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    This article appeared in a journal published by Elsevier. The attached

    copy is furnished to the author for internal non-commercial research

    and education use, including for instruction at the authors institution

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    A particle population balancing model for a circulating fluidized bed

    combustion system

    K. Redemann, E.-U. Hartge, Joachim Werther

    Institute of Solids Process Engineering and Particle Technology, Hamburg University of Technology, Denickestr. 15, D-21071 Hamburg, Germany

    a b s t r a c ta r t i c l e i n f o

    Article history:

    Received 4 September 2007

    Received in revised form 15 August 2008

    Accepted 23 September 2008

    Available online 1 October 2008

    Keywords:

    Particle population balance

    Circulating fluidized bed

    Fluid dynamics

    Refuse derived fuel

    A dynamic simulation model of the particle population in a circulating fluidized bed combustor with external

    heat exchanger has been developed. It considers the fluid dynamic processes in the various parts of the

    system, as well as the particle attrition. To handle multiple solids types simultaneously and to fulfill the mass

    balances, some of the fluid dynamic sub-models taken from the literature were modified. The model allows

    to calculate the solids mass flows as well as the corresponding particle size distributions at any point inside

    the combustion system.

    The model has been applied to the combustion plant of Stadtwerke Neumnster in Germany, which operates

    on refuse-derived fuel. The particle balancing model provides new insights into the operating behavior of

    such a system. In particular, the calculation of the residence time of different particle classes in the system

    reveals a very broad distribution of size dependent average residence times, ranging from several minutes to

    a maximum of roughly 40 h. A size fraction exists between 100 and 300 m with a maximum average

    residence time of about 40 h. The Preprint submitted to Elsevier Science 15 August 2008 simulation provides

    a means for examining possibilities to control the particle size distribution in the combustion system. It is

    shown how a recirculation of a fine ash fraction can be used to control the bed particle size distribution in the

    combustion chamber.

    2008 Elsevier B.V. All rights reserved.

    1. Introduction

    A key parameter for the proper operation of a circulating fluidized

    bed combustor (CFBC) is the particle size distribution (PSD) of the bed

    inventory.

    It governs e.g. the solids circulation rate and with it the heat

    transport from the combustion chamber into the external heat

    exchanger. The particle population results from the PSDs and mass

    flows of the solids fed into the system and reaction, classification,

    transport and comminution processes occurring in the plant.

    Improper operating conditions or imperfect plant components cancause serious problems in the plant operation.

    For example, the separation behavior of the cyclone, which is

    attached to the combustion chamber, is a major issue. A properly

    designed cyclone should be able to keep a given mass of solids with a

    predetermined particle size distribution in the cycle. If the loss of

    material through the cyclone is too high and if the input of fresh ash

    for example in the case of a coal with a low content of ash is too

    small, it may be necessary to continuously add new bed material, in

    order to keep the mass of solids in the inventory. Respective operating

    experience exists with Rheinbraun [1].

    It is thereforedesirable to have a properly designed cyclone,whose

    design is considering the special operating conditions in CFB

    operation, i.e. the high solids loading at the inlet. Comprehensive

    work on the design of cyclones under these conditions, which was

    mainly focused on the inlet design and the formation and flow of the

    strand formed there, has been carried out by Muschelknautz and his

    group at the University Stuttgart (e.g. [24]) and by Reh and his co-

    workers at ETH Zrich (e.g. [5,6]). Their results have found a striking

    confirmation by the experience made by Alstom in their Zeran project

    [7]. The Zeran A boiler in Warsaw, Poland, a 450 t/h CFB steam

    generator, was commissioned in 1995. At that time it was the largestCFB boiler in Poland and the first to operate on Polish hardcoal. Due to

    the high debris rock content in the ash it turned out to be difficult to

    achieve the proper particle size distribution of the circulating ash. The

    cyclones were not able to prevent the loss offine inert material. When

    the order for the boiler B of Zeran was placed in 1998, it was built

    almost identical to boiler A, with the exception of the cyclone design.

    In order to improve the separation efficiency the arrangement of the

    cyclone's inlet ducts with respect to the furnace was optimized, the

    inlet ducts were prolonged and inclined downward, the vertical

    velocity in the cyclone was decreased and eccentric vortex finders

    were installed.

    The new design turned out to be extremely efficient: the 50% value

    of the cumulative mass distribution of the circulating particles went

    down from 180 m for boiler A to 75 m for boiler B. The increased

    Powder Technology 191 (2009) 7890

    Corresponding author. Tel.: +49 40 42878 3239; fax: +49 40 42878 2678.

    0032-5910/$ see front matter 2008 Elsevier B.V. All rights reserved.

    doi:10.1016/j.powtec.2008.09.009

    Contents lists available at ScienceDirect

    Powder Technology

    j o u r n a l h o m e p a g e : w w w. e l s e v i e r. c o m / l o c a t e / p o w t e c

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    cyclone efficiency and the thus realized finer inventory of the system

    had several beneficial effects, including an increased overall heat

    transfer coefficient, which allowed to reduce theinventoryand thus to

    lower power consumption. Furthermore limestone utilization was

    improved and even the NOx and CO emissions were reduced.

    It is interesting to note in this context that the same experience

    with regard to the significance of the cyclone design was made over10 years before in Germany [8]. Two 105 MWth CFB boilers were built

    for Bayer AG on their Leverkusen site. Thefirst one was commissioned

    in 1988, thesecond onein 1991. Duringoperation (both units operated

    on the same coal) it turned out that in the second unit the combustion

    efficiency was lower, the Ca/S ratio was twice as high, the dp,50 of the

    recirculating ash was 170 m instead of 150 m and the fly ash had a

    dp,50 of 80 m compared to 30 m in the first unit. A detailed analysis

    brought the result that the cyclone design had been changed

    unintentionally, i.e. the diameter of the vortex finder had been

    increasedby 14% anda designchange of thevortexfinder's suspension

    enabled a short-circuiting flow to take place.

    The PSD of the bed inventory results from the fluid dynamic

    processes in the different plant components, the ash formation

    behavior of the fuel and additionally fed solids, e.g. additional inertsolids, limestone or recycled bed material. A mathematical simulation

    tool considering these effects can be used to predict the PSDs in the

    different parts of a circulating fluidized bed under various operating

    conditions. It can also be used to survey and judge the impact of

    changes in theoperation of a plant or in thecharacteristicsof theinput

    fuel on the resulting particle size distributions.

    In the present work a mathematical model based on particle

    population balances is developed, which considers the circulating

    fluidized bed combustion system as separate modules. Mathematical

    descriptions were, as far as possible, taken from the literature.

