gisap: physics, mathematics and chemistry (issue3)

International Academy of Science and Higher EducationLondon, United KingdomInternational Scientific Analytical Project

GISAP: 3 Liberal* | August 2014

PHYSICS, MATHEMATICS AND CHEMISTRY

42

Physics, mathematics and chemistry

GISAP: Physico-Mathematical and Chemical Sciences 3 Liberal* (August, 2014)chief editor J.d., Prof., acad. Pavlov V.V.

62

Biology, Veterinary Medicine and agricultural ScienceS

Chief Editor J.D., Prof., Acad. Pavlov V.V.

Copyright 2013 IASHE

Design: Yury Skoblikov, Helena Grigorieva, Alexander Stadnichenko

Published and printed by the International Academy of Science and Higher Education (IASHE), 1 Kings Avenue, London, N21 1PQ, United Kingdom.Phone: +442032899949, e-mail: [email protected], www: http://gisap.eu

! No part of this magazine, including text, illustrations or any other elements may be used or reproduced in any way without the permission of the publisher or/and the author of the appropriate article.

expert group:

Hokuma Kulieva (Azerbaijan), Maya Aizamaparashvili (Georgia), Laszlo Korpas (Hungary), Saito Kano (Japan), Dani Sarsekova (Kazakhstan), Mikhail Nikonov, Boris Testov (Russia), Gabriel Grazbungan (Switzerland), Thomas Stevens (USA)

dear friends and colleagues!

It doesnt matter how would human society lauded the importance of intelligence and social organization, the original

basis of human being is biological life. The biological evolution of man predetermined the formation of his intellectual function and social organization, as well as largely determines their current and future development. Moreover, the

human as a species can not exist in isolation from the general system of wildlife. This is connected with the fact that

most of the resources that support livelihoods and meet the basic needs of the people, also has a biological origin. The interdependence of humans and other species of biological life on Earth is so close and multifaceted, that if even one of the least significant element is falling out of the system, it reduces the overall viability of the entire biosphere. That

is why, understanding the natural environment and its embeddedness in the structure of biological processes, a human

has to take care of preservation, augmentation and development of all species. In this regard, the importance of zoology and botany, veterinary, agricultural and other biological sciences, in the context of the prospects for the survival of humanity, no less than, for example, medicine and pharmacology.

Thomas MorganHead of the IASHE International Projects Department

July 04, 2013

Dear Friends!The focus of attention - a human! That is the slogan with which conscious life of each of us flowing. In this case, the angle of the humanself-knowledge in the various historical periods of social evolution and biological phases of personal development, as well as taking intoaccount the actual circumstances of life are transforming. At the epicenter of the interests of individuals, changing places in the structure of thehierarchy of values, appear: these subjects, public concerns and interests, the other person different quality characteristics.However, the nature of our intelligence, as it is known, does not accept the boundaries literally and figuratively. Imagination andaspirations of the people will certainly captivate them to the unexplored places. But no matter how far beyond the borders of subjectivity didnot extend human imagination and thought, what would be the facts and metamorphoses they faced, the final result of such intellectual activityappears with a humanizing of reality. In this context, it is hardly surprising that, for example, all kinds of phenomena in the field of wildlife,inorganic chemistry, molecular physics or astronomy in our minds often personified purely human qualities and role attributes.Probably it is not worth to discuss how saturated with the human identity are, in particular, psychology or social sciences, the subject ofwhich is aimed at studying the properties of various social processes. Anybody thinking about this topic, surely will exclaim: "Life is just fullof human egoism." And it is right! Human selfishness, free of demonization and devoided of extremely negative manifestations - isomnipresent and progressive! It is often the most reliable point of support in the knowledge and creation. Another issue is that the dynamicsof the process of social evolution largely depends on how mankind is able to adequately recognize the progressive and negative manifestationsof human nature, and then promptly neutralize the ego that generates evil.This digital includes articles presented at the XLVII International scientific and practical conference " The person in conditions of theinterpersonal relationships intensification," on XLVIII International scientific-practical conference "Technologies of XXI century globalization:evolution or setback?" and also on the I stage of research analytics championships of various levels on the psychological, military, sociologyand political science.We sincerely thank the authors who have represented their works in the digital for an active participation in international scientificcommunication, we congratulate the winners of the respective research analytics championships, and look forward to further participation ofscientists in the "International scientific-analytical project IASHE" as well as their ideas and scientific developments.

March 07, 2013. London, UK

Sincerely yours and best wishes, -Thomas Morgan

ISSN 2054-6483ISSN 2054-6491 (Online)

* Liberal the issue belongs to the initial stage of the journal foundation, based on scientifically reasonable but quite liberal editorial policy of selection of materials. The next stage of development of the journal (Professional) involves strict professional reviewing and admission of purely high-quality original scientific studies of authors from around the world.

Expert group:

Rena Kasumova (Azerbaijan), Nathan Lebrun (France), Yuri Khlopkov (Russia), Brian Hurst (UK).

Published and printed by the International Academy of Science and Higher Education (IASHE) 1 Kings Avenue, London, N21 1PQ, United KingdomPhone: +442032899949, E-mail: [email protected], Web: http://gisap.eu

62

Biology, Veterinary Medicine and agricultural ScienceS

Chief Editor J.D., Prof., Acad. Pavlov V.V.


