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4900002213 rev. A 9-24-14

4333 W Sam Houston Pkwy N, Suite 100Houston, TX 77043-1223

Tel: 800.619.2861Fax: 713.856.6623

www.spectrasensors.com

Copyright © 2014 SpectraSensors, Inc. SpectraSensors,Inc SpectraSensors

A EO15566 1/31/14

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ii 4900002213 rev. A 9-24-14

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5:

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4900002213 rev. A 9-24-14 iii

B:

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iv 4900002213 rev. A 9-24-14

v

vi 4900002213 rev. A 9-24-14

vii

viii 4900002213 rev. A 9-24-14

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<NORMAL MODE>ANA: 4.0256ppmv

P: 954.4mb T: 76.1F

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+# 1

<NORMAL MODE>ANA: 4.0256ppmv

P: 954.4mb T: 76.1F

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+# 4

Temp: 50.6 CPres: 1103.2 mbDC: 2672Zero: 12Fit: 0.98 Mid: 60.241

f

+# 5

<TEST 4-20MA MODE>

4-20 mA output is at0.0% or 4.0mA

+# 6

<DUMP SPECTRUM MODE>

Index: 0Cycle: 1 of 10

+# 7

<MEASURE PORT1 MODE>ANA: 4.0256ppmv

P: 954.4mb T: 76.1F

+# 8

<MEASURE PORT2 MODE>ANA: 4.0256ppmv

P: 954.4mb T: 76.1F

+# 9

<VALIDATION RESULTS>Date:11-23-13 23:301pass 0.22 ppmv2pass 22.34 ppmv

+# TEST

<NORMAL MODE>

4-20 mA input is ON 4095 or 68948 mb

1000000

4.29E+09

+# 2

<SET PARAMETER MODE>Enter password:

NS 5.13-XXXX

<SET PARAMETER MODE>Validation Wait Time60Enter a value

<SET PARAMETER MODE># Spectrum Average64Enter a value

<SET PARAMETER MODE>2 Way Com Port00:Off1:Cus2:Ser3:Eth

<SET PARAMETER MODE>4-20mA Alarm Action00:None 1:L 2:H 3:T&H

<SET PARAMETER MODE>4-20 mA Val Action00:Hold 1:Measure

<SET PARAMETER MODE>AI 4 mA Value0.00000Enter a value (mb)

<SET PARAMETER MODE>AI 20 mA Value0.00000Enter a value (mb)

<SET PARAMETER MODE>AI Pressure Input00:Disable 1:Enable

<SET PARAMETER MODE>AO 4 mA Value0.00000ppmv or DewPoint F/C

I R 20mA 4mA– 4mA+=

<SET PARAMETER MODE>AO 4-20 mA Test0.00000Enter a value (%)

<SET PARAMETER MODE>AO 20 mA Value0.00000ppmv or DewPoint F/C

<SET PARAMETER MODE>Baud Rate30:19 1:38 2:57 3:115

•••••••••

<SET PARAMETER MODE>Calculate Dew Point00:Off 1:LCD&AO 2:LCD

<SET PARAMETER MODE>Cancel Val Alarms0.000001:Cancel

<SET PARAMETER MODE>Concentration Unit00:ppm 1:lbs 2:% 3:mg

<SET PARAMETER MODE>Custom Precision2Enter a value

<SET PARAMETER MODE>Daily Validation00:Disable 1:Enable

0 0000001

1 0000002

2 0000004

3 0000008

4 0000010

5 0000020

6 0000040

7 0000080

8 0000100

9 0000200

<SET PARAMETER MODE>Dew Point Method00:ISO1:AS12:AS23:AB

<SET PARAMETER MODE>DO Alarm Setup8192Enter decimal value

10 0000400

11 0000800

12 0001000

13 0002000

14 0004000

15 0008000

16 0010000

17 0020000

18 0040000

19 0080000

20 0100000

21 0200000

22 0400000

23 0800000

24 1000000

25 2000000

26 4000000

27 8000000

28 10000000

29 20000000

30 40000000

31 80000000

<SET PARAMETER MODE>General Alarm DO00:L 1:NonL 2:Reset

<SET PARAMETER MODE>High Alarm Setpoint0.00000ppmv or DewPoint F/C

<SET PARAMETER MODE>Keypad Watchdog0<5:Off>=5:Secs

<SET PARAMETER MODE>Logger Rate8Enter a value

<SET PARAMETER MODE>Low Alarm Setpoint0.00000ppmv or DewPoint F/C

<SET PARAMETER MODE>Modbus Address1Enter node (1-250)

