manipal be phys 2011 12 quantumphysics
DESCRIPTION
.TRANSCRIPT
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INTRODUCTION TO QUANTUM PHYSICS
Blackbody Radiation & Planks Hypothesis The Photoelectric Effect The Compton Effect Photons and Electromagnetic Waves The Quantum Particle The Double-Slit Experiment Revisited The Uncertainty Principle
TOPICS
Text Book PHYSICS for Scientists and Engineers with Modern Physics (6th ed) By Serway & Jewett
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INTRODUCTION
Failure of classical mechanics
Brief summary of chapter 40 of the text book
INTRODUCTION TO QUANTUM PHYSICS
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BLACKBODY RADIATION & PLANKS HYPOTHESIS
Origin of thermal radiation the classical view point
Concept of oscillators
INTRODUCTION
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Definition of a Black-Body
Black-Body Radation Laws
1- The Stefan-Boltzmann Law
2- The Wiens Displacement Law
3- The Rayleigh-Jeans Law
4- The Planck Law
Application for Black Body
Conclusion
Summary
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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Definition of a black body
An object that absorbs all incident radiation. A small hole cut into a cavity is the most popular and realistic example.
None of the
incident radiation
escapes.
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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The radiation is absorbed in the walls of the
cavity. This causes a heating of the cavity walls.
The oscillators in the cavity walls vibrate and
cavity walls re-radiate at wavelengths
corresponding to the temperature of the cavity,
producing standing waves in the cavity. Some of
the energy from these standing waves can leave
through the opening. The electromagnetic
radiation emitted by the black body is called
black-body radiation.
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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The black body is an ideal absorber of
incident radaition.
The emitted "thermal" radiation from a black
body characterizes the equilibrium
temperature of the black-body.
Emitted radiation from a blackbody does not
depend on the material of which the walls are
made.
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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Figure shows Intensity
of blackbody radiation
versus wavelength at
three temperatures.
At about 6000 K (not
shown in fig.), the peak
is in the center of the
visible wavelengths and
the object appears white.
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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Basic Laws of Radiation 1) All objects emit radiant energy.
2) Hotter objects emit more energy than colder
objects (per unit area). The total power of the emitted radiation increases with temperature.
This is Stefan-Boltzmann Law. 3) The peak of the wavelength distribution
shifts to shorter wavelengths as the black body temperature increases
This is Wiens Law.
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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Stefan Boltzmann Law.
P = Ae T4
P = power radiated from the surface of the object(W) T = temperature (K) = 5.670 x 10-8 W/m2K4 (Stefan-Boltzmann constant) A = surface area of the object (m2) e = emissivity of the surface (for a blackbody e =1).
Black-Body Radiation Laws (1)
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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Black-Body Radiation Laws (2)
Wiens Displacement Law.
lm T = constant = 2.898 10-3 m.K, or lm T
-1
Where lm = peak of the wavelength distribution in the black body emission spectrum. T- equilibrium temperature of the blackbody. (A black-body reaches thermal equilibrium when the incident radiation power is balanced by the power re-radiated).
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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SJ: P-SE 40.1 Thermal radiation from Different Objects.
Find the peak wavelength of the blackbody radiation emitted by each of the following.
A. The human body when the skin temperature is
35C
B. The tungsten filament of a light bulb, which operates at 2000 K
C. The Sun, which has a surface temperature of about 5800 K.
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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Black-Body Radiation Laws (3)
The Rayleigh-Jeans Law.
4B
Tck2)T,(I
=
This law tries to explain the distribution of energy from a black body. I (l,T) dl is the intensity or power per unit area emitted in the wavelength interval dl from a blackbody.
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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The failure has become known as the ultraviolet catastrophe.
*It agrees with experimental
measurements for long
wavelengths.
* It predicts an energy
output that diverges towards
infinity as wavelengths grow
smaller.
kB Boltzmann's constant T- equilibrium blackbody temperature c- velocity of light.
Rayleigh-Jeans Law
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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Black-Body Radiation Laws (4)
The Planck Law
1 -Tk
hc
e
1
5
2hc2= T) ,(
B
I
This law too explains the distribution of energy from a black body. I (l,T) dl is the intensity or power per unit area emitted in the wavelength interval dl from a blackbody. Only the extra quantity (compared to the Rayleigh-Jeans Law) coming here is the constant known as Planks constant introduced by Max Plank in this revolutionary theory.
