ap-42 background document, section 2.3 medical … rotary kiln incinerator s ... medical waste...

7/93 (Reformatted 1/95) Solid Waste Disposal 2.3-1

EMISSION FACTOR DOCUMENTATION FOR

AP-42 SECTION 2.6

MEDICAL WASTE INCINERATION

Office of Air Quality Planning and StandardsOffice of Air and Radiation

U.S. Environmental Protection AgencyResearch Triangle Park, North Carolina 27711

July 1993

nja.117\(Reformatted 1/95) 7/93 ii

TABLE OF CONTENTS

Section Page

List of Figures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . iv

List of Tables . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . v

1.0 INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-1

2.0 INDUSTRY DESCRIPTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1

2.1 CHARACTERIZATION OF THE INDUSTRY . . . . . . . . . . . . . . . . . . . . . . . . 2-12.2 OVERVIEW OF INCINERATOR TYPES . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1

2.2.1 Controlled Air Incinerators . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-22.2.2 Excess Air Incinerators . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-42.2.3 Rotary Kiln Incinerators . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-5

2.3 MEDICAL WASTE INCINERATOR EMISSIONS . . . . . . . . . . . . . . . . . . . . . 2-82.3.1 Particulate Matter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-82.3.2 Metals . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-92.3.3 Acid Gases . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-102.3.4 Oxides of Nitrogen . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-102.3.5 Carbon Monoxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-112.3.6 Organics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-112.3.7 Other Pollutants Specific to Medical

Waste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-122.4 CONTROL TECHNOLOGIES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-13

2.4.1 Wet Scrubbers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-132.4.2 Fabric Filters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-142.4.3 Dry Sorbent Injection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-152.4.4 Electrostatic Precipitators . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-17

2.5 REFERENCES FOR SECTION 2.0 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-18

3.0 GENERAL DATA REVIEW AND ANALYSIS PROCEDURES . . . . . . . . . . . . . . . . 3-1

3.1 LITERATURE SEARCH AND SCREENING . . . . . . . . . . . . . . . . . . . . . . . . . 3-13.2 EPA PROTOCOL FOR DATA QUALITY . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-1

4.0 POLLUTANT EMISSION FACTOR DEVELOPMENT . . . . . . . . . . . . . . . . . . . . . . . 4-1

4.1 REVIEW OF SPECIFIC SOURCES OF DATA . . . . . . . . . . . . . . . . . . . . . . . . 4-14.1.1 St. Bernardines . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-1

nja.117\sect.2-6 iii

4.1.2 Cape Fear . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-24.1.3 Jordan Hospital . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-34.1.4 Kaiser Permanente . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-34.1.5 Lenoir Memorial . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-44.1.6 AMI . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-44.1.7 Cedars Sinai . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-44.1.8 St. Agnes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-54.1.9 Sutter General . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-5

nja.117\(Reformatted 1/95) 7/93 iv

TABLE OF CONTENTS(continued)

Section Page

4.1.10 Swedish American Hospital . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-54.1.11 University of Southern California . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-64.1.12 Royal Jubilee . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-64.1.13 Borgess Medical Center . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-64.1.14 Morristown Memorial Hospital . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-74.1.15 Burlington County Memorial Hospital . . . . . . . . . . . . . . . . . . . . . . . . . 4-74.1.16 Mayo Foundation Institute Hall Research Facility - November 4 and 11 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-84.1.17 ERA Tech, North Jackson, Ohio . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-84.1.18 Milton S. Hershey Medical Center . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-84.1.19 Erlanger Medical Center - South Unit . . . . . . . . . . . . . . . . . . . . . . . . . . 4-94.1.20 Nazareth Hospital . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-94.1.21 Hamilton Hospital . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-94.1.22 Raritan Bay Health Services Corporation . . . . . . . . . . . . . . . . . . . . . . 4-104.1.23 Bio-Waste Management Corporation . . . . . . . . . . . . . . . . . . . . . . . . . 4-104.1.24 Safeway Disposal System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-104.1.25 Erlanger Medical Center - North Unit . . . . . . . . . . . . . . . . . . . . . . . . . 4-114.1.26 Memorial Hospital . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-114.1.27 ERA Tech . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-114.1.28 Southland Exchange Joint Venture . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-114.1.29 Medical Energy Generation Associates . . . . . . . . . . . . . . . . . . . . . . . . 4-124.1.30 Therm-Tec Destruction Service - January 1989 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-124.1.31 Bio-Medical Service Corporation . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-134.1.32 Mayo Foundation Institute Hills Research Facility - November 3 and 10 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-134.1.33 Therm-Tec Destruction Service - May 1989 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-134.1.34 Hamot Medical Center . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-144.1.35 HCA North Park Hospital . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-144.1.36 Humana East Ridge Hospital . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-144.1.37 Helene Fuld Medical Center . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-154.1.38 Other Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-15

4.2 PROTOCOL FOR DATABASE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-184.2.1 Charge Rates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-184.2.2 Data Presented in Pounds per Hour or

Grams per Hour . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-184.2.3 Data Presented in Grains per

Dry Standard Cubic Foot (gr/dscf) . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-574.2.4 Data Presented in Parts per Million

Dry Volume (ppmdv) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-57

nja.117\sect.2-6 v

4.2.5 Oxygen or Moisture Corrected Data . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-594.3 DATA QUALITY CHECKING . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-594.4 EMISSION FACTORS FOR AP-42 SECTION 2.6 . . . . . . . . . . . . . . . . . . . . 4-59

REFERENCES FOR SECTION 4.0 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-61

5.0 AP-42 SECTION 2.6: MEDICAL WASTE INCINERATION . . . . . . . . . . . . . . . . . . 5-1

nja.117\(Reformatted 1/95) 7/93 vi

LIST OF FIGURES

Figure Page

2-1 Controlled Air Incinerator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-3

2-2 Excess Air Incinerator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-6

2-3 Rotary Kiln Incinerator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-7

nja.117\sect.2-6 vii

LIST OF TABLES

Table Page

4-1 Summary of Controlled Air MWI Emission Factorson a Test-By-Test Basis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-19

4-2 Summary of Rotary Kiln MWI Emission Factorson a Test-By-Test Basis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-54

4-3 Conversions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-58

nja.117\sect.2-6 1-1

1.0 INTRODUCTION

The document "Compilation of Air Pollutant Emission Factors" (AP-42) has been

published by the U.S. Environmental Protection Agency (EPA) since 1970. Supplements to

AP-42 have been routinely published to add new emission source categories and to update

existing emission factors. The AP-42 is routinely updated by EPA to respond to new emission

factor needs of EPA, State, and local air pollution control programs and industry.

An emission factor relates the quantity (weight) of pollutants emitted to a unit of activity

of the source. The uses for the emission factors reported in AP-42 include:

1. Estimates of area-wide emissions;

2. Emission estimates for a specific facility; and

3. Evaluation of emissions relative to ambient air quality.

The purpose of this report is to provide background information from test reports to

support calculation of emission factors for medical waste incinerators (MWIs).

The emissions information in this document will be most useful in making preliminary

estimates of air emissions and should not be used in exact assessments of emissions from any

particular facility. The reason for this is that insufficient data are available to estimate the

statistical accuracy of these emission factors. In addition, variability in waste composition

contributes to variations in emission factors. In fact, the difference between measured and

estimated emissions could be as great as orders of magnitude in extreme cases. A test is the best

way to determine air emissions from a particular source.

Including the introduction (Chapter 1.0), this report contains five chapters. Chapter 2.0

gives a description of the medical waste incineration industry. It includes a characterization of

the industry, an overview of the different process types, a description of emissions, and

descriptions of the technologies used to control air emissions resulting from medical waste

incineration. Chapter 3.0 is a review of emissions data collection and analysis procedures. It

describes the methods used to locate and collect test data, the screening of emission data reports,

and the quality rating system for both emissions data and emission factors. Chapter 4.0 details

nja.117\6 (Reformatted 1/95) 7/93 1-2

pollutant emission factor development. It includes the review of specific data sets, the results of

data analyses, and the database protocol. Chapter 5.0 presents Section 2.6 of AP-42.

nja.117\sect.2-6 2-1

2.0 INDUSTRY DESCRIPTION

Medical waste incineration involves the burning of wastes produced by hospitals,

veterinary facilities, and medical research facilities. These wastes include both infectious

medical wastes, as well as non-infectious, general housekeeping wastes.

The primary purposes for MWIs are to: 1) reduce the hazard associated with the waste,

and 2) reduce the volume and mass of the waste. These objectives are accomplished by exposing

the waste to high temperatures over a sufficiently long period of time to destroy threatening

organisms and burn the combustible portion of the waste. The disadvantages of incineration

include the necessity of ash disposal and the potential for emissions of toxic and other pollutants.

2.1 CHARACTERIZATION OF THE INDUSTRY

An estimated 3.4 million tons of medical waste are generated annually in the

United States from hospitals, pharmaceutical companies, research facilities, nursing homes, and

other facilities. Using a broad definition that includes all of these facility types, there are an

estimated 5,000 MWIs in the U.S. About half of these MWIs are located at hospitals, and

72 percent have capacities less than 300 pounds per hour (lb/hr).1

Of MWIs identified in a previous study,2 the majority (>95 percent) are controlled air

units. A small percentage (<2 percent) were identified as excess air; less than 1 percent were

identified as rotary kiln. The rotary kiln units tend to be larger and are typically equipped with

air pollution control devices. Approximately 2 percent of the total population identified in this

study were found to be equipped with air pollution control devices.

2.2 OVERVIEW OF INCINERATOR TYPES

The design of a MWI, like that of any combustor, must account for a number of

interrelated factors, including residence time, temperature, and air/fuel mixing. Other factors

which can influence combustion performance are fuel feeding and distribution patterns, air

supply and distribution, heat transfer, and ash withdrawal. Like municipal solid waste (MSW),

medical waste is more difficult to burn than conventional fuels such as oil, gas, or coal because

its composition is highly variable.

Medical waste, also like MSW, has a variable ash content. Due to its variable moisture

content, the waste can have a relatively low heating value, although generally higher than MSW.

Usually, a heating value of approximately 19,700 kJ/kg (8,500 Btu/lb) is assumed for medical

nja.117\(Reformatted 1/95) 7/93 2-2

WasteFeed

ControlledUnderfire Airfor BurningDown Waste

Starved-AirCondition inLower Chamber

Air Air

Volatile Contentis Burned inUpper Chamber

Carbon Dioxide,Water Vapor

and ExcessOxygen and Nitrogen

to Atmosphere

Main Burner forMinimum CombustionTemperature

Excess AirCondition

UpperChamber

LowerChamber

Figure 2-1. Controlled Air Incinerator2

waste which consists of trash, paper, cardboard, and wood boxes. The heating value of waste

that consists only of human and animal remains is about 2,325 kJ/Kg (1,000 Btu/lb). Corrosion

can also be a problem with medical waste flue gases, due to the presence of chlorine, principally

from plastic materials in the waste. The composition of medical waste can be highly variable due

to differing collection and disposal practices at different hospitals.

2.2.1 Controlled Air Incinerators

Controlled air incineration is the most widely used MWI technology, and now dominates

the market for new systems at hospitals and similar medical facilities. This technology is also

known as starved air incineration, two-stage incineration, or modular combustion.

nja.117\sect.2-6 2-3

Figure 2-1 presents a schematic diagram of a controlled air unit.

Combustion of waste in controlled air incinerators occurs in two stages. In the first stage,

waste is fed into the primary, or lower, combustion chamber, which is operated with less than the

stoichiometric (theoretical) amount of air required for combustion. Combustion air enters the

primary chamber from beneath the incinerator hearth (below the burning bed of waste). This air

is called primary or underfire air. In the primary (starved air) chamber, the low air-to-fuel ratio

dries and facilitates volatilization of the waste, and most of the residual carbon in the ash burns.

At these conditions, temperatures are relatively low, about 760 to 980EC (1,400 to 1,800EF).

Because of the low air addition rates in the primary chamber and correspondingly low

flue gas velocities and turbulence, the amount of solids entrained in the gases leaving the primary

chamber is low. As a result, controlled air incinerators can meet many current State and local

particulate matter (PM) emission limits without add-on gas cleaning devices.

In the secondary chamber, excess air is added to burn the volatile gases evolved from the

primary chamber. Optimization of controlled air incinerators includes thorough fuel and air

mixing in the secondary chamber and prolonging residence time for complete combustion.

Temperatures in the secondary chamber may reach 980 to 1,090EC (1,800 to 2,000EF).

Each chamber may also be equipped with auxiliary burners to handle wastes with high

moisture content, to maintain minimum operating temperatures, or to assist in burnout during

start-up or shut-down procedures.

Waste feed capacities for controlled air incinerators range from about 35 to 2,950 kg

(75 to 6,500 lb) per hour at an assumed fuel heating value of 19,700 kJ/kg (8,500 Btu/lb). Waste

feed and ash removal can be manual or automatic, depending on the unit size and options

purchased. Throughput capacities for lower heating value wastes may be higher, since feed

capacities are limited by primary chamber heat release rates. Heat release rates for controlled air

incinerators typically range from about 430,000 to 710,000 kJ/hr-m3 (15,000 to 25,000 Btu/hr-

ft3).2

2.2.2 Excess Air Incinerators

While there are some similarities in operating procedures between excess air and

controlled air incinerators, overall equipment design and appearance are quite different. Excess

air incinerators are typically small modular units. They are also referred to as batch incinerators,

multiple chamber incinerators, or "retort" incinerators. Excess air incinerators typically appear as


a compact cube from the outside with a series of chambers and baffles on the inside. Although

they can be operated continuously, they are usually operated in a batch mode.

Incinerators in this class, designed to burn general hospital waste, operate at excess air

levels of up to 300 percent. If only pathological wastes are burned, excess air levels near

100 percent are more common. The quantity of excess air controls the secondary chamber

temperature; lower heating value fuels typically use lower amounts of excess air.

nja.117\sect.2-6 2-5

MixingChamber Flame Port

Charging Door

Hearth

PrimaryBurner Port

SecondaryUnderneath Port

CleanoutDoors

SecondaryCombustionChamber

Stack

SecondaryAir Ports

SecondaryBurner Port

Mixing Chamber

First Underneath Port

Flame Port

Charging Door

IgnitionChamber

Hearth

Figure 2.6-2. Excess Air Incinerator

9302

15D

RT

P

Side View

nja.117\sect.2-6 2-7

Figure 2-2 presents a schematic for an excess air unit. Like controlled air incinerators,

combustion of waste in excess air incinerators occurs in two stages. First, waste is fed into the

combustion (primary) chamber. The charging door is then closed, and an afterburner is ignited to

bring the secondary chamber to a target temperature [typically 870 to 980EC (1,600 to 1,800EF)].

When the target temperature is reached, the primary chamber burner ignites. The waste is dried,

ignited, and burned by heat provided from the primary chamber burner as well as by radiant heat

from the chamber walls. Moisture and volatile components in the waste are vaporized and pass

(along with combustion gases) out of the primary chamber and through a flame port which

connects the primary chamber to the secondary or mixing chamber. Secondary air is added

through the flame port and is mixed with the volatile components in the secondary chamber.

Burners are also installed in the secondary chamber to maintain adequate temperatures for

combustion of volatile gases. Optimization of excess air incinerators involves maintaining high

temperatures with afterburners and prolonging residence times. Gases exiting the secondary

chamber are directed to the incinerator stack or to an air pollution control device. When the

waste is consumed, the primary burner shuts off. Typically, the afterburner shuts off after a set

time. Once the chamber cools, ash is removed from the primary chamber floor, and a new charge

of waste can be added.


Waste Feed

Exhaust Gas to Stack orAir Pollution Control Device

Auxiliary Fuel

Ash Removal

2.2.3 Rotary Kiln Incinerators

nja.117\sect.2-6 2-9

Figure 2-3 illustrates a rotary kiln incinerator. Rotary kiln incinerators, like the incinerator types

already presented, are designed with a primary chamber, where waste is heated and volatilized

(volatile gases released), and a secondary chamber, where combustion is completed. The primary

chamber consists of a slightly inclined, rotating kiln in which waste material migrates from the

feed end to the ash discharge end. The waste throughput rate is controlled by adjusting the rate

of kiln rotation and the angle of inclination. Combustion air enters the primary chamber through

a port. An auxiliary burner is generally used to start combustion and maintain desired

combustion temperatures. Both the primary and secondary chambers are usually lined with acid-

resistant refractory brick.

Volatiles and combustion gases pass from the primary chamber to the secondary chamber

where combustion is completed. The secondary chamber operates with excess air. Due to the

turbulent motion of the waste in the primary chamber, solids burnout rates and particulate

entrainment in the flue gas are higher for rotary kiln incinerators than for other incinerator

designs; thus, rotary kiln incinerators generally have add-on gas cleaning devices.

2.3 MEDICAL WASTE INCINERATOR EMISSIONS

Medical waste incinerators can emit significant quantities of pollutants to the atmosphere.

These pollutants can include: 1) PM, 2) metals, 3) acid gases, 4) oxides of nitrogen (NOx),

5) carbon monoxide (CO), 6) organics, and 7) various other materials present in medical wastes

such as cytotoxins, radioactive diagnostic materials, infectious materials, and pathogens. This

section discusses the factors affecting emissions of these pollutants.

2.3.1 Particulate Matter

Particulate matter is emitted as a result of incomplete combustion of organics (i.e., soot)

and by the entrainment of noncombustibles in the flue gas stream. Particulate matter may exit as

a solid or an aerosol, and, in addition to fly ash, it may contain heavy metals, acids, and trace

organics. Depending on the method used to measure PM in the flue gas, condensable PM (i.e.,

materials with boiling points or condensation temperatures below 250EF and salts that form in

the back half impingers) may or may not be included in the measurement. Inorganic matter is not

destroyed during combustion; most of this material leaves the incinerator as bottom ash.

However, some does become entrained in the stack gas as PM.

In general, good combustion conditions, which depend on residence time, temperature,

and turbulence (good air/fuel mixing), minimize PM emissions. As the residence time increases,

nja.117\ (Reformatted 1/95) 7/93 2-10

particle size and total particulate mass tend to decrease.2 Smaller particle sizes and lower PM

emissions are also associated with higher temperatures. Oxidation rates increase at higher

temperatures, so more of the combustible matter is oxidized to gaseous products.

Entrainment of PM into the incinerator exhaust is often a reflection of the gas velocity

within the primary combustion chambers. Controlled air incinerators have the lowest turbulence

and, consequently, lowest PM emissions; rotary kilns employ high turbulence waste combustion

and, therefore, have the highest PM emissions. Although total particulate emission

concentrations from MWIs are generally lower than in municipal waste combustors, the particle

size range is also generally lower and in the inhalable range (<10 µm). Up to 80 percent of the

total particulate from MWIs is fine particles (<2 µm).2

2.3.2 Metals

Organo-metallic compounds and inorganic wastes present in the waste stream can be

volatilized and oxidized under high temperatures and oxidizing conditions in an incinerator. The

type and amount of trace (heavy) metals in the flue gas are directly related to the metals

contained in the incinerator waste. Some trace metal sources in the waste include surgical

blades, batteries, measuring devices, foil wrappers, and plastics. Plastic objects made of PVC

contain cadmium (Cd) heat-stabilizing compounds; additionally, Cd may be found in paints

and/or dyes.

The volatilized organo-metallic compounds condense uniformly on all available

particulate surface area. Since submicron particles contribute most of the available surface area,

these particles have a higher concentration of volatile metals per unit

nja.117\sect.2-6 2-11

of mass.10 Results of one study performed at a MSW facility indicate that trace metals are found

predominantly in the respirable particulate fraction, even when the bulk of the emissions are in

the nonrespirable fraction.11

Control of metal emissions to the atmosphere involves minimizing vaporization of metals

in the waste feed and maximizing small particle collection in the air pollution control device.

Fabric filters achieve low metal particulate emissions; this is believed to be because of their

efficient control of small particles. Generally, particulate control by the air pollution control

system is a surrogate for metal control, except for Hg; Hg is thought to leave the incinerator

largely in the vapor form.

2.3.3 Acid Gases

Combustion of medical wastes can produce acid gas emissions in the form of

hydrochloric acid (HCl) and sulfur dioxide (SO2), as well as lesser quantities of other

compounds. Acid gas control is achieved by neutralization of the acid and/or collection of the

acid constituents in dry sorbents or aqueous solutions.

Hydrochloric acid is formed in the flue gases by the conversion of chlorine found in the

waste [e.g., in plastics such as polyvinyl chloride (PVC)]. Swedish studies have found that 60 to

65 percent of the fuel-bound chlorine in MSW is converted to HCl. Uncontrolled HCl emissions

from MWIs are estimated to be on the order of 1000 ppm or less.3

Sulfur is present both in the materials making up medical waste and in auxiliary fuels.

Medical waste, like municipal waste, typically contains about 0.2 percent sulfur.3 The rate of

SO2 emissions is directly proportional to the sulfur content of the waste and auxiliary fuels.

Uncontrolled SO2 emissions from MWIs are estimated to be on the order of 100 ppm or less.3

2.3.4 Oxides of Nitrogen

Nitrogen oxides (NOx) represent a mixture mainly of nitric oxide (NO) and nitrogen

dioxide (NO2). In combustion systems, NO predominates due to kinetic limitations in the

oxidation of NO to NO2. Nitrogen oxides are formed by one of two general mechanisms.

"Thermal NOx" is the result of the high-temperature reaction between molecular nitrogen and

molecular oxygen, both of which enter the combustion zone in the combustion air. "Fuel NOx"

results from the oxidation of nitrogen that is chemically bound within the fuel structure.

Thermal NOx formation is extremely sensitive to temperature, whereas fuel NOx is not.

At the lower adiabatic temperatures which characterize MWIs, fuel NOx accounts for most NOx

nja.117\(Reformatted 1/95) 7/93 2-12

emissions, while thermal NOx generally contributes less than 10 ppm. Incinerator data indicate

that NOx levels are on the order of 200 ppm.3

2.3.5 Carbon Monoxide

Carbon monoxide (CO) is also a PIC. Carbon monoxide emissions are related to shorter

residence times, lower temperatures, and poorer mixing conditions than are optimal. When

combustion has not proceeded to completion, CO is formed in lieu of carbon dioxide (CO2).

2.3.6 Organics

Failure to achieve complete combustion can result in emissions of unreacted or partially

reacted combustion products. Products of incomplete combustion (PICs) can include compounds

ranging from low molecular weight hydrocarbons to high molecular weight chlorinated

compounds such as dibenzo-p-dioxins and dibenzofurans (CDD/CDF).

Many factors are believed to be involved in the formation of CDD and CDF compounds,

and various theories exist concerning the formation of these compounds.4-6 One theory for

CDD and CDF formation in incinerators postulates that precursors of CDD and CDF can be

produced by pyrolysis of chlorinated plastics in the waste in oxygen-starved zones, such as those

which exist in controlled air incinerators.7 Another theory proposes that CDD/CDF are

synthesized from a variety of organics and a chlorine donor.8 A third possible mechanism

involves catalytic reactions

nja.117\sect.2-6 2-13

on fly ash particles at temperatures in the range of 230 to 345EC (450-650EF).2,6 Of specific

relevance to wet scrubbing systems is the potential for formation of CDD/CDF from precursor

materials, such as chlorobenzene and chlorophenols that are present in the recirculated scrubber

solution.9 Another mechanism proposed involves the breakthrough of unburned CDDs and

CDFs present in the feed.4,10

The goal in CDD/CDF control is to minimize their formation using good combustion

practice (GCP) in the incinerator. The elements of GCP include:5

1. Uniform waste feed;

2. Adequate supply and good distribution of air in the incinerator;

3. Sufficiently high incinerator gas temperatures [>985EC (1,800EF)];

4. Gas (secondary chamber) residence time;

5. Good mixing of combustion gas and air in all zones;

6. Minimization of PM entrainment into flue gas leaving the incinerator; and

7. Control of the gas temperature entering the air pollution control device to 230EC

(450EF) or less.

Low molecular weight organic compounds (LMWC) are PICs of the volatiles evolved

from the waste. The same control mechanisms discussed above for CDDs and CDFs are also

applicable to LMWC. When residence time, temperature, and turbulence in the combustion zone

are high, LMWC emissions will be low.

2.3.7 Other Pollutants Specific to Medical Waste

Cytotoxic chemicals used in chemotherapy are toxic to cell growth and are capable of

impairing, injuring, or killing cells. Temperatures greater than 1,095EC (2,000EF) are thought to

be necessary for >99 percent destruction of cytotoxic chemicals.10 Examples of cytotoxins are

nitrosourea, cyclophoshamid, and anthracycline antibiotics.

Radioactive species used in vitro diagnostic studies may also be present in medical

wastes. The levels of radioactivity

nja.117\(Reformatted 1/95) 7/93 2-14

are thought to be low (<100 Ci/g), but are difficult to estimate.11 Incineration is considered by

the Nuclear Regulatory Commission (NRC) to be an excellent means of low level radioactive

waste disposal.11 Measures must be taken to control temperature if high overall treatment

efficiency of radioactive waste is to be maintained.

Infectious material is contributed to medical waste from animal and human blood, other

body fluids and parts, and instruments or bedding material that have come into contact with

infectious materials.

Pathogens are generally thermally sensitive and easy to destroy when exposed to typical

gas temperatures in a primary incinerator chamber for residence times of one to two seconds.11

In general, conditions that maximize the destruction of organics (i.e., time, temperature, and

turbulence) will promote proper destruction of pathogens and bacteria.11 If mainly pathological

waste is charged, burners need to operate at all times in the primary chamber to maintain

adequate temperature levels.

2.4 CONTROL TECHNOLOGIES

The most frequently used air pollution control device (APCD) for MWI emissions is a

packed bed, venturi, or other type of wet scrubber. The second most common APCD is a fabric

filter (FF), typically used with a dry injection system. A less common type of APCD used is an

electrostatic precipitator (ESP).

2.4.1 Wet Scrubbers

Wet scrubbers use gas-liquid absorption to transfer of pollutants from the flue gas to a

liquid stream. Scrubber design and the type of liquid solution used largely determine

contaminant removal efficiencies. With plain water, removal efficiencies for acid gases can be as

high as 70 percent for HCl and 30 percent for SO2. Addition of calcium hydroxide [Ca(OH)2] to

the scrubber liquor for acid neutralization has been shown to result in removal efficiencies of 93-

96 percent.2 In general, high gas-side pressure drops also provide for high removal efficiencies

for PM control with venturi scrubbers.

There are three basic types of scrubbers:

1. Low energy, primarily for acid gas control;

2. Medium energy for PM and/or acid gas control; and

3. High energy, primarily for PM control.

nja.117\sect.2-6 2-15

Low energy scrubbers (spray towers) are usually circular in cross-section. The liquid is

sprayed down the tower as the gases rise. Acid gases are absorbed/neutralized by the scrubbing

liquid. Large particles are removed by liquid impingement. Low energy scrubbers mainly

remove particles larger than 5-10 microns.2

Medium energy scrubbers achieve additional removal of PM by increasing gas-liquid

contact. This can be accomplished through a variety of configurations, such as packed columns,

baffle plates, and liquid impingement scrubbers.

High energy scrubbers utilize venturis for still greater PM removal. A typical venturi

scrubber consists of a converging section, a throat, and a diverging section. The flue gases

impinge on the liquid stream in the converging section. As the gases pass through the throat, the

shearing action atomizes the liquid into fine droplets. When the gases pass through the diverging

section, they decelerate, resulting in further contact between particles and liquid droplets. The

droplets are then removed from the device by centrifugal action in the de-entrainment section.2

When simultaneous acid gas and PM removal are necessary, a combination of scrubber

types can be used. Venturi scrubbers followed by low or medium energy acid gas scrubbers are

commonly applied. The venturi accomplishes primarily PM control, while the low/medium

energy scrubber uses an alkaline liquor and functions mainly to absorb acid gases.

2.4.2 Fabric Filters

A fabric filtration system, also called a baghouse, consists of a number of filtering

elements (bags) along with a bag cleaning system contained in a main shell structure. A

baghouse is typically divided into several compartments or sections. Particulate-laden gases pass

through the bags so that the particles are retained on the upstream side of the fabric, thus cleaning

the gas. The collection efficiency and the pressure drop across the bag surface increase as the

dust layer on the bag builds up. Since the system cannot continue to operate with an increasing

pressure drop, the bags are cleaned periodically. Cleaning processes include reverse flow with

bag collapse, mechanical shaking, or pulse-jet cleaning. When the first two cleaning methods are

used, the PM is collected on the inside of the bag; it is collected on the outside of the bag in

pulse-jet systems. Generally, reverse flow FFs operate with lower gas flow per unit area of bag

surface than pulse-jet systems. This means they are larger and, thus, more costly for a given gas

flow rate or application.

nja.117\ (Reformatted 1/95) 7/93 2-16

Fabric filters can achieve very high (>99.9 percent) PM removal efficiencies. These

systems are also very effective in controlling fine (<2 micrometers) PM, which implies good

control of condensed metals and organics, two major constituents of fine PM.9 A disadvantage

of using FFs with MWIs is the limitation of operating temperature: The upper limit of most filter

media is about 260EC (500EF). Flue gases leave the incinerator at about 815 to 1,095EC (1,500-

2,000EF), so the gases must be cooled considerably before contact with the filter bags. However,

the dew point of the flue gas must also be considered. Temperature excursions below the acid

dew point [about 110EC (230EF)] cause condensation of acid gases and can ruin the bags and

require premature replacement.

2.4.3 Dry Sorbent Injection

In the dry sorbent injection (DSI) process for controlling acid gases, a dry alkaline

material is injected into the flue gas using a dry venturi within the ducting or into the duct ahead

of a particulate control device. The alkaline material reacts with and neutralizes the acid gases in

the flue gas. Fabric filters are applied downstream of DSI to control the PM generated by the

incinerator, capture the DSI reaction products and unreacted sorbent, and increase sorbent/acid

gas contact time, thus enhancing acid gas removal efficiency and sorbent utilization.

The major factors affecting DSI performance are flue gas temperature, acid gas dew

point, and sorbent-to-acid gas ratio. Dry sorbent injection performance improves as the

difference between flue gas and acid dew point temperatures decreases and the sorbent-to-acid

gas ratio increases. Flue gas temperatures at the point of sorbent injection range from 140 to

320EC (280 to 610EF), depending on the sorbent used and the design of the process. To reduce

flue gas temperatures, some DSI systems inject water into the hot flue gas.

Acid gas removal efficiencies with DSI also depend on sorbent type, sorbent feed rate,

and the extent of sorbent mixing with the flue gas. Sorbents that have been successfully tested

include hydrated lime [calcium hydroxide, Ca(OH)2], sodium hydroxide (NaOH), sodium

bicarbonate (NaHCO3), and magnesium oxide. Based on published data for hydrated lime, DSI

can achieve relatively high removals of HCl (80 to 95 percent) and SO2 (40 to 70 percent) under

proper operating conditions. Limestone (CaCO3) and lime (CaO) have also been tested but are

relatively unreactive at the normal operating temperatures.2

Because calcium chloride (CaCl2, one of the DSI reaction products) has a high affinity

for water (deliquescent), the flue gas exit temperature for MWIs is higher than in fossil-fuel

nja.117\sect.2-6 2-17

furnaces/boilers. As a result, higher sorbent-to-acid gas ratios are needed to achieve high acid

gas control efficiencies. Water use should be minimized since excess water may cause cement-

like deposits on the fabric filters, thus impairing flow.

The primary advantage of DSI compared to wet scrubbers is the relative simplicity of the

sorbent preparation, handling, and injection systems as well as the easier handling and disposal

of dry solid process wastes. The primary disadvantages are its lower sorbent utilization rate and

correspondingly higher sorbent and waste disposal rates.

2.4.4 Electrostatic Precipitators

Particulate collection in an ESP occurs in three steps: (1) suspended particles are given

an electrical charge; (2) the charged particles migrate to a collecting electrode of opposite

polarity; and (3) the collected PM is dislodged from the collecting electrodes and collected in

hopper for disposal.

Charging of the particles is usually caused by ions produced in high-voltage corona. The

electric fields and the corona necessary for particle charging are provided by converting

conventional alternative current to direct current using high-voltage transformers and rectifiers.

Removal of the collected particulate matter is accomplished mechanically by rapping or vibrating

the collecting electrode plates.

nja.117\(Reformatted 1/95) 7/93 2-18

REFERENCES FOR SECTION 2.0

1. Durkee, K.R. and J.A. Eddinger. Status of EPA Regulatory Program for Medical WasteIncinerators--Test Program and Characterization of Emissions. Presented at the 1991Incineration Conference. May 13-17, 1991, Knoxville, Tennessee.

2. Hospital Waste Combustion Study: Data Gathering Phase. Prepared for the U.S.Environmental Protection Agency, Research Triangle Park, North Carolina, EPA-450/3-88-017, December 1988.

3. Parish, M.G., and C. Brooks. Incinerator Heat Recovery and Its Effect of Air PollutionControl Selection. Presented at the 3rd National Symposium on Infectious WasteManagement, Chicago, Illinois, April 18, 1989.

4. Stieglitz, L., and H. Vogg. Formation and Decomposition of Polychlorinated Dibenzo-dioxins and -Furans in Municipal Waste. Report KFK4379, Institut fur heisse Chemie. Kernforschungszentrum Karlsruhe, February 1988.

5. Brna, T.G., and J.D. Kilgroe. Control of PCDD/PCDF Emissions from Municipal WasteCombustion Systems. Presented at the Ninth International Symposium on ChlorinatedDioxins and Related Compounds, Toronto, Canada, September 17-22, 1989.

6. Teller, A.J., J.Y. Hsieh, P. Koch, and A. Astrand. Emission Control: Hospital WasteIncineration. Cottrell Environmental Sciences, Inc., Somerville, New Jersey, October1988.

7. Axelrod, D., MD. Lessons from the Transformer Fire at the Binghampton (New York)State Office Building. Chemosphere, 14(6/7): 775-778.

8. Doyle, B., Drum, D., and J. Lauber. The Smoldering Question of Hospital Waste. Pollution Engineering, 17:7, July 1985, p.35.

9. Marklund, S., K. Ljung, P. Andersson, and C. Rappe, Formation of ChlorinatedDibenzodioxins and Dibenzofurans in an Air Pollution Control Device for MSWCombustor. Presented at the 1993 International Symposium on Municipal WasteCombustion. U. S. Environmental Protection Agency, Research Triangle Park, NorthCarolina, 1993.

10. Germanus, D. Hypothesis Explaining the Origin of Chlorinated Dioxins and Furans inCombustion Effluents. Presented at the Symposium on Resource Recovery, HofstraUniversity, Long Island, New York, 1985.

11. Barton, R.G. et al. Energy and Environmental Research Corporation. State-of-the-ArtAssessment of Medical Waste Thermal Treatment. Prepared for the U.S. Environmental

nja.117\sect.2-6 2-19

Protection Agency and the California Air Resources Board, Irvine, California,October 15, 1989.

12. Jacko, R., and D. Neuendorf. Trace Metal Particulate Emission Test Results from aNumber of Industrial and Municipal Point Sources. APCA Journal, Volume 27, No.10,October 1977, p.989.

nja.117\sect.2-6 3-1

3.0 GENERAL DATA REVIEW AND ANALYSIS PROCEDURES

3.1 LITERATURE SEARCH AND SCREENING

The first step in this investigation was the preparation phase; namely, collecting

information relating to emissions from MWI facilities. The information collected represents

source test reports from different facilities and background documents relevant to AP-42, and,

more specifically, to Section 2.6 on medical waste incineration.

The criteria set forth in this section were taken from the bulletin, "Technical Procedures

for Developing AP-42 Emission Factors and Preparing AP-42 Sections." In order to avoid

analyzing excessive amounts of data, and also to ensure that proper data were used in updating

the section, some general criteria were used:

1. Emissions data had to be from a primary source. This means that reportsummaries could not be used, and if a source of information could not beidentified, it was eliminated.

2. More than one test run had to be performed at each facility.

3. The report had to contain sufficient data to evaluate the testing procedures andsource operating conditions: each report had to have charge rate data, runsequences referenced, and sampling methodologies stated to be considered valid.

3.2 EPA PROTOCOL FOR DATA QUALITY

Emission factors in AP-42 are based on data obtained from several sources, such as

published technical papers and reports and documented emission test results. Data provided by

individual sources vary from single values, to ranges of minimum and maximum values, and

finally to data from replicated source tests. Some data sources provide complete details about

their collecting and analyzing procedures, while others provide only sketchy information in this

regard.

In developing the section on medical waste incineration for AP-42, the following

procedures were used to select data for both its quality and quantity. The following data were

always excluded from consideration:

1. Test series averages reported in units that could not be converted to the selectedreporting units.


2. Test series representing incompatible test methods (i.e., comparison of EPAMethod 5 front-half with EPA method 5 front- and back-half).

3. Test series of controlled emissions for which the control device was not fullyspecified.

4. Test series in which the source process was not clearly identified and described.

5. Test series in which it is not clear whether the emissions measured werecontrolled or uncontrolled.

If there was no reason to exclude particular data or data sets from consideration, each data

set was assigned a quality rating from A (best) to D (worst). A rating system was needed to

indicate data reliability since some data were used when little other information was available but

were excluded when sufficient high-quality data existed. The data were rated as follows:

A - When tests are performed by a sound methodology and are reported in enoughdetail for adequate validation. These tests are not necessarily EPA referencemethod tests, although such reference methods are preferred and certainly shouldbe used as a guide.

B - When tests are performed by a generally sound methodology, but they lackenough detail for adequate validation.

C - When tests are based on an untested or new methodology or are lacking asignificant amount of background data.

D - When tests are based on a generally unacceptable method, but the method mayprovide an order-of-magnitude value for the source.

Following are the criteria used to evaluate source test reports for sound methodology and

adequate detail:

1. Source operation. The manner in which the source was operated is welldocumented in the report. The source was operating within typical parametersduring the test.

2. Sampling procedures. If actual procedures deviated from standard methods, thedeviations are well documented. Procedural alterations are often made in testingan uncommon type of source. When this occurs, an evaluation is made of howsuch alternative procedures could influence the test results.

3. Sampling and process data. Many variations can occur without warning duringtesting, sometimes without being noticed. Such variations can induce wide

nja.117\sect.2-6 3-3

deviation in sampling results. If a large spread between test results cannot beexplained by information contained in the test report, the data are suspect and aregiven a lower rating.

4. Analysis and calculations. The test reports contain original raw data sheets. Thenomenclature and equations used are compared with those specified by EPA toestablish equivalency. The depth of review of the calculations is dictated by thereviewers' confidence in the ability and conscientiousness of the tester, which inturn is based on factors such as consistency of results and completeness of otherareas of the test report.

As an example, an A-rated test may be a stack test, a material balance, or some other

methodology, as long as it is generally accepted as a sound method of measuring emissions from

that source. In some cases, a material balance calculation may be rated A, but a stack test may be

rated only B or C.

Because only one combined value was used to calculate the AP-42 emission factor for

each facility, only the results of tests of equal quality ratings were retained when multiple-series

tests were run at the same facility.

Although the rating system described above is subjective, it provided a basis for

excluding poor data when sufficient good data were available. In preparing the Medical Waste

Incinerator Section of AP-42, the quality standards were applied to the data used to calculate the

emission factors. All data ratings are documented, and the reasons for assigning the A through D

ratings will be clearly stated in the background information to follow.

The reliability of each emission factor presented in the AP-42 is indicated by an overall

Emission Factor Rating from A (excellent) to E (poor). These ratings take into account the

quality and quantity of data from which the factors were calculated. The following emission

factor ratings are applied to the emission factor table.

A - Excellent. Developed only from A-rated source test data taken from manyrandomly chosen facilities in the industry population. The source category isspecific enough to minimize variability within the source population.

B - Above average. Developed only from A-rated test data from a reasonable numberof facilities. Although no specific bias is evident, it is not clear if the facilitiestested represent a random sample of the industries. As with the A rating, thesource is specific enough to minimize variability within the source population.

nja.117\ (Reformatted 1/95) 7/93 3-4

C - Average. Developed only from A- and B-rated test data from a reasonablenumber of facilities. Although no specific bias is evident, it is not clear if thefacilities tested represent a random sample of the industry. As with the A rating,the source category is specific enough to minimize variability within the sourcepopulation.

D - Below average. The emission factor was developed only from A- and B-rated testdata from a small number of facilities, and there may be reason to suspect thatthese facilities do not represent a random sample of the industry. There also maybe evidence of variability within the source population.

E - Poor. The emission factor was developed from C- and or D- rated test data, andthere may be reason to suspect that the facilities tested do not represent a randomsample of the industry. There also may be evidence of variability within thesource category population. Any limitations on the use of these factors are alwaysclearly noted.

Ideally, a large number of A-rated source test sets representing a cross-section of the

medical waste industry would be reduced to a single emission factor value for each individual

source by computing arithmetic means for each test set and then calculating an overall arithmetic

mean for all the sources. However, because the information presented in this document

represents less than 1 percent of the total MWI population, the emission factors presented in

Section 5.0 should be used cautiously.

nja.117\sect.2-6 4-1

4.0 POLLUTANT EMISSION FACTOR DEVELOPMENT

This chapter describes the test data and methodology used to develop pollutant emission

factors for the medical waste incineration industry.

4.1 REVIEW OF SPECIFIC SOURCES OF DATA

Although there are an estimated 7,000 medical waste incinerators in the United States,

not many informational reports are in existence; in developing a revised AP-42 Section 2.6 on

medical waste incineration, only 37 source reports were used. Of these reports, only 2 contained

test data for rotary kiln incinerators, and there were no data on excess air incinerators. Other

reports exist containing source test data, but because of various deficiencies (limited process

descriptions, noncompatible analytical methods, atypical wastes charged, etc.), they were not

used.

The following is a discussion of the data contained in each of the primary references used

to develop candidate emission factors. Emission factor calculations were made in terms of

weight of pollutant per weight of waste incinerated. It should be noted that the terms

"controlled" and "uncontrolled" in this discussion are indicative only of the location in the system

where measurements were taken.

4.1.1 St. Bernardines1

This reference contains test data from a small [less than 135 kg (300 lb) per day

throughput] facility at St. Bernardines Hospital in San Bernardino, California. The tests were

conducted by the Engineering Evaluation Branch of the California Air Resources Board (CARB).

The objectives of this testing were to characterize criteria and select non-criteria air pollutants

released to the atmosphere. The incinerator was manufactured by MCI energy, has a rated

capacity of 45 kg/hr (100 lb/hr), and is manually charged. The criteria air pollutants were THC,

CO, SO2, NOx, and PM. Other, non-criteria pollutants which were tested for were eight metals

[arsenic (As), Cd, chromium (Cr), Fe, manganese (Mn), nickel (Ni), and Pb], HCl, CDDs, and

CDFs. Since this facility has no control devices, only uncontrolled data are presented.

The pollutants monitored by continuous emission monitoring (CEM) were rated "A."

These include THC, CO, SO2, and NOx. The CARB Method (1200) used for testing requires the

same CEM devices as the EPA uses for these parameters: NOx are analyzed by a

chemiluminescence, SO2 by ultra-violet (UV) photometry, CO by a non-dispersion infrared


detector (NDIR), and THC by flame ionization detector (FID). Also, the particulate data were

rated "A" because CARB Method 5 was used (equivalent to EPA Method 5).

The data for metals, HCl, and CDDs and CDFs were treated "B" because, although the

modified Method 5 (MM5) trains were similar to those used in EPA methods for these

pollutants, the number of impingers present and their contents differed; therefore, it is difficult to

determine whether the CARB and the EPA tests can be considered equivalent.

4.1.2 Cape Fear2

This facility at Cape Fear Memorial Hospital in Wilmington, North Carolina, has an

Environmental Controll Products (now Joy Energy Systems) ram-fed, controlled air incinerator

rated at 175 kg/hr (385 lb/hr); it has no add-on pollution control equipment. The objective of

testing here, conducted by EPA, was to collect incineration data to meet EPA's commitment to

the Medical Waste Tracking Act of 1988 (MWTA) which states that the EPA must prepare a

series of reports to Congress that provide information on the advantages and disadvantages of

medical waste incineration, including its ability to render a medical waste non-infectious and

unrecognizable.

Data collected at Cape Fear included the criteria pollutants mentioned above, 11 metals

[antimony (Sb), As, barium (Ba), beryllium (Be), Cd, Cr, Pb, Hg, Ni, silver (Ag), and thallium

(Tl)], acid gases [HCl, hydrogen bromide (HBr), and hydrogen fluoride (HF)], CDDs and CDFs,

and polychlorinated biphenyls (PCBs).

The PCB data in this report were not used since only one sample was analyzed and

Analytical Quantification Procedures (AQP) were not performed. The rest of the data were rated

"A" based on all tests being performed using approved EPA methodologies or draft

methodologies.

4.1.3 Jordan Hospital3

Jordan Hospital in Plymouth, Massachusetts, has a batch-fed controlled air MWI,

manufactured by Simonds, which can handle 340 kg (750 lb) per batch of waste and has a heat

exchanger. This facility also has add-on control devices, namely, a FF followed by a packed bed

absorber. Thus, both controlled and uncontrolled emissions data are presented in this report.

The U.S. EPA conducted testing here to aide in developing New Source Performance Standards

(NSPS) for MWIs under the Clean Air Act as amended in November 1990.

nja.117\sect.2-6 4-3

At the Jordan facility, uncontrolled emissions data were collected for all of the same

pollutants as were noted for the facility at Cape Fear except for PCBs. Emissions data after the

control device were collected for the HCl, HBr, HF, and SO2, 11 metals, CDDs and CDFs, and

PM.

These data were rated "A." All tests performed used approved EPA methodologies or

draft EPA methodologies. The CDD/CDF data were not used, however, because of the

uncertainty regarding the impact of the heat exchanger on dioxin formation.

4.1.4 Kaiser Permanente4

The Kaiser Permanente Hospital in San Diego, California, has a Therm-tec incinerator

rated at 365 kg/hr (800 lb/hr). It also is equipped for waste heat recovery, and it has a caustic

scrubber (which uses magnesium hydroxide) for acid gas control. Testing was conducted by

CARB for criteria and non-criteria pollutants. The pollutants included CO, SO2, NOx, PM, HCl,

the same eight metals tested for at St. Bernardines, CDDs and CDFs, and PCBs. Testing for

controlled and uncontrolled emissions was similar except for the number of test runs.

The methods and procedures followed for the testing at Kaiser Permanente were identical

to those followed at St. Bernardine's; thus, the data were rated in the same way.

The particle size distribution (PSD) data collected at Kaiser were rated "C" because a

scanning electron microscope (SEM) was used to count and measure the particles on the Method

5 filter, whereas the EPA methodology utilizes a cascade impactor to separate particulates by size

to be counted.

4.1.5 Lenoir Memorial5

The facility at Lenoir Memorial Hospital in Kinston, North Carolina, has a medical waste

incinerator rated at 145 kg/hr (320 lb/hr). The incinerator is a ram-fed (Joy Energy Systems)

model with no air pollution control devices. As with the tests conducted at Cape Fear, the EPA

conducted testing to meet reporting requirements of the MWTA to Congress. Emissions data

collected at this facility included data for the 4 acid gases, 11 metals, CDDs and CDFs, NOx,

CO, PM, PCBs, chlorinated biphenyls (CBs), and total chlorinated phenols (CPs).

The PCB data were qualitative only and were not used. The CP and CB data were given

"D" ratings and not used because only one run of each were valid and AQP were not performed.

The rest of the data were rated "A."

4.1.6 AMI6

nja.117\ (Reformatted 1/95) 7/93 4-4

The AMI Central Carolina Hospital in Sanford, North Carolina, has an incinerator with a

design charging rate for Type IV (pathological) waste of 80 kg/hr (175 lb/hr). There are no air

pollution control devices. Testing was done by the EPA to meet the requirements of the MWTA

of 1988. Testing was done at Sanford for the same pollutants as at Lenoir, except that data on

PCBs, CBs, and CPs were not collected. These data were all rated "A."

4.1.7 Cedars Sinai7

The controlled air MWI (Ecolaire Combustion Products, Inc.) at Cedars Sinai Medical

Center in Los Angeles, California, was operated at an average charge rate of 445 kg/hr

(980 lb/hr) during tests conducted by CARB. This incinerator is equipped with a fabric filter for

particulate control, so emissions data before and after the control device were collected.

Emissions data collected for uncontrolled emissions included the following pollutants: CDDs

and CDFs, HCl, As, Cd, Cr, Fe, Mn, Pb, and Ni. Data collected for controlled emissions

included all the pollutants for which uncontrolled emissions data were collected as well as PM,

SO2, NOx, and CO.

The data collected at Cedars Sinai were rated in the same way as the previously

mentioned CARB reports, and the same test methods were used as in the other CARB reports.

4.1.8 St. Agnes8

Testing was conducted by CARB at the Saint Agnes Medical Center in Fresno, California

for an incinerator operating at an average charge rate of 355 kg/hr (780 lb/hr) without pollution

control devices. The MWI at St. Agnes is a controlled air unit (Environmental Control Products)

with waste heat recovery. During the testing, emissions data were collected for HCl,

eight metals, CDDs and CDFs, and the "criteria pollutants" as specified by CARB (PM, SO2,

NOx, and CO). The data for this report was rated the same as for the other CARB reports. No

PSD data were collected.

