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    2

    SOLID WASTE MANAGEMENT URBAN

    LANDFILL

    2.1

    general concepts

    According to the Brazilian Standard ( NBR 10004 ) solids or semisolids are those that "result

    from the activity of the community of origin

    industrial , domestic , hospital , commercial, agricultural , service and sweeping .

    It is also considered from the solid residue systems oslodos

    water treatment , those generated in equipment and facilities

    pollution control, as well as certain liquids whose particularities

    make it impossible to launch the public sewage system or water bodies

    or required to do so, technical solutions and economically unviable in the face

    best available technology " ( ABNT 1987) .

    The waste can be classified according to their origin ( Table 2.1 ) ,

    as stated in the first chapter of the fourth article of the state policy management

    integrated solid waste in the state of So Paulo , or considering

    ecological, health and economic and physical characteristics of

    residues ( Table 2.2 ) , according to the Brazilian standard NBR ( 10,004 ) .

    As for Origin

    Urban Waste

    Residential , commercial activities , street sweeping ,

    tree pruning and the like.

    Special Waste

    Of the processes of transformation : Industrial ,

    Agricultural , Radioactive , from the Services

    Health and Construction .

    Table 2.1 - Classification of Solid Waste according to their origin .

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    The urban waste are generated in urban areas , while

    Specials are generated during processing . These because of

    fact possess unique characteristics , require more care

    specific to the collection , packaging , transportation , handling and

    disposal .

    Management of Municipal Solid Waste - Landfill 29

    waste Description

    class I

    ( hazardous materials )

    Characteristics of toxicity , flammability ,

    corrosivity , reactivity , radioactivity and

    pathogenicity that may present risks to

    public health or adverse effects to the

    environment.

    class II

    ( non-inert materials )

    Materials that do not fit the classes I

    and III . The residues of this class may have the

    following properties : flammability ,

    corrosivity , reactivity , or toxicity

    pathogenicity .

    class III

    ( inert )

    Materials which do not solubilize or have not

    have any component dissolved in

    concentrations greater than the standards

    established ( NBR 10,006 - Solubilization of

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    residues)

    Table 2.2 - Classification of Solid Waste according to their physical characteristics .

    The characteristics of the waste may also vary according Zanta and

    Ferreira (2003 ) , due to factors that distinguish communities together ,

    as social, economic , cultural , geographic and climatic aspects beyond

    Biological and chemical products. Knowledge of these features enables a

    most appropriate choice in the selection of treatment processes and techniques

    disposal to be used.

    The gravimetric composition of waste is another fact of great

    importance with regard to its management, and can include

    several categories as shown in Table 2.3 . It is also important to clarify the content

    This moisture due to the fact that the weight of the organic waste is

    determined in humid conditions , ( Zanta and Ferreira , 2003) .

    It is also necessary , in addition to the qualitative aspects of knowledge

    amount produced per day ( tonnes / day ; m

    3

    / day) and production per capita

    ( ton / inhab.day ) . Data to be used in the planning of

    GIRSU . Used in this practice , the quantities concerning waste

    collected, Zanta and Ferreira (2003 ) .

    Management of Municipal Solid Waste - Landfill 30

    Category Examples

    matter

    organic

    putrescible

    Food debris , flowers , pruning trees .

    plastic

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    Bags , bags , packaging for soft drinks , water and milk ,

    containers of cleaning products , beauty and food ,

    sponges, Styrofoam , kitchen , latex , bags

    raffia .

    Paper and cardboard

    Boxes , magazines , newspapers , cards , paper , plates , books ,

    books , folders .

    glass

    Glasses , beverage bottles , dishes , mirrors , packaging

    cleaning products , beauty and food .

    ferrous metal

    Steel wool , pins, needles , product packaging

    food .

    metal noferroso

    Beverage cans , scraps of lead and copper wiring

    electric .

    Madeira

    Boxes , boards , popsicle sticks and matches, caps ,

    furniture, firewood.

    Cloths , rags ,

    leather and

    rubber

    Clothes, cleaning rags , pieces of fabric , bags ,

    backpacks , shoes, carpets , gloves , belts , balloons .

    contaminant

    chemical

    Batteries , medicines , lamps , insecticides , rodenticides ,

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    adhesives in general, cosmetic , glass enamels , packaging

    pressurized pens loaded carbon paper, film

    photographic .

    contaminant

    biological

    Toilet paper, cotton swabs , cotton , bandages , gauze and

    blood cloths , diapers,

    napkins, syringes , razors , hair , hair ,

    packaging anesthetics , gloves .

