book review: the nano–micro interface: bridging the micro and nano worlds. by hans-jörg fecht and...

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Book Review DOI: 10.1002/adma.200502583 Hans-Jörg Fecht and Matthias Werner (Eds.) The Nano–Micro Interface: Bridging the Micro and Nano Worlds. Wiley-VCH, Weinheim 2004, XXIV + 327 pp., hardcover, Euro 99.00, ISBN 3-527-30978-0. The editors, Fecht and Werner, present an unusually effective and timely book dealing with a variety of aspects regard- ing science and technology on the micro- and nanoscale, and the critically impor- tant nano–micro interface. The work is divided into three subsections, dealing with I) research funding and commercia- lization of nanotechnology, II) state-of- the art nano- and microscale research leading towards new technologies, and III) current or nearly commercial appli- cations of nano- and microscale materi- als. The combination of these three com- ponents produces a compelling read that cuts across pure science, funding/market- ing, and applications. Addressing applica- tions is especially appreciated, as this pro- vides nice examples to address the often asked questions regarding “what real products are coming out of nanoscience”. Mihail Roco sets the stage in Part I by opening with a review of the US National Nanotechnology Initiative, in- cluding data that reflects the substantial increase in government support for ef- forts in nanoscience, and the impressive increase in patent activity in nanotech- nology, especially in the US, from 1980 to the present. What follows are brief and thoughtful overviews of related nanoscience, nanotechnology, and com- mercialization across the U.S., Europe, and Asian countries. These chapters also provide perspective on existing commercialization efforts, for example in the automobile, optics, and protective equipment industries. Part II, Fundamentals and Technolo- gy , offers a diverse range of topics, from scaling effects across the micro-to-nano- size scales, to measurements and char- acterization, to research activities in catalysis, biomimetics, optoelectronics, and semiconductors. The “Lab-on-a- Chip” chapter by Schafer et al. is partic- ularly topical, as it highlights the de- manding design criteria associated with electrically controlled microcompart- ments in microfluidic devices that re- quire appropriately tailored layers in terms of surface and interfacial interac- tions, and functional components within the device. Schlogl’s chapter on hetero- geneous catalysis is of fundamental im- portance to nanotechnology, given the key historical role of nanoparticulate materials on catalytic processes. Inte- grated into this chapter is the synthesis of materials that are on the nanometer scale in one dimension, but microscopic in other dimensions, such as are found in many of the beautiful inorganic and carbon-based nanorods and nanotubes prepared today. Nanostructured materi- als also carry importance in biology, in- cluding the application of inorganic ma- terials as structural components in the body. Franke’s chapter highlights in vivo applications of nanoscale titanium structures in humans and animals. Bio- compatibility, mechanical properties, and surface roughness remain key fea- tures. Kamins offers an account of an- other key area of micro/nanotechnology in his chapter on semiconductor nano- wires, where efforts towards controlled growth and positioning of nanowires are leading to new approaches to transistors and sensors. The importance of interfa- cial control is emphasized, by applying the lessons learned in silicon-based de- vices used currently to current efforts in implementing nanowires into devices. Part III covers a wide variety of inter- esting topics where materials and techniques specific to the nano- and mi- croscale are used independently or sy- nergistically in applications. The versa- tility of nanoparticles is once again apparent, for example in the application of metal oxide nanoparticles to environ- mental gas sensors, as components of Nafion membrane composites in direct methanol fuel cells, and in poly(ethylene oxide)-based lithium ion polymeric bat- teries. The effect of decreased radius of curvature (sub 5 nm) of diamond-based cutting edges is shown to drastically re- duce cutting artifacts, a topic of wide- spread interest in polymer and materials science. The preparation of designer mi- cro/nano materials is exemplified in ex- amples of controlled surface properties that dictate wetting characteristics, and in the use of LIGA (lithography, galva- noformung und abformung) technology for structuring photoresists using holo- graphic-interference techniques. Taken together, this collection of arti- cles provides a nice breadth of important current strategies and applications across the micro- and nanoscale spec- trum, and will be of interest to those working on both fundamental and ap- plied areas. Moreover, the book will serve as a useful educational tool for young graduate students who may be en- countering these topics for the first time. Todd S. Emrick Department of Polymer Science and Engineering University of Massachusetts Amherst MA 01003-9292 (USA) BOOK REVIEWS 1476 © 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Adv. Mater. 2006, 18, 1476

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Book ReviewDOI: 10.1002/adma.200502583

Hans-Jörg Fecht andMatthias Werner (Eds.)

