metal loaded epoxy putty - resin #850-978 · metal loaded epoxy putty - resin #850-978 chemwatch:...

RS Components Chemwatch Hazard Alert Code: 2

Metal Loaded Epoxy Putty - Resin #850-978 (AUS)

Chemwatch: 5420-92Version No: 2.1.1.1Safety Data Sheet according to WHS and ADG requirements

Issue Date: 28/08/2020Print Date: 07/09/2020

L.GHS.AUS.EN

SECTION 1 Identification of the substance / mixture and of the company / undertaking

Product Identifier

Product name Metal Loaded Epoxy Putty - Resin #850-978 (AUS)

Synonyms Not Available

Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains bisphenol A/ diglycidyl ether resin, liquid)

Other means of identification Not Available

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified usesEpoxy resin preparation. To be used in conjunction with Hardener Pack.Use according to manufacturer's directions.

Details of the supplier of the safety data sheet

Registered company name RS Components

Address 25 Pavesi Street Smithfield NSW 2164 Australia

Telephone +1 300 656 636

Fax +1 300 656 696

Website

Email Not Available

Emergency telephone number

Association / Organisation CHEMWATCH EMERGENCY RESPONSE

Emergency telephonenumbers

+61 2 9186 1132

Other emergency telephonenumbers

+61 1800 951 288

Once connected and if the message is not in your prefered language then please dial 01

SECTION 2 Hazards identification

Classification of the substance or mixture

HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.

ChemWatch Hazard Ratings

MaxMin

Flammability 1

Toxicity 1

Body Contact 2

Reactivity 2

Chronic 2

0 = Minimum1 = Low2 = Moderate3 = High4 = Extreme

Poisons Schedule S5

Classification [1] Skin Corrosion/Irritation Category 2, Eye Irritation Category 2A, Skin Sensitizer Category 1, Chronic Aquatic Hazard Category 2

Legend: 1. Classified by Chemwatch; 2. Classification drawn from HCIS; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI

Label elements

www.au.rs-online.com

continued...

Hazard pictogram(s)

Signal word Warning

Hazard statement(s)

H315 Causes skin irritation.

H319 Causes serious eye irritation.

H317 May cause an allergic skin reaction.

H411 Toxic to aquatic life with long lasting effects.

AUH019 May form explosive peroxides.

Precautionary statement(s) Prevention

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P261 Avoid breathing mist/vapours/spray.

P273 Avoid release to the environment.

P272 Contaminated work clothing should not be allowed out of the workplace.

Precautionary statement(s) Response

P321 Specific treatment (see advice on this label).

P362 Take off contaminated clothing and wash before reuse.

P302+P352 IF ON SKIN: Wash with plenty of water and soap.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Precautionary statement(s) Storage

Not Applicable

Precautionary statement(s) Disposal

P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

SECTION 3 Composition / information on ingredients

Substances

See section below for composition of Mixtures

Mixtures

CAS No %[weight] Name

25068-38-6 30-50

7429-90-5 10-30

Not Available balance Ingredients determined not to be hazardous

SECTION 4 First aid measures

Description of first aid measures

Eye Contact

If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upperand lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact

If skin contact occurs:Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.

Inhalation

If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained.Perform CPR if necessary. Transport to hospital, or doctor.

Ingestion

If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice.

bisphenol A/ diglycidyl ether resin, liquid

aluminium powder uncoated

Chemwatch: 5420-92

Version No: 2.1.1.1

of 10


Issue Date: 28/08/2020

Print Date: 07/09/2020

Continued...

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.Manifestation of aluminium toxicity include hypercalcaemia, anaemia, Vitamin D refractory osteodystrophy and a progressive encephalopathy (mixed dysarthria-apraxia of speech,asterixis, tremulousness, myoclonus, dementia, focal seizures). Bone pain, pathological fractures and proximal myopathy can occur. Symptoms usually develop insidiously over months to years (in chronic renal failure patients) unless dietary aluminium loads are excessive. Serum aluminium levels above 60 ug/ml indicate increased absorption. Potential toxicity occurs above 100 ug/ml and clinical symptoms are present when levels exceed 200ug/ml. Deferoxamine has been used to treat dialysis encephalopathy and osteomalacia. CaNa2EDTA is less effective in chelating aluminium.

[Ellenhorn and Barceloux: Medical Toxicology]

SECTION 5 Firefighting measures

Extinguishing media

Metal dust fires need to be smothered with sand, inert dry powders.DO NOT USE WATER, CO2 or FOAM.

Use DRY sand, graphite powder, dry sodium chloride based extinguishers, G-1 or Met L-X to smother fire. Confining or smothering material is preferable to applying water as chemical reaction may produce flammable and explosive hydrogen gas. DO NOT use halogenated fire extinguishing agents.

Special hazards arising from the substrate or mixture

Fire IncompatibilityReacts with acids producing flammable / explosive hydrogen (H2) gas Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters

Fire Fighting

Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water courses. Use water delivered as a fine spray to control fire and cool adjacent area.

Fire/Explosion Hazard

Combustible. Slight fire hazard when exposed to heat or flame. Heating may cause expansion or decomposition leading to violent rupture of containers. On combustion, may emit toxic fumes of carbon monoxide (CO).

Combustion products include:carbon monoxide (CO)carbon dioxide (CO2)metal oxidesother pyrolysis products typical of burning organic material.When aluminium oxide dust is dispersed in air, firefighters should wear protection against inhalation of dust particles, which can also containhazardous substances from the fire absorbed on the alumina particles.

HAZCHEM 2Z

SECTION 6 Accidental release measures

Personal precautions, protective equipment and emergency procedures

See section 8

Environmental precautions

See section 12

Methods and material for containment and cleaning up

Minor Spills

·In the event of a spill of a reactive diluent, the focus is on containing the spill to prevent contamination of soil and surface or groundwater.·If irritating vapors are present, an approved air-purifying respirator with organic vapor canister is recommended for cleaning up spillsand leaks.·For small spills, reactive diluents should be absorbed with sand.

Environmental hazard - contain spillage. Clean up all spills immediately. Avoid contact with skin and eyes. Wear impervious gloves and safety goggles. Trowel up/scrape up.

Major Spills

Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course.

Environmental hazard - contain spillage. Industrial spills or releases of reactive diluents are infrequent and generally contained. If a large spill does occur, the material should be captured,collected, and reprocessed or disposed of according to applicable governmental requirements.An approved air-purifying respirator with organic-vapor canister is recommended for emergency work.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 Handling and storage

Precautions for safe handling

Safe handling

Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area.

Chemwatch: 5420-92

Version No: 2.1.1.1

of 10




Continued...

Prevent concentration in hollows and sumps.

Other information

Store in original containers. Keep containers securely sealed. No smoking, naked lights or ignition sources. Store in a cool, dry, well-ventilated area.

Conditions for safe storage, including any incompatibilities

Suitable containerPolyethylene or polypropylene container. Packing as recommended by manufacturer. Check all containers are clearly labelled and free from leaks.

Storage incompatibilityAvoid reaction with oxidising agents, bases and strong reducing agents. Avoid strong acids, acid chlorides, acid anhydrides and chloroformates.

SECTION 8 Exposure controls / personal protection

Control parameters

Occupational Exposure Limits (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes

Australia Exposure Standards aluminium powder uncoated Aluminium (metal dust) 10 mg/m3 Not Available Not Available Not Available

Australia Exposure Standards aluminium powder uncoated Aluminium, pyro powders (as Al) 5 mg/m3 Not Available Not Available Not Available

Australia Exposure Standards aluminium powder uncoated Aluminium (welding fumes) (as Al) 5 mg/m3 Not Available Not Available Not Available

Emergency Limits

Ingredient Material name TEEL-1 TEEL-2 TEEL-3

bisphenol A/ diglycidyl etherresin, liquid

Epoxy resin includes EPON 1001, 1007, 820, ERL-2795 90 mg/m3 990 mg/m3 5,900 mg/m3

Ingredient Original IDLH Revised IDLH


Not Available Not Available

aluminium powder uncoated Not Available Not Available

Occupational Exposure Banding

Ingredient Occupational Exposure Band Rating Occupational Exposure Band Limit


E ≤ 0.1 ppm

Notes: Occupational exposure banding is a process of assigning chemicals into specific categories or bands based on a chemical's potency and theadverse health outcomes associated with exposure. The output of this process is an occupational exposure band (OEB), which corresponds to arange of exposure concentrations that are expected to protect worker health.

