Download - OCTOBER 30, 2017 - Hanford Site
October 30, 2017 Mr. Scot Fitzgerald CH2MHill Plateau Remediation Company MSIN R3-50 CHPRC PO Box 1600 Richland, Washington 99352 Re: CHPRC SAF F14-021 Work Order: 434194 SDG: GEL434194 Dear Mr. Fitzgerald:
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for thesample(s) we received on October 04, 2017. This original data report has been prepared and reviewed inaccordance with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needson time every time. We trust that you will find everything in order and to your satisfaction. If you have anyquestions, please do not hesitate to call me at (843) 556-8171, ext. 4505.
Sincerely, PM_SIGN_HERE Heather Shaffer Project Manager
Purchase Order: 300416 - 7H Chain of Custody: F14-021-155, F14-021-156, F14-021-157 and F14-021-158 Enclosures
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Table of Contents
Case Narrative......................................................................................1
Chain of Custody and Supporting Documentation...............................9
Data Review Qualifier Definitions.....................................................15
Laboratory Certifications....................................................................17
General Chem Analysis......................................................................19
Case Narrative............................................................................20
Sample Data Summary...............................................................24
Quality Control Summary..........................................................28
Radiological Analysis.........................................................................32
Case Narrative............................................................................33
Sample Data Summary...............................................................41
Quality Control Summary..........................................................60
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Case Narrative
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General Narrativefor
CH2MHill Plateau Remediation CompanyCHPRC SAF F14-021
SDG: GEL434194
October 30, 2017 Laboratory Identification: GEL Laboratories LLC 2040 Savage Road Charleston, South Carolina 29407 (843) 556-8171
Summary
Sample receipt
The sample(s) arrived at GEL Laboratories, LLC, Charleston, South Carolina on October 04, 2017, for analysis.The samples were delivered with proper chain of custody documentation and signatures. All sample containersarrived without any visible signs of tampering or breakage. There are no additional comments concerning samplereceipt.
Items of Note All efforts were made by the lab to meet any short hold times. Samples that were analyzed outsideof the initial hold time but still within 2X hold time will be noted in the lab case narrative.
Sample Identification The laboratory received the following samples:
LaboratoryIdentification
SampleDescription
434194001 B3F968434194002 B3F969434194003 B3F970434194004 B3F971
Case Narrative
Sample analyses were conducted using methodology as outlined in GEL Laboratories, LLC (GEL) StandardOperating Procedures. Any technical or administrative problems during analysis, data review, and reduction arecontained in the analytical case narratives in the enclosed data package.
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Data Package
The enclosed data package contains the following sections: General Narrative, Chain of Custody and SupportingDocumentation, and data from the following fractions: General Chemistry and Radiochemistry.
We certify that this package is in compliance with the SOW, both technically and for completeness, including afull description of, explanation of, and corrective actions for, any and all deviations, from either the analysesrequested or the case narrative requested. Release of the data contained in this hard copy data package has beenauthorized by the Laboratory Analytical Manager (or designee) and the laboratory’s client servicesrepresentative as verified by their signatures on this report.
PM_SIGN_HERE Heather Shaffer Project Manager
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Technical Case Narrative
CH2MHill Plateau Remediation Company (CPRC) SDG #: GEL434194
Work Order #: 434194
General Chemistry Ion Chromatography All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Quality Control (QC) Information Laboratory Control Sample Duplicate (LCSD) An LCSD was used in place of matrix QC due to the high activity of the sample matrix (ALARA). 434194001(B3F968). Miscellaneous Information Manual Integrations Sample 434194001 (B3F968) were manually integrated to correctly position the baseline as set in the calibrationstandards. Specific Conductivity There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in thisreport met the acceptance criteria specified in the analytical methods and procedures for initial calibration,continuing calibration, instrument controls and process controls where applicable.
Radiochemistry AMCMISO_EIE_PLATE_AEA: (HIGH RAD) All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Quality Control (QC) Information RDL Met The blank (See Below) did not meet the detection limit due to keeping the blank volume consistent with theother sample aliquots.
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Sample Analyte Value
1203889239 (MB)Americium-241 Result 13.7 < MDA 37.3 > RDL 1 pCi/L
Technical Information Recounts The Laboratory Control Sample 1203889241 (LCS) was recounted due to low recovery and then again due to adetector error. The third count is reported. PUISO_PLATE_AEA:COMMON (HIGH RAD) All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Quality Control (QC) Information RDL Met The blank (See Below) did not meet the detection limit due to keeping the blank volume consistent with theother sample aliquots.
Sample Analyte Value
1203889251 (MB)Plutonium-238 Result 12.5 < MDA 48.7 > RDL 1 pCi/L
Plutonium-239/240Result -4.72 < MDA 53.8 > RDL 1 pCi/L
Sample (See Below) did not meet the detection limit due to the small sample aliquot used. The aliquot wasreduced due to the high activity of other isotopes and in attempt to minimize interference.
Sample Analyte Value
434194004 (B3F971)Plutonium-238 Result 10.5 < MDA 50 > RDL 1 pCi/L
Plutonium-239/240Result 59.8 < MDA 63.4 > RDL 1 pCi/L
Technical Information Recounts Sample 1203889253 (LCS) was recounted due to high recovery and then recounted twice more due to peakshifts. The fourth count is reported. Miscellaneous Information Manual Integration Manual integration of alpha spectroscopy spectra 1203889253 (LCS) was performed to fully separate counts inRegions of Interest which would have been biased. Additional Comments The tracer peak centroid for sample 1203889253 (LCS) is greater than 50 keV from the expected library energy
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value for the tracer; however, the tracer yield requirement was met and the tracer peak is within the tracer regionof interest. UISO_PLATE_AEA:COMMON (HIGH RAD) All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Quality Control (QC) Information RDL Met The blank (See Below) did not meet the detection limit due to keeping the blank volume consistent with theother sample aliquots.
Sample Analyte Value
1203889258 (MB)Uranium-233/234Result 36.8 < MDA 72.8 > RDL 1 pCi/L
Uranium-235/236Result 39.2 < MDA 61.7 > RDL 1 pCi/L
Uranium-238 Result 15.9 < MDA 43.2 > RDL 1 pCi/L
Samples (See Below) did not meet the detection limits due to the small sample aliquots used. The aliquots werereduced due to the high activity of other isotopes and in attempt to minimize interference.
Sample Analyte Value
1203889259 (B3F969DUP)Uranium-235/236Result 3.18 < MDA 69.4 > RDL 1 pCi/L
434194003 (B3F970) Uranium-235/236Result 19.6 < MDA 53.3 > RDL 1 pCi/L
434194004 (B3F971) Uranium-233/234Result -11.5 < MDA 82.8 > RDL 1 pCi/L
Uranium-235/236Result 0 < MDA 36.6 > RDL 1 pCi/L
Uranium-238 Result 7.51 < MDA 47.4 > RDL 1 pCi/L
Miscellaneous Information Additional Comments The tracer peak centroid for sample 434194002 (B3F969) is greater than 50 keV from the expected libraryenergy value for the tracer; however, the tracer yield requirement was met and the tracer peak is within the tracerregion of interest. GAMMA_GS:COMMON (Cs137) HIGH RAD All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions.
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Quality Control (QC) Information RDL Met The blank (See Below) did not meet the detection limit due to keeping the blank volume consistent with theother sample aliquots.
Sample Analyte Value
1203889225 (MB)Cesium-137Result 1.59 < MDA 30.7 > RDL 15 pCi/L
SRTOT_SEP_PRECIP_GPC: COMMON (HIGH RAD) All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Quality Control (QC) Information RDL Met The blank (See Below) did not meet the detection limit due to keeping the blank volume consistent with theother sample aliquots.
