xafs: x-ray absorption fine- structure · 2 summary basic principles: x-ray absorption and...
TRANSCRIPT
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Paolo Ghigna, Dipartimento di Chimica Fisica “M. Rolla”, Università di Pavia
XAFS: X-rayAbsorption Fine-Structure
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Summary
Basic Principles:X-ray absorption and fluorescenceSimple theoretical description
Experiment Design:Transmission v. Fluorescence modesFluorescence detectors
Data Analysis:EXAFS Analysis: near neighbor R, N, and atomic speciesXANES Analysis: formal valence and coordination chemistry
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What is XAFS?X-ray Absorption Fine-Structure (XAFS) is the modulation of the x-ray absorption coefficient at energies near and above an x-ray absorption edge. XAFS is also referred to as X-ray AbsorptionSpectroscopy (XAS) and is broken into 2 regimes:
XANES X-ray Absorption Near-EdgeSpectroscopyEXAFS Extended X-ray Absorption Fine-Structure which contain related, but slightlydifferent information about an element’s localcoordination and chemical state.
Fe K-edge XAFS for FeO:XAFS Characteristics:• local atomic coordination• chemical / oxidation state• applies to any element• works at low concentrations• minimal sample requirements
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X-ray AbsorptionX-rays (light with wavelength 0.03<λ<12 Å or energy 1<E <500 keV) are absorbed by allmatter through the photo-electric effectAn x-ray is absorbed by an atom, promoting a core-level electron (K, L, or M shell) out of the atom and into the continuum. The atom is leftin an excited state with an empty electroniclevel (a core hole). The electron ejected fromthe atom is called the photo-electron.
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X-ray FluorescenceWhen x-rays are absorbed by the photo-electriceffect, the excited core-hole will relax back to a “ground state” of the atom. A higher level core electron drops into the core hole, and a fluorescentx-ray or Auger electron is emitted.X-ray Fluorescence: An x-ray with energy = the difference of the corelevels is emitted.Auger Effect: An electron is promoted into the continuum from another corelevel.
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The X-ray Absorption Coefficient: µ
The intensity of an x-ray beam as itpasses through a material of thickness t is given by the absorptioncoefficient µ:
where I0 is the x-ray intensity hittingthe material, and I is the intensitytransmitted through the material.
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X-ray Absorption Measurements
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X-ray Absorption Fine Structure
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EXAFS: χ(k)
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The EXAFS Equation
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XAFS Theory: X-ray Absorption by a FreeAtom
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X-ray Absorption with Photo-Electron Scattering
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The EXAFS Equation: simple description
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Development of the EXAFS Equation
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The Photo-Electron Mean-Free Path
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Scattering Amplitude and Phase-Shift
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The EXAFS Equation
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X-ray Absorption Measurements: Experimental Design
Important points to consider for measuring XAFS are:Monochromatic x-rays: Need x-rays with a small energyspread or bandwidth: ∆E<1 eV at 10keV.Linear Detectors: The XAFS (k) is small, so we need a lotofphotons (ie, a synchrotron) and detectors that are very linearin x-ray intensity (ion chambers).Well-aligned Beam: The x-ray beam hitting the detectors hasto be the same hitting the sample.Homogeneous sample: For transmission measurements, weneed a sample that is of uniform and appropriate samplethickness of nearly 2 absorptionlengths. It should be freefrom pinholes. If a powder, the grains should be very fine-grained (absorption length) and uniform.
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X-ray Absorption Measurements: The Experiment
Energy Scanning The beamline needs to deliver monochromatic x-rays thatare tunable so we can scan energy across the absorption edge. We’ll scanfrom 200 eV below to 800 eV above the Fe K-edge, like this:
Region Starting Energy (eV) Ending Energy (eV) Step Size (eV)Pre-edge -200 -20 5.0XANES -20 +30 0.5EXAFS +30 800 0.05 Å-1
Notes: all values relative to a nominal value of the edge energy. In the EXAFS region, it’s common to step in k rather than energy. Counting Statistics: The EXAFS is a fairly small signal, so for good data µ(E) should have a noiselevel of about 10−3. That means we need to collect at least 106 photons.Transmission : Fluxes at synchrotrons are > 108 photons/sec. Count rate isnot much of an issue.Fluorescence : May be a concern, especially when concentrationsare verylow.
