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Inside: Fast cure at low temperature Inside: Middle East suppliers update LEADING JOURNAL FOR THE COATINGS INDUSTRY IN EUROPE AND THE MIDDLE EAST VOL 207 – NO 4632 JUNE 2017 Colour concepts – driving the imagination for the future EXTENDERS & FILLERS ADHESIVES & SEALANTS COLOUR TECHNOLOGY PROTECTIVE COATINGS UK COUNTRY FOCUS MIDDLE EAST DIRECTORY OF SUPPLIERS

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Inside: Fast cure at low temperature

Inside: Middle East suppliers update

LEADING JOURNAL FOR THE COATINGS INDUSTRY IN EUROPE AND THE MIDDLE EAST

VOL 207 – NO 4632 JUNE 2017

Colour concepts – driving the imagination for the future

EXTENDERS & FILLERS • ADHESIVES & SEALANTS • COLOUR TECHNOLOGY • PROTECTIVE COATINGS • UK COUNTRY FOCUS • MIDDLE EAST DIRECTORY OF SUPPLIERS

www.covestro.com

Covestro is an independent, globally leading provider of polymer solutions.

network of cutting-edge production plants. By producing the same high standard at every site throughout the world, we ensure that our customers

reliable quality in every region. What can we invent for you? www.inventing-for-you.com

INVENTING POLYMER STANDARDSFOR YOU

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SECTION REPORT

1 PPCJ • June 2017 www.coatingsgroup.com

CONTENTS

VOL 207 No 4632 June 2017

Protective Coatings

18 Floor coating

To stop the ingress of water on a bakery floor, a polyaspartic resin

blend coating was used

22 Rapid curing

Fast curing at low temperatures, together with reduced VOC levels,

provide a solution to a wider range of industry requirements

Extenders & Fillers

24 Stain resistance

Improved performance for cleanable, low-gloss interior

emulsion paints, using Neuburg Siliceous Earth, preserves

application characteristics

3 Barrier protection

Thinner grades of glass flake, as an alternative to conventional

fillers, outperform standard grades and open up opportunities

34 Surface resistance

Talc, as a functional filler, is compared with additives, to show

their competitiveness in PVC and matte paints

Colour Technology

36 Drying times

Waiting for paint to dry is now a thing of the past using non-

contact spectrometers for measurement and storage of results

38 Colour matching

Customer samples can now be measured quickly and

accurately with a colour matching device

Adhesives & Sealants

39 One into two

The combination of polychloroprene, with selected nanosilica

dispersions, creates a network structure providing improvements in

cohesive strength

42 Conference update

Key speakers announced for this year’s FEICA conference in Italy

Middle East Directory of Suppliers

43 Coatings suppliers

The annual update of suppliers to the Middle East and North Africa

coatings market

Country Focus

49 UK

Strategic plans are being put in place ahead of the UK leaving the EU

Show Review

52 Nuremburg numbers

This year’s ECS proved to be another visitor drawing event with

innovations shown by major companies within this sector

COVER IMAGE CREDIT: www.merckgroup.com

Regular Features

03 From the Editor

04 News

08 Diary

10 Letter from America

12 Business Matters

16 Powder Matters

FORTHCOMING EVENTS

+44 (0)1737 [email protected] www.coatingsgroup.com'The CoatingsGroup'@CoatingsGroup

FOR UP-TO-DATE INFORMATION ON ANY OF THE ABOVE EVENTS, PLEASE

CONTACT THE COATINGS GROUP

Global links for coatings professionals

CICC, Cairo, Egypt 11 – 12 October 2017

29 – 31 May 2018Sandton Convention Centre, South Africa

Balai Sidang Jakarta Convention Center, Indonesia 13 – 15 September 2017

DWTC, Dubai UAE19 – 21 March 2018

SECTION REPORT

3 PPCJ • June 2017www.coatingsgroup.com

EDITORIAL COMMENT

Discussions to continue? Now in with the new

Over the past few months, all eyes

have been on the approach by

PPG looking to combine with

AkzoNobel. Three times AkzonNobel has

declined the offer, believing that it is not in

the best interests of the shareholders to

accept this bid. On May 10, PPG replied

to AkzoNobel’s response of April 24 and

stated that ‘PPG remains willing to meet

with AkzoNobel to engage in meaningful

discussions but without productive

engagement, PPG will assess and decide

whether or not to pursue an offer for

AkzoNobel. PPG will continue to examine

all of its options and make decisions for

the benefit of its shareholders. PPG will

make further announcements if and when

appropriate.’ Watch this space.

Sail away

A release from AkzoNobel on it being the

official sustainability partner for the next

Volvo Ocean Race arrived in my inbox. The

race is taking sustainability to its heart by

helping to ‘turn the tide on plastic’ and the

partnership with AkzoNobel will focus on

boosting awareness through an education

programme designed to inspire future

generations to act positively on marine

litter. AkzoNobel’s long association with

the sea means the company is already

playing a key role in helping to protect the

world’s oceans. For example, it’s estimated

that the Intersleek range supplied through

the International brand has helped to save

US$3bn of fuel and 32M tons of CO2 since

being introduced 21 years ago. Recently,

the company also announced its intention

to be carbon neutral and use 100%

renewable energy in its operations by 2050.

Now introducing...

As I sail off into the sunset (this is my last

comment for PPCJ and for the publishing

fraternity – I am becoming a lady of leisure),

it gives me great pleasure to introduce

Chris Malthouse as the new Editor. She

has been the Editor of sister publication,

Asia Pacific Coatings Journal, for some

six years. She took to the task in hand

like a ‘duck to water’ so to speak and

PPCJ was sufficient to keep me out of too

much mischief and interfering. So my

Senior Editor role on APCJ was more for

show than anything else! She is a highly

professional journalist, with many years’

experience and I could not leave PPCJ in

more capable hands.

I hope all the contacts and friends I have

made, during my time within the coatings

sector, will make her feel as welcome as

they have me. Some of you will already

know her, which will make her transition to

PPCJ that much easier.

Also, new to the Coatings Group is Sally

Roberts, who is Deputy Editor on both

PPCJ and APCJ. She has experience in B2B

publishing, so having her on board will, I am

sure, be a great asset.

I particularly want to thank Chris for

all her support and putting up with my

‘preciousness’ regarding PPCJ – I wouldn’t

let her touch it, so you can now expect

some exciting and imaginative layout and

articles in the future!

A fond farewell to everyone.

EDITORIAL

Senior Editor: SUE TYLERTel: +44 (0)1737 855161Email: [email protected]

ADVERTISEMENT SALES

RANJEET SANDHUGermany/Switzerland/UKTel: +44 (0)1737 855105Email: [email protected]

FAN LANDERSAsia PacificTel: +44 (0)1737 855078Email: [email protected]

JESSICA SZUTS-NARANJOAmerica & Europe (ex Germany, Switzerland & UK)Tel: +44 (0)1737 855162Email: [email protected] or [email protected]

CHRIS HAMILTONMiddle East, Africa, Turkey & IndiaTel: +44 (0)1737 855109Email: [email protected]

Group Sales Director: KEZ CHENAgency/Agents & Corporate EnquiriesTel: +44 (0)1737 855107Email: [email protected]

ADVERTISEMENT PRODUCTION

Production Manager: MELANIE CHILESTel: +44 (0)1737 855044Email: [email protected]

MARKETING

Marketing Manager: KIERAN PROVERBSTel: +44 (0)1737 855067Email: [email protected]

CORPORATE

Vice President:IAN FAUXEmail: [email protected]

© dmg events (MEA) Ltd 2017

An official journal of the European Resin Manufacturers Association

PUBLISHED BY:

dmg events (MEA) Ltd, Quartz House,20 Clarendon Road, Redhill, Surrey RH1 1QX, UKTel: +44 (0)1737 855000Fax: +44 (0)1737 855034Website: www.coatingsgroup.com

ANNUAL SUBSCRIPTION:

UK £200.00/Outside UK £252.00Single copies: £28.00Polymers Paint Colour Journal is published 10 times a year

SUBSCRIPTIONS:

Tel: +44 (0)1737 855044Fax: +44 (0)1737 855034Email: [email protected];[email protected]: Subscriptions, dmg events (MEA) Ltd, Quartz House,20 Clarendon Road, Redhill, Surrey RH1 1QX, UK

Printed by:Pensord Press, Tram Road Pontllanfraith, BlackwoodGwent NP12 2YA, Wales

ISSN 1357-731XVol 207; Number 4632; June 2017

Founded 1879

Sue TylerSenior Editor, Coatings [email protected]

twitter.com/CoatingsGroup

facebook.com/TheCoatingsGroup

Search ‘The Coatings Group’ in LinkedIn

SECTION REPORT

4 PPCJ • June 2017www.coatingsgroup.com

NEWS

Clariant and Huntsman to combine in merger of equalsClariant and Huntsman

Corporation have announced

that their Boards of Directors

unanimously approved a definitive

agreement to combine in a

merger of equals through an all-

stock transaction.

The merged company will

be named HuntsmanClariant.

On a pro forma 2016 basis, the

combination of both companies

will create a leading global

speciality chemical company

with sales of approximately

US$13.2bn, an adjusted

EBITDA of US$2.3bn and a

combined enterprise value

of approximately US$20bn

at announcement.

The combined entity will

benefit from each other’s

strengths. It will have a

significantly improved growth

profile in highly attractive end

markets and geographies.

HuntsmanClariant will

leverage shared knowledge

in sustainability and boast a

much stronger joint innovation

platform. This will enable

the development of new

products in order to deliver

superior returns and drive

shareholder value.

“This is the perfect deal

at the right time. Clariant and

Huntsman are joining forces

to gain much broader global

reach, create more sustained

innovation power and achieve

new growth opportunities”,

said Hariolf Kottmann, CEO

of Clariant. “This is in the

best interest of all of our

stakeholders. Peter Huntsman

and I share the same strategic

vision and I look forward to

working with him.”

Peter R Huntsman,

President and CEO of

Huntsman, commented: “I

could not be more enthusiastic

about this merger and look

forward to working closely

with Hariolf Kottmann, a man

I have admired and trusted for

the past decade. We also look

forward to a close association

with his immensely talented

colleagues around the world.

Together, we will create a global

leader in speciality chemicals

with a combined balance sheet

providing substantial financial

strength and flexibility”.

NEWS IN BRIEFBASF announces co-operation with HP IndigoBASF has recently entered

a strategic collaboration

with HP Indigo, the world’s

leading manufacturer of

digital printing presses. Both

companies will collaborate

to develop water-based

adhesive solutions for

flexible packaging that are

specially tailored for the

requirements of the HP

Indigo ElectroInk process, a

highly flexible and fast digital

printing process.

Covestro lifts force majeure for polymeric MDICovestro is lifting the

declared force majeure for

polymeric MDI (methylene

diphenyl diisocyanate) in

the Europe, Middle East,

Africa (EMEA) region with

immediate effect. On April

25, Covestro had declared

force majeure, due to an

unforseeable production

problem at its site in

Brunsbüttel, Germany.

Lonza announces price increase for biocidesLonza has announced a

global price increase for

biocidal products across

the market fields of plastics,

leather, textiles, metal

working fluids, paints,

coatings and inks. As

a consequence of the

persistent rise in operating,

manufacturing and

regulatory costs, Lonza will

make a 10% price increase.

to all biocidal product

lines globally.

Sika invests in larger site in KazakhstanSika has relocated its

concrete admixture and

mortar production in Almaty,

in the south of Kazakhstan,

to a larger site in the 1.7M

population city. Aside from

the booming Kazakh market,

the plant will also serve the

construction sector in the

neighbouring country of

Kyrgyzstan to the south.

Axalta Coating Systems to acquire

the Spencer Coatings GroupAxalta Coating Systems, a leading

global supplier of liquid and powder

coatings, announced on May 23, that

it has entered an agreement to acquire

the Spencer Coatings Group, a leading

manufacturer of high performance

industrial coatings for heavy-duty

equipment, general industrial, oil and

gas, and glass coatings segments.

Financial terms of the transaction were

not disclosed.

The Spencer Coatings Group, established

in 1909, is the largest independent industrial

coatings manufacturer in the UK. Spencer’s

decades of success are attributed to its high

quality, durable products, with a reputation

of unparalleled customer service. Well-

known Spencer products include Acothane

polyurethanes for internal and external pipeline

coatings, Corroless coatings, which provide

a range of highly efficient corrosion control

solutions for a variety of steel structures and

high-performance water-based coatings for both

glass and general industrial segments.

“We are very proud to welcome the Spencer

Coatings Group into the Axalta family”, said

Michael Cash, Axalta Senior Vice President

and President, Industrial Coatings. “Spencer’s

industry leading product technologies fit very

well within Axalta’s current industrial portfolio.

With the acquisition of Spencer, we will have the

opportunity to take some incredibly innovative

products and expand into new geographies,

as well as provide our combined industrial

customers with additional product technologies.

We both share a strong commitment to our

customers and to the Industrial Coatings markets

in which we participate.”

“We have spent the past 20 years building

a specialised industrial coatings business with

innovative coating systems, which are supplied

to customers in the UK and overseas”, said

Phil Buck, Spencer Coatings Group Managing

Director. “To continue to grow and provide

confidence to our customers and employees,

we felt that the Spencer Coatings Group would

benefit from being part of a larger coatings

company that would enable us to accelerate our

growth plans. Axalta Coating Systems, with its

global footprint and commitment to innovation,

will provide the best home for our company and

we are very excited about the prospects for

both companies.”

SECTION REPORT

5 PPCJ • June 2017www.coatingsgroup.com

NEWS

NEWS IN BRIEFPPG earns John Deere AwardPPG announced that it was

named Supplier of the Year

and earned recognition as

a Partner-level supplier in

the John Deere Achieving

Excellence Program for

2016. Partner-level status

is Deere & Company’s

highest supplier rating.

Wacker strengthens its presence in Southeast AsiaWacker Chemie AG is

expanding its presence in

Southeast Asia by opening

a technical centre for

construction and adhesives

applications in Indonesia’s

capital Jakarta. The

technical facility serves as

a development and testing

laboratory for dispersible

polymer powders and

dispersions, which are used

as binders for the regional

building, paint, coatings and

adhesives industries.

PLS endorses Konica Minolta sheet-fed pressKonica Minolta has

confirmed that PLS Print

Logistic Services GmbH in

Markkleeberg, Germany,

is the latest commercial

customer for its AccurioJet

KM-1 UV digital sheet-

fed press.

PLS, a subsidiary of the

American online printing

service OvernightPrints, was

announced as the first beta

site for the press a year ago.

Now it has been revealed

that the long-standing

Konica Minolta customer is

building huge new business

opportunities with this

new system.

Fluence Analytics raises Series A financingFluence Analytics,

formerly Advanced

Polymer Monitoring

Technologies (APMT),

announced it has raised

a Series A funding round

led by Energy Innovation

Capital (EIC), a venture

capital firm.

Industry and MPs aligned on future of REACHin April, the Environmental

Audit Committee published

the results of its inquiry into the

future of chemicals regulation

after Brexit, to which the BCF

submitted a response.

The Committee’s report

was aligned with the views

of the coatings and wider

chemical industries, reflecting

the sector’s concerns on

the complexities around

transferring REACH into

UK law with the Great

Repeal Bill, clarification

needed from Government

on REACH registrations,

retention of registrations

and the difficulties of having

a separate UK system of

chemicals regulation.

Select Committees are

made up of at least 11 MPs

from different political parties,

who scrutinise government

policy. The Committees publish

inquiries into specific policies

and findings are reported to

Government, which formally

responds to the Committee

but do not have to adopt the

recommendations.

The findings of the inquiry

reflect the results of the

chemicals supply chain’s recent

Brexit survey conducted earlier

in the year.

Tom Bowtell, Chief

Executive of the British

Coatings Federation, said: “I’m

pleased the inquiry report is

synonymous with the results of

the chemical industry survey

on the future of REACH in the

UK. Over three quarters of BCF

members said that a separate

UK chemical regulatory system

would be bad for business,

which is acknowledged

as being expensive for the

taxpayer and industry.

“It’s clear from our members

that access to the single market

is vital and it’s positive that

the inquiry report notes that

the UK should negotiate to

remain a participant of REACH.

I hope the Government will

pay the report heed by taking

a pragmatic approach to the

future of the UK’s chemical

regulations and provide

certainty to the industry”.

AkzoNobel launches training

programme for coatings industryAkzoNobel has announced

the launch of a training

programme for coatings

industry professionals. A range

of accredited courses are now

being offered by AkzoNobel in

partnership with The Society

for Protective Coatings (SSPC),

covering several aspects of

coatings application, including

spray painting and abrasive

blast cleaning.

With the launch of SSPC

TrainthePainter, AkzoNobel

is the only coatings supplier

offering the training globally,

bringing its product and

industry expertise to

professionals around the world.

The course focuses on correct

safe application theory and

practice, aiming to reduce

overspray and wastage, as well

as extend asset lifetimes and

minimise rework.

Mauricio Bannwart,

Managing Director of

AkzoNobel’s Protective

Coatings business, said:

“We are proud to announce

the launch of the SSPC

TrainthePainter programme. It

means that we are able to share

our expertise with the industry

and provide delegates with

training of the highest quality,

delivered by the people who

best understand the products

and practices involved in

coatings application”.

Covestro plans for succession of CEOCEO Patrick Thomas has

confirmed to the Supervisory

Board of Covestro that he

will complete his contract

as expected on September

30, 2018. Dr Richard Pott,

Chairman of the Supervisory

Board, said: “We sincerely

regret Patrick Thomas’

retirement. However, with the

end of his contract in fall 2018,

Patrick Thomas will have been

at the top of Covestro for more

than 10 years and, of course,

we respect this step. Under his

leadership, the company has

achieved remarkable success,

becoming a leading innovator

in the chemical industry with

outstanding financial results.

We, therefore, thank him

sincerely for his excellent work

and support in facilitating a

foresighted succession plan.”

Patrick Thomas, pictured,

said: “I would like to take

this opportunity to thank all

employees of Covestro. They

have done a great job in the

last few years and have made

Covestro a very successful

company. I look forward to

ensuring a successful transition

over the next 16 months”.

Patrick Thomas will be

followed as CEO by Dr Markus

Steilemann, currently Chief

Commercial Officer and long-

term colleague at the Board of

Management since 2015.

SECTION REPORT

6 PPCJ • June 2017www.coatingsgroup.com

NEWS

Site expansion strengthens International brand in South AmericaAkzoNobel has opened a Performance Coatings

production facility in Santo André, Brazil, which

will enable the company to be more agile in

responding to local customer needs and regional

market demands. The facility will manufacture

and supply products from the company’s

International® portfolio of high performance

industrial, marine and yacht coatings, which has

been present in Brazil for 90 years.

As well as reinforcing AkzoNobel’s

commitment to investing in innovation and

technology, the plant will also help to strengthen

International’s market position in South America.

Commenting on the opening, Jelena Arsic Van

Os, Director of AkzoNobel Performance Coatings

in South America, said: “Our innovation expertise

plays a key role in driving organic growth and

this new facility highlights our continued focus

on adapting to market needs in order to better

serve our customers with essential colour and

protection. The investment will add further

momentum to the instrumental role International

is playing in helping AkzoNobel to strategically

diversify its markets and expand its presence

throughout South America”.

The Santo André expansion has increased

production capacity for smaller batches by

35% and for larger batches by 50%. A new

distribution centre also means shipping capacity

has been expanded by 50%. Meanwhile, an

increase in the level of automation has improved

the control of the production process and, in

turn, the quality of the products. “AkzoNobel

stands out for having excellent products

and services and an extraordinary customer

base in this region of key importance for the

company”, explained Pablo Ribeiro, Business

Manager for Marine and Protective Coatings in

South America”.

NEWS IN BRIEFICS Cool Energy achieves carbon trust accreditationICS Cool Energy has been

added to the Carbon

Trust’s Green Business

Directory as an accredited

supplier, providing

independent recognition

of the temperature control

specialist’s skills and

services. The Carbon

Trust Accredited Supplier

Scheme recognises high

quality energy efficient

equipment and renewable

technology suppliers.

Indestructible Paint Japanese distribution Indestructible Paint

Ltd has announced

an enhancement of its

business and services in

Japan through a distribution

agreement with Todo

International. The specialist

coatings manufacturer has

confirmed a distribution

agreement with Todo’s

Japanese facility – the first

such capability agreed by

the Birmingham-based

company in the country.

The company believes that

by close co-operation with

a specialist distributor, its

links with a wide range of

aerospace component

manufacturers in Japan will

be strengthened.

AkzoNobel partners with MSLGROUPAs part of its strategy to

accelerate growth and

further strengthen its

portfolio of leading brands,

AkzoNobel has appointed

MSLGROUP as its global

communications and public

affairs agency partner.

MSL will operate from

a global team based in

London and via local

offices and affiliates in

key countries and regions

where AkzoNobel operates.

Specific areas of support

will include brand strategy,

public relations, public

affairs and digital strategy.

ABRAFATI 2017 As part of ABRAFATI 2017, the

International Coatings Congress

is taking place on October 3-5

at São Paulo Expo. Some 90

lectures plus papers at the

Poster Session, the ABRAFATI-

RadTech Seminar on Radiation

Curing and four Plenary

Sessions, will be conducted

by industry experts. Studies

will include coatings designed

for applications and covering

quality and performance-related

themes, such as durability,

strength, hiding power and

drying technologies.

Recycling options for multi-layer packagingPartners of the innovative ‘Virtuous Circle’ project

have announced the results of ground breaking

research into new recycling options for multilayer

food packaging at trade fair Interpack. The findings

shed new light on the potential of this type of

packaging to be ‘upcycled’ for use in products of

value in a circular economy.

Multimaterial multilayer films are an innovative

type of packaging used to preserve food and to

protect it from contamination or from oxygen that

would lead to faster degradation of food. Multi-

layer packaging, while highly effective, has been

criticised for being challenging to recycle due to

the challenges of separating the different layers

and sorting them by type. In addition, the general

preconception is that even if these materials can

be technically recycled, the resulting raw material

is of such poor quality that it effectively amounts

to ‘downcycling’.

One of the core aims of the ‘Virtuous Circle’

project, launched in South Africa in October

2016, has been to challenge these assumptions.

Project partners DuPont and Rural Waste

Poverty Alleviation Solutions (RWPA) have

worked together on testing innovative methods

of creating new products of genuine value from

multilayer film packaging after it has served its

original purpose. http://thevirtuouscircle.co.za

Dr Cynthia A Gosselin

accepts ASTM AwardThe ChemQuest Group, Inc, a

leading business strategy firm in

speciality chemicals, is delighted

to announce that Dr Cynthia A

Gosselin has been awarded the

ASTM International’s Kenneth

J Boedecker, Jr Distinguished

Service Award for her leadership

role as an officer within

Committee A05’s Technical

Subcommittee A05.11 on Coated

Sheet Specifications. This Award

is the highest that can be given

to a member of Committee

A05 on Metallic

Coated Iron & Steel Products.

Established in 1998, this

award recognises exemplary

leadership and significant

technical contributions, such

as organsing a new field of

standards activity or strategic

direction, authoring new

standards or major revisions to

A05 standards, as well as the

co-ordination of interlaboratory

test programmes and

conducting key research.

SECTION REPORT

7 PPCJ • June 2017www.coatingsgroup.com

NEWS

Crew announced for team AkzoNobel Volvo Ocean Race campaignSkipper Simeon Tienpont has unveiled the

eight sailors who will join him to represent team

AkzoNobel in the 2017-18 Volvo Ocean Race.

The diverse international line-up features leading

professionals from seven nations and includes four

past Volvo Ocean Race winners, who between

them have claimed six victories – three-time

winner Brad Jackson from New Zealand, Chuny

Bermudez from Spain, Joca Signorini from Brazil

and Jules Salter from Great Britain. “The crew I

have chosen blends maturity and experience with

youth and vigour”, explained Tienpont, who will be

competing in his third Volvo Ocean Race.

Commenting on the announcement,

AkzoNobel CEO Ton Büchner said: “The Volvo

Ocean Race is a wonderful showcase for the

unrivalled quality and high performance of

our products, so it’s important this is reflected

in the team itself. Simeon has assembled an

outstanding mixed crew of real pedigree, which

is fully committed to winning together and we are

proud to have them on board.”

Work is under way at the Volvo Ocean Race

Boatyard facility in Lisbon, Portugal, to fit out

and paint team AkzoNobel’s brand new Volvo

Ocean 65 yacht. The boat is scheduled to sail

for the first time in early June, with an official

christening ceremony planned to take place a

few weeks later at the team’s base in The Hague,

The Netherlands. The team AkzoNobel crew

will then begin a period of intense on-the-water

training before the eight-month round-the-

world race officially starts in Alicante, Spain, on

October 22.

Adesa first in Europe with Durst Tau 330

and inline LFS 330 laser finishing systemDurst, manufacturer of digital

production technologies,

has announced Adesa, one

of France’s most respected

label-making printers, as the

first company in Europe to

invest in the Durst in-line digital

laser finishing system for the

Tau 330 UV inkjet label press

that incorporates state-of-

the-art diecutting technology

from Spartanics.

Durst is providing a

complete digital end-to-end

workflow with fully automatic

job changeover in a single

pass. This is filling an important

gap in the market for Adesa,

which has started winning

new contracts since opting

for the Durst 330 LFS on-line

system after carrying out

extensive research.

Brice Carugati, President

of Adesa, which is

based near Nimes, in

southern France, said:

“This machine is unique

in that it does printing

and diecutting all in one

pass. Another important

factor for our investment is the

extremely vivid white, which

prints far better than on the

machine I used previously. And

screen printing was also out of

the question because is very

slow and expensive, so not

suitable for the type of work I

need to do for customers.

Brice added: “We took our

time to familiarise ourselves with

the technology, which allows

us to produce self-adhesive

labels in a totally digital stream.

This dramatically reduces

our production time and

increases responsiveness.”

Adesa has configured its

Durst Tau 330 inkjet press in

seven colours, with orange

and purple complementing the

primary colours (CMYK).

NEWS IN BRIEFAkzoNobel and Atul to start MCA productionAkzoNobel and chemicals

manufacturing company

Atul have formally agreed

the JV partnership

announced last year

for the production of

monochloroacetic acid

(MCA) in India. The

companies will establish a

new plant at Atul’s facility

in Gujarat by first quarter

2019, with each partner

holding a 50% stake in

the JV, to be registered as

‘ANAVEN’.

