advanced materials, designs and 3d package … advanced materials... · reliable two-phase cooling...

37
ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE ARCHITECTURES FOR NEXT-GEN HIGH-POWER PACKAGING DR. VANESSA SMET 3D SYSTEMS PACKAGING RESEARCH CENTER

Upload: others

Post on 18-Oct-2020

2 views

Category:

Documents


0 download

TRANSCRIPT

Page 1: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

ADVANCED MATERIALS, DESIGNS AND

3D PACKAGE ARCHITECTURES FOR

NEXT-GEN HIGH-POWER PACKAGING

D R . V A N E S S A S M E T

3 D S Y S T E M S PA C K A G I N G R E S E A R C H C E N T E R

Page 2: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Outline

Why 3D for Next-Gen SiC Packaging?

Innovations in Package Design & Materials

Summary

Page 3: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

3D Systems Packaging Research Center at Georgia Tech

Comprehensive global Industry Consortium in System Scaling to enable supply-chain manufacturing to end-user needs

Industry culture and R&D infrastructure (300mm clean room facility)

Environmental Testing Shared User Labs

Plating Facility Substrate Cleanroom Assembly Facility

Page 4: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Strategic Need: Packaging Solutions FOR WBG

Electrical power needs are increasing across the transportation field

Shift from Si to SiC with higher voltage/power ratings, switching speeds, max. junction temperatures in smaller footprint

Power ↑ + Size ↓ =

Temperature ↑

… but power packaging is slow to change and is now limiting the performance of power electronics

We need power electronics packaging AND cooling to catch up to the devices capability

Current SiC power moduleSource: Toyota

↑ capacity, ↑ efficiency, ↓ cost

Page 5: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Evolution of Power Packaging Technologies

Oakridge Nat. Lab.

3D Power Package

Molded Power Cards

Infineon

Power Embedding

SchweizerElectronics

Conventional Power Module

Wire bonds, Single-side cooling, Separate power / control / drive integration

Elimination of bond wires, Double-sided cooling, Scalability in power

Modularity vs. Integration

Leadframe-based, Cu clip package, Low-cost

Heterogeneous integration, PCB-based processing

Packaging Trends:

↓parasitic L, ↑reliability, ↑thermal behavior

Leverage more standardized manufacturing

New solutions required to fully benefit from performance improvements of SiC

Page 6: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Transition from Si to SiC… the “dv/dt” challenge

Two ways to solve the problem: topology, packaging

50 kV/us

1 nF

50 AParasitic capacitance

Heat sink

Si device 5-15 kV/us

SiC 50 kV/us

Common mode currents can lead to electrical discharge machining (EDM) on ball bearings, will be worse with SiC

Image of ball bearings in motor with voltage source converter

Fast rise and fall times of SiC devices result in high dv/dt Common mode currents EMI Complex gate driver

*Doyle Busse, Jay Erdman, Russel J. Kerkman, Dave Schlegel, and Gary Skibinski, “Bearing Currents and Their Relationship to PWM Drives “ IEEE IECON, 1995

Package parasitic capacitance plays a critical role in dv/dt capability

Source: Georgia Tech CDE

Page 7: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

What we can do on packaging side to address the transition to SiC

Parameters Current Packaging Solutions Our Targets

Heat Flux 200W/cm2 1kW/cm2

Breakdown Voltage 10kV >30kV

Max. Junction Temperature 150-175C >200C

Thermal Performance No thermal transient control Thermal transient suppression

Reliability Poor at full device rating Improved

Conventional Packaging PRC’s Solution: 3D Power Package with Die Stacking

Page 8: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Beyond Traditional 3D: Die Stacking

Thermal & Reliability

Metallization thickness scaling up to X10 for thermal management

Cparasitic

DecoupledCparasitic

DecoupledParasitic capacitance

Minimum Parasitic inductance

Lparasitic

Lparasitic

Electrical

Metallization

Metallization

Power device

Stress buffering w/ advanced die-attach /

conductors

Solder or sintered Ag

Symmetric 3D structure

10X ↓ parasitic C with <1nH parasitic L

Page 9: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Package Parasitic Capacitance

Conventional Novel 3D

BP-TN 123 pF 85 pF

BP-TO 140 pF 0.08 pF

BP-TP 15 pF 85 pF

BP-g_low 12 pF 0.015 pF

BP-g_high 9 pF 0.015 pF

CBN CBO CBP CBN CBO

CBP

Conventional Design Novel 3D Design

S2

S1

D2

D1

P

O

N

g1

g2

CTP

CTO

CTN

Cg_lo

w

Cg_high

He

ats

ink

Rgnd+Lgnd+Cgnd

iheatsink

Vs.