Sample Analyte Value
1203889261 (MB)Total StrontiumResult -82.9 < MDA 373 > RDL 2 pCi/L
Technical Information Recounts Sample 434194004 (B3F971) was recounted to confirm the result. The recount is reported. TRITIUM_DIST_LSC: COMMON (HIGH RAD) All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Quality Control (QC) Information RDL Met The blank (See Below) did not meet the detection limit due to keeping the blank volume consistent with theother sample aliquots.
Sample Analyte Value
1203889265 (MB)Tritium Result -14700 < MDA 32700 > RDL 100 pCi/L
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Laboratory Comp for preserved & unpres analysis There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in thisreport met the acceptance criteria specified in the analytical methods and procedures for initial calibration,continuing calibration, instrument controls and process controls where applicable. Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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Chain of Custody andSupporting
Documentation
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Data Review QualifierDefinitions
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GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 (843) 556−8171
Report Date: 26−OCT−17
Project Specific Qualifier Definitions for GEL Client Code: CPRC
Page 1 of 1
Qualifier Qualifier Definition Department Fraction
U
J
P
C
B
E
A
X
N
*
>
Z
B
D
E
M
o
S
T
W
B
Y
+
B
C
C
<
UX
Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equal to the IDL/MDL (asappropriate).Value is estimatedAroclor target analyte with greater than 25% difference between column analyses.
Analyte has been confirmed by GC/MS analysis
The analyte was detected in both the associated QC blank and in the sample.
Concentration exceeds the calibration range of the instrument
The TIC is a suspected aldol−condensation product
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Spike Sample recovery is outside control limits.
Duplicate analysis not within control limits
Result greater than quantifiable range or greater than upper limit of the analysis range
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equal to the IDL/MDL (asappropriate).Results are reported from a diluted aliquot of sample.
Reported value is estimated due to interferences. See comment in narrative.
Duplicate precision not met.
Analyte failed to recover within LCS limits (0rganics only)
Reported value determined by the Method of Standard Additions (MSA)
Spike and/or spike duplicate sample recovery is outside control limits.
Post−digestion spike recovery for GFAA out of control limit. Sample absorbency < 50% of spike absorbency.
The associated QC sample blank has a result >= 2X the MDA and, after corrections, result is >= MDA for this sample
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Correlation coefficient for Method of Standard Additions (MSA) is < 0.995
The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equal to the IDL/MDL (asappropriate).Target analyte was detected in the sample and the associated blank. The associated blank concentration is >= EQL or is > 5% of themeasured concentration and/or decision level for associated samples.Target analyte was detected in the sample and the associated blank. The associated blank concentration is >= EQL or is > 5% of themeasured concentration and/or decision level for associated samples.Sample is below the EPA guidance level for Reactive Releasable Cyanide and/or Reactive Releasable Sulfide
Gamma Spectroscopy−−Uncertain identification
Organics
Organics
Organics
Organics
Organics
Organics
Inorganics
General Chemistry
Inorganics
Inorganics
Inorganics
Organics
Inorganics
Organics
Inorganics
Radiological
Inorganics
General Chemistry
Inorganics
General Chemistry
General Chemistry
Radiological
Pesticide
Semi−Volatile
Metals
Metals
Metals
Metals
Page
16
of 6
4
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LaboratoryCertifications
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State CertificationAlaska
ArkansasCLIA
California Colorado
ConnecticutDelaware
DoD ELAP/ ISO17025 A2LAFlorida NELAP
Foreign Soils PermitGeorgia
Georgia SDWAHawaii
Idaho ChemistryIdaho Radiochemistry
Illinois NELAPIndiana
Kansas NELAPKentucky SDWA
Kentucky WastewaterLouisiana NELAPLouisiana SDWA
MarylandMassachusetts
MichiganMississippiNebraskaNevada
New Hampshire NELAPNew Jersey NELAP
New MexicoNew York NELAP
North CarolinaNorth Carolina SDWA
North DakotaOklahoma
Pennsylvania NELAPPuerto Rico
S.Carolina RadchemSouth Carolina Chemistry
TennesseeTexas NELAPUtah NELAP
VermontVirginia NELAP
WashingtonWest Virginia
UST−011088−0651
42D09040462940
SC00012PH−0169SC000122567.01E87156
P330−15−00283, P330−15−00253SC00012
967SC00012SC00012SC00012200029
C−SC−01E−10332
9012990129
03046 (AI33904)LA170010
270M−SC012
9976SC00012
NE−OS−26−13SC000122018−1
205415SC002
SC0001211501233
45709R−1589904
68−00485SC000121012000210120001TN 02934
T104704235−17−12SC000122017−24
VT87156460202C780
997404
List of current GEL Certifications as of 30 October 2017
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General Chem Analysis
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Case Narrative
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General Chemistry Technical Case Narrative
CH2MHill Plateau Remediation Company (CPRC) SDG #: GEL434194
Work Order #: 434194
Product: Ion Chromatography Analytical Method: 9056_ANIONS_IC Analytical Procedure: GL-GC-E-086 REV# 25 Analytical Batch: 1706568 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 434194001 B3F968 1203889097 Method Blank (MB) 1203889098 Laboratory Control Sample (LCS) 1203889099 Laboratory Control Sample Duplicate (LCSD) The samples in this SDG were analyzed on an "as received" basis. Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods and proceduresfor initial calibration, continuing calibration, instrument controls and process controls where applicable, with thefollowing exceptions. Quality Control (QC) Information Laboratory Control Sample Duplicate (LCSD) An LCSD was used in place of matrix QC due to the high activity of the sample matrix (ALARA). 434194001(B3F968). Miscellaneous Information Manual Integrations Sample 434194001 (B3F968) were manually integrated to correctly position the baseline as set in the calibrationstandards.
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Product: Specific Conductivity Analytical Method: EPA 120.1 Analytical Procedure: GL-GC-E-009 REV# 15 Analytical Batch: 1711208 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 434194001 B3F968 434194003 B3F970 434194004 B3F971 1203900828 Laboratory Control Sample (LCS) 1203900829 434194001(B3F968) Sample Duplicate (DUP) The samples in this SDG were analyzed on an "as received" basis. Data Summary: There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this reportmet the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuingcalibration, instrument controls and process controls where applicable. Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
CPRC001 CH2MHill Plateau Remediation Company
Client SDG: GEL434194 GEL Work Order: 434194
GEL requires all analytical data to be verified by a qualified data reviewer. In addition, all CLP-like deliverablesreceive a third level review of the fractional data package.
The following data validator verified the information presented in this data report:
The Qualifiers in this report are defined as follows:B The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equalto the IDL/MDL (as appropriate).U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and totalanalytical error.
