chapter 3-air pollution

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CHAPTER 3 – AIR POLLUTION The Major Air Pollution Episodes London Episodes, 1873-1963 The industrial revolution in the 19th century saw the set in of air pollution in Europe on a large scale. The industries and the households relied heavily on coal for heating and cooking. Due to burning of coal for heat during the winter months, emissions of smoke and sulphur dioxide were much greater in winters than they were during the summer months. Smoke particles trapped in the fog gave it a yellow/black colour and this smog often settled over cities for many days. The effects of smog on human health were evident, particularly when smog persisted for several days. Many people suffered respiratory problems and increased deaths were recorded, notably those relating to bronchial causes. The smog-related deaths were first recorded in London in 1873, when it killed 500 people. In 1880, the toll was more than 1000. London had one of its worst experiences of smog in December 1892. It lasted for three days and resulted in about 1000 deaths. Despite gradual improvements in air quality during the 20th century, eight air pollution episodes occurred in London between 1948 and 1962. The December 1952 episode is the major episode in the history of air pollution. The “Killer Smog” began on Thursday, Dec. 4, 1952 as a high-pressure air mass created a subsidence temperature inversion over southern England. With the particulate and SO 2 levels going up due to extensive use of coal as fuel for space heating and electric production, the fog turned black. At the same time the high-pressure area stalled and became stationary. The build up of pollutants combined with the fog resulted in essentially zero visibility. Within a matter of three days, the pollutants were concentrated enough to cause deaths. The old and respiratory affected died first, but younger people exposed to the outside atmosphere were also affected. The maximum daily SO 2 concentration recorded at that time was 1.34 ppm (about 4000 μg/m 3 , standard SO 2 conc. in clean dry atmosphere is 0.0002 ppm) and smoke levels were 4.46 mg/m 3 .

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  • CHAPTER 3 AIR POLLUTION

    The Major Air Pollution Episodes

    London Episodes, 1873-1963

    The industrial revolution in the 19th century saw the set in of air pollution in Europe on a large

    scale. The industries and the households relied heavily on coal for heating and cooking.

    Due to burning of coal for heat during the winter months, emissions of smoke and sulphur

    dioxide were much greater in winters than they were during the summer months. Smoke

    particles trapped in the fog gave it a yellow/black colour and this smog often settled over cities

    for many days.

    The effects of smog on human health were evident, particularly when smog persisted for several

    days. Many people suffered respiratory problems and increased deaths were recorded, notably

    those relating to bronchial causes.

    The smog-related deaths were first recorded in London in 1873, when it killed 500 people. In

    1880, the toll was more than 1000. London had one of its worst experiences of smog in

    December 1892. It lasted for three days and resulted in about 1000 deaths. Despite gradual

    improvements in air quality during the 20th century, eight air pollution episodes occurred in

    London between 1948 and 1962. The December 1952 episode is the major episode in the

    history of air pollution.

    The Killer Smog began on Thursday, Dec. 4, 1952 as a high-pressure air mass created a

    subsidence temperature inversion over southern England. With the particulate and SO2 levels

    going up due to extensive use of coal as fuel for space heating and electric production, the fog

    turned black.

    At the same time the high-pressure area stalled and became stationary. The build up of

    pollutants combined with the fog resulted in essentially zero visibility. Within a matter of three

    days, the pollutants were concentrated enough to cause deaths. The old and respiratory

    affected died first, but younger people exposed to the outside atmosphere were also affected.

    The maximum daily SO2 concentration recorded at that time was 1.34 ppm (about 4000 g/m3,

    standard SO2 conc. in clean dry atmosphere is 0.0002 ppm) and smoke levels were 4.46 mg/m3.

  • The Great London Smog lasted for five days and lifted on 9th Dec, resulting in about 4000 deaths.

    Bhopal Disaster, 1984

    In the mid night of 2nd - 3rd December 1984, in a densely populated area of Bhopal, Central India,

    a poisonous vapor burst from the tall stacks of the Union Carbide pesticide plant.

    About forty tons of toxic gases had leaked from the Carbides Bhopal plant and spread

    throughout the city. The cause was the contamination of Methyl Isocyanate (MIC) storage tank

    with water carrying catalytic material.

    Residents of the city awoke to clouds of suffocating gas, unaware of the magnitude of the

    devastation, which had engulfed them. The city of Bhopal was immediately turned into a city of

    dead bodies, and the whole place smelled of burning chilli peppers.

    Of the million people living in Bhopal at that time, more than 2,000 died immediately (one

    fourth of actual figures) and as many as 300,000 were injured. In addition, about 7,000 animals

    were affected, of which about 1000 were killed. The precise number of deaths still remains a

    mystery till date.

    The degree of injury was so high that about 30% of the injured were unable to return to their

    jobs. Among the survivors, most of them still suffer agonizing pain from the disastrous effects of

    the massive poisoning while there are still apprehensions of the future generations being

    affected. The Bhopal Disaster was the worst episode in the history of industrial air pollution.

    Donora Fog, 1948

    Horror visited the US Steel company town of Donora on the Halloween night of 1948, when a

    temperature inversion descended on the town.

