book review: polymer blends. macromolecular symposia, vol. 112. edited by l. a. l. kleintjens....

1
330 Book reviews The Ðnal section includes chapters on mini-emulsions, inverse EP, and solvent based emulsions, usually referred to as formed by dispersion polymerization. The Ðnal chapter includes less conventional latexes, including polymerization in vesicles. Conductive polymers (not vinyl) and, unusually, EP of a siloxane by an ionic mechanism, which may involve a basic catalyst and a cationic surfactant, or dodecylbenzene- sulphonic acid which is both catalyst and surfactant. My main criticism of this volume is that, except for two GR-S “recipesÏ and one for polychloroprene rubber in the chapter by Blackley, I have not detected a single formulation which could be used to perform a polymerization to give a stable latex, free from coagulum, freezeÈthaw stable, with the correct viscosity and Ðlm forming characteristics making it useful for a standard application, such as a coating or adhe- sive. H. Warson blends. Macromolecular symposia, Vol. 112. Polymer Edited by L. A. L. Kleintjens. Huł thig and Wepf, Zug, Switzerland, 1996. Price SFr72, DM88, oł S623, US$60. ISBN 3-85739-309-2 This issue of Macromolecular symposia, contains most of the papers presented orally at the Fifth European Symposium on Polymer Blends held in Maastricht in May 1996. After a general introduction the 27 papers fall under Ðve headings : general introduction ; blend preparation ; processing and compounding ; properties and performance of polymer blends ; reactive systems and chemical modiÐcation of Polymer Blends ; and molecular architecture : new develop- ments. The nine papers in the “General introductionÏ include work on the reactor polymer alloys, heterogeneous and homoge- neous metallocene catalysts, molecular modelling of phase behaviour of polymer blends, the correlation between segment interaction parameter and interface width and the application of equation of state theories to poly(styrene-co-acrylonitrile)/ poly(methyl methacrylate) blends. Other papers are concerned with the calculation of miscibility behaviour of multinary polymer blends, estimation of interactions in blends of poly- amides, polyesters and polycarbonate using copolymers as compatibilizers, phase separation in thermoplasticÈthermoset polymer blends and interdi†usion in a partially miscible blend system. In “Preparation, processing and compoundingÏ are papers on mixing efficiency, phase inversion, numerical simulation of distributive mixing in 3D Ñows and the morphological control of impact toughness in poly(methyl methacrylate)/acrylo- nitrileÈbutadiene rubber blends. Four papers on “Properties and performanceÏ include in situ deformation of rubber toughened poly(methyl methacrylate) using SAXS, on the compatibilization of polyamides and poly(arylether sulphone), a SAXS study of plastically deformed rubber-modiÐed polystyrene and on the limitations of short-term ageing tests. Five papers on reactive processing and compatibilization include chemical modiÐcation of polyoleÐn blends and the in situ preparation of graft copolymers. Finally, there are four papers dealing with encapsulation, surfactant-induced mesomorphic behaviour of Ñexible poly- mers, microphase separation in correlated random copoly- mers, and blends of non-Ñexible and Ñexible polymers as a route to molecular composites. This is clearly a book for the specialist and not for the beginner. It contains much that is of interest but it is quite variable in depth and in the degree to which each paper con- tributes to new knowledge. It is probably a book for the library rather than for individual purchase. J. D. Hourston POLYMER INTERNATIONAL VOL. 45, NO. 3, 1998

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Page 1: Book Review: Polymer blends. Macromolecular symposia, Vol. 112. Edited by L. A. L. Kleintjens. Hüthig and Wepf, Zug, Switzerland, 1996. Price SFr72, DM88, öS623, US$60. ISBN 3-85739-309-2

330 Book reviews

The Ðnal section includes chapters on mini-emulsions,inverse EP, and solvent based emulsions, usually referred to asformed by dispersion polymerization. The Ðnal chapterincludes less conventional latexes, including polymerization invesicles. Conductive polymers (not vinyl) and, unusually, EPof a siloxane by an ionic mechanism, which may involve abasic catalyst and a cationic surfactant, or dodecylbenzene-sulphonic acid which is both catalyst and surfactant.

My main criticism of this volume is that, except for twoGR-S “recipesÏ and one for polychloroprene rubber in thechapter by Blackley, I have not detected a single formulationwhich could be used to perform a polymerization to give astable latex, free from coagulum, freezeÈthaw stable, with thecorrect viscosity and Ðlm forming characteristics making ituseful for a standard application, such as a coating or adhe-sive.

H. Warson

blends. Macromolecular symposia, Vol. 112.PolymerEdited by L. A. L. Kleintjens.Hu� thig and Wepf, Zug, Switzerland, 1996.Price SFr72, DM88, o� S623, US$60.ISBN 3-85739-309-2

This issue of Macromolecular symposia, contains most of thepapers presented orally at the Fifth European Symposium onPolymer Blends held in Maastricht in May 1996.

After a general introduction the 27 papers fall under Ðveheadings : general introduction ; blend preparation ; processingand compounding ; properties and performance of polymerblends ; reactive systems and chemical modiÐcation ofPolymer Blends ; and molecular architecture : new develop-ments.

The nine papers in the “General introductionÏ include workon the reactor polymer alloys, heterogeneous and homoge-

neous metallocene catalysts, molecular modelling of phasebehaviour of polymer blends, the correlation between segmentinteraction parameter and interface width and the applicationof equation of state theories to poly(styrene-co-acrylonitrile)/poly(methyl methacrylate) blends. Other papers are concernedwith the calculation of miscibility behaviour of multinarypolymer blends, estimation of interactions in blends of poly-amides, polyesters and polycarbonate using copolymers ascompatibilizers, phase separation in thermoplasticÈthermosetpolymer blends and interdi†usion in a partially miscible blendsystem.

In “Preparation, processing and compoundingÏ are paperson mixing efficiency, phase inversion, numerical simulation ofdistributive mixing in 3D Ñows and the morphological controlof impact toughness in poly(methyl methacrylate)/acrylo-nitrileÈbutadiene rubber blends.

Four papers on “Properties and performanceÏ include in situdeformation of rubber toughened poly(methyl methacrylate)using SAXS, on the compatibilization of polyamides andpoly(arylether sulphone), a SAXS study of plasticallydeformed rubber-modiÐed polystyrene and on the limitationsof short-term ageing tests.

Five papers on reactive processing and compatibilizationinclude chemical modiÐcation of polyoleÐn blends and the insitu preparation of graft copolymers.

Finally, there are four papers dealing with encapsulation,surfactant-induced mesomorphic behaviour of Ñexible poly-mers, microphase separation in correlated random copoly-mers, and blends of non-Ñexible and Ñexible polymers as aroute to molecular composites.

This is clearly a book for the specialist and not for thebeginner. It contains much that is of interest but it is quitevariable in depth and in the degree to which each paper con-tributes to new knowledge. It is probably a book for thelibrary rather than for individual purchase.

J.D. Hourston

POLYMER INTERNATIONAL VOL. 45, NO. 3, 1998