devcon flexane 80 putty resin - ehs.cranesville.comd045).pdf · devcon flexane 80 putty resin...

ITW POLYMERS & FLUIDS (NZ) Chemwatch Hazard Alert Code: 2

Devcon Flexane 80 Putty Resin

Chemwatch: 21588

Version No: 8.1.1.1

Safety Data Sheet according to HSNO Regulations

Issue Date: 21/10/2015

Print Date: 22/06/2016

Initial Date: Not Available

S.GHS.NZL.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier

Product name Devcon Flexane 80 Putty Resin

Synonyms Product Code: D15820

Other means ofidentification

Not Available

Relevant identified uses of the substance or mixture and uses advised against

Relevant identifieduses

The use of a quantity of material in an unventilated or confined space may result in increased exposure and an irritatingatmosphere developing. Before starting consider control of exposure by mechanical ventilation.Requires that the two parts be mixed by hand or mixer before use, in accordance with manufacturers directions. Mix only as

much as is required. Do not return the mixed material to the original containers

CONTAINS free organic isocyanate. Mixing and application requires special precautions and use of personal protective gear[APMF]

Persons with a history of asthma or other respiratory problems or are known to be sensitised, should not be engaged in anywork involving the handling of isocyanates. [CCTRADE-Bayer, APMF]

Details of the supplier of the safety data sheet

Registered companyname

ITW POLYMERS & FLUIDS (NZ) ITW POLYMERS & FLUIDS

Address 2/38 Trugood Drive East Tamaki Auckland 2013 New Zealand 100 Hassall Street, Wetherill Park NSW 2164 Australia

Telephone +64 9 272 1945 +61 2 9757 8800

Fax +64 9 273 6489 +61 2 9757 3855

Website www.itwpf.co.nz www.itwpf.com.au

Email Not Available Not Available

Emergency telephone number

Association /Organisation

Not Available Not Available

Emergency telephonenumbers

+800 2436 2255 1800 039 008

Other emergencytelephone numbers

Not Available +61 3 9573 3112

CHEMWATCH EMERGENCY RESPONSE

Primary Number Alternative Number 1 Alternative Number 2

+800 2436 2255 +612 9186 1132 Not Available

Once connected and if the message is not in your prefered language then please dial 01

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

Considered a Hazardous Substance according to the criteria of the New Zealand Hazardous Substances New Organisms legislation.Not regulated for transport of Dangerous Goods.

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Classification [1]Acute Toxicity (Inhalation) Category 4, Skin Corrosion/Irritation Category 2, Eye Irritation Category 2A, Respiratory SensitizerCategory 1, Skin Sensitizer Category 1, Carcinogenicity Category 2, Specific target organ toxicity - single exposureCategory 3 (respiratory tract irritation)

Legend:1. Classified by Chemwatch; 2. Classification drawn from CCID EPA NZ ; 3. Classification drawn from EC Directive 1272/2008 -Annex VI

Determined byChemwatch using

GHS/HSNO criteria6.1D (inhalation), 6.3A, 6.4A, 6.5A (respiratory), 6.5B (contact), 6.7B, 6.9 (respiratory)

Label elements

GHS label elements

SIGNAL WORD DANGER

Hazard statement(s)

H332 Harmful if inhaled.

H315 Causes skin irritation.

H319 Causes serious eye irritation.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317 May cause an allergic skin reaction.

H351 Suspected of causing cancer.

H335 May cause respiratory irritation.

Precautionary statement(s) Prevention

P201 Obtain special instructions before use.

P261 Avoid breathing mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary statement(s) Response

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.

P362 Take off contaminated clothing and wash before reuse.

Precautionary statement(s) Storage

P405 Store locked up.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Precautionary statement(s) Disposal

P501 Dispose of contents/container in accordance with local regulations.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

SubstancesSee section below for composition of Mixtures

Mixtures

CAS No %[weight] Name

25791-96-2 63.5-70.1

5124-30-1 22.9-25.3

101-68-8 4.9-5.5

polypropylene glycol glyceryl ether

methylene bis(4-cyclohexylisocyanate)

4,4'-diphenylmethane diisocyanate (MDI)

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9016-87-9 2.5-2.7

Not Available 0.9-1 trade secret ingredient

SECTION 4 FIRST AID MEASURES

NZ Poisons Centre 0800 POISON (0800 764 766) | NZ Emergency Services: 111

Description of first aid measures

Eye Contact

If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionallylifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact

If skin contact occurs:Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.

Inhalation

If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aidprocedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocketmask as trained. Perform CPR if necessary. Transport to hospital, or doctor, without delay.

Following uptake by inhalation, move person to an area free from risk of further exposure. Oxygen or artificial respirationshould be administered as needed. Asthmatic-type symptoms may develop and may be immediate or delayed up to severalhours. Treatment is essentially symptomatic. A physician should be consulted.

Ingestion

If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway andprevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice.

Indication of any immediate medical attention and special treatment neededFor sub-chronic and chronic exposures to isocyanates:

This material may be a potent pulmonary sensitiser which causes bronchospasm even in patients without prior airway hyperreactivity. Clinical symptoms of exposure involve mucosal irritation of respiratory and gastrointestinal tracts. Conjunctival irritation, skin inflammation (erythema, pain vesiculation) and gastrointestinal disturbances occur soon after exposure. Pulmonary symptoms include cough, burning, substernal pain and dyspnoea. Some cross-sensitivity occurs between different isocyanates. Noncardiogenic pulmonary oedema and bronchospasm are the most serious consequences of exposure. Markedly symptomatic patients should receiveoxygen, ventilatory support and an intravenous line. Treatment for asthma includes inhaled sympathomimetics (epinephrine [adrenalin], terbutaline) and steroids. Activated charcoal (1 g/kg) and a cathartic (sorbitol, magnesium citrate) may be useful for ingestion. Mydriatics, systemic analgesics and topical antibiotics (Sulamyd) may be used for corneal abrasions. There is no effective therapy for sensitised workers.

[Ellenhorn and Barceloux; Medical Toxicology]

NOTE: Isocyanates cause airway restriction in naive individuals with the degree of response dependant on the concentration and duration of exposure.They induce smooth muscle contraction which leads to bronchoconstrictive episodes. Acute changes in lung function, such as decreased FEV1, may notrepresent sensitivity.[Karol & Jin, Frontiers in Molecular Toxicology, pp 56-61, 1992]Personnel who work with isocyanates, isocyanate prepolymers or polyisocyanates should have a pre-placement medical examination and periodicexaminations thereafter, including a pulmonary function test. Anyone with a medical history of chronic respiratory disease, asthmatic or bronchial attacks,indications of allergic responses, recurrent eczema or sensitisation conditions of the skin should not handle or work with isocyanates. Anyone whodevelops chronic respiratory distress when working with isocyanates should be removed from exposure and examined by a physician. Further exposuremust be avoided if a sensitivity to isocyanates or polyisocyanates has developed.

SECTION 5 FIREFIGHTING MEASURES

Extinguishing mediaSmall quantities of water in contact with hot liquid may react violently with generation of a large volume of rapidly expanding hot sticky semi-solidfoam. Presents additional hazard when fire fighting in a confined space. Cooling with flooding quantities of water reduces this risk.

MDI oligomer

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Water spray or fog may cause frothing and should be used in large quantities. Foam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide.

Special hazards arising from the substrate or mixture

Fire IncompatibilityAvoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition mayresult

Advice for firefighters

Fire Fighting

Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course. Use water delivered as a fine spray to control fire and cool adjacent area.

Fire/Explosion Hazard

Combustible. Moderate fire hazard when exposed to heat or flame. When heated to high temperatures decomposes rapidly generating vapour which pressures and may then rupture containerswith release of flammable and highly toxic isocyanate vapour. Burns with acrid black smoke and poisonous fumes.