    Fluoride emissions from the Donora Zinc Works smelting operation and other sources containing

    sulphur, carbon monoxide and heavy metal dusts were trapped by weather conditions, causing

    20 deaths within 14 hours.

    Cold ground and high-pressure conditions intensified the elevated inversion of the anticyclone

    that arrived in the region. The situation was aggravated by local conditions of meteorology,

    industrial pollutant emissions and peculiar terrain of the area.

    The meteorological conditions and the geographical characteristics of the area produced a

    strong temperature inversion with a temperature gradient as high as 33oC/km. The fog was held

    close to the ground by the stability of the elevated inversion layer.

  • During the third and fourth days of the episode, as ambient levels of pollutants escalated,

    almost half of the population of 14,000 people became ill. Almost 43 % of the population in

    Donora and Webster, PA experienced the effects of the smog.

    Most of the affected were above the age group of 60 years and above (29% of this group were

    seriously affected). The health effects were mainly symptoms affecting the lung, and in

    particular, upper respiratory symptoms such as nasal discharge, constriction of the throat, or

    sore throat were experienced.

    Smoke Haze Episodes in Malaysia 1997

    Between July and November 1997, an estimated 45,000 km2 of forest and land burnt

    on the islands Sumatra and Kalimantan.

    In the first half of 1998, another fire episode affected roughly a similar area in

    Kalimantan alone. The emissions of these fires caused considerable air pollution

    throughout the Southeast Asian region, notably in Indonesia, Singapore and

    Malaysia.

    The air pollutant that predominantly caused violations of ambient air quality

    standards was particulate matter. Particulate matter may cause acute and chronic

    respiratory diseases such as bronchitis, asthma and upper respiratory tract

    infections. Increased ambient particle concentrations are suspected to be linked with

    increased daily mortality. By scattering and absorbing light, particulates also result in

    reduced visibility, impairing transportation by air, land and water. Fire-related air

    pollution episodes are a recurrent phenomenon in Southeast Asia.

    Nine such incidents have been reported over the last 20 years, of which the 1997/98

    smoke haze episode attracted the broadest attention.

    In contrast to Singapore and Malaysia, Indonesia does not yet have an integrated air

    quality monitoring network which could provide real-time, region-covering air quality

    information.

    Due to the absence of such information, an assessment of the severity of the fire-

    related air pollution episodes is limited. As a surrogate, horizontal visibility was

    frequently used to report the status of ambient air pollution. However, even though

    sufficient information on the status of air quality was available in Singapore and

    Malaysia, much uncertainty existed on the impacts of such air pollution episodes and

    on how to response adequately to them.

  • The governments of the affected countries recommended the public to remain

    indoors as much as possible, to avoid physical exertion and to wear respiratory

    masks outdoors. In Kuching, Borneo-Malaysia, the state of emergency was

    proclaimed for 10 days in 1997, leading to the closure of schools, public offices and

    factories.

    Dubious statements in the media on the impacts of the smoke haze were

    disseminated - such as the daily exposure would equal to 20 to 40 cigarettes; panic

    easily evolved.

    During the peak episode, satellite imagery (NASA/TOMS aerosol index maps) showed

    a smoke haze layer which expanded over an area of more than 3 million km2,

    covering large parts of Sumatra and Kalimantan. Its northward extension partially

    reached Malaysia, Singapore, Brunei and Thailand.

    During this period, particulate matter concentrations frequently exceeded national

    ambient air quality standards.

    Scanty particle measurement data at hand for areas close to fires in Kalimantan and

    Sumatra indicate that ambient particle concentration was roughly 20 to 40 times the

    normal (non-haze) background concentration and exceeded levels categorised as

    'hazardous' (or 'significant harm level'). Monthly mean horizontal visibility at most

    locations in Sumatra and Kalimantan in September was below 1 km and daily

    maximum visibility was frequently below 100 metres.

    The neighbouring region most affected by pyrogenic transmissions in 1997 was

    Sarawak, Borneo-Malaysia. In the city of Kuching, ambient particle concentration

    rose roughly 5 to 20 times above background levels, with in total 32 days in the

    'unhealthy to hazardous' range. Visibility decreased from generally above 15 km to

    below 0.5 km during this period.

    In Singapore and Peninsular Malaysia, a 2 to 5-fold rise in ambient particle

    concentration was recorded. 12 and more than 40 days, respectively, were in the

    unhealthy' range in Singapore and Kuala Lumpur. Visibility below 2 km

    predominantly prevailed at both locations during the smoke haze episode.

    In contrast to the situation in 1997, the fire-related air pollution episode in the first

    half of 1998 was essentially restricted to Borneo. This was mainly due to the

    weakened southerly monsoonal flow by that time. However, again, the population in

    Kalimantan and Borneo-Malaysia was exposed to distinctively elevated air pollution

    for a period of months.

  • The Environmental Quality Act 1974 sets standards for emission sources.

