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    CHAPTER 2

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    2.1 MATTER

    Most of the things thatwe could see in this world

    are MATTER

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    What is matter?

    Matter means:- anything that occupies space &

    has mass- made up of tiny & discrete

    particles- Exist as element@compound

    Next

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    A pure substance whichcannot be broken down into

    simpler substance physically& chemically

    Matter

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    Usually made up of

    two or more elements

    which are chemically

    bonded together

    Matter

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    1. Matter are made up of tiny &discrete particles

    2. Size of particles are veryminute ~~ 1x 10-7cm

    3. Consist of atoms, moleculesions

    Next

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    Lets see the particles inbromine liquid

    Particle theory

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    The smallest particle of an elementand not breakable anymore.

    Examples:Atom of hydrogen

    atom of magnesium

    atom of oxygen

    atom of chlorine

    H

    Mg

    Cl

    O

    Particle theory

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    A group of two @ more atoms,which might consist of:

    one type of element (Element)

    @ different types of element(Compound)

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    Examples of element molecules:

    Molecule of hydrogen gas

    Molecule of oxygen gas

    Molecule of chlorine gas

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    Examples of compound molecules:

    Molecule of water, H2O

    Molecule of ammonia, NH3

    Molecule of ethanol, C2H5OH

    N

    C C

    Particle theory

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    Ions are atoms which havecharge

    Positively-charged ion /cation(loss e-)

    Negatively charged ion / anion (gain e-)

    +

    -

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    Hydrogen atom Hydrogen ion

    Magnesium atom Magnesium ion

    Oxygen atom Oxide ion

    Chlorine atom Chlorine ion

    Particle theory

    H+H Lose electron

    Mg2+Lose electronMg

    O2

    -

    Gain electronO

    Cl-

    Gain electronCl

    Symbol of element

    Examples of ions:

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    Kinetic means motion (move) Kinetic theory states that:

    1. Matter consist of particles whichconstantly moving

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    2. particles move in random motion ,

    collide with each other

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    A. substance is cooled,

    - particles lose kinetic energy- move slower

    B. substance is heated,- particles gain kinetic energy- move faster

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    Heat energy makes particlesmove faster!!!

    http://localhost/var/www/apps/conversion/tmp/scratch_5/Heating%20cooling.exe
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    Experiment which supports

    the kinetic theory:

    Investigating the diffusion of

    particles in asolid, liquid and gas

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    What is diffusion ?

    How diffusion supports the

    kinetic theory ?

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    Diffusion happens anyway thatdifferent concentration

    of particles

    http://localhost/var/www/apps/conversion/tmp/scratch_5/diffusion.swf
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    Is the rate of diffusion

    different in solid, liquid,and gas state?

    Lets get an experimentto check it out!!!

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    Diffusion in Solid (membrane)

    http://localhost/var/www/apps/conversion/tmp/scratch_5/Diffussion%20thru%20membrane.swf
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    Diffusion in Liquid ( )

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    Diffusion in Gas (air)

    http://localhost/var/www/apps/conversion/tmp/scratch_5/diffusion%20in%20air.exe
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    Diffusion affected by Density

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    The conclusion is.

    Diffusion happens in solid, liquid,and gas states

    Diffusion occurs slowest in solid,faster in liquid and fastest in gas

    Diffusion occurs faster in subtance

    with lower density Diffusion supports kinetic energy

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    The Physical States of Matter

    Solid

    Liquid

    Gas

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    The Arrangement of Particles

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    The Shape & Volume of Particles

    Th M & E C f

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    The Movement & Energy Content of

    Particles

    Th A F

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    The Attraction Force

    between Particles

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    The Physical Changes of Matter

    Freezing

    GasLiquid

    Solid

    MeltingSublimation

    Boiling

    Condensation

    Sublimation

    D t i th

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    Determine theMelting Point of Naphthalene

    Melting point

    the temperaturewhich a solid

    becomes liquid

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    Diagram of heating naphthalene

    Q1-Q4 Q5-Q7

    Solid naphthalene

    Water

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    Heating curve of naphthalene

    A

    CB

    D

    Temperature / C

    Time / minute

    79C

    Q1-Q4 Q5-Q7

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    What is the Melting point?A: 79C

    What is the physical state at B-C?A: solid and liquid

    Where is point that Melting process started?