Combustion products include:, carbon dioxide (CO2), isocyanates, and minor amounts of, hydrogen cyanide, nitrogen oxides

(NOx), other pyrolysis products typical of burning organic material Contains low boiling substance: Closed containers mayrupture due to pressure buildup under fire conditions. May emit corrosive fumes. When heated at high temperatures manyisocyanates decompose rapidly generating a vapour which pressurises containers, possibly to the point of rupture. Releaseof toxic and/or flammable isocyanate vapours may then occur

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Minor Spills

Remove all ignition sources. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment.

Major Spills

Liquid Isocyanates and high isocyanate vapour concentrations will penetrate seals on self contained breathing apparatus -SCBA should be used inside encapsulating suit where this exposure may occur.

For isocyanate spills of less than 40 litres (2 m2):Evacuate area from everybody not dealing with the emergency, keep them upwind and prevent further access, removeignition sources and, if inside building, ventilate area as well as possible. Notify supervision and others as necessary. Put on personal protective equipment (suitable respiratory protection, face and eye protection, protective suit, gloves andimpermeable boots). Control source of leakage (where applicable). Avoid contamination with water, alkalies and detergent solutions. Material reacts with water and generates gas, pressurises containers with even drum rupture resulting.

DO NOT reseal container if contamination is suspected. Open all containers with care.

Moderate hazard. Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Safe handling

Contains low boiling substance:Storage in sealed containers may result in pressure buildup causing violent rupture of containers not rated appropriately.

Check for bulging containers. Vent periodically Always release caps or seals slowly to ensure slow dissipation of vapours

DO NOT allow clothing wet with material to stay in contact with skinAvoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps.

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Other information

for commercial quantities of isocyanates:Isocyanates should be stored in adequately bunded areas. Nothing else should be kept within the same bunding.Pre-polymers need not be segregated. Drums of isocyanates should be stored under cover, out of direct sunlight, protectedfrom rain, protected from physical damage and well away from moisture, acids and alkalis.

Rotate all stock to prevent ageing. Use on FIFO (First In-First Out) basisStore in original containers. Keep containers securely sealed. No smoking, naked lights or ignition sources. Store in a cool, dry, well-ventilated area.

Conditions for safe storage, including any incompatibilities

Suitable containerMetal can or drum Packaging as recommended by manufacturer. Check all containers are clearly labelled and free from leaks.

Storageincompatibility

Avoid cross contamination between the two liquid parts of product (kit). If two part products are mixed or allowed to mix in proportions other than manufacturer's recommendation, polymerisationwith gelation and evolution of heat (exotherm) may occur. This excess heat may generate toxic vapour Avoid reaction with water, alcohols and detergent solutions. Isocyanates and thioisocyanates are incompatible with many classes of compounds, reacting exothermically to releasetoxic gases. Reactions with amines, strong bases, aldehydes, alcohols, alkali metals, ketones, mercaptans, strongoxidisers, hydrides, phenols, and peroxides can cause vigorous releases of heat. Acids and bases initiate polymerisationreactions in these materials. A range of exothermic decomposition energies for isocyanates is given as 20-30 kJ/mol. The relationship between energy of decomposition and processing hazards has been the subject of discussion; it issuggested that values of energy released per unit of mass, rather than on a molar basis (J/g) be used in the assessment. For example, in "open vessel processes" (with man-hole size openings, in an industrial setting), substances with exothermicdecomposition energies below 500 J/g are unlikely to present a danger, whilst those in "closed vessel processes" (opening isa safety valve or bursting disk) present some danger where the decomposition energy exceeds 150 J/g.

BRETHERICK: Handbook of Reactive Chemical Hazards, 4th Edition

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes

New Zealand WorkplaceExposure Standards(WES)


Isocyanates,all, (as -NCO)

0.02mg/m3

0.07mg/m3

NotAvailable

Sensitiser; These values apply to allisocyanates, including prepolymers,present in the workplace air asvapours, mist or dust.


4,4'-diphenylmethanediisocyanate (MDI)

Isocyanates,all, (as -NCO)

0.02mg/m3

0.07mg/m3

NotAvailable



MDI oligomerIsocyanates,all, (as -NCO)

0.02mg/m3

0.07mg/m3

NotAvailable


EMERGENCY LIMITS

Ingredient Material name TEEL-1 TEEL-2 TEEL-3


Methylene bis(4-isocyanatocyclohexane), 1,1'- 0.005 ppm 0.01 ppm 0.13 ppm


Methylene diphenyl diisocyanate; (Diphenylmethane diisocyanate; MDI)0.45mg/m3

NotAvailable

NotAvailable


Methylenebis(isocyanato-benzene), 1,1'-; (Diphenyl methane diisocyanate) 40 mg/m3 40 mg/m3 240 mg/m3

MDI oligomerPolymethylene polyphenyl isocyanate; (Polymeric diphenylmethanediisocyanate)

0.15mg/m3

0.26 mg/m3 22 mg/m3

Ingredient Original IDLH Revised IDLH

polypropylene glycolglyceryl ether


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100 mg/m3 75 mg/m3

MDI oligomer Not Available Not Available

trade secret ingredient Not Available Not Available

Exposure controls

Appropriateengineering controls

All processes in which isocyanates are used should be enclosed wherever possible. Total enclosure, accompanied by good general ventilation, should be used to keep atmospheric concentrations below therelevant exposure standards. If total enclosure of the process is not feasible, local exhaust ventilation may be necessary. Local exhaust ventilation isessential where lower molecular weight isocyanates (such as TDI or HDI) is used or where isocyanate or polyurethane issprayed.

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designedengineering controls can be highly effective in protecting workers and will typically be independent of worker interactions toprovide this high level of protection.The basic types of engineering controls are:Process controls which involve changing the way a job activity or process is done to reduce the risk.Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker andventilation that strategically "adds" and "removes" air in the work environment.Refer also to protective measures for the other component used with the product. Read both SDS before using; store andattach SDS together.

Personal protection

Eye and faceprotection

Safety glasses with side shields.Chemical goggles.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policydocument, describing the wearing of lenses or restrictions on use, should be created for each workplace or task.

Skin protection See Hand protection below

Hands/feet protection

NOTE:The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves andother protective equipment, to avoid all possible skin contact. Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.

The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary frommanufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glovematerial can not be calculated in advance and has therefore to be checked prior to the application.The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.has tobe observed when making a final choice.Suitability and durability of glove type is dependent on usage.

Do NOT wear natural rubber (latex gloves). Isocyanate resistant materials include Teflon, Viton, nitrile rubber and some PVA gloves. Protective gloves and overalls should be worn as specified in the appropriate national standard. Contaminated garments should be removed promptly and should not be re-used until they have been decontaminated. NOTE: Natural rubber, neoprene, PVC can be affected by isocyanates

DO NOT use skin cream unless necessary and then use only minimum amount. Isocyanate vapour may be absorbed into skin cream and this increases hazard.

Body protection See Other protection below

Other protection

All employees working with isocyanates must be informed of the hazards from exposure to the contaminant and theprecautions necessary to prevent damage to their health. They should be made aware of the need to carry out their work sothat as little contamination as possible is produced, and of the importance of the proper use of all safeguards againstexposure to themselves and their fellow workers. Adequate training, both in the proper execution of the task and in the use ofall associated engineering controls, as well as of any personal protective equipment, is essential.Employees exposed to contamination hazards should be educated in the need for, and proper use of, facilities, clothing andequipment and thereby maintain a high standard of personal cleanliness.

Overalls. P.V.C. apron. Barrier cream.

Thermal hazards Not Available

Respiratory protectionType A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)

Cartridge respirators should never be used for emergency ingress or in areas of unknown vapour concentrations or oxygen content. The wearer must be

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warned to leave the contaminated area immediately on detecting any odours through the respirator. The odour may indicate that the mask is notfunctioning properly, that the vapour concentration is too high, or that the mask is not properly fitted. Because of these limitations, only restricted use ofcartridge respirators is considered appropriate.

