innovative technology for processing of carbonaceous wastes · 2019-02-07 · the plant for...
TRANSCRIPT
The plant for processing of carbonaceous wastes with recovery of high-heating synthetic gas and optional production of thermal and electric energy, synthetic liquid fuel, propane
butane fraction gas, ethers or spirits
INNOVATIVE TECHNOLOGYFOR PROCESSING OF CARBONACEOUS WASTES
2019
INNOVATION OF PROJECT
The innovation of project provides:
• The recovery of high-heating synthetic gas with calorific capacity of 6000 to9000 kcal/m3 from carbonaceous solid and liquid wastes by means of thermaldestruction;
• The application of technological know-how for recovery of synthetic liquid fuel,propane butane fraction gas, ethers and spirits from generated high-heatingsynthetic gas including one with no catalysts used;
• The manufacture of mobile plant for processing of carbonaceous wastes toproduce up to 7 types of energy products in compliance with environmentalstandards;
• The plant’s power self-sufficiency with no need to provide the external sourcesof thermal and electric energy for its operation
The innovative technological solutions used in the plant’s operationalcircuit enable for
• excluding the formation of dioxins, furans , benzenes, phenols;
• possibility of substantial reduction of costs with regard to gas-cleaning andenergy equipment;
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SCOPE OF APPLICATION
Our technology enables for recovery of energy and fuel while processingany carbonaceous wastes, e.g. solid (pre-crushed to small-sized pieces),liquid (black oil and heavy oil) or gaseous (associated petroleum gases,coke gas) ones, including:
• oil sludge from oil storage tanks; oil-polluted soil, waste products of oilrefineries
• waste products of wood-processing, pulp and paper or timber industry(sawdust, wood chips, bark, lignin, etc);
• various sludge from effluent treatment facilities, drain fields or methanetanks during biological treatment, etc;
• solid household wastes;
• medical wastes;
• waste products of livestock breeding, poultry farming, plant growing as wellas all kinds of raw materials with an organic origin (peat, coal and other)
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With a view to experimental background available, a newconstruction of turbo-jet thermal destruction reactor which uses thetechnology of heat exchange in a vortex flow, which allows processing largevolumes of organic raw materials, was developed and manufactured in 2017.The technology for heat exchange arrangement in vortex flow applied in itenables for processing of greater amounts of organic raw stock.
The new reactor is characterized by small dimensions, which allowthe plant for processing of carbonaceous wastes to be implemented as amodular construction.
This reactor was tried out for such feedstock as waste water sludge,sawdust, peat, straw, chicken dung with sawdust , brown coal, lignite.
All performed tests provided good results with regard to the qualityof high-heating synthetic gas.
The respective modules are manufactured as transportablecontainers with a complete set of equipment inside.
PRACTICAL RESULTS OBTAINED
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The plant for processing of carbonaceous wastes in the city of Rybinsk, Yaroslavl region, Russia
General view
PRACTICAL RESULTS OBTAINED
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The plant for processing of carbonaceous wastes in the city of Rybinsk, Yaroslavl region, Russia
Raw stock feed-in conveyor
Ash residue collector
Stockpiling, refinement and drying section
Pre-treated feedstock piling bin
PRACTICAL RESULTS OBTAINED
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The plant for processing of carbonaceous wastes in the city of Rybinsk, Yaroslavl region, Russia
Turbo-jet thermal destruction reactor
High-heating synthetic gas after leaving the plant
PRACTICAL RESULTS OBTAINED
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TRADITIONAL TECHNOLOGY INNOVATIVE TECHNOLOGY
PROCESSING PROCEDURE
Slow (auger or retort) pyrolysis, plasma processing
Turbo-jet thermal destruction reactor