    However, in some cases available descriptions had to be modified in

    order to fulfill the requirements of particle population balancing. The

    resulting model represents a dynamical description of the system

    behavior, which also allows conclusions about the residence time of

    individual size fractions in the system to be drawn.

    The model is first applied to the simulation of the refuse-derived

    fuel fired circulating fluidized bed combustor of Stadtwerke Neumn-

    ster GmbH in Neumnster in north Germany. Its schematic layout is

    shown in Fig. 1. Refuse-derived fuel (RDF) is fed into the combustion

    chamber. Fly ash is leaving via the cyclone overflow and is collected in

    the heat recovery boiler and the multi-cyclone. Finally small quantities

    of ultra fine ash are passing into the flue gas treatment section.Since the ash particle size distribution which is produced by the

    refuse-derived fuel cannot be easily predicted, the plant contains two

    means for influencing the PSD of the bed inventory. The one is the

    addition of sand, which was also used for starting the facility. The

    second means is the recirculation offine ash, obtained after sieving of

    the bottom ash offtake.

    In the framework of a research project initiated by Stadtwerke

    Neumnster, measurement campaigns were carried out where solids

    mass flows and solids particle size distributions were measured at

    different locations at the plant. Additional lab scale investigations

    formed the basis for the development of the particle population

    balances presented here. Since the experimental facts were decisive

    for the design of the model, they will be presented below before the

    description of the theory.

    2. Experimental

    2.1. Measurements at the Neumnster plant

    In general measurements of solids mass flows and solids particle

    size distributions in an industrial plant arequite difficult. Theaccess to

    the various parts of such a complex system is not easy, safety

    precautions have to be taken and above all, the refuse-derivedfuel is a

    matter which is very difficult to characterize.

    Solids mass flows were determined on larger time intervals by

    counting the number and loading of trucks which transported the

    ashes to a disposal site. This was done for the coarse bottom ash, the

    fine bottom ash, the fly ash (sum of ashes taken from the radiation

    boiler, convection boiler and the multi-cyclone). The sand supply was

    Fig. 1. Flowsheet of a circulating fluidized bed combustion system (Neumnster plant).

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    also measured. It is admitted that all flows necessarily contain sand

    particles as well, so all ash streams are in reality mixtures of fuel ash

    and sand. However, for simplicity these streams are still called ashhere. The mass flow of the ultra-fine ash was calculated from

    information about the lime and activated coke fed to the flue gas

    cleaning andabout the solidswithdrawn from theflue gas cleaning for

    disposal. From these information the ash input with the refuse-

    derived fuel could be calculated.

    With regard to the solids particle size distributions samples were

    taken of the coarse bottom ash, the fine bottom ash, the fly ash

    (mixture offly ashes taken from the different sources) and from the

    sand. The solids samples were analyzed by sieving and a laser

    diffractometer (Beckman-Coulter LS 13 320). No sample could be

    taken from the ultra-fine ash. For this latter material the correspond-

    ing particle size distribution was estimated by calculating the

    separation efficiency of the multi-cyclone for the given fly ash. Fig. 2

    shows the particle size distributions of different samples and Table 1presents the measured solids mass flows.

    2.2. Measurement of the attrition characteristics of the refuse-derived

    fuel ash

    The RDF which is used in the Neumnster plant is produced by

    mechanical and biological processing of the municipal waste from

    the north German region around Neumnster. The processing plant

    has a total capacity of 210,000 t/h of household waste. It produces

    103,000 t/h refuse-derived fuel. The processing results in an increase

    of the calorific value of 9 MJ/kg for the original waste to 14.5 MJ/kg of

    the RDF. The RDF itself is very difficult to characterize.

    It contains pieces of wood and organic matter, as well as sheets of

    paper and plastics. The

    particles

    have a maximum dimension ofroughly 10 cm. According to the concept of the primary ash particle

    size distribution (PAPSD) suggested by Salatino and co-workers [9,10],

    devolatilization and combustion of a solid fuel leads to an ash particle

    size distribution, i.e. the PAPSD, which will during its further residence

    time in the combustion chamber undergo fragmentation and attrition.

    For population balancing purposes it is necessary to follow the

    changes of particle sizes inside the combustion system. In previouswork on the modeling offluid bed catalytic reactors [11] and coal and

    sludge combustion in the fluidized bed [12], the authors' group has

    developed a tool for the description of attrition processes. In order to

    apply the same tools to the RDF combustion problem, samples of the

    original RDF were exposed for a short time to combustion conditions

    in a fluidized bed in order to create an ash sample, which could then

    be further used.

    Fig. 3 gives an example of sucha distribution. Of course this is not a

    real PAPSD in the sense of its definition, because it has already

    undergone some stress in the fluidized bed due to the finite residence

    time under combustion conditions. However, the material is well

    suited for attrition experiments.

    Following the distinction of the three attrition mechanisms [13]:

    in-bed attrition by solids movement, induced by bubbles in-bed attrition, induced by distributor jet action

    attrition during the passage through a cyclone

    the attrition characteristicswere determinedin specialized testfacilities,

    which have been described elsewhere [13].

    Fig. 4 shows two sets of data for the bubble induced attrition. The

    attrition rate r in kg of fines produced per kg of bed material and

    second is plotted against the time. It is remarkable that contrary to

    what was observed with catalyst and coal ashes [13] no constant

    attrition rate is obtained after a certain time of operation. Obviously,

    due to the structure of the RDF ash no steady-state attrition rate is

    reached. On the contrary, the particles are continuously breaking

    down and even after 1500 h of attrition no plateau is reached.

    Fig. 2. Measured particle size distribution of ashes leaving the plant and of the feed

    sand.

    Table 1

    Measured solids mass flows and calculated feed mass flow of attrited ash at the

    Neumnster plant

    Solids stream Mass flow

    [kg/h]

    Ultra fine ash 481

    Fly ash 1778

    Fine ash 1508

    Coarse ash 1390Sand 373

    Feed of attrited ash 4786

    Fig. 3. Measured PAPSD originating from laboratory scale fluidized bed combustion.

    Fig. 4. Results for bubble induced attrition experiments with two different ash samples,

    operated at a superficial velocity of u =0.5 m/s, plotted against the operating time.

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    In Fig. 5 the attrition rate r is plotted against the relative material

    loss matt/ mb0, where matt denotes the cumulative attrited mass and

    mb0 is the initial bed solids mass. Both experiments can beapproximated by straight lines on the semi-logarithmic grid,

    r a exp b mattmb0

    & ': 1

    The different slopes are probably due to the fact that both ashes

    originate from different RDF samples.

