REMEDIAL INVESTIGATION AND FEASIBILITY STUDY

MARION PRESSURE TREATING COMPANYMARION, UNION PARISH, LOUISIANA

CTTY OF MARIONSUMMARY OF WATER QUALITY ANALYSESCITY OF MARION DRINKING WATER WELLS

Prepared for

U.S. ENVIRONMENTAL PROTECTION AGENCY1445 Ross Avenue

DaUas, TX 75202-2733

Work Assignment No.EPA RegionDate PreparedContract No.Prepared byTetra Tech Project ManagerTelephone No.EPA Work Assignment ManagerTelephone No.

031-RICO-067Z6May 19,200068-W6-0037Tetra Tech EM me.George Allman(214) 740-2029Bartolome J. Canellas(214) 665-6662

900221

CONTENTS

Section Page

I. INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1D. DISCUSSION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1ffl. RESULTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2IV. FUTUREACTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

Attachments

A LOUISIANA DEPARTMENT OF HEALTH & HOSPITALS ANALYTICAL RESULTSB U.S. ENVIRONMENTAL PROTECTION AGENCY ANALYTICAL RESULTSC TETRATECH FIELD LOG BOOK

TABLE

Table Eagfi

1 SUMMARY OF THE RESULTS OF WATER QUALITY ANALYSES . . . . . . . . . . . . . . . . . . 3

li

SUMMARY OF WATER QUALITY ANALYSISCITY OF MARION DRINKING WATER WELLS

L INTRODUCTION

In accordance with instructions from Mr. Bartolome Canellas, U. S. Environmental Protection Agency(EPA) Region 6, Tetra Tech EM Inc. (Tetra Tech) planned and conducted drinking water samplingoperations for the Marion, Louisiana City Water Wells in January 2000. The city of Marion, Louisiana,is located 33.5 miles northwest ofMonroe, Louisiana. The city acquires its water from two water wellslocated less than 1/4 mile from the intersection of State Highway (SH) 551 and SH 33, in Union Parish,Louisiana. The purpose of the sampling activity was to gather preliminary data relative to the groundwater conditions of these wells, which are located within one mile of the Marion Pressure TreatingCompany (MPTC) site. Tetra Tech utilized me services of the EPA's Environmental Services BranchLaboratory in Houston, Texas, for sample analysis.

n. DISCUSSION

Prior to conducting sampling operations, the Tetra Tech project manager contacted Mr. Jimmy Caldwell,Marion City Water Department, to obtain the historical laboratory results of previous drinking watersampling efforts. The Marion City Water Department operates the wells and, collects and tests samplesfrom the wells biannually to ensure compliance with Louisiana drinking water regulations. MarionWater System Well # 1 has a depth of 624 feet in Sparta sand, while Marion Water System Well # 2 is895 feet deep in Wilcox sand. Copies of me record of previous sampling results (Attachment A) wereforwarded to Tetra Tech on December 9,1999. Tetra Tech environmental professionals reviewed thehistorical city water well sampling records supplied by Mr. Caldwell. Historical data obtained from theMarion Water Company records indicate that the wells are in compliance with state regulations.

The Tetra Tech project manager contacted Mr. Caldwell to coordinate me January 2000 sampling effort.Mr. Caldwell met with the Tetra Tech sampling team on January 27,2000, to collect the samples. TetraTech also invited Mr. Ronnie Matte of the Louisiana Department of Environmental Quality (LDEQ) toparticipate in the sampling activities. Mr. Matte also met Tetra Tech personnel and Mr. Caldwell at thesite. Tetra Tech collected me samples on the morning of January 27,2000. In order to support the

S;\RAC\ODA031\DWSAMPLI\JAN200~1.WPD 1

quality control process, Tetra Tech also collected trip blank, field blank, and matrix spike/matrix spikeduplicate samples for analysis. The samples were immediately transported to EPA's EnvironmentalServices Branch Laboratory for analysis.

Samples were analyzed for volatile organic compounds, semi-volatile organic compounds, pesticides,polychlorinated biphenyls, metals, and cyanide; the results are listed at Attachment B. All analyticalresults were reviewed by the quality assurance personnel of the EPA Environmental Services BranchLaboratory. EPA's Houston Laboratory reported analytical results of samples collected in January 2000on March 13, 2000.

in. RESULTS

The LDHH and the OPH regulate the safety and adequacy of drinking water delivered by public watersystems in the State of Louisiana. Tetra Tech environmental professionals reviewed the laboratoryresults of samples collected on January 27,2000, and compared the results with water quality criteriaestablished by LDHH/OPH for drinking water systems. The water quality criteria established byLDHH/OPH for drinking water systems are presented in Table 1.

Laboratory results indicate that drinking water conditions of Marion City Water Wells meet waterquality criteria established by LDHH/OPH for primary drinking water systems in the State of Louisiana.Therefore, the current condition of water quality of Marion City Water Wells presents no evidence thatdrinking water quality in the City of Marion is compromised by constituents present at the MPTC site.

Tetra Tech's report evaluation team contacted Mr. David Reazin, EPA Region 6 Water Division, Mr.Greg Hill of the Louisiana Department of Health and Hospitals (LDHH), and Mr. Lance Broussard of theLDHH Office Of Public Health (OPH) to discuss the historical well records, compliance status, and thewater quality results of samples taken on January 27,2000. Tetra Tech will provide Mr. Reazin, Mr. Hilland Mr. Broussard with copies of the sampling results.

S:\RAC\ODA031\DWSAMPLI\JAN200~1.WPD 2

TABLE 1

SUMMARY OF THE RESULTS OF WATER QUALITY ANALYSESDRINKING WATER WELL SAMPLES, CITY OF MARION

"^rVi'^r;^^1';^!''^^^^

•i};' 'ff Parameter; 'l^:^^:

Antimony

Barium

Calcium

Iron

Magnesium

Potassium

Selenium

Sodium

•f^'r^^^^ipDetected^

'i'.i.^a'MWSW,'^::'".IDUPLICATE

ND

17.0

1,460

74.0

312

1.420

3.4

618,000

concentrations l

'MWSWft^i,

3.7

24.0

1,980

32.0

363

1,580

5.7

735,000

t^l)*^^.' ^1';] '

.ij.MWSW^I.

ND

18.0

1,460

49.0

322

1.440

3.6

560,000

LDHH(OPH)MCL(ug/l)

6.0

2000

NA

300

NA

NA

50

NA

Notes:

LDHHMCLMWSW^NANDOPH

Concentrations of constituents detected in well samples are presented in Table 1. Otheranalyzed constituents were not detected in well samples.Louisiana Department of Health and HospitalsMaximum Concentration LevelsMarion Water System Wellmicrograms per literNot applicableNot detectedOffice of Public Health

S:\RAC\ODA031\DWSAMPLIUAN200~1 .WPD

IV. FUTURE ACTION

Tetra Tech anticipates that sampling of the two city water wells will be repeated during the samplingactivities associated with the Remedial Investigation and Feasibility Study (RI/FS) ground waterinvestigation.

S:\RAC\ODA031\DWSAMPLIUAN200~1.WPD 4

ATTACHMENT A

LOUISIANA DEPARTMENT OF HEALTH & HOSPITALS ANALYTICAL RESULTSMARION CITY WATER WELL

(Eight Pages)

DEC-09-99 THU 16:06 Mar ion P o l i c e 110F>t .«.- - --.-„ ^._,.^um, . ,-,ui i U.ll'^11 Ln i-nUbtl 1-M <-!-<_ Ht 1UI, |U

From: LOUISIANA DEPT OF HEALTH & HOSPITALSCENTRAL LABORATORY325 LOYOLA AVB. 7th FLOORMEW ORLEANS, LA 70112

September 17, 1996TO: MARION WATER SYSTEM

PWS ID 1111011 PROJECT OB38MITOWN OP MARIONP 0 BOX 216MARION LA 71260

The following analytical results have been obtained for theindicated sample which was submitted to thie laboratory:Sample I.D. AD59622 POC ID: 6JCB-SYRFacility XDi 1111011Point Of Collection: WELL ^1 NEW WELLSample collector: MCCARTNEYSample collection date: 07/15/96 Time; 10:15Lab eubmitbal date; 07/17/96 Time: 16;56

ParameterPAH'S--- ADIPATE8/PHTHALATESSynthetic organic contaminants

Resultsee beloweee bslow

Unite HDLMicrograma/LMicrocrrams/L

D&t& for PAH'S--- ADIPATES/PHTHAIATES Micrograms/L;Coaiponent Naxae /BIS (2-ETHYLHEXYL) PHTHALATEBIS <2-ETHYLHEXYL) ADIPATEBENZO(a)PYREME

ResultNot detectedNot detectedNot detected

Caropon&nfc ICDL3.77.50.05

Data for Synthetic organic contaminants Micrograms/Li

Component NomoDALAPON2,4-DDINOSEBPICLORAMPENTACHLOROPHENOL2,4,5-TP(SILVEX)ATRAZINBALAC3tlLORCHLORDAMEENDRIHHEPTACHLORHBPTACHLOR BPOXIDBHEXACHLOROBBH2EMEHEXACHLOROCYCLOPENfADIENELINDANBMBTHOXYCHLOR

Reeult'Nob detectedNot detectedNot detectedMot detectedNot detectedNot detectedNot detectedNot detectedNot detectedNot detectedNot detectedMot detected.Ndt detectedNot .detectedNot "detectedNot detected

Component HDI»100.060.100.100.160.042.50.230.140.060.0030.0160.0020.120.0071.0

i?^?^ :! ,. ^ ru^ H- r;:1..:. .. 31e292^^... ,.../'"03

i »• ' 'MftRlOK WATER SYSTEM Sample I.D. ABS9622 (continued)Pagei ^September If. 1996

Data for Synthetic organic contaminante (continued):

Coaiponenfc NaaneSIMAZIMETOXAPHENEPCB'slSCftEEH)MJDICARB 8ULPOMEALDICARB SULFOXIDEOXAMrlb(VYDATE).METHOMYLALDIC&RBCARBOFURANDIQUATGLYPHOSATE 'ENDOTHALL

Reeuit Componon-b MDLNo.t. <^efcecced 1.0Koc detecfced 1.0Not d tect dHot detected 0.2Not detected 0.2Hot detected 0.2Noc detected 0.2Not detected 0.2Not detected 0.2Not detected 0.5Not detected 34Not detected 7

Sample conimentB; , . , • . . .

Ptttst resuteiK for voc analysis.

If there are any questions regarding ..this data. please call.

