project for performance of remedial ...fit iii sample results indicated acutely toxic levels of...
TRANSCRIPT
|A Halliburton Company
PROJECT FORPERFORMANCE OFREMEDIAL RESPONSE ACTIVITIES ATUNCONTROLLED HAZARDOUSSUBSTANCE FACILITIES-ZONE 1
NUS CORPORATIONSUPERFUND DIVISION
WQQ379
A TOXICOLOGICAL REVIEW FORMODERN SANITATION LANDFILL
PREPARED UNDER
TDD NO. F3-3211-06EPA NO. PA-154
CONTRACT NO. 68-01-6699
FOR THE.
HAZARDOUS-SITE CONTROL DIVISIONU.S. ENVIRONMENTAL PROTECTION AGENCY
DECEMBER: 18,198*.
NUS CORPORATIONSUPERFUND DIVISION
SUBMITTED BY . REVIEWED BY APPROVED BY
KENNETH G. SY S, PH.D. . WILLIAM WENTWORTH GA&TH GLENNTOXICOLOGLST__ " _,_._._.__ ...ASSISTANT MANAGER MANAGER, FIT III
Disclaimer: " This report has been prepared for the U.S. EnvironmentalProtection Agency (EPA) under Contract No. 68-01-6699. Thecontent does .not necessarily reflect the views and policies of EPAnor does the mention of trade names or common productsconstitute endorsement by EPA.
f l R l O O S S O
Site Name; Modern SanitationTDD No.:F3-821i-06
TABLE OF CONTENTS .,
SECTION __„ . . , - . .PAGE
1.0 INTRODUCTION 1-1 „
2.0 SAMPLE ANALYSES DATA 2-1
3.0 RESIDENTIAL WELLS . 3-1 ...
4.0 MONITORING WELLS 4-1
5,0 SURFACE WATER 5-1
APPENDICES _.__. . : .,— -. .-
A 1.0 COPY OF TDD - - - - A-l
B 1.0 MAPS --- -B-l ...
C 1.0 FIT III SAMPLING DATA C-lI.I ORGANICS C-2...1.2 INORGANICS C-3 .1.3 CORRECTED DATA SHEETS C-4
FOR PESTICIDE. RESULTS .. :
D 1.0 DER SAMPLING DATA D-I1.1 DER ANALYTICAL RESULTS *" D-21.2 OTHER DER FINDINGS , ; - =-- D-3
E 1.0 AGES ANALYTICAL RESULTS - - E-l
F 1.0 TAT III ANALYSES OF RESIDENTIAL - F-lWELLS FOR LEAD - - - -
G 1.0 RECORD OF COMMUNICATION REGARDING G-lBARIUM LEVELS
ii flRioose
SECTION 1
A.RI00382
Site Name; ModerrjSanitationTDD No.:F3-8211-06
1.0 INTRODUCTION
The Modern Sanitation Landfill is rurally located in Lower Windsor Township, about1/2 mile south of~Route 124 on Yorkana Road in York County, Pennsylvania. Thefacility began as a private dump in the 1940's and evolved over the years into the72 acre active, facility which it is now. _The facility.was issued a state permit formunicipal wastes. In 1978. The site reportedly received hazardous wastes from1976 to 1979. Presently, the landfill is leased and operated by SCA Services, whopurchased the trash hauling and disposal operation in 1980.
A trench, located on the western perimeter of the site, is designed to operate as aleachate collection system and, partially intercept and divert shallow groundwaterto.an on-site treatment system, which is presently inactive. Shallow groundwaterentering the trench is discharged .untreated into a tributary of Kreutz Creek.Activation of the treatment system has^een under consideration by SCA Servicespending ongoing studies. ; .._.....
The Pennsylvania Department of Environmental Resources (PA DER) hasinvestigated the site on several occasions since January, 1981.- Sampling of surfacewaters, on-site_monitoring wells, and neighboring residential wells indicated low-level contamination of ground and surface waters with chlorinated hydrocarbon andother solvents and significant levels pi some inorganics (see Sample DataSummaries for DER Analyses: January 27, 1981; March 2, 1981; May 1*, 1981).
Due to this determination that apparently landfill-related contaminants wereidentified in an "upgradient" well and concerns for neighboring residential wellsquality, SCA Services contacted AGES.T Corporation in August, 1981 to evaluategroundwater _flpw patterns and contaminant migration potential. Portions of theAGES study have been completed detailing hydrogeologic findings; copies of theAGES reports are available in the Ecology and Environment Field Investigationreport on the Modern Sanitation Landfill, TDD No. F3-S205-05.
l.-l RR100383
SECTION 2
j _ _ _ _ _ f t R I O Q 3 8 L *
(RetfiSite Name? Modern SanitationTDD No.:F3-S211-06
2.0 SAMPLE ANALYSES DATA
On June 23, 1982, Ecology and Environment-Tnc. FIT HI, under contract to theEPA, conducted a site investigation of the Modern Sanitation Landfill and sampled5 on-site monitoring wells, 3 private, domestic wells (Peters, Druck, Frey), 2springs, a Jeachate collection (trench) discharge, and site-adjacent tributaries toKreutz. Creek. Samples were split with AGES Corp. and these were analyzedindependently. While AGES data Is not available for review, other sampling resultsobtained on various occasions by AGES are summarized and included in appendix Eof this report. ....=._...--- -^ ...,==== .. — = ,-_= ,
Results of FIT III sampling are alsp presented in_appendix C of this report.
Pesticide levels, as reported initially by the contract .analyzing laboratory (CaseNumber 11*3) and incorporated in the FIT HI Site Inspection Report (TDD No. F3-8205-05), were subsequently determined by the laboratory to be quantitativelyerroneous. Corrected, data sheets are included in appendix C « *.0 of this report,together with a copy of the explanatory letter. The Sample Data Summaries of theJune 23, 1982 FIT ni sampling results (appendix C - 2.0) have been revised toInclude the recalculated pesticide values. -- . - . - . . .
