helmistik 1685 - eldorado plywood

HELMISTIK 1685Product DescriptionA high heat resistance, high solids contact adhesive canister spray system with excellent dry time, initial tack and bond strength designed to bond HPL and other decorative overlays to common core materials (particle board, MDF, OSB, etc.).

Benefits 9 High tack 9 Excellent room temperature contact bonds 9 Excellent green strength and high heat resistance 9 Fast drying with a long open time 9 Bonds HPL, particleboard, plywood, steel, and many plastics 9 Portable and convenient

Suggested Uses• Lamination of High Performance Laminate (HPL) to particleboard

and/or MDF core materials in the fabrication of store fixtures, millwork, cabinets, work surfaces, decorative panels and similar products.

• Lamination of a wide range of porous and non-porous materials to themselves and each other including, but not limited to: HPL, melamine, wood veneer, decorative metal overlays, decorative plastic overlays, foam, fabric, some rubbers, some plastics.

• Do Not use with unbacked, plasticized vinyls.• Note: The use of plywood as a core material with HPL may void

the HPL manufacturers warranty.

Meet or Exceeds• LEED Indoor Environmental Quality Credit 4.4; Low Emitting

Materials: Composite Wood and Laminate Adhesives• No added urea-formaldehyde

• January 2017 CARB VOC Limits For Web Spray Adhesives

Physical PropertiesBase: Synthetic rubberCoverage: 17 oz aerosol can - 25 - 35 ft2

38 lb Canister - 1000 - 1250 ft2 177 lb canister - 4900 - 5900 ft2 355 lb canister - 9700 - 11700 ft2Open Time: 60 minutesColor: Natural (1685) Green (1685GR)VHAP: 2.57 lb/lb of solidsVOC (canister): 3.49 lb/gal (418 g/L); less water and exempt solventsVOC (aerosol): <40%

Handling & Storage• 12 month shelf life from date of manufacture.• Rotate stock to use the oldest material first.• Freeze/Thaw Stable; if chilled below 5°C/41°F – agitate well

after first warming to 22°C/72°F• Store between 10°C/50°F and 32°C/90°F.• Keep container tightly closed and store off of the floor when

not in use.• Avoid exposure of canisters to direct sunlight.• Use at room temperature, 18°C/65°F, or warmer. For best

results use above 21°C/72°F. • Do not apply or make bonds at temperatures below

18°C/65°F.

Packaging38 lb, 177 lb, 355 lb canisters and 17 oz aerosol cans

Clean-Up• Use HELMITIN SOLVENT 665 or CITRUS CLEANER

HIGH PERFORMANCE CONTACT ADHESIVE CANISTER

HELMITIN ADHESIVESToll Free: 877.823.2624 [email protected] helmitin.com *SEE SDS FOR REGULATORY INFORMATION

HELMISTIK 1685

*SEE SDS FOR REGULATORY INFORMATION

HELMITIN ADHESIVESToll Free: 877.823.2624 [email protected] helmitin.com

APPLICATION GUIDELINES

Conditioning of MaterialsAllow the core and overlay materials to acclimate together at the same temperature and humidity for at least 48 hours before bonding. Optimum conditions are approximately 22°C/72°F and relative humidity of 45% - 55%. Provisions should be made for the circulation of air around the components.

Canister Equipment Set-up1. Attach and securely tighten each end of the adhesive supply hose to the matching fitting on the spray gun and canister. Turn the trigger pull adjusting nut to the fully closed

position to prevent accidental adhesive discharge from the spray gun.2. Check the fittings for tightness. Position and tighten the spray tip on the spray gun. Plumbers tape is recommended to ensure a tight seal. Slowly open the valve on the

canister to start the flow of adhesive and check for leaks. Partial opening is recommended initially. If there are no leaks, fully open the canister valve.3. Turn the trigger pull adjusting nut on the spray gun 3 - 6 times counterclockwise to allow the adhesive to flow when the trigger is pulled. Discharge the spray gun and adjust

the spray pattern to achieve a consistent spray of the desired width.

