource to support understanding,.,

decision making, and integration of multip7 e program technology development\

activities. Recipients are encouraged to pr_,ide comments and input to the

authors for incorporation in future _evisions.

iv

WHC--EP-0733REV 1

CONTENTS

HIGH LEVELWASTETANK REMEDIATIONTECHNOLOGYINTEGRATIONSUMMARY ..... I

APPENDICES

A HIGH LEVELWASTETANKREMEDIATIONTECHNOLOGYDEVELOPMENTACTIVITIESCHART ............... A-I

B UST-IDTECHNOLOGYINTEGRATIONSYSTEMSOFTWAREAND USER GUIDE..... B-I

EPO733R1. JNC V

WHC-EP-0733REV1

HIGHLEVELWASfETANKREHEDIATIONTECHNOLOGYINTEGRATIONSUHHARY

This documentpresentsthe resultsof ongoingeffortswithintheDepartmentof Energy's(DOE)UndergroundStorageTank - IntegratedDemonstratioa(UST-ID)programto facilitatean integratedapproachindevelopingemergingtechnologiesneededfor tankwasteremediation.TheUST-IDis conductinga numberof technologydevelopmentprojectsaimedat tankwasteremediationat fiveUST-IDparticipatingsites: Hanford,SavannahRiver,IdahoNationalEngineeringLaboratory(INEL),Oak Ridge,and Fernald(Ohio).

Productionof nuclearmaterialshas beena majormissionof DOE and itspredecessoragenciesfor the last50 years. Theseactivitieshavecontributedto a substantialaccumulationof hazardous,radioactive,and mixedwastesat anumberof sites. One of DOE'smost significantchallengeswill be remediatingthe more than300 undergroundstoragetanksand associatednear-fieldenvironmentsat the participantsites. DOE has made a commitmentto remediatethe tank sitesthat are not in compliancewith stateand federalregulationsand to treatand disposeof the wastesin accordancewith acceptedpractice.This remediationprogramwillconstituteone of the most complexandresource-intensivecleanupactionseverattemptedby a governmentagency.

The cost of cleanupof the tank siteswill be prohibitiveusingsomeofthe currentbaselinetechnologies.Furthermore,majorgapsexistin keytechnologyareas. New and improvedtechnologiesare neededthat will supportthe baselinestrategies,reducecosts,accelerateclean-up,and enhancesafety. Accordingly,DOE'sWasteManagement(EM-30),EnvironmentalRestoration(EM-40),and TechnologyDevelopment(EM-50)Programsare engagedin a numberof projectsto develop,demonstrate,test,and evaluatenewtechnologiesto supportthe tankwastecleanupmission.

The EM-30Programat each sitehas the responsibilityto safelystoreandproceedto treatand disposeof existingand new wastesin a mannerthat isenvironmentallysound,technicallycorrect,safeto workersand the public,cost-effective,and in fullcompliancewith applicablelaws,regulations,andDOE Orders. To supporttheseremediationobjectives,EM-30must developthebaselinestrategyfor retrieval,treatment,anddisposal,and ensurethat theneededtechnologiesare developed.

The EM-40Programat each sitehas a similarmissionwith theresponsibilityto cleanup and restoresitesand facilitiesthat are no longerin service. As with the EM-30Program,all activitiesmust be performedin amannerthat is environmentallysound,technicallycorrect,safe to workersand

- the public,cost-effective,and in fullcompliancewith applicablelaws,regulations,and DOE Orders.

The EM-50Programis pursuingtechnologydevelopmentactivitiesatmultiplenationallaboratoriesandwith multiplemanagement/operatingcontractorsto supportthe site remediationefforts. The UST-IDtechnology

WHC-EP-0733REV 1

development activities are focused on two major elements: theCharacterization and Retrieval Program and the Waste Processing and DisposalProgram. In addition, the UST-ID works with the various EM-50 Research andDevelopment Programs to help transition emerging technologies to a stage wherethey are ready for demonstration. Programs include Characterization,Monitoring and Sensors Technology - Integrated Program, Robotics - IntegratedProgram, Efficient Separations and Processing - Integrated Program, and InSitu Remediation - Integrated Program. The UST-ID also maintains awareness ofprogress in other integrated demonstrations with technologies that may haverelated application in tank waste remedtation.

Appendix A to this document presents the "High Level Waste TankRemediation Technology Development Activities" chart, which shows the EM-30,EM-40, and EM-50 technology development activities arranged by majorprocessing functions in the current baseline strategy. The chart is intendedas a visual tool to aid in determining applicability of technologies and therelative emphasis placed on the various functional needs.

Appendix B provides the tnittal version of the "UST-ID TechnologyIntegration System," an EXCELR-basedcomputer program that presents the datafrom the chart and other related technology development information. Theprogram provides an opening "top-level" flow diagram that allows the user toaccess more detailed levels of information with simple mouse commands.Instructions are provided for loading the program onto a personal computer andfor operating it. Investigations are underway regarding loading the programonto one of several "on-line" data communication networks to allow access on areal-time basis.

" The current vision for this activity is to transition it to the proposedHigh-Level Waste Tanks Focus Group for continued use and development. Thenext revision is tentatively planned for December 1994. Recipients areencouraged to review both the chart and the program and to provide any inputand commentsto the authors.

The work reflected in this documentwas performed as part of the UST-ID,in Technical Task Plan RL421207, under the direction of the DOE, RichlandOperations Office, and the DOE-Headquarters, Office of Technology Development.

WHC-EP-0733REV 1

APPEND]XA

HIGH LEVELWASTETANKREMEDTATIONTECHNOLOGYDEVELOPMENTACTIVITIES CHART

A-1

Ii

II

I I -- I' II5lngllP:Shell l_anks

;ST Tank Waste Retrieval

SST RetrievalProjectsEM-30,TWRS

WHC .... Henders

c-io6Re_,val.W3_

WHC Henders,

""- WHC . Bail

_='_ced SluicingEM-30,TWRSWHC "rE

Total

Hartford 149 36.6Femald 4 2.8INEL 11 2.3SRS 8 2.1OR 91 0.8

UOqJOIql)-_nlill I iirlK| i I II I _ _*

e- - - Mixer _'umpsll r__-'_lelr :)yslems|

I I II IIIII II I II I IIIII IIII I I • .........