BASF expands its offer for innovation projects BASF will combine its

competencies in design,

trend research and

simulation in the plastics

division to improve its global

offering for joint innovations

with customers. Depending

on the type of project,

the company will offer the

material consultancy of its

designfabrik, the simulation

tool Ultrasim and the trend

research know-how in a

one-stop-shop solution and

also physically bundle these

functions at one location

per region.

In order to cluster

the functions at the

Ludwigshafen site, BASF

will rebuild a former bomb

shelter outside the site

and bring in modern

architectural elements.

First graphene paints available in UKThe first commercially

available graphene-infused

paints in the UK are on

sale from The Graphene

Company, distributor of

the Graphenstone range of

paints and materials.

Sourced from pure carbon,

it is the strongest material

now known to science.

Graphene’s inclusion

in paints, coatings and

other building materials

exponentially enhances

hardness and coverage.

Dow’s Dr Melinda Keefe to receive

SCI Gordon E Moore MedalThe Society of Chemical Industry

(SCI), America Group, has

announced that Dr Melinda H

Keefe of The Dow Chemical

Company will be awarded the

14th annual SCI Gordon E. Moore

Medal. Dr Keefe has successfully

combined her passion for art and

chemistry into an exceptional

career encompassing the

multi-faceted area of coating

science. Currently a Senior

R&D Manager for Architectural

Coatings with The Dow Chemical

Company, Keefe and her co-

workers were responsible for the

development of the remarkable

EVOQUE pre-composite polymer

platform, which facilitates

higher performing and more

sustainable paints.

SECTION REPORT

8 PPCJ • June 2017www.coatingsgroup.com

DIARY | NEWS

DIARYSeptember 13-15, 2017

Asia Pacific Coatings Show

Balai Sidang Jakarta

Convention Center, Indonesia

www.coatingsgroup.com

September 13-15, 2017

FEICA 2017 Conference & EXPO

Forte Village, Sardinia, Italy

www.feica-conferences.com

September 27-29, 2017

CEPE Annual Conference &

General Assembly

Hilton Hotel, Athens, Greece

http://www.cepe.org

October 3-5, 2017

ABRAFATI 2017

São Paulo Expo, Brazil

www.abrafati2017.com.br

October 6-9, 2017

17th International Paint,

Resin, Coating and

Composites Fair

Tehran Permanent Fairground

Tehran, Iran www.ipcc.ir

October 11-12, 2017

Egyptian Coatings Show

Middle East Coatings Show

CICC, Cairo, Egypt

www.coatingsgroup.com

October 15-18, 2017

Western Coatings

Symposium 2017 (WCS 2017)

Las Vegas, NV, USA

www.westerncoatings.org

October 17-19, 2017

RadTech Europe 17

Prague, Czech Republic

www.radtech2017.com

November 15-17, 2017

CHINACOAT 2017

Shanghai New International Expo

Centre, Shanghai, PR China

www.chinacoat.net

March 19-21, 2018

Middle East Coatings Show

DWTC, Dubai, UAE

www.coatingsgroup.com

May 29-31, 2018

Coatings for Africa

Johannesburg, South Africa

www.coatingsgroup.com

EU round up: June 1 EU labelling and packaging compliance deadlineEuropean Union (EU) paint and coatings

companies and their retailers have been warned

products on sale from June 1 must be classified,

labelled and packaged in line with the EU

classification, labelling and packaging (CLP)

regulation (1272/2008). If not, they will have to be

reclassified, repackaged and labelled or withdrawn

from the market, the European Chemicals Agency

(ECHA) has said, noting that this deadline “marks

the end of the transitional period for labelling

mixtures”. In a note to chemical industries, such

as the paint and coatings sector, it said: “If you still

have products on your shelves with labels following

the requirements of the previous legislation, you

must now make sure that the products are either

no longer placed on the market, or re-classified

and re-labelled in accordance with CLP”. The

legislation was designed to bring EU rules in

line with the UN’s globally harmonised chemical

classification and labelling system.

• Meanwhile, ECHA is asking chemical companies,

including paint and coatings businesses and

their suppliers, to dig deep for more data on

their substances, to aid environmental health

assessments. The EU agency is concerned about

a shortage of information for 540 substances it

wants assessed for potential inclusion on its list

of substances of very high concern. These could

eventually be subject to special authorisation

controls. ECHA Executive Director Geert Dancet

said: “The compliance of the data provided by

companies has got to improve”.

• A draft standard has been released by CEN,

the European Committee for Standardization,

on assessing emissions of substances from

coatings into indoor air through sampling,

conditioning and testing. The standards

organisation is also developing a standard on

assessing tanning staining for coating materials

and coating systems for exterior wood. Another

standard under development will help assess

the adhesion on exterior wood by coating

materials and coating systems through a

double-X-cut test. And a standard is being

developed to lay down a wedge-cut method

for determining film thickness for paints and

coatings. See https://standards.cen.eu/dyn/

www/f?p=204:105:0

• Finnish consumer protection authorities have

ordered the withdrawal from sale of Turkey-made

Tremco illbruck-branded CT040 Kontaktiliima

Superb glue because it contains toluene

(measured value: 0.8%), breaching EU chemical

control system REACH, said a note from EU

consumer alert network RAPEX. Meanwhile,

Latvian consumer authorities have removed

Belgium-exported SOUDAL-branded CYANOFIX

84A glue from sale because of similar concerns

over toluene content (measured value: 0.17%

by weight), said a RAPEX note. And German

importers have withdrawn USA-made Eternal

Ink branded light red tattoo ink from sale over

its nickel contact, saying it breached national

legislation, said RAPEX.

People

Changes in Tikkurila Management BoardThe following persons and

responsibility areas: Meri

Vainikka is appointed as Senior

Vice President, Offering.

Vainikka will be responsible for

Research, Development and

Innovations, product portfolio

and marketing. Melisa Bärholm

is now Senior Vice President,

Human Resources. Janno Paju

continues as a member of the

Management Board. As Senior

Vice President, Sales, he will be

responsible for sales, Tikkurila

Group’s key accounts and

sales support. Petri Miettinen

continues as a member of the

Management Board responsible

for operations (Senior Vice

President, Operations). Jukka

Havia continues as a member

of the Management Board

responsible for finance and

administration (Chief Financial

Officer). The above mentioned

persons report to Erkki Järvinen,

President and CEO and the

Chairman of the Management

Board. The appointments took

effect on May 1, 2017.

Chromaflo President and CEO appointed to ACA Board of DirectorsScott Becker,

the President

and CEO of

Chromaflo

Technologies

Corp, has joined

the American

Coatings Association Board

of Directors as of May 9, 2017.

With this appointment, Becker

will serve a three-year term

ending in 2020.

Becker has been the

President of Chromaflo

Technologies since 2012.

Chromaflo hires WebsterChromaflo

Technologies

is pleased to

announce that

Casey Webster

has accepted

the position

of Human

Resources Manager for the

Americas. In this role, Webster

will facilitate implementing

and analysing polices across

the Americas with focus and

attention to consistency,

commonality and Employer of

Choice processes. Previously,

Webster was the Director

Human Resources for Haysite

Reinforced Plastics.

www.heubachcolor.com

We produce your new and universal tinting systems.Heubach has expanded its well-known universal HEUCOTINT™ UN tinting system range of water based, high performance pigment preparations to include four new tinting lines marketed under the trade names

> HEUCOTINT™ UN 41 series,> HEUCOTINT™ UN 42 series,> HEUCOTINT™ UN 43 series,> HEUCOTINT™ UN 44 series.

The sophisticated formulation technology has been further improved, resulting in a HEUCOTINT™ UN product family which allows the tinting of solvent-borne alkyd coatings up to silica plasters and is also compliant with the current regulatory requirements and environmental labels.

All of these colorant tinting systems are specifically designed for point-of-sale tinting (POS) as well as for in-plant applications (IPT).

NEW

10 PPCJ • June 2017www.coatingsgroup.com

LETTER FROM AMERICA

The Adhesive and Sealant Council

(ASC) comprises manufacturers

of adhesives and sealants and

industry raw material and equipment

suppliers, ranging in size from small,

privately held companies to multi-national

corporations. As a leader in the global

adhesive and sealant industry association

community, ASC’s mission is to deliver

career education, innovation collaboration,

community knowledge sharing and a

unified industry voice with an overall goal

of accelerating the adoption of adhesives

and sealants and, thus, strengthen its

members, businesses.

MEETING COMMUNITY KNOWLEDGE INTEGRATION

ASC publishes reports on the North

American and Asian adhesive and sealant

markets. Over the past 3.5 years, the

Council has also published more targeted

reports covering specific segments of the

adhesive and sealants industry in North

America. The three most recent reports

cover polyurethanes, hot melt adhesives and

waterborne adhesives.

In the North American Polyurethanes

Market Report, which was published in

early 2016, the ASC’s Global Resources

Committee (GRC) wanted to provide

a set of quantitative information on the

market environment for polyurethanes

in the coatings, adhesives, sealants and

elastomers (CASE) segments, as well as

detailed with qualitative information for this

key end-use market for adhesives and

sealants, according to Steve Duren, Senior

Director of Member Services with ASC.

The largest segment by weight in the

North American PU CASE market in 2014

was estimated by market research firm IAL,

which authored the report, to be coatings

(38%), followed closely by elastomers (33%)

and more distantly by adhesives (18%) and

sealants (11%). In dollar terms, coatings was

again the largest segment, accounting for

nearly half of sales in 2014 (49%), followed

by elastomers (25%), adhesives (15%) and

sealants (11%).

Key end-use applications covered

in the report include transportation,

building and construction, packaging and

assembly operations. Eighty interviews

were conducted with experts across the

PU supply chain, including raw material

suppliers, influencers and end users, to

determine likes, dislikes, unmet needs,

trends and market drivers and to obtain

their perspectives on the overall state of

the market. For instance, in transportation,

it was determined that sealants are largely

used by Tier 1 and Tier 2 suppliers but with

OEM approval. There is also limited use of

sealants, including polyurethanes, at OEM

plants. In passenger cars, demand for

sealants was estimated to be growing at a

CAGR of ~4%.

HOT MELT MARKET

The goal with ASC’s North America Hot

Melt Market Report, authored by The

ChemQuest Group and published in the

fourth quarter of 2016, also includes a

combination of quantitative and qualitative

information with more of an emphasis

on downstream qualitative interviews,

according to Duren. The report provides a

snapshot of unmet needs from end users,

outlines competitive bonding solutions,

such as ultrasonic welding with threat

assessments and key opportunities in

the fast moving consumer goods and

hygiene markets. Key end-use applications

covered in the report include paper board

and related products, transportation,

hygiene, woodworking and others (building

and construction, assembly operations,

footwear/leather and consumer/

DIY). The report also looks at different

channels to market, with a focus on the

important ‘Big Box’ channel and trends

manufacturers should be aware of that

address chemical policy, sustainability and

chemicals management.

Hot melt adhesives can be categorised

as bulk hot melts, reactive hot melts and

glue sticks and also by the chemistry of

the resins on which they are based. The

major technologies covered in the report

include ethylene vinyl acetate (EVA), styrene

block copolymer (SBC), polyolefin (PO),

polyurethane (PU), polyester (PES) and

polyamide (PA).

Notably, case and carton applications

accounted for 90% of hot melt adhesive

usage in North America in 2015 on a weight

basis. The second largest end use – paper

converting, accounted for just 6%, followed

by envelopes at 4%. Light-weighting in the

transportation segment is driving growing

interest in adhesives. Thermoplastics, in

addition to offering lower materials costs and

reduced weight compared to steel, most

aluminium and many thermosetting plastics,

also provide design flexibility. Modular

assembly and construction off-line is also

increasing, as a means for reducing costs

and improving quality and encouraging the

use of plastics. These substrates are driving

the use and selection of adhesives.

Some of the unmet market needs

identified in the report include issues with

hot melt buildup in hoses and nozzles and

undesirable odours. Sensory performance

was also noted, such as specific responses

to different touches of the finger for diaper

(nappy) applications.

The Water-Based Adhesives in North

America Market Report is the most recent

report from the ASC. This report was also

authored by ChemQuest and published in

April 2017. It provides a snapshot of unmet

needs from end users, policy and regulation

changes, competing technologies and key

� 14

Cynthia Challener looks at the Adhesives and Sealant Council’s efforts to

increase members’ businesses with innovation and career education

Expansion of

knowledge of adhesive

and sealant markets

When it comes to Adhesives & Sealants, our application experts support you with a wealth of market knowledge and depth in technical know-how. Our goal is to collaborate with you to develop solutions tailor-made to your needs – because your success is the measure of our know-how. Learn more about Evonik‘s Adhesive Resins at: www.evonik.com/designed-polymers

We design polymers with targeted know-how.Customized Adhesives & Sealants solutions for your bright ideas.

SECTION REPORTBUSINESS MATTERS

12 PPCJ • June 2017www.coatingsgroup.com

As is often the case around April,

when I am writing this, there are

many new market research titles

being published as the long window for

their research and preparation nears an

end after the start of the calendar year.

This time I am highlighting three contrasting

reports – necessarily briefly – in a whistle-

stop tour that gives insight into each.

ON CARBOXYMETHYL CELLULOSE

Looking at something from the raw

materials sector first, a new study, which

covers carboxymethyl cellulose may

interest raw material suppliers, which are

active across a breadth of raw material

intensive industries beyond paints

and coatings.

The preview material for this study is

less specific to paints and coatings as

‘our sector’ is one of an array of different

formulation-led end-uses. As the pie chart

shows, this is the sixth-largest end use

segment, occupying a middle place with

a host of other uses, such as cosmetics

and detergents.

In keeping with the desire for versatile

materials for modern formulation practices,

carboxymethyl cellulose is a multifunctional

product, which may be used to modify the

viscosity of complex chemical formulations,

while at the same time giving a smooth

texture in some areas of its product use.

Asia Pacific accounted for the largest

share at nearly 41% of the total market

volume in 2016. Furthermore, this region

is likely to witness the fastest market

growth during the forecast period, owing

to substantial consumption in the oil & gas,

pharmaceuticals, cosmetics and food &

beverage industries.

Europe turns out to be the second

largest region in the global industry. A

growing personal care products market

in key countries, including Germany, Italy,

France and UK, is expected to have a

positive impact on the industry over the

forecast period.

ON ADHESIVES

On the topic of Europe, a new Europe-

specific report on adhesives has recently

been published by the German research

firm, Ceresana. It covers vinyls, acrylics,

polyurethane, elastomers, epoxies and

other types of adhesives but excludes

sealants, cement, mortar, phenolic and

other formaldehyde condensates. Some

brief top-line figures from the report follow:

• In 2016, almost 3.2Mt of adhesives

were consumed in Europe, across

the 23 countries it covers (which also

extends to Russia and Turkey).

• The most important market for

adhesives in 2016 was the paper and

packaging sector; 29% of European

demand was generated in this

segment. The construction industry

was not too far behind in second

place, with its demand for adhesives

increasing considerably.

• The most significant class of adhesives

in 2016 was vinyls, which represented

a volume of 1.1Mt. The vinyl sector

includes PVA (polyvinyl alcohol) and

PVAC (polyvinyl acetate) and, thus, keys

in to material applications for porous

materials, such as paper, cardboard,

wood, cork and leather.

• Waterborne adhesives now comprise

about 53% of total European demand.

Demand for hot melts ranked a distant

second, followed by solventborne

adhesives and reactive adhesives.

The main consumers of vinyl adhesives

are the paper, packaging, wood processing

and construction industries that use

waterborne adhesives or hot melts,

in particular.

Market data on adhesives in the report

are given according to the following

individual technologies: waterborne

adhesives, hot melts, solventborne

adhesives, reactive adhesives and

other products.

ON PARTS OF AFRICA

The third report to highlight is in keeping

with dmg events’ East African Coatings

Congress, held this month and is a new

report from Frost & Sullivan, which covers

decorative paints in Kenya and Tanzania.

The company’s South African arm

announced the publication of a new

study entitled Decorative Paints and

Terry Knowles, this month, brings to our attention, three market reports recently released

Carboxymethyl cellulose, paints and adhesives

Global carboxymethyl cellulose market by end use, 2016 (%)

Source: Grand View Research. NB: Figures are approximate

PIGMENTS & DISPERSIONS FOR COATINGS

Strength through Experience

www.unioncolours.com

SECTION REPORT

14 PPCJ • June 2017www.coatingsgroup.com

BUSINESS MATTERS

Coatings Market for Kenya and Tanzania,

Forecast to 2020 as part of its industry

subscription programme.

The study finds that the total decorative

coatings market across these two countries

reached 66.2Mlit in 2015 and that this

is expected to reach 91.5Mlit by 2020

(that’s a whopping 38% increase in five

years). Crown Paints, Basco Paints and

Insignia reportedly dominate the market,

with Sadolin Paints and Goldstar Paints

trying to expand their shares. (Sadolin

Paints is one of the African companies,

which was recently acquired by Kansai

Paint. The group serves Kenya, Tanzania

and Uganda.)

Drivers in the market are noted as being

urban migration prompting residential

and commercial building, government

policies and a movement towards

cleaner technology.

These factors feed in to a combined

market, which is expected to grow at

6.7%/yr by 2020. Interestingly, solvent-

based decorative paints will still constitute

more than a third of the market by that

time, taking inexcess of 35% of the

decorative sector; water-based just

under 65%. Having said that, government

legislation on manufacturing processes

will drive reductions in both VOC and

lead emissions.

The importation of raw materials

in African countries is often a sticking

point and the same unhelpful scenario

arises again here. The vast majority of

the raw materials in these countries are

imported, so steady supply and access is

a considerable advantage for formulators.

Currency volatility translates into economic

vulnerability for those purchasing in the

Kenyan and Tanzanian Shilling. The lack

of local R&D and technology makes

for markets, which might attract large

companies with good R&D backbones that

can give them a competitive benefit in the

marketplace. Kansai Paint has clearly made

a shrewd move here.

“The Kenyan market outpaced the

Tanzanian market in 2015, primarily due to

its more suitably established manufacturing

industry and development of ports to

facilitate raw material imports”, said Frost

& Sullivan’s analyst, Ashley Arumero.

“On the other hand, the lower maturity

of the paint manufacturing industry in

Tanzania has eased the entry barriers for

potential participants.

“Despite the challenges of low raw

material availability and price fluctuations,

the markets are expected to grow

positively, due to rising urbanisation in

both Kenya and Tanzania”, noted Arumero.

“Additionally, the rising purchasing power

of the citizens is expanding the middle-

class demographic, which, in turn, is

creating a need for more residential and

commercial buildings – the main end users

of decorative paints and coatings.”

PPCJ

Author: Terry Knowles, Freelance Writer [email protected]

Carboxymethyl Cellulose Market Analysis By Application

(Cosmetics & Pharmaceuticals, Food & Beverages,

Oil & Gas, Paper & Board, Detergents), By Region and

Segment Forecasts, 2014 - 2025 was published by Grand

View Research in April 2017 and costs US$4950 for a

single user licence. For more information, email sales@

grandviewresearch.com

Adhesives – Europe (3rd Edition) was published by Ceresana

in March 2017. A basic copy of this costs €3000. For more

information on this title email [email protected]

Decorative Paints and Coatings Market for Kenya and

Tanzania, Forecast to 2020 has recently been published by

Frost & Sullivan and costs US$4950. For more information on

this title, browse https://store.frost.com

� 10 decisions that are driving material

selection, according to Duren. Chemistries

covered in the report include acrylic, natural,

bio-based resins, epoxies, polyurethane

dispersions (PUDs), polyvinyl acetate

(PVA), carboxylated styrene butadiene

(SBR), vinyl acetate acrylic (VAA) and vinyl

acetate ethylene (VAE). Opportunities in a

number of different end-use applications are

outlined, including in the paper board and

related products, building and construction,

transportation, woodworking, assembly

operation, footwear and leather and

consumer/DIY segments.

PRIMARY DRIVERS

The total value of the North American

water-based adhesives market in 2015

is estimated by ChemQuest to be nearly

US$3.65bn. Building and construction

is the largest end use, accounting for

37.5% of the market value, followed by

woodworking at 25.0% and paper, board

and related products at 18.2%. The other

segments all each account for less than

10% of the market value. Interestingly, by

volume woodworking accounts for slightly

more of the market value than building

and construction.

Of the different sectors, woodworking,

transportation and building and construction

are the primary drivers for growth in

demand for waterborne adhesives in North

America. Woodworking and transportation

applications are growing the fastest,

both with CAGRs of 4% but demand for

building and construction and consumer/

DIY segments waterborne adhesives in the

building and construction and consumer/

DIY segments is also experiencing

modest growth (3% CAGR). The highest

growth potential exists for woodworking

applications; water-based adhesives are

used in furniture and cabinets, as well

as in engineered and structural timber

applications. In the automotive industry,

trim and interior applications are important

because waterborne adhesives help achieve

a reduction in VOCs in the cabin air, they

more easily meet cradle-to-grave recycling

requirements and they can be applied using

existing equipment. PPCJ

Author: Cynthia A Challener, PhD, Principal Consultant, C & M Consulting1325 Center Road, Montpelier VT 05602, USA Tel: +1 802 613 3139 Email: [email protected]

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16 PPCJ • June 2017www.coatingsgroup.com

POWDER MATTERS

Hello Joe – I am new to powder coating but the plant where I work has been doing it for a few years. The guys

do a good job on single colours and are starting to experiment with multi colours. Is multi colour powder coating possible, if so, do you have any information that would help us? Thanks. Howard Satterfield,

A. Hello Howard – Thanks for the question.

One often overlooked characteristic of

powder coatings that set them apart from

liquid paint is that they are discreet fine

particles that typically stay that way when

they are sprayed. Unlike most liquid paints,

mixing two colours doesn’t result in an

intermediate colour but a blend of individual

particles. For example, mixing a red paint and

a yellow one of same technology will yield

an orange paint. With powder coatings you

get a unique speckled finish. So yes, powder

coatings can be mixed. There are many

scenarios to consider.

1. Physically blending two or more powders

will give you a speckled finish. By mixing an

orange, medium brown and a dark brown you

can simulate a rust patina. Blends of large

particle textured powder can give the effect

you see on roofing shingles. Mixing a light

teal green with a black powder will give you a

weathered copper look.

2. Some powders are blends of incompatible

materials and result in what are commonly

referred to as veins and ‘hammertone’

finishes. The veins comprise a dry blend of an

incompatible powder and a silver or bronze

pigment. Hammertones are blends of an

incompatible powder with another powder.

These are best formulated by the powder

manufacturer, however you can experiment with

blending various common powders with these

veins and hammertones to get interesting effects.

3. Metallics and pearlescents. The simplest

technique to create a metallic effect is to

blend an already made powder coating with

a metallic pigment. Aluminium flakes are

most commonly used but you can also try

bronze and stainless steel pigments to create

fascinating effects. Concentrations of 0.2 to

5.0% are typical. Pearlescents are specially

synthesised flakes that give a shimmering

effect. These can be incorporated just like

metallic pigments. Variations of pearls include

colour shifting flakes that appear as one

colour at a given viewing angle and another

colour at different angle.

4. Holographic effects. These are one of my

favourites. Microscopic flakes that possess

a prismatic effect can be added to powders.

Most dramatic effects are realised with darker,

more vibrant colours. These holographic flakes

are rather expensive but produce a rainbow of

colours as you change your viewing angle.

5. Applying dry powder on to another dry

powder. Gradient colour effects can be

achieved by applying one colour on part of

your target then covering the rest of it with

another colour. The intersection of the two

colours can be quite aesthetically pleasing.

Some people have come up with a way to

simulate wood grain by spraying multiple dry

layers of light and dark brown powders then

‘combing’ the finish before it sees the oven.

One thing to remember, dry-blends

of various powders yield a variable finish.

It is difficult to achieve the exact finish

repeatedly. Particle size differences between

powders and additives and electrostatic

variations in application will produce slightly

different looks. And reclaimed oversprayed

powder will certainly look significantly

different than the original blended powders.

Keep this in mind if you are trying to coat

large parts or long runs of parts.

I would encourage you to experiment

with the possibilities. The effects you can

create are endless and only limited by your

imagination. Let me know if you have any

further questions. Best regards, Joe Powder

Hello Joe – I’m in the powder coating business and I found your name while looking for the best way to dispose of unused powder. I just want to be sure we are up-to-date with the latest methods. Thank you for your help.Diane Stern, XYZ Finishing Co, USA

A. Hi Diane – Here’s what I think – I

owned and operated a powder coating

manufacturing company in Columbus,

Ohio for a few years. Occasionally we

would generate a small amount of unusable

powder. We would simply double-bag

it, place the bag in a heavy box or drum

and toss it into the dumpster destined for

the landfill. Here are a few very important

recommendations however:

1. You must be 100% certain that the

powder you are disposing of contains no

toxic materials. Consult the safety data

sheet (SDS) provided by your powder

supplier to ascertain this. Even better,

personally contact your supplier to ensure

there are no toxic materials present.

2. Secure the powder in a container that is

durable enough to withstand the pick-up,

transport and delivery into the land-fill.

Most waste haulers are concerned when a

package breaks creating a dusty plume.

3. Before you do anything, contact your

waste hauler. It is their job to know the local

and national regulations concerning the

acceptability of waste product disposal.

Local laws vary so my experience may not

apply to your location.

4. If your powder contains toxic materials

you should follow the guidelines for

disposal per the MSDS provided by

your powder supplier. This may involve

contracting a hazardous waste handler and

the high costs associated with using one.

For more information regarding

US regulations you can review 40-

CFR261 (code of federal regulations)

that cover solid wastes per the RCRA

(Resource Conservation and Recovery

Act). This is easily accessed on-line

at http://ecfr.gpoaccess.gov/cgi/t/

text/text-idx?c=ecfr&tpl=/ecfrbrowse/

Title40/40cfr261_main_02.tpl.

The vast majority of powder coatings are

non-toxic and safe to dispose of in a landfill.

But before doing anything, be prudent and

confirm this with your local authorities. Best

regards, Joe PPCJ

PPCJ ’s columnist, Joe Powder, provides answers to readers

questions on aspects of the powder coating process

Ask Joe Powder

QUALITY INVESTS.

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Ningbo Process® is a registered trademark of LANXESS Deutschland GmbH, registered in many countries of the world

18 PPCJ • June 2017www.coatingsgroup.com

PROTECTIVE COATINGS

The SpringHouse Country Market and

Restaurant has been a local icon

in the southwestern Pennsylvania

region for more than 40 years. In 1975,

Sam and Bev Minor, with five children

12 and under, started milking cows,

processing and bottling hormone-free milk,

and running the country store that is part

of today’s SpringHouse Country store,

creamery and eatery.

