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DOE/RL-2018-06Revision 1

Calendar Year 2017 Criteria and Toxic AirEmissions Inventory

Prepared for the U.S. Department of EnergyAssistant Secretary for Environmental Management

P.O. Box 550 Richland, Washington 99352

Approved for Public Release; Further Dissemination Unlimited


Calendar Year 2017 Criteria and Toxic Air Emissions Inventory

D. L. DyekmanMission Support Alliance

Date PublishedApril 2018

Prepared for the U.S. Department of EnergyAssistant Secretary for Environmental Management

P.O. Box 550 Richland, Washington 99352

Release Approval Date

Approved for Public Release; Further Dissemination Unlimited

By Janis D. Aardal at 12:13 pm, Apr 10, 2018


TRADEMARK DISCLAIMER Reference herein to any specific commercial product, process, or service bytradename, trademark, manufacturer, or otherwise, does not necessarilyconstitute or imply its endorsement, recommendation, or favoring by theUnited States Government or any agency thereof or its contractors orsubcontractors.

This report has been reproduced from the best available copy.

Printed in the United States of America

DOE/RL‐2018‐06 Rev. 1

iii

Contents

1.0 Introduction ........................................................................................................................1

2.0 Emissions Estimates ...........................................................................................................2 2.1 Criteria and Toxic Emissions Listed by Pollutant ...................................................2 2.2 Criteria and Toxic Emissions Listed by Emission Point Identification ...................3 2.3 Criteria and Toxic Emissions Listed by Contractor .................................................4 2.4 Fuel Use ...................................................................................................................5

3.0 References ...........................................................................................................................6

APPENDIX A: Washington Emissions Inventory Reporting System - Facility Form ........ A-i Release Point for Unit 22 - Tank Farm Exhausters, 200 E Composite ......................... A-12 Release Point for Unit 23 - Tank Farm Exhausters, 200 W Composite ....................... A-14 Release Point for Unit 24 - 242-A Evaporator, 200 East Area ..................................... A-16 Release Point for Unit 25 - 200 Area Effluent Treatment, 200 E Area ........................ A-19 Release Point for Unit 26 - ESPC Distillate Oil Boilers, 200 Area Composite............ A-21 Release Point for Unit 27 - ESPC Natural Gas Boilers, 300 Area Composite ............. A-24 Release Point for Unit 28 - CWC Diffuse and Fugitive, 200 W Area .......................... A-27 Release Point for Unit 30 - T Plant Point Source and Fugitive, 200 W Area ............... A-31 Release Point for Unit 31 - WRAP Point Source and Fugitive, 200 W Area ............... A-35 Release Point for Unit 32 - Fuel Dispensing, Evaporative Losses, Area 200/600 ....... A-39 Release Point for Unit 33 - WTP Concrete Batch Plant, 200 Area .............................. A-41 Release Point for Unit 34 - WTP Pit 30 Quarry, 600 Area ........................................... A-51 Release Point for Unit 35 - Fuel Dispensing, Evaporative Losses, WTP. .................... A-53 Release Point for Unit 36 - WTP Heaters and Dehumidifiers ...................................... A-57 Release Point for Unit 37 - Sitewide Emissions from Diesel Fuel Combustion .......... A-61 Release Point for Unit 38 - Tank Farms Direct-Fired Hot Water Heaters .................... A-64 Release Point for Unit 39 - Site-wide Emissions from Propane Fuel Combustion ...... A-67 WEIRS Emissions Summary .............................................................................. A-69

APPENDIX B: Washington Emissions Inventory Reporting System - Emissions Summary ......................................................................................................................... B-i

Tables

Table 1. Criteria and Toxic Emissions by Pollutant .......................................................................2 Table 2. Calendar Year 2017 Criteria and Toxic Emissions by Emission Point ............................3 Table 3. Calendar Year 2017 Criteria and Toxic Emissions by Contractor ...................................4 Table 4. Calendar Year 2017 Fuel Use by Contractor ....................................................................5

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ACRONYMS

AEI Air Emissions Inventory AOP Air Operating Permit CO Carbon Monoxide CWC Central Waste Complex CY Calendar Year DOE Department of Energy Ecology State of Washington, Department of Ecology EPA U.S. Environmental Protection Agency Lbs pounds N/A Not applicable

NH3 Ammonia

NOx Oxides of Nitrogen

ORP Office of River Protection PM Particulate Matter PM‐10 Particulate Matter of diameter less than 10 microns PM‐2.5 Particulate Matter of diameter less than 2.5 microns PNSO Pacific Northwest Site Office RL Richland Operations Office SAW Secure Access Washington

SOx Oxides of Sulfur

STGC Standard Terms and General Conditions TAP Toxic Air Pollutant VOC Volatile Organic Compounds WAC Washington Administrative Code WEIRS Washington Emissions Inventory Reporting System WRAP Waste Receiving and Processing WTP Waste Treatment Plant

DOE/RL‐2018‐06 Rev. 1

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1.0 Introduction In accordance with Washington Administrative Code (WAC) chapter 173‐400 “General Regulations for Air Pollution Sources,” Section 105 and the Hanford Site Air Operating Permit (AOP), Number 00‐05‐06, Renewal 2, Revision B Standard Terms and General Conditions (STGC), Section 5.9, “Annual Air Emission Inventory,” the U.S. Department of Energy (DOE), Richland Operations Office (RL), Office of River Protection (ORP), and Pacific Northwest Site Office (PNSO), and their contractors on the Hanford Site are reporting their emissions inventories for calendar year (CY) 2017. The WAC 173‐400‐105(1) specifically requires the owner(s) or operator(s) of air contaminant sources to submit an air emissions inventory (AEI) each year. The inventory should include stack and fugitive emissions of particulate matter (PM), PM of diameter less than 10 microns (PM‐10), PM of diameter less than 2.5 microns (PM‐2.5), sulfur dioxides, oxides of nitrogen, carbon monoxide, volatile organic compounds (VOCs), ammonia, and other contaminants. This report contains the summary of emissions estimates from the Hanford Site for CY 2017 necessary to demonstrate compliance with these regulatory requirements. Additionally, the AOP STGC Section 5.9 states the emissions inventory shall be submitted no later than 105 days after the end of the calendar year and will contain information on air emissions:

a. For emission units as listed in the AOP Attachment 1, Section 1.4, and b. For emission unit composites as requested by Ecology.

The Washington State Department of Ecology has requested permittees submit air emissions inventories electronically through the Secure Access Washington (SAW) web based database Washington Emission Inventory Reporting System (WEIRS). The Ecology WEIRS system is the mechanism used to define the composite emission reporting categories. Once approved, cleared for public access and published, the emissions estimates in this report are entered into WEIRS database to satisfy the reporting requirement. Multiple Hanford contractors were solicited for emissions data and contributed to this report. All the AOP Attachment 1, Section 1.4 emission units were included in the contractor evaluations of emissions. Following is the list of contractors providing data:

Bechtel National, Inc.

