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Federal Emergency Management Agency United States Fire Administration Hazardous Materials Guide for First Responders Hazardous Materials Guide First Responders for

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  • Federal Emergency Management AgencyUnited States Fire Administration

    Hazardous Materials Guidefor

    First Responders

    Hazardous Materials Guide

    First Respondersfor

  • How to Use this Guide

    If you know the Chemical/Material Name:

    1. Go to the Specific Material Guidesè locate the chemical in the alphabetical listing

    2. If you are unable to locate the chemical in the Specific Material Guide:è Go the Alphabetical Material Name Index è locate the chemical in the alphabetical listingè go to the page listed for guidance information

    3. If the chemical is not found in the index, go to the HAZMAT General ResponseScheme

    If you have only the UN Number for the Chemical/Material:

    1. Go to the UN/NA Number Index è locate the UN/NA number in the numerical listingè go to the page listed for guidance information

    2. If material UN number is not found in the index go to the HAZMAT GeneralResponse Scheme

    If you have only NFPA Placard Information:

    1. Go to the guidance information for using the NFPA 704 Placard

    If you have only DOT Placard information:

    1. Go the HAZMAT General Response Scheme

    WARNING!The best time to learn how to use this book is BEFORE you need it. Train withthis book the way you would train with any new piece of equipment - in advance!

  • Hazardous

    Materials

    Guide

    for

    First

    Responders

    The information in this book was collected from a variety of sources which were reviewed by the Firefighters’ Safety Study Technical Commit-tee and are believed to be accurate. However, the Federal Emergency Management Agency makes no claim that these data and recommenda-tions are either correct or sufficient and assumes no liability for any adverse consequences arising from their use.

    The action recommendations in this book should be considered as suggestions only. Specific circumstances at the scene of an incident as well asthe number and training of first responders will dictate what actions are actually appropriate. Final decisions are the responsibility of the IncidentCommander.

  • AcknowledgmentsThis document was prepared under a Cooperative Agreement (EMW-93-K-4351) between the Federal EmergencyManagement Agency/United States Fire Administration and the University of Louisville. The data was assembled andformatted by an active Writing Committee with direction and oversight by the Firefighters’ Safety Study Project Commit-tee. Technical content was also reviewed under a separate contract (EMW-3-4649) with Louisiana State University.

    Writing Committee

    George C. Rodgers, Jr., Editor Steve Burton Gary M. HartMedical Director Assistant Chief, Fire/EMS/Hazmat PresidentKentucky Regional Poison Center Rohm and Haas Co., Louisville (Kentucky) Paragon Enterprises, Inc.

    Plant Louisville (Kentucky)

    Nancy J. Matyunas, Associate Editor Thomas L. Coomes, II Brad LearnClinical Assistant Professor of Pediatrics Environmental Health Coordinator/ Medical Training Coordinatorand Toxicology HazMat Response, Ret. City of Louisville (Kentucky)University of Louisville Louisville/Jefferson County (Kentucky) Division of Fire

    Health Department

    Clark Bledsoe A. J. “Bud” FeketeAssistant Director Deputy ChiefJefferson County (Kentucky) Louisville (Kentucky) Fire Department, Ret.Planning and Environmental Management Coordinator of Technical Hazards, Louisville/

    Jefferson County Disaster and Emergency Services

    This project could not have been undertaken without the expertise of the following individuals who providedinvaluable guidance and input by serving on the Firefighters’ Safety Study Project Committee.

    Steven C. Bailey (Chair) Patricia Frazier George C. Rodgers, Jr.Assistant Chief, Ret. Tri Data Corporation Medical DirectorSeattle (Washington) Fire Department Kentucky Regional Poison Center

    James Brizzell Richard L. Hartnett Jerry M. Schroy, P. E., DEEChief, Hazardous Materials Bureau Chief, Emergency Management Division Senior FellowNY Office of Fire Prevention & Control Boston (Massachusetts) Fire Department Solutia Inc.

    Gary E. Curmode Charles B. Henry, Jr. Alan L. SchneiderChief Institute for Environmental Studies Chemical EngineerSedgwick County (Kansas) Fire Department Louisiana State University US Coast Guard

    John Eversole Bradley S. PabodyChief, Hazardous Materials Fire Program SpecialistChicago (Illinois) Fire Department United States Fire Administration

    In addition to the project committee members listed above, the following organizations and individuals provided invalu-able assistance in the field testing and evaluation of the Hazardous Material Guide for First Responders

    National Association of State Fire Marshals

    Ray E. Carnahan Michael Durst Donald BlissCommander, Fire Marshal’s Office State Fire Marshal State Fire MarshalArkansas State Police Nebraska State Fire Marshal’s Office New Hampshire Division of Fire Safety

  • Table of Contents

    How to Use this Guide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Inside Front Cover

    Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

    Alphabetical Material Name Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

    UN/NA Number Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39

    Specific Material Guides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49

    Materials Summary Response Table . . . . . . . . . . . . . . . . . . . . . . . . . . . . 481

    DOT Placards — Chart 10 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 521

    Silhouettes of Rail Cars, Tank Trucks and Chemical Tanks . . . . . . . . . . 525

    General Approach to a Hazmat Incident . . . . . . . . . . . . . . . . . . . . . . . . . 547

    Glossary of Terms and Abbreviations . . . . . . . . . . . . . . . . . . . . . . . . . . . 557

    Important Telephone Numbers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 562

    First Responder Strategy Using the NFPA 704 Placard . . . . . . . Inside Back Cover

    Hazmat General Response Scheme . . . . . . . . . . . . . . . . . . . . . Outside Back Cover

  • 1

    I. Objectives

    This book is the result of an extensive study of availablehazardous materials response resources for first respondersundertaken by the United States Fire Administration (USFA)as part of the Firefighters’ Safety Study Act of 1990 (P.L. 101-446). The study concluded that, while several excellent andtechnically accurate resources are available, none are directedto the specific needs of the first responder trained at theAwareness or Operational Levels of Training; the training levelsof most first responders. It is the hope and the intent of theUSFA that this book will be that much needed resource.

    This book provides important information for the initial responseto both transportation and fixed facility incidents. It has beendesigned to present the first responder with a maximum amountof useful key information in a limited amount of space. As withany reference, it cannot include all information that might beuseful or discuss all situations which might occur; nor can itreplace the training and experience of individual responders.The information contained in this book has been reviewed byseveral sources and is as technically accurate as possible.For major incidents it will be necessary to obtain more detailedinformation from other resources as well as more advancedexpertise from those with more extensive training.

    It is assumed that those using this book will have hadsome training in hazardous materials response. Becausemost first responders are trained at the Awareness orOperational levels, this book is directed at appropriateresponses for these levels of training. These levels are definedbelow as published by the National Fire Protection Association(NFPA 472, 1992) and the Occupational Safety and HealthAdministration (OSHA 1910.120).

