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    Efficacy of water spray protection against

    butane jet fires impinging on Liquefied

    Petroleum Gas (LPG) storage tanks

    Prepared by

    Shell Global Solutions (UK)

    for the Health and Safety Executive

    CONTRACT RESEARCH REPORT

    298/2000

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    Efficacy of Water Spray Protection Against Butane Jet Fires

    Impinging on LPG Storage Tanks

    LC Shirvill and JF Bennett

    HSE Consultancy

    Shell Global Solutions (UK)

    Cheshire Innovation Park

    PO Box 1

    CHESTER

    CH1 3SH

    Liquefied Petroleum Gas (LPG) storage tanks are often provided with water sprays to protect

    them in the event of a fire. In 1996 a project (Contract No. 3383/R75.009) was undertaken to

    study, at full-scale, the performance of a water spray system on an empty 13 tonne LPG vessel

    under conditions of jet fire impingement from a nearby release of liquid propane. The results,

    reported in HSE report CRR 137/1997, showed that a typical water deluge system found on an

    LPG storage vessel cannot be relied upon to maintain a water film over the whole vessel

    surface in an impinging propane jet fire scenario.

    The objective of the work described in this report (Contract No. 3985/R75.041) was to extend

    the understanding to include butane jet fires. These were known to have somewhat different

    characteristics and may result in different conclusions to those drawn from the earlier work

    with propane.

    A total of twenty butane tests are reported and these provide a direct comparison with the

    propane study. The results were in fact similar in that the water deluge did not always prevent

    dry patches appearing along the top of the vessel, although these were generally smaller than

    with the propane jet fires. The deluge also had a similar significant effect on the fire itself,

    reducing the luminosity and smoke, and resulting in a lower rate of wall temperature rise at the

    dry patches, when compared with the un-deluged case. One of the tests was repeated and run

    for a longer duration, 10 minutes, at which time the maximum temperature of the small dry

    patch had stabilised at 360oC. In the final test this was repeated again for more than twice this

    time, but with one of the spray nozzles blocked to produce a larger dry patch. The maximum

    temperature of this larger patch stabilised at 580oC. At this temperature the steel wall will be

    severely weakened but may not necessarily fail.The results of this study will be used by the HSE in assessing the risk of accidental fires on

    LPG installations leading to BLEVE incidents.

    This report and the work it describes were funded by the Health and Safety Executive. Its

    contents, including any opinions and/or conclusions expressed, are those of the author(s) alone

    and do not necessarily reflect HSE policy.

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    Crown copyright 2000Applications for reproduction should be made in writing to:Copyright Unit, Her Majestys Stationery Office,St Clements House, 2-16 Colegate, Norwich NR3 1BQ

    First published 2000

    ISBN 0 7176 1856 0

    All rights reserved. No part of this publication may bereproduced, stored in a retrieval system, or transmittedin any form or by any means (electronic, mechanical,photocopying, recording or otherwise) without the priorwritten permission of the copyright owner.

    ii

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    iii

    CONTENTS

    1. INTRODUCTION............................................................................................................1

    2. EXPERIMENTAL PLAN ................................................................................................1

    3. DESCRIPTION OF EQUIPMENT..................................................................................2

    3.1 BUTANE SUPPLY AND DISCHARGE SYSTEM....................................................2

    3.2 BUTANE FLOW MEASUREMENT..........................................................................2

    3.3 BUTANE PRESSURES AND TEMPERATURES .....................................................4

    3.4 TARGET VESSEL AND TEMPERATURE MEASUREMENTS ..............................4

    3.5 DELUGE WATER SUPPLY AND DELIVERY SYSTEM.........................................6

    3.6 AMBIENT WEATHER MONITORING ....................................................................8

    3.7 DATA LOGGING......................................................................................................8

    3.8 PHOTOGRAPHY AND VIDEO.................................................................................9

    4. RESULTS AND DISCUSSION .......................................................................................9

    4.1 TESTS DEL0401 TO DEL0423 .................................................................................9

    4.2 TESTS DEL0424 AND DEL0425............................................................................14

    5. CONCLUSIONS............................................................................................................17

    6. REFERENCES...............................................................................................................17

    7. APPENDICIES A-T.......................................................................................................18

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    1

    1. INTRODUCTION

    Liquefied Petroleum Gas (LPG) storage tanks are often provided with water sprays, referred toas water deluge, to protect them in the event of a fire. This protection has been shown to be

    effective in a pool fire(1)but uncertainties remained regarding the degree of protection afforded

    in a jet fire resulting from a liquid or two-phase release of LPG. The essential difference

    between a pool fire and a jet fire is that the latter can result in higher velocities and in the

    extreme case of a high-pressure natural gas jet fire water deluge has been shown to be totally

    ineffective(2).

    In 1996 a project (Contract No. 3383/R75.009) was undertaken to study, at full-scale, the

    performance of a water spray system on an empty 13 tonne LPG vessel under conditions of jet

    fire impingement from a nearby release of liquid propane. The results, reported in HSE report

    CRR 137/1997(3), showed that a typical water deluge system found on an LPG storage vessel

    cannot be relied upon to maintain a water film over the whole vessel surface in an impingingpropane jet fire scenario. The results of this study have been used by the HSE in assessing the

    risk of accidental fires on LPG installations leading to BLEVE incidents, but they are specific

    to propane fires only.

    The objective of the work described in this report was to extend the understanding to include

    butane jet fires, using the same equipment and a similar experimental plan to provide a direct

    comparison with the propane study. Butane jet fires were known to have somewhat different

    characteristics and it was felt that this may result in different conclusions to those drawn from

    the earlier work with propane.

    Section 2. of this report describes the experimental plan, developed in consultation with the

    HSE sponsor, and Section 3. describes the equipment used. Selected results are presented anddiscussed in Section 4. The complete sets of results for each of the twenty valid tests are

    contained in Appendices A-T. Section 5. presents the conclusions drawn from the work,

    however it should be noted that the data gathered has only been analysed to the extent that it

    could be accurately presented. A more detailed analysis may reveal additional features.

    2. EXPERIMENTAL PLAN

    The plan was to repeat the earlier propane study using butane to provide a direct comparison.

    The same hole sizes and distances, based on credible accident scenarios considered in the HSE

    model ALIBI (Assessment of LPG Installations leading to Bleve Incidents)(4), were used.

    The butane jet fires, from 12.5, 25 and 50 mm holes, were to impinge on a target vessel (an

    empty 13 tonne LPG tank) from distances of 1, 3 and 5 m. The parametric study was based

    on this 3x3 test matrix and each set of conditions were to be carried out both with the water

    deluge on before the fire, and with a 30 s delay in initiating the deluge. It was decided that the

    short duration tests without any water deluge, carried out in the propane study, would not be

    repeated as sufficient data on heat transfer without water could be obtained during the first 30 s

    of the delayed deluged tests.

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    2

    Our aim was to release butane under conditions closely similar to those that would occur if a

    pipe were punctured or severed on an LPG installation. The 12.5 and 25 mm holes were to be

    sharp-edged orifice plates on the end of a 50 mm pipe to achieve liquid releases of

    approximately 1 and 4 kg/s, respectively. The 50 mm release would be full-bore from the pipe,

    resulting in a liquid release of approximately 9 kg/s.

    The tests were to be of longer duration than typically used in the earlier propane study, and iftime permitted one test would be repeated and run for at least 10 minutes.

    3. DESCRIPTION OF EQUIPMENT

    The equipment used was the same as in the earlier propane tests, but with some modifications

    to more precisely control the discharge conditions, and more thermocouples on the target vessel

    to achieve better spatial resolution.

    3.1 BUTANE SUPPLY AND DISCHARGE SYSTEM

    A schematic diagram of the butane supply, control and measurement system is shown in

    Figure 1. The LPG storage tank, containing commercial grade butane, was elevated to achieve

    a positive liquid head at the discharge orifice. The objective was to maintain the liquid butane

    at just above its vapour pressure at the point of discharge and to achieve this in a controlled

    manner it was necessary to over-pressure the storage with nitrogen. During the tests, the

    nitrogen pressure was maintained using an Alfa Laval ECA-40 controller and Valtek pressure

    control valve. Using this arrangement some nitrogen becomes dissolved in the butane. Samples

    were taken after two of the tests and analysed, the results are given in Section 4.

    The butane was discharge from the tank through three independent valves into a common50 mm i.d. pipe into an existing supply line. This line was constructed from 149 mm i.d.

    stainless steel pipe and extended for about 25 metres between the storage tank and the

    discharge platform. Several manual and remotely operated valves were located in the line,

    together with thermal pressure relief valves. At the discharge platform the line reduced to

    50 mm i.d. stainless steel and terminated in the final, remotely operated, valve used to initiate

    the release. Spool pieces, also 50 mm internal diameter, were used beyond the final valve to

    achieve the three discharge distances of 1, 3 and 5 metres. Details of the discharge distances

    are shown in Figure 2. The 12.5, 25.0 mm releases were through sharp-edged orifice plates and

    the 50 mm release was full-bore.