Design: Yury Skoblikov, Helena Grigorieva, Alexander Stadnichenko

Published and printed by the International Academy of Science and Higher Education (IASHE), 1 Kings Avenue, London, N21 1PQ, United Kingdom.Phone: +442032899949, e-mail: [email protected], www: http://gisap.eu

! No part of this magazine, including text, illustrations or any other elements may be used or reproduced in any way without the permission of the publisher or/and the author of the appropriate article.

expert group:

Hokuma Kulieva (Azerbaijan), Maya Aizamaparashvili (Georgia), Laszlo Korpas (Hungary), Saito Kano (Japan), Dani Sarsekova (Kazakhstan), Mikhail Nikonov, Boris Testov (Russia), Gabriel Grazbungan (Switzerland), Thomas Stevens (USA)

dear friends and colleagues!

It doesnt matter how would human society lauded the importance of intelligence and social organization, the original

basis of human being is biological life. The biological evolution of man predetermined the formation of his intellectual function and social organization, as well as largely determines their current and future development. Moreover, the

human as a species can not exist in isolation from the general system of wildlife. This is connected with the fact that

most of the resources that support livelihoods and meet the basic needs of the people, also has a biological origin. The interdependence of humans and other species of biological life on Earth is so close and multifaceted, that if even one of the least significant element is falling out of the system, it reduces the overall viability of the entire biosphere. That

is why, understanding the natural environment and its embeddedness in the structure of biological processes, a human

has to take care of preservation, augmentation and development of all species. In this regard, the importance of zoology and botany, veterinary, agricultural and other biological sciences, in the context of the prospects for the survival of humanity, no less than, for example, medicine and pharmacology.

Thomas MorganHead of the IASHE International Projects Department

July 04, 2013

Print journal circulation: 1000


The history of fundamental knowledge shows that its development has always been accompanied with the inconsistent attitude from the society. Admiration, desire to understand unknown, misunderstanding, scepticism and categorical denial have always been comprehensively mixed in the structure of the traditional social reaction to achievements of natural-science and mathematics.

However knowledge of fundamental bases of life and mathematical tools of objective reality and abstract elements analysis is closely connected with public progress. Its actual improvement could be stopped only by termination of human evolution process.

Development of the society predetermines formation of new demands requiring satisfaction in mental environment. Eventually such requirements always become more and more comprehensive. The knowledge intensity of the mechanism of their satisfaction inevitably increases. At the same time being in the continuous process of consumption of social benefits the person rarely realizes the fact that many personal demands (even the most primitive) are satisfied in a way based on outstanding discoveries.

While thinking about this idea, it is easy to come to a conclusion about major injustice of the social attitude to the fundamental knowledge: they arent popular - often they are not interesting for people; natural-science and mathematical concepts are generally understood as excessively difficult and boring matters; many people consider such knowledge as useless; scientists working in this sphere are seldom famous

However one shouldnt be too quick in making conclusions. The person is always afraid of the unknown But the person always seeks for it. It is in the basis of the Homo sapiens nature. Comprehension of a mystery is always something like a fairy tale, a miracle. A person unaware of the core of things going on around will inevitable treat the unknown watchfully.

On every next stage of development fundamental sciences often considerably expand borders of human knowledge. Every such scientific breakthrough will be considered by the majority of members of the society as a miracle Certain detachment of mass consciousness from fundamental studies is not a consequence of neglect, but the result of contact of unready intellect with deep mysteries of life.

Thomas Morgan Head of the IASHE International Projects Department

august 11, 2014


CONTENTS

S. Zykova, Perm Institute of the Federal Penitentiary Service, RussiastUdy OF BiOLOGicaL actiVity OF PrOdUcts OF synthesis OF tetraKetOnes With aryLiden aryLamines 3

N. Mamulaishvili, Batumi Shota Rustaveli State University, GeorgiaT. Mamedova, Research Institute of Petrochemical processes, AzerbaijanT. Hitarishvili, Georgian Technical University, GeorgiacOncretiOn OF asPhaLtic-resinOUs cOmPOUnds OF the WOrKed-OUt mOtOr OiL With Use OF chemicaL reaGents 5

E. Suleimenov, Kazakh-British Technical University, KazakhstandeterminatiOn OF the micrO-strUctUre eLements cOmPOsitiOn OF nOn-OrGanic aQUeOUs sOLUtiOns On the eXamPLe OF VanadiUm PentOXide sOLUtiOn 7

E. Alikina, M. Degtev, Perm State University, RussiaeXtractiOn OF iOns OF Zn and cd FrOm thiOcyanate sOLUtiOns By meLts OF miXtUres OF diantiPiriLmethane and BenZOic acid 12

M.I. Degtev, S.I. Rogozhnikov, O.N. Popova, A.A. Yuminova, Perm State University, RussiadeLaminatinG system antiPyrinUm sULFOsaLicyLic acid Water and its aPPLicatiOn FOr eXtractiOn OF iOns OF indiUm (iii) and stannUm (ii, iV) 16

O. Schuchkina, I. Kirillova, Saratov State University named after N.G. Chernyshevsky, RussiamOdeLinG the hemOdynamics OF cOrOnary arteries taKinG their interactiOn With the myOcardiUm intO accOUnt 19

L. Atyuckaya, A. Bebiya, M. Boronenko, Ugra State University, RussiaeXPerimentaL stUdy OF sOLid-FLame cOmBUstiOn By the ni-aL system methOd OF hiGh-sPeed VideO FiLminG 23

Yu. Khlopkov, V. Zharov, M.M. Zay Yar, Moscow Institute of Physics and Technology, Russiacertain PrOBLems OF Laser Gas dynamics 28