    OSHA 1910.120

    First Responder At Awareness Level: First responders atthe Awareness Level are individuals who are likely to witnessor discover a hazardous substance release and who have beentrained to initiate an emergency response sequence by notifyingthe authorities of the release. First responders at theAwareness Level shall have sufficient training or have hadsufficient experience to objectively demonstrate competencyin the following areas:

    (A) An understanding of what hazardous substances are, andthe risks associated with them in an incident.

    (B) An understanding of the potential outcomes associatedwith an emergency created when hazardous substancesare present.

    (C) The ability to recognize the presence of hazardoussubstances in an emergency.

    (D) The ability to identify the hazardous substances, ifpossible.

    (E) An understanding of the role of the first responderawareness individual in the employers emergency responseplan including site security and control and the U.S.Department of Transportation’s Emergency ResponseGuidebook.

    (F) The ability to realize the need for additional resources,and to make appropriate notifications to the communicationcenter.

    First Responder Operations Level: First responders at theOperations Level are individuals who respond to releases orpotential releases of hazardous substances as part of the initialresponse to the site for the purpose of protecting nearbypersons, property, or the environment from the effects of therelease. They are trained to respond in a defensive fashionwithout actually trying to stop the release. Their function is tocontain the release from a safe distance, keep it from spreading,and prevent exposures. First responders at the OperationsLevel shall have received at least eight hours of training orhave had sufficient experience to objectively demonstratecompetency in the following areas in addition to those listedfor the Awareness Level and the employer shall so certify:

    (A) Knowledge of the basic hazard and risk assessmenttechniques.

    (B) Know how to select and use proper personal protectiveequipment provided to the first responder operational level.

    (C) An understanding of basic hazardous materials terms.

    (D) Know how to perform basic control, containment, and/orconfinement operations within the capabilities of theresources and personal protective equipment available withtheir unit.

    (E) Know how to implement basic decontamination procedures.

    (F) An understanding of the relevant standard operatingprocedures and termination procedures.

    II. How The Book is Organized

    The body of this book is divided into seven sections:• Indexes: ALPHABETICAL MATERIAL NAME INDEX followed by a UN/

    NA NUMBER INDEX.

    • SPECIFIC MATERIAL GUIDES: specific recommendations for 430commonly encountered materials.

    • MATERIALS SUMMARY RESPONSE TABLE: summary informationfor 1,422 less commonly encountered materials.

    • DOT PLACARDS - CHART 10.

    • SILHOUETTES OF RAIL CARS, TANK TRUCKS AND CHEMICAL TANKS.

    Introduction

  • 2

    • GENERAL APPROACH TO A HAZMAT INCIDENT.• GLOSSARY OF TERMS AND ABBREVIATIONS used in the book.

    The main body of the book provides information on about 1750different materials. The materials included in these sectionsinclude most of those which have been reported to have beeninvolved in hazardous materials incidents. Most drugs havebeen excluded. Materials were assigned to the SPECIFIC MATERIALGUIDE section or the MATERIALS SUMMARY RESPONSE TABLE basedupon the likelihood that they would be encountered and themagnitude of the hazards they represent, using a formuladesigned for this project. The information in these two sectionsis intended to be used during an actual incident.

    The GENERAL APPROACH TO A HAZMAT INCIDENT section providesspecific information about a number of different responsescenarios. It also provides useful information and techniquesfor assisting in the identification of materials. This sectionshould be studied as part of training for Hazmat response. It isnot intended for use during an actual incident.

    Following the General Approach section is a Glossary of thetechnical terms and abbreviations used throughout the book.While the authors have tried to use simple and straightforwardlanguage, some terms may not be familiar to all users. Alsoincluded in this last section are several Appendices providingreference information mentioned in the text.

    This book has been extensively indexed using all of the materialnames and synonyms (other names for the same chemical)found in the book. There is a separate index for UN and NAnumbers which are commonly found on shipping papers whenmaterials are in transport. While the SPECIFIC MATERIAL GUIDESsection is arranged in alphabetical order by the most widelyused name of the material, the index should be used as themost rapid way of locating information about a specificmaterial.

    This book does not contain specific recommendations aboutisolation or evacuation distances. Because this book isdesigned to be used in a wide range of scenarios involvingdifferent container sizes, it was felt that the calculation of suchdistances could be misleading and perhaps dangerous.Isolation distances are best determined by those trained abovethe operations level, taking into account the amount of materialinvolved, the weather conditions and the specificcircumstances of the release.

    III. How to Use The Specific Material Guides (ChemicalSpecific) Pages

    The SPECIFIC MATERIAL GUIDES (RED TAB ) provides detailedresponse information for 430 materials. These materials weresystematically selected based on their likelihood of beingencountered and the magnitude of the hazard they pose tothe first responder. An example of a specific material guideis shown in Figure 1 on page 4.

    The most widely accepted chemical name for the material is

    found in the top center of each page. Underneath the primaryname is the UN (United Nations) number or the NA (NorthAmerican) number. The UN number is commonly used formaterials in commerce and can be found on shipping papers.A few materials in this section do not have an assigned UNnumber. This may mean either that the material is notconsidered a hazard, or that it is not found in transport in asizeable amount. The shipping name of the material appearsdirectly under the chemical name. Finally, other less commonlyused names for the material are listed.

    In the upper right hand corner of the page are the DOTplacard(s)/label(s) assigned to the material when transportedwithin the United States. A complete list of current DOTplacards is found in Chart 10 on page 521. For a few materials,no specific DOT placard designation has been made in 49CFRand this area is left blank.

    In the upper left corner of the page is the NFPA 704 placardproviding summary information on acute health, fire andreactivity hazards plus any special concerns such as waterreactivity which apply to the material. An explanation of thenumber designations used in the NFPA placard taken from /NFPA 704 is found on page 550. The placard is commonlyfound on storage containers or is posted at fixed facilities.When posted on fixed facilities each designation representsthe worst hazard in that category within the building or facility.The placard is not found on materials in transport.

    NFPA 704 designations were taken, when available, from the1994 editions of NFPA 49 and NFPA 325. If the material wasnot rated in these references, values were determined andassigned from published data, where available, or were basedon reasonable estimation from data published on structurallysimilar materials, using the definitions for these designationsfrom NFPA 49. If the information in the placard is from theNFPA 49 or NFPA 325, the designation “NFPA” appears alongthe right edge of the placard. If there is no such designation,the content of the NFPA 704 placard was determined by theauthors.

    Below the list of synonyms may appear a section printed in redentitled WARNING. This section is vitally important. It providescrucial information about hazards that are immediately lifethreatening to the first responder. A WARNING indicates avery dangerous material because of the health risk or becauseof the extreme fire, explosion or reactivity risk(s). Most materialswill not have a WARNING section. This does not mean thatthey are not dangerous and cannot injure or kill, only that theyare not likely to do so if they are handled properly.

    Below the WARNING section is a section entitled HAZARDS .This section describes the physical, chemical, or toxicproperties of the material which create risks for the firstresponder. This section includes such things as explosionhazard, flammability risk and acute health hazards. Hazardsare arranged in the approximate order of their importance tothe first responder.