    Fig. 6 shows in its upper half the time-dependent attrition rate in

    kg of attrited material produced per time unit for the jet attrition test,

    as a function of time. Again, no steady state of attrition is reached. In

    the lower half the attrition rate is plotted against the relative material

    loss matt/mb0. Fig. 7 shows the results of the cyclone attrition test for

    two different samples operated under different conditions. Here also,

    no steady state attrition is reached.

    3. Theory

    3.1. The particle population balancing model

    Although Fig. 1 presents a special design of a circulating fluidized

    bed combustion system the model, which is presented here, can be

    applied to any other circulating fluidized bed combustor design. The

    aim of the mathematical model is to track the particle population in

    the bed inventory of a CFBC. The software tool calculates the physical

    processes in a dynamic-sequential simulation with a pipe-and-filter

    architecture [14].

    The simulation model divides the CFB system into modules, each

    representing an apparatus of the plant. The combustion chamber is

    separated into two sub-modules, the dense bottom zone and the

    upper dilute zone. The calculation of transport, classification and

    comminution of the solids in the different parts of the plant isperformed in these modules. They are calculated sequentially in the

    order the solids are passing them. An overview of the whole model

    setup is given in Fig. 8.

    Although a lot of more sophisticated models are available for the

    description of the fluid mechanics of circulating fluidized beds (e.g.

    [15]) a very simple approach is followed here, where the circulating

    fluidized bed is modeled as a bubbling fluidized bed, operated at high

    gas velocities with a correspondingly high solids elutriation. Therefore

    above a dense bottom zone which contains the bubblingfluidized bed

    and where the accumulation of solids is considered, we have a

    freeboard section with solids transport and segregation with height.

    In the cyclone the separation is considered and transport in the

    return leg. The external heat exchanger is treated simply as a stirred

    Fig. 5. Results for bubble induced attrition experiments for with different ash samples,

    operatedat a superficial velocityofu =0.5 m/s, plotted against therelative mass loss due

    to attrition.

    Fig. 6. Resultsfor jetattritionexperiments, operated at a superficialvelocityofu=0.5 m/s,

    jet velocity ofuj=50 m/s, nozzle diameter do=1 mm, ds=189 m plotted against time and

    against the relative mass loss due to attrition.

    Fig. 7. Results for cyclone attrition experiments for with different ash samples, operated

    at different operating conditions (cyclone diameter: 90 mm, further details cf. [31]).

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    tank with regard to the solids. Accumulation is taken into account, butno entrainment with the fluidizing gas. The entrainment may be

    neglected, since entrained fines are fed again to the combustion

    chamber together with the off-gas from the EHE.

    The devolatilization and combustion times of the fuel particles are

    in the order of seconds to minutes [16]. On the other hand the

    residence times of ash particles in the system are of the order of

    minutes to hours, as will be shown below. Therefore as a means of

    simplification the combustion is placed outside the combustion

    chamber and only ash with its primary ash particle size distribution

    (PAPSD) is entering into the combustion chamber. The ash particles

    are then undergoing bubble-induced attrition and jet attrition in both,

    the dense bottomzone of the combustion chamber andin the external

    heat exchanger. Furthermore attrition is occurring in the cyclone.

    In CFBCs various solid types, e.g. fuel ash, sorbent material or

    additional inert material, are present. These solids have different

    physical properties, e.g. densities and particle sizes, which are

    influencing the particle behavior in the fluidized bed system. Another

    important parameter is the stress history of the particles (e.g. [11,12]).

    In order to map all of these effects, the model treats particles of

    different size, solid type andstress history separately. For that purpose

    the bed inventory is discretized into a three dimensional matrix,

    which contains classes of particles with the same combination of the

    three characteristic properties, mentioned above. As proposed by

    Scarlett [17], the matrix entries contain the masses in the respective

    particle classes. All other characteristic values, e.g. the Sauter diameter

    and the minimum fluidizing velocity are derived from that matrix.

    3.1.1. Modeling of the combustion chamber

    The combustion chamber module is divided into two sub-modules,the dense bottom zone and the upper dilute zone. The dense bottom

    zone is modeled as a bubbling fluidized bed with an approach

    according to Werther and Wein [18] and the upper dilute zone is

    described according to Kunii and Levenspiel [19]. Both sub-modules

    calculate the vertical solids volume profile. Solids are elutriated from

    the dense bottom zone into the upper dilute zone, whereby the

    masses of the particles classes in the upper dilute zone result from the

    PSD in thedensebottom zone. Thetask of combustion chamber model

    is to find the mass and PSD in the dense bottom zone with which the

    mass balance in the total combustion chamber if fulfilled. This is

    achieved in an iterative calculation process.

    3.1.1.1. Modeling the dense bottom zone. The Werther and Wein

    model [18] was used to calculate the vertical profile of the solidsvolume concentration in the dense bottom zone. To handle conical

    shapes of the combustion chamber, thewideningof the cross-sectional

    area with height is considered forthe calculation of themasses andthe

    pressure drop in the dense bottom zone.

    From the overall solids volume concentration cv at height h above

    the gas distributor and the height of a suspension layer h, the solid

    mass of the layer m can be calculated by

    m A h s cv h h 2

    where s is the solid and A(h) the cross-sectional area of the dense

    bottom zone at the height h.

    The pressure drop pb of the dense bottom zone can be calculated

    from

    pb sZhb

    0

    A h cv h dh 3

    where hb denotes the height of the dense bottom zone.

    3.1.1.2. Elutriation into the upper dilute zone. The mass elutriated

    from the particle fraction i into the freeboard per time unit is given by

    :mi

    K4i

    Q3;i

    A

    4

    where Q3,i is the mass fraction in the dense bottom zone and A the

    cross-sectional area of the combustion chamber at the height hb above

    the distributor. The elutriation constant Ki is a key parameter for the

    modeling of the upper dilute zone. A correlation for Ki was developed

    by Colakyan and Levenspiel [20] for gas-particle systems at operating

    conditions comparable to the conditions found in CFBCs. Unfortu-

    nately, this elutriation model assumes that particles with a terminal

    velocity ut exceeding the superficial velocity u cannot be elutriated.