    3.2 BUTANE FLOW MEASUREMENT

    The mass flow rate of the butane was measured using a Coriolis-force mass flow meter,

    mounted in the butane delivery line, approximately 8 m upstream of the final valve. This flow

    meter comprised a Micro Motion flow sensor and a mass flow transmitter. The sensor was

    calibrated by the manufacturer and is accurate to within 0.5% of the mass flow rate. The mass

    flow transmitter relayed the output of the flow sensor to the data logging system, described in

    Section 3.7. The butane mass flow rate achieved was not controlled but governed by the

    diameter of the release orifice and the exit conditions.

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    3

    2 inch LPG discharge line

    N

    LPG storage tank

    Water storage tanks

    Water pump

    Water recirculation

    Buffer tank

    6 inch LPG discharge line

    Target vessel

    Water supply

    Nitrogen source

    LPG:- mass flow rate, kg/s.

    Water:- flow rate, l/min. pressure, barg.

    Exit conditions:- pressure, barg., temperature, deg C.

    Vapour pressure make-up

    Tank liquid head conditions:- pressure, barg. temperature, deg C.

    Tank vapour head conditions:-

    pressure, barg.

    Figure 1

    Schematic diagram of fuel / water storage and release systems

    1000

    3000

    5000

    Figure 2

    Fuel discharge point locations

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    3.3 BUTANE PRESSURES AND TEMPERATURES

    The static pressure and temperature of the butane was measured at a number of locations.

    Pressure and temperature at the exit of the storage tank, together with pressure and temperature

    close to the release point.

    The storage tank liquid head pressure was measured using an Ellison Sensors Intl Ltd.PR3100 pressure transmitter located in the liquid discharge from the tank. The range of this

    instrument was 0-20 bar, with a typical accuracy of 1.0% full scale, and a calibration was

    performed prior to installation. This instrument also served the Alfa Laval ECA-40 controller

    to maintain the nitrogen pressure blanket on the storage tank.

    A further Ellison Sensors Intl Ltd. PR3100 pressure transmitter, with a measuring range of 0-

    6 bar, with a typical accuracy of 1.0% full scale, was used to measure the pressure at the exit

    measurement position, 0.2 m upstream of the release point. The transmitter was calibrated on

    site, before and after the test series, using a Druck DPI 600 series digital pressure calibrator.

    The butane temperature was measured in the supply line and at the exit measurement position,

    using stainless steel sheathed mineral insulated type T thermocouples protruding inside thepipe. The thermocouple has an accuracy of 0.5C, and was connected via suitable

    compensating cable to the data logger.

    Data from the pressure transducers and temperature transmitters were recorded on the logging

    system described in Section 3.7 and converted to engineering units by applying the relevant

    calibration coefficients for each instrument.

    3.4 TARGET VESSEL AND TEMPERATURE MEASUREMENTS

    The target vessel was a redundant 13 tonne LPG storage bullet which had been modified for

    these experiments. The cylindrical shell was 2.17 m dia. x 7.5 m long, and fitted with

    torispherical end caps. The total surface area of the vessel was estimated to be 61.3 m2

    (basedon the simplifying assumption of spherically dished end caps), 51.15 m2 over the developed

    cylindrical surface. To measure the temperature of the 12 mm thick wall of the shell, 85

    thermocouples were attached to the internal surface. These comprised the original locations, 1

    to 56 for tests prior to this series plus an extra 29 thermocouples, 57 to 85. These were placed

    in an area that could be subjected to hot spots and could therefore provide increased

    resolution of the surface temperatures. The locations of these thermocouples are indicated and

    defined in Figures 3 to 5.

    At all locations the thermocouples were attached directly to the steel by capacitance discharge

    welder. The welder, type TAU, was supplied by Cooperheat Ltd. Solid conductor, 0.7 mm

    dia., type 'K' thermocouple wire supplied by Omega was used. Each leg of the thermocouple

    was welded separately to the steel, approximately 5 mm apart. Thus the steel becomes part ofthe thermocouple junction and the thermocouple accurately and unambiguously measures the

    steel temperature. The thermocouple cable was extended out of and beyond the vessel into a

    junction box. In this box type 'K' connector blocks were used to transfer the thermocouple

    output signals into multicored type 'V' compensating cables and hence to the data collection

    point.

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    5

    A B C D E F G H I

    Centre line of vessel

    CA DA

    DB

    EA

    EB

    FA

    1000.0

    2000.0

    2375.0

    2750.0

    3125.0

    3312.5

    3500.0 to Centre Line

    3687.5

    3875.0

    4250.0

    4625.0

    5000.0

    6000.0

    7000.0

    Figure 3

    Thermocouple ring locations

    3

    2

    1

    4

    7

    6

    5

    8

    13

    12

    11

    10

    9

    16

    15

    14

    6870

    29

    28

    27

    26

    25

    32

    31

    30

    45

    44

    43

    42

    41

    48

    47

    46

    51

    50

    49

    52

    55

    54

    53

    56

    Ring A Ring B Ring C

    Ring DB Ring E Ring EA

    Ring G Ring H Ring I

    FlameDirection

    59

    5761

    60

    63

    66

    Ring CA

    Ring DA Ring EB

    Ring F Ring FA

    58

    21

    20

    19

    18

    17

    24

    23

    22

    Ring D

    62

    65

    67 64 69 71 7274

    7375

    78

    77

    79 76

    37

    36

    35

    34

    33

    40

    39

    38

    80

    83

    8185

    84

    82

    Figure 4

    Thermocouple locations on the various rings

    The type 'K' thermocouple wire used to measure the vessel temperatures was supplied to

    tolerance class 2 (International Thermocouple Reference Tables: IEC 584-2:1882 and BS 4937

    Part 20:1983), giving a tolerance value of +/-2.5C or 0.0075 x T, which ever is the greatest,

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    6

    within the limits of -40C to +1200C. Although suitable for lower temperatures, these

    thermocouples may not meet the tolerance value below -40C.

    1

    2

    3

    4

    5

    6

    7

    8

    9

    10

    11

    12

    13

    14

    15

    16

    17

    18

    19

    20

    21

    22

    23

    24

    25

    26

    27

    28

    29

    30

    31

    32

    33

    34

    35

    36

    37

    38

    39

    40

    41

    42

    43

    44

    45

    46

    47

    48

    49

    50

    51

    52

    53

    54

    55

    56

    57

    58

    59

    60

    61 62

    63

    64

    65

    66

    67

    68

    69

    70

    71

    72

    73

    74

    75

    76

    77

    78

    79 80

    81

    82

    83

    84

    85

    3 7 13 21 29 37 45 51 55

    A B C D E F G H I

    Rear

    Top of vessel

    Front

    Bottom

    OWater spraynozzle

    Thermocouple+

    Bottom

    Bottom rear

    Top rear

    Top front

    Bottom front

    Figure 5

    Development of thermocouple locations

    3.5 DELUGE WATER SUPPLY AND DELIVERY SYSTEM

    The deluge system was designed by Wormald Fire Systems to achieve a minimum application

    rate of 10.2 litres/min./m2 over the whole exposed surface of the vessel, in accordance with

    NFPA 15(5). This design was originally used in an investigation of the efficacy of water deluge

    systems used on offshore facilities(2)but it is identical to that commonly used to protect LPG

    storage bullets, the design application rate being just above the minimum of 9.8 litres/min./m2

    specified in HSG 34(6).

    Twenty four spray nozzles were used in sets of four around the vessel at an axial spacing of

    1475 mm, Figure 6. This Wormald design called for a total water flow rate into the system of

    1064 litres/min. delivered at 2.4 barg, and this was the nominal flow rate used in all of the

    tests. The vessel is 2.17 m dia. thus each set of four nozzles is spraying on an area of 10.06 m2.

    It is interesting to note that this results in an actual application rate of 17.6 litres/min./m2 on

    the cylindrical shell of the vessel, some 73% excess over the design value. This large excess is

    apparently an inevitable consequence of incremental spray nozzle sizes, the minimum spacing

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    required to ensure complete coverage and the hydraulic gradient required to achieve a minimum

    pressure of 1.4 barg at the most hydraulically remote nozzle, in this particular case.

    Centre line of vessel

    1475 147514751480 1480 2460

    2460

    Figure 6

    The target vessel indicating deluge nozzles

    The spray nozzles were Wormald type MV21-110, manufactured from leaded-gunmetal with

    brass diffuser plates.

    Figure 7, shows a photograph of the deluge operating and it can be seen that a water film was

    obtained over the whole surface of the vessel.

    Figure 7

    The target vessel with deluge nozzles operating

    The layout of the water supply system is included in Figure 1. Water for the deluge was stored

    in two large tanks in which the levels were balanced. A single outlet supplied water to a skid

    mounted water pump driven by a diesel engine. The speed of the pump could be varied

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    manually. Water was discharged into a 150 mm nominal bore pipe leading to the deluge

    system. Remotely operated valves enabled the water to be recirculated to the storage tanks.