PRE-TREATMENT OF WASTES TO BE PROCESSED
Sorting, withdrawal of non-organic components, crushing to medium-sized
pieces, drying
Sorting, withdrawal of non-organic components, crushing to small-sized pieces,
drying
PRIMARY PROCESSING PRODUCTS
Low-heating pyrolysis gas (up to 2000 – 3500 kcal/m3), synthetic liquid fuel, ash residue
High-heating synthetic gas (6000-9000 kcal/m3), ash residue
ENERGY PRODUCTS
Electric power, heat energy, synthetic liquid fuel
High-heating synthetic gas, electric power, heat, synthetic liquid fuel, ethers, spirits,
propane butane fraction gas, coal dust fuel
COMPARATIVE DATA
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COMPARATIVE DATA
TRADITIONAL TECHNOLOGY INNOVATIVE TECHNOLOGY
HEAT-GENERATING EFFECT
None This effect is available, which enables for generation of additional amounts of heat and
reduction of power inputs
AUXILIARY POWER CONSUMPTION
The usage of gas produced on-site to heat the reactor is no less than 30-50% of its total
yield rate
The usage of gas produced on-site to heat the reactor is no more than 10% of its total
yield rate
CONTROL OF PRODUCED GAS COMPOSITION
None Technological procedures of gasification in the process enable to control a mass yield of
light and heavy hydrocarbon components
MOBILITY
None or limited mobility High mobility of plant due to its modular construction
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OVERVIEW OF PLANT FOR PROCESSING OF CARBONACEOUS WASTES
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CONTAINER-TYPE PLANT
FOR PROCESSING OF
CARBONACEOUS WASTES
Main characteristics of CPWC-2
Pre-treated waste processing performance, kg/h ............................... up to 2000
Initial raw stock moisture, % .................... up to 75
Temperature of gasification,°С ….............700 - 900
Pressure in the reactor, kg/сm‘.............- 0,1 - + 0,1
Period of gasification, sec ……………………….…1 - 3
High-heating synthetic gas yield, kg/h …….……………… up to 1500
Gas combustion heat, kcal/mЗ ………. 6000 - 9000
Self-supply electric power, kW/h …………up to 175
Total electric power productionusing synthetic gas, mW/h ………….......... up to 3,5
The period of reactor’s initial heating to reach its operational temperature, min ………... up to 30
The container’s dimensions, m ………. 6 x 2,4 x 2,6
Initial heat energy source………………………….… gas
Waste feed-in to the reactor……………..continuous
Maintenance staff, operator/shift ………..……...2/1
Raw stock feed-in
conveyor
Stockpiling, refinement and drying section
Gas burner
Turbo-jet thermal destruction
reactor
Ash residue collector
Pre-treated stock piling bin
Gas cleaning and cooling-down
system
TECHNICAL CHARACTERISTICS OF CONTAINER-TYPEFOR PROCESSING OF CARBONACEOUS WASTES PLANT
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TECHNOLOGICAL SCHEME FOR PROCESSING OF CARBONACEOUS WASTES
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CPPCPP
Stage 1RAW STOCK FEED-IN SECTION• Pre-treatment of raw materials to be processed (withdrawal of large-sized waste)SORTING AND CRUSHING LINE• Manual sorting (withdrawal of metal inclusions, stones and other non-organic
materials)• Crushing – preliminary refinement of wastes to medium-sized pieces• Magnetic separation – withdrawal of metal inclusions from waste flow
Stage 2DRYING, REFINEMENT AND PRE-HEATING• Pre-treated organic mass of sorted wastes is subjected to drying up to their
dampness rate of < 20% and is refined to the pieces of < 3 mm in size• Before being fed to turbo-jet thermal destruction reactor, dried and refined waste
in continuous flow is heated to 130-150 ºС
THERMOCHEMICAL PROCESSING BY THERMAL DESTRUCTION• With no access for oxygen at 700-900oС in the reactor, organic substances are
subjected to thermal destruction and they transform to gaseous state while non-organic substances deposit as an ash residue
• The period for gasification of organic substances is no more than 3 seconds
TECHNOLOGICAL SCHEME FOR PROCESSING OF CARBONACEOUS WASTES
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Stage 3CLEANING AND COOLING-DOWN OF GASES• After leaving the turbo-jet thermal destruction reactor, gases undergo a