- • • ' " 'FIT III sample results indicated acutely toxic levels of barium (100,000 ug/1) in theDruck well and levels of lead (up to 360 ug/1) to warrant immediate concern in theFrey resTdence . welL_ In response to., these reported results, Ecology andEnvironment TAT in resampled.the Frey and Druck wells and several other homewells surrounding the site (TDD No. F3T8308-1Q).-. Samples were analyzed only for! ' i . . . . _ . .lead and revealed levels welL below those reported in the FIT III analysis. TheAugust, 1982 TAT HI residential well analytical results for lead are presented inappendix F. - . . . . . . . . -
Toxicological considerations addressed in this report are based on all availableanayltical data, none of which has undergone rigorous, independent qualityassurance review.
SRI 00385
SECTION 3
(RsnSite Name: Modern SanitationTDD No.:F3-S211-06
3.0 RESIDENTIAL WELLS
Sampling and analyses performed by PA DER (Jan., March, May, 1981), FIT RegionIII (June, 1982), and AGES Corp. (Nov., Jan., Feb. 1982) indicate low levelcontamination of groundwater .underlying the Modern Sanitation Landfill- In aprevious toxicologies! assessment .performed by Ecology and Environment (SiteInspection Report, Sept. 8, 1982, TDD No. F3-S205-05), the most immediateconcern addressed the potentially life-threatening levels of barium (100,000 ug/1)reported in the Druck's well sample. The unusually high concentration of bariumreported in this one, sample, however, is most likely a reporting error, since 1)other nearby domestic.wells and monitoring well samples (e.g., MTO-15) revealedno barium above the detection limit of 100 ug/1, and 2) split samples and othermonitorings performed independently by AGES revealed only 60 to 80 ug/1 bariumin samples taken from the Druck well.. (See attached record of communication inappendix G.) No health hazards can be. anticipated, at these levels of barium.
Also reported in the FIT III, June 23, 1982 sample analysis were potentially toxiclevels of lead (360- ug/1) in the Frey residence well. Subsequent sampling andanalysis for lead only of several domestic wells adjacent to the Modern Landfillsite (Aug., 1982) revealed levels ranging from 3.7 toj.9 ug Pb/1 (5.2 ug Pb/1 in theFrey well), substantially below the National Interim Primary Drinking WaterStandard of 50. ug/1 for this toxic heavy metal. - --- -
The 3_ domestic wells (Frey, Druck, Peters) sampled by FIT III on June 23, 1982confirmed low level contamination by organic priority pollutants. The Druck well,directly south of the landfill, was found to contain trace levels (less then 10 ug/1)of the recognized human, carcinogen benzene and the suspected carcinogenchloroform. Previous monitoring of the Druck well by PA DER on March 2, 1981,also revealed the presence of, chloroform at 3 ug/1. Sampling of the Druck well byAGES.on February II and 25, 1982, indicated less than 10 ug/1 and 50 ug/1chloroform, respectively; although only methylene chloride (at 26 ug/1) wasdetected in the.January 6, 19S2 sampling. (See AGES Sample Data Summaries Inappendix E.) The additional lifetime cancer risk from ingesting 2 liters of watercontaminated with 50 ug/1 chloroform is estimated at about 26 cases per 100,000persons exposed over 70 years. The Druck residence Is now utilizing bottled waterfor drinking supplies.
w flR!00387
Site Name: Modern SanitationTDD. No.: F3-S211-06 "
Analysis of FIT IILsamples also.revealed freon-11 (trichlorofluoromethane) at trace . .levels in the .Peters1, well sample, which is located east of the landfill. While noanalytical information is available concerning AGES sampling surveys for .this well,the presence of 2 ug/1 trichiorpfiuoromethane. in the Peters' well was reported bythe PA DER on February 16, 1982 (see attached Case. History exerpt in appendix D-3.0). Freon is. .considered non-toxic at these concentrations. Bioassays of thisfluorocarbon have not shown carcinogenicity in mice, or rats.
Other organic.compounds detected in FIT HI samples of off^site.residential wells .... .include trace levels of the insecticides. DOT (0.5 ug/1) _and lindane (0.3 ug/l^B-BHC)in the Frey well. (Initial results for _the analyzing lab indicated slightly highervalues, more _frequent occurence, and the presence of BHC isomers; however,subsequent recalculation by the.lab indicated-errors and only the revised results areconsidered herein.) __No.. acute hazards_are anticipated from exposure to these levelsof DDT and BHC in drinking water. Permissible Criteria for DDT and lindane, inpublic water supplies are 2.. ug DDT/1 and 56 ug BHC/1. These chlorintatedhydrocarbon pesticides, however, are-carcinogenic in mice, but not other species.Despite a lack of correlation between, human exposure and cancer, chlorinated :hydrocarbon pesii.cides jshould be considered potentially carcinogenic in man(Ambient Water Quality Criteria, 1980). It should be noted, however, that the Freyresidence no longer utilizes their well for drinking water supplies.. Moreover, while .the Frey residence_is north .ojL.the. Landfill, it is apparently not hydrologicallyconnected..with the..groundwater:_underlying the landfill. (See letters and reports .contained in the EPA files.) The source of pesticide, contamination in this farmingarea is "not known.