III I I II I III I I IIII IIII II IIII II

nk Waste RetnoYal

.=uii=sl"i=;.o .......... R_/,o.,_u.=hani=_ ........

_T'Re_.v=_oj_ts I i-ssTRO_e_''Projects ...... I pi'slodgjng& Convey_mceM

,_o,_v_s I IE_O.'rvvRs I FM'_'UST4D'Hc Hendersor, L_C ..n._e,sonI I_.' - .... otMr"_06Re_e_:W3_ I p1o6Re_ev,w_ I !wsu

_3o,_s ] IE_.qo,_s I/HC Henderson _/WHC HendersonJ pislodging& Conveyance'S,_c ....... .=_.yI p_c MoDaniell IEMS0UST._O

nhancedSluicing .......... I ps'rTrainingand"restingFacile/ .... i I_L ....

:M=3O,TWRS ! IEM-30,TWRS J Di'slodging&C°nveyanceS'.VH,C ,,_ TBD _NHC Shen! EM-50,UST-ID.... WHC

Robol_e/2ndGeneration/_m

EM-50,Robotics-IP Jl-ligh3:_ressureJetPNL Bennett IEM-50,UST-IDORNL Hamel IOuest ,PNL Evans

SNL Horschel IMeClluml-'ressb_'e_ystem/MMETC Beddick IEM-_,UST-tD

......................... .SNL _ ,.... Hawigan IUotM

0boii_ - Cross_ I llntegraledTestingM-50,Roboties-IP IEM-SO,UST-ID

L_L Evans IPNLHollenILSNL HarriganI ISimulantDevelopment

rD&DRobotics , J IEM-_.UST4DILPNL, S_;_ughton

- ICooperatJveTe'_erobotic'l_"eIEM-S0.B'W1DilNEL

ii iii i i_

IIII I I

Tank Waste Retrieval -- ,,,,

.......... IR_otir.4Mechani(=al,xer F,umpsll iranslelr :_yslem, I poO,._,=r,,,,,. .,=.or,_ I Ic°°p'_rs='_'e,,.o_,O_cI-

DST _etriev_,l Protect.':. I IEM-s°'Ro_o_c,-_P I IEM-SO.aWeD..... I II:_IL Ben_'_ "tNEL{ •

I I IIIIIIIII I II IIIIII III

I IIIIII I I III I

m __ _ii

" - SST Leakage MitJ=aiJon

,lodging8_'Co'nveyance Mechanics I lSubsurtac.Barriers Program ....i JlSh-lPInterface .........

4-50. UST-ID I IEM-30. TWRS I IEM.50, ISR.-IP

JL Ban rgerI _C Bazinett IPNL .......... Peterson,fl_ Summers I HampstenJ .............VJsQousLiquids

SU ........... CroweI iSubsurface"_an_';r Ideasibility;TPA "' EM-50, ISR-IPdodging & Conveyance 'Systems " IM-45-07A,-0_ LBL. Pruess,4-50, USTAD IEM-30. TWRS

4L Pinker JWHCLEnserch,Bovay Cruse Jl_draulic & DiffusionBarriersIEM.S0,ISP,JPslodging & Conveyance' 'Systems _ ,._ IBNL _ Heiser,4.50, UST-ID ibemonstrationTest Ranirlg & ,,

HC Mullen ,Procurement (on hold) [Flowable Grout Barriers J..... ITesl Site Prepardons (on hold) EM-50, ISR.-IP

,gh PressU';:e'Jet .... IEM-30,TWRS Golder/MIBRAG VossIwH, IGolder/Hoechst VosiJ

M-50.uestUST-ID Coleman .. C_ ..... , Hampden ISNL ...... ReaIpsl-_U Intenace

_cl,um I-'re'ssure:_ystem/Mlnung IF:M-50. UST-ID l_em,o=vP_.nnanceauamers "M.-50, UST-ID LWHC Cru. IEM-S0,ISI:_P

otM , Summers " ...... 1,4 ...... c_.,,I'S0nic Driilin'g/l"echnology

tegraledTiding I_/i_C50,VOC-ID jC_oe,Techpology' ...........M-50,UST-ID Md.ellan Elvl-50,ISR-IP

NL ........ Halhchell ,LWS_C, _ wi,e IOnNL Sw=e,

.o,°,o.v.,o0m.n,.... ! sos.o.moo.,,ooIM-50. UST-ID EM-50. ISFHPNOC , IEM-_,,s_PNL Golcar LNUS " S,augier IBNL <' Schweiss.ingNFL Snedeker I ' ' . ....

_ontJ'nuous Air Barrier " ' IHon_.ontalGrout Bamers Iooperative Telerobot_c Retrieval ! EM..50. METC IEM-50,ISI:_.IPIVl-50,BWID J LK&M.BDM Crocker IBNL Ridenour,tEL GriebenowJ ......