    This arrangement permitted the pump engine to be brought up to operating temperature under

    working conditions and also enabled water at the required rate to flow into the deluge system at

    the desired instant during delayed deluge experiments.

    Deluge water pressure was measured with a Druck series PTX500 static pressure transducer.This instrument operated within the range of 0 to 10 barg with a typical accuracy of +/-1.0% of

    full scale and was calibrated on site using a Druck TPI 600 series digital pressure calibrator.

    The water flow rate was measured using a Krohne IFM1080 flow meter uprated to operate

    between 0 and 3000 litres/min. This instrument was supplied with a calibration produced by

    the Dutch Office of Measures and Weights. An uncertainty of +/-1.0% is quoted by the

    supplier.

    3.6 AMBIENT WEATHER MONITORING

    Equipment was deployed to monitor the ambient weather conditions in the vicinity of the test

    facility. The wind speed was monitored using four Vector Instruments A100 cup typeanemometers, located at heights of 1.2, 2.9, 6.0 and 6.4 m above the discharge axis on weather

    mast located to the west of the facility. The wind conditions were also measured using a Gill

    Instruments, Solent logging ultrasonic anemometer, located at a height of 10.0 m above the

    ground, equating to 8.2 m above the discharge axis. This instrument provided horizontal and

    vertical wind speed components together with the wind direction.

    The cup type anemometers can measure wind speed in the range 0 to 25 m/s and the accuracy

    is quoted by the manufactures as 1%. The ultrasonic anemometer is capable of measuring

    horizontal wind speeds in the range 0 to 60 m/s. The wind speed accuracy is 2.5% between 0

    and 30 m/s. The accuracy of the vertical component is within 5% of the horizontal

    component. Wind direction is measured in meteorological format i.e. as the direction the wind

    is coming from, measured clockwise from north, with an accuracy of 2% for wind speedsbetween 0 and 30 m/s.

    The ambient temperature and relative humidity were measured using a Vaisala HMD 30YB

    transmitter. This instrument was mounted on the control cabin roof. The atmospheric pressure

    was also monitored using a Vaisala PTA427 transmitter. The accuracy of the measurements,

    quoted by the manufacturers, are 0.2C for the temperature, 2% for the relative humidity

    between 0 and 90% and 3% between 90 and 100%, and 0.2 mbar for the atmospheric

    pressure.

    Data from all the ambient weather monitoring equipment was recorded on the logging system

    described in Section 3.7 and converted to engineering units applying the relevant calibration

    coefficients for each instrument.

    3.7 DATA LOGGING

    Data from all instruments were recorded using a PC based computer logging system. This

    system is based on multiplexing of signals at remote locations using equipment manufactured

    by Computer Instrumentation Limited. The concept of using this approach is based on limiting

    the amount of cabling running between the computer and the instrumentation. Individual cables

    from the instruments are fed into a multiplexer system located close to a group of instruments

    from which only one signal cable is returned to the computer. This system also has the added

    advantage that signals can be amplified by the multiplexer close to their source, thus avoiding

    the transmission of small signal levels over long distances.

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    Each instrument channel was sampled at once per second for the duration of each test.

    3.8 PHOTOGRAPHY AND VIDEO

    A video and photographic record was made of each test.

    4. RESULTS AND DISCUSSION

    4.1 Tests DEL0401 to DEL0423

    To complete the 3x3x2 test matrix (12.5, 25 and 50 mm holes, from distances of 1, 3 and 5 m,

    with deluge on before the fire, and with a 30 s delay) a total of 23 tests were carried out to

    achieve 18 valid tests. Tests DEL0401, DEL0406, DEL0407, DEL04014 and DEL04015 were

    deemed invalid, due to sudden changes in the wind or failure to reach steady flow conditions,and are not reported. Table 1 shows hole sizes, stand-off distances, and series test numbers for

    the 18 valid tests, together with the time averaging period used in deriving the subsequent data

    tables. Each test was run for at least 3 minutes and stopped when the vessel temperatures

    appeared to have stabilised, or in one case just under 7 minutes was reached.

    Table 1

    Series test numbers and averaging periods

    Deluge on Deluge delayed by 30 s.

    Hole dia., mm Stand off distance, m.

    Test number Averagingperiod, s.

    Test number Averagingperiod, s.

    12.5 1 DEL0402 9 to 335 DEL0403 56 to 277

    12.5 3 DEL0417 9 to 402 DEL0416 57 to 244

    12.5 5 DEL0418 7 to 364 DEL0419 97 to 279

    25.0 1 DEL0404 6 to 231 DEL0405 57 to 235

    25.0 3 DEL0412 4 to 302 DEL0413 56 to 252

    25.0 5 DEL0420 6 to 302 DEL0421 57 to 243

    50.0 1 DEL0408 9 to 243 DEL0409 62 to 30250.0 3 DEL0410 20 to 208 DEL0411 56 to 221

    50.0 5 DEL0422 8 to 242 DEL0423 63 to 302

    Table 2 shows the time averaged wind speeds and directions for each test. The averaged wind

    speeds of between 3 and 10 m/s were slightly higher than those encountered in the earlier

    propane tests, 1.6-7.8 m/s. A south westerly co-flowing wind would have ensured that the jet

    fire was central on the target vessel, however, a cross wind generally from the quadrant

    between west and north was deemed acceptable.

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    Table 2

    Series winds speeds and directions

    Deluge on Deluge delayed by 30 s.

    Hole dia., mm Stand off distance, m.

    Wind speed,m/s

    Winddirection,

    degs.

    Wind speed, m/s Winddirection,

    degs.

    12.5 1 2.98 8 2.49 314

    12.5 3 3.87 271 4.27 271

    12.5 5 6.40 260 8.64 261

    25.0 1 3.09 276 3.11 280

    25.0 3 3.78 262 3.60 266

    25.0 5 10.06 264 7.70 264

    50.0 1 2.83 284 2.86 289

    50.0 3 2.92 250 3.03 249

    50.0 5 9.23 265 9.23 267

    Table 3 shows the butane discharge conditions for each test. The nitrogen used to over-pressure

    the butane storage was just sufficient to achieve fully liquid releases. The exit temperature,

    measured just upstream of the hole, remained close to ambient, confirming that no flashing had

    occurred at that point and that fully liquid releases had been achieved.

    Table 3

    Series discharge conditions

    Deluge on Deluge delayed by 30 s.

    Hole dia.,

    mm

    Stand off

    distance,

    m.

    Mass flow

    rate, kg/s

    Exit

    temperature,

    de C

    Exit

    pressure,

    bar .

    Mass

    flow

    rate, k /s

    Exit

    temperature,

    de C

    Exit

    pressure,

    bar .

    12.5 1 1.00 10.1 1.3 1.01 8.9 1.3

    12.5 3 1.02 7.6 1.4 1.03 7.6 1.4

    12.5 5 1.01 7.1 1.4 0.90 6.5 1.4

    25.0 1 3.87 6.6 1.2 3.86 6.6 1.2

    25.0 3 3.77 8.1 1.5 3.63 8.0 1.6

    25.0 5 4.02 8.0 1.4 3.88 8.8 1.4

    50.0 1 9.40 5.6 1.0 8.71 4.5 1.0

    50.0 3 8.94 5.5 1.2 8.54 T/C failed 1.3

    50.0 5 9.61 8.3 1.1 9.10 7.8 1.1

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    Liquid butane samples were taken from the storage tank part way through use of the first and

    second deliveries of commercial butane. The results are shown in Table 4. Both samples

    contained some propane, which is not uncommon in commercial butane. As expected a small

    amount of the nitrogen used to over-pressure the storage had dissolved in the butane

    Table 4

    Analysis of butane samples

    Component Sample 1

    % mole

    Sample 2

    % mole

    Propane 11.6 4.0

    Isobutane 21.1 21.9

    N-butane 65.2 70.7

    Trans-2-butene 0.1 0.1

    Isopentane 1.4 2.6

    N-pentane 0.2 0.5

    Nitrogen 0.3 0.2

    The full results from each of the 18 tests are contained in Appendices A to R. Each appendix

    contains:

    a summary of the test conditions

    Figure x1 showing the fuel conditions during the test

    Figure x2 showing the water deluge conditions during the test

    Figures x3-x17, for each ring of thermocouples, showing the target vessel temperatures

    during the test

    Figures x18 and x19, development of the vessel surface with temperature contours, at 30 s

    after ignition on the delayed deluge tests only, and for all at the end of the test .

    Table 5 summarises the results, showing the different vessel wall temperature regimes found in

    each test. The 120

    o

    C criterion, also used in the earlier propane study, was chosen based on thework of Lev and Strachan(7)which showed that this temperature may be taken as "indicative of

    having achieved critical conditions for failure of the water film".

