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DANH SÁCH CÁC CHẤT BỊ HẠN CHẾ Tháng 12 năm 2015 | Phiên bản 01 Apparel and Footwear International RSL Management Group (Tập đoàn Quản lý RSL Quốc tế trong Giày dép và May mặc hay AFIRM)

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  • DANH SCH CC CHT B HN CHThng 12 nm 2015 | Phin bn 01

    Apparel and Footwear International RSL Management Group (Tp on Qun l RSL Quc t trong Giy dp v May mc hay AFIRM)

  • 2

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    Mc lc

    S mnh ca AFIRM ..................................................3Tm nhn ca AFIRM ..................................................3Tuyn b Chnh sch .................................................3

    Tuyn b Php l ........................................................4

    Lin kt v Ti liu tham kho...................................5

    nh ngha v Tui tc ...............................................6

    Danh sch cc Cht b Hn ch ca AFIRM .............7

    Ph lc A: Thuc tr su, Nng nghip .................21

  • 3

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    S mnh ca AFIRMAFIRM l Apparel and Footwear International RSL Management (AFIRM) Working Group, c thnh lp vo nm 2004. S mnh ca AFIRM l "gim thiu vic s dng v nh hng ca cc cht c hi trong chui cung ng may mc v giy dp." Mc ch ca AFIRM l cung cp mt din n thc y vic qun l cc cht b hn ch trn ton cu trong may mc v giy dp, truyn t thng tin v qun l ha cht n chui cung ng, tho lun v cc mi quan ngi, v trao i kin ci thin vic qun l ha cht.

    Tm nhn ca AFIRMAFIRM tip tc l mt trung tm xut sc ton cu c cng nhn, cung cp cc ngun lc cho php lin tc thc y cc thc tin qun l ha cht tt nht. Chng ti thc hin iu ny da trn tnh minh bch, khoa hc, v phi hp vi cc ngnh v cc chuyn gia c lin quan xy dng ha hc an ton hn v bn vng hn trong chui cung ng may mc v giy dp. iu ny c hiu rng trong vic p dng tm nhn ny, s mnh, cc mc tiu v d n ca AFIRM s tip tc tp trung vo sn phm hoc lin quan n RSL.

    Tuyn b Chnh sch v cc cch S dng RSL NyAFIRM to ra Danh sch cc Cht b Hn ch sau y gip v hng dn nhng ngi tham gia chui cung ng tm cch tng cng cht lng v s an ton ca sn phm hoc gim tc ng mi trng ca chng bng cch hn ch s dng cc cht nht nh (RSL ca AFIRM). Cc thng hiu thnh vin AFIRM c th khc nhau v thng s c nhn; nh cung cp nn kim tra vi khch hng v cc yu cu thng hiu c th. RSL ca AFIRM nn thc y s mnh ca AFIRM "gim thiu vic s dng v nh hng ca cc cht c hi trong chui cung ng may mc v giy dp" bng cch cung cp mt tp hp thng tin duy nht ti u v thc hin theo chiu su trong chui cung ng.

    Mt s v d v cc cch s dng i vi RSL ca AFIRM, ty thuc vo cc mc tiu ca ngi s dng, bao gm:

    Cung cp mt cng c cho cc nh cung cp thit lp kin thc v cc qu trnh qun l ha cht.

    Xy dng c s tun th cc hn ch ha cht ca thnh vin AFIRM.

    Cung cp mt c s chung cho cc sn phm th nghim, trong c th c nhiu thng hiu AFIRM chp nhn.

    Cc cng ty thnh vin AFIRM xc nh v trao i vi cc nh cung cp ca h v cc yu cu th nghim ca h v nghim thu cc bo co th nghim.

    bit thm thng tin v AFIRM, hy truy cp www.afirm-group.com.

  • 4

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    Tuyn b Php l RSL ca AFIRM ch cu thnh thng tin t AFIRM v khng i din cho bt k thnh vin AFIRM c nhn. RSL thng hiu c nhn c th khc nhau cc thng s c th.

    RSL ca AFIRM khng c nh v khng thit lp bt k tiu chun chm sc ca ngnh. RSL ca AFIRM khng th lun cung cp cch tip cn ph hp nht cho bt k chng trnh qun l ha cht ca tng cng ty. Nhiu thng hiu c hng dn thc hin, v cc nh cung cp phi tun theo cc hng dn nu bt buc. RSL ca AFIRM khng cu thnh t vn php l v khng thay th cho t vn php l. Khng c bo m, r rng hay ng , v s hon thin hoc tin ch ca thng tin cha trong RSL ca AFIRM ny, bao gm, nhng khng gii hn, vic thng tin l hin hnh v khng b li. AFIRM t chi trch nhim php l di bt k hnh thc pht sinh t bt k vic s dng hoc tin tng vo RSL ca AFIRM.

  • 5

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    Lin kt v Ti liu tham kho Hy ch ng! Cc lin kt ny c th cung cp thng tin quan trng b sung v nn truy cp thng xuyn.

    nh ngha v vt liu v cc thng s th nghim c lin quan www.afirm-group.com/wp-content/uploads/2013/04/AFIRMSupplierToolkit.pdf

    B dng c Nh cung cp AFIRM www.afirm-group.com/toolkit/

    C sn cc bn dch ting Trung, ting Vit v ting Ty Ban Nha.