LOUIS P. WALES, JR.''" ;'.LAB SCIENTIST MANAGER

I jW-l?^ 1g. tW," l 7 J?,a i. ^p. ,P o,l, , eg D^ <.,* €

Prom: LOUISIANA DBPT OF HEALTH & HOSPITALSCENTRAL LABORATORY325 LOYOIA AVE. 7fch FLOORMEW ORLEANS, LA 70112

October 3, IS 96To: MARXOM WATER SYSTBM

PWS ID 1111011 PROJECT 0838MITOWN OF MARIONP 0 BOX 216MARION IA 71260

The following analytical results have been obtained for theindicated sample which was (submitted to this laboratory;

ficunple I.D. AB6089E t»OC ID: 8JCC-SYRFacility ID; 1111011Point o£ Collection: WELL ff2 OLD WELLSample collector; MCCARTMEYSarople collection date; 08/19/96 Timet 10:30Lab eubmittal date; 08/21/96 Time: 15:33

Payasieter-PAH'fi--- ADIPATES/PHTaAlATESSynthetic organic contaminante

Resultsee belowsee below

Unite MDLMicrograms/LMicrograias/L

Data for PAH^S---

Conipoxifeat KacieBIS (2-ETHYLHEXYL)BIS (2-ETHYLHBXYL)BENZO(a)PYRENB

PHTHALATEADIPATE

ResultMot detectedNot detectedNot detected

Component WDL3.77.50.05

Data for Synthetic organic oohtiuninantfi Microgranis/L:

Coa^ponent KaiaeDALAPON2,4-DDtHOSEBPICLORAMPEKTACHLOROPHEMOL2.A.5-TP(SILV3BX)ATRAZXNEALACHLORCttLORDANEEKDRXKHEPTACHLORHKPTACHLOR EPOXIDEHBiCACHLOROBfiKZEMBHEXACHLOROCYCLOPENTADIENELTNDANE

^nRTHOXYCHLOR .

ResultNot detectedNot detectedMob detectedNot detectedHot detectedMot detectedKot detectedNot detectedMot detectedNot detectedNot detectedNot detectedNot detectedNot detectedNot detectedMote. detected

Component ISDL100.060.100.100.160.040.300*040.140.0010.0050.0070.0020,040.0070.02

"y-i iij? i w.6: -u, d^ r.'k . ^ « ^^^^T'T^^' »

MARION WITER SYSTEM Sample I.D. AB606?S (continued)t»agei 2October 3, l$96 • • • •

Daita for Synthetic oi?ganio contaxninanfce (continued)»

Cotrtponent NainoSIMA2.XHE .TOXAPHERSPCB'B(SCREfiN)ALDICARB SULFOHBAliDICARB SUL^OXIDBOXAMYL(Vn)ATE)MBTHororx*ALD1CARBCARBOPURANDIQTJATGLYPHOSATEEMDOTHRLI*

Refiult Coinponent; H&1«Not detectefl 0.^7Hot deteoted 0.31Mot detectedNot detected 0.33Not detected. 0.22Not detected 0.23Not detected O.X2Hot detected 0.33Hot detected 0.32Kot detected 0.5Kot Done 34Hot detected 7

Sample cornciente:

FIEASE RESUBHIt FOR VOC t d.WtlOSA'ni MMYSES.

If there are &ny questions regarding this data, pleaee c&ll

LOUIS P. WALES, JR:LAB. SCIENTIST MAMAOER

sie -t;y-^ <*. r i rDEC-09-99 THU 1 6 : 0 8 Mar i on Po I i c-e D»P-t .

^i -

1

..;> ' '

i

r1

1

>•

&;''•. •

J• .1}3*

^?r:

•

!•

•

•

WEL

C O » ( P J W Y X l a

& LA

wm. MX

FtCTA tVA

ewwry UNLoulloa

ee/ee/ePw. ,10 ,,,,Tl

P«r »p"*t P r»" 8,U< y(wroe4 rroa-:t>ritUDi'. t »af»d Fro.•{•Wy /•*;"^— ' .'r • -.sS11--.1- - •Ran No.Dtptb—DrillsDepU 4« ««rBun. Ler Int«r.Top LO( Inter,Culnc—I/rilltrCuiar—LacptrfiltGiwTn« PlaM In Hole

beu. | Vcc.pH | Fluid LouSourw •I Sftinpt*K* eNeu-Temp.Btti tf MMA. Tc«np.^k* 9 Mtu. T«*np.Se«tectil«i K-h.^Bk'r

TtrM 61«e« drc.lax. Bee. Temp.

fcqfllp. | LocationftKorMb,iUMHCd Br

•

CILL GUR\El E C

AOflN MiLtpd

. OEPT. OP 1

^<ON rf( 1 U»

TER WCLL Te(

JON

£

,. 22N .

ftOUND LEVELGAME„ 8AME

5^M^ffJ3N£fi2A626^aa———00

—»—

6 VANATIVE

1 ^MUDPIT.5.fi ^ 7^7' « 'r

e •r

« •^1/S? HR» ^

808 1 MANYDAYfB

TftffAOMV^

ABLEKEYINGT R 1 CORILLIMQ CC

PUBLIC KTOaKS

M-73

BT.

CTATP-^ L

SE S., M,

, raw... ^ TV A*^»*(I

. ..• '.

e'

1| ml

» ^« •t-

^ t» ^

•r1

afiriGEft^ MILI

NEi CC

LWPANY

OU16N

178Fen& llkt

(

(€(

i

e&

)M0

kNA

3?

*te*

.

IP1 C

Oth

Elev

','-'

»!

'^

-T-ij,

•-»,-

Aisn» , • ''

erServfeu

r.: K.Bn,r,,

.•;cA^

<

««<

€

i

f

ft

^

9

———iiiT

9 'f> • ^> *F

» *fr

•r•'

-

•

«M6ft:

E-«»-E^

(i-3i

«

TKgR

1EC?h

ppC-09-?.?, .THU, 1 6 : 0 9 M o L t - t o n Pol i ca. U»P'l - ^ Ji G ^-"y ^- •*!.*

i'- • •

CHARLENEWELL SURVEYING COMPANY

fr" •«-.

,•'•P.- ••'•

E L E C T R I C 1. 0 G:;tT;.

COMPANY.OSO(

f iLLA.

WKU..., MARpfRLD.. , MAQJ

comrry UN^l4e«tion

SE/4. 3W/

flw.. .,...J5,....Jhr»

Permanent Duturn* v

Ley U«axur«<l Frotfl—.• Orillmff Measured Froi

• D»t«Rvn No.Ptptk—DriUtTl)epUi—L<?(t([<r

. Gtftt: Lof Inter.•Trtp Loff Inttr.-C««ine—DrillerCittins—Lorrt'

"RflSix •" "'ryp* Fluid In Holt

^M. | Vl««." pH ( Mu^Low

SourreofSunpleit« <ei McBo.Ttmp.

. .£«r e Mrti. Tcrop.lt.«K @ Meax, T»mp.

" • Source: Riii( It—Rr @ BHT

• T(nw Since Circ.. f»x, Rcc, Temp.

fequip. | LocftKon: f^cordfd Byf.Witncd'Mid By

^1?.!L."LILLER 0-fiEfI QE-.Jp.u

ION ff 9 Usq

mM-JKAlEa.IE

3N

^, NE/4

»..., , aatN,,. R^5ROUNO LEVELSAME» SAME

6-19-68ONE89509?gQ-^50-.-. e>——

...6 V4.. .„, NATIVE......

| ret

m?n .0,9 ^ ((0 F

•'"• ^ "''T^ 'F|@ T

^A HR-^/-r iiik(^.

2.08.....1.WANYDAVIS

RMinFR- ny

^JLLJNG^CpMj

QL(-C ttDRKS^^« . i— *<——^*^%*-"^* ••^ - —

8.UN-74

ST

-,. i!TATR L..(

PC S»r N«

, , , . , F.l»».. J.....Ft. Alx»»»

G

|| mt

© ^@> ^e> -Fte> *F

tp1

inRFaa—..

PANY.

3Y1SIANA

AoPerm. Dklum

e'

tI

®@@te*

1

.-.

Oth<

EIcv

ml

•F•F*F

•F

*F

..—.... ...

r ServtceB;

.; K.B. — ...D.F^. - ^G.I. 1-4P ,

e"

" ' tnl

<5> t@ *r(? - ^

e» *F'

*F1

f§

.".

s';: .. •Is* ' •!;i^'; •','•. ' 'K.

?";;!'''':i'.

f-

•'.

AK

£:••':•

|f'''

1 "•I

..

•

.

•;;;

fflf..fff'

;

•

*lt> •^.f^. *» r i r r - w<DEC-09-99 THU 16:09 Moil-ton P o l i c e Dept- .

owner --J'SLJUaahS-Elevatior.J^S^p )

Ovner_ nilM» of ri

UlnTEO STATESDEPARTMENT OF THE INTERIOR

GEOLOGICAL SURVEY " .JCitllflO-4

Addreee parley L .

Location

Driller B^ F, Edtpp ,

Depth of teat hole_

Address 6hr<m rt. IA.

JCt., Depth of veil 6gg fl^

type of. veil; Du , Driven, BoredJD( m^Jet_

Stratleraphjic unit Op>rt» acod

Completed^ XQoS

Jtog: Dy E., (W or C),

Casings: KJUndKindKina"

;slge 8* ;lensth CS6 ft. tbetveen p Pn^^Bgfi,. ftJ s tze <• ^ length""~C3Tft. ifeetwea 4&t ena 6€jfe ft

ft.;betveen ft

Screen record. (aien., opening, Bottine) 60 ft» of ctftlnlcct ctool corBtn Cr&»

64ft-6&S,

Punip: Make cmA 'I pc_Pump settingCapacity^

?1______Stages: No.______,Dlera._______ft.; length and. dioaeter of footplece____ft^

_gEm; Coluan diemeier________H.P._____10 R.P.M. lyggPower, kin<l: Eicatirt.0"

_lninIJI

St&tjlc level —_| 4 f.^ ft"f rept*< aeoB') ; " i <f 19_^^Rbove/belov i p! p p

n\ -^. i^-i.!^A_______which lg ).^_____ft< above,) oelov land. surfac'

PUBtplilg level_

Drawlciwn *"

ft. Yiel L 19

Specific capacityft. after puKping hours at_

vhile puuBptng____gpci JL9__; Hre/day In use,<^___

Uac; InA., Irr.,J£»fi<t ,Dom., Stock, Obs«, Teot,_Ainount (epd); Averaee_______, naxtniuB

Odor 1^6 Temp. (•F)J1

Swirce of data t* F» Ediagtoa

Recorded 1>y Date i8*Ca*B& ;Rescheaxx]:ed by

Remarka; (l DQ«I> not include fi ffc^ »f q* «ii». g^*. p«p* ^•>m> ^«'o ^f ynriMal10 l«-ch ujx^ern»«*»d 6*0-690« Gravl p&olcod with 6 yarde of ««11 er^vel*160 r,a0if8 of »eh»nt. 14 froh bapic pf«nf v«1^.—————————————————————————

l^.^ fl^ ^<') li-7-.f

(Revised May 1, 1958)

Qaaarangle ^vwrville

vcn wo. Un^g

DEC-09-99 THU 16:10 Mar i on P o l i c e Dep-t . 318 29Z < flr

Wen No.