RR I 00388
Site Name; Modern SanitationTDD No.;F3-82ii-06
s
Other wells sampled include 3 on the property formerly owned by Brown and ^purchased recently by SCA Services, which resulted in termination of their use andthereby their associated pumping influences. These wells were sampled by AGESand found to be contaminated with numerous priority pollutants (see AGES DataSummaries in appendix E). The Brown Dug Well appears to be the most severelydegraded with several potentially carcinogenic chlorinated alkane/alkenecompounds (e.g. up to 365 ug/1 TCE). This water is hot suitable for even short-term consumption. The pattern of contaminants are similar to those reported inthe on-slte monitoring well (MW B-15) sample. This may indicate that the Druckwell, located immediately south, is at risk of further contamination with the highlyvolatile and mobile chlorinated aliphatic solvent contaminants. 'While "the Oruckresidents are utilizing an alternate source of water for drinking purposes, the wellshould be periodically monitored. In the event that contamination should approachlevels found in MW B-15, it may be advisable for the Druck residents to avoidprolonged showering in enclosed spaces with the contaminated water or to installand maintain an activated carbon filtration system for their household supply inorder to minimize risks associated with exposure to these potential carcinogens.
- , . . , . . . - - : - . , . . - - . - • " : yThe Peters well may also be at future risk. • . . . . . . - * • -
&R100389
SECTION
5RIQQ39Q
", - ----- - - - rSite Name: Modern SanitationTDD No.; F3-8211-06
4.0 MONITORING WELLS
Samples taken by FIT El, PA DER, and AGES from on-site monitoring wells allindicate contamination of the underlying aquifer. The known human carcinogens,benzene (up to 43 ug/1 in MW B_-15)_and vinyl chloride (e.g. 25 ug/1 in MW A-2),were detected on more than one occasion and sample. Other potentiallycarcinogenic compounds identified include trace levels, of B-BHC (0.1 ug/i in MWB-3 and MW B-15), low levels of PCE, TCE, chloroform, dichloroethylenes, andrelated less toxic compounds.
Samples taken from Monitoring Wells B-I (FIT and PA DER sample results) and B-2(PA DER sample results) were reported to contain elevated levels of lead (up to857 ug/1 in MW B-2), zinc (up to 12,160 ug/1 in MW_B-2), and cadmium (up to 580 . .ug/1 in MW B-l). The. potential exists for this contaminated groundwater todegrade off-site-residential wells, as_well as Kreutz Creek.
A review of-the available inorganics sampling data (FIT III and PA DER sampling ofmonitoring wells) revealed high levels jaf iron (up to 330,000 mg/l) and manganese(up to 28,000 ug/1) in some^on-site wells. Other wells and surface water samplescontained typical levels of these metals, which do not threaten jvater quality.
Grbundwater movement appears to be in several directions with variabletransmissibiiity and may be influenced by gradients created by pumping of site-adjacent wells, according to AGES hydro geological reports. Groundwater alsodischarges in places into streams and may, therefore, affect surface, waters.
RR10039!
- -=f--- - - T-——-- '•" >.„ '• • .^^ '- -.4' • -••"-- •
SECTION 5
5R100332
OSIu.Site Name; Modern SanitationTDD No.:F3-S211-06
5.0 SURFACE WATER
Analyses of samples, taken from surface waters indicate contamination and off-sitemigration of trace levels of organic priority pollutants. The inactive treatmentplant outfall, which discharges Into tributaries of Kreutz Creek, was reported (PADER, March 2 and May 14, 1982) to contain low levels of several volatilechlorinated hydrocarbons, some of which are demonstrated carcinogens in animals.In areas on and surrounding the site, the groundwater table approaches the groundsurface and In places, discharges into the streams as springs. Samples taken fromspringhouses. beyond the western perimeter of: the facility were found to becontaminated with similar organic solvent compounds. Trace levels of the humancarcinogen benzene and the potential carcinogens TCE at_75 ug/1. in Springhouse B,PCE. at less than 10 ug/1 in both springs, and other related chlorinatedalkane/alkene compounds were, detected. Much higher concentrations of these andother toxic .pollutants in on-site monitoring well samples raises concerns withregard to more extensive contamination in the future. Kreutz Creek is seasonallystocked with trout.
Samples collected by FIT HI,, from an unnamed north tributary of Kreutz Creekrevealed trace levels (less than 10 ug/1) of benzene and toluene and 16 ug/1cadmium. These pollutants were identified in the sample taken downstream of thesite, but not identified in"-"the upstream sample, suggesting a site-related release.MW B-l, which is located near to and upgradient of the north tributary between theup and downstream sampling stations, was found to be contaminated (FIT IIIsampling) by cadmium at levels up to 580 ug/1. Cadmium is toxic to fish. Whilethe drinking water MCL for this nephrotoxic bioaccumative metal is 10 ug/1, theguidelines for_the protection for freshwater_aquatic_life are 0.051 ug/1 at a waterhardness on 200 mg/1 as CaCOg and lower in softer waters. CJpronic exposures oftrout to levels below analytical detection limits can be fatal to these species andother aquatic.life. .,.,_. ... ._. . .
Proper operation of- the on-site interceptor and treatment facility is advised.Periodic monitoring of neighboring residential welts is also recommended.
RRI00393
APPENDIX A
U . .-. ................ :...._ ... ..:...... ..
&RIQQ39U
ORI&;
4
1. COSTCENTER:
ACCOUNTNO.:
3. PRIORITY:
D HIGH
Q MEDIUM
n L°W
REM/FTECHNICAL 01
4. ESTIMATE OF "TECHNICAL HOURS:
604A. ESTIMATE OF
SUBCONTRACT COST:
2. NO. :
T ZONE CONTRACTRECTIVE DOCUMENT (TOD)
F3-8211-06 - "- ":5. EPA SITE ID: 6. COMPLETION DATE:
PA-154
PAD980539068-5A. EPA SITE NAME:Modern
Sanitation 1/30/83
7. REFERENCE INFO.:
[3 ATTACHEDSPICK UP
ft fiFMFRAi TASK DESCRIPTION: Develooe a Toxicolocr'ical Zraoact Assessment.