MATERIAL DATA

Exposure controls

Appropriate engineeringcontrols

Metal dusts must be collected at the source of generation as they are potentially explosive. Avoid ignition sources. Good housekeeping practices must be maintained. Dust accumulation on the floor, ledges and beams can present a risk of ignition, flame propagation and secondary explosions.

Personal protection

Eye and face protection

Safety glasses with side shields.Chemical goggles.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describingthe wearing of lenses or restrictions on use, should be created for each workplace or task.

Skin protection See Hand protection below

Hands/feet protection

NOTE:The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protectiveequipment, to avoid all possible skin contact. Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.

When handling liquid-grade epoxy resins wear chemically protective gloves , boots and aprons.The performance, based on breakthrough times ,of:

·Ethyl Vinyl Alcohol (EVAL laminate) is generally excellent·Butyl Rubber ranges from excellent to good·Nitrile Butyl Rubber (NBR) from excellent to fair.·Neoprene from excellent to fair·Polyvinyl (PVC) from excellent to poor

As defined in ASTM F-739-96·Excellent breakthrough time > 480 min·Good breakthrough time > 20 min·Fair breakthrough time < 20 min·Poor glove material degradation

Chemwatch: 5420-92

Version No: 2.1.1.1

of 10




Continued...

Gloves should be tested against each resin system prior to making a selection of the most suitable type. Systems include both the resin and anyhardener, individually and collectively)

·DO NOT use cotton or leather (which absorb and concentrate the resin), natural rubber (latex), medical or polyethylene gloves (whichabsorb the resin).

Body protection See Other protection below

Other protection

Overalls. P.V.C apron. Barrier cream. Skin cleansing cream.

Respiratory protection

Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)

Where the concentration of gas/particulates in the breathing zone, approaches or exceeds the "Exposure Standard" (or ES), respiratory protection is required.Degree of protection varies with both face-piece and Class of filter; the nature of protection varies with Type of filter.

Required Minimum Protection Factor Half-Face Respirator Full-Face Respirator Powered Air Respirator

up to 10 x ES A-AUS P2 - A-PAPR-AUS / Class 1 P2

up to 50 x ES - A-AUS / Class 1 P2 -

up to 100 x ES - A-2 P2 A-PAPR-2 P2 ^

^ - Full-faceA(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G =Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)

Cartridge respirators should never be used for emergency ingress or in areas of unknown vapour concentrations or oxygen content.The wearer must be warned to leave the contaminated area immediately on detecting any odours through the respirator. The odour may indicate that the mask is not functioningproperly, that the vapour concentration is too high, or that the mask is not properly fitted. Because of these limitations, only restricted use of cartridge respirators is consideredappropriate.Cartridge performance is affected by humidity. Cartridges should be changed after 2 hr of continuous use unless it is determined that the humidity is less than 75%, in which case,cartridges can be used for 4 hr. Used cartridges should be discarded daily, regardless of the length of time used

SECTION 9 Physical and chemical properties

Information on basic physical and chemical properties

Appearance Grey paste with a sweet smelling odour; does not mix with water.

Physical state Non Slump Paste Relative density (Water = 1) 1.8

Odour Not AvailablePartition coefficient n-octanol

/ waterNot Available

Odour threshold Not Available Auto-ignition temperature (°C) Not Available

pH (as supplied) Not Available Decomposition temperature Not Available

Melting point / freezing point(°C)

Not Available Viscosity (cSt) Not Available

Initial boiling point and boilingrange (°C)

Not Available Molecular weight (g/mol) Not Applicable

Flash point (°C) >93 Taste Not Available

Evaporation rate Not Available Explosive properties Not Available

Flammability Not Applicable Oxidising properties Not Available

Upper Explosive Limit (%) Not AvailableSurface Tension (dyn/cm or

mN/m)Not Available

Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available

Vapour pressure (kPa) Not Available Gas group Not Available

Solubility in water Immiscible pH as a solution (1%) Not Available

Vapour density (Air = 1) Not Available VOC g/L Not Available

SECTION 10 Stability and reactivity

Reactivity See section 7

Chemical stabilityUnstable in the presence of incompatible materials.Product is considered stable.Hazardous polymerisation will not occur.

Possibility of hazardousreactions

See section 7

Conditions to avoid See section 7

Incompatible materials See section 7

Hazardous decompositionproducts

See section 5

SECTION 11 Toxicological information

Information on toxicological effects

Chemwatch: 5420-92

Version No: 2.1.1.1

of 10




Continued...

Inhaled

The material is not thought to produce respiratory irritation (as classified by EC Directives using animal models). Nevertheless inhalation, of thematerial, especially for prolonged periods, may produce respiratory discomfort and occasionally, distress.Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal handling, may be damaging to the healthof the individual.In animal testing, exposure to aerosols of some reactive diluents (notably o-cresol glycidyl ether, CAS RN: 2210-79-9) has been reported to affectthe adrenal gland, central nervous system, kidney, liver, ovaries, spleen, testes, thymus, and respiratory tract.

Inhalation of freshly formed metal oxide particles sized below 1.5 microns and generally between 0.02 to 0.05 microns may result in "metal fumefever". Symptoms may be delayed for up to 12 hours and begin with the sudden onset of thirst, and a sweet, metallic or foul taste in the mouth.Other symptoms include upper respiratory tract irritation accompanied by coughing and a dryness of the mucous membranes, lassitude and ageneralised feeling of malaise. Mild to severe headache, nausea, occasional vomiting, fever or chills, exaggerated mental activity, profusesweating, diarrhoea, excessive urination and prostration may also occur.

Ingestion Accidental ingestion of the material may be damaging to the health of the individual.

Skin Contact

Evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a substantial number of individualsfollowing direct contact, and/or produces significant inflammation when applied to the healthy intact skin of animals, for up to four hours, suchinflammation being present twenty-four hours or more after the end of the exposure period. Skin irritation may also be present after prolonged orrepeated exposure; this may result in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by skin redness (erythema)and swelling (oedema) which may progress to blistering (vesiculation), scaling and thickening of the epidermis. At the microscopic level theremay be intercellular oedema of the spongy layer of the skin (spongiosis) and intracellular oedema of the epidermis.Contact with aluminas (aluminium oxides) may produce a form of irritant dermatitis accompanied by pruritus.Though considered non-harmful, slight irritation may result from contact because of the abrasive nature of the aluminium oxide particles.Bisphenol A diglycidyl ether (BADGE) may produce contact dermatitis characterised by erythema and oedema, with weeping followed by crustingand scaling. A liquid resin with a molecular weight of 350 produced severe skin irritation in rabbits when applied daily for 4 hours over 20 days.Following the initial contact there may be a discrete erythematous lesion, confined to the point of contact, which may persist for 48 hours to 10days; the erythema may give way to a papular, vesicular rash with scaling.In animals uncured resin produces moderate ante-mortem depression, loss of body weight and diarrhoea.Skin contact with reactive diluents may cause slight to moderate irritation with local redness. Repeated or prolonged skin contact may causeburns.Open cuts, abraded or irritated skin should not be exposed to this materialEntry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with harmful effects.Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.

Eye

Evidence exists, or practical experience predicts, that the material may cause eye irritation in a substantial number of individuals and/or mayproduce significant ocular lesions which are present twenty-four hours or more after instillation into the eye(s) of experimental animals.Repeated or prolonged eye contact may cause inflammation characterised by temporary redness (similar to windburn) of the conjunctiva(conjunctivitis); temporary impairment of vision and/or other transient eye damage/ulceration may occur.

