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    SOLVAY

    Cables 2006

    ConferenceClassification of cables:

    The PVC answer

    Richard ThommeretSOLVIN Marketing Manager

    Roland DewittSOLVAY - DCRT-HSE - Products

    Regulatory Affairs

    Cologne, 15 & 16 March 2006

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    SOLVAY

    Content

    Who is SolVin?

    Global PVC Markets by Region andTrends

    European PVC Markets byApplication

    The PVC Cable Market

    Main Drivers of the Cable Market

    Innovation in PVC

    SOLVAY

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    SOLVAY

    Who is SolVin ?

    SolVin is a leading European manufacturer of PVC and associated products.

    Foundation : January first 1999 by merging the vinyls activity of BASFand Solvayin Europe.

    Ownership : Solvay 75% & BASF 25%.

    Territory : Europe for SolVin and global presence through partnershipwith Solvay.

    Employees (2005): around 2000

    Products : Cl2, NaOH, EDC, VCM, S-PVC, E-PVC, VDC, PVDC, PVCCopolymers.

    Turnover : > 1 billion

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    SOLVAY

    Content

    Who is SolVin?

    Global PVC Markets by Region andTrends

    European PVC Markets byApplication

    The PVC Cable Market

    Main Drivers of the Cable Market

    Innovation in PVC

    SOLVAY

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    SOLVAY

    PVC World Consumption The Trend

    kt

    2201500

    29400

    11400

    17500

    50

    6000

    (2004)

    0

    5000

    10000

    15000

    20000

    25000

    30000

    35000

    19451950 1960 1970 1980 1990 2000 2010

    +3%/y

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    PVC World Consumption in 2004

    Rest of Asia-Pacific

    24.5 %

    WesternEurope

    5 %

    South America 20 %

    North America23 %

    EasternEurope

    4.5 %

    AfricaMiddle East

    4%

    China19 %

    Total : 29.4 Million Tons

    Sources : CMAI & Solvay

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    PVC World Consumption in 2004

    PVC versus GDP per capita

    kg

    PVC/

    Capita

    Source : CMAI & SolVin

    AFRICA

    INDIA

    CIS

    SOUTH AMERICA

    MEAST

    SEA

    CENTRAL EUROPE

    NEA

    WEST EUROPENORTH AMERICA

    0

    2

    4

    6

    8

    10

    12

    14

    16

    0 5000 10000 15000 20000 25000 3000

    CHINA

    USD/Capita

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    PVC World ConsumptionThe Trend

    Sources : CMAI & Solvay

    CONSUMPTIONGrowth rates % per Year

    2004(kt)

    North AMERICA 7090

    Western EUROPE 5650

    East. EUROPE & RUSSIA 847

    CHINA 6905

    REST OF ASIA - PACIFIC 6377

    South AMERICA 1121AFRICA + Middle EAST 1410

    WORLD 29400

    1998

    to2003

    0.8 %

    -0.1 %

    15.0 %

    1.1 %

    -1.6 %

    3.1 %

    6.9 %

    2.0 %

    Region

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    SOLVAY

    Content

    Who is SolVin?

    Global PVC Markets by Region andTrends

    European PVC Markets byApplication

    The PVC Cable Market

    Main Drivers of the Cable Market Innovation in PVC

    SOLVAY

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    SOLVAY

    European PVC Market

    Source SolVin

    5650 kt in 2004

    PVC consumption by Market

    Western Europe

    Packaging

    10%

    Agriculture

    4%

    Construction

    67%

    Electrical

    8%

    Others

    7%

    Automotive

    3%

    Sports/leisure

    1%

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    SOLVAY

    European PVC Market

    Total consumption in 2004 : 5650 kt

    The average trend for the 5 next years:

    Moderate growth in Western Europe : +1%/y High growth in Eastern Europe : + 6-7%/y

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    SOLVAY

    Content

    Who is SolVin?

