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WHC-EP-0733Revision 1
" High-LevelWasteTank• RemediationTechnology
Integration Summary
C. R. DeLannoyC. SusieneEnserchEnvironmental,Incorporated
K. M. FowlerPacificNorthwestLaboratory
W. M. RobsonLawrenceLivermoreNationalLaboratory
J. M. CruseWestinghouseHanfordCompany
DatePublished
July 1994
Prepared for the U.S. Department of EnergyOffice of Technology Development
(_ Jl_'ti_ P.O. Box1970
Htfflf01tl_]llll_tllly Richland,Washington99352
Ha,nfordOpera_onsandEngineeringContxactorforthe.=>.ueparffnentof EnergyunderContractDE-AC06-87RL10930
Approved for PublicRelease p_t_;=_i__
MIC-EP-0733, Rev. 1Impact Level 4
Document Tttle: Htgh Level Waste Tank RemedtattonTechnology Integration Summary
Prepared by: K. II. FowlerW. 11. RobsonC. R. DeLannoyC. Sustene
/1_ 11.-Cruse_" - Dal_e "
- . _/Y • • . / /App,,,o,.e,,.: __, _..,K.,_S8. _../J_,'f;/R. L. GtTchrtst, Hanager Danceu rTechnology Demonstration Programs
RELEASE AUTHORIZATION
i i i, ii i iii i i, .,,,i .,
Document Number: WHC-EP-0733, Revision1
Do©ument Title: High-Level Waste Tank Remediation Technology IntegrationSummery
Release Date:July 15, 1994
iii i ., m|l IHI i iiii i i1,1 i ,., .i =. ,
41. 41..IF 4. ,I. 41. _ 41. 41. 41. 41. 41. ,I.
This document was reviewed following theprocedures described in WHC-CM-3-4 and is:
APPROVED FOR PUBLIC RELEASE
i1,1 iii i , iiii ii ii , ,i
WHC Information ReleaseAdministrationSpecialist:
_/_, /_Z_S"_4,.__ H.N. Boston 7/15/94(Signature) (Date)
A-6001-4,00 (07/94) MEF256
WHC-EP-0733REV I
HIGH LEVELWASTETANKRENEDIATIONTECHNOLOGYINTEGRATIONSUMMARY
ABSTRACT
The U. S. Department of Energy's Environmental Restoration and Waste
Management and Technology Development Programs are engaged in a number of
projects to develop, demonstrate, test, and evaluate new technologies to
support the cleanup and site remediation of more than 300 underground storage
tanks containing over 381,000 n_ (100 million ga7) of liquid radioactive mixed
waste. Significant development is needed within primary functions and in
determining an overall bounding strategy. This document is an update of
continuing work to summarize the overall strategy and to provide data
regarding technology development activities within the strategy. It is
intended to serve as an information resource to support understanding,.,
decision making, and integration of multip7 e program technology development\
activities. Recipients are encouraged to pr_,ide comments and input to the
authors for incorporation in future _evisions.
iv
WHC--EP-0733REV 1
CONTENTS
HIGH LEVELWASTETANK REMEDIATIONTECHNOLOGYINTEGRATIONSUMMARY ..... I
APPENDICES
A HIGH LEVELWASTETANKREMEDIATIONTECHNOLOGYDEVELOPMENTACTIVITIESCHART ............... A-I
B UST-IDTECHNOLOGYINTEGRATIONSYSTEMSOFTWAREAND USER GUIDE..... B-I
EPO733R1. JNC V
WHC-EP-0733REV1
HIGHLEVELWASfETANKREHEDIATIONTECHNOLOGYINTEGRATIONSUHHARY
This documentpresentsthe resultsof ongoingeffortswithintheDepartmentof Energy's(DOE)UndergroundStorageTank - IntegratedDemonstratioa(UST-ID)programto facilitatean integratedapproachindevelopingemergingtechnologiesneededfor tankwasteremediation.TheUST-IDis conductinga numberof technologydevelopmentprojectsaimedat tankwasteremediationat fiveUST-IDparticipatingsites: Hanford,SavannahRiver,IdahoNationalEngineeringLaboratory(INEL),Oak Ridge,and Fernald(Ohio).