CH2M HILL Plateau Remediation Company

Johnson Controls, Inc.

Mission Support Alliance

Pacific Northwest National Laboratory

Washington River Protection Solutions. Revision 1 of this document was created to address an issue with the format of data entry into the WEIRS database. The WEIRS database contains a data input quality check that requires total PM >=PM‐10>=PM‐2.5. The original data input for Emission Unit #37 did not meet this criterion and the database prevented DOE from electronically certifying the information. The PM emissions data was re‐characterized to satisfy the criterion. Additional editorial details included in revision 1 are: added specific Table of Contents entries for each emission point in Appendix A; added an acronyms list; added CY 2016 emissions to Table 1; added significant figures of reported numerical values in Tables 1 – 3 to better illustrate where numerical rounding has occurred; revised Table 4 natural gas units from therms to cubic feet; added a new Appendix B containing the WEIRS database Emissions Summary report, and finally a distribution page was added.

DOE/RL‐2018‐06 Rev. 1

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2.0 Emissions Estimates The following tables represent the CY 2017 air emissions inventory for the Hanford Site organized in various formats for future reference.

2.1 Criteria and Toxic Emissions Listed by Pollutant Table 1 lists the total sum of all emission sources by pollutant.

Table 1. Criteria and Toxic Emissions by Pollutant

Pollutant Calendar Year 2017 Emissions

(tons)

Calendar Year 2016 Emissions

(tons)

Carbon Monoxide (CO) 10.42 7.00

Nitrogen Oxides (NOx) 23.39 15.00

Particulate Matter (PM) 1.77 1.00

Particulate Matter less than 10 microns (PM10)

1.73 0.00

Particulate Matter less than 2.5 microns (PM2.5)

0.82 0.00

Sulfur Oxides (SOx) 1.27 0.00

Volatile Organic Compounds (VOCs) 4.77 5.00

Ammonia (NH3) 2.00 2.00

Other Toxic Air Pollutants (TAPs) 12.2 (pounds) 8.00 (pounds)

DOE/RL‐2018‐06 Rev. 1

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2.2 Criteria and Toxic Emissions Listed by Emission Point Identification Table 2 lists criteria and toxic air pollutants by emission point definitions provided by Ecology. These emission point identification numbers are used for AEI reporting purposes only.

Table 2. Calendar Year 2017 Criteria and Toxic Emissions by Emission Point

Emission

Point ID Emission Point Description

CO NOx PM PM10 PM2.5 SOx VOC NH3 TAPs

(Tons) (lbs)

22 Tank Farm Exhausters, 200E Composite

0.00 0.00 0.00 0.00 0.00 0.00 0.00 1.75 0.0

23 Tank Farm Exhausters, 200W Composite

0.00 0.00 0.00 0.00 0.00 0.00 0.01 0.04 0.0

24 242A Evaporator, 200E 0.00 0.00 0.00 0.00 0.00 0.00 0.26 0.05 9.0

25 200 Area Effluent Treatment, 200E

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.04 2.5

26 ESPC Dist. Oil Boilers, 200 Area Composite

0.54 1.14 0.11 0.08 0.02 0.01 0.10 0.04 N/A

27 ESPC Natural Gas Boilers, 300 Area Composite

5.62 2.50 0.30 0.30 0.30 0.01 0.32 0.08 N/A

28 CWC Diffuse and Fugitive, 200W Area

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.7

30 T Plant Point Source and Fugitive, 200W Area

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.0

31 WRAP Point Source and Fugitive, 200W Area

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.0

32 Fuel Dispensing, Evaporative Losses, Area 200/600

0.00 0.00 0.00 0.00 0.00 0.00 3.50 0.00 N/A

33 WTP Concrete Batch Plant, 200 Area

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 N/A

34 WTP Concrete Batch Plant, Pit 30 Quarry

N/A N/A 0.00 0.00 0.00 N/A N/A N/A N/A

35 Fuel Dispensing, Evaporative Losses, WTP Construction Site

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 N/A

36 WTP Heaters and Dehumidifiers

0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 N/A

37 Site‐wide Composite Emissions from Diesel Fuel Combustion

4.26 19.73 1.36 1.35 0.50 1.24 0.58 0.00 N/A

38 Tank Farms Direct‐Fired Hot Water Heaters

0.00 0.01 0.00 0.00 0.00 0.01 0.00 0.00 N/A

39 Site‐wide Composite Emissions from Propane Fuel Combustion

0.00 0.01 0.00 0.00 0.00 0.00 0.00 0.00 N/A

DOE/RL‐2018‐06 Rev. 1

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2.3 Criteria and Toxic Emissions Listed by Contractor Table 3 lists criteria and toxic air pollutants emitted by contractors working on the Hanford Site in calendar year 2017. An additional significant digit was added to the reported values for convenience of the reader.

Table 3. Calendar Year 2017 Criteria and Toxic Emissions by Contractor

(tons)

Contractor CO NOx PM PM10 PM2.5 SOx VOC NH3 TAPs

Bechtel National, Inc. 1.16 5.38 0.38 0.38 0.38 0.35 0.44 0.00 0.00

CH2M Hill Plateau Remediation Co.

0.23 1.05 0.07 0.07 0.07 0.07 0.09 0.00 0.00

Johnson Controls, Inc. 6.16 3.64 0.41 0.38 0.32 0.03 0.42 0.12 0.00

Mission Support Alliance 0.30 1.20 0.05 0.04 0.04 0.03 3.56 0.00 0.00


0.00 0.11 0.01 0.01 0.01 0.00 0.00 0.00 0.00

Washington River Protection Solutions

2.58 12.01 0.85 0.85 0.00 0.80 0.27 1.88 0.00

DOE/RL‐2018‐06 Rev. 1

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2.4 Fuel Use Table 4 lists the quantity of fuel use reported by Hanford Site contractors in CY 2017. As illustrated in this table, eight of the 17 emission points rely upon fuel use records and Environmental Protection Agency (EPA) emission factors published in AP‐42 “Compilation of Air Emissions Factors” to estimate emissions. This information is summarized here for reference.