forQualifier Definition Report
Signature: Name:
Date: Title:23 OCT 2017
Kristen Mizzell
Analyst I
Review/Validation
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Sample Data Summary
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Certificate of Analysis
GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
Report Date: October 23, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDL PF
Ion Chromatography
Titration and Ion Analysis
1706568
1711208
1839
1415
ug/Lug/Lug/Lug/Lug/Lug/Lug/L
umhos/cm
10/04/17
10/20/17
MXL2
VH1
250200500250250500500
1.00
1111111
1
Mr. Scot FitzgeraldContact:
CH2MHill Plateau Remediation CompanyCompany :MSIN R3-50 CHPRC
Richland, Washington 99352
Address :
CHPRC SAF F14-021Project:
434194001WATER03-OCT-17 07:3004-OCT-17
B3F968 CPRC0F14021Project:CPRC001Client ID:
Client
Sample ID:
Receive Date:
PO Box 1600
Client Sample ID:
Matrix:Collect Date:
Collector:
67.067.033.033.033.067.0133
1.00
1
2
UBUBUUU
BromideChlorideFluorideNitrate-NNitrite-NPhosphorus in phosphateSulfate
Conductivity
9056_ANIONS_IC: COMMON + (add-on) "As Received"
120.1_CONDUCTIVITY: COMMON "As Received"
67.089.833.081.633.067.0133
1.24
The following Analytical Methods were performed:
12
Method Description 9056_ANIONS_ICEPA 120.1
Analyst Comments
Notes:
Lc/LC: Critical Level PF: Prep Factor RL: Reporting LimitSQL: Sample Quantitation Limit
Column headers are defined as follows: DF: Dilution FactorDL: Detection LimitMDA: Minimum Detectable Activity MDC: Minimum Detectable Concentration
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Certificate of Analysis
GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
Report Date: October 23, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDL PF
Titration and Ion Analysis
17112081422umhos/cm 10/20/17VH11.00 1
Mr. Scot FitzgeraldContact:
CH2MHill Plateau Remediation CompanyCompany :MSIN R3-50 CHPRC
Richland, Washington 99352
Address :
CHPRC SAF F14-021Project:
434194003WATER03-OCT-17 07:3004-OCT-17
B3F970 CPRC0F14021Project:CPRC001Client ID:
Client
Sample ID:
Receive Date:
PO Box 1600
Client Sample ID:
Matrix:Collect Date:
Collector:
1.00 1Conductivity120.1_CONDUCTIVITY: COMMON "As Received"
1.47
The following Analytical Methods were performed:
1Method Description
EPA 120.1Analyst Comments
Notes:
Lc/LC: Critical Level PF: Prep Factor RL: Reporting LimitSQL: Sample Quantitation Limit
Column headers are defined as follows: DF: Dilution FactorDL: Detection LimitMDA: Minimum Detectable Activity MDC: Minimum Detectable Concentration
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Certificate of Analysis
GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
Report Date: October 23, 2017
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDL PF
Titration and Ion Analysis
17112081422umhos/cm 10/20/17VH11.00 1
Mr. Scot FitzgeraldContact:
CH2MHill Plateau Remediation CompanyCompany :MSIN R3-50 CHPRC
Richland, Washington 99352
Address :
CHPRC SAF F14-021Project:
434194004WATER03-OCT-17 07:3004-OCT-17
B3F971 CPRC0F14021Project:CPRC001Client ID:
Client
Sample ID:
Receive Date:
PO Box 1600
Client Sample ID:
Matrix:Collect Date:
Collector:
1.00 1Conductivity120.1_CONDUCTIVITY: COMMON "As Received"
1.90
The following Analytical Methods were performed:
1Method Description
EPA 120.1Analyst Comments
Notes:
Lc/LC: Critical Level PF: Prep Factor RL: Reporting LimitSQL: Sample Quantitation Limit
Column headers are defined as follows: DF: Dilution FactorDL: Detection LimitMDA: Minimum Detectable Activity MDC: Minimum Detectable Concentration
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Quality ControlSummary
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Ion Chromatography1706568Batch
Bromide
Chloride
Fluoride
Nitrate-N
Nitrite-N
Phosphorus in phosphate
Sulfate
Bromide
Chloride
Fluoride
Nitrate-N
Nitrite-N
Phosphorus in phosphate
Parmname
Mr. Scot FitzgeraldContact:
CH2MHill Plateau Remediation CompanyMSIN R3-50 CHPRC
Richland, Washington
October 23, 2017Report Date:
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Anlst Date Time
MXL2 10/04/17 17:42
10/04/17 18:10
QC
1240
4800
2530
2440
2470
1260
9870
1240
4830
2550
2450
2480
1280
NOM Sample Range
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
(0%-20%)
Qual
QC1203889098
QC1203889099
0.0324
0.565
0.476
0.45
0.166
1.26
REC%
98.8
96.1
101
97.6
98.8
101
98.7
98.9
96.6
102
98
99
102
1250
5000
2500
2500
2500
1250
10000
1250
5000
2500
2500
2500
1250
LCS
LCSD
434194Workorder:
PO Box 1600
RPD%
Page 1 of 3
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Ion Chromatography
Titration and Ion Analysis
1706568
1711208
Batch
Batch
Sulfate
Bromide
Chloride
Fluoride
Nitrate-N
Nitrite-N
Phosphorus in phosphate
Sulfate
Conductivity
Conductivity
Parmname Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
umhos/cm
umhos/cm
Anlst Date Time
MXL2
VH1
10/04/17 18:10
10/04/17 17:13
10/20/17 14:22
10/20/17 14:15
QC
9890
67.0
67.0
33.0
33.0
33.0
67.0
133
1.23
1400
NOM Sample
1.24
Range
(0%-20%)
(+/-1.00)
(80%-120%)
Qual
U
U
U
U
U
U
U
QC1203889097
QC1203900829 434194001
QC1203900828
The Qualifiers in this report are defined as follows:
0.17
0.81
REC%
98.9
99.3
10000
1410
MB
DUP
LCS
434194Workorder:
<
>
B
C
D
Sample is below the EPA guidance level for Reactive Releasable Cyanide and/or Reactive Releasable Sulfide
Result greater than quantifiable range or greater than upper limit of the analysis range
The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equal to the IDL/MDL (as appropriate).
Target analyte was detected in the sample and the associated blank. The associated blank concentration is >= EQL or is > 5% of the measuredconcentration and/or decision level for associated samples.Results are reported from a diluted aliquot of sample.
^
RPD%
Notes:
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QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOM Sample RangeQual REC%
434194Workorder:
N
U
X
Y
Z
Spike Sample recovery is outside control limits.
Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater thanfive times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- theRL is used to evaluate the DUP result.* Indicates that a Quality Control parameter was not within specifications.For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless qualified on the QC Summary.
RPD%
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Radiological Analysis
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Case Narrative
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Radiochemistry Technical Case Narrative
CH2MHill Plateau Remediation Company (CPRC) SDG #: GEL434194
Work Order #: 434194
Product: AMCMISO_EIE_PLATE_AEA: (HIGH RAD) Analytical Method: AMCMISO_EIE_PREC_AEA Analytical Procedure: GL-RAD-A-011 REV# 26 Analytical Batch: 1706632
The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 434194002 B3F969 434194003 B3F970 434194004 B3F971 1203889239 Method Blank (MB) 1203889240 434194002(B3F969) Sample Duplicate (DUP) 1203889241 Laboratory Control Sample (LCS) The samples in this SDG were analyzed on an "as received" basis.
Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Quality Control (QC) Information RDL Met The blank (See Below) did not meet the detection limit due to keeping the blank volume consistent with theother sample aliquots.
Sample Analyte Value
1203889239 (MB)Americium-241 Result 13.7 < MDA 37.3 > RDL 1 pCi/L
Technical Information Recounts The Laboratory Control Sample 1203889241 (LCS) was recounted due to low recovery and then again due to adetector error. The third count is reported. Product: PUISO_PLATE_AEA:COMMON (HIGH RAD) Analytical Method: PUISO_PRECIP_AEA
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Analytical Procedure: GL-RAD-A-011 REV# 26 Analytical Batch: 1706636
The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 434194002 B3F969 434194003 B3F970 434194004 B3F971 1203889251 Method Blank (MB) 1203889252 434194002(B3F969) Sample Duplicate (DUP) 1203889253 Laboratory Control Sample (LCS) The samples in this SDG were analyzed on an "as received" basis.
Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Quality Control (QC) Information RDL Met The blank (See Below) did not meet the detection limit due to keeping the blank volume consistent with theother sample aliquots.
Sample Analyte Value
1203889251 (MB)Plutonium-238 Result 12.5 < MDA 48.7 > RDL 1 pCi/L
Plutonium-239/240Result -4.72 < MDA 53.8 > RDL 1 pCi/L
Sample (See Below) did not meet the detection limit due to the small sample aliquot used. The aliquot wasreduced due to the high activity of other isotopes and in attempt to minimize interference.
