the study of waste minimization

Upload: rouss1906

Post on 14-Feb-2018

222 views

Category:

Documents


0 download

TRANSCRIPT

  • 7/23/2019 The Study of Waste Minimization

    1/25

    THE STUDY OF WASTE MINIMIZATION AND ENVIRONMENTAL

    ASSESSMENTS IN AN OFF-SITE FACILITY

    LIZA BINTI SHAH ALI CHARLIE

    UNIVERSITI TEKNOLOGI MALAYSIA

  • 7/23/2019 The Study of Waste Minimization

    2/25

    PSZ 19:16 (Pind. 1/97)

    UNIVERSITI TEKNOLOGI MALAYSIA

    BORANG PENGESAHAN STATUS TESIS

    JUDUL:THE STUDY OF WASTE MINIMIZATION ANDENVIRONMENTAL ASSESSMENTS IN AN OFF-SITE

    FACILITY

    SESI PENGAJIAN: 2008/2009

    Saya LIZA BINTI SHAH ALI CHARLIE

    (HURUF BESAR)

    mengaku membenarkan tesis *(PSM/Sarjana/Doktor Falasfah) ini disimpan di Perpustakaan

    Universiti Teknologi Malaysia dengan syarat-syarat kegunaan seperti berikut:

    1.

    Tesis adalah hakmilik Universiti Teknologi Malaysia.

    2.

    Perustakaan Universiti Teknologi Malaysia dibenarkan membuat salinan untuk tujuan

    pengajian sahaja.

    3.

    Perpustakaan dibenarkan membuat salinan tesis ini sebagai bahan pertukaran di antara

    institusi pengajian tinggi.

    4. **Sila tandakan (/ )

    SULIT (Mengandungi maklumat yang berdarjah keselamatan atau

    kepentingan Malaysia seperti yang termaktub di dalam AKTA

    RAHSIA RASMI 1972)

    TERHAD (Mengandungi maklumat TERHAD yang telah ditentukan oleh

    organisasi/badan di mana penyelidikan dijalankan)

    TIDAK TERHAD

    Disahkan oleh

    _______________________________________ _________________________________ __

    (TANDATANGAN PENULIS) (TANDATANGAN PENYELIA)

    Alamat Tetap:

    Nama Penyelia

    Tarikh : 28 APRIL 2009 Tarikh: 28 APRIL 2009

    PROF. MADYA DR. JOHAN BIN SOHAILINO 132, LORONG 5,

    TAMAN MARISA,

    34000 TAIPING,

    PERAK.

    CATATAN: * Potong yang tidak berkenaan.** Jika tesis ini SULITatau TERHAD, sila lampirkan surat daripada pihak berkuasa/organisasi

    berkenaan dengan menyatakan sekali sebab dan tempoh tesis ini perlu dikelaskan sebagai

    SULIT atau TERHAD. Tesis dimaksudkan sebagai tesis bagi Ijazah Doktor Falsafah dan Sarjana secara

    penyelidikan, atau disertasi bagi pengajian secara kerja kursus dan penyelidikan, atau

    Laporan Projek Sarjana Muda (PSM).

  • 7/23/2019 The Study of Waste Minimization

    3/25

    I hereby declare that I have read this thesis and in my opnion this thesis is sufficient

    in term of scope and quality for the award of the degree of Bachelor of Civil

    Engineering

    Signature : ....

    Name of Supervisor : ASSOC. PROF. DR. JOHAN SOHAILI

    Date : 28 APRIL 2009

  • 7/23/2019 The Study of Waste Minimization

    4/25

    THE STUDY OF WASTE MINIMIZATION AND ENVIRONMENTAL

    ASSESSMENTS IN AN OFF-SITE FACILITY

    LIZA BINTI SHAH ALI CHARLIE

    A report submitted in partial fulfillment of the

    requirements for the award of the degree of

    Bachelor of Civil Engineering

    Faculty of Civil Engineering

    Universiti Teknologi Malaysia

    MAY 2009

  • 7/23/2019 The Study of Waste Minimization

    5/25

    ii

    I declare that this thesis entitled The Study of Waste Minimization and

    Environmental Assessments in an Off-site Facility is the result of my own research

    except as cited in the references. The thesis has not been accepted for any degree and

    is not concurrently submitted in candidature of any other degree.

