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    Basic of Manufacturing Industry MEEG

    M.Tech in Health, Safety & Environment

    Engineering

    Educational Qualification Improvement

    Programme

    (EQUIP)

    SAINT-GOBAIN

    Indian School of Petroleum &

    Energy

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    in association with

    University of Petroleum & Energy Studies

    S.NO. CHAPTER NAME PAGE NO.

    UNIT-I Mechanical components operations 3

    UNIT-IIGlass manufacturing Industry

    20

    UNIT-III Paint manufacturing industry 38

    UNIT-IV Automobile manufacturing industry 43

    UNIT -V Metal manufacturing industry

    Aluminium

    Iron

    Stainless steel

    Copper

    53

    56

    61

    68

    UNIT-VI Sugar manufacturing industry 79

    UNIT-VII Beer manufacturing industry 86

    UNIT-VIII Paper manufacturing industry 91

    UNIT-IX Petroleum and its products manufacturing 97

    UNIT-X Soap manufacturing industry 104

    UNIT-XI Fertilizer manufacturing industry 109

    UNIT-XII Tyre manufacturing industry 116

    UNIT-XIII Phosphoric acid industry 122

    UNIT-XIV Sulfuric acid industry 126

    UNIT-XV Pesticides manufacturing industry 130

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    Basics of manufacturing

    Manufacturing is the use of machines, tools and labor to make things

    for use or sale. The term may refer to a range of human activity, from

    handicraft to high tech, but is most commonly applied to industrial

    production, in which raw materials are transformed into finished goods on a

    large scale. Such finished goods may be used for manufacturing other, more

    complex products, such as aircraft, household appliances or automobiles, or

    sold to wholesalers, who in turn sell them to retailers, who then sell them to

    end users the "consumers".

    Modern manufacturing includes all intermediate processes required for

    the production and integration of a product's components. Some industries,

    such as semiconductor and steel manufacturers use the term fabrication

    instead.

    In this subjects we are dealing with mechanical components

    manufacturing, glass, Automobile, paint, metals such Al, iron and stainless

    steel and copper manufacturing .

    Petroleum, Petrochemical products such as fertilizers, soaps, tyre and

    chemical & process industry products like sugar, pesticides, paper, acids and

    beer are manufactured huge quantities in our country. This material

    discusses the basics of manufacturing of these products.

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    1. MECHANICAL COMPONENTS MANUFACTURING

    1.1 CASTING

    Cupola melting This method uses a furnace in stack form as shown

    in Figure. In this method is used to produce iron plates or rods from the steel

    scraps. Fuel and metal to be melted are in direct contact. The stack is lined

    with refractory material and alternate layers of coke and metal are placed in

    it. Some minerals, primarily limestone (CaC03), are included with the metals

    to be melted. Air is blown through the stack from the bottom through

    openings called tuyeres. The bottom layer of coke is ignited initially. Heat

    from the burning coke melts the metal, which flows to the bottom of the

    cupola from where it can be removed by opening a tap hole. Slag is also

    removed from the bottom, from anexit hole just above the one used to

    remove molten metal. As the coke

    is consumed and the metal charge

    melts, the burning gradually

    proceeds upward. The upper layers

    are preheated by the flow of hot

    gases. Additional metal, coke, and

    limestone can be added from a

    charging door in the upper part of

    the stack as the operation proceeds.

    Metal charges may consist of steel

    scrap, cast iron scrap or pig iron, or,

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    more commonly, a combination of them. The molten metal absorbs carbon

    from the coke, so cupola melting is generally restricted to cast, malleable,

    and ductile iron. The above picture shows the cross section of cupola for

    melting cast iron.

    SAND CASTINGS

    In sand mold casting the mold is made of packed sand. Molten metal is

    poured into a cavity in the sand. When the metal cools and solidifies, it has

    the shape of the cavity. The sand is removed, normally by a shaking action

    that is vigorous enough to cause the mold to break apart. The casting is then

    cleaned of sand; flashing and sprues are cut off and any jagged or sharp

    edges are ground smooth. The sand mold includes binders to hold thepacked sand together and other additives. Bentonite clay is one of the most

    common binders. Organic materials and a certain amount of water are also

    used. The sand is either shoveled into the mold flask, dropped or blown from

    an overhead chute, or thrown by a sand slinging machine. The sand mixture

    is packed around a pattern which duplicates the shape wanted in the cast

    part. Various hand and machine approaches are used to compact the sand.

    Ramming, squeezing, slinging, and jolting are done before add molten metal.

    After the sand has been compacted, the pattern is removed, leaving a cavity

    that retains the inverse of the patterns shape. The sand is held together

    strongly enough so that it withstands the pressure and any eroding effects of

    the melted metal; is porous enough to allow gases to escape; yet it is weak

    enough to yield to shrinkage forces when the metal solidifies, and can be

    broken up and removed easily from the finished casting. The pattern can be

    of almost any material. In low quantity production situations, it may be made

    of wood. For repetitive manufacture, steel is more common. Plastics,

    aluminum, and other materials are also used. The pattern has the same

    shape as the desired cast part, but is slightly larger to provide a shrinkage

    allowance for the metal as it cools.

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    A typical sand mold is shown in figure and is normally made in two

    halves. The pattern is correspondingly split. The top half of the mold is

    called the cope; the

    bottom half the drag.

    Both are held in a box-like

    container called flasks.

    An entrance channel for

    the molten metal into the

    mold is provided by a

    basin and sprue formed in

    the cope half. Runners

    and gate are normally in the drag half. If the casting has some hollow or

    undercut elements, one or more additional sand pieces, called cores may

    be used. If a core is used, it is inserted in the mold cavity. The cope half of

    the mold is made similarly to the drag half and, after the pattern is removed,

    is inverted and placed over the drag. Pins in the flask insure alignment of the

    mold cavity. The two mold halves are held together with a clamp or weight.

    Sand mold casting can be used to make simple and complex parts from a

    wide variety of metals, though cast iron is the most common. Shapes with

    undercuts, contours, re-entrant angles and other complications of shape can

    be cast. Castings weighing only one ounce to those of many tons can be cast

    with the process.

    Typical applications of sand mold casting are: automotive engine

    blocks, cylinder heads, connecting rods, crankshafts and transmission cases,

    machine tool bases and other mechanical components.

    METAL FORMING PROCESS

    Many metal forming operations can be performed with the workpiece

    metal either hot or cold. The operations performed on workpiece material

    that has been heated to make it more malleable for the operation involved.

    Metals that are to be hot formed are heated above their recrystallization

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    temperature, one that varies with each material but is normally about 0.6

    times the melting temperature on the Kelvin (absolute temperature) scale.

    For example, steels require a temperature above about 980C. Warm

    forming involves heating to a temperature 30 to 60 percent of the melting

    point, while cold forming takes place when the metal temperature is below

    30% of the melting temperature.)

    1.2 HOT ROLLING

    It is commonly applied to convert steel ingots to blooms, billets, or

    slabs, and to make these shapes into suitable forms. In the process, heated

    metal is passed between two rollers whose spacing is less than the thickness

    of the metal. The rotation of the rollers moves the metal forward, squeezing

    and elongating it. Figure illustrates the process. The process extends and

    refines the grain structure of the rolled material. A number of passes may be

    required, depending on the thickness desired and the thickness of the

    entering material. Reversing rollers are often used to facilitate multiple

    passes. Thin sheet or foil is best rolled with small-diameter rollers that are

    backed up with larger rollers to provide the necessary rolling force.

    As many as twelve rollers in a cluster may be used. Shaped rollers can

    produce material with various

    cross sections including those

    of structural shapes or special

    cross sections. Low-alloy or

    plain-carbon steel is heated to

    about 1200C before rolling

    and after being preheated in a

    soaking pit. In addition to

    ferrous metals, aluminum,

    copper and copper alloys,

    magnesium, nickel, titanium, and zinc alloys are hot rolled.

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    1.3 PRESS OPERATIONS IN INDUSTRY

    Press brakes, as illustrated in Figure, are mechanical or hydraulic

    presses with long, narrow, stationary beds. The bed lengths range from 2or

    3 ft to 30 ft and press tonnages from 10 to several thousand. The ramstroke

    is short but adjustable. Dies are long, narrow, and often simple V-dies. Both

    sharp and gentle bends can be made, depending on the shape of the dies.