    Table 5 shows that when starting with the deluge on, only the larger releases result in dry

    patches. The largest dry patch being in test DEL0422 (50 mm hole, 5 m distance) where 4

    thermocouples exceeded 120oC, also see Appendix Q, Figure Q18.

    With the deluge delayed by 30 seconds dry patches are more readily formed but for the smallest

    hole size these do not persist. Again the largest dry patch occurred with the largest hole and the

    greatest distance, test DEL0423, also see Appendix R, Figure R19.

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    Table 5

    Series temperature regimes

    Deluge on Deluge delayed by 30 s.

    Hole dia.,

    mm

    Stand off

    distance,m.

    Maximum

    temp., degC

    Number

    of T/Csexceeding

    120 deg C

    Number

    of T/Csstaying in

    excess of

    120 deg C

    Maximum

    temp., degC

    Number

    of T/Csexceeding

    120 deg C

    Number of

    T/Csstaying in

    excess of

    120 deg C

    12.5 1 93 0 0 137 10 0

    12.5 3 95 0 0 137 10 0

    12.5 5 98 0 0 98 0 0

    25.0 1 103 0 0 185 19 1

    25.0 3 101 0 0 239 30 7

    25.0 5 174 1 1 283 18 6

    50.0 1 140 1 1 229 28 3

    50.0 3 107 0 0 292 26 4

    50.0 5 233 4 4 332 20 8

    Figure 8 shows an example of some target vessel wall temperatures during test DEL0409

    (50 mm hole, 1 m distance, delayed deluge). The thermocouple responses plotted were chosen

    to illustrate the different types of behaviour found in all of the tests. The last two digits of the

    identifier give the thermocouple location, see Figure 5 in Section 3.4, thus TK-40925 isthermocouple 25 located at the top of the vessel in the centre.

    0

    50

    100

    150

    200

    250

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    Time from ignition, s.

    Temperature

    ,degC. TK-40925

    TK-40963

    TK-40964

    TK-40966

    TK-40969

    120 degs

    Figure 8

    Example of wall temperatures during test DEL0409

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    The water deluge was initiated 30 seconds after ignition and the flow fully established by

    50 seconds. At some thermocouples locations, e.g. 63 and 64, a water film was quickly

    established and the wall temperature never exceeded the 120oC criterion. At location 66 a water

    film was established at 50 seconds even though the wall had initially exceeded 120oC. At

    locations 69 and 25 it is clear that once the water flow is fully established the rate of

    temperature rise is reduced. After 90 seconds a water film is established at location 69 and thetemperature drops 120

    oC. At location 25, the temperature continues to rise at the reduced rate.

    This reduced rate of temperature rise of dry patches was also seen in the earlier propane study

    and results from the combustion process being affected by the water sprays. Less soot is

    formed in the flame resulting in less luminosity and a reduction in the heat transfer by radiation

    to the vessel surface. This is most clearly illustrated by reference to Figures 9 and 10. These

    photographs were taken during test DEL0413, before and after establishment of the deluge.

    Figure 9

    Test DEL0413 before deluge

    Figure 10

    Test DEL0413 with deluge

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    In all of the tests where this behaviour was observed (DEL0409, DEL0411, DEL0413 and

    DEL0423) we have estimated the reduction in the rate of temperature rise at dry patches by

    comparing the essentially linear temperature rise before the water comes on, with that

    immediately after the deluge has become fully established. The results do not allow specific

    reductions in rate of temperature rise or heat transfer to be associated with particular

    conditions, but typically the reduction is a factor of between 2 and 5, similar to that found withpropane (between 1.5 and 5.8)

    (3).

    Some releases from 1 m and 3 m resulted in liquid butane impinging on the target vessel with

    local low temperatures on the vessel wall. Test DEL0409 is a good example, see Appendix F,

    Figures F18 and F19. In some tests some liquid butane poured onto the ground after hitting the

    vessel and produced a pool fire under the vessel.

    4.2 TESTS DEL0424 AND DEL0425

    Test DEL04024 was a repeat of test DEL0413 (25 mm hole, 3 m distance, delayed deluge) run

    for 10 minutes to establish the equilibrium temperature reached by a small dry patch. Test

    DEL04025 was a further repeat of this test, but with one nozzle blocked to induce a larger drypatch, and run for more than 20 minutes to establish the equilibrium temperature reached by a

    larger dry patch.

    Table 6 shows hole sizes, stand-off distances, and series test numbers for these two tests,

    together with the time averaging period used in deriving the subsequent data tables.

    Table 6

    Long duration test numbers and averaging periods

    Deluge on Deluge delayed by 30 s.

    Hole dia., mm Stand off distance, m.

    Test number Averagingperiod, s.

    Test number Averagingperiod, s.

    25.0 3 DEL0424 59 to 611

    25.0 3 DEL0425 57 to 1578

    Table 7 shows the time averaged wind speeds and directions for each test.

    Table 7

    Long duration tests wind speeds and directions

    Deluge on Deluge delayed by 30 s.

    Hole dia., mm Stand off

    distance, m.

    Wind speed,

    m/s

    Wind

    direction,

    degs.

    Wind speed, m/s Wind

    direction,

    degs.

    25.0 3 5.55 259

    25.0 3 7.40 261

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    Table 8 shows the butane discharge conditions for each test.

    Table 8

    Long duration tests discharge conditions

    Deluge on Deluge delayed by 30 s.

    Hole dia.,

    mm

    Stand off

    distance,

    m.

    Mass flow

    rate, kg/s

    Exit

    temperature,

    de C

    Exit

    pressure,

    bar .

    Mass

    flow

    rate, k /s

    Exit

    temperatur

    e, de C

    Exit

    pressure,

    bar .

    25.0 3 4.31 7.7 1.5

    25.0 3 4.57 6.9 1.5

    The full results from both of the tests are contained in Appendices S and T. Each appendix

    contains:

    a summary of the test conditions

    Figure x1 showing the fuel conditions during the test

    Figure x2 showing the water deluge conditions during the test

    Figures x3-x17, for each ring of thermocouples, showing the target vessel temperatures

    during the test

    Figures x18 and x19, development of the vessel surface with temperature contours, at 30 s

    after ignition on the delayed deluge tests only, and for all at the end of the test .Table 9

    summarises the results, showing the different vessel wall temperature regimes found in each

    test.

    Table 9

    Long duration tests temperature regimes

    Deluge on Deluge delayed by 30 s.

    Hole dia.,

    mm

    Stand off

    distance,

    m.

    Maximum

    temp., deg

    C

    Number

    of T/Cs

    exceeding

    120 deg C

    Number

    of T/Cs

    staying in

    excess of

    120 deg C

    Maximum

    temp., deg

    C

    Number

    of T/Cs

    exceeding

    120 deg C

    Number of

    T/Cs

    staying in

    excess of

    120 deg C

    25.0 3 372 27 6

    25.0 3 581 19 13

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    Figure 11 shows some of the dry spot wall temperatures during tests DEL0424 and DEL0425.

    Dry spot temperatures

    0

    100

    200

    300

    400

    500

    600

    060

    120

    180

    240

    300

    360

    420

    480

    540

    600

    660

    720

    780

    840

    900

    960

    1020

    1080

    1140

    1200

    1260

    1320

    1380

    1440

    1500

    1560

    Time from ignition, s.

    Temperature,deg,C.

    TK-42517

    TK-42560

    TK-42561

    TK-42562

    TK-42566

    TK-42567

    120 degs

    TK-42417

    TK-42457

    Figure 11

    Dry spot wall temperatures during tests DEL0424 and DEL0425

    The maximum temperature reached by the small dry spot (thermocouple location 17) in test

    DEL0424 was 360oC after 10 minutes. See also Appendix S, Figure S19, for details of the dry

    spot.

    The maximum temperature reached by the large dry spot (thermocouple location 62) in test

    DEL0425 was 580oC. It appears that thermocouple location 67 may be on the edge of the dry

    patch as the temperature was falling during the second half of the test. The gap in the data

    around 23 minutes was caused by the necessity to change disks in the data logging system. See

    also Appendix T, Figure T19, for details of the dry spot. The blocked water spray nozzle was

    the one above thermocouple location 24, see Figure 5 in Section 3.4.

    At the maximum temperature of 580oC the steel wall will be severely weakened but may not

    necessarily fail, resulting in a BLEVE if the vessel had contained LPG.

    Figure 12

    Test DEL0425

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    5. CONCLUSIONS

    The following conclusions are based on an analysis of the data sufficient only to allow it to be

    accurately reported. A more detailed analysis may reveal additional features.

    1. The results from the twenty tests reported show that a typical water deluge system

    found on an LPG storage tank cannot be relied upon to maintain a water film over the

    whole tank surface in an impinging butane jet fire scenario.