A. Kudryavtsev, Higher School of Social Technologies, LatviasPatiaL mULti-dimensiOnaLity OF the reaL WOrLd 31

G. Mukhamedrakhimova, Kokshetau State University named after Sh. Sh. Ualikhanov, KazakhstanK. Mukhamedrakhimov, L.N. Gumilyov Eurasian National University, KazakhstandeterminatiOn OF cOnditiOns OF FOrmatiOn OF stUdents GeneraL PhysicaL WOrLd OUtLOOK in Order tO imPrOVe FUtUre PrOFessiOn 35

A. Kryukov, Siberian Federal University, RussiaI. Kriukova, General secondary school 10, Krasnoyarsk, RussiadeterminatiOn OF eXPert QUaLity assessments 38


CONTENTS

.., , 3

H.., , .., , .., , O- 5

.., - , 7

.., .., , Zn Cd 12

.., .., .., .., , (III) (II, IV) 16

., .., . .. , 19

.., .., .., , NI-Al 23

.., .., .., - , 28

.., , 31

.., . , .., . , 35

.., , .., 10 . , 38


stUdy OF BiOLOGicaL actiVity OF PrOdUcts OF synthesis

OF tetraKetOnes With aryLiden aryLamines

s Zykova, candidate of Pharmaceutical sciencesPerm institute of the Federal Penitentiary service, russia

the author presents main stages of synthesis of new biologically active oxazines, obtained as a result of the reaction: 1,6-diaryl-3, 4-dihydroxy-2,4-hexadiene-1,6-dione with various shiff bases Obtained compounds have shown the antioxidant activity on the model of oxidative stress on the culture of bacterial cells Esherichia coli BW 25113 these compounds are promising for further studying of other kinds of biological activity

conference participant, national championship in scientific analytics

.., . .

,

- , 1,6--3,4--2,4--1,6- - . - - Esherichia coli BW 25113 - .

,

- . 1,6--3,4--2,4--1,6-, - . - [1]. - (

) -

1,6--3,4--2,4--1,6-, , 1,6--3,4--2,4--1,6- [2] ( 1).

1,6--3,4--2,4-- -1,6- 6--4---4--5,6--4-1,3- (. 2), , , -, , , , , .

- 1,6--3,4--2,4--1,6- - [3, 4].

- - .

-, - , . () , . - , - .. . - (), - , . - .

O O

OO

O O

OO

O O

OO

H

H

O

O

OHO

. 1. 1,6--3,4--2,4--1,6-

. 2. 6--

4-- 4--5,6--

4-1,3-

O

O

N

O

OH

R1

H

R2


- , . , - -. - , .

, : - (Rice-Evanset al., 1995), , ( ., 1989).

EsherichiacoliBW 25113, 9 - . - ( ) ( .., .., ..). 0,6 - E.coliBW 25113 - 1 . , (. 3).

, 1 2 , - 3 .

1,3,4,6- - 6---4--4--5,6--4-1,3--,

. -

- - - - HPI Mn-SOD, , . , - - E.coli - [5].

References:

1. Shiff, R./R.Shiff, C.Bertini// Ber.1897. Bd.30-S.601-604.

2. oje, M. 3(2H) - Furanonederivates. Ring-chaintauto- merisminthe 1,3,4,6-tetraketone series (1) / M. Poje, K Balenovich // J heterocyclic chem 1979 - vol 16 - P. 417-420.

3. 1,3,4,6- - / .., .., .. / . . . -. ., . 275- . 80- . - . - . -1998.

4. .. - 1,2,4-- 1,3,4,6- -: .... . .. . 2002. . 154-155.

5. .. - sherichiaoli / . ..., . - 2009. . 23.

E.coli BW25113 1

. 3. E.coli BW 25113 1


cOncretiOn OF asPhaLtic-resinOUs cOmPOUnds OF the WOrKed-OUt mOtOr OiL With Use OF chemicaL

reaGentsn mamulaishvili1, doctor of technical sciences, Full Professor

t mamedova2, candidate of technical sciences t hitarishvili3, doctoral candidate

Batumi shota rustaveli state University, Georgia1head of the renewable Fuels Laboratory

Research Institute of Petrochemical processes, Azerbaijan2

Georgian technical University, Georgia3

Worked-out motor oils are essential sources of environmental pollution Large volumes of motor oils are used in all branches of the national economy in the course or their exploitation they are oxidized and become useless in the world practice the worked-out motor oils (WMO) are collected and regenerated. This is economically efficient and ecologically reasonable

conference participants

-

H..1, - . , .

..2, . . , ..3,

, 1

. , 2

, 3

- , , , . () , - .

(), , , , , . - . .

- , .

- - 1.

- (AC) - -, , , , , , , , , , ..

- : 40% 60%. , , 400450 , - [1].

- - . -

1.- ,

.

500 1200

1 15 C / 20 C astmd 1298 3900-85 ./3 0,87 0,88

2 . 40 C astmD 445-06

33-852/ . 79,6 76,8

3 . 100 C astmD445-06

33-85 2/ 11,7 9,85

4 5985-79 KOH/ 2,55 2,91

5 astm d2896 11362 KOH/ 5,3 5,2

6 astmd 92 4333-87 c 208 199

7 astm D1500-98

20284 >8,5 >8,5

8 astm D6304-00

2477 %.

.

9 astm d874 12417 % 2,3 2,38

10 . 2,46 2,68


- [2]:

, ( );

, , ;

, ;

, -;

- , ,

1 - , - .

, : , - , - , . - . -

(3-4), - . . - . 203 . 2.

92,7% 95,5%. - ., . = 300 - .