__ ilium _ nuulnl II I

I,I I1, _,,

1

DovelopmenlAotivitie,(Sheet1of2)

I I I IIII I II

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SchwoissingI

I 'Ridenour -;

ii

I

I

AI i

ii

WHC-EP-07&3. REV. 1

Figure A-I. High Level Waste Tank TechnologyDevelopment Aol_ee (Sheet 1 el 2)

...... ' ...... _-ROM PI_IOCESSlNG TO DST IN W'IERiM STOI::IAGE

i

_calResistance Tomography ..50, UST-ID .,,olC Ebe

JL, -- D=htl

JioImagil_'gTomogr_hy-50, UST4DtC Ebedein1Tech Ebedein,

i ,m

i i IL

L

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III1|

- - III I I k

TO SLUDGE WASHINGIDISSOLUTION "-

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--'mP""'"" t|

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= _1_, TWITS BazinI

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EM-30, TWRSWHC Bazi

.... IDST RetrievaJlW211 ne_t

" IEM-30,TWRSWHC BaziTotal

|11

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Chauraderizalion

- |1

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lln Situ'Viscometer 1

. IEM-30."rwRsIpr IL Colso

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IIII II II II II II II IIII IIII I I I ,11 iiisto RotriovaJ

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HODOUe.,/ZnO_J-'_nerauonArm l_ooperatrveIelerObOUCHetrleval=evaiProjects J EM-50. Robotics-IP JE_50,BWID

NRS J PNL Bennett IINEL GriebBazmet ORNL Hamel |INEL Bin

. _ PNL Evans;NL Herschel

etrievaI,W151 _ 4ETC Beddick

M::=,S J SNL _ Hamgan

Bazinet ....

, Inobotics- O'o. C_ ...... J..... IEM-SO,Robotics-IP Ieval,'W211 IPNL Evans

NRS ILANL HoUenIBazinel ISNL ..... H,amganI

....

' Id'8,oRob0_c$"......... IEM-SO,Robotics-IP

I_L , , S_oughtor,i i i iii i=1

I I II I I IIIII I I I III I

I I I I II __ I I IIIIII __

3)lrt

ii i _1 i ii iii i i :i II I I III III I Ill ,11 ,111

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__ometer' ilnSi_J_heology I | Light Dg_y U_li_y Arn_ ...... _ ii JEleotromagneticMoistureMeasureme

,Ins IEM-30.TWRS I EM-30,TWRS I IEM's°'CMST4P_ Colson, IPNL Shepard WHC PropsonJ IPNL HeWHC Srn_hJ "

i ooA'........... !..... _!.o_i,, lWSAC...... _"oyl E_O._S w_c B_..... WHC .....

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.q:tS I EM-50,CMST-IP ...... EM-50,CMST-IP, Mech Am,es ........ Marlin LightDutyUtilityArm WHC BLEM-30,ORNL ....MMESIOR

iiiii iiiii i, iii ii _' ii

-- ii i iii i ii

ugnt uuty"L_lW,=.rrn Ioteclion & Monitoring i=Ie_c=HeslstanceIor_ograpny ElVl-30,INEL

enl WhileDrilling" 1 II

,/L4D LLNL D=lyI ....Floran ,LLNL .... R,,amirezI.......... ILightDutyUtilityArm(LDUA)Systems

IEM-50,UST..ID

_,_,ch_o_o_ ' I lWHC C_e,,,CAD ISpar Cunliffe

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II I I II I

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lSNL KadleoI IPNL ,_

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leonePenetrometer -in Situ Char _ IPNL ColsonJIEM-50,CMST-IP .JLWHC ,,, Bun FE_ Surface Moisture Measurement J

EM-30, TWRS IWHC Win_emanI

i i

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nF_amanP3eldTest Facility I

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-- I I

IIII me i ii II

I I I I I I I I iii

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lion ] Heal C..ap.,Hot Cell E>dra=on. Physical Raman & IR Spectroscopy ' j J rr=nkV=p_rFlowM0n_or"Properties/Abrasivity,IC_/MS, Micro- EM-50, UST4D J JEIvl-30,TWRS

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WHC Winkelman _ber Optic Pl;ocess JWHC Riech EM-50, UST4D IPNL Hartman WSRC O'Rourke Roprosontadlive Santple RolriovadLANL Villan'oad "

.... PNL Shepard Acoustic EmissionMethod n _ludge Recovery Improvement

WHC Keole Elvl-50, UST..ID I EM-30, TWRSPNL Tingey ORNL Pepper =WHC Fran_on ........ 1 PNL Ballou .......

I WHC Dodd ILaser AblaS_n-_lassSpec. .... I Pilot Scale Retrieval .......

Jenkins| WHC Bechtold IE_S0,CMST-IP I EM-30, T'WRSPNL SlmmaJl IPNL Colson WHC Blmduced Spec PNL Smith -

PNL Baldwin Gamma Etlec_ on Fiber optic I, Koskelo WHC Hiller EM-50, CMST-IP IWHC Prilucik LANL Donohoei= i

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i ii it

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EM-50, UST-,ID EM-30, TWRS I IEM-50, UST-IDWHC Ebedein L.ANt. , Nogar, IWHC Mech

Raman & IR Spectroscopy Tank Vapor F1o_vMon_0r ..... | Continuous NH3 Monitoring ->

EM-50, UST-ID EIvI-30, TWRS J EM-50, MW-IP_,WHC Reich ORNL .... Jenkins ,SNL ,, Ottesen

Advanced Fiber Optic Spectroscopy" I Airborne Alpha - R/l" Monitoring

EM-50, UST-.ID J EM-50, MW-tPLLNL Kyle I..A_L Gritzo

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EM-50, UST-ID I ....W_RC , ,, O'R,ourk,e Roprosonlllive Sample Ro_ioval

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_ntaminant AnalysisAutomationEM-50, Robts-tPPNL Dodson

SNL Hamgan

INEL WildingORNL HamelLANL Hollen

iii _ i i

iiii

iii

II III

I II] " I I imll i i i roll ii I I

Solid/I.tquid Sop_rMion Orgainic (Comple3uml) Deslru©lion

E_MYS,_:_el_arabon o, ,HUTCH ,_.,ecW. _;rys,amza,on ! ,i.,,cttocn.m,caJuestruc_on j ,Urgan,c ues_cuon.....-3o,T_s IE_SO,ESF_P IEM-._,TWRS- IE_SO,UST-ID

L , C_son IVVHC Healing _ IPNL .......Schmidt [ORNL ....

