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FORM-1

for

PROPOSED UNIT OF BULK DRUG

INTERMEDIATES AT ANKLESHWAR

of

M/s. ADARSH DYE CHEM PHARMA (UNIT - II)

Shed No. A – 1/3621, Notified Industrial Estate,

Ankleshwar – 393 002, Dist: Bharuch,

Gujarat

APPENDIX I

(See paragraph - 6)

FORM 1

(I) Basic Information

Name of the Project : M/s. Adarsh Dye Chem Pharma (Unit - II)

Location f site alternatives under

consideration

: M/s. Adarsh Dye Chem Pharma (Unit - II) Shed No.: A – 1/3621, Notified Industrial Estate, Ankleshwar – 393 002, Dist : Bharuch, Gujarat.

Size of the Project : Please refer Annexure –I.

Expected cost of the project : Rs. 45 Lacs

Contact Information : Mr. Rashikbhai J. Dobaria (Partner)

E – 10, Suflam Appartment, Near Manav Mandir

New Colony, GIDC, Ankleshwar – 393 002, Gujarat.

Phone No. : 98242 45595 Screening Category : A-5(F)

• Capacity corresponding to sectoral activity (such as production capacity for manufacturing,

mining lease area and production capacity for mineral production, area for mineral exploration, length for linear transport infrastructure, generation capacity for power generation etc.,)

(II) Activity

1. Construction, operation or decommissioning of the Project involving actions, which will cause physical changes in the locality (topography, land use, changes in water bodies, etc.)

Sr. No.

Information/Checklist confirmation Yes/No Details there of with approximate quantities/rates, wherever possible) with source of information data

1.1 Permanent or temporary change in land use, land cover or topography including increase intensity of land use (with respect to local land use plan)

No Proposed Project is within the GIDC Industrial Estate.

1.2 Clearance of existing land, vegetation and Buildings?

Yes Minor site clearance activities shall be carried out to clear shrubs and weed

1.3 Creation of new land uses?

Yes The project site is located on level ground, which does not require any major land filling for area grading work.

1.4 Pre-construction investigations e.g. bore Houses, soil testing?

No

1.5 Construction works?

Yes Please Refer Annexure – II.

1.6 Demolition works? No 1.7 Temporary sites used for construction works

or housing of construction workers? No

1.8 Above ground buildings, structures or earthworks including linear structures, cut and fill or excavations

Yes Please Refer Annexure – II.

1.9 Underground works mining or tunneling?

No

1.10 Reclamation works?

No

1.11 Dredging?

No

1.12 Off shore structures?

No

1.13 Production and manufacturing processes?

Yes Please Refer Annexure –III.

1.14 Facilities for storage of goods or materials?

Yes Raw Material Storage Area & Finished Products Area will be developed for proposed activities.

1.15 Facilities for treatment or disposal of solid waste or liquid effluents?

Yes Effluent generated from the process will send to CETP of M/s. Enviro Technology Ltd. (ETL), Ankleshwar for treatment. For treatment of solid waste please refer Annexure – IV.

1.16 Facilities for long term housing of operational workers?

No

1.17 New road, rail or sea traffic during Construction or operation?

No

1.18 New road, rail, air waterborne or other transport infrastructure including new or altered routes and stations, ports, airports etc?

No

1.19 Closure or diversion of existing transport routes or infrastructure leading to changes in Traffic movements?

No

1.20 New or diverted transmission lines or Pipelines?

No

1.21 Impoundment, damming, culverting, realignment or other changes to the hydrology of watercourses or aquifers?

No

1.22 Stream crossings? No 1.23 Abstraction or transfers of water form ground

or surface waters? Yes Water requirement will be met through

GIDC water supply. 1.24 Changes in water bodies or the land surface

Affecting drainage or run-off? No

1.25 Transport of personnel or materials for construction, operation or decommissioning?

Yes Transportation of personnel’s or raw material and products will be primarily by road only.

1.26 Long-term dismantling or decommissioning or restoration works?

No

1.27 Ongoing activity during decommissioning which could have an impact on the environment?

No

1.28 Influx of people to an area either temporarily or permanently?

No

1.29 Introduction of alien species?

No

1.30 Loss of native species or genetic diversity?

No

1.31 Any other actions? No 2. Use of Natural resources for construction or operation of the Project (such as land, water,

materials or energy, especially any resources which are non-renewable or in short supply): Sr. No.

Information/checklist confirmation Yes/No Details there of (with approximate quantities/rates, wherever possible) with source of information data

2.1 Land especially undeveloped or agricultural land (ha)

No It is within Notified Industrial area Ankleshwar, Dist-Bharuch.

2.2 Water (expected source & competing users) unit: KLD

Yes Please refer Annexure – V.

2.3 Minerals (MT) No 2.4 Construction material - stone, aggregates,

and / soil (expected source - MT) Yes Construction materials like steel, cement,

crushed stones, sand, rubble, etc. required for the project shall be procured from the local market of the region.

2.5 Forests and timber (source - MT) No.

2.6 Energy including electricity and fuels (source,competing users) Unit: fuel (MT), energy (MW)

Yes Please refer Annexure – VI.

2.7 Any other natural resources (use appropriate standard units)

No

3. Use, storage, transport, handling or production of substances or materials, which could be

harmful to human health or the environment or raise concerns about actual or perceived risks to human health.

Sr. No.

Information/Checklist confirmation Yes/No Details there of (with approximate quantities/rates, wherever possible) with source of information data

3.1 Use of substances or materials, which arehazardous (as per MSIHC rules) to humanhealth or the environment (flora, fauna, andwater supplies)

Yes Please refer Annexure –VII.