    Cc cht b hn ch b sung cng mc ph hp c th c http://echa.europa.eu

    Danh sch cc cht ng vin c mi lo ngi rt cao (SVHC) http://echa.europa.eu/de/candidate-list-table

    Tng quan v cc gii hn php l ca ha cht v nc xut x https://www.wewear.org/industry-resources/restricted-substances-list/

    Cc hp cht hu c d bay hi (VOCs) c quy nh, ch yu l EC 842/2006 http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2006:161:0001:0011:EN:PDF

    VOCs c quy nh, EC 1005/2009 http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2009:286:0001:0030:EN:PDF

  • 6

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    Tui

    Em b 0 n 36 thng

    Tr em 36 thng n 14 tui

    Ngi ln T 14 tui tr ln

    nh ngha v Tui tcCc quc gia khc nhau nh ngha cc thut ng "em b", "tr em", v "ngi ln" khc nhau. Cn c vo php lut, tui c lit k trong Bng 2 p ng cc yu cu ton cu hn ch nht.

    Bng 2 nh ngha v Tui tc

  • 7

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    c s dng rng ri trong lch s; mc xut hin cao

    Mc xut hin trung bnh Nguy c tht bi thp* 21 3

    CAS s Cht T l Xut hin*

    Gii hn Nguyn liu Th &Thnh phm

    Tim nng S dngGia cng Dt cho Trang phc & Giy dp

    Phng php Th nghim Ph hpChun b Mu v o lng

    Acetophenone v 2-Phenyl-2-Propanol

    98-86-2 Acetophenone 250 phn triu mi loi

    Sn phm phn hy tim nng trong bt EVA khi s dng dicumyl peroxide lm cht to xp.

    Tch chit trong methanol GC/MS617-94-7 2-Phenyl-2-propanol 2

    Alkylphenol (AP) v Alkylphenol Ethoxylates (APEOs), bao gm tt c cc ng phn

    104-40-5

    Nonylphenol (NP), cc ng phn hn hp

    1

    Tng: 100 phn triu

    APEO c th c s dng lm hoc c tm thy trong cht ty ra, cht ty, du quay, cht thm t, cht lm mm, cht nh ha/phn tn dng cho thuc nhum v in n, cht tm, kh keo sn xut t, thuc nhum v cc ch phm bt mu, m lt polyester v cht n y lng v (lng nhung/lng mnh).APEO v cc cng thc c cha APEO u b cm s dng trong sut chui cung ng v quy trnh sn xut. Chng ti tha nhn rng nng d hoc nh APEO vn c th c tm thy cc mc vt qu 100 phn triu v cn c nhiu thi gian hn chui cung ng loi b chng hon ton. Gii hn ny phn nh lut php EU d kin v c thit lp cung cp cho cc nh cung cp cc cnh bo trc v nh hng ci tin lin tc.

    Dt may: EN ISO 18254:2014Da: EN ISO 18218-1:2015

    11066-49-2 1

    25154-52-3 1

    84852-15-3 1

    140-66-9

    Octylphenol (OP), cc ng phn hn hp

    1

    1806-26-4 1

    27193-28-8 1

    9002-93-1

    Octylphenol ethoxylates (OPEOs)

    1

    Tng: 100 phn triu

    9036-19-5 1

    68987-90-6 1

    9016-45-9

    Nonylphenol ethoxylates (NPEOs)

    1

    26027-38-3 1

    37205-87-1 1

    68412-54-4 1

    127087-87-0 1

    Danh sch cc Cht b Hn ch ca AFIRM

  • 8

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    c s dng rng ri trong lch s; mc xut hin cao

    Mc xut hin trung bnh Nguy c tht bi thp* 21 3

    CAS s Cht T l Xut hin*

    Gii hn Nguyn liu Th &Thnh phm

    Tim nng S dngGia cng Dt cho Trang phc & Giy dp

    Phng php Th nghim Ph hpChun b Mu v o lng

    Azo-amines

    92-67-1 4-Aminobiphenyl 1

    20 phn triu mi loi

    Thuc nhum v bt mu Azo l cc cht to mu kt hp mt hoc nhiu nhm azo (-N=N-) gn vi cc hp cht thm. Hng nghn thuc nhum azo tn ti, nhng ch nhng loi phn hy hnh thnh cc amine c th phn ra lit k mi b hn ch. Thuc nhum azo gii phng cc amine ny c quy nh v khng cn c s dng nhum vi dt.

    Dt may: (EU): EN 14362-1:2015Da: (EU): CEN ISO/TS 17234-1:2015

    p-Aminoazobenzene: Dt may: EN 14362-3:2015Da: 17234-2:2011

    92-87-5 Benzidine 1

    95-69-2 4-Chloro-o-toluidine 1

    91-59-8 2-Naphthylamine 1

    97-56-3 o-Aminoazotoluene 1

    99-55-8 2-Amino-4-nitrotoluene 1

    106-47-8 p-Chloraniline 1

    615-05-4 2,4-Diaminoanisole 1

    101-77-9 4,4-Diaminodiphenylmethane 1

    91-94-1 3,3-Dichlorobenzidine 1

    119-90-4 3,3-Dimethoxybenzidine 1

    119-93-7 3,3-Dimethylbenzidine 1

    838-88-0 3,3-dimethyl-4,4-diaminodiphenylmethane 1

    120-71-8 p-Cresidine 1

    101-14-4 4,4-Methylen-bis(2-chloraniline) 1

    101-80-4 4,4-Oxydianiline 1

    139-65-1 4,4-Thiodianiline 1

    95-53-4 o-Toluidine 1

    95-80-7 2,4-Toluylendiamine 1

    137-17-7 2,4,5-Trimethylaniline 1

    95-68-1 2,4 Xylidine 1

    87-62-7 2,6 Xylidine 1

    90-04-0 2-Methoxyaniline (= o-Anisidine) 1

    60-09-3 p-Aminoazobenzene 1

  • 9

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    c s dng rng ri trong lch s; mc xut hin cao

    Mc xut hin trung bnh Nguy c tht bi thp* 21 3

    CAS s Cht T l Xut hin*

    Gii hn Nguyn liu Th &Thnh phm

    Tim nng S dngGia cng Dt cho Trang phc & Giy dp

    Phng php Th nghim Ph hpChun b Mu v o lng

    Bisphenol-A

    80-05-7 Bisphenol-A (BPA) 3 1 phn triu

    c s dng trong sn xut nha epoxy, nha polycarbonate, cht chng chy v PVC.

