boiler tube failures
DESCRIPTION
Damage Mechanisms: Overheating Waterside Corrosion Fatigue mechanical, thermo-mechanical, thermal, corrosion, creep Fireside Corrosion Oxidation Erosion MechanicalTRANSCRIPT
BOILER TUBE FAILURESIN-SERVICE INSPECTIONS OF CONVENTIONAL POWER PLANTPractical Background Information
Hands-On Experience and Information whilst employed by the Plant Life Integrity department:
RWE Power International – Owner/Operator of Conventional Power Stations
Overheating
Waterside Corrosion
Fatigue
mechanical, thermo-mechanical, thermal, corrosion, creep
Fireside Corrosion
Oxidation
Erosion
Mechanical
Damage Mechanisms
OVERHEATING
Short term overheating
Temperature transient reduces materials strength below the applied pressure stress
Appearance Thin edge tensile failure leading to an axial “fishmouth” rupture Swelling prior to thinning, evident in cracking of external / internal scale
Location Furnace wall, Pendant S/H over furnace, Radiant S/H
Causes Starvation of steam/water flow Blockages from debris Waterlogging and inadequate condensate dispersal/drainage procedures Overfiring compared to steam flow e.g. loss of HP heaters Leak upstream of failure Drum level / carry under
Short term Overheating
Solutions Solutions are normally operational. New tubes will not prevent further failures
– Drainage procedures– Matching heat input with loading rate– Loading rates, turbine following boiler
Damage tends to be more localised than long term overheating Austenitic’s more tolerant than ferritic
Exceptions Austenitic tubes can give rise to thick edge short term overheating failures Accumulation of short term overheating causes damage through oxidation
and materials softening. Material replacement may offer some improvement.
Short term Overheating
Long term Overheating
Creep rupture due to sustained stress at elevated temperatures
Appearance
Thick edge failures leading to axial rupture
Thick oxide which may be crazed local to failure often with some associated fireside corrosion
Relatively low ductility at failure with little measurable swelling
Location
Adjacent to material or size transitions. S/H and R/H
Original Top dead space header stubs and tubes
Long term Overheating
Causes Operation beyond design life, poor steam temperature distributions,
elevated gas temperatures Increased stress due to wastage and ovality stresses Rogue material Partial blockage
Solutions Tube replacement or upgrade to remove damaged tubing Damage is more widespread than short-term overheating Replacements may be targeted by NDT oxide thickness measurements Reduction of steam temperatures and pressures Alteration to boiler design and combustion
Long term Overheating
WATERSIDE CORROSION
Control of boiler chemistry is fundamental to boiler availability The preservation of a thin passive oxide film on the bore of the tubes is key to
preventing corrosion Chemical species fed to the boiler concentrate as most are not carried over in
the steam Control of chemistry - pH, Conductivity, Oxygen
– Blow down– Chemical additions to the drum – De-aeration, Physical & Chemical
Chemistry problems have the potential to cause very widespread problems throughout the furnace with large impacts on availability and maintenance
Waterside Corrosion
Caustic Attack
Caused by the concentration of NaOH
Localised boiling causes concentration factor of 10,000
The caustic causes corrosion by dissolving the oxide/metal
Deposits can also cause overheating failures
Thick waterside deposits reduced heat transfer causing the tube wall to overheat
Oxide can be deposited in the tube with no significant tube corrosion due to the transport of corrosion products from the feed system
Waterside Corrosion ON-Load Corrosion
Solutions Control of Boiler Chemistry Routine acid cleaning to remove deposits and prevent
concentration mechanisms Ensuring maintenance of adequate circulation
Waterside Corrosion
FATIGUE
Fatigue Failures
Crack initiation and growth under cyclic loads
Nearly always low cycle fatigue rather than high cycle (<104) and loading normally of yield level and above.
Ductility exhausted in 100-1000’s of stress cycles. Failures are not initiation controlled. In welded components initiating
defects are normally present. Cracking propagates at stress concentrations such as notches and changes of section.
Locations of stress concentration defects. Weld toes, Attachments, Bends, Lower furnace walls, Economiser, Header
stub welds. Pressure stresses are not normally a significant contribution to the loading
mechanism. Understanding the causes of fatigue cracking depends on understanding
the loading mechanism.
Fatigue Failures
High cycle fatigue - vibrational loads Flow induced vibration. Attemperator nozzles.
Thermo- Mechanical Fatigue Loads normally caused by constrained thermal
expansion Differential expansion.
Fatigue Failures
Pad weld repair showing renewed corrosion fatigue crack growth
Fatigue Failures Corrosion Fatigue
Solutions Provide additional flexibility through modifications. Increasing
flexibility is normally a better solution than increasing strength of design.
