lesson 8 2014. lesson 8 2014 our goal is, that after this lesson, students are able to recognize the...
TRANSCRIPT
BK50A2700 Selection Criteria of Structural Materials
Lesson 82014
Selection of adaptive materials
Lesson 82014
The goal of this lesson
Our goal is, that after this lesson, students are able to recognize the main groups of adaptive materials with their typical adaptive properties and are able to evaluate the possibilities to utilize adaptive materials in engineering applications.
Terminology and definitions
Adaptive materials have properties, which can be changed ”dramatically” by different stimulus. E.g. viscosity, density, volume, thermal or electrical conductivity can be changed in that way.
Properties of ”ordinary” materials do also change e.g. due to temperature changes. E.g. viscosity changes due to temperature, but the change is only limited, while the viscosity of adaptive materials can be changed rapidly from solid to liquid and vice versa.
The stimulus to produce the “dramatic "change of selected properties could be temperature, light, humidity, pH-value, changes of electric or magnetic fields etc.
What’s the difference between adaptive and ordinary materials?
Briefly about the terminology
Several terms are used with different emphasis :Smart materialsIntelligent materialsActive materialsAdaptive materialsFunctional materials(Adaptive) ”Material” vs. ”Surface” vs. ”Layer”
Design of intelligent products
INTELLIGENTPRODUCT
ORSMART
MACHINE
ABILITY TO ”OBSERVE” THE ENVIRONMENT
ABILITY TO ”MAKE DECISION”BASED ON STIMULUS (INPUTS)
ABILITY TO ”REACT AND/OR ADAPT” TO THE CHANGES OF
THE ENVIRONMENT
ABILITY TO COMMUNICATE WITH THE USER AND/OR
ENVIRONMENT
WHAT INTELLIGENTFEATURES
ARE REQUIRED?
WHAT IS NEEDED TO
ENABLE THESE INTELLIGENT FEATURES?
SENSOR TECHNOLOGY
MONITORING TECCNOLOGY
CONTROL-TECHNOLOGY
DATATRANSFER
TECHNOLOGY UT
ILIZ
AT
ION
OF
AD
AP
TIV
E M
AT
ER
IALS
INPUT
MEMORY MATERIALS
MAGNETOSTRICTIVE MATERIALS
PIEZOELECTRIC MATERIALS
Change of the electric field
Change of the magnetic field
Change of the temperature
TiNi, TiPd
TbFe, (TbDy)Fe, SmFe
PZT, Quartz
MAIN GROUP OF ADAPTIVE MATERIALS EXAMPLES OF MATERIALS
Material science
Composite structure
Powder metallurgy
ChemistryNano-
technology
Coating technology
ADAPTIVE MATERIALS
Different adaptive material groups
Piezoelectric materials
Rheological materials
Strictive materials
Memory materials
Auxetic materials
Phase change materials
Biologically active materials
Chromogenic materials
pH-active materials
Adaptive gels
Functional coatings
Electrostrictive, (Piezoelectric materials)Magnetostrictive
ElectrorheologicalMagnetorheological
Crystal-basedPolymers Fibre reinforced Foams
Cosmetic Medicines Sensing applications
PhotochromicThermochromicElectrochromicSolvatochromicLonchromicTribochromic Piezochromic
Temperature shape-memory materialsMagnetic shape-memory materialsShape-memory polymers
Protective DecorativeNon-reflectiveAnti-adhesiveTribologicAnti-static SensorsOptical
Polymer gelsConductive polymers Insulating elastomers Ferro-gels
ADAPTIVE MATERIALS
Piezoelectric materials
Piezoelectric materials are used in sensors to measure impact forces or density (viscosity) values of liquids.
Piezoelectric materials are also used in quartz clocks, electrical drums and guitars, microphones etc.