    B cm s dng trong cc hp ng thc phm v ung, v cc mt hng c nh tip xc vi khoang ming.

    Chun b mu: Tch chit vi methanol o lng: DIN EN ISO 18857-2 (mod)

    Paraffin Clo ho

    85535-84-8 Paraffin clo ho chui ngn (Short-chain chlorinated Paraffins hay SCCP) (C10-C13) 2 1000 phn triu C th c s dng lm cht chng chy hoc cht lng bo trong sn xut da. Chng cng c th c s dng lm cht lm do.

    ISO 18219:201585535-84-9 Paraffin clo ho chui trung bnh (Medium-chain chlorinated Paraffins hay MCCP) (C14-C17) 2 1000 phn triu

    Chlorophenol

    15950-66-0 2,3,4-Trichlorophenol 3

    0,5 phn triu mi loi

    Chlorophenol l cc hp cht polychlorinated c s dng lm cht bo qun hoc thuc tr su. Pentachlorophenol (PCP) v tetrachlorophenol (TeCP) i khi c s dng chng nm mc v dit cn trng khi trng bng v khi lu tr/vn chuyn vi. PCP v TeCP cng c th c s dng lm cht bo qun trong bt nho in n.

    Tch chit KOH, 15 gi 90 C 64 LFGB B 82.02-08 hoc DIN EN ISO 17070:2015

    933-78-8 2,3,5-Trichlorophenol 3

    933-75-5 2,3,6-Trichlorophenol 3

    95-95-4 2,4,5-Trichlorophenol 3

    88-06-2 2,4,6-Trichlorophenol 3

    609-19-8 3,4,5-Trichlorophenol 3

    4901-51-3 2,3,4,5-Tetrachlorophenol (TeCP) 3

    58-90-2 2,3,4,6-Tetrachlorophenol (TeCP) 3

    935-95-5 2,3,5,6-Tetrachlorophenol (TeCP) 3

    87-86-5 Pentachlorophenol (PCP) 3

  • 10

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    c s dng rng ri trong lch s; mc xut hin cao

    Mc xut hin trung bnh Nguy c tht bi thp* 21 3

    CAS s Cht T l Xut hin*

    Gii hn Nguyn liu Th &Thnh phm

    Tim nng S dngGia cng Dt cho Trang phc & Giy dp

    Phng php Th nghim Ph hpChun b Mu v o lng

    Cht mang Clo hu c

    95-49-8 2-Chlorotoluene 3

    Tng: 1 phn triu

    Chlorobenzenes v chlorotoluenes (Hydrocacbon thm c clo ha) c th c s dng lm cht mang trong qu trnh nhum polyester hoc si len/polyester. Chng cng c th c s dng lm dung mi.

    DIN 54232:2010

    108-41-8 3-Chlorotoluene 3

    106-43-4 4-Chlorotoluene 3

    32768-54-0 2,3-Dichlorotoluene 3

    95-73-8 2,4-Dichlorotoluene 3

    19398-61-9 2,5-Dichlorotoluene 3

    118-69-4 2,6-Dichlorotoluene 3

    95-75-0 3,4-Dichlorotoluene 3

    2077-46-5 2,3,6-Trichlorotoluene 3

    6639-30-1 2,4,5-Trichlorotoluene 3

    76057-12-0 2,3,4,5-Tetrachlorotoluene 3

    875-40-1 2,3,5,6-Tetrachlorotoluene 3

    877-11-2 Pentachlorotoluene 3

    541-73-1 1,3-Dichlorobenzene 3

    106-46-7 1,4-Dichlorobenzene 3

    87-61-6 1,2,3-Trichlorobenzene 3

    120-82-1 1,2,4-Trichlorobenzene 3

    108-70-3 1,3,5-Trichlorobenzene 3

    634-66-2 1,2,3,4-Tetrachlorobenzene 3

    634-90-2 1,2,3,5-Tetrachlorobenzene 3

    95-94-3 1,2,4,5-Tetrachlorobenzene 3

    608-93-5 Pentachlorobenzene 3

    118-74-1 Hexachlorobenzene 3

    95-50-1 1,2-Dichlorobenzene 3 10 phn triu

  • 11

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    c s dng rng ri trong lch s; mc xut hin cao

    Mc xut hin trung bnh Nguy c tht bi thp* 21 3

    CAS s Cht T l Xut hin*

    Gii hn Nguyn liu Th &Thnh phm

    Tim nng S dngGia cng Dt cho Trang phc & Giy dp

    Phng php Th nghim Ph hpChun b Mu v o lng

    Dimethylformamide

    68-12-2 Dimethylformamide (DMFa) 2 500 phn triu

    DMFa l mt dung mi c s dng trong nha, cao su, v cht ph polyurethane (PU). DMFa c mi mnh trong thnh phm. PU da trn nc khng cha DMFa v do l mt li th.

    DIN CEN ISO/TS 16189:2013

    Dimethylfumarate

    624-49-7 Dimethylfumarate (DMFu) 2 0,1 phn triu

    DMFu l mt cht chng nm mc c s dng trong cc ti trong ng gi ngn s tch t nm mc, c bit l trong qu trnh vn chuyn.