    2. The results are similar to those found in the earlier propane work, although any dry

    patches were generally smaller with the butane jet fires. The deluge also had a similar

    significant effect on the fire itself, reducing the luminosity and smoke, and resulting in

    a lower rate of wall temperature rise at the dry patches, when compared with the un-

    deluged case, typically by a factor between 2 and 5.

    3. The equilibrium temperature reached by a small dry patch was about 360oC after 10

    minutes, in one repeated test, run until an equilibrium temperature had been reached.

    4. The equilibrium temperature reached by a larger dry patch, induced by blocking one of

    the spray nozzles, was 580oC after about 20 minutes.

    5. Some releases resulted in liquid butane impinging on the target vessel with local low

    temperatures on the vessel wall. In some tests some liquid butane poured onto the

    ground after hitting the vessel and produced a pool fire under the vessel.

    6. REFERENCES

    1. Billinge, K, Moodie, K and Beckett, H. The use of Water Sprays to Protect Fire

    engulfed Storage Tanks, 5th International Symposium on Loss Prevention and Safety

    Promotion in Process Industries, 1986.

    2. Shirvill, LC and White, GC. Effectiveness of Deluge Systems in Protecting Plant and

    Equipment Impacted by High-Velocity Natural Gas Jet Fires, ICHMT 1994

    International Symposium on Heat and Mass Transfer in Chemical Process Industry

    Accidents, Rome 1994.

    3. Bennett, JF, Shirvill, LC and Pritchard, MJ. Efficacy of Water Spray ProtectionAgainst Jet Fires Impinging on LPG Storage Tanks, HSE Contract Research Report

    137/1997.

    4. Goose, MH. Recent Developments with ALIBI, a Model for Site Specific Prediction of

    LPG Tank BLEVE Frequency, IChemE Symposium Series No. 139, Major Hazards

    Onshore and Offshore II, Manchester 1995.

    5. NFPA 15, Water Spray Fixed Systems, National Fire Protection Association.

    6. HSG 34, The Storage of LPG at fixed Installations, HMSO.

    7. Lev, Y and Strachan, DC. A Study of Cooling Water Requirements for the Protection

    of Metal Surfaces Against Thermal Radiation, Fire Technology, August 1989.

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    7. APPENDICIES A-T

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    Appendix A - DEL0402

    Averaging period 9 - 335 seconds after ignition

    Summary of Release Exit Conditions

    Discharge hole diameter: 12.50 mm

    Stand-off Distance: 1.00 m

    Butane mass flow rate: 1.02 kg/s

    Exit static pressure: 1.33 barg

    Exit temperature 10.13 deg. C

    Deluge Flow

    Water sprays: Deluge on

    Water pressure 2.35 barg

    Water flow rate 1069.75 litres/min

    Ambient Weather Conditions

    Wind speed (cup anemometer 1 at 1.2m) 2.7 m/s

    Wind speed (cup anemometer 2 at 2.9m) 2.8 m/s

    Wind speed (cup anemometer 3 at 6.0m) 3.1 m/s

    Wind speed (cup anemometer 4 at 6.4m) 3.2 m/s

    Horizontal wind speed (sonic at 8.2m) No data m/s

    Vertical wind speed (sonic at 8.2m) No data m/s

    Wind direction 8.31 degrees clockwise from North

    Relative humidity 87.2 %

    Ambient temperature 12.2 deg CAtmospheric pressure 961.1 mbar

    Thermocouples not operating properly

    15, 79

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    Fuel flow 0402

    0.0

    0.5

    1.0

    1.5

    2.0

    2.5

    3.0

    3.5

    4.0

    4.5

    5.0

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    330

    Time from ignition, s.

    Massflow,kg/s

    &Pressure,barg.

    Mass flow , kg/s

    Vapour pressure,

    barg

    Liquid head

    pressure, barg

    Discharge

    pressure, barg

    Figure A1 - Fuel conditions

    Water flow 0402

    0.00

    0.50

    1.00

    1.50

    2.00

    2.50

    3.00

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    330

    Time from ignition, s.

    Pressure,barg

    &Flow

    m^3/min

    Water pressure,

    barg

    Water flow rate,

    m^3/min

    Figure A2 - Water deluge conditions

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    Ring A

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    330

    Time from ignition, s.

    Temperature,degC.

    TK-40201

    TK-40202

    TK-40203

    TK-40204

    120 deg C.

    Figure A3 - Temperatures - thermocouples 1 - 4

    Ring B

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    330

    Time from ignition, s.

    Temperature,deg

    C.

    TK-40205

    TK-40206

    TK-40207

    TK-40208

    120 deg C.

    Figure A4 - Temperatures - thermocouples 5 - 8

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    Ring C

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    330

    Time from ignition, s.

    Temperature,degC.

    TK-40209

    TK-40210

    TK-40211

    TK-40212

    TK-40213

    TK-40214

    TK-40215

    TK-40216

    120 deg C.

    Figure A5 - Temperatures - thermocouples 9 - 16

    Ring CA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    330

    Time from ignition, s.

    Temperature,deg

    C. TK-40257

    TK-40258

    TK-40259

    TK-40260

    TK-40261

    120 deg C.

    Figure A6 - Temperatures - thermocouples 57 - 61

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    Ring D

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    330

    Time from ignition, s.

    Temperature,degC.

    TK-40217

    TK-40218

    TK-40219

    TK-40220

    TK-40221

    TK-40222

    TK-40223

    TK-40224

    TK-40262

    120 deg C.

    Figure A7 - Temperatures - thermocouples 17 - 24 plus 62

    Ring DA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    330

    Time from ignition, s.

    Temperature,deg

    C. TK-40263

    TK-40264

    TK-40265

    TK-40266

    TK-40267

    120 deg C.

    Figure A8 - Temperatures - thermocouples 63 - 67

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    Ring DB

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    330

    Time from ignition, s.

    Temperature,degC.

    TK-40268

    TK-40269

    TK-40270

    120 deg C.

    Figure A9 - Temperatures - thermocouples 68 - 70

    Ring E

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    330

    Time from ignition, s.

    Temperature,degC.

    TK-40225

    TK-40226

    TK-40227

    TK-40228TK-40229

    TK-40230

    TK-40231

    TK-40232

    TK-40271

    120 deg C.

    Figure A10 - Temperatures - thermocouples 25 - 32 plus 71

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    Ring EA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    330

    Time from ignition, s.

    Temperature,degC.

    TK-40272

    TK-40273

    TK-40274

    120 deg C.

    Figure A11 - Temperatures - thermocouples 72 - 74

    Ring EB

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    330

    Time from ignition, s.

    Temperature,de

    gC. TK-40275

    TK-40276

    TK-40277

    TK-40278

    TK-40279

    120 deg C.

    Figure A12 - Temperatures - thermocouples 75 - 79

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    Ring F

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    330

    Time from ignition, s.

    Temperature,degC.

    TK-40233

    TK-40234

    TK-40235

    TK-40236

    TK-40237

    TK-40238

    TK-40239

    TK-40240

    TK-40280

    120 deg C.

    Figure A13 - Temperatures - thermocouples 33 - 40 plus 80

    Ring FA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    330

    Time from ignition, s.

    Temperature,deg

    C. TK-40281

    TK-40282

    TK-40283

    TK-40284

    TK-40285

    120 deg C.

    Figure A14 - Temperatures - thermocouples 81 - 85

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    Ring G

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    330

    Time from ignition, s.

    Temperature,degC.

    TK-40241

    TK-40242

    TK-40243

    TK-40244

    TK-40245

    TK-40246

    TK-40247

    TK-40248

    120 deg C.

    Figure A15 - Temperatures - thermocouples 41 - 48

    Ring H

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    330

    Time from ignition, s.

    Temperature,deg

    C.

    TK-40249TK-40250

    TK-40251

    TK-40252

    120 deg C.

    Figure A16 - Temperatures - thermocouples 49 - 52

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    Ring I

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    330

    Time from ignition, s.

    Temperature,degC.

    TK-40253

    TK-40254

    TK-40255

    TK-40256

    120 deg C.

    Figure A17 - Temperatures - thermocouples 53 - 56

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    A B C D E F G H I

    REAR

    TOP

    FRONT

    BOTTOM

    O Water spraynozzle

    Thermocouple+

    BOTTOM

    Temperature scale

    -20

    0

    120

    240

    360

    480

    Figure A18 Development of vessel with temperature contours at 335s after ignition.