Piezoelectric sensors are manufactured by powder metallurgy
Examples of piezoelectric materials:Aluminium phosphate (AlPO4)Some fluoropolymers Gallium phosphate (GaPO4), Some ceramics (BaTiO3, KNbO3, LiNbO3,
LiTaO3, BiFeO3, NaxWO3, Ba2NaNb5O5, Pb2KNb5O15).
Function Additional measurement of
absolute pressure through deformation of the door in a side crash and additional sensing of absolute pressure
Installation within the side door
Sensing principle Piezo-resistive, micro-
mechanical pressure sensor with highly-integrated evaluation electronics
How to measure and evaluate adaptive properties?
Output strain [m/V] Output strain/affecting electric field strength -
ratioOutput electric field strength [Vm/N]
Output electric field strength /affecting mechanical stress -ratio
Characteristic describing the change between energy types= Stimulating mechanical energy/produced
electric energy -ratio (or vice versa)
These characteristics might have different values in different directions of the sensor
Strictive materials
Electro- ands magnetostrictive materialsElectrostrictive materials strain due to the applied electric field.
They are (unlike the piezoelectric materials) not poled. The most prominent electrostrictive material is lead magnesium
niobate (PMN).Magnetostrictiive materials change their length when subjected to
a magnetic field. Magnetostrictiive materials generate a magnetic field when they are
deformed by an external force. Magnetostrictive materials can be used for both sensors and
actuators.Commercially-available magnetostrictive materials are based on
Terbium (Te), Iron (Fe), Dysprosium (Dy) alloys.
Magnetostrictive effects Joule effect : When subjected to an magnetic field the length of the
material will change.(Used in magnetostrictive actuators.) Villari effect: When a mechanical stress is imposed on a sample, there
will be a change in the magnetic flux density. (Used in magnetostrictive sensors.)
Barret effect:The volume of the material change in response to the
magnetic field.
ELECTROSTRICTIVE FIBRES ARE USED TO DAMP VIBRATIONS OF SNOWBOARDS
When skiing at high speeds and on tough terrain, skis tend to vibrate, decreasing the contact area between the snowboard edge and the snow surface.
This results in reduced stability and control and decreases the skier's speed.
Smart snowboards overcome these limitations by utilizing the integration of electrostrictive sensors and an actuator control system.
The electrostrictive ceramics or fibers embedded in the snowboard convert the unwanted vibrations into electric energy, thus keeping the snowboard on the snow.
Magnetostrictive Villari effect is utilized in position sensors of hydraulic cylinders
Rheological materials
Electrorheological materials Electrorheological (ER) materials’
flow, viscositydamping capacity internal friction the ability to absorb energy under impact
depend on the strength of the affecting electric field.
At high enough electric fields, the liquid materials can solidify rapidly (in milliseconds) into viscoelastic solids. This phenomenon is instantly reversible, if the electrical field is removed.
ER materials are typically fluids, gels or elastomers.
ER materials may consist of different types of mixtures such as silicon oxide gel, talcum powder and various polymers with liquids such as kerosene, mineral oil, toluene and silicone oil work.
Some applications:Improvement of the vibration control
characteristics of an damping absorber using ER fluid as the working fluid inside the absorber.
ER fluid based application of a clutch for direct coupling device in power transmission system of rotating machinery.
Magnetorheological materialsThe function of magnetorheological
materials (MR)is analogic with electrorheological materials.
At high enough magnetic fields, the liquid materials can solidify rapidly (in milliseconds) into viscoelastic solids. This phenomenon is instantly reversible, if the magnetic field is removed.
Magneto-rheological fluid-filled dampers are used to provide continuously variable real-time suspension damping control for cars.
RHEOLOGIC MATERIALS ARE USED E.G. IN SHOCK ABSORBERS OF AIRCRAFTS.
Memory materials
Shape memory materials (SMM)Shape memory materials (SMMs) are featured by the
ability to recover their original shape from a significant plastic deformation when a particular stimulus is applied. This is known as the shape memory effect (SME). Typically the stimulus is heat.