Adhesive Application1. Substrates to be bonded with HELMISTIK 1685 must be clean, dry and free from dust, dirt, grease, oils, solvents or any other contaminants.2. Hold spray gun at a consistent distance of 6 inches to 10 inches from the substrates producing a web pattern across the substrates with minimal overlap.3. The adhesive should be applied at a coating weight of 2.5 - 3 dry grams per ft2, at the same time achieving 80 - 100% coverage. Allow the adhesive to dry properly before

bonding.a. To check for dryness, use the back of your fingers and press into the adhesive and lift up; any adhesive transfer or legginess indicates that more dry time is required.b. Do Not use the palm of your hand to check for dryness, it is often dirty and may leave oily residues which will interfere with bonding.c. Heavy areas on the adhesive may form a skin on the surface of the adhesive. Press the back of your fingers into the adhesive and twist to tear the skin open. Allow more dry

time.d. The adhesive is ready for bonding when it feels tacky, but there is no transfer or legginess.e. Drying time will vary depending on ambient temperature, humidity and coat weight. Drying time can be reduced by using air movement, drying ovens, etc.

4. Bonds can be made as soon as the adhesive is dry. Bonds made any time during the 60 minute open time will be as strong as those made immediately after drying. 5. Apply two coats of HELMISTIK 1685 to porous materials such as plywood and edges. Allow the first coat to dry (this will act as a sealer) before applying the second coat. Allow

the second coat to dry completely before bonding. This ensures that the adhesive does not soak in below the board surface and that there is enough adhesive on the surface to achieve a strong, permanent bond.

6. A dull appearance to the dry adhesive surface indicates that an insufficient amount of adhesive has been applied.7. Position the pieces carefully, as a strong irreversible bond is made instantly upon contact.8. Apply uniform pressure to ensure proper fusion of the adhesive surfaces. A pinch roller is the best method of applying pressure. Apply the maximum amount of pressure

possible without damaging the substrates. Minimum recommended pressure is 25 psi. This is easily achieved with a 3” J-roller.9. RUBBER MALLETS, BLOCKS OF WOOD, FLOORING ROLLERS, ETC. may not apply sufficient pressure to achieve good fusion of the adhesive surfaces and are not recommended.Note:• A drying issue called “Blushing” often occurs under extremely humid conditions. “Blushing” occurs when rapidly evaporating solvents cause the temperature of the adhesive

surface to drop below dew point. Condensation then forms on the surface of the adhesive and acts as a barrier to further drying; it also interferes with the fusion of the two glued surfaces and prevents them from bonding. All moisture MUST be completely evaporated before bonding. Moderate air movement (shop fan) is the preferred method to speed drying while reducing or eliminating “Blushing” issues. Bonds can be made once all moisture and solvents have completely evaporated.

• A failed contact adhesive bond with a shiny appearance to the surface of the adhesive is an indication that the recommended open time was exceeded and/or that inadequate laminating pressure was applied during assembly.

• Do Not Exceed the Recommended Open Time! Apply Sufficient Laminating Pressure

Frequent Use of Canister1. Leave the hose and gun assembly attached to the canister and leave the canister valve open. This will keep the hose and gun charged with adhesive. Completely close the trigger pull adjusting nut when not in use. Adjust the trigger pull adjusting nut as desired to continue spraying again.2. Regular gun and hose maintenance and cleaning is recommended for best performance. Clean the spray tip with HELMITIN SOLVENT 665 or HELMITIN CITRUS CLEANER on a daily basis to avoid excessive adhesive build-up. The use of metallic objects to clean the tip is not recommended as this will cause damage to the tip and create an irregular spray pattern.

