additive manufacturing...two or more potentially different materials together while assuring...
TRANSCRIPT
Society for the Advancement of Material and Process Engineering
July/August 2017 Vol. 53, No. 4
www.sampe.org
Additive Manufacturing
INTERNATIONAL INC. EUROPE Sarl ASIA LTDADVANCED MATERIALS LTD
More than a manufacturer... A technical partner!
Excellent elongation and strength reduces bridging in corners, avoiding scrap or rework.
High visibility colors can reduce risk of FOD and leaving film on cured parts.
Color options help differentiate perforation styles.
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SAMPE Journal, Volume 53, No. 4, July/August 2017
Society for the Advancement of Material and Process Engineering
SAMPE Journal ISSN0091-1062 Copyright ©2017 by the Society for the Advancement of Material and Process Engineering (SAMPE®) is published bi-monthly, with an additional issue in the fall (Annual Resource Guide), by SAMPE, 21680 Gateway Center Drive, Suite 300, Diamond Bar, CA 91765 seven times a year (Jan., Mar., May, July, Sept., Nov.) Editorial Offices: 21680 Gateway Center Drive, Suite 300, Diamond Bar, CA 91765. Accounting and Circulation Offices: SAMPE, 21680 Gateway Center Drive, Suite 300, Diamond Bar, CA 91765. Call (626) 521.9460 to subscribe. Application to mail at Periodical postage paid at City of Industry, CA and additional mailing offices, (if applicable). SAMPE Journal, USPS (518-510).
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3 Technical Director’s Corner 5 SAMPE Journal Editorial Calender12 CAMX 201714 Industry News15 SAMPE Career Center16 SAMPE China 201817 SAMPE 2018 Call for Papers25 SAMPE Tooling Workshop26 SAMPE Seattle 2017 Review & Photos28 SAMPE Membership35 SAMPE Europe 36 Perspectives47 SAMPE Call for Videos-You Tube59 Welcome SAMPE’s Newest Members60 Advertiser’s Index61 SAMPE Mega62 Resource Center66 SAMPE Become A Member67 SAMPE Foundation68 Industry Events Calender
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Page 48Design and Fabrication of Multifunctional
Aerodynamic Structures using Additive Manufacturing
Feature Articles
SAMPE Journal
Page 6Democratizing Composites Manufacturing –
Inexpensive Tooling Empowers New Players
Page 18Design Guide Development
for Composite Tooling Produced with Additive
Manufacturing (FDM)
Page 30Design and Characterization of a Screen
Printed Conformal Broadband Composite Antenna
Page 38Evaluation of Residual Stress in TI6AL4V Parts Produced by Power Bed - EBM Process
Contents
INTERNATIONAL INC. EUROPE Sarl ASIA LTDADVANCED MATERIALS LTD
More than a manufacturer... A technical partner!
Excellent elongation and strength reduces bridging in corners, avoiding scrap or rework.
High visibility colors can reduce risk of FOD and leaving film on cured parts.
Color options help differentiate perforation styles.
Easy release off cured parts, leaving excellent finish.
Widths up to 120 inches (3.05 m) without heat seams.
A4000Wrightlon® 5200
BENEFITS
Wrightlon® 5200Elongation: 350%Use Temperature:
500°F (260°C)
A4000Elongation: 300%Use Temperature: 500°F (260°C)-Available in Bonded One Side (BOS)
Airpad Rubber Fabrication bonds well with A4000 BOS‐
HiTempReleaseFilms_03.indd 1 5/31/17 9:07:22 PM
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SAMPE Journal, Volume 53, No. 4, July/August 2017
Dr. Scott W. Beckwith, FSAMPESAMPE Journal Technical Editor
A Note from the Technical Editor
Bonding, Joining and Hybrid Joint Systems
The recent SAMPE Seattle 2017 technical program featured three sessions on “Bonding and Adhesives Technology.” A total of 21 presentations were made regarding this technology covering preparation, materials and process aspects. While much of this technology has been founded on the needs within the aerospace industry for structural joints that often are adhesively bonded, or bolted together
(maybe even both), other industries often require joining of several structures. The marine industry has long been known to require adhesively bonded joints. The automotive industry, in shifting to the application of more lightweight composites, is looking at how to join composites to traditional metal structures.Aerospace has typically bonded composite laminates to themselves, to metal structural components and to ceramic materials. Thermoset adhesives typically are used and the surface preparation methods are often rigid, well-defined and
carefully controlled. However, the cure times often are quite long and not necessarily adaptable to production line automotive requirements. Riveting, bolted and bonded-bolted joints also are common within the aerospace industry. Thermoplastic composites typically are “heat welded” together using electrical heating or hot air heating of structures. Such processes with thermoplastics offer the automotive industry faster potentially “joining times” for assembling thermoplastic composite parts to each other.Film adhesives have frequently been used to bond honeycomb core structures to composite laminates (as well as to metallic sheet materials and foam core structures). These materials typically require freezer storage, removal, thawing, application and thermal curing which requires time and expense. In many situations, they are the appropriate bonding and joining method for high performance aerospace structural applications. However, for the automotive industry, most likely other methods are preferred. The science, art and engineering aspects of “bonding and joining” technology has always involved careful material preparation so that the chemical, mechanical or combined joint structure achieves maximum structural performance over time. Surface preparation and joint preparation (machining, drilling, bolt patterns, alignment, etc.) all must be carefully controlled. Post-processing inspection is also of key importance. Testing of joints potentially to some predetermined load level may be required to assure long-term durability and ability to sustain design loads. The challenge for industries such as the automotive market, is to determine what current bonding and joining technologies meet their needs as they increase composites use within their vehicles. Automotive structures currently rely on a significant amount of steel and aluminum metallic support structures based upon decades of experience
with welding, bolting and riveting technology. The term “hybrid joint systems” is becoming a term more widely heard within that industry. CAMX 2017 will be looking at how combinations of “bonding, joining and hybrid joint systems” are being assessed across the automotive industry and other markets where traditional methods may not satisfy current production and structural requirements. Combining two or more potentially different materials together while assuring long-term structural efficiency and durability is an important technology. Non-destructively inspection (NDI) aspects for confirming joint integrity is an associated technology area of equal importance. Joints which cannot later be disassembled present a need
for more rigorous NDI methodologies.SAMPE will be addressing several of the above issues in the future at our conference and educational events. This area is important to continues aerospace industry interests as well as emerging automotive market use of composites.