Chronic

Repeated or long-term occupational exposure is likely to produce cumulative health effects involving organs or biochemical systems.Practical experience shows that skin contact with the material is capable either of inducing a sensitisation reaction in a substantial number ofindividuals, and/or of producing a positive response in experimental animals.On the basis, primarily, of animal experiments, concern has been expressed by at least one classification body that the material may producecarcinogenic or mutagenic effects; in respect of the available information, however, there presently exists inadequate data for making asatisfactory assessment.Exposure to the material may cause concerns for human fertility, on the basis that similar materials provide some evidence of impaired fertility inthe absence of toxic effects, or evidence of impaired fertility occurring at around the same dose levels as other toxic effects, but which are not asecondary non-specific consequence of other toxic effects..Bisphenol A exhibits hormone-like properties that raise concern about its suitability in consumer products and food containers. Bisphenol A isthought to be an endocrine disruptor which can mimic oestrogen and may lead to negative health effects. More specifically, bisphenol A closelymimics the structure and function of the hormone oestradiol with the ability to bind to and activate the same oestrogen receptor as the naturalhormone.. Early developmental stages appear to be the period of greatest sensitivity to its effects and some studies have linked prenatalexposure to later physical and neurological difficulties.Chronic exposure to aluminas (aluminium oxides) of particle size 1.2 microns did not produce significant systemic or respiratory system effects inworkers. Epidemiologic surveys have indicated an excess of nonmalignant respiratory disease in workers exposed to aluminum oxide duringabrasives production.Very fine Al2O3 powder was not fibrogenic in rats, guinea pigs, or hamsters when inhaled for 6 to 12 months and sacrificedat periods up to 12 months following the last exposure.When hydrated aluminas were injected intratracheally, they produced dense and numerous nodules of advanced fibrosis in rats, a reticulinnetwork with occasional collagen fibres in mice and guinea pigs, and only a slight reticulin network in rabbits.Occupational exposure to aluminium compounds may produce asthma, chronic obstructive lung disease and pulmonary fibrosis. Long-termoverexposure may produce dyspnoea, cough, pneumothorax, variable sputum production and nodular interstitial fibrosis; death has beenreported. Chronic interstitial pneumonia with severe cavitations in the right upper lung and small cavities in the remaining lung tissue, have beenobserved in gross pathology. Shaver's Disease may result from occupational exposure to fumes or dusts; this may produce respiratory distressand fibrosis with large blebs.

Metal Loaded Epoxy Putty -Resin #850-978 (AUS)

TOXICITY IRRITATION



TOXICITY IRRITATION

dermal (mouse) LD50: >1270 mg/kg[2] Eye (rabbit): 100mg - Mild

dermal (rat) LD50: >1200 mg/kg[2]

Oral (mouse) LD50: >500 mg/kg[2]

Oral (mouse) LD50: 15600 mg/kg[2]

Oral (rat) LD50: >1000 mg/kg[2]

Oral (rat) LD50: 11400 mg/kg[2]


aluminium powder uncoatedTOXICITY IRRITATION

Not Available Eye: no adverse effect observed (not irritating)[1]

Chemwatch: 5420-92

Version No: 2.1.1.1

of 10




Continued...

Legend: – Data either not available or does not fill the criteria for classification – Data available to make classification

Skin: no adverse effect observed (not irritating)[1]

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwisespecified data extracted from RTECS - Register of Toxic Effect of chemical Substances

BISPHENOL A/ DIGLYCIDYLETHER RESIN, LIQUID

Foetoxicity has been observed in animal studies Oral (rabbit, female) NOEL 180 mg/kg (teratogenicity; NOEL (maternal 60 mg/kgThe following information refers to contact allergens as a group and may not be specific to this product. Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis of contacteczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, e.g. contact urticaria,involve antibody-mediated immune reactions. The significance of the contact allergen is not simply determined by its sensitisation potential: thedistribution of the substance and the opportunities for contact with it are equally important.The chemical structure of hydroxylated diphenylalkanes or bisphenols consists of two phenolic rings joined together through a bridging carbon.This class of endocrine disruptors that mimic oestrogens is widely used in industry, particularly in plasticsBisphenol A (BPA) and some related compounds exhibit oestrogenic activity in human breast cancer cell line MCF-7, but there were remarkabledifferences in activity. Several derivatives of BPA exhibited significant thyroid hormonal activity towards rat pituitary cell line GH3, which releasesgrowth hormone in a thyroid hormone-dependent manner. However, BPA and several other derivatives did not show such activity.The substance is classified by IARC as Group 3:NOT classifiable as to its carcinogenicity to humans.Evidence of carcinogenicity may be inadequate or limited in animal testing.In mice, dermal application of bisphenol A diglycidyl ether (BADGE) (1, 10, or 100 mg/kg) for 13 weeks produced mild to moderate chronic activedermatitis. At the high dose, spongiosis and epidermal micro abscess formation were observed. In rats, dermal application of BADGE (10, 100, or1000 mg/kg) for 13 weeks resulted in a decrease in body weight at the high dose. The no-observable effect level (NOEL) for dermal exposurewas 100 mg/kg for both sexes.

ALUMINIUM POWDERUNCOATED

No significant acute toxicological data identified in literature search.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity

Serious Eye Damage/Irritation STOT - Single Exposure

Respiratory or Skinsensitisation

STOT - Repeated Exposure

Mutagenicity Aspiration Hazard

SECTION 12 Ecological information

Toxicity

Metal Loaded Epoxy Putty -Resin #850-978 (AUS)

Endpoint Test Duration (hr) Species Value Source

NotAvailable

Not Available Not AvailableNotAvailable

NotAvailable



EC50 48 Crustacea ca.2mg/L 2



LC50 96 Fish 0.001-0.134mg/L 2

EC50 48 Crustacea 0.7364mg/L 2

EC50 72 Algae or other aquatic plants 0.001-0.799mg/L 2

NOEC 240 Crustacea 0.001-0.1002mg/L 2

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN SuiteV3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard AssessmentData 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

Chemwatch: 5420-92

Version No: 2.1.1.1

of 10




Continued...

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposingof equipment wash-waters. Wastes resulting from use of the product must be disposed of on site or at approved waste sites.For bisphenol A and related bisphenols:Environmental fate:Biodegradability (28 d) 89% - Easily biodegradableBioconcentration factor (BCF) 7.8 mg/lBisphenol A, its derivatives and analogues, can be released from polymers, resins and certain substances by metabolic productsSubstance does not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIIIAs an environmental contaminant, bisphenol A interferes with nitrogen fixation at the roots of leguminous plants associated with the bacterial symbiont Sinorhizobium meliloti. Despitea half-life in the soil of only 1-10 days, its ubiquity makes it an important pollutant. According to Environment Canada, "initial assessment shows that at low levels, bisphenol A canharm fish and organisms over time. Studies also indicate that it can currently be found in municipal wastewater." However, a study conducted in the United States found that 91-98%of bisphenol A may be removed from water during treatment at municipal water treatment plants.For aluminium and its compounds and salts:Despite its prevalence in the environment, no known form of life uses aluminium salts metabolically. In keeping with its pervasiveness, aluminium is well tolerated by plants andanimals.Owing to their prevalence, potential beneficial (or otherwise) biological roles of aluminium compounds are of continuing interest.Environmental fate:Aluminium occurs in the environment in the form of silicates, oxides and hydroxides, combined with other elements such as sodium, fluorine and arsenic complexes with organicmatter.Acidification of soils releases aluminium as a transportable solution.DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air


HIGH HIGH

Bioaccumulative potential

Ingredient Bioaccumulation


LOW (LogKOW = 2.6835)

Mobility in soil

Ingredient Mobility


LOW (KOC = 51.43)

SECTION 13 Disposal considerations

Waste treatment methods

Product / Packaging disposal

Containers may still present a chemical hazard/ danger when empty. Return to supplier for reuse/ recycling if possible.

Otherwise:If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the sameproduct, then puncture containers, to prevent re-use, and bury at an authorised landfill. Where possible retain label warnings and SDS and observe all notices pertaining to the product.

Waste ManagementProduction waste from epoxy resins and resin systems should be treated as hazardous waste in accordance with National regulations. Fireretarded resins containing halogenated compounds should also be treated as special waste. Accidental spillage of resins, curing agents and theirformulations should be contained and absorbed by special mineral absorbents to prevent them from entering the environment.Contaminated or surplus product should not be washed down the sink, but preferably be fully reacted to form cross-linked solids which isnon-hazardous and can be more easily disposed.Removal of bisphenol A (BPA) from aqueous solutions was accomplished by adsorption of enzymatically generated quinone derivatives onchitosan beads. The use of chitosan in the form of beads was found to be more effective because heterogeneous removal of BPA with chitosanbeads was much faster than homogeneous removal of BPA with chitosan solutions, and the removal efficiency was enhanced by increasing theamount of chitosan beads dispersed in the BPA solutions and BPA was completely removed by quinone adsorption in the presence of chitosanbeads more than 0.10 cm3/cm3. In addition, a variety of bisphenol derivatives were completely or effectively removed by the procedureconstructed in this study, although the enzyme dose or the amount of chitosan beads was further increased as necessary for some of thebisphenol derivatives used.M.