    The measurements taken in the Neumnster plant, which will be

    described later on, have shown that this is not the case in a circulating

    fluidized bed. We have found a considerable amountof particlesin the

    external heat exchanger ash with sizes corresponding to terminal

    velocities exceeding the operating gas velocity in the upper dilute

    zone of the combustion chamber. Therefore a correction factor fKwithvalues between 0 and 1 was introduced into the Colakyan and

    Levenspiel correlation,

    K4i 0:011 s 1ut;i fK

    u

    2for ut;i fKb u

    K4i 0 for ut;i fKz u5

    where the solids density s is to be inserted in kg/m3. ut,i is the

    terminal velocity of the particle class i. The effect of the factor fk is

    shown in Fig. 9. The factor shifts the curve of the elutriation rate to the

    right, towards higher terminal velocities. It follows for the solids

    Fig. 8. General model layout.

    Fig. 9. Elutriation rate calculated from the modified Colakyan and Levenspiel [20]

    model, Eq. (5), for various values of fk (calculated with s=2350 kg/m3).

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    concentration above the transport disengaging height (TDH) which is

    due to the particle class i

    c4V;i K4i

    s u ut;i fK : 6

    The vertical solids volume profile in the upper dilute zone is

    describedby the exponential decayapproach (Kunii and Levenspiel [19]),

    cv h V c4v cvdc4v

    eh V 7

    where cvd isthe solidsvolume concentration at thesurfaceof thebed and

    cv(h) the solids concentration at the height h above the dense bottom

    zone. The decay constant is obtained from Kunii and Levenspiel [19],

    u8

    8

    :

    me;i cvi hf u ut;i fK s 9where hf is the distance between the surface of the dense bottom zone

    and the middle of the inlet duct into the gas cyclone.

    3.1.2. Modeling of the gas cyclone

    For the calculation of the solids separation in the gas cyclone the

    model of Muschelknautz [21], with themodifications by Muschelknautz

    and Trefz [22] has been taken as a basis. In this model the separation

    mechanismin the cyclone is divided into twoparts.At first, immediately

    near the inlet that part of thesolids loadinge, which exceeds a limiting

    valueg is forming a strand, whichflowsdirectly into theunderflow.The

    remaining part of the solids is undergoing the separation in the vortex.

    Both mechanisms are described by semi-empirical correlations, which

    arebased on a large numberof measurements, including measurements

    at large-scale industrial cyclones.Unfortunately,the Muschelknautz model doesnot fulfill the fractional

    solidsmass balances forthe calculationof thestrand separation, which is

    a crucial point fora particlepopulation balancingmodel. Also mixtures of

    solids with different densities and particle size distributions have to be

    considered in the present application. Therefore the Muschelknautz

    model had to be modified.

    3.1.2.1. Modeling the strand separation. Under the conditions prevail-

    ing in circulating fluidized bed combustors the solids loading e at thecyclone inlet exceeds the loading limitg by far [6]. Therefore the strand

    separation is responsible for most of the cyclone's separation efficiency.

    Theparticleattribute which is decisive forthe separation in a gascyclone

    isnot its sizebut rather its terminalvelocity. In order to beableto handle

    mixtures of solids of different sizes and densities the terminal velocity is

    chosen here as the quantity which unambiguously characterizes a given

    particle with respect to its separation in the cyclone. The particle size

    distributions of mixtures of solids of different densities are therefore

    converted into a single distribution of terminal velocities ut.

    Particles with a probability of 50% to be separated in the strand

    have according to [21] a terminal velocity of

    ws;50

    0:5 0:9

    :Ve

    Aw 10

    where Ve is the inlet gas volumeflowandAw is the sedimentation area

    of the strand, defined in [21].

    The loading limit g can by calculated from

    g Kg4ffiffiffiffiffiffiffiffiffiffiffiffi

    ws;50ut;50;e

    s 10e k 11

    The exponent k in Eq. (11) can be calculated by

    k 0:15 0:66 exp e0:015

    0:6 !12

    ut,50,e is the50% valueof the terminalvelocity distributionof the solids

    mixture entering the cyclone.In the original Muschelknautz model [21] the particle size

    distribution of the solids going into the inner vortex is described by

    Fig.10. Comparisonof theinner feedPSDs and separation efficiency curves calculated fromthe Muschelknautzand thenew model forthe strand separation in a laboratory cyclone(a,

    b) and the large cyclone of the Neumnster plant (case c).

    83K. Redemann et al. / Powder Technology 191 (2009) 7890

    where u is to be inserted in [m/s]. The mass flow in the particle class

    i (me,i) leaving the combustion chamber can be calculated with the

    particle slip velocity

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    a RRSB distribution. The assumption of this distribution leads to a

    violation of the mass balance, because the RRSB distribution implies

    the presence of particle sizes which need not exist in reality. To

    circumvent this problem, the assumption of the RRSB distribution for

    the inner feed material hasbeen replaced here by modeling the strand

    separation with a separation efficiency function.

    The mean terminal velocity of the particles entering the inner

    vortex, ut,50,v is then in analogy to [22] calculated from

    ut;50;v ut;50;e for e Vgut;50;v ffiffiffiffiffiffiffiffiffiffiffiffiut;50;ep ffiffiffiffiffiffiffiffiffiffiffiffiut;50;ep ffiffiffiffiffiffiffiffiffiffiffiws;50p 1g=e

    0:75

    2for g be V 4 g

    ut;50;v ws;50 for e N 4 g

    :

    13

    Using this terminal velocity the function for the strand separation

    efficiency can be set up in analogy to the approach by Rogers [23],

    T ut 1a T4 ut a 14

    with

    T4 ut

    1

    1 ffiffiffiffiffiffiffiffiffi

    ut;50;vut

    q exp 1

    ffiffiffiffiffiffiffiffiffiut

    ut;50;v

    q3

    !& ' ; 0 V T4 V 1 15where is the separation sharpness and a is an offset value.

    The total solids mass flow m v into the vortex, the so-called inner

    feed is prescribed by the solids loading limit g of the gas and its mass

    flow. To comply with the loading limit, the inner feed is fitted by

    means of the offset value a in Eq. (14). It adjusts the mass flow of the

    solids going to the inner vortex, but leaves the PSD of this material

    unchanged. It is calculated by

    a i T4 ut;i :me;ig 0:9 :Ve s

    i

    T4 ut;i :me;i : 16

    There are cases possible, where the total mass in the particleclasses with T(ut)b1 is too small to fulfill the required loading limit.

    This will then lead to negative values of a with Eq. (16). For these

    exceptional cases, the directive given in Eq. (13) is neglected and the

    mean terminal velocity ut,50,v is raised until the loading limit is

    fulfilled with an offset of a = 0.

    The mass flow m v, i of a particle class i entering the inner vortex is

    calculated from the massflow of theparticleclass entering thecyclone

    m e,i, multiplied with the corresponding separation efficiency.