3.2 Changes in occurrence of disease or affect disease vectors (e.g. insect or water bornediseases)

No

3.3 Affect the welfare of people e.g. by changingliving conditions?

No

3.4 Vulnerable groups of people who could beaffected by the project e.g. hospital patients,children, the elderly etc.

No

3.5 Any other causes No

4. Production of solid wastes during construction or operation or decommissioning (MT/month) Sr. No.


4.1 Spoil, overburden or mine wastes No 4.2 Municipal waste (domestic and or commercial

wastes) No

4.3 Hazardous wastes (as per Hazardous Waste Management Rules)

Yes Please refer Annexure – IV.

4.4 Other industrial process wastes No Please refer Annexure –IV. 4.5 Surplus product No 4.6 Sewage sludge or other sludge from effluent

treatment No

4.7 Construction or demolition wastes No 4.8 Redundant machinery or equipment No 4.9 Contaminated soils or other materials No 4.10 Agricultural wastes No 4.11 Other solid wastes No

5. Release of pollutants or any hazardous, toxic or noxious substances to air (Kg/hr) Sr. No.


5.1 Emissions from combustion of fossil fuelsfrom stationary or mobile sources

Yes Please refer Annexure – VIII.

5.2 Emissions from production processes Yes Please refer Annexure – VIII. 5.3 Emissions from materials handling storage or

transport No

5.4 Emissions from construction activitiesincluding plant and equipment

No

5.5 Dust or odours from handling of materialsincluding construction materials, sewage and waste

No

5.6 Emissions from incineration of waste No

5.7 Emissions from burning of waste in open aire.g. slash materials, construction debris)

No

5.8 Emissions from any other sources No

6. Generation of Noise and Vibration, and Emissions of Light and Heat: Sr. No.

Information/Checklist confirmation Yes/No Details there of (with approximate quantities/rates, wherever possible) with source of information data with source of information data

6.1 From operation of equipment e.g. engines, ventilation plant, crushers

Yes The Noise level will be within the prescribed limit. At noisy areas adequate preventive & control measures will be taken. No significant noise, vibration or emission of light & heat from the unit.

6.2 From industrial or similar processes Yes - do -

6.3 From construction or demolition No

6.4 From blasting or piling No

6.5 From construction or operational traffic No

6.6 From lighting or cooling systems Yes Adequate Lighting will be provide in proposed unit and also local ventilation system provide in proposed unit.

6.7 From any other sources No

7. Risks of contamination of land or water from releases of pollutants into the ground or into

sewers, surface waters, groundwater, coastal waters or the sea: Sr. No.


7.1 From handling, storage, use or spillage of hazardous materials

Yes Please refer Annexure – VII.

7.2 From discharge of sewage or other effluents towater or the land (expected mode and place ofdischarge)

Yes The unit will be CETP member and The final treated effluent from the CETP will be discharged through GIDC drainage line to deep sea via FETP.

7.3 By deposition of pollutants emitted to air intothe and or into water

No

7.4 From any other sources No

7.5 Is there a risk of long term build up ofpollutants in the environment from thesesources?

No

8. Risk of accidents during construction or operation of the Project, which could affect

human health or the environment S.No. Information/Checklist confirmation Yes/No Details there of (with approximate

quantities/rates, wherever possible) with source of information data

8.1 From explosions, spillages, fires etc fromstorage, handling, use or production ofhazardous substances

Yes Please refer Annexure – IX.

8.2 From any other causes No

8.3 Could the project be affected by naturaldisasters causing environmental damage (e.g. floods, earthquakes, landslides, cloudburstetc)?

No

9. Factors which should be considered (such as consequential development) which could lead to environmental effects or the potential for cumulative impacts with other existing or planned activities in the locality Sr. No.

Information/Checklist confirmation

Yes/No

Details there of (with approximate quantities/rates, wherever possible) with source of information data

9.1 Lead to development of supporting. utilities, ancillary development or development stimulated by the project which could have impact on the environment e.g. • Supporting infrastructure (roads, power supply, waste or waste water treatment, etc.)

• housing development • extractive industry • supply industry • other

Yes Please refer Annexure – X.

9.2 Lead to after-use of the site, which could have an impact on the environment

No

(II) Environmental Sensitivity

Sr. No.

Areas Name/ Identity

Aerial distance (within 15km.) Proposed project location boundary

1 Areas protected under internationalconventions, national or local legislation fortheir ecological, landscape, cultural or otherrelated value

- No protected area within 15 km from the proposed project boundary.

2 Areas which important for are or sensitive Ecollogical reasons - Wetlands, watercourses orother water bodies, coastal zone, biospheres, mountains, forests

-

3 Area used by protected, important or sensitive Species of flora or fauna for breeding, nesting,

foraging, resting, over wintering, migration

- No protected area within 15 km from the proposed project boundary.

4 Inland, coastal, marine or underground waters - No inland, costal or marine within 15 km from the proposed project

5 State, National boundaries - N.A. 6 Routes or facilities used by the public for access

to recreation or other tourist, pilgrim areas - N.A.