9, SPECIFIC ELEMENTS: 1
P
p,, ,, **--L substantial
Review, inspection., reports and" data.
R ejvi ft"to a n v pars
wa r"i one m \im •? 3 ' f-."h a f
,. . - , ...
M*** «r n,^
threat to human health, direct contact orW environmental impact. ........
3
hazards pose
Submit a report
d.- - "- " : "-"summari.T'.ina' findincr anfl
f-- — —— -: .. - - -_. .— -—- . -
11. DESIRED REPORT FORM: FORMAL REPORT
OTHFR (SPFHIFY)- -,: - _. ...
17 CHMMFNTS- -.,-,-.
10. INTERIMDEADLINES:
Q LETTER REPORT Q FORMAL BRIEFING Q
.:!---. _r: - "- .- - r i
13. AUTHORIZING RRO: ^ ^ ^ ^ " - - 14. DATE:
1 1 f>1 /&?_^NATURE) . . . . . .
15. RECEIVED BYi _ M "' _ " „ 16. DATE:A ra^CCEPTED yH ACCEPTED WITH EXCEPTIONS \~\ REJECTED
U // ~7 / rl/-2/??\ 'r (CONTRACTOR RPM SIGNATURE)
J
<Sheet 1 White - FITL Copy Sheet 3 Pink - Contracting Officer's Copy (Washington, D. C.)Sheet 2 Canary - DPO Copy Sheet 4 Goldenrod — Project Officer's Copy (Washington, D. C.)
j RRI00395
APPENDIX B
fRR 1 00396
SOU1<CE . . .
aRl00397
_ _„__..__ _..__J__ —_..,j:';U. ...—., -ORIGINAL
OSITE ;:A>:H:
TDD NO.: QZ05-O5£?A NO.:
TITLE: S'lTS Sygfdtt N4WV ^ArtttliNfe /PrgTQ6RAPh UOFIGURE NO. ft,9_ '
SOURCE: SftH Q>DSgRVAT\O^S.
BRI00398
APPENDIX C
1.1 ORGANICS
ftR 1-00399
TOD No
2a L e of S* ..?le: j_-- .7 3 - l ,-
COMPOUNDS IDENTIFIED 7W SAWP1.E P-SSULTSa INORGANIC J —————
in: ppb * ug/1 ~ T-_( qucou g ) T ??b " u£/V.g — 5 (solid)
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APPENDIX C
i.2 INORGANICS
i
.ftRIOOfcOS
05a*; ('£d_r
..-SPA No.: Pd-Dale of S*n.pje:
a ORGANIC". OMPOUNDS JDENTIFTSD IN SAMPLE RESULTS
CbncVnt rations in: pob - ug/1 - I. ("aqueous) ] ppb 3 ug/V.g. - S ("sol id)
(For I entatively indent i f ii-d compounds st-eAnalytical'Dara Sht-eLs in the ippt-nd: > t-s)
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a ORGANIC"CGXf*Ol>.:DS IDENTIFIED 1H SA^PLI >.ISULTS
Conrentrations in: tj'pb .* u-p/J - L T^
APPENDIX C
1.3 CORRECTED DATA SHEETS FOR PESTICIDE RESULTS
PJ
^ 7WastCbastT.acftmealSe/vK_afii&'' ."*orCra)523£2Qa
ReportPreparedFor ~ "" " " " "~" ~~ " ' ' ----_----- - - ----- - "Date"""
USEPA Region III October 13, 1982Curtis Building (3 AW 23)Sixth and Walnut StreetsPhiladelphia, PA i9io6 ::__'_...::.'..."_::'.: •Attn: Linda Boornazian
Date Recacved P.O. No.June 24, 1982 68-01-6077 23927/mf
Description of Samples
During review of the data for Case NumberjTusT it was foundthat the computer area counts from the PestTcide analyses werenot true representations of the chromatograms. Because of thisimproper integration by the computer, the results for all re-ported pesticides were recalculated based on peak heights.After recalculation, three samples, numbered C1387, C1391, andC1434,still had detectable levels of B-BHC although the recal-culated values were lower than those originally reported. Allother samples had pesticide concentrations ND at less than 0.1 yg/1
These recalculations included sample number C1439 which was usedfor pesticide quality control on Quality Control Report Number6077-13 which covered sample number C1435, C1436, C1437, C1438,C1439, C1440, C1441, and C1445 in this Case.
Corrected data sheets for all recalculated samples and corrected-Quality Control Report are enclosed.
We wouid appreciate a telephone call if you have any questions regarding this report . Page 1 of
rtify that this report truly represents the findings of work cerformcd by me.MJK my direct supervision. _ . .
Vvj -Vs, y ^ v --sj
Linda R. KrokenbergerSenior Chemist
Reviewed and Approved.
' 0 -"tylifctfrr?D.O. Northington,
BR I DO** 0 Technical DirectorT)»f r«ortp«rtams only to tn«s«mplM invMogatW ana dots rot n«caw*nly aop»»Woth«r aopaiwWy identical orumilar maten«ljrThn7»DOftis njSminM for ih« MC!LIIIU« us* ot m« cti*m id *i>o
1 cages.
Ph.D.
•n i! is adflre5S*a.
WEST COAST T":HNICALS6RVICe INC INQUi .RIAL CAT€GORY.