multistep cleaning to prevent the formation of dioxins, furans, phenols andbenzenes
• Cooling-down and separation of gases produce the condensate, which is runoff for its further treatment
Stage 4COLLECTION OF ASH RESIDUE• The ash residue consists of non-organic elements and carbon. It represents a
powder mass, which is not contaminated by hazardous substances and issuitable for its further application (building materials, dyes, absorbents )
Stage 5RECOVERY OF GAS FROM ENERGY PRODUCTSThe generated high-heating synthetic gas can be used for• production of electric power• production of heat energy• production of synthetic liquid fuel• production of ethers, spirits• production of propane butane fraction gas
TECHNOLOGICAL SCHEME FOR PROCESSING OF CARBONACEOUS WASTES
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The usage of waste incineration technology obliterates valuablecomponents of carbonaceous raw stock. It also provides a large amount ofhazardous combustion gases, including an ample quantity of dust-like and gaseousemissions, calling for major technological solutions to clean them, which result inconsiderable financial expenditures on their development and furthermaintenance. Thus, the incineration of 1 ton of wastes requires 10 000 - 15 000m3 of air and subsequent cleaning of total amount of combustion gases.
During thermal destruction of the same mass of wastes the respectiveamount of emitted hazardous gases to be processed after separation of gases ismerely 30-50 m3. That is 300 times less than the amount of combustion gasesformed after incineration of wastes.
Thermal destruction results in generation of high-heating synthetic gas,which can be used for production of electric power, heat, synthetic liquid fuel,ethers, spirits or propane-butane fraction gas.
Ash residue with a high content of metal oxides formed as a result ofthermal destruction can be used in metallurgy, coating plants as an absorbent orplastic filler.
ADVANTAGES OF TURBO-JET THERMAL DESTRUCTION REACTOR TECHNOLOGY OVER WASTE INCINERATION
TECHNOLOGY
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CONCLUSIONS
1. The proposed technology for processing of carbonaceous wastes excels itsworld-wide analogues with regard to their profitability and it is based mainlyon cost-efficient equipment
2. The plant enables for production of energy products from organiccomponents of wastes in compliance with the strictest environmentalstandards
3. Production of power energy and heat from wastes provides self-containedoperation of equipment with low power consumption
4. The plant’s modular construction enables for processing of carbonaceouswastes within a wide range of its daily capacity (20 – 300 tons of wastes)
5. The plant’s equipment enables for production of alternative energy products(high-heating synthetic gas, electric power, heat, synthetic liquid fuel, ethers,spirits, propane butane fraction gas) from wastes.
6. The short period of construction (9-10 months) and payback (1-3 years)
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Alexander Vladimirovich Katlovskiy - General DirectorGrigory Leonidovich Rassokhin - Adviser, Project ManagerE-mail: [email protected], tel: +7 (910) 665-22-44
In scientific and technical association with
“Rythm”, production company, Rybinsk, Russia
“Novaya energiya”, Rybinsk, Russia
“YarLes - 2012”, Rybinsk, Russia
“RUSINPRO”, Moscow, Russia
Lomonosov Moscow State University of Fine Chemical Technologies, Moscow, Russia
Topchiev Institute of Petrochemical Synthesis, RAS, Moscow, Russia
Gubkin Russian State University of Oil and Gas (National Research University), Moscow, Russia
Kirov Saint-Petersburg State University of Forestry Engineering, Saint-Petersburg, Russia
Soloviev Rybinsk State Technical University of Aviation, Rybinsk, Russia
Institute of Combustible Minerals – Technical Scientific Center for Complex Processing of SolidCombustible Minerals, Moscow, Russia
“Sevmash” Production Association, Severodvinsk, Russia
Bezhetsk ASO plant, Bezhetsk, Russia
“Bezhetskselmash”plant, Bezhetsk, Russia
PARTICIPANTS AND PARTNERS OF PROJECT
www.nt-yar.ru
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THANK YOU!