One of the more heavily used areas

of the building is the roughly 1000ft2

commercial bakery used daily to bake

a variety of pies, cakes and pastries.

Because of this daily use, the floor is

cleaned with a variety of disinfecting

chemicals like detergents and bleach. It

also experiences abrasion from wheeled

carts and shelves, and cleaning equipment.

The bakery floor had been covered

for years with a commercial sheet vinyl

applied directly to the concrete slab-on-

grade substrate. The owner’s main issue

was the failing of sheet vinyl in spots due

to the infiltration of water and cleaning

materials at the seams during the cleaning

process. Eventually, this required repairs

to the damaged seams in the sheet vinyl

by cutting out the section adjacent to the

failure and installing a new piece of vinyl.

The owner finally made the decision to

renovate the area, which would include new

wall coatings and a new floor option.

The owner reached out to a professional

flooring contractor, Seman Flooring,

to discuss renovation ideas that would

remediate the bakery area. One of the

primary requirements was a long-lasting,

durable flooring option that would hold up

to common contaminants from the baking

process, abrasion from foot and wheel

traffic, staining from spilt materials and

resistance to the cleaning process. Another

requirement was a surface with superior

cleanability that was seamless and would

resist dirt in order to minimise scrubbing.

The owner also wanted a good looking

floor since customers are able to see the

bakery area from multiple points in the

facility and aesthetics were important to

their brand.

However, the requirement that posed the

biggest challenge for the flooring contractor

was the need for the whole renovation

process to take place in a two-and-a-half-

day timeframe since the baked goods are a

significant revenue stream for the owners.

This meant the contractor would need

to remove the existing sheet vinyl, clean

and profile the underlying concrete, and

perform moisture vapour testing. Then, the

contractor would need to install a new floor

system, whether it would be another sheet

vinyl system or a high-performance coating

system, all in a span of about two days,

allowing for some time for curing, if needed

for a coating system.

After inspecting the area and taking

samples, the flooring contractor suggested

removing the existing sheet vinyl and

replacing it with a multiple-layer, high-

performance floor coating system. After

careful consideration and managing all

the owner’s expectations, the flooring

contractor determined a resinous floor

coating system incorporating a polyaspartic

coating technology would meet the

requirements. This solution would address

long-term durability, abrasion resistance,

seamless design and aesthetics, as well

as enable the contractor to meet the

stringent return to service requirements

that the owner sought. This recommended

The ingress of water and cleaning materials caused defects to appear in a bakery floor and the decision was made to

replace the existing floor with a high peformance floor coating system as Steven Reinstadtler, Covestro LLC, discusses

How a polyaspartic coating made a bakery floor look sweet

Small cracks in the bakery floor were

repaired with a fast-curing epoxy mortar

The floor coating system features rolled

on beige pigmented ultra-low VOC

polyaspartic basecoat

Measure 4 Bresle equivalent readings, in less than 3 minutes, with the Elcometer 130 SSP

Complies withNSI 009-32

Bresle EquivalentISO 8502-9 Test Method

CLEANLINESS

Meas

ure

· FA

ST ·

REPEATABLE ·

ACCURATE · D

URAB

LE

SURFACE

19 PPCJ - June 2017 www.coatingsgroup.com

20 PPCJ • June 2017www.coatingsgroup.com

PROTECTIVE COATINGS

floor coating system would also eliminate

future sheet bonding problems and offer

easier maintenance.

POLYASPARTIC COATINGS TECHNOLOGY OVERVIEW

Polyaspartic coatings were invented in

the 1980s and used for more than 25

years in high-performance, industrial

protective applications, such as bridge,

water and wastewater infrastructure,

and transportation. These types of

coatings also have proven performance in

commercial and architectural applications

due to end users’ desires to protect

their architectural infrastructure, while

maintaining a high degree of aesthetics and

beauty. Commercial and decorative flooring

is one area where polyaspartic coatings

have successfully addressed the industry’s

key unmet needs.

Whether for residential garage floors or

game rooms, or commercial applications,

such as hotel lobbies, cafeterias or retail

spaces, polyaspartic coatings provide

durable, aesthetically pleasing floor finishes

with minimal downtime and faster return to

service that meet contractors’ and end users’

needs. For multiple points in the value chain,

polyaspartic coating technology attributes are

a good match for these unmet needs.

Polyaspartics are in a class of polymers

called polyureas. Typical polyureas that

one may be familiar with are thick film,

fast-reacting, flexible, spray-applied

systems similar to a spray-in truck bedliner.

However, while a polyurea, polyaspartics

are very different than the typical polyurea

coating. They are a two-component system

consisting of:

• Polyaspartic resin blend, which is a

blend of resins, additives and possibly

a pigment

• Aliphatic hardener, which is typically

provided as-is or with a small amount of

thinning solvent for a low-VOC system

Unlike typical polyureas, polyaspartic

technology usually has a fairly high

hardness, a property preferred for floor

coatings to resist scratches, scrapes and

chips. Polyaspartics are also applied at a

thinner film thickness, typically in the 5-20

mils range suitable for flooring topcoats.

Polyaspartics are based on aliphatic

hardeners, which impart excellent long-

term colour and gloss retention and are

most often used as a topcoat due to their

non-yellowing properties. In addition, they

can be formulated to cure slow enough to

apply using conventional manual coating

methods rather than high-pressure

spray equipment.

The chemistry of polyaspartic coatings

has a unique, adjustable reactivity with the

capability for fast curing that offers high-gloss

retention and excellent abrasion resistance.

Traditional two-component aliphatic

polyurethanes, the bastion of durability,

typically cure enough to accept light foot

traffic within six to 12hr, whereas polyaspartic

coatings typically cure in one to four hours.

This ultra-low VOC to 100% solids coating

technology allows formulators the flexibility

to control the rate of reaction and cure by a

combination of fast and slow resins rather

than the use of heavy metal catalysts.

Polyaspartic coatings can be applied at

temperatures below 50°F, which extends

the application season for commercial and

residential projects. These coatings can be

applied by simple brush and roller and do

not require special application equipment.

PLANNING AND EXECUTION - THE RECIPE FOR SUCCESS

When the SpringHouse bakery was built

40 years ago, the floor was constructed as

slab-on-grade with no vapour mitigation

membrane. More recently, the bakery floor

was covered with a commercial vinyl sheet

adhered directly to the concrete using a

latex-based adhesive and heat welded

seams. Due to a flood, heat from the ovens

as well as daily cleaning and wear, the floor

needed repairs several times during its

lifecycle. This was accomplished by cutting

out the affected vinyl sheet area or seam

and gluing in a patch of vinyl sheet cut

to size.

Once the surface preparation, surface

profile, desired coating system and timeline

was agreed upon, flooring contractor

Seman Flooring got to work. The contractor

used a power scraper to remove most of

the existing sheet vinyl and adhesive. The

remaining adhesive was removed using

scrapers and solvent as needed. The

floor was then cleaned thoroughly with a

commercial degreaser to remove years

of contamination that crept underneath

the seams and into the porous concrete

surface. Following the cleaning step,

the floor was prepared with a planetary

grinder with 1820 grit diamonds. This

left the final surface with a profile of ICRI

CSP 3 and removed any small amounts

of residual adhesive. Finally, the surface

was vacuumed clean. By first cleaning and

then grinding the floor, the contaminants

were not ground into the substrate, which

can affect long-term adhesion of the

coating system.

The inspection revealed some smaller

cracks in the floor that needed repair. Since

they were relatively small, the contractor

chased them with a fast curing epoxy

mortar sanded similar to the concrete.

The next steps involved the application

of the floor coating system. Due to the

slab-on-grade concrete substrate and past

water issues, a clear vapour mitigation

epoxy layer was first applied at 12 to

15 wet mils using a squeegee and then

back rolled. The vapour mitigation layer

cured overnight. Next, a beige pigmented

ultra-low VOC polyaspartic basecoat

was applied at 15 mils thickness. During

the application of the polyaspartic

coating, the contractor wore a long-

sleeve shirt and pants, closed toe work

shoes, safety glasses, a respirator and

appropriate gloves. When following the

recommendations on the supplier’s safety

data sheet (SDS), these products can be

used and applied safely by professional

contractors. The specific types of personal

protective equipment needed will vary

based on the raw materials and method

of application. Refer to the supplier’s SDS

for additional information Colour chips in a

five-colour blend were broadcast into the

wet basecoat to create a finished, high-

end terrazzo look. Every contractor has a

technique for evenly applying these colour

chips and the process is affectionately

referred to as ‘feeding the chickens’. Once

the basecoat cured sufficiently, �23

The finished floor provides visual appeal, while being able to

handle the daily demands of a bakery

Sponsored by: Organised by:

NEW FROM THE COATINGS GROUP

29 – 31 May 2018Sandton Convention Centre, South Africa

Innovation and education for success

www.coatingsgroup.com

PROTECTIVE COATINGS

22 PPCJ • June 2017www.coatingsgroup.com

There are pressures facing any

industry and while some remain

constant, others arise in response

to changing environments and external

pressures. For coatings formulators,

keeping cost low is an issue that has long

been, and will remain, a key consideration,

while the introduction of new legislations

from 2018 are bringing compliance with

VOC regulations, REACH and product

safety to the fore.

This year’s European Coatings Show

saw Huntsman Advanced Materials, a

division of Huntsman Corporation, launch

a new portfolio of low temperature curing

agents specifically designed with these

issues in mind. The Ara Cool range

offers faster curing at low temperatures,

excellent surface appearance and adhesion

properties, helping reduce the whole-life

cost of a project. In addition, its reduced

VOC levels and unique features ensure

new legislations are met. Dr Martin Gerlitz,

Marketing Manager at Huntsman Advanced

Materials, explains more about the

range and the development process that

took place.

WHAT LED TO THE DEVELOPMENT OF ARA COOL?

Feedback from customers made it clear

there was a need for a product that offered

fast cure at low temperatures but that any

new developments also needed to help our

customers overcome the issues they were

facing around lowering costs and meeting

new regulations.

Recent years have seen a shift in

understanding that the whole life cost of

a project and the entire coatings process

need to be considered; it is no longer a

case of price per kilogram. When you

look at cost in this way, it becomes clear

that efficiency gain or improving output

per hour have a much bigger impact than

reducing the cost of formulation. For

example, the benefits of a range that offers

high reactivity and fast drying properties

can in turn:

• Save man hours in application and, in

turn, reduce applicator costs, thanks to

faster drying and recoatability;

• Increase throughput of assembling

lines, due to coated objects being able

to be taken out of a climate (and/or)

heated chamber in a faster way;

• Save energy and cost through

decreased temperatures in

drying ovens.

Once we’d established that there were

tangible benefits to developing the range,

we then agreed that any new product must

sit in line with regulatory requirements for

low temperature cure applications, as well

as meet regulations being introduced in

2018 and beyond.

WHAT WAS THE DEVELOPMENT PROCESS?

There are several other products on the

market that offer either long pot life, low

temperature curing or low VOC levels but

none offered all three. Our first step was to

compare the chemistries of the available

curatives to see which was most suited to

the product we wanted to create.

Our findings showed a variety of results.

While surface tolerant RPAA represent the

industry benchmark in terms of adhesion,

they will not cure in temperatures below

15°C. Modified phenalkamines, on the

other hand, which are considered a

Mannich-Base type hardener, offer better

cure performance at temperatures between

8-15°C, however, there are several negative

aspects including strong discolouration,

significant levels of residual volatiles amines

and potential intercoat adhesion problems.

Adduct hardeners in organic solvents

resulted in fast dust and tack free times

even at low temperatures but exhibited

extremely high viscosities and so needed a

lot of solvent in the formulations to achieve

the right application viscosity. This means

they would never be able to fulfil VOC

requirements below 350g/l.

It became clear that to get close

to fast curing at low temperature with

existing solutions, strong compromises

were required on at least one of the

following parameters:

• Anticorrosion performance

(brittleness, adhesion)

• Pot life (requiring twin-feed

application equipment)

• VOC content

• Product safety (SVHC, content on

volatile amines)

Because of this, we determined that

neither RPAAs, modified phenalkamines

or adduct hardeners would be suitable.

However, initial trials revealed that

Mannich-Base type chemistry was

best placed to achieve our desired cure

profile, thanks to its ability to cure at a

temperature range of 0-10°C.

The development of a portfolio of low temperature curing agents by Huntsman

Advanced Materials, offers faster curing at low temperatures

Bridging long pot life with fast cure at low temperature

Salt spray test results after 1008hr on sand

blasted steel. Ara Cool 1034 XW 90 cured at

5°C in combination with Araldite GZ290X90

PROTECTIVE COATINGS

23 PPCJ • June 2017www.coatingsgroup.com

Once this had been established, we then

moved on to developing and testing several

different chemical approaches using

Mannich Bases. We continued testing until

we came up with a range of curatives that

fit the product profile we wanted.

WHAT’S THE DIFFERENCE BETWEEN THE PRODUCTS?

All three of the Ara Cool products feature

faster curing at low temperatures and

reduced VOC levels, in addition to excellent

surface adhesion and adhesion properties.

However, there are slight differences

between them, which allow a wider range

of industry requirements to be met.

Ara Cool 3077 is a zero-VOC

multipurpose low temperature curing

hardener, formulated amine benzyl alcohol

and SVHC free. It has been designed to

deliver superior reactivity at temperatures

as low as 5°C and can be used either as

the sole curing agent or a co-accelerator

for slow hardeners. it is the least viscous of

the three, despite its zero-solvent content.

Ara Cool 1047 W 80 is a surface

tolerant low temperature curing hardener

for metallic surfaces, which offers at least

the same anticorrosion performance as

best in class competitive technology. It

provides excellent corrosion protection

for critical substrates that require fast

hardness development at 5°C or less and

offers superior surface appearance and

excellent adhesion, even under humid or

cold conditions. It contains less than 20%

solvent and is suitable for use in solvent-

containing formulations.

Ara Cool 1034 XW 90 is a modified

Mannich-Base type ultra-high solid

hardener for pre-treated steel surfaces.

With a slightly higher viscosity, it boasts an

extremely long pot life and has outstanding

low temperature reactivity. SVHC-free

product has a solvent content of less than

10%, so is extremely low VOC.

HOW DOES ARA COOL COMPARE TO EXISTING CHEMISTRIES?

During the testing process, we looked

at various attributes for each individual

chemistry, including curing speed at 5°C,

anti-corrosion performance, VOC levels,

pot life and compliance with EHS and

regulatory. The results can be seen in

figure 1, which clearly shows how the Ara

Cool range is the only solution that enables

all attributes to be met.

WHAT ARE THE BENEFITS OF THE PRODUCTS?

The overarching benefit of the range is its

ability to provide fast cure speeds at low

temperatures, enabling our customers to

enter markets with adverse conditions. This

not only extends the application window in

cold seasons, allowing applicators and end

users to work more efficiently but avoids

breaks in the applications schedule due

to unpredictable weather and reduces the

risk of complaints due to very robust curing

features. Furthermore, its long pot life

saves time and overall project expenditure,

while the low VOC levels across the range

enable compliant applications in harsh

climate regions and provide our customers

with reassurance that the products are

future-proofed to meet new regulations

beyond 2018.

HOW WILL THE RANGE BE EXPANDED?

We will continue to expand the Ara Cool

range in the future, using customer

feedback to ensure we’re responding to their

needs and developing products that offer

clear benefits for formulators and end users,

especially in very critical applications. PPCJ

Contact: http://huntsman-aracool.com/ Email: [email protected]

Curing at 5°C

Anti-corrosion performance

Low VOC Pot life EHS/ regulatory

Ara Cool 1047 W 80 1 1 2 2-3 2-3

Ara Cool 1034 XW 90

1 2-3 1-2 1 3

Ara Cool 3077 1 4 1 4-5 3

Surface tolerant RPAAs

5 1 2-3 2-3 3

Adduct hardeners in organic solvents

1 phys.

4 chem.

2-3 5 1 4

Modified phenalkamines

2-3 2-3 2-3 2-3 3

Mannich bases 1 4-5 1-3 4-5 3-5

Fig 1. Rating: 1 = Excellent 2 = Good 3= OK 4= Acceptable 5= Not suitable

Ara Cool is Huntsman’s registered trademark

� 20 about 90min due to the fast return-

to-service properties of the polyaspartic

coating, the excess colour chips were

vacuumed up. After the base coat was cured

for an additional 30min, two thin layers of a

clear ultra-low VOC polyaspartic topcoat, the

proverbial icing on the cake, were applied at

6-8mils thickness using a 3/8in nap roller.

Polyaspartic coatings are water clear,

which results in an eye-catching colour pop

over colour chip or decorative stained floor

systems. Two thin coats were applied to

ensure the roughness of the colour chips

was not lost since this texture imparts non-

slip characteristics to the floor surface.

SWEET SUCCESS

The finished floor was put back into service

the morning after completion, meeting the

owner’s tight two-and-a-half-day timeline

from start to finish. The end result is a

seamless floor with a visually appealing

finish able to handle the daily demands of a

commercial bakery. The new floor provides

a joint-free, tight surface that is much easier

for employees to clean. Compared to other

floor coating systems, the polyaspartic

coatings provided a fast return-to-service

time and allowed the bakery to reopen

quickly so the owner did not have to lose

revenue due to an extended shutdown. The

floor can withstand equipment, wheeled

traffic and frequent cleaning without

significant wear and tear. It offers a great

balance of abrasion, chemical and scratch

resistance, while providing excellent long-

term colour and gloss retention. For this

project, the polyaspartic coating was the

icing on the cake. PPCJ

Author: Steven Reinstadtler is the Construction Market Manager for coatings, adhesives and sealants - CAS Business Unit of Covestro LLC in Pittsburgh. Steven works closely with contractors, companies and organisations that build infrastructure with durability and sustainability in mind, by educating the market on high-performance coatings and sealant options. He has been with Covestro for more than 28 years in technical and marketing management positions. Steven holds a degree in chemistry with a polymer science option from the University of Pittsburgh and is an active member of professional societies, such as AIA, CSI, ACS, SSPC, CPI, ACA, ESWP and PDA Email: [email protected]: www.covestro.com

24 PPCJ • June 2017www.coatingsgroup.com

EXTENDERS & FILLERS

The ability to achieve a decorative

appearance is one of the most

sought-after and demanded

characteristics of modern interior

paints. Conventional, mostly low-gloss

interior emulsion paints often have the

disadvantage of having insuffi cient

resistance to staining, since liquid stains

are easily absorbed into the surface due

to the high and often supercritical pigment

volume concentration and are, therefore,

diffi cult to remove.

As a result, reduced liquid and stain

absorbency in the coating is a desirable

quality for cleanable paints. This can be

achieved by setting a suitably subcritical

pigment volume concentration, which

enables more homogeneous fi lm formation

and sealed, less absorbent coating fi lms. In

addition, the sensitivity to staining can be

reduced by using hydrophobic or oleophobic

additive components in the formulation.

Low-gloss, cleanable coatings must

also have sufficient durability and wet-

scrub resistance in order to ensure

residue-free stain removal without

removing the paint as well. In these

kinds of paints, coarser and relatively

hard fillers can help achieve better wear

resistance in addition to the matting

effect. Depending on the extent of

mechanical cleaning, this is intended

to counteract excessive paint removal,

while also preventing changes to the

surface’s visual appearance, such as

streaking or polishing.

This study builds on the principles of

protection that have already been outlined.

However, its primary aim is not just to

achieve mechanical stability in the surface

coating but also to imbue the surface with

improved resistance to staining in the fi rst

place through the use of suitable fi llers,

in order to keep the amount of cleaning

required to a minimum.

With this in mind, is further optimisation

possible with selected functional fi llers, such

as Neuburg Siliceous Earth, in order to achieve

surfaces that are easier to clean and can repel

dirt with greater resistance to staining?

The report examines this question

in detail and takes into account other

important characteristics of decorative

interior coatings, which have also been

tested as part of the investigation.

EXPERIMENTALBasic formulation and variationsThis guide formulation of a low-gloss

interior emulsion paint combines an

environmentally friendly, low-VOC

formulation with more modern binder

technology specifi cally optimised for

cleanability based on the solvent-free pure

acrylic binder Acronal PLUS 6282 from

BASF (see fi gure 1).

The reduced pigment volume

concentration relative to conventional

paints is approx 41% and the solids content

of the formulation with 5% water dilution is

at around 60%. In addition to a high level

of white pigment, the formulation contains

16.6% fi ller, the composition of which is

varied as described later.

The guide formulation (control) contains

a three-part combination of fi llers as

indicated in fi gure 2. The diatomaceous

earth is used preferably as a very coarse

matting agent in order to enable

lustre in the dull matte area. Both

types of syenite, which are present in

varying proportions by weight, exhibit

incrementally greater fi neness, as well as

signifi cantly lower oil absorptions than

the diatomaceous earth.

In the following formulation variations,

the entire fi ller package, with an average

oil absorption of 44g/100g, is replaced

with a single variant of the Neuburg

Siliceous Earth with approximately

equivalent oil consumption.

After conducting extensive preliminary

testing, the standard product Aktisil MAM

and a newly developed test product were

selected for this purpose. Aktisil MAM

exhibits a fi neness and particle size similar

to the fi ne nepheline syenite, as well as

an additional surface treatment with a

methacrylate silane. The test product

without a surface treatment is noticeably

coarser between both types of syenite.

Preparation, application, and testingThe formulations were prepared using the

laboratory dissolver under cooling with

water. White pigment and fi llers were mixed

in advance and added to the preparation

before being dispersed. After adding the

binder and the other additives, a maturation

time of 12hr was observed.

The coatings were then diluted with

5% deionised water before normally being

applied to black Leneta fi lm and contrast

cardboard. The drying and conditioning

of the paint fi lms and the testing, after 28

days, were performed in an air-conditioned

laboratory at 23°C and 50% air humidity.

For more detailed information, see fi gures 3 and 4.

RESULTSApplication characteristics and storage stabilityDuring formulation preparation, Aktisil

MAM and the test product achieve

proportionately fast and foam-free

incorporation, similar to the control, thanks

to generally good dispersion behaviour in

aqueous media.

The dispersity of the complete interior

emulsion paints refl ects the varying

Low gloss, cleanable interior emulsion paints are studied by Bodo Essen and Hubert Oggermüller, Hoffmann

Mineral, who examine the principles of protection and characteristics of decorative interior coatings

Optimisation of stain resistance through Neuburg Siliceous Earth

Fig 1. Formulation Fig 2. Fillers

25 PPCJ • June 2017www.coatingsgroup.com

EXTENDERS & FILLERS

fi neness of the fi llers used. According

to grindometer measurements, the

dispersity in the control was increased at

35-40μm, already noticeably reduced at

10-15μm with the test product TP 2015084

and at less than 10μm with the Aktisil

MAM formulation.

The rheology profi le exhibits shear

thinning, which is typical of interior

emulsion paints, whereas the signifi cantly

reduced viscosity from 0.20 to 0.40Pa s

under higher shear stress (1000s-1) enables

easy workability and spreadability. High

viscosity values from 170–250 Pa s at low

shear stress (0.1s-1) cause low sagging

tendency after application and provide the

fi lm layer thicknesses required for good

surface coverage.

All formulations exhibit very good

storage stability properties after three

months at 23°C or after 42 days at

38°C, without phase separation or

deposit characteristics.

CleanabilityTesting methodTo determine cleanability, the formulation

variants were applied to black Leneta

fi lm with a suffi cient layer thickness and

conditioned for 28 days.

As the example in fi gure 5 shows, the

staining defi ned in terms of quantity and

area was then caused by coloured and

predominantly fl uid substances that are

common in households. Once the varying

exposure time had elapsed, the fi lm surface

was simply wiped down repeatedly with a

damp cloth, as an initial cleaning step.

In the second step, the standardised

mechanical cleaning process was

performed using an abrasive pad soaked

in cleaning agent on an abrasion tester in

order to remove further staining. Finally, the

wiped-off exterior and the scrubbed middle

area were assessed colorimetrically after

24hr of drying.

The colour shift delta E* compared with

the unsoiled surface describes the level of

staining left behind quantitatively. The lower

the values, the better the cleanability.

Cleanability after short exposure timeThe following models contain the

quantitative results of the colorimetric

analysis. Each test substance specifi cally

tends towards different levels of

discolouration, which can be observed

after just 5min of exposure and wiping off

with a damp cloth. In order to account for

these circumstances as a whole, the colour

shifts of all test substances in fi gure 6 are

each consolidated into an average value for

an overall assessment.

The improved resistance of the

formulation with Aktisil MAM to stain

formation manifests in considerably lower

delta E* values, when compared to the

control, whereas the staining can be

reduced by half in the average value.

Through the more intense cleaning by

means of abrasion with a cleaning agent,

the staining can be reduced further in

both formulation variations, which results

in disproportionately positive results in

the formulation with Aktisil MAM. Through

the use of Aktisil MAM, even critical

staining from black tea, coffee or beetroot

juice, for example, can be removed

almost completely, provided cleaning is

performed promptly.

As per Aktisil MAM, use of the test

product leads to improved resistance to

stains. The individual test substances are

visibly more amenable to removal overall

than in the control, as observed in fi gure 7. This, therefore, indicates optimised

cleanability of the surface, which is also

supported by the average values of the

colour shift.

Cleanability after prolonged exposure timeProlonged exposure to the staining media

generally has a very adverse effect on

subsequent cleaning attempts (fi gure 8).

In the control formulation with

diatomaceous earth and syenite, removal

of the discoloured stain is only minimal. The

colour shifts measured are, therefore, at

a very high level, with the exception of the

test involving ketchup.

The high performance values of Aktisil

MAM meant that it is visually the more

effective solution. In view of the results

produced, when the exposure time of

stains was only brief, the protective effect

is even clearer when compared to the

control. Even as early as the damp cloth

wipe-off stage, it becomes clear from the

signifi cantly reduced delta E* values that

the staining resistance can be noticeably

increased by varying the fi ller and using

Neuburg Siliceous Earth alone.