  • 3

    Next to the Hazards is a section entitled Description . Thissection describes what the material looks and smells like,along with some important information about the physicalproperties of the material, such as whether it floats or sinksin water or whether it is heavier or lighter than air (if it is agas). The information in this section may be useful in verifyingthe identity of a hazardous material and in anticipating someof its actions.

    In the middle of the page are sections entitled Awarenessand Operational Level Training Response andOperational Level Training Response . These sections listthe appropriate actions for the first responder trained to eachof these two levels of expertise. Not all of the statementslisted may be appropriate for every situation, but actions shouldnot be more aggressive than those listed. The most importantrecommendations are given first. Remember that these areinitial recommendations for the first responder. They may bemodified by the on-scene Hazmat Incident Commander.Awareness Level Response actions are all defensive innature. Operational Level Response actions are divided intotwo general situations, those involving releases of materialwithout an accompanying fire and those where a fire is involved,whether or not the material itself is burning. OperationalLevel Responders must remember that actions listed underAwareness and Operational Level Response should becompleted before beginning the more definitive OperationalLevel Response actions.

    At the bottom of the page is a First Aid section. Theserecommendations should be used in caring for victims whoare out of the Hot zone. Rescue of victims from within a Hotzone should only be performed by trained personnel wearingappropriate chemical resistant gear and is not generally a firstresponder action.

    Removal of hazardous material from the skin, eyes or clothingof a victim (decontamination) is usually the most importantfirst aid action that can be initiated. It should be performedonly by appropriately trained and equipped individuals. Rapidremoval of the material may be the difference between a minorinjury and a serious injury. The details of decontaminationtechniques are beyond the scope of this book. In general,using large quantities of water to rinse off materials is almostalways the first choice for decontamination in the field.Materials which are so toxic that first aid should not beperformed on contaminated victims because of the risk ofserious injury to the responder are clearly labeled. There arevery few antidotes for treating victims exposed to chemicalsand they are listed in this section for the benefit of hospitalpersonnel who may care for these victims. Other First Aidinformation is also provided.

    Finally, at the middle of the page below the first aid section isa CHEMICAL ABSTRACTS SERVICE REGISTRY NUMBER(CAS: _ _ _-_ _-_). This is a specific identifying number givento each chemical by the Chemical Abstract Service. Mixturesare usually not assigned CAS numbers. While not commonlyused in shipping, the CAS number may be found on containersand Material Safety Data Sheets (MSDS) and is used by many

    more detailed references as an indexing number. It is providedas another positive identifier and to allow quick reference toother data bases.

    IV. How to Use the Materials Summary Response Table

    The MATERIALS SUMMARY RESPONSE TABLE (YELLOW TAB)provides summary information on 1,422 additional materials.These materials are either less likely to be encountered bythe first responder. This table is arranged in alphabetic orderusing the most common chemical name of the material. Foreach material the UN number and DOT placard designationare provided, if available. NFPA designations are provided forall materials. In the case where NFPA designations were notavailable from NFPA 49 or 325, values were assigned by theauthors using NFPA 49 definitions along with available dataon the material or on structurally similar materials. NFPA 704designations taken from NFPA sources are shown in greenwhile the those assigned by the authors are in black.

  • 4

    Figure 1.

    Hazards:Odor is not a reliable indicator of the presence of toxicamounts of vaporMay react with itself without warning with explosiveviolenceContainer may BLEVE or explode when exposed to fireVapors may travel long distances to ignition sources andflashbackVapors in confined areas (e.g., tanks, sewers, buildings)may explode when exposed to fireVapors are slightly lighter than air but will collect and stayin low areasCombustion products are less toxic than the material itself

    Awareness and Operational Level TrainingResponse:

    DO NOT ATTEMPT RESCUE!Stay upwind and uphillDetermine the extent of the problemBACK OFF! - Isolate a wide area around the release orfire, deny entry and call for expert helpRemove all ignition sourcesFor container exposed to fire evacuate the area in alldirections because of the risk of BLEVE or explosionEvacuate the immediate area and downwind for a largereleaseNotify local health and fire officials and pollution controlagenciesIf material or contaminated runoff enters waterways, notifydownstream users of potentially contaminated water

    HYDROGEN CYANIDE(STABILIZED)

    UN 1051Shipping Name: Hydrogen cyanide, stabilized with less than 3 percent waterOther Names: AC Hydrocyanic acid solution

    HCN Prussic acidHydrocyanic acid

    CAS: 74-90-8

    WARNING! POISON! BREATHING THE VAPORS OR SKIN CONTACT CAN KILL YOU!Firefighting gear (including SCBA) provides NO protection. If exposure occurs, remove andisolate gear immediately and thoroughly decontaminate personnelEXTREMELY FLAMMABLE!

    Description:Colorless liquid that boils at 78˚ FSweet odor like bitter almonds; many people cannot smell itDissolves slowly in water but is soluble in waterExtremely flammableVapors are slightly lighter than air but will collect and stayin low areasTransported in red and white candy striped containersProduces large amounts of vaporFreezes at 8˚ F

    Operational Level Training Response:RELEASE, NO FIRE:

    Stop the release if it can be done safely from a distanceUse large amounts of water well away from the material todisperse vapors - contain runoffVentilate confined area if it can be done without placingpersonnel at risk

    FIRE:If material is on fire and conditions permit, DO NOTEXTINGUISH; combustion products are less toxic then theoriginal material. Cool exposures using unattended monitors.Specially trained personnel operating from a safe distancecan fight fires using alcohol resistant (AFFF) foam or drychemical if available in sufficient amounts. Under favorableconditions, experienced crews can use coordinated fogstreams to sweep the flames off the surface of the burningliquid. Do not direct straight streams into the liquid.Cool exposed containers with large quantities of waterfrom unattended equipment or remove intact containers ifit can be done safelyIf cooling streams are ineffective (unvented containerdistorts, bulges or shows any other signs of expanding),withdraw immediately to a secure location

    First Aid:DO NOT ATTEMPT RESCUE!The contaminated victim poses a health risk to the responderDecontaminate the victim from a safe distance with a stream of water; have the victim remove clothing if possible; provideBasic Life Support/CPR as neededDecontaminate the victim as follows:

    Inhalation - remove the victim to fresh air and give oxygen if availableSkin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for15 minutesEye - rinse eyes with large volumes of water or saline for 15 minutesSwallowed - do not make the victim vomit

    Victims should be examined by a physician as soon as possibleToxic effects may be delayedDo NOT perform direct mouth to mouth resuscitation; use a bag/mask apparatusNote to physician: can produce cyanide toxicity; if symptoms indicate, initial treatment includes the cyanide antidote kit

    44

    2NF

    PA

  • 5

    1. North American Emergency Response Guide, 1996Edition, U.S. Department of Transportation, Washington,DC.

    2. The Merck Index, 12th Edition (1996), Merck and Co.,Inc., Rahway, NJ.

    3. Emergency Handling of Hazardous Materials in SurfaceTransportation (1992), American Association ofRailroads, Washington, DC.

    4. Emergency Action Guide (1995), American Associationof Railroads, Washington, DC.

    5. Chemical Hazards Response Information System,Hazardous Chemical Data Manual, Vol. II (1993), U.S.Department of Transportation, U.S. Coast Guard,Washington, DC.