SAMPE Journal, Volume 53, No. 4, July/August 2017
SAMPE Global Officers 2017-2018Global President, Dr. Katie Thorp
Research Lead, Organic Matrix Composite Materials and [email protected]
Global Executive Vice President, Brent Strong, PhD Professor Emeritus, Brigham Young University
President of China Region, Prof. Xiaosu YiACC Beijing S&T Co., Ltd • [email protected]
President of Europe Region, Prof. Jyrki VuorinenTampere University of Technology, Lab of Plastics & Elastomers
President of Japan Region, Prof. Kazuro Kageyama The University of Tokyo • [email protected]
President of North America Region, Ben DietschPresident, NONA Composites LLC • [email protected]
Global Immediate Past President, Prof. Luigi “Gino” Torre Professor Dept. of Civil and Environmental Engineering,
University of Perugia • [email protected]
Global Secretary, Gregg Balko, FASAE, CAE CEO and Executive Director, SAMPE • [email protected]
SAMPE International DirectorsCEO and Executive Director, Gregg Balko • [email protected] Director, Dr. Scott Beckwith • [email protected]
Editorial BoardRodrigo Berardine (2016-2018) – Owens Corning Fiberglas
Prof. Terry Creasy (2016-2018) – Texas A&M UniversityProf. Michael Czabaj (2016-2017) – University of Utah
Prof. Paolo Ermanni (2016-2017) – ETH ZuerichProf. David Fullwood (2016-2017) – Brigham Young University
Prof. Lessa Grunenfelder (2016-2018) – Univ. of Southern CaliforniaDr. Clem Hiel (2016-2017) – Composites Support & SolutionsDr. Rikard Heslehurst (2016-2017) – Heslehurst & Associates
Prof. Pascal Hubert (2016-2017) – McGill UniversityProf. Andrew Long (2016-2018) – University of Nottingham
Sandi Miller (2016-2018) – NASA Glenn ResearchProf. Andrew Mills (2017-2018) – Cranfield University
Jorge Nasseh (2016-2017) – Barracuda CompositesArnt Offringa (2016-2018) – Fokker Aerostructures BV
Prof. Young-Bin Park (2016-2017) – Ulsan National Institute of Science & Technology
Dr. Louis Pilato (2016-2017) – Pilato ConsultingProf. Anoush Poursartip (2016-2017) – Univ. British ColumbiaProf. Donald Radford (2017-2018) – Colorado State University
Kara Storage (2016-2018)–Air Force Research Laboratory (WPAFB) Tara Storage (2016-2018) – Air Force Research Laboratory (WPAFB)
Prof. Nobuo Takeda (2016-2017) – The University of TokyoDr. Robert Yancey (2016-2017) – CompForte
Prof. Xiaosu Yi (2016-2018) – AVIC Composites Corporation
SAMPE Journal Editorial Office21680 Gateway Center Drive, Suite 300, Diamond Bar, CA 91765 USA
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Publication StaffTechnical Editor, Dr. Scott Beckwith • [email protected]
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SAMPE Journal, Volume 53, No. 4, July/August 2017
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SAMPE Journal, Volume 53, No. 4, July/August 2017
Democratizing Composites Manufacturing – Inexpensive Tooling Empowers New Players
Kim-Niklas Antinab, Tuomas Pärnänenbc
a Aalto University, Department of Mechanical Engineering, Finlandb ideas2cycles r.y., Finlandc Tampere University of Technology, Laboratory of Materials Science, FinlandE-mail: [email protected]
Abstract Additive manufacturing (AM) has become more common in the composites industry during the past decade. There are several
areas where the quick production of tooling and fixtures using additive manufacturing makes sense. Typical drawbacks of AM have recently been solved, such as the low-Tg of printing materials and small build envelopes. However, wide-spread use of AM in the composites industry is not yet reality due to risks involved with investments in a new production method and the lack of expertise to use AM where the benefits are greatest.
The risks can be lowered with the right approach and acquiring AM expertise does not necessarily mean big investments in machines. We will present here an approach, which allows composites manufacturers to experiment and explore the possibilities of AM without risky purchases. A case study is presented showing how a real product, such as a bicycle frame, can be manufactured using low-cost AM techniques.
IntroductionRapid prototyping using additive
manufacturing (AM) has already been used extensively in the casting and injection molding industry for many decades1. Some composites manufacturers have also adopted the approach during the past decade. The main benefits are reduced cost, faster development cycles and freedom of design. Additive manufacturing is used for patterns, molds, pre-forms, intensifiers, caul plates, lay-up tools, high strength soluble mandrels, trim & drill tools, and even secondary processes like bonding fixtures, consumable cores and permanent core structures2. In addition to product development and prototyping, low volume production and repairs have recently gained popularity3. Furthermore, high temperature resistant materials have become available, making it possible to produce molds for elevated curing temperatures3. Big area additive manufacturing (BAAM) is seeing its first commercial machines and the cost savings compared to traditional tool making have been shown4. However, there are still obstacles in the way before we can talk about a paradigm shift or manufacturing revolution.
Composites manufacturers
have been slow to adopt additive manufacturing because there is always a risk involved in change and the gains are not clear4. There has been a lot of hype around additive manufacturing and some companies have invested in AM out of fear of being left behind the rapid development5. The sales speeches claim anything is possible with AM, but that actually leaves too many options open and it is difficult to get started. In other words, the main argument for investing in additive manufacturing has turned against itself. Tremendous disappointment follows if the machine does not do what was expected of it or if there is no real need and the machine lays dormant. Therefore, case studies are needed to show the way and act as examples of successful implementation of AM. Another obstacle in the way of adopting AM is the lack of in-house expertise. Many turn to the machine manufacturers for help in designing2. In-house expertise is needed to truly reap the benefits of fast lead times and rapid iterations, but such expertise cannot accumulate unless the designers have access to their own machine. However, investing in a $200.000 machine is too risky for small companies in particular. Especially if
the molds need to be post-machined with a 5-axis milling machine4. Moreover, expensive feedstock ($100/lb.) does not encourage experimentation or a “fail fast” approach, although that approach is one of the main benefits of additive manufacturing.