In certain circumstances, personal protection of the individual employee is necessary. Personal protective devices should be regarded as beingsupplementary to substitution and engineering control and should not be used in preference to them as they do nothing to eliminate the hazard. However, in some situations, minimising exposure to isocyanates by enclosure and ventilation is not possible, and occupational exposure standardsmay be exceeded, particularly during on-site mixing of paints, spray-painting, foaming and maintenance of machine and ventilation systems. In thesesituations, air-line respirators or self-contained breathing apparatus complying with the appropriate nationals standard must be used. Organic vapour respirators with particulate pre- filters and powered, air-purifying respirators are NOT suitable. Personal protective equipment must be appropriately selected, individually fitted and workers trained in their correct use and maintenance. Personalprotective equipment must be regularly checked and maintained to ensure that the worker is being protected. Air- line respirators or self-contained breathing apparatus complying with the appropriate national standard should be used during the clean-up of spillsand the repair or clean-up of contaminated equipment and similar situations which cause emergency exposures to hazardous atmospheric concentrationsof isocyanate.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance Clear liquid with slightly musty odour; does not mix with water.

Physical state LiquidRelative density

(Water = 1)1.1

Odour Not AvailablePartition coefficient

n-octanol / waterNot Available

Odour threshold Not AvailableAuto-ignition

temperature (°C)Not Available

pH (as supplied) Not ApplicableDecomposition

temperatureNot Available

Melting point /freezing point (°C)

Not Available Viscosity (cSt) Not Available

Initial boiling pointand boiling range (°C)

>204.4Molecular weight

(g/mol)Not Applicable

Flash point (°C) 233.8 (PMCC) Taste Not Available

Evaporation rate Not Available Explosive properties Not Available

Flammability Not Applicable Oxidising properties Not Available

Upper Explosive Limit(%)

Not AvailableSurface Tension

(dyn/cm or mN/m)Not Available

Lower Explosive Limit(%)

Not AvailableVolatile Component

(%vol)0

Vapour pressure (kPa) <1.333 @ 25C Gas group Not Available

Solubility in water(g/L)

Immiscible pH as a solution (1%) Not Applicable

Vapour density (Air =1)

8.5 (MDI) VOC g/L Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity See section 7

Chemical stabilityUnstable in the presence of incompatible materials.Product is considered stable.Hazardous polymerisation will not occur.

Possibility ofhazardous reactions

See section 7

Conditions to avoid See section 7

Incompatible materials See section 7

Hazardousdecomposition

productsSee section 5

SECTION 11 TOXICOLOGICAL INFORMATION

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Information on toxicological effects

Inhaled

The material can cause respiratory irritation in some persons. The body's response to such irritation can cause further lungdamage.The vapour/mist may be highly irritating to the upper respiratory tract and lungs; the response may be severe enough toproduce bronchitis and pulmonary oedema. Possible neurological symptoms arising from isocyanate exposure includeheadache, insomnia, euphoria, ataxia, anxiety neurosis, depression and paranoia. Gastrointestinal disturbances arecharacterised by nausea and vomiting. Pulmonary sensitisation may produce asthmatic reactions ranging from minorbreathing difficulties to severe allergic attacks; this may occur following a single acute exposure or may develop withoutwarning for several hours after exposure.Animal testing shows that when inhaled, high doses of methylenebis(4-cyclohxylisocyanate) causes marked airway irritationwith tremors and convulsions, and severe fluid build-up and congestion in the lungs. Inhaling high concentrations of vapourcan cause chest tightness, shortness of breath, breathing difficulty, cough and dry throat, airway inflammation with anasthma-like wheeze and lung inflammation, and these symptoms can be delayed several hours. Airway sensitisation canoccur n both allergy-prone and non-allergy-prone people, with symptoms as described above. Sensitised individuals shouldnot work with or near this material.

Ingestion Accidental ingestion of the material may be damaging to the health of the individual.

Skin Contact

This material can cause inflammation of the skin on contact in some persons.The material may accentuate any pre-existing dermatitis conditionSkin contact with the material may damage the health of the individual; systemic effects may result following absorption.Open cuts, abraded or irritated skin should not be exposed to this materialEntry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmfuleffects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.A 5% solution of methylene bis(4-cyclohexylisocyanate) caused strong erythema and oedema of the skin of guinea pigs.Rabbits treated with 0.1 mg showed severe skin reactions. Skin sensitisation can develop after working with this material foronly a few days. Sensitised individuals may experience symptoms such as an itchy, red, scaly rash and swelling of armsand legs if material comes in contact with unprotected skin.

Eye This material can cause eye irritation and damage in some persons.

Chronic

Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and relatedsystemic problems.Inhaling this product is more likely to cause a sensitisation reaction in some persons compared to the general population.Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the generalpopulation.Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-termoccupational exposure.There has been concern that this material can cause cancer or mutations, but there is not enough data to make anassessment.

Persons with a history of asthma or other respiratory problems or are known to be sensitised, should not be engaged in anywork involving the handling of isocyanates. [CCTRADE-Bayer, APMF]Animal testing shows that polymeric MDI can damage the nasal cavities and lungs, causing inflammation.and increased cellgrowth.This product contains a polymer with a functional group considered to be of high concern. Isothiocyanates may causehypersensitivity of the skin and airways.Isocyanate vapours are irritating to the airways and can cause their inflammation, with wheezing, gasping, severe distress,even loss of consciousness and fluid in the lungs. Nervous system symptoms that may occur include headache, sleepdisturbance, euphoria, inco-ordination, anxiety, depression and paranoia.Sensitisation may give severe responses to very low levels of exposure, i.e. hypersensitivity.

Devcon Flexane 80Putty Resin

TOXICITY IRRITATION



TOXICITY IRRITATION

dermal (rat) LD50: >2000 mg/kg[1] Eye: non-irritant *

Inhalation (rat) LC50: >200 mg/L/h *[2] Skin (rabbit): 500 mg (open)-mild

Oral (rat) LD50: >64640 mg/kg[2]


TOXICITY IRRITATION

dermal (rat) LD50: >7000 mg/kg[1] *[Bayer]

Inhalation (rat) LC50: 0.295 mg/L/4h *[2] Eye (rabbit): slight irritant*

Inhalation (rat) LC50: 0.307 mg/L/4h *[2] Skin (guinea pig): sensitiser*

Oral (rat) LD50: 18020 mg/kg[1]


TOXICITY IRRITATION

Dermal (rabbit) LD50: >6200 mg/kg[2] [* = Bayer CCINFO 2133615]

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Inhalation (rat) LC50: 0.49 mg/l/4hr[1] Dermal Sensitiser *

Oral (rat) LD50: >2000 mg/kg[1] Respiratory Sensitiser (g.pig) *

Skin (rabbit): 500 mg /24 hours

MDI oligomer

TOXICITY IRRITATION

Dermal (rabbit) LD50: >9400 mg/kg[2] Eye (rabbit): 100 mg - mild

Inhalation (rat) LC50: 0.49 mg/L/4hr[2]


Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

POLYPROPYLENE GLYCOLGLYCERYL ETHER

The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness,swelling, the production of vesicles, scaling and thickening of the skin.Data for Niax Polyol L-56 Data for Niax Polyol LG-168 * BASF Multranol 9175 SDS

METHYLENE BIS(4-CYCLOHEXYLISOCYANATE)

The following information refers to contact allergens as a group and may not be specific to this product. Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. Thepathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Otherallergic skin reactions, e.g. contact urticaria, involve antibody-mediated immune reactions.

Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be dueto a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur followingexposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence ofpreceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms withinminutes to hours of a documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presenceof moderate to severe bronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocyticinflammation, without eosinophilia, have also been included in the criteria for diagnosis of RADS.Allergic reactions involving the respiratory tract are usually due to interactions between IgE antibodies and allergens andoccur rapidly. Allergic potential of the allergen and period of exposure often determine the severity of symptoms. Somepeople may be genetically more prone than others, and exposure to other irritants may aggravate symptoms. Allergycausing activity is due to interactions with proteins.Attention should be paid to atopic diathesis, characterised by increased susceptibility to nasal inflammation, asthma andeczema.Exogenous allergic alveolitis is induced essentially by allergen specific immune-complexes of the IgG type; cell-mediatedreactions (T lymphocytes) may be involved. Such allergy is of the delayed type with onset up to four hours followingexposure.Isocyanate vapours are irritating to the airways and can cause their inflammation, with wheezing, gasping, severedistress, even loss of consciousness and fluid in the lungs. Nervous system symptoms that may occur includeheadache, sleep disturbance, euphoria, inco-ordination, anxiety, depression and paranoia.The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposureto irritants may produce conjunctivitis.Aromatic and aliphatic diisocyanates may cause airway toxicity and skin sensitization. Monomers and prepolymersexhibit similar respiratory effect. Of the several members of diisocyanates tested on experimental animals by inhalationand oral exposure, some caused cancer while others produced a harmless outcome. This group of compounds hastherefore been classified as cancer-causing.Inhalation (Rat, adult female) LC50: 307 mg/m3/4h * Inhalation (Rat, adult male) LC50: 295 mg/m3/4h * * Vendor MSDS

4,4'-DIPHENYLMETHANEDIISOCYANATE (MDI)


Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be dueto a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur followingexposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence ofpreceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms withinminutes to hours of a documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presenceof moderate to severe bronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocyticinflammation, without eosinophilia, have also been included in the criteria for diagnosis of RADS.Allergic reactions involving the respiratory tract are usually due to interactions between IgE antibodies and allergens andoccur rapidly. Allergic potential of the allergen and period of exposure often determine the severity of symptoms. Somepeople may be genetically more prone than others, and exposure to other irritants may aggravate symptoms. Allergycausing activity is due to interactions with proteins.Attention should be paid to atopic diathesis, characterised by increased susceptibility to nasal inflammation, asthma andeczema.Exogenous allergic alveolitis is induced essentially by allergen specific immune-complexes of the IgG type; cell-mediatedreactions (T lymphocytes) may be involved. Such allergy is of the delayed type with onset up to four hours followingexposure.

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Legend: – Data available but does not fill the criteria for classification – Data required to make classification available – Data Not Available to make classification

The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritantsmay produce conjunctivitis.Aromatic and aliphatic diisocyanates may cause airway toxicity and skin sensitization. Monomers and prepolymers exhibitsimilar respiratory effect. Of the several members of diisocyanates tested on experimental animals by inhalation and oralexposure, some caused cancer while others produced a harmless outcome. This group of compounds has therefore beenclassified as cancer-causing.Isocyanate vapours are irritating to the airways and can cause their inflammation, with wheezing, gasping, severedistress, even loss of consciousness and fluid in the lungs. Nervous system symptoms that may occur includeheadache, sleep disturbance, euphoria, inco-ordination, anxiety, depression and paranoia.The substance is classified by IARC as Group 3:

NOT classifiable as to its carcinogenicity to humans.Evidence of carcinogenicity may be inadequate or limited in animal testing.Inhalation (human) TCLo: 0.13 ppm/30 mins Eye (rabbit): 0.10 mg moderate

MDI OLIGOMER


Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be dueto a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur followingexposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence ofpreceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms withinminutes to hours of a documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presenceof moderate to severe bronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocyticinflammation, without eosinophilia, have also been included in the criteria for diagnosis of RADS.Allergic reactions involving the respiratory tract are usually due to interactions between IgE antibodies and allergens andoccur rapidly. Allergic potential of the allergen and period of exposure often determine the severity of symptoms. Somepeople may be genetically more prone than others, and exposure to other irritants may aggravate symptoms. Allergycausing activity is due to interactions with proteins.Attention should be paid to atopic diathesis, characterised by increased susceptibility to nasal inflammation, asthma andeczema.Exogenous allergic alveolitis is induced essentially by allergen specific immune-complexes of the IgG type; cell-mediatedreactions (T lymphocytes) may be involved. Such allergy is of the delayed type with onset up to four hours followingexposure.Isocyanate vapours are irritating to the airways and can cause their inflammation, with wheezing, gasping, severedistress, even loss of consciousness and fluid in the lungs. Nervous system symptoms that may occur includeheadache, sleep disturbance, euphoria, inco-ordination, anxiety, depression and paranoia.The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritantsmay produce conjunctivitis.Aromatic and aliphatic diisocyanates may cause airway toxicity and skin sensitization. Monomers and prepolymersexhibit similar respiratory effect. Of the several members of diisocyanates tested on experimental animals by inhalationand oral exposure, some caused cancer while others produced a harmless outcome. This group of compounds hastherefore been classified as cancer-causing.The substance is classified by IARC as Group 3:

NOT classifiable as to its carcinogenicity to humans.Evidence of carcinogenicity may be inadequate or limited in animal testing.product

Acute Toxicity Carcinogenicity

SkinIrritation/Corrosion

Reproductivity

Serious EyeDamage/Irritation

STOT - SingleExposure

Respiratory or Skinsensitisation

STOT - RepeatedExposure

Mutagenicity Aspiration Hazard

SECTION 12 ECOLOGICAL INFORMATION

Toxicity

Ingredient Endpoint Test Duration (hr) Species Value Source


LC50 96 Fish >1000mg/L 2

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EC50 48 Crustacea >100mg/L 2


NOEC 504 Crustacea >=10mg/L 2


EC50 72 Algae or other aquatic plants >100mg/L 2


LC50 96 Fish 0.69mg/L 1




NOEC 72 Algae or other aquatic plants 0.31mg/L 2


LC50 96 Fish >0.500mg/L 6


EC50 24 Crustacea 129.7mg/L 2


NOEC 504 Crustacea >=10mg/L 2



Legend:

Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity3. EPIWIN Suite V3.12 - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOCAquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. VendorData

for polyisocyanates:Polyisocyanates are not readily biodegradable. However, due to other elimination mechanisms (hydrolysis, adsorption), long retention times in water arenot to be expected. The resulting polyurea is more or less inert and, due to its molecular size, not bioavailable. Within the limits of water solubility,polyisocyanates have a low to moderate toxicity for aquatic organisms.For Isocyanate Monomers:Environmental Fate: Isocyanates, (di- and polyfunctional isocyanates), are commonly used to make various polymers, such as polyurethanes.Polyurethanes find significant application in the manufacture of rigid and flexible foams. They are also used in the production of adhesives, elastomers,and coatings. Atmospheric Fate: These substances are not expected to be removed from the air via precipitation washout or dry deposition. for methylene bis(4-cyclohexylisocyanate):Fish toxicity:Acute (Brachydanio rerio) LC0: 0.69 mg/l/96h*Acute (Brachydanio rerio) LC50: 1.20 mg/l/96h*Acute (Brachydanio rerio) LC100: 2.76 mg/l96h*Bacterial toxicity:Acute EC50: 19mg/L*- The product reacts with water at the interface forming CO2 and a solid insoluble product with high melting point (polyurea). This reaction is acceleratedby surfactants (eg. detergents) or by water soluble solvents.**[Bayer]Persistence: does not meet the P criterion for aquatic environment due to a fast hydrolysis. The expected hydrolysis product under environmentalconditions is 4,4�-diaminodicyclohexylmethane (CAS 1761-71-3). This substance is not considered inherently biodegradable and it is therefore consideredfulfilling the screening P/vP criteria.

DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air


HIGH HIGH


LOW (Half-life = 1 days) LOW (Half-life = 0.24 days)

Bioaccumulative potential

Ingredient Bioaccumulation


LOW (BCF = 7)


HIGH (LogKOW = 6.1145)


LOW (BCF = 15)

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Mobility in soil

Ingredient Mobility


LOW (KOC = 376200)


LOW (KOC = 376200)

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

Product / Packagingdisposal

Recycle wherever possible or consult manufacturer for recycling options. Consult State Land Waste Management Authority for disposal. Material may be disposed of by controlled burning in an approved incinerator or buried in an approved landfill. Prior to disposal in a landfill the material should be mixed with the other component and reacted to render the material inert.