One particular result to note is the lower

average colour shift achieved with Aktisil

MAM, bordered in red. Similarly positive

results were nowhere near being achieved

with the control fi llers, even when using a

cleaning agent and an abrasive pad. The

colour values in the right-hand diagram in

fi gure 8 indicate an even higher average

residual staining, even after the more

intense cleaning. The disadvantages

for competitor fi llers and, as it were,

Fig 3. Preparation & Testing (1)

Fig 6. Cleanability 5min stain exposure

Aktisil MAM vs control

Fig 4. Preparation & Testing (2)

Fig 7. Cleanability 5min stain exposure

TP 2015084 vs control

Fig 5. Testing cleanability

Fig 8. Cleanability 2hr stain exposure

Aktisil MAM vs control

26 PPCJ • June 2017www.coatingsgroup.com

EXTENDERS & FILLERS

the advantages for the Siliceous Earth,

become more clear when the formulation

with Aktisil MAM is also subjected to a

similar cleaning step.

The results demonstrate that Aktisil

MAM actively counteracts penetration

of the stain into the paint layer, thanks

to its special properties and that

subsequent cleaning processes can

be performed, not only more effectively

but also, occasionally, be carried out

under milder conditions. Even with more

intense cleaning, residual staining can

be eliminated more easily and 70% more

effectively relative to the control, as

indicated by the very low delta E* values of

the wet-scrubbed sample.

The test product TP 2015084 exhibits

slightly reduced effectiveness compared

to Aktisil MAM, something which can

be traced back to the absence of a

corresponding surface treatment. Even

more astonishing is that better cleanability

of the surface is nonetheless achieved in

all individual tests relative to the control,

as demonstrated in fi gure 9. After wet

scrubbing on the abrasion tester, this

advantage also remains in effect for the

test product when the coloured residues

are reduced.

Visual appearance of cleaned coatingsFigure 10 focuses on the abraded

middle section of the coating fi lms, which

is shown here separately and visually

spread out. The diagrams underscore the

cleanable nature of this emulsion paint. The

overwhelming majority of applied stains can

be removed relatively easily and effectively,

provided cleaning attempts are made within

the fi rst few minutes. But even in this early

stage, the effectiveness of both types of

siliceous earth relative to the control can

be observed. Almost complete removal of

stains can be achieved particularly through

the use of Aktisil MAM.

Prolonging the stain exposure time,

however, will have a noticeably negative

impact on cleaning options. Only ketchup is

easy to remove in all formulation variations.

With regard to the control formulation,

all other test media lead to visible stain

formation. Replacing the competitor

fi llers with the test product, improves its

characteristics. Stain formation is reduced

and cleanability is optimised. Aktisil MAM

delivers by far the best visual result.

Signifi cantly reduced stains demonstrate a

high level of resistance to soiling, even to

those test substances, which are seen as

the most drastic stains, such as black tea

and coffee.

In fi gure 11 there is also visual

confi rmation that coatings, with both

types of Neuburg Siliceous Earth, can

be cleaned more effectively by means of

simply wiping off with a damp cloth than

is possible with the control formulation,

even when subjected to intense abrasion

with a cleaning agent. When using the

test product and Aktisil MAM in particular,

annoying stains can be reduced or even

removed more effectively and gently

without the need for wet scrubbing

the surface.

Wet-scrub resistance

Assessing the effects of fi llers on

cleanability requires identical mechanical

resistance of the coating surfaces during

the cleaning process. If this condition is

not met, good properties can theoretically

only be simulated by means of excessive

removal of material and staining during

wet scrubbing (see, for example, fi lm

application in fi gure 12, with heavily

reduced discolouration from red wine after

abrasion of a fi lm with relatively poor wet-

scrub resistance).

The test was performed in accordance

with ISO 11998 using unstained coating

strips, after which the effective layer

thickness loss was measured after 200

cycles. The test produced values that are

still in the range of the best wet-scrub class

1, in accordance with EN 13300, for the

control formulation with 4-5μm removal.

Through the use of the Aktisil MAM

Neuburg Siliceous Earth, good mechanical

strength can be optimised further and can

achieve the lowest wet-scrub abrasion and

the highest durability levels with the test

product TP 2015084 below 3μm.

Combined cleanability / wet-

scrub resistance rating

Once the wet-scrub resistances have been

determined, the performance of the tested

fi ller variations can be evaluated objectively

and graphically represented in accordance

with fi gure 13.

The point of origin represents the goal of

optimal cleanability, with complete removal

of the stain without compromising the

layer thickness.

After prolonged exposure to the test

substances, the control formulation exhibits

noticeable staining and high delta E*

values. At the same time, the mechanical

resistance permits classifi cation still within

the best wet-scrub class 1.

The types of siliceous earth each

have signifi cant advantages with regard

to both testing criteria. The advantage

in terms of cleanability is primarily the

signifi cantly lower residual staining from

using Aktisil MAM, owing to its higher

staining resistance, whereas the gain for

the test product is due, to a large extent,

to the higher resilience when subjected to

wet scrubbing.

Using the selected types of Neuburg

Siliceous Earth causes a considerable

improvement in overall effectiveness. Staining

resistance and cleanability of the present

formulation are optimised signifi cantly.

Stubborn stains, as a result of prolonged

exposure or highly critical substances, can be

reduced or even avoided completely. In the

case of more intense mechanical cleaning,

both siliceous earth variants meet the most

Fig 9. Cleanability 2hr stain exposure

TP 2015084 vs control

Fig 10. Cleanability appearance wet-

scrubbed area

Fig 11. Cleanability of control wet-scrubbed

vs Aktisil and TP wiped off

Fig 12. Wet-scrub loss

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28 PPCJ • June 2017www.coatingsgroup.com

EXTENDERS & FILLERS

pertinent requirements, thanks to their

improved wet-scrub resistance.

The initial question on whether there

were further options for optimisation of

cleanability can, therefore, be answered

with a clear yes if either of these outlined

types of siliceous earth is used.

Other characteristics for the overall evaluation

In order to assess the potential of the

Neuburg Siliceous Earth more exactly,

other properties were examined, which

are important for the visual appearance

of cleanable emulsion paints. The

results are presented with previous

data in figure 14 in the form of a

summarised comparison.

With regard to the gloss, Aktisil MAM

produces a slightly higher level with

matte gloss gradations in comparison to

competitor fi llers. The test product exhibits

a signifi cantly more prominent matting

effect, which nevertheless, was still below

the level achieved by the control.

‘Dry burnish’ refers to the visual

polishing by means of dry, mechanical

friction of the coating surface. Owing

to frequent friction with textiles or other

objects, some areas may appear glossier

than others, thus, compromising the

homogeneous look of the wall surface.

In all variants, only a low absolute gloss

increase was found during testing and

this level is practically unnoticeable in

terms of overall appearance. Use of Aktisil

MAM leads to the gloss increase being

slightly higher, albeit starting from a higher

value. Despite its slightly lower starting

gloss, the test product achieves a similar

level of resistance to polishing to the

control formulation.

Both variations of the Neuburg Siliceous

Earth offer high brightness values and

extraordinarily good hiding power with

regard to visual requirements. This improves

the spreading rate of the formulation with

Aktisil MAM by almost 25%. Even the

coarser test product 2015084 achieves an

increase of more than 10%.

Cleanability when varying the binder

The effects of Neuburg Siliceous Earth can

also be proven in other binders. To this end,

the original binder was replaced by Acronal

ECO 6270 from BASF, which exhibits the

following properties:

• Environmentally friendly pure acrylic binder

• Widely used in high-quality interior and

exterior paints

• Similar physical characteristics

• Component of interior paints that

have already been internally tested

and that have used the calcined

Neuburg Siliceous Earth for partial TiO2

substitution to positive effect.

The binder was substituted using the

same weights and with approximately

the same level of pigment volume

concentration and solids. All other

components remain unchanged in the

formulation. Figure 15 illustrates the results

of the cleanability evaluation.

By varying the binder used, the good

cleanability of the formulation is only

marginally reduced. In these results as

well, black tea, coffee and red beetroot,

are found to be critical staining media,

which can, nonetheless, still be removed

easily, provided the exposure time

was short.

In both short and prolonged exposure

to the test substance, Aktisil MAM

confi rms the previous results showing very

good staining resistance and optimised

cleanability. The test product 2015084

is still classifi ed visibly above the control

formulation with diatomaceous earth and

syenite in terms of performance, which

underscores its effectiveness in spite of the

lack of surface treatment.

Further investigations into wet scrubbing

and visual characteristics attest to the

particular effectiveness of both types of

Neuburg Siliceous Earth and confi rm the

transferability of the positive effects to other

binders as well.

SUMMARYCompared to the diatomaceous earth and

nepheline syenite control fi llers, Neuburg

Siliceous Earth exhibits better performance

for cleanable, low-gloss interior

emulsion paints, preserving application

characteristics and storage stability:

With Aktisil MAM• Superior staining resistance and

signifi cantly lower soiling;

• Optimised wet-scrub resistance;

• Low gloss;

With TP 2015084• Improved staining resistance;

• Further improvement in wet-

scrub resistance;

• Excellent resistance to polishing;

• Outstanding matting effect.

With both types• Lighter and gentle stain removal, even

with just wiping off with a damp cloth;

• Improved hiding power and optimised

spreading rate with high brightness;

• Formulation with just one single fi ller;

can nonetheless, be combined freely

with other fi llers;

• Transferability of effectiveness to other

binders or formulations;

This characteristics profi le offers the

following advantages for the user:

• Reduced soiling, lower cleaning

requirements and very good

mechanical durability for the

preservation of clean surfaces with a

longer service life;

• A low gloss level can be set without the

need for an additional matting agent;

• More cost-effective formulation thanks

to visibly higher spreading rates at

low consumption;

• Improved and highly balanced

characteristics profi le based on a

single fi ller.

PPCJ

Contact: Dr Alexander Risch is Director Sales & Marketing with Hoff mann Mineral and responsible for the sales of Neuburg Siliceous Earth worldwide. Tel: +49 (0) 8431 53 260Email: alexander.risch@hoff mann-mineral.comWebsite: www.hoff mann-mineral.com Hubert Oggermüller is Hoff mann Mineral’s Manager of Application Technology and Bodo Essen works in his department in the fi eld of coatings.

Fig 13. Staining vs wet-scrub loss

Fig 14. Performance overviewFig 15. Cleanability with Acronal ECO 6270

appearance wet-scrubbed area

FEICA European Adhesive & Sealant Conference and EXPO 2017

13-15 September 2017Forte Village, Sardinia

www.feica-conferences.com

Sardinia, Italy

The adhesive and sealant industry’s essential event13, 14 & 15 September 2017

• Network with other professionals in the adhesive

and sealant value chain.

• Understand market dynamics, market trends

and emerging economic developments that

could impact your business.

• Tap into your end-users’ needs and learn what

downstream users expect from you.

• Expand your knowledge of the advances in key

technologies and applications from research and

development professionals at the cutting edge of

innovation.

• Take the pulse of the most relevant industry trends, covering the full range of adhesive and

sealant technologies, applications and markets.

• Learn about raw material supply chain trends

and what your equipment suppliers have in store

for you.

• Get informed about regulatory changes that

are coming your way and their impact on your

business.

EXPO

13, 14 & 15 September 2017

The Table Top Exhibition opens on

Wednesday 13 September at 15:00 and runs

until Friday 15 September at 14:30.

Year-on-year, FEICA attracts a record number of

industry leaders to discuss market drivers and

trends, innovation, sustainability and technological

advancements.

The FEICA Conference and EXPO is fi rmly

established as the premier event for Europe’s

adhesive and sealant industry, providing

essential insights into the key issues aff ecting

the industry and great networking opportunities

for formulators, raw materials suppliers and

customers.

2017

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Driving Innovation

EXTENDERS & FILLERS

30 PPCJ • June 2017www.coatingsgroup.com

Glass flakes outperform traditional

platelet-like fillers in corrosive

and chemically aggressive

environments. One of the main areas of

glass flake application is barrier coatings

where glass flakes are recommended for

use as a replacement for MIO and other

platelet-like fillers. Thinner grades of glass

flake are feasible for application as an

alternative to thicker grades. Moisture

vapour transmission test and cathodic

disbondment test results are used for the

characterisation of coating performance.

Early glass flakes and coatings were

somewhat crude. The flakes being hugely

variable in thickness and plate size, the

coatings being simple trowel or brush

applied materials basically designed as a

glass fibre composite layer but with glass

flake substituting for fibres.

A lot of research has been done into

the comparison of glass flake to alternative

fillers in the 1980-90s but this was done

when commercially available glass flake

was still crude. Since then, the technology

has evolved and in this article the authors

analysed the feasibility of using thinner flake

in barrier coatings.

MORPHOLOGY AND CHEMICAL RESISTANCE

Glass flakes are high aspect ratio platelets

and are irregularly shaped. Normally

the value for particle size diameter is

approximated to the average particle

diameter passing through an oscillating

sieve. Flake has a controlled thickness

and particle size diameter depends on the

degree of milling.

There are two manufacturing techniques

employed to produce glass flake. The first

is the bubble method, which has been

in use for more than 40 years, albeit, in

various iterations. The second is the spun

method (figure 1).

Currently, the former method is typically

able to produce product with a variance of

2-9μm although until recently the variation

in flake thickness was considerably larger,

between 3 and 18μm, while typically

referred to as 5μm thick flake, it still

displays a wide variance. The technique

can result in curved flake, the degree of

which depends on the bubble size.

The latter spun glass method has the

advantage of tighter product control,

typically with thickness deviation at +/-1μm

for a given product and no curved flake

is generated. The spun process is able

to produce a thinner glass flake than the

bubble method. Thicknesses as low as

100nm with a typical deviation of +/-25nm

are achievable at a commercial level.

There are many different compositions

of glass available with different functionality.

More commonly used glasses include:

electric type of glass ‘E’ type, a chemically

resistant glass ‘C’ glass and various types

of more chemically stable compositions,

such as ‘ECR’ glass, which are modified C

glasses. The choice depends first on the

performance required, ie if the coating is

to be used in an aggressive environment

and if it requires a longer service life. Glass

composition, such as E glass is not suitable

for coatings due to its relatively poor

chemical resistance.

SACRIFICIAL AND BARRIER PROTECTION

Resistance to water is the most important

characteristic of all coating materials, as

all coatings come in contact with water

in one form or another. Water, being the

closest to a universal solvent, is a very

difficult material to which to achieve

resistance. A water molecule is so small

that it is able to penetrate into and through

almost all organic compounds. For a high

performance corrosion-resistant coating to

also have excellent water resistance means

that it must not only withstand continuous

immersion in water or seawater but it

must do so without blistering, cracking,

softening, swelling or loss of adhesion.

In order for a coating to be effective,

it must have a strong resistance to the

mechanism of ionic passage. If chlorides,

sulphates, sulphides or similar ions were

readily transferred through the coating, it

would have little resistance to corrosion

and also they would reduce the dielectric

strength in the coating, making it more

conductive and, therefore, less corrosion-

resistant. Resistance to ionic passage

is also a contributing factor to chemical

resistance. A coating with a very high

molecular weight and dense molecular

structure would have greatest resistance to

the ionic transfer2.

Barrier coatings provide a physical

barrier between a metal and the

environment, thereby isolating the metal

from water, salts and other corrosive

agents that are necessary for corrosion to

occur. Barrier properties are mainly due to

Thinner grades of glass flake, as an alternative to conventional fillers, are discussed in this paper

by Victoria Mirko, Simon Brigham and Charles Watkinson, Glassflake Ltd

Glass flake in barrier coatings

Fig 1. SEM micrograph of 5μm glass flake produced by bubble method (left) and SEM

micrograph of 5μm Glassflake Ltd glass flake produced by ITS rotary method (right)1

EXTENDERS & FILLERS

31 PPCJ • June 2017www.coatingsgroup.com

the resin system chosen, which is improved

by using platy or lamellar pigments and by

applying multiple coats.

Sacrificial coatings are those materials

that give themselves up to the corrosive

media, protecting the base metal.

Increasing the thickness of sacrificial

coatings extends the effective life of

protection. Generally, sacrificial coatings

are epoxies containing MIO, aluminium or

zinc filler acting as a reactive component.

GLASS FLAKE IN BARRIER COATINGS

When added to the resin, granular or

spherical fillers, such as some forms of

zinc oxide, do not overlap and offer only

limited resistance to diffusion through the

film, providing purely sacrificial protection.

Moisture vapour transmission (MVT) tests

on flake substitution in a bis-A Epoxy

coating carried out by the University of

Prague Research Institute for Protection

of Materials, have shown that the

addition of glass flake to the formulation

reduces permeation rates significantly in

comparison to granular fillers, as would be

expected. (Figure 2).

Some lamellar structured fillers, such

as MIO, aluminium or zinc flakes, give

a degree of barrier properties to the

coating but true barrier properties can

only be achieved with lamellar chemically

inert fillers, such as glass flake (figure 3). This is due to the fact that MIO/zinc/

aluminium flakes are chemically active

and, therefore, are prone to degradation

with time.

However, sacrificial protection offered

by aluminium/zinc fillers is effective when

these are used in primer coats. These

types of filler are effective only when they

are in a direct contact with the substrate.

Whereas the addition of aluminium flake

decreases the oxygen diffusion rate

significantly and, in some instances, by up

to six times, the reduction in the diffusion

rate of water is only slightly affected3.

A study conducted by O Knudsen, E

Bardal and U Steinsmo3 has confirmed

that barrier fillers, such as aluminium/glass

flake, substantially reduce disbondment

radius in epoxy resin formulations. The

authors found that cathodic disbondment

tests explained a barrier mechanism and a

mechanism where aluminium pigments are

chemically active (figure 4). Glass flakes

inhibited the disbondment compared to the

unpigmented coating but not as much as

the aluminium pigments.

From figure 4 it can be seen that after

four months, some disbondment was found

on the epoxy with 10% wt GF (10G). For

epoxy with 20% GF (20G) disbondment

was first found after a year of exposure.

After nine to 10 months disbondment

started from random points all over epoxy

10G. For epoxy 20G some random initiation

of disbondment was first found after 18

months4. However, for aluminium flake-

based coatings, there is a restriction by

10% addition as above that, due to spark

hazard, the classification companies,

such as Norsok, have set a limit to the

concentration of aluminium in marine paints

to a maximum of 10% wt in the dry film5.

The resistance to cathodic disbondment

of MIO-filled epoxy system, when

compared to the resistance to cathodic

disbondment of glass flake epoxy, is

significantly lower. Results shown in figure

5 demonstrate that the delamination area

was almost as twice as large for the MIO-

filled system and delamination occurred

earlier in all tests. Panels coated with a

model epoxy system, containing a 20%

wt loading of each pigment, was tested

in accordance with ASTMG8-90, using a

modified method B with impressed current

and multiple samples. All tests were carried

out in triplicate in an environment consisting

of one percent each by mass of anhydrous

NaCl, Na2SO

4 and Na

2CO

3, as required by

the standard6,7.

Glass flake pigments are, therefore,

regarded as an effective alternative

to active metal flake and can be

recommended as a combination barrier

pigment, which complements the sacrificial

protection provided by the former.

EXPERIMENTALTests were carried out to evaluate the

change in MVT afforded by varying the

flake concentration. A pre-accelerated vinyl

ester resin was used as the carrier resin,

with the only difference in the materials

tested, being the addition level of glass

flake. Standard 5μm thick milled grade of

glass flake (GF750M) was used for this test

(Table 1). Tests were conducted initially to

zero-in on the area of criticality, then levels

of 14%, 15% and 16% were used to carry

out the main evaluation. MVT has been

Fig 2. MVT test on a bis-A epoxy with 2% wt granular filler and 2% wt glass flake

Fig 3. SEM micrographs of cross section of an epoxy mastic coating with 10% wt aluminium

pigments and with 10% wt glass flakes3

Fig 4. Cathodic disbondment radius of an epoxy

mastic coating, with various concentrations of

aluminium and glass pigments, measured over the

period of time (years)4

EXTENDERS & FILLERS

32 PPCJ • June 2017www.coatingsgroup.com

taken as an average result of five samples.

The optimum result was achieved for the

flake concentration at 15% wt showing the

lowest MVT rate of 3.46 x 10-5 perm inches.

Table 1. MVT tested in accordance with

ASTM D1653

Cathodic disbondment tests were

carried out to evaluate the same variations

in glass in the same resin matrix as those

tested above and the results are shown

below. Tests were conducted for 56 days at

–1.6ve. Disbondment radius was measured

as an average of three tests (Table 2).

Table 2. Cathodic disbondment tested to

BS3900 F11

Tests showed correlation between MVT

rates and cathodic disbondment. The

lowest MVT rate has been achieved for the

formulation with 15% wt glass flake and

the lowest disbondment radius shows as

3.4mm for 15% wt glass flake.

A standard grade of glass flake, ie 5μm

thick milled glass flake can be effectively

substituted by 2μm thick flake, which

enables glass flake to be used in earlier

economically unviable applications.

Thicker 5μm flake-based coatings have

always been seen as a product with a

restrictively thicker DFT (Table 3) for certain

applications and, thus, has only been

economically feasible for highly corrosive

environments. Reduction of the number

of layers and reduction of the single coat

thickness achieved by thinner flake, results

in reduced total costs of application/m2 that

makes thinner glass flake an alternative to

currently used grades and MIO.

Single coat applications, quick cure

times and simple application can reduce

down time by up to 30% and total life cycle

costs, compared with conventional paint

and coating systems, can be reduced by

up to 60%7.

Cathodic disbondment tests on a

hybrid polyurethane/vinyl ester carrier has

shown that thinner glass flake performed

significantly better than standard

thicker glass at non-standard cathodic

disbondment test, accelerated by high

temperature of 180°C (figure 6).

Moisture vapour permeation resistance

has been evaluated for different

thicknesses of glass ie for 5μm and 2.2μm

glass flake (figure 7). The difference in

performance with the change in glass

flake type can be clearly seen. The top

(red) curve represents glass at an average

thickness of 5μm in thickness, whereas the

bottom curve shows glass at an average

thickness of 2.2μm.

The curve for the thicker glass is much

steeper and the best loading value is at

approximately 23.5% by weight. A move

either side of this addition level changes the

MVT performance significantly. The thinner

glass flake only requires an addition of

between 14% and 18% to obtain an MVT,

which is almost a magnitude better. The

curve is much flatter with the optimum level

of addition being at approximately 15%.

APPLICATION AREASMetal and concrete structures are often

required to be protected from general

and chemical corrosion in non-immersed

and immersed environments often being

in contact with aggressive chemicals,

water solutions or sea water. Glass flake

linings are designed primarily for the

protection of steel and are formulated

from high performance resins combined

with glass flakes. The combination of

high performance resins and glass

flakes produces linings with outstanding

performance characteristics. They may be

applied by spray, brush or trowel.

Glass flake-filled coatings may also

demonstrate thermal expansion similar

to mild steel, which prevents the coating

from cracking. Due to the morphology and

ability of glass flakes to overlap within the

System System A: Zinc epoxy primer EpoxyEpoxy Epoxy/PU

System B: Flame sprayed Al

MIO epoxyMIO epoxyEpoxy/PU

System C: Zinc primer 5μm GF epoxyEpoxy Epoxy/PU

System D: Zinc epoxy primer 2μm GF epoxy

Coats, μm 1 x 75 1 x 125 1 x 75 1 x 75

2 x 125 2 x 250 1 x 350 1 x 500

1 x 50 1 x 50 1 x 50

Total applied cost, £/m2

18.76 24 18.54 16.5

Table 3. Estimated applied cost of offshore coating systems8

Fig 5. Cathodic disbondment of MIO and glass flake filled epoxy resin6,7

Fig 6. The results of a high temperature

accelerated cathodic disbondment test

carried out at 180°C with two different

grades of glass flake

On the left: hybrid polyurethane/vinyl ester coating filled

with av. 5μm thick glass flake: 22-25mm disbondment

after 28 days at 1.5V vs SCE reference in NaCl 30g/l at

30mA/cm2 current density

On the right: hybrid polyurethane/vinyl ester coating

filled with av. 2.2μm thick glass flake: 15-18mm

disbondment after 28 days at 1.5V vs SCE reference in

NaCl 30g/l at 30mA/cm2 current density

Glass flake concentration, % wt

Moisture vapour transmission, perm inches 10-5

14 10.61

15 3.46

16 3.64

Glass flake concentration, % wt

Disbondment radius, mm

14 5.0

15 3.4

EXTENDERS & FILLERS

33 PPCJ • June 2017www.coatingsgroup.com

resin matrix, the glass filled films exhibit low

film stress and lateral shrinkage, which all

contribute to longevity of a coating in service.

Glass flake-filled materials have a proven

record of being used on a wide variety of

substrates, including steel and concrete for

protection of bridges, offshore structures,

pipelines, tanks, chemical storage and

other types of immersed equipment

(Table 4).

FORMULATING WITH GLASS FLAKE

Although the addition of flake will generally

reduce the moisture vapour transmission

through almost any organic coating film or

membrane, there may be other benefits

with new properties being imparted or

existing ones improved. However, the

level at which the glass flake should be

added, the particle size distribution and

ensuring adhesion to the carrier, are of

paramount importance.

Although glass flakes with aspect ratios

as low as 10:1 will give benefit, generally the

higher the aspect ratio the better the barrier

presented. This premise has, however,

to be tempered to some extent, as out of

alignment large aspect ratio flakes can

afford a direct path through the film where

the film is less in thickness than the nominal

diameter of the flake or cause stress

raisers for crack propagation. In addition,

there are some properties that may be

adversely affected when using large flakes,

such as flexibility and elongation to break.

The quantity of glass flake added and

particle size distribution are as critical.

It may be possible to add up to 30% by

weight of flake with a thickness of 2-9μm

and not exceed the critical pigment volume

concentration (CPVC) in resin. It should be

noted that the majority of flake produced

by bubble process quoted at 5μm with a

deviation of +/- 2μm is typically 2-9μm.

If the same quantity by weight of a flake

produced by the spun method at 2μm with

a deviation of +/-0.5 thickness were added,

then the surface area of this flake will be at

least two and a half times that of the thicker

one and there may be insufficient resin for

surface wet out, thus the CPVC level is

exceeded. In any case, the viscosity may

be so high when changing from the thick

flake to thin flake, that addition at the same

level becomes impossible.

Even if the characteristics of a

particular resin and formulation are known,

product formulation specification rather

than performance specification can be

misleading. For example, a specification

could state ‘epoxy with a minimum glass

flake loading of 30% by weight. This level

of addition could, in many formulations,

exceed the CPVC level and, while some

coatings may perform well at this level of

addition, other coatings would give better

performance at lower glass flake loadings

and may give the best overall result.

