pond-based treatment and tertiary treatment

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    WASTEWATER TREATMENTTERTIARY TREATMENT

    PROCESS AND STABILIZATION PONDS

    DR. SUDIPTA SARKAR

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    STABILIZATION PONDS

    Waste or Wastewater Stabilization Ponds (WSPs) are artificial man-made

    lagoons in which blackwater, greywater or faecal sludge are treated by

    natural occurring processes and the influence of solar light, wind,microorganisms and algae.

    These are natural or semi-engineered processes for cost-effective

    wastewater treatment where required degree of treatment is achieved with

    minimal use of mechanical, civil and electrical facilities. These are popular

    for small communities because of their low construction and operatingcosts.

    These are essentially biological treatment processes with natural facilities

    spread over a vast area of land.

    The effluent still contains nutrients (e.g. N and P) and is therefore

    appropriate for the reuse in agriculture (irrigation) or aquaculture (e.g. fish-or macrophyte ponds) but not for direct recharge in surface waters.

    The ponds can be used individually or in series of an anaerobic, facultative

    and aerobic (maturation) pond.

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    TYPES OF STABILIZATION PONDS

    1. Anaerobic Ponds 2. Facultative Ponds 3. Aerobic Ponds 4. Maturation Ponds

    Anaerobic Treatment Ponds are deep ponds (2 to 5 m) devoid of dissolved

    oxygen, where sludge is deposited on the bottom and anaerobic bacteria break

    down the organic matter by anaerobic digestion, releasing methane and carbon

    dioxide.

    Anaerobic Ponds

    The anaerobic pond serves to:

    a)Settle undigested material and non-degradable solids as bottom sludge

    b)Dissolve organic material

    c)Break down biodegradable organic material

    BOD Loading:

    400-3000 kg/(ha.d)

    Detention Period: 5 -50 days

    BOD removal efficiency: 50-85%Volume can also

    be calculated

    considering organic loading

    in the range of 100 to 350 g

    BOD/m3/day

    NH3 80 mg NH3-N/L

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    Facultative Ponds

    CO2+NH3+CH4

    It functions aerobically at the

    surface but anaerobic conditions

    prevail at the bottom. The aerobic

    zone kept at the top is effectiveagainst release of odorous gases. It

    is most suited pond treatment

    method.Facultative

    Facultative= aerobic + anaerobic

    There is a diurnal variation in the

    concentration of dissolved oxygen.At peak sun radiation, the pond

    will be mostly aerobicdue to algal

    activity, while at sunrise the pond

    will be predominantly anaerobic.

    Daytime pH is high, as algae use bicarbonate ions to convert to new algae. NH3produced due to anaerobic digestion volatilizes out to atmosphere. pH above 9 also

    ensures killing of pathogens and E. Coli present in wastewater.

    FPs help to: a) treat wastewaterthrough sedimentationand aerobicoxidationof

    organic material b)Reduce odor c)Reduce some disease-causing microorganismsif

    pHraises d) Store residues as bottom sludge

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    Maturation Pond

    Maturation ponds are shallower (1 to 1.5 m), with 1 m being optimal. The recommended

    hydraulic retention time is 15 to 20 days. If used in combination with algae and/or fish

    harvesting, this type of pond is also effective at removing the majority of nitrogen andphosphorus from the effluent.

    These are essentially designed forpathogenremoval and retaining suspended stabilized

    solids.

    The principal mechanisms for fecal bacterial removal in facultative and maturation ponds are

    HRT, temperature, high pH (> 9), and high light intensity. Fecal bacteria and other pathogensdie off due to the high temperature, high pH or radiation of the sun leading to solar

    disinfection

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    DESIGN OF A FACULTATIVE POND (AS PER IS 5611)

    Step 1.Find out the surface

    area of the tank based on the

    rate of application of BOD5

    influent to the stabilization

    pond

    Step 2.Find out the detention

    period using the formula:

    tk

    i

    e

    eL

    L1

    tkL

    L

    i

    e

    11

    1

    Le and Liare effluent and influent BOD5, t is the detention time, k1is BOD rateconstant

    For plug flow

    For continuously

    mixed system

    Natural and constructed systems do not exactly follow either plug flow or

    completely mixed systems, hence corrections in the form of dispersion numbers

    are to be incorporated.