    A: B

    Where is point that Melting process ended?A: C

    graph apparatus

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    Why the curve of heating has no change at B-C?A: because the heat energy absorbed by

    naphthalene molecules to overcome the forces ofattraction to becomes liquid

    Why solid naphthalene heated in water ?

    A: to ensure a uniform heating

    If the melting point of Substance X is 123C, canwe still use water as medium? Why?

    A: No. Because its melting point is higher thanthe boiling point of water. We can use oil bath toreplace water. graph apparatusPhysical changes

    D t i th

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    Determine theFreezing Point of Naphthalene

    Freezing point the

    temperature which a solutionbecomes solid

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    Cooling curve of naphthalene

    Q1-Q4 Q5-Q7

    79C

    E

    Temperature / C

    G

    H

    Time / minute

    F

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    Is the freezing point same with the Melting point?A: Yes, both are 79C

    What is the physical state change in thisexperiment?A: Liquid naphthalene changes to solid

    Where is the point thatfreezing process started?A: F

    Where is the point thatfreezing process ended?A: G

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    Why the curve of heating has no change at F-G?

    A: because the heat energy released during

    formation of bonds is equal to the heat released tosurroundings

    Why liquid naphthalene in the boiling tube is cooled

    inside a conical flask?

    A: to ensure a uniform cooling

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    Different solution has differentboiling point & freezing point

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    Diagram of cooling naphthalene

    Q1-Q4 Q5-Q7

    Liquid naphthalene

    Empty conical flask

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    2.2 ATOMIC STRUCTURE

    Th Hi t i l D l t Of

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    The Historical Development OfAtomic Models

    John Dalton

    imagine atom as aindivisible tiny ball

    J.J. Thomsondiscovered electrons

    Ernest Rutherford

    discovered proton,mass of atom concentrated in nucleus

    Neils Bohrproposed the electrons

    move in shells around the nucleus James Chadwick proved the existence

    of neutrons

    S b i P i l I A A

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    Subatomic Particle In An Atom

    S b i P i l I A A

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    Subatomic Particle In An Atom

    Proton

    Neutron

    Electron

    S b t i P ti l I A At

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    Subatomic Particle In An Atom

    Proton Electron

    Neutron

    Nucleus

    of atom Electron

    shells

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    S b t i P ti l I A At

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    Subatomic Particle In An Atom

    S b t i P ti l I A At

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    Subatomic Particle In An Atom

    PROPERTIES PROTON NEUTRON ELECTRON

    Symbol

    Electric Charge

    Relative MassLocation

    S b t i P ti l I A At

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    Subatomic Particle In An Atom

    PROPERTIES PROTON NEUTRON ELECTRON

    Symbol p

    Electric Charge

    Relative MassLocation

    S b t i P ti l I A At

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    Subatomic Particle In An Atom

    PROPERTIES PROTON NEUTRON ELECTRON

    Symbol p n

    Electric Charge

    Relative MassLocation

    S b t i P ti l I A At

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    Subatomic Particle In An Atom

    PROPERTIES PROTON NEUTRON ELECTRON

    Symbol p n e-

    Electric Charge

    Relative MassLocation

    Subatomic Particle In An Atom

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    Subatomic Particle In An Atom

    PROPERTIES PROTON NEUTRON ELECTRON

    Symbol p n e-

    Electric Charge +1

    Relative MassLocation

    Subatomic Particle In An Atom

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    Subatomic Particle In An Atom

    PROPERTIES PROTON NEUTRON ELECTRON

    Symbol p n e-

    Electric Charge +1 0

    Relative MassLocation

    Subatomic Particle In An Atom

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    Subatomic Particle In An Atom

    PROPERTIES PROTON NEUTRON ELECTRON

    Symbol p n e-

    Electric Charge +1 0 -1

    Relative MassLocation

    Subatomic Particle In An Atom

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    Subatomic Particle In An Atom