    Stone, earth and

    ceramics

    Flower pots , plates , construction debris , earth, bricks ,

    gravel , decorative stones .

    several

    Candle wax, soap and soap, charcoal chalk,

    cigarette butts , corks , credit cards , crayons ,

    long-life packaging , packaging metallized bags

    vacuumed dust , abrasives and other hard materials

    identification.

    Table 2.3 - Basic examples of each category of solid waste .

    Source : Adapted from Pessin , et al . (2002 )

    It is the responsibility of GIRSU gerenciadoras actions related to

    stages of generation , storage, collection and transport , recycling ,

    treatment and disposal of solid waste , as follows:

    Waste Generation - which promotes the generation of waste and not

    changing consumption pattern of the society . Encouraging the consumption of

    products more environmentally appropriate , and segregation of waste

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    based on their characteristics , avoiding as much as possible , the mixture of waste

    that contaminate raw materials. Valuing waste and

    enabling greater efficiency in other stages of the process .

    Management of Municipal Solid Waste - Landfill 31

    Packaging Waste - which guides the coherent

    packaging waste according to its characteristics , facilitating

    identification and safe handling during the later stages .

    Collection and Transportation - which guides the operations of removal and

    the waste to the local storage , processing or

    final destination . Can be performed selectively and collection of waste

    mixed.

    Reuse and treatment - which includes , at this stage , actions

    corrective aiming waste recovery and reduction of impacts

    environmental . Recycling, reuse , recovery or composting are forms

    reuse or waste treatment .

    Final destination - that forwards following the steps previously

    described , waste unused spaces reserved for the deposition

    final ( landfill ) with health guarantees , and properly prepared

    to collect the liquid and gaseous effluents .

    Public health problems and environmental problems arise from not

    appropriate treatment of the waste generated . Transmit diseases , like

    infected animals and insects , or the air or water polluted

    contaminated with toxic chemicals , can proliferate when the trash is deposited

    open in landfills . Respiratory , intestinal and others that are

    caused by polluted environments or through contact with animals

    contaminated can lead to death .

    The fact is that more and more throughout the world , generates a higher

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    amount of waste . Therefore , the need to develop technologies

    committed to preserving the environment and the preservation of

    quality of life increases in size proportionally .

    The average daily generation of municipal solid waste , the countries of

    first world corresponds , according to Rose et al . , to 1.77 kg per capita . this

    Indeed, the aggregate cost of treatment and waste management

    resulting from revisions to the health and environmental standards , was cause for

    investments , since the 80s, the waste recycling and selective collection

    waste generated .

    In Brazil , in big cities , according to Rose et al . , Household waste

    already produced is around 0.8 kg per capita . This indicates the growing

    need , in the country , programs that address the waste generated in a

    adequate , and that may , in addition to fighting pollution , generate wealth and

    jobs . Figure 2.1 explains the situation that is Brazil, in

    Management of Municipal Solid Waste - Landfill 32

    aspect of the final disposal of waste , and reveals a good chance that the country

    have with respect to the recovery of waste generated .

    Disposal of Waste in Brazil

    21%

    36%

    37%

    6%

    dump

    landfill

    landfill

    other

    Figure 2.1 - Disposal of Waste in Brazil

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    Source : IBGE , 2000

    Figure 2.2 shows a flowchart of the allocation of routes

    solid waste in view of its energy use .

    Figure 2.2 - Flowchart of the routes of disposal of solid waste .

    Source : Adapted from Oliveira (2000 ) .

    Management of Municipal Solid Waste - Landfill 33

    The activities of reuse or treatment using waste

    as input , consuming less energy when compared to the input

    virgin . This reveals a conservation of energy that contributes to the growth

    economical, because it can generate cost savings and increase in productivity

    micro and macroeconomic frameworks .

    The reuse of solid waste through these activities , as well

    to improve the economic productivity of companies or countries , also

    contributes to minimizing the environmental impacts associated with the generation and

    energy use .