There are challenges also on the software side. Although additive manufacturing allows complex designs, it requires a different approach to modelling compared to, for example, 3-axis CNC milling, where the design limitations are different. In fact, designing for additive manufacturing differs so much from traditional manufacturing methods, that the workflow of typical CAD software, i.e. extruding and cutting using 2D-sketches in orthogonal planes, is steering the design choices towards a direction that is not fully embracing the design freedom that AM offers. Development on the software side is definitely needed, but also the designers need to be educated on additive manufacturing. The best way to do that is simply start using AM. Desktop printers are so cheap nowadays that they should be included in every creative design process. Having a printer in-house lowers the threshold for experimenting with unfinished
Feature ArticlesSubscribe or become a member to access the full issue of the SAMPE Journal, which includes the full technical articles. https://sampe.site-ym.com/page/sampejournalsub
SAMPE Journal, Volume 53, No. 4, July/August 2017
Feature ArticlesDesign Guide Development for Composite Tooling
Produced with Additive Manufacturing (FDM)
T. J. Schniepp Stratasys, Inc., Eden Prairie MN
AbstractThe advanced composites industry has a continual need for innovative tooling solutions to enable new applications and
product improvements, as well as address the constant demand for reductions in response (lead) time and costs. Stratasys Fused Deposition Modeling (FDM®) technologies allow rapid production of cost effective, highly capable composite tooling across a broad range of tool sizes, complexity, and cure temperatures. This paper will outline the development efforts, testing, and characterization performed to produce a comprehensive design guide for additive manufacturing (FDM) of high temperature (>350°F) molds and mandrels for fabrication of composite structures.
IntroductionFused Deposition Modeling
(FDM) is a Stratasys-patented additive manufacturing technology that builds parts layer-by-layer by heating and extruding thermoplastic filament. FDM builds in a wide range of standard, engineering-grade, and high-performance thermoplastics, such as ABS, PC, and ULTEM™ resins.
FDM is becoming a technology of choice for rapid production of high temperature (>180 °C), low volume composite lay-up and repair tools, as well as for production sacrificial (wash-out) tooling. Relative to traditional tooling materials and methods, FDM offers significant advantages in terms of lead time, tool cost, and simplification of tool design, fabrication, and use while enabling increased functionality and geometric complexity.
To enable successful implementation and use of FDM
composite molds and mandrels (referred to as “composite tooling” or “composite lay-up tooling” herein), Stratasys has developed a comprehensive Design Guide to address best practices for printed tooling, as well as to provide relevant performance characterization data and numerous examples of effective tool designs. A summary of the development and characterization efforts are presented herein.
Background and PurposeTraditional manufacturing
methods for high performance fiber-reinforced polymer matrix (FRP) composite structures require the use of hard tooling for the mold or mandrel that dictates the shape of the final part. The mold or mandrel is most commonly made of metallic materials (aluminum, steel, or Invar alloys), although non-metallic materials are also utilized (specialized composite tooling
materials, high temperature tooling board, etc.). Regardless of material, tool fabrication typically requires significant labor and machining, leading to high costs, material waste, and long lead times, consisting of many weeks for even relatively simple part shapes and many months for more complex tools. The use of additive manufacturing (or “3D printing”), and specifically FDM, for composite tooling has demonstrated considerable cost and lead time reductions while providing numerous other advantages such as immense design freedom and rapid iteration, nearly regardless of part complexity.
Stratasys FDM technology has been successfully utilized for low volume composite lay-up and repair tooling applications for years, but was limited by the lack of materials capable of withstanding the 180°C cure temperature frequently required for aerospace and similar high performance structures, as well as a lack of design knowledge and guidance. FDM materials ABS (and ASA), PC, and ULTEM™ 9085 have been demonstrated to be effective to temperatures up to 85°C, 135°C, and 150°C, respectively. With the introduction of ULTEM™ 1010, FDM technology has demonstrated numerous advantages for fabrication of composite structures cured at temperatures in excess of 180°C and pressures of 0.7 MPa.
Figure 1. Cure temperature capabilities for FDM materials.
SAMPE Journal, Volume 53, No. 4, July/August 2017
Feature ArticlesDesign and Characterization of a Screen Printed
Conformal Broadband Composite AntennaLan Yao, Ye Kuang, He Luan, Yiping Qiu*College of Textiles, Donghua University, Shanghai 201620 (China)*Corresponding author email: [email protected]
Abstract Nowadays, antennas have great applications in aircrafts, automobiles and numerous smart devices. When antennas are used
in aircrafts as a signal transmission component, its structure, profile, weight and strength are required to be designed carefully. In this study, a screen printed conformal broadband composite antenna is designed and fabricated. The radiation and mechanical properties of the antenna are tested and compared with the broadband composite antenna with copper foil patches. The measured results show that the bandwidth of the screen printed composite antenna is 125 MHz covering the frequency bands of both GPS and Beidou Navigation Satellite System and the radiation pattern of the antenna shows proper shape and directivity. Furthermore, the screen printed composite antenna shows higher tensile and bending strength than its copper foil path counterpart. Therefore, it is concluded that the designed antenna is a desirable candidate for the aircraft conformal antenna. Keywords: Microstrip antenna; Screen print; Composite; Radiation properties; Mechanical properties
IntroductionAntenna plays an important
role of receiving and transmitting signals in modern devices and they are becoming increasingly indispensable in aircrafts, satellites and automobiles1-3. More than 70 types of antennas were mounted in the advanced in-service aircrafts4. In early time, monopole antennas were widely adopted in aircrafts. However, the protruding structures of the antennas increased aerodynamic resistance of the aircrafts and limited its applications. In 1990s, The United States Air Force (USAF) came up with a new design of the conformal load-bearing antenna structure (CLAS) which decreases the aerodynamic resistance and saved energy. After that, efforts have been made to build models for the conformal structure by using
the computer program including the finite element method, finite difference time domain and method of moments5-8. Some researchers conducted a series of experimental to modify the performance of the conformal antenna structure. Nicholas A. Bishop9 designed a broadband high-gain bi-layer log-periodic dipole array antenna for conformal structure to increase the bandwidth and gain. P. Li10 modified the manufacturing flaws to enhance wave-transparent property of the conformal structure. However, attention is needed to pay to the integration method for obtaining better rigidity and efficiency, and reducing the structure weight at the same time.
In this study, a screen printed conformal broadband composite antenna was designed and fabricated
to cover the frequency bands of GPS (1.575GHz) and Beidou Navigation Satellite System (1.560 to 1.563GHz). The radiation patch of the antenna was fabricated with silver ink by using the screen printing process and the vacuum assistant resin transfer molding (VARTM) method was used for the composite antenna fabrication. The radiation properties and mechanical properties of the antenna was tested and compared with the copper foil patch composite antenna. The measured properties were discussed and the feasibility of the proposed screen print conformal broadband composite antenna was proved.