CONCLUSIONDue to significant improvements in process

technology, glass flakes are now available

with aspect ratios that outperform standard

grades and open further opportunities to

more cost effective formulations. Standard

grades of glass flake, ie 5μm grades have

been analysed in various types of resin

and compared to other types of filler in

MVT and cathodic disbondment tests. The

results show that standard grades of glass

flake are an efficient substitute for MIO and

metal fillers, and are the only type of filler

that provide long term barrier protection,

although are recommended for use in a

combination with sacrificial primers. Low

cost systems can be achieved at low level

loadings with thinner flake and thinner DFTs

can be used as compared to traditional

barrier systems. Care should be taken

when formulating with glass flake in order

to follow performance specification rather

than product specification. PPCJ

Author: Victoria Mirko, Business Development, Glassflake Ltd, Stafford Street, Leeds LS10 1PW, UK Tel: +44 (0)113 2703615 Email: [email protected]: www.glassflake.com

References1. S J Brigham and C Watkinson, ‘Understanding

and use of Glass flake’, 2007.

2. C G Munger and L D Vincent, ‘Corrosion

prevention by protective coatings’, NACE, 1999.

3. O Knudsen, E Bardal and U Steinsmo, ‘Effect

of barrier pigments on cathodic disbonding

part 1: Aluminium and glass pigments’,

1SINTEF Materials Technology, 1999.

4. O Knudsen and U Steinsmo, ‘Effect of barrier

pigments on cathodic disbonding part 2:

mechanism of the effect of aluminium pigments’,

1SINTEF Materials Technology, 1999.

5. NORSOK, ‘M-CR-501, Surface Preparation

and Protective Coatings’, Norwegian

Technology Standards Institution, Oslo (1994).

6. J Marsh, ‘An examination of the performance of

glass flake pigments for use in organic barrier

coatings’, CAPCIS 1999.

7. J Marsh, ‘A comparison of the mechanical

properties of glass flake and MIO pigmented

epoxy resins’, CAPCIS 2001.

8. J M Keijman, ‘High solids coatings: experience

in Europe and USA’, 1999.

9. G Gedge, ‘Painting specifications for bridges.

From Oresund to Stonecutters, searching for

the benefits for the benefits of difference’, ICorr

UK corrosion, 2003.

Fig 7. MVT test for 5μm

and 2.2μm glass flake

filled polyester

Application area Equipment

Marine Hulls, decks, rudders, thruster tunnels

Nuclear & power generation

Scrubbers, condenser water boxes, water pipes, tanks

Chemical Acid/caustic tanks, vessels, floors, neutralisation tanks

Oil, gas & petrochemical

Separators, tanks, splash zones

Food & agriculture Storage tanks, effluent tanks, juice, wine and beer tanks, sugar

processing milk parlours, floors

Water & sewage Potable water tanks, clarification tanks, pipes

Transport Railway carriages, tankers

Table 4. Application areas for glass flake filled barrier coatings9

This paper was presented at the Advances in Coatings

Technoloy-ACT’16 conference, organised by the Institute

for Engineering of Polymer Materials and Dyes, Paint and

Plastics Department, Poland, October 2016.

EXTENDERS & FILLERS

34 PPCJ • June 2017www.coatingsgroup.com

You can’t say anymore that talc

is ‘just a filler’ because it’s a

functional filler to improve the

surface resistance of coatings and,

thus, can add value. The different

source of the talc has an influence on

its chemical nature and, therefore, its

surface resistance. The impact of talc

grades with different surface reactivity

on surface resistance of a matte wall

paint was tested. It was found that the

most hydrophobic talc shows the best

performance to improve water, water/

ethanol and stain resistance. Strategies

on how to incorporate talc in coatings

will be presented, including how to

compete with additives, which are used in

this respect.

Matte surfaces are a trend at the

moment on the decorative paint market.

However, these types of coating get dirty

easily and are difficult to clean, due to their

open and/or rough structure. As a rule, the

higher the amount of filling (high PVC), the

lower the gloss levels. The aim of this study

was to show that it is possible for high PVC

wall paints to have good surface resistance

despite being matte.

Talc has a platy particle form and

a very hydrophobic surface, which

makes it highly resistant to water and

many other substances. But not all

talcs are similar. There are many talc

grades available that are blends of

talc and some other, more hydrophilic,

by-minerals. The purpose of this study

was to investigate the effect of different

talc types on the resistance properties

of matte wall paint. The resistance

properties studied were: water, water/

ethanol, stain resistance to achieve

easy-to-clean properties and dirt pick-up

resistance. Four different talc grades

were tested in this respect:

• Finntalc M30SL from Mondo Minerals BV

• Finntalc M40SL from Mondo Minerals BV

• Chloritic talc with 90% talc and 10%

chlorite (Chloritic talc 10%)

• Chloritic talc with 50% talc and 50%

chlorite (Chloritic talc 50%)

First, a guide formulation for an interior

matte wall paint was developed. Then

the different talc grades were added into

this formulation and the resistance tests

were carried out after letting the different

films cure for one week. The formulations

prepared differ in type of talc and were with

and without a silicone additive. In total eight

formulations at PVC 70% were developed

with the basic, as shown in the Table 1.

TESTING WATER RESISTANCE

To assess the water resistance of the

coating after one week of curing, a big

drop of water was applied on the film of

paint and then covered by a watch glass in

order to prevent evaporation. The damage

caused by the water was assessed after

15min, 30min, 1hr, 2hr, 4hr and 24hr. The

24hr results are shown in figure 1.

TESTING WATER/ETHANOL RESISTANCE

To assess the water and ethanol resistance

of the coating after one week of curing,

a big drop of a 50/50 mix of water and

ethanol was applied on the film of paint and

then covered by a watch glass in order to

prevent evaporation. The damage caused

by the mixture was assessed after 15min,

30min, 1hr, 2hr, 4hr and 24hr. The 24hr

results are shown in figure 2.

TESTING CLEANING AND STAIN RESISTANCE

Two types of stains were tested: coffee

and green highlighter. A few drops of

coffee were applied on the paint, as well

as a few stripes of green highlighter. They

were cleaned afterwards and the possible

remaining stains were assessed visually.

Due to the poor water resistance of the

chloritic talc-based paints, the cleaning of

the stain resulted in damaging the film and,

therefore, no good determination could be

Four different talc grades have been tested to ascertain surface resistance in high PVC and matte,

paints and the findings are provided by V Kilpelainen*, S van Loon§ and G Le Mouee§

Improved surface resistance of matte wall paint by using talc

Table 1. Basic formulation Formulation with silicon additives

Binder Mowilith LDM 1871 12.94 12.94

Solvent

Water 29.01 29.01

Additives

Lupon 895 0.32 0.32

Calgon N 0.75 0.75

Natrosol 250 HR 0.32 0.32

Schwefo Foam 6351 0.32 0.32

Silres BS 333 – 1,05

Acrosol RM8 0.25 0.25

Pigments and filler

5 micron CaCO326.97 25.92

2 micron CaCO37.55 7.55

PCC CaCO33.24 3.24

TiO210.78 10.78

Different talc grades 7.55 7.55

Total 100.00 100.00

Gloss 60° 3.1 3.1

Gloss 85° 2.6 2.6

EXTENDERS & FILLERS

35 PPCJ • June 2017www.coatingsgroup.com

made. The resistance and cleaning of the

Finntalcs were good, especially FinnTalc

M30SL, as can be seen in figures 3 and 4.

DIRT REPELLENCY – DRY EXPOSURE

On each paint film 0.02g of hydrophilically

modified carbon black (Special Black 100)

was added. After 15min the test panels

were then slightly inclined and 5ml of water

was dispensed, in order to wash away the

carbon black powder. Dust repellency was

then assessed by evaluating how much

carbon black remained on the paint film.

Dirt pick-up results for formulations are

given in figure 5.

For both films containing Finntalc

M40SL, it could be observed that a part of

the carbon black powder was not washed

away by the water.

For the formulations without Silres

BS 333, bigger carbon black particles

were left on the films with the talc-chlorite

grades than on the films with Finntalcs.

This suggested that the dust resistance

was better for the paints with Finntalcs. For

the formulations with Silres BS 33, it was

more difficult to see

differences between the

various panels.

During the tests

it was noticed that

the water drops were

running faster on the

films with the Finntalc

grades than on the films

with the talc-chlorite

grades. The water

droplets also flattened

more on the paint films where talc-chlorite

talcs were used. These indicate that the

dust repellency was better when Finntalcs

were used in the formulations.

CONCLUSIONS

Four different talc grades were tested:

two of them were highly pure talc grades

from Mondo Minerals (Finntalc M30SL

and Finntalc M40SL) and two were talc

grades with different amounts of chlorite

from another supplier. The samples were

tested for water, water/ethanol and stain

resistance (coffee and highlighter). Dirt

pick-up was also evaluated.

The paints with Finntalc grades

performed much better than the talc

grade containing chlorite on all resistance

properties tested. In particular, the

resistance to water and ethanol were

much better with Finntalc than with the talc

grades containing chlorite. Also the coffee

and highlighter pen stain resistance was

better with Finntalc compared with more

hydrophilic talc-chlorite. It was difficult to

evaluate the stain resistance by colour

difference measurement for the talc-chlorite

grades because they were damaged during

the process of washing the stains. The poor

resistance of the talc-chlorite to water used

in washing was the reason for the damage

in the cleaning. In terms of visual evaluation,

it can be said that the Finntalc grades

tested had a higher resistance to surface

cleaning than the talc grades containing

chlorite. Also dirt repellency of the paint film

with Finntalc was better than with chloritic

talc. Rinsing water ran also faster on the

films with Finntalc and water droplets did

not flatten so much as with chloritic talc.

Although the tested paint formulation was

not exactly an outdoor paint due to the

resin used, it already proves for increased

surface resistance at outdoor exposure

when Finntalc M30SL and M40SL are used

compared with hydrophilic chorite rich

talc grades.

This study has shown that with Finntalc

grades, it is possible to improve the surface

resistance in high PVC and matte paints.

Due to its excellent barrier properties,

Finntalc can compete with additives like

silicones and waxes that are usually used

to make paint film more hydrophobic in this

type of paint. PPCJ

Fig 1. Fig 2.

Fig 3. Fig 4.

Fig 5.

Authors: V Kilpelainen*Mondo Minerals BV Branch FinlandPO Box 603, FI-87101 Kajaani, FinlandTel: +358 (0)50 599 3537Email: [email protected]

S van Loon and G Le Mouee, §Van Loon Chemical Innovations, Science Park 408, 1098 XH, Amsterdam, The NetherlandsTel: +31 204 685 657Email: [email protected]

36 PPCJ • June 2017www.coatingsgroup.com

COLOUR TECHNOLOGY

For all of the advancements in colour

measurement and management,

one challenge still remains: how to

accurately measure colour for paint and

coatings without having the instrument

come in contact with the sample. In all

phases of colour evaluation in the paint

and coatings industry, waiting for samples

to dry or expending the time and energy

to use a drying implement, adds time to

specification, development, formulation and

quality control processes. In a world where

time is money, manufacturers just can’t

afford to sit and watch paint dry. Waiting for

samples to cure to a measurable condition

can take up to 24hr. Applying heat to the

sample to dry it consumes needless energy

and can change the colour metrics for

certain materials. In addition, production

runs may already be under way before

dry samples are ready and this can

result in significant amounts of waste and

rework before a quality assessment can

be completed.

Placing a barrier between the sample

and the measurement device isn’t

particularly helpful either, since it can result

in changes in appearance (especially gloss)

and even colour.

WHY MEASURE WET PAINT?

Whether you are manufacturing paint

or manufacturing painted items, there

are significant benefits to measuring

paint, while it is still wet. But obviously,

wet paint doesn’t look the same as dry

paint. To get accurate colour readings,

it is important to establish standards for

both wet and dry paint. Sometimes this is

done by the paint manufacturer with the

data being communicated to customers;

and sometimes, manufacturers using the

paint will need to do this themselves. In

either case, manufacturers using paint

should always have a process in place

to verify the quality and colour accuracy

of incoming raw materials, including

measurement of both wet and dry paint

and coatings samples. Even a small

change in ingredients can change the way

the colour appears.

For example, a paint manufacturer may

be using a yellow pigment from a certain

supplier. Due to market and other changes,

the company decides to move to a different

supplier. The pigments are chemically the

same but may be produced using different

manufacturing processes. Even something

as subtle as this can make a difference in

the final appearance of the paint.

In the end, the wet paint measurement

is only useful as a short cut, saving the time

and hassle of drying samples. What is most

important is the colour of the paint after it

dries. However, this short cut can be quite

valuable in terms of productivity and the

wet standard only needs to be established

once, unless there is a significant change in

paint formulation.

ESTABLISHING WET AND DRY STANDARDS

For manufacturers of paint and painted

products alike, then it is important to not

only measure both wet and dry samples

but to establish standards for both. That

means applying the wet paint, measuring

it, recording the colour data and then

measuring it again when the sample is dry.

This is called establishing an offset. In most

cases in this initial stage, we recommend

letting the paint dry naturally rather than

force drying it, especially if the final product

is intended to dry naturally.

Using forced air heat to dry paint risks

causing the colour to change in a different

way than it would change when drying

naturally. However, for paints that are

meant to be baked on, such as automotive

paints, samples should be dried using the

same baking process. This will typically

result in a higher shift in colour from wet

to dry than drying naturally. The bottom

line: use the same drying process that

is likely to be applied in the end use. It

also goes without saying that separate

measurements should be taken for

different types of paint, even if they are

the same colour. For example, separate

measurements are required to ensure

consistency for gloss, as opposed to

eggshell, finishes.

It should also be noted that

environmental conditions can affect both

the colour and laydown of the paint, and

this should be taken into consideration.

Paint and coatings applied in the hot, dry

Arizona climate will likely react differently

than those same paints and coatings

applied in Michigan in the winter.

By following this process, both paint

manufacturers and their customers can

build reliable databases of wet paint

standards that can then be used instead of

waiting for samples to dry every time. This

will improve productivity, quality and speed

to market.

As a cautionary note, this assumes that

there are no significant changes over time

to the actual raw materials used to make

the wet paint that will affect how it dries.

Before joining X-Rite, I worked at BASF

in the pigment division. We saw cases

where, when we changed the way we were

producing a given pigment, wet samples

would actually switch between being

lighter and darker than the dry samples.

It is also important to note that changes

in raw materials can cause wet colour to

change even though the dry colour stays

the same. Thus, with any changes in raw

materials, it is important to validate that

the wet and dry states still have the same

relationship to each other and update

standards accordingly.

STANDARDS VS TOLERANCES

The wet and dry standards we have been

discussing are the colours that you actually

want to hit. But for most applications, some

level of variance is allowed. The tolerance is

how closely you must match it for customer

acceptance. And the tolerance may be

different for wet and dry samples. For

example, if I measure a wet sample and

there is one unit of difference (whatever

measurement metric you use, such as delta

E), that might be an acceptable tolerance.

If there is a two-unit difference, that could

also be acceptable, as long as the dry

sample meets the minimum variance of

one unit. So it is important to establish not

only the standard but also the tolerance,

Waiting for paint to dry is now a thing of the past as Tom Mouw, Applications Engineering and Technical Support Team

Manager, X-Rite, discusses, following the development of a best practice for the testing of wet and dry tolerances

Tired of waiting for paint to dry?

37 PPCJ • June 2017www.coatingsgroup.com

COLOUR TECHNOLOGY

for both wet and dry samples. Both are

required for a functional database of

standards and to be able to use the wet

measurement with confidence.

THE VALUE OF DIGITAL STANDARDS

In many cases, the paint manufacturer will

provide its customer with data for both wet

and dry measurements. This could be in

the form of a Certificate of Analysis that is

produced at time of manufacture. This may

only cover dry measurements, in which

case the end customer would need to do

their own wet measurement analysis. But a

more effective means of data transfer is to

provide it digitally. ISO Standard 17972-

1:2015 defines an exchange format for

colour and process control data, as well as

the associated metadata necessary for its

proper interpretation. While CxF was initially

developed by X-Rite for use in the graphic

arts industry, the international standard also

supports the exchange of colour data in

other industries.

Across the supply chain, there are

many software packages that can both

export and import CxF files, such as

X-Rite’s Color iMatch formulation and QC

software. If your software supports digital

standards, this is the best way to go. It

ensures accurate communication of the

colour data and minimises human error in

the colour measurement and management

process. Metadata should include whether

the measurement refers to a wet or a

dry sample.

NON-CONTACT MEASUREMENT TO THE RESCUE

Luckily, today’s hardware and software

makes this process easier than ever

before. Advances in non-contact colour

measurement instruments, such as the

X-Rite VS450 45°/0° spectrophotometer

allow the fast, accurate capture of wet

samples without the worry of contamination

of or damage to the instrument. Non-

contact spectrophotometers are designed

to produce colour and gloss measurements

for many types of both wet and dry

samples without coming into contact with

them. Samples do not require any type of

protective coating and because the sample

is some distance – up to 38mm in some

cases – from the lens of the instrument.

This means that the optical system

remains free from contamination, reducing

instrument maintenance and ensuring

its accuracy.

With a non-contact instrument,

operators can measure quickly and easily

wet and dry flat samples but they can

also measure three-dimensional objects,

such as painted furniture on a production

line. Using a measurement table or stand

compatible with the instrument means

that large, bulky and/or irregular shaped

samples, can quickly be positioned

horizontally or vertically for accurate

non-contact measurement. To make the

process even better, the data secured from

these measurements can be uploaded to

computer software for further analysis and

for tracking of measurement history.

Another important capability in a non-

contact spectrophotometer is line-of-sight

visibility to the sample to enable operators

to position quickly and easily, the sample

for measurement. Active visual targeting

that projects a prominent, illuminated target

ring on to the sample also helps secure

precise, accurate colour measurements,

even on patterns.

As with any instrument, it is important

to verify that instruments remain within

specification. Most manufacturers

suggest an annual check-up to make sure

everything is in order. There is also software

that can perform interim assessments

of the condition of the instrument, such

as X-Rite’s NetProfiler and even provide

certification as to the condition of the

instrument for audit purposes.

CASE IN POINT

One paint manufacturer that produces

batches of very slow drying alkyd-

based paints used traditional contact-

based spectrophotometers for colour

measurement. It could take the company

up to 24hr before a product could be

approved, slowing down production cycles

or worse yet, risking production of batches

that do not conform to the appropriate

colour specifications.

To address this issue, the company

developed a ‘wet standard’ or offset

for its products. This is the standard its

wet samples need to meet in order to

produce a good result in a final dry-to-

dry comparison. If the batch meets the

wet tolerance test using a non-contact

spectrophotometer, packaging can start

and the final quality control will be done on

dry applications. If the batch is outside the

wet tolerance, it can often be corrected

before it goes into production. In fact,

formulation software can often produce a

correction formula that eliminates trial-and-

error corrections, saving huge amounts of

time and materials.

In this way, the paint manufacturer was

able to control day-to-day production with

a defined standard that saves time, effort

and cost.

CONCLUSION

Waiting for paint to dry is a thing of the

past. Best practices for introducing wet

standards and wet/dry tolerances include:

• Acquiring a non-contact

spectrophotometer and accompanying

formulation/QC software to enable

measurement and storage of those

results in a colour database.

• Developing a standard operating

procedure (SOP) around the use

of wet and dry standards in the

paint manufacturing or application

process. This includes specifying the

drying process to be used for the

dry standard, as well as acceptable

tolerances for both wet and

dry samples.

• Ensuring all appropriate staff is trained

against the SOP.

• Establishing good quality control

procedures for assessing incoming

materials, whether they are pigments,

resins or formulated paint.

• Exchanging colour data in CxF or

another acceptable digital format to

reduce the opportunity for error.

• Periodically reassessing both wet and

dry standards to ensure no significant

changes have occurred.

• Ensuring that colour measurement

instruments are adequately maintained

so that they remain in specification and

that all software used in the process is

kept up to date.

By employing these best practices,

your organisation can more easily move

to the use of wet standards, eliminating

the need to wait for paint to dry during the

manufacturing process.

PPCJ

Author: Tim Mouw is the Manager of the Applications Engineering and Technical Support Team for X-Rite in the Americas. In his role, Tim oversees a team of 20 technical support specialists that help customers improve colour quality control processes. Over the past two decades, Tim has taught more than 300 courses on colour science across North & South America, Europe, Asia and Australia Email: [email protected] Website: www.xrite.com

38 PPCJ • June 2017www.coatingsgroup.com

COLOUR TECHNOLOGY

Datacolor has announced the launch of ColorReaderPRO, a professional colour matching device. Its

introduction will provide paint companies with a comprehensive colour selection tool, redefining the ease and efficiency of colour matching.

ColorReaderPRO is an ultra-portable, Bluetooth connected colour selection device that works standalone or connected to the ColorReaderPRO mobile app. It provides leading colour matching performance, allowing painters to match a client’s colour inspiration to a corresponding paint colour in seconds.

“As the market leader in colour management solutions for more than 45 years, Datacolor is uniquely qualified to support paint companies’ initiatives to increase brand loyalty and improve colour selection efficiency”, said Brian Levey, Vice President, Consumer Solutions, Datacolor.

The ColorReaderPRO solution includes:An accurate colour selection device that stores up to 10,000 colours and can be used standalone with the OLED display or with the ColorReader Mobile App. When a colour is measured in the stand-alone mode, the screen displays the colour numbers of the closest matches.

Using this mobile application, you can easily store, recall and examine project colour information, while working with a

client in real time. Using the Sync option, you can add or update fan deck collections or other proprietary colour systems on the device.

The app is suitable for paint companies, which want a turnkey mobile app solution

and is available for both iPhone and Android phones.

ColorReader Software Development Kit (SDK) easily integrates ColorReaderPRO functionality into an existing mobile app with the help of the company’s ColorReader SDK.

The ColorReader Fleet Management Software can easily add, manage and assign authorised fan decks to users and leverage registration information for targeted marketing campaigns.

Model DC10-1 is a powerful, easy-to-use measurement and colour lookup tool developed for colour professionals, including painters, architects and designers.

It can be used to measure, quickly and accurately, samples selected by a customer and find the closest colour matches in a fan deck collection stored on the unit. The customer then selects the final colour on the spot. It is important to ensure fan decks are always current so users have the latest colour collection.

PPCJ

At the recent European Coatings Show, Datacolor highlighted its latest offering with the ColorReaderPRO

Professional colour matching

Contact: Barbara Rudekon behalf of DatacolorTel: +49 0173 5338732; +49 0172 4317574 Email: [email protected] Website: www.datacolor.com/colorreaderpro

Datacolor.indd 1 25/05/2017 11:57

ADHESIVES & SEALANTS

39 PPCJ • June 2017www.coatingsgroup.com

Although solventborne (sb) adhesives

are still widely used as contact

adhesives in the production of

mattresses and furniture, in the shoe

industry and multiple other industrial

applications, as well as in do-it-yourself

(DIY) adhesives, there is a growing

demand for waterborne (wb) solutions

due to changing legal requirements,

workplace hygiene considerations and

safety issues. As a result, adhesives users

are increasingly looking for alternatives to

conventional solventborne formulations.

The advances achieved in waterborne,

polychloroprene-based contact

adhesives in recent years make them an

attractive alternative.

Contact adhesives are typically applied

to both substrates. After a drying time,

the substrates must be joined under high

pressure, as the pressure correlates directly

with performance.

Polychloroprene rubber is a traditional

and well-established raw material for

contact adhesives, offering good initial

adhesion on a broad variety of substrates.

The crystallisation tendency of the

polychloroprene polymer is important

since it directly correlates with the

adhesive’s performance, as shown in

figure 1.

Polychloroprene contact adhesives

can be solventborne or waterborne, with

the adhesive polymers having a similar

polymer backbone. Comparison trials in

contact bonding applications have shown

that the adhesive strength of waterborne

and solventborne CR adhesives is quite

comparable. Differences in drying time

and open time have to be considered with

reference to the formulations and taking

into account the different drying behaviour

of solvent vs water.

Figure 2 shows final bond strength

on SBR rubber test specimens that were

joined under a pressure of 100N/cm² at

different times after adhesive application.

For wb polychloroprene adhesives, an open

time of one to two hours can be observed

(which is longer for sb polychloroprene

adhesives), while peel strength reached

with the wb adhesive is at least comparable

to the sb counterpart.

IMPROVING PERFORMANCE OF WB CONTACT ADHESIVES BY CROSSLINKING WITH NANOSILICA SOLS

In solventborne CR contact adhesives

phenolic resins are normally used as

formulation component in order to enhance

tack, prolong open time and to somewhat

improve heat resistance.

In waterborne CR adhesives, however,

nanoparticulate silica sol dispersions can

be used as suitable and effective blending

partners, yielding significant performance

improvements. If a waterborne CR

adhesive is formulated by crosslinking

the polychloroprene polymer1 with a

nanoparticulate silica sol dispersion2, the

Peter Küker*, Winfried Jeske and Dr Martin Melchiors, Covestro, report on developments to

improve further the property level of waterborne 1K polychloroprene adhesives

Modern waterborne contact adhesives: 1K application with 2K property levelWaterborne systems, based on polychloroprene dispersions have proven to be suitable in replacing solventborne contact adhesives in many applications.In foam adhesives for furniture and mattress production, polychloroprene (CR) dispersions are gaining a share relative to traditional solventborne adhesives. One reason is that such waterborne adhesives can be formulated as one-component (1K) adhesives, combining the full wet adhesion potential offered by polychloroprene dispersions with the simple and reliable handling of 1K formulations, while fulfilling relevant requirements on VOC regulations.An easy method to yield activated formulations through pH reduction, with improved wet tack properties for spray application on various substrates is presented. For rolling/brushing application, we show that the combination of polychloroprene, with selected nanosilica dispersions, creates a network structure providing significant improvements in the cohesive strength, as well as the heat resistance of the adhesive.

Fig 1. Peel strength development of polychloroprene adhesives

as a function of crystallisation

Fig 2. Final peel strength and open time of solventborne vs

waterborne polychloroprene contact adhesives on SBR rubber

ADHESIVES & SEALANTS

40 PPCJ • June 2017www.coatingsgroup.com

network formed between the polymer and

silica particles delivers several key benefits:

• Excellent wet bonding on leather

and textiles with outstanding early

wet strength.

• Dramatically improved drying speed (up

to 50% faster dry-to-touch).

• Much improved heat resistance (better

than solventborne adhesives), see

figure 3.

• Up to 50 % increase in

bonding strength.

Solventborne polychloroprene contact

adhesives usually have a heat resistance

of 60–80°C. When using a combination of

a polychloroprene dispersion, particularly

a hydroxyl-functionalised type3 in

combination with a nanoparticulate silica

sol dispersion4, a heat resistance up to

150°C can be achieved due to a network

formation caused by intermolecular

interaction between hydroxyl groups in

the polymer chain with the surface of the

silica particles.