Canister Storage/Change Over1. If the canister is not to be used for two weeks or longer, turn the canister valve completely off and dispense all material in the hose and gun assembly. Once empty and no pressure is present when the spray gun trigger is pulled, slowly disconnect the hose from the canister. Protect adjacent surfaces from any material that may drip from the hose.2. The hose and gun may be cleaned by attaching the hose to HELMITIN CITRUS CLEANER canister and flushing with a small amount of the cleaner. The hose may also be cleaned by removing the spray gun and manually flushing it with HELMITIN SOLVENT 665 or HELMITIN SOLVENT NF 699. Flushing the closed canister valve with HELMITIN SOLVENT 665 or HELMITIN CITRUS CLEANER will help to prevent any residual adhesive that is remaining in the valve from plugging it prior to the next use.

WarrantyBecause Seller has no control over methods of product application or conditions of use, its product is warranted only to be made of standard commercial grade materials and in conformance with Seller’s published specifications, if any. Any recommendations for the use of the product are based on tests or experience believed to be reliable and are furnished without compensa-tion, and Seller does not guarantee the applicability or the accuracy of this information or the suitability of its product in any given situation. Buyer must make its own tests to determine the suitability of Seller's product for Buyer’s particular use and Buyer assumes all risk and liability of use of Seller’s product.

HIGH PERFORMANCE CONTACT ADHESIVE CANISTER

HELMISTIK 1685 Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations Revision Date: 01/11/2019

Version: 1.3

01/11/2019 EN (English US) 1/8

SECTION 1: IDENTIFICATION Product Identifier

Product Form: Mixture Product Name: HELMISTIK 1685, HELMISTIK 1685GR

Intended Use of the Product

Use of the Substance/Mixture: No use is specified.

Name, Address, and Telephone of the Responsible Party

Company Helmitin Inc. 99 Shorncliffe Rd Toronto, Ontario, M8Z 5K7 877.823.2624 11110 Airport Road Olive Branch, MS 38654 Phone: 877.823.2624 www.helmitin.com

Emergency Telephone Number

Emergency Number : CANUTEC 613-996-6666 / CHEMTREC 1-800-424-9300

SECTION 2: HAZARDS IDENTIFICATION Classification of the Substance or Mixture Classification (GHS-US)

Simple Asphy H380 Flam. Gas 1 H220 Compressed gas H280 Skin Irrit. 2 H315 Eye Irrit. 2A H319 Carc. 2 H351 STOT SE 3 H336

Full text of H-phrases: see section 16

Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) :

GHS02

GHS04

GHS07

GHS08

Signal Word (GHS-US) : Danger Hazard Statements (GHS-US) : H220 - Extremely flammable gas.

H280 - Contains gas under pressure; may explode if heated. H315 - Causes skin irritation. H319 - Causes serious eye irritation. H336 - May cause drowsiness or dizziness. H351 - Suspected of causing cancer. H380 - May displace oxygen and cause rapid suffocation.

Precautionary Statements (GHS-US) : P210 - Keep away from extremely high or low temperatures, ignition sources, and incompatible materials. - No smoking. P261 - Avoid breathing vapors, mist, or spray. P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment.

HELMISTIK 1685 Safety Data Sheet According To Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations

01/11/2019 EN (English US) 2/8

Other Hazards Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. Flammable vapors can accumulate in head space of closed systems.

Unknown Acute Toxicity (GHS-US) Not available

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Mixture

Name Product Identifier % (w/w)

Methylene chloride (CAS No) 75-09-2 40 -70

Propane (CAS No) 74-98-6 10 - 30

Butane (CAS No) 106-97-8 10 - 30

SECTION 4: FIRST AID MEASURES Description of First Aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label if possible).

Inhalation: Remove to fresh air and keep at rest in a position comfortable for breathing. Obtain medical attention if breathing difficulty persists. Skin Contact: Remove contaminated clothing. Drench affected area with water or soap and water for at least 15 minutes. Wash contaminated clothing before reuse. Obtain medical attention if irritation develops or persists.

Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention.

Ingestion: Do NOT induce vomiting. Rinse mouth. Immediately call a POISON CENTER or doctor/physician.