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    Appendix B - DEL0403

    Averaging period 56 - 277 seconds after ignition

    Summary of Release Conditions

    Discharge hole diameter: 12.50 mm

    Stand-off Distance: 1.00 m

    Butane mass flow rate: 1.01 kg/s

    Exit static pressure: 1.31 barg

    Exit temperature 8.86 deg. C

    Deluge Flow

    Water sprays: Delayed by 30 secs

    Water pressure 2.35 barg

    Water flow rate 1069.38 litres/min

    Ambient Weather Conditions

    Wind speed (cup anemometer 1 at 1.2m) 2.0 m/s

    Wind speed (cup anemometer 2 at 2.9m) 2.0 m/s

    Wind speed (cup anemometer 3 at 6.0m) 2.2 m/s

    Wind speed (cup anemometer 4 at 6.4m) 2.3 m/s

    Horizontal wind speed (sonic at 8.2m) 2.49 m/s

    Vertical wind speed (sonic at 8.2m) 0.9 m/s

    Wind direction 314.29 degrees clockwise from North

    Relative humidity 88.7 %

    Ambient temperature 12.0 deg CAtmospheric pressure 961.6 mbar

    Thermocouples not operating properly

    15, 53, 54, 55, 79

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    Fuel flow 0403

    0.0

    0.5

    1.0

    1.5

    2.0

    2.5

    3.0

    3.5

    4.0

    4.5

    5.0

    030

    60

    90

    120

    150

    180

    210

    240

    270

    Time from ignition, s.

    Massflow,kg/s

    &Pressure,barg.

    Mass flow , kg/s

    Vapour pressure,

    barg

    Liquid head

    pressure, barg

    Discharge

    pressure, barg

    Figure B1 - Fuel conditions

    Water flow 0403

    0.00

    0.50

    1.00

    1.50

    2.00

    2.50

    3.00

    030

    60

    90

    120

    150

    180

    210

    240

    270

    Time from ignition, s.

    Pressure,barg

    &Flow

    m^3/min

    Water pressure,

    barg

    Water flow rate,

    m^3/min

    Figure B2 - Water deluge conditions

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    Ring A

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    Time from ignition, s.

    Temperature,degC.

    TK-40301

    TK-40302

    TK-40303

    TK-40304

    120 deg C.

    Figure B3 - Temperatures - thermocouples 1 - 4

    Ring B

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    Time from ignition, s.

    Temperature,deg

    C.

    TK-40305

    TK-40306

    TK-40307

    TK-40308

    120 deg C.

    Figure B4 - Temperatures - thermocouples 5 - 8

  • 8/13/2019 Analysis of Jetfires

    38/245

    33

    Ring C

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    Time from ignition, s.

    Temperature,degC.

    TK-40309

    TK-40310

    TK-40311

    TK-40312

    TK-40313

    TK-40314

    TK-40315

    TK-40316

    120 deg C.

    Figure B5 - Temperatures - thermocouples 9 - 16

    Ring CA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    Time from ignition, s.

    Temperature,deg

    C. TK-40357

    TK-40358

    TK-40359

    TK-40360

    TK-40361

    120 deg C.

    Figure B6 - Temperatures - thermocouples 57 - 61

  • 8/13/2019 Analysis of Jetfires

    39/245

    34

    Ring D

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    Time from ignition, s.

    Temperature,degC.

    TK-40317

    TK-40318

    TK-40319

    TK-40320

    TK-40321

    TK-40322

    TK-40323

    TK-40324

    TK-40362

    120 deg C.

    Figure B7 - Temperatures - thermocouples 17 - 24 plus 62

    Ring DA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    Time from ignition, s.

    Temperature,deg

    C. TK-40363

    TK-40364

    TK-40365

    TK-40366

    TK-40367

    120 deg C.

    Figure B8 - Temperatures - thermocouples 63 - 67

  • 8/13/2019 Analysis of Jetfires

    40/245

    35

    Ring DB

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    Time from ignition, s.

    Temperature,degC.

    TK-40368

    TK-40369

    TK-40370

    120 deg C.

    Figure B9 - Temperatures - thermocouples 68 - 70

    Ring E

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    Time from ignition, s.

    Temperature,degC.

    TK-40325

    TK-40326

    TK-40327

    TK-40328TK-40329

    TK-40330

    TK-40331

    TK-40332

    TK-40371

    120 deg C.

    Figure B10 - Temperatures - thermocouples 25 - 32 plus 71

  • 8/13/2019 Analysis of Jetfires

    41/245

    36

    Ring EA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    Time from ignition, s.

    Temperature,degC.

    TK-40372

    TK-40373

    TK-40374

    120 deg C.

    Figure B11 - Temperatures - thermocouples 72 - 74

    Ring EB

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    Time from ignition, s.

    Temperature,de

    gC. TK-40375

    TK-40376

    TK-40377

    TK-40378

    TK-40379

    120 deg C.

    Figure B12 - Temperatures - thermocouples 75 - 79

  • 8/13/2019 Analysis of Jetfires

    42/245

    37

    Ring F

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    Time from ignition, s.

    Temperature,degC.

    TK-40333

    TK-40334

    TK-40335

    TK-40336

    TK-40337

    TK-40338

    TK-40339

    TK-40340

    TK-40380

    120 deg C.

    Figure B13 - Temperatures - thermocouples 33 - 40 plus 80

    Ring FA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    Time from ignition, s.

    Temperature,deg

    C. TK-40381

    TK-40382

    TK-40383

    TK-40384

    TK-40385

    120 deg C.

    Figure B14 - Temperatures - thermocouples 81 - 85

  • 8/13/2019 Analysis of Jetfires

    43/245

    38

    Ring G

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    Time from ignition, s.

    Temperature,degC.

    TK-40341

    TK-40342

    TK-40343

    TK-40344

    TK-40345

    TK-40346

    TK-40347

    TK-40348

    120 deg C.

    Figure B15 - Temperatures - thermocouples 41 - 48

    Ring H

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    Time from ignition, s.

    Temperature,deg

    C.

    TK-40349TK-40350

    TK-40351

    TK-40352

    120 deg C.

    Figure B16 - Temperatures - thermocouples 49 - 52

  • 8/13/2019 Analysis of Jetfires

    44/245

    39

    Ring I

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    Time from ignition, s.

    Temperature,degC.

    TK-40353

    TK-40354

    TK-40355

    TK-40356

    120 deg C.

    Figure B17 - Temperatures - thermocouples 53 - 56

  • 8/13/2019 Analysis of Jetfires

    45/245

    40

    A B C D E F G H I

    REAR

    TOP

    FRONT

    BOTTOM

    O Water spraynozzle

    Thermocouple+

    BOTTOM

    Temperature scale

    -20

    0

    40

    80

    120

    Figure B18 Development of vessel with temperature contours at 30s after ignition.

    A B C D E F G H I

    REAR

    TOP

    FRONT

    BOTTOM

    O Water spraynozzle

    Thermocouple+

    BOTTOM

    Temperature scale

    -20

    0

    120

    240

    360

    480

    Figure B19 Development of vessel with temperature contours at 277s after ignition.

  • 8/13/2019 Analysis of Jetfires

    46/245

    41

    Appendix C - DEL0404

    Averaging period 6 - 231 seconds after ignition

    Summary of Release Conditions

    Discharge hole diameter: 25.0 mm

    Stand-off Distance: 1.00 m

    Butane mass flow rate: 3.87 kg/s

    Exit static pressure: 1.23 barg

    Exit temperature 6.62 deg. C

    Deluge Flow

    Water sprays: Deluge on

    Water pressure 2.34 barg

    Water flow rate 1071.53 litres/min

    Ambient Weather Conditions

    Wind speed (cup anemometer 1 at 1.2m) 2.3 m/s

    Wind speed (cup anemometer 2 at 2.9m) 2.5 m/s

    Wind speed (cup anemometer 3 at 6.0m) 2.7 m/s

    Wind speed (cup anemometer 4 at 6.4m) 2.8 m/s

    Horizontal wind speed (sonic at 8.2m) 3.09 m/s

    Vertical wind speed (sonic at 8.2m) 0.9 m/s

    Wind direction 276.20 degrees clockwise from North

    Relative humidity 91.3 %

    Ambient temperature 11.7 deg C

    Atmospheric pressure 962.0 mbar

    Thermocouples not operating properly

    15, 79

  • 8/13/2019 Analysis of Jetfires

    47/245

    42

    Fuel flow 0404

    0.0

    0.5

    1.0

    1.5

    2.0

    2.5

    3.0

    3.5

    4.0

    4.5

    5.0

    5.5

    6.0

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Massflow,kg/s

    &Pressure,barg.

    Mass flow , kg/s

    Vapour pressure,

    barg

    Liquid head

    pressure, barg

    Discharge

    pressure, barg

    Figure C1 - Fuel conditions

    Water flow 0404

    0.00

    0.50

    1.00

    1.50

    2.00

    2.50

    3.00

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Pressure,barg

    &Flow

    m^3/min

    Water pressure,

    barg

    Water flow rate,

    m^3/min

    Figure C2 - Water deluge conditions

  • 8/13/2019 Analysis of Jetfires

    48/245

    43

    Ring A

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,degC.

    TK-40401

    TK-40402

    TK-40403

    TK-40404

    120 deg C.

    Figure C3 - Temperatures - thermocouples 1 - 4

    Ring B

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,deg

    C.

    TK-40405

    TK-40406

    TK-40407

    TK-40408

    120 deg C.