    Global PVC Markets by Region andTrends

    European PVC Markets byApplication

    The PVC Cable Market

    Main Drivers of the Cable Market Innovation in PVC

    SOLVAY

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    SOLVAY

    The European PVC Cable Market

    European PVC Cable Market

    Total consumption : 428 kt in 2004

    2000-2005 in WE : -2%/y

    PVC in cables

    Good insulator for safe energy supply Above 55% among all polymers

    Mostly in low voltage : > 75%

    Telecom

    Transport (Automotive)

    Also used in Tunnels : < 1%...

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    SOLVAY

    The PVC Cable Market

    Source SolVin

    Evolution of PVC Comsumption in Cables in Europe

    0

    100000

    200000

    300000

    400000

    500000

    600000

    700000

    1994 1996 1998 2000 2002 2004 2006 2008 2010 2012

    t/y

    West-Europe

    Grand Total

    EE + Russ ia

    AAGR +/- 4%

    AAGR +/- 1%

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    SOLVAY

    Content

    Who is SolVin?

    Global PVC Markets by Region andTrends

    European PVC Markets byApplication

    The PVC Cable Market

    Main Drivers of the Cable Market Innovation in PVC

    SOLVAY

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    Main Drivers of the

    Wire & Cables Market In Grand Europe

    Less cables in general

    WE : Decrease of the cable market in volume

    Delocalisation of production to EE, N-Africa and NE-Asia

    Wireless trend accelerating (Bluetooth)

    Telecom cables affected since mid 90

    In EE + Russia : Increase of the cable market

    New buildings, reconstruction

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    Trends for PVC in the

    Wire & Cables Market

    Less apparent consumption of PVC due to :

    Inter Polymer competition HFFR accounts for +/-5% but high growth

    Some trade influences

    Export of PVC Compounds to EE + Russia

    Imports from SE-Asia

    PVC cables

    Finished goods

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    SOLVAY

    PVC Net Trade from Europe in 2004

    Western Europe

    Africa Middle East - Asie

    C/C:13.9 kgC/C : 3.1 kg

    305 kt

    Eastern Europe

    270kt

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    SOLVAY

    Trends for PVC in theWire & Cables Market

    The average Trend in the next 5 years

    PVC Consumption

    Slight Growth in Grand Europe : +1%/y

    Slight decrease in WE : -1%/y

    Clear Growth in EE : +4%/y

    PVC Compounding

    Innovation in new grades

    Higher performances

    Higher Recycling of composite materials from cables

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    SOLVAY

    Content

    Who is SolVin?

    Global PVC Markets by Region andTrends

    European PVC Markets byApplication

    The PVC Cable Market

    Main Drivers of the Cable Market Innovation in PVC

    SOLVAY

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    SOLVAY

    SolVin Awards for PVC Innovation (2004)

    Eurocompounds (Starcom)

    XL seriesPVC-P compound cross-linkable andflame retardant.

    E/8000 series

    Compound of PVC-P blended with TPU,NBR, TPU/NBR for technical cables.

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    SOLVAY

    SolVin Awards for PVC Innovation (2004)

    Eurocompounds (Starcom)

    E/7000 series

    PVC-P compound with very high flameretardancy, very low smoke and acidityemission.

    Gebauer und Griller Kabelwerk

    PVC-P compound with very hightemperature resistance up to 125C, forautomotive applications

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    SOLVAY

    SolVin involved in PVC recycling

    FeedFeed

    DissolutionDissolution

    AdditivesAdditives

    PrecipitationPrecipitation

    FilteringFilteringSecondarySecondaryMaterialMaterial

    PVC/SolventPVC/Solvent

    SolutionSolution

    Spin DryingSpin Drying AirAir

    PVCPVC

    DryerDryer

    Solvent CleaningSolvent Cleaning

    SteamSteam

    WaterWaterTreatmentTreatment

    PVCPVC

    PrecipitationPrecipitation

    Vinyloop

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    SOLVAY

    THANK YOU FOR YOUR ATTENTION

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    SOLVAY

    Cables 2006

    ConferenceClassification of cables:

    The PVC answerRichard Thommeret

    SOLVIN Marketing Manager

    Roland DewittSOLVAY - DCRT-HSE - Products

    Regulatory Affairs

    Cologne, 15 & 16 March 2006

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    SOLVAY

    Purpose of regulation

    European or national

    Often legal text supporting a frame legislation

    Europe

    European law

    referring to

    Framework laws (Directives)

    Purpose: definition of collective desires or humanprotection, such as health, safety, environment,...

