alternative fuels - latest seminar topics€¦ · web viewammonia is the second most commonly...
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ALTERNATIVE FUELS
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ABSTRACT
Since the early seventies of the last century caused by the upcoming exhaust gas legislation
and the energy crisis of that decade. With the necessity to reduce the CO2-output of the
transportation sector a third extremely important reason entered the scene in the nineties
especially in Europe. Under these aspects only those alternatives are sustainable which can make
not only a positive contribution to clean air and energy security but also to global warming.
So the challenge for the future will be to bring renewable fuels to the transportation
sector. The options we have are hydrogen, which on account of technical and economical
barriers won’t have the maturity for market penetration within the next 2 decades and liquid
biomass-based fuels. Biofuels of the first generation are Ethanol and Biodiesel. Both can be
blended to gasoline or to diesel. But these fuels if used in their pure form not only need a new
engine application but also a new distribution infrastructure. Disadvantages of the 1st generation
are the low CO2 reduction potential for CO2 emissions and the relatively little yield of fuel
amount per hectare arable land.
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INTRODUCTION
Alternative fuels, known as non-
conventional or advanced fuels, are any
materials or substances that can be used as
fuels, other than conventional fuels.
Conventional fuels include: fossil fuels
(petroleum (oil), coal, propane, and natural
gas), as well as nuclear materials such as
uranium and thorium, as well as artificial
radioisotope fuels that are made in nuclear
reactors, and store their energy.
Biodiesel, bioalcohol (methanol,
ethanol, butanol), chemically stored
electricity (batteries and fuel cells),
hydrogen, non-fossil methane, non-fossil
natural gas, vegetable oil, and other biomass
sources.
A fuel other than gasoline or diesel
for powering motor vehicles, often with
improved energy efficiency and pollution
reduction features
Example: Electricity, natural gas,
hydrogen, and fuel cells are examples of
alternative fuel.
Contents
Ammonia
Biodiesel
Hydrogen fuel
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Ammonia
Ammonia (NH3) releases H2 in an
appropriate catalytic reformer. Ammonia
provides high hydrogen storage densities as
a liquid with mild pressurization and
cryogenic constraints: It can also be stored
as a liquid at room temperature and pressure
when mixed with water. Ammonia is the
second most commonly produced chemical
in the world and a large infrastructure for
making, transporting, and distributing
ammonia exists. Ammonia can be reformed
to produce hydrogen with no harmful waste,
or can mix with existing fuels and under the
right conditions burn efficiently. Pure
ammonia burns poorly at the atmospheric
pressures found in natural gas fired water
heaters and stoves. Under compression in an
automobile engine it is a suitable fuel for
slightly modified gasoline engines.
Ammonia is a toxic gas at normal
temperature and pressure and has a potent
odor.
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Biodiesel
Biodiesel is made from animal fats or
vegetable oils, renewable resources that
come from plants such as, soybean,
sunflowers, corn, olive, peanut, palm,
coconut, safflower, canola, sesame,
cottonseed, etc. Once these fats or oils are
filtered from their hydrocarbons and then
combined with alcohol like methanol,
biodiesel is brought to life from this
chemical reaction. These raw materials can
either be mixed with pure diesel to make
various proportions, or used alone. Despite
one’s mixture preference, biodiesel will
release a smaller number of its pollutants
(carbon monoxide particulates and
hydrocarbons) than conventional diesel,
because biodiesel burns both cleaner and
more efficiently. Even with regular diesel’s
reduced quantity of sulfur from the ULSD
(ultra-low sulfur diesel) invention, biodiesel
exceeds those levels because it is sulfur-free.
Hydrogen fuel
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Hydrogen fuel is an eco-friendly fuel
which uses electrochemical cells, or
combustion in internal engines, to power
vehicles and electric devices. It is also used
in the propulsion of spacecraft and can
potentially be mass produced and
commercialized for passenger vehicles and
aircraft.
Contents
Chemistry
Manufacturing
Energy
Uses
Advantages
Disadvantages
Chemistry
Hydrogen is the first element on the
periodic table, making it the lightest element
on earth. It is also the most abundant
element on the planet, although not usually
found in its pure form, H2. This is due to the
fact that it is so light, it rises into the
atmosphere.[1] In a flame of pure hydrogen
gas, burning in air, the hydrogen (H2) reacts
with oxygen (O2) to form water (H2O) and
releases heat. This heat is what will be used
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as a fuel; therefore hydrogen is an energy
carrier, not an energy source.
