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Machine Direction Orientation Films

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  • 5/21/2018 MDO Films

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    tretching film in the machine

    direction magnifies its prop-

    ertiesnot just a little, but

    a lot. MD orientation of

    blown and cast films,

    whether off-line or in-line

    with extrusion, enhances

    barrier, stiffness, flatness,

    tensile strength, and poros-

    ity. It reduces stretchiness

    and, of course, makes two orthree times more product

    with the same amount of

    plastic. Because MDO films

    are also very flat, they run many times

    faster in downstream converting oper-

    ations, adding still more value.

    Given all these advantages, why

    arent there more MDO film products in

    the market? Because most MDO films,

    beyond a few relatively simple products

    like monolayer stretch film, are very,

    February 2005 www.ptonline.com48

    very difficult to get right. For example,

    MDO can enhance nylon and EVOH

    barrier properties, but it also makes

    them brittle. If you know how much to

    preheat, how much to stretch, and

    where to anneal, you can make a suc-

    cessful product, cautions Kevin Hen-

    derson, technical marketing manager

    at Avery Dennisons Engineered Films

    Div., Concord, Ohio.

    Machine builders report a growingvolume of processors asking about

    MDO equipment, but these processors

    often dont have any idea of what they

    need or of how difficult a challenge

    awaits them. Over the years, at least

    three major packaging companies

    invested heavily to develop MDO

    films and installed multiple production

    lines, only to abandon them with little

    to show for their effort and expense.

    Most MD orienters are used as the

    By Jan H. Schut, Senior Editor

    S

    MDO FilmsLots of Promise,Big Challenges

    Machine-direction orientation is still

    discovering new market opportunities. But

    the technical difficulties are so great that

    some big projects never came of age.

    New equipment could make it easier.

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    www.ptonline.com February 2005 49

    on wide lines with high outputs. Mar-

    shall & Williams (one of the major

    equipment providers) has sold five of its

    largest MDO units4 meters wide

    for making hygiene films. Davis-Stan-

    dard has also built its largest units2

    meters widefor hygiene films. SMLin

    Austria has built MDO lines for hygiene

    films up to 3.2 meters wide.

    Processors typically develop new

    first stage in biaxial film and sheet pro-

    duction. But stand-alone MDO units

    have generated innovative film products

    since the 1960s, such as PET strapping,

    PVC food wrap, foamed PP ribbon, and

    fibrous HDPE ribbon for weaving sacks.

    MDO film hit the big time in the 1990s

    with breathable hygienic films for dia-

    per liners, self-adhesive labels, and syn-

    thetic paper. These products were made

    MDO film products on full-scale pro-

    duction equipment or on home-made,

    half-sized R&D lines. Either way, the

    machine design is usually specific to one

    product and offers little flexibility.

    Although lab-scale MDO lines are avail-

    able from M&W and Dr. Collin GmbH

    in Germany, they are of limited use to

    processors because they are too narrow

    to make samples that converters could

    Honeywells Aclar fluoropolymer film

    gets better moisture barrier from

    MD orientation, making it a clear

    alternative to aluminum foil.

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    February 2005 www.ptonline.com50

    and number of cooling rolls.

    The number of preheat rollers is

    determined not by the amount of stretch

    desired, but by the resin and intended

    throughput ratemore rollers, more

    throughput. Standard preheat-rolldiameters are 12, 18, or 24 in., though

    they can get as big as 30 in. Film can

    be drawn once or multiple times, punc-

    tuated by intermediate heating or

    cooling to obtain different effects. Draw-

    ing can be done hot or cold.

    Drawing is relatively straightfor-

    ward. A fast-draw roller turns faster

    than a slow-draw roller by a specified

    amount, stretching the film in the gap

    between them. You just have to find

    the right temperature and draw ratio,

    and that can be a pain, says Eric Hat-

    field, managing director of operations

    at FlexTech Packaging Inc. in Cincin-

    nati, which specializes in MDO films.

    Short-gap stretching is typically

    less than 2.5 mm, long-gap stretching

    is 5 to 50 mm or more. There is evenso-called zero-gap stretching or

    compression-roll drawing. The shorter

    the gap, the less film neck-in occurs.

    Neck-in typically reduces film width by

    5% to 20%. Neck-in also reduces the

    breathability that is critical to hygiene

    films. SML patented the use of rubberdrawing rolls that reduce neck-in.