    Tandatangan :

    Nama : LIZA BINTI SHAH ALI CHARLIE

    Tarikh : 28 APRIL 2009

  • 7/23/2019 The Study of Waste Minimization

    6/25

    iii

    DEDICATION

    As this journey begun

    Passing through a long distance and difficult path

    A shine of guidance given to lead this dark trail

    To Assoc. Prof. Dr. Johan Sohaili as my supervisor to lead me patiently

    Daddy and Mommy

    You are my supports that always embrace me

    You always have been there for me

    Through your prayers and love

    Both of you as been my eyes to lead this hopeful journey

    To both of you Charlie and Zaiton

    My Siblings

    Companions where I can share my happiness and sadness

    As all of you always bringing me laughter and joy

    Presents of you all simply ease my journey

    To Kamal, Yunus and Jasmin

    As this journey nearly end

    Where all my efforts, time, hard work gathered

    Finally, to You I lay my burden

    Hoping for the Best

  • 7/23/2019 The Study of Waste Minimization

    7/25

    iv

    ACKNOWLEDGEMENT

    In writing this Projek Sarjana Muda Kejuruteraan Awam, there are so many

    persons involved to assist me to complete this project. Hence, I take this opportunity

    to thanks each and every one of them and to let them know I really do appreciate it

    all.

    My first thanks goes to my beloved Supervisors, P.M.Dr. Johan Sohaili, to

    really been patient and calm to lead me to do the best. Besides that, an important

    thanks to the owner of the off-site facility that been studied, Mr. Raja Ramasamy

    allowing me to carry this study. To Mr. Mohandas Mohunthan and Mr. Arumugham

    Balasubramaniam who really has been helpful in sharing every information about the

    off-site facility. My thanks to both of you Sir

    To the Fakulti Kejuruteraan Awam Laboratory Technicians who really had

    been helpful to assist me during the sampling and laboratory experiments. Thanks so

    much. To my friends who always has been there for me, my thanks to you all.

    Finally, my family, thanks for your support and love. Thank you for everything.

  • 7/23/2019 The Study of Waste Minimization

    8/25

    v

    ABTRACT

    Small and medium industries are very important to developing country like

    Malaysia. The growth of these industries and its productivity plays important role to

    boost the country economy. However, many of these industries are generating

    hazardous waste which can brings negative impacts to the environment and to other

    living organisms. Hence, managing the hazardous waste is very essential to prevent

    environmental pollution and providing safer environment to live. Therefore, the best

    way to manage hazardous waste is by waste minimization. One of the waste

    minimization techniques prefer by these hazardous waste generators is to send theirhazardous waste to an off-site recycling and recovery facility. A study was conducted

    to understand the recycling process of hazardous used drum, container, and

    rags/filters in an off-site facility. Based on the recycling process, the effectiveness of

    the off-site facility in minimizing hazardous waste is evaluated. Overall 99.33% of

    the hazardous wastes are been minimized by the studied facility. Environmental

    assessment comprising water quality, noise level and air quality also been carried out

    at the studied facility to identify if the facility emits any pollutants. The water quality

    parameters of Temperature, DO, pH, BOD5, COD, TSS and heavy metal of Copper

    as Cu and Iron as Fe of treated water from the wastewater treatment plant in the

    facility has been analyzed. The results shows the only concentration that not comply

    is Copper as Cu with 1.2 mg/L whereby 0.2 mg/L higher the guidelines limit. Two

    nearby streams also been assessed to obtained the Water Quality Index (WQI) toclassified the streams. The streams are in Class IV and Class II which indicating

    water qualities of streams are polluted and clean respectively. The noise levels were

    assessed at the boundary area of the studied facility. All noise levels that comply

    with the regulatory requirement. The results for all air quality parameters of TSP,

    CO, SO2, and NO2 also comply with guidelines limit showing the facility does not

    emit gases at dangerous level. Overall, it can be concluded that the studied facility

    does not creates pollutants at concerning level other than effectively minimizing

    scheduled wastes.

