Imagination at work

GE CCUS Technologies CMC CO2lloquium, Calgary November 27th, 2015

GE Proprietary Information

Development Driver

© 2015, General Electric Company and/or its affiliates. GE Proprietary Information. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. No reproduction, use or disclosure to third parties, without prior written permission.

44 GtCO2

2035 450 ppm (+2°C)

37 GtCO2

Power generation : Largest contributor and easiest to address

Who is currently emitting CO2?

Global CO2 emissions (Gt per year)

30 GtCO2

Source: © OECD/IEA – World Energy Outlook 2012

22 GtCO2

Power generation

All other sectors

2010

Power generation

Industry

Transport Others

2035 BAU (6°C)

2035 Current

Policies (4°C) Source: data from © OECD/IEA – CO2 emissions

from fossil combustion 2012

CMC CO2lloquium | 27th Nov 2015 3

© 2015, General Electric Company and/or its affiliates. GE Proprietary Information. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. No reproduction, use or disclosure to third parties, without prior written permission.

Main Industrial Sources of CO2 Emissions

Direct industrial CO2 emission projections in the ETP Baseline

Scenario

Industrial CO2 emissions contribute relevantly, too. Yet, they can be only mitigated by Carbon Capture Technology!

CMC CO2lloquium | 27th Nov 2015 4

Approach

© 2015, General Electric Company and/or its affiliates. GE Proprietary Information. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. No reproduction, use or disclosure to third parties, without prior written permission.

Efficiency: Plant optimisation & retrofit

Wind, solar & geothermal

N° 1 nuclear*

& biomass

Emissions CO2 (Gt/y)

2005 Ref 2030 1000 ppm

+6oC

Stabilize emissions 550 ppm

+30C

Needed path

450ppm +20C max

Technology Mix

Efficiency

CCS

N° 1 hydro

* Conventional islands

Carbon Capture & Utilization or Storage

Clean Power strategy

CMC CO2lloquium | 27th Nov 2015 6

© 2015, General Electric Company and/or its affiliates. GE Proprietary Information. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. No reproduction, use or disclosure to third parties, without prior written permission.

Underground permanent

Storage

Carbonates

Fuels

Urea

Food industry

Industrial flue gas with CO2:

• Power • Steel mill • Cement factory • Refinery • Methanol plant, • Ethanol plant • Fertilizer plant • etc

“Classic” CCS (Saline Aquifers or depleted Oil & Gas fields)

CCU Chemical usage

Current prospects in Fertilizer and carbonates

CO2-EOR CO2-EOR : high potential in USA

Carbon Capture & Utilization (CCU) A bridge towards large scale roll-out of CCUS

CO2 capture

unit

CMC CO2lloquium | 27th Nov 2015 7

© 2015, General Electric Company and/or its affiliates. GE Proprietary Information. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. No reproduction, use or disclosure to third parties, without prior written permission.

CCS Technologies developed by GE

GE’s activities address Installed Base, New Built and Industrial

Post-combustion Oxy-combustion (New + retrofit) (New + retrofit)

• Advanced Amines Process • Chilled Ammonia Process • Amino Silicone Process

• Oxy-combustion with ASU

• Regenerative Calcium Cycle (RCC) • Chemical Looping Combustion (CLC)

2nd Generation Post combustion: 2nd Generation OxyCombustion:

CMC CO2lloquium | 27th Nov 2015 8

Post Combustion

© 2015, General Electric Company and/or its affiliates. GE Proprietary Information. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. No reproduction, use or disclosure to third parties, without prior written permission.

CAP- Chilled Ammonia Process

TECHNOLOGY PRINCIPLE • At low temperature, flue gas is contacted with an aqueous ammoniated

carbonate solution to absorb carbon dioxide

• Raising the temperatures reverses the reaction – releasing pressurized CO2

ADVANTAGES • Energy-efficient capture of CO2 . • High CO2 purity, high CO2 pressure. • Tolerant to oxygen and other flue gas

impurities like SOx. • Stable reagent (no degradation). • No emission of harmful trace contaminants. • Low-cost and globally available reagent. • Value by-product (fertilizer). • Variable Regenerator pressure: 7 to 21 bara

• Low CO2 compression power demand

CMC CO2lloquium | 27th Nov 2015 10

© 2015, General Electric Company and/or its affiliates. GE Proprietary Information. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. No reproduction, use or disclosure to third parties, without prior written permission.

