icbces abstractbook 2016

Conference Proceedings Book

2nd International Conference on Innovations in Chemical Biological amp Environmental Sciences

(ICBCES) 12th February 2016

Being jointly organized by

Swami Sukdevanand PG College Shahjahanpur

GIAP Journals Oman and

Association of Chemistry Teachers Mumbai

Editors

Dr Priy Brat Dwivedi Senior Faculty Caledonian College of Engineering

Oman

Dr Alok Kumar Singh Head Department of Chemistry

SSPG College Shahjahanpur UP India

Published by Gyandhara International Academic Publications (GIAP Journals) Oman

wwwgiapjournalsorg wwwgiapjournalscom Email publicationsgiapgmailcom

Swami Chinmayanand Saraswati

Former Union Home Minister (State)

Govt of India

Message

An Ideal education Institution aims not just at imparting the knowledge and information rather it

equips the learner with our ancient values and ethics laid down and fostered through the

scriptures over the centuries It targets at enhancing the Intellectual as well as the daily living

standards of a common human being Over the decades the science has progressed by leaps

and bounds and yet the reflective process centered on the principles values and ethics that can

evolve a common human mind to a real human being is still the cry of the age

I am elated to proclaim that our alma mater Swami Sukdevanand PG College Shahjahanpur is

heading its way by bestowing knowledge coupled with Human Values to the sincere and

genuine learners of this small town of Uttar-Pradesh and it is proving its worth like an oasis in a

desert In this eternal continuum Swami Sukdevanand PG College Shahjahanpur UP India is

organizing 2nd International Conference on Innovations in Chemical Biological amp Environmental

Sciences (ICBCES) on 12th February in our lush green alluring college campus

I extend my warm greetings and blessings to this unstoppable journey of knowledge-seekers

and hope sanguinely that the Inter-cultural interaction of the learned scholars will surely go a

long way and set milestone on the ever sprawling path of knowledge

(Swami Chinmayanand Saraswati)

Rajni Dwivedi CEO GIAP Journals Oman

Message

The management of GIAP Journals is congratulating SSPG College Shahjahanpur for

organizing 2nd International Conference on Innovations in Chemical Biological and

Environmental Sciences on 12th February 2016 in its campus

At GIAP Journals we strongly believe in creating values for best interest of society ICBCES

2016 is a perfect platform where researchers academicians students will be delivering

innovative solutions discussing networking and motivating each other by lively interactions We

know all committee members have worked very hard to make this conference successful

To recognize special efforts of researchers and academicians GIAP Journals is announcing

GIAPrsquos Community Service award and GIAPrsquos Researcher award for year 2016

GIAP Journals is also bringing innovative mobile research conferences in 2016 so that

International and National research conferences can be organized online and huge amount of

money energy and time can be saved More details will be coming at wwwgiapconferencesorg

We are thankful to Association of Chemistry Teachers Mumbai for collaboration Reliance Rosa

power plant and all sponsors of the conference

I wish great success for ICBCES 2016

(Rajni Dwivedi)

Prof A K Mishra Principal S S PG College Shahjahanpur

Message

Founded in 1964 by HH Swami Shukdevanand Saraswati Ji Maharaj Swami Shukdevanand

(PG) College Shahjahanpur is now an idiom of success quality and world class education in

the Rohilkhand region Presently the Institution runs graduate and postgraduate courses in

Faculties of Arts Science Commerce Education and Computer Science in which the students

and scholars are learning various academic professional and life skills

The Faculty of Science has been constantly striving to establish newer heights in the firmament

of knowledge and research and is organizing 2nd International Conference on Innovations in

Chemical Biological amp Environmental Sciences (ICBCES) on 12th February 2016 I can foretell

without any frail hitch that the eminent and learned scholars hailing from different parts of the

globe will surely enlighten the participants by acquainting them with the recent innovations and

inventions in Chemical Biological and environmental sciences and prove to be beneficial for

the scientists research scholars teachers and students

I appreciate the conjoint toil of the faculty members of Science and organizing secretary in

particular and wish them for the successful publication of the souvenir

(Prof A K Mishra)

Ram Chandra Singhal Secretary S S PG College Shahjahanpur

Message

Swami Shukdevanand (PG) College Shahjahanpur is one of the pioneering educational

Institutions of M J P Rohilkhand University For the all round development of the students and

scholar community of the region the Institution is regularly organizing many symposia

Seminars workshops and other curricular and extracurricular activities and the present 2nd

International Conference on Innovations in Chemical Biological amp Environmental Sciences

(ICBCES) held on 12th February 2016 is one of such events organized by the Faculty of

Science of the college

I wish and congratulate for grand success of the Seminar

(Ram Chandra Singhal)

Dr Alok Kumar Singh Organizing Secretary ICBCES 2016 HoD Chemistry Department S S PG College Shahjahanpur

Message Organizing committee of ICBCES 2016 welcomes all delegates in beautiful campus of Swami

Shukdevanand (PG) College Shahjahanpur ICBCES 2016 is being organized in association

with GIAP Journals Oman and Association of Chemistry Teachers Mumbai This conference

has created an ecosystem in which researchers academicians and industry are working in

collaboration for better interest of society

ICBCES 2016 is attracting best research articles in the field of chemical biological and

environmental sciences We are hopeful that the outcome of ICBCES will benefit the society

and will generate innovative solutions to the chronic challenges of environment

We are thankful to management administration staff and students of college for overall support

and coordination

I wish and congratulate for grand success of the ICBCES 2016

(Dr Alok Kumar Singh)

2nd International Conference on Innovations in Chemical Biological amp Environmental Sciences (ICBCES) at SSPG College Shahjahanpur UP India

2016

1 Editors Dr Priy Brat Dwivedi Dr Alok Kumar Singh

SYNTHESIS AND FUNGICIDAL ACTIVITY OF BIOACTIVE 44rsquo-BIS [4rdquo-(N-BENZYLIDINYLAMINE) -3rdquo MERCAPTO -1rdquo2rdquo4rdquo-TRIAZOLE-5rdquoYL METHOXY] BIBENZYL

Smriti Dwivedi1IR Siddiqui

2

1Dept of Chemistry Galgotia College of Engg amp Technology Greater Noida UP India

2Laboratory of Green Technology Dept of Chemistry University of Allahabad Allahabad UP India

smriti96rediffmailcom Among heterocyclic compoundsNitrogen heterocyclic compounds containing 124 triazole nucleus posses various biological activities and have been used for development of useful pharmacological agentsIt has been found that natural as well as synthetic bibenzyls both show antifungal activity Bibenzyl are naturally occurring potential fungicidesWith the hope of exploring new antifungal bibenzyls having 124 triazole heterocyclic moieties it was considered to synthesize new potentially bio-active safe environment friendly fungicides with aim to increase permeability into the fungal cell Several bibenzyl incorporating 124 triazole heterocyclic moieties have been designed in such a way so that most of them incorporate toxophorically important grouping for fungi Keywords bibenzyltriazole fungicides toxophoric AN ESIPT BASED FLUORESCENT PROBE FOR SELECTIVE DETECTION OF CYANIDE IN DIFFERENT

MEDIUM Rashid Ali Ramesh C Gupta Sushil K Dwivedi and Arvind Misra

Department of Chemistry Institute of Science Banaras Hindu University alirashid85gmailcom

A new polynuclear hetero atom containing molecular organic scaffold 3 has been synthesized and characterized The detailed optical properties of probe 3 have been investigated in THFHEPES buffer (vv = 20 pH 704) The molecular probe 3 showed good photophysical behavior due to excited state intramolecular proton transfer (ESIPT) mechanism The UV-vis spectrum of 3 (10 microM) showed a low energy transition band at 376 nm (ε = 164 x 104 M-1cm-1) with a shoulder at 480 nm (761 x 10-2 M-1cm-1) and upon excitation at 376 nm displayed a weak emission at 528 nm (Ф3 = 0009 Stokes shift 7656 cm-1) Upon interaction with different anions 3 showed high selectively with excellent sensitivity (1534 ppb) for cyanide anion (CN-) through a reaction based chemodosimeter approach in which relative fluorescence intensity of 3 enhanced significantly bdquoturn-on‟ (~80 fold) with blue shift of ~34 nm to appear at 494 nm (Ф3+CN- = 0121) Probe 3 enabled naked-eye sensitivity in which a fluorescent dark green colour changed to bright blue-green colour with considerable fluorescence bdquoturn-on‟ due to the formation of cyclic oxazole derivative 4 in the medium Job‟s plot analysis revealed a 11 binding stoichiometry between 3-CN- The mechanism of interaction between 3 and CN- has been confirmed by the change in optical behaviours 1H NMR 13C NMR HRMS and X-ray crystallography data The potential chemodosimeter 3 has also been utilized to detect cyanide on test paper strips and silica coated microslides Moreover probe 3 is also applicable to determine CN- concentration in real contaminated water samples with excellent recovery of CN- in the range of 98 to 94

APPLICATIONS OF ULTRASOUND IN FOOD PROCESSING Ahmet UumlNVER

Necmettin Erbakan University Faculty of Engineering and Architecture Department of Food Engineering Meram Konya TURKEY

unveraetkonyaedutr Nowadays researchers are interested in minimally food processing techniques because of the fresh or fresh-like food preference of the consumers Ultrasound is an acoustic energy but its effect is a result of physical energy which is generated by the kinetic energy of the molecules in the applied medium Its powerful effect drawn the interest of the scientists to investigate on its applications in many areas In food science ultrasound has a wide range of applications Microbial inactivation drying filtration extraction homogenization cutting emulsifying cleaning degassing and inactivation of enzymes are some of the examples of efficient applications of ultrasound The two important well-known benefits of the usage of ultrasound are the reduction of the process duration and process cost In this review some ultrasound applications will be discussed in food science and technology Key words Ultrasound food processing minimally food processing


2016


HYPERSPECTRAL IMAGING TECHNIQUE AS A STATE OF ART TECHNOLOGY IN MEAT SCIENCE Hasan İbrahim KOZAN Cemalettin SARICcedilOBAN Hasan Ali AKYUumlREK Ahmet UumlNVER Necmettin Erbakan University Seydişehir Vocational School 42090 Seydişehir KonyaTURKEY

e-mail hkozankonyaedutr Selccediluk University Agricultural Faculty Department of Food Engineering Selccediluklu Konya TURKEY Necmettin Erbakan University School of Applied Sciences Department of Managemet Information

Systems Selccediluklu Konya TURKEY Necmettin Erbakan University Faculty of Engineering and Architecture Department of Food Engineering

Meram Konya TURKEY Nowadays the concern of meat consumption safety and quality has been popular due to some health risks such coronary heart disease stroke and diabetes caused by the content as saturated fat cholesterol content and carcinogenic compounds for consumers The importance of the need of new non-destructive and fast meat analyze methods are increasing day by day For this researchers have developed some methods to objectively measure the meat quality and meat safety as well as illness sources Hyperspectral imaging technique is one of the most popular technology which combines imaging and spectroscopic technology This technique is a non-destructive real-time and easy-to-use detection tool for meat quality and safety assessment It is possible to determine chemical structure and related physical properties of meat It is clear that hyperspectral imaging technology can be automated for manufacturing in meat industry and all of data‟s obtained from the hyperspectral images which represents the chemical quality parameters of meats in the process can be saved to database Keywords non-destructive method hyperspectral imaging meat science COMPARISON OF THIOBARBITURIC ACID LEVEL PREDICTION POWER BETWEEN STATISTICAL AND

ARTIFICIAL NEURAL-NETWORK MODELS IN GROUND MEAT Hasan Ali AKYUumlREK

1 Hasan İbrahim KOZAN

2 Barış KOCcedilER

3 Cemalettin SARICcedilOBAN

4

1Necmettin Erbakan University School of Applied Sciences Department of Management Information Systems

Selcuklu Konya TURKEY e-mail hakyurekkonyaedutr

2Necmettin Erbakan University Seydisehir Vocational School 42090 Seydisehir Konya TURKEY

3Selcuk University Faculty of Engineering and Architecture Department of Computer Engineering Selcuklu

Konya TURKEY 4Selcuk University Agricultural Faculty Department of Food Engineering Selcuklu Konya TURKEY

In this study it‟s aimed to predict Thiobarbituric Acid (TBA) level by processing the data from color parameters of ground meat A dataset of 600 TBA L a b Chrome Hue Day of Storage and Light Source values obtained from the experimental analysis of ground meat was mined Five hundred objects were used as the training set and one hundred as the test set in application of artificial neural-network model The final developed model presented higher performance as R2 = 099 (R2 = 099 on the training set R2 = 098 on the test set) for the artificial neural-network than statistical model as R2 = 091(R2 = 092 on the training set R2 = 090 on the test set) Artificial neural network is shown to be a powerful and suitable tool for the prediction of TBA level of ground meat Keywords Artificial Neural-Network Ground Meat Thiobarbituric Acid Statistical Model

INDIAN INITIATIVES FOR ENVIRONMENT CONSERVATION D V Prabhu

Department of Chemistry Wilson College (University of Mumbai) Mumbai 400007 Email dvprabhu48gmailcom

Society at large has to realize the gravity of environmental degradation and participate fully in the mitigation of environmental problems The commitment of the Indian Government to the cause of public awareness of environment conservation is reflected in its outreach and educational programmes involving its ministries environmental monitoring agencies NGOs academic and research institutions The Ministry of Environment and Forests (MoEF) has played a leading role in the national priority programmes of environmental monitoring assessment and pollution control All the stake holders have succeeded to some extent in creating public interest in environmental issues but much more needs to be done This presentation discusses the Indian initiatives and the important milestones in the path of environmental protection and pollution abatement


2016


A NEW TITRIMETRIC METHOD FOR DETERMINATION OF AMIDARONE HYDROCHLORIDE IN PURE FORM AND IN THEIR PHARMACEUTICAL PREPARATIONS

Sanjai Kumarab

Manoj Kumar Singhb and ICShukla

a

Department of Chemistrya University of Allahabad Allahabad-211002

Department of Chemistryb SVNPG College Kalan Sultanpur

Email sanjaichemaugmailcom

This article describes a simple and convenient titrimetric method for determination of Amidarone hydrochloride in pure form and in their pharmaceutical preparations like Cardasol and Cordarone Amidarone hydrochloride is an anti-arrhythemic agent used for various types of cardiac dysrhythmias both ventricular and atrial Aliquots containing 1 3 5 mg of samples were determined and percentage error standard deviation coefficient of variation was calculated for each sample size To evaluate the authenticity of the method recovery experiments were also carried out by standard drug addition method Key words Amidarone hydrochloride Titrimetric method Recovery experiments

MECHANISTIC ASPECT OF RH(III) CATALYSED OXIDATION OF 2-METHYL CYCLOHEXANOL AND 2-PHENYL ETHANOL BY CERIUM(IV) SULPHATE IN ACIDIC MEDIUM Alok K Singh Raj Kamal Rastogi Sumit Saxena Gulshan Rastogi Department of Chemistry SSPG College Shahjahanpur-242001 India

E-mail alokks32gmailcom

Un-catalyzed oxidation of aromatic compounds by cerium (IV) has been frequently reported from the kinetic and synthetic point of views but proper attention has not been given to these oxidations in the presence of transition metal ions Present study shows that oxidation of 2-methyl cyclohexanol and 2-phenyl ethanol by cerium (IV) sulphate in aqueous sulphuric acid medium is greatly enhanced by rhodium (III) chloride Reactions follow direct proportionality with respect to catalyst concentrations while the first order kinetics shown by the oxidant and organic substrate at their low concentrations become zero order at higher concentrations of both oxidant and organic substrate Rate decreased with increasing concentrations of H

+

ions Externally added CeIII and Cl ions have negative effects on the reaction rate Catalyst combines with the

complex formed between cerium (IV) and organic substrate and ultimately gives rise to corresponding aromatic dicarboxylic acids as the product of oxidation Complex formation in 2-methyl cyclohexanol is easier compared to that in case of 2-phenyl ethanol