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    SOLVAY

    ER2: Safety in case of fire

    ER2, as all ER, refers to the works during their

    lifetime (= period of occupancy or usage) "In case of fire" refers to the occurrence of a fire

    and the immediate impact on users, occupants

    and the construction, including the rescue period

    "In case of fire" does not refer to the longer

    terms consequences of a fire

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    ER2: Safety in case of fire

    Active protection means

    Passive protection means Fire Safety Engineering, including the selection of

    systems, the design of products and the choice of

    materials Essential characteristics:

    release of heat

    release of smoke (visibility and toxicity)

    fire propagation

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    SOLVAY

    ER2 and cables

    Proposal for a system of

    Classes of reaction to fire performance for cables 7 classes: Aca, B1ca, B2ca, Cca, Dca, Eca and Fca

    Classification criteria:

    Heat release (total and peak), FIGRA (growth index) andflame spread

    Additional classification (for B1ca to Dca):

    Smoke production (total and peak), flaming droplets,smoke acidity

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    ER2 and smoke acidity

    What is the justification of such a parameter regardingER2 ?

    acidity testing is inappropriate for assessing actual gastoxicity

    carbon monoxide is completely ignored

    the test method referred to is not a performance-basedtest

    (short-term) corrosivity is not a threat for safety

    smoke acidity does not address any of the provisionsunder ER2 of the CPD

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    SOLVAY

    Some reference values (ppm)

    0.441795100420AEGL-2 (10 min.)

    6.2271706201700AEGL-3 (10 min.)

    ?50211001500UITP (transport)

    150165290038005700ISO 13344

    308550010001200ISO/TS 13571

    (30 min.)

    25030501200IDLH (workshop)

    AcroleinHCNHFHClCO

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    Reference toxicity ratio

    9555.92250.230.24AEGL-2 (10 min.)

    274231000.10.36AEGL-3 (10 min.)

    ?2?0.0140.07UITP (transport)

    3823250.50.67ISO 13344

    4011.8330.420.83ISO/TS 13571

    (30 min.)

    6001250.0250.04IDLH (workshop)

    Acrolein

    /CO

    HCN

    /HCl

    Acrolein

    /HClCO/HFCO/HCl

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    SOLVAY

    Smoke toxicity study

    According to DIN 53436 (tube furnace)

    On cables and cable compounds:PVC, PE/EVA and PE-X

    Temperature: 600C (pre-flash over)

    Oxygen: 5% and 15% (as recommended inISO/TR 9122-1 and IEC 60695-7-1)

    Gas analyses: CO, CO2, O2, HCl, acrolein,

    formaldehydeECVM / SP (Boras, Sweden) - 2004

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    DIN 53436

    Tube Furnace test

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    Cables (compounds) toxicity ratio

    4.954.533.703.6515% vs 5% O2 (PE/EVA)

    0.610.600.600.60Low smoke PVC vsPhthalate free PVC

    0.390.430.540.57PE/EVA vs PE (sheathing)

    2.371.290.820.83PE/EVA vs PVC (insulation)

    2.281.120.570.54PE-X vs PVC (insulation)

    2.771.500.910.90PE vs Low smoke PVC

    1.050.650.500.52PE/EVA vs Low smoke PVC

    AEGL-2AEGL-3IEC

    60695

    ISO

    13344according to

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    Conclusion

    Toxicity of fire effluents is primarily dependent on CO,then LMW organic chemicals and inorganic acids

    Also, acid gases have no impact on short termcorrosivity and electric circuit integrity (main failurecause: bridging by soot)

    The criterion on smoke acidity is irrelevant and is anunfortunate diversion from more realistic safetyparameters

    Note: In terms of safety, the concept of "tenability" seemsmore appropriate (combination of heat, radiation, visibilityand toxicity)

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    SOLVAY

    THANK YOU FOR YOUR ATTENTION