An additional benefit of such wb

polychloroprene/silica sol formulations

is the improvement of early/initial as well

as final bond strength. If used on water-

absorbing substrates, such as leather

and textiles, the substrates coated with

such adhesive formulations can be joined

immediately after adhesive application. The

initial (as well as final) strength achieved

is significantly higher compared with

solventborne contact adhesives, as shown

in figure 4.

For many industrial and also DIY

adhesive applications it, therefore, is

possible to replace solventborne contact

adhesives with environmentally friendly

waterborne polychloroprene adhesives

without compromising on performance.

SPRAYABLE CR CONTACT ADHESIVES FOR FOAM BONDING APPLICATIONS

Sprayable CR contact adhesives are

of particular importance for foam-

to-foam applications in the mattress

and furniture industries. A number of

waterborne adhesive raw materials

based on polychloroprene dispersions

are offered for such applications1. These

products display similar properties to

solventborne materials but have very

low residual monomer content. The

commonly used 2K spray mix technology

has two components: the adhesive – a

polychloroprene-based waterborne

formulation – and an aqueous coagulant

solution. The two components are mixed

during spraying. The film of coagulated

adhesives guarantees high initial bond

strength, even in the wet state, to ensure

immediate foam-foam, foam-wood and

foam-plastic bonding.

As an alternative, waterborne

polychloroprene-based adhesives can

be applied as 2K systems in a spray-

mix process with a coagulant or as 1K

systems destabilised (activated) by pH

reduction. More and more furniture and

mattress manufacturers are turning to

waterborne 1K adhesives not just because

of environmental pressures and safety

issues but because they are much easier

to handle. One component (1K) foam

adhesives combine the wet adhesion

potential of polychloroprene dispersions

with the easy and reliable handling qualities

of 1K formulations, while fulfilling relevant

requirements on VOC regulations. However,

this technology is used less often for foam-

to-wood applications due to the lower tack

between the substrates.

Research has been conducted to

further improve the wet tack properties

for spray applications on a variety of

substrates. CO2 activation technology has

been developed as a result, improving

the wet bonding performance of such

sprayable 1K adhesives for foam bonding.

The CO2 activation method is based on the

very soft and homogeneous neutralisation

of the anionic emulsifier. CO2-activated

dispersions display very high wet tack

properties directly after application and

are stable to coagulation in spite of a low

pH (≈8.0).

If carbon dioxide is used for pH

reduction, the performance of 1K spray

adhesives can be significantly improved vs

state-of-the-art adhesives where organic

acids, such as glycine are used to adjust

pH. The performance of such activated

1K adhesives is similar to 2K waterborne

spray-mixing and solventborne systems.

See table.

CO2 activation is, thus, a very efficient,

simple and cheap way of producing highly

Fig 3. Softening point of sb vs wb polychloroprene adhesives tested on SBR rubber

(CR sb market sample vs CR wb with resin vs silica sol)

Fig 4. Initial and final peel strength of sb vs wb polychloroprene adhesives;

wb formulations (Toolbox #2, #3) based on Dispercoll C + Dispercoll S

pHImmediate wet bonding

foam/foam foam/wood

CR dispersion1 2K with CaCl2 12 + +

CR dispersion1 1K with glycine 9 + -

CR dispersion1 1K with CO2 8 + +

ADHESIVES & SEALANTS

41 PPCJ • June 2017www.coatingsgroup.com

active spray adhesives offering users the

advantage of easy handling.

CONCLUSION

Waterborne adhesives based on

polychloroprene dispersions are available

on the market as an alternative to

solventborne contact adhesives. As

environmentally friendly and efficient

solutions for foam-to-foam (eg mattresses)

and foam-to-wood bonding (eg upholstery

furniture), they provide high bond strength

with good and immediate wet tack

properties, very fast bond formation

and a soft bonding seam in 1K or 2K

spray applications.

For industrial, as well as DIY contact

adhesives, formulating polychloroprene

dispersions with nanosilica sol dispersions

boosts the initial and final bond strength,

as well as the heat resistance of the

adhesive bond.

PPCJReferences1. Dispercoll® C; Covestro Deutschland AG,

Leverkusen.

2. Dispercoll® S; Covestro Deutschland AG,

Leverkusen.

3. Dispercoll® C 2325 (55% solids); Covestro

Deutschland AG, Leverkusen.

4. Dispercoll® S 3030 (30% solids); Covestro

Deutschland AG, Leverkusen.

5. ZnO Dispersion 3020 (48% solids);

Micronisers Pty Ltd, Victoria, Australia.

6. Rhenofit® DDA-50 EM (50% solids); Rhein Chemie

Rheinau GmbH, Mannheim.

7. Dermulsene A 7510 (50% solids); Les Dérivés

Résiniques, Dax Cedex, France.

Authors: Peter Küker, Manager Foam bonding Adhesives, Covestro Deutschland AG, 51368 Leverkusen, GermanyEmail: [email protected] Martin Melchiors, Senior Manager Industrial Adhesives, Covestro Deutschland AG, 51368 Leverkusen, GermanyEmail: [email protected] Jeske, Field Technical Service Adhesives, Covestro Deutschland AG, 51368 Leverkusen, GermanyEmail: [email protected] Berta Vega Sánchez, Marketing Manager Furniture Coatings & Adhesives, Covestro Deutschland AG, 51368 Leverkusen, GermanyEmail: [email protected]

Current trends in key adhesive raw materialsIVK, the German Adhesive Association, has

published current trends in key adhesive

raw materials. Despite intensified political

uncertainties, the prospects for world

economic activity are improving, indicating

that business will continue to pick up

around the globe.

IVK points out that demand for base

chemicals remains high in Asia, as well as

the USA, where, as a logical consequence

of supply and demand mechanisms,

the prices for commodities are higher

than those that can be obtained on the

European market.

The disparity in prices achievable on the

Asian and USA markets and those to be

had on the European markets, means that

the tonnages imported to Europe are down,

partly because commodities are also being

exported from Europe to more lucrative

markets in other regions.

The availability of adhesive raw materials

was and will also be further impacted in Q1

and Q2 2017 by planned overhauls – as well

as unplanned stoppages in cracker plants

in Asia, as well as in the facilities dedicated

to the production of base chemicals.

Taken as a whole, all of these factors

combine to restrict the availability of key

raw materials in Europe, which will lead

to shortages, along with the attendant

price rises.

The publication states that during

the first quarter, prices for ethylene,

propylene, butadiene and styrene rose

appreciably worldwide, although the

actual availability and price levels varied

from region to region. Butadiene prices

recorded historic highs in Asia, while

ethylene ranked lower on the price scale

in the USA than in Asia.

When the production restrictions for

downstream products (eg vinyl acetate) are

factored in, costs for adhesive raw materials

have been driven up still further around the

globe. The impacts are evident in acrylates,

vinyl acetate-based raw materials and

more particularly in SBS and SIS polymers,

especially as the prices for natural rubber

have also been climbing. Also affected are

almost all solvents of key importance to the

adhesives industry.

Regarding polyurethane systems,

availability in Europe is affected not just by

rising prices for isocyanates but also by the

negative effects of arbitrage.

As a result, formulation costs are rising

across the board, affecting virtually all

water-based, solvent-based and PUR

adhesives, as well as primer systems.

The report concludes that restricted

availability of commodities coupled

with sustained demand has pushed

up raw materials prices, with inevitable

consequences on the formulation costs

for adhesives. Current market bottlenecks

can only be expected to ease when the

raw material prices on the Asian, USA

and European markets begin to converge

once again.

www.klebstoffe.com

42 PPCJ • June 2017www.coatingsgroup.com

FEICA CONFERENCE

Firmly established as the premier event

for Europe’s adhesive and sealant

industry, the FEICA Conference and

Expo continues to grow and regularly

attracts more than 500 participants from

around the globe.

Business Forum focuses on innovationThe Conference provides the ideal

environment for industry leaders to come

together to discuss market drivers and

trends, innovation, sustainability and

technological advancements. This year’s

event continues ‘the pursuit of growth’

theme of FEICA’s recent conferences,

with a particular focus on innovation.

The Business Forum – the Conference’s

plenary opening session – is titled ‘Driving

Innovation’. Innovation can be stimulated

from many directions: ‘pull’ from your

customers, ‘push’ from your suppliers,

from competitors or new entrants to the

market, learning from other industries and,

internally, from your own people, working

in a culture that nurtures innovation. At the

Business Forum, professionals representing

various links in the adhesive and sealant

supply chain will share their perspectives

on innovation and the growth opportunities

it has brought them, providing some useful

learning points for the delegates’ own

innovation processes. Once again, FEICA

has managed to attract some outstanding

keynote speakers, including:

• Dr Hugo Maria Schally, Head of Unit,

Directorate General ‘Environment’,

European Commission, deals with

‘Sustainable Production, Products

and Consumption’. In this function he

is entrusted with the co-ordination of

the follow-up to the new EU package

on the ‘Circular Economy’ and the

development and implementation of a

number of EU policies and instruments

in support of the transition to a

circular economy.

• Roger Martin-Fagg, Behavioural

Economist, combines insight into

the financial and policy worlds with

management strategy.

They will be followed by keynote

speakers from the industry, sharing their

own perspectives on innovation and a

panel discussion on the topic that will allow

delegates to put their questions to the

assembled experts.

Breakout Sessions on mission-critical topicsThe Conference’s Parallel Breakout

Sessions allow delegates to select sessions

from a range of important industry topics

so that they can customise the programme

to meet their own specific interests. This

year’s sessions encompass:

• Market trends and innovation.

• New approaches to isocyanates and

polyurethane adhesives and sealants.

• Elastomers and elastic adhesives.

• Innovations in construction.

• Olefin-based hotmelts.

• Manufacturing and processing.

• Safe use of adhesives.

• Pressure-sensitive adhesives.

• Bio-based adhesives.

• Additives and resins.

Table Top ExhibitionThe Table Top Exhibition provides an

opportunity for all producers, distributors,

suppliers and service providers, linked

to the adhesive and sealant industry, to

promote their latest developments to the

Conference’s audience of senior industry

decision-makers. More than 30 companies

have already signed up to exhibit.

Enjoy a great networking and social programmeThe FEICA Conference and Expo is

renowned for the great networking

opportunities it affords delegates.

Formulators, customers and raw materials

suppliers can come together to discuss

the latest industry trends and wider

business environment in a variety of

relaxed, informal settings. The Conference

also offers a range of sparkling social

occasions at which you can meet new

business contacts and say hello to

established industry friends. These include

the Welcome Cocktail on the first evening

and the Conference Dinner on Thursday,

September 14. PPCJ

FEICA’s 2017 Conference and Expo will take place in Forte Village, Santa Margherita di Pula, Sardinia, Italy, from September 13-15.

Where the world’s adhesive and sealant industry comes together

For more information: Kristel Ons, Communication and Event Manager, FEICATel: +32 (0)2 792 75 17Email: [email protected]: www.feica-conferences.com

SECTION REPORT

43 PPCJ • June 2017www.coatingsgroup.com

SECTION REPORTDIRECTORY

ABC Chemical Exports Pvt Ltd105/106 Kshitij BuildingVeera Desai RoadOpp Andheri Sports ComplexAndheri (W)Mumbai 400 058IndiaContact: Mr Vinay H Thadani(Business Development Manager)Tel: +91 22 2676 6643Fax: +91 22 2673 [email protected] EAST HQ:ABC Chemical ExportsPvt Ltd, PO Box 8330Saif Zone, Sharjah, UAEContact: Coating division: NK Ganeshan, Sales ManagerTel: +971 6 5579612/13Fax: +971 6 [email protected] division:Mr Kalhan KaulProduct Manager (packaging)Tel: +971 6 548 9478Fax: +971 6 557 9614

Ai Process SystemsThe Corn Mill, Church StreetBarrowfordLancashire BB9 6EBUKContact: Mr Alan Parry, Managing DirectorTel: +44 1282 611551Fax: +44 1282 [email protected] or [email protected] covered: Global

Al Khowahir Chemicals Mat Trading LLC

Sharjah Industrial Area No 2 PO Box 6870 SharjahUAE Contact: Mr Saju Mathew Regional Sales Manager Tel: +971 6 542 4116 Fax: + 971 6 542 4016 [email protected]; [email protected] www.khowahir.comTrademarks: Anodal, AQ 55S, Aerosil, Aeroxide C, BYK, Bayferrox, CAB, CAP, CPO, Ceridust, Colanyl, Cosmenyl, Densil, Hostatint, Hostaperm, Hansa, Hostapur, Licowax, Licolub, Licocene, Melment, Melflux, Mowiol, Mowital,

Novaperm, Optifilm, Proxcel, Sanodal, Sanolin, Shellsol, Tolonate, Tronox, Tylose, Tylovis, Texanol, Vantocil, Viscofil, VialkydRegions covered: A/ME

Al-Lamaan Trading PO Box 55548 DubaiUAEContact: Mushteq Ahmed, General ManagerTel: +971 4 269 0532Fax: +971 4 262 [email protected] OFFICES & AGENTS: Al-Lamaan Trading (Dz, Bh, Eg, Ir, il, Jo, Kw, Lb, Ma, Ng, Om, Qa, Sa, Sy, Tn, Ae, Ye)

Alberdingk BoleyDüsseldorfer Str 53 D-47829 KrefeldGermanyContact: Oliver Hasler, Manager New Business Development Oils/Sales OverseasTel: +49 2151 528 0Fax: +49 2151 573643alberdingk@alberdingk-boley.dewww.alberdingk-boley.comTrademarks: Alberdingk, Albodur

Allnex Corporate Centre:The SquaireAm FlughafenD 60549 Frankfurt am Main, Germany The operating Allnex group is legally owned by Allnex Holdings S.à r.l., a company based in Luxembourg, which also provides long term strategic decisions relating to its investment in Allnex.www.allnex.comRegions covered: Global

Argon Kimya San ve TIC. AS TEM otoyolu Tekstilkent Koza Plaza B Blok, Kat 25, Esenler IstanbulTurkeyContact: Cem Margunato, Vice PresidentTel: +90 212 438 5757Fax: +90 212 438 [email protected]

Ashland Industries Europe GmbH

Dubai Airport Free zone Bld 6 EB, Office 139 PO Box 293719

DubaiUAEContact: Mazen Hamadeh, Regional Sales Manager, Middle East & AfricaTel: +971 4 3818515 Fax: +971 4 7017132www.ashland.com

Astra Polymers Compounding Co

PO Box 30740 Al-Khobar 31952 Saudi ArabiaTel: +966 3 812 1232Fax: +966 3 812 [email protected] covered: A/ME

BASF SEFormulation Additives Dispersions & Pigments Division 67056 LudwigshafenGermanyTel: +49 (0)621 60 0 Fax: +49 (0)621 60 42525 [email protected]/formulation-additives Dispersing agents, wetting agents and surface modifiers, defoamers, rheology modifiers, film-forming agents

Biccs BV Industrial Colourants

Dukdalfweg 41 NL-1332 BK Almere The NetherlandsContact: Michel Kronz, Managing DirectorTel: +31 36 549 2066Fax: +31 3 6537 [email protected]: BC-S Colourants, BC-W ColourantsSALES OFFICES & AGENTS: Eurochem Int (Bh, Ir, Jo, Kw, Lb, Om, Qa, Sa, Sy, Ae, Ye)Regions covered: AP, Cn, EEC, Non-EEC, A/ME

BYK AdditivesAbelstrasse 4546483 WeselGermanyContact: Thorsten Gaertner, Head of Sales Paint AdditivesTel: +49 281 670-0Fax: +49 281 [email protected]

SALES OFFICES & AGENTS: Ellkay Middle East LLCDubai, [email protected]. Fahmy Co, [email protected] Co Ltd, [email protected] Engineering Ltd, [email protected] Chemicals [email protected] A AL Azzaz [email protected]

Cabot CorporationTwo Seaport Lane Suite 1300, Boston MA 02210-2019USATel: +1 617 345 0100Fax: +1 617 342 6103www.cabot-corp.comTrademarks: BlackPearls, Cab-O-Sil, Cab-O-Sperse, Emperor,Monarch, Spectral Regions covered: GlobalMIDDLE EAST HQ:Cabot Specialty Chemicals,Jebel Ali Free Zone LOB 15-Office N 424 Dubai, UAE Tel: +971 4 887 800Fax: +971 4 887 801www.cabot-corp.comSALES OFFICES & AGENTS: HAK Trading (Ae)Obegi Chemicals (Ae)

Celanese Emulsion PolymersSulzbachGermanyContact: Mr Michel GhestemTel: +33 3 88 76 57 [email protected] Trademarks: Celvolit, VinamulDistributor: Omya Distribution Co WLLAbdul Wahab Al Majali St ShmeisaniPO Box 105911118 Amman, JordanRegions covered: GCC (Sa, UAE, Ye, Bh, Kw, Qa, Om), Eg, Lb, Jo, Tanzania Tel: +962 6 566 5517Fax: +962 6 566 4668

www.omya.com [email protected]

Chemical Partners Europe SABoulevard Léopold II Nr 184d B-1080 BrusselsBelgiumContact: Ralph Raffoul, Didier Peeters, ManagersTel: +32 2 219 4596Fax: +32 2 219 [email protected]: Albester, Bentone, Bermocoll, CAB, Dapro, Duroct, Dynoadd, Elotex, Epolene, Kathon, Kristalex, Mattex, Meko, Metatin, NeoCryl, NeoRez, Nuosperse, Optifilm, Picco, Ravemul, Rheolate, Rocima, Satintone, Texanol, Tytan, Ultrex. Regions covered: A/ME

Chemipol C/ Joan Monpeo 149 E-08223 Terrassa SpainContact: Mr Eduard Broto Tel: +34 9 3783 1044 Fax: +34 9 3783 7580 chemipol@ chemipol.com www.chemipol.com Trademarks: Biopol, Chemipol, Densipol, Fungipol, Sanipol Regions covered: GlobalSALES OFFICES & AGENTS: BMK (Tn)IMCD Maroc (Ma)SARL Propeint (Dz)RAHA Importing (Li)CEBEX (Lb)

CNNC Hua Yuan Shanghai Titanium Dioxide Co Ltd

Room 1001, No 1 Building Sandhill Plaza, No 2290 Zuchongzhi RoadPudong New DistrictShanghai 201210PR ChinaContact: Angela GaoTel: +86 21 6072 9975Fax: +86 21 6072 [email protected] Trademarks: Tioxhua

Colour Project European Via G Marconi I-24036 Ponte S Pietro (BG)ItalyContact: Cristian Colombo, Managing Director Tel: +39 035 462 488 Fax: +39 035 462 418

Alphabetical listing of major suppliers of coatings, raw materials, plant & machinery and

services to the Middle East and North Africa coatings industry

Middle East Directory of Suppliers

SECTION REPORT

44 PPCJ • June 2017www.coatingsgroup.com

SECTION REPORTDIRECTORYSECTION REPORTDIRECTORY

[email protected] www.colorproject-european.it Regions covered: Global

Coprabel Avenue Vesale 20BE-1300 WavreBelgiumTel: +32 10 238 280Fax: +32 10 238 [email protected]: Easy Color, NariRegions covered: A/MESALES OFFICES & AGENTS: Coprabel Saudi Arabia (Sa)Coprabel Jordan (Jo)Amina Trading Establishment (Sa)Kioumgi Chemicals (Sy)Afrah Al Khaleej (Kw)

Covestro International SARoute de Beaumont 10CH – 1701 FribourgSwitzerlandContact: Sandra Gafner-HernandezBusiness AnalystCAS EEMEA Commercial OperationsBU Coatings, Adhesives and SpecialitiesTel: +41 (26) 422 82 27Fax: +41 (26) 422 81 [email protected]: Bayhydrol, Bayhydur, Crelan, Desmodur, Desmophen, PergutRegions covered: A/MESALES OFFICES & AGENTS:MS Global AG (Branch of Covestro)Nucleotide Complex, 1st Floor,Office No 110, PO Box 503073,Dubai Science Park – Dubai, UAEAgent: Younichem (Lb)

Cristal Corporate HeadquartersKing’s Road Tower,King Abdulaziz Road, 17th FloorPO Box 13586Jeddah 21414Kingdom of Saudi ArabiaTel: +966 12 224 8000Fax: +966 12 606 9087Contact: Hussain Bashihab,General Manager MEAI SalesTel: +966 2 224 [email protected]

CrodaPO Box 17916, Office 511Lease Office Building 16Jebel Ali Free ZoneDubaiUAEContact: Sujith Gopalakrishnan Tel: +971 4 887 0100Fax: +971 4 887 [email protected] [email protected] polymers.com

Trademarks: B-Tough –Toughening agentsLoVOCoat – Polymeric W/O emulsifiersMaxemul – Polymeric & reactive surfactants.MyCroFence – Antimicrobial ingredientsPriamine – Dimer diaminesPriplast – Polyester polyolsSynperonic – EO/PO-based co-polymers

Datacolor Loorenstrasse 98305 DietlikonSwitzerlandTel: +41 44 835 3711Fax: +41 44 835 3739 [email protected] www.datacolor.com Regions covered: GlobalSALES OFFICES & AGENTS: Dingo Ltd (IL)Al Khowahir Chemicals (Ae,Om,Kw,Bh,Qa))

De Vree Toekomstlaan 10 B-2170 MerksemBelgiumContact: Gert Van Herwegen, Sales Manager Tel: +32 3 641 4302 Fax: +32 3 646 4815 [email protected] www.devree.com

DIAF/Pilvad A/S Praestemosevej 2 43480 Fredensborg Denmark Contact: Hans Peter Hansen, Export Manager Tel: +45 5853 5378 Fax: +45 5853 5278 Mobile: +45 2169 2077 [email protected] www.diaf.comRegions covered: Global

Dow Chemical IMEA GmbH Dubai Downtown, Emaar Square Building 6, Level 3Sheikh Zayed RoadPO Box 7893DubaiUAETel: +971 4 4537 000Fax: +971 4 4537 117www.dow.com/middleeast/index.htm Regions covered: IMEAT (India Middle East, Africa and Turkey)SALES OFFICES & AGENTS: Dow Export (Eg, Ae)Dow Mideast Systems (Eg)

DSM Coating ResinsCeintuurbaan 5, Zwolle The Netherlands PO Box 615, 8000 AP, Zwolle The Netherlands Tel: +31 38 456 9569 Fax: +31 38 456 9500 [email protected]

Trademarks: Uralac, NeoCryl, NeoPac, NeoRad, NeoRezRegions covered: Global

Dura Chemicals, Inc 2150 Mariner Square Drive AlamedaCalifornia 94501USA Contact: Raghu Santhanam, General Manager Tel: +1 510 814 1987 Fax: +1 510 814 8025 [email protected] Trademarks: Durastab, Duroct Regions covered: Am, AP, Cn, EEC, A/MESALES OFFICES & AGENTS: Jebsen & Jessen (Eg, Jo); Taj Al Mulook

Eastman ChemicalPO Box 431, KingsportTennessee 37662USATel: +1 423 229 2000Fax: +1 423 229 2145www.eastman.comTrademarks: Eastman Texanol ester alcohol; Eastman CAB cellulose ester; Eastman adhesion promoters Regions covered: GlobalMIDDLE EAST HQ:Eastman Chemical BVFascinatio Boulevard 602-614 2909 VA Capelle aan den IJsselContact: Mr Mustafa MertTel: +90 21 22 11 3313www.eastman.comSALES OFFICES & AGENTS: Chemical Marketing & Distribution (Sa) Chemical Partners Egypt (Eg)Chemical Partners Europe (Jo, Lb, Tn and Algeria)

ECKART GmbHGuentersthal 491235 HartensteinGermanyTel: +49 9152 77 0Fax: +49 9152 77 [email protected] and pearlescent pigments for the paints and coatings industry, the plastics, lightweight concrete industries and the cosmetics industry.