    Piercing, notching, forming, shearing, edge curling, beading,

    hemming, corrugating, and tube forming can be performed with

    suitable dies. In bending, sheet metal, placed between the bed and the ram

    is most commonly bent once with each press stroke. The bend occurs when

    a shaped punch, attached to the press brake ram, descends against the

    workpiece, forcing it into a suitablyshaped die, fastened to the press brake

    bed. Multiple bends are made by repositioning the workpiece sheet between

    press strokes. Press brakes are used in the bending of long, narrow

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    workpieces and for other workpieces made in small quantities where

    standard press brake tooling can be employed.

    1.4 WELDING

    Welded connections and assemblies represent a very large group of

    fabricated steel components. The welding process itself is complex, involving

    heat and liquid-metal transfer, chemical reactions, and the gradual formation

    of the welded joint through liquid-metal deposition and subsequent cooling

    into the solid state, with attendant metallurgical transformations.

    The material in this section will provide the student with an overview of

    the most important aspects of welded design. In order that the resulting

    welded fabrication be of adequate strength, stiffness, and utility, the

    designer will often collaborate with engineers who are experts in the broad

    area of design and fabrication of elements.

    ARC WELDING

    Arc welding is one of several fusion processes for joining metal. By

    the generation of intense heat, the juncture of two metal pieces is melted

    and mixeddirectly or, more often, with an intermediate molten filler metal.

    Upon cooling and solidification, the resulting welded joint metallurgically

    bonds the former separate pieces into a continuous structural assembly (a

    weldment) whose strength properties are basically those of the individual

    pieces before welding.

    In arc welding, the intense heat needed to melt metal is produced by

    an electric arc. The arc forms between the workpieces and an electrode that

    is either manually or mechanically moved along the joint; conversely, the

    work may be moved under a stationary electrode. The electrode generally is

    a specially prepared rod or wire that not only conducts electric current and

    sustains the arc, but also melts and supplies filler metal to the joint; this

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    constitutes a consumable electrode. Carbon or tungsten electrodes may be

    used, in which case the electrode serves only to conduct electric current and

    to sustain the arc

    between tip and

    workpiece, and it is

    not consumed; with

    these electrodes, any

    filler metal required is

    supplied by rod or

    wire introduced into

    the region of the arc

    and melted there.

    Filler metal applied

    separately, rather than via a consumable electrode, does not carry electric

    current. Most steel welding operations are performed with consumable

    electrodes. The figure shows the typical welding arrangement.

    WELDING CIRCUIT ARRANGEMENT

    An ac or dc power source fitted with necessary controls is connected

    by a work cable to the work piece and by a hot cable to an electrode

    holder of some type, which, in turn, is electrically connected to the welding

    electrode. When the circuit is energized, the flow of electric current through

    the electrode heats the electrode by virtue of its electric resistance. When

    the electrode tip is touched to the workpiece and then withdrawn to leave a

    gap between the electrode and workpiece, the arc jumping the short gap

    presents a further path of high electric resistance, resulting in the generation

    of an extremely high temperature in the region of the sustained arc.

    The temperature reaches about 6,500F, which is more than adequate

    to melt most metals. The heat of the arc melts both base and filler metals,

    the latter being supplied via a consumable electrode or separately. The

    puddle of molten metal produced is called a weld pool, which solidifies as the

    electrode and a rc move along the joint being welded. The resulting

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    weldment is metallurgically bonded as the liquid metal cools, fuses,

    solidifies, and cools. In addition to serving its main function of supplying

    heat, the arc is subject to adjustment and/or control to vary the proper

    transfer of molten metal to the weld pool, remove surface films in the weld

    region, and foster gas-slag reactions or other beneficial metallurgical

    changes Filler metal composition is generally different from that of the weld

    metal, which is composed of the solidified mix of both filler and base metals.

    Shielding and Fluxing High-temperature molten metal in the weld pool

    will react with oxygen and nitrogen in ambient air. These gases will remain

    dissolved in the liquid metal, but their solubility significantly decreases as

    the metal cools and solidifies. The decreased solubility causes the gases to

    come out of solution, and if they are trapped in the metal as it solidifies,

    cavities, termed porosities, are left behind. This is always undesirable, but it

    can be acceptable to a limited degree depending on the specification

    governing the welding. Smaller amounts of these gases, particularly

    nitrogen, may remain dissolved in the weld metal, resulting in drastic

    reduction in the physical properties of otherwise excellent weld metal.

    Notch toughness is seriously degraded by nitrogen inclusions.

    Accordingly, the molten metal must be shielded from harmful atmospheric

    gas contaminants. This is accomplished by gas shielding or slag shielding or

    both.

    Gas shielding is provided either by an external supply of gas, such as carbon

    dioxide, or by gas generated when the electrode flux heats up. Slag shielding

    results when the flux ingredients are melted and leave behind a slag to cover

    the weld pool, to act as a barrier to contact between the weld pool and

    ambient air. At times, both types of shielding are utilized.

    In addition to its primary purpose to protect the molten metal, the

    shielding gas will significantly affect arc behavior. The shielding gas may be

    mixed with small amounts of other gases (as many as three others) to

    improve arc stability, puddle (weld pool) fluidity, and other welding operating

    characteristics. In the case of shielded-metal arc welding (SMAW), the

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    stick electrode is covered with an extruded coating of flux. The arc heat

    melts the flux and generates a gaseous shield to keep air away from the

    molten metal, and at the same time the flux ingredients react with

    deleterious substances, such as surface oxides on the base metal, and

    chemically combine with those contaminants, creating a slag which floats to

    the surface of the weld pool. That slag crusts over the newly solidified hot

    metal, minimizes contact between air and hot metal while the metal cools,

    and thereby inhibits the formation of surface oxides on the newly deposited

    weld metal, or weld bead.

    When the temperature of the weld bead decreases, the slag, which has

    a glassy consistency, is chipped off to reveal the bright surface of the newly

    deposited metal. Minimal surface surface oxidation will take place at lower

    temperatures, inasmuch as oxidation rates are greatly diminished as

    ambient conditions are approached.Fluxing action also aids in wetting the

    interface between the base metal and the molten metal in the weld pool

    edge, thereby enhancing uniformity and appearance of the weld bead.

    1.5 GAS CUTTING

    Oxyfuel Cutting (OFC) Oxyfuel cutting is used to cut steels and toprepare bevel and vee grooves. In this process, the metal is heated to its

    ignition temperature, or kindling point, by a series of preheat flames. After

    this temperature is attained, a high-velocity stream of pure oxygen is

    introduced, which causes oxidation or burning to occur. The force of the

    oxygen steam blows the oxides out of the joint, resulting in a clean cut. The

    oxidation process also generates additional thermal energy, which is radially

    conducted into the surrounding steel, increasing the temperature of the steel

    ahead of the cut. The next portion of the steel is raised to the kindling

    temperature, and the cut proceeds. Carbon and low-alloy steels are easily

    cut by the oxyfuel process. Alloy steels can be cut, but with greater difficulty

    than mild steel. The level of difficulty is a function of the alloy content. When

    the alloy content reaches the levels found in stainless steels, oxyfuel cutting

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    cannot be used unless the process is modified by injecting flux or iron-rich

    powders into the oxygen stream. Aluminum cannot be cut with the oxyfuel

    process. Oxyfuel cutting is commonly regarded as the most economical way

    to cut steel plates greater than 1 2 in thick. A variety of fuel gases may be

    used for oxyfuel cutting, with the choice largely dependent on local

    economics; they include natural gas, propane, acetylene, and a variety of

    proprietary gases offering unique advantages. Because of its role in the

    primary cutting stream, oxygen is always used as a second gas. In addition,

    some oxygen is mixed with the fuel gas in proportions designed to ensure

    proper combustion.

    Plasma Arc Cutting (PAC)

    The plasma arc cutting process was developed initially to cut materials

    that do not permit the use of the oxyfuel process: stainless steel and

    aluminum. It was found, however, that plasma arc cutting offered economic

    advantages when applied to thinner sections of mild steel, especially those

    less than 1 in thick. Higher travel speed is possible with plasma arc cutting,

    and the volume of heated base material is reduced, minimizing metallurgical

    changes as well as reducing distortion.