    The EQA controls pollution through :

    1. Licensing

    2. Regulations, order, guidelines

    1. To Control of Industrial Emissions:

    1. Environmental Quality (Clean Air) Regulations 1978

    2. Environmental Quality (Compounding of Offences) Rules 1978;

    2. To Control of Motor Vehicle Emissions

    1. Motor Vehicles (Control of Smoke & Gas Emission) Rules 1977

    2. Environmental Quality (Control of Lead Concentration in Motor Gasoline)

    Regulations 1985

    3. Environmental Quality (Control of Emission From Diesel Engines) Regulation

    1996

    4. Environmental Quality (Control of Emission From Petrol Engines) Regulation

    1996

    For open burning, law applicable is :

    1. Section 29A EQA (Amendment 1998)

    2. Section 29AA EQA (Amendment 2001)

    3. Environmental Quality (Prescribed Activities)(Open Burning) Order, 2000

    4. Environmental Quality (Delegation of Powers)(Investigation of Open Burning)

    Order, 2000 5. Environmental Quality (Compounding of Offences)(Open Burning) Rules, 2000

    EQASECTION 29A

    1. No person shall allow or cause open burning on any premises

    2. Maximum fine RM 500,000

    3. Maximum jail term 5 years Or Both

    Types of air pollution

    1. Sulfur dioxide

    Sulfur dioxide is a colorless gas with a pungent, suffocating odor. It is a dangerous

    air pollutant because it is corrosive to organic materials and it irritates the eyes,

    nose and lungs.

  • Sulfur is contained within all fossil fuels, and is released in the form of sulfur dioxide

    (SO2) during fossil fuel combustion. Fossil fuel combustion accounts for almost all

    anthropogenic (human-caused) sulfur emissions.

    Sulfur contents in fossil fuels range between 0.1% and 4% in oil, oil by-products

    and coal, and up to 40% in natural gas (when immediately extracted from the well;

    however, the sulfur is efficiently removed during the processing of gas before

    distribution; therefore, combustion of natural gas is not a major source of sulfur

    emissions

    Historically, the use of coal in domestic heating was a major source of sulfur dioxide

    emissions (at least in the UK), but it has declined substantially over time.

    Over the last several decades the industrial use of coal in the UK has also declined,

    whereas the use of oil and natural gas has gradually increased.

    In the UK, the sulfur dioxide emissions declined significantly since 1970, thanks to

    the introduction of low sulfur fuels, the switch from coal to gas and increased energy

    efficiency.

    This trend is possibly true for other industrialized countries as well, though the US

    as the most important economy in the world is still a large consumer of energy

    derived from coal.

    Below is a breakdown of all the significant sources of sulfur dioxide emissions (based

    on sources of the UK emissions) :

    1. Energy Production

    a. Electric power generation

    b. Petroleum refining

    c. Other combustion

    d. Commercial and residential use

    e. Combustion for industry use

    f. Production processes

    g. Extraction and distribution of fossil fuels

    h. Transport

    2. Road transport

    a. Other Transport (such as aviation, ships, trains).

    Currently, the most important sources of sulfur dioxide emissions (as a result of

    fossil fuel combustion) are electric power generating plants.

  • For example, as of 1998, 66% of all sulfur dioxide emissions in the UK came from

    power plants. In contrast, transport contributions of sulfur dioxide emissions are

    among the smallest ones

    The biggest sulfur dioxide emitters: US, China and Russia.

    In fact, you may be surprised to learn that just one Siberian city in Russia Norilsk

    produces 1% of the total global emissions of sulfur dioxide. In 2007, Norilsk was

    considered to be one of the most polluted places on Earth.

    There are also significant sulfur emissions generated by natural sources.

    The main natural sulfur emissions come in the reduced forms of sulfur compounds

    such as

    a. hydrogen sulfide (H2S)

    b. carbon disulfide (CS2)

    c. carbonyl sulfide (COS) and in the organic forms of:

    d. methyl mercaptan (CH3SH)

    e. dimethyl sulfide (DMS) (CH3SCH3)

    f. dimethyl disulfide (DMDS) (CH3SSCH3)

    Most of these compounds get oxidized to sulfur dioxide or to sulfate aerosols in the

    atmosphere.

    Marine phytoplankton produce dimethyl sulfide (DMS) which is then oxidized to SO2

    in the atmosphere; decay processes in soil and vegetation produce H2S (as one of

    sulfur compounds); and SO2 is emitted into the atmosphere by volcanoes.

    Around 90% of all natural sulfur emissions come in the form of DMS.

    Most recently the natural sources have been by far surpassed by anthropogenic

    sources. Natural sources have been estimated to produce around 24% of all sulfur

    dioxide emissions, whereas human-caused emissions made up around 76%.

    Effects of Sulfur Dioxide Emissions

    Sulfur dioxide found in the air produces following effects:

    1. Irritates eyes, nose, throat

    2. Damages lungs when inhaled

    As part of acid rain:

    a. acidifies lakes and streams

    b. destroys plant and fish life in lakes and streams

  • c. may deplete mineral nutrients in the soil

    d. may cause reduction of forest and agricultural yields

    e. corrodes metals

    f. damages surfaces of buildings.