    The use of waste energy can occur through the use

    its calorific value through incineration , gasification , the

    utilization of the calorific biogas produced from waste , or the production of

    Solid fuel from food scraps .

    Incineration takes the calorific value existing in the trash through its

    direct combustion for the production of steam. The process according to Oliveira

    (2000 ) , has the advantage of the possibility of direct use of thermal energy , the

    need for a continuous supply , which requires large amount

    waste , low noise and odor , considering a small area

    installation. Its disadvantages the impossibility to waste down

    calorific value, of the need to maintain the auxiliary equipment

    combustion , ash , for example, may have concentrations of

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    toxic metals , high investment costs and operation and maintenance also

    the possibility of emission of carcinogenic pollutants .

    Gasification is a process that consists in breaking the chains

    The residue polymeric material through a heat supplied to the

    gassing composition simpler as methane , which are

    utilized in heating processes in internal combustion engines ,

    or turbines.

    The utilization of gas from the landfill will be discussed

    in more detail in this section later in this chapter.

    It is of fundamental importance to study the composition of

    solid waste to a better decision in respect of its

    recovery and prevention, as possible , sending all materials

    to the landfill , because after his disposal the only advantage will be that of

    biogas.

    The average composition of municipal solid waste collected in Brazil

    according to research conducted in 1997 by IPT , is presented in Figure 2.3 .

    Management of Municipal Solid Waste - Landfill 34

    Average Composition of waste in Brazil

    3% 4 %

    25 %

    3%

    65% Glass

    metals

    paper

    plastic

    organic

    Figure 2.3 - Percentage breakdown of average litter weight in Brazil .

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    Source : IPT / CEMPRE 1997

    In landfill , the waste is deposited on the ground isolated so

    ordinate , and is then covered with soil from the site itself, so that

    is isolated from the environment. Formed thereby species chambers in which

    gas produced and released manure, liquid substance formed by the dark

    partially biodegraded organic waste .

    The slurry accumulates in the bottom of these chambers and tends to seep in

    soil can get up to reach the water table , which makes evident the

    need for a ground perfectly sealed prior to deposition of garbage. the

    existing standards require collection and processing of gas (NBR 8419 and

    NBR 8849 ) , and slurry ( NBR 8419 ) .

    The cell of the landfill space for the disposal of waste should be

    perfectly sealed and the leachate collection system already installed , and the

    each layer , each chamber formed in the gas collection system should

    also be installed.

    The location of the landfill should be carefully chosen ,

    should cover large and, because of their drawbacks

    operational ( smelly , garbage truck traffic , poor appearance , etc. . )

    located away from urban concentrations .

    2.2

    Gas Generation in Landfills

    The mixture of waste in landfills , discharged continually provides

    a variety chemistry under the influence of natural agents suffer

    Management of Municipal Solid Waste - Landfill 35

    physical, chemical and biological . The set of phenomena originates

    the vectors of pollution in landfills through biogas and leachate .

    See Figure 2.4 .

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    The waste gas is produced within the landfill due to changes

    biochemical occur there . The anaerobic biodegradation is achieved after

    depletion of oxygen in the chambers of landfills . Compacting Garbage

    made by machinery at the moment of deposition contributes to

    reduction of oxygen inside the chamber .

    This process occurs in several stages because the presence of

    bacteria that feed on organic matter turning it into compounds

    simpler . There are three main groups of microorganisms active in

    process , hydrolase - fermentative organisms , methanogens and acetgenos

    which are responsible for breaking the bonds of polymers and production of

    carbon dioxide, acetic acid production and methane

    respectively.

    Figure 2.4 Scheme of the main environmental impacts of the disposal of

    waste in landfills

    The generation of landfill gas is affected by several variables ,

    among which can be mentioned: nature of the wastes , humidity present in

    residues physical state of the waste ( particle size ), pH , temperature,

    nutrients , buffering capacity and rate of oxygenation . These are factors that are

    responsible for the development of anaerobic digestion of

    organic substrates ( Castillos Jr. , 2003) .

    Landfills can generate approximately up to 125 cubic meters of methane gas

    per ton of garbage in a period of 10 to 40. According to the Company

    Generation of leachate

    Emission of Odors Gas Generation

    Groundwater Level

    atmosphere

    Management of Municipal Solid Waste - Landfill 36

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    Environmental Sanitation Technology , Cetesb (1999 ) , this generation in Brazil is

    677 Gg / year, which may account for some 945 million cubic meters

    per year.