, - . , - .

References:

1. .. . -: , 1989.

2. .. . . : , 1995. 192 .

3. .., .. .

4. .., .. a .

. 1.

r r

O2h2O

O2h2O

r

2.

T C,

/

.

-l 1020 1:40 20 1517

-ll .. 1:25 20 3040

-lll 17 1:10 20 5060


determinatiOn OF the micrO-strUctUre eLements

cOmPOsitiOn OF nOn-OrGanic aQUeOUs sOLUtiOns On the eXamPLe

OF VanadiUm PentOXide sOLUtiOn e suleimenov, doctor technical sciences, Full Professor

Kazakh-British technical University, Kazakhstanresults of experimental determination of the chemical composition

of elements of the microstructure of the vanadium pentoxide solution are presented in the reports

conference participant

B

.., - . , .

- , -

- .

- - , [, 1] - . - , , - [ 2, 3]. ; - , - - , . , , - -. - , - [ 4, 5]. - [ 6]. - - - [5]. , - ; , - . - [ 7, 8, 9, 10, 11]. , .. , , , , , ( -, - , - ) [ 12, 13, 14]. , - -

. - , ( ). - - (.. , - ) . . - - , - [ 15, 16, 17]. , - , ( , .). - . - - , - . , ( , , ) - - , , , . , - . - , - -5 - ( ), [18]. - -


, . [19] - - ( [20, 21]). - - - . , . .-. , .. [18]. - [ 22, 23, 24]. - - [25]. - - , , - [26, 27].

- 5 - 0,1 10 /. - ( 500-550 ) 1. - -, . , , , -, . - . - ( - -, ). .

- Q - .

Q = (ms md)/md,

ms md . 550 . -, , -5.

- ( ) . 1.

, ,

1 ...

. 1. -5

1,9 (a) 3,67 () 7,35 g/l (c), ( , , , )

()

()

(a)

, , , ( , . 1, ). , - ( ), , ( 1020 ). - , , . , , , .


, - ( - ). (. 1).

, , -. - - (. 2).

- - . , - 12V2O5

. 480H2O - . . 3 - . ,

. - . , . , , .

- ( ) : . , ( - , ) , , , , - , .

, - ( , ). - , . . , .

1. ( )

c Q, center Q, ext Q, aver

1,75 18 100 63,1875

3,68 48 60 42,92

10,38 22 20 29,095

. 2. -5

. 3.

0


. - , - ( ) - . , , - , , .

, : 1, . - , . .. , - .

, , -, - . - . , .

, -, - , , . -, -. , , - . , ( ) - - , . , - .

- - . , - .

-, , - .

( ) - -, . .

- ( ) , ( , ). , - , . , - . ( -, [18] ). , , - .

. , -, , - , - .

, - . . , - , -

, - - : - , . , . , , - ..

-

-, . , - . . , , -, , , , . , -, - . - .

- , 12V

2O

5. 480H

2O.


-, , - ( ), ..

References:

1. . 30 30 . . . . . .: , 1982, 392 .

2. .., .. . -. ( ). .: , 1987, 320 .

3. . . ., 1980, . 1, 490 .4. .. .

.: , 1987, 336 .5 hertz hermann Gerhard electrochemistry a reformulation

of the Basic Principles springer-Verlag Berlin heidelberg New York, 1980. 231 .

6. .., .. - . -: , 1983, 176 .

7. .. . 17 - , 21-26 2003 , , , . 299.

8. .. -. -- . - , ., , 2224 2004, . 93-95.

9. .. . - - - , 26-30 2008 ., , . 88-92.

10. .. -: . III - --2010, , 30-31 2010 . , .89-92.

11. .. -: . - - . 2010. 4. C. 58-65.

12 suleimenov e n experimental validation of electrolyte microstructures and potential trends in electric power storage engineering Proceedings of the 8th international conference on lead-acid batteries, 7-10 June 2011, Albena, Bulgaria, pp. 217 220.

13. .. - . materials digest of the XXXii international research and Practice conference models and methods of solving Formal and Applied Scientific Issues in Physico Mathematical, Technical and Chemical Research, 20 - 25 September. 2012 international academy of science and higher education London, p 117 121

14. .. - . , 2007 . 6, . 105-114.

15. ., .. -

. IV - - 9-10 2012 , . . 34-39.

16. ., .. - - - . IV -- 9-10 2012 , . . 31-33.

17. .. - . -- -, . 4-5 2012 , -, . 1, 218-221.

18. .., .., .., .. - . . -. 1999. 217 .

19. Suleimenov I., Kozlov V., Suleimenov ., Bekturov e Kinetics of formation of inorganic hydrogels in solutions of oxide of vanadium 5 // Problems of evolution of opened systems. Almaty, 2000 P. 86-97.

20. .., .. -. . . 1998. 240 .

21 richa J , tanaka t // macromolecules, 1984, V 17 P 2916

22 suleimenov i e , romanteyev yu P , mahato m m and suleimenov e n effects Of Pulse energy deposition On Vanadium mesogels structure conference Proceedings Xii international conference On mineral Processing technology (MPT 2011). Recent Advances in Processing of Non Ferrous and Industrial Minerals, PR 19 i 253, October 2022, 2011, Udaipur, India.

23. .., .., .. C - 5. European Science and Technology. Materials of the iii international research and Practice conference munich, Germany. October 30th31st, 2012, vol. 1, p. 75 -79.

