current groundwater investigations at texas a&m university-corpus christi, rick hay

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Current ground water investigations at Texas A&M University- Corpus Christi Richard Hay 1 , Dorina Murgulet 2 , Richard Coffin 3 , Valeriu Murgulet 4 , 1 Assistant Director Center for Water Supply Studies, 2 Assistant Professor of Geology TAMUCC, 3 Department Chair Physical and Environmental Science TAMUCC, Research Associate Physical and Environmental Science TAMUCC. Texas Alliance of Groundwater Districts – 10/30/2014

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Page 1: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Current ground water investigations at Texas A&M

University-Corpus Christi

Richard Hay1, Dorina Murgulet2, Richard Coffin3, Valeriu Murgulet4,

1Assistant Director Center for Water Supply Studies, 2Assistant Professor of Geology TAMUCC, 3Department Chair Physical and Environmental Science TAMUCC, Research Associate Physical and Environmental Science TAMUCC.

Texas Alliance of Groundwater Districts – 10/30/2014

Page 2: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Outline• Water Resources and Climate

– Precipitation– Stream flow– Groundwater

• Ground water discharge to estuaries– Geophysics– Geochemistry– Hydrogeology

• Ground water discharge to Nueces River– Geochemistry– Geophysics– Hydrogeology

• Ground water/Surface water interaction– Thermal profilers– Geophysics

• Ground water and hydrocarbons– Stable Isotopes– C-Methane– C-Carbon dioxide

Texas Alliance of Groundwater Districts – 10/30/2014

Page 3: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Climate

Page 4: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

South Texas Precipitation

• 200 meteorological stations.

• Spatial interpolation (kriging) to fill in missing data.

• Daily precipitation datasets 1890-2006

AUSTIN

SAN ANTONIO

CORPUS CHRISTI

BRYAN

LAREDO

MCALLEN

VICTORIA

ST. HEDWIG

ARANSAS PASS

BROWNSVILLE

Ü

Legend

Meteorological Stations

Urban Area

0 10050 Km

TEXAS

Study Area

JAN

FEBM

ARAPR

MAY

JUN

JUL

AUGSE

POCT

NOVDEC

0

200

400

600

800

1000

1200

Rai

nfa

ll (m

m)

Page 5: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Climate Indicators

• ENSO – El Niño Southern Oscillation 2-4y • AMO – Atlantic Multidecadal Oscillation 20-40 y• PDO – Pacific Decadal Oscillation ~10-20y• MEI – Multivariate ENSO index 2-4y• Represent measureable phenomena that correlate

with weather patterns (climate).

Page 6: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

El Niño Southern Oscillation

• El Niño– wetter weather in Texas• La Niña – drier but more volatile weather

Page 7: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Stream Flow

• Normalized Stream Flow – data compiled from 16 unimpaired USGS stream gages.

• Transformed from a time domain to frequency

• Wavelet transform – Change in frequency

over time

Strong signals at 12,

36-64, 128 months

Page 8: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Ground Water

• Successful correlation of stream flow with climate indicators suggests that ground water resources may have a similar response to the climate “teleconnections”

• Currently developing an index similar to the normalized stream flow for ground water in south Texas.

Page 9: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Ground Water Discharge to Bays

Page 10: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Submarine Groundwater discharge and hypoxia

• Using radon and resistivity to identify areas of ground water discharge that may be delivering nutrients to the bay.

Texas Alliance of Groundwater Districts – 10/30/2014

Hypoxic Plume

Page 11: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Ground water flux to bay

• Figures 12-14: Oso Inlet time-lapse and difference conductivity inversions. (Note: Boxes represent source locations for SGD calculations and red dots indicate the location of Rn and conductivity monitoring, collected in sequence with the resistivity profiles)

D E F

Page 12: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Changes in Rn and SC

• Time-lapse Radon (Rn) and conductivity data.

Page 13: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Salinity in the Lower Nueces River

Page 14: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Ground water discharge to the Nueces River

• Calallen Pool – Small impoundment from a salt water barrier dam where Corpus Christi and other entities take water from the Nueces River

1980 1990 2000 2010

10

02

00

30

04

00

Chlorides measured a 12964 (Bluntzer)

Sample Date

Ch

lori

de

s (

mg

/l)

missingdata

Increasing chloride concentration in the river water above the Calallen Pool.