    Are presented in Table 2.4 the amount of waste and the rate of

    production of some landfills USA.

    Quantity of Waste Landfill Gas Production Rate

    Azusa 6.350 x 10

    6

    0.002 kg m

    3

    / kg.ano

    Mountain View 3628 x 10

    6

    0.008 kg m

    3

    / kg.ano

    Sheldon - Arletta 5.450 x 10

    6

    0.014 kg m

    3

    / kg.ano

    Palos Verdes 18,143 x 10

    6

    0001 kg m

    3

    / kg.ano

    Scholl Canyon 4500 x 10

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    6

    0.006 kg m

    3

    / kg.ano

    Table 2.4 Amount of waste and production rate of landfill gas

    health

    Source : Adapted from Castillos , Jr.2003

    2.3

    Composition and Utilization of Landfill Gas produced in

    toilets

    The produced gas consists primarily of methane ( CH4 ) and carbon

    dioxide ( CO2 ) . Other chemical species present in the gas depend

    directly from the composition of the waste deposited there and the stage of the process

    decomposition, which indicates that it is necessary to know their concentrations

    an assessment of environmental impacts resulting within the rules

    environmental regulations. See Table 2.4 and Table 2.5 .

    composition Concentration

    Methane CH4 44.03 %

    Carbon dioxide 34.2 %

    Oxygen O2 % 0:52

    Nitrogen N2 20.81 %

    Ammonia NH3 1.7 to 3.9 ppm

    Propane C3H8 7 ppm

    Butane C4H10 4 ppm

    50 to 90 ppm Toluene

    80 to 110 ppm benzene

    Table 2.5 Composition of gases from landfill Mountain View , California , USA .

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    Source : Adapted from Castillos , Jr.2003

    The natural methane according to the IPCC (1996) corresponds to only

    20 % of emissions leaving the remaining 80% resulting from activities

    Management of Municipal Solid Waste - Landfill 37

    human . And according to Cetesb (2001 ) among the world's emissions

    methane, 8 % fall to landfills and dumps . See Figure 2.5 .

    Studies by Keller (1988) indicate that the landfill gas

    contain six classes of compounds: saturated and unsaturated hydrocarbons ,

    alcohols, organic acids and hydrocarbons , aromatic hydrocarbons ,

    halogenated compounds , sulfur compounds and inorgnios .

    Other studies made by Allen et al. (1997) in landfills England,

    140 identify volatile organic compounds ( VOCs) , of which 90 are

    Composition detected in all samples . They are: alkanes ,

    aromatic compounds , cycle -alkanes , terpenes , alcohols and ketones and compounds

    halogenated .

    Figure 2.5 Global distribution of methane sources

    Source : Adapted from MCT 1997

    Methane , as previously stated , is a flammable gas and contributes

    very strongly for increasing the greenhouse effect. The hydrogen sulfide and other

    trace components of biogas are toxic and have unpleasant odors .

    In contrast, due to the percentage of methane in its composition,

    biogas produced in landfills can be used as fuel,

    Sources of Methane

    7%

    7%

    8%

    11%

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    17 % 22%

    28 %

    Animal waste

    Wastewater treatment

    landfills

    Biomass burning

    paddies

    enteric fermentation

    Coal , natural gas and ind .

    petrochemicals

    Management of Municipal Solid Waste - Landfill 38

    the generation of thermal or electric power , or cogeneration systems . The

    calorific value of the gas is between 14.9 and 20.5 MJ/m3 or 5,800 kcal/m3 .

    The use of waste gas is held in various countries ( Europe, America ,

    Asia) and can be considered as the simplest use of waste energy

    Urban solid .

    This use of garbage shows as advantages : the reduction of greenhouse

    greenhouse due to methane consumption , low cost for the disposal of

    waste and use as fuel for power generation or gas

    produced. The disadvantages : poor gas recovery in

    recovery of about 50 % impossibility of use of the gas in locations

    remote high cost to "upgrade " of plants , longshots autoignition or explosion . Comparing the

    advantages and disadvantages , the first

    have much larger impacts ( Oliveira , 2000) .