Egyptian Promoters Center For Pharmaceuticals SAE

40 Al Horria Street, Heliopolis CairoPO Box 8, Heliopolis 11341CairoEgyptContact: Mr Ahmed Fouad, Managing DirectorTel: +20 2 2291 8272 +20 2 2290 1642 +20 2 2417 0149 +20 2 2418 4320Fax: +20 2 2415 5023 (Direct) or +20 2 2291 8271 (General)[email protected] Regions covered: A/ME

Elcometer LimitedEdge Lane, Manchester, Greater Manchester M43 6BUUKContact: Craig Woolhouse, Sales Manager Tel: +44 (0)161 371 6000 Fax: +44 (0)161 371 6010 [email protected] www.elcometer.com Regions covered: GlobalSALES OFFICES & AGENTS: Contact Elcometer for information

EOC Tailor Made Polymers Industriezone de Bruwaan 24, B-9700 OudenaardeBelgiumContact: Francoise Cornette, Marketing Responsible Tel: +32 55 33 4278 Fax: +32 55 33 4242 [email protected] www.eocgroup.com Trademarks: Euro PU, Eurocryl, Eurothick, Eurovac, TailortacRegions covered: Global

Fast & Fluid Management PO Box 220, NL-2170 AE Sassenheim The NetherlandsTel: +31 252 240 800 Fax: +31 252 240 888 [email protected] www.fast-fluid.com Trademarks: Accutinter, Harbil, Blendorama, Skandex Regions covered: GlobalSALES OFFICES & AGENTS: Al Azzaz (Sa, Kw, Bh, Ye)Al Shihab Al Thahabi (UAE, Om, Qa)Lanai Holdings (Eg)Orom Colorants Ltd (Il)Saad Chemicals (lb, Jo, Sy)

Galstaff Multiresine SpA Via Stazione 90, 21020 Mornago (VA)ItalyContact: Mr Claudio Marzorati, Business Director Tel: +39 0331 90141 Fax: +39 0331 903777 [email protected] www.galstaffmultiresine.com Trademarks: Ftalon, Innocryl, Italester, Italkid, Itamin, Mittel, Monocryl, Poloral, Rastal, Sintal, Syncryl, Tintodyer, Uronal and Veroxan Regions covered: GlobalSALES OFFICES & AGENTS: Roumieh Trade Company (Sy) SH Chemicals & Building Materials Trading (Bh, Kw, Om, Qa, Ae)Tavan (Eg)

General Mineral Industries Co LLC

PO Box 20074 AjmanUAEContact: General Manager

Tel: +971 6 748 0101 Fax: +971 6 748 0929 [email protected] www.gmillc.com Trademarks: Emical Regions covered: AP, A/MESALES OFFICES & AGENTS: Al Haleef Paint Factory (Sa) Arab Tower Trading (Jo)

Graco BVBASlakweidestraat 31 3630 Maasmechelen Belgium Contact: Peter Bloem Sales Supervisor MEA, Russia and CISTel: +32 897 70779 [email protected] www.graco.com

Giffin Graphics Port Zayed Freezone Area PO Box 955 Abu DhabiUAEContact: Ramzi Kteily, Managing Partner Tel: +971 2 673 0555 Fax: +971 2 673 3550 [email protected] www.giffingraphics.com Regions covered: AP, A/MESALES OFFICES & AGENTS: Giffin Graphics (Bh, Qa, Om)

Gulf Polyester & Epoxy Powder Coating Factory

PO Box 6416 Riyadh 11442 Saudi ArabiaContact: Hamid Quzaih, Sales & Marketing Manager Tel: +966 265 1977 Fax: +966 265 2032 [email protected] www.altaiseer.com Regions covered: A/MESALES OFFICES & AGENTS: Alwan Paints & Chemical Trading (Ae)Gulf Polyester & Epoxy Powder Coating Factory (Sa), Seven-Star-Trading (Kw)

Harco Group SA/NVAvenue Louise 390Brussels 1050BelgiumContacts: H BabikianManaging Director; I Notoglou, COOTel: +32 2 673 27 44Fax: +32 2 672 64 [email protected] covered: EEC, A/ME, GulfSALES OFFICES & AGENTS: Harco Egypt (Eg, Libya)Harco Marketing & Trading Lebanon (Jo, Lb, Sy)Harco Marketing & Trading (Bh, Ir, Kw, Om, Qa, AE, Ye)Harco Maroc (Ma, Tn)Harco Saudi (Sa)MIDDLE EAST HQ:Harco Marketing &Trading, Jebel Ali Free

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Zone, Dubai, UAETel: +971 4 8837 955Fax: +971 4 8837 954www.harcogroup.be

Huntsman PolyurethanesEverslaan 45 3078 EverbergBelgium Contact: Marketing Executive Tel: +32 (0)2 758 9211 [email protected] www.huntsman.com/pu/ace Trademarks: Suprasec methyl di-isocyanate

Jordan Carbonate CoPO Box 1059 Amman 11118JordanContact: F Al Ghussein, Deputy GM Commercial Tel: +962 6 566 5517 Fax: +962 6 566 4668 [email protected] www.jordancarbonate.com Trademarks: Fan, Snow White Regions covered: AM, AP, A/ME

Kemira Pigments Rue De Bercy 207 F-75012 ParisFranceContact: Sales Manager Tel: +33 1 43 46 22 78 Fax: +33 1 43 46 82 78 [email protected] www.kemira.com Regions covered: GlobalSALES OFFICES & AGENTS: Occitania Chemicals (Bh, Eg, Jo, Kw, Lb, Om, Qa, Sa, Sy, Ae, Ye)

Kuwait Chemical Mfg Co (A Divn of United Oil Projects)Box 26011, Safat 13121KuwaitContact: [email protected];Tel: +965 2326 3297;Fax: +965 2326 0179www.uopkt.comProven resins for auto refinish, body filler, PC, Industrial, can, coil & architectural coatings Regions covered: Global

Linkers Chemicals & Polymers DMCC

Indigo Icon Tower, Office no 2804, Jumeirah Lakes TowersPO Box 75616 DubaiUAETel: +971 4 4474792Fax: +971 4 [email protected] www.lcp.ae Regions covered: A/ME, GCC, South Asia

Lubrizol Advanced Materials Sales Spain

Camino Can Caldés, 1308173 Sant Cugat del Vallés BarcelonaSpainTel: +34 93 590 2918 Fax: +34 93 590 2940

[email protected] www.lubrizolcoatings.com Trademarks: Carboset, Carbotac, Doresco, Permax, Sancure, Turboset Regions covered: GlobalSALES OFFICES & AGENTS: Harco Group (Jo, Lb, Sa, Ae, Qa, Om, Kw, Ym, Bh)Gadot Chemicals Division (il)RMCS (Eg)

Lubrizol Deutschland GmbH Max-Planck-Str 6 27721 RitterhudeGermanyTel: +49 (0)421 69 333 Fax: +49 (0)421 69 33 400 [email protected] www.lubrizolcoatings.com Trademarks: Antibubble, Aquaslip, Ircogel, Ircospherse, Ircothix, Lanco micronised waxes, Lanco Antimar, Lanco Flow, Lanco Glidd, Lanco Liquimatt, Lanco Matt, Powderadd Regions covered: GlobalSALES OFFICES & AGENTS: Harco Group (Jo, Lb, Sa, Ae, Qa, Om, Kw, Ym, Bh)Gadot Chemicals Division (il)RMCS (Eg)

Lubrizol LtdPO Box 42, Hexagon House BlackleyManchester M9 8ZS UKTel: +44 161 721 2004 Fax: +44 161 721 5209 [email protected] www.solsperse.com Trademarks: Solsperse, Solsplus, Solthix Regions covered: GlobalSALES OFFICES & AGENTS: Harco Group (Jo, Lb, Sa, Ae, Qa, Om, Kw, Ym, Bh)Gadot Chemicals Division (il)RMCS (Eg)

Lucite International Horndale Avenue Newton Aycliffe Durham DL5 6YEUKContact: David McDonald, Market Development Manager Tel: +44 (0)1325 300990 Fax: +44 (0)1325 314925 [email protected] www.lucitesolutions.com www.luciteinternational.com Trademarks: Colacryl, Elvacite, Lucite Regions covered: EU, A/MEMIDDLE EAST HQ:Lucite International Trading (Bahrain)PO Box 30728BudaiyaKingdom of Bahrain Contact: Alan J Gallagher Tel: +973 17582219 Fax: +973 17582267 [email protected] www.lucitesolutions.com SALES OFFICES & AGENTS: Lucite International (Bh, Tk, Eg, il, Jo, Kw, Lb, Om, Qa, Sa, SA,

Ae, Ye)

Lukem Tiranova 38, 1000 Ljubljana SloveniaTel: +386 1244 3291 94 Fax: +386 1244 3296 [email protected] Regions covered: EU, A/MESALES OFFICES & AGENTS: Atbin Fam Co Ltd (Ir)Basic Chemicals Company (UAE)

The Metal Powder Company Limited

Thirumangalam, Madurai DistrictInd-625706TamilnaduIndiaContact: Mr RajeshwaranDeputy Manager, International SalesTel: +91 4549 281995Fax: +91 4549 [email protected]@mepco.co.inwww.mepco.co.inwww.stemco.com.myTrademarks: MepcoSALES OFFICES & AGENTS: Worldwide

Moustafa Abdine & CoPO Box 2464, Hanano Street DamascusSyriaContact: Mr Nizar Abdine, Marketing Manager Tel: +963 11 321 2229 Fax: +963 11 373 1894 [email protected] Trademarks: Al Ferdoss Regions covered: A/ME

Niemann, Wilhelm, GmbH and Co

Nordlandstrasse 16 D-49326 Melle-NeuenkirchenGermanyContact: Mr Frank Niemann, General Manager Tel: +49 5428 9500 Fax: +49 5428 950 199 [email protected] www.niemann.de Trademarks: Kreis-Dissolver Kreis-Basket-MillKreis-Dissolver-ButterflyRegions covered: Global

Obegi Chemicals City Tower 1, Office 1002-4, Level 10, Sheikh Zayed RoadPO Box 28098DubaiUAETel: +971 4 33 22 440 Fax: +971 4 33 21 805 [email protected] www.obegichem.com Regions covered: A/MESALES OFFICES & AGENTS:Obegi Chemicals (Sa, Jo, Eg, Sy, Lb, Ae, Belgium, Iraq)Obegi Chemicals Ð EgyptRoad 105, Building 50Level 3, Maadi PO Box 11431, Cairo

EgyptTel: +20 2 2525 3724 - 50 Fax: +20 2 2525 3749 Contact: Ayman Fahmy, Group Vice President Tel: +20 238 326 993/4 Fax: +20 238 335 032 ayman_fahmy@obegi chem.comwww.obegichem.com Regions covered: A/ME

Oliver y Batlle S.A.U.Ctra Mataro 39-47 E-08911 Badalona SpainContact: P J Pascual, Head of Sales and Marketing Tel: +34 93 464 1010 Fax: +34 93 464 3040 [email protected] www.oliverbatlle.com Regions covered: Global

Organik KimyaCendere Yolu No 1 4634075, Kemerburgaz/Eyup, IstanbulTurkeyContact: Kemal Ersudas,Business Unit DirectorTel: +90 21 2 331 0000 Ext 307Fax: +90 21 2 331 [email protected] Trademarks: Orgal, Dispersant, ORP Regions covered: Global

Patcham (FZC)Plot C4/5, 6, 7, 8 - Sharjah Airport International Free Zone (SAIF Zone) Sharjah UAE Contact: Vishal Kulkarni, Marketing Manager Tel: +971 6 557 0035Fax: +971 6 557 0038 [email protected] www.patchamltd.com Trademarks: Patadd, Patstab, Patcom, Patcat Regions covered: GlobalSALES OFFICES & AGENTS: Cisco Trading (Kuwait), Royal Trading & Engineering (Eg), J.Nassar Tech (Lb)

Pavilion Chemicals Europe The Nook, The Allotments, Birstwith, HarrogateN Yorkshire HG3 2NQUKContact: Garry Plant, Owner Tel: +44 1423 771747 Fax: +44 1423 779147 [email protected]

Pro-Chem Trading FZE PO Box 4404 Office #708 FairmontSheikh Zayed RoadDubaiUAEContact: Riad Paul KhorosTel: + 971 4 3124057; Fax: + 971 4 3124058; Mobile: +971 508 751 [email protected];

[email protected]

Pro-Chem Sarl PO Box: 50-030Beirut LebanonTel: +961 1 280073 Fax: +961 1 280038 [email protected] Regions covered: A/ME

Poudrsazan 1 Hamsian Alley West Keshavarz BlvdTehran 1418883643 IranContact: Mr F Kazemkhani, Chairman Tel: +98 21 694 7210 13 Fax: +98 21 694 2952 [email protected] www.poudrsazan.com Regions covered: A/ME

Q-Lab Corporation European HQ, Express Trading Estate, BoltonLancashire BL4 9TPUKContact: James Regan, General Manager Tel: +44 1204 861616 Fax: +44 1204 861617 [email protected] www.q-lab.com Trademarks: Q-Lab, QUV, Q-Sun, Q-Fog, Q-Panel

RAL German Institute for Quality Assurance & Certification

Siegburger Str 39D-53757 Sankt Augustin GermanyTel: +49 2241 160560 Fax: +49 2241 160516 [email protected] www.ral-colours.de Trademarks: Ral Digital, Ral, Ral Design, Ral Classic

Recon Chemicals 324, Business Village B Near Clock Tower Port SaeedDeira 62569UAEContact: H P Shetty, Director Tel: +971 4 447 2244Fax: +971 4 447 2245 [email protected] www.reconchemicals.com

RK Print Coat InstrumentsLitlington, RoystonHertfordshire SG8 0QZUKContact: Tom Kerchiss, Managing Director Tel: +44 1763 852187 Fax: +44 1763 852502 [email protected] www.rkprint.com Regions covered: Global

Robert Kraemer Zum Roten Hahn 9 D-26180 RastedeGermany

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Contact: Werner Sarfert, General Manager Tel: +49 4402 97880 Fax: +49 4402 9788222 [email protected] www.rokra.com Trademarks: Bremapal, Bremar, Bremasin, Bremazit, Erkamar, Erkarad, Kramorex, Rokralux, Rokrapol, Rokracure Regions covered: GlobalSALES OFFICES & AGENTS: Taj Al Mulook (Bh, Eg, Ir, Jo, Kw, Lb, Om, Qa, Sa, Sy, Ae, Ye)

Rolfes Colour Pigments International

PO Box 8112, SA-1406 ElandseonteinSouth AfricaContact: Debajit Shome, Commercial DirectorTel: +27 11 874 0752Fax: +27 11 874 0694 [email protected] www.rolfesza.net Trademarks: Rolfes Regions covered: AM, AP, EEC, Non-EEC, A/ME

Rütgers Novares GmbH Varziner Str 49, D-47138 DuisburgGermanyContact: Monika Probst Tel: +49 20 3429 6735 Fax: +49 20 3429 6762 [email protected] www.novares.dewww.ruetgers-group.com

Safic-Alcan Necarbo BVNoorderkade 281948 NR BeverwijkThe NetherlandsContact: Mr Jos van Buul, Managing DirectorTel +31 251 [email protected]: Nebores, Neboplast, Nebochips, NebotintRegions covered: globalMiddle East HQSafic-Alcan Necarbo (Middle East) B.V.Jebel Ali Free Zone, DubaiContact GCC countriesMr Shaji [email protected] Saudia ArabiaMr Tahir [email protected] EgyptMr Medhat [email protected]

Sasol Middle East PO Box 61089 Jebel AliDubaiUAEContact: Shabeer Randera, Managing Director Tel: +971 4 806 8300 Fax: +971 4 806 8400 [email protected] Regions covered: Global

Sasol Servo PO Box 1, NL-7490AA Delden The NetherlandsContact: Kamal Atwani, Sales Manager Tel: +31 74 3775 000 Fax: +31 74 3775 025 [email protected] www.sasol.com Trademarks: Exkin, Nuodex, Nuosperse, Nuvis, Ser-ad, Serdas Regions covered: Global

Saudi CarbonatePO Box 25679, Riyadh 11476 Saudi ArabiaContacts: Ammar Nouri, Managing Director;Hitesh Paathak, Sales & Marketing Manager;Aziz Byari, Dep. Sales & Marketing Manager Tel: +966 11 265 1947Fax: +966 11 265 [email protected]@saudicarbonate.comwww.saudicarbonate.comProducts: Natural and Treated Precipitated Calcium Carbonate (PCC); Natural & Treated Ground Calcium Carbonate (GCC; Dolomite; TalcApplications: Building MaterialsPolymer & PlasticPaper & PulpLife SciencesRegions covered: A/ME, Asia, EEC

Schülke & Mayr GmbHRobert Koch Strasse 222851 NorderstedtGermanyContact: Fakete Luma, Sales International Coatings & Building Materials (CBM)Tel: +49 40 521 000 Fax: +49 40 521 00 244 [email protected] www.schuelke.com Trademarks: grotan, grotanol, parmetol, mikrocount Duo Regions covered: GlobalMIDDLE EAST HQ:Plastofab Technology Services PB 17883, Jebel Ali Freezone Dubai, UAE Contact: Syed Jaweed Alam, General ManagerTel: +971 4 881 4533 Fax: +971 4 881 4551 [email protected] www.schuelke-mayr.comSALES OFFICES & AGENTS: Intermediate for Chemicals & Trade (Jo)MYKO Engineering (il)Roumieh Trade (Sy)

SE Tylose GmbH & Co KG Rheingaustr. 190-19665203 WiesbadenGermanyContact: Mr Dominik ForstnerRegional Sales ManagerTel: +49 (0)611 962 6328Fax: +49 (0)611 962 [email protected]

www.setylose.com Trademark: Tylose

Shamrock Technologies Heersterveldweg 21 B-3700 TongerenBelgium Contact: Mr Jelmer Henskens, Marketing Leader Tel: +32 12 45 83 30 Fax: +32 12 45 83 40 [email protected] www.shamrockeurope.com Regions covered: GlobalSALES OFFICES & AGENTS: Tawazon Chemical (Dz, Bh, Eg, Ir, Jo, Kw, Lb, Ma, Ng, Om, Qa, Sa, Sy, Tn, Ae, Ye)

Sibelco Specialty Minerals Europe

Op de Bos 300 6223 EP Maastricht The Netherlands Contact: Maarten Van Ham, Area Sales Manager Tel: +31 (0)43 3663777 Fax: +31 (0)43 3648272 [email protected] sibelco-specialty-minerals.euRegions covered: GlobalTrademarks: Minex, Portafer, Portafill A, Portafill G, Portafill H5, Portalum B, Portaryte, Sablocolor, Sibelite, Silverbond, Tital, Unispar

SiLi Sigmund Lindner GmbHOberwarmensteinacher Str 38, 95485 Warmensteinach GermanyContact: Christoph Ruppert, Sales Director Tel: +49 9277 9940 Fax: +49 9277 99499 [email protected] www.sili.eu Regions covered: Global Trademarks: SiLibeads, Dragonit, SiLiglit

Simab Resin Co3rd Floor, No 26, Fallahi Ave South Shiraz St, TehranIran 1435813541Tel: +98 21 8821 1216-18Fax: +98 21 8803 1067Contact: Pouya Parhami (Business Dep. Supervisor) [email protected] EAST HQ:3rd Floor, No 26, Fallahi Ave South Shiraz St, TehranIran 1435813541Trademarks: Simab ResinRegions covered: A/MESALES OFFICES & AGENTS: 3rd Floor, No 26, Fallahi Ave South Shiraz St, TehranIran 1435813541Agents: Eng Hossein Pour (Sales Manager & Master Technician) & P Parhami (Business and Export Dep Supervisor)

Solvay40 Rue De La Haie-Coq Aubervilliers 93360

FranceEugenie Wartel, Solvay Novecare Communication - EMEATel: +33 1 5356 54 16Fax: +33 1 5356 [email protected] www.solvay.fr Trademarks: Rhodoline®; Rhodasurf®; Rhodapex®;Rhodafac®; Abex®; Soprophor®; Sipomer®; Rhodiasolv®

Regions covered: GlobalMIDDLE EAST HQ:Orkila Holdings SAL10th Floor, 311 Saifi Building PO Box 16-6933, Tabaris Achrafieh, Beirut, LebanonTel: +961 1 218 862/3 or +961 1 218 852Fax: +961 1 218 [email protected] SALES OFFICES & AGENTS:Orkila (A, Ma, Tn, Ae,Dz, Eg, Ir, Jo, Lb, Ng, AP, Sy) Cyprus,Kenya; Iraq; Ivory Coast; Senegal; Ghana; South Africa

Sunkem End Urunleri Sanayi

GEPOSB 7 Cadde TR-41400 Gebze/KocaeliTurkeyContact: Arda Karakas, Commercial Manager Tel: +90 262 751 2515 Fax: +90 262 751 2568 [email protected] www.sunkem.com Regions covered: EEC, Non-EEC, A/ME Trademarks: Dolphin, Suncolor, Suntone, Unisun, UnitoneSALES OFFICES & AGENTS: Arab Tower Trading (Jo, Sy, Ae)

Synthomer Marketing Centre Europe/Middle East/Africa

Werrastr 1045768 MarlGermanyTel: +49 2365 49 2552Fax: +49 2365 49 1604 [email protected] East Sales:Synthomer FZEDubai Airport Free ZoneEast Wing Building 2 - Office No. 201PO Box 54645 DubaiUnited Arab EmiratesContact: David SpensleySales Director - Middle EastTel: +971 4 [email protected]: Water-based binders for coatings & construction: Axilat, Plextol, Revacryl, Emultex, Rohagit, Lipaton

Taak Resin Kaveh Chemical Co

1st Floor, No 26, Fallahi Ave South Shiraz St, TehranIran 1435813541Tel: +98 21 8821 1231-3Fax: +98 21 8821 2130

Contact: Pouya Parhami (Business Dep. Supervisor) [email protected] EAST HQ: 1st Floor, No 26, Fallahi Ave, South Shiraz St Tehran, Iran 1435813541Trademarks: Taak Resin Kaveh Chemical Company SALES OFFICES & AGENTS: 1st Floor, No 26, Fallahi Ave South Shiraz St, TehranIran 1435813541Agents: Eng Mohammad Rahman Mohseni (Sales Manager & Master Technician), Eng Rojin Ehyaee (Sales Rep & Master Technician) & P Parhami (Business and Export Dep Supervisor)Regions covered: A/ME

Tawazon Chemical PO Box 52161 DubaiUAEContact: Oussama Ghandour, Managing Director Tel: +971 4 3368 230 Fax: +971 4 3367 357 [email protected] www.tawazon.com Regions covered: A/ME

Thor Specialties SrlVia Del Pontaccio, 221020 Casale Litta (Va) ItalyContact: Mr Michele Vallario, Business Unit ManagerTel: +39 0332 1815311Fax: +39 0332 [email protected] Trademarks: Acticide Turkey Office:Thor Specialties srlTürkiye Istanbul Subesi19 Mayis Mahallesi Sumer sokak Zitas, Bloklari C1, Blok D:12 Kozyatagi, IstanbulTurkeyContact: Gul Oztoprak, Area Sales Manager Tel: +90 216 6586285/6 Fax: +90 216 6586287 [email protected] OFFICES & AGENTS: Zen Fze (Ae, Bh, Kw, Om, Qa, Sa, Ye)Indec Industrial Chemicals & Equipment (Lb)Siwa for Import, Export and Agencies (Eg)Omnichem (Sy)Ayoub Trading Company (Jo)

TQC BVMolenbaan 19, 2908LL Capelle aan den IJsselThe NetherlandsContact: Raoul KleinveldTel: +31 (0)10 79 00 108Fax: +31 (0) 10 79 00 [email protected]: TQC, DewCheck, CureView, CurveX, PowderTAG

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Regions covered: GlobalMIDDLE EAST HQ:TQC BVMolenbaan 19, 2908LLCapelle aan den IJsselThe NetherlandsContact: George N MoonenTel: +31 (0)10 79 00 105; (0)10 79 00 100Fax: +31 (0)10 79 00 [email protected] OFFICES & AGENTS: Venktron DMCCJumeirah Lake Tower,PO Box 474054, Dubai, UAE.Tel: +9714 [email protected], [email protected]

Vibro-Mac Srl Via Primo Maggio 2/4 20070 San Zenone Al Lambro (Milano) ItalyContact: Mr Marco Gerosa, General Manager Tel: +39 02 9826 4390 Fax: +39 02 9826 4392 [email protected] www.vibromac.it Regions covered: GlobalSALES OFFICES & AGENTS: ICA Industrial & Chemical Agencies (Eg) Indec Industrial Chemicals & Equipment (Lb),Technopolymere (Tunisia)

Vinavil Egypt for Chemicals Industrial Zone, Attaqa SuezEgyptContact: Eng Said Omman, Plant Manager Tel: +20 62 230 501 Fax: +20 62 230 504 [email protected]/egSALES OFFICES & AGENTS: Obegi Chemicals (Lb)

VMA-GetzmannEuelerhammerstr 13 D-51580 Reichshof GermanyContact: C Getzmann, Managing Director Tel: +49 2296 8030 Fax: +49 2296 80333 [email protected] www.vma-getzmann.de Trademarks: Dispermat, TorusmillSALES OFFICES & AGENTS: Pine Truth Ltd (Cn)CIM Trading Co FZC (Ae)Egyptian co for Industrial and Scientific Services (Eg)Tavan Co Ltd (Ir)Weis Scientific Ltd (il)M A Al-Azzaz establishment (Sa)

Wacker Chemicals Middle East FZE

PO Box 341071Dubai Silicon OasisDubaiUAE

Tel: +971 4 709 9999Fax: +971 4 709 [email protected]: Cyril Cisinski, Managing DirectorTrademarks:Elastosil®, HDK®, Silres®,Vinnapas®, Vinnol®

Regions covered: MEAAgents & Distributors:For distributor information kindly visit: www.wacker.com oremail to [email protected] Distribution Manager: Murat Ciftci.