Manufacturing
There are different ways to
manufacture it, such as, electrolysis and
steam-methane reforming process. In
electrolysis, electricity is run through water
to separate the hydrogen and oxygen atoms.
This method can be used by using wind,
solar, geothermal, hydro, fossil fuels,
biomass, and many other resources. The
more natural methods of making electricity
(wind, solar, hydro, geothermal, biomass),
rather than fossil fuels, would be better used
as to continue the environment-friendly
process of the fuel. Obtaining hydrogen
from this process is being studied as a viable
way to produce it domestically at a low cost.
Steam-methane reforming process extracts
the hydrogen from methane. However, this
reaction causes a side production of carbon
dioxide and carbon monoxide which are
greenhouse gases and contribute to global
warming. Even so, the current leading
technology for producing hydrogen in large
quantities is steam reforming of methane gas
(CH4).
Hydrogen production
Hydrogen production is the family of
industrial methods for generating hydrogen.
Currently the dominant technology for direct
production is steam reforming from
hydrocarbons. Many other methods are
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known including electrolysis and
thermolysis.
Steam reforming
Fossil fuels are the dominant source
of industrial hydrogen.[2] Hydrogen can be
generated from natural gas with
approximately 80% efficiency, or from other
hydrocarbons to a varying degree of
efficiency. Specifically, bulk hydrogen is
usually produced by the steam reforming of
methane or natural gas. At high
temperatures (700–1100 °C), steam (H2O)
reacts with methane (CH4) to yield gas.
CH4 + H2O → CO + 3 H2 + 191.7 kJ/mol
Gasification
In a second stage, further hydrogen
is generated through the lower-temperature
water gas shift reaction, performed at about
130 °C:
CO + H2O → CO2 + H2 - 40.4 kJ/mol
Essentially, the oxygen (O) atom is stripped
from the additional water (steam) to oxidize
CO to CO2. This oxidation also provides
energy to maintain the reaction. Additional
heat required to drive the process is
generally supplied by burning some portion
of the methane.
Water
Many technologies have been
explored but it should be noted that as of
2007 "Thermal, thermo chemical,
biochemical and photochemical processes
have so far not found industrial
applications."[2] Only high temperature
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electrolysis of alkaline solutions finds some
applications.
Electrolysis
Approximately 5% of industrial
hydrogen is produced by electrolysis. Two
types of cells are popular, solid oxide
electrolysis cells (SOEC's) and alkaline
electrolysis cells (AEC's). These cells
optimally operate at high concentrations
electrolyte (KOH or potassium carbonate)
and at high temperatures, often near 200 °C.
Typical catalysts are yttrium-stabilized
zirconium together with nickel.
Thermolysis
Water spontaneously dissociates at
around 2500 C, but this thermolysis occurs
at temperatures too high for usual process
piping and equipment. Catalysts are required
to reduce the dissociation temperature.
Energy
Once manufactured, hydrogen is an
energy carrier (i.e. a store for energy first
generated by other means). The energy is
eventually delivered as heat when the
hydrogen is burned. The heat in a hydrogen
flame is a radiant emission from the newly
formed water molecules. The water
molecules are in an excited state on initial
formation and then transition to a ground
state; the transition unleashing thermal
radiation. When burning in air, the
temperature is roughly 2000°C.
Contents
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Hydrogen fuel
Hydrogen storage
Hydrogen technologies
Hydrogen vehicle
Fuel cell vehicle
Hydrogen fuel
Hydrogen fuel requires the
development of a specific infrastructure for
processing, transport and storage.
Main article: Hydrogen economy
Hydrogen fuel refers to the use of
hydrogen gas (H2) as an energy carrier.
Broadly speaking, the production of
renewable hydrogen fuel can be divided into
two general categories: biologically derived
production, and chemical production.[10] This
is an area of current research, and new
developments and technologies are causing
this field to evolve rapidly.
Fuel Cells
Hydrogen is a versatile energy
carrier that can be used to power nearly
every end-use energy need. The fuel cell an
energy conversion device that can efficiently
capture and use the power of hydrogen is the
key to making it happen.
Stationary fuel cells can be used for
backup power, power for remote locations,
distributed power generation, and
cogeneration (in which excess heat released
during electricity generation is used for
other applications). Fuel cells can power
almost any portable application that
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typically uses batteries, from hand-held
devices to portable generators.