4.1.9 Sutter General9

Due to design modifications made to the previously tested incinerator at Sutter General

Hospital in Sacramento, California, CARB performed a second evaluation test program to

evaluate the effect of the design changes on emissions from the facility. The first report was not

available for comparison. The incinerator at Sutter is a controlled air (Therm-tec) with waste

heat recovery. During testing, it operated at an average loading rate of 215 kg/hr (475 lb/hr).

Testing done at Sutter was for controlled emissions only and included collecting data on the

nja.117\sect.2-6 4-5

following pollutants: HCl, seven metals, CDDs and CDFs, PM, SO2, NOx, and CO. The data

were rated in the same way as the other CARB reports mentioned above.

4.1.10 Swedish American Hospital10

Testing at the Swedish American Hospital of Rockford, Illinois was done by Beling

Consultants for Burden-Cooper, Inc. Uncontrolled emissions were monitored for an incinerator

rated at 80 kg/hr (175 lb/hr), and the only data which was usable for AP-42 purposes were two

HCl tests, three PM tests, and two CO tests.

The data for particulate matter were rated "A" because EPA Method 5 was followed for

sampling. The data on CO and HCl were rated "D" for lack of exact documentation of test

procedures.

4.1.11 University of Southern California11

Testing at the Los Angeles County--University of Southern California Medical Facility in

Los Angeles--was conducted by CARB. The facility has three identical MWIs with no pollution

controls. They are controlled air, manually loaded, and each burn no more than 270 kg (600 lb)

per day of medical waste; testing was conducted on one of the three incinerators. Pollutants for

which emissions data were collected included HCl, eight metals, CDDs and CDFs, PM, SO2,

NOx, and CO.

The particulate data were rated "A" (MM5 train used). Carbon monoxide data were

reported but not used because most readings were off scale.

4.1.12 Royal Jubilee12

The Royal Jubilee Hospital in Victoria, British Columbia has a MWI (Consumat) with no

controls which was charged at between 680 and 910 kg/hr (1,500 and 2,000 lb/hr) during testing.

Data were collected for the following pollutants: HCl, 12 metals, particulate matter, and PCBs.

These data were rated "B." The sampling methodologies used were Canadian, and it was

not clear whether they were equivalent to EPA methods. Polychlorinated biphenyl data were

reported, but they were not used because of the methodology (rated "D").

4.1.13 Borgess Medical Center13

Borgess Medical Center in Kalamazoo, Michigan has a controlled air MWI,

manufactured for intermittent duty (manual ash removal), and roughly rated at 295 kg/hr

(650 lb/hr). It is equipped with waste heat recovery, dry lime injection for acid gas control and a

fabric filter baghouse for PM control. Activated carbon injection was used (for Hg control) on a


trial basis. Both controlled and uncontrolled emissions data are presented in this report. The

U.S. EPA sponsored testing here to aid in developing NSPS for MWIs under the Clean Air Act

as amended in November 1990.

At the Borgess facility, controlled and uncontrolled emissions data were collected for the

criteria pollutants, 13 metals (Al, Sb, As, Ba, Be, Cd, Cr, Cu, Pb, Hg, Ni, Ag, Tl), acid gases

(HCl, HBr, and HF), CDDs, and CDFs.

These data were rated "A." All tests performed used approved EPA methodologies or

draft EPA methodologies.

4.1.14 Morristown Memorial Hospital14

Morristown Memorial Hospital in Morristown, New Jersey has a rotary kiln MWI. This

facility has a spray dryer/fabric filter air pollution control device. Tests were conducted

November 18-23, 1991 for CO, PM, SO2, NOx, HCl, metals, total hydrocarbons, and

polychlorinated dibenzo-p-dioxins, and polychlorinated dibenzofurans. Controlled emissions

exiting the spray dryer/fabric filter were tested for PM, acid gases, metals, and CDD/CDF. In

addition, mercury and dioxin removal efficiencies following carbon injection were investigated.

The data were rated "A." All tests performed used EPA methodologies or draft EPA

methodologies.

4.1.15 Burlington County Memorial Hospital15

The Burlington County Memorial Hospital is located in Mount Holly, New Jersey. Tests

were conducted by the New Jersey Department of Environmental Protection, Air Quality

Engineering and Technology Element, Bureau of Technical Services in August of 1989. The

incinerator tested was an American Energy Corporation Pathological AEC Model 700 incinerator

with a York-Shipley HRH-750 heat recovery boiler. Natural gas is utilized as an auxiliary fuel

for the primary and secondary combustion chambers. This incinerator is permitted to charge up

to 318 kg (700 lbs) of waste per hour. Pollutants tested for are PM, HCl, CO, total hydrocarbons,

and NOx. The data for NOx and CO are rated "A;" the data for PM, HCl, and total hydrocarbons

were rated "B" because New Jersey test methods were used.

4.1.16 Mayo Foundation Institute Hill Research Facility -

November 4 and 1116

The Morse Boulger Incinerator at the Mayo Foundation Institute Hill Research Facility in

Rochester, Minnesota was tested November 4th and 11th, 1988 by PACE Laboratories, Inc.

nja.117\sect.2-6 4-7

Particulate matter and HCl emissions were tested. The input capacity of the incinerator is

725 kg/hr (1,600 lb/hr). Emissions are controlled by incinerator operational parameters with no

secondary control. With the exception of two runs in Test 3, which were not included because

only "red bag" waste weights were recorded, all data were rated "B" because EPA test methods

were used, but there is a lack of process description information.

4.1.17 ERA Tech, North Jackson, Ohio17

This ram feed incinerator is operated by Multitech Group, Inc. in Mahoning County, Ohio

and is fired at a rate of about 680 kg/hr (1,500 lbs/hr). It is equipped with a secondary chamber,

quench tower, absorption unit for acid removal, and baghouse for particulate removal. Tests for

controlled PM and HCl were conducted by OSA Company in December of 1988. The PM data

were rated "B" because EPA Method 5 was used, but little process description is provided; HCl

data were rated "C" because it is not clear what test method was used.

4.1.18 Milton S. Hershey Medical Center18

The Milton S. Hershey Medical Center in Derry Township, Pennsylvania operates an

Ecolaire Model 1500TE Thermal Incinerator with a maximum charging rate of approximately

590 kg/hr (1,300 lbs/hr). Emissions are controlled with a wet scrubber. Tests were conducted by

AirNova in October and November of 1989. Uncontrolled and controlled emissions of PM, CO,

and CDD/CDF were tested, as well as controlled emissions of SO2 and HCl. Metals were also

tested, but the data were not used because handwritten data conflicted with the data presented in

Table 3-7 of the test report. The PM and CO data were rated "A" because EPA methods, or

modified EPA methods, were used. The SO2 and HCl data were rated "B" because PADER test

methods were used, and insufficient information about the DER method is provided for it to be

adequately validated. Dioxins/furans test data were rated "C" because the report does not provide

a charge rate during the CDD/CDF test runs. An average charge rate as measured during the PM

and SO2 test runs was assumed to apply.

4.1.19 Erlanger Medical Center - South Unit19

Emission tests were conducted on the South incinerator unit at the Erlanger Medical

Center, Chattanooga, Tennessee, in April of 1988. Testing was conducted by Almega

Corporation. The South Unit is a Basic Model 1250 incinerator with a dry lime injector

baghouse, with a capacity of 565 kg/hr (1,250 lbs/hr), and equipped with a waste heat recovery

boiler. Pollutants tested were controlled levels of PM, HCl, Cl, CO, and NO2. The data were

nja.117\ (Reformatted 1/95) 7/93 4-8

rated "C" because the charge rates were measured on an hourly basis which did not correspond

with the actual time of testing, and the waste stream was not well characterized.

4.1.20 Nazareth Hospital20

The Nazareth Hospital is located in Philadelphia, Pennsylvania, and operates a Cleaver

Brooks Model 1280-A/72 incinerator with a waste heat recovery boiler and a maximum charging

rate of 375 kg/hr (825 lbs/hr). The main combustion chamber and integral afterburner are fired

by natural gas. Flue gas exiting the waste heat boiler is treated by a wet scrubber. Emissions

testing was performed by AirNova, Inc. in July of 1989. Controlled emissions of PM, CO, SO2

HCl, and metals were measured and uncontrolled HCl and SO2. The data were all rated "D"

because charge rates were not provided for individual test runs, only two test runs were

conducted, and for SO2 and HCl, inlet flows exceeded outlet flows.

4.1.21 Hamilton Hospital21

Hamilton Hospital in Hamilton, New Jersey operates a Comtro controlled air incinerator,

Model A-24, which is fired with No. 2 fuel oil. Tests were conducted by the New Jersey

Department of Environmental Protection, Air Quality Engineering and Technology Element,

Bureau of Technical Services in August of 1989. Uncontrolled emissions were tested for PM,

HCl, CO, NOx, and total hydrocarbons. Only runs in which mixed waste streams were fired

(rubbish and pathological) were used. All data were rated "B" because New Jersey test methods

were used and adequate detail was not provided to determine if the results are comparable to

EPA test methods.

4.1.22 Raritan Bay Health Services Corporation22

The Raritan Bay Health Services Corporation is located in Perth Amboy, New Jersey and

operates a Power Pac Environmental Control Products ECP-Model 1100 incinerator equipped

with a waste heat recovery system. The unit is fired with No. 2 fuel oil, and is permitted to

operate at a maximum charge rate of 500 kg/hr (1,100 lbs/hr). Tests were conducted in August

of 1989 by the New Jersey Department of Environmental Protection, Air Quality Engineering

and Technology Element, Bureau of Technical Services. Uncontrolled emissions of PM, HCl,

CO, NOx and total hydrocarbons were measured. All test data were rated "B" because

New Jersey test methods were used.

4.1.23 Bio-Waste Management Corporation23

nja.117\sect.2-6 4-9

This source emission evaluation was conducted at Bio-Waste Management Corporation's

facility in Klamath Falls, Oregon to quantify controlled and uncontrolled emissions of PM and

HCl. The Consumat biomedical waste incinerator is equipped with a Emcotek Corporation

Rotary Atomizing scrubber. Tests were conducted by the Air Quality Division of Am Test, Inc.

in June of 1989. All test data were rated "A" because sufficient information is provided to

evaluate the Oregon test methods used.

4.1.24 Safeway Disposal System24

Safeway Disposal System's facility in Middletown, Connecticut has a M & S Engineering

and Manufacturing model number MKI-10-S hospital waste incinerator, which was tested by

TRC Environmental Consultants, Inc. in August of 1988. This rotary kiln incinerator is equipped

with wet scrubbers. Emissions tested were controlled PM, HCl, sulfuric acid, NOx,

hydrocarbons, and CO. All test data were rated "A" because EPA methods were used, and good

documentation is provided for test methods, parameters, and results.

nja.117\(Reformatted 1/95) 7/93 4-10

4.1.25 Erlanger Medical Center - North Unit25

Emissions tests were conducted on the North Unit incinerator at the Erlanger Medical

Center, Chattanooga, Tennessee in March of 1988. Testing was conducted by Almega

Corporation. The North Unit is a Basic Model 1250 incinerator equipped with both a dry lime

injector baghouse and a waste heat recovery boiler. The incinerator has a charge rate capacity of

565 kg/hr (1,250 lbs/hr). Data were gathered to characterize the controlled emissions levels of

PM, HCl, Cl, CO, and NO2. The data were assigned a quality rating of "B" because the report

provided a good description of methods, including a complete set of appendices documenting all

phases of testing and laboratory analyses. Information was lacking on the description of the

composition of the medical waste.

4.1.26 Memorial Hospital26

Memorial Hospital, located in Chattanooga, Tennessee, conducted compliance emissions

testing on the Atlas Model CA-1500AR waste incinerator. The testing was performed by Air

Systems Testing, Inc. on July 29, 1988. Emissions were estimated for PM, HCl, and Cl. The

reported emissions data were assigned a quality rating of "C" because there was no description of

air pollution control devices associated with the incinerator. An adequate description of the

incinerated waste was also lacking.

4.1.27 ERA Tech27

CSA Company performed source emissions tests at the ERA Tech North Incinerator

located in Northwood, Ohio. The incinerator is equipped with a quench tower, absorption

reactor, and baghouse. The samples were collected in the stainless steel stack downstream of the

absorption reactor and the baghouse. The testing was completed in July of 1989, estimating

controlled PM and HCl emissions. The data were assigned a quality rating of "B" since

information describing the composition of the waste was missing.

4.1.28 Southland Exchange Joint Venture28

An emissions compliance test was conducted at the Southland Exchange Waste-to-

Energy Facility in Hampton, South Carolina in April of 1989. The facility consists of three

Consumat Model CS-3000 incinerators with two recovery boilers. Household, commercial,

industrial, and medical wastes are burned; only test data with medical waste were used. The

incinerators can employ natural gas as auxiliary fuel, but none was used during the test. The

incinerators are equipped with a DSI acid gas scrubber and three parallel ESPs. Tests were

nja.117\sect.2-6 4-11

performed by ETS, Inc. Controlled emissions of PM, HCl, and CO were tested, as well as

2,3,7,8-tetrachlorinated dibenzo-p-dioxin, 2,3,7,8-tetrachlorinated dibenzofurans, and metals (As,

Cd, Cr, Pb, Hg, and Ni). In addition, HCl emissions were measured exiting the boilers prior to

the scrubber so the HCl reduction efficiency of the scrubber could be determined, but the data

were insufficient to calculate an emission factor. For Cd, Cr, and Ni, it was reported that the

analytical blanks were high, results may be biased high due to background sample contamination.

These data were rated "D." All EPA test methods were used, or enough information was

presented to validate modified methods. With the exception of the waste composition, all

information is well documented. All data other than Cd, Cr, and Ni were rated "B."

4.1.29 Medical Energy Generation Associates29

Medical Energy Generation Associates (MEGA) of Louisville, Kentucky operates a

Simonds Model #AF-58 Incinerator to destroy hospital waste materials. The unit supports a

variable throat venturi wet scrubber and a vertical cyclonic entrainment separator. Galson

Technical Services, Inc. performed emissions testing of the incinerator unit on August 23-25,

1989, and again on November 15-16, 1989. Emissions estimates were compiled for PM, HCl,

CO, CDD, CDF, and several heavy metals including arsenic, cadmium, chromium, lead,

mercury, nickel, and silver. The estimates were assigned a data quality rating of "B" because a

description of the composition of the waste was not provided.

4.1.30 Therm-Tec Destruction Service - January 198930

The Model AR-1250-2-78DS Therm-Tec incinerator located in Elyria, Ohio was tested in

January of 1989 by Maurice L. Kelsey & Associates, Inc. and Almega Corporation. Emissions

tests for PM and HCl exiting the baghouse exhaust stack were performed. The emissions data

were rated "B" due to the lack of information regarding waste composition.

4.1.31 Bio-Medical Service Corporation31

Compliance emissions testing was performed on the incinerator at Bio-Medical Service

Corporation, Lake City, Georgia. Testing was performed in May of 1989 by Air Techniques.

The incinerator is equipped with a caustic and water quench chamber, venturi, and a packed

separator. Controlled emissions of PM and HCl were measured. The data were rated "B" due to

the lack of process description information and the use of Georgia methods for determining PM

and HCl concentrations.

4.1.32 Mayo Foundation Institute Hills Research Facility - November 3 and 1032

nja.117\(Reformatted 1/95) 7/93 4-12

PACE Laboratories conducted particulate and chloride emission compliance testing on

the Environmental Control Incinerator at the Mayo Foundation Institute Hills Research Facility

in Rochester, Minnesota on November 3rd and 10th, 1988. The waste stream for this incinerator

is typically non-infectious hospital waste and research animals. The input capacity of the

incinerator is 725 kg/hr (1,600 lbs/hr) and emissions are controlled by incinerator operational

parameters with no secondary control. Particulate matter and HCl were tested. All data were

rated "A" because EPA test methods were used and the tests are well documented.

4.1.33 Therm-Tec Destruction Service - May 198933

Therm-Tec Destruction Service incinerator Model AR-1250-2-78DS is equipped with a

heat exchanger and controlled with a fabric filter. The incinerator was again tested by Maurice L.

Kelsey and Associates, Inc. in association with the Almega Corporation on May 22, 1989 for

emissions of PM and HCl. Emissions were measured after the fabric filter using EPA Method 5

for PM and EPA Method 3 for HCl. While sufficient data were provided by the test report to

verify calculations, the data were rated "B" because the waste was not characterized.

nja.117\sect.2-6 4-13

4.1.34 Hamot Medical Center34

Hamot Medical Center in Erie Pennsylvania operates an Cleaver Brooks incinerator

Model No. 1280A/72 equipped with a heat recovery boiler and controlled with lime injection

proceeding a fabric filter and wet scrubber. The incinerator combusts approximately 455 kg/hr

(1,000 lbs/hr) of waste consisting of 85 percent hospital refuse and 15 percent infectious waste,

which is loaded into the primary chamber of the starved air thermal incinerator. Clean Air

Engineering tested the incinerator in February and March of 1990 for emissions of PM, metals,

HCl, SO2, SO3, CO, dioxins, and furans. Controlled emissions were presented for these

pollutants in addition to presenting uncontrolled emissions for HCl. Emission factors, however,

were not developed for dioxins and furans as emission rates could not be associated with

corresponding charge rates from the information available in the report. Emission factors were

developed for the remaining pollutants. The remaining pollutants were sampled with EPA

methods modified by the Pennsylvania Department of Environmental Resources (PADER), with

the exception of HCl, which was measured using a PADER method. The deviations in the test

methods were not well documented, consequently the data were rated "B."

4.1.35 HCA North Park Hospital35

Compliance emissions testing was performed on the Simonds Model 750B incinerator at

the HCA North Park Hospital located in Hixson, Tennessee in February of 1988. Testing was

conducted by Air Systems, Inc for uncontrolled PM, HCl, and Cl2 emissions. All data were

rated "B" due to the lack of process description and waste composition data.

4.1.36 Humana East Ridge Hospital36

The Humana East Ridge Hospital in Chattanooga, Tennessee contracted Air Techniques

to perform compliance emission testing on a natural gas-fired incinerator. The incinerator, which

is uncontrolled, was tested in November of 1987 for PM, HCl, and Cl2. All EPA test methods

were used, however the report lacked adequate documentation to validate the emissions data.

For this reason, the data were rated "B."

4.1.37 Helene Fuld Medical Center37

The Helene Fuld Medical Center in Trenton, New Jersey operates an incinerator with an

360 kg/hr (800 lb/hr) design charge rate, which is equipped with a waste heat boiler recovery

system and fired with auxiliary No. 2 fuel oil. Uncontrolled emissions were measured by the

State's Bureau of Technical Services in July of 1989 for PM, HCl, CO, NOx, and THC. EPA test

nja.117\(Reformatted 1/95) 7/93 4-14

methods were employed for CO and NOx, while New Jersey test methods were used for PM,

THC, and HCl. The report provide adequate detail for validation of the reported emission rates

for CO and NOx, which were rated as "A," however, PM, HCl and THC were rated as "B" due to

the use of non-EPA methods.

4.1.38 Other Data

Fifteen additional source test reports were obtained but not used. The reports and reasons

for not being included in AP-42 are listed below.

1. Source Emission Testing of Hospital and Classified Waste Incinerators, Plattsburg

AFB, New York. Hydrochloric acid and total particulate emissions were reported.

Large variations in chamber temperatures were noted during the test. The test

report recommends a maintenance inspection to insure proper operation. These

data were not included in the database due to the operating conditions during

testing. The conditions did not seem representative of typical incinerator

operation, and sufficient data were available for HCl and PM from other reports.

2. Source Emission Testing of a Hospital Pathological Waste Incinerator, K.I.

Sawyer AFB, Michigan. Total particulate emissions were reported. Data were

not included for two reasons: 1) Only the capacity of the unit and "typical"

loading rates were given. Actual loading rate during the test was not given. 2)

The incinerator was stated to be in poor repair, and thus not representative of the

general population.

3. Source Emission Testing of a Hospital Pathological Waste Incinerator, Beale

AFB, California. Total particulate and HCl emissions were reported. Data were

not reported due to poor maintenance of the incinerator. A hole in the refractory

and incinerator wall was noted as well as flames exiting the incinerator stack.

Actual loading rates during the test were also not reported.

4. Emissions Testing of Incinerator at Queen of the Valley Hospitals, Napa,

California. Total particulate and HCl emissions were reported. Data were

excluded due to the lack of process description/waste stream composition

information.

nja.117\sect.2-6 4-15

5. Compliance Test Report, Cranston General Hospital Waste Incinerator, Cranston,

Rhode Island. Particulate and HCl emissions were reported. These data were

excluded due to the lack of process description and test methods information.

6. Report of Particulate/HCl/CO Emissions Test for National Incinerator, Inc. Model

P-50 Incinerator, Corsicana, Texas. These data were excluded because of the lack

of process description, test methods, and waste stream composition data.

7. Emissions Compliance Evaluation, Particulate Matter and Hydrogen Chloride.

Pathological Waste Incinerator No. 2, Multitech Industries, Inc.. These data were

excluded due to the lack of process description information.

8. Stack Emission Testing, Anderson Scrubber, Inlet and Outlet. Albert Einstein

Waste Incinerator. These particulate data were excluded because the copy was

illegible, and no facility description or test method information was presented.

9. Performance Tests at Borgess Hospital, Kalamazoo, Michigan. These HCl were

excluded due to the absence of throughput data.

10. Report of Particulate/HCl/CO Emissions Test for National Incinerator, Inc.

Model P-200 Incinerator. Corsicana, Texas. These data were excluded because

the text states only that this pathological incinerator was charged with a

"representative mixture of refuse." It is not clear if the charge rate includes just

pathological waste or the total mixture.

11. Report of Emission Tests, American Cyanamid Company, West Windsor,

Township, New Jersey. These particulate, total hydrocarbon, nitrogen oxide, and

carbon monoxide data were not used because atypical (100% pathological) wastes

appear to have been fired.

12. Final Report, Kent County Memorial Hospital Incinerator Compliance Test.

Compounds tested for include total suspended particulate, trace metals, HCl,

carbon monoxide, and dioxins/furans. These data were excluded due to the lack

of process description and test methods information.

13. Source Sampling Report for Bio Ecological Services, Inc. Model 2500 TES

Incinerator, Huntersville, North Carolina. These particulate, carbon monoxide,

and HCl data were excluded because atypical (pathological only) wastes were

burned.

nja.117\(Reformatted 1/95) 7/93 4-16

14. Particulate, Metals, and Hydrogen Chloride Emission Test of Incinerator.

University of Michigan Hospital, Ann Arbor, Michigan. These data were

excluded because water was added to the waste during the tests, indicating that the

waste stream may not be representative.

15. Compliance Emission Testing for HCA Parkridge Hospital, Chattanooga,

Tennessee. These PM, HCl, and Cl2 test data were excluded because the charge

rate was only provided for the entire duration of testing, and one of four runs was

void. It was not clear how much waste was charged during the individual test

runs.

4.2 PROTOCOL FOR DATABASE

Due to the variety of formats used to report test results at different medical waste

incineration facilities, the emissions data required some preprocessing to standardize the units of

measure prior to computer calculation of emission factors. Emission factors were then calculated

in terms of lb/ton and mg/Mg of waste fed for all pollutants. Table 4-1 presents a list of the

emission factors, calculated on a run-by-run basis, which were used to calculate the emission

factors presented in AP-42 Section 2.6 for controlled air and rotary kiln MWIs. Table 4-1 is

sorted first by air pollution control type for controlled air incinerators, then by pollutant and

facility. Table 4-2 presents similar information for test data from two rotary kiln MWIs.

The following subsections illustrate how the raw data were manipulated to calculate all emission

factors in similar units.

4.2.1 Charge Rates

In each report, charge rates were given in either pounds per hour (lb/hr) or kilograms per

hour (kg/hr). To convert the two, the following conversion was used:

Charge rate (lb/hr) = Charge rate (kg/hr) * 2.2046

4.2.2 Data Presented in Pounds per Hour or Grams per Hour

In the simplest cases, raw data were given in units of lb/hr or g/hr. In this case, the

number given was simply divided by the charge rate for that particular test run:

EF1 (emission factor,lb/ton) = 2,000 * Emission rate (lb/hr)

nja.117\sect.2-6 4-17

Charge rate (lb/hr)

EF2 (mg/Mg) = 1,000,000 * Emission rate (g/hr) Charge rate (kg/hr)

For data presented in µg/hr or mg/hr, divide the EF2 equation by 1 or 1,000, respectively. Also,

for data presented in ng/sec, multiply the EF2 equation by 0.0036.

nja.117\ (Reformatted 1/95) 7/93 4-18

TABLE 4-1. SUMMARY OF CONTROLLED AIR MWI EMISSION FACTORSON A TEST-BY-TEST BASIS

TABLE 4-1. SUMMARY OF EMISSION FACTORS ON A TEST-BY-TEST BASIS

Emission Factor- - - - - - - - - -

Type* Facility Reference Run Pollutant lb/ton mg/Mg= = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = =

1 Cape Fear 2 1 2378 TCDD 6.66e-08 3.33e-021 Cape Fear 2 2 2378 TCDD 3.36e-08 1.68e-021 Cape Fear 2 3 2378 TCDD 9.23e-08 4.61e-021 Cape Fear 2 4 2378 TCDD 4.32e-08 2.16e-021 Cape Fear 2 5 2378 TCDD 9.83e-08 4.91e-021 Cape Fear 2 6 2378 TCDD 3.61e-08 1.80e-021 Cape Fear 2 7 2378 TCDD 2.33e-07 1.16e-011 Cape Fear 2 8 2378 TCDD 6.31e-08 3.16e-021 Cape Fear 2 9 2378 TCDD 1.23e-07 6.15e-021 Cedars Sinai 7 1 2378 TCDD 3.24e-09 1.62e-031 Cedars Sinai 7 2 2378 TCDD 7.77e-09 3.89e-031 Cedars Sinai 7 3 2378 TCDD 5.51e-09 2.75e-031 Jordan 3 2 2378 TCDD 3.10e-09 1.55e-031 Jordan 3 4 2378 TCDD 5.72e-09 2.86e-031 Jordan 3 6 2378 TCDD 3.71e-08 1.86e-021 Kaiser 4 1 2378 TCDD 8.48e-09 4.24e-031 Kaiser 4 2 2378 TCDD 3.92e-09 1.96e-031 Kaiser 4 3 2378 TCDD 1.23e-08 6.13e-031 Lenoir 5 1 2378 TCDD 3.79e-08 1.89e-021 Lenoir 5 2 2378 TCDD 1.20e-07 6.02e-021 Lenoir 5 3 2378 TCDD 2.35e-08 1.18e-021 Lenoir 5 4 2378 TCDD 3.73e-07 1.87e-01

1 Lenoir 5 5 2378 TCDD 8.13e-08 4.07e-021 Lenoir 5 6 2378 TCDD 4.39e-07 2.20e-011 Lenoir 5 7 2378 TCDD 6.44e-08 3.21e-021 Lenoir 5 8 2378 TCDD 5.41e-07 2.71e-011 Lenoir 5 9 2378 TCDD 6.14e-08 3.06e-021 Sanford 6 1 2378 TCDD 1.41e-08 7.07e-031 Sanford 6 2 2378 TCDD 3.60e-08 1.80e-021 Sanford 6 3 2378 TCDD 2.57e-08 1.29e-021 Sanford 6 4 2378 TCDD 9.17e-09 4.59e-031 Sanford 6 5 2378 TCDD 3.89e-07 1.94e-011 Sanford 6 6 2378 TCDD 1.07e-08 5.35e-031 Sanford 6 8 2378 TCDD 8.90e-07 4.45e-011 Sanford 6 9 2378 TCDD 2.92e-07 1.46e-011 Sanford 6 10 2378 TCDD 3.83e-09 1.91e-031 St. Bernardine's 1 1 2378 TCDD 1.50e-09 7.52e-041 St. Bernardine's 1 2 2378 TCDD 1.20e-08 6.02e-031 St. Bernardine's 1 3 2378 TCDD 1.81e-09 9.07e-041 St. Bernardine's 1 4 2378 TCDD 1.81e-09 9.07e-041 St.Agnes 8 2 2378 TCDD 1.07e-08 5.37e-031 Sutter 9 1 2378 TCDD 6.42e-09 3.21e-031 Sutter 9 2 2378 TCDD 3.55e-09 1.77e-031 Sutter 9 3 2378 TCDD 4.52e-09 2.26e-031 USC 11 1 2378 TCDD 1.33e-07 6.64e-021 USC 11 3 2378 TCDD 3.00e-08 1.50e-021 USC 11 4 2378 TCDD 6.62e-08 3.31e-021 Cape Fear 2 1 TOTAL TCDD 2.86e-06 1.43e+001 Cape Fear 2 2 TOTAL TCDD 7.68e-07 3.84e-011 Cape Fear 2 3 TOTAL TCDD 2.77e-07 1.38e-01

1 Cape Fear 2 4 TOTAL TCDD 1.26e-06 6.28e-011 Cape Fear 2 5 TOTAL TCDD 8.63e-08 4.32e-021 Cape Fear 2 6 TOTAL TCDD 3.66e-06 1.83e+001 Cape Fear 2 7 TOTAL TCDD 1.86e-06 9.32e-011 Cape Fear 2 8 TOTAL TCDD 1.33e-06 6.65e-011 Cape Fear 2 9 TOTAL TCDD 4.79e-07 2.40e-011 Cedars Sinai 7 1 TOTAL TCDD 3.90e-08 1.95e-021 Cedars Sinai 7 2 TOTAL TCDD 1.30e-07 6.48e-021 Cedars Sinai 7 3 TOTAL TCDD 7.63e-08 3.81e-021 Jordan 3 2 TOTAL TCDD 7.10e-09 3.55e-031 Jordan 3 4 TOTAL TCDD 3.57e-07 1.79e-011 Jordan 3 6 TOTAL TCDD 4.07e-07 2.04e-011 Kaiser 4 1 TOTAL TCDD 8.48e-09 4.24e-031 Kaiser 4 2 TOTAL TCDD 1.50e-08 7.51e-031 Kaiser 4 3 TOTAL TCDD 1.41e-07 7.06e-021 Lenoir 5 1 TOTAL TCDD 7.75e-06 3.88e+001 Lenoir 5 2 TOTAL TCDD 5.47e-06 2.74e+001 Lenoir 5 3 TOTAL TCDD 6.46e-07 3.22e-011 Lenoir 5 4 TOTAL TCDD 9.01e-07 4.51e-011 Lenoir 5 5 TOTAL TCDD 4.82e-06 2.41e+001 Lenoir 5 6 TOTAL TCDD 3.97e-07 1.98e-011 Lenoir 5 7 TOTAL TCDD 3.13e-07 1.57e-011 Lenoir 5 8 TOTAL TCDD 1.48e-06 7.40e-011 Lenoir 5 9 TOTAL TCDD 8.71e-07 4.34e-011 Sanford 6 1 TOTAL TCDD 1.02e-05 5.08e+001 Sanford 6 2 TOTAL TCDD 4.19e-07 2.09e-011 Sanford 6 3 TOTAL TCDD 1.99e-07 9.96e-021 Sanford 6 4 TOTAL TCDD 1.67e-05 8.36e+00

1 Sanford 6 5 TOTAL TCDD 7.16e-06 3.58e+001 Sanford 6 6 TOTAL TCDD 8.61e-07 4.31e-011 Sanford 6 8 TOTAL TCDD 3.37e-06 1.68e+001 Sanford 6 9 TOTAL TCDD 4.85e-07 2.43e-011 Sanford 6 10 TOTAL TCDD 2.14e-06 1.07e+001 St. Bernardine's 1 1 TOTAL TCDD 1.25e-07 6.27e-021 St. Bernardine's 1 2 TOTAL TCDD 1.75e-07 8.75e-021 St. Bernardine's 1 3 TOTAL TCDD 9.66e-08 4.83e-021 St. Bernardine's 1 4 TOTAL TCDD 3.63e-09 1.81e-031 St.Agnes 8 1 TOTAL TCDD 1.07e-06 5.36e-011 St.Agnes 8 2 TOTAL TCDD 8.76e-08 4.38e-021 Sutter 9 1 TOTAL TCDD 6.80e-07 3.40e-011 Sutter 9 2 TOTAL TCDD 6.78e-07 3.39e-011 Sutter 9 3 TOTAL TCDD 1.07e-06 5.37e-011 USC 11 1 TOTAL TCDD 8.10e-07 4.05e-011 USC 11 3 TOTAL TCDD 4.26e-07 2.13e-011 USC 11 4 TOTAL TCDD 3.64e-07 1.82e-011 Cape Fear 2 1 TOTAL CDD 3.85e-05 1.92e+011 Cape Fear 2 2 TOTAL CDD 1.91e-05 9.56e+001 Cape Fear 2 3 TOTAL CDD 6.45e-06 3.22e+001 Cape Fear 2 4 TOTAL CDD 2.45e-05 1.23e+011 Cape Fear 2 5 TOTAL CDD 2.06e-05 1.03e+011 Cape Fear 2 6 TOTAL CDD 2.46e-06 1.23e+001 Cape Fear 2 7 TOTAL CDD 1.35e-05 6.74e+001 Cape Fear 2 8 TOTAL CDD 3.26e-05 1.63e+011 Cape Fear 2 9 TOTAL CDD 2.06e-05 1.03e+011 Cedars Sinai 7 1 TOTAL CDD 3.00e-06 1.50e+001 Cedars Sinai 7 2 TOTAL CDD 4.07e-06 2.03e+00

1 Cedars Sinai 7 3 TOTAL CDD 4.83e-06 2.41e+001 Jordan 3 2 TOTAL CDD 5.93e-08 2.96e-021 Jordan 3 4 TOTAL CDD 4.96e-06 2.48e+001 Jordan 3 6 TOTAL CDD 1.69e-05 8.45e+001 Kaiser 4 1 TOTAL CDD 6.04e-06 3.02e+001 Kaiser 4 2 TOTAL CDD 7.32e-06 3.66e+001 Kaiser 4 3 TOTAL CDD 2.20e-05 1.10e+011 Lenoir 5 1 TOTAL CDD 1.55e-05 7.74e+001 Lenoir 5 2 TOTAL CDD 1.01e-04 5.06e+011 Lenoir 5 3 TOTAL CDD 4.10e-05 2.04e+011 Lenoir 5 4 TOTAL CDD 2.76e-05 1.38e+011 Lenoir 5 5 TOTAL CDD 9.63e-05 4.80e+011 Lenoir 5 6 TOTAL CDD 3.92e-05 1.95e+011 Lenoir 5 7 TOTAL CDD 4.21e-05 2.11e+011 Lenoir 5 8 TOTAL CDD 6.20e-05 3.10e+011 Lenoir 5 9 TOTAL CDD 6.82e-05 3.41e+011 Sanford 6 1 TOTAL CDD 1.31e-04 6.53e+011 Sanford 6 2 TOTAL CDD 6.22e-06 3.11e+001 Sanford 6 3 TOTAL CDD 9.67e-05 4.83e+011 Sanford 6 4 TOTAL CDD 2.53e-06 1.26e+001 Sanford 6 5 TOTAL CDD 4.25e-05 2.12e+011 Sanford 6 6 TOTAL CDD 1.21e-05 6.03e+001 Sanford 6 8 TOTAL CDD 3.62e-06 1.81e+001 Sanford 6 9 TOTAL CDD 1.93e-06 9.63e-011 Sanford 6 10 TOTAL CDD 1.04e-06 5.22e-011 St. Bernardine's 1 1 TOTAL CDD 3.26e-06 1.63e+001 St. Bernardine's 1 2 TOTAL CDD 8.76e-06 4.38e+001 St. Bernardine's 1 3 TOTAL CDD 5.15e-06 2.58e+00

1 St. Bernardine's 1 4 TOTAL CDD 1.91e-06 9.54e-011 St.Agnes 8 1 TOTAL CDD 1.25e-05 6.26e+001 St.Agnes 8 2 TOTAL CDD 7.64e-06 3.82e+001 Sutter 9 1 TOTAL CDD 2.79e-05 1.39e+011 Sutter 9 2 TOTAL CDD 3.09e-05 1.55e+011 Sutter 9 3 TOTAL CDD 3.24e-05 1.62e+011 USC 11 1 TOTAL CDD 3.21e-05 1.61e+011 USC 11 3 TOTAL CDD 7.87e-05 3.93e+011 USC 11 4 TOTAL CDD 6.37e-05 3.18e+011 Cape Fear 2 1 2378 TCDF 5.82e-07 2.91e-011 Cape Fear 2 1 2378 TCDF 2.34e-07 1.17e-011 Cape Fear 2 2 2378 TCDF 2.10e-07 1.05e-011 Cape Fear 2 2 2378 TCDF 6.09e-07 3.05e-011 Cape Fear 2 3 2378 TCDF 3.18e-07 1.59e-011 Cape Fear 2 3 2378 TCDF 2.44e-07 1.22e-011 Cape Fear 2 4 2378 TCDF 9.53e-07 4.76e-011 Cape Fear 2 5 2378 TCDF 1.35e-08 6.77e-031 Cape Fear 2 6 2378 TCDF 2.17e-07 1.08e-011 Cape Fear 2 7 2378 TCDF 3.99e-07 2.00e-011 Cape Fear 2 8 2378 TCDF 3.45e-07 1.72e-011 Cape Fear 2 9 2378 TCDF 2.28e-07 1.14e-011 Cedars Sinai 7 1 2378 TCDF 2.07e-08 1.04e-021 Cedars Sinai 7 2 2378 TCDF 4.50e-08 2.25e-021 Cedars Sinai 7 3 2378 TCDF 3.43e-08 1.72e-021 Jordan 3 2 2378 TCDF 4.56e-09 2.28e-031 Jordan 3 4 2378 TCDF 8.31e-08 4.15e-021 Jordan 3 6 2378 TCDF 2.82e-07 1.41e-011 Kaiser 4 1 2378 TCDF 3.40e-08 1.70e-02

1 Kaiser 4 2 2378 TCDF 1.50e-08 7.51e-031 Kaiser 4 3 2378 TCDF 1.53e-07 7.67e-021 Lenoir 5 1 2378 TCDF 3.80e-07 1.90e-011 Lenoir 5 1 2378 TCDF 6.42e-07 3.21e-011 Lenoir 5 2 2378 TCDF 2.45e-07 1.22e-011 Lenoir 5 2 2378 TCDF 2.71e-07 1.35e-011 Lenoir 5 3 2378 TCDF 2.20e-06 1.10e+001 Lenoir 5 3 2378 TCDF 1.31e-07 6.57e-021 Lenoir 5 4 2378 TCDF 2.01e-06 1.01e+001 Lenoir 5 5 2378 TCDF 3.86e-07 1.92e-011 Lenoir 5 6 2378 TCDF 2.20e-06 1.10e+001 Lenoir 5 7 2378 TCDF 2.20e-06 1.10e+001 Lenoir 5 8 2378 TCDF 3.66e-07 1.83e-011 Lenoir 5 9 2378 TCDF 1.83e-07 9.11e-021 Sanford 6 1 2378 TCDF 4.74e-08 2.37e-021 Sanford 6 1 2378 TCDF 9.47e-08 4.74e-021 Sanford 6 2 2378 TCDF 1.67e-07 8.35e-021 Sanford 6 2 2378 TCDF 1.42e-06 7.10e-011 Sanford 6 3 2378 TCDF 6.00e-08 3.00e-021 Sanford 6 3 2378 TCDF 8.00e-08 4.00e-021 Sanford 6 4 2378 TCDF 1.50e-08 7.50e-031 Sanford 6 5 2378 TCDF 8.90e-07 4.45e-011 Sanford 6 6 2378 TCDF 3.29e-06 1.64e+001 Sanford 6 8 2378 TCDF 1.65e-07 8.23e-021 Sanford 6 9 2378 TCDF 5.11e-08 2.56e-021 Sanford 6 10 2378 TCDF 1.76e-07 8.78e-021 St. Bernardine's 1 1 2378 TCDF 3.16e-08 1.58e-021 St. Bernardine's 1 2 2378 TCDF 2.91e-08 1.45e-02

1 St. Bernardine's 1 3 2378 TCDF 1.72e-08 8.62e-031 St. Bernardine's 1 4 2378 TCDF 1.04e-08 5.22e-031 St.Agnes 8 1 2378 TCDF 4.64e-08 2.32e-021 St.Agnes 8 2 2378 TCDF 5.62e-08 2.81e-021 Sutter 9 1 2378 TCDF 1.74e-07 8.71e-021 Sutter 9 2 2378 TCDF 1.57e-07 7.84e-021 Sutter 9 3 2378 TCDF 1.95e-07 9.76e-021 USC 11 1 2378 TCDF 6.36e-07 3.18e-011 USC 11 3 2378 TCDF 3.63e-07 1.81e-011 USC 11 4 2378 TCDF 5.22e-07 2.61e-011 Cape Fear 2 1 TOTAL TCDF 6.50e-06 3.25e+001 Cape Fear 2 2 TOTAL TCDF 1.01e-05 5.03e+001 Cape Fear 2 3 TOTAL TCDF 1.91e-05 9.56e+001 Cape Fear 2 4 TOTAL TCDF 1.20e-05 6.01e+001 Cape Fear 2 5 TOTAL TCDF 2.87e-05 1.43e+011 Cape Fear 2 6 TOTAL TCDF 1.13e-05 5.65e+001 Cape Fear 2 7 TOTAL TCDF 8.70e-06 4.35e+001 Cape Fear 2 8 TOTAL TCDF 4.73e-07 2.36e-011 Cape Fear 2 9 TOTAL TCDF 9.27e-06 4.63e+001 Cedars Sinai 7 1 TOTAL TCDF 6.53e-07 3.26e-011 Cedars Sinai 7 2 TOTAL TCDF 1.55e-06 7.77e-011 Cedars Sinai 7 3 TOTAL TCDF 1.16e-06 5.81e-011 Jordan 3 2 TOTAL TCDF 6.08e-08 3.04e-021 Jordan 3 4 TOTAL TCDF 4.09e-06 2.04e+001 Jordan 3 6 TOTAL TCDF 7.57e-06 3.79e+001 Kaiser 4 1 TOTAL TCDF 4.88e-07 2.44e-011 Kaiser 4 2 TOTAL TCDF 4.45e-07 2.23e-011 Kaiser 4 3 TOTAL TCDF 2.33e-06 1.17e+00

1 Lenoir 5 1 TOTAL TCDF 5.98e-05 2.99e+011 Lenoir 5 2 TOTAL TCDF 5.11e-06 2.56e+001 Lenoir 5 3 TOTAL TCDF 4.63e-05 2.32e+011 Lenoir 5 4 TOTAL TCDF 5.72e-05 2.86e+011 Lenoir 5 5 TOTAL TCDF 1.38e-05 6.90e+001 Lenoir 5 6 TOTAL TCDF 1.08e-05 5.38e+001 Lenoir 5 7 TOTAL TCDF 2.26e-05 1.13e+011 Lenoir 5 8 TOTAL TCDF 8.40e-06 4.19e+001 Lenoir 5 9 TOTAL TCDF 1.08e-05 5.39e+001 Sanford 6 1 TOTAL TCDF 6.15e-07 3.08e-011 Sanford 6 2 TOTAL TCDF 1.98e-06 9.91e-011 Sanford 6 3 TOTAL TCDF 2.75e-05 1.37e+011 Sanford 6 4 TOTAL TCDF 1.03e-05 5.15e+001 Sanford 6 5 TOTAL TCDF 1.67e-06 8.33e-011 Sanford 6 6 TOTAL TCDF 7.02e-06 3.51e+001 Sanford 6 8 TOTAL TCDF 9.58e-05 4.79e+011 Sanford 6 9 TOTAL TCDF 6.59e-06 3.30e+001 Sanford 6 10 TOTAL TCDF 2.24e-06 1.12e+001 St. Bernardine's 1 1 TOTAL TCDF 8.91e-07 4.46e-011 St. Bernardine's 1 2 TOTAL TCDF 1.41e-06 7.04e-011 St. Bernardine's 1 3 TOTAL TCDF 4.99e-07 2.50e-011 St. Bernardine's 1 4 TOTAL TCDF 1.33e-07 6.65e-021 St.Agnes 8 1 TOTAL TCDF 1.81e-06 9.04e-011 St.Agnes 8 2 TOTAL TCDF 2.07e-06 1.03e+001 Sutter 9 1 TOTAL TCDF 8.81e-06 4.40e+001 Sutter 9 2 TOTAL TCDF 8.16e-06 4.08e+001 Sutter 9 3 TOTAL TCDF 8.26e-06 4.13e+001 USC 11 1 TOTAL TCDF 9.25e-06 4.63e+00

1 USC 11 3 TOTAL TCDF 4.27e-06 2.13e+001 USC 11 4 TOTAL TCDF 7.18e-06 3.59e+001 Cape Fear 2 1 TOTAL CDF 1.43e-04 7.17e+011 Cape Fear 2 2 TOTAL CDF 1.14e-04 5.70e+011 Cape Fear 2 3 TOTAL CDF 1.49e-05 7.43e+001 Cape Fear 2 4 TOTAL CDF 6.99e-05 3.50e+011 Cape Fear 2 5 TOTAL CDF 4.55e-05 2.27e+011 Cape Fear 2 6 TOTAL CDF 1.20e-04 6.01e+011 Cape Fear 2 7 TOTAL CDF 1.13e-04 5.65e+011 Cape Fear 2 8 TOTAL CDF 2.05e-04 1.02e+021 Cape Fear 2 9 TOTAL CDF 1.02e-04 5.09e+011 Cedars Sinai 7 1 TOTAL CDF 8.10e-06 4.05e+001 Cedars Sinai 7 2 TOTAL CDF 1.12e-05 5.61e+001 Cedars Sinai 7 3 TOTAL CDF 1.29e-05 6.46e+001 Jordan 3 2 TOTAL CDF 2.83e-07 1.41e-011 Jordan 3 4 TOTAL CDF 1.23e-05 6.14e+001 Jordan 3 6 TOTAL CDF 6.48e-05 3.24e+011 Kaiser 4 1 TOTAL CDF 1.60e-05 7.99e+001 Kaiser 4 2 TOTAL CDF 1.46e-05 7.30e+001 Kaiser 4 3 TOTAL CDF 4.26e-05 2.13e+011 Lenoir 5 1 TOTAL CDF 2.90e-04 1.45e+021 Lenoir 5 2 TOTAL CDF 1.65e-04 8.24e+011 Lenoir 5 3 TOTAL CDF 1.21e-04 6.05e+011 Lenoir 5 4 TOTAL CDF 2.69e-04 1.34e+021 Lenoir 5 5 TOTAL CDF 1.45e-04 7.21e+011 Lenoir 5 6 TOTAL CDF 4.12e-04 2.06e+021 Lenoir 5 7 TOTAL CDF 1.11e-04 5.54e+011 Lenoir 5 8 TOTAL CDF 5.44e-05 2.72e+01

1 Lenoir 5 9 TOTAL CDF 6.45e-04 3.23e+021 Sanford 6 1 TOTAL CDF 1.40e-05 6.98e+001 Sanford 6 2 TOTAL CDF 1.50e-04 7.49e+011 Sanford 6 3 TOTAL CDF 4.87e-06 2.43e+001 Sanford 6 4 TOTAL CDF 6.54e-04 3.27e+021 Sanford 6 5 TOTAL CDF 2.61e-04 1.30e+021 Sanford 6 6 TOTAL CDF 2.00e-06 9.98e-011 Sanford 6 8 TOTAL CDF 8.69e-06 4.34e+001 Sanford 6 9 TOTAL CDF 4.49e-06 2.24e+001 Sanford 6 10 TOTAL CDF 2.99e-05 1.49e+011 St. Bernardine's 1 1 TOTAL CDF 1.01e-05 5.03e+001 St. Bernardine's 1 2 TOTAL CDF 2.13e-05 1.06e+011 St. Bernardine's 1 3 TOTAL CDF 1.10e-05 5.50e+001 St. Bernardine's 1 4 TOTAL CDF 3.63e-06 1.82e+001 St.Agnes 8 1 TOTAL CDF 2.19e-05 1.09e+011 St.Agnes 8 2 TOTAL CDF 1.85e-05 9.26e+001 Sutter 9 1 TOTAL CDF 5.40e-05 2.70e+011 Sutter 9 2 TOTAL CDF 5.92e-05 2.96e+011 Sutter 9 3 TOTAL CDF 6.11e-05 3.05e+011 USC 11 1 TOTAL CDF 1.17e-04 5.87e+011 USC 11 3 TOTAL CDF 1.66e-04 8.32e+011 USC 11 4 TOTAL CDF 1.96e-04 9.82e+011 Cape Fear 2 8 TOTAL PCB 1.23e-08 6.16e-031 Kaiser 4 1 TOTAL PCB 1.23e-08 6.16e-031 Kaiser 4 2 TOTAL PCB 8.59e-05 4.29e+011 Kaiser 4 3 TOTAL PCB 9.64e-05 4.82e+011 Lenoir 5 7 Chlorobenzene 1.40e-03 6.99e+021 Lenoir 5 7 Chlorophenol 8.24e-04 4.12e+02