    Annealing is the hardest part, says

    Flex Techs Hatfield, because film can be

    made to stretch or shrink by speeding

    up or slowing down the annealing rolls.

    Any change in speed or temperature

    changes the resulting film properties.

    MDOs ability to downgauge film

    and improve its properties at the same

    time is a compelling combination. Down-

    gauging is a large part of why proces-

    sors try so hard to make MDO work.

    Honeywell Specialty Materials took sev-eral years to develop an MDO version of

    its Aclar monolayer PCTFE fluoropoly-

    mer film to replace metal foil with a clear

    moisture barrier. Honeywell found that

    monoaxially stretching Aclar film dou-

    bled its moisture barrier, so 25-micron

    MDO Aclar has the same moisture bar-

    rier as 50-micron unoriented Aclar.

    MDO Aclar is close to its first com-

    mercial use in a pharmaceutical pack-

    age. The film is made in

    Pottsville, Pa., on three

    high-temperature ori-enters from Marshall &

    Williams with oil-

    heated rollers that can

    go up to 600 F.

    Stretchingblown film

    In the past few

    years, the pace of new

    MDO film develop-

    ments has picked up,

    especially those based

    on blown film. Machinebuilders have respon-

    ded to that interest with new hardware

    designs.

    Bruckner Maschinenbau GmbH in

    Germany, inventor of some of the earli-

    est biaxial stretching technology, has

    now taken an interest in MDO. Last

    year, Bruckner set up a new group to

    design and build monoaxial stretching

    lines for barrier and shrink films. Acom-

    pany spokesman notes that these films

    are gaining more and more signifi-

    cance in the market.Several builders of blown film

    test on full-size converting machines.

    Some resin companies, however, have

    found lab MDO lines useful.

    There are also monoaxial films that

    are stretched only in the transverse

    direction to make products like shrinklabels. But TDO systems can be even

    more limited in product flexibility than

    MDO units.

    In the past year or so, there has

    been a small but significant change in

    the flexibility of MDO equipment.

    Processors have bought full-sized pro-

    duction orienters with extra features

    intended purely for R&D. These orien-

    ters not only control the temperature

    and speed of every roller individually,

    they offer multiple web paths and mul-

    tiple draw options. This uncommonlevel of flexibility should make new film

    product development easier.

    Too many choices?MDO equipment can have an

    almost unlimited number of variables:

    the number and temperature of preheat

    rollers (two to a dozen or more); the type

    of roll heating (water, oil, or electric); the

    size of the gap between S-wrapped draw

    rollers (up to 2 in.); how many times film

    is drawn (one to three or more); tem-

    perature and dwell time for annealingor heat-setting; and the temperature

    MDO FILMS

    Black Clawsons center-opening vertical

    MDO unit is self-threading and easy to

    reconfigure, even with different roll sizes.

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    machinery have also entered the MDO

    market with starter units. Addex Inc.,

    for example, is building its first MDO

    unit now. Dubbed MDO Light, it will

    stretch coex blown film very slightly

    around 3%to flatten its inherent bag-giness. MDO Light is only a four-roll

    system with two 20-in. diam. heating

    rolls and two 20-in. cooling rolls, all indi-

    vidually driven. Tension control on the

    four rollers is accomplished not with

    load cells, but with fiber-optic tracking

    of roll diameter, rpm, and torque.

    The first of these units ships this

    month to Polyexe Corp. in Brentwood,

    N.H., to flatten an unslit tube of three-

    layer coex PP film with a layflat of 40

    in. After flattening, the film runs many

    times faster through a silicone-coatingprocess. Silicone-coated release films

    are a growing market for protective

    backings for labels, adhesive ban-

    dages, and diaper tabs.

    Polyexe plans to use its MDO

    Light line to develop other products

    with more stretch. Well see how

    much more the machine can do,

    says Oliver Zoellner, technical direc-

    tor. We intend to play with it.

    Other blown film machine

    builders have launched their own

    MDO orienters. Hosokawa Alpinehas supplied a dozen MDO units to

    processors in Europe, South Amer-

    ica, and Asia. The first went to a

    processor in France, where it runs

    in-line with extrusion after the tube

    is slit. That system requires two

    MDO units, one for the top web

    and one for the bottom. Alpines later

    MDO units are used off-line and

    need only one orienter.