Table 4. Calendar Year 2017 Fuel Use by Contractor

Contractor

Emission Point Identification Number

#26

(gallons)

#27

(cubic

feet)

#32

(gallons)

#35

(gallons)

#36

(gallons)

#37

(gallons)

#38

(gallons)

#39

(gallons)

Bechtel National, Inc. 0 0 0 34,097 87,120 17,818 0 83

CH2M Hill Plateau

Remediation Co. 0 0 0 0 0 3,465 0 0

Johnson Controls,

Inc. 109,541 4.85E+07 0 0 0 0 0 0

Mission Support

Alliance 0 0 771,182 0 0 4,918 0 831

Pacific Northwest

National Laboratory 0 0 0 0 0 606 0 0

Washington River

Protection Solutions 0 0 0 0 0 15,085 701 0

Totals 109,541 4.85E+07 771,182 34,097 87,120 41,892 701 914

DOE/RL‐2018‐06 Rev. 1

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3.0 References AP‐42: Compilation of Air Emission Factors, United States Environmental Protection Agency,

Washington, D.C. Online at: https://www.epa.gov/air‐emissions‐factors‐and‐quantification/ap‐42‐compilation‐air‐emission‐factors

Hanford Site Air Operating Permit 00‐05 Renewal 2 – Rev B, 2016, Washington State Department of

Ecology. Olympia, Washington. Online at: https://fortress.wa.gov/ecy/nwp/permitting/AOP/renewal/two/Revision_B/07_28_16/

WAC 173‐400, “General Regulations for Air Pollution Sources,” Washington Administrative Code,

Olympia, Washington. Online at: http://apps.leg.wa.gov/WAC/default.aspx?cite=173‐400

DOE/RL‐2018‐06 Rev. 1

A‐i

APPENDIX A: Washington Emissions Inventory Reporting System

Facility Summary Form

DOE/RL‐2018‐06 Rev. 1

A‐ii

This page intentionally left blank.

Facility SummaryDept. of Ecology Nuclear Waste Section

M-005-0009 U.S. Dept of Energy 2017

FACILITY OPERATIONS

Facility Category:NAICS Code:Facility Comments:

HAP and CAP Major924110Operating Status Year: 2017

Operating Status: Operating

FACILITY LOCATION

Coordinates:Reference Point:Comments:

Latitude: 46.27800 Longitude: -119.27500Entrance Point

Facility Address: Hanford ReservationRichland, WA 99352Benton County

Contact: Mr. Eric FaustPO BOX 550Richland, WA 99352(509) [email protected]

Release Point for Unit 22 - Tank Farm Exhausters, 200 E Composite

Release Point Type Status

Fugitive Operating

Stack Fugitive Comments

Height: not providedDiameter: not providedTemperature: not providedFlow Rate: not providedVelocity: not providedWater Vapor: not providedOxygen: not provided

Height: not provided Length: not provided Width: not provided Angle: not provided

The 12 tank farm exhausters vary in dimensions. The schematics have been previously provided in the AOP. Additional copies can be provided upon request.

Stack and Fugitive Release Point Coordinates

Fence Line Distance: not provided EPA Release Point ID: not provided

Reference Point: Facility Center Latitude: 46.56300 Longitude: -119.59900

Inventory Year: 2017 Site Code: M-005-0009Facility Name: U.S. Dept of EnergyPermitting Agency: Dept. of Ecology Nuclear Waste Section

DOE/RL-2018-06 Rev.1

A-1

Release Point for Unit 23 - Tank Farm Exhausters, 200 W Composite


Fugitive Operating




The 3 tank farm exhausters vary in dimensions. The schematics have been previously provided in the AOP. Additional copies can be provided upon request.




Release Point for Unit 24 - 242-A Evaporator, 200 East Area


Vertical Operating


Height: 62 ftDiameter: .7 ftTemperature: 111°FFlow Rate: 421 ACFMVelocity: 1,093.9 FPMWater Vapor: not providedOxygen: not provided


Mixed radioactive-dangerous waste evaporation; subject to RCRA Subpart AA.






A-2

Release Point for Unit 25 - 200 Area Effluent Treat, 200 E Area


Vertical Operating


Height: 50 ftDiameter: 6 ftTemperature: 85°FFlow Rate: 1,000 ACFSVelocity: 35.4 FPSWater Vapor: not providedOxygen: not provided


ETF processed waste throughout the reporting period.




Release Point for Unit 26 - ESPC Dist. Oil Blrs, 200 Area Compos.


Fugitive Operating









A-3

Release Point for Unit 27 - ESPC Nat Gas Blrs, 300 Area Compos.


Fugitive Operating







Release Point for Unit 28 - CWC Diffuse and Fugitive, 200 W Area


Fugitive Operating







Inventory Year: 2017Site Code: M-005-0009Facility Name: U.S. Dept of EnergyPermitting Agency: Dept. of Ecology Nuclear Waste Section


A-4

Release Point for Unit 30 - T Plant Point Source and Fugitive, 200 W Area


Fugitive Operating







Release Point for Unit 31 - WRAP Point Source & Fugitive, 200 W Area


Fugitive Operating









A-5

Release Point for Unit 32 - Fuel Dispensing, Evaporative Losses, Area 200/600


Fugitive Operating







Release Point for Unit 33 - WTP Concrete Batch Plant, 200 Area


Vertical Operating


Height: 25 ftDiameter: 2.5 ftTemperature: 68°FFlow Rate: 250 ACFSVelocity: 50.9 FPSWater Vapor: not providedOxygen: not provided


Stack parameters for concrete batch plant baghouse.






A-6

Release Point for Unit 34 - WTP Pit 30 Quarry, 600 Area


Fugitive Temporarily Shutdown




Pit 30 quarry operations temporarily shutdown during reporting period. Periodic stockpile removal occurred during reporting period.




Release Point for Unit 35 - Fuel Dispensing, Evaporative Losses, WTP Construction Site


Fugitive Operating




none






A-7

Release Point for Unit 36 - WTP heaters and Dehumidifiers


Fugitive Operating







Release Point for Unit 37 - Sitewide Composite Emissions from Diesel Fuel Combustion


Fugitive Operating




Release point for Unit 37 is comprised of multiple stationary diesel-powered engines, compressors, and generators.






A-8

Release Point for Unit 38 - Tank Farms Direct-Fired Hot Water Heaters Composite


Fugitive Operating




Unit consists of two units operating in C Tank Farm.




Release Point for Unit 39 - Site-wide Composite Emissions from Propane Fuel Combustion


Fugitive Operating




Unit is a composite of multiple units operated in various locations on the Hanford Site.