1 Cape Fear 2 1 Total Hydrocarbons 6.23e-02 3.12e+041 Cape Fear 2 2 Total Hydrocarbons 3.60e-02 1.80e+041 Cape Fear 2 3 Total Hydrocarbons 1.16e+00 5.82e+051 Cape Fear 2 4 Total Hydrocarbons 1.67e+00 8.37e+051 Cape Fear 2 5 Total Hydrocarbons 1.60e-01 8.00e+041 Cape Fear 2 6 Total Hydrocarbons 8.92e-02 4.46e+041 Cape Fear 2 7 Total Hydrocarbons 2.28e-01 1.14e+051 Cape Fear 2 8 Total Hydrocarbons 2.89e-01 1.45e+051 Cape Fear 2 9 Total Hydrocarbons 2.72e-01 1.36e+051 Jordan 3 2 Total Hydrocarbons 7.60e-01 3.80e+051 Jordan 3 6 Total Hydrocarbons 3.71e-01 1.85e+051 Kaiser 4 1 Total Hydrocarbons 1.27e-01 6.34e+041 Kaiser 4 2 Total Hydrocarbons 1.27e-01 6.34e+041 Kaiser 4 3 Total Hydrocarbons 1.27e-01 6.34e+041 Kaiser 4 4 Total Hydrocarbons 1.43e-01 7.16e+041 Kaiser 4 5 Total Hydrocarbons 1.43e-01 7.16e+041 Kaiser 4 6 Total Hydrocarbons 1.55e-01 7.77e+041 Kaiser 4 7 Total Hydrocarbons 1.55e-01 7.77e+041 Kaiser 4 8 Total Hydrocarbons 1.66e-01 8.28e+041 Lenoir 5 1 Total Hydrocarbons 1.68e-01 8.41e+041 Lenoir 5 2 Total Hydrocarbons 3.07e-01 1.53e+051 Lenoir 5 3 Total Hydrocarbons 2.84e-01 1.42e+051 Lenoir 5 4 Total Hydrocarbons 8.44e-02 4.22e+041 Lenoir 5 6 Total Hydrocarbons 2.25e-01 1.13e+051 Lenoir 5 7 Total Hydrocarbons 2.33e-01 1.16e+051 Lenoir 5 9 Total Hydrocarbons 9.08e-01 4.54e+051 Sanford 6 1 Total Hydrocarbons 3.54e-01 1.77e+051 Sanford 6 2 Total Hydrocarbons 6.59e-01 3.30e+05

1 Sanford 6 3 Total Hydrocarbons 3.91e-01 1.95e+051 Sanford 6 4 Total Hydrocarbons 1.96e+00 9.80e+051 Sanford 6 5 Total Hydrocarbons 1.18e-01 5.89e+041 Sanford 6 6 Total Hydrocarbons 1.94e-01 9.71e+041 Sanford 6 8 Total Hydrocarbons 9.50e-01 4.75e+051 Sanford 6 9 Total Hydrocarbons 1.17e-01 5.87e+041 Sanford 6 10 Total Hydrocarbons 1.20e-01 6.01e+041 St. Bernardine's 1 4 Total Hydrocarbons 3.95e-02 1.97e+041 St.Agnes 8 1 Total Hydrocarbons 4.15e-02 2.08e+041 St.Agnes 8 2 Total Hydrocarbons 4.88e-02 2.44e+041 St.Agnes 8 3 Total Hydrocarbons 4.88e-02 2.44e+041 St.Agnes 8 4 Total Hydrocarbons 5.58e-02 2.79e+041 St.Agnes 8 5 Total Hydrocarbons 5.16e-02 2.58e+041 St.Agnes 8 6 Total Hydrocarbons 4.67e-02 2.34e+041 St.Agnes 8 7 Total Hydrocarbons 4.67e-02 2.34e+041 St.Agnes 8 8 Total Hydrocarbons 4.91e-02 2.46e+041 St.Agnes 8 9 Total Hydrocarbons 1.11e-02 5.55e+031 Sutter 9 1 Total Hydrocarbons 5.51e-02 2.75e+041 Sutter 9 2 Total Hydrocarbons 8.60e-02 4.30e+041 Sutter 9 3 Total Hydrocarbons 8.21e-02 4.11e+041 Sutter 9 4 Total Hydrocarbons 5.03e-01 2.52e+051 Cape Fear 2 1 Antimony 3.50e-02 1.75e+041 Cape Fear 2 2 Antimony 2.02e-02 1.01e+041 Cape Fear 2 3 Antimony 8.27e-03 4.13e+031 Cape Fear 2 4 Antimony 3.57e-02 1.79e+041 Cape Fear 2 5 Antimony 6.76e-02 3.38e+041 Cape Fear 2 6 Antimony 4.54e-02 2.27e+041 Cape Fear 2 7 Antimony 4.53e-02 2.26e+04

1 Cape Fear 2 8 Antimony 1.15e-01 5.76e+041 Cape Fear 2 9 Antimony 3.86e-02 1.93e+041 Jordan 3 2 Antimony 2.74e-03 1.37e+031 Jordan 3 4 Antimony 3.70e-03 1.85e+031 Jordan 3 6 Antimony 4.51e-03 2.26e+031 Jubilee 12 1 Antimony 4.57e-04 2.29e+021 Jubilee 12 2 Antimony 6.50e-04 3.25e+021 Lenoir 5 1 Antimony 2.38e-02 1.19e+041 Lenoir 5 2 Antimony 9.99e-03 5.00e+031 Lenoir 5 3 Antimony 1.08e-02 5.38e+031 Lenoir 5 4 Antimony 4.14e-02 2.07e+041 Lenoir 5 5 Antimony 1.12e-02 5.59e+031 Lenoir 5 6 Antimony 2.13e-02 1.07e+041 Lenoir 5 7 Antimony 2.27e-02 1.13e+041 Lenoir 5 8 Antimony 6.39e-03 3.19e+031 Lenoir 5 9 Antimony 1.57e-02 7.87e+031 Sanford 6 1 Antimony 7.46e-03 3.73e+031 Sanford 6 2 Antimony 6.79e-03 3.40e+031 Sanford 6 3 Antimony 1.25e-02 6.26e+031 Sanford 6 4 Antimony 1.13e-03 5.64e+021 Sanford 6 5 Antimony 1.01e-03 5.05e+021 Sanford 6 6 Antimony 1.05e-02 5.25e+031 Sanford 6 8 Antimony 9.39e-04 4.70e+021 Sanford 6 9 Antimony 1.41e-03 7.07e+021 Sanford 6 10 Antimony 1.76e-03 8.78e+021 Cape Fear 2 1 Arsenic 2.97e-04 1.48e+021 Cape Fear 2 2 Arsenic 4.57e-04 2.28e+021 Cape Fear 2 3 Arsenic 4.37e-04 2.18e+02

1 Cape Fear 2 4 Arsenic 2.30e-04 1.15e+021 Cape Fear 2 5 Arsenic 4.56e-04 2.28e+021 Cape Fear 2 6 Arsenic 8.29e-04 4.14e+021 Cape Fear 2 7 Arsenic 8.32e-04 4.16e+021 Cape Fear 2 8 Arsenic 5.28e-04 2.64e+021 Cape Fear 2 9 Arsenic 7.52e-04 3.76e+021 Cedars Sinai 7 1 Arsenic 2.92e-04 1.46e+021 Cedars Sinai 7 2 Arsenic 1.85e-04 9.23e+011 Cedars Sinai 7 3 Arsenic 1.47e-04 7.37e+011 Jordan 3 2 Arsenic 1.42e-04 7.09e+011 Jordan 3 4 Arsenic 4.24e-05 2.12e+011 Jordan 3 6 Arsenic 2.67e-04 1.34e+021 Kaiser 4 2 Arsenic 1.66e-04 8.28e+011 Kaiser 4 3 Arsenic 4.18e-05 2.09e+011 Kaiser 4 4 Arsenic 4.18e-05 2.09e+011 Lenoir 5 1 Arsenic 2.20e-04 1.10e+021 Lenoir 5 2 Arsenic 2.94e-04 1.47e+021 Lenoir 5 3 Arsenic 2.20e-04 1.10e+021 Lenoir 5 4 Arsenic 1.47e-04 7.35e+011 Lenoir 5 5 Arsenic 2.94e-04 1.47e+021 Lenoir 5 6 Arsenic 2.94e-04 1.47e+021 Lenoir 5 7 Arsenic 1.47e-04 7.35e+011 Lenoir 5 8 Arsenic 2.20e-04 1.10e+021 Lenoir 5 9 Arsenic 2.94e-04 1.47e+021 Sanford 6 1 Arsenic 1.57e-04 7.83e+011 Sanford 6 2 Arsenic 4.41e-05 2.20e+011 Sanford 6 3 Arsenic 4.07e-03 2.03e+031 Sanford 6 4 Arsenic 1.10e-04 5.48e+01

1 Sanford 6 5 Arsenic 2.95e-03 1.48e+031 Sanford 6 6 Arsenic 2.43e-04 1.22e+021 Sanford 6 8 Arsenic 2.24e-04 1.12e+021 Sanford 6 9 Arsenic 1.73e-04 8.65e+011 Sanford 6 10 Arsenic 2.45e-04 1.22e+021 St. Bernardine's 1 1 Arsenic 3.82e-05 1.91e+011 St. Bernardine's 1 2 Arsenic 4.29e-05 2.15e+011 St. Bernardine's 1 3 Arsenic 3.60e-05 1.80e+011 St.Agnes 8 1 Arsenic 2.15e-04 1.07e+021 St.Agnes 8 2 Arsenic 7.41e-05 3.70e+011 St.Agnes 8 3 Arsenic 7.15e-05 3.58e+011 USC 11 1 Arsenic 4.00e-05 2.00e+011 USC 11 2 Arsenic 9.21e-05 4.61e+011 USC 11 4 Arsenic 3.24e-05 1.62e+011 Cape Fear 2 1 Barium 6.40e-03 3.20e+031 Cape Fear 2 2 Barium 7.30e-03 3.65e+031 Cape Fear 2 3 Barium 3.56e-03 1.78e+031 Cape Fear 2 4 Barium 1.68e-02 8.39e+031 Cape Fear 2 5 Barium 5.05e-03 2.53e+031 Cape Fear 2 6 Barium 2.35e-02 1.17e+041 Cape Fear 2 7 Barium 1.84e-02 9.20e+031 Cape Fear 2 8 Barium 8.00e-03 4.00e+031 Cape Fear 2 9 Barium 1.66e-02 8.32e+031 Jordan 3 2 Barium 7.96e-04 3.98e+021 Jordan 3 4 Barium 4.26e-03 2.13e+031 Jordan 3 6 Barium 2.03e-03 1.02e+031 Jubilee 12 1 Barium 8.24e-04 4.12e+021 Jubilee 12 2 Barium 1.97e-04 9.83e+01

1 Lenoir 5 1 Barium 2.65e-03 1.32e+031 Lenoir 5 2 Barium 3.75e-03 1.87e+031 Lenoir 5 3 Barium 1.32e-03 6.62e+021 Lenoir 5 4 Barium 1.76e-03 8.82e+021 Lenoir 5 5 Barium 3.75e-03 1.87e+031 Lenoir 5 6 Barium 2.65e-03 1.32e+031 Lenoir 5 7 Barium 3.38e-03 1.69e+031 Lenoir 5 8 Barium 2.35e-03 1.18e+031 Lenoir 5 9 Barium 1.62e-03 8.09e+021 Sanford 6 1 Barium 8.59e-04 4.30e+021 Sanford 6 2 Barium 1.60e-03 7.98e+021 Sanford 6 3 Barium 5.25e-04 2.62e+021 Sanford 6 4 Barium 1.41e-03 7.06e+021 Sanford 6 5 Barium 3.91e-04 1.96e+021 Sanford 6 6 Barium 6.43e-04 3.22e+021 Sanford 6 8 Barium 5.82e-04 2.91e+021 Sanford 6 9 Barium 0.00e+00 0.00e+001 Sanford 6 10 Barium 1.29e-03 6.44e+021 Cape Fear 2 1 Beryllium 3.04e-06 1.52e+001 Cape Fear 2 2 Beryllium 2.64e-06 1.32e+001 Cape Fear 2 3 Beryllium 2.30e-06 1.15e+001 Cape Fear 2 4 Beryllium 2.51e-06 1.25e+001 Cape Fear 2 5 Beryllium 2.08e-06 1.04e+001 Cape Fear 2 6 Beryllium 1.48e-05 7.42e+001 Cape Fear 2 7 Beryllium 1.66e-06 8.29e-011 Cape Fear 2 8 Beryllium 2.28e-06 1.14e+001 Cape Fear 2 9 Beryllium 1.46e-06 7.28e-011 Jordan 3 2 Beryllium 7.60e-06 3.80e+00

1 Jordan 3 4 Beryllium 7.83e-06 3.91e+001 Jordan 3 6 Beryllium 7.45e-06 3.72e+001 Lenoir 5 1 Beryllium 1.47e-06 7.35e-011 Lenoir 5 2 Beryllium 2.94e-06 1.47e+001 Lenoir 5 3 Beryllium 2.20e-06 1.10e+001 Lenoir 5 4 Beryllium 1.47e-06 7.35e-011 Lenoir 5 5 Beryllium 2.20e-06 1.10e+001 Lenoir 5 6 Beryllium 2.20e-06 1.10e+001 Lenoir 5 7 Beryllium 1.47e-06 7.35e-011 Lenoir 5 8 Beryllium 2.94e-06 1.47e+001 Lenoir 5 9 Beryllium 1.47e-06 7.35e-011 Sanford 6 1 Beryllium 3.74e-06 1.87e+001 Sanford 6 2 Beryllium 4.41e-06 2.20e+001 Sanford 6 3 Beryllium 2.62e-06 1.31e+001 Sanford 6 4 Beryllium 2.71e-06 1.35e+001 Sanford 6 5 Beryllium 2.61e-06 1.30e+001 Sanford 6 6 Beryllium 2.74e-05 1.37e+011 Sanford 6 8 Beryllium 4.16e-06 2.08e+001 Sanford 6 9 Beryllium 3.06e-06 1.53e+001 Sanford 6 10 Beryllium 2.88e-05 1.44e+011 Cape Fear 2 1 Cadmium 7.81e-03 3.90e+031 Cape Fear 2 2 Cadmium 1.35e-02 6.74e+031 Cape Fear 2 3 Cadmium 1.14e-02 5.72e+031 Cape Fear 2 4 Cadmium 1.25e-02 6.24e+031 Cape Fear 2 5 Cadmium 1.31e-02 6.54e+031 Cape Fear 2 6 Cadmium 1.24e-02 6.20e+031 Cape Fear 2 7 Cadmium 7.86e-03 3.93e+031 Cape Fear 2 8 Cadmium 1.25e-02 6.24e+03

1 Cape Fear 2 9 Cadmium 1.13e-02 5.64e+031 Cedars Sinai 7 1 Cadmium 6.80e-03 3.40e+031 Cedars Sinai 7 2 Cadmium 3.61e-03 1.81e+031 Cedars Sinai 7 3 Cadmium 2.90e-03 1.45e+031 Jordan 3 2 Cadmium 8.07e-03 4.04e+031 Jordan 3 4 Cadmium 7.02e-03 3.51e+031 Jordan 3 6 Cadmium 6.18e-03 3.09e+031 Jubilee 12 1 Cadmium 1.90e-03 9.51e+021 Jubilee 12 2 Cadmium 3.32e-03 1.66e+031 Kaiser 4 2 Cadmium 1.06e-02 5.31e+031 Kaiser 4 3 Cadmium 2.12e-03 1.06e+031 Kaiser 4 4 Cadmium 2.66e-03 1.33e+031 Lenoir 5 1 Cadmium 8.82e-03 4.41e+031 Lenoir 5 2 Cadmium 2.35e-03 1.18e+031 Lenoir 5 3 Cadmium 3.31e-03 1.65e+031 Lenoir 5 4 Cadmium 6.61e-03 3.31e+031 Lenoir 5 5 Cadmium 6.03e-03 3.01e+031 Lenoir 5 6 Cadmium 3.09e-03 1.54e+031 Lenoir 5 7 Cadmium 4.63e-03 2.31e+031 Lenoir 5 8 Cadmium 2.06e-03 1.03e+031 Lenoir 5 9 Cadmium 1.32e-02 6.59e+031 Sanford 6 1 Cadmium 0.00e+00 0.00e+001 Sanford 6 2 Cadmium 8.12e-04 4.06e+021 Sanford 6 3 Cadmium 3.94e-04 1.97e+021 Sanford 6 4 Cadmium 2.09e-04 1.04e+021 Sanford 6 5 Cadmium 8.07e-04 4.03e+021 Sanford 6 6 Cadmium 1.15e-03 5.75e+021 Sanford 6 8 Cadmium 4.59e-04 2.30e+02

1 Sanford 6 9 Cadmium 4.16e-04 2.08e+021 Sanford 6 10 Cadmium 1.08e-03 5.42e+021 St. Bernardine's 1 1 Cadmium 9.44e-04 4.72e+021 St. Bernardine's 1 2 Cadmium 1.03e-03 5.15e+021 St. Bernardine's 1 3 Cadmium 1.60e-03 8.00e+021 St.Agnes 8 1 Cadmium 4.09e-03 2.04e+031 St.Agnes 8 2 Cadmium 3.00e-03 1.50e+031 St.Agnes 8 3 Cadmium 2.48e-03 1.24e+031 Sutter 9 1 Cadmium 3.62e-03 1.81e+031 Sutter 9 2 Cadmium 3.71e-03 1.86e+031 USC 11 1 Cadmium 7.38e-03 3.69e+031 USC 11 2 Cadmium 6.39e-03 3.19e+031 USC 11 4 Cadmium 1.84e-03 9.21e+021 Cape Fear 2 1 Chromium 4.37e-04 2.18e+021 Cape Fear 2 2 Chromium 6.08e-04 3.04e+021 Cape Fear 2 3 Chromium 1.83e-03 9.14e+021 Cape Fear 2 4 Chromium 1.04e-03 5.20e+021 Cape Fear 2 5 Chromium 4.45e-04 2.23e+021 Cape Fear 2 6 Chromium 1.25e-03 6.26e+021 Cape Fear 2 7 Chromium 6.89e-04 3.44e+021 Cape Fear 2 8 Chromium 1.06e-03 5.28e+021 Cape Fear 2 9 Chromium 9.95e-04 4.97e+021 Cedars Sinai 7 1 Chromium 3.63e-04 1.82e+021 Cedars Sinai 7 2 Chromium 1.02e-04 5.10e+011 Cedars Sinai 7 3 Chromium 1.29e-04 6.43e+011 Jordan 3 2 Chromium 1.84e-03 9.20e+021 Jordan 3 4 Chromium 1.12e-03 5.59e+021 Jordan 3 6 Chromium 1.14e-03 5.69e+02

1 Jubilee 12 1 Chromium 1.25e-03 6.25e+021 Jubilee 12 2 Chromium 1.95e-03 9.77e+021 Kaiser 4 2 Chromium 3.94e-04 1.97e+021 Kaiser 4 3 Chromium 3.85e-04 1.93e+021 Kaiser 4 4 Chromium 4.89e-04 2.44e+021 Lenoir 5 1 Chromium 1.10e-03 5.49e+021 Lenoir 5 2 Chromium 5.88e-04 2.94e+021 Lenoir 5 3 Chromium 2.94e-04 1.47e+021 Lenoir 5 4 Chromium 6.61e-04 3.30e+021 Lenoir 5 5 Chromium 4.41e-04 2.21e+021 Lenoir 5 6 Chromium 6.61e-04 3.30e+021 Lenoir 5 7 Chromium 5.88e-04 2.94e+021 Lenoir 5 8 Chromium 5.88e-04 2.94e+021 Lenoir 5 9 Chromium 1.76e-03 8.82e+021 Sanford 6 1 Chromium 6.49e-04 3.25e+021 Sanford 6 2 Chromium 4.99e-04 2.49e+021 Sanford 6 3 Chromium 6.03e-04 3.01e+021 Sanford 6 4 Chromium 1.08e-03 5.42e+021 Sanford 6 5 Chromium 4.16e-04 2.08e+021 Sanford 6 6 Chromium 9.00e-03 4.50e+031 Sanford 6 8 Chromium 6.00e-04 3.00e+021 Sanford 6 9 Chromium 4.41e-05 2.20e+011 Sanford 6 10 Chromium 5.76e-04 2.88e+021 St. Bernardine's 1 1 Chromium 2.75e-04 1.37e+021 St. Bernardine's 1 2 Chromium 2.79e-04 1.39e+021 St. Bernardine's 1 3 Chromium 1.60e-03 8.00e+021 St.Agnes 8 1 Chromium 5.11e-04 2.55e+021 St.Agnes 8 2 Chromium 2.89e-04 1.44e+02

1 St.Agnes 8 3 Chromium 6.08e-04 3.04e+021 Sutter 9 1 Chromium 3.96e-04 1.98e+021 Sutter 9 2 Chromium 6.29e-04 3.14e+021 USC 11 1 Chromium 3.38e-04 1.69e+021 USC 11 2 Chromium 5.15e-04 2.58e+021 USC 11 4 Chromium 2.84e-04 1.42e+021 Cedars Sinai 7 1 Iron 5.20e-03 2.60e+031 Cedars Sinai 7 2 Iron 7.27e-03 3.63e+031 Cedars Sinai 7 3 Iron 4.12e-03 2.06e+031 Jubilee 12 1 Iron 2.24e-02 1.12e+041 Jubilee 12 2 Iron 1.80e-02 9.02e+031 Kaiser 4 2 Iron 1.43e-02 7.14e+031 Kaiser 4 3 Iron 9.07e-03 4.53e+031 Kaiser 4 4 Iron 1.23e-02 6.15e+031 St. Bernardine's 1 1 Iron 2.49e-03 1.24e+031 St. Bernardine's 1 2 Iron 2.27e-03 1.14e+031 St. Bernardine's 1 3 Iron 3.66e-03 1.83e+031 St.Agnes 8 1 Iron 1.02e-02 5.08e+031 St.Agnes 8 2 Iron 3.98e-03 1.99e+031 St.Agnes 8 3 Iron 8.40e-03 4.20e+031 Sutter 9 1 Iron 8.24e-03 4.12e+031 Sutter 9 2 Iron 5.75e-02 2.87e+041 USC 11 1 Iron 3.03e-02 1.52e+041 USC 11 2 Iron 2.13e-02 1.06e+041 USC 11 4 Iron 9.19e-03 4.59e+031 Cape Fear 2 1 Lead 7.38e-02 3.69e+041 Cape Fear 2 2 Lead 1.08e-01 5.41e+041 Cape Fear 2 3 Lead 1.68e-01 8.41e+04

1 Cape Fear 2 4 Lead 1.63e-01 8.16e+041 Cape Fear 2 5 Lead 2.56e-01 1.28e+051 Cape Fear 2 6 Lead 2.03e-01 1.02e+051 Cape Fear 2 7 Lead 1.83e-01 9.13e+041 Cape Fear 2 8 Lead 2.14e-01 1.07e+051 Cape Fear 2 9 Lead 7.86e-02 3.93e+041 Cedars Sinai 7 1 Lead 5.80e-02 2.90e+041 Cedars Sinai 7 2 Lead 4.18e-02 2.09e+041 Cedars Sinai 7 3 Lead 3.04e-02 1.52e+041 Jordan 3 2 Lead 2.31e-01 1.15e+051 Jordan 3 4 Lead 1.48e-01 7.42e+041 Jordan 3 6 Lead 1.96e-01 9.80e+041 Jubilee 12 1 Lead 4.90e-02 2.45e+041 Jubilee 12 2 Lead 4.34e-02 2.17e+041 Kaiser 4 2 Lead 1.04e-01 5.19e+041 Kaiser 4 3 Lead 5.88e-02 2.94e+041 Kaiser 4 4 Lead 5.63e-02 2.82e+041 Lenoir 5 1 Lead 4.54e-02 2.26e+041 Lenoir 5 2 Lead 3.51e-02 1.76e+041 Lenoir 5 3 Lead 3.67e-02 1.84e+041 Lenoir 5 4 Lead 2.75e-02 1.38e+041 Lenoir 5 5 Lead 1.46e-01 7.27e+041 Lenoir 5 6 Lead 4.10e-02 2.04e+041 Lenoir 5 7 Lead 5.32e-02 2.66e+041 Lenoir 5 8 Lead 4.16e-02 2.08e+041 Lenoir 5 9 Lead 2.67e-02 1.34e+041 Sanford 6 1 Lead 5.40e-03 2.70e+031 Sanford 6 2 Lead 6.98e-03 3.49e+03

1 Sanford 6 3 Lead 3.58e-03 1.79e+031 Sanford 6 4 Lead 0.00e+00 0.00e+001 Sanford 6 5 Lead 3.51e-02 1.75e+041 Sanford 6 6 Lead 2.27e-02 1.13e+041 Sanford 6 8 Lead 1.51e-02 7.55e+031 Sanford 6 9 Lead 1.28e-02 6.41e+031 Sanford 6 10 Lead 3.54e-02 1.77e+041 St. Bernardine's 1 1 Lead 1.12e-02 5.58e+031 St. Bernardine's 1 2 Lead 1.12e-02 5.58e+031 St. Bernardine's 1 3 Lead 2.29e-02 1.14e+041 St.Agnes 8 1 Lead 5.59e-02 2.80e+041 St.Agnes 8 2 Lead 3.10e-02 1.55e+041 St.Agnes 8 3 Lead 4.31e-02 2.16e+041 Sutter 9 1 Lead 3.42e-02 1.71e+041 Sutter 9 2 Lead 6.67e-02 3.33e+041 USC 11 1 Lead 2.40e-01 1.20e+051 USC 11 2 Lead 1.71e-01 8.54e+041 USC 11 4 Lead 6.35e-02 3.17e+041 Cedars Sinai 7 1 Manganese 4.37e-04 2.18e+021 Cedars Sinai 7 2 Manganese 4.37e-04 2.18e+021 Cedars Sinai 7 3 Manganese 3.29e-04 1.64e+021 Jubilee 12 1 Manganese 1.40e-03 6.99e+021 Jubilee 12 2 Manganese 7.80e-04 3.90e+021 Kaiser 4 2 Manganese 7.26e-04 3.63e+021 Kaiser 4 3 Manganese 8.12e-04 4.06e+021 Kaiser 4 4 Manganese 5.84e-04 2.92e+021 St. Bernardine's 1 1 Manganese 1.59e-04 7.94e+011 St. Bernardine's 1 2 Manganese 1.42e-04 7.08e+01

1 St. Bernardine's 1 3 Manganese 2.11e-04 1.06e+021 St.Agnes 8 1 Manganese 3.93e-04 1.97e+021 St.Agnes 8 2 Manganese 1.58e-04 7.92e+011 St.Agnes 8 3 Manganese 2.76e-04 1.38e+021 Sutter 9 1 Manganese 4.34e-04 2.17e+021 Sutter 9 2 Manganese 1.38e-03 6.91e+021 USC 11 1 Manganese 5.26e-04 2.63e+021 USC 11 2 Manganese 4.74e-04 2.37e+021 USC 11 4 Manganese 2.56e-04 1.28e+021 Cape Fear 2 1 Mercury 1.99e-02 9.96e+031 Cape Fear 2 2 Mercury 1.16e-03 5.80e+021 Cape Fear 2 3 Mercury 1.10e-02 5.51e+031 Cape Fear 2 4 Mercury 4.80e-03 2.40e+031 Cape Fear 2 5 Mercury 8.44e-03 4.22e+031 Cape Fear 2 6 Mercury 2.30e-02 1.15e+041 Cape Fear 2 7 Mercury 2.37e-02 1.19e+041 Cape Fear 2 8 Mercury 5.51e-03 2.76e+031 Cape Fear 2 9 Mercury 1.12e-01 5.60e+041 Jordan 3 2 Mercury 5.45e-02 2.72e+041 Jordan 3 4 Mercury 3.35e-01 1.67e+051 Jordan 3 6 Mercury 3.50e-02 1.75e+041 Jubilee 12 1 Mercury 2.69e-05 1.34e+011 Jubilee 12 2 Mercury 2.49e-05 1.24e+011 Kaiser 4 1 Mercury 2.74e-02 1.37e+041 Kaiser 4 2 Mercury 6.68e-02 3.34e+041 Kaiser 4 3 Mercury 8.20e-04 4.10e+021 Lenoir 5 1 Mercury 2.65e-03 1.32e+031 Lenoir 5 2 Mercury 1.98e-03 9.89e+02

1 Lenoir 5 3 Mercury 5.95e-03 2.97e+031 Lenoir 5 4 Mercury 1.03e-03 5.15e+021 Lenoir 5 5 Mercury 9.07e-02 4.54e+041 Lenoir 5 6 Mercury 2.06e-03 1.03e+031 Lenoir 5 7 Mercury 2.79e-03 1.40e+031 Lenoir 5 8 Mercury 3.23e-03 1.62e+031 Lenoir 5 9 Mercury 4.41e-03 2.20e+031 Sanford 6 1 Mercury 0.00e+00 0.00e+001 Sanford 6 2 Mercury 1.05e-05 5.25e+001 Sanford 6 3 Mercury 2.87e-03 1.43e+031 Sanford 6 4 Mercury 1.10e-05 5.48e+001 Sanford 6 5 Mercury 8.65e-05 4.32e+011 Sanford 6 6 Mercury 1.22e-05 6.12e+001 Sanford 6 8 Mercury 3.00e-03 1.50e+031 Sanford 6 9 Mercury 1.62e-04 8.12e+011 Sanford 6 10 Mercury 1.25e-04 6.24e+011 St. Bernardine's 1 1 Mercury 1.40e-02 7.01e+031 St. Bernardine's 1 2 Mercury 1.40e-02 6.99e+031 St. Bernardine's 1 3 Mercury 2.04e-02 1.02e+041 USC 11 1 Mercury 1.83e+00 9.14e+051 USC 11 2 Mercury 5.16e-02 2.58e+041 USC 11 3 Mercury 1.98e-02 9.92e+031 Cape Fear 2 1 Nickel 1.46e-04 7.28e+011 Cape Fear 2 2 Nickel 2.30e-04 1.15e+021 Cape Fear 2 3 Nickel 1.66e-04 8.29e+011 Cape Fear 2 4 Nickel 2.51e-04 1.25e+021 Cape Fear 2 5 Nickel 1.48e-04 7.42e+011 Cape Fear 2 6 Nickel 1.52e-04 7.60e+01

1 Cape Fear 2 7 Nickel 1.14e-03 5.71e+021 Cape Fear 2 8 Nickel 2.64e-04 1.32e+021 Cape Fear 2 9 Nickel 2.08e-04 1.04e+021 Cedars Sinai 7 1 Nickel 1.08e-04 5.42e+011 Cedars Sinai 7 2 Nickel 1.11e-04 5.54e+011 Cedars Sinai 7 3 Nickel 1.12e-04 5.58e+011 Jordan 3 2 Nickel 4.91e-04 2.46e+021 Jordan 3 4 Nickel 1.12e-03 5.59e+021 Jordan 3 6 Nickel 1.16e-03 5.80e+021 Jubilee 12 1 Nickel 4.47e-04 2.24e+021 Jubilee 12 2 Nickel 5.04e-04 2.52e+021 Kaiser 4 2 Nickel 2.48e-04 1.24e+021 Kaiser 4 3 Nickel 3.31e-04 1.66e+021 Kaiser 4 4 Nickel 3.06e-04 1.53e+021 Lenoir 5 1 Nickel 2.94e-04 1.47e+021 Lenoir 5 2 Nickel 4.41e-04 2.21e+021 Lenoir 5 3 Nickel 5.14e-04 2.57e+021 Lenoir 5 4 Nickel 1.62e-03 8.09e+021 Lenoir 5 5 Nickel 2.20e-04 1.10e+021 Lenoir 5 6 Nickel 2.94e-04 1.47e+021 Lenoir 5 7 Nickel 2.79e-04 1.40e+021 Lenoir 5 8 Nickel 4.41e-04 2.20e+021 Lenoir 5 9 Nickel 6.61e-04 3.30e+021 Sanford 6 1 Nickel 1.47e-03 7.35e+021 Sanford 6 2 Nickel 4.16e-05 2.08e+011 Sanford 6 3 Nickel 1.39e-02 6.95e+031 Sanford 6 4 Nickel 8.49e-04 4.24e+021 Sanford 6 5 Nickel 5.22e-04 2.61e+02

1 Sanford 6 6 Nickel 4.41e-05 2.20e+011 Sanford 6 8 Nickel 2.16e-04 1.08e+021 Sanford 6 9 Nickel 2.31e-04 1.15e+021 Sanford 6 10 Nickel 5.23e-04 2.62e+021 St. Bernardine's 1 1 Nickel 4.12e-04 2.06e+021 St. Bernardine's 1 2 Nickel 4.20e-04 2.10e+021 St. Bernardine's 1 3 Nickel 5.43e-04 2.72e+021 St.Agnes 8 1 Nickel 2.76e-04 1.38e+021 St.Agnes 8 2 Nickel 1.58e-04 7.92e+011 St.Agnes 8 3 Nickel 2.81e-04 1.40e+021 Sutter 9 1 Nickel 4.95e-04 2.47e+021 Sutter 9 2 Nickel 4.30e-04 2.15e+021 USC 11 1 Nickel 3.57e-04 1.79e+021 USC 11 2 Nickel 6.24e-04 3.12e+021 USC 11 4 Nickel 4.27e-04 2.13e+021 Cape Fear 2 1 Silver 7.92e-04 3.96e+021 Cape Fear 2 2 Silver 3.32e-04 1.66e+021 Cape Fear 2 3 Silver 6.24e-04 3.12e+021 Cape Fear 2 4 Silver 2.51e-04 1.25e+021 Cape Fear 2 5 Silver 3.04e-04 1.52e+021 Cape Fear 2 6 Silver 4.57e-04 2.28e+021 Cape Fear 2 7 Silver 9.19e-04 4.59e+021 Cape Fear 2 8 Silver 1.46e-04 7.28e+011 Cape Fear 2 9 Silver 1.48e-04 7.42e+011 Jordan 3 2 Silver 8.74e-05 4.37e+011 Jordan 3 4 Silver 1.68e-04 8.39e+011 Jordan 3 6 Silver 2.77e-04 1.39e+021 Jubilee 12 1 Silver 3.56e-04 1.78e+02

1 Jubilee 12 2 Silver 2.60e-04 1.30e+021 Lenoir 5 1 Silver 4.41e-04 2.20e+021 Lenoir 5 2 Silver 2.94e-05 1.47e+011 Lenoir 5 3 Silver 4.41e-05 2.20e+011 Lenoir 5 4 Silver 2.94e-05 1.47e+011 Lenoir 5 5 Silver 2.94e-04 1.47e+021 Lenoir 5 6 Silver 4.41e-05 2.21e+011 Lenoir 5 7 Silver 1.47e-04 7.35e+011 Lenoir 5 8 Silver 4.41e-05 2.21e+011 Lenoir 5 9 Silver 4.41e-04 2.20e+021 Sanford 6 1 Silver 5.25e-05 2.62e+011 Sanford 6 2 Silver 7.47e-05 3.74e+011 Sanford 6 3 Silver 8.32e-05 4.16e+011 Sanford 6 4 Silver 5.22e-05 2.61e+011 Sanford 6 5 Silver 1.73e-04 8.65e+011 Sanford 6 6 Silver 8.82e-05 4.41e+011 Sanford 6 8 Silver 6.12e-05 3.06e+011 Sanford 6 9 Silver 2.71e-04 1.35e+021 Sanford 6 10 Silver 5.48e-05 2.74e+011 Cape Fear 2 1 Thallium 3.12e-03 1.56e+031 Cape Fear 2 2 Thallium 4.59e-03 2.30e+031 Cape Fear 2 3 Thallium 4.41e-03 2.20e+031 Cape Fear 2 4 Thallium 1.05e-02 5.27e+031 Cape Fear 2 5 Thallium 4.48e-03 2.24e+031 Cape Fear 2 6 Thallium 3.01e-03 1.50e+031 Cape Fear 2 7 Thallium 3.43e-03 1.72e+031 Cape Fear 2 8 Thallium 5.24e-03 2.62e+031 Cape Fear 2 9 Thallium 5.48e-03 2.74e+03

1 Jordan 3 2 Thallium 7.60e-05 3.80e+011 Jordan 3 4 Thallium 7.83e-05 3.91e+011 Jordan 3 6 Thallium 7.45e-05 3.72e+011 Lenoir 5 1 Thallium 6.61e-05 3.30e+011 Lenoir 5 2 Thallium 6.61e-05 3.30e+011 Lenoir 5 3 Thallium 4.41e-05 2.21e+011 Lenoir 5 4 Thallium 7.35e-05 3.68e+011 Lenoir 5 5 Thallium 4.41e-05 2.21e+011 Lenoir 5 6 Thallium 6.61e-05 3.30e+011 Lenoir 5 7 Thallium 7.35e-05 3.68e+011 Lenoir 5 8 Thallium 4.41e-05 2.21e+011 Lenoir 5 9 Thallium 4.41e-05 2.21e+011 Sanford 6 1 Thallium 1.32e-04 6.61e+011 Sanford 6 2 Thallium 1.12e-04 5.60e+011 Sanford 6 3 Thallium 8.65e-05 4.32e+011 Sanford 6 4 Thallium 8.22e-05 4.11e+011 Sanford 6 5 Thallium 7.83e-05 3.91e+011 Sanford 6 6 Thallium 1.66e-04 8.32e+011 Sanford 6 8 Thallium 7.87e-05 3.94e+011 Sanford 6 9 Thallium 8.12e-05 4.06e+011 Sanford 6 10 Thallium 9.19e-05 4.59e+011 USC 11 1 PM .625 4.12e-02 2.06e+041 USC 11 2 PM .625 5.82e-03 2.91e+031 USC 11 3 PM .625 1.23e-02 6.16e+031 Sanford 6 5 PM .625 5.94e+00 2.97e+061 Sanford 6 6 PM .625 7.11e+00 3.55e+061 USC 11 1 PM 1.0 1.09e-01 5.44e+041 USC 11 2 PM 1.0 1.46e-02 7.28e+03

1 USC 11 3 PM 1.0 4.07e-02 2.04e+041 Sanford 6 5 PM 1.0 9.89e+00 4.94e+061 Sanford 6 6 PM 1.0 1.08e+01 5.39e+061 USC 11 1 PM 2.5 1.31e+00 6.53e+051 USC 11 2 PM 2.5 1.15e-01 5.76e+041 USC 11 3 PM 2.5 6.81e-01 3.40e+051 Sanford 6 5 PM 2.5 1.49e+01 7.44e+061 Sanford 6 6 PM 2.5 1.77e+01 8.83e+061 USC 11 1 PM 5.0 4.03e+00 2.01e+061 USC 11 2 PM 5.0 3.52e-01 1.76e+051 USC 11 3 PM 5.0 1.28e+00 6.39e+051 Sanford 6 5 PM 5.0 2.11e+01 1.05e+071 Sanford 6 6 PM 5.0 2.31e+01 1.15e+071 USC 11 1 PM 10.0 9.22e+00 4.61e+061 USC 11 2 PM 10.0 8.31e-01 4.16e+051 USC 11 3 PM 10.0 1.87e+00 9.33e+051 Sanford 6 5 PM 10.0 2.77e+01 1.39e+071 Sanford 6 6 PM 10.0 2.95e+01 1.48e+071 Cape Fear 2 1 Particulate Matter 3.61e+00 1.81e+061 Cape Fear 2 2 Particulate Matter 1.71e+01 8.57e+061 Cape Fear 2 3 Particulate Matter 6.17e+00 3.08e+061 Cape Fear 2 4 Particulate Matter 9.39e+00 4.70e+061 Cape Fear 2 5 Particulate Matter 8.17e+00 4.08e+061 Cape Fear 2 6 Particulate Matter 9.84e+00 4.92e+061 Cape Fear 2 7 Particulate Matter 1.08e+01 5.41e+061 Cape Fear 2 8 Particulate Matter 1.43e+01 7.15e+061 Cape Fear 2 9 Particulate Matter 8.68e+00 4.34e+061 Cedars Sinai 7 1 Particulate Matter 3.53e+00 1.77e+06

1 Cedars Sinai 7 2 Particulate Matter 2.59e+00 1.30e+061 Cedars Sinai 7 3 Particulate Matter 1.41e+00 7.04e+051 Jordan 3 2 Particulate Matter 1.90e+00 9.51e+051 Jordan 3 4 Particulate Matter 1.55e+00 7.75e+051 Jordan 3 6 Particulate Matter 2.69e+00 1.35e+061 Jubilee 12 1 Particulate Matter 1.68e+00 8.40e+051 Jubilee 12 2 Particulate Matter 1.82e+00 9.10e+051 Kaiser 4 1 Particulate Matter 8.59e+00 4.29e+061 Kaiser 4 2 Particulate Matter 4.14e+00 2.07e+061 Kaiser 4 3 Particulate Matter 8.70e+00 4.35e+061 Lenoir 5 1 Particulate Matter 1.39e+01 6.96e+061 Lenoir 5 2 Particulate Matter 8.02e+00 4.00e+061 Lenoir 5 3 Particulate Matter 7.19e+00 3.58e+061 Lenoir 5 4 Particulate Matter 4.54e+00 2.27e+061 Lenoir 5 5 Particulate Matter 1.54e+01 7.73e+061 Lenoir 5 6 Particulate Matter 6.00e+00 3.00e+061 Lenoir 5 7 Particulate Matter 6.27e+00 3.13e+061 Lenoir 5 8 Particulate Matter 1.50e+01 7.49e+061 Lenoir 5 9 Particulate Matter 8.65e+00 4.33e+061 Sanford 6 1 Particulate Matter 1.86e+00 9.32e+051 Sanford 6 2 Particulate Matter 3.99e+01 2.00e+071 Sanford 6 3 Particulate Matter 1.44e+00 7.22e+051 Sanford 6 4 Particulate Matter 6.15e+00 3.07e+061 Sanford 6 5 Particulate Matter 2.34e+00 1.17e+061 Sanford 6 6 Particulate Matter 2.38e+00 1.19e+061 Sanford 6 8 Particulate Matter 2.49e+00 1.24e+061 Sanford 6 9 Particulate Matter 9.48e+00 4.74e+061 Sanford 6 10 Particulate Matter 1.96e+00 9.82e+05

1 St. Bernardine's 1 1 Particulate Matter 5.15e+00 2.57e+061 St. Bernardine's 1 2 Particulate Matter 4.72e+00 2.36e+061 St. Bernardine's 1 3 Particulate Matter 7.43e+00 3.72e+061 St.Agnes 8 1 Particulate Matter 4.90e+00 2.45e+061 St.Agnes 8 2 Particulate Matter 4.64e+00 2.32e+061 St.Agnes 8 3 Particulate Matter 4.87e+00 2.44e+061 Sutter 9 1 Particulate Matter 5.91e+00 2.95e+061 Sutter 9 2 Particulate Matter 7.48e+00 3.74e+061 Swedish 10 1 Particulate Matter 5.83e+00 2.91e+061 Swedish 10 3 Particulate Matter 4.00e+00 2.00e+061 Swedish-American 10 2 Particulate Matter 1.51e+00 7.56e+051 USC 11 1 Particulate Matter 2.32e+01 1.16e+071 USC 11 2 Particulate Matter 5.82e+00 2.91e+061 USC 11 3 Particulate Matter 4.74e+00 2.37e+061 Cape Fear 2 1 Carbon Monoxide 5.93e+00 2.96e+061 Cape Fear 2 2 Carbon Monoxide 1.07e+00 5.35e+051 Cape Fear 2 3 Carbon Monoxide 2.21e+01 1.11e+071 Cape Fear 2 4 Carbon Monoxide 1.25e+01 6.25e+061 Cape Fear 2 5 Carbon Monoxide 1.42e+01 7.10e+061 Cape Fear 2 6 Carbon Monoxide 1.64e+01 8.18e+061 Cape Fear 2 7 Carbon Monoxide 3.62e+00 1.81e+061 Cape Fear 2 8 Carbon Monoxide 2.59e+01 1.30e+071 Cape Fear 2 9 Carbon Monoxide 1.36e+01 6.79e+061 Jordan 3 2 Carbon Monoxide 8.47e-01 4.23e+051 Jordan 3 4 Carbon Monoxide 5.78e-01 2.89e+051 Jordan 3 6 Carbon Monoxide 1.87e+00 9.33e+051 Kaiser 4 1 Carbon Monoxide 1.43e+00 7.13e+051 Kaiser 4 2 Carbon Monoxide 1.43e+00 7.13e+05

1 Kaiser 4 3 Carbon Monoxide 1.43e+00 7.13e+051 Kaiser 4 4 Carbon Monoxide 1.07e+00 5.37e+051 Kaiser 4 5 Carbon Monoxide 5.34e+01 2.67e+071 Kaiser 4 6 Carbon Monoxide 1.94e-01 9.71e+041 Kaiser 4 7 Carbon Monoxide 1.94e-01 9.71e+041 Kaiser 4 8 Carbon Monoxide 2.07e-01 1.04e+051 Lenoir 5 1 Carbon Monoxide 2.54e+00 1.27e+061 Lenoir 5 2 Carbon Monoxide 5.30e+01 2.65e+071 Lenoir 5 3 Carbon Monoxide 1.93e+00 9.61e+051 Lenoir 5 4 Carbon Monoxide 4.37e+01 2.19e+071 Lenoir 5 5 Carbon Monoxide 5.77e+00 2.89e+061 Lenoir 5 6 Carbon Monoxide 1.60e+01 8.00e+061 Lenoir 5 7 Carbon Monoxide 4.80e+00 2.40e+061 Lenoir 5 8 Carbon Monoxide 1.07e+00 5.35e+051 Lenoir 5 9 Carbon Monoxide 3.29e+00 1.64e+061 Sanford 6 1 Carbon Monoxide 6.08e+00 3.04e+061 Sanford 6 2 Carbon Monoxide 3.61e+00 1.80e+061 Sanford 6 3 Carbon Monoxide 9.34e+00 4.67e+061 Sanford 6 4 Carbon Monoxide 2.35e+00 1.17e+061 Sanford 6 5 Carbon Monoxide 3.30e+00 1.65e+061 Sanford 6 6 Carbon Monoxide 1.88e+00 9.39e+051 Sanford 6 8 Carbon Monoxide 1.86e+00 9.31e+051 Sanford 6 9 Carbon Monoxide 9.34e-01 4.67e+051 Sanford 6 10 Carbon Monoxide 6.26e+01 3.13e+071 St. Bernardine's 1 4 Carbon Monoxide 3.71e-01 1.85e+051 St.Agnes 8 1 Carbon Monoxide 1.62e+00 8.09e+051 St.Agnes 8 2 Carbon Monoxide 1.61e+00 8.07e+051 St.Agnes 8 3 Carbon Monoxide 1.61e+00 8.07e+05

1 St.Agnes 8 4 Carbon Monoxide 1.56e+00 7.78e+051 St.Agnes 8 5 Carbon Monoxide 1.53e+00 7.64e+051 St.Agnes 8 6 Carbon Monoxide 1.53e+00 7.64e+051 St.Agnes 8 7 Carbon Monoxide 1.53e+00 7.64e+051 St.Agnes 8 8 Carbon Monoxide 1.47e+00 7.36e+051 St.Agnes 8 9 Carbon Monoxide 1.37e+00 6.87e+051 Sutter 9 1 Carbon Monoxide 1.97e+00 9.86e+051 Sutter 9 2 Carbon Monoxide 2.78e+00 1.39e+061 Sutter 9 3 Carbon Monoxide 2.78e+00 1.39e+061 Sutter 9 4 Carbon Monoxide 3.41e+00 1.71e+061 Swedish 10 1 Carbon Monoxide 2.82e-01 1.41e+051 Cape Fear 2 1 Oxides of Nitrogen 6.21e+00 3.10e+061 Cape Fear 2 2 Oxides of Nitrogen 5.10e+00 2.55e+061 Cape Fear 2 3 Oxides of Nitrogen 3.60e+00 1.80e+061 Cape Fear 2 4 Oxides of Nitrogen 4.70e+00 2.35e+061 Cape Fear 2 5 Oxides of Nitrogen 5.33e+00 2.67e+061 Cape Fear 2 6 Oxides of Nitrogen 3.47e+00 1.73e+061 Cape Fear 2 7 Oxides of Nitrogen 4.93e+00 2.47e+061 Cape Fear 2 8 Oxides of Nitrogen 4.32e+00 2.16e+061 Cape Fear 2 9 Oxides of Nitrogen 2.94e+00 1.47e+061 Jordan 3 2 Oxides of Nitrogen 1.85e+01 9.26e+061 Jordan 3 4 Oxides of Nitrogen 1.14e+01 5.71e+061 Jordan 3 6 Oxides of Nitrogen 1.08e+01 5.41e+061 Kaiser 4 1 Oxides of Nitrogen 1.70e+00 8.50e+051 Kaiser 4 2 Oxides of Nitrogen 1.65e+00 8.26e+051 Kaiser 4 3 Oxides of Nitrogen 2.14e+00 1.07e+061 Kaiser 4 4 Oxides of Nitrogen 2.14e+00 1.07e+061 Kaiser 4 5 Oxides of Nitrogen 2.41e+00 1.21e+06