    ISO/TS 16186:2012

  • 12

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    c s dng rng ri trong lch s; mc xut hin cao

    Mc xut hin trung bnh Nguy c tht bi thp* 21 3

    CAS s Cht T l Xut hin*

    Gii hn Nguyn liu Th &Thnh phm

    Tim nng S dngGia cng Dt cho Trang phc & Giy dp

    Phng php Th nghim Ph hpChun b Mu v o lng

    Thuc nhum, B cm v Phn tn

    2475-45-8 C.I. Xanh da tri Phn tn 1 2

    75 phn triu mi loi

    Thuc nhum phn tn l mt loi thuc nhum khng tan trong nc xm nhp vo h thng si ca cc si tng hp hoc c ch to v c gi li bi cc lc lng vt l m khng hnh thnh lin kt ha hc. Thuc nhum phn tn c s dng trong si tng hp (chng hn nh olyester, acetate, polyamide). Thuc nhum phn tn b hn ch b nghi ng gy phn ng d ng v b cm s dng nhum vi dt.

    DIN 54231:2005

    2475-46-9 C.I. Xanh da tri Phn tn 3 2

    3179-90-6 C.I. Xanh da tri Phn tn 7 2

    3860-63-7 C.I. Xanh da tri Phn tn 26 2

    12222-75-2 C.I. Xanh da tri Phn tn 35 2

    69766-76-6 C.I. Xanh da tri Phn tn 102 2

    12223-01-7 C.I. Xanh da tri Phn tn 106 2

    61951-51-7 C.I. Xanh da tri Phn tn 124 2

    23355-64-8 C.I. Nu Phn tn 1 2

    2581-69-3 C.I. Cam Phn tn 1 2

    730-40-5 C.I. Cam Phn tn 3 2

    82-28-0 C.I. Cam Phn tn 11 2

    12223-33-5

    C.I. Cam Phn tn 37/76/59

    2

    13301-61-6 2

    51811-42-8 2

    85136-74-9 C.I. Cam Phn tn 149 2

    2872-52-8 C.I. Phn tn 1 2

    2872-48-2 C.I. Phn tn 11 2

    3179-89-3 C.I. Phn tn 17 2

    61968-47-6 C.I. Phn tn 151 2

    119-15-3 C.I. Vng Phn tn 1 2

    2832-40-8 C.I. Vng Phn tn 3 2

    6300-37-4 C.I. Vng Phn tn 7 2

    6373-73-5 C.I. Vng Phn tn 9 2

    6250-23-3 C.I. Vng Phn tn 23 2

    12236-29-2 C.I. Vng Phn tn 39 2

    54824-37-2 C.I. Vng Phn tn 49 2

  • 13

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    c s dng rng ri trong lch s; mc xut hin cao

    Mc xut hin trung bnh Nguy c tht bi thp* 21 3

    CAS s Cht T l Xut hin*

    Gii hn Nguyn liu Th &Thnh phm

    Tim nng S dngGia cng Dt cho Trang phc & Giy dp

    Phng php Th nghim Ph hpChun b Mu v o lng

    Thuc nhum, B cm v Phn tn, tip theo

    54077-16-6 C.I. Vng Phn tn 56 2

    75 phn triu mi loi

    Thuc nhum phn tn l mt loi thuc nhum khng tan trong nc xm nhp vo h thng si ca cc si tng hp hoc c ch to v c gi li bi cc lc lng vt l m khng hnh thnh lin kt ha hc. Thuc nhum phn tn c s dng trong si tng hp (chng hn nh olyester, acetate, polyamide). Thuc nhum phn tn b hn ch b nghi ng gy phn ng d ng v b cm s dng nhum vi dt.

    DIN 54231:2005

    3761-53-3 C.I. Axit 26 2

    569-61-9 C.I. C bn 9 2

    569-64-2

    C.I. Xanh l cy C bn 4

    2

    2437-29-8 2

    10309-95-2 2

    548-62-9 C.I. Tm C bn 3 2

    632-99-5 C.I. Tm C bn 14 2

    2580-56-5 C.I. Xanh da tri C bn 26 2

    1937-37-7 C.I. en trc tip 38 2

    2602-46-2 C.I. Xanh da tri Trc tip 6 2

    573-58-0 C.I. Trc tip 28 2

    16071-86-6 C.I. Nu Trc tip 95 2

    60-11-7 4-Dimethylaminoazobenzene (Vng Dung mi 2) 2

    6786-83-0 C.I. Xanh da tri Dung mi 4 2

    561-41-1 Cn 4,4'-bis(dimethylamino)-4''-(methylamino)trityl 2

    Thuc nhum, Xanh Hi qun

    118685-33-9 Thnh phn 1: C39H23ClCrN7O12S.2Na 375 phn triu mi loi

    Thuc nhum mu xanh hi qun c quy nh v b cm s dng nhum vi dt. (Ch mc 611-070-00-2)

    DIN 54231:2005Khng c phn b Thnh phn 2: C46H30CrN10O20S2

    .3Na 3

  • 14

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    c s dng rng ri trong lch s; mc xut hin cao

    Mc xut hin trung bnh Nguy c tht bi thp* 21 3

    CAS s Cht T l Xut hin*

    Gii hn Nguyn liu Th &Thnh phm

    Tim nng S dngGia cng Dt cho Trang phc & Giy dp

    Phng php Th nghim Ph hpChun b Mu v o lng

    Cht chng chy

    126-72-7 Tris(2,3,-dibromopropyl) phosphate (TRIS) 3

    Tng: 5 phn triu

    Cc ha cht chng chy t c s dng p ng yu cu v tnh d chy qun o tr em v cc sn phm dnh cho ngi ln. Cc ha cht ny khng cn c s dng trong may mc v giy dp.