    Figure 2.6 is a schematic of how small the gas is captured in the region

    the landfill and used to generate electricity .

    The capture system involves a network of pipes drilled uniformly

    which run through the biogas, which is conveyed to a collector

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    page. According to Rose et al. (2003 ), two system configurations collection

    are used : vertical wells and horizontal trenches . The capture system

    should be designed to enable monitoring and adjustments flows

    biogas , facilitating its operation .

    Liquid wastes that are collected through gutters located in

    base of the landfill , can be redirected into the landfill , allowing

    Decomposition greater and greater gas production .

    Figure 2.6 Schematic capture and electricity generation from waste gas .

    Source : Adapted from CADDET 393 2000

    biogas

    waste

    Capture of biogas

    thermoelectric

    Management of Municipal Solid Waste - Landfill 39

    Before use , the process of energy conversion , biogas

    passes through a phase of treatment. In this phase particulates are removed ,

    impurities present in the condensate and gas. This treatment depends on the

    end use of biogas .

    The treated gas is directed to systems for steam generation

    ( boilers , furnaces ) or electric energy generation systems ( engines

    stationary ) and can also be harnessed to heat rejected

    heating water.

    Its use as fuel for electricity generation is

    the most common. A cogeneration system can be an alternative , and

    obtain high efficiencies can be used for various purposes to ensure

    more revenue for the project .

    In Brazil , in 2003 , there were initiatives to leverage

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    biogas generated in landfills or dumps old . Examples of these initiatives

    are, for example , found in the cities of So Paulo and Salvador .

    2.3.1

    Bandeirantes Landfill Municipal

    The Bandeirantes Landfill , in So Paulo , is considered one of the largest

    world , receives about 7,000 tons of waste per day , 50 % of total

    produced in the city . Its use began almost 30 years ago and is being

    completed in 2006 , it is expected that this year is storing more than 30

    million tons of garbage . The gases produced were simply burned

    in vertical drains , releasing pollutants into the atmosphere . (Site Logos

    Engineering ) .

    On January 23, 2004 , was inaugurated Thermoelectric Gas

    Bandeirantes Landfill Municipal already uses the biogas produced in

    landfill to generate electricity .

    Management of Municipal Solid Waste - Landfill 40

    Bandeirantes Landfill Figure 2.7 - Aerial Photo

    Source : Website ARCADIS Logos Engineering

    The correct use of gas provides a significant reduction in gas

    methane, obeying in practice , which is given in Protocol

    Kyoto on reducing emissions of greenhouse gases .

    The capture of biogas is through pipes connected to drains

    vertical strategically placed in the landfill , along with equipment

    suction drying and burning the gas surplus .

    The collected gas is routed to motor- generators , located in the plant

    the filling, with a minimum concentration of 50% by volume , at a flow rate of

    to 12.000m3 / h . This amount can generate electricity to power

    a city of about 300,000 people .

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    Management of Municipal Solid Waste - Landfill 41

    Figure 2.8 Bandeirantes Landfill - Moto - generators

    Source : Website ARCADIS Logos Energy

    The plant is connected to four alimentadoresde energy Eletropaulo

    that delivers to parts of the city .

    2.3.2

    Social Environmental Park Canabrava

    In the period between 1974 and 1997 the former landfill received waste Canabrava

    generated by the city of Salvador . It was the scene of a reality of degradation

    significant social . About 1000 scavengers working in cooperatives and

    survived by scavenging garbage .

    In partnership with the Government of Canada , the city of Salvador

    undertook the construction project of Social and Environmental Park of Canabrava .

    This project involved studies and actions for sealing the territory of the landfill to

    the planning for recycling and composting of waste , and the

    produzidosno utilization of gases inside the old dump .

    Management of Municipal Solid Waste - Landfill 42

    Figure 2.9 Socio Environmental Canabrava Park - Units Composting

    Screening Recycled and Leisure Areas .

    The Social Environmental Park is now an urbanized area and houses a

    large space for leisure community in the region . also integrating

    this space is Canabrava Child Project , which performs actions related to

    education of children of former scavengers , Park officials today . the

    Composting plants for the production of fertilizer and screening material

    recyclable ( plastic, glass , cardboard ) and a thermal power plant for the pilot

    electric power generation .