24. Sulejmenov E.N., Utelbaeva A.B., Meldeshov A.A., romanteev y P , Utelbaev B t Kinetics of growth and weight of vanadium gel on short-circuited probes from a various material Journal of chemistry and chemical engineering, ISSN 1934-7375, USA, January 2013, Volume 7, No.1, p 13-17

25 suleimenov e n microstructure of electrolytes 11th spring meeting of the international society of electrochemistry Usa theoretical and computational electrochemistry, 21-23 May, 2012. p 104.

26 Kenzhaliev B K , Beisembaeva G Zh , Berkinbayeva a n , Utelbaev B t , Zakharova n a and suleimenov e n effects of electric current Parameters on metal solubility in Water solutions conference Proceedings Xii international Conference On Mineral Processing Technology (MPT 2011). recent advances in Processing of non Ferrous and industrial Minerals, HY 25 i 103, October 2022, 2011, Udaipur, India.

27 Kenzhaliev B K , suleimenov e n effects of electric current Parameters on metals solubility in inorganic Water solutions 11th spring meeting of the international society of electrochemistry Usa theoretical and computational Electrochemistry. 21-23 May, 2012, p. 105.


eXtractiOn OF iOns OF Zn and cd FrOm thiOcyanate sOLUtiOns

By meLts OF miXtUres OF diantiPiriLmethane

and BenZOic acid e alikina, candidate of chemistry, associate Professor

m degtev, doctor of chemistry, Full Professor, head of a chairPerm state University, russia

the extraction of ions of Zn and cd from acid thiocyanate solutions by melts of mixtures of diantipirilmethane and benzoic acid is studied Optimal conditions of delamination and formation of liquids as well as extractions of metal ions are determined the possibility of the quantitative extraction of ions of Zn and cd from thiocyanate solutions by diantipirilalcanes is presented the composition of extractable complex compounds is set and the mechanism of extraction is offered,

Keywords: extraction by melts, diantipirilmethane, thiocyanate solutions, benzoic acid

conference participants,National championship in scientific analytics

Zn Cd

.., . . ,

.., - . , ., . ,

- . , . - . - , .

: , -, , .

,

,

- [1-4]. . , , () , .. -. - , - . , - , - .

- . , , , ; , , -, , - . [5-9]. , - - . .

[10] - () . , -, 40 . : Sn(II) > Sn(IV) > Zn ( = 99,9 %, 1 / NH4SCN, 1 / 2sO4) > Co > Mo > W > Ga > Fe(III) > In > Hg(II) > Sc > V(IV) > Cd () = 60,0%, 1 / NH4SCN, 1 / 2sO4) > Mn(II) [11].

, - Zn Cd .

- Zn(II) Cd(II) - () -.

, [11]. - (0,1 /) - ZnSO47h2O 3CdSO48h2O . , - = 9 -00. - (2,0 /) - NH4SCN - . - .

-, Zn Cd - 80 10 , .

- (HCl, H2sO4 H3PO4), -- 2 / NH4scn

(10 ) , - .

() , , Zn Cd -. - .

- - . -


- , - , [11], -- . - .

80

NH4scn hX h2O - 0,01 8,0 /. V

:V

80-100

.

-, , , , - HCl H2sO4 (. 1).

0,8 1,4

. - , , . - . 20 100 .

H3PO4 , , -, HCl H2sO4

, - ( 1 , - ) : n

:n

= 1:1, n = 410-3 ,

[+] = 0,01 8,0 /, [SCN-] = 0,1 0,3 /, V

= 100 . -

Cd Zn , Cd , 90 % 0,1 0,6 / H2sO4. H3PO4 1,0 /, HCl 92 % 0,2 / (. 1).

1.

(n

:n

= 1:1, n = 0,004 , SCN = 0,25/)

, /

V ,

hcl h2sO4 h3PO40,01 0,5 1,1 0,8

0,1 1,0 1,1 0,9

0,25 1,1 1,2 1,0

0,5 1,2 1,2 0,9

1,0 1,2 1,3 0,9

2,0 1,2 1,2 0,9

4,0 1,2 1,2 0,9

. 1. NH

4SCN H . 1 HCl; 2 H

2SO

4; 3 H

3PO

4

(n

= n

= 0,002 , SCN = 0,25 /, Cd = 0,01 /, V = 20 )

chX, /0,0 0,2 0,4 0,6 0,8 1,0 1,2 1,4 1,6

ecd, %

60

70

80

90

100

1

2

3


98% 0,1 0,8 / H2sO4, 0,25 0,75 / H3PO4. HCl - 94% (0,1 / HCl). Zn Cd - (

[Zn(scn)4]

2 = 3,02;

[cd(scn)4]2 = 2,91) [12].

Zn Cd - , , .. HX H2O . , 12- -, - (> 97%) 20- . , [SCN] > 0,3 / , 70-80%, - - HSCN, - .

- . - :2+ SCN:2+, 2:1 4:1. , Cd Zn -

hX, /0,0 0,2 0,4 0,6 0,8 1,0 1,2

Zn, %

88

90

92

94

96

98

100

1

2

3

. 2. NH

4SCN :

1 HCl; 2 H2SO

4; 3 H

3PO

4 (n

= n

= 0,002 ,

SCN = 0,25 /, Zn = 0,01 /, V = 20 )

2.

(V

= 20 )

, n104 , n104

d Zn cd Zn

+

2+

scn-

8,010,04,040,0

10,010,05,030,0

7,77,83,815,1

10,210,05,019,8

()2[cd(scn)4] ()2[Zn(scn)4] - , - . . 2.