IJOG OP WE1

Type of rock

BurfeocSh&l«

• ItocfcShal 9

i Sand arid houlderci ShAlo; 6«&d

ItoofcShale

! ItoekKh»l®

; ShtleBooleShaleSutdItoflk

> yimlo; Swxi

Sh&le[took

i SftfldSftod «ZKI chdU

: 8h*l«Bool:Shale and bovldcre

i 8*1x1j • GtKile

Gftfid• Gh&lei StDd; 'Shala

SandShftl«S&Bll6h«l«GladSftndS&rd, chal«, •x*d lleniBtna SKE7TCH AUD DIA&B

Sandy chal»' S»nd

Shale

UL

Thickness

B2614

1£1616

S61

51£3 }2

1610

106

2^i 6621?7T9

17C610124

196

1180

» 20IAH 7

41626

*«

ff

Depth

I?5^36406t6670T5787&

11018S186150160161170k i——t176200SOO210as29Ttee ,SOB t,S12sie128cce890400411416^564444664T6496EOS

545696601

v.f ^

•'. r .

t^\

1,•>

»;n

/

... ' /•.

ATTACHMENT B

U.S. ENVIRONMENTAL PROTECTION AGENCY ANALYTICAL RESULTSMARION CITY WATER WELL

(44 Pages)

^ UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION 6

1445 ROSS AVENUE, SUITE 1200DALLAS. TX 75202-2733

March 21,2000

Ms. Judy Brewster, Marion Town Clerk398 Main StreetMarion, LA71260

Re: former Marion Pressure Treating Company site.Results from town drinking water well samples collected January 2000

Dear Mrs. Brewster:

Please add the following material to the repository of information related to theformer Marion Pressure Treating Company site; and share the information with the townofficials.

Enclosed is the EPA Laboratory "Final Analytical Report" with results for thewater samples collected from the town drinking water wells in January 2000. These areonly the laboratory results. Many are listed as "ND", which means that they were "NotDetected" or found during the analysis. EPA and their contractor's will further evaluatethis data, and will consult with other Federal and State agencies to produce a final reportwith the interpretation of the results.

If there is any question related to this material, you, the Town Officials and or thepublic may contact me at (214) 665-6662.

Sincerely,

Bartolome J. Cafiellas (6SF-LP)

Recycled/Recyclable •Printed with Vegetable 00 Based bite on 100% Recycled Paper (40% Postconsumer)

OT5BCW11 Pagel

United States Environmental Protection AgencyRegion 6 Environmental Services Branch Laboratory

10625 Fallstone, Houston, Texas 77099

Final Analytical Report

Site Name

CERCLIS Number

Marion Pressure Treating

........ LAD008473142

Sample Collection Date ................................... January 27,2000

Laboratory Sample Identification ................................. OT5BCW11

Contact........................................... Bart Canellas (6SF-LT)

Report Date .............................................. March 13,2000

Report Narrative:

Standard procedures for quality assurance and quality control were followed inthe analysis and reporting of the sample results. The results apply only to thesamples tested. This final report should only be reproduced in full.

The laboratory routinely disposes of samples 90 days after all analysis has beencompleted. If you have a need to hold these samples in custody longer than 90days, please send an e-mail to Lany Streck Streck.Larrv(S>epa.aov within thenext 30 days briefly stating your need to hold these samples in custody.

Report Approvals:Marvelyn HumphreyDeputy Branch Chief (Acting) Region 6 Laboratory Branch Chief

OT5BCW11 Page 2

United States Environmental Protection Agency( B, Region 6 Environmental Services Branch Laboratory

10625 Fallstone, Houston. Texas 77099

^/ Final Analytical Report

Report Contents

STATION NUMBER________LABORATORY SAMPLE NUMBER_____________PAGE(S)

01 ......................... OT5BCW11-01 ......................... 3-10

02 . . . . . . . . . . . . . . . . . . . . . . . . . OT5BCW11-02 . . . . . . . . . . . . . . . . . . . . . . . . 1 1 - 1 803 . . . . . . . . . . . . . . . . . . . . . . . . . OT5BCW11-03 . . . . . . . . . . . . . . . . . . . . . . . . 19-2604 . . . . . . . . . . . . . . . . . . . . . . . . . OT5BCW11-04 . . . . . . . . . . . . . . . . . . . . . . . . 27-2905 . . . . . . . . . . . . . . . . . . . . . . ' . . . OT5BCW11-05 . . . . . . . . . . . . . . . . . . . . . . . . 30-32QC RESULTS .................................................... 33-42

CHAIN OF CUSTODY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43

"V

OT5BCW11 Page 3

U. S. Environmental Protection AgencyRegion 6 Houston Laboratory

Report For Sample Number OT5BCW1101

Source: MARION PRESSURE TREATINGSite Description: -,

Date/Time Received: 1/31/2000 08:30 AM Date Completed 3/10/2000

Date/Time Collected: 1/27/2000 11:26 AM

Sample Type: LIQUID

Comments:

ParameterABN

CN

EMHG

MAA

MICP

P/P

VOA

DescriptionACID/BASE NEUTRALS

CYANIDE

ESAT-MERCURY

GFAAS METALS

ICP METALS

PESTICIDES/POLYCHLORIHATED BIPHEMYLS

VOLATILE ORGANIC ANALYSIS

OT5BCW11 Page 4Volatile Organic Compounds

Method CLP SOW OLM03.2 (low level)

Sample Number OT5BCW11-01

Sample Type: LIQUID

Date Extracted: not extracted

Date Analyzed: 05-Feb-OO

Compound page 1 of 1Chloromethane——————————————————————————Bromomethane——————————————————————————Vinyl Chloride——————————————————————————Chloroethane———————————————————————————Methylene Chloride————————————————————————Acetone——————————————————————————————Carbon Disulfide——————————————————————————1,1 -Dichloroethene—————————————————————————1,1 -Dichloroethane————————————————————————trans-1,2-Dichloroethene—————————————————————cis -1,2-Dichloroethene———————————————————————^l.l———^J^——^^cnioroform————————————————————————————1,2-Dichloroethane—————————————————————————2-Butanone—————————————————————————————1,1.1-Trichtoroethane———————————————————————Carbon Tetrachloride————————————————————————Bromodichloromethane———————————————————————1 2-Dichloropropanecis-1,3-Dichloropropene——————————————————————Trichloroethene———————————————————————————Benzene—————————————————————————————Dibromochloromethane———————————————————————trans-1.3-Dichloropropene—————————————————————1,1,2-Trichloroethane————————————————————————Bromoform————————————————————————————4-Methyl-2-Pentanone———————————————————————2-Hexanone————————————————————————————

1,1,2,2-Tetrachloroethane—————————————————————Toluene——————————————————————————————Chlorobenzene———————————————————————————Ethylbenzene———————————————————————————Styrene—————————————————————————————o-xylene—————————————————————————————m/p-xylene—————————————————————————————

results (ug/l)

NDND

. NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND

detection limits1111251111111511111111111

11111111

* "ND" means not detected at the corresponding detection limit

OT5BCW11 Page 5Tentatively Identified Volatile Organic Compounds

Method CLP SOW OLM03.2 (low level)

Sample Number. OT5BCW11-01

Sample Type: LIQUID

Date Extracted: not extracted

Date Analyzed: 05-Feb-OO

Number TICs found: 0

TICNO. CAS NO. COMPOUND NAME*

RTmin.

EST.**CONC.

pg/1

* The compounds listed are tentatively identified by the best match with the NIST/Wiley mass spectral databaseand/or by manual interpretation.

** An estimated concentration is obtained by quantitation using the nearest internal standard. Since no standardwas used for confirmation nor quantitation, a response factor of 1.0 is assumed.

OT5BCW11 Page 6

ORGANIC ANALYSIS DATA6HD-HO Sample NO: OT5BCW11-01

SEMI-VOLATILE COMPOUNDS BY METHOD 625(continuous extractor)

units: ug/L

Date Analyzed: 03-Feb-OO

Sample Type: Liquid

units> ug/L

Compound Name Results* | Del Limits Compound Name Results* | Del Limits

Acenaphthene . . . . . . . . . . . . . . .Acenaphthylene . . . . . . . . . . . . .Anthracene . . . . . . . . . . . . . . . . .Benzole Acid . . . . . . . . . . . . . . .Benzo(a)Anthracene . . . . . . . . .Benzo(a)Pyrene . . . . . . . . . . . . .Benzo(b)Fluoranthene . . . . . . .Benzo(g,b,i)Perylene . . . . . . .Benzo(k)Fluoranthene . . . . . . .Benzyl Alcohol . . . . . . . . . . . . .bis(2-Chloroethoxy)Methane .bis(2-Chloroethyl) Ether . . .bis(2-chloroisopropyl)Etherbis-(2-Ethylhexyl)Phthalate4-Bromophenylphenyl Ether . .Butylbenzylphthalate . . . . . . .Carbazole . . . . . . . . . . . . . . . . . .4-Chloroaniline . . . . . . . . . . . .2-Chloronaphchalene . . . . . . . .2-Chlorophenol . . . . . . . . . . . . .4-Qilorophenylphenyl Ether .4-Chloro-3-Methylphenol . . . .Chrysene . . . . . . . . . . . . . . . . . . .Dibenzofuran . . . . . . . . . . . . . . .Oibenzo(a,h)Anthracene . . . . .1.2-Oichlorobenzene . . . . . . . .1.3-Dlchlorobenzene . . . . . . . .1.4-Dichlorobenzene . . . . . . . .3,3'-Dichlorobenzidine . . . . .3.4-Dichlorophenol . . . . . . . . .Diethylphthai ate . . . . . . . . . . .3,4-Dlmethylphenol . . . . . . . . .DimethylPhthalate . . . . . . . . . .

KDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNONDNDNDND

3

a3

10

8

0.2

8

3

33

10«

2

62

2,4-Dlnltrophenol . . . . . . . . .2,4-Dlnitrotoluene . . . . . . . .2,6-Dinitrotoluene . . . . . . . .4,6-Dlnltro-2-HethylphenolCi-n-Butylphthalate . . . . . . .Di-n-Octyl Phthalate . . . . . .Fluoranthene . . . . . . . . . . . . . .Fluorene . . . . . . . . . . . . . . . . . .Hexachlorobenzene . . . . . . . . .Hexachlorobutadiene . . . . . . .Bexachlorocyclopentadiene .Hexachloroethane . . . . . . . . . .Indeno(1,2,3-cd) Pyrene . . .Isophorone . . . . . . . . . . . . . . . .2-Methylnaphthalene . . . . . . .2-Methylphenol . . . . . . . . . . . .4-Methylpbenol . . . . . . . . . . . .Naphthalene . . . . . . . . . . . . . . .2-Nltroaniline . . . . . . . . . . . .3-Nltroaniline . . . . . . . . . . . .4-Nitroaniline . . . . . . . . . . . .Nitrobenzene . . . . . . . . . . . . . .2-Nltrophenol . . . . . . . . . . . . .4-Hitrophenol . . . . . . . . . . . . .N-Nitrosodiphenylamine . . . .N-Nitroso-Di-n-PropylaminePentachlorophenol . . . . . . . . .Phenanthxene . . . . . . . . . . . . . .Phenol . . . . . . . . . . . . . . . . . . . .Pyrene . . . . . . . . . . . . . . . . . . . .1,2,4-Tricblorobenzene . . . .2.4.5-Trichlorophenol . . . . .2.4.6-Trichlorophenol . . . . .

NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNONONDNDNDNDKDNONONDNOND

3066

202

4

2

3

1

5

1038

4

2

6

6

3

88

8

2

10134

6124

3

366

0 KD - Not detected above the listed detection limit.

Analyst Notes: none

{*) NO • Not detected above the listed detection limit.

-»-

OT5BCW11 Page 7

ORGANIC ANALYSIS DATA6MD-H Sample NO:OT5BCWU-01 Dace Analyzed: 03-Feb-OO

Sample Type: Liquid

TENTATIVELY IDENTIFIED SEMI-VOLATILE COMPOUNDS BY METHOD 625units: ng/L

RT (lain)

(*) ANALYSTS N01spectral dat

( • * ) Estimated c

CAS «

FE: The compoundsa base or by mar

oncentration is

COMPOUND NAME (*)

NO ABN TIC'S detected in this sample.

3 listed are tentatively identified by the best match with the NISiual interpretation.

based on a Response Factor of 1.0 to the nearest internal scandal

Estimated |Concentration ( • • ) |

ST/EPA/Kiley mass

•d.

OT5BCW11 Page 8

PESTICIDE/PCB ANALYSIS

SAMPLE:SAMPLE TYPE:

GUIDANCE METHOD: OLC02.1

OT5BCW11-01LIQUID

DATE EXTRACTED: 2/2/2000DATE ANALYZED: 2/7/2000

CAS^

319-84-6319-85-7319-86-858-89-976-44-8309-00-21024-57-3949-98-860-57-172-55-972-20-833213-65-972-54-08742193-453494-70-510341-07-850-29-372-43-55103-71-95103-74-28001-35-212674-11-211104-28-211141-16-553469-21-912672-29-611097-69-111096-82-5

Alpha-BHCBeta-BHCDelta-BHCGamma-BHC (Lindane)HeptachlorAIdrinHeptachlor EpoxideEndosulfan IDieldrin4,4' DDEEndrinEndosulfan II4,4' -DDDEndrin AldehydeEndrin KetoneEndosulfan Sulfate4,4" -DDTMethoxychlorAlpha-ChlordaneGamma- ChlordaneToxapheneArodor 1016Arodor 1221Arodor 1232Arodor 1242Arodor 1248Arodor 1254Arodor 1260

RESULTSNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND

DL0.010.010.010.010.010.010.010.010.020.020.020.020.020.020.020.020.020.100.010.011.000.200.400.200.200.200.200.20

ND = NOT DETECTEDDL = DETECTION LIMIT

OT5BCW11 Page 9US EPA REGION 6 LABORATORY

SAMPLED: OT5BCW11-01

SOURCE:MATRIX

ANALYSTS:

PARAMETER

ALUMINUMANTIMONYARSENICBARIUMBERYLLIUMCADMIUMCALCIUMCHROMIUMCOBALTCOPPERIRONLEADMAGNESIUMMANGANESEMERCURYNICKELPOTASSIUMSELENIUMSILVERSODIUMTHALLIUMVANADIUMZINC

MARION PRESSLUQUID

KD. BB, SH

CONCENTRATION

ND3.7ND24NDND

1980NDNDND32ND

363NDNDND

15805.7ND

735000NDNDND

IRE TREATING

DETECTIONLIMIT <=

1002.02.010

2.02.01502.02020252.0150

50.120

10002.010

5002.03020

DATES ANALYZED:14-FEB-OOTO

' UNITS Ml

UG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/L

.-...- UG/LUG/LUG/LUG/L

17-FEB-OO

ETHOD .

200.7200.8200.8200.7200.8200.8200.7200.8200.7200.7200.7200.8200.7200.7245.1200.7200.7200.8200.7200.7200.8200.7200.7

ND: LESS THAN DETECTION LIMIT

'V-

TKRCCTNRCC Laboratory

Report of AnalysisMar 07,2000 9:15AM

OT5BCW11 Page 10

TNRCC Sampler 00Matrix: LIQUIDCollected: 1/27/00 0:00Program: EnvironmentalCollection Site: Marion

Constituent Name

00698

ProtectioPressure

nT

Agencyreating

Group f : 20000224Depth:Received: 02/01/00

Result Unit

Chain of Custody ftStation ID:Collected by:

Prepared Analyzed

Region:

Method<0.02 mg/LCyanide, Total 02/08/00 7:25 335.2

End of Data for TNRCC Sample f: 0000698

Laboratory Approval: —>/) 07-Mar-OO

OT5BCW11 Page 11

U. S. Environmental Protection AgencyRegion 6 Houston Laboratory

Report For Sample Number OT5BCW1102

Source: MARION PRESSURE TREATINGSite Description: —

Date/Time Received: 1/31/2000 08:30 AM Date Completed 3/10/2000

Datemme Collected: 1/27/2000 12:06 PM

Sample Type; LIQUID

Comments:

ParameterABNCNEMHGMAAMICPP/P

VOA

DescriptionACID/BASE NEUTRALSCYANIDE

ESAT-MERCURY

GFAAS METALSICP METALS

PESTICIDES/POLYCHLORIHATED BIPHENYLS

VOLATILE ORGANIC ANALYSIS

OT5BCW11 Page 12Volatile Organic Compounds

Method CLP SOW OLM03.2 (low level)

Sample Number OT5BCW11-02

Sample Type: LIQUID

Date Extracted: not extracted

Date Analyzed: 05-Feb-OO

Compound page 1 of 1Chloromethane——————————————————————————Bromomethane——————————————————————————Vinyl Chloride——————————————————————————Chloroethane———————————————————————————Methylene Chloride———————————————•————————

• Acetone—————————————————————•—————————Carbon Disuffide—————————————————————————1,1-Dichloroethene————————————————————————1,1-Dichloroethane————————————————————————trane.«1 ^—rV^hlfwwH'ir'nr^ --— - ' ,

cis - 1 , 2 - D i c h l o r o e t h e n o — — — — - — • • • • • "•—————————^ L | - ^ — a — -Chloroform——————————————————————————•——1,2-Dichloroethane—————————————————————————2-Butanone———————————————————————————1,1.1 -Trichloroethane————————————————————————^^"srhrtM Tfi r's/^Mftri ft ———

Bromodichloromethane——————————————————————1,2-Dichloropropane———————————————————————cis-1,3-Dichloropropene——————————————————————Trichloroethene——————————————————————————Benzene——————————————————————————————Dibromochloromethane———————————————————————trans-1,3-Dichloropropene—————————————————————1.1,2-Trichtoroethane————————————————————————B romoform—————————————————————————————4-Methyl-2-Pentanone———————————————————————2-Hexanone————————————————————————————

1 4 0 0 "r&tr'B/^hlArAAth^i' r^— ••

Toluene—————————————————————————————Chlocobenzene——————————————————————————Ethylbenzene————————————————————————————Styrene———————————————————————————————

m/o-xylene————————————————————————————

results (ug/1)NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND

detection limits11112511111115111111111115511111111

"ND" means not detected at the corresponding detection limit

OT5BCW11 Page 13Tentatively Identified Volatile Organic Compounds

Method CLP SOW OLM03.2 (low level)

Sample Number OT5BCW11-02

Sample Type: LIQUID

Date Extracted: not extracted

Date Analyzed: 05-Feb-OO

Number TICs found: 0

TICNO. CASNO. COMPOUND NAME*

RTmin.

EST.**CONC.

PS/I

• The compounds listed are tentatively identified by the best match with the NIST/Wiley mass spectral databaseand/or by manual interpretation.

** An estimated concentration is obtained by quantitafcon using the nearest internal standard. Since no standardwas used for confirmation nor quantitation, a response factor of 1.0 is assumed.

OT5BCW11 Page 14

ORGANIC ANALYSIS DATA6MD-HO Sample NO: OT5BCW11-02

SEMI-VOLATILE COMPOUNDS BY METHOD 625

(continuous extractor)units: ug/L

Date Analyzed: 03-Feb-OO

Sample Type: Liquid

units: ug/L

Compound Name Results* | Del Limits Compound Name Results* 1 Det Limits

Acenaphthene ...............Acenaphthylene .............Anthracene .................Benzole Acid ...............Benzo(a)Anthracene .........Benzo(a)Pyrene .............Benzo(blFluoranthene .......Benzo(g,h,l)Perylene .......Benzo{k)Fluorantbene .......Benzyl Alcohol .............bis(2-Chloroethoxy)Mettiane .bis(2-Chloroethyl) Btber ...bis(2-chloroisopropyl)Etherbis- (2-EthylhexyDPhthalate4-Bronophenylphenyl Ether ..Butylbenzylpbthalate .......Carbazole ..................4-Cnloroanlllne ............2-Chloronaphtbalene ........2-Chlorophenol .............«-Chlorophenylphenyl Ether .4-Chloro-3-Methylphenol ....Chrysene ...................Dibenzofuran ...............Dibenzo(a,h)Anthracene .....1.2-Dichlorobenzene ........1.3-Dichlorobenzene ........1.4-Dichlorobenzene ........3.3• -Dichlorobenzidlne .....2,4-Dichlorophenol .........Oiethylphthalate ...........2,4-Dlmethylphenol .........OimethylPhthalate ..........

NDNONDNDNDNONDNDNDNDNDNDNDHONDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND

2

2

210

8

0.2

as

3

3

3

10

6

2

6

2

2,4-Dlnltrophenol . . . . . . . . .2,4-Dinitrotoluene . . . . . . . .2,6-Dinitrotoluene . . . . . . . .4,6-Dinitro-2 -MethylphenolDi-n-Butylphthalate . . . . . . .Di-n-Octyl Phthalate . . . . . .Fluoranthene . . . . . . . . . . . . . .Fluorene . . . . . . . . . . . . . . . . . .Hexachlorobenzene . . . . . . . . .Hexachlorobutadiene . . . . . . .Hexachlorocyclopentadiene .Hexachloroethane . . . . . . . . . .Indeno(l,2,3-cd) Pyrene . . .Isophorone . . . . . . . . . . . . . . . .2-Methylnaphtbalene . . . . . . .2-Methylphenol . . . . . . . . . . . .4-Methylphenol . . . . . . . . . . . .Naphthalene . . . . . . . . . . . . . . .2-Nicroanlline . . . . . . . . . . . .3-Nitroaniline . . . . . . . . . . . .4-Nitroaniline . . . . . . . . . . . .Nitrobenzene . . . . . . . . . . . . . .2-Nitrophenol . . . . . . . . . . . . .4-Nierpphenol . . . . . . . . . . . . .N-Nitrosodiphenylamine . . . .N-MlCroso-Di-n-PropylaminePentachlorophenol . . . . . . . . .Phenanthrene . . . . . . . . . . . . . .Phenol . . . . . . . . . . . . . . . . . . . .Pyrene . . . . . . . . . . . . . . . . . . . .1,2,4-Trichlorobenzene . . . .2.4.5-Trichlorophenol . . . . .2.4.6-Trichlorophenol . . . . .