Take operational means to avoid thermal shocks Boiler re-circulation through economiser Control of forced cooling procedures NDT and repair at overhauls, Combinations of MPI and
Ultrasonics at targeted locations is effective at managing failures
Chemical controls where appropriate for Corrosion Fatigue
Fatigue Failures
Creep Fatigue Joint action of creep damage and fatigue damage From Creep crack growth due to a cyclic stress at
temperature enhanced fatigue Distribution tends to match temperature distribution High temperature pipe and header attachments
Fatigue Failures
FIRESIDE CORROSION
Appearance
Thin edge split of the tube
– Typically a third to half wall failure in superheater tubes
– Typically 1-2 mm on reheater tubes and thinner on stainless reheater tubes
Thick fused deposits on ferritic tubes
Pitted "orange peel" appearance or corrosion flats on Austenitic tubes
Location
High temperature section of Final S/H and R/H
Localised to tube attachments C+T, wrapper tubes
Fireside Corrosion
Causes - S/H & R/H corrosion Molten sulphate attack
– Formation of Na, K trisulphate. Strong evidence of a correlation with coal CI High metal temperatures
– High metal temps melt sulphate. Bell shape corrosion curve, peak 650-750°C – Combined with accelerated oxidation– High gas temperature, gas laning, tube alignment
Combination with creep Materials factors
– Carburisation, inadequate materials, poor HT – 310 2.5 x better than 18Cr8Ni Steel ??
Fireside Corrosion
Solutions NDT thickness testing.
EMATs on ferritic tubes Materials replacement judged on remanent life assessment Materials Upgrade - Co-extruded/Higher grade materials Reduction of metal temperatures (S/H R/H steam temps)
Fireside Corrosion
Causes -Furnace Wall Corrosion Reducing furnace atmosphere adjacent to furnace wall
– This causes sulphidation attack H2S, CO & HCl. Fuel composition There is some correlation between coal CI content and corrosion but less
than for R/H and S/H corrosion Combustion environment is the most important factor
Poor combustion, flame impingement Low furnace excess air levels, NOx abatement Worn or poorly adjusted burners PF Quality Proximity of burners to side wall, flame length and distance from rear wall
Furnace Wall Corrosion
Mechanical Solutions NDT thickness testing
EMATs on ferritic tubes Replacement Materials Upgrade - Co-extruded Weld cladding, plasma coatings
Combustion Solutions Improvement of combustion to avoid localised reducing conditions Excess air levels, PF quality, blanket air on furnace walls, burner
maintenance Fuel specification Improvement
Corrosion may be economically the best option due to savings in excess air, NOX
Furnace Wall Corrosion
OXIDATION
Accelerated Oxidation
Oxide growth rates normally decrease with oxide thickness
Temperature transients cause cracking of the oxide and spallation and increases oxidation rate
Excessive temperatures produce non protective oxides
NDT preparation Oxidation and wall loss also occurs on
the steam side Reheater more susceptible
Stainless steel internal oxide spalling Oxide can gather in bends and cause
blockage
Steam oxidation producing laminated scale on internal bore of 2¼Cr1Mo reheater tubing
Oxidation
EROSION
Dust Erosion Proportional to:
– Ash wt.%, – Hardness of ash Quartz content– Angle of impact– Gas velocity to the 3-4 power
Erosion sensitive to coal diet and load Details of design that cause locally increased velocity and laning of dust Slagging and dust build up causing gas laning
Solutions Normally managed by inspection and shielding
Sootblower Erosion Mainly as above but velocity provided by s/b Largely managed by s/b maintenance and shielding
Erosion
MECHANICAL / MANUFACTURING
Slag falls mainly on ash slope and around the ash throat Slagging coals Operation at base load with low excess air levels
Outage and maintenance damage Removal of slag & ash bridges Sootblower lances grinding, arc strikes, burning off attachments
Mechanical - Impact
Fretting is the wear caused by small movements between contacting metal surfaces Rubbing contact removes protective oxides Fretting wear occurs mostly on contact of similar metals. Does not require
high contact loads. Stainless more prone than low alloy steels.
Location Vibrational contact between tubes in platen superheaters. Finger fretting on
stainless element wraps.
Mechanical - Fretting
Materials defects ERW defects, tube laps and scores, incorrect material/heat treatment
Weld defects Welding defects, pinholes, lack of fusion, porosity etc. Reheat cracking, hot cracking, Hydrogen cracking, lamella tearing
Transition weld failure Materials transition failure in a brittle manner along the weld interface
– Carbide migration leads to decarburised zone. Differential thermal expansion. Tri-axial constraint
Stress Corrosion Initiation and growth of cracks under stress and corrosion
– Austenitic Stainless steel increased due to sensitisation– Ferritic steels of high hardness, bolting materials.
Other Mechanisms
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