    Alpine uses individual servo drives

    for heating, annealing, and cooling

    rollers, any of which can be used tostretch the film. They all have individ-

    ual tension control to take up both the

    films expansion during heating and

    its contraction during cooling, so as to

    avoid wrinkles and buckling. Individ-

    ual roll temperatures are needed for

    coex films, where a seal layer requires

    lower temperature than other layers.

    At last years K 2004 show in Dus-

    seldorf, Alpine demonstrated off-line

    MD orienting of film fed from rolls. One

    film for heavy-duty HDPE sacks was

    stretched 6:1 (gauge started at 240microns and finished at 80 microns),

    while a coex HDPE film for stand-up

    pouches was stretched 4.5:1.

    Battenfeld Gloucester Engineering

    developed an MDO unit for pre-

    stretched mono- and multi-layer

    LLDPE hand-wrapping stretch film. Itsfirst commercial model went to a Euro-

    pean processor that orients a collapsed

    tube with up to 70-in.-wide layflat.

    Macro Engineering & Technology

    also built its first MD orienter for blown

    pre-stretched (hand-wrapping) stretch

    film. It orients a collapsed bubble but

    uses cold drawing, which requires a

    triple draw and long gap. The collapsed

    bubble thins after orienting, but is

    stronger because it has two layers that

    are left stuck together in the finished

    product. Cold drawing achieves a spe-

    cial property of frozen elasticity, Macro

    explains. It takes very little stretch later

    to release the pent-up tension. So if a

    hand-wrapper exerts 5% stretch, the

    film will shrink back 20%.

    Blown film vs. castMD orienters are used with cast

    and blown film, but the properties and

    product range are very different. M&W

    says most of its blown film MDO units

    are used to make diaper film. MDO castfilm is splittier in the TD than blown

    film, since cast film has no initial orien-

    tation. But sometimes splittiness in one

    direction is desirable for films that need

    a zip strip. Cast film can also be

    thicker, and its gauge control is tighter.

    Blown film, on the other hand, hasan upper limit on starting thickness of

    about 10 to 15 mils, so after MD orient-

    ing, it can be very thin indeeddown

    to 0.2 mil (5 microns). Blown film also

    starts with an inherent degree of biax-

    ial orientation, so when strength is

    needed in an oriented film product,

    blown film may be the better choice.

    FlexTechs blown film No. 2455 is

    a paper substitute that needs biaxial

    strength. It flies through printing and

    converting machinery faster than paper

    because orienting makes it so flat andstiff. No. 2455 is an asymmetrical

    five- or seven-layer barrier film of

    nylon and HDPE. Its used for stand-

    up pouches of muffin mix.

    Trico Industries, North Kings-

    town, R.I., MD-orients cast film in

    line with extrusion to make specialty

    films for graphic arts and packaging,

    where gauge control is critical. The

    owners hail originally from M&W but

    build their own machinery.

    Avery Dennison in Painesville,

    Ohio, makes MDO cast film for self-adhesive labels. Monoaxial stiffness

    makes the labels dispense easily

    because they are stiff in one direction

    to enable easy peeling of the protec-

    tive backing. At the same time, MDO

    labels are soft in the transverse direc-

    tion, so they conform well to rounded

    shapes like bottles. Avery Dennison

    has four MDO lines making oriented

    label films in Painesville and Concord.

    Says Kelly Williams in market

    development for flexible packaging at

    Equistar, another alternative would beMDO sheet extrusion. If you MD ori-

    ent sheet, you can put out a lot more

    pounds and eliminate the need to lam-

    inate films for stiffness, Williams adds.

    Equistar is working now with an MDO

    equipment maker that also has sheet

    extrusion technology.

    Adding flexibilityEquipment suppliers are building

    new MDO units with much more flexi-

    bility than in the past. Models designed

    for product development are being con-figured with multiple web paths; one-,

    Marshall & Williams unusual lab line is

    capable of three different draw modes.

    Similar flexibility is being built for both in

    production and R&D.

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    Material mattersThe draw ratio of MDO film is lim-

    ited by the polymer: roughly 2:1 for poly-styrene, 4:1 to 5:1 for LLDPE, 5:1 for

    nylon, 6:1 to 7:1 for polypropylene, and

    8:1 to 12:1 for HDPE. (HDPE homopoly-

    mer can achieve 10 times the stiffness

    of BOPP.) PP stretch can be extended

    to 8:1 by using copolymers or blending

    in some metallocene PE. LDPE isnt

    often MD oriented because its broad

    molecular-weight distribution gives it

    too little tensile strength.