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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The Planck Law gives a distribution that
peaks at a certain wavelength, the peak
shifts to shorter wavelengths for higher
temperatures, and the area under the
curve grows rapidly with increasing
temperature. In short the law fitted the
experimental data for all wavelength
regions and at all temperatures.
But for this to happen, Plank made two bold and
controversial assumptions concerning the nature of the
oscillators in the cavity walls.
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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1) The energy of an oscillator can have only
certain discrete values En En = nhf
where n is a positive integer called a
quantum number, f is the frequency of
oscillation, and h is a constant called Plancks
constant. Energy of the oscillator is
quantized. Each discrete energy value
corresponds to a different quantum state,
represented by the quantum number n.
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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2) The oscillators emit or absorb energy only
when making a transition from one quantum state
to another.
Difference in energy will be integral multiples of hf.
If it remains in one quantum state, no energy
is emitted or absorbed.
0
EN
ER
GY
hf
2 h
f
3 h f
4 h f
0
1
2
3
4
t o n =
n E
Figure shows allowed energy
levels for an oscillator with
frequency f, and the allowed
Transitions.
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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The results of Planck's law
the denominator [exp(hc/lkBT )] tends to infinity faster than the numerator (l-5), thus resolving the infrared catastrophe. i.e. I (l,T) 0 as l 0. for very large l,
From a fit between Planck's law and experimental data, Planck's constant was derived to be
h = 6.626 10-34 J.s
TkTk
hc1)Tk/hcexp(
B4
BB
- T) ,( I
-
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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Planck's restriction of the available
energies for radiation gets around the
ultraviolet catastrophe in the following
way: the short wavelength/high frequency
modes are now limited in the energy they
can have to either zero, or E hf; in the
calculation of the average energy, these
modes with high energy are cut off by the
Boltzmann factor exp(-E/kBT), i.e. these
modes are rarely excited and, therefore,
contribute nothing to the average energy in
the limit 0.
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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Summary
The characteristics of blackbody radiation cannot
be explained using classical concepts.
Plank introduced the quantum concept and
Planks constant when he assumed that atomic
oscillators existing only in discrete energy states
are responsible for this radiation.
In Planks model, radiation is emitted in
single quantized packets whenever an oscillator
makes a transition between discrete energy states.
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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SJ: P-SE 40.2 The Quantized Oscillator A 2.0- kg block is attached to a spring that has a force constant of k = 25 N/m. The
spring is stretched 0.40 m from its equilibrium position and released.
A. Find the total energy of the system and
the frequency of oscillation according to classical calculations.
B. Assuming that the energy is quantized, find the quantum number n for the system oscillating with this amplitude.
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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SJ: P-SE 40.2 The Quantized Oscillator contd. C. Suppose the oscillator makes a transition from the n = 5.4 x 1033 state to the state corresponding to n = 5.4 x 1033 -1. By how much does the energy of the oscillator change n this one-quantum change.
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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SJ: Section 40.1 P-1 The human eye is most sensitive to 560 nm light. What is the temperature of a black body that would radiate most intensely at this wavelength?
SJ: Section 40.1 P-3 A blackbody at 7500 K consists of an opening of diameter 0.050 mm, looking into an oven. Find the number of photons per second escaping the hole and having wavelengths between 500 nm and 501 nm.
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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SJ: Section 40.1 P-5 The radius of our Sun is 6.96 x 108 m, and its total power output s 3.77 x 1026 W. (a) Assuming that the Suns surface emits as a black body, calculate its surface temperature. (b) Using the result, find lmax for the Sun.
SJ: Section 40.1 P-7 Calculate the energy in electron volts, of a photon whose frequency is (a) 620 THz, (b) 3.10 GHz, (c) 46.0 MHz. (d) Determine the corresponding wavelengths for these photons and state the classification of each on the electromagnetic spectrum.
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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Assignment: Try to answer the questions in page no. 1313, chapter 40 of the text book.
SJ: Section 40.1 P-9. An FM radio transmitter has a power output of 150 kW and operates at a frequency of 99.7 MHz. How many photons per second does the transmitter emit?