Fuel cells can also power our
transportation, including personal vehicles,
trucks, buses, marine vessels, and other
specialty vehicles such as lift trucks and
ground support equipment, as well as
provide auxiliary power to traditional
transportation technologies. Hydrogen can
play a particularly important role in the
future by replacing the imported petroleum
we currently use in our cars and trucks.
Hydrogen storage
Although molecular hydrogen has
very high energy density on a mass basis,
partly because of its low molecular weight,
as a gas at ambient conditions it has very
low energy density by volume. If it is to be
used as fuel stored on board the vehicle,
pure hydrogen gas must be pressurized or
liquefied to provide sufficient driving range.
Increasing gas pressure improves the energy
density by volume, making for smaller, but
not lighter container tanks.
Achieving higher pressures
necessitates greater use of external energy to
power the compression. Alternatively,
higher volumetric energy density liquid
hydrogen or slush hydrogen may be used.
However, liquid hydrogen is cryogenic and
boils at 20.268 K (–252.882 °C or –
423.188 °F).
Cryogenic storage cuts weight but
requires large liquification energies. The
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liquefaction process, involving pressurizing
and cooling steps, is energy intensive. The
liquefied hydrogen has lower energy density
by volume than gasoline by approximately a
factor of four, because of the low density of
liquid hydrogen — there is actually more
hydrogen in a liter of gasoline (116 grams)
than there is in a liter of pure liquid
hydrogen (71 grams). Liquid hydrogen
storage tanks must also be well insulated to
minimize boil off. Ice may form around the
tank and help corrode it further if the liquid
hydrogen tank insulation fails.
The mass of the tanks needed for
compressed hydrogen reduces the fuel
economy of the vehicle. Because it is a
small molecule, hydrogen tends to diffuse
through any liner material intended to
contain it, leading to the embrittlement, or
weakening, of its container.
The most common method of on
board hydrogen storage in today's
demonstration vehicles is as a compressed
gas at pressures of roughly 700 bar
(70 MPa).
Alternative storage proposal
It has been proposed in a
hypothetical renewable energy dominated
energy system to use the excess electricity
generated by wind, solar photovoltaic,
hydro, marine currents and others to make
methane (natural gas) by electrolysis of
water. The methane could then be injected
into the existing gas network to generate
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electricity and heat on demand to overcome
low points of renewable energy production.
The process described would be to create
hydrogen (which could partly be used
directly in fuel cells) and the addition of
carbon dioxide CO2 (Sabatier process) to
create methane as follows: CO2 + 4H2 →
CH4 + 2H2O
Internal combustion engine
The internal combustion engine is an
engine in which the combustion of a fuel
(normally a fossil fuel) occurs with an
oxidizer (usually air) in a combustion
chamber. In an internal combustion engine,
the expansion of the high-temperature and
high -pressure gases produced by
combustion apply direct force to some
component of the engine. This force is
applied typically to pistons, turbine blades,
or a nozzle. This force moves the component
over a distance, transforming chemical
energy into useful mechanical energy. The
first internal combustion engine was created
by Etienne Lenoir.
The term internal combustion engine
usually refers to an engine in which
combustion is intermittent, such as the more
familiar four-stroke and two-stroke piston
engines, along with variants, such as the six-
stroke piston engine and the Wankel rotary
engine.
A second class of internal
combustion engines use continuous
combustion: gas turbines, jet engines and
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most rocket engines, each of which are
internal combustion engines on the same
principle as previously described.
Animation of two-stroke engine in
operation
The internal combustion engine (or
ICE) is quite different from external
combustion engines, such as steam or
Stirling engines, in which the energy is
delivered to a working fluid not consisting
of, mixed with, or contaminated by
combustion products. Working fluids can be
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air, hot water, pressurized water or even
liquid sodium, heated in some kind of boiler.
A large number of different designs for ICEs
have been developed and built, with a
variety of different strengths and
weaknesses. Powered by an energy-dense
fuel (which is very frequently gasoline, a
liquid derived from fossil fuels). While there
have been and still are many stationary
applications, the real strength of internal
combustion engines is in mobile
applications and they dominate as a power
supply for cars, aircraft, and boats.
4 Stroke Engine Ortho 3D Small.gif
No higher resolution available.