DO NOT allow wash water from cleaning or process equipment to enter drains. It may be necessary to collect all wash water for treatment before disposal. In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first. Where in doubt contact the responsible authority. Recycle wherever possible or consult manufacturer for recycling options. Consult State Land Waste Authority for disposal. Bury or incinerate residue at an approved site. Recycle containers if possible, or dispose of in an authorised landfill.

SECTION 14 Transport information

Labels Required

Chemwatch: 5420-92

Version No: 2.1.1.1

of 10




Continued...

Marine Pollutant

HAZCHEM 2Z

Land transport (ADG)

UN number 3077

UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains bisphenol A/ diglycidyl ether resin, liquid)

Transport hazard class(es)Class 9

Subrisk Not Applicable

Packing group III

Environmental hazard Environmentally hazardous

Special precautions for userSpecial provisions 274 331 335 375 AU01

Limited quantity 5 kg

Environmentally Hazardous Substances meeting the descriptions of UN 3077 or UN 3082 are not subject to this Code when transported by road or rail in;(a) packagings;(b) IBCs; or(c) any other receptacle not exceeding 500 kg(L).- Australian Special Provisions (SP AU01) - ADG Code 7th Ed.

Air transport (ICAO-IATA / DGR)

UN number 3077

UN proper shipping name Environmentally hazardous substance, solid, n.o.s. * (contains bisphenol A/ diglycidyl ether resin, liquid)

Transport hazard class(es)

ICAO/IATA Class 9

ICAO / IATA Subrisk Not Applicable

ERG Code 9L

Packing group III

Environmental hazard Environmentally hazardous

Special precautions for user

Special provisions A97 A158 A179 A197

Cargo Only Packing Instructions 956

Cargo Only Maximum Qty / Pack 400 kg

Passenger and Cargo Packing Instructions 956

Passenger and Cargo Maximum Qty / Pack 400 kg

Passenger and Cargo Limited Quantity Packing Instructions Y956

Passenger and Cargo Limited Maximum Qty / Pack 30 kg G

Sea transport (IMDG-Code / GGVSee)

UN number 3077

UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains bisphenol A/ diglycidyl ether resin, liquid)

Transport hazard class(es)IMDG Class 9

IMDG Subrisk Not Applicable

Packing group III

Environmental hazard Marine Pollutant

Special precautions for user

EMS Number F-A , S-F

Special provisions 274 335 966 967 969

Limited Quantities 5 kg

Transport in bulk according to Annex II of MARPOL and the IBC code

Not Applicable

SECTION 15 Regulatory information

Safety, health and environmental regulations / legislation specific for the substance or mixture

bisphenol A/ diglycidyl ether resin, liquid is found on the following regulatory lists

Chemwatch: 5420-92

Version No: 2.1.1.1

of 10




Continued...

Australia Hazardous Chemical Information System (HCIS) - Hazardous Chemicals

Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) -Schedule 2


Australian Inventory of Industrial Chemicals (AIIC)

Chemical Footprint Project - Chemicals of High Concern List

aluminium powder uncoated is found on the following regulatory lists

Australia Hazardous Chemical Information System (HCIS) - Hazardous Chemicals Australian Inventory of Industrial Chemicals (AIIC)

National Inventory Status


Australia - AIIC Yes

Australia Non-Industrial Use No (bisphenol A/ diglycidyl ether resin, liquid; aluminium powder uncoated)

Canada - DSL Yes

Canada - NDSL No (bisphenol A/ diglycidyl ether resin, liquid; aluminium powder uncoated)

China - IECSC Yes

Europe - EINEC / ELINCS / NLP Yes

Japan - ENCS No (aluminium powder uncoated)

Korea - KECI Yes

New Zealand - NZIoC Yes

Philippines - PICCS Yes

USA - TSCA Yes

Taiwan - TCSI Yes

Mexico - INSQ Yes

Vietnam - NCI Yes

Russia - ARIPS Yes

Legend:Yes = All CAS declared ingredients are on the inventoryNo = One or more of the CAS listed ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)

SECTION 16 Other information

Revision Date 28/08/2020

Initial Date 28/08/2020

SDS Version Summary

Version Issue Date Sections Updated

2.1.1.1 28/08/2020 Storage (storage requirement)

Other information

Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classificationcommittee using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace orother settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

Definitions and abbreviations

PC－TWA: Permissible Concentration-Time Weighted AveragePC－STEL: Permissible Concentration-Short Term Exposure LimitIARC: International Agency for Research on CancerACGIH: American Conference of Governmental Industrial HygienistsSTEL: Short Term Exposure LimitTEEL: Temporary Emergency Exposure Limit。IDLH: Immediately Dangerous to Life or Health ConcentrationsOSF: Odour Safety FactorNOAEL :No Observed Adverse Effect LevelLOAEL: Lowest Observed Adverse Effect LevelTLV: Threshold Limit ValueLOD: Limit Of DetectionOTV: Odour Threshold ValueBCF: BioConcentration FactorsBEI: Biological Exposure Index

This document is copyright.Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process withoutwritten permission from CHEMWATCH.TEL (+61 3) 9572 4700.

Chemwatch: 5420-92

Version No: 2.1.1.1

of 10




end of SDS

RS Components Chemwatch Hazard Alert Code: 3

Metal Loaded Epoxy Putty - Hardener #850-978 (AUS)

Chemwatch: 5420-93Version No: 2.1.1.1Safety Data Sheet according to WHS and ADG requirements

Issue Date: 28/08/2020Print Date: 07/09/2020

L.GHS.AUS.EN

SECTION 1 Identification of the substance / mixture and of the company / undertaking

Product Identifier

Product name Metal Loaded Epoxy Putty - Hardener #850-978 (AUS)

Synonyms Not Available

Other means of identification Not Available

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified usesEpoxy hardener preparation. To be used in conjunction with Resin Pack.Use according to manufacturer's directions.

Details of the supplier of the safety data sheet

Registered company name RS Components

Address 25 Pavesi Street Smithfield NSW 2164 Australia

Telephone +1 300 656 636

Fax +1 300 656 696

Website

Email Not Available

Emergency telephone number

Association / Organisation CHEMWATCH EMERGENCY RESPONSE

Emergency telephonenumbers

+61 2 9186 1132

Other emergency telephonenumbers

+61 1800 951 288

Once connected and if the message is not in your prefered language then please dial 01

SECTION 2 Hazards identification

Classification of the substance or mixture

HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.

ChemWatch Hazard Ratings

MaxMin

Flammability 0

Toxicity 1

Body Contact 3

Reactivity 2

Chronic 2

0 = Minimum1 = Low2 = Moderate3 = High4 = Extreme

Poisons Schedule Not Applicable

Classification [1] Skin Corrosion/Irritation Category 2, Serious Eye Damage Category 1, Skin Sensitizer Category 1, Respiratory Sensitizer Category 1,Reproductive Toxicity Category 2, Specific target organ toxicity - repeated exposure Category 2, Chronic Aquatic Hazard Category 3

Legend: 1. Classified by Chemwatch; 2. Classification drawn from HCIS; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI

Label elements

www.au.rs-online.com

Page 1 continued...

Hazard pictogram(s)

Signal word Danger

Hazard statement(s)

H315 Causes skin irritation.

H318 Causes serious eye damage.

H317 May cause an allergic skin reaction.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.

H373 May cause damage to organs through prolonged or repeated exposure.

H412 Harmful to aquatic life with long lasting effects.

Precautionary statement(s) Prevention

P201 Obtain special instructions before use.

P260 Do not breathe mist/vapours/spray.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P285 In case of inadequate ventilation wear respiratory protection.

Precautionary statement(s) Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P310 Immediately call a POISON CENTER or doctor/physician.

Precautionary statement(s) Storage

P405 Store locked up.

Precautionary statement(s) Disposal

P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

SECTION 3 Composition / information on ingredients

Substances

See section below for composition of Mixtures

Mixtures

CAS No %[weight] Name

7429-90-5 30-50

14808-60-7 10-30

98-54-4 2.9-10

7727-43-7 2.9-10

111-40-0 1-2.9

112-24-3 <1

SECTION 4 First aid measures

Description of first aid measures

Eye Contact

If this product comes in contact with the eyes: Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upperand lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact

If skin contact occurs:Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.

Inhalation

If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained.


silica crystalline - quartz

p-tert-butylphenol

barium sulfate

diethylenetriamine

triethylenetetramine

Chemwatch: 5420-93

Version No: 2.1.1.1

Page 2 of 11




Continued...