1 Kaiser 4 6 Oxides of Nitrogen 2.20e+00 1.10e+061 Kaiser 4 7 Oxides of Nitrogen 2.02e+00 1.01e+061 Kaiser 4 8 Oxides of Nitrogen 2.35e+00 1.17e+061 Lenoir 5 1 Oxides of Nitrogen 1.56e+00 7.82e+051 Lenoir 5 2 Oxides of Nitrogen 3.01e+00 1.50e+061 Lenoir 5 3 Oxides of Nitrogen 2.48e+00 1.24e+061 Lenoir 5 4 Oxides of Nitrogen 2.69e+00 1.34e+061 Lenoir 5 5 Oxides of Nitrogen 2.40e+00 1.20e+061 Lenoir 5 6 Oxides of Nitrogen 1.77e+00 8.88e+051 Lenoir 5 7 Oxides of Nitrogen 1.41e+00 7.07e+051 Lenoir 5 8 Oxides of Nitrogen 1.55e+00 7.77e+051 Lenoir 5 9 Oxides of Nitrogen 1.86e+00 9.30e+051 Sanford 6 1 Oxides of Nitrogen 3.36e+01 1.68e+071 Sanford 6 2 Oxides of Nitrogen 2.97e+01 1.49e+071 Sanford 6 3 Oxides of Nitrogen 4.38e+01 2.19e+071 Sanford 6 4 Oxides of Nitrogen 3.65e+01 1.82e+071 Sanford 6 5 Oxides of Nitrogen 3.94e+01 1.97e+071 Sanford 6 6 Oxides of Nitrogen 3.15e+01 1.57e+071 Sanford 6 8 Oxides of Nitrogen 1.57e+01 7.87e+061 Sanford 6 9 Oxides of Nitrogen 1.65e+01 8.26e+061 Sanford 6 10 Oxides of Nitrogen 1.24e+01 6.19e+061 St. Bernardine's 1 4 Oxides of Nitrogen 8.29e+00 4.15e+061 St.Agnes 8 9 Oxides of Nitrogen 1.80e+00 8.98e+051 Sutter 9 1 Oxides of Nitrogen 2.49e+00 1.25e+061 Sutter 9 2 Oxides of Nitrogen 4.04e+00 2.02e+061 Sutter 9 3 Oxides of Nitrogen 3.43e+00 1.71e+061 Sutter 9 4 Oxides of Nitrogen 4.38e+00 2.19e+061 USC 11 1 Oxides of Nitrogen 4.81e+00 2.40e+06

1 USC 11 2 Oxides of Nitrogen 4.26e+00 2.13e+061 USC 11 3 Oxides of Nitrogen 4.42e+00 2.21e+061 USC 11 4 Oxides of Nitrogen 3.81e+00 1.91e+061 USC 11 5 Oxides of Nitrogen 4.59e+00 2.29e+061 USC 11 6 Oxides of Nitrogen 4.15e+00 2.07e+061 USC 11 7 Oxides of Nitrogen 5.64e+00 2.82e+061 USC 11 8 Oxides of Nitrogen 4.42e+00 2.21e+061 USC 11 9 Oxides of Nitrogen 5.03e+00 2.52e+061 USC 11 10 Oxides of Nitrogen 1.11e+01 5.55e+061 USC 11 11 Oxides of Nitrogen 9.00e+00 4.50e+061 USC 11 12 Oxides of Nitrogen 9.00e+00 4.50e+061 USC 11 13 Oxides of Nitrogen 7.91e+00 3.96e+061 USC 11 14 Oxides of Nitrogen 6.80e+00 3.40e+061 USC 11 15 Oxides of Nitrogen 6.11e+00 3.05e+061 USC 11 16 Oxides of Nitrogen 6.11e+00 3.05e+061 USC 11 17 Oxides of Nitrogen 4.16e+00 2.08e+061 USC 11 18 Oxides of Nitrogen 5.62e+00 2.81e+061 USC 11 19 Oxides of Nitrogen 4.91e+00 2.46e+061 USC 11 20 Oxides of Nitrogen 6.55e+00 3.28e+061 Cape Fear 2 1 Sulfur Dioxide 9.71e-01 4.86e+051 Cape Fear 2 2 Sulfur Dioxide 2.91e+00 1.45e+061 Cape Fear 2 3 Sulfur Dioxide 1.94e+00 9.69e+051 Cape Fear 2 4 Sulfur Dioxide 2.21e+00 1.10e+061 Cape Fear 2 5 Sulfur Dioxide 2.34e+00 1.17e+061 Cape Fear 2 6 Sulfur Dioxide 3.39e+00 1.70e+061 Cape Fear 2 7 Sulfur Dioxide 1.83e+00 9.17e+051 Cape Fear 2 8 Sulfur Dioxide 8.14e-01 4.07e+051 Cape Fear 2 9 Sulfur Dioxide 1.68e+00 8.39e+05

1 Jordan 3 2 Sulfur Dioxide 4.83e+00 2.41e+061 Jordan 3 4 Sulfur Dioxide 3.22e+00 1.61e+061 Jordan 3 6 Sulfur Dioxide 3.69e+00 1.84e+061 Kaiser 4 1 Sulfur Dioxide 3.11e+00 1.55e+061 Kaiser 4 2 Sulfur Dioxide 2.38e+00 1.19e+061 Kaiser 4 3 Sulfur Dioxide 1.39e+00 6.97e+051 Kaiser 4 4 Sulfur Dioxide 5.37e-01 2.68e+051 Kaiser 4 5 Sulfur Dioxide 2.33e+00 1.16e+061 Kaiser 4 6 Sulfur Dioxide 2.10e+00 1.05e+061 Kaiser 4 7 Sulfur Dioxide 1.71e+00 8.54e+051 Kaiser 4 8 Sulfur Dioxide 2.24e+00 1.12e+061 Lenoir 5 1 Sulfur Dioxide 2.51e-01 1.25e+051 Lenoir 5 2 Sulfur Dioxide 1.40e-01 7.01e+041 Lenoir 5 3 Sulfur Dioxide 3.86e-01 1.93e+051 Lenoir 5 4 Sulfur Dioxide 2.05e-01 1.02e+051 Lenoir 5 5 Sulfur Dioxide 3.81e-01 1.91e+051 Lenoir 5 6 Sulfur Dioxide 5.97e-01 2.99e+051 Lenoir 5 7 Sulfur Dioxide 7.60e-01 3.80e+051 Lenoir 5 8 Sulfur Dioxide 2.78e-01 1.39e+051 Lenoir 5 9 Sulfur Dioxide 4.51e-01 2.25e+051 Sanford 6 1 Sulfur Dioxide 2.19e+00 1.10e+061 Sanford 6 2 Sulfur Dioxide 2.24e+00 1.12e+061 Sanford 6 3 Sulfur Dioxide 6.03e+00 3.02e+061 Sanford 6 4 Sulfur Dioxide 5.88e+00 2.94e+061 Sanford 6 5 Sulfur Dioxide 1.58e+00 7.90e+051 Sanford 6 6 Sulfur Dioxide 7.21e+00 3.60e+061 Sanford 6 8 Sulfur Dioxide 6.45e+00 3.23e+061 Sanford 6 9 Sulfur Dioxide 5.08e+00 2.54e+06

1 Sanford 6 10 Sulfur Dioxide 5.51e+00 2.75e+061 St. Bernardine's 1 4 Sulfur Dioxide 2.57e+00 1.28e+061 St.Agnes 8 1 Sulfur Dioxide 6.64e-01 3.32e+051 St.Agnes 8 2 Sulfur Dioxide 3.90e-01 1.95e+051 St.Agnes 8 3 Sulfur Dioxide 3.90e-01 1.95e+051 St.Agnes 8 4 Sulfur Dioxide 7.29e-01 3.65e+051 St.Agnes 8 5 Sulfur Dioxide 3.37e-01 1.69e+051 St.Agnes 8 6 Sulfur Dioxide 3.17e-01 1.58e+051 St.Agnes 8 7 Sulfur Dioxide 3.17e-01 1.58e+051 St.Agnes 8 8 Sulfur Dioxide 3.43e-01 1.71e+051 St.Agnes 8 9 Sulfur Dioxide 3.23e-01 1.61e+051 Sutter 9 1 Sulfur Dioxide 1.33e+00 6.67e+051 Sutter 9 2 Sulfur Dioxide 8.12e-01 4.06e+051 Sutter 9 4 Sulfur Dioxide 1.34e+00 6.71e+051 USC 11 1 Sulfur Dioxide 3.56e+01 1.78e+071 USC 11 2 Sulfur Dioxide 3.56e+01 1.78e+071 USC 11 3 Sulfur Dioxide 2.46e+00 1.23e+061 USC 11 4 Sulfur Dioxide 2.46e+00 1.23e+061 USC 11 5 Sulfur Dioxide 7.70e-02 3.85e+041 USC 11 6 Sulfur Dioxide 2.16e+00 1.08e+061 USC 11 7 Sulfur Dioxide 2.46e+00 1.23e+061 USC 11 8 Sulfur Dioxide 4.31e+00 2.16e+061 USC 11 9 Sulfur Dioxide 2.46e+00 1.23e+061 USC 11 10 Sulfur Dioxide 7.47e+00 3.73e+061 USC 11 11 Sulfur Dioxide 4.80e+00 2.40e+061 USC 11 12 Sulfur Dioxide 4.80e+00 2.40e+061 USC 11 13 Sulfur Dioxide 2.71e+00 1.35e+061 USC 11 14 Sulfur Dioxide 1.93e-01 9.66e+04

1 USC 11 15 Sulfur Dioxide 1.93e+00 9.66e+051 USC 11 16 Sulfur Dioxide 1.93e+00 9.66e+051 USC 11 17 Sulfur Dioxide 1.93e-01 9.66e+041 USC 11 18 Sulfur Dioxide 1.47e+00 7.33e+051 USC 11 19 Sulfur Dioxide 1.30e+00 6.52e+051 USC 11 20 Sulfur Dioxide 1.63e-01 8.15e+041 Cape Fear 2 1 Hydrogen Bromide 2.16e-03 1.08e+031 Cape Fear 2 2 Hydrogen Bromide 3.84e-03 1.92e+031 Cape Fear 2 3 Hydrogen Bromide 3.24e-03 1.62e+031 Cape Fear 2 4 Hydrogen Bromide 1.78e-02 8.88e+031 Cape Fear 2 5 Hydrogen Bromide 2.31e-03 1.15e+031 Cape Fear 2 6 Hydrogen Bromide 3.12e-03 1.56e+031 Cape Fear 2 7 Hydrogen Bromide 6.88e-02 3.44e+041 Cape Fear 2 8 Hydrogen Bromide 2.98e-02 1.49e+041 Cape Fear 2 9 Hydrogen Bromide 5.39e-02 2.70e+041 Jordan 3 2 Hydrogen Bromide 3.39e-02 1.70e+041 Jordan 3 4 Hydrogen Bromide 3.10e-02 1.55e+041 Jordan 3 6 Hydrogen Bromide 2.36e-02 1.18e+041 Lenoir 5 1 Hydrogen Bromide 2.16e-03 1.08e+031 Lenoir 5 2 Hydrogen Bromide 2.31e-03 1.15e+031 Lenoir 5 3 Hydrogen Bromide 3.12e-03 1.56e+031 Lenoir 5 4 Hydrogen Bromide 3.84e-03 1.92e+031 Lenoir 5 5 Hydrogen Bromide 3.24e-03 1.62e+031 Lenoir 5 6 Hydrogen Bromide 1.78e-02 8.88e+031 Lenoir 5 7 Hydrogen Bromide 6.88e-02 3.44e+041 Lenoir 5 8 Hydrogen Bromide 2.98e-02 1.49e+041 Lenoir 5 9 Hydrogen Bromide 5.39e-02 2.70e+041 Sanford 6 1 Hydrogen Bromide 4.62e-02 2.31e+04

1 Sanford 6 2 Hydrogen Bromide 6.33e-02 3.16e+041 Sanford 6 3 Hydrogen Bromide 4.07e-02 2.04e+041 Sanford 6 4 Hydrogen Bromide 7.20e-02 3.60e+041 Sanford 6 5 Hydrogen Bromide 4.67e-03 2.34e+031 Sanford 6 6 Hydrogen Bromide 2.63e-02 1.32e+041 Sanford 6 8 Hydrogen Bromide 1.07e-01 5.35e+041 Sanford 6 9 Hydrogen Bromide 2.52e-02 1.26e+041 Sanford 6 10 Hydrogen Bromide 4.32e-02 2.16e+041 Cape Fear 2 1 Hydrogen Chloride 3.37e+01 1.69e+071 Cape Fear 2 2 Hydrogen Chloride 4.57e+01 2.28e+071 Cape Fear 2 3 Hydrogen Chloride 4.63e+01 2.31e+071 Cape Fear 2 4 Hydrogen Chloride 4.28e+01 2.14e+071 Cape Fear 2 5 Hydrogen Chloride 3.14e+01 1.57e+071 Cape Fear 2 6 Hydrogen Chloride 4.55e+01 2.28e+071 Cape Fear 2 7 Hydrogen Chloride 3.84e+01 1.92e+071 Cape Fear 2 8 Hydrogen Chloride 4.31e+01 2.16e+071 Cape Fear 2 9 Hydrogen Chloride 3.44e+01 1.72e+071 Cedars Sinai 7 1 Hydrogen Chloride 2.62e+01 1.31e+071 Cedars Sinai 7 2 Hydrogen Chloride 1.87e+01 9.37e+061 Cedars Sinai 7 3 Hydrogen Chloride 1.29e+01 6.43e+061 Jordan 3 2 Hydrogen Chloride 2.07e+01 1.03e+071 Jordan 3 4 Hydrogen Chloride 2.07e+01 1.03e+071 Jordan 3 6 Hydrogen Chloride 1.80e+01 9.01e+061 Jubilee 12 1 Hydrogen Chloride 1.48e+01 7.40e+061 Jubilee 12 2 Hydrogen Chloride 1.82e+01 9.10e+061 Kaiser 4 1 Hydrogen Chloride 1.03e+01 5.13e+061 Kaiser 4 2 Hydrogen Chloride 1.29e+01 6.47e+061 Lenoir 5 1 Hydrogen Chloride 3.37e+01 1.69e+07

1 Lenoir 5 2 Hydrogen Chloride 3.14e+01 1.57e+071 Lenoir 5 3 Hydrogen Chloride 4.55e+01 2.28e+071 Lenoir 5 4 Hydrogen Chloride 4.57e+01 2.28e+071 Lenoir 5 5 Hydrogen Chloride 4.63e+01 2.31e+071 Lenoir 5 6 Hydrogen Chloride 4.28e+01 2.14e+071 Lenoir 5 7 Hydrogen Chloride 3.84e+01 1.92e+071 Lenoir 5 8 Hydrogen Chloride 4.31e+01 2.16e+071 Lenoir 5 9 Hydrogen Chloride 3.44e+01 1.72e+071 Sanford 6 1 Hydrogen Chloride 3.24e+00 1.62e+061 Sanford 6 2 Hydrogen Chloride 2.95e+01 1.48e+071 Sanford 6 3 Hydrogen Chloride 5.72e+00 2.86e+061 Sanford 6 4 Hydrogen Chloride 4.51e+01 2.25e+071 Sanford 6 5 Hydrogen Chloride 2.46e+00 1.23e+061 Sanford 6 6 Hydrogen Chloride 2.35e+00 1.17e+061 Sanford 6 8 Hydrogen Chloride 4.39e+01 2.19e+071 Sanford 6 9 Hydrogen Chloride 4.17e+00 2.09e+061 Sanford 6 10 Hydrogen Chloride 3.95e+00 1.97e+061 St. Bernardine's 1 1 Hydrogen Chloride 5.88e+01 2.94e+071 St. Bernardine's 1 2 Hydrogen Chloride 6.48e+01 3.24e+071 St. Bernardine's 1 3 Hydrogen Chloride 8.69e+01 4.34e+071 St.Agnes 8 1 Hydrogen Chloride 1.55e+01 7.73e+061 St.Agnes 8 2 Hydrogen Chloride 1.20e+01 5.99e+061 Sutter 9 1 Hydrogen Chloride 2.35e+01 1.18e+071 Sutter 9 2 Hydrogen Chloride 5.96e-06 2.98e+001 Swedish 10 1 Hydrogen Chloride 2.40e+01 1.20e+071 Swedish 10 2 Hydrogen Chloride 2.58e+01 1.29e+071 USC 11 1 Hydrogen Chloride 1.85e+02 9.27e+071 USC 11 2 Hydrogen Chloride 2.64e+02 1.32e+08

1 USC 11 4 Hydrogen Chloride 6.73e+01 3.36e+071 Cape Fear 2 1 Hydrogen Flouride 4.67e-02 2.34e+041 Cape Fear 2 2 Hydrogen Flouride 2.56e-01 1.28e+051 Cape Fear 2 3 Hydrogen Flouride 1.42e-01 7.12e+041 Cape Fear 2 4 Hydrogen Flouride 1.06e-01 5.30e+041 Cape Fear 2 5 Hydrogen Flouride 1.84e-01 9.19e+041 Cape Fear 2 6 Hydrogen Flouride 1.67e-01 8.34e+041 Cape Fear 2 7 Hydrogen Flouride 2.07e-01 1.03e+051 Cape Fear 2 8 Hydrogen Flouride 6.23e-02 3.12e+041 Cape Fear 2 9 Hydrogen Flouride 2.19e-01 1.10e+051 Jordan 3 2 Hydrogen Flouride 5.69e-02 2.84e+041 Jordan 3 4 Hydrogen Flouride 3.55e-02 1.78e+041 Jordan 3 6 Hydrogen Flouride 7.22e-02 3.61e+041 Lenoir 5 1 Hydrogen Flouride 4.67e-02 2.34e+041 Lenoir 5 2 Hydrogen Flouride 1.84e-01 9.19e+041 Lenoir 5 3 Hydrogen Flouride 1.67e-01 8.34e+041 Lenoir 5 4 Hydrogen Flouride 2.56e-01 1.28e+051 Lenoir 5 5 Hydrogen Flouride 1.42e-01 7.12e+041 Lenoir 5 6 Hydrogen Flouride 1.06e-01 5.30e+041 Lenoir 5 7 Hydrogen Flouride 2.07e-01 1.03e+051 Lenoir 5 8 Hydrogen Flouride 6.23e-02 3.12e+041 Lenoir 5 9 Hydrogen Flouride 2.19e-01 1.10e+051 Sanford 6 1 Hydrogen Flouride 6.49e-02 3.24e+041 Sanford 6 2 Hydrogen Flouride 5.38e-01 2.69e+051 Sanford 6 3 Hydrogen Flouride 1.49e-01 7.47e+041 Sanford 6 4 Hydrogen Flouride 2.20e-01 1.10e+051 Sanford 6 5 Hydrogen Flouride 5.14e-02 2.57e+041 Sanford 6 6 Hydrogen Flouride 3.89e-02 1.94e+04

1 Sanford 6 8 Hydrogen Flouride 2.99e-01 1.49e+051 Sanford 6 9 Hydrogen Flouride 5.33e-02 2.66e+041 Sanford 6 10 Hydrogen Flouride 1.23e-01 6.15e+042 Jordan 3 1 2378 TCDD 8.51e-08 4.26e-022 Jordan 3 3 2378 TCDD 1.49e-07 7.46e-022 Jordan 3 5 2378 TCDD 6.87e-08 3.43e-022 Jordan 3 1 TOTAL TCDD 3.59e-05 1.80e+012 Jordan 3 3 TOTAL TCDD 5.09e-05 2.54e+012 Jordan 3 5 TOTAL TCDD 3.62e-05 1.81e+012 Jordan 3 1 TOTAL CDD 9.11e-05 4.55e+012 Jordan 3 3 TOTAL CDD 1.46e-04 7.29e+012 Jordan 3 5 TOTAL CDD 7.75e-05 3.88e+012 Jordan 3 1 2378 TCDF 9.27e-07 4.64e-012 Jordan 3 3 2378 TCDF 1.46e-06 7.31e-012 Jordan 3 5 2378 TCDF 6.26e-07 3.13e-012 Jordan 3 1 TOTAL TCDF 6.69e-05 3.35e+012 Jordan 3 3 TOTAL TCDF 9.97e-05 4.98e+012 Jordan 3 5 TOTAL TCDF 5.18e-05 2.59e+012 Jordan 3 1 TOTAL CDF 1.18e-04 5.88e+012 Jordan 3 3 TOTAL CDF 2.06e-04 1.03e+022 Jordan 3 5 TOTAL CDF 8.95e-05 4.47e+012 Jordan 3 1 Antimony 3.04e-04 1.52e+022 Jordan 3 3 Antimony 3.80e-04 1.90e+022 Jordan 3 5 Antimony 2.44e-04 1.22e+022 Jordan 3 1 Arsenic 1.52e-05 7.60e+002 Jordan 3 3 Arsenic 1.57e-05 7.83e+002 Jordan 3 5 Arsenic 1.49e-05 7.45e+002 Jordan 3 1 Barium 1.85e-04 9.25e+01

2 Jordan 3 3 Barium 1.90e-04 9.50e+012 Jordan 3 5 Barium 2.45e-04 1.23e+022 Jordan 3 1 Beryllium 3.80e-06 1.90e+002 Jordan 3 3 Beryllium 4.25e-06 2.12e+002 Jordan 3 5 Beryllium 4.37e-06 2.18e+002 Jordan 3 1 Cadmium 2.38e-04 1.19e+022 Jordan 3 3 Cadmium 1.57e-04 7.83e+012 Jordan 3 5 Cadmium 1.39e-04 6.94e+012 Jordan 3 1 Chromium 2.81e-04 1.41e+022 Jordan 3 3 Chromium 2.68e-04 1.34e+022 Jordan 3 5 Chromium 2.23e-04 1.12e+022 Jordan 3 1 Lead 1.59e-03 7.93e+022 Jordan 3 3 Lead 1.23e-03 6.15e+022 Jordan 3 5 Lead 1.98e-03 9.89e+022 Jordan 3 1 Mercury 1.98e-02 9.89e+032 Jordan 3 3 Mercury 6.39e-02 3.19e+042 Jordan 3 5 Mercury 8.36e-03 4.18e+032 Jordan 3 1 Nickel 2.05e-04 1.03e+022 Jordan 3 3 Nickel 9.18e-04 4.59e+022 Jordan 3 5 Nickel 4.67e-04 2.34e+022 Jordan 3 1 Silver 4.34e-04 2.17e+022 Jordan 3 3 Silver 5.48e-05 2.74e+012 Jordan 3 5 Silver 2.56e-05 1.28e+012 Jordan 3 1 Thallium 5.45e-05 2.72e+012 Jordan 3 3 Thallium 5.59e-05 2.79e+012 Jordan 3 5 Thallium 5.33e-05 2.66e+012 Jordan 3 2 PM .625 1.67e+00 8.36e+052 Jordan 3 3 PM .625 2.68e-01 1.34e+05

2 Jordan 3 22 PM .625 8.71e-01 4.35e+052 Jordan 3 33 PM .625 7.13e-01 3.57e+052 Jordan 3 2 PM 1.0 9.47e-01 4.74e+052 Jordan 3 3 PM 1.0 7.33e-01 3.66e+052 Jordan 3 22 PM 1.0 1.75e+00 8.74e+052 Jordan 3 33 PM 1.0 2.87e-01 1.44e+052 Jordan 3 2 PM 2.5 9.99e-01 5.00e+052 Jordan 3 3 PM 2.5 7.61e-01 3.81e+052 Jordan 3 22 PM 2.5 1.80e+00 9.00e+052 Jordan 3 33 PM 2.5 3.15e-01 1.58e+052 Jordan 3 2 PM 5.0 1.01e+00 5.06e+052 Jordan 3 3 PM 5.0 3.47e-01 1.73e+052 Jordan 3 22 PM 5.0 1.81e+00 9.07e+052 Jordan 3 33 PM 5.0 7.92e-01 3.96e+052 Jordan 3 2 PM 10.0 1.83e+00 9.15e+052 Jordan 3 3 PM 10.0 3.51e-01 1.75e+052 Jordan 3 22 PM 10.0 1.03e+00 5.14e+052 Jordan 3 33 PM 10.0 7.96e-01 3.98e+052 Jordan 3 1 Particulate Matter 7.24e-02 3.62e+042 Jordan 3 3 Particulate Matter 1.63e-01 8.14e+042 Jordan 3 5 Particulate Matter 2.46e-01 1.23e+052 Jordan 3 1 Sulfur Dioxide 5.18e-01 2.59e+052 Jordan 3 3 Sulfur Dioxide 1.44e-01 7.19e+042 Jordan 3 5 Sulfur Dioxide 4.64e-01 2.32e+052 Jordan 3 1 Hydrogen Bromide 2.52e-02 1.26e+042 Jordan 3 3 Hydrogen Bromide 1.11e-01 1.06e+042 Jordan 3 5 Hydrogen Bromide 2.12e-02 1.48e+062 Jordan 3 1 Hydrogen Chloride 2.96e+00 2.11e+06

2 Jordan 3 3 Hydrogen Chloride 4.21e+00 6.37e+052 Jordan 3 5 Hydrogen Chloride 1.27e+00 2.99e+042 Jordan 3 1 Hydrogen Flouride 5.99e-02 1.78e+042 Jordan 3 3 Hydrogen Flouride 3.55e-02 1.69e+042 Jordan 3 5 Hydrogen Flouride 3.38e-02 1.69e+043 Cedars Sinai 7 1 2378 TCDD 5.18e-09 2.59e-033 Cedars Sinai 7 2 2378 TCDD 8.26e-09 4.13e-033 Cedars Sinai 7 1 TOTAL TCDD 1.26e-07 6.31e-023 Cedars Sinai 7 2 TOTAL TCDD 1.21e-07 6.03e-023 Cedars Sinai 7 1 TOTAL CDD 2.69e-06 1.34e+003 Cedars Sinai 7 2 TOTAL CDD 2.67e-06 1.34e+003 Cedars Sinai 7 1 2378 TCDF 3.17e-08 1.59e-023 Cedars Sinai 7 2 2378 TCDF 4.52e-08 2.26e-023 Cedars Sinai 7 1 TOTAL TCDF 1.17e-06 5.85e-013 Cedars Sinai 7 2 TOTAL TCDF 1.38e-06 6.92e-013 Cedars Sinai 7 1 TOTAL CDF 8.02e-06 4.01e+003 Cedars Sinai 7 2 TOTAL CDF 8.99e-06 4.49e+003 Cedars Sinai 7 1 Total Hydrocarbons 1.12e-01 5.62e+043 Cedars Sinai 7 2 Total Hydrocarbons 4.42e-02 2.21e+043 Cedars Sinai 7 3 Total Hydrocarbons 4.90e-02 2.45e+043 Cedars Sinai 7 1 Arsenic 4.08e-08 2.04e-023 Cedars Sinai 7 2 Arsenic 4.08e-08 2.04e-023 Cedars Sinai 7 3 Arsenic 3.67e-08 1.84e-023 Cedars Sinai 7 1 Cadmium 5.27e-06 2.63e+003 Cedars Sinai 7 2 Cadmium 5.31e-06 2.65e+003 Cedars Sinai 7 3 Cadmium 4.90e-06 2.45e+003 Cedars Sinai 7 1 Chromium 3.24e-06 1.62e+003 Cedars Sinai 7 2 Chromium 2.45e-06 1.22e+00

3 Cedars Sinai 7 3 Chromium 7.55e-07 3.78e-013 Cedars Sinai 7 1 Iron 2.43e-05 1.21e+013 Cedars Sinai 7 2 Iron 2.45e-05 1.22e+013 Cedars Sinai 7 3 Iron 2.27e-05 1.13e+013 Cedars Sinai 7 1 Lead 1.01e-04 5.07e+013 Cedars Sinai 7 2 Lead 1.02e-04 5.10e+013 Cedars Sinai 7 3 Lead 9.41e-05 4.70e+013 Cedars Sinai 7 1 Manganese 5.27e-06 2.63e+003 Cedars Sinai 7 2 Manganese 5.31e-06 2.65e+003 Cedars Sinai 7 3 Manganese 4.90e-06 2.45e+003 Cedars Sinai 7 1 Nickel 3.04e-05 1.52e+013 Cedars Sinai 7 2 Nickel 2.14e-05 1.07e+013 Cedars Sinai 7 3 Nickel 2.82e-05 1.41e+013 Cedars Sinai 7 1 Particulate Matter 6.12e-02 3.06e+043 Cedars Sinai 7 2 Particulate Matter 4.08e-02 2.04e+043 Cedars Sinai 7 3 Particulate Matter 1.02e-01 5.10e+043 Cedars Sinai 7 1 Carbon Monoxide 1.20e+00 6.02e+053 Cedars Sinai 7 2 Carbon Monoxide 1.20e+00 5.99e+053 Cedars Sinai 7 3 Carbon Monoxide 1.21e+00 6.04e+053 Cedars Sinai 7 1 Oxides of Nitrogen 4.53e+00 2.26e+063 Cedars Sinai 7 2 Oxides of Nitrogen 3.38e+00 1.69e+063 Cedars Sinai 7 3 Oxides of Nitrogen 2.73e+00 1.36e+063 Cedars Sinai 7 1 Sulfur Dioxide 1.17e+00 5.84e+053 Cedars Sinai 7 2 Sulfur Dioxide 5.35e-01 2.68e+053 Cedars Sinai 7 3 Sulfur Dioxide 8.31e-01 4.16e+053 Cedars Sinai 7 1 Hydrogen Chloride 1.63e+01 8.14e+063 Cedars Sinai 7 2 Hydrogen Chloride 1.27e+01 6.36e+064 Kaiser 4 1 2378 TCDD 1.84e-09 9.18e-04

4 Kaiser 4 2 2378 TCDD 1.61e-09 8.05e-044 Kaiser 4 3 2378 TCDD 4.17e-09 2.09e-034 Kaiser 4 1 TOTAL TCDD 1.70e-08 8.49e-034 Kaiser 4 2 TOTAL TCDD 1.01e-08 5.04e-034 Kaiser 4 3 TOTAL TCDD 1.32e-07 6.62e-024 Kaiser 4 1 TOTAL CDD 3.51e-06 1.75e+004 Kaiser 4 2 TOTAL CDD 4.49e-06 2.25e+004 Kaiser 4 3 TOTAL CDD 3.01e-06 1.50e+004 Kaiser 4 1 2378 TCDF 1.70e-08 8.49e-034 Kaiser 4 2 2378 TCDF 1.97e-08 9.87e-034 Kaiser 4 3 2378 TCDF 4.63e-08 2.32e-024 Kaiser 4 1 TOTAL TCDF 3.69e-07 1.85e-014 Kaiser 4 2 TOTAL TCDF 5.24e-07 2.62e-014 Kaiser 4 3 TOTAL TCDF 1.72e-06 8.61e-014 Kaiser 4 1 TOTAL CDF 8.79e-06 4.39e+004 Kaiser 4 2 TOTAL CDF 1.22e-05 6.11e+004 Kaiser 4 3 TOTAL CDF 8.41e-06 4.20e+004 Kaiser 4 1 TOTAL PCB 1.18e-04 5.92e+014 Kaiser 4 2 TOTAL PCB 9.59e-05 4.79e+014 Kaiser 4 3 TOTAL PCB 1.31e-04 6.56e+014 Kaiser 4 1 Total Hydrocarbons 1.27e-01 6.34e+044 Kaiser 4 2 Total Hydrocarbons 1.27e-01 6.34e+044 Kaiser 4 3 Total Hydrocarbons 1.43e-01 7.16e+044 Kaiser 4 4 Total Hydrocarbons 1.43e-01 7.16e+044 Kaiser 4 5 Total Hydrocarbons 1.43e-01 7.16e+044 Kaiser 4 6 Total Hydrocarbons 1.43e-01 7.16e+044 Kaiser 4 7 Total Hydrocarbons 1.55e-01 7.77e+044 Kaiser 4 1 Arsenic 1.89e-04 9.46e+01

4 Kaiser 4 2 Arsenic 2.08e-04 1.04e+024 Kaiser 4 3 Arsenic 3.04e-05 1.52e+014 Kaiser 4 1 Cadmium 9.09e-03 4.54e+034 Kaiser 4 2 Cadmium 9.77e-03 4.88e+034 Kaiser 4 3 Cadmium 2.06e-03 1.03e+034 Kaiser 4 1 Chromium 4.90e-04 2.45e+024 Kaiser 4 2 Chromium 4.83e-04 2.42e+024 Kaiser 4 3 Chromium 2.66e-04 1.33e+024 Kaiser 4 1 Iron 6.69e-03 3.35e+034 Kaiser 4 2 Iron 1.65e-02 8.26e+034 Kaiser 4 3 Iron 5.18e-03 2.59e+034 Kaiser 4 1 Lead 1.01e-01 5.04e+044 Kaiser 4 2 Lead 9.77e-02 4.88e+044 Kaiser 4 3 Lead 3.96e-02 1.98e+044 Kaiser 4 1 Manganese 5.55e-04 2.77e+024 Kaiser 4 2 Manganese 5.83e-04 2.92e+024 Kaiser 4 3 Manganese 2.61e-04 1.31e+024 Kaiser 4 1 Mercury 2.12e-02 1.06e+044 Kaiser 4 2 Mercury 2.43e-02 1.22e+044 Kaiser 4 3 Mercury 8.86e-04 4.43e+024 Kaiser 4 1 Nickel 2.71e-04 1.36e+024 Kaiser 4 2 Nickel 3.90e-04 1.95e+024 Kaiser 4 3 Nickel 3.21e-04 1.61e+024 Kaiser 4 1 PM .625 1.22e-03 6.08e+024 Kaiser 4 2 PM .625 1.28e-02 6.39e+034 Kaiser 4 1 PM 1.0 1.22e-03 6.08e+024 Kaiser 4 2 PM 1.0 1.63e-02 8.16e+034 Kaiser 4 1 PM 2.5 6.93e-02 3.47e+04

4 Kaiser 4 2 PM 2.5 5.23e-01 2.62e+054 Kaiser 4 1 PM 5.0 7.88e-01 3.94e+054 Kaiser 4 2 PM 5.0 1.93e+00 9.66e+054 Kaiser 4 1 PM 10.0 2.63e+00 1.31e+064 Kaiser 4 2 PM 10.0 4.34e+00 2.17e+064 Kaiser 4 1 Particulate Matter 6.08e+00 3.04e+064 Kaiser 4 2 Particulate Matter 6.80e+00 3.40e+064 Kaiser 4 3 Particulate Matter 1.66e+00 8.28e+054 Kaiser 4 1 Carbon Monoxide 1.43e+00 7.13e+054 Kaiser 4 2 Carbon Monoxide 1.43e+00 7.13e+054 Kaiser 4 3 Carbon Monoxide 1.07e+00 5.37e+054 Kaiser 4 4 Carbon Monoxide 1.07e+00 5.37e+054 Kaiser 4 5 Carbon Monoxide 4.29e+00 2.15e+064 Kaiser 4 6 Carbon Monoxide 2.68e+00 1.34e+064 Kaiser 4 7 Carbon Monoxide 1.94e-01 9.71e+044 Kaiser 4 1 Sulfur Dioxide 3.11e+00 1.55e+064 Kaiser 4 2 Sulfur Dioxide 1.71e+00 8.56e+054 Kaiser 4 3 Sulfur Dioxide 7.51e-01 3.76e+054 Kaiser 4 4 Sulfur Dioxide 1.93e+00 9.66e+054 Kaiser 4 5 Sulfur Dioxide 3.08e+00 1.54e+064 Kaiser 4 6 Sulfur Dioxide 2.33e+00 1.16e+064 Kaiser 4 7 Sulfur Dioxide 1.71e+00 8.54e+054 Kaiser 4 1 Oxides of Nitrogen 1.65e+00 8.26e+054 Kaiser 4 2 Oxides of Nitrogen 1.89e+00 9.47e+054 Kaiser 4 3 Oxides of Nitrogen 2.03e+00 1.01e+064 Kaiser 4 4 Oxides of Nitrogen 1.92e+00 9.60e+054 Kaiser 4 5 Oxides of Nitrogen 2.69e+00 1.34e+064 Kaiser 4 6 Oxides of Nitrogen 2.47e+00 1.23e+06

4 Kaiser 4 7 Oxides of Nitrogen 2.20e+00 1.10e+064 Kaiser 4 1 Hydrogen Chloride 2.06e+00 1.03e+064 Kaiser 4 2 Hydrogen Chloride 2.14e+00 1.07e+064 Kaiser 4 3 Hydrogen Chloride 1.74e+00 8.70e+05

= = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = =Abbreviation Key----------------2378 TCDD = 2,3,7,8-Tetrachlorodibenzo-p-dioxinsTotal TCDD = Total tetrachlorinated dibenzo-p-dioxinsTotal CDD = Total chlorinated dibenzo-p-dioxins2378 TCDF = 2,3,7,8-TetrachlorodibenzofuransTotal TCDF = Total tetrachlorinated dibenzofuransTotal CDF = Total chlorinated dibenzofuransTotal PCB = Total polychlorinated biphenylsPM 0.625 = Particulate Matter 10, d # 0.625 micrometersPM 1.0 = Particulate Matter 10, d # 1.0 micrometersPM 2.5 = Particulate Matter 10, d # 2.5 micrometersPM 5.0 = Particulate Matter 10, d # 5.0 micrometers PM 10.0 = Particulate Matter 10, d # 10.0 micrometers

TABLE 4-1. SUMMARY OF CONTROLLED AIR MWI EMISSION FACTORSON A TEST-BY-TEST BASIS

Type Facility Ref. Run Pollutant lb/ton kg/Mg01 Bio-Waste Mgmt.

C23 5 Hydrogen Chloride 3.17e+01 1.59e+01

01 Bio-Waste Mgmt.C

23 2 Hydrogen Chloride 2.31e+01 1.15e+01

01 Bio-Waste Mgmt.C


01 Bio-Waste Mgmt.C


01 Bio-Waste Mgmt.C

23 4 Particulate Matter 3.92e+00 1.96e+00

01 Bio-Waste Mgmt.C


01 Bio-Waste Mgmt.C


01 Bio-Waste Mgmt.C


01 Borgess 13 1 2,3,7,8-TCDD 1.37e-09 6.85e-1001 Borgess 13 2 2,3,7,8-TCDD 3.71e-09 1.86e-0901 Borgess 13 3 2,3,7,8-TCDD 3.38e-09 1.69e-0901 Borgess 13 1 2,3,7,8-TCDF 2.28e-08 1.14e-0801 Borgess 13 2 2,3,7,8-TCDF 2.32e-08 1.16e-0801 Borgess 13 3 2,3,7,8-TCDF 3.15e-08 1.58e-0801 Borgess 13 3 Aluminum 8.80e-03 4.40e-03

01 Borgess 13 1 Aluminum 1.29e-02 6.43e-0301 Borgess 13 2 Aluminum 9.77e-03 4.88e-0301 Borgess 13 3 Antimony 2.85e-03 1.43e-0301 Borgess 13 2 Antimony 6.86e-03 3.43e-0301 Borgess 13 1 Antimony 4.11e-03 2.05e-0301 Borgess 13 3 Arsenic 5.77e-05 2.88e-0501 Borgess 13 2 Arsenic 8.84e-05 4.42e-0501 Borgess 13 1 Arsenic 9.01e-05 4.51e-0501 Borgess 13 3 Barium 1.53e-03 7.66e-0401 Borgess 13 2 Barium 1.92e-03 9.61e-0401 Borgess 13 1 Barium 1.42e-03 7.09e-0401 Borgess 13 3 Beryllium 2.63e-06 1.31e-0601 Borgess 13 2 Beryllium 2.68e-06 1.34e-0601 Borgess 13 1 Beryllium 5.05e-06 2.53e-0601 Borgess 13 1 Cadmium 5.43e-03 2.71e-0301 Borgess 13 3 Cadmium 9.74e-03 4.87e-0301 Borgess 13 2 Cadmium 2.71e-02 1.36e-0201 Borgess 13 1 Carbon Monoxide 2.11e-01 1.05e-0101 Borgess 13 2 Carbon Monoxide 1.34e-01 6.71e-0201 Borgess 13 3 Carbon Monoxide 1.29e-01 6.46e-0201 Borgess 13 2 Chromium 6.83e-04 3.41e-0401 Borgess 13 3 Chromium 5.61e-04 2.81e-0401 Borgess 13 1 Chromium 4.65e-04 2.33e-0401 Borgess 13 3 Copper 1.06e-02 5.32e-0301 Borgess 13 1 Copper 1.33e-02 6.66e-0301 Borgess 13 2 Copper 1.35e-02 6.74e-0301 Borgess 13 1 Hydrogen Bromide 7.33e-02 3.67e-0201 Borgess 13 3 Hydrogen Bromide 1.06e-01 5.29e-02

01 Borgess 13 2 Hydrogen Bromide 1.16e-01 5.78e-0201 Borgess 13 2 Hydrogen Chloride 4.33e+01 2.17e+0101 Borgess 13 1 Hydrogen Chloride 3.48e+01 1.74e+0101 Borgess 13 3 Hydrogen Chloride 3.88e+01 1.94e+0101 Borgess 13 2 Hydrogen Fluoride 2.17e-01 1.09e-0101 Borgess 13 3 Hydrogen Fluoride 1.96e-01 9.80e-0201 Borgess 13 1 Hydrogen Fluoride 2.12e-01 1.06e-0101 Borgess 13 1 Lead 2.14e-02 1.07e-0201 Borgess 13 2 Lead 2.79e-02 1.39e-0201 Borgess 13 3 Lead 2.05e-02 1.02e-0201 Borgess 13 1 Mercury 9.51e-02 4.75e-0201 Borgess 13 2 Mercury 9.99e-02 4.99e-0201 Borgess 13 3 Mercury 1.26e-01 6.31e-0201 Borgess 13 3 Nickel 4.91e-04 2.45e-0401 Borgess 13 2 Nickel 1.42e-03 7.11e-0401 Borgess 13 1 Nickel 6.49e-04 3.25e-0401 Borgess 13 1 Oxides of Nitrogen 3.71e+00 1.85e+0001 Borgess 13 2 Oxides of Nitrogen 3.49e+00 1.74e+0001 Borgess 13 3 Oxides of Nitrogen 3.88e+00 1.94e+0001 Borgess 13 2 Particulate Matter 2.26e+00 1.13e+0001 Borgess 13 3 Particulate Matter 2.35e+00 1.17e+0001 Borgess 13 1 Particulate Matter 2.41e+00 1.20e+0001 Borgess 13 2 Silver 1.64e-04 8.22e-0501 Borgess 13 3 Silver 1.75e-04 8.77e-0501 Borgess 13 1 Silver 1.43e-04 7.14e-0501 Borgess 13 3 Sulfur Dioxide 2.98e-01 1.49e-0101 Borgess 13 2 Sulfur Dioxide 1.70e-01 8.49e-0201 Borgess 13 1 Sulfur Dioxide 2.29e-01 1.14e-01

01 Borgess 13 3 Thallium 2.63e-04 1.31e-0401 Borgess 13 1 Thallium 2.76e-04 1.38e-0401 Borgess 13 2 Thallium 2.68e-04 1.34e-0401 Borgess 13 3 Total CDD 1.15e-06 5.75e-0701 Borgess 13 1 Total CDD 6.46e-07 3.23e-0701 Borgess 13 2 Total CDD 1.14e-06 5.68e-0701 Borgess 13 1 Total CDF 2.30e-06 1.15e-0601 Borgess 13 3 Total CDF 3.94e-06 1.97e-0601 Borgess 13 2 Total CDF 4.09e-06 2.05e-0601 Borgess 13 3 Total Hydrocarbons 3.49e-02 1.74e-0201 Borgess 13 2 Total Hydrocarbons 3.96e-02 1.98e-0201 Borgess 13 1 Total Hydrocarbons 7.93e-02 3.96e-0201 Borgess 13 3 Total TCDD 2.97e-08 1.48e-0801 Borgess 13 2 Total TCDD 3.58e-08 1.79e-0801 Borgess 13 1 Total TCDD 1.22e-08 6.12e-0901 Borgess 13 2 Total TCDF 3.87e-07 1.94e-0701 Borgess 13 3 Total TCDF 3.11e-07 1.56e-0701 Borgess 13 1 Total TCDF 1.84e-07 9.20e-0801 Burlington 15 3 Carbon Monoxide 3.47e-01 1.73e-0101 Burlington 15 2 Carbon Monoxide 9.98e-01 4.99e-0101 Burlington 15 1 Carbon Monoxide 2.89e-01 1.45e-0101 Burlington 15 1 Hydrogen Chloride 1.25e+01 6.24e+0001 Burlington 15 2 Hydrogen Chloride 1.53e+01 7.63e+0001 Burlington 15 3 Hydrogen Chloride 6.53e+00 3.27e+0001 Burlington 15 5 Oxides of Nitrogen 2.54e+00 1.27e+0001 Burlington 15 4 Oxides of Nitrogen 2.76e+00 1.38e+0001 Burlington 15 6 Oxides of Nitrogen 1.74e+00 8.71e-0101 Burlington 15 4 Particulate Matter 2.98e+00 1.49e+00

01 Burlington 15 5 Particulate Matter 3.37e+00 1.69e+0001 Burlington 15 6 Particulate Matter 2.36e+00 1.18e+0001 Burlington 15 1 Total Hydrocarbons 1.81e-01 9.04e-0201 Burlington 15 3 Total Hydrocarbons 1.07e-01 5.33e-0201 Burlington 15 2 Total Hydrocarbons 2.08e-01 1.04e-0101 Cape Fear 2 1 2,3,7,8-TCDD 5.00e-08 2.50e-0801 Cape Fear 2 3 2,3,7,8-TCDD 9.63e-08 4.82e-0801 Cape Fear 2 2 2,3,7,8-TCDD 1.43e-07 7.17e-0801 Cape Fear 2 2 2,3,7,8-TCDF 6.09e-07 3.05e-0701 Cape Fear 2 3 2,3,7,8-TCDF 3.18e-07 1.59e-0701 Cape Fear 2 1 2,3,7,8-TCDF 2.34e-07 1.17e-0701 Cape Fear 2 1 Antimony 5.09e-02 2.55e-0201 Cape Fear 2 3 Antimony 3.39e-02 1.69e-0201 Cape Fear 2 2 Antimony 4.98e-02 2.49e-0201 Cape Fear 2 3 Arsenic 3.27e-04 1.63e-0401 Cape Fear 2 2 Arsenic 8.00e-04 4.00e-0401 Cape Fear 2 1 Arsenic 4.48e-04 2.24e-0401 Cape Fear 2 1 Barium 9.71e-03 4.86e-0301 Cape Fear 2 3 Barium 5.77e-03 2.88e-0301 Cape Fear 2 2 Barium 1.91e-02 9.54e-0301 Cape Fear 2 1 Beryllium 2.36e-06 1.18e-0601 Cape Fear 2 3 Beryllium 1.49e-05 7.43e-0601 Cape Fear 2 2 Beryllium 2.05e-06 1.03e-0601 Cape Fear 2 3 Cadmium 1.11e-02 5.56e-0301 Cape Fear 2 2 Cadmium 1.21e-02 6.03e-0301 Cape Fear 2 1 Cadmium 1.09e-02 5.45e-0301 Cape Fear 2 1 Carbon Monoxide 6.74e+00 3.37e+0001 Cape Fear 2 3 Carbon Monoxide 1.35e+01 6.74e+00

01 Cape Fear 2 2 Carbon Monoxide 2.08e+01 1.04e+0101 Cape Fear 2 2 Chromium 1.07e-03 5.33e-0401 Cape Fear 2 1 Chromium 1.27e-03 6.37e-0401 Cape Fear 2 3 Chromium 5.35e-04 2.68e-0401 Cape Fear 2 8 Hydrogen Bromide 2.98e-02 1.49e-0201 Cape Fear 2 7 Hydrogen Bromide 6.88e-02 3.44e-02 {APP4}FLB{R 601 Cape Fear 2 5 Hydrogen Bromide 2.31e-03 1.15e-0301 Cape Fear 2 3 Hydrogen Bromide 3.24e-03 1.62e-0301 Cape Fear 2 6 Hydrogen Bromide 3.12e-03 1.56e-0301 Cape Fear 2 4 Hydrogen Bromide 1.78e-02 8.88e-0301 Cape Fear 2 9 Hydrogen Bromide 5.39e-02 2.70e-0201 Cape Fear 2 2 Hydrogen Bromide 3.84e-03 1.92e-0301 Cape Fear 2 1 Hydrogen Bromide 2.16e-03 1.08e-0301 Cape Fear 2 3 Hydrogen Chloride 4.63e+01 2.31e+0101 Cape Fear 2 7 Hydrogen Chloride 3.84e+01 1.92e+0101 Cape Fear 2 1 Hydrogen Chloride 3.37e+01 1.69e+0101 Cape Fear 2 5 Hydrogen Chloride 3.14e+01 1.57e+0101 Cape Fear 2 4 Hydrogen Chloride 4.28e+01 2.14e+0101 Cape Fear 2 9 Hydrogen Chloride 3.44e+01 1.72e+0101 Cape Fear 2 8 Hydrogen Chloride 4.31e+01 2.16e+0101 Cape Fear 2 2 Hydrogen Chloride 4.57e+01 2.28e+0101 Cape Fear 2 6 Hydrogen Chloride 4.55e+01 2.28e+0101 Cape Fear 2 2 Hydrogen Fluoride 2.56e-01 1.28e-0101 Cape Fear 2 9 Hydrogen Fluoride 2.19e-01 1.10e-0101 Cape Fear 2 6 Hydrogen Fluoride 1.67e-01 8.34e-0201 Cape Fear 2 3 Hydrogen Fluoride 1.42e-01 7.12e-0201 Cape Fear 2 1 Hydrogen Fluoride 4.67e-02 2.34e-0201 Cape Fear 2 4 Hydrogen Fluoride 1.06e-01 5.30e-02