SAMPLE ID C1387 SAMPLE ID C1387LAB ID 23927V17 LAB ID TRACE 17618DATE INJECTED 7-15-82 DATE EXTRACTED 6-27-82STD ID________SFB011 VOL344______ DATE INJECTED 7-10-82CONC. FACTOR ———— STD ID . TRACE 17616
CONC. FACTOR 100
Volatiles ug/1 Pesticides ug/I2V acrolein ND 89P aldrin ND3V4V6V7V10Vuv13V14V15V16V17V19V23V29V30V32V33V38V44V45V46V47V48V49V50V51V85V86V87V
acrylonitrilebenzenecarbon tetrachloridechlorobenzene1 , 2-dichloroethane1,1, 1-trichloroethane1 , 1-dichloroethane1 , 1 , 2-trichloroethane1,1,2, 2-tetrachloroethanechloroethanebis (chloromethyl ) ether2-chloroethyIvinyl etherchloroform1 , 1-dichlorcethylene1 , 2-trans-dichloroethylene1 , 2-dichloropropane1 . 3-dichloropropyleneethylbenzenemethylene chloridemethyl chloridemethyl bromidebromoformdichlorobromomethanetrichlorofluoromethanedichlorodifluoromethanechlorodibromo methanetetrachloroefhylenetoluenetrichloroethylene
NDNDNDNDNDNDNDNDNDNDNDNONDNDNDNONDND*
NDNOMHNO
NONONO
NOMONO
90P91P92P93P94P95P96P97P98P99P100P101P102P103P104P105P106P107P108P109PHOP111P112P113P
dieldrinchlordane4.4'-DDT4,4'-DDE4,4'-DDDalpha-endosulfanbeta-endosulfan
' endosulfan sulfateendrinendrin aldehydeheptachlorheptachlor epoxidealpha-BHCbeta-BHCgamma-BHCdelta-BHCPCB-1242"PCB-1254PCB-1221PCB-1232PCB-1248PCB-1260PCB-1016toxaphene
NDND
0.5**NDNDNDNDNDND 4——— na^NONDNDND
0.2**
NDND _
... ND _ND
NDNONONONONO
1* a Less than 10 ug/1(pesticides less than 5 ug/1)
ND = Not detected - .** = Mot confirmed by GCM& t n n r. n o
88V
west COASTTF*HNICALSERVICE INC INDUS "MAC CATEGORY* . _ . . _ .
- SAMPLE IB C1390LAB ID 23927V13
€TE INJECTED 7-15-82D ID BFB011 VOL344
CONC. FACTOR ———- - - - - -^---r:L
Volatiles2V acrolein3V acrylonitrile4V benzene6V carbon tetrachloride7V chlorobenzene10V 1 , 2-dichloroethane11V 1,1, 1-trichloroethane13V 1 , 1-dichloroethane14V 1,1, 2-trichloroethane15V 1,1,2, 2-tetrachloroethane
4fcV chloroethaneT^V bis ( chloromethyl ) ether19V 2-chloroethylvinyl ether23V chloroform29V 1 , 1-dichloroethylene30V ' 1,2-trans-dichloroethylene32V 1,2-dichloropropane -33V 1 , 3-dichloropropylene38V e^hylbenzene44V methylene chloride45V methyl chloride46V methyl bromide47V bromoform48V dichlorobromomethane49V trichlorofluoromethane50V dichlorodifluorometha-ne^P/ . chlorodibromomethane85V tetrachloroethylene86V toluene87V trichloroethylene
HS/1NDNO35NDND24*
260
_NDNO12
NDNOND*
1201_ *
NO' 53730
NONOMO.
NO
NONOMO*
42023
SAMPLE ID C1390LAB ID TRACE #7620DATE EXTRACTED 6-27-82DATE INJECTED 7-10-82STD ID TRACE #7616
.:z:CONC; FACTOR 100
Pesticides89P a-ldrin90P dieldrin91P chlordane92P 4,4'-DDT93P 4,4'-DDE94P 4,4'-DDD
. 95P alpha-endosulfan96P beta-endosulfan97P -endosulfan sulfate98P endrin99P endrin aldehyde100P Heptachlor101P heptachlor epoxide102P alpha-BHC103P beta-BHC104P gamma-BHC105P delta-BHC106P PCB-1~242107P PCB-1254108P PCB-12211Q9P PCB-1232HOP PCB-1248111P PCB-1260112P PCB-10161.13P toxaphene
* = Less than 10 ug/1{pesticides less than 5 ug/1)
r"
HE/1NDNDNDNDNDNDNDNDNDND..NDH-ND..„
ND •
NCNDNDNDNOND .ND _NO
N0_
NO
ND = Not detected** = Not confirmed by GC1&R 100^0"
flflv vlnvl ^i«^^-
• — " - - " " - - - .----——<--> —— - oRieiHA). 1W6ST COAST T^IHNICAL SERVICE INC INDUS i«AL CATEGORY ^^"
' SAMPLE ID C1391LAB ID 23927V21DATE INJECTED 7-15-82STD ID BFB012 VOA345pnwr1 TTAPTHD _____.»—
Volatiles2V acrolein3V acrylonitrile4V benzene6V carbon tetrachloride7V chlorobenzene10V 1 , 2-dichloroethane1 IV 1,1, 1-trichloroethane13V 1 , 1-dichloroethane14V 1,1, 2-trichloroethane15V 1,1,2, 2-tetrachloroethane16V chloroethane17V bis(chloromethyl) 'ether19V 2-chloroethyIvinyI ether23V chloroform29V 1 , 1-dichloroethylene30V 1,2-trans-dichloroethylene
; 32V 1 , 2-dichloropropane33V 1 , 3-dichloropropylene38V ethylbenzene44V methylene chloride45V methyl chloride46V methyl bromide