U.S. Dept of Energy UNITS

Unit ID: 22 Tank Farm Exhausters, 200 E CompositeUnit Type Status Capacity

690 - Other Process Equipment Operating capacity not provided Unit ID: 23 Tank Farm Exhausters, 200 W CompositeUnit Type Status Capacity

690 - Other Process Equipment Operating capacity not provided



A-9

Unit ID: 24242-A Evaporator, 200 East Area

Unit Type Status Capacity

490 - Other Evaporative Sources Operating capacity not provided Unit ID: 25 200 Area Effluent Treat, 200 E AreaUnit Type Status Capacity

690 - Other Process Equipment Operating capacity not provided Unit ID: 26 ESPC Dist. Oil Blrs, 200 Area Compos.Unit Type Status Capacity

100 - Boiler Operating capacity not provided Unit ID: 27 ESPC Nat Gas Blrs, 300 Area Compos.Unit Type Status Capacity

100 - Boiler Operating capacity not provided Unit ID: 28 CWC Diffuse and Fugitive, 200 W AreaUnit Type Status Capacity

999 - Unclassified Operating capacity not provided Unit ID: 30 T Plant Point Source and Fugitive, 200 W AreaUnit Type Status Capacity

999 - Unclassified Operating capacity not provided Unit ID: 31 WRAP Point Source & Fugitive, 200 W AreaUnit Type Status Capacity

999 - Unclassified Operating capacity not provided Unit ID: 32 Fuel Dispensing, Evaporative Losses, 200 AreaUnit Type Status Capacity

490 - Other Evaporative Sources Operating capacity not provided Unit ID: 33 WTP Concrete Batch Plant, 200 AreaUnit Type Status Capacity

290 - Other Combustion Operating 4 Million BTU Per Hour Unit ID: 34 WTP Pit 30 Quarry, 600 Area



A-10

Unit Type Status Capacity

300 - Open Air Fugitive Source Temporarily Shutdown

capacity not provided

Unit ID: 35 Fuel Dispensing, Evaporative Losses, WTP Construction SiteUnit Type Status Capacity

400 - Storage Tank Operating capacity not provided Unit ID: 36 WTP heaters and dehumidifiersUnit Type Status Capacity

290 - Other Combustion Operating 1 Million BTU Per Hour Unit ID: 37 Sitewide Composite Emissions from Diesel Fuel CombustionUnit Type Status Capacity

290 - Other Combustion Operating capacity not provided Unit ID: 38 Tank Farms Direct-Fired Hot Water Heaters CompositeUnit Type Status Capacity

290 - Other Combustion Operating 2.5 Million BTU Per Hour Unit ID: 39 Site-wide Composite from Propane Fuel CombustionUnit Type Status Capacity

160 - Reciprocating IC Engine Operating capacity not provided



A-11

Insignificant Emissions Unit? No

U.S. Dept of Energy PROCESSESUnit ID: 22 Process ID: 01 Process Description: not provided SCC CODE: 39999999 - Misc Manuf / Indus Processes /Other Not Classified

Fuel Parameter Content

Sulfur: no entry

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

25 %

25 %

25 %

25 %

Hours/Day 24.0

Days/Week 7.0

Weeks/Year 52

Hours/Year 8,760

sum of quarters must be 100%

Comments: 12 exhausters operated continuously and/or intermittently throughout the reporting year.

OPERATING SCHEDULE

ANNUAL THROUGHPUTOperating Type:

Material State:

Throughput and Units:

Material:

Status:Operating

RELEASE POINT APPORTIONMENTRP ID Description Ave Emissions (%)

22 Release Point for Unit 22 - Tank Farm Exhausters, 200 E Composite 100%

CONTROL APPROACHFirst Year Implemented: 2008

Control Approach Desc: Controlledcapture efficiency: % effectiveness: %

Control Measure:

High-Efficiency Particulate Air Filter (HEPA)

Control Pollutant:

PM10 Primary (Filt + Cond) 99.9% efficiency

PM2.5 Primary (Filt + Cond) 99.9% efficiency

PM Primary (Filt + Cond) 99.9% efficiency



A-12

EMISSIONS

U.S. Dept of Energy M-005-0009Unit ID: 22 Process ID: 01

CO - Carbon Monoxide 0.00 TONCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered

NOX - Nitrogen Oxides 0.00 TONCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered

PM10-PRI - PM10 Primary (Filt + Cond) 0.00 TONCalculation Method: Engineering JudgmentEmission Factor: Emission Factor Desc: none enteredComments: none entered

PM25-PRI - PM2.5 Primary (Filt + Cond) 0.00 TONCalculation Method: Engineering JudgmentEmission Factor: Emission Factor Desc: none enteredComments: none entered

PM-PRI - PM Primary (Filt + Cond) 0.00 TONCalculation Method: Engineering JudgmentEmission Factor: Emission Factor Desc: none enteredComments: none entered

SO2 - Sulfur Dioxide 0.00 TONCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered

VOC - Volatile Organic CompoundsVOC Expression: Unknown 0.00 TONCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: Calculation of air emissions sample data.

NH3 - Ammonia 1.75 TONCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: Calculation of air emissions sample data.



A-13




Sulfur: no entry

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

25 %

25 %

25 %

25 %

Hours/Day 24.0

Days/Week 7.0

Weeks/Year 52

Hours/Year 8,760


Comments: Three exhausters operated continuously and/or intermittently throughout the reporting year.

OPERATING SCHEDULE


Material State:


Material:

Status:Operating


23 Release Point for Unit 23 - Tank Farm Exhausters, 200 W Composite 100%



Control Measure:


Control Pollutant:






A-14

EMISSIONS


CO - Carbon Monoxide 0.00 TONCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered

NH3 - Ammonia 0.04 TONCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered

VOC - Volatile Organic CompoundsVOC Expression: Sum of Volatile Organic Compounds 0.01 TONCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: Calculation based on actual air emissions sampling data.

SO2 - Sulfur Dioxide 0.00 TONCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered



NOX - Nitrogen Oxides 0.00 TONCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered

PM10-PRI - PM10 Primary (Filt + Cond) 0.00 TONCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: Calculation based on actual air emissions sampling data.



A-15




Sulfur: no entry

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

%

%

50 %

50 %

Hours/Day 0.0

Days/Week 0.0

Weeks/Year 0

Hours/Year 672


Comments: The two process campaigns, EC-06 and EC-07 ran between July and September of the reporting period. Non-operational for the remainder of the year.

OPERATING SCHEDULE


Routine

Material State:

Input


1466000.00 GALLONS

Material:

004 - Wastewater

Status:Operating


24 Release Point for Unit 24 - 242-A Evaporator, 200 East Area 100%



Control Measure:


Control Pollutant:






A-16

EMISSIONS


CO - Carbon Monoxide 0.00 TONCalculation Method: Engineering JudgmentEmission Factor: Emission Factor Desc: none enteredComments: none entered

VOC - Volatile Organic CompoundsVOC Expression: Unknown 0.26 TONCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: Calculation based on actual air emissions sampling data.

SO2 - Sulfur Dioxide 0.00 TONCalculation Method: Engineering JudgmentEmission Factor: Emission Factor Desc: none enteredComments: none entered



NH3 - Ammonia 0.05 TONCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: Calculation based on actual air emissions sampling data.