    :mv;i 1T ut;i

    :me;i: 17To estimate the impact of the changes made to the strand

    separation model, three different cases were calculated with the

    original model given in [21] and with the new model discussed above.

    In Fig. 10 the results are compared.

    In cases A and B laboratory cyclones were simulated with two

    different feedparticle sizedistributions at the sameloadinglimite=0.05.

    The geometry of the cyclone and the operating conditions are given

    together with the calculation parameters values in Table 2. In case C a

    large-scale cyclone with the dimensions and operating conditions of the

    Neumnster plant has been chosen. Its dimensions and operating data

    are also listed inTable 2. The most significant distinction between cases A

    and B on the one side and case C on the other side is the high solidsloading ofg=8 in the latter case.

    In addition to theinlet PSDs and thecalculated inner feed PSDs, the

    separation efficiency curves according to the original model and the

    new model are depicted in Fig. 10. The separation efficiency of the

    original model [21] has been calculated from the ratio of the predicted

    inner feed PSD to the corresponding mass fraction in the cyclone inlet.

    In all cases the separation sharpness used in Eq. (15) was = 0.05. The

    offset a has been calculated from Eq. (16).

    It can be taken from Fig. 10 that the separation efficiency curves

    calculated with the present model are practically identical with those

    derived from the Muschelknautz model. The advantage of the present

    model is that it does not violate the fractional mass balances and

    therefore can be used for population balancing.

    3.1.2.2. The separation in the inner vortex. The particle diameter dv

    with force equilibrium on the radius with the maximum vortex

    velocity can be calculated according to [21]

    d4v ffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi

    18L0:9:Ve

    sg

    u2i 2hi

    vuut 18

    where Ve is the volumetric gas flow entering the cyclone, L the

    dynamic viscosity of the gas, g and s the densities of gas and solids,

    respectively, hi is the distance between the vortex finder and the apex

    and ui the maximum tangential gas velocity. According to Eq. (18)

    Table 2

    Cyclone dimensions, suspension and model parameters and intermediate results of the

    strand separation calculation for three different cyclone arrangements, carried out with

    the Muschelknautz [21] and the present model

    Parameter Unit Cases

    A B C

    Cyclonedimensions

    Inlet width [mm] 13 13 1890Inlet height [mm] 37 37 4240

    Outer diameter [mm] 90 90 6020

    Total height [mm] 140 140 14710

    Cylinder height [mm] 42 42 6464

    Vortex finder dia. [mm] 28 28 1325

    Vortex finder height [mm] 41 41 1065

    Apex diameter [mm] 34 34 1010

    Suspension Solids density [kg/m3] 2500 2500 2500

    Gas density [kg/m3] 1.2 1.2 0.3

    Dynamic gas viscosit y [Pa s] 18.2E6 18.2E6 46.8E6

    Inlet velocity [m/s] 16.6 16.6 15.6

    Solid loading [] 0.1 0.1 8

    Wall friction coefficient 0 [] 0.005 0.005 0.005

    Factor in Eq. (11) Kg [] 0.025 0.025 0.025

    Intermediate

    results

    Mean inlet terminal vel. ws,50 [m/s] 0.151 0.151 0.301

    Mean inlet particle dia. de [m] 19 76 76

    Exponent for loading limit k [] 0.179 0.179 0.150

    Loading limit g [] 1.69E3 4.22E4 1.96E2

    Strand separation sharpness [] 0.05 0.05 0.05

    Offset value a [] 0.632 0.323 0.991

    Fig. 11. Simplified model layout, using the attrited ash particle size distribution as the

    fuel ash PSD entering the system.

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    solids with different densities have different vortex separation cut

    sizes dv. These cut sizes are used to calculate the vortex separation

    efficiency F according to [21],

    F dp 0:5 1 cos 1 log

    dpd4v logD

    2logD

    0@ 1A24 350@ 1A: 19The parameter D is discussed in [21] and can be used for the fitting

    of the separation efficiency curve of a given cyclone. In cases where

    solids with different densities are present in the cyclone, different

    separation efficiencies for the same particle size apply due to the

    different separation cut sizes. F is then a function of both dp and s.

    The mass flow of a particle class (same size, same density) going

    into the cyclone overflow m Ov,i results from

    :mOv;i F dp;s

    :mv;i 20where m

    v,idenotes the solids mass flow of particle class i entering the

    inner vortex.

    3.1.3. Modeling of return leg and bed material bunker

    Both, the return leg and the bed material bunker are modeled as

    pipes with plug flow behavior and have a constant total mass. The

    solids leaving the bed material bunker are fed into the bottom zone of

    the combustion chamber. The solids leaving the return leg are split

    into two material streams, one going directly back to the combustion

    chamber and one going to the external heat exchanger.

    3.1.4. Modeling of the external heat exchanger

    The external heat exchanger (EHE) is modeled as a stirred tank.

    Particles in the EHE are exposed to jet and bubble induced attrition,

    when comminution processes are considered. As a simplification the

    existence of the freeboard with its entrainment and classification

    effects is neglected.

    3.1.5. Modeling of the solids recycle loop

    Part of the bottom ash can be recycled after removing the coarseparticles on a sieve. In the simulation the total solids mass in the bed

    material silo is kept constant. The solids mass needed to be drained

    fromthe combustion chamber to generatethe recyclemassflowoffine

    ash can be calculated from the PSD in the dense bottom zone and the

    separation efficiency curve of the sieve which is modeled according to

    Rogers [23]. The model parameters arederived form the split between

    the fine and coarse ash measured at the technical plant.

    3.2. Modeling the attrition

    The comminution processes of ashes in CFBCs can be divided into

    fragmentation and attrition. Fragmentation is the breakage of a

    mother particle into two or more pieces, which leads to a broader and

    finer PSD. Attrition is the abrasion of small particles from a much

    larger mother particle, making the mother particle shrinks slowly [13].

    Abrasion is the dominant mechanism for catalysts in fluidized bed

    chemical reactors [13]. As a first approximation it is assumed that the

    same mechanism generally holds also for the ash particles in fluidized

    bed combustion.

    For the population balance expressions are required for the fines

    production, on the one hand per unit time for in-bed attrition induced

    by bubbles and grid jets, respectively, and on the other hand per pass

    in the case of attrition in the cyclone.