<SET PARAMETER MODE>Modbus Mode00:Off 1:GMR 2:DMR

<SET PARAMETER MODE>Peak Tracking10:Off 1:On 2:Rst

<SET PARAMETER MODE>Pipeline Pressure0.00000Enter a value (mb)

<SET PARAMETER MODE>Pressure Unit00:mb1:Torr2:kPa3:psi

<SET PARAMETER MODE>RATA00:Disable 1:Enable

<SET PARAMETER MODE>RATA Multiplier1.00000Enter a value

<SET PARAMETER MODE>RATA Offset0.00000Enter a value

<SET PARAMETER MODE>Set Time - Day23Enter a value (DD)

<SET PARAMETER MODE>Set Time - Hour7Enter a value (0-23)

<SET PARAMETER MODE>Set Time - Minute5Enter a value (0-59)

<SET PARAMETER MODE>Set Time - Month11Enter a value (MM)

<SET PARAMETER MODE>Set Time - Year2013Enter a value (YYYY)

<SET PARAMETER MODE>Start Validation11:Start

<SET PARAMETER MODE>Temperature Unit00:C 1:F

<SET PARAMETER MODE>Val 1 Concentration60.00:ZeroGas >0:ppmvVal

<SET PARAMETER MODE>Val 2 Concentration280.0000:ZeroGas >0:ppmvVal

<SET PARAMETER MODE>Val Attempts2Enter a value

<SET PARAMETER MODE>Val Auto DumpSpectrm00:Disable 1:Enable

<SET PARAMETER MODE>Validation Allowance10.00000% of val concentra

<SET PARAMETER MODE>Validation Wait Time60Enter a value (secs)

<SET PARAMETER MODE>Val Interval1Enter a value (days)

<SET PARAMETER MODE>Val Perm Constant Kp0.240:Off >0:System Cons

<SET PARAMETER MODE>Val Perm Rate Rp0.330:Off >0:ng/min

<SET PARAMETER MODE>Val Start Time 11Hour of day (0-23)

<SET PARAMETER MODE>Zero Val Tolerance60.0Enter a value (ppmv)

S

,

C C AA

O

,

SC2 C1–

A2 A1–--------------------=

O C1 S A1 –=

S 1=

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+# 6

<DUMP SPECTRUM MODE>

Index: 0Cycle: 1 of 10

MODE

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-500

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50100

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Series1Series2

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<SET PARAMETER MODE>Enter password

FS 5.13-XXXX

<SET PARAMETER MODE>Modbus Address1Enter a value(1-250)

<SET PARAMETER MODE>Modbus Mode00:Off 1:GMR 2:DMR

<SET PARAMETER MODE>2 Way Com Port10:Off1:Cus2:Ser3:Eth

•

MAC address XXXXXXXXXXXX (E.g., 00204A808BE8)Software version V6.3.0.3RC3 (061110) (Version may vary by system)

Press Enter for Setup Mode

Change Setup: 0 Server 1 Channel 1 5 Expert 6 Security 7 Defaults 8 Exit without save 9 Save and exit Your choice ?

Save and exit Your choice ?

IP Address : (192) .(168) .(001) .(127)Set Gateway IP Address (Y) ?Gateway IP addr (192) .(168) .(001) .(127)Netmask: Number of Bits for Host Part (0=default) (16)Change telnet config password (N) ?

IP Address : (000) (000) (000) (000) _

Set Gateway IP Adress (N) ? YGateway IP addr (000) (000) (000) (000)_

0 AutoIP

1 DHCP

2 BootP

Netmask: Number of Bits for Host Part (0=default) (0) _

Change telnet config password (N)?