    Figure C4 - Temperatures - thermocouples 5 - 8

  • 8/13/2019 Analysis of Jetfires

    49/245

    44

    Ring C

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,degC.

    TK-40409

    TK-40410

    TK-40411

    TK-40412

    TK-40413

    TK-40414

    TK-40415

    TK-40416

    120 deg C.

    Figure C5 - Temperatures - thermocouples 9 - 16

    Ring CA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,deg

    C. TK-40457

    TK-40458

    TK-40459

    TK-40460

    TK-40461

    120 deg C.

    Figure C6 - Temperature - thermocouples 57 - 61

  • 8/13/2019 Analysis of Jetfires

    50/245

    45

    Ring D

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,degC.

    TK-40417

    TK-40418

    TK-40419

    TK-40420

    TK-40421

    TK-40422

    TK-40423

    TK-40424

    TK-40462

    120 deg C.

    Figure C7 - Temperatures - thermocouples 17 - 24 plus 62

    Ring DA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,deg

    C. TK-40463

    TK-40464

    TK-40465

    TK-40466

    TK-40467

    120 deg C.

    Figure C8 - Temperature - thermocouples 63 - 67

  • 8/13/2019 Analysis of Jetfires

    51/245

    46

    Ring DB

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,degC.

    TK-40468

    TK-40469

    TK-40470

    120 deg C.

    Figure C9 - Temperature - thermocouples 68 - 70

    Ring E

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,degC.

    TK-40425

    TK-40426

    TK-40427

    TK-40428TK-40429

    TK-40430

    TK-40431

    TK-40432

    TK-40471

    120 deg C.

    Figure C10 - Temperature - thermocouples 25 - 32 plus 71

  • 8/13/2019 Analysis of Jetfires

    52/245

    47

    Ring EA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,degC.

    TK-40472

    TK-40473

    TK-40474

    120 deg C.

    Figure C11 - Temperature - thermocouples 72 - 74

    Ring EB

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,de

    gC. TK-40475

    TK-40476

    TK-40477

    TK-40478

    TK-40479

    120 deg C.

    Figure C12 - Temperature - thermocouples 75 - 79

  • 8/13/2019 Analysis of Jetfires

    53/245

    48

    Ring F

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,degC.

    TK-40433

    TK-40434

    TK-40435

    TK-40436

    TK-40437

    TK-40438

    TK-40439

    TK-40440

    TK-40480

    120 deg C.

    Figure C13 - Temperatures - thermocouples 33 - 40 plus 80

    Ring FA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,deg

    C. TK-40481

    TK-40482

    TK-40483

    TK-40484

    TK-40485

    120 deg C.

    Figure C14 - Temperatures - thermocouples 81 - 85

  • 8/13/2019 Analysis of Jetfires

    54/245

    49

    Ring G

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,degC.

    TK-40441

    TK-40442

    TK-40443

    TK-40444

    TK-40445

    TK-40446

    TK-40447

    TK-40448

    120 deg C.

    Figure C15 - Temperatures - thermocouples 41 - 48

    Ring H

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,deg

    C.

    TK-40449TK-40450

    TK-40451

    TK-40452

    120 deg C.

    Figure C16 - Temperatures - thermocouples 49 - 52

  • 8/13/2019 Analysis of Jetfires

    55/245

    50

    Ring I

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,degC.

    TK-40453

    TK-40454

    TK-40455

    TK-40456

    120 deg C.

    Figure C17 - Temperatures - thermocouples 53 - 56

  • 8/13/2019 Analysis of Jetfires

    56/245

    51

    A B C D E F G H I

    REAR

    TOP

    FRONT

    BOTTOM

    O Water spraynozzle

    Thermocouple+

    BOTTOM

    Temperature scale

    -20

    0

    120

    240

    360

    480

    Figure C18 Development of vessel with temperature contours at 231s after ignition.

  • 8/13/2019 Analysis of Jetfires

    57/245

    52

    Appendix D - DEL0405

    Averaging period 57 - 235 seconds after ignition

    Summary of Release Conditions

    Discharge hole diameter: 25.0 mm

    Stand-off Distance: 1.00 m

    Butane mass flow rate: 3.86 kg/s

    Exit static pressure: 1.23 barg

    Exit temperature 6.62 deg. C

    Deluge Flow

    Water sprays: Delayed by 30 secs

    Water pressure 2.36 barg

    Water flow rate 1069.69 litres/min

    Ambient Weather Conditions

    Wind speed (cup anemometer 1 at 1.2m) 2.1 m/s

    Wind speed (cup anemometer 2 at 2.9m) 2.3 m/s

    Wind speed (cup anemometer 3 at 6.0m) 2.5 m/s

    Wind speed (cup anemometer 4 at 6.4m) 2.6 m/s

    Horizontal wind speed (sonic at 8.2m) 3.11 m/s

    Vertical wind speed (sonic at 8.2m) 0.9 m/s

    Wind direction 279.81 degrees clockwise from North

    Relative humidity 92.1 %

    Ambient temperature 11.6 deg C

    Atmospheric pressure 962.4 mbar

    Thermocouples not operating properly

    15, 79

  • 8/13/2019 Analysis of Jetfires

    58/245

  • 8/13/2019 Analysis of Jetfires

    59/245

    54

    Ring A

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,degC.

    TK-40501

    TK-40502

    TK-40503

    TK-40504

    120 deg C.

    Figure D3 - Temperatures - thermocouples 1 - 4

    Ring B

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,deg

    C.

    TK-40505

    TK-40506

    TK-40507

    TK-40508

    120 deg C.

    Figure D4 - Temperatures - thermocouples 5 - 8

  • 8/13/2019 Analysis of Jetfires

    60/245

    55

    Ring C

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,degC.

    TK-40509

    TK-40510

    TK-40511

    TK-40512

    TK-40513

    TK-40514

    TK-40515

    TK-40516

    120 deg C.

    Figure D5 - Temperature - thermocouples 9 - 16

    Ring CA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,deg

    C. TK-40557

    TK-40558

    TK-40559

    TK-40560

    TK-40561

    120 deg C.

    Figure D6 - Temperatures - thermocouples 57 - 61

  • 8/13/2019 Analysis of Jetfires

    61/245

    56

    Ring D

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,degC.

    TK-40517

    TK-40518

    TK-40519

    TK-40520

    TK-40521

    TK-40522

    TK-40523

    TK-40524

    TK-40562

    120 deg C.

    Figure D7 - Temperatures - thermocouples 17 - 24 plus 62

    Ring DA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,deg

    C. TK-40563

    TK-40564

    TK-40565

    TK-40566

    TK-40567

    120 deg C.

    Figure D8 - Temperatures - thermocouples 63 - 67

  • 8/13/2019 Analysis of Jetfires

    62/245

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    63/245

    58

    Ring EA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,degC.

    TK-40572

    TK-40573

    TK-40574

    120 deg C.

    Figure D11 - Temperatures - thermocouples 72 - 74

    Ring EB

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,de

    gC. TK-40575

    TK-40576

    TK-40577

    TK-40578

    TK-40579

    120 deg C.

    Figure D12 - Temperatures - thermocouples 75 - 79

  • 8/13/2019 Analysis of Jetfires

    64/245

    59

    Ring F

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,degC.

    TK-40533

    TK-40534

    TK-40535

    TK-40536

    TK-40537

    TK-40538

    TK-40539

    TK-40540

    TK-40580

    120 deg C.

    Figure D13 - Temperatures - thermocouples 33 - 40 plus 80

    Ring FA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,deg

    C. TK-40581

    TK-40582

    TK-40583

    TK-40584

    TK-40585

    120 deg C.

    Figure D14 - Temperatures - thermocouples 81 - 85

  • 8/13/2019 Analysis of Jetfires

    65/245

    60

    Ring G

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,degC.

    TK-40541

    TK-40542

    TK-40543

    TK-40544

    TK-40545

    TK-40546

    TK-40547

    TK-40548

    120 deg C.

    Figure D15 - Temperatures - thermocouples 41 - 48

    Ring H

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,deg

    C.

    TK-40549TK-40550

    TK-40551

    TK-40552

    120 deg C.

    Figure D16 - Temperatures - thermocouples 49 - 52

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    61

    Ring I

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    Time from ignition, s.

    Temperature,degC.

    TK-40553

    TK-40554

    TK-40555

    TK-40556

    120 deg C.

    Figure D17 - Temperatures - thermocouples 53 - 56

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    67/245

    62

    A B C D E F G H I

    REAR

    TOP

    FRONT

    BOTTOM

    O Water spraynozzle

    Thermocouple+

    BOTTOM

    Temperature scale

    -20

    0

    40

    80

    120

    Figure D18 Development of vessel with temperature contours at 30s after ignition.

    A B C D E F G H I

    REAR

    TOP

    FRONT

    BOTTOM

    O Water spraynozzle

    Thermocouple+

    BOTTOM

    Temperature scale

    -20

    0

    120

    240

    360

    480

    Figure D19 Development of vessel with temperature contours at 235s after ignition.