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    PAC is a thermal and mechanical process. To utilize PAC, the material

    is heated until molten and expelled from the cut with a high-velocity stream

    of compressed gas. Unlike oxyfuel cutting, the process does not rely on

    oxidation. Because high amounts of energy are introduced through the arc,

    PAC is capable of extremely high-speed cutting. The thermal energy

    generated during the oxidation process with oxyfuel cutting is not present in

    plasma; hence, for thicker sections, PAC is not economically justified. The

    use of PAC to cut thick sections usually is restricted to materials that do not

    oxidize readily with oxyfuel.

    WELDING SAFETY

    Welding is safe when sufficient measures are taken to protect the

    welder from potential hazards. When these measures are overlooked or

    ignored, welders can be subject to electric shock; overexposure to radiation,

    fumes, and gases; and fires and explosion. Any of these can be fatal.

    Everyone associated with welding operations should be aware of the

    potential hazards and help ensure that safe practices are employed.

    Infractions must be reported to the appropriate responsible authority.

    Oxygen is incorrectly called air in some fabricating shops. Air from the

    atmosphere contains only 21 percent oxygen and obviously is different from

    the 100 percent pure oxygen used for cutting. The unintentional confusion of

    oxygen with air has resulted in fatal accidents. When compressed oxygen is

    inadvertently used to power air tools, e.g., an explosion can result. While

    most people recognize that fuel gases are dangerous, the case can be made

    that oxygen requires even more careful handling

    1.6 LATHE AND OTHER OPERATIONS

    Lathe operations

    It produce, with a cutting action, surfaces of rotation (surfaces having a

    round or partly-round cross section), both external and internal, in a work

    piece. The work piece is rotated in a lathe, screw machine, or chucking

    machine. It is held between centers or in a chuck or collet, or fastened to a

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    face place. The cutting tool is fed into the work or along the work, or both, to

    produce a part of the desired shape. There are several basic types of lathes

    and related machines as described below and many varieties of tools that

    can be fed against the workpiece. These machines are used extensively in

    the production of parts that contain surfaces of rotation. The basic

    operations performed on lathes are the following:

    Turning - is the most prevalent lathe operation. In its most common form, a

    single-point cutting tool is moved on a precise path with respect to a rotating

    workpiece. When the tool moves parallel to the axis of rotation, straight

    turning takes place and the surface machined is cylindrical or part of a

    cylinder. When the cutting tool moves uniformly closer or farther from the

    axis of rotation as it moves longitudinally, a tapered surface is generated

    Grooving - The cutting tool, usually ground to the width and bottom shape

    required, is fed into the work, cutting a groove of the desired dimensions.

    Groves can be cut into any external or internal surface that such a cutting

    tool can reach. (Internal grooves are usually called recesses.)

    Knurling - is not really a machining (cutting) operation because the knurl is

    formed, not cut, in the workpiece. Knurling is a common lathe or screw

    machine operation. The hardened hurling tool rolls against the cylindrical

    surface of the rotating workpiece with high pressure, causing the surface

    material of the workpiece to flow into peaks and valleys according to the

    pattern of the hurling tool.

    Facing - produces flat surfaces whose plane is at right angles to the axis of

    rotation of the part As the part rotates in the lathe, the cutting tool moves

    radially toward the axis of rotation, removing material as it advances. It can

    also move outward from the center, but the other direction is much more

    common. The operation is used to produce flat surfaces on castings and

    other parts that usually also require turning or some other lathe operation

    Cutting off (parting) - When parts are made in lathes and screw machines

    from bar stock, the final operation is to sever the part from the remaining

    bar material. This is accomplished by advancing the cutoff tool, a narrow

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    grooving tool, radially into the work. When the cutting edge advances to the

    axis of rotation of the part, the part is severed and falls to the bed of the

    machine. Some machines, which make blanks for further machining or other

    operations, are designed to perform only cut off operations and other simple

    ones on bar and tubular stock.

    Common Lathe operations are shown in figure.

    1.7 DRILLING OPERATION

    Drilling - The most common tool for drilling, a twist drill, is a rod with helical

    flutes and two or more cutting edges at the end. It is rotated about its axis

    and fed axially into the work. As it advances, it produces or enlarges a round

    hole in the workpiece. The chips are carried away from the hole by the flutesin the drill. When drilling an axial hole with a lathe, the workpiece rotates

    rather than the drill.

    There are other types of drills that may not have helical flutes. Others may

    have only one cutting edge. The drilling process is very common and is used

    with a wide variety of machines ranging from the most sophisticated

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    computer controlled or multiple spindle machines to hand-held electric or

    crank-driven drills.

    1.8 GRINDING AND ABRASIVE MACHINING

    At the point where the cutting takes place, grinding is very similar to other

    machining operations, the difference being that the workpiece is cut by the

    sharp edges of small pieces of abrasive material, rather than the edge of a

    hardened steel or carbide cutting tool. The irregularly-shaped abrasive

    particles may be bonded to a wheel or coated belt, or may be used loose.

    The particles commonly consist of aluminum oxide, silicon carbide, cubic

    boron nitride, diamond, or other hard materials. The individual abrasive

    grains are each smaller than a conventional metalworking cutting tool, andthe grains on a typical wheel make a multitude of minute cuts (Some grains,

    depending on their shape, do not cut but instead rub or slightly deform the

    surface of the workpiece.) Cutting speeds are high but the depth of cut from

    each grain is shallow. A water or water-oil emulsion is often sprayed on the

    wheel and workpiece to control the dust that otherwise arises and to

    overcome the heating effect of the operation.

    Grinding wheels are often porous, especially those designed for use with

    softer materials. Asthe wheel cuts, it wears, causing some abrasive particles

    to become smooth but causing others to fracture, exposing new sharp

    edges. New wheels, and those that have become worn, are dressed with a

    diamond tool that removes some of the abrasive material and bonding

    agent, exposing sharp edges of new abrasive grains and providing a

    straighter, more uniform, cutting surface. Grinding is most commonly a

    finish-machining operation to provide a smoother surface or greater

    dimensional accuracy, particularly with hardened materials. When used as

    the primary metal removal method, the term, abrasive machining is often

    used.

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    1.9 MILLING

    Milling is a means of creating a desired surface with a rotating multi-toothed

    cutter. Each tooth of the cutter removes material as the workpiece advances

    against it. The axis of rotation of the cutter may be either horizontal or

    vertical. The cutter can provide cutting action on its side or at its end (face),

    or both. The cutter rotates rather rapidly and its position is normally

    stationary; the work moves past the cutter with a suitable depth of cut at a

    relatively slow feed rate. Milling is the most common machining operation for

    producing flat surfaces, but slots, and contoured or stepped surfaces and

    screw threads can also be produced.

    The different types of millings are face milling, peripheral milling, slabmilling, form milling, gand milling, straddle milling, fly cutter milling etc.

    1.10 SAWING

    Sawing is the parting of material through the use of a narrow cutter, a saw,

    which contains a series of cutting edges that pass against the work in a

    continuous or reciprocating motion. As the cutter is advanced into the work,

    material is removed by each tooth, and a slot is formed, eventually

    extending through the entire thickness of the workpiece, and severing it into

    two pieces.

    The chip produced by each tooth is carried in the space between the teeth

    until the teeth exit the workpiece. The cutter can be in disk, band, or

    reciprocating blade form. Cutting teeth are typically set, i.e., offset slightly

    and alternately from both sides of the saw blade to provide a slightly wider

    cut (kerf) than the thickness of the blade so that there is room for its

    passage. The operation is used to cut billets, extrusions, castings, forgings,

    and various other shapes into blanks for further operations. Bars of various

    cross sections, rods, angles, and various other structural sections are cut to

    length by sawing.

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    Circular sawing - uses a saw in the form of a circular disk, with cutting

    teeth on the periphery. As the circular saw rotates, it is fed against the

    workpiece, machining a narrow slot in the workpiece and eventually severing

    it. Circular saws for metal cutting are sometimes called cold sawsbecause

    they dont significantly heat the workpiece as friction saws do. They often

    have inserted cutter teeth of carbide rather than teeth formed of the blade

    material, or have cutter segments fastened to a center disc. Blades are

    sometimes large in diameter to permit the sawing of bulky workpieces. Kerfs

    are considerably wider than

    those on band or hack-saws

    because the circular blade must

    be thick enough to provide

    rigidity. Accurate and smooth

    cut surfaces are feasible with

    this method. The circular saw

    process is used to make blanks

    for subsequent operations or to

    cut structural members to the

    desired length. Figure illustrates

    a circular cutoff saw (coldsaw).