BLACKBODY RADIATION & PLANKS HYPOTHESIS
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Introduction
What is Photoelectric Effect
Apparatus for studying Photoelectric Effect
Experimental Observations
Classical Predictions
Clash between Classical predictions
& Observed Experimental results
Einsteins model of the Photoelectric Effect
Explanation for the observed features of PE
Application
Conclusion
Summary
THE PHOTOELECTRIC EFFECT
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What is Photoelectric Effect?
Apparatus for studying Photoelectric Effect
T
T Evacuated
glass/ quartz tube
E Emitter Plate/
Photosensitive
material /Cathode
C Collector Plate /
Anode
V Voltmeter
A - Ammeter
THE PHOTOELECTRIC EFFECT
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Experimental Observations
1. When plate E is illuminated by light of suitable frequency, electrons are emitted from E and a current is detected in A.
2. Photocurrent produced Vs potential difference applied graph shows that maximum kinetic energy of the emitted electrons,
Kmax = e Vs
THE PHOTOELECTRIC EFFECT
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3. Maximum kinetic energy of the
photoelectron is independent of light
intensity.
4. Electrons are emitted from the surface of the
emitter almost instantaneously.
5. No electrons are emitted if the incident light
frequency falls below a cutoff frequency.
6. Maximum kinetic energy of the
photoelectrons increases with increasing
light frequency.
THE PHOTOELECTRIC EFFECT
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Classical Predictions
1. If light is really a wave, it was thought that
if one shine light of any fixed wavelength, at
sufficient intensity on the emitter surface,
electrons should absorb energy continuously
from the em waves and electrons should be
ejected.
2. As the intensity of light is increased (made it
brighter and hence classically, a more
energetic wave), kinetic energy of the
emitted electrons should increase.
3. Measurable/ larger time interval between
incidence of light and ejection of
photoelectrons.
THE PHOTOELECTRIC EFFECT
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4. Ejection of photoelectron should not
depend on light frequency
5. Photoelectron kinetic energy should not
depend upon the frequency of the
incident light.
In short experimental results contradict classical predictions.
THE PHOTOELECTRIC EFFECT
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Einsteins Interpretation of em radiation
(A new theory of light)
Electromagnetic waves carry discrete energy packets (light quanta called photons now). The energy E, per packet depends on frequency f.
E = hf. More intense light corresponds to more photons, not higher energy photons. Each photon of energy E moves in vacuum at the speed of light c, where c = 3x 108 m/s. Each photon carries a momentum p = E/C.
THE PHOTOELECTRIC EFFECT
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Einsteins model of the photoelectric effect
A photon of the incident light gives all its
energy hf to a single electron (Absorption
of energy by the electrons is not a
continuous process as envisioned in the
wave model) and Kmax = hf -
is called the work function of the metal.
It is the minimum energy with which an
electron is bound in the metal.
THE PHOTOELECTRIC EFFECT
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All the observed features of photoelectric effect could be explained by Einsteins photoelectric equation.
1. Equation shows that Kmax depends only on
frequency of the incident light.
2. Almost instantaneous emission of photoelectrons
due to one -to one interaction between photons
and electrons.
3. Ejection of electrons depends on light frequency
since photons should have energy greater than
the work function in order to eject an electron.
4. The cutoff frequency fc is related to by fc = /h.
If the incident frequency f is less than fc , no
emission of photoelectrons.
THE PHOTOELECTRIC EFFECT
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Einstein predicted that a
graph of the maximum
kinetic energy Kmax Vs
frequency f would be a
straight line, given by the
linear relation,
Kmax = hf -
And indeed such a linear
relationship was observed.
And this work won Einstein his Nobel Prize in 1921
THE PHOTOELECTRIC EFFECT
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Application of photoelectric effect
Photomultiplier tube
Explain the device, theory, and its working
THE PHOTOELECTRIC EFFECT
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Summary
Einstein successfully extended Planks quantum hypothesis to explain photoelectric effect. In Einsteins model, light is viewed as a stream of particles, or photons, each having energy E = hf , where h is Planks constant and f is the frequency. The maximum kinetic energy Kmax of the ejected photoelectron is
Kmax = hf -
Where is the work function of the photocathode.