Perform CPR if necessary. Transport to hospital, or doctor, without delay.

Ingestion

If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice.

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.Manifestation of aluminium toxicity include hypercalcaemia, anaemia, Vitamin D refractory osteodystrophy and a progressive encephalopathy (mixed dysarthria-apraxia of speech,asterixis, tremulousness, myoclonus, dementia, focal seizures). Bone pain, pathological fractures and proximal myopathy can occur. Symptoms usually develop insidiously over months to years (in chronic renal failure patients) unless dietary aluminium loads are excessive. Serum aluminium levels above 60 ug/ml indicate increased absorption. Potential toxicity occurs above 100 ug/ml and clinical symptoms are present when levels exceed 200ug/ml. Deferoxamine has been used to treat dialysis encephalopathy and osteomalacia. CaNa2EDTA is less effective in chelating aluminium.

[Ellenhorn and Barceloux: Medical Toxicology]

SECTION 5 Firefighting measures

Extinguishing media

DO NOT use halogenated fire extinguishing agents. Metal dust fires need to be smothered with sand, inert dry powders.DO NOT USE WATER, CO2 or FOAM.

Use DRY sand, graphite powder, dry sodium chloride based extinguishers, G-1 or Met L-X to smother fire. Confining or smothering material is preferable to applying water as chemical reaction may produce flammable and explosive hydrogen gas.

Special hazards arising from the substrate or mixture

Fire IncompatibilityReacts with acids producing flammable / explosive hydrogen (H2) gas Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters

Fire Fighting

When silica dust is dispersed in air, firefighters should wear inhalation protection as hazardous substances from the fire may be adsorbed onthe silica particles. When heated to extreme temperatures, (>1700 deg.C) amorphous silica can fuse.Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water courses. Use water delivered as a fine spray to control fire and cool adjacent area.

Fire/Explosion Hazard

DO NOT disturb burning dust. Explosion may result if dust is stirred into a cloud, by providing oxygen to a large surface of hot metal. DO NOT use water or foam as generation of explosive hydrogen may result.

With the exception of the metals that burn in contact with air or water (for example, sodium), masses of combustible metals do not representunusual fire risks because they have the ability to conduct heat away from hot spots so efficiently that the heat of combustion cannot bemaintained - this means that it will require a lot of heat to ignite a mass of combustible metal.Combustion products include:carbon monoxide (CO)carbon dioxide (CO2)nitrogen oxides (NOx)silicon dioxide (SiO2)metal oxidesother pyrolysis products typical of burning organic material.When aluminium oxide dust is dispersed in air, firefighters should wear protection against inhalation of dust particles, which can also containhazardous substances from the fire absorbed on the alumina particles.Decomposes at high temperatures to produce barium oxide. Barium oxide is strongly alkaline and, upon contact with water, is exothermic. Whenbarium oxide reacts with oxygen to give a peroxide, there is a fire and explosion risk.May emit poisonous fumes.May emit corrosive fumes.

HAZCHEM Not Applicable

SECTION 6 Accidental release measures

Personal precautions, protective equipment and emergency procedures

See section 8

Environmental precautions

See section 12

Methods and material for containment and cleaning up

Minor Spills

Environmental hazard - contain spillage. Clean up all spills immediately. Avoid contact with skin and eyes. Wear impervious gloves and safety goggles. Trowel up/scrape up.

Major Spills

Environmental hazard - contain spillage. Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus. Prevent, by all means available, spillage from entering drains or water courses.

Chemwatch: 5420-93

Version No: 2.1.1.1

Page 3 of 11




Continued...

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 Handling and storage

Precautions for safe handling

Safe handling

Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps.

Other information

Store in original containers. Keep containers securely sealed. Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers.

Conditions for safe storage, including any incompatibilities

Suitable container

CARE: Packing of high density product in light weight metal or plastic packages may result in container collapse with product release Heavy gauge metal packages / Heavy gauge metal drums Polyethylene or polypropylene container. Check all containers are clearly labelled and free from leaks.

Storage incompatibilityAvoid reaction with oxidising agents, bases and strong reducing agents. Avoid strong acids, acid chlorides, acid anhydrides and chloroformates.

SECTION 8 Exposure controls / personal protection

Control parameters

Occupational Exposure Limits (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes

Australia Exposure Standardsaluminium powderuncoated

Aluminium (weldingfumes) (as Al)

5 mg/m3NotAvailable

NotAvailable

Not Available


Aluminium (metal dust) 10 mg/m3NotAvailable

NotAvailable

Not Available


Aluminium, pyropowders (as Al)

5 mg/m3NotAvailable

NotAvailable

Not Available

Australia Exposure Standardssilica crystalline -quartz

Silica - Crystalline:Quartz (respirable dust)

0.05 mg/m3NotAvailable

NotAvailable

Not Available

Australia Exposure Standards barium sulfate Barium sulphate 10 mg/m3NotAvailable

NotAvailable

(a) This value is for inhalable dustcontaining no asbestos and < 1%crystalline silica.

Australia Exposure Standards diethylenetriamine Diethylene triamine1 ppm / 4.2mg/m3

NotAvailable

NotAvailable

Not Available

Emergency Limits

Ingredient Material name TEEL-1 TEEL-2 TEEL-3

silica crystalline - quartz Silica, crystalline-quartz; (Silicon dioxide) 0.075 mg/m3 33 mg/m3 200 mg/m3

p-tert-butylphenol Tert-butylphenol, p-; (Tert-butylphenol, 4-) 1.5 mg/m3 40 mg/m3 240 mg/m3

barium sulfate Barium sulfate 15 mg/m3 170 mg/m3 990 mg/m3

diethylenetriamine Diethylenetriamine 3 ppm 8.5 ppm 51 ppm

triethylenetetramine Triethylenetetramine 3 ppm 14 ppm 83 ppm

Ingredient Original IDLH Revised IDLH

aluminium powder uncoated Not Available Not Available

silica crystalline - quartz 25 mg/m3 / 50 mg/m3 Not Available

p-tert-butylphenol Not Available Not Available

barium sulfate Not Available Not Available

diethylenetriamine Not Available Not Available

triethylenetetramine Not Available Not Available

Occupational Exposure Banding

Ingredient Occupational Exposure Band Rating Occupational Exposure Band Limit

p-tert-butylphenol E ≤ 0.01 mg/m³

triethylenetetramine E ≤ 0.1 ppm

Notes: Occupational exposure banding is a process of assigning chemicals into specific categories or bands based on a chemical's potency and theadverse health outcomes associated with exposure. The output of this process is an occupational exposure band (OEB), which corresponds to arange of exposure concentrations that are expected to protect worker health.

MATERIAL DATA

Exposure controls

Chemwatch: 5420-93

Version No: 2.1.1.1

Page 4 of 11




Continued...

Appropriate engineeringcontrols

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls canbe highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically"adds" and "removes" air in the work environment.

Personal protection

Eye and face protection

Safety glasses with side shields.Chemical goggles.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describingthe wearing of lenses or restrictions on use, should be created for each workplace or task.

Skin protection See Hand protection below

Hands/feet protection

Elbow length PVC gloves NOTE:

The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protectiveequipment, to avoid all possible skin contact. Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.

Body protection See Other protection below

Other protection

Overalls. P.V.C apron. Barrier cream. Skin cleansing cream.

Recommended material(s)

GLOVE SELECTION INDEX

Glove selection is based on a modified presentation of the: "Forsberg Clothing Performance Index". The effect(s) of the following substance(s) are taken into account in the computer-generated selection: Metal Loaded Epoxy Putty - Hardener #850-978 (AUS)

Material CPI

BUTYL A

NEOPRENE A

VITON A

NITRILE C

PE/EVAL/PE C

PVC C

* CPI - Chemwatch Performance IndexA: Best SelectionB: Satisfactory; may degrade after 4 hours continuous immersionC: Poor to Dangerous Choice for other than short term immersionNOTE: As a series of factors will influence the actual performance of the glove, a finalselection must be based on detailed observation. -* Where the glove is to be used on a short term, casual or infrequent basis, factors suchas "feel" or convenience (e.g. disposability), may dictate a choice of gloves which mightotherwise be unsuitable following long-term or frequent use. A qualified practitionershould be consulted.

Respiratory protection

Type AK-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001,ANSI Z88 or national equivalent)

Where the concentration of gas/particulates in the breathing zone, approaches orexceeds the "Exposure Standard" (or ES), respiratory protection is required.Degree of protection varies with both face-piece and Class of filter; the nature ofprotection varies with Type of filter.