    Tch chit methanol, GC/MS

    545-55-1 Tris(1-aziridinyl)phosphine oxide) (TEPA) 3 LC-MS

    32534-81-9 Pentabromodiphenyl ether (PentaBDE) 3

    Tch chit acetonitril, LC-DAD-MS, v xc nhn vi GC/MS

    32536-52-0 Octabromodiphenyl ether (OctaBDE) 3

    1163-19-5 Decabromodiphenyl ether (DecaBDE) 3

    79-94-7 Tetrabromobisphenol A (TBBP A) 3

    115-96-8 Tris(2-chloroethyl)phosphate (TCEP) 3

    Tch chit methanol, GC/MS

    59536-65-1 Polybromobiphenyls (PBB) 3

    5412-25-9 Bis(2,3-dibromopropyl) phosphate (BIS) 3

    3194-55-6 Hexabromocyclododecane (HBCDD) 3

    3296-90-0 2,2-bis(bromomethyl)-1,3-propanediol (BBMP) 3

    13674-87-8 Tris(1,3-dichloro-isopropyl) phosphate (TDCPP) 3

    25155-23-1 Trixylyl phosphate (TXP) 3

    Kh Nh knh cha Flo

    Khc Xem Quy nh (EC) s 842/2006 c danh sch y . 2 0,1 phn triu mi loi

    Chun b mu: Cht hp th kh (purge and trap) gii hp nhit hay SPMEo lng: GC/MS

    Formaldehyde

    50-00-0 Formaldehyde 1Ngi ln v tr em: 75 phn triuEm b: 16 phn triu

    c s dng trong dt may di dng mt cht chng nhn v chng co. Cng thng c s dng trong nha polymer.

    Dt may: JIS L 1041-1983 A (Lut Nht Bn 112) hay EN ISO 14184-1:2011Da: ISO 17226-1:2008

  • 15

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    c s dng rng ri trong lch s; mc xut hin cao

    Mc xut hin trung bnh Nguy c tht bi thp* 21 3

    CAS s Cht T l Xut hin*

    Gii hn Nguyn liu Th &Thnh phm

    Tim nng S dngGia cng Dt cho Trang phc & Giy dp

    Phng php Th nghim Ph hpChun b Mu v o lng

    Kim loi Nng

    7440-36-0 Antimon (Sb) 3 C th tch chit: 30 phn triu

    c tm thy trong hoc c s dng lm cht xc tc trong polyme ha polyester, cht chng chy, thuc hm, bt mu v hp kim.

    Chun b mu: EN ISO 105-E04:2013 o lng: EN ISO 17294-2:2014

    7440-38-2 Asen (As) 3C th tch chit: 0,2 phn triuTng: 100 phn triu cho tt c cc vt liu tr nha

    Asen v cc hp cht ca Asen c th c s dng trong cc cht bo qun, thuc tr su v cht dit c s dng cho bng, si tng hp, sn, mc, trang tr v nha.

    Chun b mu: C th tch chit: Dt may: EN ISO 105-E04:2013 Da: DIN EN ISO 17072-1:2014 Tng: Ph mu bng vi sng vi H2O2/HNO3 o lng: EN ISO 17294-2 :2014

    7440-43-9 Cadimi (Cd) 3

    C th tch chit: 0,1 phn triuTng: Ngi ln: 75 phn triu Tr em v em b: 40 phn triu

    Hp cht cadimi c s dng lm bt mu (c bit l mu , mu cam, mu vng v mu xanh l cy); lm cht n nh cho PVC; v trong phn bn, cht dit khun v cc loi sn.Bn cp nht tip theo s gim tng gii hn xung 40 phn triu i vi tt c cc cht.

    Chun b mu: C th tch chit: Dt may: EN ISO 105-E04:2013 Da: DIN EN ISO 17072-1:2014 Tng: Ph mu bng vi sng vi H2O2/HNO3 o lng: EN ISO 17294-2:2014

    7440-47-3 Crom (Cr) 3

    C th tch chit cho hng dt may: 1 phn triuGiy dp da cho em b: 60 phn triu

    Hp cht crom c th c s dng lm cht ph gia nhum, cht c nh thuc nhum, bn mu sau khi x l, thuc nhum cho len, la v polyamide (c bit l mu ti) v thuc da.

    Chun b mu: EN ISO 105-E04:2013o lng: EN ISO 17294-2:2014

    18540-29-9 Crom VI 1

    C th tch chit:Ngi ln: 3 phn triu Tr em v em b: 0,5 phn triuDt kim, khng phi da

    Mc d thng c kt hp vi thuc da, Crom VI cng c th c s dng trong nhum len (sau qu trnh m crom).

    Chun b mu: Dt may: EN ISO 105-E04:2013 Gi ha da: Cc iu kin gi ha da: 24 gi, 80 C, ti a 5% m tng i, khng c thng gi; EN 17075-1:2015o lng: Dt may: EN ISO 17294-2 Da: EN 17075-1:2015 Th nghim gi ha c s dng ty tng thng hiu.

    7440-48-4 Coban (Co) 3 C th tch chit: 1 phn triuCoban v cc hp cht ca Coban c th c s dng trong cc hp kim, bt mu, dng c nhum, v vic sn xut nt nha.

    Chun b mu: EN ISO 105-E04:2013o lng: EN ISO 17294-2

  • 16

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    c s dng rng ri trong lch s; mc xut hin cao

    Mc xut hin trung bnh Nguy c tht bi thp* 21 3

    CAS s Cht T l Xut hin*

    Gii hn Nguyn liu Th &Thnh phm

    Tim nng S dngGia cng Dt cho Trang phc & Giy dp

    Phng php Th nghim Ph hpChun b Mu v o lng

    Kim loi Nng, tip theo

    7440-50-8 ng (Cu) 2 C th tch chit: 25 phn triuC th tm thy ng v cc hp cht ca ng trong cc hp kim v bt mu, v trong dt may di dng cht khng khun.