THE PHOTOELECTRIC EFFECT
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SJ: P-SE 40.3 The Photoelectric Effect for Sodium
A sodium surface is illuminated with light having
a wavelength of 300 nm. The work function for
sodium metal is 2.46 eV. Find
A. The maximum kinetic energy of the ejected
photoelectrons and
B. The cutoff wavelength for sodium.
SJ: Section 40.2 P-13. Molybdenum has a
work function of 4.2eV. (a) Find the cut off
wavelength and cut off frequency for the
photoelectric effect. (b) What is the stopping
potential if the incident light has wavelength of
180 nm?
THE PHOTOELECTRIC EFFECT
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SJ: Section 40.2 P-14. Electrons are ejected
from a metallic surface with speeds up to 4.60 x 105
m/s when light with a wavelength of 625 nm is used.
(a) What is the work function of the surface? (b)
What is the cut-off frequency for this surface?
SJ: Section 40.2 P-16. The stopping
potential for photoelectrons released from a
metal is 1.48 V larger compared to that in
another metal. If the threshold frequency for
the first metal is 40.0 % smaller than for the
second metal, determine the work function for
each metal.
THE PHOTOELECTRIC EFFECT
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THE PHOTOELECTRIC EFFECT
Assignment: Try to answer the questions in page no. 1313, chapter 40 of the reference book.
SJ: Section 40.2 P-17. Two light sources are
used in a photoelectric experiment to determine
the work function for a metal surface. When
green light from a mercury lamp (l = 546.1 nm)
is used, a stopping potential of 0.376 V reduces
the photocurrent to zero. (a) Based on this
what is the work function of this metal? (b)
What stopping potential would be observed
when using the yellow light from a helium
discharge tube (l = 587.5 nm)?
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Introduction
What is Compton Effect
Schematic diagram of Comptons apparatus
Experimental Observations
Classical Predictions
Explanation for Compton Effect
Derivation of the Compton Shift Equation.
Conclusion
Summary
THE COMPTON EFFECT
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Introduction
Relativistic formula relating energy and momentum of a particle
2 2 2 2 4E p c m c
Here E is the total energy of the particle
Relativistically E = m c2
P and m are the momentum and mass of the particle.
Relativistic expression for the momentum of a particle
P = m v
where m = mass of the particle, v = speed of the particle & c = speed of light in vacuum
Expressions for relativistic momentum and relativistic kinetic energy of a particle
THE COMPTON EFFECT
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For light, m = 0, E= pc . Also c = l f
h
=fhf
=c
Ep=
2
2
c
v - 1
1 and
And finally, the relativistic kinetic energy of a particle is K = ( -1) m c2.
SUMMARY OF PHOTON PROPERTIES
Energy, frequency, and wavelength, E = hf = hc / l
Also we have relation between momentum and wavelength of a photon as follows
Relation between particle and wave properties of light
THE COMPTON EFFECT
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Compton (1923)
measured intensity of
scattered X-rays from
solid target (scattering of
X-rays from electrons), as
function of wavelength
for different angles. In
such a scattering, a shift
in wavelength for the
scattered X-rays takes
place, which is known as
Compton Effect.
scattered beam
What is Compton Effect ?
THE COMPTON EFFECT
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Classical Predictions
Oscillating electromagnetic waves of frequency f0
incident on electrons should have two effects. (a)
oscillating electromagnetic field causes oscillations in
electrons, which re-radiate in all directions (b)
radiation pressure should cause the electrons to
accelerate in the direction of propagation of the waves.
Because different electrons will move at different
speeds after the interaction, depending on the amount
of energy absorbed from em waves, for a particular
angle of incidence of the incoming radiation, the
scattered wave frequency should show a distribution of
Doppler- shifted values.
THE COMPTON EFFECT
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Schematic diagram of Comptons apparatus
Here X- ray photons are
scattered through 90
from a carbon target.
The wavelength is
measured with a
rotating crystal
spectrometer using
Braggs law. Intensity
of the scattered X-rays
are measured using the
ionization chamber.