    PROPERTIES PROTON NEUTRON ELECTRON

    Symbol p n e-

    Electric Charge +1 0 -1

    Relative Mass 1Location

    Subatomic Particle In An Atom

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    Subatomic Particle In An Atom

    PROPERTIES PROTON NEUTRON ELECTRON

    Symbol p n e-

    Electric Charge +1 0 -1

    Relative Mass 1 1Location

    Subatomic Particle In An Atom

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    Subatomic Particle In An Atom

    PROPERTIES PROTON NEUTRON ELECTRON

    Symbol p n e-

    Electric Charge +1 0 -1

    Relative Mass 1 1 1/1240 0Location

    Subatomic Particle In An Atom

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    Subatomic Particle In An Atom

    PROPERTIES PROTON NEUTRON ELECTRON

    Symbol p n e-

    Electric Charge +1 0 -1

    Relative Mass 1 1 1/1240 0Location in the

    nucleusatom

    Subatomic Particle In An Atom

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    Subatomic Particle In An Atom

    PROPERTIES PROTON NEUTRON ELECTRON

    Symbol p n e-

    Electric Charge +1 0 -1

    Relative Mass 1 1 1/1240 0Location in the

    nucleusatom

    in thenucleusatom

    Subatomic Particle In An Atom

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    Subatomic Particle In An Atom

    PROPERTIES PROTON NEUTRON ELECTRON

    Symbol p n e-

    Electric Charge +1 0 -1

    Relative Mass 1 1 1/1240 0Location in the

    nucleusatom

    in thenucleusatom

    Electronshells whicharound the

    nucleus atom

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    Symbol of Element

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    40

    20CaNucleon number

    Proton number

    Symbol of Element

    -When an atom is neutral ,(1.refer ions)

    its number of proton = e-

    - number of protons = 20

    so number of elecrons = 20- 2.electron configuration = 2.8.8.2

    valence electron = 2

    Symbol of element

    3.Next

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    Electron Configuration

    Also known as electron arrangement

    How electrons fill into the shells?

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    Helium He

    Proton number 2

    2

    Hydrogen H

    Proton number 1

    1

    Lithium Li

    Proton number 3

    2 . 1

    Beryllium Be

    Proton number 4

    2 . 2

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    Boron B

    proton number 5

    2 . 3

    Carbon C

    Proton number 6

    2 . 4

    Nitrogen N

    Proton number 7

    2 . 5

    Oxygen O

    Proton number 8

    2 . 6

    Fluorine F Neon Ne

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    Proton number 9

    2 . 7

    Proton number 10

    2 . 8

    Sodium Na

    Proton number 11

    2 . 8 . 1

    Magnesium Mg

    Proton number 12

    2 . 8 . 2

    Aluminium Al

    P t b 13Silicon Si

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    Proton number 13

    2 . 8 . 3

    Proton number 14

    2 . 8 . 4

    Phosphorus P

    Proton number 15

    2 . 8 . 5

    Sulphur S

    Proton number 16

    2 . 8 . 6

    Chlorine Cl Argon Ar

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    Chlorine Cl

    Proton number 17

    2 . 8 . 7

    Argon Ar

    Proton number 18

    2 . 8 . 8

    Potassium K

    Proton number 19

    2 . 8 . 8 . 1

    Calcium Ca

    Proton number 20

    2 . 8 . 8 . 2

    C l i

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    Conclusion:

    1st Shell: max 2 e-2nd Shell: max 8 e-

    3rd Shell: max 8 e-

    1) Because they have the same

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    ) ynumber of orbits, they have 2

    orbits / electron shells2) Group 1 is alkaline metals,

    hydrogen is a type of gas /hydrogen is not alkaline metal3) They have stable// electron

    arrangement (Helium, pn=2

    duplet, Argon, 2.8.8 octet)

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    4) Li, Be, B, C, N,O,Br, Ne

    5) i) K, Ca, Mgii) C, S, Cl

    ARRANGEMENT OF SHELLS IN AN ATOM

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    NUCLEUS

    2 ELECTRONS

    8 ELECTRONS

    8ELECTRONS

    18 ELECTRONS

    1

    23

    4

    Electron arrangement in the

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    Electron arrangement in the

    carbon atom

    C12

    6

    proton number = 6

    number of protons = 6

    number of electrons = 6

    2 . 4

    = electron

    nucleus

    Number of valence

    electrons = 4

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    23

    11 Na

    2 . 8 . 1

    number of protons = 11

    proton number = 11

    number of electrons = 11

    = electron

    Nucleus

    Number of valence

    electrons = 1 Symbol of element

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    Draw & state the electron arrangement of

    the elements below

    X

    15

    7 Y

    24

    12 Z

    39

    19

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    Let us learn somechemical words !!