7 Defense installations - N.A.

8 Densely populated or built-up area Ankleshwar Ankleshwar city is around 4-5 km from the proposed project site.

9 Area occupied by sensitive man-made land uses Hospitals, schools, places of worship,community facilities)

No

10 Areas containing important, high quality orscarce resources (ground water resources,surface resources, forestry, agriculture,fisheries, tourism, minerals)

No

11 Areas already subjected to pollutionenvironmental damage. (those where existinglegal environmental standards are exceeded)or

- NA

12 Areas susceptible to natural hazard which couldcause the project to present environmentalproblems (earthquake s, subsidence ,landslides,flooding erosion, or extreme or adverse climatic conditions)

- NA

IV). Proposed Terms of Reference for EIA studies: For detail please refer Annexure – XI

9.3 Set a precedent for later developments No

9.4 Have cumulative effects due to proximity to other existing or planned projects with similar effects

No

LIST OF ANNEXURES

SR. NO. NAME OF ANNEXURE

I List of Products along with their Production Capacity

II Layout of Plant

III Brief Manufacturing Process Description

IV Details of Hazardous Waste Generation & Disposal

V Details of Water And Wastewater

VI Fuel & Energy Requirements

VII Details of Hazardous Chemicals Storage & Handling

VIII Details of Stacks and Vents

IX Risk Scenario

X Socio-economic Impacts

XI Proposed Terms of Reference for EIA studies

ANNEXURE-I _______________________________________________________________________ LIST OF PROPOSED PRODUCTS ALONGWITH THEIR PRODUCTION CAPACITY

SR. NO. NAME OF PROPOSED PRODUCTS QUNTITY

(MT/Month)

1 Dimethyl Amino Ethyl Chloride Hydrochloride 5

2 2 – Chloro Ethyl Amino Hydrochloride 7

3 N, N – Bis [(Dichloro Ethyl) Amine] Hydrochloride 4

4 Diethyl Amino Ethyl Chloride Hydrochloride 3

5 N – Methyl (Diethyl Chloride) Amine 1

6 1 – (4 – Hydroxy Phenyl) – Piperazine

Hydrochloride

12

7 2 (4,6 – Dimethoxy Pyrimidine) Piperazine

Hydrochloride

5

8 2 – Bromo Ethyl Amine Hydrobromide 5

9 1 –(4 – Bromo – 2,5 – Dimethoxy Phenyl)

Piperazine Dihydrobromide

13

10 2,4 – Dichloro – 5 – Fluoro - Acetophenone 5

BY – PRODUCTS

11 Sodium Sulphide (30% Solution) 40

12 Hydrochloric Acid 20

Total 120

LIST OF RAW MATERIALS

Storage Facilities

(MT or KL/Month) Sr. No.

Name of Raw Materials

Quantity (MT/Month)

Max. Storage Capacity

Actual Storage Capacity

DIMETHYL AMINO ETHYL CHLORIDE HYDROCHLORIDE (5 MT/MONTH)

1 Di Methyl Amino Ethanol 6.148 3.0 2 Sodium Hydroxide 8.115 5.0 3 EDC 8.197 5.0 4 Thionyl Chloride 5.328 4.0

Purchase from market as and when required which is less than max. storage capacity

2 – CHLORO ETHYL AMINE (7 MT/MONTH)

1 Ethanol Amine 9.567 4.0 2 Thionyl Chloride 14.233 4.0 3 Sodium Hydroxide 2.333 5.0


N, N – BIS [(DICHLORO ETHYL) AMINE] HYDROCHLORIDE (4 MT/MONTH)

1 Di Ethanol Amine 4.870 5.0 2 EDC 7.304 5.0 3 Thionyl Chloride 4.348 4.0 4 Sodium Hydroxide 2.609 5.0


DIETHYL AMINO ETHYL CHLORIDE HYDROCHLORIDE (3 MT/MONTH)

1 Di Ethyl Amino Ethanol 3.343 2.0 2 EDC 7.413 5.0 3 Thionyl Chloride 2.314 4.0 4 Sodium Hydroxide 1.114 5.0


N – METHYL DI ETHYL CHLORIDE AMINE (1 MT/MONTH)

1 Di Ethanol Amine 1.105 5.0 2 EDC 2.263 5.0 3 Thionyl Chloride 1.526 4.0 4 Formaldehyde 0.168 0.2 5 Sodium Hydroxide 0.153 5.0


1 – (4 – HYDROXY PHENYL) PIPERAZINE HYDROCHLORIDE (12 MT/MONTH)

1 4 – Hydroxy Aniline 14.667 7.5 2 Bis (Dimethyl Chloride)

Amine Hydrochloride 15.227 7.5

3 KOH 0.133 0.5 4 Methanol 32.000 10.0 5 K2CO3 1.600 1.5


2 (4,6 – DIMETHOXY PYRIMIDINE) PIPERAZINE HYDROCHLORIDE (5 MT/MONTH)

1 2 – Amino – 4,6 – Di Methoxy Pyrimidine

6.200 3.0

2 Bis (Dimethyl Chloride) Amine Hydrochloride

4.880 7.5

3 KOH 0.600 0.5 4 Methanol 10.40 10.0 5 Hydrochloric Acid 10.00 5.0 6 K2CO3 0.120 1.5


2 – BROMO ETHYL AMINE HYDRO BROMIDE (5 MT/Month)

1 Ethanol Amine 6.074 4.0 2 Hydrobromic Acid 5.259 3.0 3 EDC 15.185 5.0


1 ( 4 – BROMO – 2,5 – DIMETHOXY PHENYL) PIPERAZINE DIHYDROCHOLRIDE (13 MT/Month)

1 2,5 – Dimethoxy Aniline 15.60 7.5 2 N,N – Bis (Diethyl

Chloride) Amine Hydrochloride

5.824 3.0

3 KOH 0.541 0.5 4 Methanol 24.96 10.0 5 Hydrochloric Acid 0.749 5.0 6 K2CO3 0.208 1.5 7 Bromine 0.666 0.5 8 Acetic Acid 0.416 0.5


2,4 – DICHLORO – 5 – FLUORO ACETO PHENONOE (5 MT/Month)