- , -, :

2Lhscno + n(Lh)OOcc6h5() + [me2+(scn)4]

2()

(Lh)2[me

2+(scn)4]n(Lh)OOcc6h5() + 2scn()

,

.. -, .

, , - , - , . - , , .

, - Cd Zn . - , - , . - - . - , - .

References:

1 Umland, F ber die Verteilung von metall-8-hydroxychinolinverbindungen zwischen Wasser und organischen Lsungsmitteln Vii mitteilung bersicht ber die ph-Bereiche der Verteilung der bekannten metall-oxinverbindungen zwischen Wasser und chloroform mit1 textabbildung / F Umland, K adam, h baden, G h Gudmundsson, r haar, W rachwitz, d schnemann, V shah, d thierig, R. Werrmann // Z. Analyt. Chem. 1962. B. 190. H.1. P. 186 202.


2 Umland, F ber additionsverbindungen des tris-(8-hydroxychinolinato)-chrom (iii) mit alkoholen, thern und aminen // F Umland, K adam // Zeitschrift fr anorganische und allgemeine Chemie. 1965. B.341. H.5-6. P. 308323.

3. Fujinaga, T. Analysis of metals by solid-liquid separation after liquid-liquid extraction spectrophotometric determination of palladium (ii) by extraction of palladium dimethylglyoximate with melted naphthalene / T. Fujinaga, H. Satake, T. Yonekubo // Talanta. 1972. V.19. 5. p. 689 692

4. , .. - : - . . . .7. ., 1980. 84 .

5. , .. - / .. , .. // . . -. 1985. .58. 10. . 21942199.

6. , .. - - / .. , .. , .. // . . . 1992. .65. 5. . 10001007.

7. , ..

, -2- / .. , .. , .. , .. // . . . 1998. .53. 3. . 287290.

8. , .. - - -2- // .. , .. , .. // . . . 1999. .44. 1. . 141143.

9. , .. - -2- / .. , .. , .. // . . . 2003. .48. 8. . 13811385.

10. , .. - / .. // . . . 1983. .38. 11. . 20512077.

11. , .. / .. , .. // -. : . -. 1974. 324. . 252269.

12. , .. / .. . 3- ., . .: , 1967. 390 .


deLaminatinG system antiPyrinUm sULFOsaLicyLic acid Water

and its aPPLicatiOn FOr eXtractiOn OF iOns OF indiUm (iii) and stannUm (ii, iV)

m i degtev, doctor of chemistry, Full Professor, head of a chairs i rogozhnikov, candidate of chemistry, associate Professor

O n Popova, Postgraduate studenta a yuminova, Postgraduate student

Perm state University, russia

Optimal conditions of the field delamination in the system antipyrinum sulfosalicylic acid water are found they depend on the base compounds concentrations, the medium acidity and the salting-out agent the received organic phase extracts macro-amounts of indium (iii) and stannum (ii, iV) effectively the composition and the extracted compounds mechanism are determined and the method of their selective extraction is suggested

Keywords: antipyrinum, sulfosalicylic acid, hydrochloric acid, degree of extraction, sodium sulfate

conference participants, national championship in scientific analytics

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, lgDin lgC() - - , :In(III): = 2:1:2. - [()2 In

3+2]+(2H)

References:

1. ., . - . .: , 1970. 360 .

2. .., .. () / - . . 1971. .26, .1. . 134-142.

(III)

: 0,6 /; 0,32 /

c.

, /10

In3+, %

(nh4)2sO4 K2sO4 ** na2sO4 **

0,10 79,0 82,1 83,3

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0,75 90,5 * 98,4

1,00 94,0 * 98,6* .** 333-343 5-7 .


mOdeLinG the hemOdynamics OF cOrOnary arteries taKinG their interactiOn With the myOcardiUm

intO accOUntO schuchkina, postgraduate student

I. Kirillova, andidate of Mathematical and Physical sciences, associate Professor

saratov state University named after n G chernyshevsky, russiaauthors have carried out a study of mechanical properties of

coronary arteries (ca), computer-based 3d modeling and numerical analysis of the stress-strain state (sss) and hemodynamics of the left and right coronary arteries the arterial wall material was assumed to be linear isotropic, and the blood - a Newtonian fluid. The data on the coronary arteries was analyzed taking into account their interaction with the myocardium

Keywords: ischemic heart disease, atherosclerosis, coronary arteries, finite-element modeling.


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References:

1 malek a m , alper s L , izumo s hemodynamic shear stress and its role in atherosclerosis // J am med assoc 282(21), 1999. P. 20352042.

2 cunningham, K s , Gotlieb, a i the role of shear stress in the pathogenesis of atherosclerosis // Lab invest 85 (1), 2005. P. 923.

3 Jung J , Lyczkowski r W , Panchal ch B , hassanein A. Multiphase hemodynamic simulation of pulsatile flow in a coronary artery // J. Biomech. 2006. Vol. 39, issue 11. P. 2064-2073.

4 Gotlieb a i atherosclerosis // cardiovascular Pathology 3rd ed / eds m d silver, a i Gotlieb, F J schoen N.Y.: Churchill livingstone, 2001. P. 68-106.

5 Kumar a computational model of Blood Flow in the Presence of atherosclerosis // 6th World congress of Biomechanics (WCB 2010). Singapore IFMBE Proceedings, 2010. Vol. 31, part 6. P. 1591-1594.

6. .., .., .. - . // ., 2005 . 384 .

. 11.

. 12.

. 13.