  • 7/23/2019 The Study of Waste Minimization

    9/25

    vi

    ABSTRAK

    Industri kecil dan sederhana adalah amat penting bagi negara yang sedang

    membangun seperti Malaysia. Kemajuan and produktiviti industri-industri ini

    memainkan penting dalam meningkatkan ekonomi negara. Akan tetapi, kebanyakan

    industri-industri ini menjana sisa berbahaya yang boleh mengundang impak negatif

    kepada kehidupan. Maka, pengurusan sisa berbahaya ini penting untuk

    mengurangkan pencemaran alam serta untuk menyediakan persekitaran yang selamat

    untuk hidup. Cara terbaik untuk menguruskan sisa berbahaya adalah pengurangan

    sisa. Salah satu teknik pengurangan sisa berbahaya yang menjadi pilihan penjana sisaberbahaya adalah menghantar sisa berbahaya ke pusat kitar semula dan memperoleh

    kembali di luar dari kawasan penjanaan sisa berbahaya. Satu kajian telah dijalankan

    bagi memahami proses kitar semula tong drum, bekas and kain buruk/penapis

    terpakai yang berbahaya di sesebuah pusat kitar semula dan memperoleh kembali

    buangan terjadual. Berdasarkan proses proses kitaran semula tong drum, bekas, kain

    buruk/penapis terpakai yang dijalankan, keberkesanan pusat tersebut dalam

    mengurangkan buangan terjadual dinilai. Secara keseluruhan, 99.33% buangan

    terjadual dapat dikurangkan oleh pusat kitar semula dan memperoleh kembali

    tersebut. Penilaian alam sekitar merangkumi kualiti air, paras bunyi dan kualiti udara

    juga telah dijalankan di pusat kitar semula bagi menentukan samada pusat yang

    dikaji melepaskan sebarang bahan cemar. Parameter bagi kualiti air seperti suhu,

    DO, pH, BOD5, COD, TSS and logam berat kuprum (Cu) dan Ferum (Fe) ke atas airdirawat daripada loji rawatan air sisa di pusat tersebut dikaji. Keputusan

    menunjukkan hanya kepekatan logam berat kuprum (Cu) tidak mematuhi standard

    dimana 1.2 mg/L iaitu 0.2 mg/L lebih tinggi daripada had yang dibenarkan. Dua

    batang sungai yang berhampiran pusat yang dikaji juga dinilai untuk mendapatkan

    Indeks Kualiti Air bagi mengklasifikasikan kedua-dua sungai tersebut. Sungai-sungai

    tersebut dikelaskan dalam Kelas IV and Kelas II menunjukkan kualiti air sungai

    masing-masing tercemar dan bersih. Ukuran paras bunyi di sempadan pusat yang

    dikaji juga dijalankan. Kesemua paras bunyi yang mematuhi undang-undang.

    Keputusan bagi semua parameter kualiti udara seperti TSP, CO, SO2, dan NO2juga

    mematuhi standard menunjukkan pusat kitar semula dan memperoleh kembali

    tersebut tidak melepaskan gas pada tahap yang berbahaya. Keseluruhan, boleh

    disimpulkan pusat yang dikaji tidak menghasilkan pencemaran pada tahap yangmembimbangkan selain daripada mengurangkan buangan terjadual secara berkesan.

