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  • ii

    The Mineral Grain

    and Mineral-grain

    Surfaces:

    a low-technology

    approach, description,

    and use

    By Wallace D. Kleck NoticeI claim copyright protections for this work and its contents. However, I freely

    grant anyone permission to make one paper or electronic copy for their own personal use. If any

    of the contents are quoted, there must be an appropriate technical reference. The total or any part

    of this work, may not be copied for sale or sold without the direct, personal permission of

    Wallace D. Kleck or his estate. I may be contacted by standard-mail at 23940 Basin Harbor Court, Tehachapi, CA, 93561 or by e-mail at [email protected].

    So stated, May, 10, 2012, Tehachapi, California.

    mailto:[email protected]

  • iii

    TABLE OF CONTENTS

    Note, page numbers are shown for 1st and 2

    nd

    level headings

    ------section heading---------------------------------------------------------------------page

    ABSTRACT 1

    INTRODUCTION 1

    DEFINITIONS 2

    FORMATION OF GRAINS 4

    GRAIN SURFACESPROCESSES OF FORMATION 5

    Grain Growth 5

    Growth-free

    Growth-partially-free

    Growth-restricted

    Dissolution (s.l.--sensu lato) 6

    Mechanical Modification 6

    Other (Grains at or Near Equilibrium) 6

    MINERAL GRAIN AND CRYSTAL 7

    MINERALOID 8

    GRAIN SURFACESDETAILS 8

    Growth Surfaces (redefined; new) 9

    Type-1 surfaces

    Type-2 surfaces

    Type-3 surfaces

    Type-4 surfaces

    Type 4-1 surfaces; mutual growth and relative bond strength

    Type 4-1 surfaces; metamorphic environments

    Type 4-1 surfaces; igneous environments

    Type-5 surfaces

    Paramorphic-surfaces (redefined) 22

    Dissolution (s.l.) (modified) 23

    Features of melt surfaces

    Features of a chemical solution surface

    Features of dissolution surfaces on quartz phenocrysts in rhyolite

    Recognizing dissolution surfaces

    Mechanically modified (new) 28

    Phantom Surface (modified) 30

    Artificial 30

    Mineraloid (modified) 30

    Gel-mineral (modified)

    Grain-replaced (new)

    Crystallized gel (new)

    Grain-metamict.

    Grain-domain Containing (new)

    THREE EXAMPLES 34

    Pegmatite-Example 1 34

    Quartz in Rhyolite (Crystal Tuff)-Example 2 35

  • iv

    Spodumene Crystal-Example 3 36

    DISCUSSION 36

    Other Surfaces 36

    Crystals 37

    Mixed and Complex Surfaces 37

    Surfaces on Grains from Pegmatite Rocks 37

    Grains in Cavities36

    Some Comments on the Nature of Selected Minerals 42

    Feldspar (in crystal tuffs)

    -quartz (in crystal tuffs)

    Mica (in a variety of environments)

    Graphite (in tactite)

    CREATION OF SUITABLE GRAINS FOR STUDY 43

    Weathering 43

    Cavities 44

    Artificially Crushed, Broken, or Naturally Fragmented Rocks 44

    Separation by Chemical or Physical Properties 44

    ACKNOWLEDGEMENTS 44

    REFERENCES CITED 45

  • 1

    The Mineral Grain and Mineral-grain Surfaces: a low-technology approach and uses

    Wallace D. Kleck [email protected]

    23940 Basin Harbor Court, Tehachapi, California 93561, USA; retired--no present college

    affiliation

    ABSTRACT

    A grain (mineral grain) is redefined as the fundamental unit of mineralogy. Grain surfaces (in

    3-dimensions) provide considerably more information about the geologic history of grains in a

    rock than do a small number of thin sections through grains. Grain surfaces are formed by one or

    a combination of growth, dissolution, and mechanical modification. Herein, grain surfaces are

    divided into six classes and ten subclasses (in parentheses)growth (type-1, type-2, type-3,

    type-4, type 4-1, type-5), paramorphic, dissolution, mechanically modified (cleavage, parting,

    fracture, smoothed), phantom, and artificial. In addition, mineraloid is redefined and divided into

    five subclasses (gel-mineral, grain-replaced, crystallized gel, grain-metamict, and grain-domain

    containing).

    Type 4-1 growth surfaces are a newly defined type of surface, resulting from competitive growth

    (primarily) in igneous and metamorphic environments. It is proposed that the determining factor

    in the goodness of development of crystal surfaces on such grains is the relative difference in

    bond strength. An imprecise measure of the difference in bond strength is the relative difference

    in mineral hardness (H). Where the difference of hardness between two competing grains is

    approximately >2, recognizable crystal surfaces develop.

    INTRODUCTION

    For approximately 100 years, petrologists and mineralogists have dealt with the interpretation of

    the features of mineral grains primarily in section. This is a useful and well developed technique,

    but it ignores features that can provide a great deal of information about the environment of

    formation of mineral grainsi.e. the nature of and the features on the surfaces of the mineral

    grains. These surface features are the last to form and then are the latest of the mineral-grain

    surface features. For a compete interpretation of the grains, this information needs to be added to

    information about the internal (and former grain surfaces) features gained by section studies.

    This paper has three purposes:

    To gather and develop information on the origin and nature of grain surfaces;

  • 2

    To develop a classification system that places this information in a coordinated and logical format;

    To demonstrate how this information can be used. In doing this, it is necessary to develop a certain amount of new terminology and to modify some

    existing terminology; if this approach is valid, the new and modified terminology will need to

    become a part of mineralogy and petrology. It is suggested that information on grain surfaces

    become one of the standard types of information collected and interpreted for mineral grains in

    rocks.

    Further, this paper is primarily concerned with natural, solid grains that have formed at or near

    the surface of Earth. It is not that other substances or environments are uncommon or

    uninteresting, but for the practical reasons of length and coherence of topic. The surface and near

    surface processes of the planetary body called Earth are complex enough. But as we scientists

    begin to consider the interior of Earth, outer-space, other planetary bodies, etc., the job of

    understanding natural solids grows to unimagined proportions. Truly, we are cursed (or blessed)

    and live in interesting times.

    Note that Geosphere (the GSA online jo