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Ge11d: Connection between seismic observations and Earth’s average mineralogy Jennifer M. Jackson Lecture slides: January 25, 27, and 29, 2010

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Page 1: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

Ge11d: Connection between seismic observations and Earth’s average mineralogy

Jennifer M. Jackson

Lecture slides: January 25, 27, and 29, 2010

Page 2: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

PREM Earth’s internal divisions

Model A Bullen 1942

PREM Fraction

of MEarth

Region

(km)

Layer Depth

range (km)

(%)

A Crust:

Upper

0-15

0.10 (O)

0.37 (C) Lower 15-24

B Upper

mantle: Uppermost

24-80

10.3

Low-velocity

layer

80-220

220-400

C U.M.:

Transition zones

400-670 670-770

7.5

D Lower

mantle: D’

770-2740 49.2

D” 2740-2890

E Outer core 2890-5140 30.8

F Transition layer

G Inner core 5150-6370 1.7

(Dziewonski & Anderson 1981)

Page 3: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

Basic information needed to formulate a mineralogical &

compositional model of Earth’s crust:

Field observations: hand samples

Laboratory measurements: Density (as a function of chemistry)

Wave velocities (as a function of chemistry)

“Mineral Physics” constraints

Solar system constraints

Page 4: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

Crustal minerals

D.L. Anderson, New Theory of the Earth (2007) Oceanic crustal minerals

Page 5: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

Basic information needed to formulate a mineralogical &

compositional model of Earth’s crust:

Field observations: hand samples

Laboratory measurements:

Density (as a function of chemistry) Wave velocities (as a function of chemistry)

Solar system constraints

D.L. Anderson, New Theory of the Earth (2007)

Average crustal abundance, density, & seismic velocities of major crustal minerals.

Oceanic crustal minerals

Page 6: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

D.L. Anderson, New Theory of the Earth (2007)

Density, VP, and VS in rock types found in ophiolite sections (~oceanic crust)

Dunite

Lower, depleted oceanic crust (~20km) “ultramafics”

Upper oceanic crust (~7km)

Page 7: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

D.L. Anderson, New Theory of the Earth (2007)

Continental crustal thickness

Page 8: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

Density, VP and VS for continental minerals & rocks

D.L. Anderson, New Theory of the Earth (2007)

Density & seismic velocities of major crustal minerals.

Oceanic crustal minerals

Page 9: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s
Page 10: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

PREM (mantle)

Earth’s internal divisions

Model A Bullen 1942

PREM Fraction

of MEarth

Region

(km)

Layer Depth range

(km)

(%)

A Crust:

Upper

0-15

0.10 (O) 0.37 (C)

Lower 15-24

B Upper mantle:

Uppermost

24-80

10.3

Low-velocity

layer

80-220

220-400

C U.M.:

Transition zones

400-670 670-770

7.5

D Lower mantle:

D’ 770-2740 49.2

D” 2740-2890

E Outer core 2890-5140 30.8

F Transition layer

G Inner core 5150-6370 1.7

(Dziewonski & Anderson 1981)

Page 11: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

Sources of information about the composition

of Earth’s deep interior

Solar atmosphere analyses

Mineralogy and (isotope) geochemistry:

Meteorites

Mantle xenoliths

Inclusions in diamond

Geophysical observations and modeling:

Seismic body waves, normal-modes, gravity, magnetic field, viscosity, heat flow, …

High-pressure-temperature experiments: elasticity (wave velocities), phase equilibrium, thermodynamic data, calculations, …

Kola borehole: 12.6 km

Page 12: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

Understand the structure, dynamics and evolution of

Earth’s interior….

…in terms of the physical, chemical and thermodynamic

properties of minerals under extreme conditions.

“Micro to macro”

Page 13: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

Basic information to understand seismic observations:

As a function of P-T-X

Density

Wave velocities

Clausius-Clapeyron

slope: dP/dT = S/ V

Elastic anisotropy

Texture development

Phase Equilibrium Chemistry

“sharpness” of transition interval Solid, melt, or partial melt?

Deep interior behavior?