EFFICIENCY OF SOME CORROSION INHIBITORS ON REBAR IN SALINE MEDIA

Monalisa Kundu1

Shailesh Kumar Prasad2 Virendra Kumar

3

12 Department of Chemistry

3Department of Civil Engineering National Institute of Technology Jamshedpur

E-mail address monaiitr08gmailcom

Many different methods have been proposed to address rebar corrosion in reinforced concrete structures Corrosion inhibitors may be a good way to control reinforcing steel corrosion because they are easy to apply and less costly than other prevention methods like barrier layers and cathodic protection The objective of this paper is to study the inhibitive effects of several inhibitors when they are used in reinforced cement mortars Electrochemical monitoring of half-cell potential (HCP) linear polarization resistance (LPR) and compressive strength taking different inhibitor concentrations were performed in 35 NaCl medium in order to obtain inhibitor information on the corrosion behavior of the reinforcing steel in cement mortar Results demonstrated best inhibitory effect in presence of inorganic Sodium nitrite based inhibitor compare to chromate inhibitor and DMEA based inhibitor Moreover in case of DMEA based organic corrosion inhibitor the passivation of the steel was reached in much longer time Compressive strength effect showed significant reduction with nitrite inhibitor whereas in the case of chromate inhibitor there was an improvement in the compressive strength of the rebar in saline medium No significant change in compressive strength was determined with DMEA based inhibitors Keywords Corrosion inhibitor inorganic inhibitor organic inhibitor half-cell potential linear polarization resistance compressive strength


2016


PHYSICOCHEMICAL PARAMETERS STUDY OF CHITOSAN-STARCH-GLUTARIC ACID IN ACETIC ACID-WATER MIXTURES

Virpal Singh Department of Applied Chemistry M J P Rohilkhand University Bareilly - 243006 (UP) India

Email singh_veer_palrediffmailcom Chitosanstarch solutions of different concentrations (9010 to1090) are prepared in dilute acetic acid solution (1 ) Glutaric acid solution concentration is 1 fixed The solution properties such as viscosity and refractive index are measured Viscosity of Chitosan-Starch-Glutaric acid solution is measured by Brookfield viscometer modal DV-E version 100 and refractive index is also measured by Abbes refractometer The influence of concentration of solution and speed of rotation on shear stress are also determined for polymer solution Keywords Chitosan starch Glutaric acid refractive index viscosity

SYNTHESIS AND CHARACTERIZATION OF TI (III) V (III)VO (IV) MOO (V)FE (II) AND FE (III) COMPLEXES OF BENZIL- 24-DINITROPHENYL HYDRAZONE P-BROMO ANILINE

Raj Kamal Rastogi Sonu Sharma

Gulshan Rastogi

Alok K Singh

Department of Chemistry SS (PG) College Shahjahanpur

MSIC Shahjahanpur Arya Mahila ( PG) College Shahjahanpur (UP) India

Email rajkamal902gmailcom The complexes of Benzil-2 4-dinitrophenyl hydrazone-p- bromo aniline with Ti(III)V(III) VO(IV)MoO (V) Fe(II) Fe(III) have synthesized and characterized by elemental analysis magnetic measurement data molar conductance TGAUV-visible and IR spectra data The complexes of Ti (III) V (III) Fe (II) and Fe (III) have octahedral geometry while VO (IV) and MoO (V) have distorted octahedral geometry due to the presence of M=O moiety Key word Schiff base Synthesis Molar Conductance Spectroscopy

DESTRUCTION OF RESINOUS COMPOUND FROM WASTE BY USE OF NATURAL ENZYMES 1Dr Harsha Chatrath

2Rohit Durge

1Adjunct Professor

2Research Associate Department of Chemistry

Dr DY Patil ACS College Pimpri Pune (India) harshamohinigmailcom

In present scenario huge quantity of waste are produced every day It contains plastics waste papers plastic containers some of these are degradable and some of these are non degradable waste Non biodegradable things are present in waste treated with mechanical pulverizing mechanisms and with few of strong chemical Chemicals such as concentrated Hydrochloric Sulphuric acids sulphamic acids and many other hazardous chemicals are used for destroying wastes in simple form or in disperse form Almost 70 of the waste is being dumped in the soil layer After certain interval of time compounds present in soils such as salts of the metals and temperature of soil help in decomposing the waste periodically Due to this process large quantity of soil gets contaminated In this project we have tried to replace hazardous chemicals with other non-hazardous chemicals and some natural enzymes which may give same reactions as with toxic chemicals Objectives may also helps in use of eco friendly chemicals for reducing soil pollution and water pollutions Hence it will minimize the other impacts on environment such as air pollution noise pollutions water pollutions and soil pollutions All process will carry out under Green Chemistry cycles Key Words Non biodegradable waste material Hazardous chemicals natural enzymes Green Chemistry

SYNTHESIS AND ANTIFUNGAL ACTIVITY OF SOME 3 5- BIS (3-ARYL RHOCLANIN-5-ALAZO) -4- PHENYL-124-TRIAZOLES

Bandana Dwivedi Department of Chemistry TDPG College Jaunpur

Email drrajnishdwivedijnpgmailcom 3 5- Bis (3-Aryl Rhoclanin-5-Alazo) -4- Phenyl-124-Triazoles were prepared by diazotization of 4-Phenyl -34 - diamino-1 2 4-triazoles followed by adding ice cold solution of 3-Phenyl rhodanin in acetone containing sodium acetate gradually by stirring and cooling The synthesized triazoles were screened their antifungal activity against the test fungi viz Aflavus and Calbicans at different concentrations


2016


DESIGN AND SYNTHESIS OF AN EFFICIENT MOLECULAR ORGANIC SCAFFOLD EXHIBITING HG2+

INDUCED FLUORESCENCE QUENCHING AND CYANIDE SENSING (ON-OFF-ON) VIA MERCURY DISPLACEMENT APPROACH

Ramesh C Gupta Syed S Razi Sushil K Dwivedi Rashid Ali and Arvind Misra Department of Chemistry Faculty of Science Banaras Hindu University

Varanasi INDIA Email arvindmisra2003yahoocom amisrabhuacin

A simple triazole-appended antharacene-quinoline conjugates probe 7 have been designed and synthesized The photophysical behaviour of probes and their interaction with metal ions and anions have been examined through the absorption and fluorescence spectroscopy in HEPES buffer medium Probe 7 showed good optical behaviour in 60 aqueous THF and upon interaction with different metal ions and anions displayed strong fluorescence quenching (~ 94 switch-Off) selectively with Hg

2+ Moreover 7-Hg

2+ ensemble when tested

toward different anions only cyanide (CN-) enable mercury displacement (as Hg(CN)2) and led to fluorescence

enhancement (switched-On) Probe 7 has shown high sensitivity to detect Hg2+

selectively in real water sample and on cellulose paper strips Additionally the naked eye sensitive ldquoOn-Off-Onrdquo sensing behaviour of probe 7 mimics the function of a sequential logic circuit at molecular level The proposed mechanism of interaction has been supported by FTIR NMR (

1H and

13C) ESI-MS spectroscopy and DFT

STUDY OF POLYVINYL BUTYRAL COMPOSITE MATERIALS WITH THEIR NOVEL CHARACTERISTICS

AND VARIOUS POTENTIAL APPLICATIONS 1Nida Khan

2Deepak Kumar

3Pramendra Kumar

3Assistant Professor

12 Research Scholar Department of Applied Chemistry

MJP Rohilkhand University Bareilly 243006 (UP) Email nidarehman09gmailcom

As composite materials are crucial part of life a great deal of composites is available around us and is also synthesized in laboratory since these are being used for the preparation of significant articles Their classification and applications in various fields are highly governed by the size of particles they acquire Polyvinyl butyral (PVB) is a material when used as a constituent part in the formation of composite induces a specific property in a resulting one which are utilized by various ways because of being stronger in binding sharper in optical clarity and being able for providing flexibility and toughness in the formed composite This random copolymer is constituted by means of hydrophilic vinyl alcohol group and hydrophobic vinyl butyral group which behave as promoters of polymer adhesive and binders for organic moieties to provide a vast area of applications using this polymer in different forms like as material to produce antireflecting coating to generate mesosphere in the formation of polymeric electrode in the formation of polymeric electrolyte as nanofibre and in the synthesis of alumina fiber and in other ways as in manufacturing of photovoltaic thin film solar modules and as nanofibre in the construction of surface acoustic wave humidity sensor Key words- Composite Nanoparticle PVB nanofibre antireflecting material etc A MOLECULAR KEYPAD LOCK SYSTEM EXHIBITS TUNABLE FLUORESCENCE SWITCHING (ON-OFF)

WITH ZN2+

AND F- IONS

Arvind Misra Mohammad Shahid Priyanka Srivastava Ramesh C Gupta Sushil K Dwivedi Rashid Ali and Syed S Razi

Department of Chemistry Faculty of Science Banaras Hindu University Varanasi UP India alirashid85gmailcom arvindmisra2003yahoocom amisrabhuacin

A bischromophoric dyad 1 upon interaction with various cation and anion exhibits fluorescence enhancement and quenching with Zn

2+ and F

- ions in H2O-ACN (10) respectively The output emission signals providing

chemical inputs of H+ OH

- Zn

2+ and F

- have been implemented to construct OR INHIBIT and TRANSFER

logic gates The fluorescence bdquoOn-Off‟ switching behavior of a molecular keypad lock authorizing password entries has been realized in which computing the output emissions of chemical inputs sequentially (F

-(A) then

Zn2+

(I) ions) unlock the keypad lock (M On state) whereas on reversing the sequence of inputs it remained locked (T Off state) keeping in memory a correct and incorrect password entries AIM and IAT respectively A correct combination of chemical inputs (F

- Zn

2+ and EDTA) easily reset-set logic operations and make the

device reusable


2016


QSPRS STUDY ON HUMAN CARBONIC ANHYDRASE IV INHIBITORS Shalini Singh

a and MB Kalhans

a

aQSAR amp Cheminformatics Laboratory Department of Chemistry Bareilly College Bareilly (UP) India

shalinisingh_15yahoocom

The membrane-associated CA IV increased production of aqueous humor and excitatory function Neurons causes glaucoma and epilepsy disease A series of 2-substituted-134-thiadiazole-5-sulfamides was prepared and assayed as inhibitors of carbonic anhydrase (CA EC 4211) the membrane-associated CA IV by CT Supran This paper presents result of quantitative structurendashProperty relationships (QSPR) study realized with the PRECLAV omega brood and MOPAC software The dependent property is the inhibitory activity against human carbonic membrane-associated hCAIV The calibration set includes 11 heterocyclic sulphonamides incorporating with two clinically used CA inhibitors namely AZA and ZNS molecules The prediction set contains 11 others not yet synthesized substituted sulphonamides having unknown observed values of activity In the presence of prediction set the predictive quality of QSPR of hCA VI (r2 = 09869 F =3381053 r2CV =09795) is large The obtained models suggest a slightly different inhibition mechanism for the two isoforms Large percentage in weight of C2HN3 Br atom molecular fragments seems to be favorable to inhibitory activity and NH2 and SO2 Keywords QSAR omega brood PRECLAV carbonic anhydrase IV SYNTHESIS AND CNS DEPRESSENT ACTIVITY OF NOVAL SERIES OF THIAZOLIDENE DERIVATIVES

Dhananjay Singh Department of Chemistry PPN (PG) College CSJM University Kanpur (UP) India

Email- dhananjay360gmailcom Several new 5

-(p-substituted unsubstituted) phenyl-134- Thiadiazolyl-2

-(5-pheyl-2- oxo-thiazolidine) amp 4

-

(p-substituted unsubstituted) phenyl-13- oxazolyl -2-(5-pheyl-2- oxo-thiazolidine) have been prepared by

reaction of 2-substituted arylidine- 5-phenyl thiadiazole amp 2-substituted arylidine- 5-phenyl oxazole with thioglycolic acid respectively Few of these compounds are characterized by IR and NMR spectra These compounds have been tasted for their CNS activity Spontaneous motor activity (SMA) of mice in group was recorded by using automatic activity cage Some of the compounds were possess a moderate degree of central sedative action as in evident from the reduction in SMA Keywords Oxazole Thiadiazole Spontaneou motor activity CNS

IRIDIUM CHEMISTRY AND ITS CATALYTIC APPLICATIONS A BRIEF REVIEW Santosh Bahadur Singh

Department of Chemistry National Institute of Technology Raipur Raipur-492010 Chhattisgarh (India) E-mail singhsbnitrr15gmailcom

Iridium is very important element among the all transition metals with highest reported oxidation state ie +9 in gas phase existing species IrO4

+ Instead of its less reactivity it forms number of compounds having oxidation

states between -3 to +9 It is second known densest element after osmium Till now its toxicity and environmental impact is not much more reported and thus it may be use as green element in various fields of its application Reason behinds it‟s less toxicity and environmental impact may be due to its less reactivity and solubility Corrosion and heat resistant properties of Iridium makes it much more useful element for alloying purpose Iridium is the member of platinum family and used as catalyst due to its variable oxidation states Iridium(III) complexes shows great catalytic activity in both the acidic and basic medium for various organic as well as inorganic chemical conversions Catalyst may be defined as the substance which can increases the rate of reaction of a specific chemical reaction without changing its own composition Iridium is only one reported catalyst which is able to capture the sunlight and convert it into the chemical energy Thus it may be used in artificial photosynthesis process to solve our future food problem Instead of these advantage Iridium chemistry and its catalytic activity is not much reviewed till date therefore present review includes a brief introduction about chemistry and catalytic application of Iridium which proof itself a boon for beginners to start their research career in the field of Iridium chemistry Keywords Iridium Oxidation State Catalysis Photosynthesis Alloys Environmental Impact


2016


IMMUNOMODULATORY POTENTIAL OF MADHUCA LONGIFOLIA Dr Santosh Kumar Singh

Assistant Professor Department of Chemistry Sri JNPG College Lucknow

E-mail santoshsinghjnpggmailcom A large number of plants and their isolated constituents have been shown to have potential immunity Some medicinal plants have been shown to exert immunomodulatory and anti-cancer activity The present study was undertaken to evaluate the effect of Madhuca latifolia on immunomodulatory activity that comprises of screening to identify the activity of ethanolic extract of Madhuca latifolia on humoral and cell mediated immunity (specific immune response) Experiments were conducted in vivo in Swiss albino mice Madhuca latifolia ethanolic extract was found to enhance humoral immune response on 10th day by 15 as compared to the standard control cyclophosphamide that exhibited 64 humoral immune response where as cell mediated immune response was observed with an enhancement in the values (2557) in comparison with control cyclosporine (4780)

SHIFTING PRACTICES IN PHARMACEUTICAL INDUSTRY ROLE OF GREEN CHEMISTRY

Dr Abha Dubey Dr Rakhi Dwivedi Dr Subhashini Sharma Dr Renu Sharma Dept of Chemistry MMH College Ghaziabad CCS University Meerut UP

E-mail abhaadubeygmailcom

Madison Wisconsin ndash ldquoProduction of a single kilogram of pharmaceuticals often yields hundreds of kilograms of chemical wasterdquo The mute point is to deal with this mountain of chemical waste This chemical waste seems impossible to be disposed off without leaving damages to the environment Link between pharmaceutical industry and environment is the serious concern for the researchers Certain pharmaceutical contains chemicals which can adversely affect living beings To address the problem of this chemical waste would be a patch work if we just think of dealing with this waste Instead Green Chemistry has a momentous task of creating newer practices of producing relevant molecules with least generation of hazardous by products Modern pharmaceutical research has taken up this challenge of investing massively on new facilities of RampD to reach out to the desired products with possibility of recycling the by-products Taking up the responsible the pharmaceutical industry has started adopting ldquogreenerrdquo processes and technological operations Big drug manufacturers in the developed countries are advancing new methodologies better bio-catalytic reactions less solvents and generation of lesser waste Pharmaceutical industry introduces practices to save a negative impact of its products on environment Still bigger is the challenge that this is to be done without adding to the cost by resorting to financially viable methods Safety Efficiency Reliability and Economy are the four pillars of establishing a sound foundation for Green Practices and their promotion is considered as bringing competitive advantage better environmental credentials and economic benefits The hope is that new technology will contribute to the bdquogreening‟ of the pharmaceutical industry COMPETITIVE ADSORPTION BEHAVIOR OF CR(VI) AND MO(VI) THROUGH SIX TYPES OF SOIL BEDS

Abdul Mohemana

and Ali Mohammadb

aDepartment of Chemistry Gandhi Faiz-e-Aam (Post Graduate) College Shahjahanpur 242 001 India

bDepartment of Applied Chemistry Aligarh Muslim University Aligarh 202 002 India

E-mail amohemanappchemgmailcom

Generally chromium(VI) and molybdenum(VI) are found in soil at low concentration level as a result of contamination by agricultural activities sewage sludge industrial wastes and waste water Both metals have many physical and chemical similarities and belong to the same group (group VI) of the periodic table These metals when apply to soil may transport through soil and can react with organic and inorganic compounds to form soluble or insoluble compounds or get adsorbed on soil colloids Our goal was to investigate the adsorption behavior of chromium (VI) and molybdenum (VI) using six types of soil beds by thin layer chromatography On the basis of differential migration optimum conditions for the separation of Cr(VI) from Mo(VI) on soil thin layer plates were identified The adsorption of Cr(VI) and Mo(VI) through all soils follows the order Mo(VI) gt Cr(VI) A statistical analysis of the results (p le 005 and 001 level) revealed a significant positive correlation between RF values of Cr(VI) and Mg content of soil (r = 0930) or the base saturation (r = 0831) as well as between RF value of Mo(VI) and Mg content of soil (r = 0872) sum of bases (r = 0847) or