Antenna DesignThe broadband antenna proposed
in this study was a microstrip antenna which consists of radiation patch, substrate and ground plane as shown in Figure 1. The antenna was designed with frequency band covering both GPS (1.575GHz) and Beidou satellite (1.560 to 1.563GHz) frequency band. A modified U-slot was introduced into the radiation patch to obtain broadband effect. The substrate of the antenna was a laminated glass fabric composite with thickness of 2.28mm and dielectric constant and loss tangent of 3.763 and 0.01 respectively. The dimensions of the antenna were
SAMPE Journal, Volume 53, No. 4, July/August 2017
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Evaluation of Residual Stress in TI6AL4V Parts Produced by Power Bed - EBM Process
A. A. Antonysamy1,2 and L. L. Parimi1
1Additive Manufacturing Centre, Global Engineering,GKN Aerospace, Bristol, BS34 7QQ, UK
2Previously, Manchester Materials Science Centre,The University of Manchester, Manchester, M13 9PL, UK
Email: [email protected]
AbstractElectron Beam Melting (EBM) is a type of Additive Manufacturing (AM) technique where the 3D geometries are produced
from the CAD files using electron beam as a heat source. Electron beam is used to melt the powder layer by layer under vacuum which would result in very low oxidation in titanium alloys. In AM due to the nature of repeated heating and cooling of layers, residual stresses are observed in the components. It is important to understand the magnitude of residual stresses in the parts to design further post process treatments to deal with these stresses and resulting distortion. This paper focuses on characterising the magnitude of residual stresses in Ti6Al4V EBM components. A portable X-ray diffraction system was used to assess the stress levels in the parts. The key findings showed that there were no significant residual stresses present in the Ti6Al4V component which is attributed to the nature of pre-heated powder bed used in EBM unlike other conventional AM techniques using lasers.
IntroductionAdditive Manufacturing (AM), a near-net-shape fabrication technique used to produce solid components by
consolidating layers of powder, or wires, or ribbons. The materials to be deposited are melted by a focused heat source, such as an electron beam (e-beam), or laser, or plasma in arc welding. Each layer is a 2-D slice built layer-by-layer of a final 3D CAD component. The deposition process is usually carried out under vacuum (e-beam) or in an inert gas (laser) environment to avoid contamination1. The AM technique is not a new process and is essentially a rapid proto-typing technique that has been used for many years to produce 3D parts in the field of polymeric materials processing. However, in the past few years, a considerable amount of attention has been given to the direct deposition of metallic materials, especially in sectors like aerospace, defence, automobile and medical industries2. This is mainly because AM of metal components with virtually no geometric limitations or tools, offers new ways to increase product performance or to establish new processes and revenue streams. AM is an energy efficient environmentally clean and sustainable manufacturing processes with almost no wastage of raw powder materials as it is a near or net-shape manufacturing process unlike conventional cast/forged parts with subsequent heavy machining with a buy-to-fly ratio of 20:1, whereas AM, is 2-5: 1. Although metallic AM was initially exploited as the rapid prototype for tooling and test flight demonstrations, now it is on the verge of shifting from a pure rapid prototyping technology to series production readiness and is, therefore, opening up new market opportunities for machine suppliers, manufacturing service providers, designers and original equipment manufacturers.
Feature Articles
SAMPE Journal, Volume 53, No. 4, July/August 2017
Design and Fabrication of Multifunctional Aerodynamic Structures using Additive Manufacturing
G. F. Nino, A. Wadhwa1
QUEST Integrated, LLC. (Qi2).Kent, WA
F. Spencer, R. Breidenthal Department of Aeronautics and Astronautics University of Washington
Seattle, WA
AbstractThe recent advances of additive manufacturing are opening the doors for the development of novel applications in the aerospace
field. One area of particular interest is the development and fabrication of multifunctional systems on aerospace systems. Here, printed electronics have been used to add new functions such as sensing and acting onto novel 3D printed aircraft structural designs. The combination of both additive manufacturing techniques allows the fabrication of highly integrated vehicles such as unmanned aircraft vehicles (UAVs), drones, and aerodynamic wind tunnel models at low cost. In this paper, we present the development and fabrication of several multifunctional systems such as ice protection systems, structural health monitoring, and sensing surfaces among others deposited over 3D printed structures. In particular, we will discuss processing and manufacturing conditions for the development of aircraft wind tunnel models. This work has been funded by the U.S. Air Force Research Laboratory to demonstrate technology maturity as well as feasibility and viability of printed electronics for flying applications.
IntroductionWith the increasing demand on
structural performance as well as decreasing size and weight of advanced flying structures, there is a reduction in the available volume for aircraft instrumentation. In addition, integral fabrication of structures using composite materials and close integration and optimization of aircraft system and subsystems limit further access and space for sensors, wiring, and instrumentation. This situation becomes more critical during aircraft Testing and Evaluation (T&E) phases than during service phase. In order to assess how new flying systems perform during T&E, new technologies and
approaches are needed to monitor aircraft loads and structural responses during different flight stages and missions. Some ways to reach this goal is by replacing “conventional” instrumentation and testing methods with:• Smart materials that can be embedded into or deposit onto the structure such as piezoelectrics, carbon nanotubes, or metamaterials.• Smart manufacturing methods based on additive manufacturing for structures (3D printing) or for electronics (printed electronics).• Flexible electronics where sensors and electronic devices are fabricated on flexible substrates ready for bonding onto any structure.
• Embedded sensors within composite structures to produce multifunctional systems.• Virtual models (digital twin) of real vehicles to update and recreate performance as well to assess integrity based on actual system data.
Most of these techniques are suitable for implementation on new systems but have limited application to current flying structures except for printed electronics. It is clear that a robust sensing system for T&E aircraft applications needs to be friendly to the host structure, sensitive, accurate, reproducible, reliable over time, and durable.
Today, additive manufacturing techniques for structural components are becoming popular not only in daily use products, but also are becoming an alternative to fabricate high performance structures. In parallel, printed electronics technologies are being transitioned from lab systems into real life applications, from consumer electronics to solar panels and to sensing/acting networks, for example. The use of different inks (e.g., conductors, semiconductors, and dielectrics) can be used to produce highly Figure 1. PSKIN: Printed sensing network concept.
Feature Article
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SAMPE Journal, Volume 53, No. 4, July/August 2017
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Combination vacuum bag materials with Release Film, Breather, and/or Peel Ply bonded
into a multi-function laminate
Wrightlon® 5200 Release Film and Airweave® Breather bonded together
SAMPE Journal, Volume 53, No. 4, July/August 2017
[email protected] • 904 Buffaloville Rd., Dale, IN 47523 • 800-533-6901
SAMPE Journal, Volume 53, No. 4, July/August 2017
For most people, creating professional relationships is important. When you join SAMPE, you gain immediate access to benefits valued by thousands of M&P professionals, including:
Join SAMPE Today www.sampe.org
Get immediate access to member benefits when you join SAMPE today.
