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    HeatTreatment

    Dr.SantoshS.Hosmani

    1

    Brief Intro. about Myself

    uca ona ac groun :

    1997 2001: B.E. (Metallurgy), V. Regional College of Engineering (currently NIT), Nagpur

    2001 2003: M.Tech. (Process Meta.), Indian Institute of Technology, Bombay

    2003 2006: Ph.D. (Physical Meta.), Max-Planck Institute for Metals Research, Stuttgart, Germany

    Assistant Professor,Dept. Metallurgy & Materials Science, College of Engineering, Pune, India.

    Assistant Professor,Dept. of Applied Mechanics,Indian Institute of Technology, Delhi, India.

    Lecturer,Dept. of Metallurgical & Materials Engineering, National Institute of Technology

    Karnataka, Surathkal, India.

    Postdoctoral researcher, Dept. of Materials Science and Engineering, Case Western Reserve

    , . . ..

    Postdoctoral researcher,Max-Planck-Institute for Metals Research, Stuttgart, Germany.

    2

    HEAT TREATMENT

    LECTURES: 3 hrs/week

    FACULTY: Dr. Santosh S. Hosmani

    Dept. of Metallurgy & Materials Science,

    COE, Pune

    Email: [email protected]

    Phone (use only in case of emergency plz): 9762316594

    OFFICE HOURS: Open

    3

    GRADING / EXAMINATION SCHEME:

    e g age

    Quiz**- 1 & 2 20%

    Mid-Sem Exam 30%

    End Sem Exam 50%

    **Note: Quiz can be surprise quiz OR Quizzes can be held on shortnotice. Therefore, continuous stud and attendance is desired.

    Minimum passing marksfor this course is 40%.

    Total attendancerequirement is as per the insti tu te rules. Any kind of

    proxy is strictly prohibited.

    Quiz/Exam wil l not be conducted againif anyone is absent without any

    .

    Depending upon the requirement of the course, Assignments/Home-work

    could be given. However, there will be no weightage for the assignmentsin this course.

    4

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    Introduction of the course

    In many engineering applications, steels are the most preferred material. There

    are various types of steels which are evolved from the requirements of the

    engineering components. Requi rement s is di rect ly l inked t o desi red

    properties .

    Properties can be manipulated by altering the chemistry of the alloyand/or bymechanical treatmentsand/or by giving appropriate heat-treatments.

    As a materials engineer, literacy about the heat-treatment technology

    processing & fundamental concepts is very essential. This knowledge teaches

    the intelligent use of the existing grade of steel for a particular application.

    Heat-treatment technology touches many important applications in automobile

    and aerospace sectors.

    -

    treatment and metallurgy of the some important iron-based alloys.

    Note: There are some topics in the course which does not require class-room

    -

    5

    , - .

    SYLLABUS:Available on your department website.

    Heat Treatment of Metals, Vijendra Singh, 2007, Standard Publishers andDistributors, New Delhi

    R.A. Hi ins En ineerin Metallur Part I A . Ph sical Met ELBS 5th

    . . , , , . , ,

    ed., 1983

    REFERENCE BOOKS:

    Steel and its Heat Treatment -K.E Thelning, Butterworth, London Handbook of Heat Treatment of Steels Prabhudev-Tata Mc Graw Hill.

    New Delhi, 1988

    , , .,1979

    =>You can read any book available in your library.

    =>Whenever lectures are in power-point-presentations, pdf-files of the

    slides will be provided to you by email.

    6

    Friendly suggestion: Please learn to make good class-notes.

    Some Basics revision of the concepts

    7

    Familytrees:organizingmaterialsandprocesses

    likenessuseful to know when deciding which family to use for a given

    design.

    Choosing a material is only half the story. The other half is the choice of a

    process route to shape, join and finish it.

    processed in some ways but not others, and a given process can be applied to

    some materials but not to others.

    8

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    Thematerialstree Classificationofmaterials

    It is conventional to classify the materials of engineering into the six

    broad families:

    There is sense in this classification: the members of a family have certain features in

    common: similar properties, similar processing routes and, often, similar applications.

    9

    , ,

    each of which is characterized by a set ofattributes:its properties..

    10

    Metals:

    They have relativelyhigh stiffness(modulus, E).

    Most,when pure, are softand easily deformed, meaning that yis low.

    Theycan be made strongby alloying and by mechanical and heat treatment,

    y, ,

    deformation processes.

    And, broadly speaking, they aretough, with a usefully high fracture toughnessK1c. They are good electrical and thermal conductors.

    But metals have weaknesses too: they are reactive; mostcorrode rapidlyif not

    protected.

    11

    Stiffness and strength are central to mechanical design, often in

    combination with thedensity,.