Explain the experimental details and results
THE COMPTON EFFECT
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Experimental Observations
Contrary to the classical predictions where X-rays are treated as waves, in Compton experiment, at a given angle, only one frequency for scattered radiation is seen. This is shown in the figure, scattered x-ray intensity versus wavelength for Compton scattering at = 0, 45, 90, and 135. Compton could explain the experimental result by taking a billiard ball type collisions between particles of light (X-ray photons) and electrons in the material.
THE COMPTON EFFECT
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The graphs for three nonzero angles show two peaks,
one at l0 and one at l > l0 . The shifted peak at l is
caused by the scattering of X-rays from free electrons.
Shift in wavelength was predicted by Compton to
depend on scattering angle as
This is known as Compton shift equation, and the
factor is called the Compton wavelength.
) cos - 1(cm
h - '
e
0
cm
h
e nm 0.00243 = cm
h
e
Prediction were in excellent agreement with the experimental results.
THE COMPTON EFFECT
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Derivation of the Compton Shift Equation
Photon is treated as a particle having energy E = hf = hc/l and zero rest energy. They collide elastically with free electrons initially at rest as shown in figure.
In the scattering
process, the total
energy and total
linear momentum of
the system must be
conserved.
THE COMPTON EFFECT
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K+'
hc=
hce
0
Applying the law of conservation of energy to the process gives
where
hc/ l0 = E0 is the energy of the incident photon,
hc/ l = E is the energy of the scattered photon, and Ke is the kinetic energy of the recoiling electron.
Substituting for Ke we get
me
(40.12)2)( c1- +'hc
=hc
0
THE COMPTON EFFECT
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Applying law of conservation of momentum to this collision, both in x and y components of momentum are conserved independently.
(40.13) :component x em + 'h=
0h coscos v
(40.14) :component y 0 em - 'h= sinsin v
where h/l0 = p0 is the momentum of the incident photon h/l = p is the momentum of the scattered photon mev = Pe is the momentum of the scattered electron
THE COMPTON EFFECT
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Rewriting the above equations as
(40.13) :component x ' p p-p cosecos0
(40.14) :component y ' e p sinsin p
Squaring and adding the above equations give
) (a p= p'+ p'p2- p 220
20 ecos
Rewriting equation 40.12 in terms of respective energy notations as
E0 = E + Ee - mc2
i.e., E0 - E + mc2 = Ee ---------(b)
THE COMPTON EFFECT
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Square equation (b), substitute for
4222e
2e cmcpE
and for from equation (a). Write the resulting equation in terms of respective wavelengths, we get the Compton shift equation as
2ep
) cos - 1(cm
h - '
e
0
THE COMPTON EFFECT
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Summary
X-rays are scattered at various angles by electrons in
a target. In such a scattering, a shift in wavelength is
observed for the scattered X-rays and the
phenomenon is known as Compton Effect. Classical
physics does not predict the correct behaviour in this
effect. If x-ray is treated as a photon, conservation of
energy and linear momentum applied to the photon-
electron collisions yields for the Compton shift:
Where me is the mass of the electron, c is the speed of
light, and is the scattering angle.
) cos - 1(cm
h - '
e
0
THE COMPTON EFFECT
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SJ: P-SE 40.4 Compton scattering at 45
X-rays of wavelength l0 = 0.20 nm are scattered from
a block of material. The scattered X-rays are observed
at an angle of 45 to the incident beam. Calculate
their wavelength.
What if we move the detector so that scattered x-
rays are detected at an angle larger than 45? Does
the wavelength of the scattered x-rays increase or
decrease as the angle increase?
SJ: Section 40.3 P-21 Calculate the energy and momentum of a photon of wavelength 700 nm.
THE COMPTON EFFECT
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SJ: Section 40.3 P-23. A 0.00160 nm photon scatters from a free electron. For what photon scattering angle does the recoiling electron have kinetic energy equal to the energy of the scattered photon?
SJ: Section 40.3 P-25. A 0.880 MeV photon is scattered by a free electron initially at rest such that the scattering angle of the scattered electron is equal to that of the scattered photon ( = ). (a) Determine the angles & . (b) Determine the energy and momentum of the scattered electron and photon.
THE COMPTON EFFECT
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THE COMPTON EFFECT
Assignment: Try to answer the questions in page no. 1313, chapter 40 of the reference book.