Voltage at heatsink node

Common mode current (noise)

Simplified networkANSYS MAXWELL simulations

LTSPICE simulations

• Minimized output capacitance with new design (die stacking)

• Impact of dv/dt coupling with parasitic capacitance of package significantly reduced

Simulations by H. Lee

Page 10: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Package Parasitic Inductance

Conventional Design Novel 3D Design

35.5

24.5

1.77 1.75

0

5

10

15

20

25

30

35

40

loop1 loop2

Para

siti

c In

du

ctan

ce L

[n

H] Conventional

Novel 3D

• Significant reduction in parasitic inductance – matching other 3D solutions

• Faster response achieved with less resonance in the waveforms

• Significant reduction in switching losses

Vs. Double pulse tester setup for switching

performance comparison

Eon

[mJ]

Eoff

[mJ]

Conventional 0.80 0.27

Novel3D 0.48 0.19

Turn-on Turn-off

Switching energy loss

Simulations by H. Lee

Page 11: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Package Thermal Design – Effect of Cu Thickness

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

0 0.5 1 1.5 2 2.5 3

Therm

al R

esis

tance R

JA

[oC

/W]

Thickness of Heat-Spreader [mm]

h=10000

h=50000

300

310

320

330

340

350

0 0.2 0.4 0.6 0.8 1 1.2 1.4

Junction T

em

pera

ture

[K

]

Time [s]

heat spreader 0.2mmheat spreader 0.4mmheat spreader 1mmheat spreader 2mmheat spreader 3mm

70.0oC

62.3oC

56.4oC

50.7oC

44.9oC

Heat generation

100 W Heat transfer coefficient

10,000~50,000 W/m2K

Modeling by H. Lee

Contrary to 2D integration, increasing heat spreader thickness critical to thermal management in 3D

Page 12: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Thermomechanical Modeling – Effect of Cu Thickness

0.0E+00

2.0E+08

4.0E+08

6.0E+08

8.0E+08

1.0E+09

1.2E+09

0 0.5 1 1.5 2 2.5 3 3.5

Vo

n-M

ises

Str

ess

[Pa]

Heat Spreader Thickness [mm]

Max. Stress on Die @ 105C

3.50E+07

3.70E+07

3.90E+07

4.10E+07

4.30E+07

4.50E+07

4.70E+07

4.90E+07

0 1 2 3

Vo

n-M

ises

Str

ess

[Pa]

Heat Spreader Thickness [mm]

Max. Stress Top Die Attach @ 105C

Max. Stress Bottom Die Attach @ 105C

0.00E+00

1.00E-02

2.00E-02

3.00E-02

4.00E-02

5.00E-02

6.00E-02

7.00E-02

0 0.5 1 1.5 2 2.5 3 3.5

Equ

ival

ent

Pla

stic

Str

ain

Heat Spreader Thickness [mm]

Max. Strain Top Die Attach @ 105C

Max. Strain Bottom Die Attach @ 105C

Uniform temperature 105oC

Max limit

Safe margin

Trade-offs between thermal & reliability performances material innovations to improve reliability

Modeling by H. Lee

Die stress Die-attach stress Die-attach plastic strain

Page 13: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Key Basic Technologies For Next-Gen SiC PKG

SiC

Cu

SiC

Cu Cu / low-stress conductors(integrated heat spreading)

Die-attach by film sintering

High-temp. HV dielectrics / encapsulants

2-phase cold plate

Thinfilm insulators

Multiphysics Design

Transition from sequential electrical thermal mechanical to true multiphysics design

Understanding of tradeoffs

Materials Innovations

Die-attach film sintering (Cu, organics-free, compliant)

Low-stress, high-conductivity conductors (Cu-graphene)

High-temp. HV dielectrics / encapsulants / thinfilm insulators

System-level Cooling

Single phase: ↑temperature uniformity

Two phase: ↑dryoutperformance

Manufacturing

Standard panel-scale processing

Co-develop with supply chain

Reliability

Power & thermal cycling

↑ max. junction temp.

3D Power Card with Die Stacking

Page 14: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

PRC’s Die-Attach Solution: Nanoporous-Cu Film Sintering

Thin NP-Cu cap

High compliance pre-sintering

Low-cost synthesis by selective etching

• Electroplating• Furnace or arc

melting

Cu pillar with NP-Cu caps (semi-additive processing)

Die-attach films, inserts or preforms

Nanoporous (NP) Cu: nanoscale metal sponges

Controlled densification

Collaboration with Prof. Antoniou

Page 15: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Versatility in Implementation