Sample Analyte Value
434194004 (B3F971)Plutonium-238 Result 10.5 < MDA 50 > RDL 1 pCi/L
Plutonium-239/240Result 59.8 < MDA 63.4 > RDL 1 pCi/L
Technical Information Recounts Sample 1203889253 (LCS) was recounted due to high recovery and then recounted twice more due to peakshifts. The fourth count is reported. Miscellaneous Information Manual Integration Manual integration of alpha spectroscopy spectra 1203889253 (LCS) was performed to fully separate counts inRegions of Interest which would have been biased. Additional Comments
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The tracer peak centroid for sample 1203889253 (LCS) is greater than 50 keV from the expected library energyvalue for the tracer; however, the tracer yield requirement was met and the tracer peak is within the tracer regionof interest. Product: UISO_PLATE_AEA:COMMON (HIGH RAD) Analytical Method: UISO_IE_PRECIP_AEA Analytical Procedure: GL-RAD-A-011 REV# 26 Analytical Batch: 1706639
The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 434194002 B3F969 434194003 B3F970 434194004 B3F971 1203889258 Method Blank (MB) 1203889259 434194002(B3F969) Sample Duplicate (DUP) 1203889260 Laboratory Control Sample (LCS) The samples in this SDG were analyzed on an "as received" basis.
Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Quality Control (QC) Information RDL Met The blank (See Below) did not meet the detection limit due to keeping the blank volume consistent with theother sample aliquots.
Sample Analyte Value
1203889258 (MB)Uranium-233/234Result 36.8 < MDA 72.8 > RDL 1 pCi/L
Uranium-235/236Result 39.2 < MDA 61.7 > RDL 1 pCi/L
Uranium-238 Result 15.9 < MDA 43.2 > RDL 1 pCi/L
Samples (See Below) did not meet the detection limits due to the small sample aliquots used. The aliquots werereduced due to the high activity of other isotopes and in attempt to minimize interference.
Sample Analyte Value
1203889259 (B3F969DUP)Uranium-235/236Result 3.18 < MDA 69.4 > RDL 1 pCi/L
434194003 (B3F970) Uranium-235/236Result 19.6 < MDA 53.3 > RDL 1 pCi/L
434194004 (B3F971) Uranium-233/234Result -11.5 < MDA 82.8 > RDL 1 pCi/L
Uranium-235/236Result 0 < MDA 36.6 > RDL 1 pCi/L
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Uranium-238 Result 7.51 < MDA 47.4 > RDL 1 pCi/L
Miscellaneous Information Additional Comments The tracer peak centroid for sample 434194002 (B3F969) is greater than 50 keV from the expected libraryenergy value for the tracer; however, the tracer yield requirement was met and the tracer peak is within the tracerregion of interest. Product: GAMMA_GS:COMMON (Cs137) HIGH RAD Analytical Method: 901.1_GAMMA_GS Analytical Procedure: GL-RAD-A-013 REV# 27 Analytical Batch: 1706626
The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 434194002 B3F969 434194003 B3F970 434194004 B3F971 1203889225 Method Blank (MB) 1203889226 434194002(B3F969) Sample Duplicate (DUP) 1203889227 Laboratory Control Sample (LCS) The samples in this SDG were analyzed on an "as received" basis.
Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Quality Control (QC) Information RDL Met The blank (See Below) did not meet the detection limit due to keeping the blank volume consistent with theother sample aliquots.
Sample Analyte Value
1203889225 (MB)Cesium-137Result 1.59 < MDA 30.7 > RDL 15 pCi/L
Product: SRTOT_SEP_PRECIP_GPC: COMMON (HIGH RAD)
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Analytical Method: SRTOT_SEP_PRECIP_GPC Analytical Procedure: GL-RAD-A-004 REV# 19 Analytical Batch: 1706640
The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 434194002 B3F969 434194003 B3F970 434194004 B3F971 1203889261 Method Blank (MB) 1203889262 434194002(B3F969) Sample Duplicate (DUP) 1203889263 Laboratory Control Sample (LCS) The samples in this SDG were analyzed on an "as received" basis.
Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Quality Control (QC) Information RDL Met The blank (See Below) did not meet the detection limit due to keeping the blank volume consistent with theother sample aliquots.
Sample Analyte Value
1203889261 (MB)Total StrontiumResult -82.9 < MDA 373 > RDL 2 pCi/L
Technical Information Recounts Sample 434194004 (B3F971) was recounted to confirm the result. The recount is reported. Product: TRITIUM_DIST_LSC: COMMON (HIGH RAD) Analytical Method: TRITIUM_DIST_LSC Analytical Procedure: GL-RAD-A-002 REV# 22 Analytical Batch: 1706641
The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 434194001 B3F968 434194003 B3F970 434194004 B3F971 1203889265 Method Blank (MB) 1203889266 434194001(B3F968) Sample Duplicate (DUP)
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1203889267 434194001(B3F968) Matrix Spike (MS) 1203889268 Laboratory Control Sample (LCS) The samples in this SDG were analyzed on an "as received" basis.
Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods andprocedures for initial calibration, continuing calibration, instrument controls and process controls whereapplicable, with the following exceptions. Quality Control (QC) Information RDL Met The blank (See Below) did not meet the detection limit due to keeping the blank volume consistent with theother sample aliquots.
Sample Analyte Value
1203889265 (MB)Tritium Result -14700 < MDA 32700 > RDL 100 pCi/L
Product: Laboratory Comp for preserved & unpres analysis Composite Preparation Method: GL-RAD-A-026 Composite Preparation Procedure: GL-RAD-A-026 REV# 17 Composite Preparation Batch: 1706579
The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 434194003 B3F970 434194004 B3F971 The samples in this SDG were analyzed on an "as received" basis.
Data Summary: There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in thisreport met the acceptance criteria specified in the analytical methods and procedures for initial calibration,continuing calibration, instrument controls and process controls where applicable. Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
CPRC001 CH2MHill Plateau Remediation Company
Client SDG: GEL434194 GEL Work Order: 434194
GEL requires all analytical data to be verified by a qualified data reviewer. In addition, all CLP-like deliverablesreceive a third level review of the fractional data package.
The following data validator verified the information presented in this data report:
The Qualifiers in this report are defined as follows:U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and totalanalytical error.
forQualifier Definition Report
Signature: Name:
Date: Title:30 OCT 2017
Theresa Austin
Group Leader
Review/Validation
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Sample Data Summary
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GEL Laboratories LLC
Rad Certificate of Analysis
Sample Summary
Page 1 of 1
October 30, 2017Report Date:
SDG Number: GEL434194Lab Sample ID: 434194001 Matrix: WATER
Date Received: 10/04/2017 09:05Date Collected: 10/03/2017 07:30
Surrogate/Tracer recovery Recovery% Acceptable Limits
8.72E+05 1.79E+05 33200
Client: CPRC001 Project: CPRC0F14021
CAS No. Parmname ResultQual RDL
Method: TRITIUM_DIST_LSC GL-RAD-A-002Batch ID: 1706641Instrument: LSCYELLOW
15 min
SOP Ref:Run Date: 10/19/2017 09:13 Analyst: JXC5
1 mLAliquot:
Units
pCi/L
B3F968Client ID:
Prep Date: 10/18/2017 00:00
Result Nominal
1706641 EPA 906.0 Modified
"As Received"
Prep Method:
Prep Basis:
TPU MDC
Count Time:
Comments:
Prep Batch:T1706641.xlsData File:
Tritium10028-17-8 100
Units
+/-59600
Uncert
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The MDC is a sample specific MDC.