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Photons and Electromagnetic Waves
Evidence for wave-nature of light Diffraction Interference Evidence for particle-nature of light Photoelectric effect Compton effect
PHOTONS AND ELECTROMAGNETIC WAVES
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Light exhibits diffraction and interference phenomena that are only explicable in terms of wave properties.
Photoelectric effect and Compton effect can only be explained taking light as photons/ particle
This means true nature of light is not describable in terms of any single classical picture.
In short, the particle model and the wave model of light compliment each other.
PHOTONS AND ELECTROMAGNETIC WAVES
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The Wave Properties of Particles
We have seen that light comes in discrete units
(photons) with particle properties (energy and
momentum) that are related to the wave-like
properties of frequency and wavelength.
In his 1923 doctoral dissertation, Louis de Broglie
postulated that because photons have both wave
and particle characteristics, perhaps all forms of
matter have wave-like properties, with the
wavelength related to momentum p in the same
way as for light
De Broglie PHOTONS AND ELECTROMAGNETIC WAVES
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de Broglie Hypothesis
h
pl
de Broglie wavelength
346.63 10 Jsh -
Plancks constant
and
frequency of the particle
hE=f
Energy of the particle
PHOTONS AND ELECTROMAGNETIC WAVES
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mv
hph ==
p = momentum of the particle,
p = m v for a non-relativistic particle
m = mass of the particle
v = velocity of the particle
V ev m 22
1
The electron accelerated through a potential difference of V has a non relativistic kinetic energy
m = mass, v = velocity
p = m v = V e m 2
PHOTONS AND ELECTROMAGNETIC WAVES
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Davisson -Germer experiment
& Electron Diffraction pattern
(Go through the details of the experiments)
These two experiments confirmed de- Broglie relationship p = h /l.
Subsequently it was found that atomic beams,
and beams of neutrons, also exhibit diffraction
when reflected from regular crystals. Thus de
Broglie's formula seems to apply to any kind of
matter.
PHOTONS AND ELECTROMAGNETIC WAVES
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Now the dual nature of matter and radiation is
an accepted fact. And it is stated in the principle
of complementarity. This states that wave and
particle models of either matter or radiation
compliment each other.
SJ: P-SE 40.5 The wavelength of an Electron Calculate the de- Broglie wavelength for an electron moving at 1.0 x 107 m/s.
SJ: P-SE 40.6 The Wavelength of a Rock A rock of mass 50 g is thrown with a speed of 40 m/s. What is its de Broglie wavelength?
PHOTONS AND ELECTROMAGNETIC WAVES
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SJ: P-SE 40.7 An Accelerated Charged Particle A particle of charge q and mass m has been accelerated from rest to a nonrelativistic speed through a potential difference of V. Find an expression for its de Broglie wavelength.
SJ: Section 40.5 P-35 (a) An electron has a kinetic energy of 3.0 eV. Find its wavelength. (b) Also find the wavelength of a photon having the same wavelength.
PHOTONS AND ELECTROMAGNETIC WAVES
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SJ: Section 40.5 P-38 In the Davisson-Germer experiment, 54.0 eV electrons were diffracted from a nickel lattice. If the first maximum in the diffraction pattern was observed at = 50.0,
what was the lattice spacing a between the vertical rows of atoms in the figure?
PHOTONS AND ELECTROMAGNETIC WAVES
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What is a Quantum Particle?
How to represent a quantum particle?
Wave packet Phase velocity Group velocity
Double Slit Experiment
Conclusion
Summary
THE QUANTUM PARTICLE
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What is a Quantum Particle?
Quantum particle is a model by which
particles having dual nature are represented.
We must choose one appropriate behavior for
the quantum particle (particle or wave) in
order to understand a particular behavior.
THE QUANTUM PARTICLE
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How to represent a quantum particle?
To represent a quantum wave, we have to
combine the essential features of both an ideal
particle and an ideal wave.
An essential feature of a particle is that it is
localized in space. But an ideal wave is
infinitely long (unlocalized) as shown in figure
below.
THE QUANTUM PARTICLE
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Now to build a localized entity from an infinitely long wave, waves of same amplitude, but slightly different frequencies are superposed. The result of superposition of two such waves are shown below.