Ensure that the disposal of material is carried out in accordance with Hazardous Substances (Disposal) Regulations 2001.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant NO

HAZCHEM Not Applicable

Land transport (UN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

Transport in bulk according to Annex II of MARPOL and the IBC codeNot Applicable

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixtureThis substance is to be managed using the conditions specified in an applicable Group Standard

HSR Number Group Standard

HSR002679 Surface Coatings and Colourants (Toxic [6.7]) Group Standard 2006

POLYPROPYLENE GLYCOL GLYCERYL ETHER(25791-96-2) IS FOUND ON THE FOLLOWING REGULATORY LISTS

New Zealand Hazardous Substances and New Organisms (HSNO) Act -Classification of Chemicals

New Zealand Inventory of Chemicals (NZIoC)

METHYLENE BIS(4-CYCLOHEXYLISOCYANATE)(5124-30-1) IS FOUND ON THE FOLLOWING REGULATORY LISTS



New Zealand Workplace Exposure Standards (WES)

4,4'-DIPHENYLMETHANE DIISOCYANATE (MDI)(101-68-8) IS FOUND ON THE FOLLOWING REGULATORY LISTS

International Agency for Research on Cancer (IARC) - Agents Classifiedby the IARC Monographs




MDI OLIGOMER(9016-87-9) IS FOUND ON THE FOLLOWING REGULATORY LISTS





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Location Test CertificateSubject to Regulation 55 of the Hazardous Substances (Classes 1 to 5 Controls) Regulations, a location test certificate is required when quantity greaterthan or equal to those indicated below are present.

Hazard ClassQuantity beyond which controls apply for closedcontainers

Quantity beyond which controls apply when use occurring inopen containers

Not Applicable Not Applicable Not Applicable

Approved HandlerSubject to Regulation 56 of the Hazardous Substances (Classes 1 to 5 Controls) Regulations and Regulation 9 of the Hazardous Substances (Classes 6,8, and 9 Controls) Regulations, the substance must be under the personal control of an Approved Handler when present in a quantity greater than orequal to those indicated below.

Class of substance Quantities

Not Applicable Not Applicable

Refer Group Standards for further information

Tracking RequirementsNot Applicable

National Inventory Status

Australia - AICS Y

Canada - DSL Y

Canada - NDSL N (polypropylene glycol glyceryl ether; 4,4'-diphenylmethane diisocyanate (MDI); MDI oligomer)

China - IECSC Y

Europe - EINEC /ELINCS / NLP

N (MDI oligomer)

Japan - ENCS Y

Korea - KECI Y

New Zealand - NZIoC Y

Philippines - PICCS Y

USA - TSCA Y

Legend:Y = All ingredients are on the inventoryN = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredientsin brackets)

SECTION 16 OTHER INFORMATION

Other information

Ingredients with multiple cas numbers

Name CAS No


25791-96-2, 37239-38-6, 51938-80-8, 68518-66-1, 9062-54-8


103072-21-5, 107314-16-9, 123773-48-8, 135822-12-7, 13622-90-7, 190601-97-9, 201536-77-8, 5124-30-1, 68966-63-2,73156-15-7, 88504-76-1


101-68-8, 26447-40-5

Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by theChemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at: www.chemwatch.net

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards areRisks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current oravailable engineering controls must be considered.

This document is copyright.Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may bereproduced by any process without written permission from CHEMWATCH.TEL (+61 3) 9572 4700.

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ITW POLYMERS & FLUIDS (NZ) Chemwatch Hazard Alert Code: 2

Devcon Flexane 80 Putty Curing Agent

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Safety Data Sheet according to HSNO Regulations



Initial Date: Not Available

S.GHS.NZL.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier

Product name Devcon Flexane 80 Putty Curing Agent

Synonyms Not Available

Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (diethyltoluenediamine)

Other means ofidentification

Not Available

Relevant identified uses of the substance or mixture and uses advised against

Relevant identifieduses

The use of a quantity of material in an unventilated or confined space may result in increased exposure and an irritatingatmosphere developing. Before starting consider control of exposure by mechanical ventilation.Curing agent component of two part polyurethane system.

Details of the supplier of the safety data sheet

Registered companyname

ITW POLYMERS & FLUIDS (NZ) ITW POLYMERS & FLUIDS

Address 2/38 Trugood Drive East Tamaki Auckland 2013 New Zealand 100 Hassall Street, Wetherill Park NSW 2164 Australia

Telephone +64 9 272 1945 +61 2 9757 8800

Fax +64 9 273 6489 +61 2 9757 3855

Website www.itwpf.co.nz www.itwpf.com.au

Email Not Available Not Available

Emergency telephone number

Association /Organisation


Emergency telephonenumbers

+800 2436 2255 1800 039 008

Other emergencytelephone numbers

Not Available +61 3 9573 3112

CHEMWATCH EMERGENCY RESPONSE

Primary Number Alternative Number 1 Alternative Number 2

+800 2436 2255 +612 9186 1132 Not Available

Once connected and if the message is not in your prefered language then please dial 01

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

Considered a Hazardous Substance according to the criteria of the New Zealand Hazardous Substances New Organisms legislation.Classified as Dangerous Goods for transport purposes.

Classification [1] Acute Toxicity (Oral) Category 4, Acute Toxicity (Dermal) Category 4, Eye Irritation Category 2A, Specific target organtoxicity - repeated exposure Category 2, Acute Aquatic Hazard Category 1, Chronic Aquatic Hazard Category 1

Legend:1. Classified by Chemwatch; 2. Classification drawn from CCID EPA NZ ; 3. Classification drawn from EC Directive 1272/2008 -Annex VI

Continued...

Determined byChemwatch using

GHS/HSNO criteria6.1D (dermal), 6.1D (oral), 6.4A, 6.9B (oral), 9.1A

Label elements

GHS label elements

SIGNAL WORD WARNING

Hazard statement(s)

H302 Harmful if swallowed.

H312 Harmful in contact with skin.

H319 Causes serious eye irritation.

H373 May cause damage to organs.

H410 Very toxic to aquatic life with long lasting effects.

Precautionary statement(s) Prevention

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P270 Do not eat, drink or smoke when using this product.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary statement(s) Response

P363 Wash contaminated clothing before reuse.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313 If eye irritation persists: Get medical advice/attention.

P391 Collect spillage.

Precautionary statement(s) StorageNot Applicable

Precautionary statement(s) Disposal

P501 Dispose of contents/container in accordance with local regulations.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

SubstancesSee section below for composition of Mixtures

Mixtures

CAS No %[weight] Name

27138-31-4 45.6-50.4

68479-98-1 37-40.9

8013-07-8 4.2-4.7

32686-95-6 2.5-2.8

1333-86-4 1.8-2

197178-94-2 1-1.1

19224-26-1 1-1.1

SECTION 4 FIRST AID MEASURES

NZ Poisons Centre 0800 POISON (0800 764 766) | NZ Emergency Services: 111

dipropylene glycol dibenzoate

diethyltoluenediamine

soybean oil, epoxidised

dipropylene glycol monobenzoate

carbon black

(2-propenyloxy)propylbenzoate

propylene glycol dibenzoate

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Description of first aid measures

Eye Contact

If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionallylifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact

If skin contact occurs:Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation.

Inhalation

If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aidprocedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocketmask as trained. Perform CPR if necessary. Transport to hospital, or doctor.

Ingestion

If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway andprevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Seek medical advice.

Indication of any immediate medical attention and special treatment neededTreat symptomatically.The material may induce methaemoglobinaemia following exposure.

Initial attention should be directed at oxygen delivery and assisted ventilation if necessary. Hyperbaric oxygen has not demonstrated substantialbenefits. Hypotension should respond to Trendelenburg's position and intravenous fluids; otherwise dopamine may be needed. Symptomatic patients with methaemoglobin levels over 30% should receive methylene blue. (Cyanosis, alone, is not an indication for treatment). Theusual dose is 1-2 mg/kg of a 1% solution (10 mg/ml) IV over 50 minutes; repeat, using the same dose, if symptoms of hypoxia fail to subside within 1hour. Thorough cleansing of the entire contaminated area of the body, including the scalp and nails, is of utmost importance.