01 Cape Fear 2 5 Hydrogen Fluoride 1.84e-01 9.19e-0201 Cape Fear 2 7 Hydrogen Fluoride 2.07e-01 1.03e-0101 Cape Fear 2 8 Hydrogen Fluoride 6.23e-02 3.12e-0201 Cape Fear 2 1 Lead 1.82e-01 9.11e-0201 Cape Fear 2 3 Lead 1.05e-01 5.23e-0201 Cape Fear 2 2 Lead 1.99e-01 9.94e-0201 Cape Fear 2 1 Mercury 7.00e-03 3.50e-0301 Cape Fear 2 2 Mercury 1.43e-02 7.13e-0301 Cape Fear 2 3 Mercury 4.67e-02 2.33e-0201 Cape Fear 2 3 Nickel 1.78e-04 8.92e-0501 Cape Fear 2 1 Nickel 5.42e-04 2.71e-0401 Cape Fear 2 2 Nickel 2.46e-04 1.23e-0401 Cape Fear 2 2 Oxides of Nitrogen 4.99e+00 2.50e+0001 Cape Fear 2 1 Oxides of Nitrogen 5.49e+00 2.74e+0001 Cape Fear 2 3 Oxides of Nitrogen 3.97e+00 1.99e+0001 Cape Fear 2 2 Particulate Matter 1.36e+01 6.82e+0001 Cape Fear 2 1 Particulate Matter 7.32e+00 3.66e+0001 Cape Fear 2 3 Particulate Matter 8.78e+00 4.39e+0001 Cape Fear 2 1 Silver 3.07e-04 1.53e-0401 Cape Fear 2 3 Silver 2.08e-04 1.04e-0401 Cape Fear 2 2 Silver 5.33e-04 2.67e-0401 Cape Fear 2 2 Sulfur Dioxide 2.51e+00 1.26e+0001 Cape Fear 2 1 Sulfur Dioxide 2.03e+00 1.02e+0001 Cape Fear 2 3 Sulfur Dioxide 1.87e+00 9.37e-0101 Cape Fear 2 2 Thallium 3.84e-03 1.92e-0301 Cape Fear 2 3 Thallium 6.76e-03 3.38e-0301 Cape Fear 2 1 Thallium 4.39e-03 2.19e-0301 Cape Fear 2 1 Total CDD 1.39e-05 6.97e-06

01 Cape Fear 2 2 Total CDD 2.96e-05 1.48e-0501 Cape Fear 2 3 Total CDD 1.50e-05 7.48e-0601 Cape Fear 2 1 Total CDF 7.62e-05 3.81e-0501 Cape Fear 2 2 Total CDF 1.58e-04 7.88e-0501 Cape Fear 2 3 Total CDF 7.67e-05 3.83e-0501 Cape Fear 2 2 Total Hydrocarbons 3.60e-02 1.80e-0201 Cape Fear 2 8 Total Hydrocarbons 2.89e-01 1.45e-0101 Cape Fear 2 5 Total Hydrocarbons 1.60e-01 8.00e-0201 Cape Fear 2 4 Total Hydrocarbons 1.67e+00 8.37e-0101 Cape Fear 2 1 Total Hydrocarbons 6.23e-02 3.12e-0201 Cape Fear 2 9 Total Hydrocarbons 2.72e-01 1.36e-0101 Cape Fear 2 3 Total Hydrocarbons 1.16e+00 5.82e-0101 Cape Fear 2 6 Total Hydrocarbons 8.92e-02 4.46e-0201 Cape Fear 2 7 Total Hydrocarbons 2.28e-01 1.14e-0101 Cape Fear 2 8 Total PCB 1.23e-08 6.16e-0901 Cape Fear 2 3 Total TCDD 9.84e-07 4.92e-0701 Cape Fear 2 2 Total TCDD 2.71e-06 1.35e-0601 Cape Fear 2 1 Total TCDD 6.09e-07 3.04e-0701 Cape Fear 2 2 Total TCDF 2.02e-05 1.01e-0501 Cape Fear 2 1 Total TCDF 6.15e-06 3.08e-0601 Cape Fear 2 3 Total TCDF 9.56e-06 4.78e-0601 Cedars Sinai 7 3 2,3,7,8-TCDD 5.51e-09 2.75e-0901 Cedars Sinai 7 1 2,3,7,8-TCDD 3.24e-09 1.62e-0901 Cedars Sinai 7 2 2,3,7,8-TCDD 7.77e-09 3.89e-0901 Cedars Sinai 7 2 2,3,7,8-TCDF 4.50e-08 2.25e-0801 Cedars Sinai 7 3 2,3,7,8-TCDF 3.43e-08 1.72e-0801 Cedars Sinai 7 1 2,3,7,8-TCDF 2.07e-08 1.04e-0801 Cedars Sinai 7 3 Arsenic 1.47e-04 7.37e-05

01 Cedars Sinai 7 1 Arsenic 2.92e-04 1.46e-0401 Cedars Sinai 7 2 Arsenic 1.85e-04 9.23e-0501 Cedars Sinai 7 2 Cadmium 3.61e-03 1.81e-0301 Cedars Sinai 7 1 Cadmium 6.80e-03 3.40e-0301 Cedars Sinai 7 3 Cadmium 2.90e-03 1.45e-0301 Cedars Sinai 7 3 Chromium 1.29e-04 6.43e-0501 Cedars Sinai 7 2 Chromium 1.02e-04 5.10e-0501 Cedars Sinai 7 1 Chromium 3.63e-04 1.82e-0401 Cedars Sinai 7 2 Hydrogen Chloride 1.87e+01 9.37e+0001 Cedars Sinai 7 1 Hydrogen Chloride 2.62e+01 1.31e+0101 Cedars Sinai 7 3 Hydrogen Chloride 1.29e+01 6.43e+0001 Cedars Sinai 7 3 Iron 4.12e-03 2.06e-0301 Cedars Sinai 7 1 Iron 5.20e-03 2.60e-0301 Cedars Sinai 7 2 Iron 7.27e-03 3.63e-0301 Cedars Sinai 7 1 Lead 5.80e-02 2.90e-0201 Cedars Sinai 7 3 Lead 3.04e-02 1.52e-0201 Cedars Sinai 7 2 Lead 4.18e-02 2.09e-0201 Cedars Sinai 7 3 Manganese 3.29e-04 1.64e-0401 Cedars Sinai 7 1 Manganese 4.37e-04 2.18e-0401 Cedars Sinai 7 2 Manganese 4.37e-04 2.18e-0401 Cedars Sinai 7 1 Nickel 1.08e-04 5.42e-0501 Cedars Sinai 7 2 Nickel 1.11e-04 5.54e-0501 Cedars Sinai 7 3 Nickel 1.12e-04 5.58e-0501 Cedars Sinai 7 2 Particulate Matter 2.59e+00 1.30e+0001 Cedars Sinai 7 3 Particulate Matter 1.41e+00 7.04e-0101 Cedars Sinai 7 1 Particulate Matter 3.53e+00 1.77e+0001 Cedars Sinai 7 3 Total CDD 4.83e-06 2.41e-0601 Cedars Sinai 7 2 Total CDD 4.07e-06 2.03e-06

01 Cedars Sinai 7 1 Total CDD 3.00e-06 1.50e-0601 Cedars Sinai 7 1 Total CDF 8.10e-06 4.05e-0601 Cedars Sinai 7 3 Total CDF 1.29e-05 6.46e-0601 Cedars Sinai 7 2 Total CDF 1.12e-05 5.61e-0601 Cedars Sinai 7 1 Total TCDD 3.90e-08 1.95e-0801 Cedars Sinai 7 3 Total TCDD 7.63e-08 3.81e-0801 Cedars Sinai 7 2 Total TCDD 1.30e-07 6.48e-0801 Cedars Sinai 7 2 Total TCDF 1.55e-06 7.77e-0701 Cedars Sinai 7 1 Total TCDF 6.53e-07 3.26e-0701 Cedars Sinai 7 3 Total TCDF 1.16e-06 5.81e-0701 Hamilton 21 2 Carbon Monoxide 1.48e+00 7.41e-0101 Hamilton 21 1 Carbon Monoxide 2.26e+00 1.13e+0001 Hamilton 21 4 Carbon Monoxide 4.06e-01 2.03e-0101 Hamilton 21 3 Carbon Monoxide 4.68e-01 2.34e-0101 Hamilton 21 3 Hydrogen Chloride 1.08e+01 5.40e+0001 Hamilton 21 4 Hydrogen Chloride 1.22e+01 6.11e+0001 Hamilton 21 1 Hydrogen Chloride 2.82e+01 1.41e+0101 Hamilton 21 3 Oxides of Nitrogen 2.34e+00 1.17e+0001 Hamilton 21 4 Oxides of Nitrogen 3.65e+00 1.83e+0001 Hamilton 21 1 Oxides of Nitrogen 5.33e+00 2.67e+0001 Hamilton 21 3 Particulate Matter 1.27e+00 6.35e-0101 Hamilton 21 1 Particulate Matter 3.81e+00 1.90e+0001 Hamilton 21 4 Particulate Matter 2.03e+00 1.02e+0001 Hamilton 21 2 Total Hydrocarbons 1.04e+00 5.18e-0101 Hamilton 21 1 Total Hydrocarbons 5.95e-01 2.98e-0101 Hamilton 21 3 Total Hydrocarbons 4.68e-01 2.34e-0101 Hamot 34 1 Hydrogen Chloride 9.77e+00 4.89e+0001 Hamot 34 2 Hydrogen Chloride 1.12e+01 5.60e+00

01 Hamot 34 3 Hydrogen Chloride 1.25e+01 6.27e+0001 HCA Northpark 35 1 Chlorine 1.30e-01 6.50e-0201 HCA Northpark 35 1 Hydrogen Chloride 1.32e+01 6.58e+0001 HCA Northpark 35 1 Particulate Matter 4.58e-01 2.29e-0101 Helene Fuld 37 2 Carbon Monoxide 1.75e-01 8.77e-0201 Helene Fuld 37 1 Carbon Monoxide 4.86e-01 2.43e-0101 Helene Fuld 37 3 Carbon Monoxide 2.15e-01 1.08e-0101 Helene Fuld 37 2 Hydrogen Chloride 9.65e+00 4.82e+0001 Helene Fuld 37 4 Hydrogen Chloride 1.45e+01 7.23e+0001 Helene Fuld 37 6 Hydrogen Chloride 1.27e+01 6.35e+0001 Helene Fuld 37 4 Oxides of Nitrogen 3.17e+00 1.59e+0001 Helene Fuld 37 2 Oxides of Nitrogen 2.81e+00 1.40e+0001 Helene Fuld 37 6 Oxides of Nitrogen 2.21e+00 1.10e+0001 Helene Fuld 37 1 Particulate Matter 2.85e+00 1.42e+0001 Helene Fuld 37 3 Particulate Matter 2.37e+00 1.18e+0001 Helene Fuld 37 5 Particulate Matter 1.90e+00 9.52e-0101 Helene Fuld 37 2 Total Hydrocarbons 3.23e-01 1.61e-0101 Helene Fuld 37 3 Total Hydrocarbons 4.27e-01 2.13e-0101 Helene Fuld 37 1 Total Hydrocarbons 6.25e-01 3.12e-0101 Hershey 18 1 1,2,3,4,6,7,8-HpCDD 5.32e-09 2.66e-0901 Hershey 18 2 1,2,3,4,6,7,8-HpCDD 4.41e-09 2.20e-0901 Hershey 18 3 1,2,3,4,6,7,8-HpCDD 5.96e-09 2.98e-0901 Hershey 18 3 1,2,3,4,6,7,8-HpCDF 1.61e-08 8.06e-0901 Hershey 18 2 1,2,3,4,6,7,8-HpCDF 2.18e-08 1.09e-0801 Hershey 18 1 1,2,3,4,6,7,8-HpCDF 1.48e-08 7.40e-0901 Hershey 18 1 1,2,3,4,7,8,9-HpCDF 1.36e-09 6.81e-1001 Hershey 18 3 1,2,3,4,7,8,9-HpCDF 2.09e-09 1.05e-0901 Hershey 18 2 1,2,3,4,7,8,9-HpCDF 4.71e-09 2.35e-09

01 Hershey 18 2 1,2,3,4,7,8-HxCDF 9.67e-09 4.83e-0901 Hershey 18 3 1,2,3,4,7,8-HxCDF 7.15e-09 3.58e-0901 Hershey 18 1 1,2,3,4,7,8-HxCDF 5.82e-09 2.91e-0901 Hershey 18 3 1,2,3,6,7,8-HxCDD 5.37e-10 2.69e-1001 Hershey 18 2 1,2,3,6,7,8-HxCDD 3.02e-10 1.51e-1001 Hershey 18 1 1,2,3,6,7,8-HxCDD 2.96e-10 1.48e-1001 Hershey 18 1 1,2,3,6,7,8-HxCDF 2.48e-09 1.24e-0901 Hershey 18 3 1,2,3,6,7,8-HxCDF 2.92e-09 1.46e-0901 Hershey 18 2 1,2,3,6,7,8-HxCDF 2.18e-09 1.09e-0901 Hershey 18 2 1,2,3,7,8,9-HxCDD 6.65e-10 3.33e-1001 Hershey 18 3 1,2,3,7,8,9-HxCDD 2.32e-09 1.16e-0901 Hershey 18 1 1,2,3,7,8,9-HxCDD 6.51e-10 3.25e-1001 Hershey 18 3 1,2,3,7,8-PeCDF 8.95e-10 4.47e-1001 Hershey 18 2 1,2,3,7,8-PeCDF 5.45e-10 2.72e-1001 Hershey 18 1 1,2,3,7,8-PeCDF 8.30e-10 4.15e-1001 Hershey 18 1 2,3,4,6,7,8-HxCDF 5.92e-09 2.96e-0901 Hershey 18 2 2,3,4,6,7,8-HxCDF 7.26e-09 3.63e-0901 Hershey 18 3 2,3,4,6,7,8-HxCDF 8.35e-09 4.18e-0901 Hershey 18 2 2,3,4,7,8-PeCDF 2.11e-09 1.06e-0901 Hershey 18 3 2,3,4,7,8-PeCDF 2.50e-09 1.25e-0901 Hershey 18 1 2,3,4,7,8-PeCDF 1.60e-09 7.99e-1001 Hershey 18 2 2,3,7,8-TCDF 3.39e-09 1.69e-0901 Hershey 18 3 2,3,7,8-TCDF 4.00e-09 2.00e-0901 Hershey 18 1 2,3,7,8-TCDF 3.25e-09 1.63e-0901 Hershey 18 2 Carbon Monoxide 3.04e-01 1.52e-0101 Hershey 18 1 Carbon Monoxide 2.63e-01 1.32e-0101 Hershey 18 3 Carbon Monoxide 1.75e-01 8.73e-0201 Hershey 18 3 OCDD 1.91e-08 9.56e-09

01 Hershey 18 1 OCDD 2.37e-08 1.18e-0801 Hershey 18 2 OCDD 2.36e-08 1.18e-0801 Hershey 18 2 OCDF 1.39e-07 6.95e-0801 Hershey 18 3 OCDF 3.82e-08 1.91e-0801 Hershey 18 1 OCDF 4.55e-08 2.28e-0801 Hershey 18 3 Particulate Matter 2.79e+00 1.40e+0001 Hershey 18 1 Particulate Matter 3.29e+00 1.64e+0001 Hershey 18 2 Particulate Matter 1.54e+00 7.68e-0101 Humana 36 1 Chlorine 7.92e-02 3.96e-0201 Humana 36 1 Hydrogen Chloride 1.25e+01 6.25e+0001 Humana 36 1 Particulate Matter 1.14e+00 5.72e-0101 Jordan 3 2 2,3,7,8-TCDD 3.10e-09 1.55e-0901 Jordan 3 6 2,3,7,8-TCDD 3.71e-08 1.86e-0801 Jordan 3 4 2,3,7,8-TCDD 5.72e-09 2.86e-0901 Jordan 3 6 2,3,7,8-TCDF 2.82e-07 1.41e-0701 Jordan 3 2 2,3,7,8-TCDF 4.56e-09 2.28e-0901 Jordan 3 4 2,3,7,8-TCDF 8.31e-08 4.15e-0801 Jordan 3 6 Antimony 4.51e-03 2.26e-0301 Jordan 3 4 Antimony 3.70e-03 1.85e-0301 Jordan 3 2 Antimony 2.74e-03 1.37e-0301 Jordan 3 4 Arsenic 4.24e-05 2.12e-0501 Jordan 3 2 Arsenic 1.42e-04 7.09e-0501 Jordan 3 6 Arsenic 2.67e-04 1.34e-0401 Jordan 3 4 Barium 4.26e-03 2.13e-0301 Jordan 3 2 Barium 7.96e-04 3.98e-0401 Jordan 3 6 Barium 2.03e-03 1.02e-0301 Jordan 3 4 Beryllium 7.83e-06 3.91e-0601 Jordan 3 2 Beryllium 7.60e-06 3.80e-06

01 Jordan 3 6 Beryllium 7.45e-06 3.72e-0601 Jordan 3 4 Cadmium 7.02e-03 3.51e-0301 Jordan 3 6 Cadmium 6.18e-03 3.09e-0301 Jordan 3 2 Cadmium 8.07e-03 4.04e-0301 Jordan 3 6 Carbon Monoxide 1.87e+00 9.33e-0101 Jordan 3 4 Carbon Monoxide 5.78e-01 2.89e-0101 Jordan 3 2 Carbon Monoxide 8.47e-01 4.23e-0101 Jordan 3 2 Chromium 1.84e-03 9.20e-0401 Jordan 3 4 Chromium 1.12e-03 5.59e-0401 Jordan 3 6 Chromium 1.14e-03 5.69e-0401 Jordan 3 6 Hydrogen Bromide 2.36e-02 1.18e-0201 Jordan 3 4 Hydrogen Bromide 3.10e-02 1.55e-0201 Jordan 3 2 Hydrogen Bromide 3.39e-02 1.70e-0201 Jordan 3 6 Hydrogen Chloride 1.80e+01 9.01e+0001 Jordan 3 2 Hydrogen Chloride 2.07e+01 1.03e+0101 Jordan 3 4 Hydrogen Chloride 2.07e+01 1.03e+0101 Jordan 3 4 Hydrogen Fluoride 3.55e-02 1.78e-0201 Jordan 3 6 Hydrogen Fluoride 7.22e-02 3.61e-0201 Jordan 3 2 Hydrogen Fluoride 5.69e-02 2.84e-0201 Jordan 3 2 Lead 2.31e-01 1.15e-0101 Jordan 3 6 Lead 1.96e-01 9.80e-0201 Jordan 3 4 Lead 1.48e-01 7.42e-0201 Jordan 3 2 Mercury 5.45e-02 2.72e-0201 Jordan 3 4 Mercury 3.35e-01 1.67e-0101 Jordan 3 6 Mercury 3.50e-02 1.75e-0201 Jordan 3 2 Nickel 4.91e-04 2.46e-0401 Jordan 3 6 Nickel 1.16e-03 5.80e-0401 Jordan 3 4 Nickel 1.12e-03 5.59e-04

01 Jordan 3 6 Oxides of Nitrogen 1.08e+01 5.41e+0001 Jordan 3 2 Oxides of Nitrogen 1.85e+01 9.26e+0001 Jordan 3 4 Oxides of Nitrogen 1.14e+01 5.71e+0001 Jordan 3 4 Particulate Matter 1.55e+00 7.75e-0101 Jordan 3 2 Particulate Matter 1.90e+00 9.51e-0101 Jordan 3 6 Particulate Matter 2.69e+00 1.35e+0001 Jordan 3 6 Silver 2.77e-04 1.39e-0401 Jordan 3 2 Silver 8.74e-05 4.37e-0501 Jordan 3 4 Silver 1.68e-04 8.39e-0501 Jordan 3 2 Sulfur Dioxide 4.83e+00 2.41e+0001 Jordan 3 6 Sulfur Dioxide 3.69e+00 1.84e+0001 Jordan 3 4 Sulfur Dioxide 3.22e+00 1.61e+0001 Jordan 3 2 Thallium 7.60e-05 3.80e-0501 Jordan 3 6 Thallium 7.45e-05 3.72e-0501 Jordan 3 4 Thallium 7.83e-05 3.91e-0501 Jordan 3 2 Total CDD 5.93e-08 2.96e-0801 Jordan 3 6 Total CDD 1.69e-05 8.45e-0601 Jordan 3 4 Total CDD 4.96e-06 2.48e-0601 Jordan 3 2 Total CDF 2.83e-07 1.41e-0701 Jordan 3 6 Total CDF 6.48e-05 3.24e-0501 Jordan 3 4 Total CDF 1.23e-05 6.14e-0601 Jordan 3 2 Total Hydrocarbons 7.60e-01 3.80e-0101 Jordan 3 6 Total Hydrocarbons 3.71e-01 1.85e-0101 Jordan 3 6 Total TCDD 4.07e-07 2.04e-0701 Jordan 3 4 Total TCDD 3.57e-07 1.79e-0701 Jordan 3 2 Total TCDD 7.10e-09 3.55e-0901 Jordan 3 4 Total TCDF 4.09e-06 2.04e-0601 Jordan 3 6 Total TCDF 7.57e-06 3.79e-06

01 Jordan 3 2 Total TCDF 6.08e-08 3.04e-0801 Jubilee 12 1 Antimony 4.57e-04 2.29e-0401 Jubilee 12 2 Antimony 6.50e-04 3.25e-0401 Jubilee 12 2 Barium 1.97e-04 9.83e-0501 Jubilee 12 1 Barium 8.24e-04 4.12e-0401 Jubilee 12 2 Cadmium 3.32e-03 1.66e-0301 Jubilee 12 1 Cadmium 1.90e-03 9.51e-0401 Jubilee 12 2 Chromium 1.95e-03 9.77e-0401 Jubilee 12 1 Chromium 1.25e-03 6.25e-0401 Jubilee 12 1 Hydrogen Chloride 1.48e+01 7.40e+0001 Jubilee 12 2 Hydrogen Chloride 1.82e+01 9.10e+0001 Jubilee 12 1 Iron 2.24e-02 1.12e-0201 Jubilee 12 2 Iron 1.80e-02 9.02e-0301 Jubilee 12 2 Lead 4.34e-02 2.17e-0201 Jubilee 12 1 Lead 4.90e-02 2.45e-0201 Jubilee 12 2 Manganese 7.80e-04 3.90e-0401 Jubilee 12 1 Manganese 1.40e-03 6.99e-0401 Jubilee 12 2 Mercury 2.49e-05 1.24e-0501 Jubilee 12 1 Mercury 2.69e-05 1.34e-0501 Jubilee 12 2 Nickel 5.04e-04 2.52e-0401 Jubilee 12 1 Nickel 4.47e-04 2.24e-0401 Jubilee 12 2 Particulate Matter 1.82e+00 9.10e-0101 Jubilee 12 1 Particulate Matter 1.68e+00 8.40e-0101 Jubilee 12 1 Silver 3.56e-04 1.78e-0401 Jubilee 12 2 Silver 2.60e-04 1.30e-0401 Kaiser 4 2 2,3,7,8-TCDD 3.92e-09 1.96e-0901 Kaiser 4 3 2,3,7,8-TCDD 1.23e-08 6.13e-0901 Kaiser 4 1 2,3,7,8-TCDD 8.48e-09 4.24e-09

01 Kaiser 4 1 2,3,7,8-TCDF 3.40e-08 1.70e-0801 Kaiser 4 3 2,3,7,8-TCDF 1.53e-07 7.67e-0801 Kaiser 4 2 2,3,7,8-TCDF 1.50e-08 7.51e-0901 Kaiser 4 2 Arsenic 1.66e-04 8.28e-0501 Kaiser 4 3 Arsenic 4.18e-05 2.09e-0501 Kaiser 4 4 Arsenic 4.18e-05 2.09e-0501 Kaiser 4 3 Cadmium 2.12e-03 1.06e-0301 Kaiser 4 4 Cadmium 2.66e-03 1.33e-0301 Kaiser 4 2 Cadmium 1.06e-02 5.31e-0301 Kaiser 4 4 Carbon Monoxide 1.07e+00 5.37e-0101 Kaiser 4 6 Carbon Monoxide 1.94e-01 9.71e-0201 Kaiser 4 7 Carbon Monoxide 1.94e-01 9.71e-0201 Kaiser 4 2 Carbon Monoxide 1.43e+00 7.13e-0101 Kaiser 4 1 Carbon Monoxide 1.43e+00 7.13e-0101 Kaiser 4 3 Carbon Monoxide 1.43e+00 7.13e-0101 Kaiser 4 8 Carbon Monoxide 2.07e-01 1.04e-0101 Kaiser 4 5 Carbon Monoxide 5.34e+01 2.67e+0101 Kaiser 4 4 Chromium 4.89e-04 2.44e-0401 Kaiser 4 2 Chromium 3.94e-04 1.97e-0401 Kaiser 4 3 Chromium 3.85e-04 1.93e-0401 Kaiser 4 2 Hydrogen Chloride 1.29e+01 6.47e+0001 Kaiser 4 1 Hydrogen Chloride 1.03e+01 5.13e+0001 Kaiser 4 3 Iron 9.07e-03 4.53e-0301 Kaiser 4 2 Iron 1.43e-02 7.14e-0301 Kaiser 4 4 Iron 1.23e-02 6.15e-0301 Kaiser 4 2 Lead 1.04e-01 5.19e-0201 Kaiser 4 3 Lead 5.88e-02 2.94e-0201 Kaiser 4 4 Lead 5.63e-02 2.82e-02

01 Kaiser 4 2 Manganese 7.26e-04 3.63e-0401 Kaiser 4 4 Manganese 5.84e-04 2.92e-0401 Kaiser 4 3 Manganese 8.12e-04 4.06e-0401 Kaiser 4 1 Mercury 2.74e-02 1.37e-0201 Kaiser 4 2 Mercury 6.68e-02 3.34e-0201 Kaiser 4 3 Mercury 8.20e-04 4.10e-0401 Kaiser 4 3 Nickel 3.31e-04 1.66e-0401 Kaiser 4 4 Nickel 3.06e-04 1.53e-0401 Kaiser 4 2 Nickel 2.48e-04 1.24e-0401 Kaiser 4 1 Oxides of Nitrogen 1.70e+00 8.50e-0101 Kaiser 4 2 Oxides of Nitrogen 1.65e+00 8.26e-0101 Kaiser 4 4 Oxides of Nitrogen 2.14e+00 1.07e+0001 Kaiser 4 3 Oxides of Nitrogen 2.14e+00 1.07e+0001 Kaiser 4 8 Oxides of Nitrogen 2.35e+00 1.17e+0001 Kaiser 4 7 Oxides of Nitrogen 2.02e+00 1.01e+0001 Kaiser 4 5 Oxides of Nitrogen 2.41e+00 1.21e+0001 Kaiser 4 6 Oxides of Nitrogen 2.20e+00 1.10e+0001 Kaiser 4 1 Particulate Matter 8.59e+00 4.29e+0001 Kaiser 4 3 Particulate Matter 8.70e+00 4.35e+0001 Kaiser 4 2 Particulate Matter 4.14e+00 2.07e+0001 Kaiser 4 4 Sulfur Dioxide 5.37e-01 2.68e-0101 Kaiser 4 5 Sulfur Dioxide 2.33e+00 1.16e+0001 Kaiser 4 3 Sulfur Dioxide 1.39e+00 6.97e-0101 Kaiser 4 7 Sulfur Dioxide 1.71e+00 8.54e-0101 Kaiser 4 6 Sulfur Dioxide 2.10e+00 1.05e+0001 Kaiser 4 1 Sulfur Dioxide 3.11e+00 1.55e+0001 Kaiser 4 2 Sulfur Dioxide 2.38e+00 1.19e+0001 Kaiser 4 8 Sulfur Dioxide 2.24e+00 1.12e+00

01 Kaiser 4 2 Total CDD 7.32e-06 3.66e-0601 Kaiser 4 3 Total CDD 2.20e-05 1.10e-0501 Kaiser 4 1 Total CDD 6.04e-06 3.02e-0601 Kaiser 4 2 Total CDF 1.46e-05 7.30e-0601 Kaiser 4 1 Total CDF 1.60e-05 7.99e-0601 Kaiser 4 3 Total CDF 4.26e-05 2.13e-0501 Kaiser 4 3 Total Hydrocarbons 1.27e-01 6.34e-0201 Kaiser 4 1 Total Hydrocarbons 1.27e-01 6.34e-0201 Kaiser 4 2 Total Hydrocarbons 1.27e-01 6.34e-0201 Kaiser 4 8 Total Hydrocarbons 1.66e-01 8.28e-0201 Kaiser 4 5 Total Hydrocarbons 1.43e-01 7.16e-0201 Kaiser 4 7 Total Hydrocarbons 1.55e-01 7.77e-0201 Kaiser 4 6 Total Hydrocarbons 1.55e-01 7.77e-0201 Kaiser 4 4 Total Hydrocarbons 1.43e-01 7.16e-0201 Kaiser 4 2 Total PCB 9.64e-05 4.82e-0501 Kaiser 4 3 Total PCB 9.70e-05 4.85e-0501 Kaiser 4 1 Total PCB 8.59e-05 4.29e-0501 Kaiser 4 2 Total TCDD 1.50e-08 7.51e-0901 Kaiser 4 1 Total TCDD 8.48e-09 4.24e-0901 Kaiser 4 3 Total TCDD 1.41e-07 7.06e-0801 Kaiser 4 2 Total TCDF 4.45e-07 2.23e-0701 Kaiser 4 1 Total TCDF 4.88e-07 2.44e-0701 Kaiser 4 3 Total TCDF 2.33e-06 1.17e-0601 Lenoir 5 3 2,3,7,8-TCDD 4.51e-07 2.25e-0701 Lenoir 5 2 2,3,7,8-TCDD 5.46e-08 2.73e-0801 Lenoir 5 1 2,3,7,8-TCDD 7.50e-08 3.75e-0801 Lenoir 5 3 2,3,7,8-TCDF 2.20e-06 1.10e-0601 Lenoir 5 2 2,3,7,8-TCDF 2.71e-07 1.35e-07

01 Lenoir 5 1 2,3,7,8-TCDF 3.80e-07 1.90e-0701 Lenoir 5 2 Antimony 1.33e-02 6.67e-0301 Lenoir 5 3 Antimony 2.88e-02 1.44e-0201 Lenoir 5 1 Antimony 1.23e-02 6.15e-0301 Lenoir 5 1 Arsenic 1.91e-04 9.54e-0501 Lenoir 5 2 Arsenic 2.42e-04 1.21e-0401 Lenoir 5 3 Arsenic 2.64e-04 1.32e-0401 Lenoir 5 2 Barium 3.37e-03 1.69e-0301 Lenoir 5 3 Barium 2.48e-03 1.24e-0301 Lenoir 5 1 Barium 1.92e-03 9.62e-0401 Lenoir 5 1 Beryllium 2.94e-06 1.47e-0601 Lenoir 5 2 Beryllium 2.20e-06 1.10e-0601 Lenoir 5 3 Beryllium 1.47e-06 7.34e-0701 Lenoir 5 3 Cadmium 5.21e-03 2.61e-0301 Lenoir 5 2 Cadmium 7.07e-03 3.54e-0301 Lenoir 5 1 Cadmium 4.36e-03 2.18e-0301 Lenoir 5 3 Carbon Monoxide 3.78e+01 1.89e+0101 Lenoir 5 2 Carbon Monoxide 2.59e+00 1.29e+0001 Lenoir 5 1 Carbon Monoxide 3.89e+00 1.94e+0001 Lenoir 5 7 Chlorobenzene 1.40e-03 6.99e-0401 Lenoir 5 7 Chlorophenol 8.24e-04 4.12e-0401 Lenoir 5 3 Chromium 8.81e-04 4.41e-0401 Lenoir 5 2 Chromium 7.71e-04 3.85e-0401 Lenoir 5 1 Chromium 4.55e-04 2.28e-0401 Lenoir 5 3 Hydrogen Bromide 3.12e-03 1.56e-0301 Lenoir 5 4 Hydrogen Bromide 3.84e-03 1.92e-0301 Lenoir 5 8 Hydrogen Bromide 2.98e-02 1.49e-0201 Lenoir 5 2 Hydrogen Bromide 2.31e-03 1.15e-03

01 Lenoir 5 1 Hydrogen Bromide 2.16e-03 1.08e-0301 Lenoir 5 6 Hydrogen Bromide 1.78e-02 8.88e-0301 Lenoir 5 5 Hydrogen Bromide 3.24e-03 1.62e-0301 Lenoir 5 7 Hydrogen Bromide 6.88e-02 3.44e-0201 Lenoir 5 9 Hydrogen Bromide 5.39e-02 2.70e-0201 Lenoir 5 7 Hydrogen Chloride 3.84e+01 1.92e+0101 Lenoir 5 2 Hydrogen Chloride 3.14e+01 1.57e+0101 Lenoir 5 8 Hydrogen Chloride 4.31e+01 2.16e+0101 Lenoir 5 1 Hydrogen Chloride 3.37e+01 1.69e+0101 Lenoir 5 4 Hydrogen Chloride 4.57e+01 2.28e+0101 Lenoir 5 5 Hydrogen Chloride 4.63e+01 2.31e+0101 Lenoir 5 6 Hydrogen Chloride 4.28e+01 2.14e+0101 Lenoir 5 9 Hydrogen Chloride 3.44e+01 1.72e+0101 Lenoir 5 3 Hydrogen Chloride 4.55e+01 2.28e+0101 Lenoir 5 7 Hydrogen Fluoride 2.07e-01 1.03e-0101 Lenoir 5 1 Hydrogen Fluoride 4.67e-02 2.34e-0201 Lenoir 5 9 Hydrogen Fluoride 2.19e-01 1.10e-0101 Lenoir 5 5 Hydrogen Fluoride 1.42e-01 7.12e-0201 Lenoir 5 2 Hydrogen Fluoride 1.84e-01 9.19e-0201 Lenoir 5 3 Hydrogen Fluoride 1.67e-01 8.34e-0201 Lenoir 5 4 Hydrogen Fluoride 2.56e-01 1.28e-0101 Lenoir 5 6 Hydrogen Fluoride 1.06e-01 5.30e-0201 Lenoir 5 8 Hydrogen Fluoride 6.23e-02 3.12e-0201 Lenoir 5 3 Lead 3.89e-02 1.95e-0201 Lenoir 5 2 Lead 7.73e-02 3.87e-0201 Lenoir 5 1 Lead 3.47e-02 1.73e-0201 Lenoir 5 1 Mercury 2.66e-03 1.33e-0301 Lenoir 5 2 Mercury 4.14e-03 2.07e-03

01 Lenoir 5 3 Mercury 3.14e-02 1.57e-0201 Lenoir 5 2 Nickel 3.96e-04 1.98e-0401 Lenoir 5 1 Nickel 3.52e-04 1.76e-0401 Lenoir 5 3 Nickel 7.78e-04 3.89e-0401 Lenoir 5 3 Oxides of Nitrogen 2.76e+00 1.38e+0001 Lenoir 5 2 Oxides of Nitrogen 4.42e+00 2.21e+0001 Lenoir 5 1 Oxides of Nitrogen 3.05e+00 1.52e+0001 Lenoir 5 3 Particulate Matter 1.48e+01 7.39e+0001 Lenoir 5 1 Particulate Matter 6.40e+00 3.20e+0001 Lenoir 5 2 Particulate Matter 7.16e+00 3.58e+0001 Lenoir 5 3 Silver 1.76e-04 8.81e-0501 Lenoir 5 2 Silver 5.07e-04 2.53e-0401 Lenoir 5 1 Silver 4.41e-05 2.20e-0501 Lenoir 5 1 Sulfur Dioxide 8.47e-01 4.23e-0101 Lenoir 5 3 Sulfur Dioxide 1.03e+00 5.13e-0101 Lenoir 5 2 Sulfur Dioxide 7.48e-01 3.74e-0101 Lenoir 5 2 Thallium 6.61e-05 3.30e-0501 Lenoir 5 3 Thallium 4.41e-05 2.20e-0501 Lenoir 5 1 Thallium 5.87e-05 2.94e-0501 Lenoir 5 1 Total CDD 2.84e-05 1.42e-0501 Lenoir 5 2 Total CDD 5.88e-05 2.94e-0501 Lenoir 5 3 Total CDD 7.70e-05 3.85e-0501 Lenoir 5 1 Total CDF 1.13e-04 5.67e-0501 Lenoir 5 3 Total CDF 4.48e-04 2.24e-0401 Lenoir 5 2 Total CDF 1.75e-04 8.73e-0501 Lenoir 5 3 Total Hydrocarbons 2.84e-01 1.42e-0101 Lenoir 5 2 Total Hydrocarbons 3.07e-01 1.53e-0101 Lenoir 5 1 Total Hydrocarbons 1.68e-01 8.41e-02

01 Lenoir 5 7 Total Hydrocarbons 2.33e-01 1.16e-0101 Lenoir 5 6 Total Hydrocarbons 2.25e-01 1.13e-0101 Lenoir 5 9 Total Hydrocarbons 9.08e-01 4.54e-0101 Lenoir 5 4 Total Hydrocarbons 8.44e-02 4.22e-0201 Lenoir 5 1 Total TCDD 8.97e-07 4.49e-0701 Lenoir 5 2 Total TCDD 6.38e-07 3.19e-0701 Lenoir 5 3 Total TCDD 6.00e-06 3.00e-0601 Lenoir 5 3 Total TCDF 5.44e-05 2.72e-0501 Lenoir 5 1 Total TCDF 1.38e-05 6.92e-0601 Lenoir 5 2 Total TCDF 1.00e-05 5.00e-0601 Mayo 32 3 Hydrogen Chloride 4.78e+01 2.39e+0101 Mayo 16 6 Hydrogen Chloride 1.02e+02 5.11e+0101 Mayo 32 3 Hydrogen Chloride 3.74e+01 1.87e+0101 Mayo 16 2 Hydrogen Chloride 8.65e+01 4.32e+0101 Mayo 32 2 Hydrogen Chloride 5.10e+01 2.55e+0101 Mayo 16 1 Hydrogen Chloride 4.79e+01 2.39e+0101 Mayo 32 3 Hydrogen Chloride 4.57e+01 2.28e+0101 Mayo 16 3 Hydrogen Chloride 1.06e+02 5.30e+0101 Mayo 16 7 Hydrogen Chloride 6.49e+01 3.25e+0101 Mayo 16 5 Hydrogen Chloride 7.20e+01 3.60e+0101 Mayo 32 1 Hydrogen Chloride 6.27e+01 3.14e+0101 Mayo 32 1 Hydrogen Chloride 7.19e+01 3.60e+0101 Mayo 16 4 Hydrogen Chloride 7.69e+01 3.84e+0101 Mayo 32 2 Hydrogen Chloride 7.90e+01 3.95e+0101 Mayo 32 2 Hydrogen Chloride 4.53e+01 2.26e+0101 Mayo 32 1 Hydrogen Chloride 3.50e+01 1.75e+0101 Mayo 32 3 Particulate Matter 4.07e+00 2.04e+0001 Mayo 16 2 Particulate Matter 7.15e+00 3.57e+00

01 Mayo 32 2 Particulate Matter 4.50e+00 2.25e+0001 Mayo 16 4 Particulate Matter 5.36e+00 2.68e+0001 Mayo 16 7 Particulate Matter 5.08e+00 2.54e+0001 Mayo 32 3 Particulate Matter 4.29e+00 2.14e+0001 Mayo 16 3 Particulate Matter 9.74e+00 4.87e+0001 Mayo 32 1 Particulate Matter 6.63e+00 3.32e+0001 Mayo 16 1 Particulate Matter 5.67e+00 2.84e+0001 Mayo 32 1 Particulate Matter 3.25e+00 1.62e+0001 Mayo 32 2 Particulate Matter 7.18e+00 3.59e+0001 Mayo 32 1 Particulate Matter 7.37e+00 3.68e+0001 Mayo 32 3 Particulate Matter 5.48e+00 2.74e+0001 Mayo 32 2 Particulate Matter 4.52e+00 2.26e+0001 Mayo 16 5 Particulate Matter 6.05e+00 3.03e+0001 Mayo 16 6 Particulate Matter 8.81e+00 4.41e+0001 Memorial 26 2 Hydrogen Chloride 2.37e+01 1.19e+0101 Memorial 26 1 Hydrogen Chloride 2.46e+01 1.23e+0101 Memorial 26 3 Hydrogen Chloride 1.89e+01 9.43e+0001 Memorial 26 3 Particulate Matter 1.90e+00 9.50e-0101 Memorial 26 2 Particulate Matter 1.26e+00 6.30e-0101 Memorial 26 1 Particulate Matter 1.67e+00 8.35e-0101 Nazareth 20 1 Hydrogen Chloride 6.06e+01 3.03e+0101 Nazareth 20 2 Hydrogen Chloride 3.49e+01 1.74e+0101 Nazareth 20 1A Sulfur Dioxide 2.20e-01 1.10e-0101 Nazareth 20 1B Sulfur Dioxide 4.00e-01 2.00e-0101 Nazareth 20 2A Sulfur Dioxide 1.20e-01 6.00e-0201 Nazareth 20 2B Sulfur Dioxide 1.30e-01 6.50e-0201 Raritan 22 1 Carbon Monoxide 3.08e-01 1.54e-0101 Raritan 22 2 Carbon Monoxide 1.73e-01 8.64e-02

01 Raritan 22 3 Carbon Monoxide 1.30e-01 6.48e-0201 Raritan 22 1 Hydrogen Chloride 2.09e+01 1.05e+0101 Raritan 22 3 Hydrogen Chloride 1.41e+01 7.07e+0001 Raritan 22 2 Hydrogen Chloride 1.18e+01 5.92e+0001 Raritan 22 1 Oxides of Nitrogen 2.13e+00 1.06e+0001 Raritan 22 3 Oxides of Nitrogen 1.81e+00 9.06e-0101 Raritan 22 2 Oxides of Nitrogen 2.27e+00 1.13e+0001 Raritan 22 3 Particulate Matter 4.20e+00 2.10e+0001 Raritan 22 4 Particulate Matter 3.41e+00 1.70e+0001 Raritan 22 2 Particulate Matter 3.88e+00 1.94e+0001 Raritan 22 2 Total Hydrocarbons 2.45e-01 1.23e-0101 Raritan 22 4 Total Hydrocarbons 2.84e-01 1.42e-0101 Raritan 22 3 Total Hydrocarbons 2.10e-01 1.05e-0101 Sanford 6 3 2,3,7,8-TCDD 1.76e-08 8.80e-0901 Sanford 6 2 2,3,7,8-TCDD 5.16e-07 2.58e-0701 Sanford 6 1 2,3,7,8-TCDD 1.67e-08 8.37e-0901 Sanford 6 2 2,3,7,8-TCDF 1.42e-06 7.10e-0701 Sanford 6 1 2,3,7,8-TCDF 9.47e-08 4.74e-0801 Sanford 6 3 2,3,7,8-TCDF 8.00e-08 4.00e-0801 Sanford 6 3 Antimony 1.02e-03 5.09e-0401 Sanford 6 2 Antimony 1.02e-02 5.10e-0301 Sanford 6 1 Antimony 3.18e-03 1.59e-0301 Sanford 6 3 Arsenic 1.54e-03 7.70e-0401 Sanford 6 1 Arsenic 1.06e-03 5.31e-0401 Sanford 6 2 Arsenic 1.94e-04 9.71e-0501 Sanford 6 1 Barium 5.31e-04 2.65e-0401 Sanford 6 3 Barium 5.23e-04 2.61e-0401 Sanford 6 2 Barium 1.44e-03 7.21e-04

01 Sanford 6 3 Beryllium 2.75e-06 1.38e-0601 Sanford 6 1 Beryllium 4.08e-06 2.04e-0601 Sanford 6 2 Beryllium 2.77e-05 1.39e-0501 Sanford 6 3 Cadmium 3.58e-04 1.79e-0401 Sanford 6 2 Cadmium 9.15e-04 4.58e-0401 Sanford 6 1 Cadmium 5.31e-03 2.65e-0301 Sanford 6 3 Carbon Monoxide 2.41e+00 1.21e+0001 Sanford 6 2 Carbon Monoxide 2.50e+01 1.25e+0101 Sanford 6 1 Carbon Monoxide 2.11e+00 1.05e+0001 Sanford 6 3 Chromium 3.08e-03 1.54e-0301 Sanford 6 2 Chromium 6.10e-04 3.05e-0401 Sanford 6 1 Chromium 5.31e-04 2.65e-0401 Sanford 6 3 Hydrogen Bromide 4.07e-02 2.04e-0201 Sanford 6 4 Hydrogen Bromide 7.20e-02 3.60e-0201 Sanford 6 1 Hydrogen Bromide 4.62e-02 2.31e-0201 Sanford 6 2 Hydrogen Bromide 6.33e-02 3.16e-0201 Sanford 6 6 Hydrogen Bromide 2.63e-02 1.32e-0201 Sanford 6 10 Hydrogen Bromide 4.32e-02 2.16e-0201 Sanford 6 5 Hydrogen Bromide 4.67e-03 2.34e-0301 Sanford 6 9 Hydrogen Bromide 2.52e-02 1.26e-0201 Sanford 6 8 Hydrogen Bromide 1.07e-01 5.35e-0201 Sanford 6 10 Hydrogen Chloride 3.95e+00 1.97e+0001 Sanford 6 2 Hydrogen Chloride 2.95e+01 1.48e+0101 Sanford 6 8 Hydrogen Chloride 4.39e+01 2.19e+0101 Sanford 6 1 Hydrogen Chloride 3.24e+00 1.62e+0001 Sanford 6 5 Hydrogen Chloride 2.46e+00 1.23e+0001 Sanford 6 9 Hydrogen Chloride 4.17e+00 2.09e+0001 Sanford 6 6 Hydrogen Chloride 2.35e+00 1.17e+00

01 Sanford 6 4 Hydrogen Chloride 4.51e+01 2.25e+0101 Sanford 6 3 Hydrogen Chloride 5.72e+00 2.86e+0001 Sanford 6 2 Hydrogen Fluoride 5.38e-01 2.69e-0101 Sanford 6 8 Hydrogen Fluoride 2.99e-01 1.49e-0101 Sanford 6 5 Hydrogen Fluoride 5.14e-02 2.57e-0201 Sanford 6 4 Hydrogen Fluoride 2.20e-01 1.10e-0101 Sanford 6 6 Hydrogen Fluoride 3.89e-02 1.94e-0201 Sanford 6 1 Hydrogen Fluoride 6.49e-02 3.24e-0201 Sanford 6 3 Hydrogen Fluoride 1.49e-01 7.47e-0201 Sanford 6 10 Hydrogen Fluoride 1.23e-01 6.15e-0201 Sanford 6 9 Hydrogen Fluoride 5.33e-02 2.66e-0201 Sanford 6 3 Lead 5.42e-03 2.71e-0301 Sanford 6 1 Lead 1.45e-02 7.27e-0301 Sanford 6 2 Lead 3.11e-02 1.55e-0201 Sanford 6 2 Mercury 1.39e-04 6.93e-0501 Sanford 6 1 Mercury 1.39e-03 6.94e-0401 Sanford 6 3 Mercury 3.16e-03 1.58e-0301 Sanford 6 2 Nickel 4.44e-04 2.22e-0401 Sanford 6 3 Nickel 4.87e-03 2.43e-0301 Sanford 6 1 Nickel 5.72e-04 2.86e-0401 Sanford 6 2 Oxides of Nitrogen 5.93e+00 2.97e+0001 Sanford 6 1 Oxides of Nitrogen 1.45e+01 7.23e+0001 Sanford 6 3 Oxides of Nitrogen 1.33e+01 6.67e+0001 Sanford 6 3 Particulate Matter 1.93e+00 9.67e-0101 Sanford 6 2 Particulate Matter 1.81e+01 9.05e+0001 Sanford 6 1 Particulate Matter 2.19e+00 1.09e+0001 Sanford 6 6 PM 10.0 2.95e+01 1.48e+0101 Sanford 6 5 PM 10.0 2.77e+01 1.39e+01

01 Sanford 6 6 PM 1.0 1.08e+01 5.39e+0001 Sanford 6 5 PM 1.0 9.89e+00 4.94e+0001 Sanford 6 5 PM 2.5 1.49e+01 7.44e+0001 Sanford 6 6 PM 2.5 1.77e+01 8.83e+0001 Sanford 6 6 PM 5.0 2.31e+01 1.15e+0101 Sanford 6 5 PM 5.0 2.11e+01 1.05e+0101 Sanford 6 6 PM .625 7.11e+00 3.55e+0001 Sanford 6 5 PM .625 5.94e+00 2.97e+0001 Sanford 6 2 Silver 2.22e-04 1.11e-0401 Sanford 6 1 Silver 8.17e-05 4.08e-0501 Sanford 6 3 Silver 5.50e-05 2.75e-0501 Sanford 6 2 Sulfur Dioxide 1.99e+00 9.96e-0101 Sanford 6 1 Sulfur Dioxide 6.25e+00 3.13e+0001 Sanford 6 3 Sulfur Dioxide 5.79e+00 2.89e+0001 Sanford 6 2 Thallium 8.32e-05 4.16e-0501 Sanford 6 3 Thallium 8.25e-05 4.13e-0501 Sanford 6 1 Thallium 1.63e-04 8.17e-0501 Sanford 6 1 Total CDD 6.16e-06 3.08e-0601 Sanford 6 3 Total CDD 3.38e-06 1.69e-0601 Sanford 6 2 Total CDD 8.90e-05 4.45e-0501 Sanford 6 2 Total CDF 3.49e-04 1.75e-0401 Sanford 6 3 Total CDF 7.04e-06 3.52e-0601 Sanford 6 1 Total CDF 1.51e-05 7.57e-0601 Sanford 6 5 Total Hydrocarbons 1.18e-01 5.89e-0201 Sanford 6 8 Total Hydrocarbons 9.50e-01 4.75e-0101 Sanford 6 9 Total Hydrocarbons 1.17e-01 5.87e-0201 Sanford 6 1 Total Hydrocarbons 3.54e-01 1.77e-0101 Sanford 6 6 Total Hydrocarbons 1.94e-01 9.71e-02