  • 7/23/2019 The Study of Waste Minimization

    10/25

    vii

    TABLE OF CONTENT

    CHAPTER TITLE PAGE

    DECLARATION ii

    DEDICATION iii

    ACKNOWLEDGEMENT iv

    ABSTRACT v

    ABSTRAK vi

    TABLE OF CONTENTS vii

    LIST OF TABLES x

    LIST OF FIGURES xii

    LIST OF SYMBOLS AND ABBREVIATIONS xv

    I INTRODUCTION

    1.1 Introduction 1

    1.2 Problem Statement 2

    1.3 Study Objectives 5

    1.4 Scope of Study 5

    1.5 Significance of Study 6

    II LITERATURE REVIEW

    2.1 Waste 8

    2.2 Non-Hazardous Waste versus Hazardous Waste 12

  • 7/23/2019 The Study of Waste Minimization

    11/25

    viii

    2.3 Hazardous Waste 12

    2.3.1 Hazardous Waste Identification and Characteristics 13

    2.3.2 Scheduled Waste Definition in Malaysia 18

    2.3.3 Waste Mixture 19

    2.3.4 Waste Derived from Hazardous Waste 20

    2.4 Hazardous Waste Generators 21

    2.5 Hazardous Waste Generations 25

    2.6 Impacts of Hazardous Waste 28

    2.7 Hazardous Waste Management 30

    2.7.1 Hazardous Waste Minimization 32

    2.7.2 Waste Minimization Assessment 33

    2.8 Drum and IBC 34

    2.8.1 Drum 35

    2.8.2 IBC 37

    2.8.3 Drum and IBC Quality Testing 38

    2.8.4 Waste Drum and IBC 38

    2.8.5 Drum Reconditioning and Management 39

    2.8.6 Used Industrial Drum/Container Recycling Facility 41

    2.9 Rags/Filters 42

    2.9.1 Sources of Contaminated Rags/Filters 43

    2.9.2 Management of Contaminated Rags/Filters 44

    2.9.3 Used Industrial Rags/Filters Recycling Facility 46

    2.10 Conclusion 47

    III METHODOLOGY

    3.1 Description of Study Fields 49

    3.2 Location of Study Field 49

    3.3 Study Methodology 50

    3.4 Sampling Locations 52

    3.5 Parameters Analyzed and Methodology Instruments 55

    3.5.1 Water Quality Assessment 55

  • 7/23/2019 The Study of Waste Minimization

    12/25

    ix

    3.5.2 Noise Level Assessment 59

    3.5.3 Air Quality Assessment 60

    IV RESULT AND ANALYSIS

    4.1 Recycling and Recovery Facility 63

    4.2 Used Industrial Drum (SW 409) 64

    4.2.1 Used Drum Segregations 65

    4.2.2 Cargo Types Cleaned by the Studied Facility 66

    4.2.3 Drum Recycling Process 68

    4.3 Industrial Cotton Rags/Filters (SW410) 79

    4.3.1 Rags/Filters Segregations 79

    4.3.2 Rags/Filters Recycling Process 81

    4.4 Waste Minimization in the Studied Facility 83

    4.4.1 Incoming Raw Wastes 84

    4.4.2 Recovered Wastes 86

    4.4.3 Wastes Generated During the Recycling Process 92

    4.4.4 Overall Waste Minimization in the Studied Facility 98

    4.5 Environmental Assessment of the Studied Facility 104

    4.5.1 Water Quality Assessment 104

    4.5.2 Noise Level Assessment 106

    4.5.3 Air Quality Assessment 107

    V CONCLUSION

    5.1 Conclusion 108

    5.2 Recommendations 110

    REFERENCES 111

  • 7/23/2019 The Study of Waste Minimization

    13/25

    x

    LIST OF TABLES

    TABLE TITLE PAGE

    2.1 Waste Categories based Chemical Composition 9

    2.2 Waste Categories based on Reactivity and Environmental Risk 10

    2.3 Waste Categories based on Source of Generation 11

    2.4 Maximum Concentration of Contaminants for Toxicity

    Characteristics Leaching Procedure 16

    2.5 Maximum Concentration of Contaminants for Toxicity

    Characteristics Compositional Analysis 17

    2.6 Categories of RCRA Hazardous Waste 21

    2.7 Typical Hazardous Household Products 22

    2.8 Hazardous Waste Generated by Industry 24

    2.9 Malaysia: Scheduled Waste Handling in 2006 26

    2.10 Malaysia: Quantity of Scheduled Wastes Generated by

    Category in 2006 27

    2.11 Malaysia: Quantity of Scheduled Wastes Generated by

    Industry in 2006 28

    2.12 Potential Human Exposure to Toxic Waste 29

    2.13 List of Off-Site Facilities (Used Drums/Containers-SW409)

    Licensed by DOE in 2008 42

    2.14 Sources of Contaminants Rags/Filters 44

    2.15 List of Off-Site Facilities (Used Rags-SW410) Licensed by DOE

    in 2008 47

    3.1 Summary of Methodologies for Primary Data 51

    3.2 Summary of Methodologies for Secondary Data 51

    3.3 Summary of Laboratory Experiments 62

    3.4 Summary of Field Experiments 62

  • 7/23/2019 The Study of Waste Minimization

    14/25

    xi

    4.1 Incoming Raw Wastes into the Studied Facility 86

    4.2 Incoming and Outgoing Steel Drum, Plastic Drums and

    IBCs to the Studied Facility 87