    Band sawing - is most commonly a cut-off operation. Instead of a circular

    disk, the saw is an endless steel band with cutting teeth on one edge. The

    blade moves as it cuts in one direction. Cutting is continuous and blade

    wear is uniform over the whole length of the blade. Since the blade is

    normally thin, little material is lost to chip waste and power requirements are

    modest. The work piece or the blade can be fed manually or mechanically.

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    2.0 GLASS MANUFACTURING

    2.1 INTRODUCTION

    Glassmaking involves three basic steps: batching, melting, and

    forming. Batching is the preparation of a mixture of sand and stabilizing

    oxides, all in fine granular form. Melting involves the heating of the mixture

    to change it into a liquid and to further homogenize the various ingredients.

    Forming is the creation of useful objects or products from the molten mixture

    before it has completely solidified. The process can be carried out on either a

    batch or continuous-flow basis, the latter being used in mass production

    situations. Normally, forming operations take place immediately after thebasic glassmaking, with the molten glass being cooled to increase its

    viscosity for forming.

    There are many different kinds of glass. Soda lime glass is used for bottles,

    window panes and drinking glasses. Lead-alkali silicate glass has lead oxide

    in place of much of the calcined lime and is used for highly worked shapes

    including decorative glassware (lead crystal) that is engraved. Borosilicate

    glasses, which contain boric oxide, are used when chemical and temperature

    change resistance is important, for example, in pharmaceutical containers,

    chemical process components and lamp envelopes. Aluminosilicate glasses

    are used where high temperature conditions exist. Several other mixtures

    may be used when optical properties are important.

    2.2 RAW MATERIALS

    Silica sand (SiO2) is the most common glass ingredient and has

    excellent resistance to attack, low thermal expansion, and resistance to

    devitrification (crystallization which impairs the optical and mechanical

    properties). However, in its unalloyed state, silica sand is difficult to process

    because of its high melting temperature and high viscosity when melted.

    Various other oxides are added to silica to improve its processibility and

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    modify the properties of the finished glass. When soda-lime glass, the most

    common variety, is made, the ingredients consist of about 73 percent sand

    (SiO2), about 14 percent soda ash or sodium carbonate (Na2C02) and about

    13 percent limestone (CaC03). Sodium oxide, (Na20) is an effective fluxing

    agent, i.e., a means for reducing the melting temperature, but too much can

    produce glass that is water soluble. Calcium oxide, calcined lime (CaO),

    increases the hardness and resistance of the glass to moisture. Alumina

    (A1203) improves durability and reduces thermal expansion. Potassium oxide

    (K20) from potash, increases durability and helps prevent devitrification,

    which has adverse effects. Other glass ingredients include borax or boric

    acid for boric oxide (B203), fluorspar (CaF), litharge or lead oxide (PbO),

    barium carbonate (BaC03), magnesium oxide (MgO), zinc oxide (ZnO), and

    other inorganic materials, some of which are colorants. Glass cullet (factory

    scrap or recycled glass), may be added to the mixture. It provides fluxing

    action and reduces the energy required for melting. About 30 to 40% cullet

    provides the maximum furnace efficiency. In some mixtures, cullet content

    can reach 66 percent. A typical commercial mixture has from 7 to about 12

    different minerals, 4 to 6 of which are major ingredients.

    2.3 COLORING MATERIALS - Glass is colored by adding small quantities

    (usually less than 0.5 percent) of certain metal oxides or other metallic

    compounds to the glass batch. Copper produces light blue; chromium - green

    and yellow; iron - bluish green or yellowish brown; cobalt - intense blue;

    nickel grayish brown, yellow, green, blue or violet depending on the glass

    matrix; neodymium - reddish violet; manganese - violet; vanadium - green or

    brown.

    2.4 BATCHING - involves weighing, milling as necessary, and mixing to

    produce the glass furnace charge, a blend that can be melted to provide the

    composition desired. Quality control, including chemical analyses, must

    precede these steps to insure that each raw material is of the proper

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    composition with impurities within limits. and of the proper grain size. Grain

    or particle size is important and must be controlled so that materials do not

    segregate during mixing, storage, and handling and so that they melt

    properly. Overly-fine particles of some materials may retard the elimination

    of gas bubbles from the melted charge. Milling and screening of raw

    materials may be required for some mixtures, though the common practice

    is to have suppliers of raw materials provide them with the desired grain size

    and size distribution. Water may be added to the batch to the extent of 2 to

    4percent to prevent segregation prior to melting. More recently, methods

    have been developed to consolidate the batch material in a form that more

    easily preserves the uniformity of the batch mixture, provides easier

    handling, improved melting, and better uniformity of the glass mixture

    during melting.

    These consolidation methods usually involve the following steps:

    1. reducing and controlling the grain size of the batch materials by various

    milling operations and screening, mixture,

    2. adding wetting and binding agents to the

    3. thoroughly mixing the mixture and additives,

    4. consolidation - briquetting, pelletizing or other means of holding the

    mixture into a stable but easily handled form, and

    5. preheating the consolidation before melting.

    Alc. melting - Melting the glass materials, known as the batch, enables the

    ingredients to be completely blended to produce glass of the desired

    properties and puts the glass in condition for forming. Typical melting

    temperatures are approximately 1450 to 1600. Heat is provided by gas, oil

    or electricity. Natural gas is the major fuel; propane is used as a standby.

    When quantities are small, melting is performed on a batch basis in pot

    furnaces or day tanks. High production melting is done in continuous

    furnaces that have output levels ranging to several hundred tons per day.

    Pots are made of refractory clay and are heated in brick furnaces. Day tanks

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    are larger pots for batch production and are typically run on a one-day cycle,

    with melting at night and production and refilling the next day. Ten tons is a

    typical daily production quantity. Pots are typically round crucibles made of

    one piece of refractory material with individual capacities of one to two tons

    of glass. Several pots may occupy one furnace. Day tanks are made from

    refractory blocks. Continuous furnaces are used for flat glass and for mass-

    produced containers and other highproduction items. They are lined with

    refractory ceramics and are divided into a large melting section and a small

    refining section called a forehearth. The forehearth is used to cool glass from

    the melt temperature to a suitable temperature for whatever forming

    operation follows. Daily production levels are on the order of 100 to 400 tons

    of glass.

    The glass charge is fed from one end of the melting area. Temperatures in

    the melting area are as high as the glass mixture can tolerate in order to

    drive off carbon dioxide, steam, trapped air, and other gases, which could

    cause bubbles in the glass. Convection currents in the molten glass, which

    result from natural unevenness of heating and cooling from side walls,

    provide stirring that helps the glass mixture to become homogeneous. The

    molten glass that passes to the refining section does so through an opening

    below the surface of the melt, thus preventing any surface foam or scum

    from entering the forehearth. The temperature in the forehearth is typically

    cooler than that in the melting section by 100 to 200C.

    Furnaces may operate continuously for approximately a year before

    rebuilding is necessary. With gas and oil furnaces the glass is heated by

    exhaust gases that travel above the molten glass. Air for combustion is

    preheated by either a preheating chamber in the furnace or by regeneration

    where the cold air and cold gas are made to flow through brickwork that

    shortly before carried hot exhaust gases from the furnace. The flow is

    typically reversed at half-hour intervals. Immersed electrodes are used when

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    heat is provided by electrical resistance. This resistance is that of the glass

    when current is passed through the molten glass from electrode to electrode.

    Electric heating is sometimes used as a booster in gas- or oilfired furnaces.

    Electrical heating has quality and environmental advantages and is more

    common for batch production of specialty glasses, particularly those with a

    volatile component. Electrical induction heating is used for small quantity

    work.

    2.5 PRIMARY FORMING PROCESSES

    Pressing - A gob of molten glass is placed in a mold by an automatic gob-

    feeding machine. A plunger descends and presses against the gob of glass

    which flows upward around the plunger and outward to fill the mold cavity.

    When the glass cools and solidifies, the plunger is withdrawn, the mold is

    opened, if necessary (because of undercuts in the part), and the part is

    removed. In some cases, excess glass may have to be trimmed from the

    part. The process is illustrated by Figure. In production situations, a turntable

    is used to carry the molds and may have as many as twenty. As the

    turntable indexes to new positions, each mold proceeds step by step through

    the full cycle of loading, pressing, cooling, trimming, and ejection or removal.