2016


the base saturation (r = 0925) Conversely a significant negative correlation between RF values of Cr(VI) and soil organic matter (r = -0916) or cation exchange capacity of soil (r = -0851) was observed Similarly significant negative correlation between RF values of Mo(VI) and clay content (r = -0928) or cation exchange capacity (r = -0852) of soil also exists The adsorption of Cr(VI) and Mo(VI) were found to depend upon the soil parameters such as soil organic matter clay content of soil cation exchange capacity of soil cation saturation size of soil particles soil pH sewage sludge content as well as the sample pH and the nature of surfactant in the mobile phase Key words Adsorption metal ions soil parameters surfactants soil thin layer chromatography

SYNTHESIS AND CHARACTERIZATION OF ZINC COMPLEXES WITH NUCLEOBASES

Dr Shalu Tyagi

MMHCollege Ghaziabad UP shalutyagi30gmailcom

The metal coordination of nucleobases their precursors derivatives and of nucleosides nucleotides is very active area of research Zinc is also present in various enzymes along the biosynthetic pathways of the nucleobases or for phosphate transfer during nucleotide interconversions The synthesis of HB(3-Bu

t-5-

Pripz)3)ZnX (where X is thymine 2 adenine 3) using HB(3-Bu

t-5-Pr

ipz)3)Zn-OH 1 has been described The

complexes were characterized by elemental analysis I R and X-ray powder diffraction I R data also suggested that the thymine is bound to zinc via N1 as in the case of uracil while N9 seems to be preferred donor atom in case of zinc complex of adenine The indexing pattern of X-ray powder diffraction yield the lattice constants a = b = 1431 c = 1924 Aring for 2 a = b = 1338 c = 1507 Aring for 3 indicating tetragonal symmetry for these complexes During these studies it became obvious that the deprotonation of mildly acidic NH functions is facilitated in the presence of zinc ions and the encapsulation of zinc by sterically demanding tripodal ligands facilitates complexation of the corresponding anionic species The substituted pyrazolylborate ligand KHB(3-Bu

t-5-Pr

ipz)3) was found to stabilize monoanionic species X by protecting them in the

hydrophobic pocket of the neutal complexes 2 and 3

SYNTHESIS SPECTROSCOPIC AND BIOLOGICAL STUDIES OF LANTHANUM(III) AND PRASEODYMIUM (III) DERIVATIVES WITH LIGANDS DERIVED FROM BENZIL-α-MONOOXIME

Anita Rai Department of Chemistry PPN PG College Kanpur UP India

Email raianita19gmailcom

Eighteen new lanthanum(III) and praseodymium(III) complexes of the general formula [LnCl(L)H2O]2 (Ln=La or Pr) L=benzil-α-monoxime semicarbazones thiosemicarbazones dithiocarbazates have been synthesized in methanol in presence of potassium hydroxide The complexes have been characterized by elemental analysis molar conductance electronic absorption fluorescence infrared far infrared

1H and

13C NMR spectral

studies Thermal studies of these complexes have been carried out in the temperature range 25-800oC using

TG DTG and DTA techniques All these complexes decompose gradually with the formation of Ln2O3 These complexes are used as polymer catalyst fungicides and bactericides SYNTHESIS CHARACTERIZATION AND APPLICATIONS OF SILVER NANOPARTICLES PREPARED BY

BIOMIMETIC METHODS A REVIEW Mahesh Kumar Gupta Girdhari Lal Chaurasia Neelam Shukla PKTandon

Department of Chemistry University of Allahabad Allahabad UP E-mail pktandon1gmailcom mahesh27620gmailcom

Nanotechnology is science engineering and technology conducted at the nanoscale which is about 1 to 100 nanomters In the nano size range the physical chemical and biological properties of matter may change drastically in relation to the bulk of atoms or molecules The applications of nanoparticles and nanomaterials are increasing rapidly due to their enhanced properties based on size their distribution and morphology It is an important discipline which has multiple applications such as in the fields of health care cosmetics biomedical food and feed drug-gene delivery environment health mechanics optics chemical industries electronics space industries energy science catalysis light emitters single electron transistors nonlinear optical devices photo-electrochemical industries etc Metallic nanoparticles are long being used by different disciplines in the science and engineering and are still charming the scientists to explore the valuable


2016


characteristics properties and application tiny size of nonmaterial Conventionally silver nanoparticles are synthesized by chemical methods using chemicals as reducing agents which may be harmful to living organisms and pose environmental contamination To reduce the hazards of contamination to the environment and other organisms the ecofriendly biomimetic synthetic methods have been used by different researchers in which bio-molecules extracted from the parts of plants are used for the synthesis of nanoparticles The present review explores the use of various bio molecules obtained from different plant parts for the rapid and one step green synthetic methods and also describes the applications of these materials for environmental applications and also for the remediation of water contaminated with chemical and microbial pollutants Keywords Ecofriendly Nanoparticles biomolecules Pollution remediation

SYNTHESIS AND CHARACTERIZATION OF POLY(ESTER-AMIDE ) RESIN OF MALEIC ACID DERIVED FROM MELIA AZEDARACH SEED OIL

A Hasnat and Sageer Ahamad Department of Chemistry GF College (MJP Rohilkhand University) Shahjahanpur UP

Email amohemanappchemgmailcom

Synthesis of polymeric materials using renewable resources as precursor now- a-days attracted the attention of academia and scientists due to depletion of traditional resources petrochemical and environmental problems both It is desire to innovate the materials which are not only eco-friendly but it must also be friendly to environment Numerous polymers have been synthesised using the renewable resources such as starch lignin protein cashew nut wool fibre vegetable oil and many others They find innumerable application in diverse field of life Among the different renewable resources vegetable oils especially those obtained from seeds of different plants play vital role in the syntheses of various polymers Melia azedarach belongs to the family of Meliaceae largely cultivated in rural areas with especial reference to its wood and ornamental look The seeds of plant contain triglyceride oil comprise with saturated and unsaturated fatty acids The iodine value of oil is found sufficiently high encourage us to utilized this seed oil in making poly(ester-amide) - a polymer of film forming ability Poly(ester-amide)s are amide modified alkyds reported for improve performances due to presence of both groups Keeping these facts in mind in present work we have made effort to utilized the Melia azedarach seed oil in the synthesis of poly(ester-amide) using the poly(condensation) polymerizing techniques where maleic acid is used as dibasic acid The synthesized polymer and intermediates were characterized as per standard reported method and by spectral analyses Synthesis of poly(ester-amide) of maleic acid provides a suitable and profitable utilization of the Melia azedarach seed oil a precursor of natural renewable resource

POLYMER OF NATURE Gihar Sachin Itwari lal

Sr Lecturer VRAL Govt Degree College Bareilly Email gungunpapa15gmailcom

Green polymers are those produced using green ( sustainable ) chemistry Polymers are the sustances having very large number of repeatig units and hence having very high molecular massThe polymers are formed by polymerisation processThey may be natural or syntheticThe green polymers are dedicated to the latest developments in producing conventinal polymers from sustainable sources including plants and biofertilisers algae waste and carbon di oxide In modern society the life is fully crowded by innumerable applications of polymers or roughly called plastics The synthetic polmers are used in industrial production of elastomers fibers resins adhesives plastics etc Besides above excessive uses of polymers due to their low cost they have many environmental hazards issues like occupational hazards pollutions ( land air water marinemountain ) health hazards etcThe plastic products are nongradable to environmental forces like solar radiations hydrolysis atomospheric oxidationThese synthetics are also nonbiodegradable because of high molecular weight poor water solubility and high branched structure Nowadays synthetic polymers having some structural similarities with natural biodegradable polymers have been prepared under the concept of green chemistry ie green polymers Some examples are polyhydroxybutyrate ( PHB ) polyhydroxyvalerate ( PHV ) polylactides ( PLA )carboxy methoxy cellulose ( CMC ) BIOPOL COHPOL bioplast etcThe PLA can be obtained from the renewable sources like sugarcane and corn Key words- Sustainable chemistry polymers pollution biodegradable PHB PHV BIOPAL


2016


SUSTAINABLE BIODEGRADATION OF POLYMERS A COMPARATIVE ANALYSIS

Alka Chaudhary Govt Raza (PG) College Rampur (UP)

Email alkach4gmailcom Development of ecofriendly pathways to create sustainable livelihood is the focus of modern chemical research It is necessary to set benchmark in the area of environmental and social responsibility Many pathways are being developed to achieve status of carbon positive solid waste positive and cycling positive globally The study is about ecofriendly non-toxic pathways in synthetic chemistry and safe pollution free decomposition of wastes in the field of polymer chemistry The polymers produced by renewable resources such as poly lactic acid created by fermenting starch has shown the potential of replacing some regular plastics The co-polymers of poly lactic acid (PLA) and polyethylene glycol (PEG) produce biodegradable polymers Oil eating microbes have also been discovered The study conducted with samples of some bio-degradable polymers at various temperatures gave interesting results In many cases addition of metal salts catalyzed the degradation process and produced water carbon di oxide and bio mass The degradation time of different samples with different metal salts depends upon the type of linkage in polymers and temperature Key words Biodegradation Metal Catalysts

CATALYTIC ACTIVITY OF SILVER NANOPARTICLES APPLICATION IN FIELD OF MICROWAVE

ASSISTED OXIDATION OF SOME AROMATIC ALCOHOLS BY IN SITU GENERATED ZINC DICHROMATE TRIHYDRATE

Manish Srivastava Aakankasha Mishra and Anamika Srivastava Department of Chemistry Banasthali Vidyapith Banasthali Rajasthan 304022 India

Email sagermanish1gmailcom The oxidation of some aromatic alcohols by zinc dichromate trihydrate has been presented As the activator of ZDT the catalytic amount of AgNPs was chosen as catalyst was examined in homogeneous condition The reaction in conventional conditions was compared with the microwave assisted reactions It was found that without catalyst no reaction takes place in 70 min under microwave irradiation although in presence of nanocatalyst reaction completed within 20 min with excellent yield The size of silver nanoparticles was found that the average particle size of individual silver nanoparticles is approximately 2784 nm on the basis of XRD SEM and TEM analysis ROLE OF GREEN ECO-FRIENDLY TECHNOLOGY IN SYNTHESIS OF VARIOUS INDOLE DERIVATIVES

OF MEDICINALLY POTENT PROPERTIES Rajendra

1 Tiwari S P

2and Dwivedi Jay

a1

1Department of Chemistry Banasthali University Banasthali Rajasthaan-304022

2Department of Chemistry The IIS University Jaipur Rajasthaan-302 020

Email sagermanish1gmailcom

This paper explores importance of synthesis of various indole derivatives using microwave assisted techniques Additionally this paper enlightens the biological applications of indole and its derivatives Preparation of differently substituted indoles through microwave-assisted technique found to be efficient and resulted in intermediate to high yields These reactions did not involve any added catalyst like acid or base and conventional heating This approach has been used for catalytic hydrogenation reactions and furnishes the indole derivatives in good yields Eventually in this paper microwave-assisted engineered indole derivatives are discussed to develop new drugs for instance thieno[32-b]indoles for M tuberculosis H37Rv (MTB) and multi-drug resistant M tuberculosis (MDR-TB) INTRINSIC VISCOSITY OF HYDROXYL TERMINATED POLYBUTADIENE (HTPB)-AN ENVIRONMENTAL

APPROACH VSGangwar and Sandeep Singh

Department of Chemistry VSSD CollegeKanpur (India) Email vs_gangwarrediffmailcom

In this work theoretical determination of intrinsic viscosity [η] of HTPB polymers was carried out which have environmental utility as they use relatively less solvent than the classical methods Various theoretical


2016


methods were utilized to study the intrinsic viscosity [η] of HTPB The polymer-solvent interaction parameter in three different solvents ie toluene tetra hydro furan and chloroform was evaluated to select the suitable solvent for this study Two approaches ie Hoftyzer-Van Krevelen and Hoy were used for estimation of solubility parameter (δHTPB) of the polymers The δHTPB obtained by Hoftyzer-Van Krevelen method was found to deviate slightly from Hoy‟s method The ∆ value (difference between solubility parameters of polymer and solvent) was in the order toluene lt chloroform lt tetrahydrofuran The value in toluene was the lowest (ie 038) indicating good solvation of the polymer The results of [η] in toluene at 30 plusmn 01 degC obtained were compared with the value obtained by graphical extrapolation methods based on Huggins Kraemer Martin and Schulz-Blaschke equations The Huggins constant was lt 04 for both the polymers The single point method based on Kuwahara was found to be the best alternative to the graphical extrapolation methods with a deviation of plusmn 01 from the value obtained by Huggins method The proposed method would save approximately 80 solvent used as well as labour and time Thus it is the most economical and environmental method for the determination of intrinsic viscosity of HTPB polymer CATALYTIC EFFECT OF TRANSITION METAL IONS AU (III) AND PD (II) ON THE OXIDATION OF AROMATIC

AND CYCLIC HYDROCARBONS BY IN SITU GENERATED SODIUM FERRATE UNDER MICROWAVE IRRADIATION

Anamika Srivastava and Manish Srivastava Department of Chemistry Banasthali Vidyapith Banasthali Rajasthan 304022 India


Oxidations of various aromatic and cyclic hydrocarbons by in-situ sodium ferrate in the presence of metal ion catalysts like Au (III) and Pd (II) Ethyl benzene propyl benzene cyclohexane naphthalene anthracene and phenanthrene dissolved in minimum amount of acetic acid oxidized by in-situ sodium ferrate in the presence of traces of Au (III) catalyst and Pd (II) catalyst under microwave irradiation In case of oxidation of ethyl benzene propyl benzene cyclohexane naphthalene anthracene and phenanthrene dissolved in acetic acid to give 9333 8666 5755 8208 9134 and 8333 yields in case of gold catalyst and 4833 450 3237 4768 4807 and 4702 yields in case of palladium as a catalyst That in case of gold(III) catalyst give the higher yield as compare to copper(II) catalyst because the electrode potential of the Au(III) is +15 and Pd(II) is +0987The electrode potential of Au(III) is higher than compared to Pd(II) electrode potential so Au

3+ oxidation

state is more stable and more reactive than Pd2+

The reported novel one-pot system is highly efficient and also can be used to oxidize a variety of other functional group comparisons for which studies are being done SYNTHESIS AND EVALUATION OF HERBICIDAL ACTIVITY OF SOME 13-DIARYL-10-SUBSTITUTED-2-

THIOIMIDAZOLO[45-B] PYRIMIDINO[32-A] PYRIDINES Kahkashan Begum

Department of Chemistry Gandhi Faiz-e-Aam College Shahjahanpur UP E-mail apkahkashanbegumgmailcom

A series of compounds involving five and six membered nitrogenous heterocyclics have been synthesized and screened for their herbicidal activity 13-Diaryl-10-substituted-2-thioimidazolo[45-b] pyrimidino[32-a] pyridines have been synthesized by refluxing a mixture of 13-diaryl-5-alkyledin-2-thiohydantoin (001 M) and fused sodium acetate (001 M) in dioxane (10 mL) for 5 hours The required reactant was obtained when a mixture of 13-diaryl-2-thiohydantoin (001 M) an aldehyde (001 M) and anhydrous sodium acetate (011M) in acetic acid (30 mL) was refluxed for 3-4 hours Newly synthesized compounds have been characterized by IR recorded in KBr as Perkin Elmer 881 spectrophotometer PMR spectra was recorded in CDCl3 All other analysis was carried out at RSIC CDRI Lucknow and at BHU Varansi These compounds have been found to have mild to high herbicidal activity against D Ciliaris Calbum and N Tabacum Key words Herbicidal activity nitrogenous compounds Heterocyclic compounds

Au (III) AND Cu (II) CATALYST FOR OXIDATION OF AROMATIC AND CYCLIC HYDROCARBON BY

CERIUM (IV) IN ACIDIC MEDIUM UNDER MICROWAVE IRRADIATION Manish Srivastava Ashu Goyal Anamika Srivastava Aakanksha Mishra and Preeti Tomar

Department of Chemistry Banasthali Vidyapith Banasthali Rajasthan 304022 India

sagermanish1gmailcom

The addition of traces of Au(III) chloride with Ce(IV) sulphate (catalyst substrate ratio (1 80 to 1 300)) and in case of Cu(II) sulphate with Ce(IV) sulphate(catalyst substrate ratio (1 60 to 1 250)) in solution phase under