Productionof nuclearmaterialshas beena majormissionof DOE and itspredecessoragenciesfor the last50 years. Theseactivitieshavecontributedto a substantialaccumulationof hazardous,radioactive,and mixedwastesat anumberof sites. One of DOE'smost significantchallengeswill be remediatingthe more than300 undergroundstoragetanksand associatednear-fieldenvironmentsat the participantsites. DOE has made a commitmentto remediatethe tank sitesthat are not in compliancewith stateand federalregulationsand to treatand disposeof the wastesin accordancewith acceptedpractice.This remediationprogramwillconstituteone of the most complexandresource-intensivecleanupactionseverattemptedby a governmentagency.
The cost of cleanupof the tank siteswill be prohibitiveusingsomeofthe currentbaselinetechnologies.Furthermore,majorgapsexistin keytechnologyareas. New and improvedtechnologiesare neededthat will supportthe baselinestrategies,reducecosts,accelerateclean-up,and enhancesafety. Accordingly,DOE'sWasteManagement(EM-30),EnvironmentalRestoration(EM-40),and TechnologyDevelopment(EM-50)Programsare engagedin a numberof projectsto develop,demonstrate,test,and evaluatenewtechnologiesto supportthe tankwastecleanupmission.
The EM-30Programat each sitehas the responsibilityto safelystoreandproceedto treatand disposeof existingand new wastesin a mannerthat isenvironmentallysound,technicallycorrect,safeto workersand the public,cost-effective,and in fullcompliancewith applicablelaws,regulations,andDOE Orders. To supporttheseremediationobjectives,EM-30must developthebaselinestrategyfor retrieval,treatment,anddisposal,and ensurethat theneededtechnologiesare developed.
The EM-40Programat each sitehas a similarmissionwith theresponsibilityto cleanup and restoresitesand facilitiesthat are no longerin service. As with the EM-30Program,all activitiesmust be performedin amannerthat is environmentallysound,technicallycorrect,safe to workersand
- the public,cost-effective,and in fullcompliancewith applicablelaws,regulations,and DOE Orders.
The EM-50Programis pursuingtechnologydevelopmentactivitiesatmultiplenationallaboratoriesandwith multiplemanagement/operatingcontractorsto supportthe site remediationefforts. The UST-IDtechnology
WHC-EP-0733REV 1
development activities are focused on two major elements: theCharacterization and Retrieval Program and the Waste Processing and DisposalProgram. In addition, the UST-ID works with the various EM-50 Research andDevelopment Programs to help transition emerging technologies to a stage wherethey are ready for demonstration. Programs include Characterization,Monitoring and Sensors Technology - Integrated Program, Robotics - IntegratedProgram, Efficient Separations and Processing - Integrated Program, and InSitu Remediation - Integrated Program. The UST-ID also maintains awareness ofprogress in other integrated demonstrations with technologies that may haverelated application in tank waste remedtation.
Appendix A to this document presents the "High Level Waste TankRemediation Technology Development Activities" chart, which shows the EM-30,EM-40, and EM-50 technology development activities arranged by majorprocessing functions in the current baseline strategy. The chart is intendedas a visual tool to aid in determining applicability of technologies and therelative emphasis placed on the various functional needs.
Appendix B provides the tnittal version of the "UST-ID TechnologyIntegration System," an EXCELR-basedcomputer program that presents the datafrom the chart and other related technology development information. Theprogram provides an opening "top-level" flow diagram that allows the user toaccess more detailed levels of information with simple mouse commands.Instructions are provided for loading the program onto a personal computer andfor operating it. Investigations are underway regarding loading the programonto one of several "on-line" data communication networks to allow access on areal-time basis.
" The current vision for this activity is to transition it to the proposedHigh-Level Waste Tanks Focus Group for continued use and development. Thenext revision is tentatively planned for December 1994. Recipients areencouraged to review both the chart and the program and to provide any inputand commentsto the authors.
The work reflected in this documentwas performed as part of the UST-ID,in Technical Task Plan RL421207, under the direction of the DOE, RichlandOperations Office, and the DOE-Headquarters, Office of Technology Development.
Ii
II
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WHC-EP-07&3. REV. 1
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_s_Jcbon ! ,,P" 'Vus..u'_u--'u ..... Jr.)._u.v,,opment ' ! ,_r[xMa, er,aJ$/_epara,'onsJST-ID IE_30.TWRS IEM-S0,UST-ID IEM-.30.TWOS
.. I:)NL . . LatemirHu., _ I_LWHC GaddI_L ... R_chmo.d"--W I.....
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_ma/Prooe-s-sing .... = - IPNL L=eminaI ISKIDTest Unit ' ' ' I |Cation ExCh_ge-D(-,_so_oers----
rWRS PNL .rayI IE_50,UST4D I iE_3o._vRs.......... __auel°w ' IWSRC atbler ILANL ...............