1 2,4 – Dichloro – 5 – Fluoro Benzene

6.167 3.0

2 Acetyl Chloride 3.333 2.0 3 Aluminum chloride 5.667 3.0


ANNEXURE-II _______________________________________________________________________ LAY OUT OF PLANT

Lay Out Plan

Sr. No. Proposed Construction Area Dimension (sq. meter)

1 Office 4.5 X 4.5 2 Storage Area 7.5 X 4.5 3 Raw Material 7.5 X 4.5 4 Production Area 7.5 X 12.5 5 Utility 2.5 X 2.5 6 Toilet / Bathroom 2.0 X 2.5 7 Laboratory 7.5 X 9.0 8 Boiler 5.5 X 5.5 9 Scrubber 5.5 X 5.5 10 Cooling Tower 5.0 X 5.0

Total Plot Area: 2,750 m2

Off

ice

1

Laboratory 7

Stor

age

Are

a 2

Raw

Mat

eria

l 3

4

Toilet 6

Utility 5

R3 R2 R1

8 Boiler

Scrubber 9

Cooling Tower 10

Parking Area Main Gate

GREGREEN BELT AREA

GR

EEN

BEL

T A

REA

GR

EEN

BEL

T A

REA

ANNEXURE-III _______________________________________________________________________ BRIEF MANUFACTURING PROCESS DESCRIPTION 1. DIMETHYL AMINO ETHYL CHLORIDE HYDROCHLORIDE Process Description A mixture of Dimethyl Amino Ethanol with EDC takes in dried reactor and addition of Thionyl Chloride slowly with stirring after 8 hours. After completion of reaction, distillation of EDC is started. Taken the reaction mixture in centrifuge and wash with methanol dried and packed and EDC is used next batch. Chemical Reaction CH3 CH3 I SOCl2 I N – CH2 – CH2OH N – CH2 – CH2Cl - HCl I I CH3 CH3 DI METHYL AMINO ETHANOL DI – METHYL AMINO ETHYL

CHLORIDE HYDROCHLORIDE Material Balance Dimethyl Amino Sod. SulphideEthanol 750.0 Kg. CHLORIDE GROUP 850 Ltr. Thionyl Chloride 650 Kg. FORMATION Water 650 Ltr. EDC 1000.0 Ltr. SCRUBBER NaOH 200 Kg. DISTILATION SO2 Gas EDC Recovered &Water 350.0 Lit. CETNTRIFUGE Reuse 960.0 Ltr. ML send to ETL 1055.0 Lit. DRYING Evaporation Loss 125 Ltr. PRODUCT 610 KG

2. 2 – CHLORO ETHYL AMINE HYDROCHLORIDE Process Description A mixture of Ethanol Amine is dissolved in EDC with sealed mechanical stirrer, an sufficient reflux condenser and is added was Thionyl Chloride slowly at room temperature for 8 hours & the reaction mixture is maintain and after cooled and EDC is distilled out and semi solid mixture is filtrate and wash with methanol and dried packed it. Chemical Reaction SO2Cl HO – CH2 – CH2 – NH2 Cl – CH2 – CH2 – NH2 - HCl EDC ETHANOL AMINE 2 – CHLORO ETHYL AMINE

HYDROCHLORIDE Material Balance Ethanol Amine Sod. Sulphide164. 0 Kg. CHLORIDE GROUP 250 Ltr. Thionyl Chloride FORMATION Water 200 Ltr. 244.0 Kg. SCRUBBER NaOH 50 Kg. DISTILATION SO2 Gas Water 250.0 Lit. CETNTRIFUGE ML send to ETL 513.0 Lit. DRYING Evaporation Loss 25 Ltr. PRODUCT 120 KG

3. N,N – BIS [(DICHLORO ETHYL) AMINE] HYDROCHLORIDE Process Description In a dry reactor fitted with a sealed mechanical stirring an efficient reflux condenser and a dropping funnel is placed of Thionyl Chloride and EDC. The reactor mixture flask must be cooled in an ice bath through out the entire period of operation. N,N – Di Ethanol amine is added drop wise through the Funnel to be cooled Thionyl Chloride over a period of an hour during which time there is a copious evolution sulfer dioxide after all the addition has been added and the reactor mixture is stirred for another hour and distilled out EDC and the semisolid product was filter and dried and packed. Chemical Reaction CH2CH2OH CH2CH2Cl I SOCl2 I NH NH I EDC I CH2CH2OH CH2CH2Cl DI ETHANOL AMINE N,N – BIS [(DICHLORO ETHYL) AMINE]

HYDROCHLORIDE

Material Balance

Di Ethanol Amine Sod. Sulphide

1400.0 Kg. CHLORIDE GROUP 2600 Ltr. Thionyl Chloride 1250 Kg. FORMATION Water 2000 Lt. EDC 2100.0 Ltr. SCRUBBER NaOH 600 Kg. DISTILATION SO2 Gas EDC Recovered &Water 500.0 Lit. CETNTRIFUGE Reuse 2020.0 Ltr. ML send to ETL 1850.0 Lit. DRYING Evaporation Loss 230 Ltr. PRODUCT 1150 KG

4. DIETHYL AMINO ETHYL CHLORIDE HYDROCHLORIDE Process Description A mixture of Diethyl Amino Ethanol charge in a reactor with EDC and slowly addition of Thionyl Chloride after 10 hours with stirring. After completion of reaction, start to distillate EDC. The mixture is then centrifuged, dried and packed. Recovered EDC reuse in Next Batch. Chemical Reaction CH2CH3 CH2CH3 I SOCl2 I N – CH2 – CH2 – OH N – CH2 – CH2 – Cl - HCl I I CH2CH3 CH2CH3 DIETHYL AMINO ETHANOL DIETHYL AMINO ETHYL CHLORIDE