i 47V bromoform48V dichlorobromomethane49V trichlorofluoromethane50V dichlorodifluoromethane51 V chlorodib romomethane85V tetrachloroethylene86V toluene8?V trichloroethylene
ug/1NDNDNDNDND .NDNDNDNDNDNDNDNDNDNDNONONDND*
ND
NO
NO
NO
NO
NO
NO
NO
WO
wn
SAMPLE ID C1391LAB ID TRACE #7621DATE EXTRACTED 6-25-82DATE INJECTED 7-10-82STD ID TRACE #7625CONC. FACTOR 10°
Pesticides89P ald*in90P dieldrin91P chlordane92P 4,4'-DDT93P 4,4'-DDE94P 4. 4 '-ODD95P alpha-endosulfan96P . beta-endosulfan97P endosulfan sulfate98P endrin99P endrin aldehyde100P heptachlor101P heptachlor epoxide102P alpha-BHC103P beta-BHC104P gamma-BHC105P delta-BHC106P PCB-1242107P PCB-1254108P PCB-12Z1109P PCB-1232 , -HOP PCB-1248111P PCB-1260112P PCB-1016113P toxaphene
* m Less than 10 ug/1(pesticides less than 5 ug/1)
ND = Not detected ap j Q Q t±** = Not confirmed by GCMS
g|^
ugANDNDNONDNDNONDNDND
"D4._ NO •NDNO..NDNUND
NDNOND ..NONONONONO
NO _•10
^ —————————— UftJUilKML jy/,Jf*f ' J * , Sfs /, L_
i W65T COAST t^HNICAL S6RVIC6 INC., iWsOl \*S£tfe&£ £S#
SAMPLE ID C1391 ~~~LAB
feDATlSTDCONC
ID 23927V21• INJECTED 7-15-82ID BFB012 VOA345
PAPTOP-• rAClUK
- - - • ! i """
Volatiles .._ . .,:_2V3V4V6V7V10V11V13V14V15V
tty.6v17V19V23V29V30V32V33V38V44V45V46V47V48V49V,50V
4P£iI85V86V
. 87V86V
acroleinacrylonitrile -benzenecarbon tetrachloride — -chlorobenzene1 , 2-dichloroethane1,1, 1-trichloroethane1 , 1-dichloroethane1,1, 2-trichloroethane1,1,2, 2-tetrachloroethanechloroe thanebis (chloromethyl ) ether2-chloroethylvinyl etherchloroform1 , 1-dichloroethylene1 , 2-trans-dichloroethylene1 , 2-dichloropropane1 , 3-dichloropropyleneethylbenzenemethylene chloridemethyl chloride "..methyl bromide :bromoformdichlorobromomethanetrichlorofluoromethanedichlorodifluoromethanechlorodibromomethanetetrachloroethylenetoluene -trichloroethylene .vinyl chloride ,= _ = _~,
ug/lNDNDNDNDNDNDNDNDNDNDNDNONO 'NONONDNONO
ND.. *
-NONONO
NO
...NO
NO
NO
wnwn~NO
-M_n
SAMPLE ID ... C1391 *LAB ID TRACE #7621DATE EXTRACTED 6-25-82 ^^• ————————— - — a^i — iDATE INJECTED 7-10-82STD ID "TRACE #76255.COMC. FACTOR 100
* _Pesticides89P aldrin RECEIVED90P dieldrin ^nv - ~ "?-~ "91P chlordane _ ..,-,. - - -•yzf 4,4 -DDI env.: ... ..93P 4,4'-DDE *"'•••—-- •94P 4, 4 '-ODD95P alpha-endosulfan96P beta-endosulfan97P ' endosulfan sulfate98P endrin99P endrin aldehyde100P heptachlor101P heptachlor epoxide102P alpha-BHC103P beta-BHC104P gamma-BHC "
' 105P delta-BHC106P PCB-1242107P PCB-1254108P PCB-1221109P" PCB-1232HOP PCB-1248HIP PCB-1260112P PCB-1016113P toxaphene
* = Less than 10 ug/1(pesticides less than 5 ug/1 }
ND = Not detected** a Not confirmed bjt flfcdwsU 4
. . . . _ . . - - .
: //
y r^ i^ •" -^ g t/€>fff
ug/1ND
"ND"N'DND"ND"NDNDNDNDNDNDNDNO.NO9.1**
ND
NDit NDNO
- NONONHNONO
I I
WEST COAST W "HNICAL S€RVIC6 INC. INDUS IAL CATEGORY
SAMPLE ID_____ri434____________ SAMPLE ID C1434LAB ID________23927V11__________ LAB ID________TRACE #7623DATE INJECTED 7-15-82__________ DATE EXTRACTED 6-27-82 •STD ID________VQL344 23927V8_____ DATE INJECTED 7-10-82CONC. FACTOR ——— STD ID TRACE #7625
CONC. FACTOR 100
Volatlles ug/l Pesticides ug/12V acrolein_____________ ND 89P aldrin ND3V4V6V7V10V11 V13V14V15V16V17V19V23V29V30V32V33V38V44V45V46V47V48V49V50V51VS5V86V87V
acrylonitrilebenzenecarbon tetrachloridechlorobenzene1 , 2-dichloroethane1,1, 1-trichloroethane1 , 1-dichloroethane1,1, 2-trichloroethane1,1,2, 2-tetrachloroethanechloroethanebis ( chloromethyl ) ether2-chloroethylvinyl etherchloroform1 r 1-dichloroethylene1 , 2-trans-dichloroethylene1 , 2-dichloropropane1 , 3-dichloropropyleneethylbenzenemethylene chloridemethyl chloride'methyl bromidebromoformdichlorobromomethanetrichlorofluoromethanedichlorodifluoromethanechlorodibromomethanetetrachloroethylenetoluenetrichloroethylene