BIOLOGICAL EXPOSURE INDEX - BEIThese represent the determinants observed in specimens collected from a healthy worker exposed at the Exposure Standard (ES or TLV):Determinant Index Sampling Time Comment1. Methaemoglobin in blood 1.5% of haemoglobin During or end of shift B, NS, SQ

B: Background levels occur in specimens collected from subjects NOT exposedNS: Non-specific determinant; also observed after exposure to other materialsSQ: Semi-quantitative determinant - Interpretation may be ambiguous; should be used as a screening test or confirmatory test.

SECTION 5 FIREFIGHTING MEASURES

Extinguishing mediaFoam. Dry chemical powder. BCF (where regulations permit). Carbon dioxide.

Special hazards arising from the substrate or mixture

Fire IncompatibilityAvoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition mayresult

Advice for firefighters

Fire Fighting

Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course. Use water delivered as a fine spray to control fire and cool adjacent area.

Fire/Explosion Hazard

Combustible. Slight fire hazard when exposed to heat or flame. Heating may cause expansion or decomposition leading to violent rupture of containers. On combustion, may emit toxic fumes of carbon monoxide (CO).

Combustion products include:, carbon dioxide (CO2), nitrogen oxides (NOx), other pyrolysis products typical of burning organic

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material Contains low boiling substance: Closed containers may rupture due to pressure buildup under fire conditions.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Minor Spills

Environmental hazard - contain spillage. Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb spill with sand, earth, inert material or vermiculite.

Major Spills

Environmental hazard - contain spillage. Moderate hazard.

Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Safe handling

Contains low boiling substance:Storage in sealed containers may result in pressure buildup causing violent rupture of containers not rated appropriately.

Check for bulging containers. Vent periodically Always release caps or seals slowly to ensure slow dissipation of vapours

DO NOT USE brass or copper containers / stirrers

DO NOT allow clothing wet with material to stay in contact with skinThe tendency of many ethers to form explosive peroxides is well documented. Ethers lacking non-methyl hydrogen atomsadjacent to the ether link are thought to be relatively safe

DO NOT concentrate by evaporation, or evaporate extracts to dryness, as residues may contain explosive peroxides withDETONATION potential. Any static discharge is also a source of hazard. Before any distillation process remove trace peroxides by shaking with excess 5% aqueous ferrous sulfate solution or bypercolation through a column of activated alumina.

The substance accumulates peroxides which may become hazardous only if it evaporates or is distilled or otherwise treatedto concentrate the peroxides. The substance may concentrate around the container opening for example.Purchases of peroxidisable chemicals should be restricted to ensure that the chemical is used completely before it canbecome peroxidised.

A responsible person should maintain an inventory of peroxidisable chemicals or annotate the general chemical inventory toindicate which chemicals are subject to peroxidation.Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps.

Other information

Store in original containers. Keep containers securely sealed. Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers.

Conditions for safe storage, including any incompatibilities

Suitable container

DO NOT use aluminium, galvanised or tin-plated containersMetal can or drum Packaging as recommended by manufacturer. Check all containers are clearly labelled and free from leaks.

Storageincompatibility

Many arylamines (aromatic amines such as aniline, N-ethylaniline, o-toluidine, xylidine etc. and their mixtures) arehypergolic (ignite spontaneously) with red fuming nitric acid. When the amines are dissolved in triethylamine, ignition occursat -60 deg. C. or less. Various metal oxides and their salts may promote ignition of amine-red fuming nitric acid systems.Glycol ethers may form peroxides under certain conditions; the potential for peroxide formation is enhanced when thesesubstances are used in processes such as distillation where they are concentrated or even evaporated to near-dryness ordryness; storage under a nitrogen atmosphere is recommended to minimise the possible formation of highly reactiveperoxides Nitrogen blanketing is recommended if transported in containers at temperatures within 15 deg C of the flash-point and at orabove the flash-point - large containers may first need to be purged and inerted with nitrogen prior to loading In the presence of strong bases or the salts of strong bases, at elevated temperatures, the potential exists for runawayreactions.

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Contact with aluminium should be avoided; release of hydrogen gas may result- glycol ethers will corrode scratchedaluminium surfaces. May discolour in mild steel/ copper; lined containers, glass or stainless steel is preferred Glycols and their ethers undergo violent decomposition in contact with 70% perchloric acid. This seems likely to involveformation of the glycol perchlorate esters (after scission of ethers) which are explosive, those of ethylene glycol and3-chloro-1,2-propanediol being more powerful than glyceryl nitrate, and the former so sensitive that it explodes on additionof water .Avoid oxidising agents, acids, acid chlorides, acid anhydrides, chloroformates.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes


carbon black Carbon black 3 mg/m3 Not Available Not Available 2011 correction; Suspected carcinogen

EMERGENCY LIMITS

Ingredient Material name TEEL-1 TEEL-2 TEEL-3

carbon black Carbon black 9 mg/m3 99 mg/m3 590 mg/m3

Ingredient Original IDLH Revised IDLH

dipropylene glycol dibenzoate Not Available Not Available

diethyltoluenediamine Not Available Not Available

soybean oil, epoxidised Not Available Not Available

dipropylene glycolmonobenzoate


carbon black N.E. mg/m3 / N.E. ppm 1,750 mg/m3

(2-propenyloxy)propylbenzoate Not Available Not Available

propylene glycol dibenzoate Not Available Not Available

Exposure controls

Appropriateengineering controls

Use in a well-ventilated areaGeneral exhaust is adequate under normal operating conditions.Refer also to protective measures for the other component used with the product. Read both SDS before using; store andattach SDS together.

Personal protection

Eye and faceprotection

Safety glasses with side shields.Chemical goggles.Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policydocument, describing the wearing of lenses or restrictions on use, should be created for each workplace or task.

Skin protection See Hand protection below

Hands/feet protection

Wear chemical protective gloves, e.g. PVC. Wear safety footwear or safety gumboots, e.g. Rubber

NOTE:The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves andother protective equipment, to avoid all possible skin contact. Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.

The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary frommanufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glovematerial can not be calculated in advance and has therefore to be checked prior to the application.The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.has tobe observed when making a final choice.Suitability and durability of glove type is dependent on usage.

Body protection See Other protection below

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Other protectionOveralls. P.V.C. apron. Barrier cream.

Thermal hazards Not Available

Respiratory protectionType AK-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)

Cartridge respirators should never be used for emergency ingress or in areas of unknown vapour concentrations or oxygen content. The wearer must bewarned to leave the contaminated area immediately on detecting any odours through the respirator. The odour may indicate that the mask is notfunctioning properly, that the vapour concentration is too high, or that the mask is not properly fitted. Because of these limitations, only restricted use ofcartridge respirators is considered appropriate.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance Black mobile liquid with mild ammonia-like odour; does not mix with water.

Physical state LiquidRelative density

(Water = 1)1.08

Odour Not AvailablePartition coefficient

n-octanol / waterNot Available

Odour threshold Not AvailableAuto-ignition

temperature (°C)Not Available

pH (as supplied) Not AvailableDecomposition

temperatureNot Available

Melting point /freezing point (°C)

Not Available Viscosity (cSt) Not Available

Initial boiling pointand boiling range (°C)

>232.2Molecular weight

(g/mol)Not Applicable

Flash point (°C) >135 (TCC) Taste Not Available

Evaporation rate <<1 BuAC = 1 Explosive properties Not Available

Flammability Not Applicable Oxidising properties Not Available

Upper Explosive Limit(%)

Not AvailableSurface Tension

(dyn/cm or mN/m)Not Available

Lower Explosive Limit(%)

Not AvailableVolatile Component

(%vol)0

Vapour pressure (kPa) < 0.13 @ 24 C Gas group Not Available

Solubility in water(g/L)

Immiscible pH as a solution (1%) 7-8 (5%)

Vapour density (Air =1)

> 1 VOC g/L Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity See section 7

Chemical stabilityUnstable in the presence of incompatible materials.Product is considered stable.Hazardous polymerisation will not occur.