    4.3 Recovered Steel Drum (kg) in the Studied Facility 88

    4.4 Recovered Plastic Drum (kg) in the Studied Facility 88

    4.5 Recovered IBCs (kg) in the Studied Facility 89

    4.6 Incoming and Outgoing Rags/Filters (kg) to the Facility

    in 2008 89

    4.7 Recovered Rags/Filters (kg) in the Studied Facility 90

    4.8 Recovered Wastes in the Studied Facility in 2008 92

    4.9 Heels Disposed by the Studied Facility in 2008 95

    4.10 Disposed Rags/Filters by the Studied Facility in 2008 95

    4.11 Amount Cleaning Agent Used During the Recycling Process

    in 2008 96

    4.12 Amount of Products Used During the Recycling Process in

    2008 97

    4.13 Streams Water Quality and Its Compliances 104

    4.14 Facilitys Treated Water Quality and its Compliances 105

    4.15 Facilitys Noise Level and its Compliances 106

    4.16 Facilitys Air Quality and Its Compliances 107

  • 7/23/2019 The Study of Waste Minimization

    15/25

    xii

    LIST OF FIGURES

    FIGURES TITLE PAGE

    2.1 Characteristics of Hazardous Waste 18

    2.2 The Mixing Rules Producing Hazardous Waste 20

    2.3 The Mixing Rules Producing Non-Hazardous Waste 20

    2.4 Global Hazardous Waste Generation by Type as reported by

    the Parties to the Basel Convention 25

    2.5 Environmental Contamination Caused By the Leaks from

    Stored Drum 30

    2.6 Waste Minimization Hierarchy Approaches to Pollution

    Pollution Prevention 32

    2.7 Waste Minimization Techniques 33

    2.8 Balances of Input and Output of Process 34

    2.9 Recommended External Color of Steel Drum 35

    2.10 Steel Drum with Maximum Capacity of 44 Gallon in Yellow

    and Blue Color 36

    2.11 Blue Colored Plastic Drum with Maximum Capacity of 44

    Gallon 36

    2.12 Black and Clear IBC with Maximum Capacity of 1000L 37

    2.13 Waste Management Hierarchy 40

    2.14 Cotton Rags from Drum Recycling Industry 43

    3.1 Location of Field Study 50

    3.2 Water Quality Sampling Point Locations 52

    3.3 Noise Sampling Point Locations 53

    3.4 Air Emission Sampling Point Locations 53

    3.5 Sampling Point Locations for Environmental Assessments

    in the Studied Facility 54

  • 7/23/2019 The Study of Waste Minimization

    16/25

    xiii

    3.6 Multi Parameter YSI-550A Instrument Used to obtain

    DO Level 56

    3.7 Preparing BOD Trak along with Bottles of 350 mL water

    Sample to be Stored in the Incubator 58

    3.8 Glass Microfiber Filter Disk which attached to Vibrator for TSS

    Experiment 58

    3.9 HACH DR/4000 Spectrometer and Blank Sample for COD,

    NH3-N, and Heavy Metals Laboratory Apparatus 59

    3.10 Bruel and Kjaer Prescision Integrated Sound Meter Type

    2238 Instrument was read every 5 Minutes for 1 Hour 60

    3.11 Gray Wolf Direct Sense Apparatus was used to Obtained

    SO2, NO2 and CO directly 61

    3.12 TSP Apparatus was used to assess TSP Parameter 61

    4.1 Drum Reconditioning Plant in the Studied Facility 65

    4.2 Incoming Used Drums Segregation in Studied Facility 66

    4.3 Cargo Types Cleaned by the Studied Facility 67

    4.4 Cargos of Used Drums Rejected by the Studied Facility 68

    4.5 Steel Drum (A-Drum) Recycling Process 70

    4.6 Type of Heel Collected from B-drum 71

    4.7 Steel Drum (B-Drum) Recycling Process 72

    4.8 Lids of Open Headed Top Drum 73

    4.9 Open Headed Top Steel Drum and AK-Drum Recycling Process 74

    4.10 Plastic Drum Cleaning Process Area in the Studied Facility 75

    4.11 Plastic Drum Recycling Process in the Studied Facility 76

    4.12 IBC Recycling Process in the Studied Facility 78

    4.13 Contaminated Rags/Filters in the Studied Facility 79

    4.14 Incoming Rags/Filters Segregations in the Studied Facility 80

    4.15 Contaminated Rags/Filters Washing Area in the Studied Facility 80

    4.16 Rags/Filters Recycling Process in the Studied Facility 82

    4.17 Waste Minimization Analysis in the Studied Facility 83

    4.18 Incoming Raw Wastes (kg) in the Studied Facility 85

    4.19 Total of Recovered Wastes in the Studied Facility 91

    4.20 Heels Removal in the Each Containers Recycling Process

    in the Studied Facility 93

  • 7/23/2019 The Study of Waste Minimization

    17/25

    xiv

    4.21 Amount of Heels (kg) Disposed by the Studied Facility 94

    4.22 Sludge Cake (kg) Generated by WWTP in the Studied Facility 97

    4.23 Waste Steel Drum Minimization in the Studied Facility 99

