perovskite photovoltaic development - cbirc · perovskite photovoltaic development mark drier and...
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ABSTRACT
The current solar panels that are on the market now are expensive, use rare metals, and are very fragile causing a very high initial investment. The quick development of perovskite photovoltaics is a pathway to finding solving this problem. Perovskite photovoltaics will lead to a cheaper, more durable, and rare metals free solar panel in the very near future. Perovskite photovoltaics are developed in the laboratory using fairly simple and proven low temperature, thin-film techniques with relative success. Although efficiency and reliability are not as high as silicon based photovoltaics, the pace and opportunity perovskite photovoltaics possess makes them a tremendous candidate to study.
The material presented here is based upon work supported by the National Science Foundation under Award No. EEC-0813570 and EEC-1406296. Any opinions, findings, and
conclusions or recommendations expressed in this material are those of the author(s) and do not necessarily reflect the views of the National Science Foundation.
Perovskite Photovoltaic DevelopmentMark Drier and Feng Zhu*, Javier Vela*, Department of Chemistry, Iowa State University, Ames, IA 50011
RESEARCH QUESTION/HYPOTHESIS
Can a reliable, inexpensive and elimination of rare
metals in the construction of photovoltaics be developed
and used on a large and commercial scale? The rapid
study and development of perovskite photovoltaics has
this potential.
REFERENCES
Electron-Hole Diffusion Lengths Exceeding 1
Micrometer in an Organometal Trihalide Perovskite
Absorber, Samuel D. Stranks et. al. Science 342, 341
(2013); DOI: 10.1126/science.1243982
RESULTS & GRAPHICS/CHARTS
The following graphics and charts show the thickness of each layer of a perovskite photovoltaic, a schematic of a photovoltaic, a
picture of an actual perovskite photovoltaic made in the lab and a I-V curve from the batch.
BACKGROUND
The study of perovskite photovoltaics is a relatively new area of
study. Although the perovskite crystalline structure has been
known for many years, only recently it was discovered of its
photovoltaic capabilities. With this new discovery, the challenge
of making perovskite photovoltaics a truly viable option in solar
power generation has been researched.
ACKNOWLEDGEMENT
I would like to thank Dr. Javier Vela, Feng Zhu, and the Vela
Lab Team for making this summer experience enjoyable. You
are a great group of people.
DISCUSSION
The goal of replicating working perovskite photovoltaics in the lab will have monumental effects in the making solar power more viable. This exercise in replicating the process will only add to the ever growing knowledge base. Although this batch did not test well, another batch was tested at an efficiency of 4-5%, which is still lower than the reference standard, but clearly shows advancements are being made. Once the reference standard is approached further enhancements can be addressed such as humidity resistance, durability concerns, and diffusion length maximization to reach higher efficiencies.
Standard
Graph
Glass
Fluorine-doped Tin Oxide Anode
TiO2
Thin Film Perovskite
spiro-OMeTAD (spirobifluorene)
Silver Cathode100-200 nm
100-200 nm
300-500 nm
100 nm
500 nm
Want low series resistance to
complete circuit
Want high shunt resistance to
prevent electrons from escaping
η=0.13%
METHODS
The process of making perovskite photovoltaics is well documented.
Starting with a fluorine doped tin oxide glass, spin coated thin-film layers
of titanium oxide, perovskite crystals, and spirobifluorine layers are
added at thicknesses ranging from 100 nm to 500 nm. A final layer of
silver is thermoevaporated (100 to 200 nm thick) on the perovskite
photovoltaic to complete the circuit.
Graph of
newly
tested
batch
η=4%
Graph of
first batch
η=12%