The Society for the Advancement of Material and Process Engineering (SAMPE®) is a global professional
member society. SAMPE provides information on new materials and processing technology via conferences,
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of endeavor in materials and processes, SAMPE provides a unique and valuable network for scientists,
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BECOME A MEMBER
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SAMPE Journal, Volume 53, No. 4, July/August 2017
COMPOSITE TEST FIXTURES
Wheeling, IL USA www.mttusa.net
Material Testing Technology
Ph (847) 215-7448
ASTM D3410
ASTM D7249
ASTM D2344 ASTM D4255
ASTM D5379
ASTM C297 ASTM D7332
ASTM D6641
ASTM D695 ASTM D7264
ASTM C393
ASTM D3039
SAMPE Journal, Volume 53, No. 4, July/August 2017
a
High Desert SAMPE Technical Conference
October 4, 2017 8:00 am - 4:30 pm
Antelope Valley Fairgrounds Hunter Pavilion Lancaster, CA
Featuring: 10 Technical Presentations
75 Material Supplier Exhibitors
Limited Booths Available
Contact: Ashok Shah [email protected]
661-572-7243
Entrance Fee and Lunch are Complimentary and Provided by:
Pre-register online at www.highdesertsampe.org
Technical Conference 2017 High Desert SAMPE
Society for the Advancement of Material and Process Engineering High Desert Chapter
SAMPE Tooling Workshop
Register today atwww.nasampe.org
Tooling Technologies for Composites: A Hands-on Workshop
October 17-18, 2017 Los Angeles, CA
Take part in this new Seminar which includes a Hands-On Workshop as part of our contribution to Workforce Development. In addition to being an interactive event involving the composites industry's leading tooling companies and presenters, participants are able to engage in several hands-on exercises within the University of Southern California's composites laboratory.
Day OneDay One features tooling materials and applications presentations from leading companies, providing a comprehensive overview of tooling materials and processes. Participating companies include:
Upcoming Events For a complete list of upcoming SAMPE Events and details visit www.nasampe.org. Current members receive discounted registration rates for SAMPE Events.
Supporting Partners
IACMI - Tooling for Automotive & Energy Applications
Janicki IndustriesRubbercraftCoast Composites ToolingAirtech International, Inc.
Day Two Day two is entirely focused on several "hands-on" exercises with composite materials, observations of tooling-part interactions, a tooling demonstration and – plenty of time for discussions with presenters and tooling technologists.
Abaris Training ResourcesSpinTech (Smart Tooling)Advanced Ceramics ManufacturingStratasys Inc.Carbon Innovations LLC (CFoam)
BTG Composites, Inc.
SAMPE Journal, Volume 53, No. 4, July/August 2017
CALL FOR VIDEOSSAMPE’s YouTube channel aims to educate and connect materials and process engineering professionals and students through sharing ideas and best practices, evaluating research and new applications and generally informing members and non-members of SAMPE’s mission and goals. We invite you to partner with us by submitting your company’s videos that demonstrate a process, a test method, a unique application or considerations in a design for such topics as:
Advances in ThermoplasticsBonding and Adhesives TechnologyNext Generation CoatingsDesign, Analysis and TestingProcess ModelingSimulation, and Computational ModelingNDE and Structural Health MonitoringTextilesMarket Applications - Aerospace and Automotive Market Applications - Energy and Sporting GoodsMarket Applications - BiomaterialsSpace Structures and Materials
Green TechnologiesAdditive ManufacturingAdvances in Composite Manufacturing TechnologiesEmergent Materials & Technologies
Please consider the following when submitting a video:■ Must be educational/informational
■ No purely promotional videos; product videos are acceptable as long as their goal is to educate the public.
■ Must be < 2 min in length. Exceptions can be made on a case-by-case basis
Please visit our website for additional guidelines. Submit your videos online at tinyurl.com/SAMPE-youtube
DOING BUSINESS SINCE 1981With over 4,000 hot bonders delivered to over 800 customers, over 3,000 are still in service.
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For over 30 years, HEATCON Composite Systems has been at the forefront in supporting advanced composite repair and manufacturing.
We achieve thermal uniformity through Heat and Control.
To find out more visit www.heatcon.com or email [email protected]
Contact Heatcon for hot bonders, heat blankets, and materials Authorized Distributor for 3M and Hexcel
480 Andover Park East Seattle, WA 98188 | P: 206.575.1333 | F: [email protected] | www.heatcon.com
Over 50 years Advanced Composites & FRP Composites experience
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www.BTGCompositesPro.com Email: [email protected]
Manufacturing, Processing, Design, Analysis Support:
Training Services:In-plant courses, tutorials, seminars, workshops, training manuals, and plant documents
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Over 550 technical publications, presentations and reports
SAMPE Journal, Volume 53, No. 4, July/August 2017
NEW COMPOSITE MANUFACTURING TECHNOLOGY BADGES
• Learn more at badges.wichita.edu
$50 Scholarships are available! Enroll before September 15, 2017
Wichita State University is offering a series of four 0.5 credit hour online badge courses and a hands-on lab course beginning August, 2017. This coursework provides an overview of the workflow in a composite manufacturing facility. Topics include:Badge 1: Background of composites materials and their usage, manufacturing methods and the relevant regulatory guidance.Badge 2: Raw materials manufacturing, transportation of materials, incoming quality control and storage, tool preparation, cutting of prepreg, layup and bagging, and the cure and solidification of composites.Badge 3: Trimming and drilling of composite parts, inspection techniques, bonding and part assembly.Badge 4: Painting and finishing of composite parts, handling and storage, and common manufacturing issues.
The fifth badge course is a hands on lab experience offered at Wichita State’s National Institute for Aviation Research.The badge courses are self-paced. Students must complete the modules in sequence by the end of the semester. The online content includes course notes and engaging lecture videos with voice over power point presentations. The students are required to complete quizzes at the end of each module to evaluate their learning.
SAMPE Journal, Volume 53, No. 4, July/August 2017
- Compression - Mechanical Testing - Physical Properties - Flammability Testing
- Shear Testing - Fatigue Testing - Peel Resistance- Flexure Testing
- DMA - DSC - TMA - TGA - DLF-1200- Thermal Analysis
Testing Capabilities Include:
www.WMTR.com
Westmoreland Mechanical Testing & Research
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1967 2017
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SAMPE Journal, Volume 53, No. 4, July/August 2017
Foundation
SAMPE Journal, Volume 53, No. 4, July/August 2017
Company
Abaris Training
Airtech International, Inc.
American Elements
APCM
Bally Ribbon Mills
BTG Composites, Inc.
CAMX
ChemTrend
Cincinnati Testing Labs
Coast-Line International
Composite & Wire Machinery
Composite Polymer Design
Composites One
Composites Sources
Concordia Manufacturing, LLC
Daicel ChemTech, Inc.