•

A 24

B 16

C 8

•

Change DHCP device name (not set)? (N) YEnter new DHCP device name XPort Direct

•

Change Setup: 0 Server 1 Channel 1 5 Expert 6 Security 7 Defaults 8 Exit without save 9 Save and exit Your choice ? 1

Baudrate (9600) ?

I/F Mode (4C) ?

Flow (00) ?

Port No (10001) ?

ConnectMode (C0) ?

00

01

02

05

1–1024

9999

14000-14009

30704

30718

0 0 0

0 1 0

1 1 0

0

1

0 0 0 0

0 0 0 1

0 0 1 0

0 0 1 1

0 1 0 0

0 1 0 1

0 0 1 0

1 1 0 0

0 0 1 1

0 1 1 1 1

0 1 1 1 0

0 0 1 1 1 1

0 0 1 1 1 0

Baudrate (9600) ?I/F Mode (4C) ?Flow (00) ?Port No (10001) ?ConnectMode (C0) ?Send ‘+++’ in Modem Mode (Y) ?Auto increment source port (N) ?

Hostlist :01. IP : 172.019.000.001 Port : 0002301. IP : 172.019.000.002 Port : 0300101. IP : 172.019.000.003 Port : 10001

Change Hostlist ? (N) ? _

Change Hostlist ? (N) ? Y01. IP address : (172) .(019) .(000) .(001) Port : (23) ?01. IP address : (172) .(019) .(000) .(002) Port : (3001) ?01. IP address : (172) .(019) .(000) .(003) Port : (10001) ?

01. IP address : (000) .(000) .(000) .(000)Hostlist :01. IP : 172.019.000.001 Port : 0002301. IP : 172.019.000.002 Port : 0300101. IP : 172.019.000.003 Port : 10001

Change Hostlist ? (N) ? _

Change Hostlist ? (N) ? NHostlist Retrycounter (3) ?

Hostlist Retrytimeout (250) ?

0

1

2

3

4

Full Verbose

••

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•

Send ‘+++’ in Modem Mode (Y) ? _

Show IP addr after ‘RING’ (Y) ? _

Auto increment source port (N) ? _

Remote IP Address : (000) (000) (000) (000)

Remote Port (0) ? _

DisConnMode (00) ?

FlushMode (00) ? _

1

0

1

1

0

1

1

1

1

1

1

1

1

1

1

0 0

0 1

1 0

1 1

0 0

0 1

1 0

1

1

DisConnTime (00:00) ? _

SendChar 1 (00) ? _SendChar 2 (00) ? _

TCP Keepalive time in s (1s – 65s; 0s=disable): (45)? _

ARP Cache timeout in s (1s – 65s; 0s=disable): (600)? _

Disable Monitor Mode @ bootup (N) ? _

MTU Size: (1400) ? _

Enable alternate MAC (N) ? _

Ethernet connection type: (0) ? _

Disable Telnet Setup (N) ? _

Disable TFTP Firmware Update (N) : _

Disable Port 77FEh (N) ? _

Disable ECHO ports (Y) ? _

Enable Enhanced Password (Y) ? _

MAC address 00204A808BE8Software version V6.3.0.3RC3 (061110)

Press Enter for Setup Mode

0>

1>

2>

8>

9>

Kp = Cp/Rp

•••

••

yw

106 [ppm] , (1)

nw nm

WC 3

[mg/Nm3] , (2)

Mw TN PNZN

R

803745 [mg/Nm3] . (3)

ywnw

nw nm+-------------------=

PN T N

WCyw

1 yw–---------------

M wPNZ N RT N-------------------=

Z N 1=

WCyw

1 yw–---------------=

��� ��� A–1

NS 5.13 ���

, (4)

yw P xwT

. (5)

T P

ywP xwPwsat T =

Pwsat

xw 1=

ywPw

sat T P

-------------------=

A–2 4900002213 rev. A 6-12-15

, (6)

WC Tb Pb w3 P T

w

w

, (7)

WCP B

, (8)