    6. NIOSH Pocket Guide to Chemical Hazards (1990), U.S.Department of Health and Human Services,Washington, DC.

    7. L. Bretherick, Bretherick’s Handbook of ReactiveChemical Hazards, 4th Edition (1990), Butterworth-Heinemann, Ltd., Boston, MA.

    8. Tomes Plus (1995), Micromedex, Denver, CO.

    9. CAMEO (1990), U.S. Environmental Protection Agency,National Oceanic and Atmospheric Administration,National Safety Council, Washington, DC.

    10. Fire Protection Guide to Hazardous Materials; 10thEdition (1991), National Fire Protection Association,Quincy, MA.

    11. Responding to Hazardous Materials Incidents, ANSI/NFPA 473 (1992), National Fire Protective Association,Quincy, MA.

    12. Responders to Hazardous Materials Incidents, ANSI/NFPA 472 (1992), National Fire Protective Association,Quincy, MA.

    13. Identification of the Fire Hazards of Materials, ANSI/NFPA 704 (1990), National Fire Protective Association,Quincy, MA.

    14. Field Guide to Tank Care Identification (1992),Association of American Railroads, Washington, D.C.

    15. Hazardous Materials Response Handbook, 2nd Edition(1993), National Fire Protective Association, Quincy,MA.

    16. R.J. Lewis, SAX’s Dangerous Properties of IndustrialMaterials, 8th Edition (1992), Van Nostrand Reinhold,New York, NY.

    17. R.J. Lewis, Hazardous Chemicals Desk Reference, 3rdEdition (1993), Van Nostrand Reinhold, New York, NY.

    18. A Guide to Fire Hazard Properties of Flammable Liquids,Gases and Volatile Solids, ANSI/NFPA 325 (1994),National Fire Protective Association, Quincy, MA.

    19. Hazardous Chemicals Data, ANSI/NFPA 49 (1994),National Fire Protective Association, Quincy, MA.

    20. Code of Federal Regulations 49 Transportation (1996),Office of Federal Register National Archives and RecordsAdministration, Washington, DC.

    21. Chemical/Biological Incident Handbook, (1995), TheDirector of Central Intelligence Committee on Terrorism/Community Counterterrorism Board.

    References

  • Alphabetical Material Name Index

    Click on letter to go to section

    A

    B

    C

    D

    E

    F

    G

    H

    I

    J

    K

    L

    M

    N

    O

    P

    Q

    R

    S

    T

    U

    V

    W

    X

    Y

    Z

  • 8

    Alphabetical Material IndexA-150 .......................................................................... 476AA ................................................................................ 67AC .............................................................................. 285Acetaldehyde ................................................................ 51Acetaldehyde cyanohydrin ......................................... 305Acetaldehyde ethylacetal .............................................. 50Acetamide ................................................................... 482Acetene ...................................................................... 243Acetic acid .................................................................... 52Acetic acid anhydride ................................................... 53Acetic acid bromide ...................................................... 57Acetic acid chloride ...................................................... 58Acetic acid dimethylamide .......................................... 206Acetic acid, ethinyl ester ............................................. 468Acetic acid, methyl ester ............................................. 319Acetic acid, n-butyl ester ............................................ 113Acetic acid, n-propyl ester .......................................... 408Acetic acid, vinyl ester ................................................ 468Acetic aldehyde ............................................................ 51Acetic anhydride ........................................................... 53Acetic chloride .............................................................. 58Acetic ester ................................................................ 230Acetic ether ................................................................ 230Acetoacetone .............................................................. 381Acetocyanohydrin ......................................................... 55Acetocyanohydrin ....................................................... 305Acetol ........................................................................... 50Acetone ........................................................................ 54Acetone cyanohydrin .................................................... 55Acetone thiosemicarbazide ......................................... 482Acetonitrile .................................................................... 56

    Acetophenone ............................................................. 4821-Acetoxyethylene ...................................................... 4681-Acetoxypropane ....................................................... 408Acetyl acetone ............................................................ 381Acetyl anhydride ........................................................... 53Acetyl bromide .............................................................. 57Acetyl chloride .............................................................. 58Acetyl ether .................................................................. 53Acetyl ketene .............................................................. 204Acetyl oxide .................................................................. 53Acetyl peroxide solution .............................................. 4822-Acetylaminofluorene ................................................ 482Acetylene ...................................................................... 59Acetylene dichloride ................................................... 186Acetylene tetrachloride ............................................... 438Acetylene trichloride ................................................... 454Acetylenogen .............................................................. 128Acetylsilicon trichloride ................................................. 72Acid ............................................................................ 155Acridine ...................................................................... 482Acroleic acid ................................................................. 62Acrolein ........................................................................ 60Acrylaldehyde .............................................................. 60Acrylamide.................................................................... 61

    Acrylic acid .................................................................. 62Acrylic acid chloride ..................................................... 64Acrylic acid, butyl ester .............................................. 114Acrylic acid, ethyl ester .............................................. 231Acrylic acid, methyl ester ........................................... 321Acrylic amide ................................................................ 61Acrylonitrile ................................................................... 63Acryloyl chloride ........................................................... 64Acrylyl chloride ............................................................. 64Actidione..................................................................... 171Actidone ..................................................................... 171Adipic acid .................................................................. 482Adipic acid dinitrile ....................................................... 65Adiponitrile .................................................................... 65Agent T ....................................................................... 482Alachlor ...................................................................... 482Alcide ......................................................................... 140Aldicarb ........................................................................ 66Aldifen ........................................................................ 223Aldrin .......................................................................... 482Algrain ........................................................................ 232Alkyl benzene sulfonic acids ....................................... 482Allene .......................................................................... 482Allene-methyl acetylene mixture .................................. 320Allethrin ....................................................................... 482Allyl acetate ................................................................ 482Allyl al ........................................................................... 67Allyl alcohol ................................................................... 67Allyl aldehyde ................................................................ 60Allyl bromide ................................................................. 69Allyl chloride ................................................................. 70Allyl chlorocarbonate ..................................................... 71Ally chloroformate ......................................................... 71Allyl ether .................................................................... 482Allyl ethyl ether ............................................................ 482Allyl iodide .................................................................. 482Allyl isothiocyanate ..................................................... 482Allylamine ..................................................................... 68Allylic alcohol ................................................................ 67Allyltrichlorosilane ......................................................... 72alpha-Bromotoluene ...................................................... 95alpha-Chlorobenzaldehyde............................................ 94alpha-Chloropropionic ................................................. 155alpha-Chlorotoluene ...................................................... 96alpha-Cumene hydroperoxide ..................................... 161alpha-Endosulfan ........................................................ 497alpha-Methacrylic acid ................................................ 313alpha-Methyl benzyl alcohol ........................................ 505alpha-Methyl styrene ................................................... 299alpha-Naphthylamine................................................... 507alpha-Pinene............................................................... 398alpha-Tolunitrile ........................................................... 385Aluminum (dust) .......................................................... 482Aluminum borohydride ................................................ 482Aluminum chloride ...................................................... 482Aluminum fluoride ....................................................... 482