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GEL Laboratories LLC
Rad Certificate of Analysis
Sample Summary
Page 1 of 1
October 30, 2017Report Date:
SDG Number: GEL434194Lab Sample ID: 434194002 Matrix: WATER
Date Received: 10/04/2017 09:05Date Collected: 10/03/2017 07:30
Surrogate/Tracer recovery Recovery% Acceptable Limits
8.19E+05 71800 445
Client: CPRC001 Project: CPRC0F14021
CAS No. Parmname ResultQual RDL
Method: 901.1_GAMMA_GS GL-RAD-A-013Batch ID: 1706626Instrument: WELL
120 min
SOP Ref:Run Date: 10/13/2017 09:23 Analyst: JXC5
0.2 LAliquot:
Units
pCi/L
B3F969Client ID:
Prep Date: 10/09/2017 00:00
Result Nominal
1706626 EPA 901.1
"As Received"
Prep Method:
Prep Basis:
TPU MDC
Count Time:
Comments:
U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Prep Batch:G434194002.CNF;2 Data File:
Cesium-13710045-97-3 15.0
Units
+/-2820
Uncert
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The MDC is a sample specific MDC.
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GEL Laboratories LLC
Rad Certificate of Analysis
Sample Summary
Page 1 of 1
October 30, 2017Report Date:
SDG Number: GEL434194Lab Sample ID: 434194002 Matrix: WATER
Date Received: 10/04/2017 09:05Date Collected: 10/03/2017 07:30
Surrogate/Tracer recovery Recovery% Acceptable Limits
4990 718 51.9
Client: CPRC001 Project: CPRC0F14021
Curium-243/244 Tracer 105 (30%-105%)
CAS No. Parmname ResultQual RDL
Method: AMCMISO_EIE_PREC_AEA GL-RAD-A-011Batch ID: 1706632Instrument: 1066
240 min
SOP Ref:Run Date: 10/19/2017 13:33 Analyst: AXM6
0.001 LAliquot:
Units
pCi/L
B3F969Client ID:
Prep Date: 10/18/2017 00:00
Result Nominal
2640 2500 pCi/L
1706632 DOE EML HASL-300, Am-05
"As Received"
Prep Method:
Prep Basis:
TPU MDC
Count Time:
Comments:
U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Prep Batch:S0434194002_AM.1A.gcnfData File:
Americium-24114596-10-2 1.00
Units
+/-368
Uncert
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The MDC is a sample specific MDC.
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GEL Laboratories LLC
Rad Certificate of Analysis
Sample Summary
Page 1 of 1
October 30, 2017Report Date:
SDG Number: GEL434194Lab Sample ID: 434194002 Matrix: WATER
Date Received: 10/04/2017 09:05Date Collected: 10/03/2017 07:30
Surrogate/Tracer recovery Recovery% Acceptable Limits
861
5950
197
968
50.8
48.5
Client: CPRC001 Project: CPRC0F14021
Plutonium-236 Tracer 84.3 (30%-105%)
CAS No. Parmname ResultQual RDL
Method: PUISO_PRECIP_AEA GL-RAD-A-011Batch ID: 1706636Instrument: 1077
239.9998 min
SOP Ref:Run Date: 10/19/2017 13:33 Analyst: AXM6
0.001 LAliquot:
Units
pCi/L
pCi/L
B3F969Client ID:
Prep Date: 10/18/2017 00:00
Result Nominal
1130 1340 pCi/L
1706636 DOE EML HASL-300, Pu-11-
"As Received"
Prep Method:
Prep Basis:
TPU MDC
Count Time:
Comments:
U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Prep Batch:S0434194002_PU.1A.gcnfData File:
Plutonium-238
Plutonium-239/240
13981-16-3
OER-100-70
1.00
1.00
Units
+/-149
+/-388
Uncert
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The MDC is a sample specific MDC.
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GEL Laboratories LLC
Rad Certificate of Analysis
Sample Summary
Page 1 of 1
October 30, 2017Report Date:
SDG Number: GEL434194Lab Sample ID: 434194002 Matrix: WATER
Date Received: 10/04/2017 09:05Date Collected: 10/03/2017 07:30
Surrogate/Tracer recovery Recovery% Acceptable Limits
91.9
30.9
54.3
U
60.9
40.9
47.3
54.9
30.9
46.1
Client: CPRC001 Project: CPRC0F14021
Uranium-232 Tracer 91 (30%-105%)
CAS No. Parmname ResultQual RDL
Method: UISO_IE_PRECIP_AEA GL-RAD-A-011Batch ID: 1706639Instrument: 1150
240 min
SOP Ref:Run Date: 10/18/2017 21:26 Analyst: AXM6
0.001 LAliquot:
Units
pCi/L
pCi/L
pCi/L
B3F969Client ID:
Prep Date: 10/18/2017 00:00
Result Nominal
1890 2080 pCi/L
1706639 DOE EML HASL-300, U-02-R
"As Received"
Prep Method:
Prep Basis:
TPU MDC
Count Time:
Comments:
U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Prep Batch:S0434194002_UU.1A.gcnfData File:
Uranium-233/234
Uranium-235/236
Uranium-238
13968-55-3/13966-29-5
U-233/234
15117-96-1/13982-7
7440-61-1
1.00
1.00
1.00
Units
+/-59.5
+/-40.6
+/-46.7
Uncert
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The MDC is a sample specific MDC.
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GEL Laboratories LLC
Rad Certificate of Analysis
Sample Summary
Page 1 of 1
October 30, 2017Report Date:
SDG Number: GEL434194Lab Sample ID: 434194002 Matrix: WATER
Date Received: 10/04/2017 09:05Date Collected: 10/03/2017 07:30
Surrogate/Tracer recovery Recovery% Acceptable Limits
4.22E+05 97500 397
Client: CPRC001 Project: CPRC0F14021
Strontium Carrier 93 (40%-110%)
CAS No. Parmname ResultQual RDL
Method: SRTOT_SEP_PRECIP_GPC GL-RAD-A-004Batch ID: 1706640Instrument: PIC9B
60 min
SOP Ref:Run Date: 10/18/2017 17:19 Analyst: JXB7
1 mLAliquot:
Units
pCi/L
B3F969Client ID:
Prep Date: 10/18/2017 00:00
Result Nominal
7.30 7.85 mg
1706640 EPA 905.0 Modified/DOE RP50
"As Received"
Prep Method:
Prep Basis:
TPU MDC
Count Time:
Comments:
U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Prep Batch:S1706640r1.xlsData File:
Total StrontiumSR-RAD 2.00
Units
+/-5500
Uncert
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The MDC is a sample specific MDC.
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GEL Laboratories LLC
Rad Certificate of Analysis
Sample Summary
Page 1 of 1
October 30, 2017Report Date:
SDG Number: GEL434194Lab Sample ID: 434194003 Matrix: WATER
Date Received: 10/04/2017 09:05Date Collected: 10/03/2017 07:30
Surrogate/Tracer recovery Recovery% Acceptable Limits
1.20E+06 1.05E+05 496
Client: CPRC001 Project: CPRC0F14021
CAS No. Parmname ResultQual RDL
Method: 901.1_GAMMA_GS GL-RAD-A-013Batch ID: 1706626Instrument: WELL
120 min
SOP Ref:Run Date: 10/13/2017 16:56 Analyst: JXC5
0.2 LAliquot:
Units
pCi/L
B3F970Client ID:
Prep Date: 10/09/2017 00:00
Result Nominal
1706626 EPA 901.1
"As Received"
Prep Method:
Prep Basis:
TPU MDC
Count Time:
Comments:
U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Prep Batch:G434194003.CNF;1 Data File:
Cesium-13710045-97-3 15.0
Units
+/-3390
Uncert
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The MDC is a sample specific MDC.