    Pressing is used to make drinking glasses and other household glassware,

    lenses, lamp globes, and TV tube parts.

    Blowing - is similar to blow molding of plastics. As in blow molding of

    plastics, there are two operations, one to make the parison and the other to

    make the hollow glass object from the parison. The operation can be manual,

    with or without a mold to control the shape of the finished part, or automatic

    with a number of process variations.

    Hand blowing into the open air, without a mold, but with shaping of the

    bubble with the aid of hand tools, has been practiced for centuries. The basic

    process with molds is illustrated in Figure. Blowing is used extensively in the

    production of glass bottles, containers, and vases and jars.

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    Electrically heated

    Typical glass pot furnace for melting glass.

    Manual blowing - The skilled artisan uses a glassworkers blowpipe

    consisting of a metal tube with a wooden handle and mouthpiece at one end

    and a nose or gathering head at the other end. Making a container, vase,

    drinking glass, etc. with purely manual methods, involves the following

    steps:

    1. Gathering - The nose end of the blowpipe is immersed in melted glass and

    is rotated slowly. The viscous glass sticks to the end of the blowpipe. For

    large objects, several repeats of gathering may be required.

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    2. The blowpipe is continually rotated to keep the gob of glass centered and

    the artisan blows a small amount of air from the mouth through the pipe,

    making a bubble in the center of the glass gob and thereby creating a

    parison.

    3. Marvering - The parison (hollow gob) is rolled against a surface of metal or

    stone or wet wood, cooling the surface and imparting a straight or curved

    side to the object.

    4.The parison is enlarged by further blowing. Further contact of the parison

    with the work surface and with hand-held shaping tools in a series of steps,

    gradually produces the desired shape.

    Some reheating may be required and continual rotation of the blowpipe is

    carried out to keep the workpiece circular and centered. Selective cooling or

    heating, cutting with shears, and attachment of glass handles or other

    elements may be carried out before the object is completed. Figure

    illustrates a typical sequence in making a glass pitcher. Figure shows a

    collection of glassblowers hand tools. For repetitive blowing of some

    particular object, the glassworker may blow the parison into a mold made

    from water-soaked wood (beechwood has been traditionally used), graphite,

    or cast iron. This reduces or eliminates much of the tool and workpiece

    manipulation required, speeds the operation, and reduces the skill required

    by the glassworker. Because of the high level of skill required, the use of

    manual methods of blowing has declined in favor of machine blowing except

    for artistic work. The method is still used for art work, prototypes, and mall

    quantity production of bottles, containers, laboratory vessels, and other

    specialty glassware.

    Lampworking (lamp blowing, and scientific glass blowing) - is the

    forming of glass articles from tubing and rods by heating in a gas flame

    (lamp). The operation i s essentially manual, but differs from the manual

    glass blowing described above in that it starts with a tube or rod rather than

    a gob of molten glass. Its primary application is the fabrication of laboratory

    apparatus and instruments. Medical, veterinary, food processing, and

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    chemical industries require apparatus that use glassware made with this

    approach. The tubing or rod is heated by a gas flame and then formed by

    any of a variety of manual operations including blowing, bending, flaring,

    cutting, sealing, joining, and working with a large number of hand tools. In

    higher production situations, the end of a glass rod is heated and placed in a

    die that presses the softened material into a small part and severs it from

    the rod. Tubing can be similarly heated at the end, which can then be formed

    by blowing in a suitable mold. Scientific glass blowing has broadened in

    recent years to include working with flat and powdered glass as well as

    tubing and rods, and working with a variety of glass types and surface

    treatments.

    Machine blowing Automatic machine blowing is used in the production of

    glass bottles, jars, drinking glasses, and other glass containers that are

    manufactured in mass-production quantities. Machine blowing methods have

    the following elements:

    1. equipment for feeding a gob of melted glass to the machine,

    2.a means for converting the gob into a parison, i.e., introducing a hollow in

    the gob for later blowing,

    3. inflation of the hollow gob (parison) against the inner surfaces of a mold,

    4.a means for forming the elements at the open end of the object molded,

    5. a means for trimming any excess material from the finished object, and,

    6. annealing the finished product.

    Material in process may be reheated during the operation sequence. Notable

    machine methods are the press-blow, blow-blow, suck-blow and

    rotary-mold (paste mold) processes.

    SUCKFLOW PROCESS

    The original machine developed by M. J. Owens was put into production

    around 1904 but has been much further developed since then. The glass is

    brought into the parison mold by suction, hence the name, suck-blow

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    process. The work is performed on a large rotary table. Motion of molds and

    other elements is controlled by cams.

    The operating sequence is as follows: The parison mold, with an open

    bottom, is lowered into the surface of molten glass. Suction applied to the

    top of the mold draws glass into the mold cavity. A pin with a rounded end

    puts The neck portion of the bottle is also formed in this mold.

    The parison mold is lifted and a knife passes across the bottom of the mold,

    severing any excess glass from the parison. At the same time, the rounded

    pin at the top is withdrawn, and air pressure in the resulting opening

    enlarges the

    top of the parison, forming a bubble. The mold opens, freeing the parison

    which is held by neck rings at its upper end. The parison is out in the open as

    the machine table rotates. The parison elongates from the effects of gravity

    and from several puffs of air into the bubble.

    The parison enters the blow mold, which closes around it. Air is blown into

    the bubble, expanding the parison against the mold walls The neck rings

    open and the mold with the bottle inside drops below the pot as the table

    continues to rotate. The mold and bottle cool. mold opens and the bottle is

    discharged. Figure illustrates the molding action schematically. The machine

    is used for largescale production. With smaller bottles, double and triple

    molds are used so that each cycle of the machine produces two or three

    bottles.

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    Suck flow

    process

    FLAT CLASS PROCESS:

    Drawing sheet glass (the

    Fourcault process) - The

    Fourcault process was the first

    successful mechanized production

    method for drawing sheet glass

    directly from a tank. It was first

    carried out on a production basis in

    1914. Prior to that, the production

    of flat glass was at least partly a

    manual operation. The method is

    keyed to the debiteuse, a long

    clay block with a lengthwise slot.

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    The block floats on the molten glass but, when it is pressed slightly down,

    into the molten glass, some glass rises out of the slot. This glass is grasped

    by an iron bait and is pulled upward past a cooling station and into an

    annealing tower. The tower contains rollers that draw the glass upward and

    the operation is thereafter continuous. The rate of drawing, among other

    factors, determines the thickness of the glass. (Slower drawing yields greater

    thickness.) The length of the slot in the debiteuse determines the width of

    the ribbon. Width is maintained by pairs of knurled rollers at the edges that

    maintain a constant side pull on the ribbon. The drawback of the process is a

    tendency toward a small amount of waviness in the sheet, which cannot be

    avoided. There may also be fine marks on the glass surface left by the rollers

    and some tendency to devitrification caused by the refractory material from

    which the debiteuse is made. Figure illustrates the process

    Drawing sheet glass (the Colburn or Libby-Owens process) - This

    process, seen in Figure, is similar to the Fourcault process but does not use

    the debiteuse. Instead, the initial ribbon of glass is picked up from the tank

    with a metal bait and immediately controlled by chilled rollers at the

    edges. It also is

    diverted into a

    horizontal

    direction by a

    polished roller

    after traveling

    upward only

    about 27 in (70

    cm). It is

    stretched,

    flattened, and

    supported by

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    transporting rollers as it moves into a 200 ft (60 m) annealing l hr. The

    drawing speed with the Colburn process is twice that used with Fourcault.