    What is the stiffness?

    ,

    meaning that the material returns to its original shape

    when the stress is removed. Stiffness is measured bythe elastic modulusE.

    E reflects stiffness, S, of the bonds that hold them

    together.But, remember thatES

    What is the strength?

    failure. Strength is measured by the elastic limit y or

    tensile strength ts.

    Note: Stress and strain are not material properties.12

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    It is theplasticityof iron and steel that made them thestructural materials

    on which theIndustrial Revolutionwas built

    18061859

    British

    Engineer

    (17571834)

    ThomasTelford He was perhaps the greatest engineer of the

    Industrial Revolution in terms of design

    co s eng neer, ,

    theplasticity of iron and steel.

    13

    18061859

    British

    Engineer

    IsambardKingdomBrunel

    GreatEastern

    Launched:

    31

    Jan.

    1858

    greatthingsarenot

    donebythosewho

    simplycountthecost14

    engineering, derives from their ability

    o e ro e , orge , rawn an

    stamped.

    15

    Strength,plasticworkandductility

    y ,

    onset of plasticity is not always

    distinct so we identify y with the

    0.2% roo stressthat is the stress

    forMetals

    ,

    at which the stressstrain curve for

    axial loading deviates by a strain of

    0.2% from the linear elastic line. It is

    the same in tension and

    compression.

    ,

    most metals work harden, causing

    the rising part of the curve, until a

    maximum, the tensile strength, is

    reached.

    This is followed in tension by non-

    fracture.

    16

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    Strength,plasticworkandductility

    forMetals

    Howstressstraincurvelookslikeformetalsincompression? 17

    Stress-strain dia rams for

    Strength,plasticworkandductility

    compression have different shapes

    from those for tension. forMetals

    limits in compression very close tothose in tension. However, when

    ieldin be ins the behavior is uite,

    different.

    When a small specimen of ductile

    ,

    bulge outward on the sides and

    become barrel shaped. With

    ,

    flattened out, thus offering increased

    resistance to further shortening

    which means the stress-strain

    Ref.:DepartmentofCivilEngineeringattheUniversityofMemphis

    curve goes upward).

    18

    TheoriginsofstrengthandductilityFundamentals

    Perfection:theidealstrength

    Thebondsbetweenatoms,likeanyotherspring,haveabreakingpoint.

    Figure:Stressstrain curve for a

    single bond.

    Here an atom is assumed to occu a cube of sidea so that a force F corres ondsoto astress =F/ao

    2.

    The force stretches the bond from its initial length ao to a new length a, giving a

    strain = a a a .o o.

    In case of the modulus we focused on the initial, linear part of this curve, with a

    slope equal to the modulus, E. Stretched further, the curve passes through a

    .

    bond strengthif you pull harder than this it will break.

    19

    The distance over which interatomic forces act is smalla bond is broken if it is

    Perfection:theidealstrength

    .

    So the force needed to break a bond is roughly:

    F

    t nesson =,

    10%10

    %10

    oaaa

    lengthbondorigionalof

    ===

    =

    10100oo

    10/oa

    FS=

    On this basis the ideal strength of a solid

    should therefore be roughly:

    10

    oaSF =Q

    SF

    ES

    =

    =

    :andbetweenRelation

    2

    o

    oo

    a

    S=

    &etweenrelationlinearAssume

    oa

    SE=Q

    Note: This relationship doesnt allow for the

    curvatureof the forcedistance curve;more refined

    calculations give a ratio of 1/15. 20

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    Perfection:theidealstrength

    Surprisingly,

    None of the metals, polymers and ceramics achieve the ideal value of1/10; most dont even come close.

    21

    CriticalResolvedShearStress

    eory

    (GPa)

    xper men

    (MPa)

    a o

    Theory/Exp

    Fe (BCC) 12 15 800

    Cu (FCC) 7 0.5 14,000

    Zn (HCP) 5 0.3 17,000

    22

    Perfection:theidealstrength

    Surprisingly,

    None of the metals, polymers and ceramics achieve the ideal value of

    1/10; most dont even come close.

    Whynot?

    Nothing is perfect in this world.!

    Existence of Imperfections / Defects in materials.!

    23

    Dislocation

    Thedislocationis the key player in explaining important mechanical properties, like

    strength and ductility.

    Dislocated means out of joint and this is not a bad description of what is

    happening here. The upper part of the crystal has extra halflayer of atoms than

    the lower part.

    It is dislocations that make metals soft and ductile.

    because of this they have elastic energy associated with them.

    24

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    Inventorsofdislocationconcepts

    an ideal strength aroundE/15 (whereEis the modulus).