Late Wash FilterDemo I_acuum Distillation IHeal& Digest Basic I IEle_tr°chemicalDestrlJct,

EM30 SRS IEMS0 ESRP IEM3Orwns I IEMSO/ESPlPWSRC NashNan_ntILANL Garcia IWHC Delegard [WSRCIPNL Schmiclti ......... _.........

.....! i jFiltrationto Remove TRU Sludges IEMS0ESPIP IEM30TV_SEM-30 ORNL Slmulant Development

MMES/OR Bond [ANL Nunez EIvI-30 TWRS |LANLWHC Hohl .........

Te;iraphenytborate _ecipilation " i_sian Sep&rations Work I I::_IL BryanI Eliminatiorvl::tecycle/RedL

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Continuo_JsPrecipitation IS_,lec_,C,_tall_tion l EI_0.TYroSEM.-30, INEL IElvl-50,ESPIP PNL Schmiclt /Hydrotherm'al _'0cessingWlNCO Boardman lwHC ...... Hefting L Eak,n IE_o, TwRs

..... , IPNL ....

Solids

Liquids

To CTree

Sludge Weshing/DissoluUon (Potentially In-Tank)

l.._b'Testing/_3tudies _ludge Washing & Dissolution ] -.EM-30 TWRS EM-50 UST-ID

PNL Lumelta MMESIOR ,E,,,g,,an =='==

PNL Elmore "

PNL Norton MVST Sludge Wash/Dissoluti()n

,PNL , Lalemina EM-50, ESPtP "MMES/OR Beahm

Field InsVSys.'DevelOpment ....EM-30, TWRS Dissolution w/HNO2WHC McClean EM-30, ORNL

" MMES/OR Youngblood

CorrosionAssessment, ....

pH Measurements in Pad Field IExtendedSludge Processing _.. EVAP RECYCLEEM--30, TWITS IE_.30,SRS _" ' "--"PNL ......... Bunnell |WSRC ......... Hay

Solids

To OffgasTreatment

I

t

I II

Cs Removal Sr/TRU Removal

_s_Jcbon ! ,,P" 'Vus..u'_u--'u ..... Jr.)._u.v,,opment ' ! ,_r[xMa, er,aJ$/_epara,'onsJST-ID IE_30.TWRS IEM-S0,UST-ID IEM-.30.TWOS

.. I:)NL . . LatemirHu., _ I_LWHC GaddI_L ... R_chmo.d"--W I.....

•_emiCaJDestructionSRP IEM'_'ICsIXDevelopmentrrestTWRS I /csExtra"°nT';ting'IEM.so,UST-ID I Is'_._p"a"°r'Test''iEM-_,TWRS..... H0bbs IPNL Carlson IWSRC ..... aible,r [WHC HertirPNL Kurathl , "

_ma/Prooe-s-sing .... = - IPNL L=eminaI ISKIDTest Unit ' ' ' I |Cation ExCh_ge-D(-,_so_oers----

rWRS PNL .rayI IE_50,UST4D I iE_3o._vRs.......... __auel°w ' IWSRC atbler ILANL ...............

[Ele.o.'m,ca,cstx 1 l ---

on_ewcle/Reduc_on IEM-30."rWRS Ic'Ex_r.._o.T.;".0 rmu_a_ w_ .................._icsinREDCWastes II:'NL SurmaIEM-30,SRS _ IEM.-30.TWRS_)RNL ......... "" IWSRC, Bibler |LANL Yarb

EM-3Q'TW_S Sludge/Supemate Process sr Removal - SrSpe_)ermal Processing _ LANL Marsh Tesling EM-30. INEL

TWRS ........... EM-50. UST-ID lWlNCO M,lh,_gan..... Schm,,= I_,=,_,ne:_lliCb'tltanle$ l MME,_OR

IEIvl-30, TWRS I Sr RemovaJ by CoprecipitatJon/LS,NL ..................... Brown jln-Situ Magnetically Assisted I Highly AJk,Waste

IEM.._,ESPIP ] EM-30. ORNLjcr_tallineSilic0titanaleIX J IANL Nunez MMESIOR Ke,IEM-50, ESPIP I[SNL ....... Brown Develop and Test Sorbents .........

EM-60, ESRP !Inorganic IX - FeCN trom PNL WesterHighly Alkaline Waste/:11

' Resorcinol torCs - REDC Waste Carbollide/CDC Process Jo EM-30, ORNL EM-50, SRS I= MMES/OR Kent WSRC McCabe '_

i i III II I

To Offgas ' MMESIOR Egan C,tustio RooyeloTreatmenl'

' .... "' c=u_ ....., C Recycle

-I_ EM-30, TWRS. WHC, PNL...........

Eleckolysi's'S_ll Spl_ngI I III III II II I

EM-30, INELWINCe McO

/ I IIII I I I I

Removal Teohnitium and Other Fix RemovM

r bK Ma,enals/'_epara,,ons al i=L;rysta,l,ne:_,,,cO,,tana,ei;_ ! , c _orp.on_esorp.on : i_a,,,ne _,i,co.tana,e _x......M-3oTWRS IE_60ES_P EM-,mTWOS IE_50ESPlP

'NL __ , Lafemin ISNL .... Brown lll='ll LANL _Schroede! [SNL Brow

,i Precip_5on Tests ........ Biphas;c Systems for Rx ExIT r¢_lais-Sppe_ ....................... IEM-50, ESPtP:M-3o_s EM-5oES_P E_0W_SVHC Herring IANL ,, , Chaiko LANL . ,,i, Nogal IANL Cha,,

_.or,_oh=_,__X_+or_,r,1 iDevelopandTestSorbef:;i;........ i Electr°chemicalTreatment- IRssi°n Pr°duct:_eparati°ns

:M-,_, TWRS lUgands.RllaJed Clays (::ST EM-30, SRS IEM-SOESPIPANL IEM-_ESPtP WSRC Hobbs L,LANL Afire

'......... IPNL& Industry Wesler ',,,' ......................Ru _.mo_b_o<.......... ] i(_,_sc AIl!e:l S,gnai) Ru Removal by Precipitalion/ Tc Removal Crown Ethers.M-30, TWI:IS I ' IX/Sorplion - Highly AIk, Waste EM..50,ESPIP

ANL , YarbroI IColoids 'DestrJction ' I EM-30, ORNL MMES/OR MoyE

IEM-50, ESPIP I MMESIOR Kent .....;rRemoval-Srsp'ec(TM) I IMMEs/°R Bond

;M-30, INEL I ....VINCO Miller

;rRemoval by Coprecipitation/{ighly AIk. Waste i ll,l II I ,,,,,,,,,,,,,_, ORNL4MES/OR Kent

I I I II II I IIII I _ I

I II I'1

r i i iiiiiiiiii ii ii I i

uslio Recycle

:austic Recycle ...... IRemoval &Reco/;_ ]

_c _L lU3L. _s ....