    4.24 Waste Plastic Drum and IBC Minimization in the Studied

    Facility 100

    4.25 Waste Rags/Filters Minimization in the Studied Facility 101

    4.26 Overall Waste Minimization in the Studied Facility 103

  • 7/23/2019 The Study of Waste Minimization

    18/25

    xv

    LIST OF SYMBOL AND ABBREVIATION

    % Percentage

    g/m3 Microgram per cubic meter

    NH3-N Ammonia Nitrogen

    BOD Biochemical Oxygen Demand

    CFR Code of Federation

    CO Carbon Monoxida

    COD Chemical Oxygen Demand

    Cu Copper

    dB Desibels

    DO Dissolved Oxygen

    DOE Department of Environmental

    Fe Iron

    IBC Integrated Bulk Containers

    kg Kilogram

    L Liter

    m3 Cubic Meter

    mg/L milligram per liter

    NO2 Nitrogen Dioxide

    oC Celsius

    ppm part per million

    SO2 Sulfur Dioxide

    TSP Total Suspended Particulates

    TSS Total Suspended Solid

    USEPA United State Environmental of Agency

    WQI Water Quality Index

  • 7/23/2019 The Study of Waste Minimization

    19/25

    16

    CHAPTER 1

    INTRODUCTION

    1.1

    Introduction

    Malaysia is a one of developing country and in such country, industrial

    growth and its productivity plays an important role in contributing to the

    development of the nation. Thus, Government is encouraging small and medium

    industrial to be established to boost the country economy. One of business that are

    preferred is recycling and recovery scheduled wastes such as used drums/containers

    and rags/filters business which is expanding rapidly now days because it pays

    incomes. As in United State of America, many American believes that recycling will

    pay itself. Certainly, more and more material recovery facilities were being opened

    and, material manufacturing industries are retooling to accept recyclables (Rogoff

    and Williams, 1994).

    Local off-site recycling and recovery facilities play important roles in

    managing scheduled waste as the rising amount of the scheduled wastes from varies

    types of industries. According to Department of Environment (DOE, 2007), a total of

    1,103,457.06 metric tones of scheduled wastes were generated in 2006 as compared

    to 548,916.11 metric tones in 2005 in Malaysia. These facilities are experts in cater

    proper scheduled wastes management. The local off-site recovery facilities handled

    29,001.41 metric tones of scheduled wastes, which are 26 % of the scheduled wastes

    generated in 2006 (DOE, 2007). This approved these facilities good in waste

    management which can prevent illegal dumping of generators of scheduled wastes.

  • 7/23/2019 The Study of Waste Minimization

    20/25

    17

    By preventing the illegal dumping indicates the environment is secure from the

    pollutants from scheduled wastes. Besides that, this facility also helping other

    industries to reducing of environmental liabilities and to disposal its in a proper and

    safest manner.

    The most fascinating about these facilities is that indirectly these facilities are

    implementing waste minimization which is absolute solution to growing number of

    scheduled wastes problem. By applying the techniques of reuse, recycle and recovery

    of waste, these facilities has been great helpful to environment by conserving of the

    natural resources. Many toxic or hazardous wastes contain valuable materials.

    Whenever this is the case, recovery and reuse is one of the most desirable methods of

    hazardous waste avoidance (Power, 1976). It does also lengthen the economic life of

    ultimate waste disposal through volume reduction of scheduled wastes that undergo

    final disposal. This reduces the ultimate disposal of wastes and only requires smaller

    area of landfills where landfills area are very few and new landfill site are not be

    welcomed by the public.

    In minimizing scheduled wastes recycling and recovery is the technique use

    in these facilities because source reduction from generators are difficult to put into

    action. Source reduction involves the use of process, practices or products to reduce

    or eliminate the generation and or the toxicity of pollutants and wastes (Abbas

    Ghassemi, 2002).Yet, these facilities have its own risk of handling scheduled wastes

    because these facilities take incoming wastes from vary of developing industries.