Most Important Symptoms and Effects Both Acute and Delayed General: Causes serious eye irritation. May cause drowsiness and dizziness. Causes skin irritation. Suspected of causing cancer. Gas can be toxic as a simple asphyxiant by displacing oxygen from the air.

Inhalation: May cause drowsiness or dizziness. May displace oxygen and cause rapid suffocation.

Skin Contact: Causes skin irritation. Symptoms may include: Redness, pain, swelling, itching, burning, dryness, and dermatitis.

Eye Contact: Causes serious eye irritation. Symptoms may include: Redness, pain, swelling, itching, burning, tearing, and blurred vision.

Ingestion: Ingestion is likely to be harmful or have adverse effects.

Chronic Symptoms: Suspected of causing cancer.

Indication of Any Immediate Medical Attention and Special Treatment Needed

If you feel unwell, seek medical advice (show the label where possible).

SECTION 5: FIRE-FIGHTING MEASURES Extinguishing Media

Special Hazards Arising From the Substance or Mixture

P280 - Wear respiratory protection, protective gloves, protective clothing, face protection, eye protection. P302+P352 - IF ON SKIN: Wash with plenty of water. P304+P340 - IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P377 - Leaking gas fire: Do not extinguish, unless leak can be stopped safely. P381 - Eliminate all ignition sources if safe to do so.

Suitable Extinguishing Media: Water spray, fog, carbon dioxide (CO2), alcohol-resistant foam, dry chemical, or sand. Unsuitable Extinguishing Media: Do not use a heavy water stream. Use of heavy stream of water may spread fire.

Fire Hazard: Extremely flammable gas. Explosion Hazard: May form flammable/explosive vapor-air mixture. Reactivity: Reacts with (strong) oxidizers: (increased) risk of fire.


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Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Under fire conditions, hazardous fumes will be present. Firefighting Instructions: Exercise caution when fighting any chemical fire. Leaking gas fire: Do not extinguish, unless leak can be stopped safely. In case of leaking gas fire, eliminate all ignition sources if safe to do so. Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection. Hazardous Combustion Products: Burning can produce carbon monoxide, carbon dioxide, chloride and hydrocarbons. Carbon monoxide is highly toxic if inhaled; carbon dioxide in sufficient concentrations can act as an asphyxiant. Acute overexposure to the products of combustion may result in irritation of the respiratory tract.

Reference to Other Sections Refer to section 9 for flammability properties.

SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures

General Measures: Avoid all contact with skin, eyes, or clothing. Avoid breathing (gas). Use special care to avoid static electric charges. Keep away from heat, sparks, open flames, hot surfaces. – No smoking.

For Non-Emergency Personnel Protective Equipment: Use appropriate personal protection equipment (PPE). Emergency Procedures: Evacuate unnecessary personnel.

For Emergency Personnel Protective Equipment: Equip cleanup crew with proper protection. Emergency Procedures: Stop leak if safe to do so. Eliminate ignition sources. Ventilate area.

Environmental Precautions

Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

Methods and Material for Containment and Cleaning Up

For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams. Do not take up in combustible material such as: saw dust or cellulosic material. Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Spills should be contained with mechanical barriers. Transfer spilled material to a suitable container for disposal. Contact competent authorities after a spill. Use only non-sparking tools.

Reference to Other Sections

See Heading 8. Exposure controls and personal protection. For further information refer to section 13.

SECTION 7: HANDLING AND STORAGE Precautions for Safe Handling

Additional Hazards When Processed: Handle empty containers with care because residual vapors are flammable. Extremely flammable gas. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

Conditions for Safe Storage, Including Any Incompatibilities

Technical Measures: Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating, lighting equipment. Use only non-sparking tools. Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Keep in fireproof place. Keep/Store away from direct sunlight, extremely high or low temperatures and incompatible materials. Incompatible Materials: Strong acids. Strong bases. Strong oxidizers.