T

WC w 106 PbP------ T

T b------=

WC 760.4 Pw

sat

P---------- 0.016016B+=

Pwsat

Blog 1713.66–T

---------------------- 6.69449+=

��� ��� A–3

NS 5.13 ���

, (9)

T Tc Pc

, (10)

A B

A B

A B

P

. (11)

(12)

, (13)

, (14)

lnPw

sat

Pc---------- T c

T------ 7.85823– 1.839911.5 11.78113–+=

22.6705+ 3.5 15393934– 1.775167.5 +

1 T T c–=

WC AP--- B+=

T b 520=Pb 14.7=

P T V, RTV b–------------- a T

V 2 2bV b2–+

-----------------------------------–=

b 0.07780RT cPc

----------=

a T 0.45724R2T c

2

Pc----------------------------------- T r =

T r T T c= T r

T r 1 1 T r1 2

– + 2

=

A–4 4900002213 rev. A 6-12-15

, (15)

iPc Tc

iPc Tc

0.37464 1.54226 0.269922–+=

T r 1 A1 1 T r1 2

– A2 1 T r1 2

– 2

A3 1 T r1 2

– 4

+ + + 2

=

��� ��� A–5

NS 5.13 ���

(16)

, (17)

(18)

, (19)

, (20)

i ii

i

T T

A1

A2

A3

am T xix jaij T j 1=

nc

i 1=

nc

=

bm xibii 1=

nc

=

nc xia aij T

aij T ai T a j T 1 kij T – =

kij T kij 0 kij 1T

273.15---------------- 1– +=

kij 0 kij 1kij k ji= kii k jj 0= =

il xi i

v yi=

il xi

iv yi

A–6 4900002213 rev. A 6-12-15

i i j j kij 0 kij 1

��� ��� A–7

NS 5.13 ���

, (21)

Z

. (22)

T

Z

Z

T

lnibibm------ Z 1– ln Z B*– –=

A*

2 2B*-----------------

bibm------

2 ai T am T

--------------------- x j ai T 1 kij– j–

ln Z B* 1 2++

Z B* 1 2–+------------------------------------–

A* am T P RT 2= B* bmP RT =

Z3 1 B*– Z2– A* 2B*– 3B*2

– Z A*B*– B*2 B*3+ + + 0=

yi

Ki PciP exp 5.373 1 i+ 1 T 1–

ri– =Ki i

l iv=

xi yi Ki=

yi iv

xi il

xi' xi iv i

l =

xi' xi– 0xi'

i 1

A–8 4900002213 rev. A 6-12-15

Temperature [K]

Water

Con

tent

[mg/N

m3]

250 300 350101

102

103

104

ASTM1ASTM2ISOGERG Meas.

Natural Gas NG1

P=5 bar

P=100 bar

Temperature [K]

Water

Con

tent

[mg/N

m3]

250 300 350101

102

103

104

ASTM1ASTM2ISOGERG Meas.

Natural Gas NG3

P=5 bar

P=100 bar

��� ��� A–9

NS 5.13 ���

Temperature [K]

Water

Con

tent

[mg/N

m3]

250 300 350101

102

103

104

ASTM1ASTM2ISOGERG Meas.

Natural Gas NG4

P=5 bar

P=100 bar

Temperature [K]

Water

Con

tent

[mg/N

m3]

250 300 350101

102

103

104

ASTM1ASTM2ISOGERG Meas.

Natural Gas NG7

A–10 4900002213 rev. A 6-12-15

i i j j kij 0 kij 1

��� ��� A–11

NS 5.13 ���

PT

PT

A–12 4900002213 rev. A 6-12-15

Temperature [K]

Water

Con

tent

[mg/N

m3]

250 260 270 280 290 300101

102

103

NG1NG3NG4NG7

P=60 bar

��� ��� A–13

NS 5.13 ���

[1] McNaught, A. D. and Wilkinson, A., eds., Compendium of Chemical Terminology: IUPAC Recommendations (2nd Edition), Blackwell Science, Malden, MA, 1997.

[2] ISO 13443: Natural Gas – Standard Reference Conditions, International Organization for Standardization, Geneva, Switzerland, 1996.