THE QUANTUM PARTICLE
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If we add up large number of waves in a similar way, the small localized region of space where constructive interference takes place is called a wavepacket, which represents a particle.
In the figure, large number of waves are Combined. The result is a wave packet,
which represents a
particle.
THE QUANTUM PARTICLE
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Mathematical Representation of a wave packet
superposition of two waves of equal amplitude, but
with slightly different frequencies, f1 & f2 and
wavelengths, traveling in the same direction are
considered. The waves are written as
( )t -xk cos A y1 11
= ( )t -xk cos A y2 22
=and
The resultant wave is, y = y1 + y2
t2
+ -x
2
k + k cost
2
-x
2
k cos 2A =y )()]([ 2121
Amplitude varies with t and x
THE QUANTUM PARTICLE
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Where k = k1 k2 and = 1 2.
The resulting wave oscillates with the average
frequency, and its amplitude envelope (in
square brackets, shown by the blue dotted
curve in figure) varies according to the
difference frequency.
THE QUANTUM PARTICLE
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This envelope can travel through space with a different speed than the individual waves. This speed is called the group speed or the speed of the wave packet (the group of waves)
k
k
g
2
2 speed, group The v
For a superposition of large number of waves to form a wave packet, this ratio is
dk
dg v
THE QUANTUM PARTICLE
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A realistic wave (one of finite extent in space) is
characterized by two different speeds. The phase
speed, the speed with which wave crest moves,
which is given by
& the group speed, the speed with which the
envelope (energy) moves. This is given by
In general these two speeds are not the same.
THE QUANTUM PARTICLE
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fp v
dk
dg v
-
Relation between group speed and phase speed
ppp
+dk
dk=
dk
)kv(d =
dk
d=But
g
p==.,e.i
==,havewe
phase
phase
k k
f k
g = p l d
dp
Substituting for k in terms of l, we get
THE QUANTUM PARTICLE
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Relation between group speed and particle speed
h
E 2f 2 ==
h
p 2=
ph
2=
2= kand
dp
dE=
dp h
2
dEh
2
=dk
d=v
g
For a classical particle moving with speed u, the kinetic energy E is given by
u=m
p =
dp
dE or
m2
dp p 2= dE and
m2
p
2
1 E
2
=mu= 2
velocity particle the v,dp
dE
dk
d i.e., g ===
THE QUANTUM PARTICLE
speed
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ie., we should identify the group speed with
the particle speed, speed with which the
energy moves.
To represent a realistic wave packet, confined to
a finite region in space, we need the
superposition of large number of harmonic waves
with a range of k values.
THE QUANTUM PARTICLE
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THE QUANTUM PARTICLE
SJ: Section 40.6 P-43 Consider a freely moving
quantum particle with mass m and speed u. Its
energy is E= K= mu2/2. Determine the phase
speed of the quantum wave representing the
particle and show that it is different from the
speed at which the particle transports mass and
energy.
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The slit separation d is much greater than the individual slit
widths and much less than the distance between the slit and
the detector. The electron detector is movable along the y
direction in the drawing and so can detect electrons
diffracted at different values of . The detector acts like the
viewing screen of Youngs double-slit experiment with
light as learned in interference of light.
Electron interference
Experimental details
And the discussion of
the results
THE DOUBLESLIT EXPERIMENT REVISITED
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Photograph of a double-slit interference pattern produced by electrons.
2pd
h sin
THE DOUBLESLIT EXPERIMENT REVISITED
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The minimum occurs when
Electron wavelength is given by
For small angle ,
/2 sind l
/p h l
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This experiment proves the dual nature of electrons.
The electrons are detected as particles at a localized
spot at some instant of time, but the probability of
arrival at that spot s determined by finding the
intensity of two interfering waves.
If slit 2 is blocked half the time, keeping slit 1
open, and slit 1 blocked for remaining half the time,
keeping 2 open, the accumulated pattern of
counts/ min is shown by blue curve. That is
interference pattern is lost and the result is simply
the sum of the individual results.
THE DOUBLESLIT EXPERIMENT REVISITED
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Results of the two-slit electron diffraction experiment with each slit closed half the time (blue). The result with both slits open (interference pattern) is shown in brown.