01 Sanford 6 10 Total Hydrocarbons 1.20e-01 6.01e-0201 Sanford 6 2 Total Hydrocarbons 6.59e-01 3.30e-0101 Sanford 6 3 Total Hydrocarbons 3.91e-01 1.95e-0101 Sanford 6 4 Total Hydrocarbons 1.96e+00 9.80e-0101 Sanford 6 2 Total TCDD 1.12e-05 5.62e-0601 Sanford 6 3 Total TCDD 1.11e-06 5.55e-0701 Sanford 6 1 Total TCDD 1.52e-06 7.58e-0701 Sanford 6 3 Total TCDF 3.16e-06 1.58e-0601 Sanford 6 1 Total TCDF 4.99e-06 2.50e-0601 Sanford 6 2 Total TCDF 4.25e-05 2.12e-0501 St. Bernardine's 1 3 2,3,7,8-TCDD 1.81e-09 9.07e-1001 St. Bernardine's 1 2 2,3,7,8-TCDD 1.20e-08 6.02e-0901 St. Bernardine's 1 4 2,3,7,8-TCDD 1.81e-09 9.07e-1001 St. Bernardine's 1 1 2,3,7,8-TCDD 1.50e-09 7.52e-1001 St. Bernardine's 1 1 2,3,7,8-TCDF 3.16e-08 1.58e-0801 St. Bernardine's 1 4 2,3,7,8-TCDF 1.04e-08 5.22e-0901 St. Bernardine's 1 3 2,3,7,8-TCDF 1.72e-08 8.62e-0901 St. Bernardine's 1 2 2,3,7,8-TCDF 2.91e-08 1.45e-0801 St. Bernardine's 1 3 Arsenic 3.60e-05 1.80e-0501 St. Bernardine's 1 2 Arsenic 4.29e-05 2.15e-0501 St. Bernardine's 1 1 Arsenic 3.82e-05 1.91e-0501 St. Bernardine's 1 2 Cadmium 1.03e-03 5.15e-0401 St. Bernardine's 1 3 Cadmium 1.60e-03 8.00e-0401 St. Bernardine's 1 1 Cadmium 9.44e-04 4.72e-0401 St. Bernardine's 1 4 Carbon Monoxide 3.71e-01 1.85e-0101 St. Bernardine's 1 2 Chromium 2.79e-04 1.39e-0401 St. Bernardine's 1 1 Chromium 2.75e-04 1.37e-0401 St. Bernardine's 1 3 Chromium 1.60e-03 8.00e-04

01 St. Bernardine's 1 3 Hydrogen Chloride 8.69e+01 4.34e+0101 St. Bernardine's 1 1 Hydrogen Chloride 5.88e+01 2.94e+0101 St. Bernardine's 1 2 Hydrogen Chloride 6.48e+01 3.24e+0101 St. Bernardine's 1 2 Iron 2.27e-03 1.14e-0301 St. Bernardine's 1 1 Iron 2.49e-03 1.24e-0301 St. Bernardine's 1 3 Iron 3.66e-03 1.83e-0301 St. Bernardine's 1 3 Lead 2.29e-02 1.14e-0201 St. Bernardine's 1 2 Lead 1.12e-02 5.58e-0301 St. Bernardine's 1 1 Lead 1.12e-02 5.58e-0301 St. Bernardine's 1 3 Manganese 2.11e-04 1.06e-0401 St. Bernardine's 1 1 Manganese 1.59e-04 7.94e-0501 St. Bernardine's 1 2 Manganese 1.42e-04 7.08e-0501 St. Bernardine's 1 3 Mercury 2.04e-02 1.02e-0201 St. Bernardine's 1 1 Mercury 1.40e-02 7.01e-0301 St. Bernardine's 1 2 Mercury 1.40e-02 6.99e-0301 St. Bernardine's 1 3 Nickel 5.43e-04 2.72e-0401 St. Bernardine's 1 1 Nickel 4.12e-04 2.06e-0401 St. Bernardine's 1 2 Nickel 4.20e-04 2.10e-0401 St. Bernardine's 1 4 Oxides of Nitrogen 8.29e+00 4.15e+0001 St. Bernardine's 1 3 Particulate Matter 7.43e+00 3.72e+0001 St. Bernardine's 1 2 Particulate Matter 4.72e+00 2.36e+0001 St. Bernardine's 1 1 Particulate Matter 5.15e+00 2.57e+0001 St. Bernardine's 1 4 Sulfur Dioxide 2.57e+00 1.28e+0001 St. Bernardine's 1 3 Total CDD 5.15e-06 2.58e-0601 St. Bernardine's 1 2 Total CDD 8.76e-06 4.38e-0601 St. Bernardine's 1 1 Total CDD 3.26e-06 1.63e-0601 St. Bernardine's 1 4 Total CDD 1.91e-06 9.54e-0701 St. Bernardine's 1 3 Total CDF 1.10e-05 5.50e-06

01 St. Bernardine's 1 4 Total CDF 3.63e-06 1.82e-0601 St. Bernardine's 1 2 Total CDF 2.13e-05 1.06e-0501 St. Bernardine's 1 1 Total CDF 1.01e-05 5.03e-0601 St. Bernardine's 1 4 Total Hydrocarbons 3.95e-02 1.97e-0201 St. Bernardine's 1 2 Total TCDD 1.75e-07 8.75e-0801 St. Bernardine's 1 4 Total TCDD 3.63e-09 1.81e-0901 St. Bernardine's 1 3 Total TCDD 9.66e-08 4.83e-0801 St. Bernardine's 1 1 Total TCDD 1.25e-07 6.27e-0801 St. Bernardine's 1 4 Total TCDF 1.33e-07 6.65e-0801 St. Bernardine's 1 2 Total TCDF 1.41e-06 7.04e-0701 St. Bernardine's 1 1 Total TCDF 8.91e-07 4.46e-0701 St. Bernardine's 1 3 Total TCDF 4.99e-07 2.50e-0701 St.Agnes 8 2 2,3,7,8-TCDD 1.07e-08 5.37e-0901 St.Agnes 8 1 2,3,7,8-TCDF 4.64e-08 2.32e-0801 St.Agnes 8 2 2,3,7,8-TCDF 5.62e-08 2.81e-0801 St.Agnes 8 3 Arsenic 7.15e-05 3.58e-0501 St.Agnes 8 2 Arsenic 7.41e-05 3.70e-0501 St.Agnes 8 1 Arsenic 2.15e-04 1.07e-0401 St.Agnes 8 2 Cadmium 3.00e-03 1.50e-0301 St.Agnes 8 1 Cadmium 4.09e-03 2.04e-0301 St.Agnes 8 3 Cadmium 2.48e-03 1.24e-0301 St.Agnes 8 3 Carbon Monoxide 1.61e+00 8.07e-0101 St.Agnes 8 8 Carbon Monoxide 1.47e+00 7.36e-0101 St.Agnes 8 9 Carbon Monoxide 1.37e+00 6.87e-0101 St.Agnes 8 2 Carbon Monoxide 1.61e+00 8.07e-0101 St.Agnes 8 5 Carbon Monoxide 1.53e+00 7.64e-0101 St.Agnes 8 6 Carbon Monoxide 1.53e+00 7.64e-0101 St.Agnes 8 4 Carbon Monoxide 1.56e+00 7.78e-01

01 St.Agnes 8 1 Carbon Monoxide 1.62e+00 8.09e-0101 St.Agnes 8 7 Carbon Monoxide 1.53e+00 7.64e-0101 St.Agnes 8 2 Chromium 2.89e-04 1.44e-0401 St.Agnes 8 3 Chromium 6.08e-04 3.04e-0401 St.Agnes 8 1 Chromium 5.11e-04 2.55e-0401 St.Agnes 8 1 Hydrogen Chloride 1.55e+01 7.73e+0001 St.Agnes 8 2 Hydrogen Chloride 1.20e+01 5.99e+0001 St.Agnes 8 2 Iron 3.98e-03 1.99e-0301 St.Agnes 8 1 Iron 1.02e-02 5.08e-0301 St.Agnes 8 3 Iron 8.40e-03 4.20e-0301 St.Agnes 8 1 Lead 5.59e-02 2.80e-0201 St.Agnes 8 2 Lead 3.10e-02 1.55e-0201 St.Agnes 8 3 Lead 4.31e-02 2.16e-0201 St.Agnes 8 3 Manganese 2.76e-04 1.38e-0401 St.Agnes 8 2 Manganese 1.58e-04 7.92e-0501 St.Agnes 8 1 Manganese 3.93e-04 1.97e-0401 St.Agnes 8 3 Nickel 2.81e-04 1.40e-0401 St.Agnes 8 2 Nickel 1.58e-04 7.92e-0501 St.Agnes 8 1 Nickel 2.76e-04 1.38e-0401 St.Agnes 8 9 Oxides of Nitrogen 1.80e+00 8.98e-0101 St.Agnes 8 3 Particulate Matter 4.87e+00 2.44e+0001 St.Agnes 8 2 Particulate Matter 4.64e+00 2.32e+0001 St.Agnes 8 1 Particulate Matter 4.90e+00 2.45e+0001 St.Agnes 8 7 Sulfur Dioxide 3.17e-01 1.58e-0101 St.Agnes 8 6 Sulfur Dioxide 3.17e-01 1.58e-0101 St.Agnes 8 5 Sulfur Dioxide 3.37e-01 1.69e-0101 St.Agnes 8 1 Sulfur Dioxide 6.64e-01 3.32e-0101 St.Agnes 8 9 Sulfur Dioxide 3.23e-01 1.61e-01

01 St.Agnes 8 2 Sulfur Dioxide 3.90e-01 1.95e-0101 St.Agnes 8 3 Sulfur Dioxide 3.90e-01 1.95e-0101 St.Agnes 8 4 Sulfur Dioxide 7.29e-01 3.65e-0101 St.Agnes 8 8 Sulfur Dioxide 3.43e-01 1.71e-0101 St.Agnes 8 1 Total CDD 1.25e-05 6.26e-0601 St.Agnes 8 2 Total CDD 7.64e-06 3.82e-0601 St.Agnes 8 1 Total CDF 2.19e-05 1.09e-0501 St.Agnes 8 2 Total CDF 1.85e-05 9.26e-0601 St.Agnes 8 9 Total Hydrocarbons 1.11e-02 5.55e-0301 St.Agnes 8 4 Total Hydrocarbons 5.58e-02 2.79e-0201 St.Agnes 8 2 Total Hydrocarbons 4.88e-02 2.44e-0201 St.Agnes 8 6 Total Hydrocarbons 4.67e-02 2.34e-0201 St.Agnes 8 1 Total Hydrocarbons 4.15e-02 2.08e-0201 St.Agnes 8 3 Total Hydrocarbons 4.88e-02 2.44e-0201 St.Agnes 8 8 Total Hydrocarbons 4.91e-02 2.46e-0201 St.Agnes 8 5 Total Hydrocarbons 5.16e-02 2.58e-0201 St.Agnes 8 7 Total Hydrocarbons 4.67e-02 2.34e-0201 St.Agnes 8 1 Total TCDD 1.07e-06 5.36e-0701 St.Agnes 8 2 Total TCDD 8.76e-08 4.38e-0801 St.Agnes 8 2 Total TCDF 2.07e-06 1.03e-0601 St.Agnes 8 1 Total TCDF 1.81e-06 9.04e-0701 Sutter 9 1 2,3,7,8-TCDD 6.42e-09 3.21e-0901 Sutter 9 3 2,3,7,8-TCDD 4.52e-09 2.26e-0901 Sutter 9 2 2,3,7,8-TCDD 3.55e-09 1.77e-0901 Sutter 9 1 2,3,7,8-TCDF 1.74e-07 8.71e-0801 Sutter 9 2 2,3,7,8-TCDF 1.57e-07 7.84e-0801 Sutter 9 3 2,3,7,8-TCDF 1.95e-07 9.76e-0801 Sutter 9 1 Cadmium 3.62e-03 1.81e-03

01 Sutter 9 2 Cadmium 3.71e-03 1.86e-0301 Sutter 9 3 Carbon Monoxide 2.78e+00 1.39e+0001 Sutter 9 2 Carbon Monoxide 2.78e+00 1.39e+0001 Sutter 9 1 Carbon Monoxide 1.97e+00 9.86e-0101 Sutter 9 4 Carbon Monoxide 3.41e+00 1.71e+0001 Sutter 9 1 Chromium 3.96e-04 1.98e-0401 Sutter 9 2 Chromium 6.29e-04 3.14e-0401 Sutter 9 2 Hydrogen Chloride 5.96e-06 2.98e-0601 Sutter 9 1 Hydrogen Chloride 2.35e+01 1.18e+0101 Sutter 9 1 Iron 8.24e-03 4.12e-0301 Sutter 9 2 Iron 5.75e-02 2.87e-0201 Sutter 9 1 Lead 3.42e-02 1.71e-0201 Sutter 9 2 Lead 6.67e-02 3.33e-0201 Sutter 9 2 Manganese 1.38e-03 6.91e-0401 Sutter 9 1 Manganese 4.34e-04 2.17e-0401 Sutter 9 1 Nickel 4.95e-04 2.47e-0401 Sutter 9 2 Nickel 4.30e-04 2.15e-0401 Sutter 9 4 Oxides of Nitrogen 4.38e+00 2.19e+0001 Sutter 9 1 Oxides of Nitrogen 2.49e+00 1.25e+0001 Sutter 9 3 Oxides of Nitrogen 3.43e+00 1.71e+0001 Sutter 9 2 Oxides of Nitrogen 4.04e+00 2.02e+0001 Sutter 9 2 Particulate Matter 7.48e+00 3.74e+0001 Sutter 9 1 Particulate Matter 5.91e+00 2.95e+0001 Sutter 9 4 Sulfur Dioxide 1.34e+00 6.71e-0101 Sutter 9 1 Sulfur Dioxide 1.33e+00 6.67e-0101 Sutter 9 2 Sulfur Dioxide 8.12e-01 4.06e-0101 Sutter 9 2 Total CDD 3.09e-05 1.55e-0501 Sutter 9 1 Total CDD 2.79e-05 1.39e-05

01 Sutter 9 3 Total CDD 3.24e-05 1.62e-0501 Sutter 9 1 Total CDF 5.40e-05 2.70e-0501 Sutter 9 2 Total CDF 5.92e-05 2.96e-0501 Sutter 9 3 Total CDF 6.11e-05 3.05e-0501 Sutter 9 2 Total Hydrocarbons 8.60e-02 4.30e-0201 Sutter 9 1 Total Hydrocarbons 5.51e-02 2.75e-0201 Sutter 9 3 Total Hydrocarbons 8.21e-02 4.11e-0201 Sutter 9 4 Total Hydrocarbons 5.03e-01 2.52e-0101 Sutter 9 2 Total TCDD 6.78e-07 3.39e-0701 Sutter 9 1 Total TCDD 6.80e-07 3.40e-0701 Sutter 9 3 Total TCDD 1.07e-06 5.37e-0701 Sutter 9 3 Total TCDF 8.26e-06 4.13e-0601 Sutter 9 2 Total TCDF 8.16e-06 4.08e-0601 Sutter 9 1 Total TCDF 8.81e-06 4.40e-0601 Swedish 10 1 Carbon Monoxide 2.82e-01 1.41e-0101 Swedish 10 1 Hydrogen Chloride 2.40e+01 1.20e+0101 Swedish 10 2 Hydrogen Chloride 2.58e+01 1.29e+0101 Swedish 10 1 Particulate Matter 5.83e+00 2.91e+0001 Swedish 10 3 Particulate Matter 4.00e+00 2.00e+0001 Swedish-America

n10 2 Particulate Matter 1.51e+00 7.56e-01

01 USC 11 4 2,3,7,8-TCDD 6.62e-08 3.31e-0801 USC 11 3 2,3,7,8-TCDD 3.00e-08 1.50e-0801 USC 11 1 2,3,7,8-TCDD 1.33e-07 6.64e-0801 USC 11 1 2,3,7,8-TCDF 6.36e-07 3.18e-0701 USC 11 4 2,3,7,8-TCDF 5.22e-07 2.61e-0701 USC 11 3 2,3,7,8-TCDF 3.63e-07 1.81e-0701 USC 11 2 Arsenic 9.21e-05 4.61e-05

01 USC 11 1 Arsenic 4.00e-05 2.00e-0501 USC 11 4 Arsenic 3.24e-05 1.62e-0501 USC 11 1 Cadmium 7.38e-03 3.69e-0301 USC 11 2 Cadmium 6.39e-03 3.19e-0301 USC 11 4 Cadmium 1.84e-03 9.21e-0401 USC 11 2 Chromium 5.15e-04 2.58e-0401 USC 11 1 Chromium 3.38e-04 1.69e-0401 USC 11 4 Chromium 2.84e-04 1.42e-0401 USC 11 4 Hydrogen Chloride 6.73e+01 3.36e+0101 USC 11 1 Hydrogen Chloride 1.85e+02 9.27e+0101 USC 11 2 Hydrogen Chloride 2.64e+02 1.32e+0201 USC 11 1 Iron 3.03e-02 1.52e-0201 USC 11 2 Iron 2.13e-02 1.06e-0201 USC 11 4 Iron 9.19e-03 4.59e-0301 USC 11 2 Lead 1.71e-01 8.54e-0201 USC 11 1 Lead 2.40e-01 1.20e-0101 USC 11 4 Lead 6.35e-02 3.17e-0201 USC 11 2 Manganese 4.74e-04 2.37e-0401 USC 11 1 Manganese 5.26e-04 2.63e-0401 USC 11 4 Manganese 2.56e-04 1.28e-0401 USC 11 2 Mercury 5.16e-02 2.58e-0201 USC 11 3 Mercury 1.98e-02 9.92e-0301 USC 11 1 Mercury 1.83e+00 9.14e-0101 USC 11 2 Nickel 6.24e-04 3.12e-0401 USC 11 1 Nickel 3.57e-04 1.79e-0401 USC 11 4 Nickel 4.27e-04 2.13e-0401 USC 11 3 Oxides of Nitrogen 4.42e+00 2.21e+0001 USC 11 9 Oxides of Nitrogen 5.03e+00 2.52e+00

01 USC 11 15 Oxides of Nitrogen 6.11e+00 3.05e+0001 USC 11 18 Oxides of Nitrogen 5.62e+00 2.81e+0001 USC 11 16 Oxides of Nitrogen 6.11e+00 3.05e+0001 USC 11 19 Oxides of Nitrogen 4.91e+00 2.46e+0001 USC 11 10 Oxides of Nitrogen 1.11e+01 5.55e+0001 USC 11 4 Oxides of Nitrogen 3.81e+00 1.91e+0001 USC 11 12 Oxides of Nitrogen 9.00e+00 4.50e+0001 USC 11 8 Oxides of Nitrogen 4.42e+00 2.21e+0001 USC 11 13 Oxides of Nitrogen 7.91e+00 3.96e+0001 USC 11 2 Oxides of Nitrogen 4.26e+00 2.13e+0001 USC 11 20 Oxides of Nitrogen 6.55e+00 3.28e+0001 USC 11 1 Oxides of Nitrogen 4.81e+00 2.40e+0001 USC 11 7 Oxides of Nitrogen 5.64e+00 2.82e+0001 USC 11 17 Oxides of Nitrogen 4.16e+00 2.08e+0001 USC 11 14 Oxides of Nitrogen 6.80e+00 3.40e+0001 USC 11 5 Oxides of Nitrogen 4.59e+00 2.29e+0001 USC 11 6 Oxides of Nitrogen 4.15e+00 2.07e+0001 USC 11 11 Oxides of Nitrogen 9.00e+00 4.50e+0001 USC 11 3 Particulate Matter 4.74e+00 2.37e+0001 USC 11 1 Particulate Matter 2.32e+01 1.16e+0101 USC 11 2 Particulate Matter 5.82e+00 2.91e+0001 USC 11 2 PM 10.0 8.31e-01 4.16e-0101 USC 11 1 PM 10.0 9.22e+00 4.61e+0001 USC 11 3 PM 10.0 1.87e+00 9.33e-0101 USC 11 3 PM 1.0 4.07e-02 2.04e-0201 USC 11 1 PM 1.0 1.09e-01 5.44e-0201 USC 11 2 PM 1.0 1.46e-02 7.28e-0301 USC 11 3 PM 2.5 6.81e-01 3.40e-01

01 USC 11 2 PM 2.5 1.15e-01 5.76e-0201 USC 11 1 PM 2.5 1.31e+00 6.53e-0101 USC 11 2 PM 5.0 3.52e-01 1.76e-0101 USC 11 3 PM 5.0 1.28e+00 6.39e-0101 USC 11 1 PM 5.0 4.03e+00 2.01e+0001 USC 11 2 PM .625 5.82e-03 2.91e-0301 USC 11 1 PM .625 4.12e-02 2.06e-0201 USC 11 3 PM .625 1.23e-02 6.16e-0301 USC 11 8 Sulfur Dioxide 4.31e+00 2.16e+0001 USC 11 19 Sulfur Dioxide 1.30e+00 6.52e-0101 USC 11 14 Sulfur Dioxide 1.93e-01 9.66e-0201 USC 11 18 Sulfur Dioxide 1.47e+00 7.33e-0101 USC 11 6 Sulfur Dioxide 2.16e+00 1.08e+0001 USC 11 7 Sulfur Dioxide 2.46e+00 1.23e+0001 USC 11 9 Sulfur Dioxide 2.46e+00 1.23e+0001 USC 11 2 Sulfur Dioxide 3.56e+01 1.78e+0101 USC 11 11 Sulfur Dioxide 4.80e+00 2.40e+0001 USC 11 13 Sulfur Dioxide 2.71e+00 1.35e+0001 USC 11 4 Sulfur Dioxide 2.46e+00 1.23e+0001 USC 11 20 Sulfur Dioxide 1.63e-01 8.15e-0201 USC 11 5 Sulfur Dioxide 7.70e-02 3.85e-0201 USC 11 1 Sulfur Dioxide 3.56e+01 1.78e+0101 USC 11 15 Sulfur Dioxide 1.93e+00 9.66e-0101 USC 11 3 Sulfur Dioxide 2.46e+00 1.23e+0001 USC 11 17 Sulfur Dioxide 1.93e-01 9.66e-0201 USC 11 16 Sulfur Dioxide 1.93e+00 9.66e-0101 USC 11 10 Sulfur Dioxide 7.47e+00 3.73e+0001 USC 11 12 Sulfur Dioxide 4.80e+00 2.40e+00

01 USC 11 1 Total CDD 3.21e-05 1.61e-0501 USC 11 4 Total CDD 6.37e-05 3.18e-0501 USC 11 3 Total CDD 7.87e-05 3.93e-0501 USC 11 4 Total CDF 1.96e-04 9.82e-0501 USC 11 1 Total CDF 1.17e-04 5.87e-0501 USC 11 3 Total CDF 1.66e-04 8.32e-0501 USC 11 3 Total TCDD 4.26e-07 2.13e-0701 USC 11 4 Total TCDD 3.64e-07 1.82e-0701 USC 11 1 Total TCDD 8.10e-07 4.05e-0701 USC 11 4 Total TCDF 7.18e-06 3.59e-0601 USC 11 1 Total TCDF 9.25e-06 4.63e-0601 USC 11 3 Total TCDF 4.27e-06 2.13e-0602 ERA Tech 17 3 Hydrogen Chloride 2.22e+00 1.11e+0002 ERA Tech 27 2 Hydrogen Chloride 7.29e-01 3.65e-0102 ERA Tech 27 1 Hydrogen Chloride 6.74e-01 3.37e-0102 ERA Tech 17 2 Hydrogen Chloride 2.85e+00 1.42e+0002 ERA Tech 27 3 Hydrogen Chloride 7.66e-01 3.83e-0102 ERA Tech 17 1 Hydrogen Chloride 4.14e+00 2.07e+0002 ERA Tech 17 2 Particulate Matter 1.35e+00 6.74e-0102 ERA Tech 17 1 Particulate Matter 1.29e+00 6.45e-0102 ERA Tech 27 2 Particulate Matter 5.71e-01 2.86e-0102 ERA Tech 27 3 Particulate Matter 5.81e-01 2.91e-0102 ERA Tech 27 1 Particulate Matter 5.57e-01 2.78e-0102 ERA Tech 17 3 Particulate Matter 1.11e+00 5.54e-0102 Jordan 3 5 2,3,7,8-TCDD 6.87e-08 3.43e-0802 Jordan 3 3 2,3,7,8-TCDD 1.49e-07 7.46e-0802 Jordan 3 1 2,3,7,8-TCDD 8.51e-08 4.26e-0802 Jordan 3 5 2,3,7,8-TCDF 6.26e-07 3.13e-07

02 Jordan 3 3 2,3,7,8-TCDF 1.46e-06 7.31e-0702 Jordan 3 1 2,3,7,8-TCDF 9.27e-07 4.64e-0702 Jordan 3 3 Antimony 3.80e-04 1.90e-0402 Jordan 3 1 Antimony 3.04e-04 1.52e-0402 Jordan 3 5 Antimony 2.44e-04 1.22e-0402 Jordan 3 1 Barium 1.85e-04 9.25e-0502 Jordan 3 5 Barium 2.45e-04 1.23e-0402 Jordan 3 3 Barium 1.90e-04 9.50e-0502 Jordan 3 5 Cadmium 1.39e-04 6.94e-0502 Jordan 3 3 Cadmium 1.57e-04 7.83e-0502 Jordan 3 1 Cadmium 2.38e-04 1.19e-0402 Jordan 3 3 Chromium 2.68e-04 1.34e-0402 Jordan 3 1 Chromium 2.81e-04 1.41e-0402 Jordan 3 5 Chromium 2.23e-04 1.12e-0402 Jordan 3 5 Hydrogen Bromide 2.12e-02 1.06e-0202 Jordan 3 1 Hydrogen Bromide 2.52e-02 1.26e-0202 Jordan 3 3 Hydrogen Bromide 1.11e-01 5.54e-0202 Jordan 3 3 Hydrogen Chloride 4.21e+00 2.11e+0002 Jordan 3 5 Hydrogen Chloride 1.27e+00 6.37e-0102 Jordan 3 1 Hydrogen Chloride 2.96e+00 1.48e+0002 Jordan 3 3 Lead 1.23e-03 6.15e-0402 Jordan 3 5 Lead 1.98e-03 9.89e-0402 Jordan 3 1 Lead 1.59e-03 7.93e-0402 Jordan 3 1 Mercury 1.98e-02 9.89e-0302 Jordan 3 5 Mercury 8.36e-03 4.18e-0302 Jordan 3 3 Mercury 6.39e-02 3.19e-0202 Jordan 3 5 Nickel 4.67e-04 2.34e-0402 Jordan 3 1 Nickel 2.05e-04 1.03e-04

02 Jordan 3 3 Nickel 9.18e-04 4.59e-0402 Jordan 3 1 Particulate Matter 7.24e-02 3.62e-0202 Jordan 3 3 Particulate Matter 1.63e-01 8.14e-0202 Jordan 3 5 Particulate Matter 2.46e-01 1.23e-0102 Jordan 3 22 PM 10.0 1.03e+00 5.14e-0102 Jordan 3 3 PM 10.0 3.51e-01 1.75e-0102 Jordan 3 2 PM 10.0 1.83e+00 9.15e-0102 Jordan 3 33 PM 10.0 7.96e-01 3.98e-0102 Jordan 3 22 PM 1.0 1.75e+00 8.74e-0102 Jordan 3 2 PM 1.0 9.47e-01 4.74e-0102 Jordan 3 33 PM 1.0 2.87e-01 1.44e-0102 Jordan 3 3 PM 1.0 7.33e-01 3.66e-0102 Jordan 3 3 PM 2.5 7.61e-01 3.81e-0102 Jordan 3 33 PM 2.5 3.15e-01 1.58e-0102 Jordan 3 2 PM 2.5 9.99e-01 5.00e-0102 Jordan 3 22 PM 2.5 1.80e+00 9.00e-0102 Jordan 3 33 PM 5.0 7.92e-01 3.96e-0102 Jordan 3 2 PM 5.0 1.01e+00 5.06e-0102 Jordan 3 3 PM 5.0 3.47e-01 1.73e-0102 Jordan 3 22 PM 5.0 1.81e+00 9.07e-0102 Jordan 3 2 PM .625 1.67e+00 8.36e-0102 Jordan 3 3 PM .625 2.68e-01 1.34e-0102 Jordan 3 33 PM .625 7.13e-01 3.57e-0102 Jordan 3 22 PM .625 8.71e-01 4.35e-0102 Jordan 3 5 Silver 2.56e-05 1.28e-0502 Jordan 3 1 Silver 4.34e-04 2.17e-0402 Jordan 3 3 Silver 5.48e-05 2.74e-0502 Jordan 3 1 Sulfur Dioxide 5.18e-01 2.59e-01

02 Jordan 3 3 Sulfur Dioxide 1.44e-01 7.19e-0202 Jordan 3 5 Sulfur Dioxide 4.64e-01 2.32e-0102 Jordan 3 3 Total CDD 1.46e-04 7.29e-0502 Jordan 3 1 Total CDD 9.11e-05 4.55e-0502 Jordan 3 5 Total CDD 7.75e-05 3.88e-0502 Jordan 3 5 Total CDF 8.95e-05 4.47e-0502 Jordan 3 3 Total CDF 2.06e-04 1.03e-0402 Jordan 3 1 Total CDF 1.18e-04 5.88e-0502 Jordan 3 1 Total TCDD 3.59e-05 1.80e-0502 Jordan 3 3 Total TCDD 5.09e-05 2.54e-0502 Jordan 3 5 Total TCDD 3.62e-05 1.81e-0502 Jordan 3 3 Total TCDF 9.97e-05 4.98e-0502 Jordan 3 5 Total TCDF 5.18e-05 2.59e-0502 Jordan 3 1 Total TCDF 6.69e-05 3.35e-0503 Cedars Sinai 7 2 2,3,7,8-TCDD 8.26e-09 4.13e-0903 Cedars Sinai 7 1 2,3,7,8-TCDD 5.18e-09 2.59e-0903 Cedars Sinai 7 2 2,3,7,8-TCDF 4.52e-08 2.26e-0803 Cedars Sinai 7 1 2,3,7,8-TCDF 3.17e-08 1.59e-0803 Cedars Sinai 7 1 Arsenic 4.08e-08 2.04e-0803 Cedars Sinai 7 3 Arsenic 3.67e-08 1.84e-0803 Cedars Sinai 7 2 Arsenic 4.08e-08 2.04e-0803 Cedars Sinai 7 3 Carbon Monoxide 1.21e+00 6.04e-0103 Cedars Sinai 7 1 Carbon Monoxide 1.20e+00 6.02e-0103 Cedars Sinai 7 2 Carbon Monoxide 1.20e+00 5.99e-0103 Cedars Sinai 7 2 Chromium 2.45e-06 1.22e-0603 Cedars Sinai 7 1 Chromium 3.24e-06 1.62e-0603 Cedars Sinai 7 3 Chromium 7.55e-07 3.78e-0703 Cedars Sinai 7 1 Hydrogen Chloride 1.63e+01 8.14e+00

03 Cedars Sinai 7 2 Hydrogen Chloride 1.27e+01 6.36e+0003 Cedars Sinai 7 2 Lead 1.02e-04 5.10e-0503 Cedars Sinai 7 1 Lead 1.01e-04 5.07e-0503 Cedars Sinai 7 3 Lead 9.41e-05 4.70e-0503 Cedars Sinai 7 1 Oxides of Nitrogen 4.53e+00 2.26e+0003 Cedars Sinai 7 2 Oxides of Nitrogen 3.38e+00 1.69e+0003 Cedars Sinai 7 3 Oxides of Nitrogen 2.73e+00 1.36e+0003 Cedars Sinai 7 1 Particulate Matter 6.12e-02 3.06e-0203 Cedars Sinai 7 3 Particulate Matter 1.02e-01 5.10e-0203 Cedars Sinai 7 2 Particulate Matter 4.08e-02 2.04e-0203 Cedars Sinai 7 2 Sulfur Dioxide 5.35e-01 2.68e-0103 Cedars Sinai 7 1 Sulfur Dioxide 1.17e+00 5.84e-0103 Cedars Sinai 7 3 Sulfur Dioxide 8.31e-01 4.16e-0103 Cedars Sinai 7 2 Total CDD 2.67e-06 1.34e-0603 Cedars Sinai 7 1 Total CDD 2.69e-06 1.34e-0603 Cedars Sinai 7 2 Total CDF 8.99e-06 4.49e-0603 Cedars Sinai 7 1 Total CDF 8.02e-06 4.01e-0603 Cedars Sinai 7 1 Total Hydrocarbons 1.12e-01 5.62e-0203 Cedars Sinai 7 3 Total Hydrocarbons 4.90e-02 2.45e-0203 Cedars Sinai 7 2 Total Hydrocarbons 4.42e-02 2.21e-0203 Cedars Sinai 7 2 Total TCDD 1.21e-07 6.03e-0803 Cedars Sinai 7 1 Total TCDD 1.26e-07 6.31e-0803 Cedars Sinai 7 1 Total TCDF 1.17e-06 5.85e-0703 Cedars Sinai 7 2 Total TCDF 1.38e-06 6.92e-0703 Therm-Tec 33 2 Hydrogen Chloride 6.54e-01 3.27e-0103 Therm-Tec 30 3 Hydrogen Chloride 1.49e+00 7.44e-0103 Therm-Tec 30 2 Hydrogen Chloride 1.84e+00 9.18e-0103 Therm-Tec 33 3 Hydrogen Chloride 7.35e-01 3.68e-01

03 Therm-Tec 33 1 Hydrogen Chloride 6.65e-01 3.32e-0103 Therm-Tec 30 1 Hydrogen Chloride 1.97e+00 9.84e-0103 Therm-Tec 33 1 Particulate Matter 4.31e-01 2.16e-0103 Therm-Tec 30 3 Particulate Matter 1.84e-01 9.18e-0203 Therm-Tec 30 2 Particulate Matter 1.01e-01 5.07e-0203 Therm-Tec 33 3 Particulate Matter 1.43e-01 7.15e-0203 Therm-Tec 33 2 Particulate Matter 2.62e-01 1.31e-0103 Therm-Tec 30 1 Particulate Matter 2.52e-01 1.26e-0104 Bio-Medical

Servi31 2 Hydrogen Chloride 5.69e-02 2.85e-02

04 Bio-MedicalServi

31 1 Hydrogen Chloride 7.59e-02 3.80e-02

04 Bio-MedicalServi


04 Bio-MedicalServi

31 2 Particulate Matter 1.21e+00 6.07e-01

04 Bio-MedicalServi


04 Bio-MedicalServi


04 Bio-Waste Mgmt.C


04 Bio-Waste Mgmt.C


04 Bio-Waste Mgmt.C


04 Bio-Waste Mgmt.C


04 Bio-Waste Mgmt.C

23 5 Particulate Matter 8.10e-01 4.05e-01

04 Bio-Waste Mgmt.C


04 Bio-Waste Mgmt.C


04 Bio-Waste Mgmt.C

23 4 Particulate Matter 8.20e-01 4.10e-01

04 Hershey 18 2 1,2,3,4,6,7,8-HpCDD 1.41e-08 7.05e-0904 Hershey 18 3 1,2,3,4,6,7,8-HpCDD 1.34e-08 6.70e-0904 Hershey 18 1 1,2,3,4,6,7,8-HpCDD 1.09e-08 5.46e-0904 Hershey 18 2 1,2,3,4,6,7,8-HpCDF 3.62e-08 1.81e-0804 Hershey 18 1 1,2,3,4,6,7,8-HpCDF 3.23e-08 1.62e-0804 Hershey 18 3 1,2,3,4,6,7,8-HpCDF 3.60e-08 1.80e-0804 Hershey 18 2 1,2,3,4,7,8,9-HpCDF 2.91e-09 1.46e-0904 Hershey 18 1 1,2,3,4,7,8,9-HpCDF 3.23e-09 1.62e-0904 Hershey 18 3 1,2,3,4,7,8,9-HpCDF 4.36e-09 2.18e-0904 Hershey 18 2 1,2,3,4,7,8-HxCDD 5.65e-10 2.82e-1004 Hershey 18 1 1,2,3,4,7,8-HxCDD 5.45e-10 2.73e-1004 Hershey 18 3 1,2,3,4,7,8-HxCDD 6.22e-10 3.11e-1004 Hershey 18 3 1,2,3,4,7,8-HxCDF 1.77e-08 8.86e-0904 Hershey 18 1 1,2,3,4,7,8-HxCDF 1.54e-08 7.69e-0904 Hershey 18 2 1,2,3,4,7,8-HxCDF 1.74e-08 8.71e-0904 Hershey 18 1 1,2,3,6,7,8-HxCDD 1.54e-09 7.69e-1004 Hershey 18 3 1,2,3,6,7,8-HxCDD 2.01e-09 1.00e-0904 Hershey 18 2 1,2,3,6,7,8-HxCDD 1.88e-09 9.40e-1004 Hershey 18 3 1,2,3,6,7,8-HxCDF 6.22e-09 3.11e-0904 Hershey 18 1 1,2,3,6,7,8-HxCDF 6.94e-09 3.47e-09

04 Hershey 18 2 1,2,3,6,7,8-HxCDF 7.06e-09 3.53e-0904 Hershey 18 3 1,2,3,7,8,9-HxCDD 2.69e-09 1.34e-0904 Hershey 18 2 1,2,3,7,8,9-HxCDD 2.16e-09 1.08e-0904 Hershey 18 1 1,2,3,7,8,9-HxCDD 1.99e-09 9.93e-1004 Hershey 18 3 1,2,3,7,8,9-HxCDF 5.27e-10 2.64e-1004 Hershey 18 1 1,2,3,7,8,9-HxCDF 1.99e-10 9.93e-1104 Hershey 18 2 1,2,3,7,8,9-HxCDF 3.29e-10 1.64e-1004 Hershey 18 3 1,2,3,7,8-PeCDD 7.17e-10 3.59e-1004 Hershey 18 2 1,2,3,7,8-PeCDD 6.59e-10 3.30e-1004 Hershey 18 1 1,2,3,7,8-PeCDD 4.48e-10 2.24e-1004 Hershey 18 1 1,2,3,7,8-PeCDF 2.04e-09 1.02e-0904 Hershey 18 2 1,2,3,7,8-PeCDF 2.54e-09 1.27e-0904 Hershey 18 3 1,2,3,7,8-PeCDF 2.11e-10 1.05e-1004 Hershey 18 3 2,3,4,6,7,8-HxCDF 1.87e-08 9.33e-0904 Hershey 18 2 2,3,4,6,7,8-HxCDF 1.84e-08 9.18e-0904 Hershey 18 1 2,3,4,6,7,8-HxCDF 1.84e-08 9.18e-0904 Hershey 18 2 2,3,4,7,8-PeCDF 5.65e-09 2.82e-0904 Hershey 18 3 2,3,4,7,8-PeCDF 6.70e-09 3.35e-0904 Hershey 18 1 2,3,4,7,8-PeCDF 4.62e-09 2.31e-0904 Hershey 18 1 2,3,7,8-TCDD 1.49e-10 7.44e-1104 Hershey 18 3 2,3,7,8-TCDD 1.91e-10 9.57e-1104 Hershey 18 2 2,3,7,8-TCDD 4.70e-11 2.35e-1104 Hershey 18 2 2,3,7,8-TCDF 1.03e-08 5.17e-0904 Hershey 18 3 2,3,7,8-TCDF 9.57e-09 4.79e-0904 Hershey 18 1 2,3,7,8-TCDF 8.93e-09 4.47e-0904 Hershey 18 3 Carbon Monoxide 1.75e-01 8.73e-0204 Hershey 18 1 Carbon Monoxide 2.63e-01 1.32e-0104 Hershey 18 2 Carbon Monoxide 2.32e-01 1.16e-01

04 Hershey 18 1 Hydrogen Chloride 8.46e-01 4.23e-0104 Hershey 18 3 Hydrogen Chloride 2.79e-01 1.40e-0104 Hershey 18 2 Hydrogen Chloride 1.61e-01 8.04e-0204 Hershey 18 1 OCDD 3.98e-08 1.99e-0804 Hershey 18 2 OCDD 6.77e-08 3.38e-0804 Hershey 18 3 OCDD 5.13e-08 2.56e-0804 Hershey 18 3 OCDF 5.35e-08 2.68e-0804 Hershey 18 2 OCDF 7.20e-08 3.60e-0804 Hershey 18 1 OCDF 4.95e-08 2.48e-0804 Hershey 18 1 Particulate Matter 9.58e-01 4.79e-0104 Hershey 18 3 Particulate Matter 9.26e-01 4.63e-0104 Hershey 18 2 Particulate Matter 8.40e-01 4.20e-0104 Hershey 18 3 Sulfur Dioxide 3.06e-02 1.53e-0204 Hershey 18 2 Sulfur Dioxide 3.03e-02 1.51e-0204 Hershey 18 1 Sulfur Dioxide 1.63e-02 8.15e-0304 Kaiser 4 2 2,3,7,8-TCDF 1.97e-08 9.87e-0904 Kaiser 4 1 2,3,7,8-TCDF 1.70e-08 8.49e-0904 Kaiser 4 3 2,3,7,8-TCDF 4.63e-08 2.32e-0804 Kaiser 4 1 Arsenic 1.89e-04 9.46e-0504 Kaiser 4 3 Arsenic 3.04e-05 1.52e-0504 Kaiser 4 2 Arsenic 2.08e-04 1.04e-0404 Kaiser 4 3 Cadmium 2.06e-03 1.03e-0304 Kaiser 4 2 Cadmium 9.77e-03 4.88e-0304 Kaiser 4 1 Cadmium 9.09e-03 4.54e-0304 Kaiser 4 5 Carbon Monoxide 4.29e+00 2.15e+0004 Kaiser 4 3 Carbon Monoxide 1.07e+00 5.37e-0104 Kaiser 4 1 Carbon Monoxide 1.43e+00 7.13e-0104 Kaiser 4 4 Carbon Monoxide 1.07e+00 5.37e-01

04 Kaiser 4 6 Carbon Monoxide 2.68e+00 1.34e+0004 Kaiser 4 7 Carbon Monoxide 1.94e-01 9.71e-0204 Kaiser 4 2 Carbon Monoxide 1.43e+00 7.13e-0104 Kaiser 4 3 Chromium 2.66e-04 1.33e-0404 Kaiser 4 1 Chromium 4.90e-04 2.45e-0404 Kaiser 4 2 Chromium 4.83e-04 2.42e-0404 Kaiser 4 3 Hydrogen Chloride 1.74e+00 8.70e-0104 Kaiser 4 2 Hydrogen Chloride 2.14e+00 1.07e+0004 Kaiser 4 1 Hydrogen Chloride 2.06e+00 1.03e+0004 Kaiser 4 2 Iron 1.65e-02 8.26e-0304 Kaiser 4 1 Iron 6.69e-03 3.35e-0304 Kaiser 4 3 Iron 5.18e-03 2.59e-0304 Kaiser 4 3 Lead 3.96e-02 1.98e-0204 Kaiser 4 1 Lead 1.01e-01 5.04e-0204 Kaiser 4 2 Lead 9.77e-02 4.88e-0204 Kaiser 4 2 Manganese 5.83e-04 2.92e-0404 Kaiser 4 3 Manganese 2.61e-04 1.31e-0404 Kaiser 4 1 Manganese 5.55e-04 2.77e-0404 Kaiser 4 3 Mercury 8.86e-04 4.43e-0404 Kaiser 4 2 Mercury 2.43e-02 1.22e-0204 Kaiser 4 1 Mercury 2.12e-02 1.06e-0204 Kaiser 4 3 Nickel 3.21e-04 1.61e-0404 Kaiser 4 2 Nickel 3.90e-04 1.95e-0404 Kaiser 4 1 Nickel 2.71e-04 1.36e-0404 Kaiser 4 5 Oxides of Nitrogen 2.69e+00 1.34e+0004 Kaiser 4 2 Oxides of Nitrogen 1.89e+00 9.47e-0104 Kaiser 4 3 Oxides of Nitrogen 2.03e+00 1.01e+0004 Kaiser 4 1 Oxides of Nitrogen 1.65e+00 8.26e-01

04 Kaiser 4 7 Oxides of Nitrogen 2.20e+00 1.10e+0004 Kaiser 4 6 Oxides of Nitrogen 2.47e+00 1.23e+0004 Kaiser 4 4 Oxides of Nitrogen 1.92e+00 9.60e-0104 Kaiser 4 3 Particulate Matter 1.66e+00 8.28e-0104 Kaiser 4 2 Particulate Matter 6.80e+00 3.40e+0004 Kaiser 4 1 Particulate Matter 6.08e+00 3.04e+0004 Kaiser 4 1 PM 10.0 2.63e+00 1.31e+0004 Kaiser 4 2 PM 10.0 4.34e+00 2.17e+0004 Kaiser 4 1 PM 1.0 1.22e-03 6.08e-0404 Kaiser 4 2 PM 1.0 1.63e-02 8.16e-0304 Kaiser 4 2 PM 2.5 5.23e-01 2.62e-0104 Kaiser 4 1 PM 2.5 6.93e-02 3.47e-0204 Kaiser 4 2 PM 5.0 1.93e+00 9.66e-0104 Kaiser 4 1 PM 5.0 7.88e-01 3.94e-0104 Kaiser 4 1 PM .625 1.22e-03 6.08e-0404 Kaiser 4 2 PM .625 1.28e-02 6.39e-0304 Kaiser 4 2 Sulfur Dioxide 1.71e+00 8.56e-0104 Kaiser 4 3 Sulfur Dioxide 7.51e-01 3.76e-0104 Kaiser 4 6 Sulfur Dioxide 2.33e+00 1.16e+0004 Kaiser 4 4 Sulfur Dioxide 1.93e+00 9.66e-0104 Kaiser 4 7 Sulfur Dioxide 1.71e+00 8.54e-0104 Kaiser 4 5 Sulfur Dioxide 3.08e+00 1.54e+0004 Kaiser 4 1 Sulfur Dioxide 3.11e+00 1.55e+0004 Kaiser 4 2 Total CDD 4.49e-06 2.25e-0604 Kaiser 4 1 Total CDD 3.51e-06 1.75e-0604 Kaiser 4 3 Total CDD 3.01e-06 1.50e-0604 Kaiser 4 1 Total CDF 8.79e-06 4.39e-0604 Kaiser 4 2 Total CDF 1.22e-05 6.11e-06

04 Kaiser 4 3 Total CDF 8.41e-06 4.20e-0604 Kaiser 4 5 Total Hydrocarbons 1.43e-01 7.16e-0204 Kaiser 4 7 Total Hydrocarbons 1.55e-01 7.77e-0204 Kaiser 4 1 Total Hydrocarbons 1.27e-01 6.34e-0204 Kaiser 4 3 Total Hydrocarbons 1.43e-01 7.16e-0204 Kaiser 4 6 Total Hydrocarbons 1.43e-01 7.16e-0204 Kaiser 4 2 Total Hydrocarbons 1.27e-01 6.34e-0204 Kaiser 4 4 Total Hydrocarbons 1.43e-01 7.16e-0204 Kaiser 4 3 Total TCDD 1.32e-07 6.62e-0804 Kaiser 4 2 Total TCDD 1.01e-08 5.04e-0904 Kaiser 4 1 Total TCDD 1.70e-08 8.49e-0904 Kaiser 4 3 Total TCDF 1.72e-06 8.61e-0704 Kaiser 4 2 Total TCDF 5.24e-07 2.62e-0704 Kaiser 4 1 Total TCDF 3.69e-07 1.85e-0704 Mega 29 2 1,2,3,4,6,7,8-HpCDD 1.25e-09 6.27e-1004 Mega 29 1 1,2,3,4,6,7,8-HpCDD 1.29e-09 6.47e-1004 Mega 29 3 1,2,3,4,6,7,8-HpCDD 6.46e-10 3.23e-1004 Mega 29 2 1,2,3,4,6,7,8-HpCDF 1.87e-09 9.37e-1004 Mega 29 1 1,2,3,4,6,7,8-HpCDF 1.17e-09 5.87e-1004 Mega 29 3 1,2,3,4,6,7,8-HpCDF 4.89e-11 2.45e-1104 Mega 29 1 1,2,3,4,7,8-HxCDF 7.99e-10 3.99e-1004 Mega 29 2 1,2,3,4,7,8-HxCDF 1.50e-09 7.50e-1004 Mega 29 3 1,2,3,4,7,8-HxCDF 9.29e-10 4.65e-1004 Mega 29 2 1,2,3,6,7,8-HxCDF 8.46e-10 4.23e-1004 Mega 29 3 1,2,3,6,7,8-HxCDF 3.91e-11 1.96e-1104 Mega 29 1 1,2,3,6,7,8-HxCDF 3.63e-11 1.82e-1104 Mega 29 3 1,2,3,7,8-PeCDF 5.97e-10 2.98e-1004 Mega 29 2 1,2,3,7,8-PeCDF 8.46e-10 4.23e-10