NDNDNDNDNONDNDNDNDNDNDNDNDKDNDNDNDNDNDNONDNONDNONONDNDNONDNDNDNOND

30

6

6

20

2

4

2

2

1

5

10

38

4

8

2

10

13

4

6

1

2

4

2

3

66

(•) ND - Not detected above the listed detection limit.

Analyst Notes: none

(*) ND - Not detected above the listed detection limit.

OT5BCW11 Page 15

ORGANIC ANALYSIS DATA6MD-H Sample NO:OT5BCW11-02 Date Analyzed: 03-Feb-OO

Sample Type: Liquid

TENTATIVELY IDENTIFIED SEMI-VOLATILE COMPOUNDS BY METHOD 625unite: ug/L

RT (min)

——————————

—————————

( • ) ANALYSTS MOIspectral dat

( • • ) Estimated c

I CAS «

I

——————————

FE: The compoundsa base or by man

oncentration is

COMPOUND NAME (*)

Ho ABN TIC'S detected in this sample.

•

listed are tentatively Identified by the best match with the HISmal interpretation.

based on a Response Factor of 1.0 to the nearest internal standaz

EstimatedConcentration { • • )

ST/EPA/Hiley mass

rd.

OT5BCW11 Page 16

PESTICIDE/PCB ANALYSISGUIDANCE METHOD: OLC02.1

SAMPLE:SAMPLE TYPE:

OT5BCW11-02LIQUID

DATE EXTRACTED: 2/2/2000DATE ANALYZED: 2/7/2000

CAS#

319-84-6319-85-7319-86-858-89-976-44-8309-00-21024-57-3949-98-860-57-172-55-972-20-833213-65-972-54-08742193-453494-70-510341-07-850-29-372-43-55103-71-95103-74-28001-35-212674-11-211104-28-211141-16-553469-21-912672-29-611097-69-111096-82-5

Alpha-BHCBeta-BHCDelta-BHCGamma-BHC (Lindane)HeptachlorAldrinHeptachlor EpoxideEndosulfan IDieldrin4.4' DDEEndrinEndosutfan II4.4' -DDDEndrin AldehydeEndrin KetoneEndosulfan Sulfate4,4' -DDTMethoxychlorAlpha-ChlordaneGamma- ChlordaneToxapheneAroclor1016Aroclor 1221Aroclor 1232Aroclor 1242Aroclor 1248Aroclor 1254Aroclor 1260

RESULTSNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND .NDNDNDNDNDND

DL0.010.010.010.010.010.010.010.010.020.020.020.020.020.020.020.020.020.100.010.011.000.200.400.200.200.200.200.20

WD=//OF DETECTEDDL = DETECTION LIMIT

OT5BCW11 Page 17US EPA REGION 6 LABORATORY

SAMPLE #:

SOURCE:MATRIX

ANALYSTS:

PARAMETER

ALUMINUMANTIMONYARSENICBARIUMBERYLLIUMCADMIUMCALCIUMCHROMIUMCOBALTCOPPERIRONLEADMAGNESIUMMANGANESEMERCURYNICKELPOTASSIUMSELENIUMSILVERSODIUMTHALLIUMVANADIUMZINC

OT5BCW11-02

MARION PRESSUUQUID

KD.BB, SH

CONCENTRATION

NDNDND18NDND

1460NDNDND49ND

322NDNDND

14403.6ND

560000NDNDND

IRE TREATING

DETECTIONLIMIT <=

1002.02.010

2.02.01502.02020252.0150

50.120

10002.010

5002.03020

DATES ANALYZED:14-FEB-OO TO

UNITS Ml

UG/LUG/LUG/LUG/LUG/LUG/L

• "• UG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/L"UG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/L

17-FEB-OO

ETHOD

200.7200.8200.8200.7200.8200.8200.7200.8200.7200.7200.7200.8200.7200.7245.1200.7200.7200.8200.7200.7200.8200.7200.7

ND: LESS THAN DETECTION LIMIT

TNRCC LaboratoryReport of AnalysisMar 07,2000 9:1 SAM

OT5BCW11 Page 18

TNRCC Sample «: 0000699 Group«: 20000224Matrix: LIQUID Depth:Collected: 1/27/DO 0:00 Received; 02/01/00Program: Environmental Protection AgencyCollection Site: Marion Pressure Treating

Chain of Custody < Region:Station ID:Collected by:

Cyanide, TotalConstituent Name Result_____Unit______Prepared_____Analyzed______Method

<0.02 mg/L 02/08/00 7:25 335.2End of Data for TNRCC Sample S: 0000699

^ ^Laboratory Approval; -^y^________________ 07-Mar-oo

OT5BCW11 Page 19

U. S. Environmental Protection AgencyRegion 6 Houston Laboratory

Report For Sample Number OT5BCW1103

Source: MARION PRESSURE TREATINGSite Description: -,_

Date/Time Received: 1/31/2000 08:30 AM Date Completed 3/10/2000

Date/Time Collected: 1/27/2000 12:12 PM

Sample Type: LIQUID

Comments:

Parameter DescriptionABN ACID/BASE NEUTRALS

CN CYANIDE

EMHG ESAT-MERCORY

MAA GFAAS METALSMICP ICP METALSP/P PESTICIDES/POLYCHLORIKATED BIPHENYLS

VOA VOLATILE ORGANIC ANALYSIS

OT5BCW11 Page 20Volatile Organic Compounds

Method CLP SOW OLM03.2 (low level)

Sample Number OT5BCW11-03

Sample Type: LIQUID

Date Extracted: not extracted

Date Analyzed: 05-Feb-OO

Compound page 1 of 1Chloromethane——————————————————————————Bromomethane——— ——Vinyl Chloride—————————————————————Chloroethane————————————————————————————Methylene Chloride————————————————————————A^otnnft

Carbon Disuffide—————————————————————————11-Dichtoroethene——11-Dichloroethane———————————————————trans-1,2-Dichloroethene—————————————————————ds -1 2-Dichloroethene^l»lo»r<* «•—»Chloroform————————————————————————————

2-Butanone—————————————————————————————1.1,1-Trichloroethane———————————————————————Carbon Tetrachloride———————————————————————Bromodichloro me thane———————————————————————1,2-DichIoropropane————————————————————————ds-1,3-Dichloropropene———————————————————————Trich loroethene———————————————————————————Benzene—————————————————————————————Dibromochloromethane———————————————————————trans-1,3-Dichloropropene—————————————————————1,1,2-Tricnloroethane————————————————————————Brornofomn——————————•—————————————————4-Methyl-2-Pentanone———————————————————————2-Hexanone——————————————————————————————Tetrachloroethene————————————————————————11,2,2-Tetrachloroethane—————————————————————Toluene——————————————————————————————Chlorobenzene———————————————————————————Ethylbenzene———————————————————————————Styrene————;————————————————————————r\ v^flcmJfi —••

m/p-xylene—————————————————————————————

results (ug/l)NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND

- NDNDNDNDNDNDNDNDND

detection limits11112511111115111111111115511111111

"ND" means not detected at the corresponding detection limit.

OT5BCW11 Page 21Tentatively Identified Volatile Organic Compounds

Method CLP SOW OLM03.2 (low level)

Sample Number. OT5BCW11-03

Sample Type: LIQUID

Date Extracted: not extracted

Date Analyzed: 05-Feb-OO

Number TICs found:

TICNO. CAS NO. COMPOUND NAME*

RTmin.

EST.**CONC.

V9/1

• The compounds Bsted are tentatively identified by the best match w'rth the NtST/Wiley mass spectral databaseand/or by manual interpretation.

** An estimated concentration is obtained by quantitation using the nearest internal standard. Since no standardwas used for confirmation nor quantitation, a response factor of 1.0 is assumed.

OT5BCW11 Page 22

ORGANIC ANALYSIS DATA6MD-HO Sample OT5BCW11-03 Date Analyzed: 03-Feb-OO

Sample Type: Liquid

SEMI-VOLATILE COMPOUNDS BY METHOD 625(continuous extractor)

units: ug/L units > ug/L

1 Name

teid .................

cohol ...............

oroethyl) Ether .....

AylhexyllRitbalate ..

Eyiphthalate .........

3-Methylphenol ......

thalate .............

hthalate ............

| Results*

....... KDWD

....... SD

....... KD

....... KD

....... SDffr\

....... ND

....... ND

....... ND

....... ND

....... ND

....... ND

....... ND

....... ND

....... ND

....... ND

....... ND

....... ND

....... ND

....... ND

....... ND

....... ND

UT)

....... KDMT^

....... ND

....... ND

....... ND

....... NDMT1

....... MD

Del Limits

1aa

108

o.as884a2

a4B4a4

a488828333

106a62

Codipound Name

2,4-Dinitrophenol ...........

4,6-Dinitro-a-Methylphenol ..Di-n-Butylphthalate .........Di-n-Octyl Phthalate ........

2-Kethylnaphthalene .........2-Methylphenol ..............4-Methylphenol ..............Naphthalene .................2-Nitroaniline ..............3-Nitroaniline ..............4-Nitroaniline ..............

2-Nltrophenol ...............4-Nitrophenol ...............

Pentachlorophenol ...........

Pyrene ......................

| Results* |

......... ND

......... ND

......... ND

......... ND

......... ND

......... ND

......... ND

......... ND

......... ND

......... ND

......... NDMn

......... ND

......... ND

......... ND

......... ND

......... ND........ ND

unMTt

......... ND........ ND........ NO........ ND........ ND........ ND....'.... ND

......... ND........ ND........ ND........ ND........ ND........ ND

Del Limits

306fi

2024221

51038426628882

1013

461

243366

0 KD - Not detected above the listed detection limit.

Analyst Notes: none

(*) ND • Not detected above the listed detection limit.

OT5BCW11 Page 23

ORGANIC ANALYSIS DATA6MD-H Sample NO:OT5BCW11-03 Date Analyzed: 03-Feb-OO

Sample Type: Liquid

TENTATIVELY IDENTIFIED SEMI -VOLATILE COMPOUNDS BY METHOD 625unite: ug/L

EstimatedRT (min) CAS • COMPOUND NAME (*) Concentration (*•) |

16.6 638675 Tricosane 1„.-- „——.„——-—— -——.. . . . . . .„ .——.. . . - . - . . -„————.-——————.————„——.—— -.--——.——17.0 Onknown SC Paraffin a

17.5 Unknown SC Paraffin 1

I

I

(*) ANALYSTS NOTE: The compounda listed are tentatively identified by the best match with the NIST/EPA/oiley mass•pectral data base or by manual interpretation.