Specific End Use(s)

No use is specified.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control Parameters

Propane (74-98-6)

USA NIOSH NIOSH REL (TWA) (mg/m³) 1800 mg/m³

USA NIOSH NIOSH REL (TWA) (ppm) 1000 ppm

USA IDLH US IDLH (ppm) 2100 ppm (10% LEL)


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USA OSHA OSHA PEL (TWA) (mg/m³) 1800 mg/m³

USA OSHA OSHA PEL (TWA) (ppm) 1000 ppm

Butane (106-97-8)

USA ACGIH ACGIH STEL (ppm) 1000 ppm

USA NIOSH NIOSH REL (TWA) (mg/m³) 1900 mg/m³

USA NIOSH NIOSH REL (TWA) (ppm) 800 ppm

Methylene chloride (75-09-2)

USA ACGIH ACGIH TWA (ppm) 50 ppm

USA ACGIH ACGIH chemical category Confirmed Animal Carcinogen with Unknown Relevance to Humans

USA OSHA OSHA PEL (TWA) (ppm) 25 ppm

USA OSHA OSHA PEL (STEL) (ppm) 125 ppm (see 29 CFR 1910.1052)

USA IDLH US IDLH (ppm) 2300 ppm

Alberta OEL TWA (mg/m³) 174 mg/m³

Alberta OEL TWA (ppm) 50 ppm

British Columbia OEL TWA (ppm) 25 ppm

Manitoba OEL TWA (ppm) 50 ppm

New Brunswick OEL TWA (mg/m³) 174 mg/m³

New Brunswick OEL TWA (ppm) 50 ppm

Newfoundland & Labrador OEL TWA (ppm) 50 ppm

Nova Scotia OEL TWA (ppm) 50 ppm

Nunavut OEL STEL (mg/m³) 1737 mg/m³

Nunavut OEL STEL (ppm) 500 ppm

Nunavut OEL TWA (mg/m³) 347 mg/m³

Nunavut OEL TWA (ppm) 100 ppm

Northwest Territories OEL STEL (mg/m³) 1737 mg/m³

Northwest Territories OEL STEL (ppm) 500 ppm

Northwest Territories OEL TWA (mg/m³) 347 mg/m³

Northwest Territories OEL TWA (ppm) 100 ppm

Ontario OEL TWA (ppm) 50 ppm

Prince Edward Island OEL TWA (ppm) 50 ppm

Québec VEMP (mg/m³) 174 mg/m³

Québec VEMP (ppm) 50 ppm

Saskatchewan OEL STEL (ppm) 63 ppm 75 ppm (regulated under Dichloromethane)

Saskatchewan OEL TWA (ppm) 50 ppm

Yukon OEL STEL (mg/m³) 870 mg/m³ 720 mg/m³ (regulated under Dichloromethane)

Yukon OEL STEL (ppm) 250 ppm 200 ppm (regulated under Dichloromethane)

Yukon OEL TWA (mg/m³) 700 mg/m³ 720 mg/m³ (regulated under Dichloromethane)

Yukon OEL TWA (ppm) 200 ppm

Exposure Controls

Appropriate Engineering Controls: Gas detectors should be used when flammable gases/vapors may be released. Proper grounding procedures to avoid static electricity should be followed. Use explosion-proof equipment. Ensure adequate ventilation, especially in confined areas. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure all national/local regulations are observed.


01/11/2019 EN (English US) 5/8

Personal Protective Equipment: Protective goggles. Gloves. Face shield. Insufficient ventilation: wear respiratory protection. Full protective flameproof clothing.

Materials for Protective Clothing: Chemically resistant materials and fabrics.

Hand Protection: Wear chemically resistant protective gloves.

Eye Protection: Chemical safety goggles.

Skin and Body Protection: Wear suitable protective clothing.

Respiratory Protection: Use a NIOSH-approved respirator or self-contained breathing apparatus whenever exposure may exceed established Occupational Exposure Limits.