DeComp Composites, Inc.
Dexmet
Diab
DuraFiber Technologies
Elantas PDG
Element Materials Technology Los Angeles, LLC
Engineered Solutions
Fabric Development, Inc.
General Plastics
General Sealants, Inc.
Heatcon Composite Systems
High Desert SAMPE Chapter
C.A. Litzler Co., Inc.
McClean Anderson
Masterbond, Inc.
Matec Instrument Companies
Material Testing Technology
Maverick Corporation/Renegade Materials
Mitsubishi Gas Chemical America, Inc.
National Aerospace Supply Company
Web-Site/E-Mail
www.abaris.com
www.airtechonline.com
www.americanelements.com
www.prepregs.com
www.ballyribbon.com
www.BTGCompositesPro.com
www.thecamx.org
www.chemtrend.com
www.cintestlabs.com
www.coast-lineintl.com
www.compositewire.com
www.epoxi.com
www.compositesone.com
www.forcomposites.com
www.concordiafibers.com
www.daicel.com/en/us
www.decomp.com
www.expanded-materials.com
www.diabgroup.com
www.durafibertech.com
www.elantas.com/pdg
www.element.com
www.edactechnologies.com
www.fabricdevelopment.com
www.generalplastics.com
www.generalsealants.com
www.heatcon.com
www.highdesertsampe.org
www.calitzler.com
www.mccleananderson.com
www.masterbond.com
www.matec.com
www.mttusa.net
www.maverickcorp.com
www.mgc-a.com
www.nationalaerospace.com
Phone
+1 775.827.6568
+1 714.899.8100
+1 310.208.0551
+1 860.564.7817
+1 610.845.2211
+1 801.232.5407
+1 626 521.9460
+1 517.545.7981
+1 513.851.3313
+1 631.226.0500
+1 401.884.4760
+1 800.755.8568
+1 800.621.8003
+1 225.273.4001
+1 401.828.1100
+1 201.461.4466
+1 918.358.5881
+1 203.294.4440
+1 972.228.7612
+1 704.912.3700
+1 314.622.8748
+1 818.247.4106
+1 203.806.6818
+1 215.536.1420
+1 253.330.7782
+1 800.762.1144
+1 800.556.1990
+1 661.572.7243
+1 216.267.8020
+1 715.355.3006
+1 201.343.8983
+1 508.393.0155
+1 847.215.7448
+1 513.469.9919
+1 212.687.9030
+1 949.240.6353
Page
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BC
62
62
47
12,13
IBC
62
62
62
62
11
63
62
63
21
41
15
62
63
63
63
63
7
63
47
29
64
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65
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64
Advertisers Index (As seen in the full print and online versions of the SAMPE Journal.)
SAMPE Journal, Volume 53, No. 4, July/August 2017
SAMPE MEGA is our new community discussion forum. MEGA allows current SAMPE members to engage with each other, using our experienced and diverse community to educate and share. Peer Reviews, Expert Q&As, Spring Conference Prep and more. JOIN THE CONVERSATION!
Members Engaging and Getting Acquainted.
sampe.org/mega
Advertisers Index (As seen in the full print and online versions of the SAMPE Journal.)
NDT Solutions
Northern Composites
Pacific Coast Composites
Precision Measurements & Instruments
Renegade Materials/Maverick Corporation
Revchem Composites
SAMPE Foundation
Scott Bader North America
SDI-Talon
Siltech Corporation
Technology Marketing, Inc.
Textile Products
Thermal Wave Imaging
Thermwood
TMP, A Division of French
Torr Technologies, Inc.
Westmoreland Mech. Testing & Research
Wichita State University
Wyoming Test Fixtures, Inc.
64
5
30
64
65
45
67
64
65
15
65
65
65
8
65
55
59
44
2
www.ndts.com
www.northerncomposites.com
www.pccomposites.com
www.pmiclab.com
www.renegadematerials.com
www.revchem.com
www.sampe.org
www.scottbader.com/na
www.sdindt.com
www.siltech.com
www.tmi-slc.com
www.textileproducts.com
www.thermalwave.com
www.thermwood.com
www.frenchoil.com
www.torrtech.com
www.wmtr.com
www.badges.wichita.edu
+1 715.246.0433
+1 603.926.1910
+1 888.535.1810
+1 541.753.0607
+1 508.579.7888
+1 800.281.4975
+1 626.521.9460
+1 330.920.4410
+1 805.987.7755
+1 416.424.4567
+1 801.265.0111
+1 714.761.0401
+1 248.414.3730
+1 800.533.6901
+1 937.773.3420
+1 800.845.4424
+1 724.537.3131
+1 316.978.7579
+1 801.484.5055
Company Page Web-Site/E-Mail Phone
SAMPE Journal, Volume 53, No. 4, July/August 2017
West Coast 310-277-0748 • www.ballyribbon.comE-Mail: [email protected]
Coast-Line International
Stocking Locations in NY, GA, MA with Same Day ShippingPh: 631-226-0500 - Fax: 631-226-5190
[email protected] - www.coast-lineintl.com
Woven Cloth & Prepreg, Film Adhesives, Sealants, Core Splice, Potting Compound, Hot Bonders, Vacuum Bag & Release Film, Breather, Tooling Materials, Connections,
Vacuum Pumps, Infusion Resins, Core Material, Specialty Tapes, Penetrants, Clean Room Consumables
Your One Stop Tech Shop
Woven and braided 2D and 3D structures, complex shapes, contour and polar structures and multi-dimensional engineered materials.
ISO-9001 &
AS-9100
Blended Continuous Filament Thermoplastic and Reinforcement
Fibers for Composites
Markets Served Aerospace, Automotive, Oil/Gas, Sporting Goods
Contact Randy Spencer at401-828-1100 ext 111 or
www.concordiafibers.com
NEW & REBUILT
Resource Center
SAMPE Journal, Volume 53, No. 4, July/August 2017
Apex Machine Tool - dba- Engineered Solutions Division of EDAC Technologies Corporation
Experts in molds for composite part fabrication. We specialize in designing & manufacturing precision multi-piece molds for close tolerance military & commercial applications. Our ability to produce molds for highly detailed complex parts with an experienced team of tool designers & toolmakers makes us your best choice to meet your stringent requirements for RTM, compression, duct & lay up molds.