. 14.


eXPerimentaL stUdy OF sOLid-FLame cOmBUstiOn By the ni-aL system methOd OF hiGh-sPeed VideO FiLminG

L atyuckaya, studenta Bebiya, student

m Boronenko, postgraduate studentUgra state University, russia

authors present results of the experimental study of a wave of combustion in powder mixes of the nial system with the help of the of high-speed video filming method. Characteristic spatial-temporal scales of the thermal structure of the shs wave and temperature dynamics in a local point were determined on the basis of the received data

Keywords: self-extending high-temperature synthesis, thermogram, reaction cell, brightness pyrometry, temperature field.


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1 ( 1, ) ( , )( , )2

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1

1 ,

2;

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References:

1. .., .., .., .. - // - , 1994, . 30, 1, .72-77.

2. .., .., .., .. - // 2005. 1-. 313-320

3. .., .., .. - -

.// . 2003. 4. - . 3-6.

4. .., .., .., .., .. - NiAl. //// (, 24-27 2002.), . . 2002. -. 391-395.

5. .., .., .. - - // , 2003, 4, . 3-6.

6. .. . - -, , 2000. - 224 .

7. 2099674 . G01J 5/52. - / .. , .. , .. , .. , .. . 01.07.1996; . 20.12.1997, . 35. - 2 .

8. 2094787 . G01N 25/28, G01J 5/12. - - / .. , .. , .. -. 01.07.1996; . 16.01.1998, . 1. - 5 .

9 hwang s , mukasyan a s , rogachev a s , Varma a combustion wave microstructures in gas-solid system: experiments and theory // combustion sci technology, 1997 Vol 123 P 165-183

10. Hwang S., Mukasyan A.S., Varma A. Mechanisms of combustion wave propagation heterogeneous reaction systems // combustion Flame 1998 Vol 115 P 354 363

[ ]1 1( , ) ( , ) ( , )( , ) 2 2

1 1( , ) ( , ) ( , )2 2

1 ( 1, ) ( , )( , )2

( 1, ) ( , )

1 ( 1, ) ( , )( , )2

0

1

1 ,

2;

2( )

(

i j i j i ji jx x

i j i j i jy y


x x

i j i ji j

T T Tc k kt x x x

T Tk k Qy y y t

k kkk k

T T Tt d

k Ht

+

+

++

+

++

= + D + + D

=+

= =

0

) (1 ),

1const;

ign

r

T T H

kt

= =

[ ]1 1( , ) ( , ) ( , )( , ) 2 2

1 1( , ) ( , ) ( , )2 2

1 ( 1, ) ( , )( , )2

( 1, ) ( , )

1 ( 1, ) ( , )( , )2

0

1

1 ,

2;

2( )

(

i j i j i ji jx x

i j i j i jy y


x x

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k Ht

+

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certain PrOBLems OF Laser Gas dynamics

yu Khlopkov, doctor of mathematical and Physical sciences, Full Professor

V Zharov, candidate of mathematical and Physical sciences, associate Professor

m m Zay yar, candidate of mathematical and Physical sciences, doctoral candidate

moscow institute of Physics and technology, russiaUsually the science dealing with the problem of creating coherent

radiation is called quantum electronics studying the properties of laser radiation has opened new page in science - non-linear optics it seems that both of these disciplines are very far from the gas dynamics that has no relation to the creation and application of lasers the purpose of this paper to show that creation and use of lasers requires multiple solutions of gas dynamic problems which are the fundamental importance for the development of laser technology

Keywords: laser technology, laser in gas dynamics, quantum electronics, gas dynamics problems


.., - .-. , . .., . .-. , .., . .-. ,

- ,

, - , . . , , - . , , - , - .

: , , - , .

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21.372.531Udc 21 372 531

, , -. . , -, . , , - -, . - , . . - [1, 2]. , , , AVCO, NASA, ONERA, , , .

, : lASER = light Amplification by Stimulated Emission of Radiation. , (-) , , . 1918 . - - h, h . - . , , . c -, ,

. , - , , ( ) [3].

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m

nm nm

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=

=

= D =D

>

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v v v

nv nm m n

m

nm nm

m n

m n

dI k I dx

hv gk b N Nc g

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N Ng g

=

=

= D =D

>

,

,

( )( ) , ( ) ,

v v v

nv nm m n

m

nm nm

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dI k I dx

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=

=

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>

0


, ( )

, .. , , . , , . , - - .

: ; . - .

, , - , . - ( - ), , . .

, - , , , - Tdiff,

D , (, , ), l , c -, .

, V, D/V

, - , , , , (D/l)(V/c). 103 105. , - , , 50- 60- , , - -.

- , - - , .

, ( , , ) , - , - . , - .

References:

1. .. . .: , 1977.

2. Gerry .. Gasdynamic lasers IEEE Spectrum, 1970, November, .51-58.

3. Clark .. Design considerations for high power cavities - AIAA Paper, N 72-708, 1972.

4. Christiansen W.H., Russell D.A., Hertzberg . Flow lsrs - Ann. Rev. Fluid Mech. 1975, vol 7, . 115-139.

5. .. . . 3, - 2011.

,

,

( )( ) , ( ) ,

v v v

nv nm m n

m

nm nm

m n

m n

dI k I dx

hv gk b N Nc g

g vb v B v g v dvv

N Ng g

=

=

= D =D

>

2 2

diffD l DTl c lc

=


sPatiaL mULti-dimensiOnaLity OF the reaL WOrLda Kudryavtsev, associate Professor

higher school of social technologies, Latvia concept of multidimensional embedded space was introduced

three-dimensionality of physical world and ten-dimensionality of real Universe space was grounded Principles of organization of multidimensional space were formulated conditional-graphical schemes of components of multidimensional space were proposed higher reasons place and role in general scheme of multidimensional world was shown

Keywords: real world, unmanifested world, multidimensional space, space environment, space dimension, conditional-graphical scheme of space, principles of organization of space, divine world, higher reason, God

conference participant, national championship in scientific analytics

.., ,

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.

