chem introduction part 1
DESCRIPTION
chem 31 introductionTRANSCRIPT
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• Introduction
– Organic Chemistry
• The chemistry of the compounds of carbon
• The human body is largely composed of organic compounds
• Organic chemistry plays a central role in medicine, bioengineering etc.
– Vitalism
• Organic compounds could be made only by living things by intervention of a “vital force”
• Fredrich Wöhler disproved vitalism in 1828
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CRITERIA INORGANIC ORGANIC
1. Elements involved All of the elements Relatively few elements
(mainly C, H, N, O, S, P, X)
2. Type of bonding
- within a unit
- between units
Mostly ionic
Mostly electrostatic
Covalent
Dispersion forces, dipole-
dipole, H-bonding
3. Units of structure Ions Molecules
4. Rates of reaction
- at room temperature
- at higher
temperature
Generally fast
Very fast
Generally slow
Moderately fast to explosive
5. Catalyst requirement sometimes Often
6. Side reactions None, many are quantitative Yes, nearly always
7. combustibility Non-combustible Usually combustible
8. Physical properties
- solubility
-- in water
-- in organic
solvents
- electrical conduction
- melting point
- boiling point
- volatility
Mostly soluble
Insoluble
Yes
Relatively high
High
Nonvolatile
Mostly insoluble
Mostly soluble
No
Relatively low
Low
Usually volatile
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• Structural Theory
– Central Premises
• Valency: atoms in organic compounds form a fixed number of bonds (covalency number)
• Carbon can form one or more bonds to other carbons
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– Isomers
• Isomers are different molecules with the same molecular formula
• Many types of isomers exist
• Example – Consider two compounds with molecular formula C2H6O
– These compounds cannot be distinguished based on molecular formula; however they have different structures
– The two compounds differ in the connectivity of their atoms
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– Three Dimensional Shape of Molecules
• Virtually all molecules possess a 3-dimensional shape which is often not accurately represented by drawings
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• Chemical Bonds: – Octet Rule
Electronegativity Electronegativity is the ability of an atom to attract electrons
It increases from left to right and from bottom to top in the periodic table (noble gases excluded)
Fluorine is the most electronegative atom and can stabilize excess electron density the best
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Chapter 1 7
• Writing Lewis Structures • Atoms bond by using their valence electrons • The number of valence electrons is equal to the group
number of the atom – Carbon is in group 4A and has 4 valence electrons – Hydrogen is in group 1A and has 1 valence electron – Oxygen is in group 6A and has 6 valence electrons – Nitrogen is in group 5A and has 5 valence electrons
• To construct molecules the atoms are assembled with the correct number of valence electrons
• If the molecule is an ion, electrons are added or subtracted to give it the proper charge
• The structure is written to satisfy the octet rule for each atom and to give the correct charge
• If necessary, multiple bonds can be used to satisfy the octet rule for each atom
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Propane (C3H8)
Acetylene (C2H2)
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Acetone (C3H6O)
Ethanol (C2H5OH)
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Acetic acid (C2H4O2)
Acetonitrile (CH3CN)
Try these…
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• Formal charge
• A formal charge is a positive or negative charge on an individual atom
• The sum of formal charges on individual atoms is the total charge of the molecule or ion
• The formal charge is calculated by subtracting the assigned electrons on the atom in the molecule from the electrons in the neutral atom
• Electrons in bonds are evenly split between the two atoms; one to each atom
• Lone pair electrons belong to the atom itself
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Ethene (C2H4)
Aminomethane (CH3NH2)
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Methaniminium
Ethyl acetate
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Nitromethane
Try these…
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• A Summary of Formal Charges
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3) Condensed structures
Representing Organic Compounds
1) Molecular Formula C2H6O Ethanol/ethyl alcohol
2) Lewis Dot Structures
CH3CH2OH CH3OH
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- using lines to show covalent bonds
Representing Organic Compounds
4) Dash Structural Formula
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line structures:
each intersection is a carbon
H on carbon is invisible – assume carbons are saturated
Representing Organic Compounds
5) Bond Line Structural Formula
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Br
Cl
line structure:
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21
Representing Organic Compounds
6) 3D Structural Formula