04 Mega 29 1 1,2,3,7,8-PeCDF 3.63e-11 1.82e-1104 Mega 29 1 2,3,4,6,7,8-HxCDF 5.93e-10 2.96e-1004 Mega 29 2 2,3,4,6,7,8-HxCDF 7.93e-10 3.96e-1004 Mega 29 3 2,3,4,6,7,8-HxCDF 7.73e-10 3.86e-1004 Mega 29 2 2,3,4,7,9-PeCDF 1.35e-09 6.75e-1004 Mega 29 3 2,3,4,7,9-PeCDF 3.91e-11 1.96e-1104 Mega 29 1 2,3,4,7,9-PeCDF 3.63e-11 1.82e-1104 Mega 29 1 2,3,7,8-TCDF 3.87e-10 1.94e-1004 Mega 29 2 2,3,7,8-TCDF 6.64e-10 3.32e-1004 Mega 29 3 2,3,7,8-TCDF 4.50e-10 2.25e-1004 Mega 29 2 Arsenic 3.06e-05 1.53e-0504 Mega 29 1 Arsenic 2.97e-05 1.49e-0504 Mega 29 3 Arsenic 3.79e-05 1.90e-0504 Mega 29 1 Cadmium 2.71e-03 1.35e-0304 Mega 29 3 Cadmium 1.25e-02 6.26e-0304 Mega 29 2 Cadmium 2.32e-03 1.16e-0304 Mega 29 2 Chromium 1.34e-03 6.72e-0404 Mega 29 3 Chromium 1.97e-03 9.86e-0404 Mega 29 1 Chromium 2.56e-03 1.28e-0304 Mega 29 4 Hydrogen Chloride 2.88e-02 1.44e-0204 Mega 29 5 Hydrogen Chloride 7.36e-02 3.68e-0204 Mega 29 6 Hydrogen Chloride 1.55e-02 7.76e-0304 Mega 29 3 Lead 1.52e-01 7.59e-0204 Mega 29 2 Lead 1.04e-01 5.19e-0204 Mega 29 1 Lead 1.16e-01 5.80e-0204 Mega 29 1 Mercury 4.16e-03 2.08e-0304 Mega 29 3 Mercury 5.69e-03 2.84e-0304 Mega 29 2 Mercury 9.47e-03 4.74e-03

04 Mega 29 1 Nickel 1.46e-03 7.28e-0404 Mega 29 3 Nickel 4.17e-03 2.09e-0304 Mega 29 2 Nickel 1.99e-03 9.93e-0404 Mega 29 3 Other HpCDD 0.00e+00 0.00e+0004 Mega 29 1 Other HpCDD 1.03e-09 5.14e-1004 Mega 29 2 Other HpCDD 1.72e-09 8.62e-1004 Mega 29 2 Other HpCDF 1.09e-09 5.46e-1004 Mega 29 1 Other HpCDF 1.05e-09 5.26e-1004 Mega 29 3 Other HpCDF 0.00e+00 0.00e+0004 Mega 29 3 Other HxCDD 9.69e-10 4.84e-1004 Mega 29 2 Other HxCDD 8.46e-10 4.23e-1004 Mega 29 1 Other HxCDD 8.47e-11 4.24e-1104 Mega 29 3 Other HxCDF 2.24e-09 1.12e-0904 Mega 29 2 Other HxCDF 4.32e-09 2.16e-0904 Mega 29 1 Other HxCDF 2.18e-09 1.09e-0904 Mega 29 3 Other PeCDD 5.48e-10 2.74e-1004 Mega 29 1 Other PeCDD 0.00e+00 0.00e+0004 Mega 29 2 Other PeCDD 8.89e-10 4.44e-1004 Mega 29 2 Other PeCDF 9.18e-09 4.59e-0904 Mega 29 3 Other PeCDF 3.22e-09 1.61e-0904 Mega 29 1 Other PeCDF 3.24e-09 1.62e-0904 Mega 29 2 Other TCDD 0.00e+00 0.00e+0004 Mega 29 1 Other TCDD 2.30e-10 1.15e-1004 Mega 29 3 Other TCDD 3.23e-10 1.62e-1004 Mega 29 3 Other TCDF 1.29e-08 6.46e-0904 Mega 29 1 Other TCDF 1.45e-08 7.27e-0904 Mega 29 2 Other TCDF 2.42e-08 1.21e-0804 Mega 29 6 Particulate Matter 3.07e+00 1.54e+00

04 Mega 29 5 Particulate Matter 2.48e+00 1.24e+0004 Mega 29 4 Particulate Matter 3.25e+00 1.63e+0004 Mega 29 3 Silver 4.17e-04 2.09e-0404 Mega 29 1 Silver 1.49e-04 7.43e-0504 Mega 29 2 Silver 7.33e-04 3.67e-0404 Mega 29 2 Total HpCDD 2.98e-09 1.49e-0904 Mega 29 3 Total HpCDD 6.46e-10 3.23e-1004 Mega 29 1 Total HpCDD 2.32e-09 1.16e-0904 Mega 29 3 Total HpCDF 2.54e-10 1.27e-1004 Mega 29 1 Total HpCDF 2.34e-09 1.17e-0904 Mega 29 2 Total HpCDF 3.15e-09 1.57e-0904 Mega 29 2 Total HxCDD 1.19e-09 5.94e-1004 Mega 29 3 Total HxCDD 1.31e-09 6.56e-1004 Mega 29 1 Total HxCDD 2.66e-10 1.33e-1004 Mega 29 1 Total HxCDF 3.68e-09 1.84e-0904 Mega 29 2 Total HxCDF 7.57e-09 3.79e-0904 Mega 29 3 Total HxCDF 4.05e-09 2.03e-0904 Mega 29 3 Total OCDD 0.00e+00 0.00e+0004 Mega 29 1 Total OCDD 0.00e+00 0.00e+0004 Mega 29 2 Total OCDD 0.00e+00 0.00e+0004 Mega 29 1 Total OCDF 1.45e-10 7.26e-1104 Mega 29 2 Total OCDF 1.93e-10 9.64e-1104 Mega 29 3 Total OCDF 1.13e-09 5.67e-1004 Mega 29 1 Total PCDD 3.97e-09 1.98e-0904 Mega 29 2 Total PCDD 5.40e-09 2.70e-0904 Mega 29 3 Total PCDD 3.22e-09 1.61e-0904 Mega 29 1 Total PCDF 2.44e-08 1.22e-0804 Mega 29 2 Total PCDF 4.72e-08 2.36e-08

04 Mega 29 3 Total PCDF 2.26e-08 1.13e-0804 Mega 29 2 Total PeCDD 9.75e-10 4.88e-1004 Mega 29 1 Total PeCDD 4.84e-11 2.42e-1104 Mega 29 3 Total PeCDD 6.36e-10 3.18e-1004 Mega 29 3 Total PeCDF 3.85e-09 1.93e-0904 Mega 29 2 Total PeCDF 1.14e-08 5.69e-0904 Mega 29 1 Total PeCDF 3.32e-09 1.66e-0904 Mega 29 1 Total TCDD 2.66e-10 1.33e-1004 Mega 29 3 Total TCDD 3.82e-10 1.91e-1004 Mega 29 2 Total TCDD 6.43e-11 3.22e-1104 Mega 29 2 Total TCDF 2.49e-08 1.24e-0804 Mega 29 1 Total TCDF 1.49e-08 7.47e-0904 Mega 29 3 Total TCDF 1.34e-08 6.68e-0904 Nazareth 20 1 Antimony 4.08e-04 2.04e-0404 Nazareth 20 2 Antimony 4.08e-04 2.04e-0404 Nazareth 20 1 Cadmium 2.84e-01 1.42e-0104 Nazareth 20 2 Cadmium 1.43e-03 7.14e-0404 Nazareth 20 1 Carbon Monoxide 3.88e-01 1.94e-0104 Nazareth 20 2 Carbon Monoxide 6.53e-01 3.27e-0104 Nazareth 20 2 Chromium 0.00e+00 0.00e+0004 Nazareth 20 1 Chromium 2.04e-04 1.02e-0404 Nazareth 20 2 Hydrogen Chloride 2.04e-02 1.02e-0204 Nazareth 20 1 Hydrogen Chloride 2.04e-02 1.02e-0204 Nazareth 20 2 Lead 6.94e-03 3.47e-0304 Nazareth 20 1 Lead 2.45e-02 1.22e-0204 Nazareth 20 1 Manganese 6.12e-04 3.06e-0404 Nazareth 20 2 Manganese 6.12e-04 3.06e-0404 Nazareth 20 2 Mercury 1.61e-02 8.06e-03

04 Nazareth 20 1 Mercury 4.02e-02 2.01e-0204 Nazareth 20 2 Particulate Matter 5.71e-01 2.86e-0104 Nazareth 20 1 Particulate Matter 6.33e-01 3.16e-0104 Nazareth 20 6 Particulate Matter 6.33e-01 3.16e-0104 Nazareth 20 5 Particulate Matter 6.73e-01 3.37e-0108 Borgess 13 1 2,3,7,8-TCDD 5.61e-10 2.81e-1008 Borgess 13 1 2,3,7,8-TCDF 4.93e-09 2.47e-0908 Borgess 13 1 Aluminum 3.03e-03 1.51e-0308 Borgess 13 1 Antimony 2.10e-04 1.05e-0408 Borgess 13 1 Arsenic 1.19e-05 5.93e-0608 Borgess 13 1 Barium 7.39e-05 3.70e-0508 Borgess 13 1 Cadmium 2.46e-05 1.23e-0508 Borgess 13 1 Carbon Monoxide 7.13e-02 3.57e-0208 Borgess 13 1 Chromium 3.06e-04 1.53e-0408 Borgess 13 1 Copper 1.25e-03 6.25e-0408 Borgess 13 1 Hydrogen Chloride 1.63e+00 8.13e-0108 Borgess 13 1 Lead 6.25e-05 3.12e-0508 Borgess 13 1 Mercury 1.11e-01 5.55e-0208 Borgess 13 1 Nickel 4.54e-04 2.27e-0408 Borgess 13 1 Oxides of Nitrogen 4.97e+00 2.49e+0008 Borgess 13 1 Particulate Matter 8.95e-02 4.48e-0208 Borgess 13 1 Silver 6.65e-05 3.32e-0508 Borgess 13 1 Sulfur Dioxide 3.83e-01 1.92e-0108 Borgess 13 1 Total CDD 3.44e-07 1.72e-0708 Borgess 13 1 Total CDF 1.47e-06 7.37e-0708 Borgess 13 1 Total Hydrocarbons 4.71e-02 2.35e-0208 Borgess 13 1 Total TCDD 6.50e-09 3.25e-0908 Borgess 13 1 Total TCDF 1.39e-07 6.96e-08

08 Erlanger-N 25 3 Carbon Monoxide 1.44e-01 7.18e-0208 Erlanger-N 25 4 Carbon Monoxide 2.17e-01 1.08e-0108 Erlanger-N 25 6 Carbon Monoxide 2.52e+00 1.26e+0008 Erlanger-N 25 5 Carbon Monoxide 6.59e-01 3.29e-0108 Erlanger-N 25 2 Carbon Monoxide 2.55e-01 1.27e-0108 Erlanger-N 25 1 Carbon Monoxide 2.16e-01 1.08e-0108 Erlanger-N 25 1 Hydrogen Chloride 1.29e+01 6.46e+0008 Erlanger-N 25 2 Hydrogen Chloride 8.32e+00 4.16e+0008 Erlanger-N 25 3 Hydrogen Chloride 2.00e+01 9.98e+0008 Erlanger-N 25 6 Hydrogen Chloride 5.26e+01 2.63e+0108 Erlanger-N 25 5 Hydrogen Chloride 3.63e+01 1.81e+0108 Erlanger-N 25 4 Hydrogen Chloride 8.11e+00 4.06e+0008 Erlanger-N 25 6 Oxides of Nitrogen 7.71e+00 3.86e+0008 Erlanger-N 25 5 Oxides of Nitrogen 6.56e+00 3.28e+0008 Erlanger-N 25 2 Particulate Matter 2.60e-01 1.30e-0108 Erlanger-N 25 6 Particulate Matter 3.20e-01 1.60e-0108 Erlanger-N 25 1 Particulate Matter 1.90e-01 9.50e-0208 Erlanger-N 25 4 Particulate Matter 4.10e-01 2.05e-0108 Erlanger-N 25 5 Particulate Matter 2.70e-01 1.35e-0108 Erlanger-N 25 3 Particulate Matter 3.60e-01 1.80e-0108 Erlanger-S 19 2 Carbon Monoxide 7.83e-01 3.92e-0108 Erlanger-S 19 5 Carbon Monoxide 1.15e+00 5.76e-0108 Erlanger-S 19 3 Carbon Monoxide 6.92e-01 3.46e-0108 Erlanger-S 19 1 Carbon Monoxide 8.02e-01 4.01e-0108 Erlanger-S 19 5 Hydrogen Chloride 3.68e+01 1.84e+0108 Erlanger-S 19 1 Hydrogen Chloride 9.44e+00 4.72e+0008 Erlanger-S 19 3 Hydrogen Chloride 2.20e+01 1.10e+0108 Erlanger-S 19 1 Hydrogen Chloride 2.41e+01 1.20e+01

08 Erlanger-S 19 2 Hydrogen Chloride 2.67e+01 1.34e+0108 Erlanger-S 19 3 Hydrogen Chloride 3.40e+01 1.70e+0108 Erlanger-S 19 2 Hydrogen Chloride 2.70e+01 1.35e+0108 Erlanger-S 19 1 Oxides of Nitrogen 7.34e+00 3.67e+0008 Erlanger-S 19 5 Oxides of Nitrogen 6.61e+00 3.31e+0008 Erlanger-S 19 1 Oxides of Nitrogen 6.79e+00 3.40e+0008 Erlanger-S 19 2 Oxides of Nitrogen 7.26e+00 3.63e+0008 Erlanger-S 19 3 Oxides of Nitrogen 5.88e+00 2.94e+0008 Erlanger-S 19 2 Oxides of Nitrogen 7.68e+00 3.84e+0008 Erlanger-S 19 3 Oxides of Nitrogen 7.21e+00 3.60e+0008 Erlanger-S 19 1 Particulate Matter 7.38e-01 3.69e-0108 Erlanger-S 19 2 Particulate Matter 1.01e+00 5.06e-0108 Erlanger-S 19 5 Particulate Matter 2.31e-01 1.15e-0108 Erlanger-S 19 1 Particulate Matter 5.54e-01 2.77e-0108 Erlanger-S 19 2 Particulate Matter 3.49e-01 1.74e-0108 Erlanger-S 19 3 Particulate Matter 9.30e-01 4.65e-0108 Erlanger-S 19 3 Particulate Matter 5.32e-01 2.66e-0108 Hamot 34 1 Hydrogen Chloride 4.91e-01 2.45e-0108 Hamot 34 2 Hydrogen Chloride 6.50e-01 3.25e-0108 Hamot 34 3 Hydrogen Chloride 7.99e-01 4.00e-0109 Borgess 13 2 2,3,7,8-TCDF 9.26e-10 4.63e-1009 Borgess 13 3 2,3,7,8-TCDF 5.36e-10 2.68e-1009 Borgess 13 3 Aluminum 2.94e-03 1.47e-0309 Borgess 13 2 Aluminum 3.04e-03 1.52e-0309 Borgess 13 3 Antimony 1.49e-04 7.44e-0509 Borgess 13 2 Antimony 1.53e-04 7.63e-0509 Borgess 13 3 Arsenic 1.24e-05 6.18e-0609 Borgess 13 2 Arsenic 1.69e-05 8.45e-06

09 Borgess 13 3 Barium 7.97e-05 3.98e-0509 Borgess 13 2 Barium 6.80e-05 3.40e-0509 Borgess 13 2 Beryllium 3.07e-06 1.53e-0609 Borgess 13 3 Beryllium 4.62e-06 2.31e-0609 Borgess 13 3 Cadmium 1.66e-04 8.32e-0509 Borgess 13 2 Cadmium 3.33e-05 1.67e-0509 Borgess 13 3 Carbon Monoxide 5.33e-03 2.66e-0309 Borgess 13 2 Carbon Monoxide 4.84e-03 2.42e-0309 Borgess 13 3 Chromium 1.62e-04 8.09e-0509 Borgess 13 2 Chromium 2.21e-04 1.11e-0409 Borgess 13 2 Copper 2.70e-04 1.35e-0409 Borgess 13 3 Copper 2.80e-04 1.40e-0409 Borgess 13 2 Hydrogen Bromide 6.98e-03 3.49e-0309 Borgess 13 3 Hydrogen Bromide 1.86e-03 9.30e-0409 Borgess 13 3 Hydrogen Chloride 1.01e+00 5.06e-0109 Borgess 13 2 Hydrogen Chloride 7.89e-01 3.95e-0109 Borgess 13 3 Hydrogen Fluoride 5.28e-03 2.64e-0309 Borgess 13 2 Hydrogen Fluoride 2.13e-02 1.07e-0209 Borgess 13 3 Lead 1.12e-04 5.62e-0509 Borgess 13 2 Lead 7.30e-05 3.65e-0509 Borgess 13 3 Mercury 6.06e-03 3.03e-0309 Borgess 13 2 Mercury 1.34e-02 6.71e-0309 Borgess 13 3 Nickel 3.46e-04 1.73e-0409 Borgess 13 2 Nickel 2.21e-04 1.10e-0409 Borgess 13 3 Oxides of Nitrogen 2.07e+00 1.04e+0009 Borgess 13 2 Oxides of Nitrogen 3.72e+00 1.86e+0009 Borgess 13 3 Particulate Matter 8.98e-02 4.49e-0209 Borgess 13 2 Particulate Matter 5.48e-02 2.74e-02

09 Borgess 13 3 Silver 8.32e-05 4.16e-0509 Borgess 13 2 Silver 6.06e-05 3.03e-0509 Borgess 13 3 Sulfur Dioxide 6.77e-01 3.39e-0109 Borgess 13 2 Sulfur Dioxide 7.50e-01 3.75e-0109 Borgess 13 3 Total CDD 3.26e-08 1.63e-0809 Borgess 13 2 Total CDD 7.50e-08 3.75e-0809 Borgess 13 2 Total CDF 1.32e-07 6.58e-0809 Borgess 13 3 Total CDF 5.77e-08 2.89e-0809 Borgess 13 3 Total TCDD 7.90e-10 3.95e-1009 Borgess 13 2 Total TCDD 8.56e-10 4.28e-1009 Borgess 13 3 Total TCDF 7.23e-09 3.61e-0909 Borgess 13 2 Total TCDF 1.31e-08 6.53e-0911 Southland 28 1 2,3,7,8-TCDD 1.69e-10 8.44e-1111 Southland 28 2 2,3,7,8-TCDD 1.72e-10 8.59e-1111 Southland 28 3 2,3,7,8-TCDD 1.78e-10 8.91e-1111 Southland 28 3 2,3,7,8-TCDF 1.28e-09 6.41e-1011 Southland 28 1 2,3,7,8-TCDF 1.74e-09 8.69e-1011 Southland 28 2 2,3,7,8-TCDF 2.18e-09 1.09e-0911 Southland 28 5 Arsenic 3.91e-05 1.95e-0511 Southland 28 4 Arsenic 6.45e-05 3.22e-0511 Southland 28 6 Arsenic 4.69e-05 2.35e-0511 Southland 28 4 Cadmium 7.20e-04 3.60e-0411 Southland 28 5 Cadmium 5.32e-04 2.66e-0411 Southland 28 6 Cadmium 5.29e-04 2.64e-0411 Southland 28 3 Carbon Monoxide 1.38e-02 6.88e-0311 Southland 28 1 Carbon Monoxide 6.25e-03 3.12e-0311 Southland 28 2 Carbon Monoxide 1.25e-03 6.25e-0411 Southland 28 4 Chromium 5.90e-04 2.95e-04

11 Southland 28 5 Chromium 3.44e-04 1.72e-0411 Southland 28 6 Chromium 1.04e-03 5.20e-0411 Southland 28 4 Hydrogen Chloride 2.78e-01 1.39e-0111 Southland 28 6 Hydrogen Chloride 4.56e-01 2.28e-0111 Southland 28 5 Hydrogen Chloride 7.60e-01 3.80e-0111 Southland 28 6 Lead 4.72e-03 2.36e-0311 Southland 28 4 Lead 4.80e-03 2.40e-0311 Southland 28 5 Lead 4.56e-03 2.28e-0311 Southland 28 5 Mercury 5.46e-03 2.73e-0311 Southland 28 6 Mercury 1.54e-02 7.70e-0311 Southland 28 4 Mercury 3.34e-02 1.67e-0211 Southland 28 4 Nickel 5.55e-04 2.78e-0411 Southland 28 6 Nickel 6.21e-04 3.11e-0411 Southland 28 5 Nickel 2.75e-04 1.37e-0411 Southland 28 6 Particulate Matter 9.75e-01 4.88e-0111 Southland 28 5 Particulate Matter 9.80e-01 4.90e-0111 Southland 28 4 Particulate Matter 2.46e-01 1.23e-0112 Hamot 34 3 Cadmium 9.71e-06 4.85e-0612 Hamot 34 2 Cadmium 9.58e-06 4.79e-0612 Hamot 34 1 Cadmium 1.96e-05 9.81e-0612 Hamot 34 2 Chromium 3.79e-05 1.90e-0512 Hamot 34 1 Chromium 3.14e-05 1.57e-0512 Hamot 34 3 Chromium 4.95e-05 2.47e-0512 Hamot 34 2 Hydrogen Chloride 8.31e-02 4.16e-0212 Hamot 34 1 Hydrogen Chloride 5.89e-02 2.94e-0212 Hamot 34 3 Hydrogen Chloride 1.41e-01 7.04e-0212 Hamot 34 2 Lead 6.68e-05 3.34e-0512 Hamot 34 3 Lead 6.85e-05 3.43e-05

12 Hamot 34 1 Lead 1.96e-05 9.81e-0612 Hamot 34 3 Mercury 1.27e-04 6.37e-0512 Hamot 34 2 Mercury 7.05e-04 3.52e-0412 Hamot 34 1 Mercury 2.36e-04 1.18e-0412 Hamot 34 2 Particulate Matter 1.55e+00 7.77e-0112 Hamot 34 1 Particulate Matter 3.43e+00 1.72e+0012 Hamot 34 3 Particulate Matter 3.04e+00 1.52e+0012 Hamot 34 1 Sulfur Dioxide 2.45e-02 1.23e-0212 Hamot 34 3 Sulfur Dioxide 1.71e-02 8.53e-0312 Hamot 34 2 Sulfur Dioxide 3.87e-03 1.94e-0312 Hamot 34 2 Sulfur Trioxide 1.28e-02 6.39e-0312 Hamot 34 3 Sulfur Trioxide 8.53e-04 4.27e-04

35.510638 12 Hamot 34 1 Sulfur Trioxide 1.36e-02 6.79e-03

Type 1 = Controlled Air Incinerator UncontrolledType 2 = Controlled Air Incinerator with Wet Scrubber/FF ControlType 3 = Controlled Air Incinerator with FF OnlyType 4 = Controlled Air Incinerator with Wet Scrubber OnlyType 8 = Controlled Air Incinerator with DSI/FF ControlType 9 = Controlled Air Incinerator with DSI/Carbon Injection/FFType 11 = Controlled Air with DSI/ESPType 12 = Controlled Air with DSI/FF/Wet Scrubber

Emission FactorType Facility Ref. Run Pollutant lb/ton kg/Mg05 Morristown 14 2 2,3,7,8-TCDD 4.91e-10 2.45e-1005 Morristown 14 1 2,3,7,8-TCDD 8.31e-10 4.16e-1005 Morristown 14 2 2,3,7,8-TCDF 5.40e-09 2.70e-0905 Morristown 14 1 2,3,7,8-TCDF 2.81e-08 1.40e-0805 Morristown 14 2 Aluminum 4.94e-01 2.47e-0105 Morristown 14 1 Aluminum 7.31e-01 3.66e-0105 Morristown 14 2 Antimony 2.39e-02 1.19e-0205 Morristown 14 1 Antimony 1.60e-02 7.98e-0305 Morristown 14 2 Arsenic 2.73e-04 1.37e-0405 Morristown 14 1 Arsenic 3.90e-04 1.95e-0405 Morristown 14 2 Barium 7.88e-02 3.94e-0205 Morristown 14 1 Barium 9.97e-02 4.99e-0205 Morristown 14 2 Beryllium 5.00e-05 2.50e-0505 Morristown 14 1 Beryllium 4.63e-05 2.32e-05

05 Morristown 14 2 Cadmium 1.51e-02 7.53e-0305 Morristown 14 1 Cadmium 1.51e-02 7.53e-0305 Morristown 14 2 Carbon Monoxide 2.97e-01 1.49e-0105 Morristown 14 1 Carbon Monoxide 4.67e-01 2.34e-0105 Morristown 14 2 Chromium 4.66e-03 2.33e-0305 Morristown 14 1 Chromium 4.19e-03 2.09e-0305 Morristown 14 2 Copper 2.13e-01 1.07e-0105 Morristown 14 1 Copper 1.77e-01 8.87e-0205 Morristown 14 2 Hydrogen Bromide 6.51e-01 3.25e-0105 Morristown 14 1 Hydrogen Bromide 1.45e+00 7.24e-0105 Morristown 14 2 Hydrogen Chloride 4.53e+01 2.26e+0105 Morristown 14 1 Hydrogen Chloride 4.32e+01 2.16e+0105 Morristown 14 2 Hydrogen Fluoride 1.42e-01 7.11e-0205 Morristown 14 1 Hydrogen Fluoride 4.40e-02 2.20e-0205 Morristown 14 2 Lead 1.37e-01 6.85e-0205 Morristown 14 1 Lead 1.11e-01 5.53e-0205 Morristown 14 2 Mercury 8.06e-02 4.03e-0205 Morristown 14 1 Mercury 9.30e-02 4.65e-0205 Morristown 14 2 Nickel 3.97e-03 1.98e-0305 Morristown 14 1 Nickel 3.09e-03 1.55e-0305 Morristown 14 2 Oxides of Nitrogen 4.46e+00 2.23e+0005 Morristown 14 1 Oxides of Nitrogen 4.80e+00 2.40e+0005 Morristown 14 2 Particulate Matter 3.44e+01 1.72e+0105 Morristown 14 1 Particulate Matter 3.46e+01 1.73e+0105 Morristown 14 2 Silver 2.25e-05 1.13e-0505 Morristown 14 1 Silver 2.38e-04 1.19e-0405 Morristown 14 2 Sulfur Dioxide 1.36e+00 6.79e-0105 Morristown 14 1 Sulfur Dioxide 8.13e-01 4.07e-01

05 Morristown 14 2 Thallium 6.58e-04 3.29e-0405 Morristown 14 1 Thallium 8.58e-04 4.29e-0405 Morristown 14 2 Total CDD 7.19e-07 3.59e-0705 Morristown 14 1 Total CDD 7.80e-07 3.90e-0705 Morristown 14 2 Total CDF 5.00e-06 2.50e-0605 Morristown 14 1 Total CDF 5.40e-06 2.70e-0605 Morristown 14 2 Total Hydrocarbons 5.83e-02 2.91e-0205 Morristown 14 1 Total Hydrocarbons 7.49e-02 3.75e-0205 Morristown 14 2 Total TCDD 7.05e-09 3.53e-0905 Morristown 14 1 Total TCDD 7.40e-09 3.70e-0905 Morristown 14 2 Total TCDF 1.98e-07 9.91e-0805 Morristown 14 1 Total TCDF 3.12e-07 1.56e-0706 Morristown 14 1 2,3,7,8-TCDD 4.52e-10 2.26e-1006 Morristown 14 1 2,3,7,8-TCDF 1.68e-08 8.42e-0906 Morristown 14 1 Aluminum 4.18e-03 2.09e-0306 Morristown 14 1 Antimony 2.31e-04 1.15e-0406 Morristown 14 1 Barium 2.71e-04 1.35e-0406 Morristown 14 1 Beryllium 5.81e-06 2.91e-0606 Morristown 14 1 Cadmium 5.36e-05 2.68e-0506 Morristown 14 1 Carbon Monoxide 3.89e-02 1.94e-0206 Morristown 14 1 Chromium 9.85e-05 4.92e-0506 Morristown 14 1 Copper 6.23e-04 3.12e-0406 Morristown 14 1 Hydrogen Bromide 6.01e-02 3.00e-0206 Morristown 14 1 Hydrogen Chloride 2.68e-01 1.34e-0106 Morristown 14 1 Hydrogen Fluoride 2.99e-02 1.50e-0206 Morristown 14 1 Lead 1.89e-04 9.47e-0506 Morristown 14 1 Mercury 6.65e-02 3.33e-0206 Morristown 14 1 Nickel 8.69e-05 4.34e-05

06 Morristown 14 1 Oxides of Nitrogen 5.25e+00 2.63e+0006 Morristown 14 1 Particulate Matter 3.09e-01 1.54e-0106 Morristown 14 1 Silver 9.23e-05 4.61e-0506 Morristown 14 1 Sulfur Dioxide 6.47e-01 3.24e-0106 Morristown 14 1 Total CDD 5.79e-08 2.90e-0806 Morristown 14 1 Total CDF 7.91e-07 3.96e-0706 Morristown 14 1 Total Hydrocarbons 4.11e-02 2.05e-0206 Morristown 14 1 Total TCDD 4.16e-09 2.08e-0906 Morristown 14 1 Total TCDF 1.92e-07 9.58e-0807 Morristown 14 2 2,3,7,8-TCDD 6.42e-11 3.21e-1107 Morristown 14 2 2,3,7,8-TCDF 4.96e-10 2.48e-1007 Morristown 14 2 Aluminum 2.62e-03 1.31e-0307 Morristown 14 2 Antimony 1.41e-04 7.04e-0507 Morristown 14 2 Barium 1.25e-04 6.25e-0507 Morristown 14 2 Cadmium 2.42e-05 1.21e-0507 Morristown 14 2 Carbon Monoxide 4.99e-02 2.50e-0207 Morristown 14 2 Chromium 7.73e-05 3.86e-0507 Morristown 14 2 Copper 4.11e-04 2.06e-0407 Morristown 14 2 Hydrogen Bromide 1.90e-02 9.48e-0307 Morristown 14 2 Hydrogen Chloride 3.57e-01 1.79e-0107 Morristown 14 2 Lead 7.38e-05 3.69e-0507 Morristown 14 2 Mercury 7.86e-03 3.93e-0307 Morristown 14 2 Nickel 3.58e-05 1.79e-0507 Morristown 14 2 Oxides of Nitrogen 4.91e+00 2.45e+0007 Morristown 14 2 Particulate Matter 7.56e-02 3.78e-0207 Morristown 14 2 Silver 8.05e-05 4.03e-0507 Morristown 14 2 Sulfur Dioxide 3.00e-01 1.50e-0107 Morristown 14 2 Total CDD 2.01e-08 1.01e-08

07 Morristown 14 2 Total CDF 7.57e-08 3.78e-0807 Morristown 14 2 Total Hydrocarbons 5.05e-02 2.53e-0207 Morristown 14 2 Total TCDD 1.55e-10 7.77e-1107 Morristown 14 2 Total TCDF 1.15e-08 5.74e-0910 Safeway Disposal 24 6 Carbon Monoxide 7.03e-02 3.52e-0210 Safeway Disposal 24 5 Carbon Monoxide 2.10e-02 1.05e-0210 Safeway Disposal 24 4 Carbon Monoxide 1.21e-01 6.05e-0210 Safeway Disposal 24 3 Carbon Monoxide 5.55e-02 2.78e-0210 Safeway Disposal 24 2 Carbon Monoxide 5.71e-02 2.86e-0210 Safeway Disposal 24 1 Carbon Monoxide 3.45e-02 1.72e-0210 Safeway Disposal 24 3 Hydrogen Chloride 6.35e+01 3.17e+0110 Safeway Disposal 24 3 Hydrogen Chloride 5.40e-01 2.70e-0110 Safeway Disposal 24 2 Hydrogen Chloride 6.78e+01 3.39e+0110 Safeway Disposal 24 2 Hydrogen Chloride 3.70e-01 1.85e-0110 Safeway Disposal 24 1 Hydrogen Chloride 2.30e-01 1.15e-0110 Safeway Disposal 24 1 Hydrogen Chloride 4.39e+01 2.19e+0110 Safeway Disposal 24 6 Oxides of Nitrogen 4.70e+00 2.35e+0010 Safeway Disposal 24 5 Oxides of Nitrogen 2.51e+00 1.25e+0010 Safeway Disposal 24 4 Oxides of Nitrogen 3.87e+00 1.94e+0010 Safeway Disposal 24 3 Oxides of Nitrogen 5.05e+00 2.52e+0010 Safeway Disposal 24 2 Oxides of Nitrogen 4.08e+00 2.04e+0010 Safeway Disposal 24 1 Oxides of Nitrogen 4.29e+00 2.14e+0010 Safeway Disposal 24 3 Particulate Matter 3.20e-01 1.60e-0110 Safeway Disposal 24 2 Particulate Matter 2.70e-01 1.35e-0110 Safeway Disposal 24 1 Particulate Matter 1.97e+00 9.85e-0110 Safeway Disposal 24 3 Sulfuric Acid 2.00e-02 1.00e-0210 Safeway Disposal 24 3 Sulfuric Acid 1.10e+01 5.50e+0010 Safeway Disposal 24 2 Sulfuric Acid 6.58e-01 3.29e-01

10 Safeway Disposal 24 2 Sulfuric Acid 1.00e-02 5.00e-0310 Safeway Disposal 24 1 Sulfuric Acid 6.15e+00 3.08e+0010 Safeway Disposal 24 1 Sulfuric Acid 3.00e-02 1.50e-0210 Safeway Disposal 24 6 Total Hydrocarbons 4.00e-02 2.00e-0210 Safeway Disposal 24 5 Total Hydrocarbons 0.00e+00 0.00e+0010 Safeway Disposal 24 4 Total Hydrocarbons 0.00e+00 0.00e+0010 Safeway Disposal 24 3 Total Hydrocarbons 9.00e-02 4.50e-0210 Safeway Disposal 24 2 Total Hydrocarbons 0.00e+00 0.00e+0010 Safeway Disposal 24 1 Total Hydrocarbons 0.00e+00 0.00e+00

Type 5 = Rotary Kiln Incinerator UncontrolledType 6 = Rotary Kiln Incinerator with Spray Dryer/FF ControlType 7 = Rotary Kiln Incinerator with Spray Dryer/Carbon Injection/FFType 10 = Rotary Kiln with Wet Scrubber Only

nja.117\ (Reformatted 1/95) 7/93 4-54

Table 4-2. SUMMARY OF ROTARY KILN MWI EMISSION FACTORSON A TEST-BY-TEST BASIS-

nja.117\sect.2-6 4-57

4.2.3 Data Presented in Grains per Dry Standard Cubic Foot (gr/dscf)

For raw data presented in grains per dry standard cubic foot, flue gas flow rates for each

test run in dry standard cubic feet per minute are necessary. When this is the case, the following

equation is used:

Emission rate = 0.00857 * Emission rate * flow rate (lb/hr) (gr/dscf) (dscfm)

The factor of 0.00857 includes the conversion from minutes to hours and the conversion from

grains to pounds (7,000 grains = 1 pound).

4.2.4 Data Presented in Parts per Million, Dry Volume (ppmdv)

In order to convert gas concentrations in parts per million (ppm) to lb/hr or g/hr flow

rates, the stack gas flow rate in dry standard cubic feet per minute (dscfm) or dry standard cubic

meters per minute (dscmm) was needed. Also, each gas has an individual conversion factor due

to its molecular weight. To convert ppmdv to concentrations in micrograms per cubic meter and

pounds per cubic foot, the following equations are used. The first equation represents the

conversion of the reported gas concentration from STP conditions (Standard Temperature and

Pressure, equal to 273K and 101.3 kPa) to standard atmospheric conditions (293K and 101.3

kPa):

1 ppmdv = (1 mole/22.4L)*(1000L/m3)*(MW)/(294K/273K) µg/m3

L = litersMW = molecular weight of the given gas (g/mole)

Concentration (lb/ft3) = 6.243 * 10-11 * conc (µg/m3)

The compounds for which these conversions were needed and the conversions are listed

in Table 4-3

nja.117\ (Reformatted 1/95) 7/93 4-58

Table 4-3. CONVERSIONSa

PollutantTo get µg/m3,

Multiply ppmdv by:To get lb/ft3,

Multiply ppmdv by:

SO2 2654.56 1.6572*10-7

NOx 1906.59 1.19*10-7

CO 1160.7 7.25*10-8

THC 1827.86 1.14*10-7

aFlue gas referenced to 20EC (293EK) AND 101.3 kPa

nja.117\sect.2-6 4-59

. Once the data are in this form, the conversion to lb/hr or g/hr is:

Emissions (lb/hr) = 60*Conc (lb/ft3)*Flow rate (dscfm)

Emissions (g/hr) = 6.0*10-5*Conc (µg/m3)*Flow rate (dscmm)

Conc ( ) = concentration in units listed in parentheses

nja.117\(Reformatted 1/95) 7/93 4-60

With the data in one of these forms, the equations of Section 4.2.2 can be used.

4.2.5 Oxygen or Moisture Corrected Data

Some of the data reviewed were reported in terms of ppmv, wet, and some were reported

as ppmv corrected to a percent oxygen (O2). The equations to convert these to ppmdv are as

follows:

Conc(ppmdv dry gas) = Conc(ppmv, wet)/(1-moisture fraction)

Conc(ppmdv @ measured%O2) = (20.9 - (measured%O2)*Conc(ppmdv@x%O2)/(20.9 - x%O2)

x = dummy variable

The measured oxygen and moisture fractions, respectively, must be reported on a percent volume

basis for each equation to be properly manipulated. Once the data are in the form of parts per

million, dry volume, the equations of Section 4.2.4 may be used to convert to mass flow rates

(lb/hr or g/hr). Finally, those results may be used with the equations of Section 4.2.2 to calculate

emission factors.

4.3 DATA QUALITY CHECKING

Originally, the emission factor calculations done for the

AP-42 Section 2.6 were done by hand. In order to condense the data, and also to validate the

calculations, the raw data were entered into two separate spreadsheets, one for controlled

emissions and one for uncontrolled emissions. Once the raw data were entered, calculations

were done within the spreadsheet. As a second check, emission factors calculated in the

spreadsheet were directly compared to those done on paper; at least 20 percent of the values were

checked in this way. Emission factors for the remaining test reports (which were added later)

were calculated in a spreadsheet, with a random check of over 10 percent of the calculations

performed by a different team member.

4.4 EMISSION FACTORS FOR AP-42 SECTION 2.6

Once the database was completed, composite emission factors from all the test reports

were calculated. For each pollutant, the test runs for each facility were averaged to determine a

final emission factor by facility. Data from each facility were then combined to develop an

overall average by pollutant, facility type, and air pollution control type. Non-detect values were

included in the averages only if the pollutant was detected in at least one of the runs. For

nja.117\sect.2-6 4-61

example, if all three runs showed non-detect values for a given pollutant, the data were excluded

from Tables 4-1 and 4-2 and no emission factor was calculated. This may result in an emission

factor that is more conservative than if non-detect values were included.

Particle size distribution data are presented only as percent of total PM because the data

(as emission factors) conflicted with the total PM emission factors which were derived from

many more test reports.

The emission factors presented following control with some type of wet scrubber

delineate the scrubbers as high, medium, or low energy for PM, metals, and acid gases.

In rating the emission factors, two main factors, number of data points and equivalent

testing methodologies, were weighed. All of the "B" rated factors were compiled from multiple

source test reports, and the results from each of those reports were compiled using equivalent test

methodologies. All data rated "E" were taken from only one or two sources. Emissions data for

pathogens (spore survivability) are not presented here because the EPA test program was

designed primarily to further develop testing methods to determine microbial survivability in

incinerator processes.2,3,5,6,13

nja.117\6 (Reformatted 1/95) 7/93 4-62

REFERENCES FOR SECTION 4.0

1. McCormack, J., P. Ouchida, and G. Lew. Evaluation Test on a Small Hospital RefuseIncinerator at Saint Bernardine's Hospital, San Bernardino, California, California AirResources Board, July 1989.

2. Medical Waste Incineration Emission Test Report, Cape Fear Memorial Hospital,Wilmington, North Carolina. Prepared for the U.S. Environmental Protection Agency,Office of Air Quality Planning and Standards. December 1991. EMB Report 90-MWI-4.

3. Medical Waste Incineration Emission Test Report, Jordan Hospital, Plymouth,Massachusetts. Prepared for the U.S. Environmental Protection Agency, Office of AirQuality Planning and Standards. February 1992. EMB Report 90-MWI-6.

4. McCormack, James E. Evaluation Test of the Kaiser Permanente Hospital WasteIncinerator in San Diego, California Air Resources Board, March 1990.

5. Medical Waste Incineration Emission Test Report, Lenoir Memorial Hospital, Kinston,North Carolina. Prepared for the U.S. Environmental Protection Agency, Office of AirQuality Planning and Standards. August 12, 1991. EMB Report 90-MWI-3.

6. Medical Waste Incineration Emission Test Report, AMI Central Carolina Hospital,Sanford, North Carolina. Prepared for the U.S. Environmental Protection Agency, Officeof Air Quality Planning and Standards. December 1991. EMB Report 90-MWI-5.

7. Jenkins, A. Evaluation Test on a Hospital Refuse Incinerator at Cedars Sinai MedicalCenter, Los Angeles, California, California Air Resources Board, April 1987.

8. Jenkins, A. Evaluation Test on a Hospital Refuse Incinerator at Saint Agnes MedicalCenter, Fresno, California, California Air Resources Board, April 1987.

9. Jenkins, A., P. Ouchida, and G. Lew. Evaluation Retest on a Hospital Refuse Incineratorat Sutter General Hospital, Sacramento, California, California Air Resources Board, April1988.

10. Swedish-American Hospital Consumat Incinerator, Beling Consultants, Test Report forSwedish American Hospital Consumat Incinerator. Rockford, Illinois, December 1986.

11. McCormack, James E. ARB Evaluation Test Conducted on a Hospital Waste Incineratorat Los Angeles County--USC Medical Center, Los Angeles, California, California AirResources Board, January 1990.

12. Bumbaco, M.J. Report on a Stack Sampling Program to Measure the Emissions ofSelected Trace Organic Compounds, Particulates, Heavy Metals, and HCl from the Royal

nja.117\sect.2-6 4-63

Jubilee Hospital Incinerator, Victoria, British Columbia. Environmental ProtectionPrograms Directorate, April 1983.

13. Medical Waste Incineration Emission Test Report, Borgess Medical Center, Kalamazoo,Michigan. Prepared for the U.S. Environmental Protection Agency, Office of Air QualityPlanning and Standards. December 1991. EMB Report 91-MWI-9.

14. Medical Waste Incineration Emission Test Report, Morristown Memorial Hospital,Morristown, New Jersey. Prepared for the U.S. Environmental Protection Agency, Officeof Air Quality Planning and Standards. December 1991. EMB Report 91-MWI-8.

15. Report of Emission Tests, Burlington County Memorial Hospital, Mount Holly, NewJersey, New Jersey State Department of Environmental Protection, November 28, 1989.

16. Results of the November 4 and 11, 1988 Particulate and Chloride Emission ComplianceTest on the Morse Boulger Incinerator at the Mayo Foundation Institute Hills ResearchFacility Located in Rochester, Minnesota. Prepared for HDR Techserv, Inc. November 39, 1988.

17. Source Emission Tests at ERA Tech, North Jackson, Ohio. Custom Stack AnalysisEngineering Report, CSA Company, December 28, 1988.

18. Memo to Data File, Hershey Medical Center, Derry Township, Pennsylvania, fromThomas P. Bianca, Environmental Resources, Commonwealth of Pennsylvania, May 9,1990.

19. Stack Emission Testing, Erlanger Medical Center, Chattanooga, Tennessee. Prepared forCampbell & Associates, Report I-6299-2, May 6, 1988.

20. Emission Compliance Test Program, Nazareth Hospital, Philadelphia, Pennsylvania. Prepared for Ralph Manco, Nazareth Hospital, September 1989.

21. Report of Emission Tests, Hamilton Hospital, Hamilton, New Jersey, New Jersey StateDepartment of Environmental Protection, December 19, 1989.

22. Report of Emission Tests, Raritan Bay Health Services Corporation, Perth Amboy,New Jersey, New Jersey State Department of Environmental Protection, December 13,1989.

23. Hansen, Kris A. Source Emission Evaluation on a Rotary Atomizing Scrubber atKlamath Falls, Oregon, AM Test, Inc., July 19, 1989.

24. Wilder, Albert A. Final Report for Air Emission Measurements from a Hospital WasteIncinerator, Safeway Disposal Systems, Inc., Middletown, Connecticut.

nja.117\ (Reformatted 1/95) 7/93 4-64

25. Stack Emission Testing, Erlanger Medical Center, Chattanooga, Tennessee. Prepared forCampbell & Associates, Report I-6299, April 13, 1988.

26. Compliance Emission Testing for Memorial Hospital, Chattanooga, Tennessee. AirSystems Testing, Inc. July 29, 1988.

27. Source Emission Tests at ERA Tech, Northwood, Ohio. Custom Stack AnalysisEngineering Report, CSA Company, July 27, 1989.

28. Compliance Testing for Southland Exchange Joint Venture, Hampton, South Carolina,ETS, Inc., July 1989.

29. Source Test Report, MEGA of Kentucky, Louisville, Kentucky, August, 1988.

30. Report on Particulate and HCL Emission Tests on Therm-Tec Incinerator Stack, Elyra,Ohio, Maurice L. Kelsey & Associates, Inc., January 24, 1989.

31. Compliance Emission Testing for Particulate and Hydrogen Chloride at Bio-MedicalService Corporation, Lake City, Georgia, Air Techniques Inc., May 8, 1989.

32. Particulate and Chloride Emission Compliance Test on the Environmental ControlIncinerator at the Mayo Foundation Institute Hills Research Facility, Rochester,Minnesota. Prepared for HDR Techserv, Inc., November 30, 1988.

33. Report on Particulate and HCL Emission Tests on Therm-Tec Incinerator Stack,Cincinnati, Ohio, Maurice L. Kelsey & Associates, Inc., May 22, 1989.

34. Report on Compliance Testing, Hamot Medical Center, Erie, Pennsylvania. Prepared forHamot Medical Center, July 19, 1990.

35. Compliance Emission Testing for HCA North Park Hospital, Hixson, Tennessee, AirSystems Testing, Inc., February 16, 1988.

36. Compliance Particulate Emission Testing on the Pathological Waste Incinerator, HumanaHospital-East Ridge, Chattanooga, Tennessee, Air Techniques, Inc., November 12, 1987.

37. Report of Emission Tests, Helene Fuld Medical Center, Trenton, New Jersey, New JerseyState Department of Environmental Protection, December 1, 1989.

nja.117\sect.2-6 5-1

5.0 AP-42 SECTION 2.6

Section 2.6 of AP-42 is presented in the following pages as it would appear in the document.

2.3 MEDICAL WASTE INCINERATION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

2.3.1 Process Description . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

2.3.1.1 Controlled-Air Incinerators . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

2.3.1.2 Excess Air Incinerators . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3

2.3.1.3 Rotary Kiln Incinerators . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3

2.3.2 Emissions and Controls . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

Figure 2.3-1. Controlled Air Incinerator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Figure 2.3-2. Excess Air Incinerator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Figure 2.3-3. Rotary Kiln Incinerator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Table 2.3-1 (Metric And English Units). EMISSION FACTORS FOR NITROGEN OXIDES

(NOx),CARBON MONOXIDE (CO), AND SULFUR DIOXIDE (SO2) FOR CONTROLLED

AIR MEDICAL WASTE INCINERATORS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

Table 2.3-2 (Metric And Electric Units). EMISSION FACTORS FOR TOTAL PARTICULATE

MATTER, LEAD, AND TOTAL ORGANIC COMPOUNDS (TOC) FOR CONTROLLED AIR

MEDICAL WASTE INCINERATORS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

Table 2.3-3 (Metric And English Units). EMISSION FACTORS FOR HYDROGEN

CHLORIDE (HCl) AND POLYCHLORINATED BIPHENYLS (PCBs) FOR CONTROLLED

AIR MEDICAL WASTE INCINERATORS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12

nja.117\ (Reformatted 1/95) 7/93 5-2

Table 2.3-4 (Metric And English Units). EMISSION FACTORS FOR ALUMINUM,

ANTIMONY, AND ARSENIC CONTROLLED AIR MEDICAL WASTE INCINERATORS 13

Table 2.3-5 (Metric And English Units). EMISSION FACTORS FOR BARIUM, BERYLLIUM,

AND CADMIUM FOR CONTROLLED AIR MEDICAL WASTE INCINERATORS . . . . . . 14

Table 2.3-6 (Metric And English Units). EMISSION FACTORS FOR CHROMIUM, COPPER,

AND IRON FOR CONTROLLED AIR MEDICAL WASTE INCINERATORS . . . . . . . . . . . 15

Table 2.3-7 (Metric And English Units). EMISSION FACTORS FOR MANGANESE,

MERCURY, AND NICKEL FOR CONTROLLED AIR MEDICAL WASTE

INCINERATORS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16

Table 2.3-8 (Metric And English Units). EMISSION FACTORS FOR SILVER AND

THALLIUM FOR CONTROLLED AIR MEDICAL WASTE INCINERATORS . . . . . . . . . . . 17

Table 2.3-9 (Metric And English Units). EMISSION FACTORS FOR SULFUR TRIOXIDE

(SO3) AND HYDROGEN BROMIDE (HBr) FOR CONTROLLED AIR MEDICAL WASTE

INCINERATORS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18

Table 2.3-10 (Metric And English Units). EMISSION FACTORS FOR HYDROGEN

FLUORIDE AND CHLORINE FOR CONTROLLED AIR MEDICAL WASTE

INCINERATORS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19

Table 2.3-11 (Metric And English Units). CHLORINATED DIBENZO-P-DIOXIN EMISSION

FACTORS FOR CONTROLLED AIR MEDICAL WASTE INCINERATORS . . . . . . . . . . . . 20

Table 2.3-12 (Metric And English Units). CHLORINATED DIBENZO-P-DIOXIN EMISSION


nja.117\sect.2-6 5-3

Table 2.3-13 (Metric And English Units). CHLORINATED DIBENZOFURAN EMISSION


Table 2.3-14 (Metric And English Units). CHLORINATED DIBENZOFURANS EMISSION


Table 2.3-15. PARTICLE SIZE DISTRIBUTION FOR CONTROLLED AIR MEDICAL

WASTE INCINERATOR PARTICULATE MATTER EMISSIONS . . . . . . . . . . . . . . . . . . . . 24

Table 2.6-16 (Metric And English Units). ROTARY KILN MEDICAL WASTE

INCINERATOR EMISSION FACTORS FOR CRITERIA POLLUTANTS AND ACID

GASES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25


INCINERATOR EMISSION FACTORS FOR METALS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26


INCINERATOR EMISSION FACTORS FOR DIOXINS AND FURANS . . . . . . . . . . . . . . . . 27

References For Section 2.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28

nja.117\sect.2-6 5-5

2.3 Medical Waste Incineration

Medical waste incineration involves the burning of wastes produced by hospitals, veterinary

facilities, and medical research facilities. These wastes include both infectious ("red bag") medical

wastes as well as non-infectious, general housekeeping wastes. The emission factors presented here

represent emissions when both types of these wastes are combusted rather than just infectious wastes.