    The experiments described in Section 2.2 above have shown that

    the rate of bubble induced attrition rb(t) is described by Eq. (1). rb is

    defined as the ratio offines produced due to attrition matt to the

    product of the bed mass at the time t, mb(t) and the time interval t.

    rb t mattmb t t: 21

    Among the factors influencing the bubble induced attrition are the

    most important ones theexcess gas velocity (uumf) and the diameter

    of the particle size fraction under consideration. Since no systematic

    investigation of these parameters has been carried out in the present

    work it is assumed according to Merrick and Highley [24], Arena et al.

    [25] and Pis et al. [26],

    rb~ uumf : 22

    Furthermore, according to Ray et al. [27], Donsi et al. [28] and

    Chirone et al. [29] it holds

    rb~1

    dp: 23

    Fig. 12. Overview of the solids streams entering and leaving the circulating fluidized bed combustion plant.

    Fig.13. Measured particle size distributions of ashes leaving the plant, the sand and the

    calculated AAPSD.

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    Since the dependence of the attrition rate on time twas found to

    be described by Eq. (1), as a first assumption it is now assumed that

    the attrition rate rb(t) is given by

    rb t Kb uumf

    dp exp bb

    matt t mb0

    & '24

    where Kb and bb are material specific constants.

    For grid jet attrition we are in the same situation: The influencing

    parameters particle size dp, orifice diameter dor and jet velocity uorhave not been systematically varied in the present work. Therefore we

    adopt the findings by Werther and Xi [30], who found that

    rj~dp g d2or u3or: 25

    Although the description of the time-dependence with an

    exponential function is not as good as in the case of bubble-induced

    attrition, we formulate

    rj t Kj dp g d2or u3or exp bj matt t

    mb0

    & ': 26

    The attrition in the cyclone occurs during the passage of the solids.

    The cyclone attrition rate is therefore defined as the ratio of the mass

    offines matt(n) produced during the nth passage to the mass of the

    solids passing through the cyclone in this passage. According to the

    experimental results in Section 2.2, rc is also described by an

    exponential function. The governing parameters according to Reppen-

    hagen and Werther [13] for cyclone attrition are the solids loading at

    the cyclone entry e, the inlet velocity uc,in and the particle size dp.

    With the same reasoning that was used above in the derivation of

    Eqs. (24) and (26) the relationship determined by Reppenhagen and

    Werther [13] is adapted here, which leads to

    rc t Kc dp u2c;in

    ffiffiffiffiffie

    p exp bc matt t mc0;in

    & '27

    where mc0,in is the mass of the solids batch at the beginning of the setof experiments.

    With the population balances the unsteady state changes in the

    various parts of the fluidized bed system are monitored. For the

    description of what happens during a given time interval in a given

    part of the system with regard to attrition an information about the

    stress history which the particle have previously undergone is

    required. How far is a given particle fraction already attrited?

    In previous work (Klett et al. [11]) on the time-dependence of ash

    particle attrition in fluidized bed systems a stress history parameter

    was used. This latter parameter basically indicates how far a given

    particle is away fromthe steady stateof attrition.Unfortunately, for the

    present RDFash such a steadystate is notreached, as hasbeenfoundin

    the experiments described above. Therefore another description has to

    be found. It is suggested now to characterize the state of the stresshistory by calculating the ratio of the mass offines matt produced

    from the beginning of the attrition process, to the initial mass of the

    same particle fraction m0. is taken as an indication of the amount of

    stress the particle has already experienced,

    mattm0

    : 28

    The mass offines matt can either result from the time-dependent

    attrition induced by bubbles and grid jets, or from the attrition in the

    cyclone, which is dependent on the number of passes or a successive

    mixture of these mechanisms.

    The particle population balancing calculation proceeds sequen-

    tially from one module of the system to another. At the beginning of

    each time-interval in a given module, the particle class i indicates itsstatus of the stress history by the mass of attrited fines matt,i, which

    have originated from this particle class since its introduction into the

    system, divided by the original mass m0,i. For this value ofthe actual

    amountof attrition, which is occurring in the givenmodule duringthe

    time-intervalt, can then be calculated as the product of attrition rate

    and time-interval t, with the attrition rate being given either by

    Eq. (24), (26) or (27), respectively.

    3.3. The AAPSD concept

    Upon entering the combustion chamber the fuel particles will be

    heated and dried. Then they will devolatilize until finally the

    Fig.14. Development with time of the mean particle diameter in the dense bottom zone

    of the combustion chamber, the external heat exchanger and the cyclone overflow.

    Fig.15. Comparison of the measured values of the pressure profile and the profile of the solids volume concentration with steadystate calculation results for the 100% load operating

    conditions at the Neumnster plant.

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    carbonaceous matrix is burnt out leaving the primary ash behind. Thisprimary ash will then undergo fragmentation and attrition. The

    determination of the primary ash particle size distribution (PAPSD)

    and of its attrition characteristics is quite difficult. The question is

    whether it is absolutely necessary to consider the ash fragmentation

    and attrition processes inside the combustion system, when aiming at

    the population balancing of the CFB system as a whole. In this respect

    a comparison of the mean residence time of the ash particles in the

    combustion system with the burnout time of coal particles in a

    fluidized bed combustor can be helpful.

    If we take the conditions of the Neumnster plant, we have an solids

    inventory in the combustion chamber of 43 t, in the external heat

    exchanger of 23 t and in the return line of 6 t, whichyields a total solids

    inventory of 72t. Considering thetotal ash inputof 4.8 t/hand of sand of

    0.8 t/h we obtain a total solids flux of 5.6 t/h, which leads a to mean

    residence time of the solids in the system of roughly 13 h. On the other

    hand the burnout time of coal particles with 13 mm in afluidized bed

    combustoris between 1 and10 minaccordingto La Nauze [16].Ifwetake

    into account that most of thefragmentation andattritionoccurs with the

    fresh ash particles, this may be taken as a justification to neglect in a

    first approximation ash formation, fragmentation and attrition influ-

    ences in the calculation of the particle population balances for the

    fluidized bed system. This simplified model of the fluidized bed

    combustor is shown in Fig. 11, which now shifts the ash formation,

    fragmentation and attrition effects out of the combustion chamber such

    that attrited ash only is entering the combustor. This simplified model

    canonlybe used forcases as theone treated here, wherethe ashparticles

    do not or onlynegligibly changethere size for most of the time theystay

    in the system. In cases where larger primary ash particles shrink over a

    long period and are carried out as fines only, this concept would fail.From Fig.12 it follows that thefollowing mass balance holds for the

    integral mass flow

    :mAA :muf

    :mfly

    :mcoarse :mfine

    :msand: 29

    However, the analogous balance also holds for the particle size

    class i

    :mAA;i

    :muf;i

    :mfly;i

    :mcoarse;i

    :mfine;i

    :msand;i: 30

    4. Results and discussion

    4.1. Determination of the attrited ash particle size distribution (AAPSD)

    In the first step the measurements of the solids mass flows and

    corresponding particle size distributions, which have been described

    in Section 2.1 in detail were used to calculate the attrited ash particle

    size distribution. For this purpose both, the fractional and the integral

    mass balances Eqs. (29) and (30) were solved. Fig.13 shows the result

    in comparison with the measured particle size distribution of the

    various flows. The attrited ash particle size distribution is a very wide

    distribution. It contains all particle sizes occurring in the system, from

    the coarse ash particles, which end up in the bottom ash, to the veryfine particles in the micron range, which result from attrition

    processes. The thus determined AAPSD is the starting point for the

    population balance modeling of the CFB system.