Superelasticity (in alloys) or visco-elasticity (in polymers) are also commonly observed under certain conditions.
Most of the memory properties are based on the changes of the crystal structures of the materials.
An other remarkable stimulus of shape memory materials (MSM-materials) is magnetic field.
Metallic Shape memory alloys (SMA) AuCd and AgCd alloys were the first memory alloys
Three alloy systems
NiTi-basedCu-based (CuAlNi , CuSn, CuZnAl) Fe-based
have the largest commercial importance.
All these SMAs are thermo-responsive, i.e., the stimulus required to trigger the shape recovery is heat (not more than 10 degrees change of the temperature might start the adaptive function).
NiTi-based alloys should be the first choice if high performance and good biocompatibility are required. However, the manufacturing processes of NiTi-alloys is challenging.
Cu-based SMAs have the advantages of low material cost and good workability in processing.
Fe-based SMAs are used as a fastener/clamp for one-time actuation due to the extremely low cost.
Shape memory materials, which react to the changes of the magnetic field are usually based on Ni-Mn-Ga-alloys (eg. Ni2MnGa). The deformation due to stimulus could be even 10%.
PZT-material
MSM Ni-Mn-Ga
Control Field Electric Magnetic
Max. strain ξ (µm/mm), linear 0.3 100
Compressive strength (MPa) 60 700
Max. operating temp. (°C) 100 70
Field strength for max. strain 2 MV/m 400 kA/m
COMPARISON OF MSM MATERIALS
Shape memory polymers (SMP)Advantages of SMPs compared to metal alloys:Tailoring the material properties of polymers is much easier.Both the material cost and the processing cost of polymers are
much lower .SMPs are much lighter. Different stimuli can be utilized: The stimulus could be heat, UV- or
infrared light, moisture or pH change. Many SMPs are naturally biocompatible and even biodegradable.
Some typical materials:The thermoplastic polyurethane (e.g. in clothes)Composites with fillers based on SiC nanoparticles) Ni powder in a polyurethane SMP/carbon black composite.
Other shape memory materialsShape memory compositesShape memory composites (SMC), which include at least
one type of SMM, either SMA or SMP, as one of the components
Shape memory hybridsShape memory hybrids (SMH) are made of conventional
materials.They are based on the dual-domain system, in which one is
the elastic domain and the other is the transition domain, which is able to change its stiffness remarkably if the stimulus is present.
Auxetic materials
Auxetic materialsAuxetic materials are a special kind of materials that
exhibit negative Poisson’s ratio effect. They get fatter when stretched and thinner when compressed.
Auxetic behavior is can be achieved at different structural levels from molecular to macroscopic levels.
The internal (geometrical) structure of material plays an important role in obtaining auxetic effect
The behaviour of the auxetic material could be illustrated as a desired “function of a mechanism” .
Auxetic materialsPractical examples:
Auxetic polyurethane (PU) foamAuxetic microporous PTFESome forms of graphiteNi3Al crystals Carbon/epoxy, Kevlar/epoxy or Glass/epoxy composites could
have auxetic properties in a minor scale.
Advantages:Adjustable strength and rigidity based on the loading directionImproved ware resistanceImproved ductility of fibre reinforced composites
Fpull
Fpull
Fpull
Fpull
Fpull
Fpull
Fpull
Fpull THE STRUCTURE GETS THINNER
THE STRUCTURE GETS THICKER
Principal function of auxetic materials
ORDINARY
AUXETIC
Fpull Fpull
Fpull Fpull
MATRIXFIBRE
TRADITIONAL FIBRE GETS THINNER UNDER
TENSILE LOAD
AUXETIC FIBRE GETS THICKER UNDER TENSILE LOAD
IMPROVING THE DUCTILITY OF FIBRE REINFORCED COMPOSITES
Properties of the foam can be specified by defining three independent characteristics: 1. Pore Size 2. Relative Density 3. Base Material
Chromogenic materials
Chromogenic materialsChromogenic materials are able to change
their optical properties in response to an external stimulus such as temperature, light, electrical current or pressure etc.