    2. Nitrogen Oxides

    Oxides of nitrogen are produced by combustion of all fossil fuels including coal- and

    gas-fired power stations and motor vehicles

    Whereas fuel itself can produce some nitrogen (for example, oil and coal contain

    around 0.5 1.5% of nitrogen, and natural gas contains less than that most of

    nitrogen oxides' production comes from the reaction of atmospheric nitrogen and

    oxygen within the combustion chamber.

    The two main nitrogen oxides are nitric oxide (NO), or nitrogen monoxide, and

    nitrogen dioxide (NO2) the sum of which is equal to NOx.

    Nitric oxide (NO) is a colorless gas.

    Nitrogen dioxide (NO2) is a gas of reddish-brown color with a distinct sharp, biting

    odor. (26)

    Combustion of fuels always produces both NO2 and NO.

    But almost 90% of the NOX combustion product is in the form of NO which is then

    oxidized to nitrogen dioxide (NO2) in the air

    Therefore, only a small percentage of NO2 found in the atmosphere is directly

    emitted there in this form. The rest has been formed as a result of chemical

    reactions in the atmosphere itself.

    Road transport (motor vehicles) is by far the largest contributor of nitrogen

    emissions (in contrast, it contributes a very small proportion to sulfur dioxide

    emissions, as discussed above).

    For example, based on 1998 UK figures, road transport contributed nearly half of

    all nitrogen emissions, followed by contributions from electric power generating

    plants which only contributed around 20% of total nitrogen emissions

    Below is a breakdown of the significant sources of emissions of nitrogen oxides

    (based on sources of the UK emissions):

    1. Road transport

    2. Other Transport

    3. Energy Production

    4. Electric power generation

  • 5. Petroleum refining

    6. Other combustion

    7. Combustion for industry use

    8. Production processes

    9. Extraction and distribution of fossil fuels.

    Nitric oxide (NO) is also emitted by soils but there is very little data available for the proper

    assessment of this area.

    Some estimates suggest that the soil production of NO in the UK may be around 2 5% of its

    production from fossil fuel combustion.

    Effects of Nitrogen Dioxide (NO2) Emissions

    When inhaled, nitrogen dioxide becomes a serious air pollutant which may :

    Cause pulmonary edema (accumulation of excessive fluid in the lungs)

    Be part of acid rain (destroying fish and plant life in lakes, damaging surfaces of buildings etc)

    Contribute to photochemical smog.

    3. Carbon monoxide (CO)

    Carbon monoxide is a colorless, odorless gas which is highly toxic to humans.

    The combustion of carbon-based fuels produces carbon dioxide (CO2).

    But not all such combustion is complete, and this leads to the production of carbon monoxide

    (CO).

    Motor vehicles and industry are among the largest anthropogenic sources of carbon monoxide

    emissions.

    Effects of Carbon Monoxide Emissions

    Carbon monoxide is the most common type of fatal poisoning in many countries around the

    world.

    Exposures to carbon monoxide may lead to

    Toxicity of the central nervous system and heart

    Severe effects on the baby of a pregnant woman

    Headaches and dizziness

    Problems with getting oxygen supplied to some body parts which may be life-

    threatening.

    4. Particular Matter

    Particles can come in almost any shape or size, and can be solid particles or liquid

    droplets. We divide particles into two major groups. These groups differ in many

  • ways. One of the differences is size, we call the bigger particles PM10 and we call the

    smaller particles PM2.5.

    The big particles are between 2.5 and 10 micrometers (from about 25 to 100 times

    thinner than a human hair). These particles are called PM10 (we say "P M ten", which

    stands for Particulate Matter up to 10 micrometers in size). These particles cause

    less severe health effects.

    The small particles are smaller than 2.5 micrometers (100 times thinner than a

    human hair). These particles are called PM2.5 (we say "P M two point five", as in

    Particulate Matter up to 2.5 micrometers in size).

    Size isn't the only difference. Each type of particle is made of different material and

    comes from different places.

    Coarse Particles (PM10)

    Fine Particles (PM2.5)

    What they

    are

    smoke, dirt and dust

    from factories, farming,

    and roads

    mold, spores, and

    pollen

    toxic organic

    compounds

    heavy metals

    How theyre

    made

    crushing and grinding rocks and

    soil then blown by wind

    driving automobiles

    burning plants (brush

    fires and forest fires or

    yard waste)

    smelting (purifying)

    and processing metals

  • The smaller particles are lighter and they stay in the air longer and travel farther.

    PM10 (big) particles can stay in the air for minutes or hours while PM2.5 (small)

    particles can stay in the air for days or weeks. And travel? PM10 particles can travel

    as little as a hundred yards or as much as 30 miles. PM2.5 particles go even farther;

    many hundreds of miles.

    When you inhale, you breathe in air along with any particles that are in the air. The

    air and the particles travel into your respiratory system (your lungs and airway).

    Along the way the particles can stick to the sides of the airway or travel deeper into

    the lungs.

    Smaller particles can pass through the smaller airways. Bigger particles are more

    likely to stick to the sides or get wedged into one of the narrow passages deep in the

    lung.