    Chun b mu: EN ISO 105-E04:2013o lng: EN ISO 17294-2:2014

    7439-92-1 Ch (Pb) 3

    C th tch chit: Ngi ln v tr em: 1 phn triu Em b: 0,2 phn triuTng: 90 phn triu

    C th c kt hp vi nha, sn, mc, bt mu v cht ph b mt.

    Chun b mu: C th tch chit: EN ISO 105-E04:2013 Tng: Ph mu bng vi sng vi H202/HNO3Ch trong sn v cht ph b mt: CPSIA Mc 101 16 CFR 1303 o lng: EN ISO 17294-2:2014

    7439-97-6 Thy ngn (Hg) 3C th tch chit: 0,02 phn triuTng: 0,5 phn triu

    Cc hp cht thy ngn c th hin din trong thuc tr su v cc cht gy nhim nh trong xt (NaOH). Cc hp cht ny cng c th c s dng trong sn.

    Chun b mu: C th tch chit: EN ISO 105-E04:2013Tng: Ph mu bng vi sng vi H202/HNO3 o lng: EN ISO 17294-2:2014

    7440-02-0 Niken (Ni) 1

    C th tch chit: 1 phn triuGii phng: Tip xc vi da ko di: 0,5 g/cm/tunPhn c l: 0,2 g/cm/tun

    Niken v cc hp cht ca Niken c th c s dng m hp kim v ci thin kh nng chng n mn v cng ca hp kim. Chng cng c th xut hin di dng cc tp cht trong bt mu v hp kim.

    Chun b mu: Dt may: EN ISO 105-E04:2013 Phn kim loi: EN 12472:2005+ A1:2009 o lng: Dt may: EN ISO 17294-2:2014 Phn kim loi: EN 1811:2015

    7782-49-2 Selen (Se) 3 C th tch chit: 500 phn triuC th c tm thy trong cc si tng hp, sn, mc, nha v trang tr kim loi.

    Chun b mu: EN ISO 105-E04:2013o lng: EN ISO 17294-2:2014

  • 17

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    c s dng rng ri trong lch s; mc xut hin cao

    Mc xut hin trung bnh Nguy c tht bi thp* 21 3

    CAS s Cht T l Xut hin*

    Gii hn Nguyn liu Th &Thnh phm

    Tim nng S dngGia cng Dt cho Trang phc & Giy dp

    Phng php Th nghim Ph hpChun b Mu v o lng

    N-Nitrosamine

    62-75-9 N-nitrosodimethylamine (NDMA) 2

    0,5 phn triu mi loiC th c hnh thnh di dng sn phm ph trong sn xut cao su.

    GB/T 24153-2009

    55-18-5 N-nitrosodiethylamine (NDEA) 2

    621-64-7 N-nitrosodipropylamine (NDPA) 2

    924-16-3 N-nitrosodibutylamine (NDBA) 2

    100-75-4 N-nitrosopiperidine (NPIP) 2

    930-55-2 N-nitrosopyrrolidine (NPYR) 2

    59-89-2 N-nitrosomorpholine (NMOR) 2

    614-00-6 N-nitroso N-methyl N-phenylamine (NMPhA) 2

    612-64-6 N-nitroso N-ethyl N-phenylamine (NEPhA) 2

    Cc Hp cht Organotin

    Khc Dibutyltin (DBT) 3

    1 phn triu mi loi

    Loi ha cht c cha thic v cht hu c nh cc nhm butyl v phenyl. Organotin ch yu c tm thy trong mi trng di dng cht chng bn trong sn hng hi, nhng chng cng c th c s dng lm cht dit sinh vt (v d, cht khng khun), cht xc tc trong sn xut nha v keo v cht n nh nhit trong nha/cao su. Trong dt may v may mc, organotin c kt hp vi nha/cao su, mc, sn, cht lm kim long lanh, cc sn phm polyurethane v vt liu truyn nhit.

    CEN/ISO 16179:2012

    Khc Dioctyltin (DOT) 3

    Khc Monobutyltin (MBT) 3

    Khc Tributyltin (TBT) 30,5 phn triu mi loi

    Khc Triphenyltin (TPhT) 3

    Khc Tt c cc hp cht Organotin c ba nhm th 3 1 phn triu mi loi

    Ortho-phenylphenol

    90-43-7 Ortho-phenylphenol (OPP) 2 1000 phn triuOPP c th c s dng v cc c tnh bo qun ca n trong da hoc di dng cht mang trong qu trnh nhum.

    Chun b Mu: 64 BVL B 82.02.08 o lng: GC-MS, LC-MS xc nhn

  • 18

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    c s dng rng ri trong lch s; mc xut hin cao

    Mc xut hin trung bnh Nguy c tht bi thp* 21 3

    CAS s Cht T l Xut hin*

    Gii hn Nguyn liu Th &Thnh phm

    Tim nng S dngGia cng Dt cho Trang phc & Giy dp

    Phng php Th nghim Ph hpChun b Mu v o lng

    Cc cht ph hy tng ozone

    Khc Xem Quy nh (EC) s 1005/2009 c danh sch y . 3 Cc cht ph hy tng ozone b cm s dng. Tch chit KOH, 15 gi 90 C; 64 LFGB B 82.02-08 hoc DIN EN ISO 17070:2015

    Cc Hot cht Perfluorinated v Polyfluorinated (PFCs)

    2795-39-3 Perfluorooctane Sulfonate (PFOS) 2

    1 g/m2 mi loi

    PFOA v PFOS c th hin din di dng cc sn phm ph d kin trong cc cht chng thm nc, du v bn thng mi chui di. PFOA cng c th c s dng trong cc polyme nh polytetrafluoroethylene (PTFE)