Sacrificial carrier

Sacrificial carrier with a seed layer

Sacrificial carrier

Cu-Zn

Deposit Cu-X alloy layer 15–30 µm thick

Cu-Zn

Isolate the Cu-X film and dealloy

Standalone NP-Cu films

Nano-Cu film

NP-Cu film with a Cu core

Copper foil Copper foil

Deposit Cu-Zn alloy layer 5-30 µm thick

After dealloying

Thin Cu foil

Cu-Zn

Cu-Zn

Copper foil

Nano-Cu film

Nano-Cu film

Sputter oxide and Ti/Cu seed layer on Si wafer

Photoresist lamination and patterning

Deposit Cu-Zn alloy layer 5 – 10 µm thick

Lift-off photoresist, etch Ti/Cu seed and dealloy

Patterned nano-Cu on substrate/device

Collaboration with Prof. Antoniou

Page 16: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

NP-Cu Die-Attach Films on Thinfilm Cu Core

• Total thickness easily adjustable

• 8-10µm nano-Cu films on both sides

Dealloying

Collaboration with Prof. Antoniou Data collected by K. Mohan

Page 17: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Sintering Demo of NP-Cu Film on Bulk Cu

~1.5cm x 1.5cmDiced into sections ~25mm2

10MPa, 250C, 30min, forming gas

>99% density achieved

Cu foil

Cu metallization

Cu metallization

Cu metallization

Sintered foam

Sintered foam

Cu foil

Cu metallization Cu metallization

Sintered foam

Collaboration with Prof. Antoniou Data collected by K. Mohan

Page 18: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Direct Patterning by Semi-Additive Processing

Silicon

Silicon

Cu Metallization

Cu Metallization

NP-Cu

9MPa, 250C, 30min, forming gas

Die: 6.5mmx6.5mmSubstrate: 10mmx10mm

Apply & pattern on substrate, wafer,

busbar, etc

Collaboration with Prof. Antoniou Data collected by K. Mohan

Page 19: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

4” Wafer Bumping – Semi-additive Process

Precursor alloy: Cu-Zn

Successful plating of Cu-Zn in all the patterns, smooth surface profile, uniform Cu-Zn composition across wafer

5mmx5mm die size

30um

~8um Cu+Cu-Zn

Collaboration with Prof. Antoniou Data collected by K. Mohan

Page 20: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

4” Wafer Bumping – NP-Cu Cap Formation

• Initial Cu:Zn ~ 35:65• Dealloying time in dil. HCl:

90-120min• Feature sizes: 40-250nm

Uniform and smooth surface morphology of NP-Cu caps

after dealloying

Cu pillar

NP-Cu cap

30um dia

Collaboration with Prof. Antoniou Data collected by K. Mohan

Page 21: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Cu Pillar with NP-Cu caps – Assembly Demo

Assembly parameters: 30MPa, 300C, 30min, forming gas

Collaboration with Prof. Antoniou Data collected by K. Mohan

Page 22: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Low-stress Conductors: Cu-Graphene Composites

Laminates vs. Composites

Cu composites preferred to retain thermal conductivity of Cu while offering a CTE range

Cu/Mo/Cu

Cu-graphene bulk composites

• Tailorable CTE 3-15ppm/K with λ ~ 460W/m·K

• “Second sound” effect in graphene

• Direct plating & vacuum powder processing

• Applications: Cu functionalization, metallization on DBC/AMB substrates, integrated heat spreaders

• Electrochemical exfoliation of graphene from graphite

Lin et al (2017)

• Orientation control by magnetic field

Implementation in plating line

Plasma sintering

PRC’s Solution

Low-cost Synthesis

Page 23: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

High-temperature HV Mold Compound (Prof. C.P. Wong)

High-Temperature Dielectrics & EMCs

High-temp. & high-conductivity hybrid dielectrics

High-temp. dielectrics with improved interfacial reliability & processability

Low-cost and polymer-compatible hermetic coating

BCBHigh-temp. glass PKG with BCB

Polyimide

Titania-organic hybrid

CE/EP chemistry

Treated/ coated silica

New concept for high-temp. stability

Formulation design for:• High-temperature stability • High breakdown voltage

With Prof. Losego

With Prof. Losego

Page 24: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

New ConceptPrior Art

• Aluminum channels brazed onto substrate, single phase, WEG (Prius)

• Snaking injection-molded copper channels, single phase, WEG (Volt)

CAD model

NEW CONCEPTS

• Additively manufactured (AM) foam-type structures

– Rhombic dodecahedron unit cell for stochastic foam imitation

• Elimination of contact resistance

– Direct printing to eliminate thermal interface materials

• Local control of parameters such as pores per inch (PPI), porosity (ε), elongation, etc. – Allows for localized hotspot cooling, thermal gradient management, vapor pathways

System-level Cooling: Advanced Cold Plates

• Decrease temperature non-uniformity and hotspot formation in single phase

• Increase critical heat flux by delaying dryout failure for reliable two-phase cooling

Collaboration with Prof. Joshi

Page 25: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Summary

Advances in several building block technologies from low to high power electronics for next-gen 3D power modules