    The gas produced is channeled through vertical drains . after studies

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    made chose three such drains , according to the level of

    concentration of methane to power the motor- generator. See Figure 2.9 .

    The biogas captured is filtered and dehumidified before being directed to

    the generator , providing a greater concentration of methane in the combustor . The

    remaining gases follow for burning in a flare .

    Today , there is only a pilot plant with a capacity of 75kWh , which

    feeds all the equipment and part of the complex of residences

    residents.

    In the graph shown in Figure 2.1 , one can still identify a

    high percentage of the presence of garbage dumps in Brazil . In this sense , means

    Management of Municipal Solid Waste - Landfill 43

    that initiatives such as this , held in Salvador , may set in

    excellent opportunities for other cities in Brazil .

    Figure 2.10 - Social Environmental Park Canabrava - Ducted Gas Inlet ,

    Valves and Input Generator .

    The biogas composition , are known volume concentrations

    methane , carbon dioxide and oxygen in each well of power generator .

    The average composition of September 2003 and February 2004 are

    presented in Table 2.6.

    Biogas composition ( vol )

    September 2003

    Biogas composition ( vol )

    February 2004

    CH4 39.6 % 24.6 %

    CO2 32.8 % 27%

    O2 0.2 % 0.4 %

    Blend 27.4 % 48 %

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    Table 2.6 Composition of the gases generated in the Park Partner Environmental Canabrava

    Salvador , Bahia , Brazil

    2.3.3

    Center of Waste Disposal - Montreal (1988 )

    The Centre for Waste Disposal , in Montreal , in 1988 ,

    received about 30,000 tons of solid waste since 1968 . From the

    Management of Municipal Solid Waste - Landfill 44

    motivation to improve the quality of life of people living

    near the landfill , the city hall , along with companies

    particular , built a plant for generating electricity , and

    as fuel gas produced in landfills . The project was also contained

    treatment of this gas to prevent environmental problems . CADDET (Result 393

    - 2000) .

    The gas produced in landfills is channeled into a filter , which removes

    and particles existing in the condensed gas. Condensate is , in turn ,

    piped to a place of treatment. Umcompressor raises the gas pressure

    35kpa to ( g).

    The compressed gas is burnt in a combustor having the capability of

    produce 100.000kg / h of steam . The temperature inside the combustor is between

    1650 and 1700

    the

    C. The steam is in turn channeled to a turbine

    coupled to a generator. In the design conditions have to supply

    a plant for generating electricity with installed capacity of 25MW .

    The gas produced after combustion is composed mainly of

    carbon dioxide ( CO2 ) and water vapor with traces of nitrogen oxides

    (NOx) , carbon monoxide (CO) , sulfur dioxide (SO2 ) , hydrocarbons, and

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    unburnt compounds .

    In Table 2.7 we can find the composition of the gas produced in

    and landfill gas composition delivered after combustion .

    compounds

    concentration

    ( by vol)

    emissions

    concentration

    ( by vol)

    CH435 CO266 % , 7%

    N220 % H2O 15.6 %

    N217 O2 5 % 7%

    CO 40% CO2 24 ppmv

    232 ppmv ppmv H2S NOX21

    VOC 's 743 ppmv ppmv SO233

    HC 2 ppmv Table 2.7 Composition of gas produced in the landfill in Montreal and its

    emissions after combustion process.

    The concentration values obtained in the landfill in question ,

    comply with regulatory laws on air quality in force in Canada .

    According to the mass balance conducted using air as the oxidant

    with 78 % nitrogen, 21 % oxygen and 1 % argon , emissions

    nitrogen and carbon dioxide would be reversed. We present in Table 2.8 ,

    probable values for concentrations of emissions in landfill montreal .

    Management of Municipal Solid Waste - Landfill 45

    emissions

    concentration

    ( by vol)

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    CO217 , 7%

    H2O 15.6 %

    N266 , 7%

    24 ppmv CO

    NOX21 ppmv

    SO233 ppmv

    HC 2 ppmv

    Table 2.8 emissions after combustion process of the gas produced in the landfill

    Montreal , according to a mass balance conducted in this study.

    From the values presented for the landfill in Montreal

    began a study of a model for the simulation of a process

    Combustion in which it was possible to investigate the concentration of pollutants

    formed from biogas produced in landfills .