    4.2. Particle balance modeling with the AAPSD

    Tofit the calculation results to measured values some adjustments

    of the models had to be done. In the cyclone model the wall friction

    coefficient of the brick-lined gas cyclone in the Neumnster plant was

    set to 0=0.0075.

    In order to consider the entrainment of large particles into the

    external heat exchanger, theelutriationparameter in Eq. (5) was set to

    fK=0.4.

    The population balance modeling gives a dynamic description ofthe system behavior. In the present case the calculation was started

    with only sand as the solid material in the system and ash with the

    AAPSD was added. Fig.14 shows the developmentof themean particle

    diameter in the dense bottom zone, in the external heat exchanger

    (EHE) and in the cyclone overflow. We see that the bed material in the

    dense bottom zone is getting coarser, while the inventory of the EHE

    becomesfiner and there is practically no change in themean diameter

    at the cyclone overflow. It takes of the order of 100 h to reach a steady

    state.

    Fig. 15 shows the pressure profile and the profile of the solids

    volume concentration under conditions of steady state. The compar-

    ison with the measurements shows that the calculated steady state is

    in quite good agreement with the actual situation in the Neumnster

    plant.

    The particle balancing model allows us now to calculate solids

    particle size distributions and mass flows at any point inside the

    fluidized bed system. As an example Fig. 16 shows the comparison

    between measured and calculated particle size distributions in the

    bottom zone of the combustion chamber, in the EHE and in the

    overflow of the cyclone. The matching between measurement and

    calculation is excellent. Thesame is true forthe ashmassflows leaving

    theplant, which arecompared in Table 3. An interesting information is

    the solids mass flow into the cyclone. We see that for an input of fresh

    ash of 4.8 t/h a circulating mass flow of 1343 t/h is achieved. This

    enormous solids circulation rate, which corresponds to a mass flow

    rate of 11.7 kg/m2/s in the upper part of the combustion chamber, is

    one of the characteristic advantages of circulating fluidized bed

    combustion systems, because it is responsible for the temperature

    homogeneity.Another interesting feature of population balancing modeling is

    that it allows to follow the fate of individual particle classes. As a result

    it is possible to calculate the average residence times of different size

    classes, as it is shown in Fig. 17. We see that particle sizes below 80 m

    have an average residence time of a few minutes only, whereas

    particles between roughly 100 and 1000 m have residence times

    Fig. 16. Measured (symbols) and calculated (lines) particle size distributions in the

    combustion chamber, the external heat exchanger and in the cyclone overflow for the

    Neumnster plant, together with measured and calculated solids mass flows.

    Table 3

    Comparison of the measured and calculated ash mass flows at the Neumnster plant

    Ash stream Measured Calculated

    [kg/h] [kg/h]

    Cyclone overflow 2259 2259Fine ash 1508 1535

    Coarse ash 1390 1361

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    between 2040 h. Larger particles have residence times below 5 h,

    because they are accumulating in the bottom dense bed and are

    withdrawnwiththe bottom ash. As a practical conclusion onecan take

    from Fig. 17 that, if supporting bed material is to be fed, one shouldchoose a size fraction between 200300 m because such a material

    will be kept for a maximum time in the system.

    4.3. Particle balancing modeling with consideration of attrition effects

    When the attrition behavior of the bed material is known, the

    PAPSDof thefuel ashcan be calculated by utilizingthe simulation tool.

    The calculation is carried out with consideration of the particle

    attrition, while the PSD of fuel ash fed is varied until the PSDs of the

    solids discharged from the plant are identical to the measured PSDs.

    The ash particle size distribution in the fuel feed is the identical with

    the PAPSD.

    The characteristic attrition parameters used for the calculation

    were distinguished by fitting the correlations discussed in Section 3.2to the attrition rate measurements, shown in Figs. 57. The derived

    attrition parameters are summarized in Table 4.

    The PAPSD calculated by this procedure is depicted in Fig. 18. One

    can see clearly that differences between the AAPSD and the PAPSD are

    only observed for particle sizes below 200 m. Larger particles have a

    limited entrainment rate from the combustion chamber and therefore

    do not experience the cyclone attrition, which is the governing

    attrition source here. The limited attrition the large particles are

    facing, in combination with their comparatively short residence time

    causes no distinct change to their particle size and thus they leave the

    system almost unchanged. As it should be, the AAPSD contains more

    finesthan thePAPSD, since theformer distributioncontainsthe effects

    of fragmentation and attrition.

    Further calculations were carried out for an alternative operating

    point with a recycled ash mass flow of 3360 kg/h instead of 840 kg/h.

    Both conditions were simulated using either the AAPSD, not

    considering the particle attrition in the plant, or the PAPSD under

    consideration of the particle attrition. Fig. 19 shows the results of the

    four simulation runs. First of all, it is obvious that the particle size

    distributions in the cyclone overflow and in the EHE vary to a minor

    extent only, although the recycle feed rate was drastically changed.

    In contrast, the particle size distribution in the dense bottom zone

    of the combustion chamber becomes significantly finer with the

    higher recirculation rate. One can further see that the symbols,

    representing the results of the calculations using the PAPSD are

    concurrent with the lines, representing the results using the AAPSD.

    This can be taken as a justification for simulating the plant behavior

    under various operating conditions by using the AAPSD without

    consideration of the ash comminution effects inside the plant.

    5. Summary and conclusions

    A dynamic simulation tool to model the particle population of a

    circulating fluidized bed combustor with external heat exchanger and a

    recycling of a fine fraction of the bottom drain material into the

    combustionchamberhas been developed. It considersthefluid dynamic

    processes in the combustion chamber and in the gas cyclone, as well as

    the particle attrition. Tohandle multiple solidstypes simultaneouslyand

    to fulfill the massbalances, some of the fluid dynamic sub-models taken

    from the literature were modified. The model allows to calculate the

    solids massflowsas well as the corresponding particle size distributions

    at any point inside the combustion system.