  • 9

    Alphabetical Material IndexAluminum nitrate ......................................................... 482Aluminum oxide ........................................................... 482Aluminum phosphide ................................................... 482Aluminum sulfate ......................................................... 482Aluminum, triisobutyl ................................................... 459AMFO ........................................................................... 84Am-fol ........................................................................... 74Aminic acid ................................................................. 2691-Amino-2,4-dinitrobenzene ........................................ 2202-Amino-2-methyl-1-propanol ..................................... 4821-Amino-2-propanol .................................................... 2984-Aminoazobenzene ................................................... 482Aminobenzene .............................................................. 851-Aminobutane............................................................ 1164-Aminobutyl diethoxymethyl silane ............................. 482Aminocyclohexane ...................................................... 172Aminoethane ............................................................... 2332-Aminoethanol ........................................................... 2292-(2-Aminoethoxy)ethanol ........................................... 482Aminoethyl ethanol amine ........................................... 482Aminoethylethandiamine ............................................. 198Aminohexahydrobenzene ............................................ 1722-Aminoisobutane ....................................................... 117Aminomethane ............................................................ 323Aminomethane ............................................................ 3244-Amino-N,N-dimethylaniline ....................................... 2152-Aminopentane .......................................................... 195Aminophen.................................................................... 852-Aminopropane ......................................................... 3003-Aminopropene ........................................................... 684-Aminopropiophenone ............................................... 4823-Aminopropylene ......................................................... 684-Aminopyridine ........................................................... 73Aminopyridines ............................................................. 73Aminotoluene .............................................................. 451Amiton ........................................................................ 482Amiton oxalate ............................................................. 482Amitrole ...................................................................... 482Ammonia ....................................................................... 74Ammonia monohydrate ................................................. 77Ammonia solution .......................................................... 77Ammonia water ............................................................. 77Ammonia, anhydrous .................................................... 74Ammonium acetate ..................................................... 483Ammonium aminoformate ............................................. 76Ammonium benzoate ..................................................... 75Ammonium bicarbonate .............................................. 483Ammonium bifluoride .................................................. 483Ammonium bisulfite ..................................................... 483Ammonium bromide .................................................... 483Ammonium carbamate .................................................. 76Ammonium carbonate ................................................. 483Ammonium chloride .................................................... 483Ammonium chromate .................................................. 483Ammonium citrate ....................................................... 483Ammonium dichromate ............................................... 483

    Ammonium fluoborate ................................................. 483Ammonium fluoride ..................................................... 483Ammonium formate ..................................................... 483Ammonium gluconate .................................................. 483Ammonium hydroxide ................................................... 77Ammonium hypophosphite .......................................... 483Ammonium iodide ....................................................... 483Ammonium lactate ....................................................... 483Ammonium lauryl sulfate ............................................. 483Ammonium molybdate ................................................. 483Ammonium monosulfide ................................................ 79Ammonium nitrate ....................................................... 483Ammonium nitrate fertilizers ........................................ 483Ammonium nitrate: fuel oil ............................................. 84Ammonium nitrate-phosphate mixture ......................... 483Ammonium nitrate-sulfate mixture ............................... 483Ammonium nitrate-urea solution .................................. 483Ammonium oleate ....................................................... 483Ammonium oxalate ...................................................... 483Ammonium pentaborate .............................................. 483Ammonium perchlorate .................................................. 78Ammonium perchlorate high explosive .......................... 78Ammonium perchlorate oxidizer .................................... 78Ammonium permanganate .......................................... 483Ammonium persulfate ................................................. 483Ammonium phosphate ................................................. 483Ammonium picrate (wet) ............................................. 483Ammonium rhodanate ................................................... 81Ammonium silicofluoride ............................................. 483Ammonium stearate .................................................... 483Ammonium sulfamate .................................................. 483Ammonium sulfate ....................................................... 483Ammonium sulfide ......................................................... 79Ammonium sulfite .......................................................... 80Ammonium sulfocyanide ............................................... 81Ammonium sulphite ....................................................... 80Ammonium tartrate ...................................................... 483Ammonium thiocyanate ................................................. 81Ammonium thiosulfate ................................................. 483AMS ............................................................................ 299Amthio .......................................................................... 81Amyl alcohol ................................................................. 82Amyl methyl ketone ..................................................... 325Amyl phthalate ............................................................ 484Amylol ........................................................................... 82Amyltricholorsilane ........................................................ 83AN/FO ........................................................................... 84Anhydrol ..................................................................... 232Anhydrous ammonia ..................................................... 74Anhydrous ethanol ...................................................... 232Anhydrous hydrobromic acid ...................................... 283Anhydrous hydrofluoric acid ....................................... 286Aniline ........................................................................... 85Aniline oil ...................................................................... 85Anisole ........................................................................ 484Anisoyl chloride .......................................................... 484

  • 10

    Alphabetical Material IndexAnone ......................................................................... 170Ansul ether 121 ........................................................... 205Anthion ....................................................................... 401Anthracene ................................................................. 484Antimony (powder) ...................................................... 484Antimony pentachloride .............................................. 484Antimony pentafluoride ............................................... 484Antimony potassium tartrate ........................................ 484Antimony tribromide .................................................... 484Antimony trichloride .................................................... 484Antimony trifluoride ..................................................... 484Antimony trioxide ........................................................ 484ANTU .......................................................................... 484Aqua fortis .................................................................. 361Aqueous ammonia ........................................................ 77Aramite ....................................................................... 484Arctic .......................................................................... 331Argon .......................................................................... 484Arsenic ....................................................................... 484Arsenic acid ............................................................... 484Arsenic butter ............................................................... 86Arsenic chloride ............................................................ 86Arsenic dichloroethane ............................................... 241Arsenic disulfide ......................................................... 484Arsenic hydride ............................................................ 87Arsenic pentoxide ....................................................... 484Arsenic trichloride ......................................................... 86Arsenic trihydride ......................................................... 87Arsenic trioxide ........................................................... 484Arsenic trisulfide ......................................................... 484Arsenous chloride ......................................................... 86Arsenous trichloride ...................................................... 86Arsine ........................................................................... 87Asbestos ..................................................................... 484Asphalt ........................................................................ 484Asphalt blending stocks: roofers flux ........................... 484Asphalt blending stocks: straight run residue .............. 484asym-Dimethylhydrazine ............................................. 214Atrazine ...................................................................... 484Auramine .................................................................... 484Avitrol ............................................................................ 73Azabenzene ................................................................ 415Azacyclohexane .......................................................... 399Azacyclopropane ........................................................ 253Azide .......................................................................... 419Azine .......................................................................... 415Azirane ....................................................................... 253Aziridine ..................................................................... 253Azophos ...................................................................... 349Barium ........................................................................ 485Barium carbonate ....................................................... 485Barium chlorate .......................................................... 485Barium cyanide .......................................................... 485Barium nitrate ............................................................. 485Barium perchlorate ..................................................... 485Barium permanganate ................................................. 485