[3] Wagman, D. D., Evans, W. H., Parker, V. B., Schumm, R. H., Halow, I., S Bailey, S. M., Churney, K. L. � Nuttall, R. L., “The NBS Tables of Chemical Thermodynamic Properties,” J. Phys. Chem. Ref. Data, Vol. 11, Suppl. 2, 1982.

[4] The SI Metric System of Units � SPE Metric Standard, Society of Petroleum Engineers of AIME, Richardson, TX, 1984.

[5] Ibrahim, O. ed., Annual Statistical Bulletin, Organization of the Petroleum Exporting Countries, Vienna, Austria, 2008.

[6] “Storage and Handling of Liquefied Petroleum Gases,” 29 CFR-Labor, Chapter XVII, Part 1910, Sect. 1910.110 and 1910.111, 1993.

[7] Prausnitz, J. M., Molecular Thermodynamics of Fluid-Phase Equilibria, Prentice-Hall, Inc., Englewood Cliffs, New Jersey, 1969.

[8] ASTM D 1142-95: Standard Test Method for Water Vapor Content of Gaseous Fuels by Measurement of Dew Point Temperature, ASTM International, West Conshohocken, Pennsylvania, 2006.

[9] Bukacek, R. F., “Equilibrium Moisture Content of Natural Gases,” Research Bulletin 8, Institute of Gas Technology, 1955.

[10] ISO 18453: Natural Gas-Correlation between Water Content and Water Dew Point, International Organization for Standardization, Geneva, Switzerland, 2006.

[11] Buck, A. L. (1981), “New equations for computing vapor pressure and enhancement factor”, J. Appl. Meteorol. 20: 1527-1532

[12] Buck Research Instruments, LLC, “Model CR-1A Hygrometer with Autofill Operating Manual”, Appendix 1: Humidity Conversion Equations, May 2012.

[13] Saul, A. and Wagner, W., “International Equations for the Saturation Properties of Ordinary Water Substance,” J Phys Chem Ref Data, 16:893-901, 1987.

[14] Oellrich, L. R. and Althaus, K., “Relationship between Water Content and Water Dew Point keeping in consideration the Gas Composition in the Field of Natural Gas,” GERG Technical Monograph TM14, Verein Deutscher Ingenieure, Duesseldorf, 2000.

[15] Peng, D. Y. and Robinson, D. B., “A New Two-Constant Equation of State,” Ind. Eng. Chem. Fundam., 15(1):59-64, 1976.

A–14 4900002213 rev. A 6-12-15

[16] Copeman, T. W. and Mathias, P. M., “Recent Mixing Rules for Equations of State,” in Chao, K. C. ed., Equation of State: Theories and Applications, ACS Symposium Series 300:352-370, 1986.

[17] Reid, R. C., Prausnitz, J. M. and Poling, B. E., The Properties of Liquids and Gases (4th Edition), McGraw-Hill Book Company, New York, New York, 1987.

[18] Wilson, G., “A Modified Redlich-Kwong Equation of State Applicable to General Physical Data Calculations,” Paper No. 15C, 65th AIChE National meeting, May, 1968.

[19] Avila, S., Blanco, S. T., Valesco, I., Rauzy, E. and Otin, S., “Thermodynamic Properties of Synthetic Natural Gases Part 4. Dew Point Curves of Synthetic Natural Gases and their Mixtures with Water: Measurement and Correlation,” Fluid Phase Equilibria 202:399-412, 2002.

��� ��� A–15

NS 5.13 ���

A–16 4900002213 rev. A 6-12-15

SpectraSensors

.

DO(General Alarm DO) *

<SET PARAMETER MODE>Enter password

NS 5.13-XXXX

<SET PARAMETER MODE>Peak Tracking10:Off 1:On 2:Rst

<SET PARAMETER MODE>General Alarm DO20:L 1:NonL 2:Reset

f

–1

–2 4900002213 rev. A 9-24-14

4900002213 rev. A 9-24-14 –3

–4 4900002213 rev. A 9-24-14