– High-density passives

– Package designs for high dv/dt capability vs. soft switching topologies

– Low-cost sintered Cu die-attach films

– Low-CTE high-conductivity conductors

– High-temperature dielectrics and interfaces

– Low-cost panel-based fabrication with supply chain

First prototype (SiC full-bridge rectifier) expected in 2019 end

Page 26: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Acknowledgements

This work is funded by PRC’s Industry Consortium & SRC’s “Global Research Collaboration”

Collaborators: GRAs K. Mohan, H. Lee, R. Sosa, J. Li, J. Broughton, GT Profs. Antoniou, Joshi, Losego, Wong, Center for Distributed Energy

PRC & IEN staff & infrastructures

Page 27: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies
Page 28: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Back-Up Slides

Page 29: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Nanoporous (NP) Cu Synthesis – Concept

Dissolution of more reactive ‘B’ element in the etchant

Rearrangement of ‘A’by surface diffusion

Final nanoporous structure after dealloying

Hakamada, M. and M. Mabuchi (2013)." Critical Reviews in Solid State and Materials Sciences 38(4): 262-285.

Alloying and chemical delalloying

A-B alloy fabrication:

• Electro-deposition• Co-sputtering• Melt spinning• Furnace melting

Dealloying parameters are:

• Etchant chemistry• Dealloying time• Applied potential (Vc)• Temperature

Page 30: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

NP-Cu deforms at very low load

Limit to amount of displacement of the NP-Cu before micro-cracking starts: ~20% of initial height (conservative estimate)

The Promise of Nanoporous (NP) Cu: Compliance

Die

Substrate

100µm

Cu pad

Die

Substrate

100µm

pm

h/hnano-Cu

pm

, M

Pa

hNP-Cu

`

Possible cracking in the NP-Cu

1 µm1 µm

(experimental data for hnano-Cu=2µm)

Experiments at room temperature

Courtesy of A. Antoniou

Page 31: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

The Promise of Nanoporous (NP) Cu: Sintering Kinetics

Thermal sintering carried out in inert N2 and reducing environments (N2 + 3% H2)

Studies ongoing to understand nature of sintering under different environments to be able to design NP metals

for sintering applications

N. Shahane, V. Smet, A. Antoniou “Anomalous coarsening in nanoporous metals” (nearing submission)

Page 32: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

The Promise of Nanoporous (NP) Cu: Sintering Kinetics

• More complex mechanism than simple surface diffusion under heat• Surface diffusion driven kinetics under electrolyte coarsening

Grain-growth model

Arrhenius function

Combined equation

The initial results indicate NP metals have very high surface energy resulting in complex sintering kinetics that need to be further studied and understood

N. Shahane, V. Smet, A. Antoniou “Anomalous coarsening in nanoporous metals” (nearing submission)

Page 33: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Wafer Bumping Process Flow – Solder vs. NP-Cu Caps

Substrate (Si, Organic, Glass)

Package RDL

Seed layer deposition (Ti/Cu)

PR patterning

Cu-Zn co-plating Sn-Ag co-plating

PR strip and dealloying PR strip and solder reflow

Etch seed layer and dicing Etch seed layer and dicing

Nanocopper foam caps fabrication Solder cap fabrication

Chip/Substrate

Assembly

Page 34: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Concept of anisotropic foams for stress buffering in die-attach

Cu foil

Power dieMetallization

DBC

Nano-Cu foam filmLarge - area insert

Anisotropic nano-Cu foams with Cu core

Power diemetallization

DBC

Anisotropic densified structure with good thermal and electrical performance in Z direction and compliance in X-Y plane

Anisotropic platinum foams with vertical channels

Antoniou, Antonia, et al., 2009

Page 35: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

EDX Analysis of Sintered Joint

• All-Cu joints• Residual Zn<0.2%

Si substrate

Si die

Cu metallizationDensified foam

Cu pillar

Data collected by K. Mohan

Page 36: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Fracture Interface Analysis after Die Shear Test

Die-side Substrate-side

• Failure within the sintered foam layer, not at the interface, signifying good metallurgical bonding between NP- and bulk-Cu

• NP-Cu caps were able to compensate for the variation in their heights as well as the surface roughness of the substrates

Data collected by K. Mohan

Page 37: ADVANCED MATERIALS, DESIGNS AND 3D PACKAGE … Advanced Materials... · reliable two-phase cooling Collaboration with Prof. Joshi. Summary Advances in several building block technologies

Improve Dielectric-Metal Adhesion: Vapor-Phase-Infiltration

Polymer

O O O O O O O

CopperSeed layer

VPI modified surface

Adhesion improvement by chemical modification

• Peel strength increases with time of infiltration, indicating that more exposure to precursor is favorable

VPI Temperature 150 CVPI Temperature 120 C

Collaboration with Prof. Losego