2016


microwave irradiation resulted in good to excellent yields of corresponding to phenol quinone and carbonyl compounds In case of oxidation of anthracene phenanthrene naphthalene cyclohexane and toluene dissolved in acetic acid to give 9502 8525 3468 4094 and 5654 yields in case of gold catalyst and 935 834 2468 3825 and 4711 yields in case of copper as a catalyst Phenanthrene was oxidized in 9-Fluorenone instead of phenanthraquinone to get the benzylic rearrangement Keywordsndash Aromatic hydrocarbons Oxidation Cerium(IV) sulphate Ce(IV)-Au(III) Ce(IV)-Cu(II) system Characterization Microwave Synthesizer

SYNTHESIS AND CHARACTERIZATION OF ALUMINA-INCORPORATED POLY (ESTER-AMIDE) FROM

JATROPHA CURCAS SEED OIL Mohsin Hasan Khan

Department of Chemistry GF College (M J P Rohilkhand University) Shahjahanpur UP India drmhkhan6485gmailcom

Polymers are one the applied part of Chemistry and technology as it receives versayile application in our day to day life However most of the polymeric materials are derived from the petrochemicals which are going deplete with fats rate consequently cost of final product in increasing order Over the last few years research workers are trying to search economical and friendly to environment specialty chemicals from the spectrum of natural renewable resource The utilization of vegetable oils (VO) for the synthesis of polymers provides an opportunity to utilize a renewable raw material which benefits industries and environmental stakeholders The common seed oils such as linseed sunflower castor soybean and many others have already been utilized in the synthesis of useful polymers Among these traditional oils some of them have medicinal values and are also edible Therefore it is required to explore the spectrum of nature‟s gifts and utilized the vegetable oil of non-edible characteristics in the development of polymers to arrest the demand of feed stock Jatropha curas is a medium sized tree wildly grown in different part of the country and also largely cultivated in rural areas with special reference to its wood Its seed contain about 46- wt triglyceride oil of saturated and unsaturated fatty acids Meager utilization of Jatropha curcas seed oil (JCSO) especially in the syntheses of polymeric materials encourages us to prepare alumina-incorporated poly (ester-amide) of adipic acid (JCAPEAU) Jatropha curcas Poly (ester-amide) of adipic acid (JCAPEA) is synthesized by the aminolysis of JCSO followed by the step-growth polymerization with adipic acid To improve the physic-mechanical and chemical resistance properties Alumina was incorporated in the JCPEA The synthesized resin and intermediates were characterized by measuring the physic-chemical properties as per standard laboratory methods where as structural elucidation of the resins were carried out by the spectral analyses The studies reveals that JCAPEA resin of adipic acid holds promise for one of the useful utilization of Jatropha curcas seed oil which is also eco-friendly

APPLICATION OF MICROWAVE IN API SYNTHESIS Poonam Gupta

Department of Chemistry MMH College GhaziabadUP E mail pg4542yahoocoin

Microwave chemical synthesis has become a method of choice for chemists through out many industries The technology allows the synthesis to be done faster and cleaner with reduced solvent consumption as a ldquogreenerrdquo process Due to mass heating effect much faster temperature increase can be obtained depending upon microwave power A variety of organic reactions

can be done faster and with higher yield with microwave

assistance It allows less byproducts high purity selective heating low energy input green solvent less solvent usage and software supported experiment documentation Many active pharmaceutical agents (API) have synthesized using microwave assistance For example Trimethoprim Albuterol and oxaprozin etc In the synthesis of Albuterol the different steps require prolonged heating With microwave heating the rate of reaction and yields are significantly increased

FACILE ECO-FRIENDLY SYNTHESIS CHARACTERISATION AND EVALUATION OF ANTI-MICROBIAL

ACTIVITY OF Cu(II) COMPLEXES OF TRIDENTATE LIGANDS Krishna P Srivastava Om Prakash Putul amp Nagendra Kumar

Department of Chemistry Jai Prakash University Chapra-841301 Saran Bihar INDIA Presently Principal NLSCollege Jaitpur-Daudpur Saran (Bihar) E-Mail gscdrkpsritpringmailcom jpukpsrichemrediffmailcom


2016


A facile fast simple highly efficient environmentally safe and economical method has been used for the synthesis of the two new biologically active 12-dihydroquinazolin-4(3H)-ones (L1 amp L2) in single step by treating o-aminobenzoylhydrazone (o-ABH) with aromatic aldehydes with superior yields using microwave irradiation in polyethylene glycol (PEG) as an alternative solvent and other two new hydrazones (L3 amp L4) by condensing o-ABH with same aromatic aldehydes under normal conditions The copper (II) complexes of synthesed ligands have been prepared in an environmentally benign microwave protocol and characterized by elemental analysis conductivity measurements magnetic moment spectral and thermogravimetric analysis The antimicrobial activity of the free ligands and their copper (II) complexes clearly indicates that the ligands have both an antibacterial and antifungal potency against the organisms tested In most cases the complexes were found to be more active than the free ligands but in some cases an equal activity was displayed Keywords Coordination Complexes Quinazolinone antimicrobial activity PEG-300 Copper (II)

IMPROVE THE NATIVE CHARACTERISTICS OF POLYSACCHARIDES BY GRAFTING THROUGH THE

GAMMA RADIATION A REVIEW Deepak kumar

1 Nida khan

1 Pramendra Kumar

1 Jyoti Pandey

2

1Department of Applied Chemistry M J P Rohilkhand University Bareilly (UP) India

2Department of Applied Chemistry Babasaheb Bhimrao Ambedkar Central Government

University Lucknow (UP) India Email dpk4470yahooin deepak200789gmailcom

Polysaccharides are bio-degradable inexpensive and easily available from consistent agricultural resources Polysaccharides and their derivatives represent a group of polymer widely used in pharmaceutical and biomedical fields The biodegradability of natural polymers reduces their shelf life Grafting copolymerization technique is a most effective fascinating way for chemical modification of native characteristics of polysaccharides with maximum possibilities for improving the properties of polysaccharides and enhanced the range of exploitation While the major difficulty facing us during synthesizing a graft copolymers reaction is the lack of commercial methods of synthesis and lower percent graft yield It is well known that the most important methods of synthesis engage the employ of chemical free radical initiator ie conventional based methods Graft copolymerization through γ-radiation method is a better method of grafting in comparison to chemical method and exhibits a great potential to synthesize the graft copolymers by virtue of its higher efficiency low cost higher thermal stability as well as enhanced the yield of graft copolymer Future prospective of irradiation technique would be significant impacts to develop of polymerization Key words - Grafting Polysaccharides Gamma Radiation Copolymer Polymerization

SYNTHESIS CHARACTERIZATION AND ANTIFUNGAL ACTIVITY OF SOME NOVEL 4-ARYL HYDRAZONO-25-DISUBSTITUTED-24-DIHYDRO-3H-PYRAZOL-3-ONES

Vipin Kumar Singh Dr DP Singh Synthetical Organic Research Lab Department of Chemistry

T D P G College Jaunpur (UP) INDIA E-Mail vipinksingh24gmailcom

4-Aryl hydrazono-25-disubstituted-24-dihydro-3H-pyrazol-3-ones were prepared by the reaction of ethyl-2-arylhydrazono-3-oxobutyrates with substituted hydrazine in the presence of glacial acetic acid The synthesized compounds have been characterized by elemental and spectroscopic methods viz UV IR amp PMR spectroscopic methods The title compounds have been screened antifungal activity against PGraminis tritici and Precondita at different concentrations Keywords pyrazol-3-one antifungal substituted hydrazine oxybutyrates

SYNTHESIS CHARACTERISATION AND PERFORMANCE EVALUATION OF IRON CONTAINING

POLYESTERAMIDE FROM MELIA AZEDARACH SEED OIL-A RENEWABLE RESOURCE MohdNaseem AHasnat and SAziz Ahmad

Applied Chemistry Lab University Polytechnic Integral University Campus Shahjahanpur UP Email naseemm53yahoocom

The depletion of petroleum oil reserves and the environmental issues draw the attention of modern day chemists to search low cost renewable starting raw material for the chemical industries In this regard the seed oil of different plants pay considerable attraction by the academia and scientists for the utilization as a starting raw material especially for the polymer industries Melia azedarach is a medium sized tree widely grown


2016


throughout the country as a shadow tree and its wood largely used as a timber The seeds of the plant have approximately 40-wt non edible oil with sufficiently high unsaturation In the present work oil of the M azedarach seeds utilized in making low molecular weight polyesteramide which was further modified by the incorporation of iron The physico-chemical characterization of the polyesteramide and iron-filled polyesteramide were carried out as per standard reported methods The newly developed polyesteramide and iron- incorporated polyesteramide resins were applied on mild steel strips of required size to investigate the chemical resistance performances The results show that the incorporation of iron had enhanced the performance of polyesteramide and is more suitableas a coating material Key words- Mazedarach seed oil Iron-filled polyesteramide coating material SYNTHETIC AND SPECTRAL STUDIES OF COMPLEXING BEHAVIOR OF NITRITO COMPLEX OF 4[(N-

BENZALIDENE) AMINO] ANTIPYRINE Sakshi Chaudhary

DN (PG) College Meerut shivashish08gmailcom

Pyrazolones have been reported to be potential extractants as well as powerful drugs Trivalent Lanthanides behave as hard acid and thus are expected to form stronger stable complexes with ligands having N-donor atoms Coordination number less than six are uncommon for the lanthanides Substituted Pyrazolones have been reported to possess strong pharmaceutical properties Lanthanide (III) Nitrate and double amount of ligand 4[(N-benzalidene)amino]antipyrine(C18H17N3O) are used for the preparation of complexes Molar conductance molecular weight magnetic susceptibility infrared and electronic spectroscopy were used to characterization of newly synthesized complexes Key Words Lanthanide Nitrate Pyrazolones Magnetic susceptibility Infra red and electronic spectroscopy Molar conductance and Thermal studies of the complexes

CONVERSION OF PRIMARY AMIDES INTO NITRILES ADAPTING NEW PROCEDURE

Rakesh Mani Misra Assistant Prof Department of Chemistry Harish Chandra P G College Varanasi

Email rakeshmanimisrahotmailcom The conversion of amide group into cyano group is an important conversion with wide utility in organic synthesis Although there are various pathway by which this change in functionality may be brought about but in this piece of work we wish to report more convenient way for this conversion Basically this conversion can be brought about by dehydration The new process of dehydration can be facilitated by coupling amide with methyl di chloro phosphate (MeOPOCl2) or phenyl dichlorophosphate (C6H5OPOCl2) followed by rapid elimination with 18 - [diazabicyclo 540]undec-7-ene (DBU) to form the corresponding nitriles the mild reagent either MeOPOCl2 or C6H5OPOCl2 applied in this newly developed methodology to our knowledge are unprecedented We carried out the experiment with benzamide in presence of different bases to get Benzonitrile accompanied with different dehydrating agent including NN-dimethylphosphoramidic dichloride [(CH3)2NPOCl2] and NN-dimethylphosphoramidous dichloride [(CH3)2NPCl2] considered the reagent of choice to facilitate the dehydration reaction in terms of conversion rate and reaction time (Entry 3) As well DBU was found to be more effective than other commonly used bases such as triethylamine and pyridine among the dehydration systems investigated Under similar conditions dehydration of several functionally diverse primary amides can further be performed Key words nitriles DBU dehydration

CLEAN AND SELECTIVE BAEYERndashVILLIGER OXIDATION OF KETONES WITH HYDROGEN PEROXIDE

CATALYZED BY Sn-PALYGORSKITE Dr Ashok Kumar Singh

Asst Prof Department of Chemistry Harish Chandra P G College Varanasi Email rakeshmanimisrahotmailcom

An environmentally benign and selective BaeyerndashVilliger oxidation system is introduced Palygorskite-supported Sn complexes were prepared by a simple procedure Cyclic ketones and acyclic ketones were oxidized by hydrogen peroxide in a reaction catalyzed by palygorskite-supported Sn complexes affording corresponding lactones or esters with selectivity for the product of 90ndash99 The influence of the solvents reaction temperature the amount of catalyst used and the reaction time on the catalytic activity and product


2016


selectivity were investigated in detail The catalyst is cheap easy to be prepared in large scale and can be recycled An environmentally benign and selective BaeyerndashVilliger oxidation system is introduced Palygorskite-supported Sn complexes were prepared by a simple procedure Cyclic ketones and acyclic ketones were oxidized by hydrogen peroxide in a reaction catalyzed by palygorskite-supported Sn complexes affording corresponding lactones or esters with selectivity for the product of 90ndash99 The influence of the solvents reaction temperature the amount of catalyst used and the reaction time on the catalytic activity and product selectivity were investigated in detail The catalyst is cheap easy to be prepared in large scale and can be recycled

NEW CHELATING QUATERNARY AMMONIUM CRYSTAL VIOLET POLYELECTROLYTE SOLVATION PROPERTIES AND ANALYTICAL APPLICATION

Dr Anil Kumar Department of Chemistry Harish Chandra P G College (MGKVP University) Varanasi-221001

anilk642gmailcom Three new classes of quaternary ammonium crystal violet polyelectrolyte have been synthesized and their characterization through elemental analysis infrared spectroscopy and conductometric titration Their stability as ascertained by thermo gravimetric technique such as TGA and DTA The purity (monodispersity) of the prepared compound was verified by thin layer chromatography The solvation properties of these three linear polyelectrolytes containing crystal violet in the main chain like Poly [ N-ethylene monohydroxy crystal violet dibromide ] Poly [ N-p-xylylene crystal violet trimethoxide] and Poly [ N-25-diacylthiophenylene crystal violet trichloride] The solvation characteristics of these systems are explored in dipolar aprotic solvents through viscosity measurements in Propylene Carbonate (PC) and Sulfolane over small temperature range 25plusmn5˚C in PC and 35plusmn5˚C in sulfolane Intrinsic viscosities of these systems are also studied These polymers were found to be useful for the modification of Chromatographic column packing materials to provide robust chelating resins A comprehensive work for the applications of these resins for metal speciation of Ganges river water and sediments has been undertaken in our laboratory Keywords Quaternary ammonium polyelectrolytes reduced viscosity crystal violet

ICB Tracks

GENETICALLY MODIFIED FOOD ADARSH PANDEY

Department of Botany SS (PG) college Shahjahanpur UP INDIA Adarshspn73gmailcom

With the increasing pressure of population of india the prime need of our nation is to improve the vegetables As most of the population of INDIA is vegetarian the consumption of vegetables is enormous here Of all the vegetables consumed in this country Brinjal or Eggplant or Aubergine constitute the bulk of it due to its cheaper rate and easy availability Brinjal is the king of vegetables which comes with its own crown The eggplant aubergine or Brinjal (Solanum melongena) is a plant of the family Solanaceae It bears a fruit of the same name commonly used as a vegetable in cooking It is closely related to the tomato and potato and is native to Bangladesh Sri Lanka and India Bt brinjal is a transgenic Brinjal created by inserting a gene cry1Ac from soil bacterium Bacillus thuringiensis into brinjal Bt brinjal is marketed in India by MaHyCo (Maharashtra Hybrid Seed Company) and Monsanto a US-based agricultural company Six varieties of Brinjal were evaluated in at Kolhapur and Gadhinglaj in Maharashtra and at Kallolli Karnataka and at Brahmavar in coastal Karnataka To be active against LEPIDOPTERANS insects (brinjal fruit and shoot borer) the protein must be ingested In the insect gut the protein binds to specific receptors on the insect midgut inserts into the membrane and forms ion-specific-poresThese events disrupt the digestive processes and cause death of the insect The Cry1AC protein produced in Bt brinjal is non-toxic to non-lepidopteran insects In 2003 nearly 2500 sheep died after grazing in Bt cotton fields In a study rats fed with GM tomatoes developed bleeding stomachs Of the 20 rats 7 developed stomach lesions another 7 of 40 died within two weeks Again rats fed with Monsantos GM maize exhibited significant changes in their blood cells livers and kidneys Matti is a village in the Udupi district of Karnataka state in India famous for a particular variety of Brinjal Mattu Gulla which is known for its non-septic nature and special flavour But the insertion of gene from Bt would remove the flavor of matti gulla and its medicinal properties Key words Bt Brinjal Eggplant Aubergine Bioterrorism Bacillus thuringiensis


2016


EFFECT OF WATER STRESS ON INSECT INFESTATION IN SUGARCANE Keshav Shukla

Department of Zoology SS (PG) College Shahajahanpur UP India keshavupcsrrediffmailcom