Required MinimumProtection Factor

Half-FaceRespirator

Full-FaceRespirator

Powered AirRespirator

up to 10 x ES AK-AUS P2 -AK-PAPR-AUS /Class 1 P2

up to 50 x ES -AK-AUS / Class1 P2

-

up to 100 x ES - AK-2 P2 AK-PAPR-2 P2 ^

^ - Full-faceA(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas orhydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfurdioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO =Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organiccompounds(below 65 degC)

If inhalation risk above the TLV exists, wear approved dust respirator.Use respirators with protection factors appropriate for the exposure level.

Up to 5 X TLV, use valveless mask type; up to 10 X TLV, use 1/2 mask dustrespirator Up to 50 X TLV, use full face dust respirator or demand type C air suppliedrespirator Up to 500 X TLV, use powered air-purifying dust respirator or a Type C pressuredemand supplied-air respirator Over 500 X TLV wear full-face self-contained breathing apparatus with positivepressure mode or a combination respirator with a Type C positive pressuresupplied-air full-face respirator and an auxiliary self-contained breathing apparatusoperated in pressure demand or other positive pressure mode Cartridge respirators should never be used for emergency ingress or in areas ofunknown vapour concentrations or oxygen content.The wearer must be warned to leave the contaminated area immediately ondetecting any odours through the respirator. The odour may indicate that the mask isnot functioning properly, that the vapour concentration is too high, or that the mask isnot properly fitted. Because of these limitations, only restricted use of cartridgerespirators is considered appropriate.Cartridge performance is affected by humidity. Cartridges should be changed after 2hr of continuous use unless it is determined that the humidity is less than 75%, inwhich case, cartridges can be used for 4 hr. Used cartridges should be discardeddaily, regardless of the length of time used

SECTION 9 Physical and chemical properties

Information on basic physical and chemical properties

Appearance Black paste with ammoniacal odour; partly mixes with water.

Chemwatch: 5420-93

Version No: 2.1.1.1

Page 5 of 11




Continued...

Physical state Non Slump Paste Relative density (Water = 1) 1.81-1.87

Odour Not AvailablePartition coefficient n-octanol

/ waterNot Available

Odour threshold Not Available Auto-ignition temperature (°C) Not Available

pH (as supplied) Not Available Decomposition temperature Not Available

Melting point / freezing point(°C)

Not Available Viscosity (cSt) 900000

Initial boiling point and boilingrange (°C)

Not Available Molecular weight (g/mol) Not Applicable

Flash point (°C) Not Available Taste Not Available

Evaporation rate Not Available Explosive properties Not Available

Flammability Not Available Oxidising properties Not Available

Upper Explosive Limit (%) Not AvailableSurface Tension (dyn/cm or

mN/m)Not Available

Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available

Vapour pressure (kPa) <0.02 Gas group Not Available

Solubility in water Partly miscible pH as a solution (1%) Not Available

Vapour density (Air = 1) Not Available VOC g/L Not Available

SECTION 10 Stability and reactivity

Reactivity See section 7

Chemical stabilityUnstable in the presence of incompatible materials.Product is considered stable.Hazardous polymerisation will not occur.

Possibility of hazardousreactions

See section 7

Conditions to avoid See section 7

Incompatible materials See section 7

Hazardous decompositionproducts

See section 5

SECTION 11 Toxicological information

Information on toxicological effects

Inhaled

Strong evidence exists that exposure to the material may produce very serious irreversible damage (other than carcinogenesis, mutagenesis andteratogenesis) following a single exposure by inhalation.The material is not thought to produce respiratory irritation (as classified by EC Directives using animal models). Nevertheless inhalation, of thematerial, especially for prolonged periods, may produce respiratory discomfort and occasionally, distress.Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal handling, may be damaging to the healthof the individual.

Inhalation of freshly formed metal oxide particles sized below 1.5 microns and generally between 0.02 to 0.05 microns may result in "metal fumefever". Symptoms may be delayed for up to 12 hours and begin with the sudden onset of thirst, and a sweet, metallic or foul taste in the mouth.Other symptoms include upper respiratory tract irritation accompanied by coughing and a dryness of the mucous membranes, lassitude and ageneralised feeling of malaise. Mild to severe headache, nausea, occasional vomiting, fever or chills, exaggerated mental activity, profusesweating, diarrhoea, excessive urination and prostration may also occur.Effects on lungs are significantly enhanced in the presence of respirable particles. Overexposure to respirable dust may produce wheezing,coughing and breathing difficulties leading to or symptomatic of impaired respiratory function.

IngestionAccidental ingestion of the material may be damaging to the health of the individual.Acute toxic responses to aluminium are confined to the more soluble forms.

Skin Contact

Skin contact with the material may be harmful; systemic effects may result following absorption.

Evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a substantial number of individualsfollowing direct contact, and/or produces significant inflammation when applied to the healthy intact skin of animals, for up to four hours, suchinflammation being present twenty-four hours or more after the end of the exposure period. Skin irritation may also be present after prolonged orrepeated exposure; this may result in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by skin redness (erythema)and swelling (oedema) which may progress to blistering (vesiculation), scaling and thickening of the epidermis. At the microscopic level theremay be intercellular oedema of the spongy layer of the skin (spongiosis) and intracellular oedema of the epidermis.Contact with aluminas (aluminium oxides) may produce a form of irritant dermatitis accompanied by pruritus.Though considered non-harmful, slight irritation may result from contact because of the abrasive nature of the aluminium oxide particles.Open cuts, abraded or irritated skin should not be exposed to this materialEntry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with harmful effects.Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.

Eye When applied to the eye(s) of animals, the material produces severe ocular lesions which are present twenty-four hours or more after instillation.

Chronic

Practical evidence shows that inhalation of the material is capable of inducing a sensitisation reaction in a substantial number of individuals at agreater frequency than would be expected from the response of a normal population.Pulmonary sensitisation, resulting in hyperactive airway dysfunction and pulmonary allergy may be accompanied by fatigue, malaise and aching.Significant symptoms of exposure may persist for extended periods, even after exposure ceases. Symptoms can be activated by a variety ofnonspecific environmental stimuli such as automobile exhaust, perfumes and passive smoking.Practical experience shows that skin contact with the material is capable either of inducing a sensitisation reaction in a substantial number ofindividuals, and/or of producing a positive response in experimental animals.On the basis, primarily, of animal experiments, the material may be regarded as carcinogenic to humans. There is sufficient evidence to provide a

Chemwatch: 5420-93

Version No: 2.1.1.1

Page 6 of 11




Continued...

strong presumption that human exposure to the material may result in cancer on the basis of:- appropriate long-term animal studies- other relevant informationToxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Serious damage (clear functional disturbance or morphological change which may have toxicological significance) is likely to be caused byrepeated or prolonged exposure. As a rule the material produces, or contains a substance which produces severe lesions. Such damage maybecome apparent following direct application in subchronic (90 day) toxicity studies or following sub-acute (28 day) or chronic (two-year) toxicitytests.There is sufficient evidence to establish a causal relationship between human exposure to the material and subsequent developmental toxiceffects in the off-spring.Exposure to the material may cause concerns for human fertility, generally on the basis that results in animal studies provide sufficient evidenceto cause a strong suspicion of impaired fertility in the absence of toxic effects, or evidence of impaired fertility occurring at around the same doselevels as other toxic effects, but which are not a secondary non-specific consequence of other toxic effects.Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs orbiochemical systems.Chronic exposure to aluminas (aluminium oxides) of particle size 1.2 microns did not produce significant systemic or respiratory system effects inworkers. Epidemiologic surveys have indicated an excess of nonmalignant respiratory disease in workers exposed to aluminum oxide duringabrasives production.Very fine Al2O3 powder was not fibrogenic in rats, guinea pigs, or hamsters when inhaled for 6 to 12 months and sacrificedat periods up to 12 months following the last exposure.When hydrated aluminas were injected intratracheally, they produced dense and numerous nodules of advanced fibrosis in rats, a reticulinnetwork with occasional collagen fibres in mice and guinea pigs, and only a slight reticulin network in rabbits.Occupational exposure to aluminium compounds may produce asthma, chronic obstructive lung disease and pulmonary fibrosis. Long-termoverexposure may produce dyspnoea, cough, pneumothorax, variable sputum production and nodular interstitial fibrosis; death has beenreported. Chronic interstitial pneumonia with severe cavitations in the right upper lung and small cavities in the remaining lung tissue, have beenobserved in gross pathology. Shaver's Disease may result from occupational exposure to fumes or dusts; this may produce respiratory distressand fibrosis with large blebs.Metallic dusts generated by the industrial process give rise to a number of potential health problems. The larger particles, above 5 micron, arenose and throat irritants. Smaller particles however, may cause lung deterioration. Particles of less than 1.5 micron can be trapped in the lungsand, dependent on the nature of the particle, may give rise to further serious health consequences.