THE DOUBLESLIT EXPERIMENT REVISITED
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The observed interference pattern when both the
slits are open, suggests that each particle goes
through both slits at once. We are forced to
conclude that an electron interacts with both the
slits simultaneously shedding its localized
behaviour.
If we try to find out which slit the particle goes
through the interference pattern vanishes! Means,
if we know which path the particle takes, we lose
the fringes. We can only say that the electron
passes through both the slits.
THE DOUBLESLIT EXPERIMENT REVISITED
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SJ: Section 40.7 P-46 Electrons are incident on a
pair of narrow slits 0.060 m apart. The bright
bands in the interference pattern are separated
by 0.40 mm on a screen 20.0 cm from the slits.
Determine the potential difference through which
the electrons were accelerated to give this
pattern.
THE UNCERTAINTY PRINCIPLE
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Quantum theory predicts that, it is fundamentally
impossible to make simultaneous measurements
of a particles position & momentum with
infinite accuracy. This is known as Heisenberg
uncertainty principle. The uncertainties arise from
the quantum structure of matter.
For a particle represented by a single wavelength
wave existing throughout space, l is precisely
known, and according to de- Broglie hypothesis, its p
is also known accurately. But the position of the
particle in this case becomes uncertain.
THE UNCERTAINTY PRINCIPLE
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This means l = 0, p =0; but x =
In contrast, if a particle whose momentum is
uncertain (combination/ a range of wavelengths
are taken to form a wavepacket ), so that x is
small, but l is large. If x is made zero, l, &
thereby p will become .
In short ( x ) ( px) h / 4
Also ( E ) ( t) h / 4
THE UNCERTAINTY PRINCIPLE
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SJ: P-SE 40.8 Locating an electron
The speed of an electron is measured to be
5.00 x 103 m/s to an accuracy of 0.0030%.
Find the minimum uncertainty in determining
the position of this electron.
SJ: P-SE 40.9 The Line Width of Atomic Emissions
The lifetime of an excited atom is given as 1.0 x 10-8 s.
Using the uncertainty principle, compute the line width
f produced by this finite lifetime?
THE UNCERTAINTY PRINCIPLE
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SJ: Section 40.8 P-51 Use the uncertainty
principle to show that if an electron were
confined inside an atomic nucleus of diameter
2x 10-15 m, it would have to be moving
relativistically, while a proton confined to the
same nucleus can be moving
nonrelativistically.
THE UNCERTAINTY PRINCIPLE
SJ: Section 40.8 P-52 Find the minimum
kinetic energy of a proton confined within a
nucleus having a diameter of 1.0 x 1015 m.
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INTRODUCTION TO QUANTUM PHYSICS
QUESTIONS 1. Explain (a) Stefans law (b) Wiens displacement law
(c) Rayleigh-Jeans law. [1 EACH] 2. Sketch schematically the graph of wavelength vs intensity of
radiation from a blackbody. [1] 3. Explain Plancks radiation law. [2] 4. Write the assumptions made in Plancks hypothesis of
blackbody radiation. [2] 5. Explain photoelectric effect. [1] 6. What are the observations in the experiment on photoelectric
effect? [5] 7. What are the classical predictions about the photoelectric
effect? [3] 8. Explain Einsteins photoelectric equation. [2]
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INTRODUCTION TO QUANTUM PHYSICS
QUESTIONS 10.Which are the features of photoelectric effect-experiment
explained by Einsteins photoelectric equation? [2] 11.Sketch schematically the following graphs with reference to
the photoelectric effect: (a) photoelectric current vs applied voltage (b) kinetic energy of most-energetic electron vs frequency of incident light. [1EACH]
12.Explain compton effect. [2] 13.Explain the experiment on compton effect. [5] 14.Derive the compton shift equation. [5] 15.Explain the wave properties of the particles. [2] 16.Explain a wavepacket and represent it schematically. [2] 17.Explain (a) group speed (b) phase speed, of a wavepacket.
[1+1]
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INTRODUCTION TO QUANTUM PHYSICS
QUESTIONS 20.Show that the group speed of a wavepacket is equal to the
particle speed. [2] 21.Explain Heisenberg uncertainty principle. [1] 22.Write the equations for uncertainty in (a) position and
momentum (b) energy and time. [1]
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