Studies on relationship of shoot borer infestation in sugarcane varieties growing under soil moisture stress (2080-2500 ASM) and in respective normal soil moisture (5200-5800 ASM) was carried out The results revealed that the shoot borer infestation in sugarcane varieties under soil moisture stress was severely higher while the sugarcane varieties grown in respective normal soil moisture pots did not show shoot borer infestation The rate of shoot borer infestation varied from 8-20 in open condition and 1428-4545 in mosquito net covered pots respectively In covered pots the pupae of shoot borer was released thereby the covered pots showed more infestation than the respective normal pots where no pupae was released It has been observed on the basis of overall mean free amino acid and protein contents decreased from 013 in open pots and 027 in covered pots after insect infestation The protein content decreased 2522 in open condition and 5325 in covered conditions after insect infestation Concomitantly there was no decrease of these molecules in sugarcane varieties which were growing in normal soil moisture condition having no infestation of shoot borers The rate of decrease of these constituents showed relationship with the rate of infestation being more decrease where more infestation of shoot borer was observed On the basis of observations it has been reviewed that the shoot borer infestation might have relationship with the soil moisture stress and specific type of protein and amino acids in sugarcane varieties Key Words Sugarcane varieties total soluble protein free amino acids shoot borer soil nutrients

ROLE OF AZOSPIRILLIUM IN OKRA LEAVES 1Mumtaz Husain and

2Adarsh Pandey

12 Department of Botany SS (PG) College Shahjahanpur UP (India)

Email husainmumtaz786786gmailcom A simple randomized pot experiment was conducted at G F College Shahjahanpur during January to March-2011 Efficacy of various doses of nitrogen in combination with Azospirillium was studied on the nitrogen content of okra leaves Two controls were set one without nitrogen and Azospirillium and another without nitrogen with Azospirillium to compare the effect of Azospirillium alone and in combination with various nitrogen doses The nitrogen was estimated in dry leaves at 15 30 and 45 days after germination All the treatments of nitrogen and Azospirillium seed inoculation gave significantly higher nitrogen contents in the leaves of okra The maximum nitrogen content was reported in okra leaves receiving N225 + Azospirillium The minimum nitrogen content was reported in control (N0+B0) where no nitrogen and Azospirillium was applied Therefore it can be recommended that use of lower doses of nitrogen and Azospirillium seed inoculation improved the nitrogen content of leaves in okra plants which will enhanced the final yield of the crop On the other hand a large amount of nitrogen fertilizer is also saved thereby decreasing the cost of production of crop Key words Azospirillium Nitrogen Okra

STUDY ON THE POLLUTION STATUS OF RIVER RAMGANGA IN BAREILLY UP INDIA Ramesh Chandra

Department of Zoology SS(PG) College Shahjahanpur (UP)India rameshraj379gmailcom

River Ramganga is a major source of water to the rural population of western Uttar Pradesh India The main goal of the present study was to assess the impact of urban and industrial activities on the water quality of river Ramganga at the Bareilly For this river water samples were collected from five different sites all along the route of Ramganga main streamline and were analyzed for chemical oxygen (COD) demand and biochemical oxygen demand (BOD) levels There were variations for BOD (275ndash684 mg lthinspminusthinsp1) and COD (2390-4360 mg lthinspminusthinsp1) levels at different sites The BOD values noticed were almost within the permissible limits of USPH and WHO (5mgL and 6mgL) at most of the sampling sites The COD values in the present study remained higher than the COD values published for most of other Indian rivers by CPCB (1991) The values generally exceeded the tolerance limit of -5mgL prescribed by USPH and WHO This is the study on itself and the interrelationship of human activities and river water quality makes the study significant and


2016


interesting to assess the pollution load discharges in catchments of Ramganga at Bareilly Overall the water quality of Ramganga was relatively poor with respect to its use for domestic purposes

PHYTOEXTRACTION OF LEAD FROM TWO VARIETIES OF MARIGOLD 1Shikha Saxena and

2Adarsh Pandey

12 Department of Botany SS (PG) College Shahjahanpur 242001 UP India

Corresponding Author drjauhari26gmailcom Phytoextraction involves specific plant species which can absorb and hyperaccumulate metal contaminants andor excess nutrients in harvestable root and shoot tissuefrom the growth substrate(soil)The objective of present investigation is to examine the accumulation potential of lead in marigoldThe experiment was carried out with two varieties of marigold ie Pusa narangi and Ritu rajThe seeds of marigold of two varieties were presoaked in distilled water and were sown in the field without any treatment as controlAfter 20 daysthe plantlets of marigold of both varieties were transplanted into the potssupplied with different doses of Pb (50100 and 200 mgkg of soil) at 101525 and 30 daysThe growth parameters were recorded at 25 and 45 days The result of the present investigation clearly indicate that different concentration of Pb(50100 and 200 mgkg of soil) did not adversely affect the growth parameters of marigold in both varieties in terms of plant height fresh and dry weight chlorophyllCarotenoid carbohydrate nitrogen and protein contents but some insignificant reduction were noticed in these parameters as compared to control proline content insignificantly increased under the influence of different concentration of Pb at 25 daysAt 45 days tooa insignificant reduction was noticed in these parameters and also the proline content was insignificantly increased as compared to 25 days old plantsThe accumulation of Pb was found to be more in shoot than in the rootWe have noticed that among both the varietiesPusa narangi was found to be more resistant to metal toxicity and the accumulation potential of Pb was found to be more than in variety Ritu rajSo the marigold can be considered as a potential economic crop for phytoremediation of Pb contaminated sites Keywords Marigold Phytoextraction Lead Accumulation

THE DUSKY SIDE OF SYNTHETIC FOOD DYES Dr Madhumita Bhattacharjee

Assistant Professor Post Graduate Govt College For GirlsSector -11 Chandigarh madhumita3680gmailcom

Now -a -days increasing use of synthetic food dye is the consequence of industrialization and the development of food processing technology All synthetic food dyes are chemicalsThe indiscriminate use of synthetic food dyes pose a serious health hazards in human beings Children are more prone to chemicals found in food dyes than the adults as they are attracted more towards the coloured food items Numerous studies have demonstrated the dangers of artificial dyes in food which include the possibility of onset of attention deficit disorder (ADD)inhibition of the immune system hyperactivity and allergic reactions Many studies also showed the carcinogenic neurotoxic and genotoxic nature of synthetic food dyes Long term use of synthetic food dyes also induce many chromosomal aberrations In addition the use of non-permitted colours or overindulgence of permitted colours may also cause thyroid tumours dermatitis asthma nasal congestion abdominal pain nausea eczema liver and kidney damage and cancer So the continuous monitoring of use of permitted colours in food products especially by the food processors manufacturers street vendors must be carried out by the regulatory authorities The developing countries like India need to frame proper legislation for the use of food dyes to protect our health especially our children

CONSEQUENCES OF PLANT GROWTH PROMOTING FUNGI AND PLANT HEALTH PROMOTING BACTERIA ON THE GROWTH ENZYME ACTIVITIES AND ROOT-ROT OF CHICKPEA

Mohd Sayeed Akhtar Akil Ahmad Khan Department of Botany Gandhi Faiz-E-Aam College Shahjahanpur UP India

Email(s) sayeedbotgmailcom akil_nbriyahoocom The effect of plant growth promoting fungi (Aspergillus awamori Aspergillus niger and Pochonia chlamydosporia) and plant health promoting bacteria (Panibacillus polymyxa and B pumilus) were studied alone and in combination under pot conditions on the growth and enzyme activities (catalase and peroxidase) and on the root-rot of chickpea caused by Macrophomina phaseolina Application of plant growth promoting fungi and plant health promoting bacteria caused a significant increase in growth and enzyme activities of both


2016


root-rot fungus inoculated and uninoculated chickpea plants Use of P polymyxa was more efficient in reducing disease severity and improving the growth of root-rot fungus inoculated plants than A niger and P chlamydosporia The greatest increase in growth and enzyme activities (catalase and peroxidase) of root-rot fungus inoculated plants and reduction in disease severity was achieved when A awamori or B pumilus was used with P polymyxa compared to other investigated combinations Keywords Aspergillus Bacillus catalase Macrophomina paseolina peroxidase EFFICIENCY OF VITAMIN-B1 (THIAMINE HYDROCHLORIDE) IN IMPROVING GROWTH AND YIELD OF

MUSTARD (BRASSICA JUNCEA L) Azahar Sajjad

Department of Botany Gandhi Faiz-E-Aam College Shahjahanpur UP India Email azharsajjadrediffmailcom

An experiment was conducted to evaluate the effects of foliar spray (001 002 and 003 wt-) of thiamine hydrochloride (vitamin-B1) on growth and yield characteristics of mustard (Brassica juncea L) cultivar Varuna under field condition The spraying was done only at 40 days after sowing (DAS) which coincide to the flower initiation stage The growth parameters studied include plant fresh weight plant dry weight leaf area (LA) leaf area index (LAI) crop growth rate (CGR) relative growth rate (RGR) net assimilation rate (NAR) at different growth stages Yield as well as its components such as number of pods per plant 1000 seed weight yield biological yield harvest index oil content and oil yield were measured at harvest In general 003 wt- of thiamine hydrochloride solution was more effective compared to other tested concentration for most of the parameters studied Growth parameters like plant fresh weight plant dry weight CGR RGR and NAR showed significant results at the early stages of sampling (ie 60-80 DAS) There was no significant difference between the different treatments of thiamine hydrochloride in case of LA and LAI Different yield parameters like the pod number per plant biological yield and seed yield as well as oil yield registered significant results The results suggest that the performance of B juncea can be improved by spraying the plants with aqueous thiamine hydrochloride solution Thus it was concluded that the spray of thiamine hydrochloride solution ensured better growth and yield Keywords Brassica juncea Vitamin B1 Foliar Spray Growth and Yield

EFFECTS OF METAL ABSORPTION IN HUMAN BODY Dr Shabana Sajid

(DEPTT OF CHEMISTRY) G F PG COLLEGE SHAHJEHANPUR UP E-maildrshabanaatharrediffmailcom

Are you tired Are you suffering from depression or Anaemia These are just a few signs that you may be suffering from metal poisoning-a toxic accumulation of metals in the tissues of the body Zinc Copper and iron etc these transition metals generally present in our environment When these metals enter in human body they seriously attack on kidney lungs and brain Zinc is an essential nutrient particularly for growing children and those who experience frequent infections Many children in developing countries have insufficient Zinc nutrition that impairs their immune system and causes Diarrhoea and Pneumonia Copper found in many kinds of food drinking water and air It is the trace element which is necessary for human health Too much Copper can cause eminent health problems People that live in houses still have Copper plumbing due to this plumbing copper released into their drinking water through corrosion of pipes In working environment Copper contagion can cause flu called ldquoMETAL FEVERrdquo long term copper exposure can raise irritation body aches liver and kidney damage and even death Anaemia is the primary consequence of Iron deficiency Excess Iron level can enlarges the liver may provoke diabetes and cardiac failure This paper reviews certain transition metals and their absorption effects in human body

MORINGA OLEIFERA A RICH SOURCE OF NATURAL ANTIOXIDANTS

Nidhi Srivastava Department of Chemistry PPN College Kanpur

nidhisrivastava2006gmailcom Antioxidant play an important role in inhibiting and scavenging free radicals thus providing protection to human against certain disastrous diseases and strengthen the immune system of our body Current research is now directed towards natural antioxidant originated from plant rather than investing in synthetic ones Two


2016


flavonoid 3572ˊ4ˊpentahydroxyflavone 1 and 3573ˊ4ˊ5ˊ hexahydroxyflavone 2 have been isolated from the seeds of Moringa oleifera have potent antioxidant activity The structures have been established on the basis of chemical evidences and spectroscopic methods Key word Antioxidant scavenging free radicals flavones spectroscopic methods

BIOSENSORS RECENT ADVANCES Dr Renu Goel

Assistant Professor Department of Zoology PPN College Kanpur E-mailgoelrenu63gmailcom

Biosensors represent biophysical devices which will detect the presence and measure the quantities of specific substances in a variety of environments These specific substances may include sugars proteins or hormones in human body pollutants in abiotic components of the environment including air soil and water and a variety of toxins in the industrial effluents In designing a biosensor an enzyme or an antibody or even microbial cells are associated with microchip devices which are used for quantitative estimation of a substance The first reported application of biosensor dates back to 1860 when start content was estimated with the help of malt extract Biosensor today is an analytical tool which consists of biological material in intimate contact with a transducer This review discusses recent advances in biosensors technology which draw on the disciplines of physics chemistry biochemistry and electronics

A NEW RECORD OF NAUCORIDAE SPECIES (HEMPTERA HETEROPTERA) FROM UTTAR PRADESH

Mohammad Shoeb Jameel Ahmad Department of Zoology Gandhi Faiz-E-Aam College Shahjahanpur 242001 UP India

Email soabkhan92gmailcom Naucoridae is the most studied fauna of water bugs throughout the world The aim of the present study was to find out the diversity among the Naucoridae fauna To achieve the objectives a survey of various rivers ponds ditches and water reservoirs form different parts of Uttar Pradesh were conducted during season 2012-2013 The collected materials were examined under the compound and stereoscope microscope The various taxonomic parameters were assessed for the sample collected and the sketches were made with the help of Camera lucida On comparing the result using the taxonomic key the present study showed a new record of Naucoridae species This study is of great concern because of its ability in destroying the eggs and juveniles of mosquitoes Thus it could be a probable a potent candidate species for the control mosquito larvae in the future Keywords Waterbug Chirochel mosquito larvae

BOTANICALS THE GREEN PESTICIDES Rajendra Singh Amrita Singh and Mamta Singh

Plant Nematology Research Lab Department of Zoology Bareilly College Campus MJP Rohilkhand University Bareilly-243001 UP

Email singhrajendra007gmailcom Discovery of insecticidal properties of DDT in 1939 led the foundation of green revolution to enhance the agricultural production but the indiscriminate use of pesticides has generated problems like pest resistance resurgence of pests eco toxicity and elimination of natural enemies These glitches attract the attention of scientific world to develop an ecofriendly and human safe alternative method of pest control In this regard use of phytochemicals (botanicals) biopesticides and biocontrol agents (natural enemies) offer a good alternative to manage the different pests and diseases in an ecofriendly manner Over the last four decades there many useful phytochemicals have been identified and isolated with specific and general application to pest control Of the known about 400000 plant species only about 3000 plant species have been screened to possess pesticidal potential Till now more than 500 pesticidal compounds have been identified from various plant species and few have achieved the commercial status worldwide Present day biopesticide market in the world includes pyrethrins rotenone nicotine ryanodine sabadilla and azadirachtins During last few years‟ plant essential oils comprising mono and sesquiterpenoids are being developed as green pesticides Some of these oils are well known insect toxins repellents and deterrents Currently ecofriendly pest management strategies are being popular worldwide to enhance crop production while maintaining and contributing to agriculture


2016


sustainability In context the relevance of ongoing researches on botanicals and their applications here we have compiled the national and international bibliography for scholars of bioactive compounds Keywords Botanicals Biocontrol Biopesticides IPM Phytochemicals

EVALUATION OF ARTIFICIAL DIET FOR MULTIPLICATION OF LADYBIRD BEETLE COCCINELLA SEPTEMPUNCTATA (COLEOPTERA COCCINELLIDAE) IN THE LABORATORY

ARSHAD ALI and AA Rehman Department of Zoology GF College Shahjahanpur

Email drarshadaliyahoocom About thirty artificial diets have been evaluated for feeding of ladybird beetle Coccinella septempunctata but no successful result was obtained for their development The diets were prepared by using chemicals ie agar agar ascorbic acid casein chloramphenicol dried yeast powder formaldehyde fructose glucose nutipet proteinex riboflavin sorbitol sugar vitamin b complex vitamin E mixed in different combinations in the distilled water In addition aphid-mixed-diet (AMD) was prepared by adding paste of aphids (Lipaphis erysimi Myzus persicae Aphis craccivora) in the aforesaid artificial diets The observations revealed that C septempunctata showed successful development and highest fecundity was recorded on AMD-2 and AMD-3 However highest survival and better reproduction was obtained on control (L erysimi) Moreover the cost effectiveness of the successful diets was recorded cheaper with rupees 417gm and 536gm respectively Key words cost effective development ladybird beetle reproduction survival