Three main types of incinerators are used: controlled air, excess air, and rotary kiln. Of the

incinerators identified in this study, the majority (>95 percent) are controlled air units. A small

percentage (<2 percent) are excess air. Less than 1 percent were identified as rotary kiln. The rotary

kiln units tend to be larger, and typically are equipped with air pollution control devices.

Approximately 2 percent of the total population identified in this study were found to be equipped with

air pollution control devices.

2.3.1 Process Description1-6

Types of incineration described in this section include:

- Controlled air,

- Excess air, and

- Rotary kiln.

2.3.1.1 Controlled-Air Incinerators -

Controlled-air incineration is the most widely used medical waste incinerator (MWI) technology,

and now dominates the market for new systems at hospitals and similar medical facilities. This

technology is also known as starved-air incineration, two-stage incineration, or modular combustion.

Figure 2.3-1 presents a typical schematic diagram of a controlled air unit.

nja.117\ (Reformatted 1/95) 7/93 5-6

Combustion of waste in controlled air incinerators occurs in two stages. In the first stage, waste is

fed into the primary, or lower, combustion chamber, which is operated with less than the stoichiometric

amount of air required for combustion. Combustion air enters the primary chamber from beneath the

incinerator hearth (below the burning bed of waste). This air is called primary or underfire air. In the

primary (starved-air) chamber, the low air-to-fuel ratio dries and facilitates volatilization of the waste,

and most of the residual carbon in the ash burns. At these conditions, combustion gas temperatures are

relatively low (760 to 980EC [1,400 to 1,800EF]).

In the second stage, excess air is added to the volatile gases formed in the primary chamber to

complete combustion. Secondary chamber temperatures are higher than primary chamber temperatures-

-typically 980 to 1,095EC (1,800 to 2,000EF). Depending on the heating value and moisture content of

the waste, additional heat may be needed. This can be provided by auxiliary burners located at the

entrance to the secondary (upper) chamber to maintain desired temperatures.

nja.117\sect.2-6 5-7

WasteFeed

ControlledUnderfire Airfor BurningDown Waste

Starved-AirCondition inLower Chamber

Air Air

Volatile Contentis Burned inUpper Chamber

Carbon Dioxide,Water Vapor

and ExcessOxygen and Nitrogen

to Atmosphere

Main Burner forMinimum CombustionTemperature

Excess AirCondition

UpperChamber

LowerChamber

Waste feed capacities for controlled air incinerators range from about 0.6 to 50 kg/min (75 to

6,500 lb/hr) (at an assumed fuel heating value of 19,700 kJ/kg [8,500 Btu/lb]). Waste feed and ash

removal can be manual or automatic, depending on the unit size and options purchased.


Throughput capacities for lower heating value wastes may be higher, since feed capacities are limited

by primary chamber heat release rates. Heat release rates for controlled air incinerators typically range

from about 430,000 to 710,000 kJ/hr-m3 (15,000 to 25,000 Btu/hr-ft3).

Because of the low air addition rates in the primary chamber, and corresponding low flue gas

velocities (and turbulence), the amount of solids entrained in the gases leaving the primary chamber is

low. Therefore, the majority of controlled air incinerators do not have add-on gas cleaning devices.

2.3.1.2 Excess Air Incinerators -

Excess air incinerators are typically small modular units. They are also referred to as batch

incinerators, multiple chamber incinerators, or "retort" incinerators. Excess air incinerators are typically

a compact cube with a series of internal chambers and baffles. Although they can be operated

continuously, they are usually operated in a batch mode.

nja.117\sect.2-6 5-9

MixingChamber Flame Port

Charging Door

Hearth

PrimaryBurner Port

SecondaryUnderneath Port

CleanoutDoors

SecondaryCombustionChamber

Stack

SecondaryAir Ports

SecondaryBurner Port

Mixing Chamber

First Underneath Port

Flame Port

Charging Door

IgnitionChamber

Hearth

Figure 2.6-2. Excess Air Incinerator

93

02

15D

RT

P

Side View

nja.117\(Reformatted 1/95) 7/93 5-10

Figure 2.3-2 presents a schematic for an excess air unit. Typically, waste is manually fed into the

combustion chamber. The charging door is then closed, and an afterburner is ignited to bring the

secondary chamber to a target temperature (typically 870 to 980EC [1600 to 1800EF]). When the target

temperature is reached, the primary chamber burner ignites. The waste is dried, ignited, and combusted

by heat provided by the primary chamber burner, as well as by radiant heat from the chamber walls.

Moisture and volatile components in the waste are vaporized, and pass (along with combustion gases)

out of the primary chamber and through a flame port which connects the primary chamber to the

secondary or mixing chamber. Secondary air is added through the flame port and is mixed with the

volatile components in the secondary chamber. Burners are also installed in the secondary chamber to

maintain adequate temperatures for combustion of volatile gases. Gases exiting the secondary chamber

are directed to the incinerator stack or to an air pollution control device. When the waste is consumed,

the primary burner shuts off. Typically, the afterburner shuts off after a set time. Once the chamber

cools, ash is manually removed from the primary chamber floor and a new charge of waste can be

added.

Incinerators designed to burn general hospital waste operate at excess air levels of up to 300 percent.

If only pathological wastes are combusted, excess air levels near 100 percent are more common. The

lower excess air helps maintain higher chamber temperature when burning high- moisture waste.

Waste feed capacities for excess air incinerators are usually 3.8 kg/min (500 lb/hr) or less.

2.3.1.3 Rotary Kiln Incinerators -

Rotary kiln incinerators, like the other types, are designed with a primary chamber, where the waste

is heated and volatilized, and a secondary chamber, where combustion of the volatile fraction is

completed. The primary chamber consists of a slightly inclined, rotating kiln in which waste materials

migrate from the feed end to the ash discharge end. The waste throughput rate is controlled by

adjusting the rate of kiln rotation and the angle of inclination. Combustion air enters the primary

chamber through a port. An auxiliary burner is generally used to start combustion and maintain desired

combustion temperatures. Both the primary and secondary chambers are usually lined with acid-

resistant refractory brick, as shown in the schematic drawing, Figure 2.3-3.

nja.117\sect.2-6 5-11

Volatiles and combustion gases pass from the primary chamber to the secondary chamber. The

secondary chamber operates at excess air. Combustion of the volatiles is completed in the secondary

chamber. Due to the turbulent motion of the waste in the primary chamber, solids burnout rates and

particulate entrainment in the flue gas are higher for rotary kiln incinerators than for other incinerator

designs. As a result, rotary kiln incinerators generally have add-on gas cleaning devices.

nja.117\(Reformatted 1/95) 7/93 5-12

Figu

re 2

.3-3

. R

otar

y K

iln

Inci

nera

tor

nja.117\sect.2-6 5-13

2.3.2 Emissions And Controls2,4,7-43

Medical waste incinerators can emit significant quantities of pollutants to the atmosphere. These

pollutants include: (1) particulate matter (PM), (2) metals, (3) acid gases, (4) oxides of nitrogen (NOx),

(5) carbon monoxide (CO), (6) organics, and (7) various other materials present in medical wastes, such

as pathogens, cytotoxins, and radioactive diagnostic materials.

Particulate matter is emitted as a result of incomplete combustion of organics (i. e., soot) and by the

entrainment of noncombustible ash due to the turbulent movement of combustion gases. Particulate

matter may exit as a solid or an aerosol, and may contain heavy metals, acids, and/or trace organics.

Uncontrolled particulate emission rates vary widely, depending on the type of incinerator,

composition of the waste, and the operating practices employed. Entrainment of PM in the incinerator

exhaust is primarily a function of the gas velocity within the combustion chamber containing the solid

waste. Controlled air incinerators have the lowest turbulence and, consequently, the lowest PM

emissions; rotary kiln incinerators have highly turbulent combustion, and thus have the highest PM

emissions.

The type and amount of trace metals in the flue gas are directly related to the metals contained in the

waste. Metal emissions are affected by the level of PM control and the flue gas temperature. Most

metals (except mercury) exhibit fine-particle enrichment and are removed by maximizing small particle

collection. Mercury, due to its high vapor pressure, does not show significant particle enrichment, and

removal is not a function of small particle collection in gas streams at temperatures greater than 150EC

(300EF).

Acid gas concentrations of hydrogen chloride (HCl) and sulfur dioxide (SO2) in MWI flue gases are

directly related to the chlorine and sulfur content of the waste. Most of the chlorine, which is

chemically bound within the waste in the form of polyvinyl chloride (PVC) and other chlorinated

compounds, will be converted to HCl. Sulfur is also chemically bound within the materials making up

medical waste and is oxidized during combustion to form SO2.

nja.117\(Reformatted 1/95) 7/93 5-14

Oxides of nitrogen (NOx) represent a mixture of mainly nitric oxide (NO) and nitrogen dioxide

(NO2). They are formed during combustion by: (1) oxidation of nitrogen chemically bound in the

waste, and (2) reaction between molecular nitrogen and oxygen in the combustion air. The formation of

NOx is dependent on the quantity of fuel-bound nitrogen compounds, flame temperature, and air/fuel

ratio.

Carbon monoxide is a product of incomplete combustion. Its presence can be related to insufficient

oxygen, combustion (residence) time, temperature, and turbulence (fuel/air mixing) in the combustion

zone.

Failure to achieve complete combustion of organic materials evolved from the waste can result in

emissions of a variety of organic compounds. The products of incomplete combustion (PICs) range

from low molecular weight hydrocarbon (e. g., methane or ethane) to high molecular weight

compounds (e. g., polychlorinated dibenzo-p-dioxins and dibenzofurans [CDD/CDF]). In general,

combustion conditions required for control of CO (i. e., adequate oxygen, temperature, residence time,

and turbulence) will also minimize emissions of most organics.

Emissions of CDDs/CDFs from MWIs may occur as either a vapor or as a fine particulate. Many

factors are believed to be involved in the formation of CDDs/CDFs and many theories exist concerning

the formation of these compounds. In brief, the best supported theories involve four mechanisms of

formation.2 The first theory states that trace quantities of CDDs/CDFs present in the refuse feed are

carried over, unburned, to the exhaust. The second theory involves formation of CDDs/CDFs from

chlorinated precursors with similar structures. Conversion of precursor material to CDDs/CDFs can

potentially occur either in the combustor at relatively high temperatures or at lower temperatures such

as are present in wet scrubbing systems. The third theory involves synthesis of CDDs/CDFs

compounds from a variety of organics and a chlorine donor. The fourth mechanism involves catalyzed

reactions on fly ash particles at low temperatures.

To date, most MWIs have operated without add-on air pollution control devices (APCDs). A small

percentage (approximately 2 percent) of MWIs do use APCDs. The most frequently used control

devices are wet scrubbers and fabric filters (FFs). Fabric filters provide mainly PM control. Other PM

nja.117\sect.2-6 5-15

control technologies include venturi scrubbers and electrostatic precipitators (ESPs). In addition to wet

scrubbing, dry sorbent injection (DSI) and spray dryer (SD) absorbers have also been used for acid gas

control.

Wet scrubbers use gas-liquid absorption to transfer pollutants from a gas to a liquid stream.

Scrubber design and the type of liquid solution used largely determine contaminant removal

efficiencies. With plain water, removal efficiencies for acid gases could be as high as 70 percent for

HCl and 30 percent for SO2. Addition of an alkaline reagent to the scrubber liquor for acid

neutralization has been shown to result in removal efficiencies of 93 to 96 percent.

Wet scrubbers are generally classified according to the energy required to overcome the pressure

drop through the system. Low-energy scrubbers (spray towers) are primarily used for acid gas control

only, and are usually circular in cross section. The liquid is sprayed down the tower through the rising

gas. Acid gases are absorbed/neutralized by the scrubbing liquid. Low-energy scrubbers mainly

remove particles larger than 5-10 micrometers (Fm) in diameter.

Medium-energy scrubbers can be used for particulate matter and/or acid gas control. Medium

energy devices rely mostly on impingement to facilitate removal of PM. This can be accomplished

through a variety of configurations, such as packed columns, baffle plates, and liquid impingement

scrubbers.

Venturi scrubbers are high-energy systems that are used primarily for PM control. A typical venturi

scrubber consists of a converging and a diverging section connected by a throat section. A liquid

(usually water) is introduced into the gas stream upstream of the throat. The flue gas impinges on the

liquid stream in the converging section. As the gas passes through the throat, the shearing action

atomizes the liquid into fine droplets. The gas then decelerates through the diverging section, resulting

in further contact between particles and liquid droplets. The droplets are then removed from the gas

stream by a cyclone, demister, or swirl vanes.

A fabric filtration system (baghouse) consists of a number of filtering elements (bags) along with a

bag cleaning system contained in a main shell structure with dust hoppers. Particulate-laden gas passes

nja.117\(Reformatted 1/95) 7/93 5-16

through the bags so that the particles are retained on the upstream side of the fabric, thus cleaning the

gas. A FF is typically divided into several compartments or sections. In a FF, both the collection

efficiency and the pressure drop across the bag surface increase as the dust layer on the bag builds up.

Since the system cannot continue to operate with an increasing pressure drop, the bags are cleaned

periodically. The cleaning processes include reverse flow with bag collapse, pulse jet cleaning, and

mechanical shaking. When reverse flow and mechanical shaking are used, the particulate matter is

collected on the inside of the bag; particulate matter is collected on the outside of the bag in pulse jet

systems. Generally, reverse flow FFs operate with lower gas flow per unit area of bag surface (air-to-

cloth ratio) than pulse jet systems and, thus, are larger and more costly for a given gas flow-rate or

application. Fabric filters can achieve very high (>99.9 percent) PM removal efficiencies. These

systems are also very effective in controlling fine particulate matter, which results in good control of

metals and organics entrained on fine particulate.

Particulate collection in an ESP occurs in 3 steps: (1) suspended particles are given an electrical

charge; (2) the charged particles migrate to a collecting electrode of opposite polarity; and (3) the

collected PM is dislodged from the collecting electrodes and collected in hoppers for disposal.

Charging of the particles is usually caused by ions produced in a high voltage corona. The electric

fields and the corona necessary for particle charging are provided by converting alternating current to

direct current using high voltage transformers and rectifiers. Removal of the collected particulate

matter is accomplished mechanically by rapping or vibrating the collecting electrode plates. ESPs have

been used in many applications due to their high reliability and efficiency in controlling total PM

emissions. Except for very large and carefully designed ESPs, however, they are less efficient than FFs

at control of fine particulates and metals.

Dry sorbent injection (DSI) is another method for controlling acid gases. In the DSI process, a dry

alkaline material is injected into the flue gas into a dry venturi within the ducting or into the duct ahead

of a particulate control device. The alkaline material reacts with and neutralizes acids in the flue gas.

Fabric filters are employed downstream of DSI to: (1) control the PM generated by the incinerator, (2)

capture the DSI reaction products and unreacted sorbent, and (3) increase sorbent/acid gas contact time,

thus enhancing acid gas removal efficiency and sorbent utilization. Fabric filters are commonly used

nja.117\sect.2-6 5-17

with DSI because they provide high sorbent/acid gas contact. Fabric filters are less sensitive to PM

loading changes or combustion upsets than other PM control devices since they operate with nearly

constant efficiency. A potential disadvantage of ESPs used in conjunction with DSI is that the sorbent

increases the electrical resistivity of the PM being collected. This phenomenon makes the PM more

difficult to charge and, therefore, to collect. High resistivity can be compensated for by flue gas

conditioning or by increasing the plate area and size of the ESP.

The major factors affecting DSI performance are flue gas temperature, acid gas dew point

(temperature at which the acid gases condense), and sorbent-to-acid gas ratio. DSI performance

improves as the difference between flue gas and acid dew point temperatures decreases and the sorbent-

to-acid gas ratio increases. Acid gas removal efficiency with DSI also depends on sorbent type and the

extent of sorbent mixing with the flue gas. Sorbents that have been successfully applied include

hydrated lime (Ca[OH]2), sodium hydroxide (NaOH), and sodium bicarbonate (NaHCO3). For hydrated

lime, DSI can achieve 80 to 95 percent of HCl removal and 40 to 70 percent removal of SO2 under

proper operating conditions.

The primary advantage of DSI compared to wet scrubbers is the relative simplicity of the sorbent

preparation, handling, and injection systems as well as the easier handling and disposal of dry solid

process wastes. The primary disadvantages are its lower sorbent utilization rate and correspondingly

higher sorbent and waste disposal rates.

In the spray drying process, lime slurry is injected into the SD through either a rotary atomizer or

dual-fluid nozzles. The water in the slurry evaporates to cool the flue gas, and the lime reacts with acid

gases to form calcium salts that can be removed by a PM control device. The SD is designed to provide

sufficient contact and residence time to produce a dry product before leaving the SD adsorber vessel.

The residence time in the adsorber vessel is typically 10 to 15 seconds. The particulates leaving the SD

(fly ash, calcium salts, and unreacted hydrated lime) are collected by an FF or ESP.

Emission factors and emission factor ratings for controlled air incinerators are presented in

Tables 2.3-1, 2.3-2, 2.3-3, 2.3-4, 2.3-5, 2.3-6, 2.3-7, 2.3-8, 2.3-9, 2.3-10, 2.3-11, 2.3-12, 2.3-13, 2.13-

14, and 2.3-15. For emissions controlled with wet scrubbers, emission factors are presented separately

nja.117\(Reformatted 1/95) 7/93 5-18

for low-, medium-, and high-energy wet scrubbers. Particle size distribution data for controlled air

incinerators are presented in Table 2.3-15 for uncontrolled emissions and controlled emissions

following a medium-energy wet scrubber/FF and a low-energy wet scrubber. Emission factors and

emission factor ratings for rotary kiln incinerators are presented in Tables 2.3-16, 2.3-17, and 2.3-18.

Emissions data are not available for pathogens because there is not an accepted methodology for

measurement of these emissions. Refer to References 8, 9, 11, 12, and 19 for more information.

nja.117\

sect.2-6

5-19

Table 2.3-1 (English And Metric Units). EMISSION FACTORS FOR NITROGEN OXIDES (NOx), CARBON MONOXIDE (CO),AND SULFUR DIOXIDE (SO2) FOR CONTROLLED AIR MEDICAL WASTE INCINERATORSa

Rating (A-E) Follows Each Factor

NOxc COc SO2

c

Control Levelb lb/ton kg/Mg

EMISSIONFACTORRATING lb/ton kg/Mg


EMISSIONFACTORRATING

Uncontrolled 3.56 E+00 1.78 E+00 A 2.95 E+00 1.48 E+00 A 2.17 E+00 1.09 E+00 B

Low Energy Scrubber/FF

Medium Energy Scrubber/FF 3.75 E-01 1.88 E-01 E

FF 8.45 E-01 4.22 E-01 E

Low Energy Scrubber 2.09 E+00 1.04 E+00 E

High Energy Scrubber 2.57 E-02 1.29 E-02 E

DSI/FF 3.83 E-01 1.92 E-01 E

DSI/Carbon Injection/FF 7.14 E-01 3.57 E-01 E

DSI/FF/Scrubber 1.51 E-02 7.57 E-03 E

DSI/ESPa References 7-43. Source Classification Codes 5-01-005-05, 5-02-005-05. Blanks indicate no data.b FF = Fabric Filter

DSI = Dry Sorbent InjectionESP = Electrostatic Precipitator

c NOx and CO emission factors for uncontrolled facilities are applicable for all add-on control devices shown.

nja.117\

sect.2-6

5-21

Table 2.3-2 (English And Metric Units). EMISSION FACTORS FOR TOTAL PARTICULATE MATTER, LEAD, ANDTOTAL ORGANIC COMPOUNDS (TOC) FOR CONTROLLED AIR MEDICAL WASTE INCINERATORSa


Total Particulate Matter Leadc TOC





Uncontrolled 4.67 E+00 2.33 E+00 B 7.28 E-02 3.64 E-02 B 2.99 E-01 1.50 E-01 B

Low Energy Scrubber/FF 9.09 E-01 4.55 E-01 E

Medium Energy Scrubber/FF 1.61 E-01 8.03 E-02 E 1.60 E-03 7.99 E-04 E

FF 1.75 E-01 8.76 E-02 E 9.92 E-05 4.96 E-05 E 6.86 E-02 3.43 E-01 E

Low Energy Scrubber 2.90 E+00 1.45 E+00 E 7.94 E-02 3.97 E-02 E 1.40 E-01 7.01 E-02 E

High Energy Scrubber 1.48 E+00 7.41 E-01 E 6.98 E-02 3.49 E-02 E 1.40 E-01 7.01 E-02 E

DSI/FF 3.37 E-01 1.69 E-01 E 6.25 E-05 3.12 E+01 E 4.71 E-02 2.35 E-02 E

DSI/Carbon Injection/FF 7.23 E-02 3.61 E-02 E 9.27 E-05 4.64 E-05 E

DSI/FF/Scrubber 2.68 E+00 1.34 E+00 E 5.17 E-05 2.58 E-05 E

DSI/ESP 7.34 E-01 3.67 E-01 E 4.70 E-03 2.35 E-03 Ea References 7-43. Source Classification Codes 5-01-005-05, 5-02-005-05. Blanks indicate no data. b FF = Fabric Filter


c Hazardous air pollutants listed in the Clean Air Act.

nja.117\

sect.2-6

5-23

Table 2.3-3 (English And Metric Units). EMISSION FACTORS FOR HYDROGEN CHLORIDE (HCl) ANDPOLYCHLORINATED BIPHENYLS (PCBs) FOR CONTROLLED AIR MEDICAL WASTE INCINERATORSa


HClc Total PCBsc




Uncontrolled 3.35 E+01 1.68 E+01 C 4.65 E-05 2.33 E-05 E

Low Energy Scrubber/FF 1.90 E+00 9.48 E-01 E

Medium Energy Scrubber/FF 2.82 E+00 1.41 E+00 E

FF 5.65 E+00 2.82 E+00 E

Low Energy Scrubber 1.00 E+00 5.01 E-01 E


DSI/FF 1.27 E+01 6.37 E+00 D



DSI/ESP 4.98 E-01 2.49 E-01 Ea References 7-43. Source Classification Codes 5-01-005-05, 5-02-005-05. Blanks indicate no data. b FF = Fabric Filter



nja.117\

(Reform

atted 1/95) 7/935-24

Table 2.3-4 (English And Metric Units). EMISSION FACTORS FOR ALUMINUM, ANTIMONY, AND ARSENICCONTROLLED AIR MEDICAL WASTE INCINERATORSa


Aluminum Antimonyc Arsenicc





Uncontrolled 1.05 E-02 5.24 E-03 E 1.28 E-02 6.39 E-03 D 2.42 E-04 1.21 E-04 B



FF 3.95 E-08 1.97 E-08 E

Low Energy Scrubber 1.42 E-04 7.12 E-05 E

High Energy Scrubber 4.08 E-04 2.04 E-04 E 3.27 E-05 1.64 E-05 E

DSI/FF 3.03 E-03 1.51 E-03 E 2.10 E-04 1.05 E-04 E 1.19 E-05 5.93 E-06 E

DSI/Carbon Injection/FF 2.99 E-03 1.50 E-03 E 1.51 E-04 7.53 E-05 E 1.46 E-05 7.32 E-06 E

DSI/FF/Scrubber




nja.117\

(Reform

atted 1/95) 7/935-26

Table 2.3-5 (English And Metric Units). EMISSION FACTORS FOR BARIUM, BERYLLIUM, AND CADMIUMFOR CONTROLLED AIR MEDICAL WASTE INCINERATORSa


Barium Berylliumc Cadmiumc





Uncontrolled 3.24 E-03 1.62 E-03 D 6.25 E-06 3.12 E-06 D 5.48 E-03 2.74 E-03 B



FF

Low Energy Scrubber 6.97 E-03 3.49 E-03 E


DSI/FF 7.39 E-05 3.70 E-05 E 2.46 E-05 1.23 E-05 E

DSI/Carbon Injection/FF 7.39 E-05 3.69 E-05 E 3.84 E-06 1.92 E-06 E 9.99 E-05 4.99 E-05 E





nja.117\

(R

eformatted 1/95) 7/93

5-28

Table 2.3-6 (English And English Units). EMISSION FACTORS FOR CHROMIUM, COPPER, AND IRONFOR CONTROLLED AIR MEDICAL WASTE INCINERATORSa


Chromiumc Copper Iron





Uncontrolled 7.75 E-04 3.88 E-04 B 1.25 E-02 6.24 E-03 E 1.44 E-02 7.22 E-03 C



FF 2.15 E-06 1.07 E-06 E

Low Energy Scrubber 4.13 E-04 2.07 E-04 E 9.47 E-03 4.73E -03 E


DSI/FF 3.06 E-04 1.53 E-04 E 1.25 E-03 6.25 E-04 E






nja.117\

(Reform

atted 1/95) 7/935-30

Table 2.3-7 (English and Metric Units). EMISSION FACTORS FOR MANGANESE, MERCURY, AND NICKELFOR CONTROLLED AIR MEDICAL WASTE INCINERATORSa


Manganesec Mercuryc Nickelc





Uncontrolled 5.67 E-04 2.84 E-04 C 1.07 E-01 5.37 E-02 C 5.90 E-04 2.95 E-04 B



FF

Low Energy Scrubber 4.66 E-04 2.33 E-04 E 1.55 E-02 7.75 E-03 E 3.28 E-04 1.64 E-02 E

High Energy Scrubber 6.12 E-04 3.06 E-04 E 1.73 E-02 8.65 E-03 E 2.54 E-03 1.27 E-03 E

DSI/FF 1.11 E-01 5.55 E-02 E 4.54 E-04 2.27 E-04 E



DSI/ESP 1.81 E-02 9.05 E-03 E 4.84 E-04 2.42 E-04 Ea References 7-43. Source Classification Codes 5-01-005-05, 5-02-005-05. Blanks indicate no data. b FF = Fabric Filter



nja.117\

(Reform

atted 1/95) 7/935-32

Table 2.3-8 (English And Metric Units). EMISSION FACTORS FOR SILVER AND THALLIUMFOR CONTROLLED AIR MEDICAL WASTE INCINERATORSa


Silver Thallium




Uncontrolled 2.26 E-04 1.13 E-04 D 1.10 E-03 5.51 E-04 D



FF

Low Energy Scrubber


DSI/FF 6.65 E-05 3.32 E-05 E


DSI/FF/Scrubber

DSI/ESPa References 7-43. Source Classification Codes 5-01-005-05, 5-02-005-05. Blanks indicate no data. b FF = Fabric Filter


nja.117\

(R

eformatted 1/95) 7/93

5-34

Table 2.3-9 (English And Metric Units). EMISSION FACTORS FOR SULFUR TRIOXIDE (SO3)AND HYDROGEN BROMIDE (HBr) FOR CONTROLLED AIR MEDICAL WASTE INCINERATORSa


SO3 HBr




Uncontrolled 4.33 E-02 2.16 E-02 D



FF

Low Energy Scrubber

High Energy Scrubber

DSI/FF





nja.117\

(Reform

atted 1/95) 7/935-36

Table 2.3-10 (English And Metric Units). EMISSION FACTORS FOR HYDROGEN FLUORIDE AND CHLORINE FOR CONTROLLED AIR MEDICAL WASTE INCINERATORSa


Hydrogen Fluoridec Chlorinec




Uncontrolled 1.49 E-01 7.43 E-02 D 1.05 E-01 5.23 E-02 E


Medium Energy Scrubber/FF

FF

Low Energy Scrubber

High Energy Scrubber

DSI/FF


DSI/FF/Scrubber




EN

DFIE

LD

nja.117\

sect.2-6

5-37

Table 2.3-11 (English And Metric Units). CHLORINATED DIBENZO-P-DIOXIN EMISSION FACTORSFOR CONTROLLED AIR MEDICAL WASTE INCINERATORSa


Uncontrolled Fabric Filter Wet Scrubber DSI/FFc

Congenerb lb/ton kg/Mg





TCDD 2,3,7,8- Total

5.47 E-081.00 E-06

2.73 E-085.01 E-07

EB

6.72 E-091.23 E-07

3.36 E-096.17 E-08

EE

1.29 E-102.67 E-08

6.45 E-111.34 E-08

EE

5.61 E-106.50 E-09

2.81 E-103.25 E-09

EE

PeCDD 1,2,3,7,8- Total

6.08 E-105.53 E-10

3.04 E-102.77 E-10

EE

HxCDD 1,2,3,6,7,8- 1,2,3,7,8,9- 1,2,3,4,7,8- Total

3.78 E-101.21 E-09

1.89 E-106.07 E-10

EE

1.84 E-092.28 E-099.22 E-105.77 E-10

9.05 E-101.14 E-094.61 E-102.89 E-10

EEEE

HpCDD 1,2,3,4,6, 7,8- Total

5.23 E-09 2.62 E-09 E 6.94 E-091.98 E-09

3.47 E-099.91 E-10

EE

OCDD - total 2.21 E-08 1.11 E-08 E

Total CDD 2.13 E-05 1.07 E-05 B 2.68 E-06 1.34 E-06 E 1.84 E-06 9.18 E-07 E 3.44 E-07 1.72 E-07 Ea References 7-43. Source Classification Codes 5-01-005-05, 5-02-005-05. Blanks indicate no data. b Hazardous air pollutants listed in Clean Air Act.c FF = Fabric Filter

DSI = Dry Sorbent Injection

nja.117\

sect.2-6

5-39

Table 2.3-12 (English And Metric Units). CHLORINATED DIBENZO-P-DIOXIN EMISSION FACTORSFOR CONTROLLED AIR MEDICAL WASTE INCINERATORSa


DSI/Carbon Injection/FFc DSI/ESPd




TCDD 2,3,7,8- Total

8.23 E-10 4.11 E-10 E 1.73 E-10 8.65 E-11 E

PeCDD 1,2,3,7,8- Total

HxCDD 1,2,3,6,7,8- 1,2,3,7,8,9- 1,2,3,4,7,8- Total

HpCDD 2,3,4,6,7,8- 1,2,3,4,6,7,8- Total

OCDD - Total

Total CDD 5.38 E-08 2.69 E-08 Ea References 7-43. Source Classification Codes 5-01-005-05, 5-02-005-05. Blanks indicate no data. b Hazardous air pollutants listed in the Clean Air Act.c FF = Fabric Filter

DSI = Dry Sorbent Injectiond ESP = Electrostatic Precipitator

EN

DFIE

LD

nja.117\

(Reform

atted 1/95) 7/935-40

Table 2.3-13 (English And Metric Units). CHLORINATED DIBENZOFURAN EMISSION FACTORSFOR CONTROLLED AIR MEDICAL WASTE INCINERATORSa


Uncontrolled Fabric Filter Wet Scrubber DSI/FFc






TCDF 2,3,7,8- Total

2.40 E-077.21 E-06

1.20 E-073.61 E-06

EB

3.85 E-081.28 E-06

1.97 E-086.39 E-07

EE

1.26 E-084.45 E-07

6.30 E-092.22 E-07

EE

4.93 E-091.39 E-07

2.47 E-096.96 E-08

EE

PeCDF 1,2,3,7,8- 2,3,4,7,8- Total

7.56 E-102.07 E-09

3.78 E-101.04 E-09

EE

1.04 E-093.07 E-096.18 E-09

5.22 E-101.53 E-093.09 E-09

EEE

HxCDF 1,2,3,4,7,8- 1,2,3,6,7,8- 2,3,4,6,7,8- 1,2,3,7,8,9- Total

7.55 E-092.53 E-097.18 E-09

3.77 E-091.26 E-093.59 E-09

EEE

8.96 E-093.53 E-099.59 E-093.51 E-105.10 E-09

4.48 E-091.76 E-094.80 E-091.76 E-102.55 E-09

EEEEE

HpCDF 1,2,3,4,6,7,8- 1,2,3,4,7,8,9- Total

1.76 E-082.72 E-09

8.78 E-091.36 E-09

EE

1.79 E-083.50 E-091.91 E-09

8.97 E-091.75 E-099.56 E-10

EEE

OCDF - Total 7.42 E-08 3.71 E-08 E 4.91 E-10 2.45 E-10 E

Total CDF 7.15 E-05 3.58 E-05 B 8.50 E-06 4.25 E-06 E 4.92 E-06 2.46 E-06 E 1.47 E-06 7.37 E-07 Ea References 7-43. Source Classification Codes 5-01-005-05, 5-02-005-05. Blanks indicate no data. b Hazardous air pollutants listed in the Clean Air Act.c FF = Fabric Filter

DSI = Dry Sorbent Injection

nja.117\

(Reform

atted 1/95) 7/935-42

Table 2.3-14 (English And Metric Units). CHLORINATED DIBENZOFURANS EMISSION FACTORSFOR CONTROLLED AIR MEDICAL WASTE INCINERATORSa


DSI/Carbon Injection/FFc DSI/ESPd




TCDF 2,3,7,8- Total

7.31 E-101.01 E-08

3.65 E-105.07 E-09

EE

1.73 E-09 8.66 E-10 E

PeCDF 1,2,3,7,8- 2,3,4,7,8- Total

HxCDF 1,2,3,4,7,8- 1,2,3,6,7,8- 2,3,4,6,7,8- 1,2,3,7,8,9- Total

HpCDF 1,2,3,4,6,7,8- 1,2,3,4,7,8,9- Total

OCDF - Total

Total CDF 9.47 E-08 4.74 E-08 Ea References 7-43. Source Classification Codes 5-01-005-05, 5-02-005-05. Blanks indicate no data. b Hazardous air pollutants listed in the Clean Air Act.c FF = Fabric Filter

DSI = Dry Sorbent Injectiond ESP = Electrostatic Precipitator

nja.117\sect.2-6 (Reformatted 1/95) 7/93 5-44

Table 2.3-15. PARTICLE SIZE DISTRIBUTION FOR CONTROLLED AIR MEDICAL WASTE

INCINERATOR PARTICULATE MATTER EMISSIONSa

EMISSION FACTOR RATING: E

Cut Diameter

(µm)

Uncontrolled Cumulative

Mass % Less Than Stated Size

Scrubber

Cumulative Mass % Less

Than Stated Size

0.625 31.1 0.1

1.0 35.4 0.2

2.5 43.3 2.7

5.0 52.0 28.1

10.0 65.0 71.9a References 7-43. Source Classification Codes 5-01-005-05, 5-02-005-05.

nja.117\

sect.2-6

5-45

Table 2.3-16 (English And Metric Units). ROTARY KILN MEDICAL WASTE INCINERATOR EMISSION FACTORSFOR CRITERIA POLLUTANTS AND ACID GASESa


Uncontrolled SD/Fabric Filterb SD/Carbon Injection/FFc High Energy Scrubber

Pollutant lb/ton kg/Mg lb/ton kg/Mg lb/ton kg/Mg lb/ton kg/Mg

Carbon monoxide 3.82 E-01 1.91 E-01 3.89 E-02 1.94 E-02 4.99 E-02 2.50 E-02 5.99 E-02 3.00 E-02

Nitrogen oxides 4.63 E+00 2.31 E+00 5.25 E+00 2.63 E+00 4.91 E+00 2.45 E+00 4.08 E+00 2.04 E+00

Sulfur dioxide 1.09 E+00 5.43 E-01 6.47 E-01 3.24 E-01 3.00 E-01 1.50 E-01

PM 3.45 E+01 1.73 E+01 3.09 E-01 1.54 E-01 7.56 E-02 3.78 E-02 8.53 E-01 4.27 E-01

TOC 6.66 E-02 3.33 E-02 4.11 E-02 2.05 E-02 5.05 E-02 2.53 E-02 2.17 E-02 1.08 E-02

HCld 4.42 E+01 2.21 E+01 2.68 E-01 1.34 E-01 3.57 E-01 1.79 E-01 2.94 E+01 1.47 E+01

HFd 9.31 E-02 4.65 E-02 2.99 E-02 1.50 E-02

HBr 1.05 E+00 5.25 E-01 6.01 E-02 3.00 E-02 1.90 E-02 9.48 E-03

H2SO4 2.98 E+00 1.49 E+00a References 7-43. Source Classification Codes 5-01-005-05, 5-02-005-05. Blanks indicate no data. b SD = Spray Dryerc FF = Fabric Filterd Hazardous air pollutant listed in the Clean Air Act.

nja.117\

(Reform

atted 1/95) 7/935-46

Table 2.3-17 (English And Metric Units). ROTARY KILN MEDICAL WASTE INCINERATOREMISSION FACTORS FOR METALSa


Uncontrolled SD/Fabric Filterb SD/Carbon Injection/FFc

Pollutant lb/ton kg/Mg lb/ton kg/Mg lb/ton kg/Mg

Aluminum 6.13 E-01 3.06 E-01 4.18 E-03 2.09 E-03 2.62 E-03 1.31 E-03

Antimonyd 1.99 E-02 9.96 E-03 2.13 E-04 1.15 E-04 1.41 E-04 7.04 E-05

Arsenicd 3.32 E-04 1.66 E-04

Barium 8.93 E-02 4.46 E-02 2.71 E-04 1.35 E-04 1.25 E-04 6.25 E-05

Berylliumd 4.81 E-05 2.41 E-05 5.81 E-06 2.91 E-06

Cadmiumd 1.51 E-02 7.53 E-03 5.36 E-05 2.68 E-05 2.42 E-05 1.21 E-05

Chromiumd 4.43 E-03 2.21 E-03 9.85 E-05 4.92 E-05 7.73 E-05 3.86 E-05

Copper 1.95 E-01 9.77 E-02 6.23 E-04 3.12 E-04 4.11 E-04 2.06 E-04

Leadd 1.24 E-01 6.19 E-02 1.89 E-04 9.47 E-05 7.38 E-05 3.69 E-05

Mercuryd 8.68 E-02 4.34 E-02 6.65 E-02 3.33 E-02 7.86 E-03 3.93 E-03

Nickeld 3.53 E-03 1.77 E-03 8.69 E-05 4.34 E-05 3.58 E-05 1.79 E-05

Silver 1.30 E-04 6.51 E-05 9.23 E-05 4.61 E-05 8.05 E-05 4.03 E-05

Thallium 7.58 E-04 3.79 E-04a References 7-43. Source Classification Codes 5-01-005-05, 5-02-005-05. ND = no data. Blanks indicate no data.b SD = Spray Dryer.c FF = Fabric Filter.d Hazardous air pollutant listed in the Clean Air Act.

nja.117\

sect.2-6

5-47

Table 2.3-18 (English And Metric Units). ROTARY KILN MEDICAL WASTE INCINERATOR EMISSION FACTORSFOR DIOXINS AND FURANSa


Uncontrolled SD/Fabric Filterb SD/Carbon Injection/FFc

Congenerd lb/ton kg/Mg lb/ton kg/Mg lb/ton kg/Mg

2,3,7,8-TCDD 6.61 E-10 3.30 E-10 4.52 E-10 2.26 E-10 6.42 E-11 3.21 E-11

Total TCDD 7.23 E-09 3.61 E-09 4.16 E-09 2.08 E-09 1.55 E-10 7.77 E-11

Total CDD 7.49 E-07 3.75 E-07 5.79 E-08 2.90 E-08 2.01 E-08 1.01 E-08

2,3,7,8-TCDF 1.67 E-08 8.37 E-09 1.68 E-08 8.42 E-09 4.96 E-10 2.48 E-10

Total TCDF 2.55 E-07 1.27 E-07 1.92 E-07 9.58 E-08 1.15 E-08 5.74 E-09

Total CDF 5.20 E-06 2.60 E-06 7.91 E-07 3.96 E-07 7.57 E-08 3.78 E-08a References 7-43. Source Classification Codes 5-01-005-05, 5-02-005-05.b SD = Spray Dryer.c FF = Fabric Filter.d Hazardous air pollutants listed in the Clean Air Act.

nja.117\6 (Reformatted 1/95) 7/93 5-48

References For Section 2.3

1. Locating And Estimating Air Toxic Emissions From Medical Waste Incinerators,

U. S. Environmental Protection Agency, Rochester, New York, September 1991.

2. Hospital Waste Combustion Study: Data Gathering Phase, EPA-450/3-88-017,

U. S. Environmental Protection Agency, Research Triangle Park, North Carolina, December 1988.

3. C. R. Brunner, "Biomedical Waste Incineration", presented at the 80th Annual Meeting of the Air

Pollution Control Association, New York, New York, June 21-26, 1987. p.10.

4. Flue Gas Cleaning Technologies For Medical Waste Combustors, Final Report,

U. S. Environmental Protection Agency, Research Triangle Park, North Carolina, June 1990.

5. Municipal Waste Combustion Study; Recycling Of Solid Waste, U. S. Environmental Protection

Agency, EPA Contract 68-02-433, pp.5-6.

6. S. Black and J. Netherton, Disinfection, Sterilization, And Preservation. Second Edition, 1977, p.

729.

7. J. McCormack, et al., Evaluation Test On A Small Hospital Refuse Incinerator At Saint

Bernardine's Hospital In San Bernardino, California, California Air Resources Board, July 1989.

8. Medical Waste Incineration Emission Test Report, Cape Fear Memorial Hospital, Wilmington,

North Carolina, U. S. Environmental Protection Agency, December 1991.

9. Medical Waste Incineration Emission Test Report, Jordan Hospital, Plymouth, Massachusetts, U. S.

Environmental Protection Agency, February 1992.

10. J. E. McCormack, Evaluation Test Of The Kaiser Permanente Hospital Waste Incinerator in

San Diego, California Air Resources Board, March 1990.

nja.117\sect.2-6 5-49

11. Medical Waste Incineration Emission Test Report, Lenoir Memorial Hospital, Kinston,

North Carolina, U. S. Environmental Protection Agency, August 12, 1991.

12. Medical Waste Incineration Emission Test Report, AMI Central Carolina Hospital, Sanford,

North Carolina, U. S. Environmental Protection Agency, December 1991.

13. A. Jenkins, Evaluation Test On A Hospital Refuse Incinerator At Cedars Sinai Medical

Center, Los Angeles, California, California Air Resources Board, April 1987.

14. A. Jenkins, Evaluation Test On A Hospital Refuse Incinerator At Saint Agnes Medical

Center, Fresno, California, California Air Resources Board, April 1987.

15. A. Jenkins, et al., Evaluation Retest On A Hospital Refuse Incinerator At Sutter General

Hospital, Sacramento, California, California Air Resources Board, April 1988.

16. Test Report For Swedish American Hospital Consumat Incinerator, Beling Consultants,

Rockford, Illinois, December 1986.

17. J. E. McCormack, ARB Evaluation Test Conducted On A Hospital Waste Incinerator At Los

Angeles County--USC Medical Center, Los Angeles, California, California Air Resources

Board, January 1990.

18. M. J. Bumbaco, Report On A Stack Sampling Program To Measure The Emissions Of

Selected Trace Organic Compounds, Particulates, Heavy Metals, And HCl From The Royal

Jubilee Hospital Incinerator, Victoria, British Columbia, Environmental Protection

Programs Directorate, April 1983.

19. Medical Waste Incineration Emission Test Report, Borgess Medical Center, Kalamazoo,

Michigan, EMB Report 91-MWI-9, U. S. Environmental Protection Agency, Office of Air

Quality Planning and Standards, December 1991.

ja.117\(Reformatted 1/95) 7/93 5-50

20. Medical Waste Incineration Emission Test Report, Morristown Memorial Hospital,

Morristown, New Jersey, EMB Report 91-MWI-8, U. S. Environmental Protection Agency,

Office of Air Quality Planning and Standards, December 1991.

21. Report Of Emission Tests, Burlington County Memorial Hospital, Mount Holly, New Jersey,

New Jersey State Department of Environmental Protection, November 28, 1989.

22. Results Of The November 4 And 11, 1988 Particulate And Chloride Emission Compliance

Test On The Morse Boulger Incinerator At The Mayo Foundation Institute Hills Research

Facility Located In Rochester, Minnesota, HDR Techserv, Inc., November 39, 1988.

23. Source Emission Tests At ERA Tech, North Jackson, Ohio, Custom Stack Analysis

Engineering Report, CSA Company, December 28, 1988.

24. Memo to Data File, Hershey Medical Center, Derry Township, Pennsylvania, from Thomas

P. Bianca, Environmental Resources, Commonwealth of Pennsylvania, May 9, 1990.

25. Stack Emission Testing, Erlanger Medical Center, Chattanooga, Tennessee,

Report I-6299-2, Campbell & Associates, May 6, 1988.

26. Emission Compliance Test Program, Nazareth Hospital, Philadelphia, Pennsylvania, Ralph

Manco, Nazareth Hospital, September 1989.

27. Report Of Emission Tests, Hamilton Hospital, Hamilton, New Jersey, New Jersey State

Department of Environmental Protection, December 19, 1989.

28. Report of Emission Tests, Raritan Bay Health Services Corporation, Perth Amboy,

New Jersey, New Jersey State Department of Environmental Protection, December 13, 1989.

29. K. A. Hansen, Source Emission Evaluation On A Rotary Atomizing Scrubber At Klamath

Falls, Oregon, AM Test, Inc., July 19, 1989.

nja.117\sect.2-6 5-51

30. A. A. Wilder, Final Report For Air Emission Measurements From A Hospital Waste

Incinerator, Safeway Disposal Systems, Inc., Middletown, Connecticut.

31. Stack Emission Testing, Erlanger Medical Center, Chattanooga, Tennessee, Report I-6299,

Campbell & Associates, April 13, 1988.

32. Compliance Emission Testing For Memorial Hospital, Chattanooga, Tennessee, Air Systems

Testing, Inc., July 29, 1988.

33. Source Emission Tests At ERA Tech, Northwood, Ohio, Custom Stack Analysis Engineering

Report, CSA Company, July 27, 1989.

34. Compliance Testing For Southland Exchange Joint Venture, Hampton, South Carolina,

ETS, Inc., July 1989.

35. Source Test Report, MEGA Of Kentucky, Louisville, Kentucky, August, 1988.

36. Report On Particulate And HCl Emission Tests On Therm-Tec Incinerator Stack, Elyra,

Ohio, Maurice L. Kelsey & Associates, Inc., January 24, 1989.

37. Compliance Emission Testing For Particulate And Hydrogen Chloride At Bio-Medical

Service Corporation, Lake City, Georgia, Air Techniques Inc., May 8, 1989.

38. Particulate And Chloride Emission Compliance Test On The Environmental Control

Incinerator At The Mayo Foundation Institute Hills Research Facility, Rochester,

Minnesota, HDR Techserv, Inc., November 30, 1988.

39. Report On Particulate And HCl Emission Tests On Therm-Tec Incinerator Stack, Cincinnati,

Ohio, Maurice L. Kelsey & Associates, Inc., May 22, 1989.

nja.117\(Reformatted 1/95) 7/93 5-52

40. Report On Compliance Testing, Hamot Medical Center, Erie, Pennsylvania, Hamot Medical

Center, July 19, 1990.

41. Compliance Emission Testing For HCA North Park Hospital, Hixson, Tennessee, Air

Systems Testing, Inc., February 16, 1988.

42. Compliance Particulate Emission Testing On The Pathological Waste Incinerator, Humana

Hospital-East Ridge, Chattanooga, Tennessee, Air Techniques, Inc., November 12, 1987.

43. Report Of Emission Tests, Helene Fuld Medical Center, Trenton, New Jersey, New Jersey

State Department of Environmental Protection, December 1, 1989.

ap-42 background document, section 2.3 medical … rotary kiln incinerator s ... medical waste...

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