[Ele.o.'m,ca,cstx 1 l ---
on_ewcle/Reduc_on IEM-30."rWRS Ic'Ex_r.._o.T.;".0 rmu_a_ w_ .................._icsinREDCWastes II:'NL SurmaIEM-30,SRS _ IEM.-30.TWRS_)RNL ......... "" IWSRC, Bibler |LANL Yarb
EM-3Q'TW_S Sludge/Supemate Process sr Removal - SrSpe_)ermal Processing _ LANL Marsh Tesling EM-30. INEL
TWRS ........... EM-50. UST-ID lWlNCO M,lh,_gan..... Schm,,= I_,=,_,ne:_lliCb'tltanle$ l MME,_OR
IEIvl-30, TWRS I Sr RemovaJ by CoprecipitatJon/LS,NL ..................... Brown jln-Situ Magnetically Assisted I Highly AJk,Waste
IEM.._,ESPIP ] EM-30. ORNLjcr_tallineSilic0titanaleIX J IANL Nunez MMESIOR Ke,IEM-50, ESPIP I[SNL ....... Brown Develop and Test Sorbents .........
EM-60, ESRP !Inorganic IX - FeCN trom PNL WesterHighly Alkaline Waste/:11
' Resorcinol torCs - REDC Waste Carbollide/CDC Process Jo EM-30, ORNL EM-50, SRS I= MMES/OR Kent WSRC McCabe '_
i i III II I
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' .... "' c=u_ ....., C Recycle
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A
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- "' - ' TWRS EM-50, ESPIP PNL
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ate Other Processes IEM-3O,INEL "'"--TVVI:_S [ o,nallo ,sso ubon WINCO Herbsl
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ii iii i i
I I
HIGH LEVEL WASTE TANK REMEDIA T/ON TECHNOLOGYDE VEL OPMEN T A C TIVITIES
Compilation of EM-30. EM-40 and EM-50 Projects atParticipating DOE Sites
June 15. 1994
Prepared by:Underground Storage Tank-lnteorated DemonstrationJ. M. Cruse. WHC. 509-372-1024K. M. Fowler. PNL 509-372-4233
WHC-EP-0733REV1
UST-IDTECHNOLOGYINTEGRATIONSYSTEMUSER'S GUIDE
1.0 INTRODUCTION
The UndergroundStorage Tank - Integrated Demonstration (UST-ID)Technology Integration System (TIS) provides you with a computerized directoryof the technologies being developed to support high-level waste tankremediation at multiple U.S. Departmentof Energy (DOE) sites. By using yourmouseto click on a series of buttons, you can call up a complete flow diagramof a particular technology function, obtain general information about thefunction, and then find out which projects (technology developmentactivities)are being conducted, along with information about the projects. Suchalayered information systemwill enable you to obtain only as muchinformationon a technology as you require. This program and guide _ssumesthat you havea basic knowledgeof computersand of Microsoft Windows.
2.0 COMPUTERREQUIREMENTS
To run the UST-ID TIS programyou need the following:
• IBMz or ]00% IBM-compatible computerwith 4 megabytes(MB) ofrandomaccessmemory(RAM)(for maximumefficiency in running theprogram, at least 6 MBof RAMis recommended)
• EGA/VGAmonitor with a screen resolution of either 640 x 480 or 800x 600 dots per inch
• A 3.5-in. high-density floppy disk drive
• At least 5 MBavailable for use on your hard drive
• Microsoft Windows(Version 3.1) andMicrosoft Excelz (Version 4.0)installed on your hard drive (Excel Version 5.0 is NOTcompatiblewith the UST-ID TIS program)
• A computermousecompatible with Windows._
I MicrosoftWindowsis a trademarkof MicrosoftCorporation.
z IBM is a trademarkof InternationalBusinessMachines,Incorporated.
z MicrosoftExcelis a trademarkof MicrosoftCorporation.
B-2
WHC-EP-0733REV1
3.0 PROGRAMINSTALLATION
To install UST-ID TIS, follow these steps•
1. Insert the 3.5-in. installation disk into either your A or B drive.
2. If you inserted the disk in the A drive, type A: (or B: if the diskis in the B drive) andpress Enter. Your screen should nowshow"A: "
3. At the A: prompt, type install. Your screen should show"A:install." Press Enter. The program is nowbeing copied ontoyour hard drive (C drive) and placed in the UST-ID-TIS D_rector¥.If this directory does not already exist, the installation programwill automatically create it.