NOX - Nitrogen Oxides 0.00 TONCalculation Method: Engineering JudgmentEmission Factor: Emission Factor Desc: none enteredComments: none entered




A-17

67641 - Acetone 5.20 LBCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: Calculation based on actual air emissions sampling data.

71363 - 1-Butanol 3.80 LBCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: Calculation based on actual air emissions sampling data.



A-18




Sulfur: no entry

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

13 %

33 %

52 %

2 %

Hours/Day 24.0

Days/Week 7.0

Weeks/Year 10

Hours/Year 1,608


Comments: ETF processed waste throughout the reporting period.

OPERATING SCHEDULE


Routine

Material State:

Input


5656000.00 GALLONS

Material:

004 - Wastewater

Status:Operating


25 Release Point for Unit 25 - 200 Area Effluent Treat, 200 E Area 100%



Control Measure:


Control Pollutant:






A-19

EMISSIONS



NH3 - Ammonia 0.04 TONCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: Calculation based on waste sampling and mass balance.






VOC - Volatile Organic CompoundsVOC Expression: Sum of Volatile Organic Compounds 0.00 TONCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: Calculation based on waste sampling and mass balance.



A-20

56235 - Carbon Tetrachloride 0.02 LBCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: Calculation based on actual air emissions sampling data.

67641 - Acetone 0.39 LBCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: Calculation based on waste sampling and mass balance.

71363 - 1-Butanol 2.10 LBCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered


U.S. Dept of Energy PROCESSESUnit ID: 26 Process ID: 01 Process Description: not provided SCC CODE: 10200501 - Ext Comb /Industrial /Distillate Oil - Grades 1 and 2 /Boiler


Sulfur: 0%

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

4.5 %

16.7 %

78.8 %

%

Hours/Day 24.0

Days/Week 7.0

Weeks/Year 35

Hours/Year 5,832


Comments:

OPERATING SCHEDULE


Routine

Material State:

Input


109.54 1000 GALLONS

Material:

823 - Distillate Oil (No. 1 & 2)

Status:Operating



A-21


26 Release Point for Unit 26 - ESPC Dist. Oil Blrs, 200 Area Compos. 100%



Control Measure:

Low NOx Burner (LNB)

Flue Gas Recirculation

Control Pollutant:

Carbon Monoxide

Nitrogen Oxides

PM10 Primary (Filt + Cond)

PM2.5 Primary (Filt + Cond)

PM Primary (Filt + Cond)

Sulfur Dioxide

Volatile Organic Compounds

EMISSIONS




A-22

PM10-PRI - PM10 Primary (Filt + Cond) 0.08 TONCalculation Method: S/L/T Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered

PM-PRI - PM Primary (Filt + Cond) 0.11 TONCalculation Method: S/L/T Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered

NOX - Nitrogen Oxides 1.14 TONCalculation Method: S/L/T Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered

VOC - Volatile Organic CompoundsVOC Expression: Unknown 0.10 TONCalculation Method: S/L/T Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered

SO2 - Sulfur Dioxide 0.01 TONCalculation Method: USEPA Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered

CO - Carbon Monoxide 0.54 TONCalculation Method: S/L/T Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered

PM25-PRI - PM2.5 Primary (Filt + Cond) 0.02 TONCalculation Method: S/L/T Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered

NH3 - Ammonia 0.04 TONCalculation Method: USEPA Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered

c7439921 - Lead and Compounds 0.00 LBCalculation Method: S/L/T Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered



A-23


U.S. Dept of Energy PROCESSESUnit ID: 27 Process ID: 01 Process Description: not provided SCC CODE: 10200602 - Ext Comb /Industrial /Natural Gas /10-100 Million Btu/hr


Sulfur: no entry

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

8 %

54 %

3 %

35 %

Hours/Day 24.0

Days/Week 7.0

Weeks/Year 52

Hours/Year 8,760


Comments:

OPERATING SCHEDULE


Routine

Material State:

Input


48.51 MILLION CUBIC FEET

Material:

209 - Natural Gas

Status:Operating


27 Release Point for Unit 27 - ESPC Nat Gas Blrs, 300 Area Compos. 100%



A-24



Control Measure:

Flue Gas Recirculation


Control Pollutant:

Carbon Monoxide

Nitrogen Oxides




Sulfur Dioxide


EMISSIONS




A-25

SO2 - Sulfur Dioxide 0.01 TONCalculation Method: S/L/T Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered

CO - Carbon Monoxide 5.62 TONCalculation Method: S/L/T Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered

NOX - Nitrogen Oxides 2.50 TONCalculation Method: S/L/T Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered

VOC - Volatile Organic Compounds 0.32 TONCalculation Method: S/L/T Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered

PM-PRI - PM Primary (Filt + Cond) 0.30 TONCalculation Method: S/L/T Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered

PM10-PRI - PM10 Primary (Filt + Cond) 0.30 TONCalculation Method: S/L/T Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered


PM25-PRI - PM2.5 Primary (Filt + Cond) 0.30 TONCalculation Method: S/L/T Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered

c7439921 - Lead and Compounds 0.00 LBCalculation Method: S/L/T Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered



A-26




Sulfur: no entry

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

25 %

25 %

25 %

25 %

Hours/Day 24.0

Days/Week 7.0

Weeks/Year 52

Hours/Year 8,736


Comments: storage of vented containers pursuant to DE00NWP-002, Revision 1

OPERATING SCHEDULE


Material State:


Material:

Status:Operating


28 Release Point for Unit 28 - CWC Diffuse and Fugitive, 200 W Area 100%



Control Measure:


Control Pollutant:






A-27

EMISSIONS








VOC - Volatile Organic CompoundsVOC Expression: Unknown 0.00 TONCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered




A-28

56235 - Carbon Tetrachloride 0.16 LBCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered

67641 - Acetone 0.06 LBCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered

67663 - Chloroform 0.08 LBCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered

71556 - 1,1,1-Trichloroethane 0.05 LBCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered

75092 - Dichloromethane 0.25 LBCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered

75694 - Trichlorofluoromethane 0.04 LBCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered

8001589 - Creosote 0.00 LBCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered

64197 - Acetic Acid 0.00 LBCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered

67561 - Methanol 0.00 LBCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered

71432 - Benzene 0.03 LBCalculation Method: Material Balance



A-29

Calculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered

79016 - Trichloroethylene 0.03 LBCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered

80626 - Methyl Methacrylate 0.00 LBCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered

141786 - Ethyl Acetate 0.00 LBCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered

1330207 - Xylenes (Mixed Isomers) 0.00 LBCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered



A-30




Sulfur: no entry

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

25 %

25 %

25 %

25 %

Hours/Day 24.0

Days/Week 7.0

Weeks/Year 52

Hours/Year 8,736


Comments:

OPERATING SCHEDULE


Material State:


Material:

Status:Operating


30 Release Point for Unit 30 - T Plant Point Source and Fugitive, 200 W Area

100%



A-31



Control Measure:


Control Pollutant:




EMISSIONS




A-32


VOC - Volatile Organic CompoundsVOC Expression: Sum of Volatile Organic Compounds 0.00 TONCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered









A-33









A-34




Sulfur: no entry

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

25 %

25 %

25 %

25 %

Hours/Day 24.0

Days/Week 7.0

Weeks/Year 52

Hours/Year 8,736


Comments: Store and repack vented containers pursuant to DE03NWP-002, Amendment 1.