    Barium peroxide .......................................................... 485BCME ......................................................................... 188BD .............................................................................. 111Benomyl ...................................................................... 485Bentazon..................................................................... 485Benzal chloride ............................................................. 98Benzaldehyde ............................................................... 88Benzalmalonoitrile ....................................................... 145Benzamide .................................................................... 89Benzenamine ................................................................ 85Benzene ....................................................................... 90Benzene arsonic acid ................................................. 485Benzene chloride ........................................................ 147Benzene fluoride ......................................................... 264Benzene hexachloride ................................................. 485Benzene methylal .......................................................... 88Benzene nitro ............................................................. 263Benzene phosphorous dichloride ................................ 388Benzene sulfonyl chloride ........................................... 485Benzeneacetonitrile .................................................... 385Benzenecarbonal .......................................................... 88Benzenecarbonyl chloride ............................................ 94Benzenehexahydride .................................................. 169Benzenenitrile ............................................................... 91Benzenethiol ............................................................... 387Benzenol ..................................................................... 384Benzidine .................................................................... 485Benzin ........................................................................ 258Benzo (A) anthracene ................................................. 485Benzo (A) pyrene ....................................................... 485Benzo (B) fluoranthene ............................................... 485Benzo (GHI) perylene ................................................. 485Benzoic acid ............................................................... 485Benzoic acid amide ...................................................... 89Benzoic aldehyde ......................................................... 88Benzoic trichloride ........................................................ 93Benzol ........................................................................... 90Benzonitrile ................................................................... 91Benzophenone ............................................................ 485Benzoquinone ............................................................... 921,4-Benzoquinone ......................................................... 92Benzotrichloride ............................................................ 93Benzoyl chloride ........................................................... 94Benzoyl peroxide ........................................................ 485Benzoylamide ............................................................... 89Benzyl acetate ............................................................ 485Benzyl alcohol ............................................................. 485Benzyl amine .............................................................. 485Benzyl bromide ............................................................. 95Benzyl carbonyl chloride ............................................... 97Benzyl chloride ............................................................. 96Benzyl chlorocarbonate ................................................ 97Benzyl chloroformate .................................................... 97Benzyl cyanide ........................................................... 385Benzyl dichloride .......................................................... 98Benzyl dimethyl amine ................................................ 485

  • 11

    Alphabetical Material IndexBenzyl dimethyl octadecyl ammonium chloride ........... 485Benzyl ether ................................................................ 178Benzyl iodide .............................................................. 485Benzyl nitrile ............................................................... 385Benzyl oxide ............................................................... 178Benzyl trichloride .......................................................... 93Benzyl trimethyl ammonium chloride ........................... 485Benzyl violet ................................................................ 485Benzylene chloride ....................................................... 98Benzylidene chloride ..................................................... 98Beryllium ..................................................................... 485Beryllium chloride ....................................................... 485Beryllium fluoride ........................................................ 485Beryllium nitrate .......................................................... 485Beryllium oxide ............................................................ 485Beryllium sulfate .......................................................... 485beta-Butyrolactone ...................................................... 487beta-Chloroprene ........................................................ 154beta-Endosulfan .......................................................... 497beta-Methyl acrolein .................................................... 160beta-Propiolactone ...................................................... 405BHA ............................................................................ 485BHC, alpha- ................................................................ 485BHC, beta- .................................................................. 485BHC, delta- ................................................................. 486BHC, gamma- ............................................................. 486BIC ............................................................................. 121Bicylcopentadiene ...................................................... 192Biethylene ................................................................... 111Bimethyl ...................................................................... 228Biocide ......................................................................... 60Biogas ........................................................................ 315Bioxirane..................................................................... 193Biphenyl ...................................................................... 486Bis (chloromethyl) ketone ........................................... 181Bis-(2-aminoethyl) amine ............................................ 198Bis-(2-chloro-1-methyl ethyl) ether .............................. 486Bis-(2-chloroethoxy) methane ..................................... 486Bis-(2-chloroethyl) ether ............................................. 184Bis-(2-chloroethyl) methylamine .................................. 311Bis-(2-chloroethyl) sulfide ............................................ 99Bis-(2-chloroisopropyl) ether ...................................... 486Bis-(2-ethyl hexyl) adipate .......................................... 486Bis-(2-ethyl hexyl) phthalate ........................................ 486Bis-(chloromethyl) ether ............................................. 188Bismuth oxychloride .................................................... 486Bis-O,O-diethylpyrophosphoric anhydride .................. 441Bisphenol A ................................................................ 486Bisphenol A diglycidyl ether ........................................ 486Bisulfite ....................................................................... 430Bithionol ...................................................................... 486Bitoscanate ................................................................. 486Bivinyl ......................................................................... 111B-K Liquid ................................................................... 422Black powder, compressed ......................................... 486Black powder, granular ............................................... 486

    Black powder, pellets .................................................. 486Bladan ........................................................................ 377Bladan-M .................................................................... 349Blasting oil .................................................................. 366Bleach ........................................................................ 422Blue oil .......................................................................... 85Bolero ......................................................................... 486Bondolane A ............................................................... 427Bonoform .................................................................... 438Boric acid ................................................................... 486Borneol ....................................................................... 486Boroethane ................................................................. 179Boron bromide ............................................................ 100Boron chloride ............................................................ 101Boron fluoride ............................................................. 102Boron hydride ............................................................. 177Boron hydride ............................................................. 179Boron hydride ............................................................. 378Boron tribromide ......................................................... 100Boron trichloride ......................................................... 101Boron trifluoride .......................................................... 102Boron trifluoride: dimethyl etherate ............................. 486Bottled gas .................................................................. 308BPL ............................................................................ 405Brimstone ................................................................... 428Brom ........................................................................... 103Bromacil ..................................................................... 486Bromadiolone .............................................................. 486Bromide fluoride ......................................................... 104Bromine ...................................................................... 103Bromine chloride ......................................................... 486Bromine cyanide ......................................................... 164Bromine fluoride ......................................................... 105Bromine pentafluoride ................................................. 104Bromine trifluoride ...................................................... 1053-Bromo-1-propene ...................................................... 691-Bromo-3-methylbutane............................................. 486Bromoacetic acid ........................................................ 486Bromoacetone ............................................................ 486Bromoacetyl bromide .................................................. 106Bromoallylene ............................................................... 69Bromobenzene............................................................ 1071-Bromobutane ........................................................... 1082-Bromobutane ........................................................... 486Bromochloromethane .................................................. 486Bromocyan ................................................................. 164Bromoethanoyl bromide .............................................. 106Bromoethene .............................................................. 4692-Bromoethyl ethyl ether ............................................. 486Bromoethylene ............................................................ 469Bromoform .................................................................. 486Bromofume ................................................................. 247Brom-O-Gas ............................................................... 326Bromomethane............................................................ 3262-Bromopentane ......................................................... 4864-Bromophenyl phenyl ether ....................................... 486