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    63

    Appendix E - DEL0408

    Averaging period 9 - 243 seconds after ignition

    Summary of Release Conditions

    Discharge hole diameter: 50.0 mm

    Stand-off Distance: 1.00 m

    Butane mass flow rate: 9.40 kg/s

    Exit static pressure: 1.04 barg

    Exit temperature 5.63 deg. C

    Deluge Flow

    Water sprays: Deluge on

    Water pressure 2.40 barg

    Water flow rate 1067.29 litres/min

    Ambient Weather Conditions

    Wind speed (cup anemometer 1 at 1.2m) 1.8 m/s

    Wind speed (cup anemometer 2 at 2.9m) 1.9 m/s

    Wind speed (cup anemometer 3 at 6.0m) 2.2 m/s

    Wind speed (cup anemometer 4 at 6.4m) 2.3 m/s

    Horizontal wind speed (sonic at 8.2m) 2.83 m/s

    Vertical wind speed (sonic at 8.2m) 0.9 m/s

    Wind direction 284.31 degrees clockwise from North

    Relative humidity 93.1 %

    Ambient temperature 11.2 deg C

    Atmospheric pressure 963.2 mbar

    Thermocouples not operating properly

    15, 79

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    64

    Fuel flow 0408

    0.0

    1.0

    2.0

    3.0

    4.0

    5.0

    6.0

    7.0

    8.0

    9.0

    10.0

    11.0

    030

    60

    90

    120

    150

    180

    210

    240

    Time from ignition, s.

    Massflow,kg/s

    &Pressure,barg.

    Mass flow , kg/s

    Vapour pressure,

    barg

    Liquid head

    pressure, barg

    Discharge

    pressure, barg

    Figure E1 - Fuel conditions

    Water flow 0408

    0.00

    0.50

    1.00

    1.50

    2.00

    2.50

    3.00

    030

    60

    90

    120

    150

    180

    210

    240

    Time from ignition, s.

    Pressure,barg

    &Flow

    m^3/min

    Water pressure,

    barg

    Water flow rate,

    m^3/min

    Figure E2 - Water deluge conditions

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    65

    Ring A

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    Time from ignition, s.

    Temperature,degC.

    TK-40801

    TK-40802

    TK-40803

    TK-40804

    120 deg C.

    Figure E3 - Temperatures - thermocouples 1 - 4

    Ring B

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    Time from ignition, s.

    Temperature,deg

    C.

    TK-40805

    TK-40806

    TK-40807

    TK-40808

    120 deg C.

    Figure E4 - Temperatures - thermocouples 5 - 8

  • 8/13/2019 Analysis of Jetfires

    71/245

    66

    Ring C

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    Time from ignition, s.

    Temperature,degC.

    TK-40809

    TK-40810

    TK-40811

    TK-40812

    TK-40813

    TK-40814

    TK-40815

    TK-40816

    120 deg C.

    Figure E5 - Temperatures - thermocouples 9 - 16

    Ring CA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    Time from ignition, s.

    Temperature,deg

    C. TK-40857

    TK-40858

    TK-40859

    TK-40860

    TK-40861

    120 deg C.

    Figure E6 - Temperatures - thermocouples 57 - 61

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    72/245

    67

    Ring D

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    Time from ignition, s.

    Temperature,degC.

    TK-40817

    TK-40818

    TK-40819

    TK-40820

    TK-40821

    TK-40822

    TK-40823

    TK-40824

    TK-40862

    120 deg C.

    Figure E7 - Temperatures - thermocouples 17 - 24 plus 62

    Ring DA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    Time from ignition, s.

    Temperature,deg

    C. TK-40863

    TK-40864

    TK-40865

    TK-40866

    TK-40867

    120 deg C.

    Figure E8 - Temperatures - thermocouples 63 - 67

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    73/245

    68

    Ring DB

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    Time from ignition, s.

    Temperature,degC.

    TK-40868

    TK-40869

    TK-40870

    120 deg C.

    Figure E9 - Temperatures - thermocouples 68 - 70

    Ring E

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    Time from ignition, s.

    Temperature,degC.

    TK-40825

    TK-40826

    TK-40827

    TK-40828TK-40829

    TK-40830

    TK-40831

    TK-40832

    TK-40871

    120 deg C.

    Figure E10 - Temperatures - thermocouples 25 - 32 plus 71

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    74/245

    69

    Ring EA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    Time from ignition, s.

    Temperature,degC.

    TK-40872

    TK-40873

    TK-40874

    120 deg C.

    Figure E11 - Temperatures - thermocouples 72 - 74

    Ring EB

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    Time from ignition, s.

    Temperature,de

    gC. TK-40875

    TK-40876

    TK-40877

    TK-40878

    TK-40879

    120 deg C.

    Figure E12 - Temperatures - thermocouples 75 - 79

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    75/245

    70

    Ring F

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    Time from ignition, s.

    Temperature,degC.

    TK-40833

    TK-40834

    TK-40835

    TK-40836

    TK-40837

    TK-40838

    TK-40839

    TK-40840

    TK-40880

    120 deg C.

    Figure E13 - Temperatures - thermocouples 33 - 40 plus 80

    Ring FA

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    Time from ignition, s.

    Temperature,deg

    C. TK-40881

    TK-40882

    TK-40883

    TK-40884

    TK-40885

    120 deg C.

    Figure E14 - Temperatures - thermocouples 81 - 85

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    76/245

    71

    Ring G

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    Time from ignition, s.

    Temperature,degC.

    TK-40841

    TK-40842

    TK-40843

    TK-40844

    TK-40845

    TK-40846

    TK-40847

    TK-40848

    120 deg C.

    Figure E15 - Temperatures - thermocouples 41 - 48

    Ring H

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    Time from ignition, s.

    Temperature,deg

    C.

    TK-40849TK-40850

    TK-40851

    TK-40852

    120 deg C.

    Figure E16 - Temperatures - thermocouples 49 - 52

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    72

    Ring I

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    Time from ignition, s.

    Temperature,degC.

    TK-40853

    TK-40854

    TK-40855

    TK-40856

    120 deg C.

    Figure E17 - Temperatures - thermocouples 53 - 56

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    78/245

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    A B C D E F G H I

    REAR

    TOP

    FRONT

    BOTTOM

    O Water spraynozzle

    Thermocouple+

    BOTTOM

    Temperature scale

    -20

    0

    120

    240

    360

    480

    Figure E18 Development of vessel with temperature contours at 243s after ignition.

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    79/245

    74

    Appendix F - DEL0409

    Averaging period 62 - 302 seconds after ignition

    Summary of Release Conditions

    Discharge hole diameter: 50.0 mm

    Stand-off Distance: 1.00 m

    Butane mass flow rate: 8.71 kg/s

    Exit static pressure 1.05 barg

    Exit temperature 4.51 deg. C

    Deluge Flow

    Water sprays: Delayed by 30 secs

    Water pressure 2.37 barg

    Water flow rate 1064.02 litres/min

    Ambient Weather Conditions

    Wind speed (cup anemometer 1 at 1.2m) 2.1 m/s

    Wind speed (cup anemometer 2 at 2.9m) 2.2 m/s

    Wind speed (cup anemometer 3 at 6.0m) 2.4 m/s

    Wind speed (cup anemometer 4 at 6.4m) 2.5 m/s

    Horizontal wind speed (sonic at 8.2m) 2.86 m/s

    Vertical wind speed (sonic at 8.2m) 0.9 m/s

    Wind direction 289.47 degrees clockwise from North

    Relative humidity 93.2 %

    Ambient temperature 11.1 deg C

    Atmospheric pressure 963.5 mbar

    Thermocouples not operating properly

    15, 79

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    75

    Fuel flow 0409

    0.0

    1.0

    2.0

    3.0

    4.0

    5.0

    6.0

    7.0

    8.0

    9.0

    10.0

    11.0

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    Time from ignition, s.

    Massflow,kg/s

    &Pressure,barg.

    Mass flow , kg/s

    Vapour pressure,

    barg

    Liquid head

    pressure, barg

    Discharge

    pressure, barg

    Figure F1 - Fuel conditions

    Water flow 0409

    0.00

    0.50

    1.00

    1.50

    2.00

    2.50

    3.00

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    Time from ignition, s.

    Pressure,barg

    &Flow

    m^3/min

    Water pressure,

    barg

    Water flow rate,

    l/min

    Figure F2 - Water deluge conditions

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    Ring A

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270

    300

    Time from ignition, s.

    Temperature,degC.

    TK-40901

    TK-40902

    TK-40903

    TK-40904

    120 deg C.

    Figure F3 - Temperatures - thermocouples 1 - 4

    Ring B

    0

    50

    100

    150

    200

    250

    300

    350

    400

    030

    60

    90

    120

    150

    180

    210

    240

    270