    Other factors that affect how deep into the lungs particles can go:

    1. Mouth or nose breathing. Breathing through your mouth allows particles to travel

    deeper into your lungs.

    2. Exercise. While exercising, particles can travel deeper.

    3. Age. Older people breath less deeply so particles may not get as deep.

    4. Lung disease. If lung diseases block the airway, particles will not travel as far.

    5. Weather (temperature).

    6. Other pollutants in the air.

    Lungs produce mucous to trap the particles, and tiny hairs wiggle to move the

    mucous and particles out of the lung. If the particle is small and it gets very far into

    the lungs, special cells in the lung trap the particles and then they can't get out and

    this can result in lung disease, emphysema, lung cancer.

    Health Effects

    Both PM10 (big) and PM2.5 (small) particles can cause health problems; specifically

    respiratory health (that's the lungs and airway).

    Because the PM2.5 travels deeper into the lungs AND because the PM2.5 is made

    up things that are more toxic (like heavy metals and cancer causing organic

    compounds), PM2.5 can have worse health effects than the bigger PM10.

    Exposure to particulate matter leads to increased use of medication and more visits

    to the doctor or emergency room. Health effects include the following:

    1. Coughing, wheezing, shortness of breath

    2. Aggravated asthma

  • 3. Lung damage (including decreased lung function and lifelong respiratory

    disease)

    4. Premature death in individuals with existing heart or lung diseases

    5. Lead Dust

    Lead occurs naturally in the environment and has many industrial uses. However,

    ongoing exposure to even small amounts of lead can be harmful to your health.

    Everyone is exposed to trace amounts of lead through air, soil, household dust, food,

    drinking water and some consumer products. The amount of lead in the environment

    increased during the industrial revolution, and again significantly in the 1920s with

    the introduction of leaded gasoline.

    However, since the early 1970s lead exposure in Canada has gone down

    substantially, mainly because leaded gasoline and lead-based paint were phased out

    and the use of lead solder in food cans was virtually eliminated.

    Source Of lead:

    o Food - Traces of lead are found in almost all food. Airborne lead falls onto

    crops or soil and is absorbed by plants. Lead solder used in making cans may

    also contaminate food. However, in Canada food manufacturers have

    eliminated the use of lead-soldered cans. Infants can also absorb lead from

    their mothers' bodies through breast milk

    o Air - Lead in soil can come from the air or from erosion of lead-bearing rocks,

    and may be carried indoors as dust. Lead dust can also come from within the

    home, especially older homes that used lead-based paints or lead solder.

    Lead dust is especially dangerous for babies and young children, because they

    tend to put things in their mouths and their breathing zone is closer to floor

    level where lead dust tends to collect.

    o Drinking Water - lead can enter the water supply from lead solder in

    plumbing, lead service connections or lead pipes in your home. Lead is more

    likely to be found in soft or very acidic water and in very old or very new

    homes

    o Paint - In 1976, the amount of lead that could be intentionally added to

    interior paints was limited by federal law, but exterior paints could still

    contain higher amounts of lead, provided they carried a warning label. Most

    indoor and outdoor paints made before 1950 contained substantial amounts

    of lead. If you strip or sand old paint that contains lead, you could breathe in

    lead particles.

  • Short-term exposure to high levels of lead can cause vomiting, diarrhea,

    convulsions, coma or even death. Severe cases of lead poisoning are rare in Canada.

    Lead builds up in the body, so ongoing exposure to even very small amounts of lead

    can be harmful, especially to infants and young children. Lead taken in by pregnant

    women can also present a danger to the health of unborn children.

    Anaemia is common and lead can also damage the brain and nervous system. Other

    symptoms are:

    appetite loss

    abdominal pain

    constipation

    fatigue

    sleeplessness

    irritability

    headache

    Repeated, prolonged exposure to lead can affect your kidneys.

    Lead exposure is most serious for young children because their growing bodies

    absorb lead more easily than adults and they are more vulnerable to its harmful

    effects.

    Young children and infants are more likely to be exposed to lead because of their

    natural habit of putting objects into their mouths.

    even low level lead exposure may harm the intellectual development, behaviour, size

    and hearing of infants. During pregnancy, especially in the last trimester, lead can

    cross the placenta and affect an unborn child.

    Female workers exposed to high levels of lead have more miscarriages and

    stillbirths.

    5. Ozone (O3)

    Ozone (O3) is a colorless, poisonous gas with a sharp, cold, irritating odor.

    Ozone can be found in

    1. the stratosphere, one of the upper layers of the atmosphere, where it occurs

    naturally, and

    2. the troposphere, the lowest layer of the atmosphere, where it occurs both naturally

    and as a result of human-generated emissions.

    The natural stratospheric ozone is considered to be of beneficial nature it keeps

    harmful excessive ultraviolet sunlight from reaching the surface of the Earth.

  • Ozone which is formed in the troposphere as a result of anthropogenic emissions of

    primary pollutants, has negative effects on humans and the natural environment.

    And from this point of view it is an air pollutant.