As their name implies, four-stroke
internal combustion engines have four basic
steps that repeat with every two revolutions
of the engine:
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(1) Intake stroke
(2) Compression stroke
(3) Power stroke and
(4) Exhaust stroke
1. Intake stroke: The first stroke of the
internal combustion engine is also known as
the suction stroke because the piston moves
to the maximum volume position
(downward direction in the cylinder). The
inlet valve opens as a result of piston
movement, and the vaporized fuel mixture
enters the combustion chamber. The inlet
valve closes at the end of this stroke.
2. Compression stroke: In this stroke, both
valves are closed and the piston starts its
movement to the minimum volume position
(upward direction in the cylinder) and
compresses the fuel mixture. During the
compression process, pressure, temperature
and the density of the fuel mixture increases.
3. Power stroke: When the piston reaches
the minimum volume position, the spark
plug ignites the fuel mixture and burns. The
fuel produces power that is transmitted to
the crank shaft mechanism.
4. Exhaust stroke: In the end of the power
stroke, the exhaust valve opens. During this
stroke, the piston starts its movement in the
minimum volume position. The open
exhaust valve allows the exhaust gases to
escape the cylinder. At the end of this
stroke, the exhaust valve closes, the inlet
valve opens, and the sequence repeats in the
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next cycle. Four-stroke engines require two
revolutions.
Many engines overlap these steps in
time; jet engines do all steps simultaneously
at different parts of the engines.
Four-strokecycle
Idealised Pressure/volume diagram
of the Otto cycle showing combustion heat
input Qp and waste exhaust output Qo, the
power stroke is the top curved line, the
bottom is the compression stroke
Hydrogen vehicle
A hydrogen vehicle is a vehicle that
uses hydrogen as its onboard fuel for motive
power. Hydrogen vehicles include hydrogen
fueled space rockets, as well as automobiles
and other transportation vehicles. The power
plants of such vehicles convert the chemical
energy of hydrogen to mechanical energy
either by burning hydrogen in an internal
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combustion engine, or by reacting hydrogen
with oxygen in a fuel cell to run electric
motors. Widespread use of hydrogen for
fueling transportation is a key element of a
proposed hydrogen economy.
The drawbacks of hydrogen use are
low energy content per unit volume, high
tankage weights, very high storage vessel
pressures, the storage, transportation and
filling of gaseous or liquid hydrogen in
vehicles, the large investment in
infrastructure that would be required to fuel
vehicles, and the inefficiency of production
process
Airplanes
For more details on this topic, see Hydrogen
planes.
The Boeing Fuel Cell Demonstrator
powered by a hydrogen fuel cell.
Companies such as Boeing, Lange
Aviation, and the German Aerospace Center
pursue hydrogen as fuel for manned and
unmanned airplanes. In February 2008
Boeing tested a manned flight of a small
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aircraft powered by a hydrogen fuel cell.
Unmanned hydrogen planes have also been
tested. For large passenger airplanes
however, The Times reported that "Boeing
said that hydrogen fuel cells were unlikely
to power the engines of large passenger jet
airplanes but could be used as backup or
auxiliary power units onboard.
In Europe, the Reaction Engines A2
has been proposed to use the thermodynamic
properties of liquid hydrogen to achieve
very high speed, long distance (antipodal)
flight by burning it in a precooled jet engine.
Rockets
Many large rockets use liquified
cryogenic hydrogen as a propellant. In
addition they use liquified cryogenic
oxygen, and liquified cryogenic hydrogen in
the space shuttle, to charge the fuel cells that
power the electrical systems. The biproduct
of the fuel cell is water, and is used for
drinking, and any other application that
requires water in space. The oxygen is also
used to provide the rocket engines with
oxygen for better thrust in space, due to the
lack of oxygen in space. Just prior to a
launch, the rocket fuel tanks are filled and
chilled. Particularly when used for upper
stages this permits a lighter rocket for any
given payload. The main disadvantage of
hydrogen in this application is the low
density and deeply cryogenic nature,
requiring insulation; this makes the
hydrogen tanks relatively heavy, which
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offsets the advantages for this application,
but these disadvantages could be overcome
through the advent of better on board
hydrogen refrigeration, and liquifier
technology to produce fuel needed for long
distance space travel to a destination where
salt water is available, such as possibly
comets, moons, and planets. But another
advantage of using cryogenic fuel is that the
fuel system is able to be routed in specific
paths to act as a cooling system for the
rocket, which is crucial for temperature
regulation in extended use of rocket
propulsion.