4.0 PROGRAMEXECUTION
Onceyou have installedthe UST-IDTIS programon your harddrive,youcan enterthe programfrom eitherDOS or Windows. It is usefulto noteherethatthe UST-IDTIS programwas writtenas an add-onapplicationto ExcelVersion4.0.
4.1 RUNNINGTHEPROGRAMFROMDOS
At the C:\UST-ID\TIS prompt, type TIS and press Enter. This willautomatically take you into Excel for Windowsand into the UST-ID TIS.
NOTE: You must first close out any startup program on your screen, suchas E-mail, before you can get into Excel and the UST-ID TIS program.
4.2 RUNNINGTHEPROGRAMFROMWINDOWS
1. Once in Windows,double click on the Excel icon. This will open theExcel program.
2. Once in Excel, click on "Open"under the File menu. "Directories"will appear.
3. Doubleclickon Directoriesto openthe file,and thendoubleclickon "C:\"to openthe directoryfor the C drive.
4. Scrolldown and doubleclickon "UST-ID." "TIS"will appear.
5. Doubleclickon "TIS." "Files"will appear.
6. Under"Files,"doubleclickon "TIS.XLS."
B-3
WHC-EP-0733REV1
5.0 PROGRAMFEATURES
The UST-IDTIS programwas designedto be user friendly.ThroughExcel,you gaineasy accessto the program. The UST-IDTIS programthen operatesinan Excelworkspacecustomizedspecificallyfor the program. Simplyclickingon clearlylabeledon-screenbuttonswithinthis customizedframeworkwilltakeyou to any of the programfunctions. The specialformattingfeaturesusedto customizethe Excelworkspaceand the on-screenbuttonsusedthroughoutthe programaredescribedbelow.
5.1 CUSTOMFORMATTING
The Excelworkspacehas beenmodifiedonly for use by the UST-IDTISprogram. Modificationsincluderemovingthe standardExcelmenu bar,toolbars,formulabar,messagebar, andscrollbars. The formattedworkspaceis shownin FigureB-].
The UST-IDTIS programautomaticallyfitsall graphicsto the screensize. To viewdiagramsin theirentiretyon screenwithoutscrolling,ascreenresolutiondialogbox appears(FigureB-I). It will ask you to selectthe currentresolutionof the computerscreen. Thiswilldeterminetherelativesizeof the objectson screen. Only two computerscreenchoicesaregiven: 640 x 480 dots per inch(standardresolution)or800 x 600 dots perinch (highresolution).Ifyou do not knowthe currentresolutionof yourscreen,you can findthe informationby activatingWindowsSetupfromtheProgramManager. If it showsa VGA display,the resolutionof your screenis640 x 480 dots per inch. VGA is the most commonscreendisplayand is thedefaultdisplayon mostmonitors. If it showsa differentcurrentscreenresolutionfromthe two choiceslistedabove,you shouldchangeit so that thegraphicscan be viewedproperly.To make the change,go to the WindowsSetupunderProgramManagerand clickon the "Options"menu. WithinOptions,clickon "ChangeSystemSettings."Severaloptionswill appearincluding"Display."Clickon "Display,"then scrolldown and clickon "VGA."
Finally,all modelelementsarewriteprotected.Thismeansyou cannotchangeany partof the program. This prevenLsyou from accidentallycausingUST-IDTIS errors.
5.2 ON-SCREENBUTTONS
On-screenbuttonscontrolthe entireUST-IDTIS program. You activatethesebuttonssimplyby clickingon themwiththe mouse. You will use mostbuttonsto move fromone technologydiagramto another. Thesebuttonshavenamescorrespondingto the diagramtheyactivate. Otherbuttonsperformfunctionssuch printingand exitingthe program. Thesebuttonsalsohavecorrespondingnames. The buttonsavailable(shownin FigureB-2)are:"Technologies,""TechnologyInformation,""Projects,""NextLevelUp,""Previous,""Print,""Key,""OK,"and "Quit." Thesebuttonsare describedbelow.