    Resin suppliers are becoming more

    interested in MDO, which achieves

    properties that biaxial orienting cantmatch. MDO can improve EVOH bar-

    rier properties, whereas biaxial orient-

    ing destroys them. MDO HDPE has

    great deadfold properties, which dis-

    appear if the film is biaxially oriented.

    Equistar Chemicals just bought a lab

    MDO machine from Dr. Collin and has

    created a computer model of how

    MDO enhances films physical proper-

    ties. Equistar is using this software to

    develop new bimodal HDPEs for MDO

    applications.

    Bimodal HMW-HDPE allows awider range of drawing conditions and

    higher draw ratios, Equistar says, such

    as 12:1 or 13:1 draw instead of the usual

    10:1. At such extreme draw ratios, struc-

    tural changes occur in the polymer,

    enhancing film properties, says Ryan

    Breese, product development engineer.

    MD orienting can open pores that

    impart breathability to products like

    hygienic liners for incontinence pads.

    Such films are filled with calcium car-

    bonate and other minerals. After MD

    orienting, the film is shocked with a

    chill roll, and then MD oriented again

    to a much greater extent to open up

    porosity by pulling the polymer away

    from the filler particles.

    A similar porosity effect occurs

    when stretching film that contains hard

    spherulites or beta-formation crystals

    that form during annealing. The crys-

    tals can be controlled to open pores of a

    particular size when the film is

    stretched. Depending on the crystal size,

    stretching leaves film that is clear, hazy,

    white, or pearlescent. Avery Dennison

    uses the smallest crystals to create clar-

    ity in its latest MDO label film, a coex

    PP grade called GCX.

    two-, and three-draw options; and self-

    threading for safety. M&W is building

    its most complex orienter ever. It com-

    bines three styles of stretchingsingle

    draw, dual draw, and zero draw gap

    under compressionas well as indi-

    vidual temperature and speed control

    on all preheat, annealing, and cooling

    rollers. The orienter is being built for

    both production and R&D use.

    The Zero Gap feature on this

    machine is a new technology licensed

    from ITW Signode and introduced last

    year by M&W. Zero Gap stretching

    takes place under compression between

    two counter-rotating draw rolls. Itresults in less neck-in and some biax-

    ial orientation, M&W says.

    Vertical orienters are also being

    built with new features for added flex-

    ibility. Two years ago, Black Clawson

    built its first vertical MD orienter (with

    a 9-ft tower) and has delivered three so

    far. Their vertical format is self-thread-

    ing and more accessible to operators.

    M&W built its first vertical MD orien-

    ter in 1995 and says about 20% of its

    MDO units now are vertical. Battenfeld

    Gloucesters MDO unit is also a verti-cal self-threading design.

    PT

    NEED TO KNOW MORE?For more information, enter PTDirect code atwww.ptonline.com

    Addex Inc., Stoughton, Mass.(781) 344-5800 PTDirect:274WX

    Battenfeld Gloucester Engineering Co.,Gloucester, Mass.(978) 281-1800 PTDirect:837KP

    Black Clawson Converting Machinery Inc.,Fulton, N.Y.(315) 593-0396 PTDirect:683CT

    Bruckner Inc., Greenville, S.C.(864) 234-7111 PTDirect:343TF

    Davis-Standard Film & Coating Systems,Somerville, N.J.

    (908) 722-6000 PTDirect:151JBDr. Collin GmbH, Ebersberg, Germany+49 8092 20 96-0 www.drcollin.de

    Equistar Chemicals, Houston(713) 652-7300 PTDirect:189PB

    Hosokawa Alpine American, Natick, Mass.(508) 655-1123 PTDirect:664YD

    Macro Engineering & Technology Inc.,Mississauga, Ont.(905) 507-9000 PTDirect:597VB

    Marshall & Williams Plastics, Woonsocket, R.I.(401) 765-7770 PTDirect:627FK

    SML Extrusion Technology Inc., Kennesaw, Ga.(770) 924-0991 PTDirect:756DM

    Addex is introducing MDO Light, a four-roll MDO system that reheats blown film

    and stretches it just enough to flatten it for faster downstream converting.

    MDO FILMS