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GEL Laboratories LLC
Rad Certificate of Analysis
Sample Summary
Page 1 of 1
October 30, 2017Report Date:
SDG Number: GEL434194Lab Sample ID: 434194003 Matrix: WATER
Date Received: 10/04/2017 09:05Date Collected: 10/03/2017 07:30
Surrogate/Tracer recovery Recovery% Acceptable Limits
7110 1010 46.6
Client: CPRC001 Project: CPRC0F14021
Curium-243/244 Tracer 99.5 (30%-105%)
CAS No. Parmname ResultQual RDL
Method: AMCMISO_EIE_PREC_AEA GL-RAD-A-011Batch ID: 1706632Instrument: 1255
240 min
SOP Ref:Run Date: 10/19/2017 09:31 Analyst: AXM6
0.001 LAliquot:
Units
pCi/L
B3F970Client ID:
Prep Date: 10/18/2017 00:00
Result Nominal
2490 2500 pCi/L
1706632 DOE EML HASL-300, Am-05
"As Received"
Prep Method:
Prep Basis:
TPU MDC
Count Time:
Comments:
U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Prep Batch:S0434194003_AM.1A.gcnfData File:
Americium-24114596-10-2 1.00
Units
+/-457
Uncert
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The MDC is a sample specific MDC.
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GEL Laboratories LLC
Rad Certificate of Analysis
Sample Summary
Page 1 of 1
October 30, 2017Report Date:
SDG Number: GEL434194Lab Sample ID: 434194003 Matrix: WATER
Date Received: 10/04/2017 09:05Date Collected: 10/03/2017 07:30
Surrogate/Tracer recovery Recovery% Acceptable Limits
1160
8400
257
1400
61.1
53.8
Client: CPRC001 Project: CPRC0F14021
Plutonium-236 Tracer 84.5 (30%-105%)
CAS No. Parmname ResultQual RDL
Method: PUISO_PRECIP_AEA GL-RAD-A-011Batch ID: 1706636Instrument: 1078
239.9998 min
SOP Ref:Run Date: 10/19/2017 13:33 Analyst: AXM6
0.001 LAliquot:
Units
pCi/L
pCi/L
B3F970Client ID:
Prep Date: 10/18/2017 00:00
Result Nominal
1130 1340 pCi/L
1706636 DOE EML HASL-300, Pu-11-
"As Received"
Prep Method:
Prep Basis:
TPU MDC
Count Time:
Comments:
U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Prep Batch:S0434194003_PU.1A.gcnfData File:
Plutonium-238
Plutonium-239/240
13981-16-3
OER-100-70
1.00
1.00
Units
+/-183
+/-485
Uncert
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The MDC is a sample specific MDC.
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GEL Laboratories LLC
Rad Certificate of Analysis
Sample Summary
Page 1 of 1
October 30, 2017Report Date:
SDG Number: GEL434194Lab Sample ID: 434194003 Matrix: WATER
Date Received: 10/04/2017 09:05Date Collected: 10/03/2017 07:30
Surrogate/Tracer recovery Recovery% Acceptable Limits
88.2
19.6
63.4
U
63.4
38.6
54.6
63.1
53.3
59.3
Client: CPRC001 Project: CPRC0F14021
Uranium-232 Tracer 84.4 (30%-105%)
CAS No. Parmname ResultQual RDL
Method: UISO_IE_PRECIP_AEA GL-RAD-A-011Batch ID: 1706639Instrument: 1113
240 min
SOP Ref:Run Date: 10/19/2017 10:25 Analyst: AXM6
0.001 LAliquot:
Units
pCi/L
pCi/L
pCi/L
B3F970Client ID:
Prep Date: 10/18/2017 00:00
Result Nominal
1760 2080 pCi/L
1706639 DOE EML HASL-300, U-02-R
"As Received"
Prep Method:
Prep Basis:
TPU MDC
Count Time:
Comments:
U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Prep Batch:S0434194003_UU.1B.gcnfData File:
Uranium-233/234
Uranium-235/236
Uranium-238
13968-55-3/13966-29-5
U-233/234
15117-96-1/13982-7
7440-61-1
1.00
1.00
1.00
Units
+/-62.0
+/-38.5
+/-53.8
Uncert
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The MDC is a sample specific MDC.
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GEL Laboratories LLC
Rad Certificate of Analysis
Sample Summary
Page 1 of 1
October 30, 2017Report Date:
SDG Number: GEL434194Lab Sample ID: 434194003 Matrix: WATER
Date Received: 10/04/2017 09:05Date Collected: 10/03/2017 07:30
Surrogate/Tracer recovery Recovery% Acceptable Limits
6.55E+05 1.51E+05 490
Client: CPRC001 Project: CPRC0F14021
Strontium Carrier 86.6 (40%-110%)
CAS No. Parmname ResultQual RDL
Method: SRTOT_SEP_PRECIP_GPC GL-RAD-A-004Batch ID: 1706640Instrument: PIC9C
60 min
SOP Ref:Run Date: 10/18/2017 17:19 Analyst: JXB7
1 mLAliquot:
Units
pCi/L
B3F970Client ID:
Prep Date: 10/18/2017 00:00
Result Nominal
6.80 7.85 mg
1706640 EPA 905.0 Modified/DOE RP50
"As Received"
Prep Method:
Prep Basis:
TPU MDC
Count Time:
Comments:
U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Prep Batch:S1706640r1.xlsData File:
Total StrontiumSR-RAD 2.00
Units
+/-7140
Uncert
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The MDC is a sample specific MDC.
Page 52 of 64
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GEL Laboratories LLC
Rad Certificate of Analysis
Sample Summary
Page 1 of 1
October 30, 2017Report Date:
SDG Number: GEL434194Lab Sample ID: 434194003 Matrix: WATER
Date Received: 10/04/2017 09:05Date Collected: 10/03/2017 07:30
Surrogate/Tracer recovery Recovery% Acceptable Limits
8.67E+05 1.78E+05 33100
Client: CPRC001 Project: CPRC0F14021
CAS No. Parmname ResultQual RDL
Method: TRITIUM_DIST_LSC GL-RAD-A-002Batch ID: 1706641Instrument: LSCYELLOW
15 min
SOP Ref:Run Date: 10/19/2017 09:29 Analyst: JXC5
1 mLAliquot:
Units
pCi/L
B3F970Client ID:
Prep Date: 10/18/2017 00:00
Result Nominal
1706641 EPA 906.0 Modified
"As Received"
Prep Method:
Prep Basis:
TPU MDC
Count Time:
Comments:
U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Prep Batch:T1706641.xlsData File:
Tritium10028-17-8 100
Units
+/-59300
Uncert
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The MDC is a sample specific MDC.
Page 53 of 64
OCTOBER 30, 2017
55 of 66
GEL Laboratories LLC
Rad Certificate of Analysis
Sample Summary
Page 1 of 1
October 30, 2017Report Date:
SDG Number: GEL434194Lab Sample ID: 434194004 Matrix: WATER
Date Received: 10/04/2017 09:05Date Collected: 10/03/2017 07:30
Surrogate/Tracer recovery Recovery% Acceptable Limits
1130 138 28.6
Client: CPRC001 Project: CPRC0F14021
CAS No. Parmname ResultQual RDL
Method: 901.1_GAMMA_GS GL-RAD-A-013Batch ID: 1706626Instrument: GAM08
90 min
SOP Ref:Run Date: 10/14/2017 09:57 Analyst: JXC5
0.2 LAliquot:
Units
pCi/L
B3F971Client ID:
Prep Date: 10/09/2017 00:00
Result Nominal
1706626 EPA 901.1
"As Received"
Prep Method:
Prep Basis:
TPU MDC
Count Time:
Comments:
U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Prep Batch:G434194004.CNF;1 Data File:
Cesium-13710045-97-3 15.0
Units
+/-99.8
Uncert
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The MDC is a sample specific MDC.