Whyte ChemicalsMarlborough House298 Regents Park Road FinchleyLondon N3 2UAUKContact: Ray Calladine, Director Tel: +44 208 346 5946Fax: +44 208 349 4589 [email protected] www.whytechemicals.co.uk Trademarks: Deviawhyte, Deviachem Regions covered: GlobalMIDDLE EAST HQ:Whyte Chemicals Dubai PO Box 17126, Jebal Ali, Dubai UAE Contact: Ghuldu Gurmukh, Managing Director Tel: +971 4 887 1288 [email protected] www.whytechemicals.co.ukSALES OFFICES & AGENTS: Pavilion Chemicals (Eg, il, Jo, Kw, Lb, Ma, Sa, Tn, Ye)

X-Rite Europe - European Headquarters

Althardstrasse 70Regensdorf 8105SwitzerlandContact: Simone ViscomiSales Director Turkey and MEA Industrial, Graphic Art and Pantone XRite GmbHTel: +39 335 [email protected]; www.xrite.comRegions covered: Il, Jo, Lb, Sy, Tr, Eg, Ae, Kw, Ng, Qa, Sa, Et, Ke, Mg, Om, Mz, Ug, Tz, Za

Yantai Dongyuan Powder Equipment

5-1 APEC Science & Technologies Industry Gardens Yantai 264002 PR ChinaContact: Liu Gejun, General Manager Tel: +86 536 684 6842Fax: +86 536 684 6843 [email protected]; www.ytgj.com.cn Regions covered: Cn, A/ME

Yantai East Sea Machinery & Electricity Tech

N 32 Zhujiang Road, Yantai ET DZ 264006 PR ChinaContact: Mr Hanli Chun

Managing Director Tel: +86 535 639 8125 Fax: +86 535 690 2145 or +86 535 639 8126 [email protected]: Powder coating production lines (eg mixers, extruders, cooling belts, ACM grinding systems)

Yantai Lingyu Powder Machinery Ltd

6 Longchang RoadLaishan Industry ParkYantai 264003PR ChinaContact: Sherry Zhao, Sales Manager Tel: +86 535 691 9139Fax: +86 535 691 9129 [email protected] www.lingyumach.com Trademarks: Lingyu Regions covered: Global

Zehntner GmbH Testing Instruments

Gewerbestrasse 4 CH-4450 SissachSwitzerlandContact: Mr Peter Zehntner, Owner & Managing DirectorTel: +41 61 953 05 50Fax: +41 61 953 05 [email protected] OFFICES & AGENTS: Algeria:Socemi6, avenue SébastopolFR-57070 MetzFranceContact: Bernard JacobyTel: +33 387 74 51 48 / +33 387 64 25 65Fax: +33 387 74 53 [email protected]:Color ZoneArcadia branch office:PO Box - 10222SA-21433 Jeddah Saudi ArabiaContact: Mrs Samia M Al-Aydeross Tel: +966 2 6693 170 Fax: +966 2 6693 109 [email protected]:Precisa International (Shanghai) Co LtdRoom 402, Building B, No 808 Hongqiao Rd, Xuhui District Shanghai 200030PR ChinaContact: Albert Lin, Sales ManagerTel: +86 21 6447 7888Fax: +86 21 6448 3377Email: [email protected]:Sadex Technical Consulting & Agencies6/8 Ahmed Farid Pasha StrDream House Tower, LoranEG-21411 AlexandriaEgyptContact: Mr Mohamed Abdel-

SadekTel: +20 3 5832 299Fax: +20 3 5848 [email protected]:Beesh Agahan Fan Tehran Inc Ltd, Flat 10, 88, 3rd Golestan, 3rd Boustan, IR-14716 TehranIranContact: Mr Morteza PasianiTel: +98 21 440 810 44Fax: +98 21 441 493 38Israel:WeisScientific Ltd13 Mor’an Street IL-36576 Timrat IsraelContact: Mr Arie Weiss Tel: +972 4 644 15 75 Fax: +972 4 644 06 20 [email protected] [email protected]:Color ZoneArcadia branch officePO Box - 10222SA-21433 Jeddah Saudi ArabiaContact: Mrs Samia M Al-Aydeross Tel: +966 2 6693 170 Fax: +966 2 6693 109 [email protected]:Socemi6, avenue SébastopolFR-57070 MetzFranceContact: Bernard JacobyTel: +33 387 74 51 48 / +33 387 64 25 65Fax: +33 387 74 53 [email protected]:Color ZoneArcadia branch officePO Box - 10222SA-21433 Jeddah Saudi ArabiaContact: Mrs Samia M Al-Aydeross Tel: +966 2 6693 170 Fax: +966 2 6693 109 [email protected]:Color ZoneArcadia branch officePO Box - 10222SA-21433 Jeddah Saudi ArabiaContact: Mrs Samia M Al-Aydeross Tel: +966 2 6693 170 Fax: +966 2 6693 109 [email protected] Arabia:Color ZoneArcadia branch officePO Box - 10222SA-21433 Jeddah Saudi ArabiaContact: Mrs Samia M Al-Aydeross Tel: +966 2 6693 170 Fax: +966 2 6693 109 [email protected]:Socemi6, avenue Sébastopol

FR-57070 MetzFranceContact: Bernard JacobyTel: +33 387 74 51 48 / +33 387 64 25 65Fax: +33 387 74 53 [email protected]:Color ZoneArcadia branch officePO Box - 10222SA-21433 Jeddah Saudi ArabiaContact: Mrs Samia M Al-Aydeross Tel: +966 2 6693 170 Fax: +966 2 6693 109 [email protected]

If you would like to update your details or include your company in this listing, please email:[email protected]

AM: AmericasAP: Asia PacificCn: ChinaEEC/non-EEC - EuropeA/ME: Africa/Middle East Ae: UAEBh: BahrainDz: AlgeriaEg: EgyptIr: Iranil: IsraelJo: JordanKw: KuwaitLb: LebanonLi: LibyaMa: MoroccoNg: NigeriaOm: OmanQa: QatarSa: Saudi ArabiaSA: South AfricaSy: SyriaTn: TunisiaYe: Yemen

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SECTION REPORT

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COUNTRY FOCUS

UK paint sector pre-occupied with Brexit as growth continuesStrategic alliances are being forged, documents published and negotiating positions rehearsed in a bid to ensure the industry is not adversely affected once the UK leaves the EU, as Sarah Gibbons writes

It is fair to say the eyes of the UK paint and

coatings industry are firmly on Brussels

and Downing Street now that Article 50

has been triggered and negotiations on

Britain quitting the European Union (EU)

are now under preparation. Indeed, it is no

exaggeration to say that the EU has a huge

influence on the industry – from regulatory

systems to innovation grants, imports and

exports, the EU holds a pivotal role.

So, companies and industry experts

are engaged. Strategic alliances are

being forged, documents published and

negotiating positions rehearsed in a bid

to ensure the industry is not adversely

affected by any ‘divorce settlement’ once

the UK leaves the EU in two years’ time.

“Historically, the UK has been an

attractive place to manufacture and it’s

imperative that this continues post Brexit”,

warned Tom Bowtell, CEO of the British

Coatings Federation (BCF).

OPERATING COSTS CONSTRICTAlready tight operating costs have been

squeezed by the fall in the value of Sterling

since the UK voted to leave the EU last

June, driving up the prices of raw materials,

many of which are sourced from the

remainder of the EU.

“The option of a ‘hard Brexit’, which

would see all customs, regulatory and

migration ties with the EU severed, could

add up to 6.5% to the cost of raw materials.

Further, an additional 6.5% tariff on finished

goods under WTO rules for coatings and

inks may be handed down to industry,

impacting global manufacturers and SMEs

alike”, said Bowtell.

The UK is a net exporter of paint and

inks – and most recent figures from 2015

show that 58% (£543M/US$677M) of the

£936M (US$1.16bn) UK-exported coatings

and printing inks in 2015 went to the EU.

The BCF wants the negotiation to

remove tariffs from chemicals and finished

goods, such as coatings and printing

inks. And critically, it wants to avoid being

alienated from the European chemicals

regulatory framework REACH, as the BCF

fears multinational companies in the sector

would then move production away from

Britain to mainland Europe.

The REACH registration process is now

almost completed – the final deadline for

registering chemicals made and used in

the EU is in 2018. So, “to have a separate

UK registration system for the thousands

of raw materials used in UK coatings

and printing ink production would be

completely uneconomic for BCF members”,

said Bowtell.

In a move set to raise its voice for the

sector during the brokering of a trade deal,

the BCF has become an affiliate partner of

EEF, the manufacturers’ organisation, to

fight for a competitive post-Brexit future.

In a recent BCF member survey, 75% of

respondents said they saw Brexit as a risk

rather than an opportunity.

Steve Elliott, Chief Executive of the

Chemical Industries Association (CIA) said

the UK’s exit terms are “critically important

for the sector”.

“In these negotiations, there is much

more to unite the European chemical

industry than divide us, with minimal

disruption to our current trading

relationships being our collective goal”, he

told Polymers Paint Colour Journal.

The CIA’s Brexit manifesto: ‘Exiting the

European Union’ backs calls for a tariff-free

single market, identifies the USA, China

and South Korea as key future trading

partners and suggests “our departure

could provide circumstances for more

favourable regulation, using a risk-based

approach and a respect for sound science

that fosters innovation”.

HORIZON 2020 PROJECTSOne important guarantee is that UK

projects under way through the EU’s

Horizon 2020 research scheme are

UK

“The option of a ‘hard Brexit’, which would

see all customs, regulatory and migration ties with the EU severed, could add up to 6.5% to the cost of raw materials.

SECTION REPORT

50 PPCJ • June 2017www.coatingsgroup.com

COUNTRY FOCUS

guaranteed funding throughout their

lifetime – for instance, projects devised

under Horizon 2020’s ‘Climate action,

environment, resource efficiency and raw

materials’ section.

For example, London-based AM

Technology Ltd is in receipt of €1.2M of

EU funding to develop an innovative paint

based on its ‘airlite’ technology that can

transform any surface into a natural air

purifier, using only light. The durable paint

will not require maintenance and will be

able to eliminate mould, bacteria and bad

smells, and repel dirt.

In its 2016 report, ‘Paint, Wallcoverings

and Woodcare’, UK construction sector

market researchers AMA Research

estimated the UK industry, minus industrial

and automotive coatings, was worth

£594M (US$741M) in 2015 – up 3% on

2014 and 12% since £532M (US$663M) in

recessional 2009.

Improvements in the housing market

and an upbeat economic forecast were

behind the rise, it claimed. Looking

ahead, it predicted: “The current positive

conditions in the housing market are

expected to prevail in the short to medium

term and will continue to drive demand

for decorative paints and effects into the

medium-term”. Annual value growth in

the decorative paint and coatings (plus

wallpaper) sector of around 2%-3% is

currently forecast to 2020 to reach £665M

(US$896M), although it notes that volatile

raw material costs could have a bearing on

overall performance figures.

Their research also points to a return

of ‘do it for me’ in a move away from DIY

trends, as consumer skills appear to be

reducing in this area at a time when they

are feeling more confident in the economy

so willing to outlay additional income on

hiring professional decorators.

ENVIRONMENTALLY FRIENDLY PAINTS

Meanwhile, water-based paints have

continued to dominate the market, with

rising sales reflecting increasingly restrictive

VOC regulations and higher levels of

consumer awareness, as well as the wider

availability of eco-friendly paints.

Adverse weather has also been behind

market demand with sales of paint and

woodcare products increasing to repair

2013-14 winter storm damage across

the country.

Regarding another key environmental

issue – waste – with most of the 55M litres

of leftover paint in the UK making its way

to landfill, the BCF has created PaintCare,

a programme linking industry and waste

authorities to create a solution to the issue,

which saves local governments money

and returns unwanted paint into reuse and

remanufacturing. PaintCare is calling on the

government to stipulate 5% of government

painting contracts use a significant

percentage of remanufactured paint to

boost the available market.

This will benefit manufacturers, such

as Newlife Paints, which produces award

winning emulsion paint produced from

at least 50% recycled waste paint. It will

also utilise Community RePaint, a national

network, sponsored by Dulux, which

in 2014 alone redistributed more than

300,000lit of paint to community groups,

charities, voluntary organisations and

people in need.

Dulux owner, AkzoNobel last year

opened its second innovative not-for-

profit paint remanufacturing plant in the

Wirral, north-west England, as part of

its undertaking to produce 100,000lit

of remanufactured paint by the end of

this year.

As for greening manufacturing, Slough-

based inks and coatings manufacturer Sun

Chemical, has collaborated with packaging

provider Smurfit Kappa to produce a digital

laser-based coding solution SunLase,

allowing customers to mark cartons at the

end of the manufacturing process offering

an efficient replacement to direct thermal

labelling, speeding up the packaging line

and driving operational savings.

The company has also teamed up

with Den Hartogh Logistics to design

customised tanks to transport its flush

product for publications via intermodal

transport, not simply road haulage. The

new products are better insulated, meaning

lower energy consumption and have an

increased payload to reduce journeys.

Meanwhile, despite the potential

disruption of Brexit, consolidation and

innovation continues in the UK sector. In

October 2016, Sun Chemical acquired

Wales’ Gwent Electronic Materials Ltd,

a leading manufacturer of conductive

inks, pastes and powders for the printed

electronic market, for instance.

And new UK products include Pro-Netic,

a water-based, magnetic chalkboard paint

from Yorkshire’s Coo-Var, which provides a

matte black finish when used with a brush

and creates a magnetic surface. PPCJ

For more information, contact: www.internationalnewsservices.com

Sun Chemical, with

Smurfit Kappa, has

produced a digital

laser-based coding

solution, SunLase, for

marking of cartons

Testing laboratory at NewLife

Paints, which produces emulsion

paint from around 50% recycled

waste paint

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SPECHEM CHINA 2017

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52 PPCJ • June 2017www.coatingsgroup.com

SHOW REVIEW

Once again the European Coatings

Show held in Nuremberg from

April 4-6, did not disappoint. Some

40 nations took part providing more than

30,000 trade visitors with their knowledge

and expertise within the coatings industry.

The exhibition filled seven halls, with a

Chinese pavilion, group pavilions of the

Czech Republic and the Republic of Korea.

With so many stands and exciting

innovations on show, it was difficult to

get around to see all of them, so in these

pages are some of the solutions provided

by international companies, which caught

my eye.

First was a visit to the Lanxess stand,

when Stephan Spiegelhauer, Head

of Global Competence Center Paints

& Coatings, BU Inorganic Pigments,

Lanxess, spoke about the company’s

pigments market. It has now completed

its investment in China, with a market still

growing in sustainable pigments. Lanxess

supplies sustainable pigments and has

longterm partnerships with its customers.

“Lanxess is the supplier of choice and

its investment in Ningbo, which is a

major step, was limited in chemistry and

physics abilities, so we looked at existing

technology and found how to produce

these bright red pigments, hence the

development of the Ningbo process, which

has virtually the same materials but with

zero emissions”. The plant was completed

last year and is now producing a new range

of pigments, ie bright yellows, in several

applications, including construction. One

of the highlights was the Bayferrox iron

oxide pigments, which are manufactured

at the Ningbo site. Lanxess emphasises

that sustainability is paramount and it will

not compromise.

Lanxess is looking to increase its

capacities for iron oxide pigments by

around 23,000t by 2019, with expansion at

its Krefeld-Uerdingen, Germany and Porto

Feliz, Brazil sites.

Speaking to Felix Schmollgruber,

Head Application Engineering & Technical

Support EMEA and Antoine Preisig,

GM EMEA at X-Rite, I was shown

the latest developments in bench top

spectrophotometry but of particular

interest was an App, which can be used

to match a colour by simply focussing on

the colour choice and obtaining the correct

shade. Color-Eye, is a solution that helps

consumers shop for products whose colour

accurately matches the colour of items

they have at home. Shoppers can use their

smartphone with a colour calibration card

to measure the colour of any item they want

to match. The colour readings sync with

a retailer’s mobile shopping application to

show the consumer a set of matching or

co-ordinating products.

Pantone shades are available in

colour libraries for different applications,

whether paper cups, industrial or inks on

paper print. It is also easier for decorative

applications, for paint manufacturers as

they can match colours. The colour data

libraries can measure and match shades in

a controlled environment.

Also on show was the Ci7860 Bench top

Spectrophotometer – the industry’s most

advanced colour measurement instrument

that reduces the margin of error when

communicating colour specifications for

plastics, coatings or textiles across the

supply chain and ensures the highest level

of colour accuracy and control throughout

the entire production process. This has a

high accuracy from 1-5mm.

Speaking to Perstorp, its hot topic was

the launch of its cationic UV curing range

of boosters, Curalite. With speeds up to

15x faster reactivity, this enables higher

line speeds. Free from odour and non-toxic

This year’s European Coatings Show heralded a record number of visitors to Nuremberg

in April and exhibitors had plenty to talk about as Sue Tyler reports

Innovations on display in Germany

53 PPCJ • June 2017www.coatingsgroup.com

SHOW REVIEW

the advantages and the message Perstorp

wishes to convey is the safety of use in

food packaging, where low migration,

low odour and scratch resistance are

key considerations.

As well as highlighting the Curalite

range, Perstorp also presented on its stand

the comeback of alkyd resins technology,

offering a low carbon footprint and wood

protection with its renewable Penta –

Voxtar. With its intumescent paints, its

Charmor range is used to provide more

time to escape from burning buildings; and

its Capa 4101, high performance polyol

for tough conditions in two component

polyurethane coatings.

Once again, I had the opportunity to

speak to Patrick Niels, President of Resins

& Functional materials, DSM. He was proud

to speak about the exciting sustainable

coating including DSM’s Decovery plant-

based resin. Besides the already available

interior wall paint, DSM Coating Resins

developed an industrial furniture version

called Iridea Bio.

Iridea Bio can be used in interior

wood applications. It was developed

jointly between DSM and Italian paint

manufacturer, ICA Group. As Decovery

resins are made from renewable resources

and combine typical acrylic performance

with sustainability characteristics, the

coatings are more resilient, resistant to

chemicals and lightfast.

In fact, the whole of DSM’s stand at

the ECS was testament to the way the

company has sustainability in its DNA.

The booth was made as much as possible

out of recyclable materials and had Niaga

carpets on the floor. The latter plays

an important part in waste elimination,

as these carpets are 100% recyclable.

Designing new materials to use, the second

largest carpet manufacturer in the world is

utilising this new chemistry. Fully recyclable,

the aesthetics are the same and the

carpets feel like carpets!

A visit to the Merck stand is always

something to look forward to. This year,

the vibrant array of colours made it

impossible for anyone to miss the stand.

A Rolls-Royce featuring a magnificent

special effect pigment from Merck took

centre stage. Filip Roscam, Merck’s

Design Director, Performance Materials –

Pigments & Functional Materials, provided

in-depth information on the latest addition

to the company’s Xirallic NXT portfolio,

Cougar Red. Its intense chroma can be

used to enhance new or existing styling

options. Due to its colour intensity,

customers can achieve nearly the same

intensity offered by complex three-coat

formulations in just two application layers.

Used with black, it can add depth, offering

an interplay of effects.

Providing intense colour and

extraordinary brilliance, Meoxal Victoria

Red will bring a touch of Australia’s Great

Victoria Desert to innovative stylings. At

ECS, visitors gained a first impression

of the possibilities the fourth pigment of

the Meoxal range will offer starting in late

2017 for designs, ranging from pure red to

bluish nuances.

The Merck portfolio also includes the

latest in the Iriotec 7000 range of specially

developed pigments, Iriotec 7340. These

feature light-coloured and conductive

pigments that offer functionality with little

impact on colour.

The market launch of the first non-ionic

fluorosurfactant, the new Tivida FL3000, is

also worth mentioning. With this addition,

Merck´s Tivida FL range now covers anionic

and non-ionic fluorosurfactants.

The Durazane range is completely new

in Merck´s functional portfolio. This product

group consists of polymers that harden

into ceramic once cured. Completely new

applications open up coating fields, such

as high-temperature, corrosion or easy-to-

clean applications.

Which colours will be hot? Merck

answers this question with its Global

Mobility Color Inspirations, a tool that

sums up the experiences, observations

and analyses of Merck´s trend researchers

around the world. Five trends for innovative

car body paints briefly describe the colours,

54 PPCJ • June 2017www.coatingsgroup.com

SHOW REVIEW

materials and social trends that will be

popular in the future.

What will the car of tomorrow look like?

The Intelligent Concept Car triggered the

imagination of visitors to the stand through

a fascinating insight: Wearing smart

glasses and in a virtual reality environment,

they could actually see such a car – with

weather-resistant effect pigments providing

high chroma for strong, deep colours and

with an innovative interior design created

with effect pigments that visually enhance

all kinds of materials, such as leather,

textile and plastics. The general concept of

this future car also includes autonomous

driving, online communication, adaptive

headlights and uniquely shaped displays

– all realised with innovative materials

from Merck.

This year Clariant, under the motto

‘Painted love; Its innovation. Its passion. Its

love’, chose a different format to present its

products to the media. Experts in the areas

of additives, pigments, UV and industrial,

spoke about market developments

and trends within these areas in small

concentrated sessions. Making their debut

at ECS were the first hazard label-free,

VOC/SVOC-free and renewable-based

neutralising agent for waterborne paints

and coatings, the Genamin Gluco 50;

Dispersogen SPS and SPG, biocide-

free mineral paints, which have been

awarded an EcoTain label for sustainability

excellence; Exolit fire protection ingredients

for intumescent coatings that also prolong

shelf life; AddWorks IBC 251, a tribo

enhancing additive for electrostatic powder

coatings; Hostabin TB-03, a UV absorber/

light stabiliser for solvent- and water-based

coatings; Linocare RBW, a new family of

waxes based on renewable feedstocks;

and for colouration, Clariant’s Hostatint A

100-ST, a range of nine non-halogenated,

ready to use, highly transparent pigment

preparations that offer the entire colour

circle to solvent-based paint systems.

Plus Hostatint UV, a colour range of high

performance, easy to use colourants for UV

cured wood coatings to support the trend

for colour UV systems.

Wacker, once again, provided its

comprehensive overview of its products via

its Trends in the Paints & Coatings Market

presentation on its stand. Its Primis SAF

9000 series of waterborne dispersions for

easy to clean floor and wall applications;

Silres BS 6920, a novel hybrid polymer

for stain-resistant impregnating agents or

cementitious-based floorings; and Silres BS

710 a concentrated silicone elastomer for

long-lasting anti-graffiti coatings.

Huntsman launched its low temperature

curing agents this year, with its Ara Cool

range, which enables formulators to

address the needs for faster processing

in cold and unpredictable weather

across a variety of industries, including

oil & gas, marine, transportation and

industrial maintenance.

The range includes Ara Cool 3077,

a multipurpose low temperature curing

hardener with zero-VOC. It is suitable

as a hardener for coatings and flooring

applications that have been designed to

deliver superior reactivity at temperatures

as low as 5°C and can be used as a

co-accelerator for slow hardeners. Ara

Cool 1047 W 80 is a surface tolerant low

temperature curing hardener that provides

corrosion protection for critical substrate

that require fast hardness development at

5°C or less. Ara Cool 1034 XW 90 is a low

temperature curing hardener with a long

pot life.

Speaking to Andrew Trapani, Technical

Director for Dow Coating Materials EMEAI,

he highlighted the company’s popular

and enduring developments. The two-

in-one PRIMAL PR-45 is a good primer

combined with stain blocking. This works

well on unpainted wood, with excellent

tannin blocking and adhesion properties,

which can be applied to concrete and

wood. “It is as good as any three coat

application and replaces three coats with

two – one type of paint – easier for the

consumer. As a true paint and primer

enabler PRIMAL PR-45 offers improved

marker stain-blocking capability for

hydrophilic stains. This new technology

‘locks’ stains into the first coat and then

covers stains with the second coat,

maintaining excellent topcoat properties.

This product is already available in the UK

and throughout Europe.”

PRIMAL ST-410 is for woodstains

and composite decking – a stabilisation

system for controlled erosion. The five

year accelerated testing proved really

good and talking to the market, it has

surpassed expectations.

PRIMAL ST-410, high performance

binder for stains replaces solvent-based

alternatives, while offering excellent

adhesion to metalised and exotic woods

with excellent appearance properties, flow

and wetting and hardness development.

Dow is working together with Europe

and changing its approach in the Middle

East, as there is a lot of potential with

the technology. The one coat application

has been developed for the Middle East

region, especially the Saudi Arabian

market and Andrew sees future, positive

steps following good response to more

ideas in this market. With the expansion

of Dow’s network, including Saudi, key

55 PPCJ • June 2017www.coatingsgroup.com

SHOW REVIEW

drivers, which are hot topics, are low VOCS

and sustainability.

Its acrylic epoxy hybrid (AEH), is easier

to work with; epoxy resins liquid acrylic,

which is a crosslinked epoxy hybrid

polamine or epoxy resins. The epoxy has

a very good UV resistance and is fast

drying. This is particularly beneficial for

flooring and driveways, as drying times

are very short. Benefits include no special

mixing; lower toxicity; user friendly; and DIY

and inexperienced people can achieve a

successful outcome from the application.

In a nutshell key benefits of MAINCOTE

AEH-10 resin include ultra-low VOC: <50g/

lit and increased productivity through fast

dry and re-coat, fast chemical/mechanical

resistance and longer pot life (up to one

working day). The improved durability is

due to better UV resistance, thus these

stable and easy-to-use waterborne

dispersions offer an improved performance

compared to waterborne epoxy systems.

There is a lot of interest out of the

Middle East, Africa and India, and there are

commercial systems planned.

Another innovation on show was

Dow CANVERA polyolefin dispersions,

providing progressive food and beverage

brand owners with a can coating made

from polyethylene resins, replacing epoxy

coating systems using BPA, bisphenols,

epoxies and other materials of concern

to consumers and regulators. CANVERA

uses Dow’s proprietary and patented

BLUEWAVE dispersion technology to

create an aqueous polyolefin dispersion,

applied directly to the interior metal surface

of cans using the same equipment as

current epoxy coatings. CANVERA makes

a very thin, protective, thermoplastic

lining with excellent food and flavour

retention, adhesion, corrosion protection,

and film flexibility. CANVERA polyolefin

dispersions utilise the existing can-

making infrastructure, facilitating world-

wide adoption.

Dow Coating Materials has been

working on this progressive technology

for several years and it is really exciting to

finally see it being adopted by the market

place. CANVERA polyolefin dispersions

offer a genuine breakthrough in can

coatings and are a great testimony of the

company’s ability to deliver science-based,

sustainable solutions that aim to improve

people’s lives.

For the first time, Songwon Industrial

Co Ltd was present, showcasing its

latest high performance solutions. The

company, which recently celebrated

its 50th anniversary, has grown from a

small organisation active mainly in Asia to

become the second largest manufacturer

of polymer stabilisers worldwide and

a global company with branches and

production facilities all over the world.

Sun Chemical Performance Pigments

introduced its Sunbrite Yellow 74 high

performance pigment at the show.

Its newest Azo yellow pigment for

architectural coatings was developed

specifically for decorative coatings

producers and the needs of machine

colourants. Easier to disperse than previous

grades, Sunbrite Yellow 74 pigments

deliver 15-20% more tint strength than

comparable products.

Highly desired by formulators because of

its colour point for existing and new VOC-

free colourant systems, Sunbrite Yellow

74 saves customers time and money, and

offers stronger lightfastness compared to

other low cost diarylide yellow pigments.

Also launched was Quindo Magenta 202

pigment, which delivers highly pigmented

bases in low-VOC, high-solid coatings.

Suitable for water and solventborne

systems, Quindo Magenta 202 enables

excellent styling for highly transparent and

chromatic effect shades, has excellent

durability and fastness properties for

automotive and high-performance coatings.

As a market leader in quinacridone

pigments, Sun Chemical offers the widest

colour index on the market with colour

options ranging from the brilliant orange

shade of Fastogen Super Red 209 to

the red shade Violet 55 for use in every

coating industry.

Sun Chemical Advanced Materials

introduced the newest addition to

the Fineplus HM reactive adhesives

product line from DIC Corporation. This

is a solvent-free 2K reactive hotmelt

adhesive designed to adhere to laminate

furniture, metal, plastics, textiles and

glass that replaces solvent-based

hotmelt adhesive chemistries. Ideal for

improving environmental performance,

ease of use and reliability in automotive

assembly, the full portfolio includes

amorphous, crystalline and liquid versions

of the high-quality polyester polyols for

reactive adhesives.

CONFERENCE IMPRESSES With more than 840 participants, the

European Coatings Show Conference

was even more heavily attended than in

previous years. More than 140 specialised

presentations by internationally renowned

speakers explored the production of paints,

sealing compounds, construction chemical

materials and adhesives.

The keynote speech at the Plenary

Session was given by Renaud Nicolaÿ,

a researcher from the École Supérieure

de Physiques et de Chimie Industrielles

de la Ville de Paris who studies covalent

bonds and their potential applications. In

his talk, ‘When every day plastics become

high-performance re-usable materials’, he

showed how to produce high-resistance

vitrimers with new properties, including

ease of deformation, self-healing capability

and recyclability – all while still maintaining

their original characteristics.

This year’s European Coatings Show

Award for the best submission went to Bas

Tuijtelaars from DSM Coating Resins. The

jury recognised his environmentally friendly

approach to making amine-free resins.

PPCJ

Contact: www.european-coatings-show.comImages: NürnbergMesse

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