NDNDNDNDNDNDNDNDNONDNDNONDNDNDNDNONO*
NONONO
NO
ND
NO
NO
NO
NH
Mn
90P91P92P93P94P95?96P97P98P99P100P101P102P103P104P105P106P107P108P109PHOP1UP112P113P
* =
dieldrinchlordane4,4'-DDT4,4'-DDE4,4'-DDDalpha-endosulfanbeta-endosulfanendosulfan sulfateendrinendrin aldehydeheptachlorheptachlor epoxidealpha-BHCbeta-BHCgamma-BHCdelta-BHCPCB-1242PCB-1254PCB-1221PCB-1232PCB-1248PCB-1260PCB-1016toxaphene
Less than 10 ug/1
NDNDNDNDNDNDNDNDNDND *NDNDND
oa**NONDNDNDNDNONONO
NO
NO
(pesticides less than 5 ug/1)ND = Not detected** « Not confirmed by GCMS nn, ,9
88V vinyl chloride
COAST T^HNICAL SERVICE INC INDUS ^iAL CATEGORY
SAMPLE ID C1436
LAB ID 23Q27V9tfATE INJECTED 7-15-82STD ID 23927V8 VOL344CONC. FACTOR ___
Volatiles2V acrolein'3V acrylonitrile4V benzene6V carbon tetrachloride7V chlorobenzene10V 1 , 2-dichloroethane11V 1,1, 1-trichloroethane13V 1 , 1-dichloroethane14V 1,1, 2-trichloroethane15V 1,1,2, 2-tetrachloroethane6V chloroethane• —————————— - —— ———— ————^7V bis (chloromethyl) ether19V 2-chloroethylvinyl ether23V chloroform29V 1 , 1-dichloroethylene30V 1 , 2-trans-dichloroethylene32V 1 , 2-dichloropropane33V 1 , 3-dichloropropylene38V ethylbenzene -44V methylene chloride45V methyl chloride46V 'methyl bromide47V bromoform48V dichlorobromomethane49V trichlorofluoromethane50V dichlorodifluoromethaneK.V chlorodibromomethane^ HF • - • -. -5V tetrachloroethylene86V toluene ,87V trichloroethylene
ug/1NDNDHe
NONDND5537*
ND__. *
NDNDND1137NDND
- ND170 'NONONO _NO*
NO
NO*
NO75
SAMPLE ID <"™°
LAB ID TRACE #7626DATE EXTRACTED 6-27-82DATE INJECTED 7-10-82STD ID TRACE #7625CONC. FACTOR 100
Pesticides89P aldrin90P dieldrin91P chlordane92P 4,4'-DDT93P 4,4'-DDE94P 4,4'-DDD95P alpha-endosulfan96P beta-endosulfan97P -endosulfan sulfate98P endrin99P endrin aldehyde100P heptachlor101P heptachlor epoxide102P alpha-BHC103P beta-BHC104P gamma-BHC105P delta-BHC166P PCB-1242107P PCB-1254108P PCB-1221109P PCB-1232HOP PCB-1248111P PCB-1260112P PCB-1016-113P toxaphene
* = Less than 10 ug/1(pesticides less than 5 ug/1)
ND = Not detected** = Not confirmed by /fgMSQ Q k '
ug/1NDNONDNDNDNDNDNDNDNDNDNDNONDND
NDND
NDNDNDNDNO
NO
NO
wn
i388V vinyl chloride
WEST COAST T NICAL SERVICE INC INDUS ~*JALCATEGOR^j(/fed)
SAMPLE ID_____T1439_________ SAMPLE ID C1439 _____LAB ID________23927V7________. LAB ID_______TRACE #7629DATE INJECTED 7-14-82 ______ DATE EXTRACTED 6-25-82STD ID________BFB071482 VOA343 DATE INJECTED 7-10-82CONC. FACTOR ———— STD ID TRACE #7625
CONC. FACTOR 50
Volatiles ug/1 Pesticides . . . . ug/l2V acrolein__ ND 89P aldrin ND3V4V6V7V10V11V13V14V15V16V17V19V23V29V30V32V33V38V44V45V46V47V48V49V50V51V85V86V87V
acrylonitrilebenzenecarbon tetrachloridechlorobenzene1 , 2-dichloroethane1,1, 1-trichloroethane1 , 1-dichloroethane1 , 1, 2-trichloroe thane1,1.2, 2-tetrachloroethanechloroethanebis £ chloromethyl ) ether2-chloroethylvinyl etherchloroform1 , 1-dichloroethylene1 , 2-trans-dichloroethylene1 , 2-dichloropropane1,3-dichloroprooyleneethylbenzenemethylene chloridemethyl chloride'methyl bromidebromoformdichlorobromomethanetrichlorofluoromethanedichlorodifluoromethanechlorodibromo methanetetrachloroethylenetoluenetrichloroethylene
NONDNDNDNDNDNDNONDNDNDNONDNDNONONDND*
NONO ...NO
NO
NO
NO
NO
NO
ND
, wn
90P91P92P93P94P95P96P97P98P99P100P101P102P103P104P105P106P107P108P109PHOPHIP112P
" 113P
dieldrinchlordane4,4'-DDT4,4'-DDE4,4'-DDDalpha-endosulfanbeta-endosulfan•endosulfan sulfateendrinendrin aldehydeheptachlorheptachlor epoxidealpha-BHCbeta-BHCgamma-BHCdelta-BHCPCB-1242PCB-1254 -PCB-1221PCB-1232PCB-1248PCB-1263PCB-1016toxaphene
* = Less than 10 ug/l(pesticides less than 5 ug/l)
ND = Not detected** = Not confirmed by GCMS "
NDNDNDNDNDNDNDNDND J^ND ND_ND_ND
NDNDND
ND_NO
NO
NO
ND
NO
NO .