EFFECT OF GAMMA RADIATION ON TESTICULAR PROTEIN OF SWISS ALBINO MICE Arib Anjum Rehman

Department of Zoology GF College Shahjahanpur Email rehmanaribgmailcom

Testis is considered as one of the most radiosensitive organ of the mammals The amount of total protein in the testes of irradiated mice displayed decremental trend vis-a-vis control Total protein of control was obtained 16233 mgml While in case of irradiated groups the corresponding values for 005Gy was 13483 mgml it is 1677 less than the control for 01Gy it was 15093 mgml and for 015Gy 02Gy and 025Gy the corresponding values were 14213 mgml 14993 mgml and 14923 mgml which shows 683 1227 745 and 788 lower than the control respectively Fluctuating but decremental trend was observed in the total testicular protein This may be due to random collision of gamma radiation on polypeptide chain of protein molecule causing fragmentation of definitive point ie ldquoFragile sitesrdquo This process of collision and fragmentation is based on the theory of probability The fragments thus produced may be small or large and consequently may escape detection by standard biochemical techniques as used in the present studies The study of gamma radiation thus absorbed may also causes denaturation or coagulation of protein Key words Ionized radiation mammalian testis protein

EFFECT OF TEMPERATURE ON THE DEVELOPMENT OF SILK WORM BOMBYX MORI L (LEPIDOPTERA BOMBYCIDAE) ON MORUS SPECIES

Jamil Ahmad and Nidhi Tripathi Department of Zoology GF (PG) College Shahjahanpur Uttar Pradesh India

E-mail jamilahmadgfcgmailcom Four different temperatures viz 20plusmn1degC 24plusmn1degC 28plusmn1degC and 32plusmn1degC maintained in BOD incubators to observed development of B mori The different life stages including egg incubation larval (Ist IInd IIIrd IVth and Vth) instars prepupal and cocoon period was recorded significantly (F3 19 = 016 022 013 016 020 020 019 and 020 p lt 001) shortest at 32plusmn1degC However the observations recorded on male and female showed a variable pattern of development and recorded significantly (F3 19 = 018 and 014 p lt 001) longest period at 24plusmn1degC On the other hand the findings on weight of last larval instar and cocoon was recorded significantly (F3 19 = 0034 amp 0020 p lt 001) maximum at 24plusmn1degC Whereas weight of cocoon shell was observed significantly (F3 19 = 0020 amp 010 p lt 001) minimum at 24plusmn1degC compared to 20plusmn1degC 28plusmn1degC and 32plusmn1degC In conclusion silk worm Bombyx mori attained shortest development at 32plusmn1degC but better performance of adult and maximum yield of was obtained on 24plusmn1degC therefore among all the temperature 24plusmn1degC considered to be most suitable for its development Key words Biology mulberry sericulture weight


2016


ISOLATION AND CHARACTERIZATION OF FUNGAL DISEASES OF MULBERRY (MORUS ALBA) IN

UTTAR PRADESH Rajesh Kumar and Jamil Ahmad

Department of ZoologyGandhi Faiz-e-Aam (PG) College Shahjahanpur (Uttar Pradesh) India Emailrajeshseriyahooin drrajesh10yahoocom

Mulberry (Morus alba) plant leaf is only natural food of silkworm (Bomyx mori L) which is affected by number of vectors ie fungi bacteria viruses and nematodes The fungal infection severely damage the plant leaves causes leaf rust leaf spot powdery mildew and leaf blight The aim of present study to investigate the fungal infection in mulberry leaves at different districts of Uttar Pradesh The findings revealed that maximum leaf affected by powdery mildew (Phyllactinia corylea) and leaf spot (Cercospora moricola) ie 2000 and 1650 respectively The infection of fungal disease in mulberry was observed maximum during rainy as well as winter season in different places of Uttar Pradesh Such abnormalities severely affected the life cycle of silkworm consequently the production and quality of silk Key Words Leaf spot leaf rust powdery mildew silk

CADMIUM TOXICITY CAUSES DEPLETION OF LIVER GLYCOGEN RESERVE IN ALBINO RATS

KSHAMA DWIVEDI AND D K GUPTA DEPARTMENT OF ZOLOOGY BAREILLY COLLEGE BAREILLY-243005

Email kshamadwivedi74gmailcom Cadmium is an important environmental pollutant present as a non-essential element in food water as well as in polluted air Because of its non-corrosive properties its main use is in electroplating or galvanizing It is also used as colour pigments for paints and plastics and as cathode material for nickel -cadmium batteries About 50 ndash 75 percent of the body burden of cadmium is in the liver and kidneys Exposure to high concentration of cadmium causes a debilitating and often fatal illness that affects most organ system Chronic exposure appears to cause cancer renal and liver toxicity It also affects calcium metabolism and individual with severe neuropathy In present study albino rats were divided into three groups A B and C and were exposed to different doses of cadmium chloride Group A control Group B with low dose of 26 mg kgbwt and Group C with high dose of 52 mg kgbwt These albino rats were exposed to two test concentration for varying exposure periods of 15 30 and 60 days At the end of three treatment periods animals were sacrificed and liver tissue was collected for glycogen estimation After exposure of 15 days animals of group B and group C shows sharp decline of liver glycogen (911)and (1267) respectively On 30 days exposure fall of liver glycogen reserve become more significant ie (2056) and (2652) in group B and C respectively On exposure to 60 days maximum fall of liver glycogen was observed ie (3468) in group B and (3948) in group C respectively Animals of both the Groups B and C showed marked depletion of glycogen content in liver The high dose of cadmium concentration has showed more adverse effect The effect of cadmium in albino rats was found to be dependent on the period of exposure and concentration of metal Key Words Cadmium Glycogen Liver

EFFECT OF LEAD CONTAMINATION ON DEVELOPMENT OF TEETH IN CHILDREN Dr Ashish Kumar Singh and

Dr Abhishek Singh

Assistant Professor Department of Chemistry VSSD College Kanpur UP Anand Multi Speciality Dental Clinic Swaroop Nagar Kanpur wwwananddentalclincin

Email- ashish4808yahoocom singhabhi_49yahoocoin The sources and intensity of lead exposure in utero and in early childhood were determined using stable lead isotopic ratios and lead concentrations of incisal and cervical sections of deciduous teeth from 30 exposed and non exposed children Incisal sections consisting mostly of enamel generally have low amounts of lead and isotopic compositions consistent with those expected in the mother during pregnancy Cervical sections consisting mostly of dentine with secondary dentine removed by resorption and reaming generally have higher amounts of lead than the enamel and isotopic compositions consistent with the source of postnatal exposure There are significant differences in lead concentrations between incisal and cervical sections representing within-tooth variation for children with low and high lead exposure The dentine results reflect an increased exposure to lead from the lead-zinc-silver mineral deposit (ore-body lead) during early childhood


2016


probably associated with hand-to-mouth activity Leaded paint was identified as the source of elevated tooth lead in at least two cases Increased exposure to lead from ore-body and paint sources in utero was implicated in two cases but there was no indication of previous exposure from the mothers current blood reports suggesting an acute rather than a chronic exposure for the mothers Permanent teeth from one subject had lower amounts of lead in the roots compared with the crowns and the isotopic compositions of the crowns were consistent with the data for the deciduous teeth from the same subject Based on changes in the isotopic composition of enamel and dentine it is provisionally estimated that lead is added to dentine at a rate of approximately 2-3 per year

A REVIEW STUDY OF BENEFITS OF OCIMUM TENUIFLORUM (TULASI)

DrVikas Kurana AsstProfesssor SSCollege Shahjahanpur

drvikaskhurana2015gmailcom

Ocimum tenuiflorum also known as Ocimum sanctum holy basil or tulasi (also spelled thulasi) is an aromatic plant in the family Lamiaceae which is native to the Indian Subcontinent and widespread as a cultivated plant throughout the Southeast Southeast Asian tropics It is an erect many branched subshrub 30ndash60 cm (12ndash24 in) tall with hairy stems and simple phyllotaxic green or purple leaves that are strongly scented

Leaves have petioles and are ovate up to 5 cm (20 in) long usually slightly toothed The flowers are purplish in elongate racems in close whorls The two main morphotypes cultivated in India and Nepal are green-leaved (Sri or Lakshmi tulasi) and purple-leaved (Krishna tulasi)

Tulasi is cultivated for religious and medicinal purposes and for its essential oil It is widely known across the Indian subcontinent as a medicinal plant and an herbal tea commonly used in Ayurveda and has an important role within the Vaishnava tradition of Hinduism in which devotees perform worship involving holy basil plants or leaves This plant is revered as an elixir of life Tulsi is an aromatic shrub in the basil family Lamiaceae (tribe ocimeae) that is thought to have originated in north central India and now grows native throughout the eastern world tropiIn Ayurveda tulsi is known as ldquoThe Incomparable Onerdquo ldquoMother Medicine of Naturerdquo and ldquoThe Queen of Herbsrdquo and is revered as an ldquoelixir of liferdquo that is without equal for both its medicinal and spiritual properties

DISTRIBUTION AND MOLECULAR IDENTIFICATION OF PHYTOPLASMA DISEASES IN ORNAMENTALS

Akil Ahmad Khan Shoeb Ahmad Mohd Sayeed Akhtar Department of Botany Gandhi Faiz-E-Aam College Shahjahanpur 242001 Uttar Pradesh India

E-mail akil_nbriyahoocom Phytoplasma is the serious constraints for the most of the economically ornamental plants worldwide It may reduce the quality and yield of ornamental plants because of its unspecific symptoms viz flower malformation growth abnormalities yellowing or decline of leaves elongation and etiolation of internodes witches broom stunting little leaf and virescence The aim of the present study is to identify and characterize the various types of phytoplasmas using phytoplasma universal primers pair P1P7 in a polymerase chain reaction followed by primers pair R16F2nR16R2 in the nested-PCR to amplify the 16S RNA gene fragments The DNA samples were used to extend the RP and Tuf gene fragments by PCR using aster yellows group specific primer pairs RP(l)F1ARP(l)R1A and fTufAyrTufAy respectively Moreover Restriction fragment length polymorphism (RFLP) analysis of RP gene fragments using digestion with Alul Msel and Tsp5091 restriction enzymes were also tested for aster yellows group Keywords Candidatus PCR RFLP Transmission Yellows disease

EFFECT OF FERTILIZER FACTORY EFFLUENT ON SEED GERMINATION AND EARLY SEEDLING

GROWTH OF BROAD BEAN (Vicia fabaL) CV T-41 Manoj Kumar Srivastava and Aquil Ahmad

PG Department of Botany GF College Shahjahanpur rajeevarora999gmailcom

A factorial randomized experiment was performed in petri plates to study the effect of fertilizer factory effluent on seed germination and early seedling growth of broad bean (vicia faba) CV T-41 which was procured from IARI New Delhi and local The percent seed germination and seadling growth in term of shoot and root length and their fresh and dry weights were studied under the influence of various concentrations(1 2 5


2016


1025 50 and pure ie 100 ) Fertilizer Factory Effluents(FFE) Tthe percent seed germination did not show any adverse effect under low FFE concentrations ie 1 2 5 10 and 25 However in higher effluent concentrations of 50 and pure (100) reduced the seedling germination by 60 and 45 respectively as compared to 92 in control(distilled water) Dilution of effluents 1 2 5 and 10 did not show any significant effect on seedling growth On the other hand 25 dilution of effluent improved the seedling growth by 72 6 8 7 10 and 14 in term of shoot length root length shoot fresh weight root fresh weight shoot dry weight and root dry weights of seedling respectively Highier effluent concentration of 50 and pure reduced the seedling growth in term of all the parameters noted As far varietal difference is concerned seed germination percentage percentage was found maximum in T-41 followed by local variety

ICE Tracks

STUDY OF RADON THORON ATTACHEDUNATTACHED PROGENY UNATTACHED FRACTIONS EQUILIBRIUM FACTORS AND THE RADIATION DOSES IN THE INDOOR ENVIRONMENT OF GARHWAL

HIMALAYA Mukesh Prasad

1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline

Mishra3 and RC Ramola

1 1Department of Physics HNB Garhwal University Badshahi Thaul Campus Tehri GarhwalIndia

3Radiological Physics and Advisory Division Bhabha Atomic Research Centre Mumbai - 400 085 India

2German Federal Office for Radiation Protection Berlin Germany

Presenting author bijalwanmukesh111gmailcom The annual exposure to indoor radon thoron and their progeny imparts a major contribution to inhalation dose received by the public In this study we report the time integrated passive measurements of indoor radon thoron and their attached and unattached progeny concentrations that were carried out in Garhwal Himalaya with the aim of investigating whether the exposure to these nuclei involves significant health risk to the dwellers of the investigated region The experimentally determined values of radon thoron and their progeny concentrations were used to estimate the total annual inhalation dose annual effective doses and equilibrium factors The attached and unattached progeny fractions are found positively correlated although only weakly with Pearson correlations Rsup2 = 028 and 031 for radon and thoron respectively (significant with p lt 001 in both cases) The estimated values of equilibrium factors for radon and its progeny and for thoron and its progeny were found to be 042 and 007 respectively The estimated value of total annual inhalation dose due to the exposure of radon thoron and progeny was found to vary from 08 mSvy to 46 mSvy with an average of 18 plusmn 07 mSvy The estimated values of annual effective doses from the exposure to radon and its progeny and from the exposure to thoron and its progeny were found to vary from 05 mSvh to 31 mSvh with an average of 12 plusmn 05 mSvy and from 02 mSvh to 13 mSvh with an average of 05 plusmn 03 mSvy respectively The estimated values of radiation doses have shown no significant health

MEASUREMENTS AND ANALYSIS OF SEASONAL VARIATION OF RADIOACTIVE GASES IN THE ENVIRONMENT OF RAMPUR AND NEARBY TOWN (UP) BY USING SOLID STATE NUCLEAR TRACK

DETECTOR (SSNTD) TECHNIQUE M S A Khan

Department of Physics Gandhi Faiz-a-Aam College Shahjahanpur (UP) India E-mail Salim_labphysicsrediffmailcom

In the present study twin cup radon-thoron dosimeter based on LR-115 type-II plastic track detectors have been used for the measurement of radioactive gases ie radon and thoron in some selected dwellings of Rampur and nearby town of Uttar Pradesh The measurement was repeated on a time integrated four quarterly cycles to cover all the four seasons (summer rainy autumn ampwinter) of the calendar year During winter season the radon and progeny concentration was found to vary from 25 Bqm3 to 85 Bqm3 with an average of 4492 Bqm3 where as thoron and progeny concentration was found to vary from 1766 Bqm3 to 30 Bqm3 with an average value of 2135 Bqm3 During autumn season indoor radon and progeny concentration was found to vary from 15 Bqm3 to 46 Bqm3 with an average of 2995 Bqm3 where as thoron and progeny concentration was found to vary from 1166 Bqm3 to 245 Bqm3 with an average value of 1744 Bqm3 During summer season indoor radon and progeny concentration was found to vary from 9 Bqm3 to 55 Bqm3 with an average of 1872 Bqm3 where as thoron and progeny concentration was found to vary from


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733 Bqm3 to 225Bqm3 with an average value of 1186Bqm3 During rainy season indoor radon and progeny concentration was found to vary from 11Bqm3 to 40 Bqm3 with an average of 2441 Bqm3 where as thoron and progeny concentration was found to vary from 1050 Bqm3 to 23Bqm3 with an average value of 1606 Bqm3 The detail results will be presented in the paper A CRITICAL AND COMPARATIVE STUDY OF INDOOR AIR POLLUTION FROM HOUSEHOLD COOKING

FUELS Basant Shubhankar

1 Balram Ambade

2 12

Department of Chemistry National Institute of Technology Jamshedpur Jharkhand India 2013rsch001nitjsracin

This paper throws light on household cooking related exposures and level of indoor air pollutants (particulate matter and gaseous pollutants CO CO2 SO2 NO NO2) in different exposure area from the different types of cooking fuels used Still the prevalence of biomass fuels exists in Indian households combustion of which releases higher levels of solid and gaseous pollutants during the cooking hours The indoor air pollutants (SPM CO CO2 SO2 NO NO2) were measured with handy samplers with different types of cooking fuels (biomassand LPG) For this purpose 50 randomly selected sampled of the indoor air quality were monitored The results suggests that average concentration of PM10 (39407 μgm3) and gaseous pollutants (CO-315 ppm CO2- 49263 ppm SO2-056 ppm NO-058 ppm NO2-052 ppm) were highest during cooking hours with biofuels cooking places Thus not only the women who are involved in cooking suffer from the various ill effects but also other family members who are inside the house during cooking hours also face exposures The recorded SPM (11473 μgm3 for PM10) and gaseous pollutants (CO-134 ppm CO2-37983 ppm SO2-052 ppm NO-054 ppm NO2-052 ppm) in LPG using households were lower as compared to biomass fuel using households Due to the LPG efficiency the time involved in cooking is also low leading to less exposure to the pollutants released Key words PM10 SPM Biomass LPG Gaseous pollutant Household cooking fuel Health

ldquoEVALUATION AND MODELLING OF GROUND WATER QUALITY DATA OF ALLAHABAD CITY BY ENVIRONMETRIC METHODS

Girdhari Lal Chaurasia Mahesh Kumar Gupta Praveen Kumar Tandon Department of Chemistry University of Allahabad Allahabad UP India-211002