    In reality the strengths of engineering materials are nothing like this big;

    o ten t ey are are y 1% o it.

    Hungarian/US

    physicist and

    British

    mathematician,

    metallurgistphysicist and

    expert on fluid

    dynamics and

    wave theor

    Sir Geoffrey Ingram Taylor Egon Orowan

    ese two persona t es rea ze t at a s ocate crysta

    could deform at stresses far below the ideal.25 Ref.: Book by W.D. Callister

    Ref.: Book by W.D. Callister Ref.: Book by W.D. Callister

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    Ref.: Book by W.D. Callister Ref.: Book by W.D. Callister 30

    Thelatticeresistance

    Dislocation Motion Plastic Deformation

    asy s oca on o on asy as c e orma on

    Weak Cr stal

    Difficult

    Dislocation Motion

    Difficult

    Plastic Deformation

    Strong Crystal

    31

    Where does the resistance to

    . . , ,

    come from?

    32

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    The lattice resistance

    There are several contributions to this resistance.

    I. Lattice resistance, fi:

    s s e n r ns c res s ance o e crys a s ruc ure o p as c s ear.

    Plastic shear, as we have seen, involves the motion of dislocations.

    Pure metals are soft because the non-localized metallic bond does little

    to obstruct dislocation motion, whereas ceramics are hard because their

    more localized covalent and ionic bonds (which must be broken and

    reformed when the structure is sheared) lock the dislocations in place.

    The electrons and +ve ions

    are all in a fixed position.

    The electrons are in a fixed

    position

    The electrons are not

    fixed and free to move

    throughout the lattice. 33

    The lattice resistance

    When the lattice resistance is hi h, as in ceramics, further hardenin is

    more than sufficientthe problem becomes that of suppressing fracture: i.e.yield strength is much larger than fracture strength of ceramics.

    On the other hand, when the lattice resistance fiis low, as in metals, the

    material can be strengthened by introducing obstacles to slip.

    II. other dislocations giving what is called Work Hardening (fwh),

    III. grain boundaries introducing Grain-size Hardening (fgb),

    IV. precipitates or dispersed particles giving Precipitation Hardening (fppt),

    V. by adding alloying elements to give Solid Solution Hardening (fss).

    ese ec n ques or man pu a ng s reng are cen ra o a oy es gn.

    34

    II. Work hardening / Strain hardening, fwh:

    ur ng p ast c e ormat on s ocat on ens ty

    of a crystal should go down

    But,

    Experimental Result

    Well-annealed crystal: 1010 m-2

    Lightly cold-worked: 1012 m-2

    eav y co -wor e : m-

    35

    II. Work hardening / Strain hardening, fwh:

    Workhardeningor

    StrainHardening

    y

    Strain,

    see Book by V. Raghvan36

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    II. Work hardening / Strain hardening, fwh:

    37

    II. Work hardening / Strain hardening, fwh:

    During plastic deformation dislocation density increases.

    Plastic deformation increases the yield strength of the

    crystal: strain hardening or work hardening

    Why deformation increases strength?

    What exactly is the Strain Hardening?

    38

    II. Work hardening / Strain hardening, fwh:

    Strain Hardening:

    Dislocation against Dislocation

    A dislocation in the path of other

    dislocation can act as an obstacle to the

    motion of the latter

    39

    Sessile dislocation in an FCC crystal:

    < + a

    2

    2

    1bE =

    g,

    fwh:

    1

    222aaa

    + is the shear stress required to move a single dislocation in theabsence of any other dislocation

    42

    II. Work hardening / Strain hardening, fwh:

    metals and alloys, e.g. Al-based alloys

    43

    III. Grain-size / Grain-boundary hardening, fgb:

    ran

    Grain1

    Grain boundary

    44

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    III. Grain-size / Grain-boundary hardening, fgb:

    Discontinuity of a slip plane across a grain boundary

    Slip plane

    Dislocation

    Grain Boundary

    45

    III. Grain-size / Grain-boundary hardening, fgb:

    A dislocation cannot glide across a grain

    Higher stresses required for deformation

    Finer the grains, greater the strength

    Ref.: Book by V. Raghavan46

    III. Grain-size / Grain-boundary hardening, fgb:

    Role of Grain Size in Strengthening

    Hall-Petch Relation

    k y

    D= +0

    y y e strengt

    D: average grain diameter

    0,k: constants

    Coarse Grains Fine Grains0 => yield strength of a single

    crystal

    47

    III. Grain-size / Grain-boundary hardening, fgb:

    Role of Grain Size in Strengthening

    k y

    D= +0

    Coarse Grains Fine Grains

    This concept is relevant to annealing,-

    alloy design, e.g. HSLA steel 48