    P t b ( )

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    Proton number (p) number of protons in the nucleus of atom

    Nucleon number (p+n)total number of protons and neutrons inthe nucleus of atom

    3. Valence electron the electrons in the outermost shell

    4. Electron configuration arrangement of electron

    Repeat them !!

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    epeat t e !!Proton number

    number of protons in the nucleus of atomNucleon number

    total number of protons and nucleons

    in the nucleus of atomValence electron

    the electrons in the outermost shell

    Electron configuration arrangement of electron

    T h !!!

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    Try this out!!!

    Q1 Fill in the blanks

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    Elements Proton

    Number

    Nucleon

    Number

    Number

    ofNeutrons

    A 3 7

    B 6 12

    C 19 10

    D 16 16

    E 17 18

    F 40 20

    Q1 Fill in the blanks

    Q1 Answers

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    Elements Proton

    Number

    Nucleon

    Number

    Number

    ofNeutrons

    A 3 7 4

    B 6 12 6

    C 9 19 10

    D 16 32 16

    E 17 35 18

    F 20 40 20

    Q1 Answers

    Q2 Fill in the blanks

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    Elements NumberofNeutron

    NucleonNumber Numberofelectrons

    ElectronConfiguration

    A 5 9

    B 8 2.6C 19 2.7

    D 14 2.8.3

    E 32 16

    F 20 40

    Q2 Fill in the blanks

    Q2 Answers

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    Elements NumberofNeutron

    NucleonNumber Numberofelectrons

    ElectronConfiguration

    A 5 9 4 2.2

    B 8 16 8 2.6C 10 19 9 2.7

    D 14 27 13 2.8.3

    E 16 32 16 2.8.6

    F 20 40 20 2.8.8.2

    Q2 Answers

    2 3 ISOTOPES

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    2.3 ISOTOPES

    What is isotopes?

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    Isotopes is just like twins,

    same genetic but different of DNA

    atoms of the same element withsame number of protons butdifferent number of neutrons

    What is isotopes?

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    Examples of Isotopes Take a look at Wikipedia isotopes table

    Hydrogen :

    Graphite :

    Oxygen :

    1

    1

    H3

    1

    H2

    1

    H

    12

    6C

    14

    6C

    13

    6C

    16

    8O18

    8O17

    8O

    Isotopes of Hydrogen

    http://localhost/var/www/apps/conversion/tmp/scratch_5/Isotope%20table%20(complete)%20-%20Wikipedia,%20the%20free%20encyclopedia.htmhttp://localhost/var/www/apps/conversion/tmp/scratch_5/Isotope%20table%20(complete)%20-%20Wikipedia,%20the%20free%20encyclopedia.htm
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    Isotopes of Hydrogen

    Hydrogen :

    1

    1

    H

    2

    1

    H

    3

    1

    H

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    Properties of isotopesOxygenIsotopes

    No of proton

    No of neutron

    No of e-

    e- configuration

    Valence e-

    16

    8O

    18

    8O17

    8O

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    Properties of isotopesOxygenIsotopes

    No of proton 8

    No of neutron

    No of e-

    e

    -

    configurationValence e-

    16

    8O

    18

    8O17

    8O

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    Properties of isotopesOxygenIsotopes

    No of proton 8 8

    No of neutron

    No of e-

    e

    -

    configurationValence e-

    16

    8O

    18

    8O17

    8O

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    Properties of isotopesOxygenIsotopes