E-mail girdharienvgmailcom In the present study water samples were analyzed for various physicochemical analyses by different methods following the standards of APHA BIS and WHO and were subjected to further statistical analysis viz the cluster analysis to understand the similarity and differences among the various sampling stations Three clusters were found Cluster 1 was marked with 3 sampling locations 1 3 amp 5 Cluster-2 was marked with sampling location-2 and cluster-3 was marked with sampling location-4 Principal component analysisfactor analysis is a pattern reorganization technique which is used to assess the correlation between the observations in terms of different factors which are not observable Observations correlated either positively or negatively are likely to be affected by the same factors while the observations which are not correlated are influenced by different factors In our study three factors explained 99827 of variances F1 marked 51619 of total variances high positive strong loading with TSS TS TempTDS phosphate and moderate with electrical conductivity with loading values of 0986 0970 0792 0744 0695 0701 respectively Factor 2 marked 27236 of the total variance with moderate positive loading with total alkalinity amp temp With loading values 0723 amp 0606 respectively It also explained the moderate negative loading with conductivity TDS and chloride with loading values -0698 -0690 -0582 Factor F 3 marked 20972 of the variances with positive loading with PH chloride and phosphate with strong loading of pH 0872 and moderate positive loading with chloride and phosphate with loading values 0721 and 0569 respectively Keywords Water Physico-chemical Environ-metric methods Cluster Analysis FAPCA


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ESTIMATION OF INDOOR RADON AND THORON DECAY PRODUCTS CONCENTRATION IN DWELLINGS OF SHAHJAHANPUR AND NEARBY TOWNSUTTAR PRADESH INDIA USING

DEPOSITION BASED DIRECT PROGENY SENSOR (DPS) TECHNIQUE a Anil Kumar

b R B S Rawat amp

a Brij Nandan Singh

a Department of Physics S S (PG) College Shahjahanpur Uttar Pradesh India b Department of Physics M S (PG) College Saharanpur Uttar Pradesh India

singhakphy586gmailcom

Radon and thoron present in indoor environment is a potential source of radioactive dose which is mostly contributed by inhalation of their decay products Decay products of radon and thoron present in indoor environment are the most important sources of radiation from natural sources which affect human beings since general public spend at least 80 of their time in indoor Radon decays with a half-life of 3825 days by alpha emission to a series of particulate progeny The measurement of indoor radon and thoron decay products concentration in dwellings of Shahjahanpur and nearby towns have been carried out using deposition based direct progeny sensor (DPS) technique In Present study the concentration of radon and thoron decay products were made to estimate the seasonal variations during different seasons of the year In summer the radon and thoron decay products concentrations have been found to vary from 735 Bqm3 2450 with an average of 1265 Bqm3 and 053 to 232 Bqm3 with an average of 102 Bqm3 respectively In rainy the radon and thoron decay products concentrations have been found to vary 822 from to 2035 Bqm3 with an average of 1369 Bqm3 and 034 to 212 Bqm3 with an average of 096 Bqm3 respectively In autumn the radon and thoron decay products have been found to vary from 812 to 2604 Bqm3 with an average of 1353 Bqm3 and 061 to 17 Bqm3 with an average of 107 Bqm3 respectively In winter the radon and thoron decay products have been found to vary from 811 to 2479 Bqm3 with an average of 1537 Bqm3 and 013 to 202 Bqm3 with an average of 089 Bqm3 respectively It has been observed that the average value of radon decay products concentration is maximum in winter and minimum in summer season while thoron decay products concentration is maximum in autumn and minimum in summer The results and their significance will be discussed in detail

STUDY OF RADON AND THORON CONCENTRATION IN ENVIRONMENT OF MORADABAD DISTRICT OF UTTAR PRADESH INDIA

Indu Singh a and Anil Kumar

b a Department of Physics IFTM University Moradabad

b Department of Physics S S (PG) College Shahjahanpur Uttar Pradesh India


Measurement of indoor radon and thoron has been carried out in dwelling of Moradabad Uttar Pradesh India using LR-115 type II plastic track detectors Radon is an invisible radioactive gas that occurs naturally in the indoor atmosphere It comes from the naturally breakdown of uranium in soils and rocks Lung cancer risk depends upon the concentration of radon thoron and their decay product in air above recommendation level In the present study the value of radon concentration from105 Bqm3to 30Bqm3 with an average199 Bqm3and thoron concentration from 56 Bqm3 to 24 Bqm3 with an average of 149 Bqm3 It is observed that the concentration of radon is maximum in winter and minimum during summer The maximum concentration in winter is essentially influenced by the intense temperature inversion which generally occurs in winter season when the wind velocity is low The maximum concentration in winter is also the result of decreased ventilation because in this season the houses are closed for long time and radon accumulated inside the room The variation in indoor radon and thoron concentration for different seasons will be discussed in the paper

THE EFFECT OF GLOBAL WARMING ON ENVIRONMENT Dr Hitendra Kumar Singh

Assistant Professor Department of Botany Govt Raza Post Graduate College Rampur UP India

drhksingh1gmailcom

The planet is warming from North Pole to South Pole and everywhere in between Signs are appearing all over and some of them are surprising Global warming is far-reaching long lasting and in many cases devastating consequences or planet earth Global warming is caused due to human activity like burning of


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fossil fuels that release carbon dioxide methane and other green house gases into environment Ice is melting worldwide especially at the Earth‟s poles This includes mountain glaciers ice sheets covering West Antarctica and Greenland and Arctic sea ice Sea level rise became faster over the last century Alpine plants have moved faster to north or higher cooler areas Storms are likely to become stronger Floods and droughts have become more common Many species of plants are moving their range to higher altitudes as a result of warming temperatures Global warming affects the range of plans and animals changing their behavior and causing disruptions up and down the food chain Some warm weather species will expand while cool weather species will face shrinking habitats Spring arrives much earlier than it used to ten days earlier on average in the northern hemisphere International Seminar on 12 Feb 2016 organized by SS PG College Shahjahanpur Snow melts earlier Vegetation and soils dry out earlier setting the stage for longer and more damaging wildfire seasons Global warming change affects people and environment in many ways We can reduce global warming emissions and ensure communities have the resources they need to withstand the effects of climate change but not without us We should try our best to reduce global warming effects than we can save earth plant humans etc Key Words Environment Global warming Greenhouse effect

ESTIMATION OF THE PARTICULATE MATTERS EMITTED FROM COAL POWER PLANTS IN ALLAHABAD DISTRICTS AND ITS EFFECT ON HUMAN HEALTH IN THIS AREA

Anil Kumar Singh amp Jay Prakash Patel Department of Physics Ewing Christian College Allahabad

anilsingh012rediffmailcom In this project we will estimate the effect of particulate matter sulfur dioxide (SO2) and nitrogen oxides (NOx) on human health and environment from individual coal-fired power plants in Allahabad We will estimate health damages by combining data on power plant emissions of particulate matter SO2 and NOx In addition to the environmental and human health harm caused by greenhouse gas emissions coal-fired power plants emit massive amounts of toxic air pollutants that result in significant numbers of deaths and disease Keywords Particulate Matter (PM) health damages coal-fired power plant pollution control

BIOMONITORING WITH MOSSES AN EXTENSIVE STUDY OF METALS POLLUTION OF ATMOSPHERE

a Kajal Srivastava and

b Shivom Singh

a Department of Biological Sciences CBSH GB Pant University of Agriculture and Technology Pantnagar

b Department of Environmental Science ITM University Gwalior

Shivom101rediffmailcom The environmental quality can be monitored by measuring pollutants metals precipitation using bio-indicators Biomonitoring of atmophile element by mosses is one of the most popular and cost effective method to control detect and evaluate changes in the air quality They represent a suitable approach for screening air quality at higher spatial resolution The most important environmental features of mosses as a good tool of air pollution deposition reflection are mosses do not have any roots their surface is large they grow in wide-spread population in groups they have long life cycle they survive in the high-polluted environment they are able to obtain nutrients from wet and dry deposition and clearly reflect the atmospheric deposition The moss biomonitoring technique is usually used for the monitoring of airborne metals and polycyclic aromatic hydrocarbons (PAHs) but it can also be very helpful for biomagnetic analysis So far leaf magnetic properties such as susceptibility and remanence have been reported as valuable proxies for PM pollution In addition the abundance and large geographical distribution of mosses is advantageous and provides for an inexpensive and simple alternative to conventional bulk deposition analysis Thus a high density network of sampling sites is easily achieved This allows for pollution distribution maps to be produced This technique as a complementary method to standardized measurements by filling gaps in the regulatory monitoring network Moss biomonitoring surveys could be of great use as they provide a cost-effective and efficient means for a time-integrated assessment of the environmental situation and evaluation of anthropogenic changes Keywords Bioindicator biomonitoring metals mosses pollution


2016


ENVIRONMENTAL IMPACT OF NUCLEAR POWER LAW AND POLICY MEASURES IN INDIA Dr Ajay Kumar Singh Nalnish Chandr Singh

ajay24bhugmailcom Healthy and clean environment is a fundamental right in India simultaneously in modern time energy requirements are increasing It is required that dependency on traditional source of energy should be decreased because of environmental and other reasons Nuclear energy undoubtedly a present day hope for the energy requirement due to rich and eco-friendly source of energy But this source also contains some danger for human health and wellbeing It is a basic question before every nation that what safety and regulatory measures should be adopted to secure the safe use of nuclear energy This article is an attempt to analyse the impact radiations caused by nuclear accidents on human health and environment It also analyse the international regulatory measures and national legal and policy measures adopted to combat the nuclear disaster The article enumerates the liability issue arise due to the enactment of new law in 2010 it analyse the controversy and provide concluding remarks on the issue Keywords nuclear environment pollution protection judiciary

EVALUATION OF WATER QUALITY OF GANGA RIVER AT ALLAHABAD PHYSICO-CHEMICAL PROPERTIES AND CORRELATION CO-EFFICIENT

Neelam Shuklaa Vandana Srivastava

b BK Dwivedi

b Mahesh Kumar Gupta

a D N Shukla

b P K

Tandona

a Department of Chemistry

b Department of Botany University of Allahabad Allahabad-211002 email neelamshukla82yahoocom

Physico-chemical parameters of water samples of river Ganga at Allahabad district were analyzed to see the water quality of river Water samples were collected from five sampling stations from Phaphamau Ghat to Chatnaag Ghat in the year 2014 Sixteen water quality parameters for all the sites were estimated by adopting the standard methods and procedures The samples were analyzed for Physico-chemical attributes and Pearson‟s correlation (r values) was calculated to quantify relationships between various physico-chemical attributes of river Ganga at Allahabad It is found that turbidity COD and electrical conductivity were found to be positively correlated with temperature while pH and transparency was negatively correlated with temperature DO was negatively correlated with temperature turbidity electrical conductivity TS TDS and TSS during the study of period and positively correlated with pH BOD was positively correlated with temperature electrical conductivity turbidity TS TDS and TSS whereas negatively correlated with DO Free CO2 was positively correlated with temperature Calcium and Magnesium hardness were negatively correlated with pH and DO whereas positively correlated with electrical conductivity BOD COD TS TDS and TSS Nitrate and Phosphate showed almost no significant correlation with each other and with other parameters during the course of study Keywords Physico-chemical parameters correlation water quality hardness turbidity

EVALUATION OF PHARMACEUTICALS INDUSTRIAL EFFLUENT TOXICITY AND GENOTOXICITY EFFLUENT USING- ALLIUM CEPA MODEL

Vineeta kumari A K Tripathi Forest Ecology amp Environment Division Forest Research Institute Dehradun

Email Vineetaenvgmailcom Water is the fundamental resource for the living beings Water is basic need for all types of the small and large scale industrial sectors Pharmaceutical industries are among the major contributors to industrial waste Their effluents when wrongly handled and disposed of endanger both human and environmental health In this study we investigated the potential cytotoxicity and genotoxicity effect of effluents released by two different pharmaceutical industries in Lucknow India by using the Allium cepa Acepa model was used to determine the mean root lengthmitotic index and chromosomal aberrations effects of these plants on Onion bulbs using 625 125 and 25 concentration of the pharmaceutical effluent at 6 or 24 h treatment The Acepa test showed significant results of cytotoxicity mutagenic index and chromosome aberration in the area under the same influence The concentration of some toxic metals and anions in the effluent were above standard permissible limits There was a statistically different (p lt 005) concentration-dependent inhibition of onion root growth and mitotic index and induction of chromosomal aberrations in the onion The pharmaceutical industrial effluents induced chromosomal aberrations in root tip cells of A cepa with vagrant chromosome


2016


bridges fragments tripolar anaphase and micronucleated cell observed At lower concentrations sticky chromosome bridges and fragments were the most common aberration KEYWORDS Pharmaceutical Industrial effluent Alliums cepa Mitotic index chromosomal aberrations

EFFECT OF CONCENTRATION OF WATER POLLUTANTS ON ADSORPTION Jyotsna Chaturvedi and N K Pandey

DEPARTMENT OF CHEMISTRY HARISHCHANDRA PG COLLEGE VARANASI-221001 UP INDIA

jyotsna1junegmailcom

A study on removal of water pollutants by adsorption method was carried out using water sample from ghats of river Ganga at Mirzapur district The water samples having effluents of carpet industries were rich in heavy metals and dyes For removal of heavy metals wallastonite and china clay were used as adsorbents during the adsorption process The results showed that under similar reaction conditions the time required to attain equilibrium for adsorption of Cr(VI) and Ni(II) on wallastonite was more than the time required by china clay whereas the dyes (OCR and OCB) required more time for saturation state on china clay than on wallastonite Also the saturation state was independent of adsorbate concentrations

EFFICACY OF A NEWLY FORMULATED AREA SPECIFIC MINERAL MIXTURE ON PRODUCTION AND HAEMATOBIOCHEMICAL PARAMETERS OF CATTLE

Chinmay Joshi Assistant Professor in Zoology

HNB Govt PG College Khatima Udham Singh Nagar Uttarakhand Email joshic28yahoocoin

A study was conducted in Uttarakhand state to observe the mineral status in soil fodder and serum samples of the bovines Significant deficiency of copper zinc iodine and phosphorus was observed in this hilly area Deficient cattle showed anemia debility and dullness Symptoms of parakeratosis and pica were also observed in deficient animals The biochemical profile viz enzymes hormones and vitamins also showed severe deficiency Therapeutic trial was conducted on some cattle in local dairy farm for sixty day It was observed that after the experimental study all the parameters returned towards normalcy Significant improvement was observed in Thyroid hormone Vitamin A and E level The treated animals also showed a significant gain in milk yield and body weight gain Approximately 37 increase in milk yield and 30 increase in body weight of calves and heifers was observed after supplementation of this newly formulated mineral mixture From the overall analysis it was envisaged that mineral supplements should be provided to the deficient animals for their better health and production Key Words shy Cattle Mineral Deficiency hormones vitamin AampE Haematobiochemical profile Therapy Production

SYNTHESIS OF SOME NEW INDOLE DERIVATIVES WITH POSSIBLE LOCAL ANESTHETIC ACTIVITY Roopali Tandon S C Mehra

Chemistry Dept Bareily College yashishucommgmailcom

Indole and their derivatives possess various pharmacological activities Thus new indole derivatives have been synthesized as potential local anesthetic by treating indole with chloroacotyle chloride to get N‟-[1-chloro acetyl]-Indole which on further treatment with amines to afford N‟(1-morphollino-1-acetylpiperidino-1-acetyl dimethyl-1-aminoacetyl diethyl-1-aminoacetyl NN-dimethyl amino-p-aminoacetyl NN-diethylamino-p-aminoacetylpyridine-1-amino acetyl pyrimidine-1-aminoacetyl diphenyl-1-aminoacetyl piperizino-1-acetyl]-Indole

2nd International Conference on Innovations in Chemical Biological amp

Environmental Sciences (ICBCES) at SSPG College Shahjahanpur UP India 2016


खादय पदारथो म जहर घोऱत रगीन रसायन १डॉ ममता ससह एव २डॉ राजदर ससह

१ पोसट डोक फ़ऱो (यजीसी)ऱसऱतकऱा ववभाग बरऱी कॉऱज बरऱी २ सह आचायय जतववजञान ववभाग बरऱी कॉऱज बरऱी