M-30, INEL EM..50, ESRP II l'

VINCO McCray WHC Herring

11,=,---

---- I IIIIIII I

IIII I I I II

Figure A-I. High Level Waste "Devolopmont A(:_Mtioo(Shoet ;

"' "' ' u_w............. ' "" ........ --mr_E' .........Evaporation LLW NT

-- , lll l ill i

.an=e_ u.W_-vapora_on...... jMoo,e_v_j_ncen_=or iu..wv_m_uo_ - -EM-30,TWRS IEM-S0,UST-iD IEM-30,rwns

......... Browr WHC ,,, [ANL. UCO N .... ChambedaJn' '=' IwHc Mo,

.... ..._ I_:_NL;i0r Rx Extr:..... I ..v MVST/LLW Evaporation LEM-30, ORNL .......

____ ChaikoI MMES/OR/ Kent ILLMelter Oevelo'i)ment

Sopar_ons UCON Davidson IEM-30.TWRS

Altrep "" '' '' .......... [Grout Program (__.ondng'enw)'

..... '" IEM-30, TWITS

own Ethers I IWHCIPNL

....... MoyerGrout/Evaporation-V_'ification/_C

EM-30, ORNLa MMESIORI

Bonnc! "

• Walker,-- |

l

a Disposal Option; ...., EM..30, INEL

-- , , o WINCO i

I

n Fossil-Fired Vitri_'ca_on', EM.-50, Misc.

-- "' ' -- a '_> Vorteci i ..ill

linnlli i iiiii,i

I

I

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--- II

I

I

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OFPGAS ]rHEATMENT T .......

gaSTreatmoni .... ] I'bont, Monitor"Diode Lasers l_o,TwRs IEM-_O._4P I

C Roal lSNL Otlesen|

PNL Morrey! ......PNL S_gnvi _rbome Alpha- R/T Monitoring"......I

L H-finalIEM's°'Mw'iP IILANL G_oI

I I

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Figure A..1 High Level Waste Tank TechnologyDevelopment Aoirvities(Shoot 2 of 2)

A

1, , , W TREATMENT """ '" 'W Evaporation EL

___ j_ I-.'roces$UeVelOp'menl jLLW P..v_oratlbn '" iMOOllel::vap'JConcentralor "' ILLW v_rmcuon ' j IEM--50/UST-ID IEM.3O,TWRS IEM.S0,UST-ID IEM-30,TWRS J IMMES/OR MattusWHC __ IANL,MCON Chamberlain _ IWHC Murkowski ..............

............... I_pNL CreerJJP_'_ethy_'n.'Encapsulation IMVST/1.LWEvaporation L , elal,J IEM-50/UST-IDEM-30. ORNL " ' IBNL Kaib

MMES/OR/ Kent LL Melter D.velopmen, J J

LICON Davidson EM30 TWRS BioJogicd Destruction

WHC ....... Real EM50 USTIDEG&G/ID Andrews

II I i I I IIII I I i = =

lGr'outI_ogram (Contingency) ! J

IEM-30.TWRS IMW_r_Gatio_........

IC IEM-SO,ESPIPL ,,, Westsik JPNL , Peters

Grout/Evaporation-V'drification/ IPhos.-Bonded Ceramics JNAC IEMSOESPIP IP ............. EM30 ORNL IANL Wagh

= MMES/OR Baldwin 'I

o Bonng/White Jwltte Porm I-'enormance r,.,;rn, i. m " Walker/Mattus IEM-S0,ESPIP Im I IBNL Fuhrmann

m Disposal Options .......

, EM-30. INEL _ Vdr_ic_0'n ....=_ o WINCe ,, Siemer nE_6OESRP

, IWSRC ....... Bickfordn iFossil Fired Vitrification Im EMS0 Misc J

o Vortec PattenJ "..I

!

' DISPOSALI

I

IJ

!

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I

I

__,_s ...... T .....YREATMENT

Otfgas Treatment .... J _-.ont. Monitor-Diode Lasers J

EM-3O,_s j IE_So._4F, I

V_C Roal I_SNL OltesenJ

PNL MorreyJPNL Sevignyj JAirbomeAlpha-R/T Monitonng J

_, ._ F_.so.,._,p It_' _=oI

II I_ I III -- I III

!

I

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.,,= rl

on Assessment,

..urement.inRadRe,d IExtead;'_t'Sludge_oo,.sin_..... I _C:LE ......TWRS IEM-_.SRS '- ' '"'"" '....... '......

......... Bunne!llWSnC........... Hay

_lids

To OltllasTreatment

|

!

! n.oo--''_sat.tlo,t _ _ a=

_n Engin'ering. '........ _ In-an e. ustlc as Calcine Residue Leaching !....ent Development, IEM-30,TWRS EM-30, TWRS EM-50, ESPIP _ Bench/."