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    Step 3.Find out the surface area and the depth. The optimal depth is 1.5 m. If the

    calculation shows less than 1 m depth, minimum depth to be provided is 1 m.

    Step 4.calculate sludge accumulation based on the design data of accumulation

    rate of 0.07 cum/ person/ year. The desludging period is normally taken to beequal to 6-12 years. Add depth for accumulation of sludge.

    Step 5.Find out the sizes of the stabilization pond. Take length as double the

    width. Provide a free board of 0.5 m to 1 m.

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    DESIGN OF A FACULTATIVE POND

    Consider that desludging interval is equal to 6 years. Consider that the pond is exactly in

    between a plug flow and completely mixed flow reactor

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    Typical Process flow DiagramDifferent Treatment Blocks

    Bar Screens Grit RemovalPrimary Clarifier

    O2

    Aeration

    tank

    Secondary

    ClarifierNutrient

    Removal

    D

    I

    S

    P

    OS

    A

    L

    Dewatered

    Sludge to

    landfill

    AnaerobicDigester

    Gravity Sludgethickener

    Filter Press

    Screenings Grit

    PRELIMINARY PRIMARY SECONDARY TERTIARY

    Advanced

    Treatments

    SLUDGE PROCESSING

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    Treated Wastewater Effluent Still Contains

    A portion of initial organic load (residual BOD)

    Carbon matter, depletes O2, causes biomat growth

    TSS (total suspended solids)

    Depletes O2

    NH3 (ammonia)

    Toxic to fish, depletes O2, a nutrient that promotes biol. growth

    NO3 (nitrate)

    Toxic to babies, drinking water regulated, a nutrient

    Total P (total phosphorus) A nutrient

    Pathogens (bacteria/viruses)

    Disease causing

    There is a need of tertiary treatment to tackle the contaminants still remainingin the treated effluent

    To better protect public health and environment from creating a potentially

    hazardous condition such as eutrophication

    To provide additional treatment when soils or receiving waters cannot

    naturally degrade the small amount of contaminant released.

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    Nutrients Removal

    Basic nutrients present in the domestic wastewater are

    Nitrogen (ammonia, nitrite, nitrate)

    Phosphorus (soluble and insoluble) Sulfate

    Other compounds of nitrogen & phosphorus

    Problems associated with nutrients presence in wastewater are accelerate the eutrophication

    stimulate the growth of algae & rooted aquatic plants

    aesthetic problems & nuisance

    depleting D.O. concentration in receiving waters Toxicity towards aquatic life

    increasing chlorine demand

    presenting a public health hazard

    affecting the suitability of wastewater for reuse

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    Control and Removal of Nitrogen (Biologically):

    Removal of Nitrogen by Nitrification/Denitrification Processes:

    It is a two step processes

    Conversion of Ammonia to Nitrite (Nitrosomonas)

    NH4++ 2 O2 Bacteria (Nitrosomonous) NO2

    -+ 2 H++ H2O

    Conversion of Nitrite to Nitrate (Nitrobacter)

    NO2-+ 0.5 O2(Nitrobactor)NO3

    -Nitrification

    Process

    Denitrifying bacteria obtain energy from the conversion of NO3-

    to N2gas, but require a carbon source

    NO3-

    + CH3OH + H2CO3 C5H7O2N + N2+ H2O + HCO3-

    (organic matter) (cell mass)DenitrificationProcess

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    SuspendedGrowth SeparateStage Nitrification

    Single State Nitrification

    Nitrification Processes

    The following factors affect nitrification:

    a) Conc of NH4+and NO2

    -, b) BOD/TKN ratio (BOD should be gone/removed) ;

    c)Dissolved oxygen conc (need oxygen); d) Temperature; e) pH (7.5 to 8.6)

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    Need low (no) oxygen (< 1 mg/L)

    Need carbon source (BOD in Wastewater)

    Neutral pH (pH 7)

    Conc of nitrate

    Denitrification

    Separate-stage denitrification process using a separate carbon source

    O2

    Denitrification

    clarifier

    Return sludge

    Effluent

    EffluentMedia

    Carbon

    source

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    Phosphorus Removal

    Chemical Precipitation

    Calcium (lime) addition at high pH (>10)

    Reacts with alkalinity

    Alum (Aluminum Sulfate)precipitation

    Iron precipitation