    CEN/TS 15968:2014

    3825-26-1 Axit Perfluorooctanoic (PFOA) v cc mui v este ca n 2

    Thuc tr su, Nng nghip

    Khc Xem Ph lc A c danh sch y . 3 0,5 phn triu mi loi C th c tm thy trong si t nhin, ch yu l cotton.ISO 15913/DIN 38407 F2 hoc EPA 8081/EPA 8151A hoc BVL L 00.00-34:2010-09

  • 19

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    c s dng rng ri trong lch s; mc xut hin cao

    Mc xut hin trung bnh Nguy c tht bi thp* 21 3

    CAS s Cht T l Xut hin*

    Gii hn Nguyn liu Th &Thnh phm

    Tim nng S dngGia cng Dt cho Trang phc & Giy dp

    Phng php Th nghim Ph hpChun b Mu v o lng

    Phthalat

    28553-12-0 Di-Iso-nonylphthalate (DINP) 1

    500 phn triu mi loiTng: 1000 phn triu

    Este ca axit orthophthalic (phthalat) l mt loi hp cht hu c thng c thm vo nha tng tnh linh hot. i khi chng c s dng to thun li cho vic c nha bng cch gim nhit nng chy ca n.C th tm thy phthalat trong:

    Cc thnh phn bng nha do (v d, PVC)

    Bt nho in n Cht kt dnh Nt nha ng cch in nha Cht ph bng nha polyme

    Cc phthalat c lit k l nhng loi thng c s dng cho cc ngnh cng nghip. Tm thm thng tin v cc phthalat b hn ch theo lut php trong danh sch REACH SVHC, c cp nht thng xuyn.

    Chun b mu: CPSC-CH-C1001-09o lng: Dt may: GC-MS, EN ISO 14389:2014 Da: GC-MS

    117-84-0 Di-n-octylphthalate (DNOP) 1

    117-81-7 Di(2-ethylhexyl)-phthalate (DEHP) 1

    26761-40-0 Diisodecylphthalate (DIDP) 1

    85-68-7 Butylbenzylphthalate (BBP) 1

    84-74-2 Dibutylphthalate (DBP) 1

    84-69-5 Diisobutylphthalate (DIBP) 1

    68515-42-4 Di(C7-C11 alkyl) phthalate (DHNUP), tuyn tnh + mch nhnh 1

    71888-89-6 Di(C6-C8 alkyl) phthalate (DIHP), mch nhnh, giu C7 1

    117-82-8 Di(2-methoxyethyl) phthalate (DMEP) 1

    84-75-3 Di-n-hexylphthalate (DnHP) 1

    84-66-2 Diethylphthalate (DEP) 1

    605-50-5 Diisopentylphthalate (DIPP) 1

    776297-69-9 n-Pentylisopentylphthalate (NPIPP) 1

    131-18-0 Di-n-pentylphthalate (DPP) 1

    68515-50-4 Dihexylphthalate, mch nhnh + tuyn tnh 1

    131-11-3 Dimethylphthalate (DMP) 1

    84777-06-0 Axit 1,2-Benzenedicarboxylic, dipentylester, mch nhnh + tuyn tnh 1

  • 20

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    c s dng rng ri trong lch s; mc xut hin cao

    Mc xut hin trung bnh Nguy c tht bi thp* 21 3

    CAS s Cht T l Xut hin*

    Gii hn Nguyn liu Th &Thnh phm

    Tim nng S dngGia cng Dt cho Trang phc & Giy dp

    Phng php Th nghim Ph hpChun b Mu v o lng

    Hydrocacbon Thm a vng (Polycyclic Aromatic Hydrocarbons - PAHs)

    83-32-9 Acenaphtene 1

    Khng c gii hn ring

    PAHs l nhng thnh phn t nhin ca du th v l cc d lng ph bin t qu trnh lc du. PAHs c mi c trng tng t nh ca lp xe hoc nha ng. D lng du c cha PAHs c thm vo cao su v nha di dng cht lm mm hoc cht m rng v c th c tm thy trong cao su, nha, sn v cht ph. PAHs thng c tm thy trong ngoi ca giy dp v trong bt nho in n in mn hnh. PAHs c th hin hu di dng cc tp cht trong Than en. Chng cng c th c hnh thnh t s phn hy nhit ca vt liu ti ch trong qu trnh ti ch

    **Naphthalene: Cc cht phn tn dng cho thuc nhum trong dt may c th cha nng naphthalene cn cao do vic s dng cc dn xut naphthalene cht lng thp (chng hn nh cc sn phm c c naphthalene sulphonate formaldehyde cht lng km).

    AFPS GS 2014

    208-96-8 Acenaphthylene 1

    120-12-7 Anthracene 1

    191-24-2 Benzo(g,h,i)perylene 1

    86-73-7 Fluorene 1

    206-44-0 Fluoranthene 1

    193-39-5 Indeno(1,2,3-cd)pyrene 1

    91-20-3 Naphthalene** 1

    85-01-8 Phenanthrene 1

    129-00-0 Pyrene 1

    56-55-3 Benzo(a)anthracene 1

    1 phn triu mi loiHng chm sc tr em: 0,5 phn triu mi loi

    50-32-8 Benzo(a)pyrene 1

    205-99-2 Benzo(b)fluoranthene 1

    192-97-2 Benzo[e]pyrene 1

    205-82-3 Benzo[j]fluoranthene 1

    207-08-9 Benzo(k)fluoranthene 1

    218-01-9 Chrysene 1

    53-70-3 Dibenzo(a,h)anthracene 1

    Tng: 10 phn triu

  • 21

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    c s dng rng ri trong lch s; mc xut hin cao

    Mc xut hin trung bnh Nguy c tht bi thp* 21 3

    CAS s Cht T l Xut hin*

    Gii hn Nguyn liu Th &Thnh phm

    Tim nng S dngGia cng Dt cho Trang phc & Giy dp

    Phng php Th nghim Ph hpChun b Mu v o lng

    Cc Hp cht Hu c D bay hi (VOC)

    71-43-2 Benzen 2 5 phn triu

    Khng nn s dng cc VOC ny trong cc ch phm ha cht dt ph tr. Chng cng lin quan n qu trnh da trn dung mi v d nh cht ph polyurethane da trn dung mi v cc loi keo/cht kt dnh. Khng nn s dng cc hp cht ny cho bt k hnh thc v sinh c s hoc v sinh ti ch.