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[3] [4] [5] .

, , , - . . , -, (!), - [6].

, . - . - , , (. 3). , . - . - 96% .

- , , , , , , , , , . . - , -: , , , , .

, - . , - , .

, . -

() , - (, ).

, , , - [1], -?

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, . - 3- . , , 6- (. 3).

2. , . - 1580/2007 . [7].

3. - , , , . , , - - ?

, - .

, : , . , - , -. , , [8].

, - - . , : , -, . , . [9].

, () - : , , , -, , , - () - - , [10].

4. ( 2500 ) , , - , , , , - , , [2].

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.

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, 3- 4D- () 8 3D- ().

. 4, S4 S3. , - , , , , ( -) . , , - 4-. , -, , .

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4. , , - - -, (6- ) 4- , (5- ) .

5. - - [1] .

References:

1. . -? [ ] www.akotlin.com/index.php?sec=1&lnk=3_11

2. .. ? // Models and methods of solving formal and applied scientific issues in physico-mathematical, technical and chemical research: materials digest of the XXXii international Research and Practice Conference. london, September 20September 25, 2012.

3. .., .. - ? , 2002. [ ] http://n-t ru/tp/in/efv htm

4. .., .. -. . - : - - - 18-24 1988, I. , 1988, . 32-35.

5. .. . .: -, 1997. 450 .

6. ( ). .: : , - . - . / . : Vieda, 1995. 238 .

7 the dangers of creationism in education: resolution 1580 (4 October 2007). Adopted by the Parliamentary Assemly, Council of Europe (35th Sitting). [ ] http://assembly.coe.int/Main.asp?link=/Documents/AdoptedText/ta07/ERES1580.htm

8. .. , .. . : -: 1011 : . [ ] http://www.math.ru/dic/206

9. . . II. - . II. - . ., 1910. [ ] http://www philosophy ru/library/poincare/index htm

10. . . . .: - / . . . .: . , 1980. [ -] http://www.ega-math.narod.ru/Quant/Sawyer.htm


determinatiOn OF cOnditiOns OF FOrmatiOn OF stUdents GeneraL PhysicaL WOrLd

OUtLOOK in Order tO imPrOVe FUtUre PrOFessiOn

G mukhamedrakhimova1, candidate of Pedagogical sciencesK mukhamedrakhimov2, candidate of mathematical

and Physical sciencesKokshetau state University named

after sh sh Ualikhanov, Kazakhstan1L n Gumilyov eurasian national University, Kazakhstan2

certain aspects of conditions of formation of the students general physical world outlook of are considered in the article. Scientific novelty of the research is the consideration of the trend of the higher education level improvement up to modern stage of science and technology from the standpoint of unity of three subjects of the natural scientific cycle - physics, astronomy and ecology. it will also help to study the psychological level of students perception of elements of astronomy in integration with physics - moreover, on basis of ecologization

Keywords: education, ecologization system in education, ecological thinking, physical world outlook

conference participants, national championship in scientific analytics, Open European and Asian

research analytics championship

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determinatiOn OF eXPert QUaLity assessments

a Kryukov1, doctor of economic sciences, Full Professor, head of a chair

i Kriukova2, lecturersiberian Federal University, russia1

General secondary school 10, Krasnoyarsk, Russia2

For automatic processing of expertise results at assessment of the quality of work the algorithm of detection of the expert quality assessment on the basis of indexes of the assessment matrix lines was built methods of assessment of quality of products, works or services require the use of subjective marks of experts it is possible to use the grading system of quality indicators for the express-assessment of quality of production

Keyword: expertise results processing, quality assessment, algorithm, express-assessment, grading system

conference participants, national championship in scientific analytics, Open European and Asian

research analytics championship

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GISAP Championships and Conferences 2014

Branch of science Dates Stage Event name

AUGUSTPhysics, mathematics, chemistry, earth and space sciences 28.08-02.09 ii

Properties of matter in the focus of attention of modern theoretical doctrines

technical sciences, architecture and construction 28.08-02.09 ii

creation as the factor of evolutionary development and the societys aspiration to perfection

SEPTEMBER

Psychology and education 17.09-22.09 iii interpersonal mechanisms of knowledge and experience transfer in the process of public relations developmentOCTOBER

Philology, linguistics 02.10-07.10 iii Problems of combination of individualization and unification in language systems within modern communicative trendsculturology, art history, Philosophy and history 16.10-21.10 iii

cultural and historical heritage in the context of a modern outlook formationNOVEMBER

medicine, Pharmaceutics, Biology, Veterinary medicine, agriculture 05-11-10.11 iii

techniques of ensuring the duration and quality of biological life at the present stage of the humanity development

economics, management, Law, sociology, Political and military sciences

20.11-25.11 iii Influence of the social processes globalization factor on the economical and legal development of states and corporations

DECEMBERPhysics, mathematics, chemistry, earth and space sciences 04.12-09.12 iii

Variety of interaction forms of material objects through a prism of the latest analytical concepts

technical sciences, architecture and construction 18 12-23 12 iii

Target and procedural aspects of scientific and technical progress at the beginning of the XXi century

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2014