Visit our website @ edactechnologies.comContact Tom Branday
[email protected] • 203.806.6819-direct5 McKee Place Cheshire, CT 06410203.806.2090 • 203.250.3870 (fax)
www.forcomposites.comComposites Industry Recruiting & Placement
Composites SourcesPhone (225) 273-4001, Fax (225) 273-1138
P.O. Box 86185, Baton Rouge, LA 70879-6185E-mail: [email protected]
• Mechanical Testing• Thermal Analysis DMA, DSC, TMA, TGA• Electrical Properties
• Metallography• Flammability Smoke Toxicity and OSU Heat Release
Element Materials Technology1857 Business Center Drive Duarte, CA 91010USA
P 818 247 4106F 818 247 4537T 888 433 [email protected]
element.comThe Global Leader in High Quality Electrical Insulation Products
www.elantas.com 314-621-5700
Epoxylite® Hi Temp Epoxy Systems
• Mechanical & Electrical Stability at Extreme Temperatures• Exceptional Chemical Resistance• Long Pot Life• Short Cure Cycles• Radiation Resistant
Daicel Cycloaliphatic EpoxyDaicel Cycloaliphatic Epoxy~ High ~ High TgTg, High , High TrasparencyTrasparency & Low viscosity & Low viscosity ~~
O
ROCC
OCH2
O HOR
nOO
O
O
1) Standard grade 2) High Tg grade 3) Methacry‐Epoxy grade
O
CYCLOMER M100O
f
EHPE3150
CELLOXIDE 2021PCELLOXIDE 2021 P
4) Flexible epoxy grade
OOO
OO
On
CELLOXIDE 2080 series; 2081(n=1), 2083(n=3), 2085(n=5) CELLOXIDE 2081OO
O
O
O
O
O
O
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m
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C O 08
OHO
O
EPOLEAD PB seriesEPOLEAD GT401
O
O
O
O
O
O
O
O n
O
O
O
o
EPOLEAD PB seriesEPOLEAD GT401
CHCH CH CH CHCH CH CH
5) Toughness additive 6) Special grade 7) New grade
“CELLOXIDE8000”O
CELLOXIDE 2000
CHCH2
n
O
m
CH2CH CHCH2 CH2CH
CHCH2
EPOFRIEND series
CELLOXIDE8000> High Tg> High modulus> High transparency> Low viscosity
CopyCopyright right DAICEL DAICEL ChemTech, Inc. All Rights Reserved
Contact info.
Daicel ChemTech, Inc. TEL : 201-461-4466 E – mail:[email protected], [email protected]
®
®
Resource Center
SAMPE Journal, Volume 53, No. 4, July/August 2017
LONG
WOR
KING
LIFE
5-7 h
ours
per 1
00 gr
ams
IDEAL FOR LARGE
CASTINGS
4,000-15,000 cpsLow viscosity
HIGH THERMALCONDUCTIVITY9-10BTU•in/ft 2 •hr•°F W
ITHSTANDS
CRYOGENIC SHOCKS
Serviceable from
4K to +275°F
RELIABLE ELECTRICALINSULATION PROFILE
Volume resistivity >1015 ohm-cm
LO
W EXOTHERM EPOXY SYSTEM EP29LPSPAO
Hackensack NJ 07601, USA ∙ +1.201.343.8983 ∙ [email protected]
www.masterbond.com
Slow&SteadyWINS THE RACE
National Aerospace Supply Company
Vacuum Bagging Support MaterialsPrecut Bagging Kits Available
33155 Camino Capistrano Unit CSan Juan Capistrano, CA 92675
Phone (949) 240-6353 Fax (949) 248-5655www.NationalAerospace.com
Scott Bader North AmericaStow, OH USADrummondville (Quebec) CanadaT: +1 330 920 4410F +1 330 920 4415E: [email protected] www.scottbader.com/na
Making a positive difference
12121210Crestapol® ResinRange 1214 1250
LV
WHAT KIND OF TESTING?Precision Thermal ExpansionThermal ConductivityMoisture ExpansionSpecific HeatThermal CyclingMechanical, Creep, Microyield
WHAT KIND OF MATERIALS?Carbon fiber products, metals, ceramics, polymers, foams, adhesives, electronic assemblies
WHAT TEMPERATURE RANGE?20K to over 1,600°C
WHO DO WE SERVE?PMIC provides testing services to companies worldwide
WHY TEST AT PMIC?• Cost effective precision testing• Independent, ISO Accredited, Testing Laboratory• Absolute confidentiality• Data and specimen archiving• Test plan design• Expert analysis of test results
SPECIALISTS IN PRECISION MATERIALS TESTING
www.pmiclab.com • 541.753.0607
C. A. Litzler Co., Inc. 4800 W. 160 St., Cleveland, OH USA 44135-2689
Phone: 216.267.8020 • Web Site: www.calitzler.com
Your single source for: • Hot Melt & Solution Based Prepreg Systems • Carbon Fiber Oxidation Ovens & Plasma Oxidation Ovens • Automation Control Systems
Resource Center
SAMPE Journal, Volume 53, No. 4, July/August 2017
Partnerships succeed that have a shared vision.
Partnerships create new op-portunities not available to any sole group.
SAMPE’s Corporate Partners help fund: • Bridge Building Contests • Faculty Advisor Meetings • Student Chapter Grants • Student Exchange Programs
Become a SAMPE Corporate Partner today!Contact Patty Hunt: [email protected]
TMI CLAVEHOZE™ the original and
industry standard.
Call today 801-265-0111www.tmi-slc.com
Thermal Wave Imaging, Inc.
State of the Art System Solutions
Leaders and Innovators in ThermographyDetect…• Delamination• Bond Integrity• Inclusions (FOD)• Water Ingress
Lab / R&DPortable Automated
248.414.3730 [email protected] www.thermalwave.com
Measure…• Size• Depth• Porosity• TBC Thickness
2512 W. Woodland Dr. • Anaheim, CA 92801Tel: 714-761-0401 • Fax: 714-761-2928
www.textileproducts.com
Utilizing Fibers: Carbon, Quartz,
Ceramics, Aramids, Fiberglass, Etc.
Textile Products, Inc.Manufacturer of fabrics to:
Aerospace & Commercial applicationsBi-directional, Uni-directional, Hybrids,
Tapes, Metallic Wire, Polar Weaves, Fluted Core and Preforms
Resource Center
SAMPE Journal, Volume 53, No. 4, July/August 2017
An Agent of Change. A Breakthrough That Will Forever Change Molding
The revolutionary breakthrough in Chem-Trend’s new Zyvax® Release Agent will forever change the way you see composite molding. The future starts today. Upgrade to Chem-Trend now.
• Reduce tool prep from hours to minutes. Wipe on. Let dry. No Cure.
• Easy tool cleanup. Minimal abrasion required. Simply wipe clean.
• Silicone-free release agent decimates molded part prep time and effort.