(**) Estimated concentration is based on a Response Factor of 1.0 to the nearest internal ctandard.

OT5BCW11 Page 24

PESTICIDE/PCB ANALYSISGUIDANCE METHOD; OLC02.1

SAMPLE:SAMPLE TYPE:

OT5BCW11-03LIQUID

DATE EXTRACTED: 2/2/2000DATE ANALYZED: 2/7/2000

CAS#

319-84-6319-85-7319-86-858-89-976-44-8309-00-21024-57-3949-98-860-57-172-55-972-20-833213-65-972-54-08742193-453494-70-510341-07-850-29-372-43-55103-71-95103-74-28001-35-212674-11-211104-28-211141-16-553469-21-912672-29-611097-69-111096-82-5

Alpha-BHCBeta-BHCDelta-BHCGamma-BHC (Lindane)HeptachlorAldrinHeptachlor EpoxideEndosulfan IDieldrin4,4' DDEEndrinEndosulfan II4,4' -DDDEndrin AldehydeEndrin KetoneEndosulfan Sulfate4,4' -DDTMethoxychlorAlpha-ChlordaneGamma- ChlordaneToxapheneAroclor1016Arodor 1221Aroclor 1232Arodor 1242Aroclor 1248Arodor 1254Aroclor 1260

RESULTSNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND

DL0.010.010.010.010.010.010.010.010.020.020.020.020.020.020.020.020.020.100.010.011.000.200.400.200.200.200.200.20

ND = NOT DETECTEDDL = DETECTION LIMIT

OT5BCW11 Page 25US EPA REGION 6 LABORATORY

SAMPLED

SOURCE:MATRIX

ANALYSTS:

PARAMETER

ALUMINUMANTIMONYARSENICBARIUMBERYLUUMCADMIUMCALCIUMCHROMIUMCOBALTCOPPERIRONLEADMAGNESIUMMANGANESEMERCURYNICKELPOTASSIUMSELENIUMSILVERSODIUMTHALLIUMVANADIUMZINC

OT5BCW11-03

MARION PRESSLLIQUID

KD. BB, SH

CONCENTRATION

NDNDND17NDND

1460NDNDND74ND

312NDNDND

14203.4ND

618000NDNDND

IRE TREATING

DETECTIONUMIT <=

1002.02.010

2.02.01502.02020252.0150

50.120

10002.010

5002.03020

DATES ANALYZED:14-FEB-OOT

UNITS

UG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/LUG/L

•O 17-FEB-OO

METHOD

200.7200.8200.8200.7200.8200.8200.7200.8200.7200.7200.7200.8200.7200.7245.1200.7200.7200.8200.7200.7200.8200.7200.7

ND: LESS THAN DETECTION LIMIT

TNRCC LaboratoryReport of AnalysisMar 07,2000 9:1 SAM

OT5BCW11 Page 26

TNRCC Sample «: 0000700 Group »: 20000224Matrix: LIQUID Depth;Collected: 1/27/00 0:00 Received: 02/01/00Program: Environmental Protection AgencyCollection Site: Marion Pressure Treating

Chain of CustodyStation ID:Collected by:

Region:

Constituent Name Result______Unit______Prepared____Analyzed______MethodCyanide, Total <0.02 mg/L 02/08/00 7:25 335.2

End of Data for TNRCC Sampled 0000700

Laboratory Approval:^^_________________ 07-Mar-oo

OT5BCW11 Page 27

U. S. Environmental Protection AgencyRegion 6 Houston Laboratory

Report For Sample Number OT5BCW1104

Source: MARION PRESSURE TREATINGSite Description: «,

Datemme Received: 1/31/2000 08:30 AM Date Completed 3/10/2000

Date/Time Collected: 1/27/2000 12:30 PM

Sample Type: LIQUID

Comments:

Parameter DescriptionVOA VOLATILE ORGANIC ANALYSIS

OT5BCW11 Page 28Volatile Organic Compounds

Method CLP SOW OLM03.2 (low level)

Sample Number OT5BCW11-04

Sample Type: LIQUID

Date Extracted: not extracted

Date Analyzed: 05-Feb-OO

Compound page 1 of 1Chloromethane———————————————————————————Bromomethane——————————————————————————Wnyl Chloride——————————————————————————Chloroethane———————————————————————————Methylene Chloride—————————————————————————Acetone——————————————————————————————Carbon Disulfide—————————————————————————Il.rv^hlrtmcifhr'n/ft—— •i

1,1-Dichloroethane—————————————————————————trans-1,2-Dichloroethene—————————————————————cis -1,2-Dichloroethene——————————————————————Chloroform————————————————————————————1,2-Dichtoroethane—————————————————————————2-Butanone—————————————————————————————1 11-Trichloroethane————————————————————————Carbon Tetrachloride———————————————————————Bromodichtoromethane————•—————————————————1,2-Oichloropropane————————————————————————cis-1,3-Dichloropropene——————————————————————

Benzene—————————————————————————————Dibromochloromethane———————————————————————trans-1,3-Dichloropropene—————————————————————1 1 OaTri hlftrr^rhthcii'iA———

Bromoform————————————————————————————4-Methyl-2-Pentanone———————————————————————2-Hexanone——————————————————————————————Tetrachloroethene—————————————————————————

Toluene—————————————————————————————Chlorobenzene——————————————————————————Ethylbenzene————————————————————————————Styrene—————————————————————————————

m/n-Yvlianp—————.—————————~——-—.—.—...—.————————

results (ug/1)NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDND

detection limits11112511111115111111111115511111111

"ND" means not detected at the corresponding detection limit

OT5BCW11 Page 29Tentatively Identified Volatile Organic Compounds

Method CLP SOW OLM03.2 (low level)

Sample Number OT5BCW11-04

Sample Type: LIQUID

Date Extracted:

Date Analyzed:

not extracted

05-Feb-OO

Number TICs found: 0

TICNO. CAS NO. COMPOUND NAME*

RTmin.

EST-CONC.

tig/l

* The compounds listed are tentatively identified by the best match w'rth the NIST/Wiley mass spectral databaseand/or by manual interpretation.

** An estimated concentration is obtained by quantitation using the nearest internal standard. Since no standardwas used for confirmation nor quantitation, a response factor of 1.0 is assumed.

OT5BCW11 Page 30

U. S. Environmental Protection AgencyRegion 6 Houston Laboratory

Report For Sample Number OT5BCW1105

Source: MARION PRESSURE TREATINGSite Description: -g

Date/Time Received: 1/31/2000 08:30 AM Date Completed 3/10/2000

Date/Time Collected: 1/27/2000 01:00 PM

Sample Type: LIQUID

Comments:

Parameter DescriptionVOA VOLATILE ORGANIC ANALYSIS

•?-

OT5BCW11 Page 31Volatile Organic Compounds

Method CLP SOW OLM03.2 (low level)

Sample Number OT5BCW11-05

Sample Type: LIQUID

Date Extracted: not extracted

Date Analyzed: 05-Feb-OO

Compound page 1 of 1Chtoromethane——————————————————————————Brornomethane——————————————————————————Vinyl Chloride——————————————————————————Chloroethane———————————————————————————Methylene Chloride—————————————————————————Acetone—————————————————————————————Carbon Disulfide—————————————————————————1,1 -Dichloroethene—————————————————————————1,1 -Dichloroethane—————————————————————————trans-1,2-Dichloroethene—————•——————————————cis -1,2-Dichloroethene———————————————————————^^« • »- -Chloroform—————————————————————————————1,2-Dichloroethane————————————————————————2-Butanone———————————————————————————1.1,1 -Trichloroethane———————————————————————Carbon Tetrachtoride———————————————————————Bromodichloromethane——————————————————————1,2-Dichtoropropane————————————————————————ds-1,3-Dichloropropene——————————————————————Trichloroethene———————————————————————————R&I^^AF*^ ^k^ • u — ^ — — — — — — k

Dibromochloromethane——————————————————:———trans-1.3-Dichloropropene—————————————————————1.1,2-Trichloroethane————————————————————————Bromofonn————————————————————————————4-Methyl-2-Pentanone——————————————————————2-Hexanone—————————————————————————————Tetrachloroethene————————————————————————1.1,2,2-Tetrachloroethane—————————————————————Toluene—————————————————————————————Chlorobenzene————"—————————————————————Ethylbenzene————————————————————————————Styrene——————————————————————————————

m/p-xylene—————————————————————————————

results (ug/l)NDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNDNONDNDNDNDNDNDNDNDND

- NDNDNDND

detection limits11112511111115111111111115511111111

"ND" means not detected at the corresponding detection limit

OT5BCW11 Page 32Tentatively Identified Volatile Organic Compounds

Method CLP SOW OLM03.2 (low level)

Sample Number. OT5BCW11-05

Sample Type: LIQUID

Date Extracted:

Date Analyzed:

not extracted

05-Feb-OO

Number TICs found: 0

TICNO. CAS NO. COMPOUND NAME*

RTmin.

EST."CONC.

PS/I

* The compounds listed are tentatively identified by the best match with the NIST/Wiley mass spectral databaseand/or by manual interpretation.

** An estimated concentration Is obtained by quantitation using the nearest internal standard. Since no standardwas used for confirmation nor quantitation, a response factor of 1.0 is assumed.-

OT5BCW11 Page 33

WATER VOLATILE SYSTEM MONITORING COMPOUND RECOVERY

Instrument ID:Set Number OT5BCW11

System 5-HP 5972

Method: CLPSOWO

Set Name: MARION PRES Column Info: 0.25 -HP-624

010203040506070809

EPASAMPLE NO.

OT5BCW11-BLKOT5BCW11-DLOT5BCW11-01OT5BCW11-01 MOT5BCW11-01 MOT5BCW11-02OT5BCW11-03OT5BCW11-04OT5BCW11-05

SMC1(DCE) «

10310398

10010197

10298

101

SMC2(TOL) H-

102106959999

1001009899

SMC3(BFB) #

1021069498

1011009798

101

TOTOUT

000000000

SMC1 (DCE)SMC2 (TOL)SMC3 (BFB)

1,2-Dichloroethane-d4Toluene-dSBromofluorobenzena

QC LIMITS(76-114)(88-110)(86-115)

ff Column to be used to flag recovery values* Values outside of contract required QC limitsD System Monitoring Compound diluted out

page 1 of 1

OT5BCW11 Page 34

WATER VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Set Name: MARION PRESSURE TRE Lab File: V50F0509.DMethod: CLPSOWOEPA Sample No.OTSBCW11-01

Set Number OT5BCW11Sample Type: LIQUID

COMPOUND1,1-DichloroetheneTrichloroetheneBenzeneTolueneChlorobenzene

SPIKEADDEDM)

5050505050

SAMPLECONCENTRATION

(ug/i)0.00.00.00.00.0

MSCONCENTRATION

W)5247504848

MS%

REC<1

10494

1009696

QCLIMITSREC.