HYDROCHLORIDE Material Balance Di Ethanol Amine Sod. Sulphide117.0 Kg. CHLORIDE GROUP 250 Ltr. Thionyl Chloride 81.0 Kg. FORMATION Water 200 Lt. EDC 250.0 Ltr. SCRUBBER NaOH 50.0 Kg. DISTILATION SO2 Gas EDC Recovered &Water 250.0 Lit. CETNTRIFUGE Reuse 240.0 Ltr. ML send to ETL 328.0 Lit. DRYING Evaporation Loss 25.0 Ltr. PRODUCT 105 KG

5. N – METHYL DIETHYL CHLORIDE AMINE Process Description A mixture of Diethyl Amine in reaction vessel with add Formaldehyde slowly addition and hydrochloric Acid as catalyst and reflux it for 10 hours with continuous stirring. Reaction mixture maintain for 6 hours after completion of reaction. Cooled and distillate this product. This product is in a dry reactor fitted with a sealed mechanical stirrer, an efficient reflux condenser, and a dropping funnel is placed N – Methyl Diethanol with EDC and addition of slowly Thionyl chloride after 8 hours. The addition is over after reaction is maintained 6 hours. Distillation of EDC carry out after completion of final product. Filter, drying and pack the final product. Chemical Reaction CH2CH2OH CH2CH2OH CH2CH2OH I HCHO I SOCl2 I NH NCH3 CH3 I HCl I EDC ICH2CH2OH CH2CH2OH CH2CH2OH N – METHYL DIETHYL CHLORIDE

AMINE

Material Balance Di Ethanol Amine 210.0 Kg. METHYLATION Formaldehyde 32.0 Kg. EDC 430.0 Ltr. DISTILLATION EDC 412.0 Kg. Thionyl Chloride CHLORIDE GROUP SO2 Gas 290.0 Kg. FORMATION Water 125 Lt. SCRUBBER NaOH 30 Kg. ISOLATION Sod. Sulphide 155 Lit. Water 250.0 Lit. FILTRATION ML send to ETL 570.0 Lit. DRYING Evaporation Loss 40.0 Ltr. PRODUCT 190 KG

6. 1 – ( 4 – HYDROXY PHENYL) PIPERAZINE HYDROCHLORIDE A mixture of N,N – Bis (Diethyl Chloride) Amine Hydrochloride in Methanol with addition of 4 – Hydroxy Aniline in presence of K2CO3 and KOH. Reaction mixture refluxed for 20 hours with stirring. After completion of reaction distilled out methanol and add ice cold water and stirring for ½ hour and added slowly Hydrochloric Acid with adjustment of pH at 7. the isolated product is filtered, drying and packed. Chemical Reaction OH

CH2CH2Cl + I NH I CH2CH2Cl

NH2 OH I N N H

HCl 1 – (4 – HYDROXY PHENYL)

PIPERAZINE HYDROCHLORIDE

KO

H, H

Cl,

K2C

O3

Material Balance 4 – Hydroxy Aniline 1100 Kg. Bis (Diethyl Chloride) Amine REACTOR – I Hydrochloride 1142 Kg Methanol 2400 Ltr Methanol 2300 Ltr. DISTILLATION Residues 22.0 Kg. HCl 1500 Ltr. ISOLATION Water 1500 Ltr. SCRUBBER KOH 10 Kg. SALT FORMATION Cl2 GAS Water 350.0 Lit. FILTRATION ML send to ETL 1600.0 Lit. DRYING Evaporation Loss 180.0 Ltr. FINAL PRODUCTS 900 KG

7. 2 (4,6 – DIMETHOXY PYRIMIDINE) PIPERAZINE HYDROCHLORIDE A mixture of N,N – Bis (Diethyl Chloride) Amine Hydrochloride in Methanol with addition of 2 – Amino – 4,6 – Dimethoxy Pyrimidine in presence of K2CO3 and KOH. After addition, reaction mixture is refluxed for 24 hours with stirring. After completion of reaction methanol distilled out from the mixture and add ice cold water and stirring for ½ hour and add Hydrochloric Acid slowly with adjustment of pH 7. the isolated product is filtered, dried and packed. Chemical Reaction

OCH3 CH2CH2Cl I + NH

I CH3O NH2 CH2CH2Cl

N OCH3 CH3O N NH ----HCl N 2 – (4,6 – DIMETHOXY

PYRIMIDINE) PIPERAZINE HCL

KO

H, H

Cl,

K2C

O3

Material Balance 2 – Amino – 4,6 – Dimethoxy Pyrimidine 155 Kg. Methanol 260 Kg. Bis (Diethyl Chloride) Amine REACTOR – I HCl 122 Kg. KOH 15 Kg. K2CO3 3 Kg. Methanol 245 Kg. DISTILLATION Residues 3.0 Kg. ISOLATION HCl 250 Ltr. SALT FORMATION Water 400 Lit. FILTRATION ML send to ETL 807.0 Lit. Evaporation Loss DRYING 25 Ltr. FINAL PRODUCTS 125 KG

8. 2 – BROMO ETHYL AMINE HYDROBROMIDE Take EDC and Ethanol Amine in reactor, maintain temperature by using ice cold water. Add Ice cold Hydro Brominc Acid drop wise by using dropping funnel. Heating and reflux reaction mixture for 1 hour and maintain this situation for 10 hours. After completion of reaction filter, drying and pack the final product. Chemical Reaction Br2 HO – CH2 – CH2 – NH2 Br – CH2 – CH2 – NH - CHBr 2 – BROMO ETHYL AMINE

HYDROBROMIDE Material Balance Ethanol Amine 164 Kg. Hydrobromic Acid 142 Kg. REACTOR – I . EDC 410 Kg. DISTILLATION EDC 395.0 Kg. Water 250.0 Ltr. FILTERATION ML send to ETL 406.0 Ltr. DRYING Evaporation Loss 30.0 Ltr. PRODUCT 135 KG.