Metal Loaded Epoxy Putty -Hardener #850-978 (AUS)

TOXICITY IRRITATION



TOXICITY IRRITATION

Not Available Eye: no adverse effect observed (not irritating)[1]

Skin: no adverse effect observed (not irritating)[1]


TOXICITY IRRITATION

0.3 mg/kg[2] Not Available

50 mg/kg[2]

Oral (rat) LD50: =500 mg/kg[2]

p-tert-butylphenol

TOXICITY IRRITATION

=3620 mg/kg[2] Eye (rabbit) 0.05 mg/24h - SEVERE

=5360 mg/kg[2] Eye (rabbit): 10 mg - SEVERE

Dermal (rabbit) LD50: 2288 mg/kg[2] Eye: adverse effect observed (irritating)[1]

Oral (rat) LD50: 2951 mg/kg[2] Skin (rabbit): 500 mg/4h - mild

Skin: adverse effect observed (irritating)[1]

barium sulfate

TOXICITY IRRITATION

=15000 mg/kg[2] Not Available

Oral (mouse) LD50: >3000 mg/kg[2]

diethylenetriamine

TOXICITY IRRITATION

>=43<=127 mg/kg[2] Eye: adverse effect observed (irritating)[1]

70 mg/kg[2] Skin (rabbit): 10 mg/24h - SEVERE

Dermal (rabbit) LD50: 1090 mg/kg[2] Skin (rabbit):500 mg open moderate

Oral (rat) LD50: ~1140 mg/kg[2] Skin: adverse effect observed (corrosive)[1]

Oral (rat) LD50: =819-1430 mg/kg[2]



TOXICITY IRRITATION

Dermal (rabbit) LD50: 805 mg/kg[2] Eye (rabbit):20 mg/24 h - moderate

Oral (mouse) LD50: =1600 mg/kg[2] Eye (rabbit); 49 mg - SEVERE

Oral (rat) LD50: =2780 mg/kg[2] Skin (rabbit): 490 mg open SEVERE

Oral (rat) LD50: =4300 mg/kg[2] Skin (rabbit): 5 mg/24 SEVERE


Chemwatch: 5420-93

Version No: 2.1.1.1

Page 7 of 11




Continued...

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwisespecified data extracted from RTECS - Register of Toxic Effect of chemical Substances

SILICA CRYSTALLINE -QUARTZ

WARNING: For inhalation exposure ONLY: This substance has been classified by the IARC as Group 1: CARCINOGENIC TO HUMANS

The International Agency for Research on Cancer (IARC) has classified occupational exposures to respirable (<5 um) crystalline silica as beingcarcinogenic to humans . This classification is based on what IARC considered sufficient evidence from epidemiological studies of humans forthe carcinogenicity of inhaled silica in the forms of quartz and cristobalite. Crystalline silica is also known to cause silicosis, a non-cancerous lungdisease.Intermittent exposure produces; focal fibrosis, (pneumoconiosis), cough, dyspnoea, liver tumours.

* Millions of particles per cubic foot (based on impinger samples counted by light field techniques).NOTE : the physical nature of quartz in the product determines whether it is likely to present a chronic health problem. To be a hazard thematerial must enter the breathing zone as respirable particles.

P-TERT-BUTYLPHENOL

for alkylphenolics category:The alkylphenolics may be divided into three groups.Group I: ortho-substituted mono-alkylphenols:Group II para-substituted mono-alkylphenolsGroup III: di- and tri-substituted mixed alkyl phenolsThe subdivision of the category alkylphenols into ortho, para and the di/tri-substituted mixed members is supported by several publishedinvestigations. In assessing antimicrobial and antifouling activity of twenty-three alkylphenols, a significant difference was notedbetween para and ortho-substituted materials. In particular, biological activity was found to vary parabolically with increasing hydrophobicity ofthe para-substituent while introduction of a bulky substituent at the ortho-position resulted in a very significant decrease in antimicrobial,antifouling, and membrane-perturbation potency. Several alkylphenolic analogs of butylated hydroxytoluene (BHT) were examined forhepatotoxicity in mice depleted of hepatic glutathione.For p-tert-butylphenolAcute toxicity: Acute toxicity of p-t-butylphenol is low via any administration routes. This chemical is considered as an irritant to the skin, eyesand respiratory tract. The possibility of skin sensitisation in humans still remains because of some positive results in human patch tests, despitenegative results in animal experiments (OECD TG 406). The depigmentation was observed on the skin of various animals and humans exposedto this chemical.The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form ofdermatitis is often characterised by skin redness (erythema) and swelling epidermis. Histologically there may be intercellular oedema of thespongy layer (spongiosis) and intracellular oedema of the epidermis.

DIETHYLENETRIAMINE

Allergic reactions which develop in the respiratory passages as bronchial asthma or rhinoconjunctivitis, are mostly the result of reactions of theallergen with specific antibodies of the IgE class and belong in their reaction rates to the manifestation of the immediate type. In addition to theallergen-specific potential for causing respiratory sensitisation, the amount of the allergen, the exposure period and the genetically determineddisposition of the exposed person are likely to be decisive. Factors which increase the sensitivity of the mucosa may play a role in predisposing aperson to allergy. They may be genetically determined or acquired, for example, during infections or exposure to irritant substances.Particular attention is drawn to so-called atopic diathesis which is characterised by an increased susceptibility to allergic rhinitis, allergic bronchialasthma and atopic eczema (neurodermatitis) which is associated with increased IgE synthesis.Exogenous allergic alveolitis is induced essentially by allergen specific immune-complexes of the IgG type; cell-mediated reactions (Tlymphocytes) may be involved. Such allergy is of the delayed type with onset up to four hours following exposure.

TRIETHYLENETETRAMINE

Triethylenetetramine (TETA) is a severe irritant to skin and eyes and induces skin sensitisation.TETA is of moderate acute toxicity: LD50(oral, rat) > 2000 mg/kg bw, LD50(dermal, rabbit) = 550 - 805 mg/kg bw. Acute exposure to saturatedvapour via inhalation was tolerated without impairment. Exposure to to aerosol leads to reversible irritations of the mucous membranes in therespiratory tract.Following repeated oral dosing via drinking water only in mice but not in rats at concentration of 3000 ppm there were signs of impairment. TheNOAEL is 600 ppm [92 mg/kg bw (oral, 90 days)].Exposure to the material for prolonged periods may cause physical defects in the developing embryo (teratogenesis).

ALUMINIUM POWDERUNCOATED & BARIUM

SULFATENo significant acute toxicological data identified in literature search.

P-TERT-BUTYLPHENOL &DIETHYLENETRIAMINE &

TRIETHYLENETETRAMINE

The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants mayproduce conjunctivitis.

Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergeniccondition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritatingcompound. Key criteria for the diagnosis of RADS include the absence of preceding respiratory disease, in a non-atopic individual, with abruptonset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow pattern, onspirometry, with the presence of moderate to severe bronchial hyperreactivity on methacholine challenge testing and the lack of minimallymphocytic inflammation, without eosinophilia, have also been included in the criteria for diagnosis of RADS.