Possibility ofhazardous reactions

See section 7

Conditions to avoid See section 7

Incompatible materials See section 7

Hazardousdecomposition

productsSee section 5

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

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Inhaled

Inhalation of aerosols (mists, fumes), generated by the material during the course of normal handling, may be damaging tothe health of the individual.There is some evidence to suggest that the material can cause respiratory irritation in some persons. The body's response tosuch irritation can cause further lung damage.Inhalation of epoxy resin amine hardeners (including polyamines and amine adducts) may produce bronchospasm andcoughing episodes lasting several days after cessation of the exposure. Even faint traces of these vapours may trigger anintense reaction in individuals showing "amine asthma".Inhalation hazard is increased at higher temperatures.

Ingestion

Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram maybe fatal or may produce serious damage to the health of the individual.Ingestion of amine epoxy-curing agents (hardeners) may cause severe abdominal pain, nausea, vomiting or diarrhoea. Thevomitus may contain blood and mucous.The substance and/or its metabolites may bind to haemoglobin inhibiting normal uptake of oxygen. This condition, known as"methaemoglobinemia", is a form of oxygen starvation (anoxia). Symptoms include cyanosis (a bluish discolouration skin and mucous membranes) and breathing difficulties. Symptomsmay not be evident until several hours after exposure.

Skin Contact

Skin contact with the material may be harmful; systemic effects may result following absorption.There is some evidence to suggest that this material can cause inflammation of the skin on contact in some persons.Amine epoxy-curing agents (hardeners) may produce primary skin irritation and sensitisation dermatitis in predisposedindividuals. Cutaneous reactions include erythema, intolerable itching and severe facial swelling.Open cuts, abraded or irritated skin should not be exposed to this materialEntry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmfuleffects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.

Eye

There is evidence that material may produce eye irritation in some persons and produce eye damage 24 hours or more afterinstillation. Severe inflammation may be expected with pain.Vapours of volatile amines irritate the eyes, causing excessive secretion of tears, inflammation of the conjunctiva and slightswelling of the cornea, resulting in "halos" around lights. This effect is temporary, lasting only for a few hours. However thiscondition can reduce the efficiency of undertaking skilled tasks, such as driving a car. Direct eye contact with liquid volatileamines may produce eye damage, permanent for the lighter species.

Chronic

There is limited evidence that, skin contact with this product is more likely to cause a sensitisation reaction in some personscompared to the general population.Harmful: danger of serious damage to health by prolonged exposure if swallowed. This material can cause serious damage if one is exposed to it for long periods. It can be assumed that it contains asubstance which can produce severe defects.Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-termoccupational exposure.There is some evidence that inhaling this product is more likely to cause a sensitisation reaction in some persons comparedto the general population.Some glycol esters and their ethers cause wasting of the testicles, reproductive changes, infertility and changes to kidneyfunction. Shorter chain compounds are more dangerous.Most arylamines are very toxic to the blood cell-forming system, and they produce methaemoglobinaemia in humans. Highdoses congest the spleen and then cause formation of sarcomas (a type of malignant tumour).

Devcon Flexane 80 PuttyCuring Agent

TOXICITY IRRITATION


dipropylene glycol dibenzoate

TOXICITY IRRITATION

dermal (rat) LD50: >2000 mg/kg[1] * [Van Waters & Rogers]

Inhalation (rat) LC50: >200 mg/l/4h *][2] Nil reported


diethyltoluenediamine

TOXICITY IRRITATION

Dermal (rabbit) LD50: >700 mg/kg[2] [Manufacturer]

Oral (rat) LD50: 470-540 mg/kg[2] Eye (rabbit): moderate-SEVERE

soybean oil, epoxidised

TOXICITY IRRITATION

Dermal (rabbit) LD50: >19900 mg/kg[1] [KIRK-OTHMER]

Oral (rat) LD50: 22387.5 mg/kg[1] Skin (rabbit): non-irritating

dipropylene glycolmonobenzoate

TOXICITY IRRITATION


carbon blackTOXICITY IRRITATION

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Legend: – Data available but does not fill the criteria for classification – Data required to make classification available – Data Not Available to make classification

Dermal (rabbit) LD50: >3000 mg/kg[2] Not Available

Oral (rat) LD50: >8000 mg/kg[1]

(2-propenyloxy)propylbenzoateTOXICITY IRRITATION


propylene glycol dibenzoate

TOXICITY IRRITATION

Dermal (rabbit) LD50: >2000 mg/kg[2] * Sigma/Aldrich

Inhalation (rat) LC50: >200 mg/l/4h *[2] Nil reported


Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

Devcon Flexane 80 Putty CuringAgent

The following information refers to contact allergens as a group and may not be specific to this product. Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke'soedema. The pathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction ofthe delayed type. Other allergic skin reactions, e.g. contact urticaria, involve antibody-mediated immunereactions.The material may produce severe irritation to the eye causing pronounced inflammation. Repeated orprolonged exposure to irritants may produce conjunctivitis.p-Phenylenediamine is oxidised by the liver microsomal enzymes (S9). Pure p-phenylenediamine does notcause mutations, but after it is oxidized, it does.

DIETHYLTOLUENEDIAMINE

Oral (rat) LD50: 470-540 mg/kg Skin (rabbit): slightThe material may produce severe irritation to the eye causing pronounced inflammation. Repeated orprolonged exposure to irritants may produce conjunctivitis.p-Phenylenediamine is oxidised by the liver microsomal enzymes (S9). Pure p-phenylenediamine does notcause mutations, but after it is oxidized, it does.

SOYBEAN OIL, EPOXIDISED

Epoxidised Oils and Derivatives (EOD) are epoxidised fatty acid esters, and are derived from naturally-occurring oils from long chain fatty acid sources. They are mostly the C18 acids: oleic, linoleic, and linolenicacid. Animal testing suggests that they were only slightly irritating to the eye and skin and were virtuallynon-toxic on swallowing, in the acute setting. However, chronic exposure caused increased mortality, damageto the kidney, liver and testes, and slight changes to the uterus.The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skinredness, swelling, the production of vesicles, scaling and thickening of the skin..

CARBON BLACK

No significant acute toxicological data identified in literature search.

WARNING: This substance has been classified by the IARC as Group 2B: Possibly Carcinogenic to Humans.Inhalation (rat) TCLo: 50 mg/m3/6h/90D-I Nil reported

DIPROPYLENE GLYCOLDIBENZOATE & PROPYLENE GLYCOL

DIBENZOATE

The following information refers to contact allergens as a group and may not be specific to this product. Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke'soedema. The pathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction ofthe delayed type. Other allergic skin reactions, e.g. contact urticaria, involve antibody-mediated immunereactions.

DIPROPYLENE GLYCOLMONOBENZOATE &

(2-PROPENYLOXY)PROPYLBENZOATENo significant acute toxicological data identified in literature search.

Acute Toxicity Carcinogenicity

SkinIrritation/Corrosion

Reproductivity

Serious EyeDamage/Irritation

STOT - SingleExposure

Respiratory or Skinsensitisation

STOT - RepeatedExposure

Mutagenicity Aspiration Hazard

SECTION 12 ECOLOGICAL INFORMATION

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Toxicity

Ingredient Endpoint Test Duration (hr) Species Value Source

dipropylene glycoldibenzoate

EC50 96 Algae or other aquatic plants 0.358mg/L 3


LC50 96 Fish >3mg/L 2


NOEC 96 Fish 1.2mg/L 2

diethyltoluenediamine LC50 96 Fish ca.183mg/L 2

diethyltoluenediamine EC50 48 Crustacea 0.5mg/L 2

diethyltoluenediamine EC50 96 Algae or other aquatic plants ca.1.157mg/L 2

diethyltoluenediamine NOEC 72 Algae or other aquatic plants ca.32mg/L 2

soybean oil,epoxidised

EC50 72 Algae or other aquatic plants =8mg/L 1


EC50 72 Algae or other aquatic plants 8mg/L 2


NOEC 72 Algae or other aquatic plants 0.7mg/L 2

carbon black LC50 96 Fish >100mg/L 2

carbon black NOEC 720 Fish 17mg/L 2

carbon black EC50 48 Crustacea >100mg/L 2

carbon black EC50 384 Crustacea 4.9mg/L 2

carbon black EC50 96 Algae or other aquatic plants 95mg/L 2

propylene glycoldibenzoate

EC50 96 Algae or other aquatic plants 0.418mg/L 3


LC50 96 Fish 4.927mg/L 3

Legend:

Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity3. EPIWIN Suite V3.12 - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOCAquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. VendorData

Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water whencleaning equipment or disposing of equipment wash-waters.Wastes resulting from use of the product must be disposed of on site or at approved waste sites.For Glycol Ethers:Environmental Fate: Several glycol ethers have been shown to biodegrade however; biodegradation slows as molecular weight increases. No glycol ethersthat have been tested demonstrate marked resistance to biodegradative processes. No glycol ethers that have been tested demonstrate markedresistance to biodegradative processes.Atmospheric Fate: Upon release to the atmosphere by evaporation, high boiling glycol ethers are estimated to undergo photo-degradation (atmospherichalf lives = 2.4-2.5 hr).Phenylenediamines are not readily biodegradable via CO2 evolution, but they are susceptible to both hydrolysis and photodegradation. These materialshave been shown not to partition to water or air if released into the environment due to their low water solubility and low vapor pressure. It is unclear howphenylenediamines are eliminated from water bodies, but it is assumed that this is through processes such as oxidation reactions, adsorption, andstripping effects. It is assumed that any phenylenediamines released into the atmosphere are destroyed by photodegradation.For Arylamines (Aromatic Amines):Aquatic Fate - Arylamines, particularly aromatic amines, irreversibly bind with humic substances present in most natural waters. The estimated half-life ofaromatic amines in water is approximetly 100 days.Ecotoxicity: Anilines, benzidines and toluidines are of environmental concern. Anilines and benzidines are both acutely toxic and toxic depending on thespecific aquatic species (except algae).

DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air


HIGH HIGH


LOW LOW

Bioaccumulative potential

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Ingredient Bioaccumulation


MEDIUM (LogKOW = 4.0228)


LOW (LogKOW = 3.7326)

Mobility in soil

Ingredient Mobility


LOW (KOC = 1845)


LOW (KOC = 2573)

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

Product / Packagingdisposal

Recycle wherever possible or consult manufacturer for recycling options. Consult State Land Waste Management Authority for disposal. Material may be disposed of by controlled burning in an approved incinerator or buried in an approved landfill. Prior to disposal in a landfill the material should be mixed with the other component and reacted to render the material inert.

Ensure that the disposal of material is carried out in accordance with Hazardous Substances (Disposal) Regulations 2001.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant

HAZCHEM •3Z

Land transport (UN)

UN number 3082

Packing group III

UN proper shippingname

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (diethyltoluenediamine)

Environmental hazard Not Applicable

Transport hazardclass(es)

Class 9

Subrisk Not Applicable

Special precautionsfor user

Special provisions 274; 331; 335; 375

Limited quantity 5 L

Air transport (ICAO-IATA / DGR)

UN number 3082

Packing group III


Environmentally hazardous substance, liquid, n.o.s. * (diethyltoluenediamine)

Environmental hazard Not Applicable

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ICAO/IATA Class 9

ICAO / IATA Subrisk Not Applicable

ERG Code 9L


Special provisions A97 A158 A197

Cargo Only Packing Instructions 964

Cargo Only Maximum Qty / Pack 450 L

Passenger and Cargo Packing Instructions 964

Passenger and Cargo Maximum Qty / Pack 450 L

Passenger and Cargo Limited Quantity Packing Instructions Y964

Passenger and Cargo Limited Maximum Qty / Pack 30 kg G

Sea transport (IMDG-Code / GGVSee)

UN number 3082

Packing group III


ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (diethyltoluenediamine)

Environmental hazard Marine Pollutant


IMDG Class 9

IMDG Subrisk Not Applicable


EMS Number F-A, S-F

Special provisions 274 335 969

Limited Quantities 5 L

Transport in bulk according to Annex II of MARPOL and the IBC codeNot Applicable

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixtureThis substance is to be managed using the conditions specified in an applicable Group Standard

HSR Number Group Standard

HSR002670 Surface Coatings and Colourants (Subsidiary Hazard) Group Standard 2006

DIPROPYLENE GLYCOL DIBENZOATE(27138-31-4) IS FOUND ON THE FOLLOWING REGULATORY LISTS


DIETHYLTOLUENEDIAMINE(68479-98-1) IS FOUND ON THE FOLLOWING REGULATORY LISTS



SOYBEAN OIL, EPOXIDISED(8013-07-8) IS FOUND ON THE FOLLOWING REGULATORY LISTS



DIPROPYLENE GLYCOL MONOBENZOATE(32686-95-6) IS FOUND ON THE FOLLOWING REGULATORY LISTS


CARBON BLACK(1333-86-4) IS FOUND ON THE FOLLOWING REGULATORY LISTS





(2-PROPENYLOXY)PROPYLBENZOATE(197178-94-2) IS FOUND ON THE FOLLOWING REGULATORY LISTS

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PROPYLENE GLYCOL DIBENZOATE(19224-26-1) IS FOUND ON THE FOLLOWING REGULATORY LISTS


Location Test CertificateSubject to Regulation 55 of the Hazardous Substances (Classes 1 to 5 Controls) Regulations, a location test certificate is required when quantity greaterthan or equal to those indicated below are present.

Hazard ClassQuantity beyond which controls apply for closedcontainers

Quantity beyond which controls apply when use occurring inopen containers

Not Applicable Not Applicable Not Applicable

Approved HandlerSubject to Regulation 56 of the Hazardous Substances (Classes 1 to 5 Controls) Regulations and Regulation 9 of the Hazardous Substances (Classes 6,8, and 9 Controls) Regulations, the substance must be under the personal control of an Approved Handler when present in a quantity greater than orequal to those indicated below.

Class of substance Quantities

9.1A, 9.2A, 9.3A, and9.4A

Any quantity

Refer Group Standards for further information

Tracking RequirementsSubject to Hazardous Substances (Tracking) Regulation 2001- Refer to the regulation for more information

National Inventory Status

Australia - AICS N (dipropylene glycol monobenzoate; (2-propenyloxy)propylbenzoate)

Canada - DSL N (propylene glycol dibenzoate; dipropylene glycol monobenzoate; (2-propenyloxy)propylbenzoate)

Canada - NDSLN (dipropylene glycol monobenzoate; dipropylene glycol dibenzoate; diethyltoluenediamine; carbon black;(2-propenyloxy)propylbenzoate; soybean oil, epoxidised)

China - IECSC N (dipropylene glycol monobenzoate; (2-propenyloxy)propylbenzoate; soybean oil, epoxidised)

Europe - EINEC /ELINCS / NLP

N (dipropylene glycol monobenzoate; (2-propenyloxy)propylbenzoate)

Japan - ENCS N (dipropylene glycol monobenzoate; diethyltoluenediamine; (2-propenyloxy)propylbenzoate; soybean oil, epoxidised)

Korea - KECI N (dipropylene glycol monobenzoate; (2-propenyloxy)propylbenzoate)

New Zealand - NZIoC Y

Philippines - PICCS N (dipropylene glycol monobenzoate; (2-propenyloxy)propylbenzoate)

USA - TSCA N (dipropylene glycol monobenzoate; (2-propenyloxy)propylbenzoate)

Legend:Y = All ingredients are on the inventoryN = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredientsin brackets)

SECTION 16 OTHER INFORMATION

Other information

Ingredients with multiple cas numbers

Name CAS No


20109-39-1, 27138-31-4

Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by theChemwatch Classification committee using available literature references.A list of reference resources used to assist the committee may be found at: www.chemwatch.net

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards areRisks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current oravailable engineering controls must be considered.

This document is copyright.

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Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may bereproduced by any process without written permission from CHEMWATCH.TEL (+61 3) 9572 4700.

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end of SDS

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