    This human-caused ozone in the troposphere is a secondary pollutant because it is

    produced by the reaction of primary pollutants, nitrogen oxides and hydrocarbons

    [including VOCs], in the presence of sunlight.

    The troposphere ozone is the main component of the photochemical smog.

    A photochemical smog (of brown-yellow color) is a product of the chemical reaction

    between sunlight, nitrogen oxides and VOCs, which results in the formation of ozone

    and airborne particles.

    The process of ozone formation may take several days to complete, and ozone itself

    may turn out to be far from the sources of original primary pollutant emissions.

    Effects of Ozone as an Air Pollutant

    Ozone in the troposphere can have the following negative effects on animals (including

    humans) and the natural environment :

    Irritation of the respiratory system causing coughing, throat irritation and an

    uncomfortable sensation in the chest

    Susceptibility to respiratory infections

    Compromised lung function harming the breathing process which may become more

    rapid and more shallow than normal

    Inflammation and damage to the lining of the lungs

    Aggravation of asthma

    Reduction in agricultural yields

    Interference with photosynthesis and suppression of growth of some plant species

    Greenhouse Effect

    3. Happen when Earths temperature rise by certain atmospheric gases that trap

    the Suns energy

    4. Suns energy passes through atmosphere

    1. 26% is reflected or scattered

    2. 19% absorbed by clouds, gases, and particles

    3. 4% reflected to space by surface

    4. 51% reaches the surface

  • Examples of Heat Trapping Gases (greenhouse gasses):

    1. Water vapor (H 2 O)

    2. Carbon dioxide (CO 2 )

    3. Nitrous oxide (N 2 O)

    4. Methane (CH 4 )

    5. Causes of greenhouse effect are from:

    1. Deforestation and agriculture

    2. Burning of fossil fuels, gasoline, oil

    3. Burning of wood and coal

    4. CFCs

    5. Population Growth

    6. Greenhouse gasses can effect:

    1. Deforestation and agriculture

    2. Burning of fossil fuels, gasoline, oil

    3. Burning of wood and coal

    4. Population Growth

    Global Warming

    1. Heat trapped inside earth that cause general warming affected. When global

    warming happen its can increase air and water temperature

    2. Cause of global warming

    1. Greenhouse gases increase through human activity

  • 2. Deforestation

    3. Use of fertilizers

    4. Burning of organic matter

    5. Burning of fossil fuels

    Effect of global warming:

    1. Climate changes

    2. Changes in wildlife adaptations and cycles

    3. Melting of polar ice caps

    4. Increase in sea level

    5. Flooding in coastal areas

    6. Ocean Acidification

    Indoor Pollution

    Pollutant Source Health Effect What to do

    By-products of

    combustion (such

    as CO, CO 2 , NO x )

    Unvented kerosene

    and gas heaters,

    gas appliances,

    wood- and gas-

    burning fireplaces,

    leaking chimneys

    and furnaces,

    tobacco smoke,

    automobile

    exhaust in

    attached garages

    Eye, nose, and

    throat irritation,

    impaired lung

    function and

    respiratory

    function in

    children,

    bronchitis, lung

    cancer, flu-like

    symptoms.

    1. Avoid use of

    unvented gas or

    kerosene space

    heaters

    2. Keep gas

    appliances and

    furnaces properly

    adjusted

    3. Install and use

    exhaust fans

    4. Change filters on

    heating/cooling

    systems and air

    cleaners

    5. Increase of

    supply of outside

    air 6. Proper

    location of air

    intakes to avoid

    exhaust from

  • vehicles

    Radon Local geology,

    soil, water

    Lung cancer,

    possibly

    stomach cancer

    1.Seal crack and

    opening in the

    basement

    2.ventilate crawl

    space

    3.Increase

    ventilation

    Asbestos Deteriorating or

    damaged

    insulation,

    fireproofing, or

    acoustical

    materials

    Cancer and Lung

    diseases

    (smoker at

    higher risk)