    Upon entering the combustion chamber the solid fuel particles are

    heated and dried. The devolatilization follows and finally the char is

    burning out, leaving the primary ash behind. The particle size

    Fig. 17. Residence time of particles in the Neumnster plant.

    Table 4

    Attrition parameters of the refuse-derived fuel ash

    Attrition source Kb/c/j bb/c/j

    Bubble induced attrition 3.10E13 [] 54.9

    Cyclone attrition8:46E2

    s2

    m3

    ! 14.5

    Jet attrition2:58E2

    s2

    m3

    ! 37.7

    Fig.18. Measured ash particle size distributions and the AAPSD in comparison with the

    PAPSD.

    Fig. 19. Calculated PSDs for the operation with different ash recycle feed rates, carried

    out using the AAPSD and the PAPSD, respectively, as feed PSDs.

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    distribution of the primary ash, i.e. the primary ash particle size

    distribution, is then undergoing fragmentation and attrited. These

    processes have been considered in the model such that the population

    balances canbe calculated if the PAPSD is known. However, in the case

    of a given industrial plant for RDF combustion it is very difficult to

    determine the PAPSD with sufficient accuracy.

    The measurements at the Neumnster plant have shown that theaverage particle residence time in the system is of the order of 13 h,

    while on the other hand, coal particles burn-out times influidized bed

    combustor are in the range of several minutes. Taking into account

    that most of the fragmentation and attrition occurs with the fresh

    particles and this also happens in a comparatively short time, ash

    formation, fragmentation and attrition influences are neglected in the

    calculation of the particle population balances for the fluidized bed

    system. Instead a model is suggested, were the fuel enters with the

    attrited ash particle size distribution (AAPSD) into the combustion

    chamber. The AAPSD concept shift ash formation, fragmentation and

    attrition effects out of the fluidized bed system. For a given plant the

    AAPSD can be calculated from the ash flows and their particle size

    distributions leaving the plant.

    The model has been applied to a refuse-derived fuelfi

    red plant ofStadtwerke Neumnster. The results of the measured and calculated

    mass flows and particle size distributions are in good agreement. It is

    shown that the AAPSD concept is sufficient to simulate the operating

    behavior of the plant. The particle balancing model provides new

    insides into the operating behavior. In particular the calculations of

    the residence time of different particle classes in the system reveal a

    very broad residence time distribution, ranging from several minutes

    to a maximum of roughly 40 h. A size fraction exists between 100 and

    300 m with a maximum residence time of about 40 h.

    The simulation provides a means for examining possibilities to

    control the particle size distribution in the combustion system. It is

    shown howrecirculation of a fine ash fraction can be used to achieve a

    finer bed particle size distribution in the combustion chamber.

    Acknowledgments

    The help of the staff of the Neumnster plant during the mea-

    surement campaigns and with supplying operating data is gratefully

    acknowledged. One of the authors (K. Redemann) would like to thank

    Stadtwerke Neumnster GmbH for financial support.

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    Glossary

    : Sharpness of the separation efficiency function of the cyclone strand, m e: Mass flowof solids entrained fromthe combustion chamber, enteringthe

    gas cyclone, kg/sm v: Mass flow of solids going to the inner vortex of the gas cyclone, kg/sm AA: Mass flow of attrited ash fed into the combustion chamber, kg/sm coarse: Mass flow of the coarse ash fraction of the bottom drain material, kg/sm fine: Mass flow of the fine ash fraction of the bottom drain material, kg/sm fly: Mass flow offly ash, separated in the boiler and the multi-cyclone, kg/sm Ov: Mass flow in the cyclone overflow, kg/sm sand: Mass flow of sand fed into the combustion chamber, kg/sm uf: Mass flow of ultra fine ash, separated in the flue gas cleaning plant, kg/sVe: Cyclone inlet gas volume flow, m

    3/sF: Separation efficiency function of the inner vortex of the gas cyclone, L: Dynamic gas viscosity, Pa s: Exponent for the calculation of exponential decay of the solids volume

    concentration in the upper dilute zone, e: Gas loading in the cyclone inlet, g: Loading limit of the gas going to the inner vortex, g: Gas density, kg/m

    3

    s: Solid density, kg/m3

    : Attrition history parameter, a: Offset value for the separation efficiency function of the cyclone strand,

    Aw: Sedimentation area of the cyclone strand, defined in [21], m2

    bb/j/c: Exponent for calculation of the bubble-induced, grid jet and cycloneattrition rate (aterial property),

    cv: Solid volume concentration, cv: Solids volume concentration above the transport disengaging height, cvd: Solids volume concentration at the surface of the dense bottom zone, D: Modeling parameter for the separation efficiency function of the inner

    vortex of the gas cyclone, dp: Particle diameter, mdv*: Particle size with force equilibrium on the radius with the maximum

    cyclone vortex velocity, mdor: Orifice diameter of the grid jets, m

    fK: Elutriation correction factor, h: Height above surface of dense bottom zone, m

    89K. Redemann et al. / Powder Technology 191 (2009) 7890

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    Author's personal copy

    hf: Total height of the upper dilute zone, mhi: Distance between the vortexfinder and the apex in the gas cyclone, mk: Exponent for the calculation of the loading limit in the gas cyclone, Kb: Parameter for the calculation of the bubble-induced attrition rate

    (material property), Kg: Model parameter for the calculation of the loading limit in the gas

    cyclone, Ki: Elutriation rate, kg/m

    2/s

    Kj/c: Parameter for the grid jet and cyclone attrition rate (material property),s2/m3

    m0: Solid mass before any attrition occurred, kgmatt: Total attrited mass, kgnor: Total number of orifices of the grid jets, rb: Bubble-induced attrition rate, kg/kg/s

    rc: Cyclone attrition rate, kg/kgrj: Grid jet attrition rate, kg/sT: Total separation efficiency function of the cyclone strand, T: Reduced separation efficiency function of the cyclone strand, u: Superficial gas velocity, m/sui: Maximum tangential gas velocity in the inner vortex of the gas cyclone,

    m/sut: Terminal velocity, m/s

    umf: Minimum fluidizing velocity, m/sut,50,e: Mean terminal velocity of the particles in the cyclone inlet, m/sut,50,v: Mean terminal velocity of the particles going to the inner vortex, m/sws,50: Terminal velocityof a particleshavinga probability of 50% to be separated

    in the cyclone strand, m/s

    90 K. Redemann et al. / Powder Technology 191 (2009) 7890