9. 1 – (4 – BROMO – 2, 5 – DIMETHOXY PHENYL) PIPERAZINE DIHYDROCHLORIDE A mixture of N,N – Bis (Diethyl Chloride) Amine Hydrochloride and Anhydrous K2CO3 (freshly distilled), 2,5 – Dimethoxy Anilines and methanol was heated and refluxed for 40 hours. After completion of reaction cool down the mixture at room temperature. The mixture pour then in cold ice water. Adjust the pH of mixture at 12 by using KOH solution. Now take this mixture in another reactor with methanol and add Glacial Acetic Acid with Br2 slowly and complete the reaction after 4 hours. After completion of reaction maintain this situation for 1 hour. Distilled out Hydrobromic Acid and add Hydrochloric Acid for salt formation. Now filter, dry and pack the final product. Chemical Reaction OCH3 CH2CH2Cl OCH3 I NH2 + NH N N NH I CH2CH2Cl

OCH3

OCH3 OCH3 N NH2HCl OCH3 1 – (4 – BROMO – 2,5 – DIMETHOXY PHENYL)

PIPERAZINE DIHYDROCHLORIDE

MeOH, KOH, K2CO3

Gl.

Ace

tic A

cid

, 2H

Cl,

Br 2

Material Balance 2,5 – Dimethoxy Aniline 750 Kg. KOH 26 Kg. K2CO3 10 Kg. REACTOR – I Methanol 1200 Ltr. N, N - Bis (Diethyl Chloride) Amine HCl 280 Kg. Methanol 1150 Kg. DISTILLATION Residues 400 Kg ISOLATION Methanol 1150 Kg. Methanol 1100 Kg.HCl 36 Ltr. BROMINATION Bromine 32 Kg. Residues 14.0 Kg. Water 400.0 Lit. FILTRATION ML send to ETL 470.0 Lit. Evaporation Loss DRYING 125 Ltr. FINAL PRODUCTS 625 KG

10. 2, 4 – DICHLORO – 5 – FLUORO ACETOPHENONE Take 2, 4 – Dichloro – 5 – Fluoro Benzene in a dried reactor and add Aluminium Chloride and stirring it. During this reaction also slowly add Acetyl Chloride and reaction carry out for 10 hours. After completion of reaction, cool it at room temperature for 2 hours. Filter, dry and packed the final products. Chemical Reaction F F COCH3 AlCl3 CH3COCl Cl Cl Cl Cl 2,4 – DICHLORO – 5 – FLUORO

ACETOPHENONE Material Balance 2,4 – Dichloro – 5 – Fluoro Benzene 111 Kg. REACTOR – I Acetyl Chloride 60 Kg. Aluminum Chloride 102 Kg. ISOLATION Water 350.0 Ltr. FILTERATION ML send to ETL 513.0 Lit. DRYING Evaporation Loss 20 Ltr. PRODUCT 90 KG.

ANNEXURE - IV HAZARDOUS WASTE GENERATION AND DISPOSAL (PROPOSED)

Source of waste

Type of waste Category Quantity per Month

Method of storage Method of disposal

Discarded Begs & containers

50 Nos. Packing & handling

Discarded barrels & drums

33.3 30 Nos.

Reused or sale to GPCB approved Scrape vendor

Plant & machinery

Waste or Spent Oil

5.1

2.0 Ltr/Year

Reused as lubricant in plant machinery or sale to MoEF approved recycler

Process Residues 28.1 0.7 MT

Store within company premises having area 450 Sq. Feet.

Send to BEIL, Ankleshwar for Incineration.

ANNEXURE – V

_______________________________________________________________________

DETAILS OF WATER AND WASTEWATER (PROPOSED) Sr.

No.

Category Water Consumption

(Lit./Day)

Waste Water

Generation (Lit./Day)

1. Domestic 1000 1000

2. Other (Gardening) 1000 -

3. Industrial

Process 3000 5500

Boiler 1500 -

Cooling 2000 300

Washing 1000 1000

APCE 2000 -*

Total Industrial 9500 6800

Grand Total 11500 7800

* = BY PRODUCT GENERATE FROM APCE WILL BE SOLD TO END USERS.

WATER BALANCE DIAGRAM (Lit/Day)

Fresh Water (11500)

1000

1000

3000

1500

2000

1000

2500

Domestic

Gardening

Process

Boiler

Cooling

Washing

APCE

1000

5500

300

1000

6800 Soak Pit

ETL

ANNEXURE-VI _______________________________________________________________________ FUEL & ENERGY REQUIREMENT TOTAL POWER REQUIREMENT (KW) (PROPOSED)

Sr.

No. Scenario

Project

(KW)

Township

(KW) Other (KW) Total (KW)

A Proposed 45 NA NA 45

Total 45

SOURCE OF POWER (KW)

Sr.

No.

Scenario Power requirement DG Sets

A Proposed D.G.V.C.L 45 KVA

Total 45 KVA

FUEL REQUIREMENT

Sr. No. Fuel Proposed Consumption

1 FO 600 Lit/Day

ANNEXURE-VII _______________________________________________________________________ STORAGE DETAILS OF HAZARDOUS CHEMICALS (PROPOSED)

Quantity Sr. No. Name of hazardous

substances Max.