61 - 14571 - 17076- 12776- 12575- 130

COMPOUND-1,1-DichloroetheneTrichloroetheneBenzeneTolueneChlorobenzene

SPIKEADDED

frig/I)5050505050

MSDCONCENTRATION

W)4746514948

MSD%

REC<?9492

1029896

%RPD#

102220

QCLRPD

14141 11313

IMITSREC.

61 - 14571 - 17076- 12776- 12575- 130

ft Column to be used to flag recovery and RPD values with an asterisk* Values outside of QC limitsRPD: 0 out of 5 outside limitsSpike Recovery: 0 out of 10 outside limitsCOMMENTS:

Lab Name:

Lab Code:

- 2CWATER SEM1VOLATILE SURROGATE RECOVERY

US EPA REGION 6 LABORATORY Contract:

OT5BCW11 Page 35

SiteNam Marion Pr SASNo.: Act.#: OTCW11

010203040506

Sample No.:OCW11-BLKOCW11-01OCW11-01MSOCW11-01MSDOCW11.02OCW11-03

S12FP #

696875657574

S2PHL #

716776677875

S32CP #

757282698079

S4DCB «

626371606868

S5NBZ #

827685708482

S6FBP#

867781698279

S7TBP #

848491808899

S8TPH #

898380708388

TOT •OUT

000000

81 2FP52 PHL53 2CP54 DCB55 NBZ56 FBP57 TBP58 TPH

QC LIMITS2-Fluorophenol (surrt) (30-106)Phenol-dS (surr2) (27-112)2-Chlorophenol-d4 (surr3) (39-105)1 -Dichlorobenzene-(14(sun4) (42-103)Nitrobenzene-dS (surr5) (29-121)2-Fluoroblphenyl (SUITS) (36-111)2,4,6-Tribromophenol (surr7) (29-129)(114-Terphenyl (surr8) (39-135)

# Column to be used to flag recovery values* Values outside of contract required QC limitsD Surrogate diluted out

page 1 of 1 FORM II SV-1 3/90

3C OT5BCW11 Page 36WATER SEMIVOLAT1LE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY

Lab Name:Lab Code:

US EPA REGION 6 LABORATORY Contract:SiteNam Marion Pr SASNo.: OTCW11 Act.#:

Matrix Spike- Sample No.: OCW11-01

COMPOUNDPhenol2-ChlorophenoI1,4-DichlorobenzeneN-Nitroso-di-propylamine1,2,4-Trichlorobenzene4-Chloro-3-methylphenolAcenaphthene4-Nitrophenol2,4-DinitrototuenePentachlorophenotPyrene

SPIKEADDED(ug/L)

1010

5.05.05.010

5.0105.0105.0

SAMPLECONCENTRATION

(ug/L)0.00.00.00.00.00.00.00.00.00.00.0

MSCONCENTRATION

(ug/L)6.37.22.82.83.17.13.46.13.57.74.0

MS%

REC#6372565662716861707780

QCLIMITSREC.

40- 9747- 9841 - 9426- 1 1 141 • 9932- 10941 - 10432- 13041 • 10640 - 13652- 122

COMPOUNDPhenol2-ChlorophenoI1,4-DichlorobenzeneN-Nitroso-di-propylamine1,2,4-Trichloroben2ene4-Chloro-3-methylphenolAcenaphthene4-Nitrophenol2,4-DinitrotoluenePentachloropheno!Pyrene

SPIKEADDED(ug/L)

10105.05.05.0105.0105.0105.0

MSDCONCENTRATION

(ug/L)5.66.12.42.42.86.22.95.63.17.03.4

MSD%

REC#5661484856625856627068

%RPD#

121715151014169

121016

QCLRPD

2926245025394333343022

IMITSREC.

40 - 9747 - 9841 - 9426 - 1 1 141 - 9932 - 10941 - 10432 - 13041 - 10640 - 13652 - 122

# Column to be used to flag recovery and RPD values with an asterisk• Values outside of QC limitsRPD: 0 out of 11 outside limitsSpike Recovery: 0 out of 22 outside limitsCOMMENTS:

FORM III SV-1 3/90

OT5BCW11 Page 37

PESTICIDE/PCB SURROGATE REPORTU.S. ENVIRONMENTAL PROTECTION AGENCY

HOUSTON LABORATORY BRANCH

INSTRUMENT: GC7 (HP-689<nCOLUMNS: DB-35MS COLUMNS: DB-5MSCOLUMN LENGTH: 30m COLUMN LENGTH (m): 30mCOLUMN ID: 0.32mm COLUMN ID (mm): 0.32mm

EPA SAMPLE NUMBER

OT5BCW11-BLKOT5BCW11-01MSOT5BCWI1-01MSDOT5BCW11-01OT5BCW11-02OT5BCW11-03

TCMX%REC

638081778380

DCB% REC

1029597919691

TCMXOut

000000

DCB Out

000000

Q.C. LIMITS-WATERWARNING 61-94 60-114ACTION 52-103 47-127

• a Values outside ofQC Kmlts

N.D. = CAN NOT DETECTED DUE TO INTERFERENCES

OT5BCW11 Page 38

WATER PESTICIDE MATRIX SPIKE / MATRIX SPIKE DUPLICATE REPORT

Lab Name: U.S. EPA Houston Lab6MD-HOLab Code:

Matrix Spike - EPA Sample No.:Date Extracted: 2/2/00Date Analyzed: __2/7/00

Case No.: __________OT5BCW11-01. 01MS, 01MSD

COMPOUND

LINDANEHEPTACHLORALDRINDIELDRINENDRINDDT

spike

(ug/ml)

0.05000.05000.05000.10000.10000.1000

concentration in• Sample

(rg/mi I000000

MSRECOVERY

( "9/ml 1

0.03670.03170.03730.07600.08460.0769

MS%

REC#

73.4%63.5%74.5%75.0%84.6%76.9%

QC.LimitsREC.

56-12340-13140-12052-12656-12138-127

COMPOUND

LINDANEHEPTACHLORALDRINDIELDRINENDRINDDT

spike

(yg/ml)

0.05000.05000.05000.10000.10000.1000

MSDRECOVERY

("gl0.03650.02960.0371

. 0.07390.08320.0826

MSD•/.

REC

73.0%59.2%74.2%73.9%83.2%82.6%

%RPDS

0.5%6.9%0.4%1.5%1.7%7.2%

QCLRPD

152022182127

JmttsREC.

56-12340-13140-12052-12656-12138-127

# = column to be used to flag recovery and RPD values with an asterisk

* e values outside of QC limits

OT5BCW11 Page 39Quality Control Report - Metals Laboratory

Site Name: MARION PRESSURE TREATINGSample«: OT5BCW1101

Date Received:. Date Reported:

31-Jan-OO25-Feb-OO

Quality Control for Sample Numbers: OT5BCW1101-03AQ (DWMCLS)

105%96°/o87%99%96%

Sb 123AS 75Be 9Cd 111Cr 52Pb 208Se 82Tl 205

Comments:

27533.530.534.533.637.033.836.8

27533.331.234.433.737.533.537.8

DLDLDLDLDLDLDLDL

0.00.62.30.30.31.30.92.7

0.92 104%95%95%101%102%102%98%99%

106%92% 1.43

105%

ALL SAMPLES AND SPIKES @ 1:4 DILUTIONAN ADDITIONAL 10 ug/l WAS ADDED TO THE SPIKE & SPIKE DUP

DL0 Detection Limits

Acceptable Percent Recovery Range = 75-125%Acceptable Relative Percent Difference = < 20

OT5BCW11 Page 40U.S. EPA Region 6 Laboratory

Quality Control Report - Metals Laboratory

Site Name: MARION PRESSURE TREATINGSample«: OT5BCW1101

Date Received:Date Reported:

QuaBty Control for Sample Numbers: OT5BCW1101-03 AQ HSL

31-Jan-OO25-Feb-OO

Comments: a) ANALYTICAL ADD ON OF DIGESTED PREP BLANK WAS 1 1 3 % FOR Cu

DL= Detection Limits

Acceptable Percent Recovery Range = 75-125%Acceptable Relative Percent Difference = < 20

2/15/00Data File:Method File:Sample Table

13:09CN021500CN

File: CN021500

Standard Set #1 OT5BCW11 Page 41

S2Concentration

Peak66 545836 109814 86097 52432 61750 0000

Value0.50000.25000.10000.05000.02000.0000

Calc0.49130.26410.10540.05070.0140-0.0055

Coefficients;Intercept :Slope :Std Dev :Corr Coef :R^2 :

-0.0055130.0074660.009614770.9989960.997994

\

——

» ^ -

\^ °

r V 0 '-»—.

-Q 0 QS^ r^-^ s- >. < X- ^ ^ V \M ^ T »

(<» 01

t»l 1

0 LJ 0

(0 M

M M

10 M

M M

M M

•-*

»-• »

-* »-•

•-t >

-•-1

-> >-

* »0

CD s

l CT 0

1 . W

M-K

Ul 4N

00 M

»-. 0

»0 CO

sl 0

> Ul

M M

l-» 0

<0 CO

sl 0

» in

10 M

»-* 0

CO 0

£; C

tB 0

"^10

» Qt O

t <?>

0^ 0»

0» W

0» 0

» 0» (M

/l 10

M M

l/l M

t0 0

•fl

t-*T

)13

^-^O

^D^O

^O^O

^D^O

^D^D

^O^D

^O^D

O^C

^JS0

^^1^

- 0

00

O

^OC

DN

lCM

n.t

-tO

M*-

**-1!-

^coco

i p

n 1 u

(OMO

- ^f

^ ?^?

ui

H^H

^V

SM

^^

,(S

s\^

?y'^

z -s ^

.

(0

(OM

•

•

•

0

00

0

00

0

00

0

00

•

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

00

0o

oo

o^

oo

o^

i-^

too

^o

oo

oo

oo

oo

oim

oo

oo

o^

to^

oo

^0

^4

SJ

SO

CO

G)O

tf?

»D

OO

»0

00

00

00

00

0(.

0(^

00

0»

-»m

OO

»»

00

'JlO

OO

NJlO

'slC

BO

»0»-,

<00»O

t-»00000000

0»

Os

l00

04

sO

Ul^

-KO

C>

>0

OC

Mn

^'s

ltO

CT

OC

OO

^^

sO

OO

OO

OO

OO

OO

W-'

OO

OO

sj^

t^O

OC

ftC

J

t'

.0'

O*

1

l^

-^

^M

rr

oN

N

N

N

NN

NN

NN

NW

s

,N M

N.M

A

MI

MM

M»-»

•-

11

-fW

O.