    This Industrial development has generated complex waste, a complexity not only due

    to the quantity of wastes, but also to their composition (Wei and Huang, 2001). Thus,

    recycling and recovery facility always have a high threat of dealing with incoming

    hazardous wastes.

    1.2 Problem Statement

    Drum is very convenience container that serve as storage and shipping for a

    variety of hazardous and non-hazardous substances which including beverages,

  • 7/23/2019 The Study of Waste Minimization

    21/25

    18

    foods, chemicals, petroleum, paint and many more. The increasing demand for drums

    and containers from varies of industries makes the production of drums and

    containers become higher. However, discarding large amount of used drums and

    containers can be a problem if the left over of the used drums contents hazardous

    wastes. Dumping such used drums/containers can be harmful to environment which

    can leads to water, air or soil pollution. Besides that, it also lost the natural resources

    such as steels and plastics.

    The used drums contained a wide variety of hazardous wastes including oil,

    acids, solvent, paint wastes, polychlorinated-biphenyls (PBC), pesticides and

    radioactive material (Schuezt, 1995). Hazardous substances are those chemical and

    petroleum products which exhibit characteristic of toxicity, ignitability, flammability,

    reactivity and corrosivity. Depending on their quantities, concentrations, and

    physical and chemical characteristics, these substances may pose substantial present

    or future hazards to human health or the environmental if improperly treated, stored,

    transported or disposed of (Whitman and Baltimore, 1985).

    Even if the drums not contents hazardous wastes, disposal of the used drums

    as solid wastes can be difficult because drums require bigger area of landfills. So,

    many of the industries choose to send the used drums and containers to off-site

    recycling and recovery facilities which make them got off the hook. On the other

    hand, these recycling and recovery facilities still always have the threats of managing

    the hazardous wastes, in order to recycle and recondition the used drums and

    containers to the workers and surrounding environment.

    For instances, the risks of occupational exposure of workers to the chemical

    residues and volatile organic are high. Accidental spill or releases of hazardous

    substances can result in contamination of groundwater and surface water, exposure

    of populations to toxic or carcinogenic chemicals, destruction of property, severe

    financial liabilities, and adverse corporate publicity (Whitman and Baltimore, 1985).

    Meanwhile, used industrial rags that has been sent of to recycling and recovery

    facilities because its also could be classified as scheduled wastes if contents any

    hazardous substances. Industrial rags are use as wiping fabrics along with solvent to

    clean variety materials widely used in industries. Its might content solvent, ink,

  • 7/23/2019 The Study of Waste Minimization

    22/25

    19

    acids, alkaline or petroleum based products which could not be disposal as solid

    wastes. Its can not be simply clean wet washing, even if it so, the washing water used

    may also be contaminated.

    Similar to rags, filters are cotton construction used mainly for particulate and

    organic waste removal to protect sensitive machines. The material attached is

    valuable and could be recovered. An extensive use of rags/filters from cleaning and

    decreasing process of from electronics manufacturers, paint industry from solvent

    based paint manufacturers and paint packaging factories, ink industry from ink

    manufacturers and printing companies contributes mountains contaminated

    rags/filters. Hence, recycle at the recycling and recovery facilities is the best way to

    minimize the ultimate disposal of used rags/filters and to safe handle of hazardous

    substances.

    Off-site recycling and recovery of some hazardous materials is difficult

    because of the dangerous nature of the chemicals themselves. Unlike some municipal

    waste such as aluminum which is fairly easy to recycle, some hazardous chemicals

    are prone to ignite and be reactive. In addition, the fear that industries have of

    accidents and spills during transportation or recycling operations and the resulting

    liability can sometimes present an obstacle to the recycling of hazardous materials

    off-site.

    The chemical or hazardous substances in residues in the drums/containers or

    in contaminated rags/filters collected by these facilities can change significantly in

    terms of their chemical characteristics especially with the advent of new costumers

    and different types of residues transported. This also can greatly influence the

    characteristics of the wastewater generated by the washing operations. Increases in

    the number of drums, containers and rags/filters processed also to an increased

    quantity of wastewater generated in the washing operations. The reuse of treated

    water which is discharge from inefficiency wastewater treatment plant can be

    harmful to workers during the washing process.