    Manufacturing Sequence for Plate glass

    1) Raw materials are received and stored2) Materials are weighed and mixed

    3) Batch is fed to furnace and melted

    4) Molten glass flows from the furnace through forming rolls to form a rough,

    continuous ribbon

    5) Ribbon is stretched slightly to improve flatness

    6) Ribbon travels through annealing l hr

    7) Both top and bottom surfaces are ground flat by a series of vertical

    spindle, large-disc grinding machines as the ribbon travels past them

    8) Both surfaces are polished with similar machines using finer abrasive

    9) An acid wash removes grinding residue

    10) Sheets are cut from the ribbon

    11) Sheets are inspected and sent to storage for later final cutting and

    shipment

    STEAM BLOWING

    Steam blowing - Streams of molten glass flowing from a melting tank

    through sievelike platinum bushings are impinged upon by jets of steam. The

    jets approach the glass streams at a small included angle, and push them at

    a faster rate, causing them to draw into finer fibers. If the steam jets are

    strong enough, the fibers will break into shorter lengths. The strength of the

    steam jets determines how discontinuous and fine the final fibers will be. The

    fibers can be processed in several ways. When used to make thick pads or

    wool, they are sprayed with a binder and fall on to a conveyor where they

    pile up into wool. The binder is dried and the wool is cut into discrete batts of

    fibrous glass. Figure illustrates this process. When made into glass mat, the

    fibers are allowed to fall into a thin, web-like mat that is then immersed into

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    a bath of binder and then passed through a drying oven. A major use for

    such mat is the reinforcement of fiber glass-reinforced plastic products.

    PORCELAN

    The term porcelain refers to a wide range of ceramic products that

    have been baked at high temperatures to achieve vitreous, or glassy,

    qualities such as translucence and low porosity. Among the most familiar

    porcelain goods are table and decorative china, chemical ware, dental

    crowns, and electrical insulators. Usually white or off-white, porcelain comes

    in both glazed and unglazed varieties, with bisque, fired at a high

    temperature, representing the most popular unglazed variety.

    Raw Materials

    The primary components of porcelain are clays, feldspar or flint, and

    silica, all characterized by small particle size. To create different types of

    porcelain, craftspeople combine these raw materials in varying proportions

    until they obtain the desired green (unfired) and fired properties. Although

    the composition of clay varies depending upon where it is extracted and how

    it

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    To make porcelain, the raw materials such as clay, felspar, and silica are first

    crushed using jaw crushers, hammer mills, and ball mills. After cleaning to

    remove improperly sized materials, the mixture is subjected to one of four

    forming processes soft plastic forming, stiff plastic forming, pressing, or

    casting depending on the type of ware being produced. The ware then

    undergoes a preliminary firing step, bisque-firing.It is treated, all clays vitrify (develop glassy qualities), only at extremely high

    temperatures unless they are mixed with materials whose vitrification

    threshold is lower. Unlike glass, however, clay is refractory, meaning that it

    holds its shape when it is heated. In effect, porcelain combines glass's low

    porosity with clay's ability to retain its shape when heated, making it both

    easy to form and ideal for domestic use. The principal clays used to make

    porcelain are china clay and ball clay, which consist mostly of kaolinate, a

    hydrous aluminum silicate.

    Feldspar, a mineral comprising mostly aluminum silicate, and flint, a type of

    hard quartz, function as fluxes in the porcelain body or mixture. Fluxes

    reduce the temperature at which liquid glass forms during firing to between

    1,000 and 1,300 degrees Celsius. This liquid phase binds the grains of the

    body together.

    Silica is a compound of oxygen and silicon, the two most abundant elements

    in the earth's crust. Its resemblance to glass is visible in quartz (its

    crystalline form), opal (its amorphous form), and sand (its impure form).

    Silica is the most common filler used to facilitate forming and firing of the

    body, as well as to improve the properties of the finished product. Porcelain

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    may also contain alumina, a compound of aluminum and oxygen, or low-

    alkali containing bodies, such as steatite, better known as soapstone.

    The Manufacturing Process

    After the raw materials are selected and the desired amounts weighed, they

    go through a series of preparation steps. First, they are crushed and purified.

    Next, they are mixed together before being subjected to one of four forming

    processessoft plastic forming, stiff plastic forming, pressing, or casting; the

    choice depends upon the type of ware being produced. After the porcelain

    has been formed, it is subjected to a final purification process, bisque-firing,

    before being glazed. Glaze is a layer of decorative glass applied to and fired

    onto a ceramic body. The final manufacturing phase is firing, a heating step

    that takes place in a type of oven called a kiln.

    Crushing the raw materials

    First, the raw material particles are reduced to the desired size, which

    involves using a variety of equipment during several crushing and grinding

    steps. Primary crushing is done in jaw crushers which use swinging metal

    jaws. Secondary crushing reduces particles to 0.1 inch (.25 centimeter) or

    less in diameter by using mullers (steel-tired wheels) or hammer mills,

    rapidly moving steel hammers. For fine grinding, craftspeople use ball mills

    that consist of large rotating cylinders partially filled with steel or ceramic

    grinding media of spherical shape.

    Cleaning and mixing

    The ingredients are passed through a series of screens to remove any under-

    or over-sized materials. Screens, usually operated in a sloped position, are

    vibrated mechanically or electromechanically to improve flow. If the body is

    to be formed wet, the ingredients are then combined with water to produce

    the desired consistency. Magnetic filtration is then used to remove iron from

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    the slurries, as these watery mixtures of insoluble material are called.

    Because iron occurs so pervasively in most clays and will impart

    After bisque firing, the porcelain wares are put through a glazing operation,

    which applies the proper coating. The glaze can be applied by painting,

    dipping, pouring, or spraying. Finally, the ware undergoes a firing step in an

    oven or kiln. After cooling, the porcelain ware is complete.

    Forming the body

    Next, the body of the porcelain is formed. This can be done using one of four

    methods, depending on the type of ware being produced:

    Soft plastic forming, where the clay is shaped by manual molding, wheel

    throwing, jiggering, or ram pressing. In wheel throwing, a potter places the

    desired amount of body on a wheel and shapes it while the wheel turns. In

    jiggering, the clay is put on a horizontal plaster mold of the desired shape;

    that mold shapes one side of the clay, while a heated die is brought down

    from above to shape the other side. In ram pressing, the clay is put between

    two plaster molds, which shape it while forcing the water out. The mold is

    then separated by applying vacuum to the upper half of the mold and

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    pressure to the lower half of the mold. Pressure is then applied to the upper

    half to free the formed body.

    Stiff plastic forming, which is used to shape less plastic bodies. The body

    is forced through a steel die to produce a column of uniform girth. This is

    either cut into the desired length or used as a blank for other forming

    operations.

    Pressing, which is used to compact and shape dry bodies in a rigid die or

    flexible mold. There are several types of pressing, based on the direction of

    pressure. Uniaxial pressing describes the process of applying pressure from

    only one direction, whereas isostatic pressing entails applying pressure

    equally from all sides.

    slip casting, in which a slurry is poured into a porous mold. The liquid is

    filtered out through the mold, leaving a layer of solid porcelain body. Water

    continues to drain out of the cast layer, until the layer becomes rigid and can

    be removed from the mold. If the excess fluid is not drained from the mold

    and the entire material is allowed to solidify, the process is known as solid

    casting.

    Bisque-firing

    After being formed, the porcelain parts are generally bisque-fired, which

    entails heating them at a relatively low temperature to vaporize volatile

    contaminants and minimize shrinkage during firing.

    Glazing

    After the raw materials for the glaze have been ground they are mixed with

    water. Like the body slurry, the glaze slurry is screened and passed through

    magnetic filters to remove contaminants. It is then applied to the ware by

    means of painting, pouring, dipping, or spraying. Different types of glazes

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    can be produced by varying the proportions of the constituent ingredients,

    such as alumina, silica, and calcia. For example, increasing the alumina and

    decreasing the silica produces a matte glaze.

    Firing

    Firing is a further heating step that can be done in one of two types of oven,

    or kiln. A periodic kiln consists of a single, refractory-lined, sealed chamber

    with burner ports and flues (or electric heating elements). It can fire only one

    batch of ware at a time, but it is more flexible since the firing cycle can be

    adjusted for each product. A tunnel kiln is a refractory chamber several

    hundred feet or more in length. It maintains certain temperature zones

    continuously, with the ware being pushed from one zone to another.

    Typically, the ware will enter a preheating zone and move through a central

    firing zone before leaving the kiln via a cooling zone. This type of kiln is

    usually more economical and energy efficient than a periodic kiln.

    During the firing process, a variety of reactions take place. First, carbon-

    based impurities burn out, chemical water evolves 100 to 200 degrees

    Celsius, and carbonates and sulfates begin to decompose 400 to 700

    degrees Celsius. Gases are produced that must escape from the ware. On

    further heating, some of the minerals break down into other phases, and the

    fluxes present (feldspar and flint) react with the decomposing minerals to

    form liquid glasses 700 to 1,100 degrees Celsius. These glass phases are

    necessary for shrinking and bonding the grains. After the desired density is

    achieved 1,200 degrees Celsius, the ware is cooled, which causes the liquid

    glass to solidify, thereby forming a strong bond between the remaining

    crystalline grains. After cooling, the porcelain is complete.