    1.Test the

    suspected

    material

    2.Remove

    asbestos by

    trained

    contractor

    3.Develop

    maintenance plan

    4.Encapsulation

    of material

    containing

    asbestos

    Organic Material Paint, solvent,

    wood

    preservative,

    aerosol spray,

    cleaner and

    disinfectant, air

    freshener, hobby

    supplier and dry

    cleaned clothes

    Eye, nose and

    throat irritation,

    head ache, loss

    of coordination,

    nausea, damage

    to kidney and

    nervous system,

    Some cause

    cancer in animal

    and human

    1.Buy only what

    you need

    2.Read label and

    follow instruction

    3.Used in well

    ventilate area or

    outdoor

    4. Hang dry clean

    clothes in open

    area about 6

    hour

    Formaldehyde Pressed wood

    product

    (hardwood,

    Eye, nose and

    throat irritation,

    coughing,

    1.Used product

    with low emission

    rates of

  • plywood,

    particleboard,

    fiberboard) used

    in building and

    furniture,

    permanent press

    textile, glue,

    vehicle exhaust,

    stoves, fireplace

    fatigue, rashes

    and allergic

    reaction, cause

    cancer to

    animal, death at

    very high

    concentration

    formaldehyde

    2.Keep humidity

    low in house

    3.Increase

    ventilation

    Lead/heavy

    metal

    Paint,

    automobile,

    tobacco smoke,

    soil and dust

    Headache,

    irritation in

    mouth, rash,

    kidney damage

    1.Vaccum

    regularly

    2. Removal of

    lead in paint

    Biological

    Pollutant

    Mold, dust

    mites, pet

    dander (skin

    flakes),

    droppings and

    body parts from

    cockroaches,

    rodents and

    other pests or

    insects, viruses,

    and bacteria

    Allergic reactions,

    including

    hypersensitivity

    pneumonitis,

    allergic rhinitis,

    and some types of

    asthma. Infectious

    illnesses, such as

    influenza, measles,

    and chicken pox

    are transmitted

    through the air.

    Molds and mildews

    release disease-

    causing toxins.

    Symptoms of

    health problems

    caused by

    biological

    pollutants include

    sneezing, watery

    eyes, coughing,

    1. Install and use

    exhaust fans that

    are vented to the

    outdoors in

    kitchens and

    bathrooms and

    vent clothes

    dryers outdoors.

    2. Thoroughly

    clean and dry

    water-damaged

    carpets and

    building materials

    (within 24 hours

    if possible) or

    consider removal

    and replacement.

    3. Keep the

    house clean.

    House dust

    mites, pollens,

    animal dander,

  • shortness of

    breath, dizziness,

    lethargy, fever,

    and digestive

    problems.

    and other

    allergy-causing

    agents can be

    reduced,

    although not

    eliminated,

    through regular

    cleaning.

    4. Clean and

    disinfect the

    basement floor

    drain regularly

    Air pollution control equipment

    Type of

    equipme

    nt

    How its work Advantages/Disadvantage

  • 1.

    Gravitatio

    nal

    Sedimenta

    tion

    Chambers

    (oldest)

    1. Settling chambers are also

    referred to as gravity settling

    chambers or expansion

    chambers.

    2.In the expansion chamber, the

    velocity of the gas stream is

    reduced significantly, as the gas

    expands in a large chamber.

    3. The sudden reduction in

    velocity forces larger particles to

    settle out of the gas stream.

    4. To improve settlement

    efficiency in this settling

    chamber, baffle plates are

    provided.

    Ad

    van

    tag

    es:

    1.

    to r

    em

    ove p

    art

    icle

    s f

    rom

    the g

    as s

    tream

    2.

    used o

    nly

    for

    very

    larg

    e p

    art

    icle

    s in t

    he u

    pper

    end o

    f th

    e s

    uper

    coars

    e s

    ize r

    ange

    (appro

    xim

    ate

    ly 7

    5 m

    icro

    mete

    rs a

    nd larg

    er)

    3.L

    ow

    capital cost;

    Very

    low

    energ

    y c

    ost;

    4.

    No m

    ovin

    g p

    art

    s,

    there

    fore

    , fe

    w m

    ain

    tenance r

    equir

    em

    ents

    and low

    opera

    ting c

    osts

    ;

    5.

    Excellent

    reliability;

    6.

    Low

    pre

    ssure

    dro

    p t

    hro

    ugh d

    evic

    e;

    7.

    Devic

    e n

    ot

    subje

    ct

    to a

    bra

    sio

    n d

    ue t

    o low

    gas v

    elo

    city;

    8.

    Pro

    vid

    e incid

    enta

    l cooling o

    f gas s

    tream

    ;

    9.

    Tem

    pera

    ture

    and p

    ressure

    lim

    itations a

    re o

    nly

    dependent

    on t

    he m

    ate

    rials

    of

    constr

    uction;

    and

    10.

    Dry

    collection a

    nd d

    isposal

    Dis

    ad

    van

    tag

    es:

    1.R

    ela

    tively

    low

    PM

    collection e

    ffic

    iencie

    s,

    part

    icula

    rly f

    or

    PM

    less t

    han 5

    0

    m in s

    ize;

    2.

    Unable

    to h

    andle

    sticky o

    r ta

    cky m

    ate

    rials

    ;

    3.

    Larg

    e p

    hysic

    al siz

    e;

    and

    4.

    Tra

    ys in m

    ultip

    le-t

    ray s

    ett

    ling c

    ham

    ber

    may w

    arp

    during h

    igh-t

    em

    pera

    ture

    opera

    tions.

    2. Cyclone

    Collector

    1.Cyclone is an enclosed,

    conical tube

    2. Particle-filled air is pumped

    in at the top, above the wide

    end of the cone.

    3. As the air comes in at an

    angle, it moves down the

    cone in a spiral, increasing in

    speed as the cones

    Advantages:

    1. remove particles from the

    airstream eliminating the need

    2.to replace expensive filters and expose

    maintenance workers

    3. Can be designed to remove liquids from

    gas.

    4. Low capital costs,

    Low maintenance costs.

  • circumference grows smaller.

    4. This creates a vortex much

    like a tornado or cyclone.