- - - - NO
R100UIU88V vinyl chloride
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APPENDIX D
DER ANALYTICAL RESULTS
'-„, ', •- . , v _..„,.•; , . . ,-
V SAMPLE DATA SUMMARY
Site Name:-•- TDD No. :
• EPA No . : f
Date of Sample;
a . ORGAN.alNORGAN
i
• Concentrations in
(For tentatively identifi -
d£T'er} /' 2-7' Xi /
x*1— --—
J Sample 1.0. No,Types and Location
Sample Blankj ———— L. ——————————————— . —————— -
Lab Blank
H\.\i B-15 ' •-£W,/< tot/G--K /L/w/ £-3\
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WJ- - - , :: ppb » ug/l - L (aqueous); ppb - ug/kg - S (solid)
ied compounds see Analytical Data Sheets In the appendixes)
~ "~ - Element /Compound Name
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Date of Sample:
COMpOUNDS IDENTIFIED IN SAMPLE RESULTS
Concentrations in: ppb = ug/l - L (aqueous)^ ppb - ug/kg - S (solid)
(For tentatively identified compounds see Analytical Data Sheets in the appendixes)
_El_ement_/Compound Name
t Orj*n** !W #All/fiN/^,\^/ - / ?„ / /^ / v«.f >/J$i Sample I.D. No. •"ypes and Location
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SAMPLE DATA SUMXARY
Slie^Kirae:- -——— -&..==^TDD NoTf____EPA No.: ~2
"Date of Samp3e:
COMPOUNDS IDENTIFIED IN SAMPLE RESULTS.cConcentrations in: ppb * ug/l - L (aqueous)J ppb - ug/kg - S (solid)
(For tentatively identified compounds see Analytical Data Sheets in the appendixes)
ab Blank XLI*
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APPENDIX D
1.2 OTHER DER FINDINGS
RRJGGUZS
History?uern Landfill
Page 21282
01-12-32 - Survey of residences around !tod!ern Landfill to arrange forsampling February 16 , 1982. Accompanied Bob Sdiott to in-spect leachate collection system of ?todarn Landfill.
01-13-82 - Conpile report for tcmorrow's staff nesting.
01-14-82 - Staff meeting at Regional Office between Bureaus of SolidWaste Management/ Water Quality Management, and CEC todiscuss landfill sanitary surveys. Discussion canteredaround Old Yorx City landfill, but in regard to T-'odemLandfill a map of the area, previous aarrple results, andproposed sstrpls sites for February 16 surrey are providedto each insnfortr or this meerfcing.
02-11-82 - Further arrangements made for sampling February 16.
02-16-G2 - Volatile organic and iiiorqanic chemical survey with Daryl;--fcng of nine (9) auditicnal residences and Helder well(sampled at licldcr well are VQA, oesticides , and inorgan-ic chemicals) and pesticide analysis of Fielder spring.Residents sampled include Stafoley, Z-terkey, Shue, Garden.Illyes, itouffinan, Hsindel, L er, and Peters. 2 nrb
in Perai-3- vLl. Heis ajiiatel ad£se5 tobcd.3. his' water before drinking.
.report7 also suggested <and spring*. ., - a sacent to Helder .res-
and volatile, organic . 0 . 1.detected iiLstreata with some smaiir xii- •
02-17-82 - Yesterday's samples hand delivered to
03-03-82' - Attempted to bail sairple fron Kan Oiilcoa : wall with DarylT*fcng to determine effect of -punp acticn on volatils organ-ic levels found at pressure tank. Plan incluu rl hailingsarrple directly frcrn well and sailing at pressure tankto conpare results. However/ attemt to bail was unsuc>-cessful as sufccnEsrsibls pump apparatus vrf.ll not permitentry of the bailer to the .water level, gpljgcj d.?GtS fe SC aTial J sanipie; ii Helder -soring to ioentifv
; .ocnyounSs }o:rt:.'Jziebzary' Ifi sraonle.Plcyd.Eeters
It26
APPENDIX E
!
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APPENDIX F
(Red)f UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
"•>' REGION 111% ttf _ - • — - _ - CENTRAL REGIONAL LABORATORY
4 *10 •. - : - - 838 SESTGATE ROAO 301-22d-27dOANNAPOLIS, MARYLAND 21401 FTS-922-37S2
DATE : August 16, 1982
SUBJECT: Analysis of York County Samples (820810-01 - 06) forLead - Superfund
FROM: : E. R. TrovatOChemist
TO: : Daniel K. DonnellyChief, Lab Section
Samples 820810-01 - 06 were analyzed by flameless atomic absorption forlead. The sample identifications and analytical results are presentedbelow. - - - - - . . - . . . . - . .
Lab f- - - .= - -. - Identification Pb_(yg/L)
820810-01 York County, Pa.-02 York County, Pa.-03 York County, Pa.-04 York County, Pa.-05 York County,' Pa.-06 York County,.Pa.
Wells, Sample Blank <2.0Frey Well 5.2.(MSA*)Kaufman Well 3.7 (MSA)Gordon Well 2.9 (MSA)Peters"Well 5.9 (MSA)Druck Well 4.9 (MSA)
*MSA = Method of Standard Additions"
Additional quality control data is available upon request
£RT:ad : . , . . .
cc: P. J. Krantz - - - - - - - - :;—- . -_•-.— —_--.- -QAO
fiR10Qi*3l
APPENDIX G
_(Red). . v.,s.-< g
/
« __ Q DISCUSSIONRECORD OF
COMMUNICATION QOTHCB (SPECIFY)
(Record of Item checked ibov*)FROM: DATS
TIME/
SUBJECT
SUMMARY OF COMMUNICATION
CONCLUSIONS, ACTION TAKEN Ofl REQU1RCO
J ftRIOOii33COPI