That can be

stored (MT)

Actually

Stored

(MT)

State &

operating

pressure &

temp.

Type of

Hazard

Possible

(Fire, explosion,

etc.)

Control measures

provided

Remarks

1 Hydrochloric Acid 5.0 NTP 2 Hydrobromic Acid 3.0 NTP 3 Acetic Acid 0.5 NTP

Acidic in nature and corrosive

4 Sodium Hydroxide 5.0 NTP 5 Potassium Hydroxide 0.5 NTP

Alkaline in nature and Corrosive

6 Dimethyl Amino Ethanol

3.0 NTP

7 EDC 5.0 NTP 8 Thionyl Chloride 4.0 NTP 9 Ethanol Amine 4.0 NTP 10 Diethanol Amine 5.0 NTP 11 Diethyl Amino Ethanol 2.0 NTP 12 Formaldehyde 0.2 NTP 13 4 – Hydroxy Aniline 7.5 NTP 14 Bis (Dimethyl

Chloride) Amine Hydrochloride

7.5 NTP

15 Methanol 10.0 NTP Highly inflammable

and give explosion

16 K2CO3 1.5 NTP 17 2 – Amino – 4,6 –

Dimethoxy Pyrimidine 3.0 NTP

18 2,5 – Dimethoxy Aniline

7.5 NTP

19 N,N – Bis (Diethyl Chloride) Amine Hydrochloride

3.0 NTP

20 Bromine 0.5 NTP 21 2,4 – Dichloro – 5 –

Fluoro Benzene 3.0 NTP

22 Acetyl Chloride 2.0 NTP 23 Aluminum Chloride 3.0

Purchase from market as and when required which will less than max. storage capacity

NTP

Prevent leakage & spillage, used neutralization chemicals, use adequate PPE’s, fire extinguisher

Material Safety Data Sheet attached for Hazardous Chemicals

ANNEXURE-VIII _______________________________________________________________________ DETAILS OF STACKS & VENTS (PROPOSED) DETAILS OF FLUE GAS STACKS

Sr.

No.

Stack

Attached To

Stack

Height

(meter)

Stack

Dia

(meter)

Fuel Consumption of fuel

( Lit./Day)

Pollutants

1.

Baby Boiler

15

0.3

FO

500

2.

Hot Air

Generator

15

0.3

FO

100

PM, SOx, NOx

DETAILS OF SCRUBBER

Scrubber

Attached To

Height

of scrubber

(feet)

Dia of

Scrubber

(inch)

Type of

Scrubber

Scrubber

Media

Pollutants

Reactor

10

9

Packed Tower

NaOH, Water

SO2, Cl2

DETAILS OF PROCESS VENT

SR. NO. Stack Attached

to

Height of stack

(meter)

Diameter of

stack

(inch)

Scrubber

System

Pollutants

1.

Reactor

10

4

Water

SO2, Cl2

Two Stage Scrubbers

To Atmosphere 10 Meter 10 Meter HCl &SO2,

Water Circulation Pump 3m3

Caustic Circulation Pump 2.5 m3

3.0 m3/Hr

2.5 m3/Hr

ANNEXURE-IX

_______________________________________________________________________ RISK SCENARIO

Sr. No.

Name of Hazardous Material

Operating Pressure &

temperature

Types of Hazards

Control measures provided

Maximum storage capacity

(MT/Month) 1 EDC NTP 5.0

2 Ethanol Amine NTP 4.0

3 Di Ethanol Amine NTP 5.0

4 Formaldehyde NTP 0.2

5 Methanol NTP

Highly inflammable and also explosive when storage in bulk quantity

Provide & use adequate PPE’s. Use DCP as Fire Extinguishers.

10.0

6 Hydrochloric Acid NTP 5.0

7 Hydrobromic Acid NTP 3.0

8 Acetic Acid NTP

Corrosive and irritant

Prevent leakage and spillage, Provide & use Adequate PPE’s

0.5

9 Sodium Hydroxide NTP Irritant Prevent leakage and spillage, Provide & use Adequate PPE’s

5.0

ANNEXURE-X

_______________________________________________________________________ SOCIO - ECONOMIC IMPACTS

1) EMPLOYMENT OPPORTUNITIES

During construction phase, skilled and unskilled manpower will be needed. This will

temporarily increase the employment opportunity. Secondary jobs are also bound to be

generated to provide day-to-day needs and services to the work force. This will also

temporarily increase the demand for essential daily utilities in the local market.

The manpower requirement for the proposed expansion is expected to generate some

permanent jobs and secondary jobs for the operation and maintenance of plant. This will

increase direct / indirect employment opportunities and ancillary business development to

some extent for the local population.

This phase is expected to create a beneficial impact on the local socio-economic environment.

2) INDUSTRIES

During construction of the project, the required raw materials and skilled and unskilled

laborers will be utilized maximum from the local area. The increasing industrial activity will

boost the commercial and economical status of the locality, to some extent.

3) PUBLIC HEALTH

During construction period, workers will be provided with basic amenities like safe water

supply, low cost sanitation facilities, first aid, required personal protective equipment, etc.

Otherwise, there could be an increase in diseases related to personal hygiene.

Emission, if uncontrolled from process and utility stacks may cause discomfort, burning of

eyes to the recipients in the down wind direction. This may be caused due to the failure of

control equipment / process. The company regularly examines, inspects and tests its emission

from sources to make sure that the emission is below the permissible limit.

Hence, there will not be any significant change in the status of sanitation and the community

health of the area, as sufficient measures have been taken and proposed under the EMP.

4) TRANSPORTATION AND COMMUNICATION

Since the existing factory is having proper linkage for the transport and communication, the

development of this project will not cause any additional impact.