OPERATING SCHEDULE


Material State:


Material:

Status:Operating


31 Release Point for Unit 31 - WRAP Point Source & Fugitive, 200 W Area

100%



A-35



Control Measure:


Control Pollutant:




EMISSIONS




A-36


VOC - Volatile Organic CompoundsVOC Expression: Unknown 0.00 TONCalculation Method: Material BalanceEmission Factor: Emission Factor Desc: none enteredComments: none entered









A-37









A-38


U.S. Dept of Energy PROCESSESUnit ID: 32 Process ID: 01 Process Description: not provided SCC CODE: 40400402 - Petrol Prod Stor-Underground Tanks /Gasoline RVP 13: Working Loss


Sulfur: no entry

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

26 %

24 %

24 %

26 %

Hours/Day 24.0

Days/Week 7.0

Weeks/Year 52

Hours/Year 8,760


Comments: fuel dispensing, evaporative loss

OPERATING SCHEDULE


Routine

Material State:

Output


771.18 1000 GALLONS

Material:

127 - Gasoline

Status:Operating


32 Release Point for Unit 32 - Fuel Dispensing, Evaporative Losses, Area 200/600

100%



Control Measure:

Other Control Device

Control Pollutant:




A-39

EMISSIONS



NH3 - Ammonia 0.00 TONCalculation Method: Engineering JudgmentEmission Factor: Emission Factor Desc: none enteredComments: none entered

VOC - Volatile Organic CompoundsVOC Expression: Unknown 3.50 TONCalculation Method: USEPA Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered








A-40


U.S. Dept of Energy PROCESSESUnit ID: 33 Process ID: 01 Process Description: not provided SCC CODE: 30501199 - Concrete Batching /Other Not Classified


Sulfur: no entry

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

25 %

25 %

25 %

25 %

Hours/Day 10.0

Days/Week 4.0

Weeks/Year 52

Hours/Year 2,080


Comments: Sand and aggregate delivery to ground and transfer to conveyor.

OPERATING SCHEDULE


Routine

Material State:

Input


20121.00 TONS

Material:

189 - Material

Status:Operating


33 Release Point for Unit 33 - WTP Concrete Batch Plant, 200 Area 100%



Control Measure:

Dust Suppression

Control Pollutant:

PM10 Primary (Filt + Cond) 50% efficiency

PM2.5 Primary (Filt + Cond) 50% efficiency

PM Primary (Filt + Cond) 50% efficiency



A-41

EMISSIONS


PM10-PRI - PM10 Primary (Filt + Cond) 0.00 TONCalculation Method: USEPA Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered


PM-PRI - PM Primary (Filt + Cond) 0.00 TONCalculation Method: USEPA Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered



A-42




Sulfur: no entry

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

25 %

25 %

25 %

25 %

Hours/Day 10.0

Days/Week 4.0

Weeks/Year 52

Hours/Year 2,080


Comments: Cement unloading to silo, weight hopper loading, mixer loading, truck loading.

OPERATING SCHEDULE


Routine

Material State:

Input


42858.00 TONS

Material:

696 - Cement

Status:Operating





Control Measure:

Fabric Filter / Baghouse

Control Pollutant:






A-43

EMISSIONS







A-44




Sulfur: no entry

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

25 %

25 %

25 %

25 %

Hours/Day 10.0

Days/Week 4.0

Weeks/Year 52

Hours/Year 2,080


Comments: Sand and aggregate transfer to bins.

OPERATING SCHEDULE


Routine

Material State:

Input


11484.00 TONS

Material:

189 - Material

Status:Operating





Control Measure:

Process Enclosed

Control Pollutant:






A-45

EMISSIONS







A-46


U.S. Dept of Energy PROCESSESUnit ID: 33 Process ID: 04 Process Description: not provided SCC CODE: 10300503 - Ext Comb /Comm-Inst /Distillate Oil /< 10 Million Btu/hr **


Sulfur: 0%

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

%

%

%

%

Hours/Day 10.0

Days/Week 4.0

Weeks/Year 52

Hours/Year 2,080


Comments: Boiler did not operate during reporting period.Sulfur content Fuel Parameter = 0.0015%

OPERATING SCHEDULE


Shutdown

Material State:

Input


0.00 1000 GALLONS

Material:

056 - Distillate Oil

Status:Operating





Control Measure:


Control Pollutant:




A-47

EMISSIONS




VOC - Volatile Organic Compounds 0.00 TONCalculation Method: USEPA Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered


NOX - Nitrogen Oxides 0.00 TONCalculation Method: USEPA Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered


CO - Carbon Monoxide 0.00 TONCalculation Method: USEPA Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered




A-48


U.S. Dept of Energy PROCESSESUnit ID: 33 Process ID: 05 Process Description: not provided SCC CODE: 20100107 - Int Comb /Electric Gen /Distillate Oil (Diesel) /Reciprocating: Exhaust


Sulfur: 0%

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

25 %

25 %

25 %

25 %

Hours/Day 10.0

Days/Week 4.0

Weeks/Year 52

Hours/Year 2,080


Comments: Emergency Generator was not used for power production during reporting period.Sulfur content Fuel Parameter = 0.0015%

OPERATING SCHEDULE


Routine

Material State:

Input


0.00 1000 GALLONS

Material:

056 - Distillate Oil

Status:Operating





Control Measure:


Control Pollutant:

Nitrogen Oxides



A-49

EMISSIONS












A-50


U.S. Dept of Energy PROCESSESUnit ID: 34 Process ID: 01 Process Description: not provided SCC CODE: 30502090 - Stone Quarrying & Processing /Haul Roads - General


Sulfur: no entry

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

25 %

25 %

25 %

25 %

Hours/Day 10.0

Days/Week 4.0

Weeks/Year 52

Hours/Year 2,080


Comments: Mining did not occur during reporting period. Periodic stockpile removal and haul road use did occur during reporting period.