Page 54 of 64
OCTOBER 30, 2017
56 of 66
GEL Laboratories LLC
Rad Certificate of Analysis
Sample Summary
Page 1 of 1
October 30, 2017Report Date:
SDG Number: GEL434194Lab Sample ID: 434194004 Matrix: WATER
Date Received: 10/04/2017 09:05Date Collected: 10/03/2017 07:30
Surrogate/Tracer recovery Recovery% Acceptable Limits
68.2 47.7 39.7
Client: CPRC001 Project: CPRC0F14021
Curium-243/244 Tracer 103 (30%-105%)
CAS No. Parmname ResultQual RDL
Method: AMCMISO_EIE_PREC_AEA GL-RAD-A-011Batch ID: 1706632Instrument: 1256
240 min
SOP Ref:Run Date: 10/19/2017 09:31 Analyst: AXM6
0.001 LAliquot:
Units
pCi/L
B3F971Client ID:
Prep Date: 10/18/2017 00:00
Result Nominal
2570 2500 pCi/L
1706632 DOE EML HASL-300, Am-05
"As Received"
Prep Method:
Prep Basis:
TPU MDC
Count Time:
Comments:
U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Prep Batch:S0434194004_AM.1A.gcnfData File:
Americium-24114596-10-2 1.00
Units
+/-46.9
Uncert
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The MDC is a sample specific MDC.
Page 55 of 64
OCTOBER 30, 2017
57 of 66
GEL Laboratories LLC
Rad Certificate of Analysis
Sample Summary
Page 1 of 1
October 30, 2017Report Date:
SDG Number: GEL434194Lab Sample ID: 434194004 Matrix: WATER
Date Received: 10/04/2017 09:05Date Collected: 10/03/2017 07:30
Surrogate/Tracer recovery Recovery% Acceptable Limits
10.5
59.8
U
U
28.9
52.8
50.0
63.4
Client: CPRC001 Project: CPRC0F14021
Plutonium-236 Tracer 80 (30%-105%)
CAS No. Parmname ResultQual RDL
Method: PUISO_PRECIP_AEA GL-RAD-A-011Batch ID: 1706636Instrument: 1079
239.9998 min
SOP Ref:Run Date: 10/19/2017 13:33 Analyst: AXM6
0.001 LAliquot:
Units
pCi/L
pCi/L
B3F971Client ID:
Prep Date: 10/18/2017 00:00
Result Nominal
1070 1340 pCi/L
1706636 DOE EML HASL-300, Pu-11-
"As Received"
Prep Method:
Prep Basis:
TPU MDC
Count Time:
Comments:
U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Prep Batch:S0434194004_PU.1A.gcnfData File:
Plutonium-238
Plutonium-239/240
13981-16-3
OER-100-70
1.00
1.00
Units
+/-28.8
+/-51.8
Uncert
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The MDC is a sample specific MDC.
Page 56 of 64
OCTOBER 30, 2017
58 of 66
GEL Laboratories LLC
Rad Certificate of Analysis
Sample Summary
Page 1 of 1
October 30, 2017Report Date:
SDG Number: GEL434194Lab Sample ID: 434194004 Matrix: WATER
Date Received: 10/04/2017 09:05Date Collected: 10/03/2017 07:30
Surrogate/Tracer recovery Recovery% Acceptable Limits
-11.5
0.00
7.51
U
U
U
31.1
24.7
28.2
82.8
36.6
47.4
Client: CPRC001 Project: CPRC0F14021
Uranium-232 Tracer 87.2 (30%-105%)
CAS No. Parmname ResultQual RDL
Method: UISO_IE_PRECIP_AEA GL-RAD-A-011Batch ID: 1706639Instrument: 1152
240 min
SOP Ref:Run Date: 10/18/2017 21:26 Analyst: AXM6
0.001 LAliquot:
Units
pCi/L
pCi/L
pCi/L
B3F971Client ID:
Prep Date: 10/18/2017 00:00
Result Nominal
1810 2080 pCi/L
1706639 DOE EML HASL-300, U-02-R
"As Received"
Prep Method:
Prep Basis:
TPU MDC
Count Time:
Comments:
U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Prep Batch:S0434194004_UU.1A.gcnfData File:
Uranium-233/234
Uranium-235/236
Uranium-238
13968-55-3/13966-29-5
U-233/234
15117-96-1/13982-7
7440-61-1
1.00
1.00
1.00
Units
+/-31.1
+/-24.6
+/-28.2
Uncert
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The MDC is a sample specific MDC.
Page 57 of 64
OCTOBER 30, 2017
59 of 66
GEL Laboratories LLC
Rad Certificate of Analysis
Sample Summary
Page 1 of 1
October 30, 2017Report Date:
SDG Number: GEL434194Lab Sample ID: 434194004 Matrix: WATER
Date Received: 10/04/2017 09:05Date Collected: 10/03/2017 07:30
Surrogate/Tracer recovery Recovery% Acceptable Limits
1120 436 466
Client: CPRC001 Project: CPRC0F14021
Strontium Carrier 101 (40%-110%)
CAS No. Parmname ResultQual RDL
Method: SRTOT_SEP_PRECIP_GPC GL-RAD-A-004Batch ID: 1706640Instrument: LB4100E2
60 min
SOP Ref:Run Date: 10/19/2017 11:25 Analyst: JXB7
1 mLAliquot:
Units
pCi/L
B3F971Client ID:
Prep Date: 10/18/2017 00:00
Result Nominal
7.90 7.85 mg
1706640 EPA 905.0 Modified/DOE RP50
"As Received"
Prep Method:
Prep Basis:
TPU MDC
Count Time:
Comments:
U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Prep Batch:S1706640r1.xlsData File:
Total StrontiumSR-RAD 2.00
Units
+/-347
Uncert
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The MDC is a sample specific MDC.
Page 58 of 64
OCTOBER 30, 2017
60 of 66
GEL Laboratories LLC
Rad Certificate of Analysis
Sample Summary
Page 1 of 1
October 30, 2017Report Date:
SDG Number: GEL434194Lab Sample ID: 434194004 Matrix: WATER
Date Received: 10/04/2017 09:05Date Collected: 10/03/2017 07:30
Surrogate/Tracer recovery Recovery% Acceptable Limits
8.63E+05 1.77E+05 33900
Client: CPRC001 Project: CPRC0F14021
CAS No. Parmname ResultQual RDL
Method: TRITIUM_DIST_LSC GL-RAD-A-002Batch ID: 1706641Instrument: LSCYELLOW
15 min
SOP Ref:Run Date: 10/19/2017 09:45 Analyst: JXC5
1 mLAliquot:
Units
pCi/L
B3F971Client ID:
Prep Date: 10/18/2017 00:00
Result Nominal
1706641 EPA 906.0 Modified
"As Received"
Prep Method:
Prep Basis:
TPU MDC
Count Time:
Comments:
U Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Prep Batch:T1706641.xlsData File:
Tritium10028-17-8 100
Units
+/-60000
Uncert
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
The MDC is a sample specific MDC.