Uses
Hydrogen fuel can provide motive
power for cars, boats and airplanes, portable
fuel cell applications or stationary fuel cell
applications, which can power an electric
motor. Main article: Hydrogen economy
With regard to safety from unwanted
explosions, hydrogen fuel in automotive
vehicles is at least as safe as gasoline.
Californiahydrogen highway
As of July 2007, twenty five stations
were in operation, and ten more stations
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have been planned for vehicle refueling in
California. However, three hydrogen fueling
stations have completed the terms of their
government funded research demonstration
project and have been decommissioned.[2]
As of July 2007 the state of California had
179 Fuel Cell Vehicles.
Advantages
1. Hydrogen has the highest energy content.
Energy content of hydrogen is the highest
per unit of weight of any fuel. Therefore it
offers the most "bang for the buck". When
water is broken down into HHO, otherwise
known as oxyhydrogen or Brown's Gas, it
becomes a very, very efficient fuel. The
flame is cool to the touch but will still cut
tungsten steel like butter.
2. Hydrogen is non-polluting. Along with
it's effectiveness as a fuel, hydrogen is non-
polluting. The only byproduct of hydrogen
when it burns is heat and water.
3. Hydrogen is a renewable fuel source.
Again, think of where you can find
hydrogen. I have a glass of it on my desk
right now. A glass of water. I can get a few
gallons of it out of my faucet in my sink
right now. And just a few miles to then East
of me is the Atlantic Ocean.
Disadvantages
1. The Hydrogen Hazard Stereotype. By its
very nature, hydrogen is very powerful.
Who has not heard of the hydrogen bomb? I
have even had my HHO generator explode
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when I tried to ignite the gas coming from
the generator without the check valve
attached to the tubing. It sounded like a 12
gauge shotgun and only blew the cap off the
device
2. Costly to convert to liquid. Because
hydrogen is a gas, it cannot be compressed
into a liquid form without intensive cost and
energy input. Hydrogen is the lightest
element on earth. As a gas, it dissipates
rapidly. To compress this gas is very, very
difficult .For that matter, the cost to even
produce hydrogen gas is expensive. Even
the electrolysis units of the HHO generators
used in the hydrogen boost apparatus such
as in Water4Gas come at the expense of
horsepower. It takes electricity to generate
the HHO gas..
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CONCLUSION
In the long term, it is to be expected that the persisting problems of hydrogen storage and
infrastructure will be solved. The green light for the hydrogen economy can then be given
subject to a sufficiently positive overall evaluation. However, that is unlikely to happen in the
next 20 years.
The search for alternative fuels is ongoing. Hydrogen production continues to be
researched as a feasible solution. One way scientists are trying to overcome the obstacle of costly
hydrogen production is by harnessing the hydrogen released by cyanobacteria. Certain types of
bacteria contain the enzymes hydrogenase and nitrogenase, which catalyze the production of
hydrogen. Still, major obstacles must be overcome if this method is to become an economically
viable source of energy.
One is creating a strain of bacteria that does not simultaneously produce and consume
H2. This will allow production to be increased. The other problem is that cyanobacteia are
anaerobic, but also produce O2. Therefore, a way must be found to remove the O2 produced to
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enable constant production of H2. Though there are hindrances, potential solutions do exist. For
example, the next steps in overcoming these problems may include optimizing cyanobacteria, to
more effieiently produce hydrogen, and using nanotechnology to create semi-permeable
membrane to expell and block O2 from the cell.
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References:
1. Altork, L.N. & Busby, J. R. (2010 Oct). Hydrogen fuel cells: part of the solution.
Technology & Engineering Teacher, 70(2), 22-27.
2. Florida Solar Energy Center. (n.d.). Hydrogen Basics. Retrieved from:
http://www.fsec.ucf.edu/en/consumer/hydrogen/basics/index.htm
3. Altork, L.N. & Busby, J. R. (2010 Oct). Hydrogen fuel cells: part of the solution.
Technology & Engineering Teacher, 70(2), 22-27.
4. U.S. Department of Energy. (2007 Feb). Potential for hydrogen production from key
renewable resources in the Unites States. (Technical Report NREL/TP-640-41134).
National Renewable Energy Laboratory Golden, CO: Milbrandt, A. & Mann, M.