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X-ray Absorption Measurements: Transmission
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X-ray Absorption Measurements: Fluorescence
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Fluorescence Measurements: Solid-StateDetectors
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Data Reduction: Strategy
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Data Reduction: Pre-Edge Subtraction, Normalization
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Data Reduction: Normalized XANES and E0
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Data Reduction: Post-Edge Background Subtraction
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Data Reduction: χ(k), k-weighting
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Fourier Transform: χ(R)
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EXAFS Analysis: two shell model of FeO
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XANES: X-ray Absorption NearEdge Structure
At photoelectron kinetic energies withwavelengths near the first interatomicdistance:• Discrete transitions to unpopulated states• XANES is a probe of the density of emptyelectron states projected onto the phtoabsorberAt higher XANES energies:• The multiple scattering phenomenondominates• XANES is a probe for high order correlationfunctions
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XANES: fingerprintingDespite large advances in the past years, predictive XANES calculations are not satisfactory. Interpretation is still qualitative by comparison to known,
reference spectra (“fingerprint”) or theoretically calculated spectra (e.g., multiple scattering or band structure calculations).
XANES features and their intensity and energy position are dependent on a number of factors including
•absorbing atom valence•coordination geometry•orbital occupancy•electronegativityof coordinating atoms•interatomicdistances•orientation (for anisotropic samples)
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Multiple scattering (MS) in the XAFS regime
In addition to SS in EXAFS, oscillations from MS of the photoelectron can be observed in EXAFS - mostly at low k•MS is most likely along atoms with a collinear arrangement (“lensing” or “focussing” effect)•MS peaks are never found in the FT spectrum at distances shorter than the secondcoordination shellA simple assumption is that the rel. mean square displacement is additive - paths longer thantriple scattering paths are rare
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XANES Analysis: Oxidation State
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XANES: orbital occupancy
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XANES Analysis: Oxidation State and Coordination Chemistry
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Polarized XAFS -U LIII and LI edge XANES features of oriented samples
The linear uranyl (O=U=O2+) cation exhibitsstriking variations in its XAFS spectra as a function of orientation relative to the incidentradiation’s polarization vector.
Changes in U LIII XANES edge features: white line (2p→6d (6s) transition), 10eV feature (scattering on Oax), and 35eV feature(scattering on Leq)U LI XANES polarization dependency is more dramatic, due to the higher orientation of p-like final states.
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Polarized XAFS -- U LIII and LIedge XANES of orientedUO2(CH3CO2)2*2H2O
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Polarized XAFS -- U LIII and LIedge XANES of orientedUO2(CH3CO2)2*2H2O
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XANES Interpretation
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XMCD: X-Ray Magnetic Circular Dichroism
DOS
E
k
EF
DOS
E
EF-1/2
1/2
DOS
E
EF
ml=1, 2
ml= -1, -2
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XMCD: X-Ray Magnetic Circular Dichroism
DOS
E
k
EF
L l+s3 L l-s2
E
I L( )3
I L( )2
E
m
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XMCD: X-Ray Magnetic Circular Dichroism
I L( )3
I L( )2
E
Dic
rois
mo
DOS
E
EF-1/2
1/2
L l+s3 L l-s2
EE
DestraSinistra
DOS
E
EF-1/2
1/2
L l+s3
L l-s2
EE
Destra Sinistra
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XMCD: X-Ray Magnetic Circular Dichroism
DOS
E
EF
ml=1, 2
ml= -1, -2
I L( )3
I L( )2
E
Dic
rois
mo
l=1
l=2
EE
DestraSinistra
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Regole di sommazione
Lo spin s viene eliminato se si sommano gli integrali del segnale dicroico sulle soglie LIII (l+s) ed LII (l-s): l » I(LIII)+I(LII)Per eliminare il momento angolare l occorre tenere conto della degenerazione: s = I(LIII)-2I(LII)
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Esempio: Mn12AcSecondo la teoria dei gruppi, il momento angolare orbitale è nullo (si dice che è quenchiato dal campo cristallino)
O
Mn(IV)
Mn(III)
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Esempio: Mn12Ac
0
5
10
15
Photon Energy (eV)635 640 645 650 655 660 665 670
-10
-5
0
5
-10
-5
0
50
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15
Abs
. Coe
ff. (
ar. u
n.)
XM
CD
. (ar
. un.
)
Inte
grat
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MC
D. (
ar. u
n.)