year 12 chemistry easter revision session learning outcomes - cer: be aware of the key skills...
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Year 12 Chemistry Easter Revision Session
Learning Outcomes - CER:• Be aware of the key skills required in the AS
chemistry exams.• Pick up some useful exam tips.
Content (if time allows):• Mechanisms• Reactions of alcohols• Analysis• Enthalpy
Mechanisms - 1• You need to know 3 different mechanisms for this paper.
• The first one involves the reaction between alkenes and chemicals such as Br2
• Write a balanced equation (using displayed formulae) for the reaction between ethene and bromine, name the product formed and state what type of mechanism this is.
• Now draw out the mechanism.
Mechanisms - 1• Now redraw/adapt this mechanism for the reaction
between ethene and hydrogen chloride.
• What would be different about this reaction if you used propene as your organic starting material instead of ethene?
• Draw out the two products formed using skeletal formulae and structural formulae, and name both of them.
• Alkenes can also be used to form alcohols and alkanes. In each case state the conditions required for the reaction.
• Write a balanced symbol equation for the hydrogenation of but-1,3-diene.
Mechanisms – 1• An example PPQ from CER June 10 – definitely worth
attempting this question at some point during your revision (if we have time we’ll come back to it).
Mechanisms - 2• The second curly arrow mechanism you need to be aware of
is used for the reaction between halogenoalkanes and ____?
• What is the name of this type of mechanism?
• Write a balanced equation for the reaction between 1-iodopropane and sodium hydroxide.
• Now draw a mechanism for this reaction and name the product formed.
• What simple chemical test could you use to check that this reaction had occurred?
Mechanisms - 2• Would iodoethane hydrolyse faster or slower than
chloroethane? Explain your answer.
Iodoethane would hydrolyse faster because the C-I bond is weaker than the C-Cl bond.
Mechanisms - 3• Radical substitution.
• Attempt Q4 from CER Jan 10 – you have 9 mins max.
• The second page (part b) is included for those that finish quickly.
• The markscheme is printed on the back so that you can see it in detail later – DO NOT LOOK AT IT YET!!!
Reactions of alcohols:• There are two ways to make ethanol that you should know.
• For each method you need to be able to give the conditions and starting material(s), write balanced equations, and state advantages and disadvantages of each.
Reactions of alcohols:Divide your mini-whiteboard/page as shown below and see how many boxes you can complete.
Name of method 1, balanced equation and conditions.
Advantages of method 1
Disadvantages of method 1
Name of method 2, balanced equation and conditions.
Advantages of method 2
Disadvantages of method 2
Reactions of alcohols:• You’ve covered four different reactions of alcohols in this
course. What are they?
• Oxidation
• Esterification
• Combustion
• Dehydration
Reactions of alcohols:• You need to be able to write balanced equations for each
of these reactions. • We’ll come back to oxidation in a moment so instead write
balanced equations for:
• the esterification reaction between propan-1-ol and ethanoic acid (and name the product formed),
• the dehydration of butan-1-ol (stating the conditions required),
• and also the combustion of pentan-2-ol.
Reactions of alcohols:• the esterification reaction between propan-1-ol and
ethanoic acid (and name the product formed)
CH3COOH + CH3CH2CH2OH CH3COOCH2CH2CH3 + H2O propyl ethanoate
• the dehydration of butan-1-ol (stating the conditions required),
CH3CH2CH2CH2OH CH3CH2CH=CH2 + H2O
conditions required = conc. H2SO4 and heat
Reactions of alcohols:
• and also the combustion of pentan-2-ol.
CH3CH2CH2CH(OH)CH3 + 7.5 O2 5 CO2 + 6 H2O
Make sure you don’t forget about this oxygen when balancing the equation
Reactions of alcohols:
• Write down everything you can remember about the oxidation of alcohols on your mini-whiteboard – 1 min.
• Compare your efforts with the person sat next to you – 1 min.
• I’m now going to ask everyone to state one fact about the oxidation of alcohols.
Reactions of alcohols:• Students often find it difficult to write out the balanced
equations for these reactions.
• Have a go at writing balanced equations (using displayed formulae) for the oxidation of:
• Ethanol (distillation conditions)
• Propan-1-ol (reflux conditions)
• Propan-2-ol
We’ll come back to this section in a moment when we look at PPQ that combines oxidation of alcohols and analysis.
Analysis:• Infra-red spectroscopy and mass spectrometry.
• With regards to the analysis of organic molecules, what does each technique tell us about a molecule?
• IR – tells us the types of bonds that are present.
• MS – tells us the molar mass of the whole molecule and also of fragments of the molecule.
Analysis:• Infra-red spectroscopy:
• This spectra either represents propan-1-ol, propanal or propanoic acid.
• State which compound it is giving reasons for your answer.
Analysis:• Mass spectrometry:
• This spectra has been produced from pent-1-ene.• Identify the ions responsible for the peaks labelled A, B and
C.• What name is given to peak A?
Analysis:• Attempt the PPQ combining analysis and oxidation of
alcohols taken from the CER Jan 10 paper – you have 7 mins max.
• Once again the markscheme is on the back of your handout to make it easier for you to read it later - DO NOT LOOK AT IT YET!!
You also have this on the back of your handout so don’t worry if you can’t read this slide clearly.
Enthalpy:• There are three ways to determine the enthalpy change of
a reaction:
• Measure it directly
• Calculate it from bond enthalpies
• Calculate it from enthalpy of combustion or formation data via a Hess cycle.
Enthalpy:• Measuring enthalpy changes directly (CER Jan 10, Q3 a+b):
Enthalpy:• Calculate enthalpy changes from bond enthalpy data
(CER June 10, Q1 c):
Enthalpy:• Calculate from enthalpy of formation data via a Hess cycle
(CER June 10, Q1 d):
Enthalpy:• Calculate from enthalpy of combustion data via a Hess
cycle (CER Jan 10, Q3 c):