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    3. PAINT MANUFACTURING

    Paint is a term used to describe a number of substances that consist of

    a pigment suspended in a liquid or paste vehicle such as oil or water. With a

    brush, a roller, or a spray gun, paint is applied in a thin coat to various

    surfaces such as wood, metal, or stone. Although its primary purpose is toprotect the surface to which it is applied, paint also provides decoration.

    Perhaps the greatest paint-related advancement has been its proliferation.

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    The first step in making paint involves mixing the pigment with resin,

    solvents, and additives to form a paste. If the paint is to be for industrial use,

    it usually is then routed into a sand mill, a large cylinder that agitates tiny

    particles of sand or silica to grind the pigment particles, making them

    smaller and dispersing them throughout the mixture. In contrast, most

    commercial-use point is processed in a high-speed dispersion tank, in which

    a circular, toothed blade attached to a rotating shaft agitates the mixture

    and blends the pigment into the solvent. Today, paints are used for interior

    and exterior housepainting, boats, automobiles, planes, appliances,

    furniture, and many other places where protection and appeal are desired.

    Raw Materials

    A paint is composed of pigments, solvents, resins, and various additives. The

    pigments give the paint color; solvents make it easier to apply; resins help it

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    dry; and additives serve as everything from fillers to anti fungicidal agents.

    Hundreds of different pigments, both natural and synthetic, exist. The basic

    white pigment is titanium dioxide, selected for its excellent concealing

    properties, and black pigment is commonly made from carbon black. Other

    pigments used to make paint include iron oxide and cadmium sulfide for

    reds, metallic salts for yellows and oranges, and iron blue and chrome

    yellows for blues and greens.

    Solvents are various low viscosity, volatile liquids. They include petroleum

    mineral spirits and aromatic

    solvents such as benzol, alcohols,

    esters, ketones, and acetone. Thenatural resins most commonly

    used are lin-seed, coconut, and

    soybean oil, while alkyds, acrylics,

    epoxies, and polyurethanes

    number among the most popular

    synthetic resins. Additives serve

    many purposes. Some, like calcium

    carbonate and aluminum silicate,

    are simply fillers that give the

    paint body and substance without

    changing its properties. Other additives produce certain desired

    characteristics.

    Paint canning is a completely automated process. For the standard 8 pint

    paint can available to consumers, empty cans are first rolled horizontally

    onto labels, then set upright so that the point can be pumped into them. One

    machine places lids onto the filled cans while a second machine presses on

    the lids to seal the cons. From wire that is fed into it from coils, a bailometer

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    cuts and shapes the handles before hooking them into holes precut in the

    cans. In paint, such as the thixotropic agents that give paint its smooth

    texture, driers, anti-settling agents, anti-skinning agents, defoamers, and a

    host of others that enable paint to cover well and last long.

    Design

    Paint is generally custom-made to fit the needs of industrial customers. For

    example, one might be especially interested in a fast-drying paint, while

    another might desire a paint that supplies good coverage over a long

    lifetime. Paint intended for the consumer can also be custom-made. Paint

    manufacturers provide such a wide range of colors that it is impossible tokeep large quantities of each on hand. To meet a request for "aquamarine,"

    "canary yellow," or "maroon," the manufacturer will select a base that is

    appropriate for the deepness of color required. (Pastel paint bases will have

    high amounts of titanium dioxide, the white pigment, while darker tones will

    have less.) Then, according to a predetermined formula, the manufacturer

    can introduce various pigments from calibrated cylinders to obtain the

    proper color.

    The Manufacturing Process

    Making the paste

    Pigment manufacturers send bags of fine grain pigments to paint plants.

    There, the pigment is premixed with resin (a wetting agent that assists in

    moistening the pigment), one or more solvents, and additives to form a

    paste.

    Dispersing the pigment

    The paste mixture for most industrial and some consumer paints is now

    routed into a sand mill, a large cylinder that agitates tiny particles of sand or

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    silica to grind the pigment particles, making them smaller and dispersing

    them throughout the mixture. The mixture is then filtered to remove the

    sand particles.

    Instead of being processed in sand mills, up to 90 percent of the water-based

    latex paints designed for use by individual homeowners are instead

    processed in a high-speed dispersion tank. There, the premixed paste is

    subjected to high-speed agitation by a circular, toothed blade attached to a

    rotating shaft. This process blends the pigment into the solvent.

    Thinning the paste

    Whether created by a sand mill or a dispersion tank, the paste must now be

    thinned to produce the final product. Transferred to large kettles, it is

    agitated with the proper amount of solvent for the type of paint desired.

    Canning the paint

    The finished paint product is then pumped into the canning room. For the

    standard 8 pint (3.78 liter) paint can available to consumers, empty cans are

    first rolled horizontally onto labels, then set upright so that the paint can be

    pumped into them. A machine places lids onto the filled cans, and a second

    machine presses on the lids to seal them. From wire that is fed into it from

    coils, a bailometer cuts and shapes the handles before hooking them into

    holes precut in the cans. A certain number of cans (usually four) are then

    boxed and stacked before being sent to the warehouse.

    Byproducts/Waste

    A recent regulation concerning the emission of volatile organic compounds

    (VOCs) affects the paint industry, especially manufacturers of industrial oil-

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    based paints. It is estimated that all coatings, including stains and varnishes,

    are responsible for 1.8 percent of the 2.3 million metric tons of VOCs

    released per year. The new regulation permits each liter of paint to contain

    no more than 250 grams of solvent. Paint manufacturers can replace the

    solvents with pigment, fillers, or other solids inherent to the basic paint

    formula. This method produces thicker paints that are harder to apply, and it

    is not yet known if such paints are long lasting. Other solutions include using

    paint powder coatings that use no solvents, applying paint in closed systems

    from which VOCs can be retrieved, using water as a solvent, or using acrylics

    that dry under ultraviolet light or heat.

    A large paint manufacturer will have an in-house wastewater treatmentfacility that treats all liquids generated on-site, even storm water run-off. The

    facility is monitored 24 hours a day, and the Environmental Protection

    Agency (EPA) does periodic records and systems check of all paint

    facilities. The liquid portion of the waste is treated on-site to the standards of

    the local publicly owned wastewater treatment facility; it can be used to

    make low-quality paint. Latex sludge can be retrieved and used as fillers in

    other industrial products. Waste solvents can be recovered and used as fuels

    for other industries. A clean paint container can be reused or sent to the

    local landfill.

    4.0 AUTOMOBILE INDUSTRY

    Raw Materials

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    Although the bulk of an automobile is virgin steel, petroleum-based products

    (plastics and vinyls) have come to represent an increasingly large

    percentage of automotive components. The light-weight materials derived

    from petroleum have helped to lighten some models by as much as thirty

    percent. As the price of fossil fuels continues to rise, the preference for

    lighter, more fuel efficient vehicles will become more pronounced.

    Design

    With the help of computer-aided design equipment, designers develop basic

    concept drawings that help them visualize the proposed vehicle's

    appearance. Based on this simulation, they then construct clay models that

    can be studied by styling experts familiar with what the public is likely to

    accept. Aerodynamic engineers also review the models, studying air-flow

    parameters and doing feasibility studies on crash tests. Only after all models

    have been reviewed and accepted are tool designers permitted to begin

    building the tools that will manufacture the component parts of the new

    model.

    Automobiles:

    The production process for automobiles consists of the manufacture of all the

    individual parts, including their finishing with heat treatments, plating and

    painting, if used, their assembly into various mechanical subassemblies,

    followed by the combination of all these subassemblies and parts into a

    finished vehicle. Automatic and robotic equipment is interspersed with

    human assemblers.

    Many of the components assembled on the line are subassemblies that

    were, themselves, manually assembled on lines with some interspersed

    robotic and automatic assembly stations. Examples of these subassemblies

    are the chassis, body, bumpers, fuel pumps, piping and tank, radiator,

    suspension system, seats, engine, transmission, drive shaft, rear axle, wheel

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    assemblies, instruments and instrument panel assembly, steering system,

    brake system assemblies, electrical wiring, battery, generator or alternator,

    starter, headlights and interior lighting system, as well as auxiliary

    equipments such as air conditioning, radio, stereo, and cruise control.