    No of proton 8 8 8

    No of neutron

    No of e-

    e

    -

    configurationValence e-

    16

    8O

    18

    8O17

    8O

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    Properties of isotopesOxygenIsotopes

    No of proton 16 16 16

    No of neutron 16

    No of e-

    e

    -

    configurationValence e-

    16

    8O

    18

    8O17

    8O

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    Properties of isotopesOxygenIsotopes

    No of proton 16 16 16

    No of neutron 16 17

    No of e-

    e

    -

    configurationValence e-

    16

    8O

    18

    8O17

    8O

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    Properties of isotopesOxygenIsotopes

    No of proton 16 16 16

    No of neutron 16 17 18

    No of e-

    e

    -

    configurationValence e-

    16

    8O

    18

    8O17

    8O

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    Properties of isotopesOxygenIsotopes

    No of proton 16 16 16

    No of neutron 16 17 18

    No of e- 16

    e- configuration

    Valence e-

    16

    8O

    18

    8O17

    8O

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    Properties of isotopesOxygenIsotopes

    No of proton 16 16 16

    No of neutron 16 17 18

    No of e- 16 16

    e- configuration

    Valence e-

    16

    8O

    18

    8O17

    8O

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    Properties of isotopesOxygenIsotopes

    No of proton 16 16 16

    No of neutron 16 17 18

    No of e- 16 16 16

    e- configuration

    Valence e-

    16

    8O

    18

    8O17

    8O

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    Properties of isotopesOxygenIsotopes

    No of proton 16 16 16

    No of neutron 16 17 18

    No of e- 16 16 16

    e- configuration 2.8.6

    Valence e-

    16

    8O

    18

    8O17

    8O

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    Properties of isotopesOxygenIsotopes

    No of proton 16 16 16

    No of neutron 16 17 18

    No of e- 16 16 16

    e- configuration 2.8.6 2.8.6

    Valence e-

    16

    8O

    18

    8O17

    8O

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    Properties of isotopesOxygenIsotopes

    No of proton 16 16 16

    No of neutron 16 17 18

    No of e- 16 16 16

    e- configuration 2.8.6 2.8.6 2.8.6

    Valence e-

    16

    8O

    18

    8O17

    8O

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    Properties of isotopesOxygenIsotopes

    No of proton 16 16 16

    No of neutron 16 17 18

    No of e- 16 16 16

    e- configuration 2.8.6 2.8.6 2.8.6

    Valence e- 6

    16

    8O

    18

    8O17

    8O

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    Properties of isotopesOxygenIsotopes

    No of proton 16 16 16

    No of neutron 16 17 18

    No of e- 16 16 16

    e- configuration 2.8.6 2.8.6 2.8.6

    Valence e- 6 6

    16

    8O

    18

    8O17

    8O

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    Properties of isotopesOxygenIsotopes

    No of proton 16 16 16

    No of neutron 16 17 18

    No of e- 16 16 16

    e- configuration 2.8.6 2.8.6 2.8.6

    Valence e- 6 6 6

    16

    8O

    18

    8O17

    8O

    Conclusion:

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    Conclusion:

    Number of valence electron are same

    The chemical properties also same

    The physical properties might besame, might be different

    Try this out!!!

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    Try this out!!!

    Q3. Answer the structure questions

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    Elements Proton Number Nucleon Number

    P 3 7

    Q 9 19

    R 16 32

    S 15 31T 16 33

    U 18 40

    a ) What means proton number?

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    A: The numbers of proton in the nucleus of an atom

    b) What means nucleon number?A: The numbers of proton & neutron in the nucleus

    of an atom

    c) Write the electron arrangement for element Q.

    A: 2.7

    d) How many valence electrons that element Q has?

    A: 7

    e) How many electron shells that element Q has?

    A: two

    f) Which pair of elements are isotopes? Explain.

    A R & T

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    4018

    U

    A: R & T.

    Because they have same proton number but

    different nucleon number

    g) Is R&T have same chemical properties? Why?

    A: Yes. Because they have same valence electron

    h) How many protons, neutrons, and electrons are

    there in atom S?

    A: 15 protons, 16 neutrons and 15 electrons

    i) Write the symbol to represent atom U.A: 40

    18U

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