OPERATING SCHEDULE


Routine

Material State:

Output


0.00 TONS

Material:

253 - Product

Status:Temporarily Shutdown


34 Release Point for Unit 34 - WTP Pit 30 Quarry, 600 Area 100%



Control Measure:

Dust Suppression

Control Pollutant:






A-51

EMISSIONS







A-52

Insignificant Emissions Unit? Yes

U.S. Dept of Energy PROCESSESUnit ID: 35 Process ID: 01 Process Description: not provided SCC CODE: 39090011 - Fuel Storage - Fixed Roof Tanks /Dual Fuel (Gas/Oil): Breathing Loss


Sulfur: 0%

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

25 %

25 %

25 %

25 %

Hours/Day 24.0

Days/Week 7.0

Weeks/Year 52

Hours/Year 8,760


Comments: Diesel fuel dispensing, evaporative loss.Sulfur content Fuel Parameter = 0.0015%

OPERATING SCHEDULE


Routine

Material State:

Input


34.10 1000 GALLONS

Material:

044 - Diesel

Status:Operating


35 Release Point for Unit 35 - Fuel Dispensing, Evaporative Losses, WTP Construction Site

100%



Control Measure:


Control Pollutant:




A-53

EMISSIONS












A-54


U.S. Dept of Energy PROCESSESUnit ID: 35 Process ID: 02 Process Description: not provided SCC CODE: 39090011 - Fuel Storage - Fixed Roof Tanks /Dual Fuel (Gas/Oil): Breathing Loss


Sulfur: no entry

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

%

%

%

%

Hours/Day 0.0

Days/Week 0.0

Weeks/Year 0

Hours/Year 0


Comments: Gasoline fuel dispensing did not occur during reporting period.

OPERATING SCHEDULE


Shutdown

Material State:

Existing


0.00 1000 GALLONS

Material:

127 - Gasoline

Status:Operating


35 Release Point for Unit 35 - Fuel Dispensing, Evaporative Losses, WTP Construction Site

100%



Control Measure:


Control Pollutant:




A-55

EMISSIONS












A-56


U.S. Dept of Energy PROCESSESUnit ID: 36 Process ID: 01 Process Description: not provided SCC CODE: 10500205 - Ext Comb /Space Heater /Comm-Inst /Distillate Oil


Sulfur: 0%

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

10 %

40 %

10 %

40 %

Hours/Day 20.0

Days/Week 4.0

Weeks/Year 52

Hours/Year 4,160


Comments: Various diesel heaters are allowed for operation pursuant to Air Permit DE07NWP-004.Sulfur content Fuel Parameter = 0.0015%

OPERATING SCHEDULE


Routine

Material State:

Input


28.69 1000 GALLONS

Material:

044 - Diesel

Status:Operating


36 Release Point for Unit 36 - WTP heaters and Dehumidifiers 100%



Control Measure:


Control Pollutant:

Nitrogen Oxides



A-57

EMISSIONS












A-58


U.S. Dept of Energy PROCESSESUnit ID: 36 Process ID: 02 Process Description: not provided SCC CODE: 10500210 - Ext Comb /Space Heater /Comm-Inst /Liquified Petroleum Gas (LPG)


Sulfur: no entry

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

10 %

40 %

10 %

40 %

Hours/Day 20.0

Days/Week 5.0

Weeks/Year 52

Hours/Year 5,200


Comments: Various propane heaters and dehumidifiers are allowed for operation pursuant to Air Permit DE07NWP-004.

OPERATING SCHEDULE


Routine

Material State:

Input


58.43 1000 GALLONS

Material:

255 - Propane

Status:Operating


36 Release Point for Unit 36 - WTP heaters and Dehumidifiers 100%



Control Measure:


Control Pollutant:

Nitrogen Oxides



A-59

EMISSIONS












A-60


U.S. Dept of Energy PROCESSESUnit ID: 37 Process ID: 01 Process Description: not provided SCC CODE: 20200401 - Int Comb /Industrial /Large Bore Engine /Diesel


Sulfur: 0%

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

25 %

25 %

25 %

25 %

Hours/Day 24.0

Days/Week 7.0

Weeks/Year 52

Hours/Year 8,736


Comments: Composite includes other SCC codes and emissions per NWP-96-1, DE02NWP-002, PSD-02-01, DE07NWP-002, DE08NWP-001, DE12NWP-002, and DE02NWP-001

OPERATING SCHEDULE


Routine

Material State:

Input


41.89 1000 GALLONS

Material:

823 - Distillate Oil (No. 1 & 2)

Status:Operating


37 Release Point for Unit 37 - Sitewide Composite Emissions from Diesel Fuel Combustion

100%



A-61



Control Measure:


Control Pollutant:

Nitrogen Oxides




Sulfur Dioxide




A-62

EMISSIONS







PM25-PRI - PM2.5 Primary (Filt + Cond) 0.50 TONCalculation Method: USEPA Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered





A-63


U.S. Dept of Energy PROCESSESUnit ID: 38 Process ID: 01 Process Description: Tank Farms Direct-Fired Hot Water Heaters Comp SCC CODE: 10200503 - Ext Comb /Industrial /Distillate Oil /< 10 Million Btu/hr **


Sulfur: 0%

Ash: no entry

Heat: no entry

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

50 %

%

50 %

%

Hours/Day

Days/Week

Weeks/Year

Hours/Year 19


Comments: Two direct-fired diesel water heaters allowed intermittent operation for a maximum number of hours per year in accordance with DE12NWP-003.

OPERATING SCHEDULE


Routine

Material State:

Input


701.00 GALLONS

Material:

044 - Diesel

Status:Operating


38 Release Point for Unit 38 - Tank Farms Direct-Fired Hot Water Heaters Composite

100%



A-64



Control Measure:


Control Pollutant:

Nitrogen Oxides 99% efficiency

Carbon Monoxide 99% efficiency

Sulfur Dioxide 99% efficiency

Volatile Organic Compounds 99% efficiency






A-65

EMISSIONS


NOX - Nitrogen Oxides 0.01 TONCalculation Method: Vendor Emission Factor (no Control Efficiency used)Emission Factor: 0.25 Pounds / Million BTUs Emission Factor Desc: none enteredComments: Manufacturer's Product Data Sheet

CO - Carbon Monoxide 0.00 TONCalculation Method: Vendor Emission Factor (no Control Efficiency used)Emission Factor: 0.07 Pounds / Million BTUs Emission Factor Desc: none enteredComments: Manufacturer's Product Data Sheet

SO2 - Sulfur Dioxide 0.01 TONCalculation Method: Vendor Emission Factor (no Control Efficiency used)Emission Factor: 0.52 Pounds / Million BTUs Emission Factor Desc: none enteredComments: Manufacturer's Product Data Sheet

VOC - Volatile Organic Compounds 0.00 TONCalculation Method: Vendor Emission Factor (no Control Efficiency used)Emission Factor: 0.03 Pounds / Million BTUs Emission Factor Desc: none enteredComments: Manufacturer's Product Data Sheet

PM-PRI - PM Primary (Filt + Cond) 0.00 TONCalculation Method: Vendor Emission Factor (no Control Efficiency used)Emission Factor: 0.03 Pounds / Million BTUs Emission Factor Desc: none enteredComments: Manufacturer's Product Data Sheet



A-66


U.S. Dept of Energy PROCESSESUnit ID: 39 Process ID: 01 Process Description: Internal Combustion SCC CODE: 20201001 - Int Comb /Industrial /Liquified Petroleum Gas /Propane: Reciprocating


Sulfur: no entry

Ash: no entry

Heat: 91502.00 BTUs / GAL

FUEL PARAMETERS

Winter %

Spring %

Summer %

Fall %

25 %

25 %

25 %

25 %

Hours/Day 24.0

Days/Week 7.0

Weeks/Year 52

Hours/Year 8,736


Comments: Multiple internal combustion units operate intermittently throughout the reporting period as needed.

