18.1 rates of reaction - mr. walkmrwalk.com/chapter 18 - reaction rates and... · 18.1 rates of...
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Rates of Reaction
The heat given off by the corrosion reaction of an iron-magnesium alloy with salt water can produce a hot meal. The rate of reaction is increased by adding salt water, so heat is produced rapidly. You will learn some ways in which the rate of a reaction can be increased.
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Rates of Reaction >
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Collision Theory
Collision Theory
How is the rate of a chemical change
expressed?
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18.1 Collision Theory
In chemistry, the rate of chemical
change, or the reaction rate, is usually
expressed as the amount of reactant
changing per unit time.
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>Rates of Reaction18.1 Collision Theory
A rate is a measure of the speed of any change
that occurs within an interval of time.
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>Rates of Reaction
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Collision Theory
Rates of chemical reactions are often measured
as a change in the number of moles during an
interval of time.
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>Rates of Reaction Collision Theory
According to collision theory, atoms, ions, and
molecules can react to form products when they
collide with one another, provided that the
colliding particles have enough kinetic energy.
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>Rates of Reaction
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Collision Theory
Effective Collision
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>Rates of Reaction
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Collision Theory
Ineffective Collision
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>Rates of Reaction Collision Theory
The minimum energy that colliding particles
must have in order to react is called the
activation energy.
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>Rates of Reaction Collision Theory
An activated complex is an unstable
arrangement of atoms that forms momentarily at
the peak of the activation-energy barrier.
The activated complex is sometimes called the
transition state.
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Factors Affecting Reaction Rates
Factors Affecting Reaction Rates
What four factors influence the rate of a
chemical reaction?
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Factors Affecting Reaction Rates
The rate of a chemical reaction depends
upon temperature, concentration,
particle size, and the use of a catalyst.
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Factors Affecting Reaction Rates
Animation 22
Explore several factors that control the speed of a
reaction.
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>Rates of Reaction Factors Affecting Reaction Rates
Temperature
Lower temperatures = Slower reactions
Higher temperatures = Faster reactions
Storing foods in a refrigerator keeps them fresh
longer. Low temperatures slow microbial action.
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>Rates of Reaction Factors Affecting Reaction Rates
Concentration
Higher concentration = faster reactions
a. In air, a lighted splint glows and soon goes out.
b. When placed in pure oxygen (higher oxygen concentration), the splint bursts into flame.
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>Rates of Reaction Factors Affecting Reaction Rates
Particle Size
Smaller Particles = More surface area = faster reactions
The minute size of the reactant particles (grain dust), and the mixture of the grain dust with oxygen in the air caused the reaction to be explosive, destroying the grain elevator.
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>Rates of Reaction Factors Affecting Reaction Rates
Catalysts
Catalysts are substances that increase the rate
of a reaction without being used up during the
reaction.
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>Rates of Reaction Factors Affecting Reaction Rates
An inhibitor is a substance that interferes with
the action of a catalyst. Antioxidants and
antimicrobials used in drying fruits and
preserving fruit juices slow the action of microbes
and limit contact with air.
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