coalescence modelling for design of technical equipment

15
1 David Leleu , Andreas Pfennig [email protected] Products, Environment, and Processes (PEPs) Department of Chemical Engineering Université de Liège www.chemeng.uliege.be/Pfennig Coalescence Modelling for Design of Technical Equipment

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1

David Leleu, Andreas Pfennig

[email protected]

Products, Environment, and Processes (PEPs)

Department of Chemical Engineering

Université de Liège

www.chemeng.uliege.be/Pfennig

Coalescence Modelling for

Design of Technical Equipment

agenda

motivation

basic understanding

coalescence modelling

settler simulation

2

gravity settler

3

technical equipment’s

4

stirring cell

5

stirring-cell experiment

0 5 10 15 20 25 300.00

0.02

0.04

0.06

0.08

0.10

0.12

0.14

0.16

0.18stirr

ing

ce

ll he

ight

in m

time in s

sedimentation curve

coalescence curve

6

effect description influenced by

frequency at which

drops meet

equipment type,

fluid dynamics,

holdup

drops bounce at high

relative velocity

equipment type,

fluid dynamics,

operating conditions

time drops stay in

contact, tcontact

equipment type,

fluid dynamics,

operating conditions

characteristic time

drops need to

coalesce, tcoalescence

material system,

drop size

modelling coalescence of drops

7

coalescence probability: fundamental

8

pcoalescence,Coulaloglou&Tavlarides = exp −tcoalescence

tcontact

Coulaloglou & Tavlarides, Chem. Eng. Sci., 1977

coalescence probability: fundamental

9

pnon−coal,Δt =exp −Δt

tcoal

pcoal = 1−exp −tcontacttcoal

pnon−coal =exp −tcontacttcoal

∆t

n=tcontact

Δt

tcontact

pnon−coal,nΔt = pnon−coal,Δtn

pnon−coal,nΔt =exp −nΔt

tcoal

close-packed zone

drops deformation

film drainage

Arnaud Saint-Jalmes, 2006

10

counterflow

11

continuous flow

droplets

εΔh ΔPhydrostaticΔPcounterflow v

ΔPtotal = Δphydrostatic -ΔPcounterflow

iso-optical settling experiment

12

settling simulation

13

0 20 40 60 80 100 120

20

40

60

80

100

120

140

160

180

time in s

ce

ll h

eig

th in

mm

summary

consistent coalescence model

calibrated setup for model validation

purposes

model able to characterize settling

behavior for any system

14

15

David Leleu, Andreas Pfennig

[email protected]

Products, Environment, and Processes (PEPs)

Department of Chemical Engineering

Université de Liège

www.chemeng.uliege.be/Pfennig

Coalescence Modelling for

Design of Technical Equipment