Environmental Exposure Controls: Do not allow the product to be released into the environment. Consumer Exposure Controls: Do not eat, drink or smoke during use

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Information on Basic Physical and Chemical Properties

Physical State : Gas (Aerosol)

Appearance : Amber, green

Odor : Etherial

Odor Threshold : Not available

pH : Not applicable

Evaporation Rate : Concentrate: 14.5 [Ref Std: n-Butyl acetate = 1.0]

Melting Point : Not available

Freezing Point : Not available

Boiling Point : Propellant: -24.4 °C (-11.9 °F) ; Concentrate: 39.8 °C (103.6 °F)

Flash Point : Propellant: -105 °C (-157 °F) (Tag Closed Cup); Concentrate: None

Auto-ignition Temperature : Concentrate: >556 °C (1032 °F)

Decomposition Temperature : Not available

Flammability (solid, gas) : Not available

Lower Flammable Limit : Propellant: 1.8%; Concentrate: 14.0%

Upper Flammable Limit : Propellant: 9.5%; Concentrate: 22.0%

Vapor Pressure : Propellant: 70 psig (3620 mmHg) @20 °C; Concentrate: 355 mmHg @20 °C

Relative Vapor Density at 20 °C : Not available

Relative Density : 1.20 g/mL (Concentrate)

Specific Gravity : 1.20 @ 20 °C (Concentrate)

Solubility : Not soluble in water

Partition Coefficient: N-Octanol/Water : Not available

Viscosity : Not available

Explosion Data – Sensitivity to Mechanical Impact : Do not subject aerosol products to mechanical impact.

Explosion Data – Sensitivity to Static Discharge : Not expected to present an explosion hazard due to static discharge.

VOC Content (SCAQMD Rule 1168) : 418 g/L (3.49 lbs/gal) VHAP Content : 2.57 lbs/lb solids


01/11/2019 EN (English US) 6/8

SECTION 10: STABILITY AND REACTIVITY Reactivity: Reacts with (strong) oxidizers: (increased) risk of fire.

Chemical Stability: Extremely flammable gas.

Possibility of Hazardous Reactions: Hazardous polymerization will not occur.

Conditions to Avoid: Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks.

Incompatible Materials: Strong acids. Strong bases. Strong oxidizers.

Hazardous Decomposition Products: Carbon oxides (CO, CO2). Decomposition may produce fumes, smoke, oxides of carbon and hydrocarbons.

SECTION 11: TOXICOLOGICAL INFORMATION Information on Toxicological Effects - Product

LD50 and LC50 Data: Not available

Skin Corrosion/Irritation: Causes skin irritation.

Serious Eye Damage/Irritation: Causes serious eye irritation.

Respiratory or Skin Sensitization: Not classified

Germ Cell Mutagenicity: Not classified Teratogenicity: Not classified

Carcinogenicity: Suspected of causing cancer.

Specific Target Organ Toxicity (Repeated Exposure): Not classified Reproductive Toxicity: Not classified Specific Target Organ Toxicity (Single Exposure): May cause drowsiness or dizziness.

Aspiration Hazard: Not classified Symptoms/Injuries After Inhalation: May cause drowsiness or dizziness. May displace oxygen and cause rapid suffocation. Symptoms/Injuries After Skin Contact: Causes skin irritation. Symptoms may include: Redness, pain, swelling, itching, burning, dryness, and dermatitis. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms may include: Redness, pain, swelling, itching, burning, tearing, and blurred vision. Symptoms/Injuries After Ingestion: Ingestion is likely to be harmful or have adverse effects. Chronic Symptoms: Suspected of causing cancer.

Information on Toxicological Effects - Ingredient(s) LD50 and LC50 Data:


LD50 Oral Rat 1600 mg/kg

LC50 Inhalation Rat 53 mg/l (Exposure time: 6 h)


IARC Group 2B

National Toxicology Program (NTP) Status In OSHA Hazard Communication Carcinogen list.

OSHA Hazard Communication Carcinogen List In OSHA Hazard Communication Carcinogen list.