Photochromic
Thermochromic
Electrochromic
Solvatochromic
Lonchromic
Tribochromic
Piezochromic
Light
Temperature
Current
Polarity of liquids
Ions
Mechanical friction
Mechanical pressure CH
AN
GE
OF
TH
E O
PT
ICA
L M
AT
ER
IAL
PR
OP
ER
TIE
S
MATERIAL GROUPS
CHROMOGENIC MATERIALS
STIMULUS OUTPUT
Self darkening electrochromic rear view mirrorPhotochromic sunglasses
Properties of the chromogenic materialCan be tuned either passively or actively.
Solar panel applications
Biologically active materials
Biologically active materialsThe most important material property is
biocompatibility (non-rejection property)Applications:Bio-electric prosthetic noseTaste receptors of an electronic artificial tongue:Vibrotactile sensing elements for artificial skin
applicationsArtificial skin made of polymer applications like
synthetically manufactured collagens and polypeptidesMaking individually tuned “spare parts” for a human
body (like bones of ceramics)“So-called Tissue engineering”
Phase change materials
Phase change materials (PCM)In theory when the temperature rises, the PCM melts and the
material absorbs heat. When the temperature drops, the PCM solidifies, and heat is emitted. During the phase change, the temperature remains constant.
Of course ordinary materials do also absorb and emit heat energy, but their phase remains the same.
PCM’s capacity to absorb and emit heat energy could be 5…10 times higher compared with ordinary materials.
Possible PCM material types: Polyethylene-paraffin compounds, mixtures based on hydrated salts such as CaCl2+6H2O, Na2SO4+10H2O, Na2HPO4+12H2O, NaCO3+10H2O, and Na2S2O4+5H2O.
WATER
STONE
WOOD
POLYM
ER
PHASE CHANGE M
ATERIALS
0
0.5
1
1.5
2
2.5
3
3.5
4
4.5
HE
AT
CA
PA
CIT
Y k
J/k
g,
ΔT
15
°
pH-active materials
pH-active materials Microcapsules embedded in a coating can detect corrosion by detecting the
pH-change caused by it and release their contents automatically to indicate, protect, and repair damaged areas.
Adaptive gels
Adaptive gelsDifferent ways to classify adaptive gels:
Applications of adaptive polymer gels in general
Polymers with electric conductivity properties
Insulating elastomersFerrogels
The initial volume of polymer gels can be increased 1000-times larger based on stimulating pH, temperature or electromagnetic field changes
The size of the artificial muscle is near the size of real human muscle (if the performance is about the same)
Smart gels can have either electro- or magnetostrictive properties
Some important polymer gels:- PVA - PAA - PAN
Electrostrictive gels:Applications of PMMAFerrogels made of PVA-polymer and Fe3O4
mixture
Electrically conductive polymers:PAni PPYPPV
Functional coatings
Functional coatingsDIFFERENT MATERIAL OPTIONS: COMPOSITES , NANO OR
HYBRID COATING MATERIALS
ADAPTIVE GENERAL SURFACE PROPERTIES Self-cleaning, , anti-fingerprint, antifogging, anti-icing
ADAPTIVE PHYSICAL AND MECHANICAL PROPERTIES scratch resistant (CrN, TiAlN, TiC) , abrasion resistant, low-friction MoS2 PbO, MoO3,
TiO2, self-polishing, fire resistance
ADAPTIVE BIOACTIVE PROPERTIES Antimicrobial, antifouling, hygienic coatings, antifungal, antioxidant
ADAPTIVE CHEMICAL , ELECTRICAL AND THERMAL PROPERTIES
Anticorrosion, conductive coatings, anti-static coatings, dielectric coatings, piezoelectric coatings, electro-magnetic shielding
ADAPTIVE RADIATION AND OPTICAL PROPERTIES photochromic, thermochromic, anti-reflection