AAP - Advanced Amine Process

TECHNOLOGY PRINCIPLE • An amine based solvent reacts with the CO2 in the flue gas

• Raising the temperature reverses this reaction, the CO2 is released and the solvent recycled

ADVANTAGES • Proven in natural gas & syngas purification

• More efficient capture of CO2 and less

solvent degradation than MEA

• Higher tolerance against oxygen &

trace contaminants

MARKET INTRODUCTION • Ready for small-scale and CCU full

commercial offering

• Ready for large-scale demonstration projects

CMC CO2lloquium | 27th Nov 2015 11

© 2015, General Electric Company and/or its affiliates. GE Proprietary Information. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. No reproduction, use or disclosure to third parties, without prior written permission.

RCC- Regenerative Calcium Cycle

ADVANTAGES • RCC increases the total

power production, adding capacity

• High potential for lower net cycle efficiency penalty

• Ideal fit to the cement industry (and good potential in other industries)

• Spent limestone can be reused

TECHNOLOGY PRINCIPLE • Lime reacts with the CO2 in the flue gas to form Limestone while producing heat

• Raising temperature reverses reaction, CO2 is released and sorbent recycled

• Indirect heat transfer boosts Plant efficiency and CO2 quality

CMC CO2lloquium | 27th Nov 2015 12

Oxy Combustion

© 2015, General Electric Company and/or its affiliates. GE Proprietary Information. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. No reproduction, use or disclosure to third parties, without prior written permission.

DCC Direct Contact Cooler

GPU Gas Processing Unit

FGD Desulfurization

ESP/FF Dust Elimination

ASU Air Separation Unit

Oxy-Combustion Process

TECHNOLOGY PRINCIPLE • Fuel is burned in a mixture of Oxygen and re-circulated flue-gas.

• Due to absence of Nitrogen, flue gas is enriched in CO2 and H2O

• After H2O condensing and purification, CO2 is compressed and send to storage

ADVANTAGES • Reliability

• Adaptable to all boiler types and fuels

• Rapid scale-up to >1,000 MWel range

• Retrofit in Oxy can be addressed

• Higher efficiency with supercritical/ultra-supercritical cycles

CMC CO2lloquium | 27th Nov 2015 14

© 2015, General Electric Company and/or its affiliates. GE Proprietary Information. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. No reproduction, use or disclosure to third parties, without prior written permission.

CLC - Chemical Looping Combustion TECHNOLOGY PRINCIPLE • Oxygen Carrier picks up oxygen in Air Reactor and brings oxygen to the

Fuel Reactor for Combustion • Oxygen Carrier regenerated in Air Reactor

ADVANTAGES • Eliminates need for energy

intensive ASU • Heat generated to produce

steam for electricity • Concentrated CO2 leaves Fuel

Reactor for utilization and storage (CCUS) 6 90% Capture

CMC CO2lloquium | 27th Nov 2015 15

Summary

© 2015, General Electric Company and/or its affiliates. GE Proprietary Information. All rights reserved. Information contained in this document is indicative only. No representation or warranty is given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical and commercial circumstances. It is provided without liability and is subject to change without notice. No reproduction, use or disclosure to third parties, without prior written permission.

We are a recognized leader in CCUS Technologies for a promising market after 2020

CCUS development conclusion

– CCUS is the sole solution to address CO2 emissions from industries

– Recognized leader on CCUS technology based on last 10 years development including 13 pilots and validation plants

– Proven and robust technologies capable to serve power and industry

– 2nd gen technologies promise to be breakthrough technologies in terms of energy penalty and CoE

– R&D focused on closing technology gaps, supporting new large demo-plants and develop 2nd generation to maintain a leading role in CCUS Technologies

CMC CO2lloquium | 27th Nov 2015 17