The Nano–MicroInterface: Bridgingthe Micro andNano Worlds.Wiley-VCH, Weinheim 2004,XXIV + 327 pp., hardcover, Euro 99.00,ISBN 3-527-30978-0.

The editors, Fecht and Werner, presentan unusually effective and timely bookdealing with a variety of aspects regard-ing science and technology on the micro-and nanoscale, and the critically impor-tant nano–micro interface. The work isdivided into three subsections, dealingwith I) research funding and commercia-lization of nanotechnology, II) state-of-the art nano- and microscale researchleading towards new technologies, andIII) current or nearly commercial appli-cations of nano- and microscale materi-als. The combination of these three com-ponents produces a compelling read thatcuts across pure science, funding/market-ing, and applications. Addressing applica-tions is especially appreciated, as this pro-vides nice examples to address the oftenasked questions regarding “what realproducts are coming out of nanoscience”.

Mihail Roco sets the stage in Part Iby opening with a review of the USNational Nanotechnology Initiative, in-cluding data that reflects the substantialincrease in government support for ef-forts in nanoscience, and the impressiveincrease in patent activity in nanotech-nology, especially in the US, from 1980to the present. What follows are briefand thoughtful overviews of relatednanoscience, nanotechnology, and com-mercialization across the U.S., Europe,and Asian countries. These chaptersalso provide perspective on existingcommercialization efforts, for examplein the automobile, optics, and protectiveequipment industries.

Part II, Fundamentals and Technolo-gy, offers a diverse range of topics, fromscaling effects across the micro-to-nano-size scales, to measurements and char-acterization, to research activities incatalysis, biomimetics, optoelectronics,and semiconductors. The “Lab-on-a-Chip” chapter by Schafer et al. is partic-ularly topical, as it highlights the de-manding design criteria associated withelectrically controlled microcompart-ments in microfluidic devices that re-quire appropriately tailored layers interms of surface and interfacial interac-tions, and functional components withinthe device. Schlogl’s chapter on hetero-geneous catalysis is of fundamental im-portance to nanotechnology, given thekey historical role of nanoparticulatematerials on catalytic processes. Inte-grated into this chapter is the synthesisof materials that are on the nanometerscale in one dimension, but microscopicin other dimensions, such as are foundin many of the beautiful inorganic andcarbon-based nanorods and nanotubesprepared today. Nanostructured materi-als also carry importance in biology, in-cluding the application of inorganic ma-terials as structural components in thebody. Franke’s chapter highlights invivo applications of nanoscale titaniumstructures in humans and animals. Bio-compatibility, mechanical properties,and surface roughness remain key fea-

tures. Kamins offers an account of an-other key area of micro/nanotechnologyin his chapter on semiconductor nano-wires, where efforts towards controlledgrowth and positioning of nanowires areleading to new approaches to transistorsand sensors. The importance of interfa-cial control is emphasized, by applyingthe lessons learned in silicon-based de-vices used currently to current efforts inimplementing nanowires into devices.

Part III covers a wide variety of inter-esting topics where materials andtechniques specific to the nano- and mi-croscale are used independently or sy-nergistically in applications. The versa-tility of nanoparticles is once againapparent, for example in the applicationof metal oxide nanoparticles to environ-mental gas sensors, as components ofNafion membrane composites in directmethanol fuel cells, and in poly(ethyleneoxide)-based lithium ion polymeric bat-teries. The effect of decreased radius ofcurvature (sub 5 nm) of diamond-basedcutting edges is shown to drastically re-duce cutting artifacts, a topic of wide-spread interest in polymer and materialsscience. The preparation of designer mi-cro/nano materials is exemplified in ex-amples of controlled surface propertiesthat dictate wetting characteristics, andin the use of LIGA (lithography, galva-noformung und abformung) technologyfor structuring photoresists using holo-graphic-interference techniques.

Taken together, this collection of arti-cles provides a nice breadth of importantcurrent strategies and applicationsacross the micro- and nanoscale spec-trum, and will be of interest to thoseworking on both fundamental and ap-plied areas. Moreover, the book willserve as a useful educational tool foryoung graduate students who may be en-countering these topics for the first time.

Todd S. EmrickDepartment of Polymer Science and

EngineeringUniversity of Massachusetts

Amherst MA 01003-9292 (USA)

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1476 © 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Adv. Mater. 2006, 18, 1476