OPERATING SCHEDULE


Routine

Material State:

Input


914.00 GALLONS

Material:

255 - Propane

Status:Operating


39 Release Point for Unit 39 - Site-wide Composite Emissions from Propane Fuel Combustion

100%


Control Approach Desc: Not-Controlledcapture efficiency: % effectiveness: %

Control Measure:


Control Pollutant:

Nitrogen Oxides



A-67

EMISSIONS





PM25-PRI - PM2.5 Primary (Filt + Cond) 0.00 TONCalculation Method: USEPA Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered


VOC - Volatile Organic CompoundsVOC Expression: Sum of Volatile Organic Compounds 0.00 TONCalculation Method: USEPA Emission Factor (no Control Efficiency used)Emission Factor: Emission Factor Desc: none enteredComments: none entered

END



A-68

DOE/RL‐2018‐06 Rev. 1

B‐i

APPENDIX B: Washington Emissions Inventory Reporting System

Emissions Summary

DOE/RL‐2018‐06 Rev. 1

B‐ii


Emissions Unit 22, Tank Farm Exhausters, 200 E Composite

Process 01, SCC 39999999 0.00 0.00 0.00 0.00 0.00 0.00 0.00 1.75 NO

Emissions Unit 23, Tank Farm Exhausters, 200 W Composite

Process 01, SCC 39999999 0.00 0.00 0.00 0.00 0.00 0.01 0.00 0.04 NO

Emissions Unit 24, 242-A Evaporator, 200 East Area

Process 01, SCC 39999999 0.00 0.00 0.00 0.00 0.00 0.26 0.00 0.05 NO

Emissions Unit 25, 200 Area Effluent Treat, 200 E Area

Process 01, SCC 39999999 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.04 NO

Emissions Unit 26, ESPC Dist. Oil Blrs, 200 Area Compos.

Process 01, SCC 10200501 0.11 0.08 0.02 0.01 1.14 0.10 0.54 0.04 NO

Emissions Unit 27, ESPC Nat Gas Blrs, 300 Area Compos.

Process 01, SCC 10200602 0.30 0.30 0.30 0.01 2.50 0.32 5.62 0.08 NO

Emissions Unit 28, CWC Diffuse and Fugitive, 200 W Area

Process 01, SCC 39999999 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NO

Emissions Unit 30, T Plant Point Source and Fugitive, 200 W Area

Process 01, SCC 39999999 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NO

Emissions Unit 31, WRAP Point Source & Fugitive, 200 W Area

Process 01, SCC 39999999 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NO

Emissions Unit 32, Fuel Dispensing, Evaporative Losses, 200 Area

Process 01, SCC 40400402 0.00 0.00 0.00 0.00 0.00 3.50 0.00 0.00 NO

Emissions Unit 33, WTP Concrete Batch Plant, 200 Area

Process 01, SCC 30501199 0.00 0.00 0.00 NO

Process 02, SCC 30501199 0.00 0.00 0.00 NO

Process 03, SCC 30501199 0.00 0.00 0.00 NO

Process 04, SCC 10300503 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NO

Process 05, SCC 20100107 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NO

Emissions Unit 34, WTP Pit 30 Quarry, 600 Area Temporarily Shutdown

Process 01, SCC 30502090 NO

Emissions Unit 35, Fuel Dispensing, Evaporative Losses, WTP Construction Site

Process 01, SCC 39090011 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 YES

Process 02, SCC 39090011 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 YES

Emissions Unit 36, WTP heaters and dehumidifiers

Process 01, SCC 10500205 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NO

Emission Summary 2017M-005-0009

U.S. Dept of EnergyDept. of Ecology Nuclear Waste Section

Richland

Operating

Emissions Units and Processes TSP PM10 PM2.5 SO2 NOx VOC CO NH3 IEU?

B-1


Process 02, SCC 10500210 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 NO

Emissions Unit 37, Sitewide Composite Emissions from Diesel Fuel Combustion

Process 01, SCC 20200401 1.36 1.35 0.50 1.24 19.73 0.58 4.26 0.00 NO

Emissions Unit 38, Tank Farms Direct-Fired Hot Water Heaters Composite

Process 01, SCC 10200503 0.00 0.01 0.01 0.00 0.00 YES

Emissions Unit 39, Site-wide Composite from Propane Fuel Combustion

Process 01, SCC 20201001 0.00 0.00 0.00 0.01 0.00 0.00 NO

Total Emissions (in tons) 2 2 1 1 23 5 10 2

Total Fee Eligible Emissions 2 1 23 5

Emission Summary 2017M-005-0009

U.S. Dept of EnergyDept. of Ecology Nuclear Waste Section

Richland

Operating

Emissions Units and Processes TSP PM10 PM2.5 SO2 NOx VOC CO NH3 IEU?

B-2

DOE/RL-2018-06Rev.1

DOE/RL-2018-06

Rev. 1

Distr-1

DISTRIBUTION

All distribution will be made electronically unless otherwise noted.

U.S. Department of Energy, Richland Operations Office

E.T. Faust

U.S. Department of Energy, Office of River Protection

B. R. Trimberger

U.S. Department of Energy, Pacific Northwest Site Office

T. M. McDermott

Bechtel National, Inc.

R.D. Haggard

B. A. Walker

CH2M Hill Plateau Remediation Company

F.J. Carleo

P.T. Karschnia

Johnson Controls, Inc.

J.G. Burrell

Mission Support Alliance, LLC

D.L. Dyekman

A. L. Johnson


J. M. Barnett

C.J. Duchsherer

Washington River Protection Solutions, LLC

M.D. Gerle

B.E. Nichols

DOE/RL-2018-06

Rev. 1

Distr-2


calendar year 2017 criteria and toxic air emissions inventory library/other... · table 2 lists...

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