:.ionChemist_ PNL Bunnell PNL Lumetla WHC .... Culley EM-30,

TWRS PNL Lafemina AI Removal' .... PNL

- "' - ' TWRS EM-50, ESPIP PNL

1 Reconstitution ......... PNL Schmidl MMESIOR ..... Egan PNL

ate Other Processes IEM-3O,INEL "'"--TVVI:_S [ o,nallo ,sso ubon WINCO Herbsl

Kuralh IEM'50' UST-ID EM-30.

-'..... WHC Henddckson WHC .......

EM-30.WHCiimm=m,_

EM-30/TLANL

EM-30/TLANL

LANL

EF

"Ec/ystaninEM-30, TSNt.

EM-30. II_WINCO....

I

............. II I III III I II I I II I I II

To LLWV'drili©aUon

- I I Ill Ig I I I

Advanoed Sludge I_ro©essing

I Separ_ons_ech. Renew ' 'Sludge Washing & Di,solutJon ' ' I

ohing =-,=,11 Bench/Solvent Extraction EM-50. UST-ID

Culley EM-30. TWITS MMES/OR EganPNL SevignlII=l= I

I PNL Lumett TRUEX Model Validalion

PNL Bunne EM..50, UST-ID

....... Egan PNL Kurath ..M.MES/OR Felker

WHCEM-30.CcSolids Behavior Tests......TWRS . Hohl! '_'RuEX M°d'. Devel°p_n.,ANL,EM-50, UST-ID Vand.grift.......... i

EM-30.C°rr°s'°nTests/ReqtSTWRS ,1 Tech Exchange" CEA FranceIEM-50. UST-ID HLW Ev, )Ol'liionWHC Hoh MMESIOR Jubin HLW Ev_ralion ....... pEM-30 TWRS

]R_JRemovalby_ ........... '| Sequestering Agent; for TRU ...... WHCEM-3(_'rwns I EM-SOESP_P .......,LANE....... YarbroI LANE Jatvlnen I-_LWI=vaporaton

Elvl-30. INEL !E..atlOh-_h-_irl_8--l;K/iZ_b?b-6iS- ........ I I ,=K :_luage i realmen! I WlNCO Wood

E_s I IEM's°'ESPtP I ....L_NL sv_ i IPNL ou,nn "

_L_LN_....... Marsh| I _dv" Processing/Clean Option IIHigh Gl'adient Magnetic Sep I IEM-50,ESPIP IIEM'3u1_Rs ! 1ANE Horwitz I!,,LANL................ .__AvertsI

Continuous Chromatography I

IGTMEnhancements, ' ] EM-50, ESPIP

ITRUEX/SRF.XDevel. Test ritti MMESIOR WilliamsIEM-30.TWnS

IANL Vandeg /Talspeak IANL HorwitzI IEM-S0,ESPIP

' IMMESIOR Toth

-_NM.30CDevelopment rwfiz_

TWRS Cs. Sr Ru Removal by IX/L Ho Precipdation

EIvI-30, ORNL

EM-30, TWRS

NL Bro I_s Removal-AMP; CSTIEM-30,INELi #1ii

fRUEX; SREX: Crown Ethers I _V1NCO MillerCMP: CMPO !EM-30, INEL

IWINCO BrewerL

HLW Evap_ralJor_ jMobit_' kvap JConcentralor IEM-SO,TWnS IEM-SO.dST-ID I ,_

WHC....... IANL.... Ch,_be.=,,IJill II

IHLW l::v_oraton I

IF..k_k30,INELI_NCO Woodii |1 i i

I IIIII III I I I

.......... Systems Analysis/Crosscut

E_vHIV_cSySIemsEngineering .... Clean OptionStudy

•TWRS Elvl-50,UST-IDHolmes MMESIOR Mall,

_! BartonBoomer IESPIPCoordin_on ....WoodsIEM-_O,ESPIP

lV_C......... et=IPNL ,,

ematJve Process Evaluation .... i ESPIP Support "

30. TWRS I EM-50. ESRP

Barton I MMES/OR W

WHC Sutherlandi "PNL BrothersI I_lo_al I-'r'_cess'l::valuauon '"

C BearyI IEIVl-50,ESPIPI=sAIc , Nicholson! IWHC .... Se,

_lter Co_:'osi(_nTesting ' | Waste Processing Advisory

EM-30. TWRS i GroupWHC Schwenk EM-.30. SRS

WHC ..... BritonI ,,WSRC ..... Thorn

_'_/ster_sAna_is .... i ID'/_amicComputer " 'S,mulabon

E_S I IE_30,SRSLANL ,.FarishIWSRC ,I I i I I iiiii ii i i• iiiiii

IExperimentalInfra,tructure i IIntegrateaFlowsheetDevel.iEM'30/TWns ! !EM-30,INEL_LANL Buetow_ |WINCC,

i -- i _ i _ rInn.

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.TWRS IEM-50.MW-IP

WHC Powell IPNL , Pete_

.._ PNL MorreyI,,, , ' ' " ........... v PhIL SevignyI WasteFormPedormanceCrit.

,mL ,,t=1 IE_s°'_4pIBNL Fuhrmar

SSrredMelter ' ' ' HLW'_driflcationEM.-30.SRS EM-30,INEL

' WSRC Smith WINCO Woo

i lll il ii

I n I

:is/Crosscut

,eering ..... dean Optionstudy .......EM-50,UST-ID

Holmes IMMES/OR MalkemusBarton

Boomer IE'SPIPCoordination "Woods IEM-50,ESPIP

, etal L__L Kuhn

tess Evalua_'on' ' IESRPSupport "IE_r,o,ESPIP

Barton IMMES/OR WatsonSuthedand

Brothersl_uooalProcessl::vaJuauoneea_ JEM-SO,ESRP

NicholsonlWHC Seeman HIGHL_

"tTesdng' '1Iwaste Pr°cessingAdvisOryIGr°up I DEVEL,SohwenkIEM-30. $RS Compile..... BdtonlIWS,RC Thompsonl Particip,