    Some subassemblies are put together completely with dedicated

    (special purpose), high production equipment, others with a combination of

    robotic and dedicated equipment, with or without manual assembly of some

    components.

    Robotic operation is common for such operations as welding, painting,

    windshield assembly, and placement of heavy components like the engine,

    transmission and body assembly. Fully automatic assembly with dedicated

    equipment is most common with components such as spark plugs, hydraulic

    brake cylinders, shock absorbers and other subassemblies that are used in

    multiples in the car.

    The Manufacturing Process

    Automobile engines - are assemblies of many precision cast,

    stamped, forged, and machined parts, some of which are electroplated or

    painted. Except for specialty situations where only a very limited number of

    a particular engine is built, assembly takes place on an assembly line. Some

    portions of the assembly operation may be robotic or mechanized with

    special equipment.

    The basic engine block is normally an iron casting made in sand molds.

    It is then machined extensively by milling, drilling, boring, reaming, grinding,

    and honing.The crankshaft is either forged or cast , and is turned and

    ground. Connecting rods are usually forged, bored and honed. Pistons are

    sand cast or permanent mold cast of aluminum and turned on special

    machines. Valves are forged, turned, and ground. Camshafts are forged or

    cast, and turned and ground on special machines. Manifolds are cast and

    machined by milling and other operations.

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    Machine screws to fasten parts together are usually cold headed with

    rolled threads. the engine factory or purchased, are included in the

    assembly. These include parts that may be stamped from sheet metal, die

    cast, or molded from plastics. They also include spark plugs, electrical wiring,

    oil and air filters. bearings, seals, insulators, electronic ignition and fuel

    metering parts, carburetors, fuel injection parts, coils, drive belts, and

    pulleys. After assembly,

    the engine is tested for correct operation and power at a test stand. If

    satisfactory, it is moved to the final assembly line for installation in an

    automobile. Due to the high production volumes that typically accompany

    automotive production, many of the parts making operations are highly

    automatic and engineered specifically for the component in question. Special

    machines and transfer lines are often part of the parts-making operations.

    Automobile bodies - Auto body parts are made from sheet steel

    although, increasingly, fiberglass reinforced polyester plastic and formed

    thermoplastic sheet parts are finding their way into current designs. With the

    sheet steel parts, blanking, forming, and deep drawing operations are

    performed. These operations are performed on high-production equipment

    with compound dies and progressive dies, where applicable, with robotic

    unloading of the stamped parts. Body parts are fastened together by

    resistance welding and some arc welding, most of it robotic. Weld joints are

    made smooth by application of high-lead body solder, sanded smooth. The

    welded body assembly is dipped in a cleaning bath and then given a zinc

    phosphate treatment to aid in corrosion resistance. Plastic sealers are

    applied in locations where moisture can be trapped. The complete metal

    body assembly is then painted. The first coat is often applied with the

    electrophoretic method, dipping the body into a vat of water based paint.

    The selected color is often applied with robotically-manipulated, electrostatic

    paint guns, with some manual spray application to selected or difficult-to-

    cover areas. A final clear coating is applied similarly, and is buffed and

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    polished after it dries. Sound deadening materials are applied in some areas

    with rubber-based adhesives.

    A polyurethane coating is applied to the bottom surfaces to provide

    protection against flying stones gravel and other debris. After painting,

    doors, deck lids, hood, trim, windows, doors, bumpers, interior panels, the

    dashboard with instruments, seats, lights, radios, speakers, carpeting, and

    various hardware items are assembled to the body as part of the final auto

    assembly operation. The body is then conveyed to the main assembly line

    where it is assembled to the other components that make up the car.

    Automobile chassis - the steel frame that supports the car, is used in

    many automobiles. However, the more common auto designs now

    incorporate a unitized body. With the unitized design, extra members are

    added to the body to enable it to support the weight of the vehicle and to

    withstand road shocks.

    The supporting members then, are in the body assembly rather than part of

    a separate chassis. Where a separate chassis is used, it is made from heavy

    gauge sheet steel that is blanked, formed, and hole-punched. It is assembled

    and arc welded with other similarly-made chassis components into a strong

    and rigid assembly. Even with a unitized body, however, there normally is a

    sub frame, similar to the earlier chassis but only in the front of the vehicle, to

    support the engine, transmission, and front suspension. In many designs

    there also is a small rear frame to support the rear axle, differential, and

    suspension. These frames are also made of heavy gage steel stampings,

    welded together. The net effect of the unitized body construction is a

    reduction in vehicle weight.

    Automobile windshields - consist of curved pieces of safety glass.

    The glass is made with raw materials including potassium, magnesium, and

    aluminum oxides, in addition to the more common materials, to provide

    hardness and other properties. The molten glass is fed to float glass

    equipment to produce a large, flat glass sheet. Each sheet is cut into smaller,

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    windshield-size sheets. These are then bent to the desired curvature by

    heating them and draping them over. a form of refractory material. Gravity,

    and the softness of the heated sheets, causes them to take the shape of the

    form. The bent sheet is tempered cleaned and assembled with an internal

    layer of plastic and a second layer of glass. These three assembled pieces

    are placed in an autoclave, which provides pressure to force the three layers

    together and heat to bond the plastic to the glass surfaces. The finished

    windshield then undergoes a plastic injection molding operation where it

    becomes an insert in an injection mold and a plastic frame is molded around

    it. The windshield is then ready for shipment to the automobile assembly

    factory.

    Components

    The automobile assembly plant represents only the final phase in the

    process of manufacturing an automobile, for it is here that the components

    supplied by more than 4,000 outside suppliers, including company-owned

    parts suppliers, are brought together for assembly, usually by truck or

    railroad. Those parts that will be used in the chassis are delivered to one

    area, while those that will comprise the body are unloaded at another.

    Chassis

    The typical car or truck is constructed from the ground up (and out). The

    frame forms the base on which the body rests and from which all subsequent

    assembly components follow. The frame is placed on the assembly line and

    clamped to the conveyer to prevent shifting as it moves down the line. From

    here the automobile frame moves to component assembly areas where

    complete front and rear suspensions, gas tanks, rear axles and drive shafts,

    gear boxes, steering box components, wheel drums, and braking systems

    are sequentially installed.

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    An off-line operation at this stage of production mates the vehicle's engine

    with its transmission. Workers

    use robotic arms to install

    these heavy components

    inside the engine

    compartment of the frame.

    After the engine and

    transmission are installed, a

    On automobile assembly lines,

    much of the work is now done

    by robots rather than humans.In the first stages of automobile manufacture, robots weld the floor pan

    pieces together and assist workers in placing components such as the

    suspension onto the chassis. The worker attaches the radiator, and another

    bolts it into place. Because of the nature of these heavy component parts,

    articulating robots perform all of the lift and carry operations while

    assemblers using pneumatic wrenches bolt component pieces in place.

    Careful ergonomic studies of every assembly task have provided assembly

    workers with the safest and most efficient tools available.

    Body

    Generally, the floor pan is the largest body component to which a

    multitude of panels and braces will subsequently be either welded or bolted.

    As it moves down the assembly line, held in place by clamping fixtures, the

    shell of the vehicle is built. First, the left and right quarter panels are

    robotically disengaged from pre-staged shipping containers and placed onto

    the floor pan, where they are stabilized with positioning fixtures and welded.

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    The front and rear door pillars, roof, and body side panels are

    assembled in the same fashion. The shell of the automobile assembled in

    this section of the process lends itself to the use of robots because

    articulating arms can easily introduce various component braces and panels

    to the floor pan and perform a high number of weld operations in a time

    frame and with a degree of accuracy no human workers could ever

    approach. Robots can pick and load 200-pound (90.8 kilograms) roof panels

    and place them precisely in the proper weld position with tolerance

    variations held to within .001 of an inch. Moreover, robots can also tolerate

    the

    The bodyis built up on a

    separate

    assembly line

    from the

    chassis. Robots

    once again

    perform most

    of the welding

    on the various panels, but human workers are necessary to bolt the parts

    together. During welding, component pieces are held securely in a jig while

    welding operations are performed. Once the body shell is complete, it is

    attached to an overhead conveyor for the painting process. The multi-step

    painting process entails inspection, cleaning, undercoat (electrostatically

    applied) dipping, drying, topcoat spraying, and baking.

    As t