In brief, as a result of the expansion there will be no adverse impact on sanitation,

communication and community health, as sufficient measures have been proposed to be taken

under the EMP. The proposed expansion is not expected to make any significant change in

the existing status of the socio - economic environment of this region.

ANNEXURE-XI _______________________________________________________________________ TERMS OF REFERENCE FOR EIA STUDIES

Taking into consideration proposed project activities and guidelines, an area of 10 km radius

from the center of the project shall be selected and shall be designated as the study area for

the purpose of EIA study.

1) Base Line Environmental Condition

The samples of ambient air, ground and surface water and soil shall be collected and analysed

as per the standard methods for establishing the baseline data and to determine the impact of

proposed activity on the same.

2) Ambient Air Environment

The air environment around the plant shall be studied by setting up twelve locations within

the study area of 10 Km radius from the project site and collection and monitoring the site

specific meteorological data, viz. wind speed and direction, humidity, rainfall and ambient

temperature. Design of network for ambient air quality monitoring location is based on

guidelines provided by CPCB. The ambient air samples shall be collected and analysed for

SPM, RSPM, SO2, NOx and NH3 for prediction, evaluation and assessment of potential

impact on ambient air environment.

3) Ground and Surface Water Environment

The water required for domestic and industrial uses is being made available from ground

water only. Hence, to assess the Physico-chemical quality of the water, a number of water

samples shall be collected and analyzed for pollution parameters viz., pH, TDS, Turbidity,

BOD3, COD, Fluorides, Chlorides, Sulphates, Nitrates, Ammonical Nitrogen, Hardness,

Alkalinity, Iron, Oil & Grease and some trace heavy metals, in order to find out the

contamination, if any.

4) Noise Environment

Noise pollution survey shall be conducted in the study zone for evaluating existing status.

The anticipated noise sources shall be automobile activities, which are likely to be increased

due to proposed activity. Noise levels shall also be recorded at the noise generating places

and in the surrounding villages for evaluating general scenario of the study area. Hourly

equivalent sound levels (Leq) shall also be recorded for calculating Day and Night noise

levels in the surrounding villages.

5) Soil Environment

Soil sampling and analysis shall be carried out to assess physico-chemical characteristics of

the soils and delineate existing cropping pattern, existing land use and topography, within the

study area. Identification of potential utilities of effluent in land application and subsequent

impacts shall be assessed, if any.

6) Biological Environment

Keeping in view, the importance of biological component of total environment due to the

proposed project, biological characterization of terrestrial and aquatic environments, changes

in species diversity of flora and fauna in terrestrial as well as aquatic systems shall be studied

for impact analysis due to proposed project activity.

7) Socio-economic Environment

Demographic and related socio-economic data shall be collected from census handbook and

EIC to assess socio-economic status of study area. Assessment of impact on significant

historical, cultural, and archeological sites/places in the area and economic and employment

benefit arisen out from the project shall be given special attention.

8) Identification of Source of Pollution

Detailed studies of manufacturing process for existing production scenario and proposed

expansion scenario shall be carried out along with input and output of materials, water, and

wastewater as well as infrastructure facilities available.

9) Evaluation of Pollution Control and Environmental Management System

The qualitative and quantitative analysis of various pollution sources as well as evaluation of

pollution control system shall be carried out.

10) Evaluation of Impact

A comprehensive evaluation of environmental impact with reference to proposed expansion

activities shall be carried out.

Cancellation

11) Preparation of Environmental Management Plan

A comprehensive Environmental Management Plan shall be prepared covering all the aspects

of pollution prevention measures, Air and Water Pollution Control measures, Hazardous

Waste Management, Environmental Surveillance and Environmental Management Plan.

The contents of EIA report, details of data collection and source of secondary data are

presented below.

E.I.A. PLAN & PROCEDURE

RECONNAISSANCE SURVEY OF EXISTING PLANT

ANNUAL REPORT MARKET ASSESSMENT FINANCIAL REPORT PROJECT REPORT

INTRODUCTION

MONITORING OF AIR, WATER & SOIL QUALITY & NOISE LEVELS. DATA ON METEOROLOGY SOCIO-ECONOMIC STATUS & BASIC AMENITIES. SITE VISITS BY AND INTERVIEWS WITH LOCALS

BASELINE ENVIRONMENTAL

STATUS ENVIRONMENTAL INFORMATION CENTRE CENTRAL GROUND WATER BOARD GUJARAT POLLUTION CONTROL BOARD (GPCB)

PUBLIC HEALTH ENGINEERING DEPT. AGRICULTURE DEPARTMENT FOREST DEPARTMENT IRRIGATION DEPARTMENT EMPLOYMENT EXCHANGE HEALTH CENTER CENSUS DEPT. INDIAN METEOROLOGICAL DEPT.

SOCIOECONOMIC STATUS &

INFRASTRUCTURE

EXISTING PLANT

FACILITY DESCRIPTION IMPACTS

METHODOLOGY OF IMPACT

ASSESSMENT

IDENTIFICATION & ASSESSMENT OF IMPACTS

EVALUATION OF IMPACTS BY MATRIX METHOD

SOURCE OF INFORMATIONOVERVIEW OF

E. I. A. STUDIES

ACTIVITIES

ENVIRONMENTAL MANAGEMENT

PLAN

DESCRIPTION OF EFFLUENT TREATMENT PLAN, AIR POLLUTION CONTROL, HAZARDOUS WASTE MANAGEMENT, GREEN BELT DEVELOPMENT MONITORING PROGRAM

form-1 adarsh pharma€¦ · no proposed project is within the gidc industrial estate. 1.2...

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