    Besides that, the activities that carried out in such facility itself will

    contribute pollutants which will be hazardous to health workers in the facility and the

  • 7/23/2019 The Study of Waste Minimization

    23/25

    20

    surrounding area such as occupational noise pollution. Health hazards are those

    which can cause illness or biologic damage, such as through exposure to toxic

    materials, including carcinogens or physical agents (Whitman and Baltimore, 1985).

    Too long of exposure to the loud noise, the workers might suffering for long-term

    hearing loss. It is also a disturbance to neighboring residents. On the other hand,

    these facilities also might emit of air pollutions which will be hazardous to the

    environment. The workers are in high risk in expose to hazardous substances which

    can be very hazardous to human skin.

    1.3 Study Objectives

    The objectives of this study are:

    (i) To study the recycling process of used steel drum, plastic drum,

    integrated bulk container (IBC) and used rags/filters in the studied

    facility.

    (ii) To evaluate the overall waste minimization in the studied facility that

    involved recycling process of raw wastes of used steel drum, plastic

    drum, IBC and rags/filters.

    (iii) To assess the environmental regulatory compliances of the studied

    facility which comprises of water quality, air quality and noise level.

    1.4 Scope of Study

    This study is carried out in a local off-site recycling and recovery facility,

    Ranama Resources Sdn Bhd which is private owned company in Plentong, Johor.

    This off-site premise has its own storage, treatment and recovery facility completed

    with closed-loop wastewater treatment plant. Therefore, this facility high demand in

  • 7/23/2019 The Study of Waste Minimization

    24/25

    21

    receiving different types of wastes such as plastic and steel drums, rags, filters,

    solvents, discarded paint, for recycling and recovery from industrial and commercial

    businesses surrounding regions throughout Peninsular Malaysia. In this study, the

    limitation of the wastes that has been studied is only part of the types of waste that

    the facility received only which are used plastic and steel drums both with open and

    close top with capacity of 44 gallon, IBC of 1000 L and rags/filters.

    The study of regulatory compliance of the studied facility is only covered of

    three major parts of environments which are water quality, air quality and noise

    level. The assessment of water quality then is checked with the compliance with

    associated standard namely Water Quality Index and Environmental Quality

    (Sewerage and Industrial Effluents) Regulations 1979. Thus, the parameters of water

    quality that considered are temperature, pH, Dissolved oxygen (DO), Biochemical

    Oxygen Demand (BOD), Chemical Oxygen Demand (COD), Ammonia Nitrogen

    (NH3-N) and Suspended Solid (SS).

    Meanwhile, for the assessment of air quality of the studied facility is verified

    with Environmental Quality (Clean Air) Regulations, 1978. The parameters of air

    quality are measured in order to fulfill the regulatory are Total Suspended

    Particulates (TSP), Sulfur Dioxide (SO2), Nitrogen Dioxide (NO2) and also Carbon

    Monoxide (CO). Finally, the noise level also been assessed in the studied facility

    which is checked with its compliance to The Planning Guidelines for Environmental

    Noise Limits and Control (Maximum Permissible Sound Level of Receiving Land

    Use for Planning and New Development (DOE, 2004). The parameter of the noise

    level is measured in the decibel (dB) within the boundary of the studied facility.

    1.5 Significance of Study

    This recycling and recovery facility has been very helpful to environment in

    minimizing the rising amount of scheduled wastes. Thus, the process of how the of

    used drums, containers and rags/filters is studied to understand more about raw waste

    minimizing in the studied facility. Hence, the products and wastes generated during

  • 7/23/2019 The Study of Waste Minimization

    25/25

    22

    the process can be identified. Besides that, the impacts of the operations involve

    recycling the wastes of the studied facility to the surrounding environment can be

    investigated. Therefore, this study benefits the owner of this studied facility to

    improve the facility for environment and safer place to work.

    In evaluating the products and wastes produce in recycling the drums,

    containers and rags/filters are to find out the effectiveness of the studied facility in

    minimizing wastes. This study will help the owner to alter the facility operation in

    aiming for producing zero wastes. Besides that, the operations of recycling wastes

    may emit pollutions. Hence, this research is an advantage to the owner about the

    knowledge of the facility impacts to environment. Moreover, it also benefits to the

    residents to provide safer environment. It also can be helpful to the owner to

    upgrading its operating machineries to implementing zero pollution emitting.