    Chit tch dung mi ha hi 120 C trong mt gi GC-MS; Tch chit methanol 60

    56-23-5 Cacbon tetraclorua 2

    Tng: 1000 phn triu

    67-66-3 Chloroform 2

    107-06-2 1,2-Dichloroethane 2

    75-35-4 1,1-Dichloroethylene 2

    127-19-5 Dimethylacetamide (DMAC) 2

    76-01-7 Pentachloroethane 2

    630-20-6 1,1,1,2- Tetrachloroethane 2

    79-34-5 1,1,2,2- Tetrachloroethane 2

    127-18-4 Tetrachloroethylene (PER) 2

    108-88-3 Toluene 2

    71-55-6 1,1,1- Trichloroethane 2

    79-00-5 1,1,2- Trichloroethane 2

    79-01-6 Trichloroethylene 2

    1330-20-7 Xylene (meta-, ortho-, para-) 2

  • 22

    Danh sch cc Cht b Hn ch ca AFIRM | Thng 12 nm 2015

    c s dng rng ri trong lch s; mc xut hin cao

    Mc xut hin trung bnh Nguy c tht bi thp* 21 3

    115-32-2 Dicofol

    141-66-2 Dicrotophos

    60-57-1 Dieldrine

    60-51-5 Dimethoate

    88-85-7 Dinoseb, cc mui v acetat ca n

    57648-21-2 DTTB (Timiperone)

    115-29-7 Endosulfan

    959-98-8 Endosulfan I (alpha)

    33213-65-9 Endosulfan II (beta)

    72-20-8 Endrine

    66230-04-4 Esfenvalerate

    108-93-4 Ethylendibromid

    56-38-2 Ethylparathione

    51630-58-1 Fenvalerate

    1336-36-3Biphenyl halogen ha, bao gm c Polychlorinatedbiphenyl (PCB)53469-21-9

    Khc

    Khc Terphenol halogen ha, bao gm c polychlorinated terphenyl (PCT)

    Khc Naphthalene halogen ha, bao gm c polychlorinated naphthalenes (PCNs)

    Khc Diarylalkane halogen ha

    99688-47-8 Cc diphenyl methane halogen ha, bao gm c Monomethyl-dibromo-diphenyl methane, Monomethyl-dichloro-diphenyl methane, v Monomethyl-tetrachloro-diphenyl methane

    81161-70-8

    76253-60-6

    76-44-8 Heptachlor

    1024-57-3 Heptachloroepoxide

    36355-01-8 Hexabromobiphenyl

    319-84-6 a-Hexachlorocyclohexane c v khng c Lindane

    319-85-7 b-Hexachlorocyclohexane c v khng c Lindane

    319-86-8 g-Hexachlorocyclohexane c v khng c Lindane

    118-74-1 Hexachlorobenzene

    465-73-6 Isodrine

    4234-79-1 Kelevane

    143-50-0 Kepone

    7784-40-9 Asenat hydro ch

    58-89-9 Lindane

    121-75-5 Malathione

    94-74-6 MCPA

    94-81-5 MCPB

    93-65-2 Mecoprop

    10265-92-6 Metamidophos

    72-43-5 Methoxychlor

    2385-85-5 Mirex

    6923-22-4 Monocrotophos

    56-38-2 Parathion

    298-00-0 Parathion-methyl

    608-90-2 Pentabromobenzene

    1825-21-4 Pentachloroanisole

    52645-53-1 Permethrine

    7786-34-7 Phosdrin/Mevinphos

    72-56-0 Perthane

    31218-83-4 Propethamphos

    41198-08-7 Profenophos

    13593-03-8 Quinalphos

    82-68-8 Quintozene

    8001-50-1 Strobane

    297-78-9 Telodrine

    8001-35-2 Toxaphene

    731-27-1 Tolylfluanide

    1582-09-8 Trifluraline

    Ph lc A: Thuc tr su, Nng nghipCAS s Tn Thuc tr su CAS s Tn Thuc tr su CAS s Tn Thuc tr su

    93-72-1 2-(2,4,5-trichlorophenoxy) axit propionic, cc mui v hp cht ca axit

    93-76-5 2,4,5-T

    93-72-1 2,4,5-TP ChemRRV

    94-75-7 2,4-D

    309-00-2 Aldrine

    86-50-0 Azinophosmethyl

    2642-71-9 Azinophosethyl

    4824-78-6 Bromophos-ethyl

    2425-06-1 Captafol

    63-25-2 Carbaryl

    510-15-6 Chlorbenzilat

    57-74-9 Chlordane

    6164-98-3 Chlordimeform

    470-90-6 Chlorfenvinphos

    1897-45-6 Chlorthalonil

    56-72-4 Coumaphos

    68359-37-5 Cyfluthrin

    91465-08-6 Cyhalothrin

    52315-07-8 Cypermethrin

    78-48-8 S,S,S-Tributyl phosphorotrithioate (Tribufos)

    52918-63-5 Deltamethrin

    53-19-0DDD

    72-54-8

    3424-82-6DDE

    72-55-9

    50-29-3DDT

    789-02-6

    333-41-5 Diazinone

    1085-98-9 Dichlofluanide

    120-36-2 Dichloroprop

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