DAC, mulit-anvil, theory

Page 14: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

Upper mantle mineralogy

D.L. Anderson, New Theory of the Earth (2007)

Page 15: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

Measurements to determine: wave velocities

Ultrasonic interferometry

crustal and mantle rocks

Brillouin light scattering

crustal and mantle minerals

High-resolution inelastic x-ray scattering

lower mantle & core materials

Measurements to determine: density

Immersion

Determination of mass & volume (density = mass/volume)

Chemical analysis: mass

Diffraction: volume

Page 16: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

3 million times atmospheric pressure

Clarity Hardness Conductivity Melting point

Page 17: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

1 sq. centimeter

The Boeing 747-200 is ~500 tons

(1 million pounds)

3.6 million times atmospheric pressure = 360 GPa

1/2 million times atmospheric pressure = 50 GPa

Page 18: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

The diamond anvil cell

X-rays in

X-rays out

0.5 mm

gasket

rubies

medium surrounding

sample

metal

6 cm

IR laser in

IR laser in

Jackson’s lab, Caltech

Page 19: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

6900 6950 7000 7050Wavelength, A

Inte

nsity

0 5 10 15 20 25 30Pressure, GPa

Annealed18.6 GPa

Ambient

Pressure Measurement

Un-annealed

R2 R1

Pressure measurements by ruby fluorescence

Jackson’s lab, Caltech

DAC

Spectrometer

Page 20: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

Frost, Elements (2008)

See also D. Anderson, New Theory of the Earth (2007)

Average mineralogy of the deep Earth

Page 21: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

90 μm

57Fe sample

Creating high-temperatures in the diamond anvil cell: Novel mineral physics studies

X-ray meV bandwidth, focused

Laser Laser 8μm 30μm

Be-mirror (transparent for x-rays)

SMS signal

Jackson’s lab, Caltech

Page 22: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

Advanced Photon Source (APS) Argonne National Laboratory, Chicago, IL

High-resolution X-ray scattering measurements at high-pressures and high-temperatures

Page 23: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s
Page 24: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

Frost, Elements (2008)

Suggested isochemical mineralogy of the Earth’s mantle

Page 25: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

Model A Bullen 1942

PREM Fraction

of MEarth

Region

(km)

Layer Depth

range (km)

(%)

A Crust:

Upper

0-15

0.10 (O)

0.37 (C) Lower 15-24

B Upper

mantle: Uppermost

24-80

10.3

Low-velocity

layer

80-220

220-400

C U.M.:

Transition zones

400-670 670-770

7.5

D Lower

mantle: D’

770-2740 49.2

D” 2740-2890

E Outer core 2890-5140 30.8

F Transition layer

G Inner core 5150-6370 1.7

The Lower Mantle

4.6%

6.8%

Page 26: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

Compare measurements of aluminous MgSiO3 perovskite compressional (VP) and shear (VS) velocities

with PREM

Jackson et al. (2005)

D.L. Anderson, New Theory of the Earth (2007)

Page 27: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

The core-mantle boundary region: D”

VS ~2%

VP <1%

Page 28: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

Sound velocities of MgSiO3 post-perovskite:

Determined by Brillouin Spectroscopy Murakami et al. EPSL (2007)

Effect of iron?

Effect of aluminum?

More complicated chemistries and/or phases

Page 29: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

Model A Bullen 1942

PREM Fraction

of MEarth

Region

(km)

Layer Depth

range (km)

(%)

A Crust:

Upper

0-15

0.10 (O)

0.37 (C) Lower 15-24

B Upper

mantle: Uppermost

24-80

10.3

Low-velocity

layer

80-220

220-400

C U.M.:

Transition zones

400-670 670-770

7.5

D Lower

mantle: D’

770-2740 49.2

D” 2740-2890

E Outer core 2890-5140 30.8

F Transition layer

G Inner core 5150-6370 1.7

The Core

Page 30: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

Densities in the Core

(PREM)

Density deficit of ~3-5% in the outer core

Page 31: Ge11d: Connection between seismic observations and …web.gps.caltech.edu/classes/ge11d/doc/Ge11d_EarthComposition.pdf · Ge11d: Connection between seismic observations and Earth’s

Measured velocities of candidate core materials