    Large particles are thrown

    against the sides of the cone

    and drop to a bin at the

    bottom.

    5. A fan at the top of the

    cyclone cone draws lighter

    particles and the air up the

    center of the cyclone to an

    exhaust tube or outlet, usually

    to a filter for catching fine

    particles.

    Disadvantage :

    1.Lower collection efficiency

    2. Higher collection only when used higher

    pressured drop

    3. Collection efficiency sensitive to changes of

    gas flow, dust load and particle size

    distribution

    3.Wet

    Scrubber

    1. In the flue gas scrubber,

    the gas gets in close contact

    with fine water drops in a co-

    current or counter current

    flow.

    2. As the liquid drains through

    the vanes, it creates curtains

    of scrubbing liquid

    Advantages:

    1. remove various types of pollutants from the

    gas streams in a furnace, flue, or other device.

    2. The devices can handle a wide range of

    temperatures and moisture content, making

    them ideal for operation in just about any

    environment.

    3. Any type of contaminant can be removed

  • 3. Dust laden gas enters the

    scrubber tangentially and

    collides with the curtains

    initiating particle

    agglomeration.

    4. The coarser particles

    produced are washed down to

    the slurry outlet.

    5. A restriction disc located in

    the scrubbing vane assembly

    accelerates the spin velocity

    of the gas. This action

    combined with the flood of

    atomized liquid from the spray

    causes the formation of fine

    liquid droplets which

    encapsulate the fine

    particulates, again enhancing

    agglomeration.

    4.No secondary dust sources

    Once particles are collected, they cannot

    escape from hoppers or during transport.

    5.Ability to collect both gases and particles

    Disadvantages:

    1. the devices do require maintenance in order

    to continue operating efficiently

    2. Corrosion problems

    Water and dissolved pollutants can form highly

    corrosive acid solutions. Proper construction

    materials are very important. Also, wet-dry

    interface areas can result in corrosion.

    3. High collection efficiencies for particles are

    attainable only at high pressure drops, resulting in

    high operating costs.

  • 4. Fabric

    Collector

    1 In a bag house, dirty air

    flows into and through a

    number of cloth filter bags

    that are placed in parallel.

    2. The filters remove the

    particulate from the gas

    stream while the cleaned gas

    passes through the cloth and

    is exhausted to the

    atmosphere.

    3.The fabric filters do some

    filtering of the dust particles;

    however, their more

    important role is to act as a

    support for the layer of dust

    (filter cake) that quickly

    accumulates on it.

    3. This layer then acts in a

    highly efficient manner to

    filter both the large and small

    particles from the gas stream

    and becomes the main

    filtration mechanism

    throughout the process.

    Advantages:

    1.Bag houses have a very high collection

    efficiency for both large and small particle

    2. They are modular in design, and they can

    operate on a wide variety of dust types and

    wide range of flow rates with reasonably low

    pressure drops.

    Disadvantages:

    1. Bag houses require large floor areas to

    operate, need frequent cleaning, have the

    potential for fire/explosion hazards, and need

    bag replacement.

    2.The fabric filters have the potential to

    degrade from high temperatures or corrosive

    environments. The filters may also become

    clogged in highly humid or moist

    environments.

  • 5.Electric

    Precipitato

    r

    1. These dust-laden gases

    pass through an electrostatic

    precipitator that collects most

    of the dust. These dust-laden

    gases pass through an

    electrostatic precipitator that

    collects most of the dust.

    2. Precipitators function by

    electro statically charging the

    dust particles in the gas

    stream.

    3. The charged particles are

    then attracted to and

    deposited on plates or other

    collection devices.

    4. When enough dust has

    accumulated, the collectors

    are shaken to dislodge the

    dust, causing it to fall with the

    force of gravity to hoppers

    below

    5. The dust is then removed

    by a conveyor system for

    disposal or recycling.

    Advantages:

    1. Precipitators typically collect 99.9% or more

    of the dust from the gas stream.

    2.Very high efficiency

    3. Ability to handle very large gas flow rates

    with low pressure losses

    4. Ability to remove dry as well as wet particle

    Disadvantages:

    1.High capital cost

    2.Taking a lot of space

    3. Failure to operate on particles with high

    electrical resistivity

  • Air Pollution Index

    The air quality in Malaysia is reported as the API or Air Pollution Index. API reported

    daily air quality.API is calculated based on major air pollution in Malaysia.

    The main purpose of API is to help people to understand mean to your health.

    Five of the index's pollutant components used in Malaysia is:

    1. Carbon monoxide is reported in ppm

    2. Ozone is reported in ppm

    3. Nitrogen dioxide is reported in ppm

    4. Sulfur dioxide is reported in ppm

    5. PM10 particulate matter is reported in g/m3.

    Final API valued is calculated based on the highest reading for all 5 parameter. Each

    parameter value is calculated per day.

    This scale below shows the Health classifications used by the Malaysian government.

    0-50 Good

    51-100 Moderate

    101-200 Unhealthy

    201-300 Very unhealthy

    301- Hazardous

    If the API exceeds 500, a state of emergency is declared in the reporting area.