Email manumamtamanangmailcom

जीवन क ऱगभग हर तर म मानव क कायय कऱाऩो स ऩयायवरण म जो ऩररवरयन आय ह उनहोन हमार सवासय को परभभर ककया ह यह मानयरा सही नहीॊ ह कक आरथयक समरध मानव की परगतर का अकऱा सचक ह हररर काॊतर क दौरान खादय-उतऩादन बढ़ान वाऱ कीटनाशको न खतरहर मजदरो को और ऩदावार का उऩयोग कर रह हम सभी को परभाववर ककया ह

ऱाखो ऱोग काययसथऱो ऩर या घरो म घटक रसायनो क सॊऩकय म आर ह जजस स सवासय ऩर परतरकऱ असर ऩड़रा ह कयोकक उदयोगो म तनयॊतरण उऩायो का ठीक स ऩाऱन नहीॊ ककया जारा रसायनो स परदवषर भोजन जन सवासय की एक परमख समसया ह यह परदषण हवा ऩानी और भमटटी क घटको को असॊरभऱर कररा ह ववषऱी धारएॊ ऩी सी बी और दाइअकसन का या रोगनाशको ऩशओॊ कक दवाओॊ और दसर खतरहर रसायनो जस ववभभनन रसायनो का समवर उऩयोग मनषय क सवासय ऩर गमभीर परभाव डाऱरा ह खादय ऩदाथो क ववतनमायण और पर-सॊसकरण क दौरान उनम भमऱाए जान वाऱ ऩदाथय और परदषक भी मानव क सवासय ऩर परतरकऱ असर छोड़र ह

मानवीय ककया-कऱाऩो व पराकतरक सॊसाधनो क अवववक ऩणय व अनतरक दोहन क ऩररणाम सवरऩ ऩाररजसथकी घटको म ववघटन एवॊ रण क साथ साथ ऩयायवरण म ववषऱी धारओॊ की मातर म अपरतयाभशर ववि हई ह जजनका घनतव ५ गरामघन समी स अरधक होरा ह जस आसतनक कडभमयम कोभमउम कोऩर ऱड मगनीज मकय री सभऱतनयम ऱोहा आदद इन भरी रतवो क परमख सरोर कीटनाशक उवयरक परदवषर जऱ धार गऱान वाऱ उऩकम रथा औदयोरगक बदहसराब मखय ह य रतव भोजन शरॊखऱा दवारा मनषय म ऩहॉच कर क सर हाइऩरककराटोभसस मधमह हरदय रोग नऩॊसकरा भमनीमारा रोग रथा अनक सनाय रोगो को जनम द रह ह ववशव सवासय सॊगठन (डबऱएचओ) की ददसमबर २०१५ की ररऩोटय क अनसार सॊदवषर भोजन स मनषय म २०० स भी अरधक परकार क रोग होर ह परतरवषय ऱगभग ६ करोड ऱोग दवषर भोजन स बीमार होर ह और इनम स ४ ऱाख २० हज़ार ऱोग उरचर इऱाज न भमऱन क कारण मतय को परापर हो जार ह इस मतय दर म १ ऱाख २५ हज़ार ५ वषय की आय स कम क बचच होर ह डबऱएचओ न भोजन को सॊदवषर करन वाऱ ३१ कारको का ऩरा ऱगाया जजसम भारी रतव ऱड (शीशा) कडभमयम रथा मकय री मखय रऩ स सनाय रॊतर और गदो को परभभर करर ह

कजी शबद खादय ऩदाथय भारी रतव रसायन परदषण मानव सवासय

2nd International Conference on Innovations in Chemical Biological ampEnvironmental Sciences (ICBCES) at SSPG College Shahjahanpur UP India 2016


SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF Cr (III)

COMPLEXES OF 2 amp 3 PYRIDINEFORMAMIDE SEMICARBAZONES AND

THIOSEMICARBAZONES Smriti Raizada and Sangeeta Sadwal

Department of Chemistry MMH College Ghaziabad (UP)India

Email smriti_raizadalivecom

New Cr (III) metal complexes containing ligands2-pyridineformamide semicarbazone (L1) 2-

pyridineformamidethiosemicarbazone (L2) 3-pyridineformamide semicarbazone (L3) 3-

pyridineformamidethiosemicarbazone (L4) have been synthesized These ligands were characterized on basis of

elemental analyses molar conductance IR electronic and EPR spectral studies The complexes may be formulated

as [Cr(L)2X2]X where L = L1 L2 L3 L4 X =Cl- NO3

-) The significant IR spectral bands of the metal complexes

show the shifting of the bands corresponding to (-C=N) and (-C=S) towards lower side (around ca~~20 ndash 50 cm-1

)

on complexation for L1 L3 and (C=O) for L2 L4 In all the Cr(III) complexes observed magnetic moment is 374 ndash

389 BM suggesting an octahedral environment An intense EPR line centered at about 340 mT(geff ~ 1972) is also

observed for all the analyzed samples On the basis of IR electronic and EPR spectra of complexes octahedral

geometry is assigned for all the complexes

Swami Chinmayanand Saraswati

Former Union Home Minister (State)

Govt of India

Message

An Ideal education Institution aims not just at imparting the knowledge and information rather it

equips the learner with our ancient values and ethics laid down and fostered through the

scriptures over the centuries It targets at enhancing the Intellectual as well as the daily living

standards of a common human being Over the decades the science has progressed by leaps

and bounds and yet the reflective process centered on the principles values and ethics that can

evolve a common human mind to a real human being is still the cry of the age

I am elated to proclaim that our alma mater Swami Sukdevanand PG College Shahjahanpur is

heading its way by bestowing knowledge coupled with Human Values to the sincere and

genuine learners of this small town of Uttar-Pradesh and it is proving its worth like an oasis in a

desert In this eternal continuum Swami Sukdevanand PG College Shahjahanpur UP India is

organizing 2nd International Conference on Innovations in Chemical Biological amp Environmental

Sciences (ICBCES) on 12th February in our lush green alluring college campus

I extend my warm greetings and blessings to this unstoppable journey of knowledge-seekers

and hope sanguinely that the Inter-cultural interaction of the learned scholars will surely go a

long way and set milestone on the ever sprawling path of knowledge

(Swami Chinmayanand Saraswati)


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2016



Sanjai Kumarab


a








+




Monalisa Kundu1


3






2016







Gulshan Rastogi

Alok K Singh





2Rohit Durge

1Adjunct Professor








2016







2+ Moreover 7-Hg





1H and




2Deepak Kumar

3Pramendra Kumar





WITH ZN2+

AND F- IONS




2+ and F



- Zn

2+ and F



-(A) then

Zn2+


- Zn


device reusable


2016



a and MB Kalhans

a








-









2016









Abdul Mohemana

and Ali Mohammadb






2016




Dr Shalu Tyagi



t-5-


t-5-Pr



t-5-Pr







1H and

13C NMR spectral







2016











2016










1 Tiwari S P

2and Dwivedi Jay

a1









2016







3+ oxidation












2016
















2016





1 Nida khan

1 Pramendra Kumar

1 Jyoti Pandey

2














2016














2016






ICB Tracks





2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






Message















(Prof A K Mishra)


Message




















and coordination




2016




2











2016










4











2016



Sanjai Kumarab


a








+




Monalisa Kundu1


3






2016







Gulshan Rastogi

Alok K Singh





2Rohit Durge

1Adjunct Professor








2016







2+ Moreover 7-Hg





1H and




2Deepak Kumar

3Pramendra Kumar





WITH ZN2+

AND F- IONS




2+ and F



- Zn

2+ and F



-(A) then

Zn2+


- Zn


device reusable


2016



a and MB Kalhans

a








-









2016









Abdul Mohemana

and Ali Mohammadb






2016




Dr Shalu Tyagi



t-5-


t-5-Pr



t-5-Pr







1H and

13C NMR spectral







2016











2016










1 Tiwari S P

2and Dwivedi Jay

a1









2016







3+ oxidation












2016
















2016





1 Nida khan

1 Pramendra Kumar

1 Jyoti Pandey

2














2016














2016






ICB Tracks





2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






Message




















and coordination




2016




2











2016










4











2016



Sanjai Kumarab


a








+




Monalisa Kundu1


3






2016







Gulshan Rastogi

Alok K Singh





2Rohit Durge

1Adjunct Professor








2016







2+ Moreover 7-Hg





1H and




2Deepak Kumar

3Pramendra Kumar





WITH ZN2+

AND F- IONS




2+ and F



- Zn

2+ and F



-(A) then

Zn2+


- Zn


device reusable


2016



a and MB Kalhans

a








-









2016









Abdul Mohemana

and Ali Mohammadb






2016




Dr Shalu Tyagi



t-5-


t-5-Pr



t-5-Pr







1H and

13C NMR spectral







2016











2016










1 Tiwari S P

2and Dwivedi Jay

a1









2016







3+ oxidation












2016
















2016





1 Nida khan

1 Pramendra Kumar

1 Jyoti Pandey

2














2016














2016






ICB Tracks





2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)















and coordination




2016




2











2016










4











2016



Sanjai Kumarab


a








+




Monalisa Kundu1


3






2016







Gulshan Rastogi

Alok K Singh





2Rohit Durge

1Adjunct Professor








2016







2+ Moreover 7-Hg





1H and




2Deepak Kumar

3Pramendra Kumar





WITH ZN2+

AND F- IONS




2+ and F



- Zn

2+ and F



-(A) then

Zn2+


- Zn


device reusable


2016



a and MB Kalhans

a








-









2016









Abdul Mohemana

and Ali Mohammadb






2016




Dr Shalu Tyagi



t-5-


t-5-Pr



t-5-Pr







1H and

13C NMR spectral







2016











2016










1 Tiwari S P

2and Dwivedi Jay

a1









2016







3+ oxidation












2016
















2016





1 Nida khan

1 Pramendra Kumar

1 Jyoti Pandey

2














2016














2016






ICB Tracks





2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016




2











2016










4











2016



Sanjai Kumarab


a








+




Monalisa Kundu1


3






2016







Gulshan Rastogi

Alok K Singh





2Rohit Durge

1Adjunct Professor








2016







2+ Moreover 7-Hg





1H and




2Deepak Kumar

3Pramendra Kumar





WITH ZN2+

AND F- IONS




2+ and F



- Zn

2+ and F



-(A) then

Zn2+


- Zn


device reusable


2016



a and MB Kalhans

a








-









2016









Abdul Mohemana

and Ali Mohammadb






2016




Dr Shalu Tyagi



t-5-


t-5-Pr



t-5-Pr







1H and

13C NMR spectral







2016











2016










1 Tiwari S P

2and Dwivedi Jay

a1









2016







3+ oxidation












2016
















2016





1 Nida khan

1 Pramendra Kumar

1 Jyoti Pandey

2














2016














2016






ICB Tracks





2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016










4











2016



Sanjai Kumarab


a








+




Monalisa Kundu1


3






2016







Gulshan Rastogi

Alok K Singh





2Rohit Durge

1Adjunct Professor








2016







2+ Moreover 7-Hg





1H and




2Deepak Kumar

3Pramendra Kumar





WITH ZN2+

AND F- IONS




2+ and F



- Zn

2+ and F



-(A) then

Zn2+


- Zn


device reusable


2016



a and MB Kalhans

a








-









2016









Abdul Mohemana

and Ali Mohammadb






2016




Dr Shalu Tyagi



t-5-


t-5-Pr



t-5-Pr







1H and

13C NMR spectral







2016











2016










1 Tiwari S P

2and Dwivedi Jay

a1









2016







3+ oxidation












2016
















2016





1 Nida khan

1 Pramendra Kumar

1 Jyoti Pandey

2














2016














2016






ICB Tracks





2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016



Sanjai Kumarab


a








+




Monalisa Kundu1


3






2016







Gulshan Rastogi

Alok K Singh





2Rohit Durge

1Adjunct Professor








2016







2+ Moreover 7-Hg





1H and




2Deepak Kumar

3Pramendra Kumar





WITH ZN2+

AND F- IONS




2+ and F



- Zn

2+ and F



-(A) then

Zn2+


- Zn


device reusable


2016



a and MB Kalhans

a








-









2016









Abdul Mohemana

and Ali Mohammadb






2016




Dr Shalu Tyagi



t-5-


t-5-Pr



t-5-Pr







1H and

13C NMR spectral







2016











2016










1 Tiwari S P

2and Dwivedi Jay

a1









2016







3+ oxidation












2016
















2016





1 Nida khan

1 Pramendra Kumar

1 Jyoti Pandey

2














2016














2016






ICB Tracks





2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016







Gulshan Rastogi

Alok K Singh





2Rohit Durge

1Adjunct Professor








2016







2+ Moreover 7-Hg





1H and




2Deepak Kumar

3Pramendra Kumar





WITH ZN2+

AND F- IONS




2+ and F



- Zn

2+ and F



-(A) then

Zn2+


- Zn


device reusable


2016



a and MB Kalhans

a








-









2016









Abdul Mohemana

and Ali Mohammadb






2016




Dr Shalu Tyagi



t-5-


t-5-Pr



t-5-Pr







1H and

13C NMR spectral







2016











2016










1 Tiwari S P

2and Dwivedi Jay

a1









2016







3+ oxidation












2016
















2016





1 Nida khan

1 Pramendra Kumar

1 Jyoti Pandey

2














2016














2016






ICB Tracks





2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016







2+ Moreover 7-Hg





1H and




2Deepak Kumar

3Pramendra Kumar





WITH ZN2+

AND F- IONS




2+ and F



- Zn

2+ and F



-(A) then

Zn2+


- Zn


device reusable


2016



a and MB Kalhans

a








-









2016









Abdul Mohemana

and Ali Mohammadb






2016




Dr Shalu Tyagi



t-5-


t-5-Pr



t-5-Pr







1H and

13C NMR spectral







2016











2016










1 Tiwari S P

2and Dwivedi Jay

a1









2016







3+ oxidation












2016
















2016





1 Nida khan

1 Pramendra Kumar

1 Jyoti Pandey

2














2016














2016






ICB Tracks





2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016



a and MB Kalhans

a








-









2016









Abdul Mohemana

and Ali Mohammadb






2016




Dr Shalu Tyagi



t-5-


t-5-Pr



t-5-Pr







1H and

13C NMR spectral







2016











2016










1 Tiwari S P

2and Dwivedi Jay

a1









2016







3+ oxidation












2016
















2016





1 Nida khan

1 Pramendra Kumar

1 Jyoti Pandey

2














2016














2016






ICB Tracks





2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016









Abdul Mohemana

and Ali Mohammadb






2016




Dr Shalu Tyagi



t-5-


t-5-Pr



t-5-Pr







1H and

13C NMR spectral







2016











2016










1 Tiwari S P

2and Dwivedi Jay

a1









2016







3+ oxidation












2016
















2016





1 Nida khan

1 Pramendra Kumar

1 Jyoti Pandey

2














2016














2016






ICB Tracks





2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016




Dr Shalu Tyagi



t-5-


t-5-Pr



t-5-Pr







1H and

13C NMR spectral







2016











2016










1 Tiwari S P

2and Dwivedi Jay

a1









2016







3+ oxidation












2016
















2016





1 Nida khan

1 Pramendra Kumar

1 Jyoti Pandey

2














2016














2016






ICB Tracks





2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016











2016










1 Tiwari S P

2and Dwivedi Jay

a1









2016







3+ oxidation












2016
















2016





1 Nida khan

1 Pramendra Kumar

1 Jyoti Pandey

2














2016














2016






ICB Tracks





2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016










1 Tiwari S P

2and Dwivedi Jay

a1









2016







3+ oxidation












2016
















2016





1 Nida khan

1 Pramendra Kumar

1 Jyoti Pandey

2














2016














2016






ICB Tracks





2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016







3+ oxidation












2016
















2016





1 Nida khan

1 Pramendra Kumar

1 Jyoti Pandey

2














2016














2016






ICB Tracks





2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016
















2016





1 Nida khan

1 Pramendra Kumar

1 Jyoti Pandey

2














2016














2016






ICB Tracks





2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016





1 Nida khan

1 Pramendra Kumar

1 Jyoti Pandey

2














2016














2016






ICB Tracks





2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016














2016






ICB Tracks





2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016






ICB Tracks





2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016






2Adarsh Pandey







2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016




2Adarsh Pandey










2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016













2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016













2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016













2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016










Dr Abhishek Singh




2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016

















2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016



ICE Tracks



1 Anik Rudra

1 Tushar Kandari

1 Preeti Pant

1 Peter Bossew

2 Rosaline











2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016




1 Balram Ambade

2 12







2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016




b R B S Rawat amp

a Brij Nandan Singh












drhksingh1gmailcom



2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016








b Shivom Singh





2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016






b BK Dwivedi


a D N Shukla

b P K

Tandona








2016






































)






2016






































)





























)





icbces abstractbook 2016

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