• Water-based technology radically reduces VOCs.
ChemTrend.com
Clean molds. Clean parts. Clean air.Chem-Trend does it all.
chemtrend.com/agent-of-change-video
Scan the QR code below to learn
more about what Chem-Trend can
do for you!
CT_Aerospace_Ad_7x10.indd 1 5/23/17 3:34 PM
An Agent of Change. A Breakthrough That Will Forever Change Molding
The revolutionary breakthrough in Chem-Trend’s new Zyvax® Release Agent will forever change the way you see composite molding. The future starts today. Upgrade to Chem-Trend now.
• Reduce tool prep from hours to minutes. Wipe on. Let dry. No Cure.
• Easy tool cleanup. Minimal abrasion required. Simply wipe clean.
• Silicone-free release agent decimates molded part prep time and effort.
• Water-based technology radically reduces VOCs.
ChemTrend.com
Clean molds. Clean parts. Clean air.Chem-Trend does it all.
chemtrend.com/agent-of-change-video
Scan the QR code below to learn
more about what Chem-Trend can
do for you!
CT_Aerospace_Ad_7x10.indd 1 5/23/17 3:34 PM
Inks
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catalog: americanelements.com
1.00794Hydrogen
1 1
H
6.941Lithium
3 21
Li9.012182
Beryllium
4 22
Be
22.98976928Sodium
11 281Na
24.305Magnesium
12 282Mg
39.0983Potassium
19 2881K
40.078Calcium
20 2882Ca
85.4678Rubidium
37 28
1881Rb
87.62Strontium
38 28
1882Sr
132.9054Cesium
55 28
181881Cs
137.327Barium
56 28
181882Ba
(223)Francium
87 28
18321881
Fr(226)
Radium
88 28
18321882
Ra
44.955912Scandium
21 2892Sc
47.867Titanium
22 28
102Ti
50.9415Vanadium
23 28
112V
51.9961Chromium
24 28
131Cr
54.938045Manganese
25 28
132Mn
55.845Iron
26 28
142Fe
58.933195Cobalt
27 28
152Co
58.6934Nickel
28 28
162Ni
63.546Copper
29 28
181Cu
65.38Zinc
30 28
182Zn
88.90585Yttrium
39 28
1892Y
91.224Zirconium
40 28
18102Zr
92.90638Niobium
41 28
18121Nb
95.96Molybdenum
42 28
18131Mo
(98.0)Technetium
43 28
18132Tc
101.07Ruthenium
44 28
18151Ru
102.9055Rhodium
45 28
18161Rh
106.42Palladium
46 28
1818Pd
107.8682Silver
47 28
18181Ag
112.411Cadmium
48 28
18182Cd
138.90547Lanthanum
57 28
181892La
178.48Hafnium
72 28
1832102Hf
180.9488Tantalum
73 28
1832112Ta
183.84Tungsten
74 28
1832122W
186.207Rhenium
75 28
1832132Re
190.23Osmium
76 28
1832142Os
192.217Iridium
77 28
1832152Ir
195.084Platinum
78 28
1832171Pt
196.966569Gold
79 28
1832181Au
200.59Mercury
80 28
1832182Hg
(227)Actinium
89 28
18321892
Ac(267)
Rutherfordium
104 28
183232102
Rf(268)
Dubnium
105 28
183232122
Db(271)
Seaborgium
106 28
183232112
Sg(272)
Bohrium
107 28
183232132
Bh(270)
Hassium
108 28
183232142
Hs(276)
Meitnerium
109 28
183232152
Mt(281)
Darmstadtium
110 28
183232171
Ds(280)
Roentgenium
111 28
183232181
Rg(285)
Copernicium
112 28
183232182
Cn
4.002602Helium
2 2
He
10.811Boron
5 23
B12.0107Carbon
6 24
C14.0067
Nitrogen
7 25
N15.9994Oxygen
8 26
O18.9984032Fluorine
9 27
F20.1797Neon
10 28
Ne
26.9815386Aluminum
13 283Al
28.0855Silicon
14 284Si
30.973762Phosphorus
15 285P
32.065Sulfur
16 286S
35.453Chlorine
17 287Cl
39.948Argon
18 288Ar
69.723Gallium
31 28
183Ga
72.64Germanium
32 28
184Ge
74.9216Arsenic
33 28
185As
78.96Selenium
34 28
186Se
79.904Bromine
35 28
187Br
83.798Krypton
36 28
188Kr
114.818Indium
49 28
18183In
118.71Tin
50 28
18184Sn
121.76Antimony
51 28
18185Sb
127.6Tellurium
52 28
18186Te
126.90447Iodine
53 28
18187I
131.293Xenon
54 28
18188Xe
204.3833Thallium
81 28
1832183Tl
207.2Lead
82 28
1832184Pb
208.9804Bismuth
83 28
1832185Bi
(209)Polonium
84 28
1832186Po
(210)Astatine
85 28
1832187At
(222)Radon
86 28
1832188Rn
(284)Ununtrium
113 28
183232183
Uut(289)
Flerovium
114 28
183232184
Fl(288)
Ununpentium
115 28
183232185
Uup(293)
Livermorium
116 28
183232186
Lv(294)
Ununseptium
117 28
183232187
Uus(294)
Ununoctium
118 28
183232188
Uuo
140.116Cerium
58 28
181992Ce
140.90765Praseodymium
59 28
182182Pr
144.242Neodymium
60 28
182282Nd
(145)Promethium
61 28
182382Pm
150.36Samarium
62 28
182482Sm
151.964Europium
63 28
182582Eu
157.25Gadolinium
64 28
182592Gd
158.92535Terbium
65 28
182782Tb
162.5Dysprosium
66 28
182882Dy
164.93032Holmium
67 28
182982Ho
167.259Erbium
68 28
183082Er
168.93421Thulium
69 28
183182Tm
173.054Ytterbium
70 28
183282Yb
174.9668Lutetium
71 28
183292Lu
232.03806Thorium
90 28
183218102
Th231.03588
Protactinium
91 28
18322092
Pa238.02891Uranium
92 28
18322192
U(237)
Neptunium
93 28
18322292
Np(244)
Plutonium
94 28
18322482
Pu(243)
Americium
95 28
18322582
Am(247)
Curium
96 28
18322592
Cm(247)
Berkelium
97 28
18322782
Bk(251)
Californium
98 28
18322882
Cf(252)
Einsteinium
99 28
18322982
Es(257)
Fermium
100 28
18323082
Fm(258)
Mendelevium
101 28
18323182
Md(259)
Nobelium
102 28
18323282
No(262)
Lawrencium
103 28
18323283
Lr
Now Invent.TM
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