DIETHYLENETRIAMINE &TRIETHYLENETETRAMINE

The following information refers to contact allergens as a group and may not be specific to this product. Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis of contacteczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, e.g. contact urticaria,involve antibody-mediated immune reactions. The significance of the contact allergen is not simply determined by its sensitisation potential: thedistribution of the substance and the opportunities for contact with it are equally important.Handling ethyleneamine products is complicated by their tendency to react with other chemicals, such as carbon dioxide in the air, which resultsin the formation of solid carbamates. Because of their ability to produce chemical burns, skin rashes, and asthma-like symptoms, ethyleneaminesalso require substantial care in handling. Higher molecular weight ethyleneamines are often handled at elevated temperatures further increasingthe possibility of vapor exposure to these compounds.Because of the fragility of eye tissue, almost any eye contact with any ethyleneamine may cause irreparable damage, even blindness. A single,short exposure to ethyleneamines, may cause severe skin burns, while a single, prolonged exposure may result in the material being absorbedthrough the skin in harmful amounts.The material may produce severe skin irritation after prolonged or repeated exposure, and may produce a contact dermatitis (nonallergic). Thisform of dermatitis is often characterised by skin redness (erythema) thickening of the epidermis. Histologically there may be intercellular oedema of the spongy layer (spongiosis) and intracellular oedema of the epidermis. Prolonged contact isunlikely, given the severity of response, but repeated exposures may produce severe ulceration.For alkyl polyamines:The alkyl polyamines cluster consists of organic compounds containing two terminal primary amine groups and at least one secondary aminegroup.Typically these substances are derivatives of ethylenediamine, propylenediamine or hexanediamine. The molecular weight range for theentire cluster is relatively narrow, ranging from 103 to 232Acute toxicity of the alkyl polyamines cluster is low to moderate via oral exposure and a moderate to high via dermal exposure. Cluster members

Chemwatch: 5420-93

Version No: 2.1.1.1

Page 8 of 11




Continued...

Legend: – Data either not available or does not fill the criteria for classification – Data available to make classification

have been shown to be eye irritants, skin irritants, and skin sensitisers in experimental animals. Repeated exposure in rats via the oral routeindicates a range of toxicity from low to high hazard.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity

Serious Eye Damage/Irritation STOT - Single Exposure

Respiratory or Skinsensitisation

STOT - Repeated Exposure

Mutagenicity Aspiration Hazard

SECTION 12 Ecological information

Toxicity

Metal Loaded Epoxy Putty -Hardener #850-978 (AUS)


NotAvailable


NotAvailable



LC50 96 Fish 0.001-0.134mg/L 2


EC50 72 Algae or other aquatic plants 0.001-0.799mg/L 2

NOEC 240 Crustacea 0.001-0.1002mg/L 2



NotAvailable


NotAvailable

p-tert-butylphenol


LC50 96 Fish >1mg/L 2

EC50 48 Crustacea =3.9mg/L 1

EC50 72 Algae or other aquatic plants ca.2.4mg/L 2

NOEC 3072 Fish 0.01mg/L 2

barium sulfate


LC50 96 Fish >3.5mg/L 2

EC50 48 Crustacea 0.032-mg/L 2

EC50 72 Algae or other aquatic plants >1.15mg/L 2

NOEC 2016 Algae or other aquatic plants 0.004-mg/L 2

diethylenetriamine


LC50 96 Fish 1-14mg/L 2

EC50 48 Crustacea =16mg/L 1

EC50 72 Algae or other aquatic plants 1-164mg/L 2

NOEC 504 Crustacea =5.6mg/L 1



LC50 96 Fish 180mg/L 1


EC50 72 Algae or other aquatic plants 2.5mg/L 1

NOEC 72 Algae or other aquatic plants <2.5mg/L 1

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN SuiteV3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard AssessmentData 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposingof equipment wash-waters. Wastes resulting from use of the product must be disposed of on site or at approved waste sites.For aluminium and its compounds and salts:Despite its prevalence in the environment, no known form of life uses aluminium salts metabolically. In keeping with its pervasiveness, aluminium is well tolerated by plants andanimals.Owing to their prevalence, potential beneficial (or otherwise) biological roles of aluminium compounds are of continuing interest.Environmental fate:Aluminium occurs in the environment in the form of silicates, oxides and hydroxides, combined with other elements such as sodium, fluorine and arsenic complexes with organicmatter.Acidification of soils releases aluminium as a transportable solution.DO NOT discharge into sewer or waterways.

Chemwatch: 5420-93

Version No: 2.1.1.1

Page 9 of 11




Continued...

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air

p-tert-butylphenol HIGH HIGH

diethylenetriamine LOW LOW

triethylenetetramine LOW LOW

Bioaccumulative potential

Ingredient Bioaccumulation

p-tert-butylphenol LOW (BCF = 240)

diethylenetriamine LOW (BCF = 1.7)

triethylenetetramine LOW (LogKOW = -2.6464)

Mobility in soil

Ingredient Mobility

p-tert-butylphenol LOW (KOC = 1912)

diethylenetriamine LOW (KOC = 87.53)

triethylenetetramine LOW (KOC = 309.9)

SECTION 13 Disposal considerations

Waste treatment methods

Product / Packaging disposal

Containers may still present a chemical hazard/ danger when empty. Return to supplier for reuse/ recycling if possible.

Otherwise:If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the sameproduct, then puncture containers, to prevent re-use, and bury at an authorised landfill. Where possible retain label warnings and SDS and observe all notices pertaining to the product. DO NOT allow wash water from cleaning or process equipment to enter drains. It may be necessary to collect all wash water for treatment before disposal. In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first. Where in doubt contact the responsible authority. Recycle wherever possible or consult manufacturer for recycling options. Consult State Land Waste Authority for disposal. Bury or incinerate residue at an approved site. Recycle containers if possible, or dispose of in an authorised landfill.

SECTION 14 Transport information

Labels Required

Marine Pollutant NO

HAZCHEM Not Applicable

Land transport (ADG): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Transport in bulk according to Annex II of MARPOL and the IBC code

Not Applicable

SECTION 15 Regulatory information

Safety, health and environmental regulations / legislation specific for the substance or mixture

aluminium powder uncoated is found on the following regulatory lists

Australia Hazardous Chemical Information System (HCIS) - Hazardous Chemicals Australian Inventory of Industrial Chemicals (AIIC)

silica crystalline - quartz is found on the following regulatory lists



Chemical Footprint Project - Chemicals of High Concern List

International Agency for Research on Cancer (IARC) - Agents Classified by the IARCMonographs

International Agency for Research on Cancer (IARC) - Agents Classified by the IARCMonographs - Group 1 : Carcinogenic to humans

p-tert-butylphenol is found on the following regulatory lists




barium sulfate is found on the following regulatory lists


diethylenetriamine is found on the following regulatory lists

Chemwatch: 5420-93

Version No: 2.1.1.1

Page 10 of 11




Continued...

Australia Hazardous Chemical Information System (HCIS) - Hazardous Chemicals Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) -Schedule 5


triethylenetetramine is found on the following regulatory lists







Australia - AIIC Yes

Australia Non-Industrial Use No (aluminium powder uncoated; silica crystalline - quartz; p-tert-butylphenol; barium sulfate; diethylenetriamine; triethylenetetramine)

Canada - DSL Yes

Canada - NDSL No (aluminium powder uncoated; silica crystalline - quartz; p-tert-butylphenol; barium sulfate; diethylenetriamine; triethylenetetramine)

China - IECSC Yes

Europe - EINEC / ELINCS / NLP Yes

Japan - ENCS No (aluminium powder uncoated)

Korea - KECI Yes

New Zealand - NZIoC Yes

Philippines - PICCS Yes

USA - TSCA Yes

Taiwan - TCSI Yes

Mexico - INSQ Yes

Vietnam - NCI Yes

Russia - ARIPS Yes

Legend:Yes = All CAS declared ingredients are on the inventoryNo = One or more of the CAS listed ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)

SECTION 16 Other information

Revision Date 28/08/2020

Initial Date 28/08/2020

Other information

Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classificationcommittee using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace orother settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.

Definitions and abbreviations

PC－TWA: Permissible Concentration-Time Weighted AveragePC－STEL: Permissible Concentration-Short Term Exposure LimitIARC: International Agency for Research on CancerACGIH: American Conference of Governmental Industrial HygienistsSTEL: Short Term Exposure LimitTEEL: Temporary Emergency Exposure Limit。IDLH: Immediately Dangerous to Life or Health ConcentrationsOSF: Odour Safety FactorNOAEL :No Observed Adverse Effect LevelLOAEL: Lowest Observed Adverse Effect LevelTLV: Threshold Limit ValueLOD: Limit Of DetectionOTV: Odour Threshold ValueBCF: BioConcentration FactorsBEI: Biological Exposure Index

This document is copyright.Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process withoutwritten permission from CHEMWATCH.TEL (+61 3) 9572 4700.

Chemwatch: 5420-93

Version No: 2.1.1.1

Page 11 of 11




end of SDS

metal loaded epoxy putty - resin #850-978 · metal loaded epoxy putty - resin #850-978 chemwatch:...

Documents