Page 15: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Specific Conductance v. Depth

• Specific conductance measurements show higher values at deeper depths

• Suggests ground water influence. Specific Conductance (uS)

De

pth

(m

)

0.5

1.0

1.5

2.0

2.5

3.0

0 5000

Run 01 Run 02

0 5000

Run 03 Run 04

0 5000

Run 05 Run 06

0 5000

Run 07

Run 08 Run 09 Run 10 Run 11 Run 12 Run 13

0.5

1.0

1.5

2.0

2.5

3.0

Run 14

0.5

1.0

1.5

2.0

2.5

3.0

Run 15

0 5000

Run 16 Run 17

0 5000

Run 18 Run 19

0 5000

Run 20 Run 21

Page 16: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Calallen Pool and Hazel Basemore Park

• Location of monitoring wells

• Geophysical Transect

• Salt water barrier dam

Page 17: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Soil conductivity survey at Hazel Basemore Park.

• Red indicates higher conductivity (saltier)

• Green indicates lower conductivity (fresher)

• Monitoring wells in agreement.

Page 18: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Resistivity measurements

• Top panel resistivity array• Bottom panel magnetotelluric sounding• Red indicates high resistivity (fresher)• Blue indicates low resistivity (saltier)

MT x-section (ohm-m)

Distance (m)

Depth (m

)

50

100

150

50 100 150 200 250

Site.1

6

Site.2

1 Site.2

2

Site.2

0

Site.1

9

Site.1

8

Site.1

7

Site.1

5

Site.1

3

Min Coh = 0.7

Mean Coh = 0.936

1 2 3 4 5

Page 19: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Resistivity along the river channel

• Fresher water in aquifer beneath river closest to the dam and furthest upstream

Page 20: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Ground Water Flux• conversion of resistivity in ohm-ms (Ωm) to salinity in

parts per thousand (ppt):

S = 7.042 x Rp ¹· ²³³⁻ ⁰ (Manheim et al. 2004 )

Vgwr = Vsal* [(Sw-Sb)/Sb]* Sb (Dimova et al., 2012)

Base Station

Qsaline= 172.4 m3/dayQfresh= 65.7 m3/day

Page 21: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Presence of Radon

• Surface water normally contains little or no radon (short half life, dissolved gas)

• Presence of radon in surface water indicates recent ground water discharge

Page 22: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Ground Water – Surface Water

Page 23: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Ground water - Surface water interaction using thermal and

geophysical techniques• Low gradient stream on coastal plain.• Time lapse resistivity measurements• Thermal profiler

Temperature Loggers

WELL PROFILER

WATER TABLE

Page 24: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Data from Thermal Profilers

Jul Sep Nov Jan Mar May

10

15

20

25

30

Site SB-GW 08

Time

Te

mp

era

ture

(Ce

lciu

s)

Level 0 TemperatureLevel 1 TemperatureLevel 2 TemperatureLevel 3 TemperatureGroundwater

30

25

20

15

10

Jul Sep Nov Jan Mar May

Data collected over a 1 year period.

Page 25: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Statistical Decomposition of Timeseries

• Random component represents period where vertical advection occured

Page 26: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Time Lapse Resistivity

• Profile A and B were measured 2 months apart.

• C is the difference between the two measurements with the greatest change (red area) showing lateral discharge to the creek.

Page 27: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Stable Isotopes

Page 28: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Methane Source Assessment• 35 groundwater samples were collected from active

and non-active shale play areas to better define the extent of contamination and/or differentiate between methane sources (i.e. deep and shallow).

• δ13CCH4 and δ13CDIC values were measured to determine the range of signatures for shale petroleum-sourced methane and to differentiate between microbial and thermogenic methane sources.

Page 29: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Results

• Both microbial and thermogenic methane (petroleum) were indicated in this preliminary study.

Page 30: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Texas Alliance of Groundwater Districts – 10/30/2014

Source Water• Deuterium• Oxygen• Meteoric line• Mixing• Heat

Page 31: Current Groundwater Investigations at Texas A&M University-Corpus Christi, Rick Hay

Thank You!

Questions?

Texas Alliance of Groundwater Districts – 10/30/2014

Contact:[email protected] (361)[email protected] (361)[email protected] (361)825-2456