  • 12

    Alphabetical Material IndexBromophenylmethane ................................................... 951-Bromopropane ......................................................... 4862-Bromopropane ......................................................... 1093-Bromopropylene ........................................................ 69Bromopropyne ............................................................ 1103-Bromopropyne ......................................................... 110Bromotrifluoroethylene ................................................ 486Bromotrifluoromethane ................................................ 486Brucine ....................................................................... 487Butadiene ................................................................... 1111,3-Butadiene ............................................................. 111Butadiene diepoxide .................................................... 193Butadiene dioxide ....................................................... 193Butal ........................................................................... 125Butaldehyde ................................................................ 125Butanal ........................................................................ 125Butane ........................................................................ 112Butane nitrile ............................................................... 126Butanedione ................................................................ 487Butanethiol .................................................................. 1221-Butanethiol ............................................................... 1222-Butanone ................................................................. 338Butanoyl chloride ........................................................ 1273-Buten-2-one ............................................................. 3562-Butenal .................................................................... 160Butene ........................................................................ 1181-Butene oxide ............................................................ 1191,4-Butenediol ............................................................. 4873-Buteno-beta-lactone ................................................. 2041-Butyl acetate ............................................................ 113Butyl acid phosphate ................................................... 487Butyl acrylate .............................................................. 114Butyl alcohol ............................................................... 115Butyl aldehyde ............................................................ 125Butyl benzyl phthalate ................................................. 487Butyl bromide .............................................................. 108Butyl butyrate .............................................................. 487Butyl chloride .............................................................. 148Butyl ethanoate ........................................................... 113Butyl ether .................................................................. 487Butyl ethylene ............................................................. 277Butyl isocyanate ......................................................... 121Butyl isovalerate .......................................................... 487Butyl mercaptan .......................................................... 122Butyl methyl ether ....................................................... 487Butyl nitrite .................................................................. 487Butyl toluene ............................................................... 487Butyl, decyl, cetyl-eicosyl methacrylate ...................... 487Butyl-2-propenoate ..................................................... 114Butylacetic acid .......................................................... 129Butylacetone ............................................................... 325Butylamine .................................................................. 116Butylated hydroxyanisole ............................................ 487Butylene ...................................................................... 1181,2-Butylene oxide ...................................................... 1191-Butylene oxide ......................................................... 119

    2,3-Butylene oxide ...................................................... 487Butylethylamine ........................................................... 236Butylsilicon trichloride ................................................. 123Butyltrichlorosilane ...................................................... 1232-Butyne-1,4-diol ........................................................ 124Butynediol ................................................................... 1241,4-Butynediol ............................................................. 1242-Butynediol ................................................................ 124Butyral ........................................................................ 125Butyraldehyde ............................................................. 125Butyric acid chloride ................................................... 127Butyric acid nitrile ....................................................... 126Butyric acid, ethyl ester .............................................. 237Butyric acid, methyl ester ........................................... 330Butyric aldehyde ......................................................... 125Butyric chloride .......................................................... 127Butyronitrile ................................................................ 126Butyryl chloride ........................................................... 127BZCF ............................................................................ 97C.I. acid blue 9, diammonium salt ............................... 490C.I. acid blue 9, disodium salt ..................................... 490C.I. acid green 3 ......................................................... 490C.I. basic green 4 ....................................................... 490C.I. basic red 1 ........................................................... 490C.I. disperse yellow 3 ................................................. 490C.I. food red 15 .......................................................... 490C.I. food red 5 ............................................................ 490C.I. solvent orange 7 ................................................... 490C.I. solvent yellow 14 .................................................. 490C.I. solvent yellow 3 .................................................... 490C.I. vat yellow 4 .......................................................... 490Cacodylic acid ............................................................ 487Cadmium acetate ........................................................ 487Cadmium bromide ....................................................... 487Cadmium chloride ....................................................... 487Cadmium fluoroborate ................................................. 487Cadmium nitrate .......................................................... 487Cadmium oxide ........................................................... 487Cadmium stearate ....................................................... 487Cadmium sulfate ......................................................... 487Cadmium(powder) ...................................................... 487CADOXTHB................................................................. 120CAF ............................................................................ 144Calcium ...................................................................... 488Calcium acetylide ....................................................... 128Calcium arsenite ......................................................... 488Calcium carbide .......................................................... 128Calcium chlorate ......................................................... 488Calcium chloride ......................................................... 488Calcium chromate ....................................................... 488Calcium cyanide ......................................................... 488Calcium fluoride .......................................................... 488Calcium hydride .......................................................... 489Calcium hydroxide ...................................................... 488Calcium hypochlorite .................................................. 488Calcium nitrate ............................................................ 488

  • 13

    Alphabetical Material IndexCalcium oxide ............................................................. 488Calcium peroxide ........................................................ 488Calcium phosphate ..................................................... 488Calcium phosphide ..................................................... 489Calcium resinate ......................................................... 488Camphene .................................................................. 488Camphor oil ................................................................ 488Cantharidin ................................................................. 488CAP ............................................................................ 144Caproic acid ............................................................... 129Caprolactam ............................................................... 488Capronic acid ............................................................. 129Caprylene ................................................................... 373Capsicum ................................................................... 488Capsine ...................................................................... 222Captan ........................................................................ 488Carbachol ................................................................... 130Carbachol chloride ...................................................... 130Carbacholin ................................................................ 130Carbacholine dichloride .............................................. 130Carbacryl ...................................................................... 63Carbamic acid, ammonium salt ..................................... 76Carbamide peroxide .................................................... 466Carbamiotin ................................................................ 130Carbamoyl dimethyl chloride ....................................... 209Carbamyl ...................................................................... 66Carbaryl (solid) ........................................................... 488Carbide ....................................................................... 128Carbinol ...................................................................... 318Carbofuran ................................................................. 131Carbolic acid .............................................................. 384Carbolic oil .................................................................. 488Carbon bisulfide .......................................................... 133Carbon chloride .......................................................... 135Carbon dichloride oxide .............................................. 390Carbon difluoride ........................................................ 136Carbon dioxide ............................................................ 132Carbon disulfide .......................................................... 133Carbon disulphide ....................................................... 133Carbon monoxide ........................................................ 134Carbon nitride ............................................................. 163Carbon oxide .............................................................. 134Carbon oxide sulfide ................................................... 137Carbon oxychloride ..................................................... 390Carbon oxyfluoride ...................................................... 136Carbon oxysulfide ....................................................... 137Carbon sulfide ............................................................ 133Carbon tet ................................................................... 135Carbon tetrachloride ................................................... 135Carbona ...................................................................... 135Carbonic acid anhydride ............................................ 132Carbonic acid gas ...................................................... 132Carbonic acid, diethyl ester ........................................ 197Carbonic anhydride .................................................... 132Carbonic difluoride oxide ............................................ 136Carbonic ether ............................................................ 197