Page 59 of 64
OCTOBER 30, 2017
61 of 66
Quality ControlSummary
Page 60 of 64
OCTOBER 30, 2017
62 of 66
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
High Rad Testing1706626
1706632
1706636
Batch
Batch
Batch
Cesium-137
Cesium-137
Americium-241
Cobalt-60
Cesium-137
Americium-241
Curium-243/244 Tracer
Americium-241
Curium-243/244 Tracer
Americium-241
Curium-243/244 Tracer
Plutonium-238
Parmname
Mr. Scot FitzgeraldContact:
CH2MHill Plateau Remediation CompanyClient :MSIN R3-50 CHPRC
Richland, Washington
October 30, 2017Report Date:
Units
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Analyst Date Time
JXC5
AXM6
AXM6
10/14/17
10/13/17
10/14/17
10/19/17
10/19/17
10/23/17
10/19/17
09:57
19:12
09:58
09:31
09:31
10:39
13:33
QC
1.59
8.24E+05
3.10E+05
66400
1.03E+05
13.7
2420
5080
2540
2150
2270
12.5
NOM Sample
8.19E+05
4990
2640
Range
(80%-120%)
(80%-120%)
(80%-120%)
(30%-105%)
(30%-105%)
(80%-120%)
(30%-105%)
Qual
U
U
U
QC1203889225
QC1203889226 434194002
QC1203889227
QC1203889239
QC1203889240 434194002
QC1203889241
QC1203889251
99352
108
109
109
97
102
109
91
2.88E+05
60800
94900
2500
2500
1970
2500
MB
DUP
LCS
MB
DUP
LCS
MB
434194Workorder:
PO Box 1600
**
**
**
+/-2820
+/-368
+/-259
+/-15.4
+/-2800
+/-6290
+/-2000
+/-2110
+/-26.9
+/-272
+/-406
+/-283
+/-186
+/-199
+/-28.3
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
+/-71800
+/-718
+/-403
+/-15.4
+/-72300
+/-30500
+/-6750
+/-8850
+/-27.0
+/-420
+/-783
+/-435
+/-292
+/-329
1
2
RPD:
RPD:
(0%-20%)
(0%-20%)
0.0943
0.165
RER:
RER:
(0-2)
(0-2)
REC:
REC:
REC:
REC:
REC:
REC:
REC:
QC Criteria
Page 1 of 4
Page 61 of 64
OCTOBER 30, 2017
63 of 66
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
High Rad Testing1706636
1706639
Batch
Batch
Plutonium-239/240
Plutonium-236 Tracer
Plutonium-238
Plutonium-239/240
Plutonium-236 Tracer
Plutonium-238
Plutonium-239/240
Plutonium-236 Tracer
Uranium-233/234
Uranium-235/236
Uranium-238
Uranium-232 Tracer
Uranium-233/234
Uranium-235/236
Uranium-238
Parmname Units
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Analyst Date Time
AXM6
10/24/17
10/18/17
10/19/17
10:10
21:26
10:25
QC
-4.72
1070
751
5040
1310
26.5
2120
886
36.8
39.2
15.9
1660
94.5
3.18
45.9
NOM Sample
861
5950
1130
91.9
30.9
54.3
Range
(30%-105%)
(30%-105%)
(80%-120%)
(30%-105%)
(30%-105%)
Qual
U
U
U
U
U
U
QC1203889252 434194002
QC1203889253
QC1203889258
QC1203889259 434194002
80
98
108
67
80
1330
1340
1970
1330
2080
DUP
LCS
MB
DUP
434194Workorder:
**
**
**
**
U
+/-149
+/-388
+/-186
+/-59.5
+/-40.6
+/-46.7
+/-21.3
+/-189
+/-134
+/-339
+/-176
+/-29.0
+/-208
+/-171
+/-48.4
+/-49.6
+/-31.2
+/-272
+/-63.0
+/-33.2
+/-44.3
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
+/-197
+/-968
+/-273
+/-60.9
+/-40.9
+/-28.4
+/-21.4
+/-277
+/-171
+/-794
+/-260
+/-29.2
+/-363
+/-253
+/-48.7
+/-50.0
+/-31.3
+/-416
+/-64.5
+/-33.3
14
17
3
77
17
RPD:
RPD:
RPD:
RPD:
RPD:
(0%-20%)
(0%-20%)
(0% - 100%)
N/A
(0% - 100%)
0.826
1.44
0.0561
1.03
RER:
RER:
RER:
RER:
(0-2)
(0-2)
(0-2)
(0-2)
REC:
REC:
REC:
REC:
REC:
QC Criteria
Page 2 of 4
Page 62 of 64
OCTOBER 30, 2017
64 of 66
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
High Rad Testing1706639
1706640
1706641
Batch
Batch
Batch
Uranium-232 Tracer
Uranium-233/234
Uranium-235/236
Uranium-238
Uranium-232 Tracer
Total Strontium
Strontium Carrier
Total Strontium
Strontium Carrier
Total Strontium
Strontium Carrier
Tritium
Tritium
Tritium
Tritium
Parmname Units
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
mg
pCi/L
mg
pCi/L
mg
pCi/L
pCi/L
pCi/L
pCi/L
Analyst Date Time
JXB7
JXC5
10/18/17
10/18/17
10/18/17
10/19/17
10/19/17
10/19/17
10/19/17
21:26
17:19
17:19
10:02
10:18
10:34
10:50
QC
1890
2760
210
2840
1820
-82.9
7.30
4.17E+05
7.10
20700
7.70
-14700
8.06E+05
9.82E+05
1.02E+05
NOM Sample
1890
4.22E+05
7.30
8.72E+05
8.72E+05
Range
(30%-105%)
(80%-120%)
(30%-105%)
(40%-110%)
(40%-110%)
(80%-120%)
(40%-110%)
(75%-125%)
(80%-120%)
Qual
U
U
QC1203889260
QC1203889261
QC1203889262 434194002
QC1203889263
QC1203889265
QC1203889266 434194001
QC1203889267 434194001
QC1203889268
91
105
87
93
90
87
98
100
93
2080
2690
2080
7.85
7.85
23700
7.85
1.10E+05
1.10E+05
LCS
MB
DUP
LCS
MB
DUP
MS
LCS
434194Workorder:
**
**
**
**
**
+/-261
+/-5500
+/-59600
+/-59600
+/-274
+/-305
+/-95.5
+/-306
+/-265
+/-165
+/-5620
+/-1220
+/-16200
+/-57900
+/-63400
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
Uncert:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
TPU:
+/-47.3
+/-401
+/-97500
+/-1.79E+05
+/-1.79E+05
+/-44.9
+/-418
+/-504
+/-100
+/-514
+/-406
+/-165
+/-96200
+/-4930
+/-16200
+/-1.66E+05
+/-2.00E+05
1
8
RPD:
RPD:
(0%-20%)
(0%-20%)
0.251
0.0744
0.527
RER:
RER:
RER:
(0-2)
(0-2)
(0-2)
REC:
REC:
REC:
REC:
REC:
REC:
REC:
REC:
REC:
QC Criteria
Page 3 of 4
Page 63 of 64
OCTOBER 30, 2017
65 of 66
QC Summary
GEL LABORATORIES LLC2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
High Rad Testing1706641Batch
Parmname
Page 4 of 4
Units Analyst Date TimeQCNOM Sample RangeQual
The Qualifiers in this report are defined as follows:
434194Workorder:
<
>
B
B
C
D
N
U
UX
X
Y
Z
Sample is below the EPA guidance level for Reactive Releasable Cyanide and/or Reactive Releasable Sulfide
Result greater than quantifiable range or greater than upper limit of the analysis range
The analyte was detected at a value less than the contract required detection limit (RDL), but greater than or equal to the IDL/MDL (as appropriate).
The associated QC sample blank has a result >= 2X the MDA and, after corrections, result is >= MDA for this sample
Target analyte was detected in the sample and the associated blank. The associated blank concentration is >= EQL or is > 5% of the measuredconcentration and/or decision level for associated samples.Results are reported from a diluted aliquot of sample.
Spike Sample recovery is outside control limits.
Analyzed for but not detected above limiting criteria. Includes MDL, MDA, PQL, zero, counting error, and total analytical error.
Gamma Spectroscopy--Uncertain identification
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.** Indicates analyte is a surrogate compound.^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/-the RL is used to evaluate the DUP result.For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of therequirements of the NELAC standard unless qualified on the QC Summary.
+/-26800Uncert: TPU: +/-33300
Notes:
TPU and Counting Uncertainty are calculated at the 95% confidence level (1.96-sigma).
QC Criteria
Page 64 of 64
OCTOBER 30, 2017
66 of 66