MQ

.M»^

I^M

»-(

»-»

»--

<»-i

^ \^

.»-IM

»-lyM

M t

fl M

t-IM

^^^^^^^

.^^

MIO

MM

lOM

tsllO

lOtO

tOlO

tOtO

MM

tJM

IOtO

MM

MM

MtO

MtO

tOM

t-*^

»-*»

-*»-*

tnO

lOl0

10l4

^^•4

^^^^

^^C

l)CO

Cl)C

JC>»

^)^)

^0^)

^)••

l•-tl^

•^^^

0000

01U

(U^U

lC^

VO 1

Ul 0

» »-•

<0

CO 0»

4^

0 CO

0» •P

* (0 0

CD Cf

t <'• M

0 CO

0^ t-

M 0

CO 0»

4s-(0

<0 CO

Cft

Min

in < n

cn cn

W 0

0 •-

• Oi >

-*•-

*»-0 0

0 0

0 0

0 0

0 0

o 0

0 >-

1 »-•

-•»-

• oi o

0 0

0fn

ft>n>

n<fT

»r»(

.»N.

|i •f

T>r•

^o<"

»»O

fn'•.

l<'I>

(/l<ll<

ll^'^

<l)^

ll(^'O

noo»

•M

» •<

T>o(

i»ch

io

w ftt 9 •O 1-' ft M 0) ^ »-• n> >-i f? t» »— »-• r: rt i— 0 y. £: (t ^~ O'l.

.y f+ 0 0 3 0 • •*! i-« &• Od u H S (li

C30>

?0

3 (6

0» 3

(I>h-

.<+r

t0>'

0fty

o» »

-o0)

0.

»<»!

" 0

.11(

0 (+

»—

l-k

Z^-C

T 0

0> A

&)

B "

art

(D

0> (T

>•«

ft

»•

a ••

B O

OtO

M(M

^Z

.-.

••>.

o»-*»

-1>-

bO

Oitn

SlO

O0

00

0

to ft a * 00

a ow

<^

•>•

« 1

M•• •• •*

00

0•

•

•

0»0<

DO

vD<0

»OCO

-sl

0»tD

U3•-*

»o<o

010»

4S

tt C» IW .<» •• >-* 0 1 a (D »1 0 H» •*! ^^

ft

,^*

0 0 •»

!(ft M

»1

KM

•• <

+

»-» U ft «• 1 0 « 0 s m lo

o3-1 acn

•* Q

O ?i 0-^

0 ^0

uin> (Q 0) ^

PRQJ.NO. j PROJECT N A M E ~ " ' " ] ] / / A./ / / / " '

^-^3 I /W; P/^(/^ Trec^ NO. ///^y//SAWLERS.CT< ./ n w / / r^f^y / /^^/^J^________ coN. A)/^^^ REMARKS

/ / - ^ 5 • . TA•NEBS /y/^y^^ /ST/^NO. DATE TIME § K STATION LOCATION /T^^^S^^^ /

•TTT'iSihW'J m-f\ar-^i'6i ^ysy\Y\)(w \/^/^i)^iMiwc. yw'^^I y Y^ttt_________^3~^M YMfT-^i^L-03 g- yZ^KZ _________g?-i i YMfT-Fe-o 'T^ -5 . ? ~^JJ^or jg^isoo y/w-TB-or 3. ^ J^Rio^

ReUdfluished by: «rMiucJ Date/Time Received by:/yig»wrur»/ Relinquished by: ^niww; Date/Time Received by: (S f»«n»/«;

^.^J^ lIPKAttw______________L______'ReKn^ttffwd b^rs/siutuMi Date /Time Received by: IStymwl Rclinqimhod by; {SifMiunf ' Date /Time Received by; tSiymurf)

Relinquished by: (SifimunI Date /Time Received foyLaboratpfy by: i Dite /Time Remarks_________ , I | ' >gfe ^^ , , ^SMppedby: ^e.^fey lAirbmNumbe / igy C l / &T ok

Dtetributlon; White Accompanies Shipment; Pink to Coordinator Field Fites;PDfl 7<?nn R^ Green to Report; Yettow Returns wtth Warrant _ -t -» Oft A

(11/961

ATTACHEMENTC

TETRA TECH FIELD LOG BOOK

^TW^S^l ^7ZW TES^ ^r^Lb ^ssooc.

^ c-syyo^^w (^PAWW 3Field Logbook No.___________Date I / •'•7/60 ' Field Logbook No._____________Dat»^!rM&——

| I | J | I | | | | | | T]——[ J | I j ( | 1 | | J I J I | | |2fflL-p^L_[J2tI-^i&|^^^tb^ ' J2!l^^i(ffiSa!0A^iC^»iiELp^^t^iefl-------^^^l^a^^^i^^ ^ fe^ f W y u^A^^^AGn^__^^J^^i^^^^^ , ___„.___„ —-^^____-_____^J^^^J^&^4^^ ^?7 - - A ^L A^^^^^^^^,-^.^i^^-^^-^ZZL^^A ^6-H _„_„____ ^^^-J——._-___iAAr^4]^[^^ -^^__3.r^^_ipz5^^^is^^^J^^^^ dg^A- ^L-Llr^^^^fiLA^^^--__^^J^^A^ .^LJL-S—CLi-LASA^lL——_-^te--^^1^ ^< .fi ylg-ljfl i \—___„_--_„_ | _______^L^f . ^ ^^^_ Ns,I^_________„_„_

_^^AAL^4^»4<^ 1 —''4-— ——-4_ —————z£L35a^£p.^^-^^^_^:______„___fe^Jdp^^ . - I C ^ ^ . - _ _ _ „ _ _ _^^11^^-4^^^^^^-^^—— -—i--'^^":— I | —-———^^^l^^Jal^^^ oy ^^igfl—_ — • 1 — P^^ I — — — — — ———^^-^Ir^^4i^ i — —————-^<;^_— ——__—_--B l-^Xe^S^^ ————————^^_————————^^^AJ^^J^eA^ULnJ\^Le^ , _ -___—————_—£.________——h:^J^^-^pJG_y^A-£[i—————— —————————-___—^____———Z^^—,^^._---—-L---————L- „——————_—^ ______JZ ^ l -L • ^"""—^^^^a.zzzi mmmm-sir| | | | | I r:__^.- . —-————-Y

4 (^yoAffffW c-^Wf^ 5Reld Logbook No. ___________Date //^/^—— ^ Reld Logbook No. ___________Date '/gt ^Ov

SSS—I&^—^L-^SACoI^I^i- • Z?LZc/!:^^JL^^ac^^CL-;^A^_-__^-nUL^Al^^-fc^^^^UQ--- ———-I^Lf ftl^i^J&^^.Jwdf'J^

1 1 ^ ^ , ^^ 6-f ?/fft,J^.^_ . JA^N^^——^^-^^--,—

_^-^-.L_^aU^LJ^^(J._fc^iL uS ^^-^Q^J'i/lc_^^_li^L-___hd^^.'a4^^^^^^^^^ —_-J^^i^U^JMflz-.________^JdiL^^L^ua.^J^ • 1^-^^^^^-^^^___0^^\L^^^^-J^J^J__ J/3? ^^^V^-JdLJL^^L^J^'___^d^^^_--— —___-—— .. 7/^-^^^^^-J^yJt lu^le^—^^-^^^-(LJJfi^^_^lr^{^._h^sJL JL^..^^/h;J(^JLxLjCjg^^^o,f^____^^^L!ri^^^;iLjL^ -^-g^^lffl.LtflJ:^7:————__^^^J^^^^^^^^-^L > //-^ y^^^^^^-J^gJL^d:^^:—^_J^^^-i!ii3L- iL^^_ --^I^^^-i'- l ^^ca.iJ^__JXj-4^^^^^ . — ^ ji^i^^^^:--------_^J^-4^?^^4s-——----TT-—-—-- —— yA^ ^,/!iQdgJL-^-<JiU^-tf-Ji,.cL<^-^•^r ^^^ H)U ^o, fc^r^ ZFAJi^L-Ai^^sLJEl^^-

1 |/^LiJ^l4^J^^--._-__ • ^^--^/KaJ^^_____—_| . , —____—— __>gc»ktJ'n<J Kfad^—___, | _ _^J:^^J^JSl:^^^__ , ^iq ftm^^fft^^^^^^7A^^^^-4.^^-1</^---- ^f7' }\^ -^j;^ |.AJf^^^(;.4_JA^4-^}k ^>J3j^___-__- lip ^cF^'T^^llps| P)^^, f^^ tofl/ ^^/^/a)[ • |1J( p^^ ^•M^\c\fo^^^wi^^^^ :.: ^^^^^_^ S IpO^%3S?z^^

e GffyOA^W wyo/\^si^ ^

Reld Logbook No.___________nafo //J-7^^ 1 Field Logbook No.___________DateJAS^6— !

S^L^^e^^-^^^iAe.-^^^^L--- Z?[I _^^<-h</ ,J/A£-.^ fJ li - ---^;7^^1^^^^^ ^.OLE4^JUA^^LL__-1^^toi^^^^^^h^ , ^__4———^——-i——i~-^ ^i^^ffc 7J' / , ^<4^ i ^ l/g,/L ^L: .J|AJL^ AAb^-^- >-j-AL^fl^^ 4^;7^^ v n__^__pZpC-c^^^l2&Z^fcL^4-^^te^^^M ^^/^V^^^ $'rM ^_ HAJL „^„I^-„_rt„„_„„._._ ^4l___^dL^^^A^J^^^^_s^^^ | I T. M l ^ l"^ ^>J^^^^^^Ji^^l^Lfid--^^_._ . _ . _^ ____._' . ^Jl4'- ^1— LH£ K*^ •^L^^^^^c^.. | | I ^4- 13-1^^-1— '_lb<LJ^^q <:rM A^i ^^^l^aSK^^F^J—^^iL^^4^J^^^^ Ak^ I | | Q'^/fCl- 4 ||"^A(r _ ,—.-^^.^:^^U__________ ^:a_^___L^U-!l^ 1*3^^fc^^^^.^ _ 'T—^~ ___g^_| |_IIg_^^-^_^^^^A^^^^d-^_ __„_4_T_„ t^c| J_J^LI--'^^^^x.^^ ^^4 ^•^^^W 7 •^^^^^^^£4^^A^ ^2n___niJ^4^--^^^^JU^^UJ_,__T_ t^<L _-_—__ TfW5 IL -^=£L- ^'3'^:^-—l:„r-__„„_Ir _^^__JZ^aJi^±i^^i-—^^^rri_<_--______._____ ^^JteJEfl ---———^^———— • i | r | „-—————^^^-4..-___:_ Tr!i,t_^CL^O^L-^/C_3---a^---

^<^>, ,

I I I I I I I I I In^J l 1 1 1 - 1 i i I I I I Id^<toL I N 1 "