    Carbonic oxide ............................................................ 134Carbonochloride acid, ethyl ester ............................... 240Carbonyl chloride ....................................................... 390Carbonyl fluoride ........................................................ 136Carbonyl sulfide .......................................................... 137Carene........................................................................ 488Casing head gasoline ................................................. 272Castor oil, edible ......................................................... 488Caswell No 805 ........................................................... 424Catechol ..................................................................... 488Caustic potash solution ............................................... 488Caustic soda ............................................................... 421Caustic soda, solution ................................................. 421Cellon ......................................................................... 438Certox ......................................................................... 424Cesium ....................................................................... 489CHA ............................................................................ 172Chloral ........................................................................ 138Chlorallylene ................................................................. 70Chloramben ................................................................ 488Chlorbisan .................................................................. 488Chlordane, flammable liquid ........................................ 488Chlordecone ............................................................... 488Chlorex ....................................................................... 184Chlorfenvinfos ............................................................. 488Chloride of phosphorus ............................................... 396Chlorine ...................................................................... 139Chlorine cyanide ......................................................... 165Chlorine dioxide .......................................................... 140Chlorine dioxide hydrate ............................................. 140Chlorine dioxide hydrate (frozen) ................................ 140Chlorine fluoride ......................................................... 141Chlorine monoxide ...................................................... 489Chlorine pentafluoride ................................................. 489Chlorine peroxide ........................................................ 140Chlorine sulfide ........................................................... 429Chlorine trifluoride ...................................................... 141Chlormephos............................................................... 489Chlormequat chloride .................................................. 489

    2-Chlorobenzylidine malononitrile............................... 145Chloro methyl sulfane ................................................. 316Chloro(chloromethoxy) methane ................................. 1882-Chloro-1,3-butadiene ............................................... 1542-Chloro-1-ethanol ...................................................... 2444-Chloro-1-methylbenzene .......................................... 1581-Chloro-1-propene .................................................... 4891-Chloro-2,3-epoxypropane ........................................ 2271-Chloro-2-cyanoethane ............................................. 1561-Chloro-2-nitrobenzene ............................................. 1511-Chloro-4-methylbenzene .......................................... 15810-Chloro-5,10-dihydrophenarsazine (DM) ................ 489Chloroacetaldehyde .................................................... 1422-Chloroacetaldehyde ................................................. 142Chloroacetaldehyde monomer .................................... 142Chloroacetaphenone ................................................... 144

  • 14

    Alphabetical Material IndexChloroacetic acid ........................................................ 489Chloroacetic acid chloride .......................................... 146Chloroacetic acid, ethyl ester ..................................... 239Chloroacetic acid, methyl ester ................................... 332Chloroacetic chloride .................................................. 146Chloroacetone, stabilized ............................................ 489Chloroacetonitrile ........................................................ 143Chloroacetyl chloride .................................................. 1462-Chloroacrylic acid, methyl ester .............................. 333Chloroaldehyde ........................................................... 142Chlorobenzene............................................................ 147Chlorobenzilate ........................................................... 4892-Chlorobuta -1,3-diene .............................................. 154Chlorobutadiene .......................................................... 154Chlorobutane .............................................................. 1481-Chlorobutane ........................................................... 1482-Chlorobutane ........................................................... 489Chlorocarbonic acid, ethyl ester ................................. 240Chlorocyan ................................................................. 165Chlorocyanogen ......................................................... 165Chlorodibromomethane ............................................... 489Chlorodifluoromethane ................................................ 489Chloroethanal .............................................................. 1422-Chloroethanal .......................................................... 142Chloroethane .............................................................. 238Chloroethane .............................................................. 4532-Chloroethane sulfonyl chloride ................................. 489Chloroethanenitrile ...................................................... 143Chloroethanol .............................................................. 2442-Chloroethanol .......................................................... 244Chloroethene .............................................................. 4702-Chloroethyl chlorocarbonate .................................... 1492-Chloroethyl vinyl ether ............................................. 489Chloroethylene ............................................................ 470Chloroform .................................................................. 150Chloroformate ............................................................. 149Chloroformic acid, isopropyl ester .............................. 302Chloroformyl chloride .................................................. 390Chlorohydrins ............................................................. 489Chloromethane............................................................ 331(Chloromethyl) benzene ............................................... 96Chloromethyl cyanide ................................................. 143Chloromethyl ether ...................................................... 188Chloromethyl ethyl ether ............................................. 489Chloromethyl methyl ether ........................................... 4891-(Chloromethyl)-4-nitrobenzene ................................ 489Chloromethyloxirane ................................................... 2272-Chloronaphthalene ................................................... 489Chloronitrobenzene ..................................................... 151Chlorophenyl methane .................................................. 964-Chlorophenyl phenyl ether ....................................... 4892-Chlorophenylthiourea ............................................... 152Chloropicrin ................................................................ 153Chloropicrin: methyl chloride ...................................... 489Chloropivaloyl chloride ................................................ 489Chloroprene ................................................................ 154

    1-Chloropropane ......................................................... 4892-Chloropropane ......................................................... 4893-Chloropropanenitrile ................................................ 156Chloropropene .............................................................. 702-Chloropropene ......................................................... 4893-Chloropropene ........................................................... 70Chloropropham ........................................................... 4892-Chloropropionic acid ............................................... 1553-Chloropropionitrile ................................................... 1563-Chloropropyl octyl sulfoxide ..................................... 489Chloropropylene ........................................................... 701-Chloropropylene ...................................................... 489Chloropropylene oxide ................................................ 227Chlorosulfane .............................................................. 432Chlorosulfonic acid ..................................................... 157Chlorosulfuric acid ...................................................... 157Chlorothalonil .............................................................. 489Chlorotoluene .............................................................. 1583-Chlorotoluene .......................................................... 4894-Chlorotoluene .......................................................... 158Chlorotrifluoride .......................................................... 141Chlorotrifluoroethane................................................... 489Chlorotrifluoroethylene ................................................ 458Chlorotrifluoromethane ................................................ 490Chlorotrimethylsilane ................................................... 462Chlorovinylarsine dichloride ........................................ 306Chlorovinyldichloroarsine ............................................ 306Chloroxuron ................................................................ 490Chlorpyrifos ................................................................ 159Chlorthiophos .............................................................. 490Chlorylen .................................................................... 453Choline chloride carbamate ........................................ 130

    Chromic acetate ......................................................... 490Chromic acid .............................................................. 490Chromic anhydride ..................................................... 490Chromic sulfate ........................................................... 490Chromium (dust) ......................................................... 490Chromium oxychloride ................................................ 490Chromous chloride ...................................................... 490Chrysene .................................................................... 490Cinnamenol ................................................................. 425cis-Butene .................................................................. 118Citric acid ................................................................... 490Citrus red No. 2 .......................................................... 490CK .............................................................................. 165Clorox ......................................................................... 422CN .............................................................................. 144CO .............................................................................. 134Coal gas ..................................................................... 490Coal naphtha ................................................................. 90Coal oil ........................................................................ 304Cobalt ......................................................................... 490Cobalt acetate ............................................................. 490Cobalt bromide............................................................ 490Cobalt carbonyl ........................................................... 490

  • 15

    Alphabetical Material IndexCobalt chloride ............................................................ 490Cobalt fluoride ............................................................. 490Cobalt formate ............................................................ 490Cobalt nitrate ...........