OSHA Specifically Regulated Carcinogen List In OSHA Specifically Regulated Carcinogen list.

SECTION 12: ECOLOGICAL INFORMATION Toxicity

Ecology - General: Harmful to aquatic life.


LC50 Fish 1 140.8 - 277.8 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through])

EC50 Daphnia 1 1532 - 1847 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static])

LC 50 Fish 2 262 - 855 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])

EC50 Daphnia 2 190 mg/l (Exposure time: 48 h - Species: Daphnia magna)

Persistence and Degradability Not available

Bioaccumulative Potential

Acute Toxicity: Not classified


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BCF Fish 1 6.4 - 40

Log Pow 1.25

Mobility in Soil Not available

Other Adverse Effects

Other Information: Avoid release to the environment.

SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, provincial, territorial and international regulations. Additional Information: Handle empty containers with care because residual product is flammable. Ecology – Waste Materials: Avoid release to the environment.

SECTION 14: TRANSPORT INFORMATION In Accordance with DOT

Proper Shipping Name : CHEMICAL UNDER PRESSURE, FLAMMABLE, TOXIC, N.O.S.(Petroleum gases, liquefied; Methylene chloride)

Hazard Class : 2.1 (6.1)

Identification Number : UN3504 Label Codes : 2.1,6.1

ERG Number : 119

In Accordance with IMDG

Proper Shipping Name : CHEMICAL UNDER PRESSURE, FLAMMABLE, TOXIC, N.O.S. (Petroleum gases, liquefied; Methylene chloride)

Hazard Class : 2 Identification Number : UN3504 Label Codes : 2.1,6.1

EmS-No. (Fire) : F-D EmS-No. (Spillage) : S-U

In Accordance with IATA

Proper Shipping Name : CHEMICAL UNDER PRESSURE, FLAMMABLE, TOXIC, N.O.S. (Petroleum gases, liquefied; Methylene chloride)

Identification Number : UN3504

Hazard Class : 2 Label Codes : 2.1,6.1

*According to IATA, Forbidden to transport via passenger craft. If shipping on cargo aircraft, adhere to special provisions A1 and A187.

In Accordance with TDG

Proper Shipping Name : CHEMICAL UNDER PRESSURE, FLAMMABLE, TOXIC, N.O.S.(Petroleum gases, liquefied; Methylene chloride)

Hazard Class : 2.1 (6.1) (

Identification Number : 3504 Label Codes : 2.1,6.1

SECTION 15: REGULATORY INFORMATION US Federal Regulations

Propane (74-98-6)

Listed on the United States TSCA (Toxic Substances Control Act) inventory

Butane (106-97-8)

Listed on the United States TSCA (Toxic Substances Control Act) inventory

SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Fire hazard Delayed (chronic) health hazard


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Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313

SARA Section 313 - Emission Reporting 0.1 %

US State Regulations

Proposition 65 – WARNING: Cancer and Reproductive Harm - www.P65Warnings.ca.gov.

Propane (74-98-6)

U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List

Butane (106-97-8)

U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List


U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) - Special Hazardous Substances U.S. - Pennsylvania - RTK (Right to Know) List

Canadian Regulations

Propane (74-98-6)

Listed on the Canadian DSL (Domestic Substances List)

Butane (106-97-8)

Listed on the Canadian DSL (Domestic Substances List)


Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian IDL (Ingredient Disclosure List)

IDL Concentration 0.1 %

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all of the information required by CPR.

SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION

Revision Date : 01/11/2019 Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA

Hazard Communication Standard 29 CFR 1910.1200. GHS Full Text Phrases:

------ H220 Extremely flammable gas

------ H280 Contains gas under pressure; may explode if heated

------ H315 Causes skin irritation

------ H319 Causes serious eye irritation

------ H336 May cause drowsiness or dizziness

------ H351 Suspected of causing cancer

------ H380 May displace oxygen and cause rapid suffocation

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. North America GHS US 2012 & WHMIS 2015

helmistik 1685 - eldorado plywood

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