B-4
_J UST - ID - Top Level Flow Diagram " ' ........ _
TOP LEVEL FLOW DIAG_
4.0 7.0 [ -,1
Low-LevelWaste _ Lo_-Level Waste _"Txeetment Disposmi......... ='_
/ i'D
P.0 I 2.0 H 3.0 5.0 |
Tank Waste = TankWaste Tank Waste _ Effluent
Storage Retrieval Pmc_siz_ Tzeetment c_ I:q i ill jj._____., i mr=
_._:._ . _.::-_-_i_i_:_:_..:.'-_._:_i_':_'-"_i"_..'.'.............. _.:...._ ......... " _ a
| _!iii_ii'-__:.i_J_i':':""" _':_"_""":_':_;'" "_>'_'::::':":";'_:""'::'" ":::::':'_'_"_'''" ":':' __":_:'_':_":_""" .... :_ ' __I'"" (_
._ ...... ::,..-:_::-..._:.......-..,::.:.:,i:_::.:::._!.':.::.-':_::':"_:_.;:!:!:_:,_':.::::_:......._:......_" .-_ . _ . !i..... "'-_. : --'
. ::c -':: "_i_'_ " , _'_ _r'rl
1.0 _harecterization / Light Duty Utility ArmC_
10.0 Systems Aa_ysLs/Czosscut o
I_."__._| o_::_:::_.-._IIE;_.I_W._'._ X
l___
WHC-EP-0733REV1
• Technologies
Technologybuttons represent the main categories and subcategortesof technologies evaluated under the UST-ID program. A technologybutton activates the flow diagram corresponding to the given
. technology or subtechnology. The technology buttons are numberedinthe order in which they are found on the top-level flow diagram,with subtechnologies numberedas a point extension of the parent
• technology. For example, tank waste processing is numbered3.0, andorganic destruction, a subtechnologyof tank waste processing, isnumbered3.2.
* TechnologyInformation
Clickingon thisbutton,locatedat the top of eachtechnologydiagram,will displaygeneraltechnologyinformation.
• Projects
You can obtainmoredetailedinformationon individualprojects(specifictechnologydevelopmentactivities)withina technologybyclickingon the projectsbuttons. Thesebuttonsare color-codedtodistinguishthe fundingsource.
• Next Level Up
Thisbuttonwill let you move froma subtechnologydiagramto theparenttechnologydiagramor froma technologydiagramto the
' top-leveldiagram. It effectively"unlayers"your screen.
• Previous
Thisbuttonactivatesthe lastdiagramviewedbeforewhateveriscurrentlyon the screen.
Clickon this buttonto printthe contentsof the currentscreen.
• Key
This buttonprovidesa color-codingkey for the projectsbuttons.
• OK
This buttonclearsdialogboxesfrom the screen.
• Quit
This buttonstopsthe programand returnsMicrosoftExcelto itsoriginalsettings.
B-7
WHC-EP-0733REV1
6.0 TECHNICALSUPPORT
The UST-ID TIS wascreated by Enserch Environmental, Inc., underdirection by the WestinghouseHanford Company. Any commentsand questions
. regarding the program ttself maybe forwarded to:
Cartna Sustene• EnserchEnvironmental, Inc.
Bellevue, WAPhone: (206) 451-4981Fax: (206) 451-4187
B-8
WHC-EP-0733REV1
DISTRIBUTION
Number_ofCODJeS
OFFSITE
" 5 U.S. DeDartmentof Enerqy-Headouarters
S. M. Gtbson (5)
2 ArqonneNatlonal Laboratory9700 South CassAvenueArgonne, IL 60439
D. B. ChamberlainG. F. Vandegrlft
4 En_ierchEnvironmental, Inc.1201 Jadwtn, Suite 202Rtchland WA 99352
R. L. TreatB. B. PetersC. R. DeLannoy
• C. Sustene
1 EG&GlIdaho.Inc." 2525 FremontAvenue
P. O. Box 1625Idaho Falls, ID 83403
K. Kostelntk
2 LosAlamosNational LaboratoryP. O. Box 1663LosAlamos, NM 87545
M. AttrepK. Thomas
1 FERMCo25 MerchantStreet,MS82-24th Floor
• Springfield,Ohio45246
D. Jacoboski
Distr-1
WHC-EP-0733REV]
DISTRTBUTZON(continued)
Numberof copies
OFFSITE
' 5 Marttn Marietta EnergySv,_temsP. O. Box 2008
, OakRidge, TN 37831
J. B. BerryC. M. KendrtckC. P. McGtnnts (2)W. J. Wtlkenson
2 Sandta Natlorl_] LaboratoryDepartment6612Albuquerque, NM 87185
L. Bustard (2)
2 Sctence AoD11cationsInternational CorD.555 OulnceOrchard Rd., Sutte 500Gatthersburg, MD 20878
• A. LtvnatP. S. Szerszen
' 1 Unlverslty of South CarolinaDepartmentof Chemical EngineeringColumbia, SC 29208
V. VanBrunt
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