,sis IDynamioComputerSimulabon nIEM-30.SRS I Jun e 15,, ,, Farish IWSRC Wach

nfr_aslructure I IIntegratedRowsheetDevel. '"' Prep are

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[V_:ts_r°gram(Baseline) - i IEM'_'IMW VitrificatiOnMw.ipPowell IPNL Peters

MorreyISe._gnyI IWa._teForm Performance Crit. _*'-_

,et IEM's°' w-,P...... [BNL Fuhrmann,

SRS IEM-30,INEL DISPOSALSmith IWNCO Wood

IIIII IIII

I I

Key

T_le ...... I ,ElVl-50/lntegrated[DOE/Field Program Element JDemonstrations

Contraclor/Lab, PI IFunded ActMties o

i.-MJ,._J.'1WH_ Ei_1-t>U,lntegraleo I-'rogams .........Funded Activities Funded Acth_es

i i i H i ii i

Funded AclJvilies

IFunded A_e,si

EM-30/'T_VRS/SNL IEM-30,INEL

Funded AclJvilJes IFundedActivitiesr i

EM-30/_51/_NL I_¢-30,SRS 'Funded Activities Funded Activities

ii iii i i

I I

HIGH LEVEL WASTE TANK REMEDIA T/ON TECHNOLOGYDE VEL OPMEN T A C TIVITIES

Compilation of EM-30. EM-40 and EM-50 Projects atParticipating DOE Sites

June 15. 1994

Prepared by:Underground Storage Tank-lnteorated DemonstrationJ. M. Cruse. WHC. 509-372-1024K. M. Fowler. PNL 509-372-4233

_IHC-EP-0733REV1

APPENDIXB

UST-ID TECHNOLOGYINTEGRATIONSYSTERSOFTWAREANDUSER'SGUIDE

B-]

WHC-EP-0733REV1

UST-IDTECHNOLOGYINTEGRATIONSYSTEMUSER'S GUIDE

1.0 INTRODUCTION

The UndergroundStorage Tank - Integrated Demonstration (UST-ID)Technology Integration System (TIS) provides you with a computerized directoryof the technologies being developed to support high-level waste tankremediation at multiple U.S. Departmentof Energy (DOE) sites. By using yourmouseto click on a series of buttons, you can call up a complete flow diagramof a particular technology function, obtain general information about thefunction, and then find out which projects (technology developmentactivities)are being conducted, along with information about the projects. Suchalayered information systemwill enable you to obtain only as muchinformationon a technology as you require. This program and guide _ssumesthat you havea basic knowledgeof computersand of Microsoft Windows.

2.0 COMPUTERREQUIREMENTS

To run the UST-ID TIS programyou need the following:

• IBMz or ]00% IBM-compatible computerwith 4 megabytes(MB) ofrandomaccessmemory(RAM)(for maximumefficiency in running theprogram, at least 6 MBof RAMis recommended)

• EGA/VGAmonitor with a screen resolution of either 640 x 480 or 800x 600 dots per inch

• A 3.5-in. high-density floppy disk drive

• At least 5 MBavailable for use on your hard drive

• Microsoft Windows(Version 3.1) andMicrosoft Excelz (Version 4.0)installed on your hard drive (Excel Version 5.0 is NOTcompatiblewith the UST-ID TIS program)

• A computermousecompatible with Windows._

I MicrosoftWindowsis a trademarkof MicrosoftCorporation.

z IBM is a trademarkof InternationalBusinessMachines,Incorporated.

z MicrosoftExcelis a trademarkof MicrosoftCorporation.

B-2

WHC-EP-0733REV1

3.0 PROGRAMINSTALLATION

To install UST-ID TIS, follow these steps•

1. Insert the 3.5-in. installation disk into either your A or B drive.

2. If you inserted the disk in the A drive, type A: (or B: if the diskis in the B drive) andpress Enter. Your screen should nowshow"A: "

3. At the A: prompt, type install. Your screen should show"A:install." Press Enter. The program is nowbeing copied ontoyour hard drive (C drive) and placed in the UST-ID-TIS D_rector¥.If this directory does not already exist, the installation programwill automatically create it.

4.0 PROGRAMEXECUTION

Onceyou have installedthe UST-IDTIS programon your harddrive,youcan enterthe programfrom eitherDOS or Windows. It is usefulto noteherethatthe UST-IDTIS programwas writtenas an add-onapplicationto ExcelVersion4.0.

4.1 RUNNINGTHEPROGRAMFROMDOS

At the C:\UST-ID\TIS prompt, type TIS and press Enter. This willautomatically take you into Excel for Windowsand into the UST-ID TIS.

NOTE: You must first close out any startup program on your screen, suchas E-mail, before you can get into Excel and the UST-ID TIS program.

4.2 RUNNINGTHEPROGRAMFROMWINDOWS

1. Once in Windows,double click on the Excel icon. This will open theExcel program.

2. Once in Excel, click on "Open"under the File menu. "Directories"will appear.

3. Doubleclickon Directoriesto openthe file,and thendoubleclickon "C:\"to openthe directoryfor the C drive.

4. Scrolldown and doubleclickon "UST-ID." "TIS"will appear.

5. Doubleclickon "TIS." "Files"will appear.

6. Under"Files,"doubleclickon "TIS.XLS."

B-3

WHC-EP-0733REV1

5.0 PROGRAMFEATURES

The UST-IDTIS programwas designedto be user friendly.ThroughExcel,you gaineasy accessto the program. The UST-IDTIS programthen operatesinan Excelworkspacecustomizedspecificallyfor the program. Simplyclickingon clearlylabeledon-screenbuttonswithinthis customizedframeworkwilltakeyou to any of the programfunctions. The specialformattingfeaturesusedto customizethe Excelworkspaceand the on-screenbuttonsusedthroughoutthe programaredescribedbelow.

5.1 CUSTOMFORMATTING

The Excelworkspacehas beenmodifiedonly for use by the UST-IDTISprogram. Modificationsincluderemovingthe standardExcelmenu bar,toolbars,formulabar,messagebar, andscrollbars. The formattedworkspaceis shownin FigureB-].

The UST-IDTIS programautomaticallyfitsall graphicsto the screensize. To viewdiagramsin theirentiretyon screenwithoutscrolling,ascreenresolutiondialogbox appears(FigureB-I). It will ask you to selectthe currentresolutionof the computerscreen. Thiswilldeterminetherelativesizeof the objectson screen. Only two computerscreenchoicesaregiven: 640 x 480 dots per inch(standardresolution)or800 x 600 dots perinch (highresolution).Ifyou do not knowthe currentresolutionof yourscreen,you can findthe informationby activatingWindowsSetupfromtheProgramManager. If it showsa VGA display,the resolutionof your screenis640 x 480 dots per inch. VGA is the most commonscreendisplayand is thedefaultdisplayon mostmonitors. If it showsa differentcurrentscreenresolutionfromthe two choiceslistedabove,you shouldchangeit so that thegraphicscan be viewedproperly.To make the change,go to the WindowsSetupunderProgramManagerand clickon the "Options"menu. WithinOptions,clickon "ChangeSystemSettings."Severaloptionswill appearincluding"Display."Clickon "Display,"then scrolldown and clickon "VGA."

Finally,all modelelementsarewriteprotected.Thismeansyou cannotchangeany partof the program. This prevenLsyou from accidentallycausingUST-IDTIS errors.

5.2 ON-SCREENBUTTONS

On-screenbuttonscontrolthe entireUST-IDTIS program. You activatethesebuttonssimplyby clickingon themwiththe mouse. You will use mostbuttonsto move fromone technologydiagramto another. Thesebuttonshavenamescorrespondingto the diagramtheyactivate. Otherbuttonsperformfunctionssuch printingand exitingthe program. Thesebuttonsalsohavecorrespondingnames. The buttonsavailable(shownin FigureB-2)are:"Technologies,""TechnologyInformation,""Projects,""NextLevelUp,""Previous,""Print,""Key,""OK,"and "Quit." Thesebuttonsare describedbelow.

B-4

_J UST - ID - Top Level Flow Diagram " ' ........ _

TOP LEVEL FLOW DIAG_

4.0 7.0 [ -,1

Low-LevelWaste _ Lo_-Level Waste _"Txeetment Disposmi......... ='_

/ i'D

P.0 I 2.0 H 3.0 5.0 |

Tank Waste = TankWaste Tank Waste _ Effluent

Storage Retrieval Pmc_siz_ Tzeetment c_ I:q i ill jj._____., i mr=

_._:._ . _.::-_-_i_i_:_:_..:.'-_._:_i_':_'-"_i"_..'.'.............. _.:...._ ......... " _ a

| _!iii_ii'-__:.i_J_i':':""" _':_"_""":_':_;'" "_>'_'::::':":";'_:""'::'" ":::::':'_'_"_'''" ":':' __":_:'_':_":_""" .... :_ ' __I'"" (_

._ ...... ::,..-:_::-..._:.......-..,::.:.:,i:_::.:::._!.':.::.-':_::':"_:_.;:!:!:_:,_':.::::_:......._:......_" .-_ . _ . !i..... "'-_. : --'

. ::c -':: "_i_'_ " , _'_ _r'rl

1.0 _harecterization / Light Duty Utility ArmC_

10.0 Systems Aa_ysLs/Czosscut o

I_."__._| o_::_:::_.-._IIE;_.I_W._'._ X

l___

WHC-EP-0733REV1

• Technologies

Technologybuttons represent the main categories and subcategortesof technologies evaluated under the UST-ID program. A technologybutton activates the flow diagram corresponding to the given

. technology or subtechnology. The technology buttons are numberedinthe order in which they are found on the top-level flow diagram,with subtechnologies numberedas a point extension of the parent

• technology. For example, tank waste processing is numbered3.0, andorganic destruction, a subtechnologyof tank waste processing, isnumbered3.2.

* TechnologyInformation

Clickingon thisbutton,locatedat the top of eachtechnologydiagram,will displaygeneraltechnologyinformation.

• Projects

You can obtainmoredetailedinformationon individualprojects(specifictechnologydevelopmentactivities)withina technologybyclickingon the projectsbuttons. Thesebuttonsare color-codedtodistinguishthe fundingsource.

• Next Level Up

Thisbuttonwill let you move froma subtechnologydiagramto theparenttechnologydiagramor froma technologydiagramto the

' top-leveldiagram. It effectively"unlayers"your screen.

• Previous

Thisbuttonactivatesthe lastdiagramviewedbeforewhateveriscurrentlyon the screen.

• Print

Clickon this buttonto printthe contentsof the currentscreen.

• Key

This buttonprovidesa color-codingkey for the projectsbuttons.

• OK

This buttonclearsdialogboxesfrom the screen.

• Quit

This buttonstopsthe programand returnsMicrosoftExcelto itsoriginalsettings.

B-7

WHC-EP-0733REV1

6.0 TECHNICALSUPPORT

The UST-ID TIS wascreated by Enserch Environmental, Inc., underdirection by the WestinghouseHanford Company. Any commentsand questions

. regarding the program ttself maybe forwarded to:

Cartna Sustene• EnserchEnvironmental, Inc.

Bellevue, WAPhone: (206) 451-4981Fax: (206) 451-4187

B-8

WHC-EP-0733REV1

DISTRIBUTION

Number_ofCODJeS

OFFSITE

" 5 U.S. DeDartmentof Enerqy-Headouarters

S. M. Gtbson (5)

2 ArqonneNatlonal Laboratory9700 South CassAvenueArgonne, IL 60439

D. B. ChamberlainG. F. Vandegrlft

4 En_ierchEnvironmental, Inc.1201 Jadwtn, Suite 202Rtchland WA 99352

R. L. TreatB. B. PetersC. R. DeLannoy

• C. Sustene

1 EG&GlIdaho.Inc." 2525 FremontAvenue

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